e-mail [email protected] FAX 04-7136-3756e-mail [email protected] FAX 04-7136-3756 1990...

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e-mail [email protected] FAX 04-7136-3756 1990 Harada 1) cyclodextrin (CD) polyethylene glycol (PEG) CD PEG 2000 2) PEG -CD -CD Slide-Ring Materials 1999 de Gennes 3) sliding gel 1839 2000

Transcript of e-mail [email protected] FAX 04-7136-3756e-mail [email protected] FAX 04-7136-3756 1990...

Page 1: e-mail kohzo@k.u-tokyo.ac.jp FAX 04-7136-3756e-mail kohzo@k.u-tokyo.ac.jp FAX 04-7136-3756 1990 Harada 1) cyclodextrin (CD) polyethylene glycol (PEG) CD PEG 2000 2) PEG -CD-CD Slide-Ring

e-mail [email protected]

FAX 04-7136-3756

1990 Harada 1) cyclodextrin

(CD) polyethylene glycol (PEG)

CD PEG

20002) PEG -CD

-CD

Slide-Ring Materials 1999

de Gennes3) sliding gel

1839

2000

Page 2: e-mail kohzo@k.u-tokyo.ac.jp FAX 04-7136-3756e-mail kohzo@k.u-tokyo.ac.jp FAX 04-7136-3756 1990 Harada 1) cyclodextrin (CD) polyethylene glycol (PEG) CD PEG 2000 2) PEG -CD-CD Slide-Ring

PEG -CD

CD

CD

35000 PEG 90 100 CD4)

CD

CD

PEG/CD CD

DMSO NaOH Li DMAc DMF Ca(SCN)2

5)

CD

PEG

-CD

PEG PPG -CD6)

CD

CD

24000

24 80 90%

7)

Page 3: e-mail kohzo@k.u-tokyo.ac.jp FAX 04-7136-3756e-mail kohzo@k.u-tokyo.ac.jp FAX 04-7136-3756 1990 Harada 1) cyclodextrin (CD) polyethylene glycol (PEG) CD PEG 2000 2) PEG -CD-CD Slide-Ring
Page 4: e-mail kohzo@k.u-tokyo.ac.jp FAX 04-7136-3756e-mail kohzo@k.u-tokyo.ac.jp FAX 04-7136-3756 1990 Harada 1) cyclodextrin (CD) polyethylene glycol (PEG) CD PEG 2000 2) PEG -CD-CD Slide-Ring

1/3

7)

Page 5: e-mail kohzo@k.u-tokyo.ac.jp FAX 04-7136-3756e-mail kohzo@k.u-tokyo.ac.jp FAX 04-7136-3756 1990 Harada 1) cyclodextrin (CD) polyethylene glycol (PEG) CD PEG 2000 2) PEG -CD-CD Slide-Ring

tan

tan

1 SeRM

tan

tan

Page 6: e-mail kohzo@k.u-tokyo.ac.jp FAX 04-7136-3756e-mail kohzo@k.u-tokyo.ac.jp FAX 04-7136-3756 1990 Harada 1) cyclodextrin (CD) polyethylene glycol (PEG) CD PEG 2000 2) PEG -CD-CD Slide-Ring
Page 7: e-mail kohzo@k.u-tokyo.ac.jp FAX 04-7136-3756e-mail kohzo@k.u-tokyo.ac.jp FAX 04-7136-3756 1990 Harada 1) cyclodextrin (CD) polyethylene glycol (PEG) CD PEG 2000 2) PEG -CD-CD Slide-Ring

Flory-Rhener

Flory-Rhener

Flory-Rhener 8)

Page 8: e-mail kohzo@k.u-tokyo.ac.jp FAX 04-7136-3756e-mail kohzo@k.u-tokyo.ac.jp FAX 04-7136-3756 1990 Harada 1) cyclodextrin (CD) polyethylene glycol (PEG) CD PEG 2000 2) PEG -CD-CD Slide-Ring

1) A. Harada et al., Nature, 356, 325 (1992). 2) Y. Okumura and K. Ito, Adv. Mater., 13,

485 (2001). 3) P. G. de Gennes, Physica A, 271, 231 (1999). 4) J. Araki et al., Macromolecules, 38,

7524 (2005). 5) J. Araki and K. Ito, Soft Matter, 3(12), 1456 (2007). 6) K. Kato et al.,

Macromolecules, 43, 8799 (2010). 7) J. Araki et al., Soft Matter, 4, 245 (2008). 8) N. Murata et al.,

Macromolecules, 42 (21), 8485 (2009).