ch03_141

36
p. 74

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Transcript of ch03_141

  • p. 74

  • pp. 74-75

  • p. 75

  • Table 3-2, p. 79

  • p. 84Naming Organic Molecules

  • Table 3-3, p. 80

  • p. 84Naming Organic Molecules

  • Table 3-4, p. 81

  • Some alkanes have nonsystematic, common namesThree-carbon alkyl group

    Four-carbon alkyl groups

    Five-carbon alkyl groupsNaming Alkyl Groups

  • p. 82

  • p. 84Naming Organic Molecules

  • p. 84Molecular Conformations

  • Molecular ConformationsEthane

  • Melvin Spencer NewmanNewman Projections

  • Molecular ConformationsDihedral angle

  • Fig. 3-7, p. 92

  • Hyperconjugation in Ethanes-bonding orbitals*-antibonding orbital

  • Overlap= 0.173Overlap= 0.087

  • Molecular ConformationsPropane

  • Molecular ConformationsButane

  • Fig. 3-9, p. 95

  • End

  • Table 3-5, p. 95

  • Lineolic AcidA polyunsaturated fat

  • p. 78

  • Fig. 3-3, p. 82

  • Fig. 3-3a, p. 82

  • Fig. 3-3b, p. 82

  • Fig. 3-8, p. 93

  • p. 93

  • p. 94

  • p. 94

  • p. 92

    **************Figure 3.7A graph of potential energy versus bond rotation in ethane. The staggered conformers are 12 kJ/mol lower in energy than the eclipsed conformers.***Figure 3.9A plot of potential energy versus rotation for the C2C3 bond in butane. The energy maximum occurs when the two methyl groups eclipse each other, and the energy minimum occurs when the two methyl groups are 180 apart (anti). Go to this books student companion site at www.cengage.com/chemistry/mcmurry to explore an interactive version of this figure.***Figure 3.3Alkyl groups generated from straight-chain alkanes.*Figure 3.3Alkyl groups generated from straight-chain alkanes.*Figure 3.3Alkyl groups generated from straight-chain alkanes.*Figure 3.8Newman projections of propane showing staggered and eclipsed conformations. The staggered conformer is lower in energy by 14 kJ/mol.****