27Apr2016 Page 1 of 15 FLUOR®4.6 Cycle Chemistry Guidelines for Combined Cycle/ Heat Recovery Steam...

Duke Energy Florida Citrus County Combined Cycle Project Contract A5VI

FLUOR®

Project Calculation CCCOO-CA-M-YA.00.00-01 27Apr2016

Page 1 of 15 Revision B

CHEMICAL ADDITION SYSTEM SIZING CALCULATIONS

This document has been revised as indicated below and described in the revision record on the following page Please destroy all previous revisions.

Revision Number

Date Originator's Name & Initials Reviewed / Checked By Name

A 31-Jul-15 David Rhodes

B 27-Aor-16

APPROVALS

Lead Engineer:

Engineering Manager:

ISSUED FOR: 0Design

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& Initials

Dennins McBride

SIGNATURES

D Construction [El Other IFR

Pages Revised

N/A

All

Mechanical Engineering


FLUOR® CHEMICAL ADDITION SYSTEM SIZING CALCULATIONS



Record of Revisions

Rev No Date A 31-Jul-15 Issued for Review (IFR} B 27-Apr-16 Issued for Review (IFR}

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Description


Duke Energy Florida Project Calculation CCCOO-CA-M-YA.00.00-01 27Apr2016

Page 3 oflS RevisionB

Citrus County Combined Cycle Project Contract ASVI

CHEMICAL ADDITION SYSTEM SIZING CALCULATIONS

1.0 PURPOSE AND SCOPE The purpose of this calculation is to determine the sizing and design parameters of the Chemical Addition (YA) System for the cooling tower, condensate and HRSG.

2.0 DESIGN CRITERIA

2.1

2.2

2.3

2.4

Per the Scope of Facilities Section 3.8.3 (Reference 4.3) The cooling tower Chemical Addition System shall provide treatment of the circulating water to control deposition, corrosion, and biofouling in the condenser, heat exchangers, cooling tower, and associated piping

Per the Nalco cooling tower treatment recommendations for Citrus County (Reference 4.1) The following are the recommended treatment plans for the cooling tower and makeup

Chemical Service Treatment Volume Treatment Duration Sodium Hypochlorite Cooling Tower 150 gallons 30 minutes Sodium Bromide Cooling Tower 15 gallons 30 minutes Biopenetrant Cooling Tower 5 gallons 30 minutes Dispersant Cooling Tower 30 gallons continuous

Sodium Hypochlortie Makeup Water 150 gallons 30 minutes Bromine Makeup Water 15 gallons 30 minutes Sodium Bisulfite Slowdown Stream 10 allons 90 minutes

Per the Nalco cooling tower treatment recommendations for Citrus County (Reference 4.1) Dechlorination product should be fed at a rate of 3.6 ppm per 1 ppm chlorine residual.

Per Reference 4.2, the Case 14 blowdown and dilution flowrates are as follows

Daily Usage 150 gallons 15 gallons 5 gallons 30 gallons

75 gallons 7.5 gallons 10 allons

Makeup (Per Cooling Tower) Slowdown Dilution Discharge Total

14006 gallons per minute 21547 gallons per minute 43093 gallons per minute 64640 gallons per minute

2.5 Cooling Tower Chemical Tanks to be sized for at least 30 days storage and to accommodate half-tank refills Refill sizes are as follows:

Sodium Hypochlorite Sodium Bromide Sodium Bisulfite Dispersant Biopenetrant

5000 Gallons split between 2 of 3 tanks 2000 Gallons split between 2 of 3 tanks 2000 Gallons for 1 tank 2500 Gallons split between 2 tanks 1000 Gallons split between 2 tanks

2.6 Ammonia tank requires less storage capacity due to more frequent ammonia delievery schedule for the Selective Catalytic Reduction Ammonia Tanks. Storage required for cycle ammonia will be 2 weeks.

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3.0 ASSUMPTIONS

3.1 Chlorine residual from all sources is 1 ppm

3.2 Chlorine solution concentration is 10%

3.3 Cooling tower volume is 1,200,000

3.4 Stochiometric Sodium Bromide to Sodium Hypochlorite is 0.3:1.0

3.5 Target Chlorine Residual is 5 ppm in all services

3.6 Phosphate Concentration is 5%

4.0 REFERENCES



4.1 Nalco Water Treatment Proposal Citrus County Combined Cycle Station. Seen in Attachment 1

4.2 Citrus County Water Ba!ance CCCOO-ME-M-WB-01 Rev. B

4.3 Citrus County Exhibit A-2 Scope of Facilities CCCOO-SP-G-00-02, Rev. 1

4.4 "Nalco Product Weights" 7/05/2015: Email from Ellie Palomo to Jeff Richardson. Seen in Attachment 2

4.5 Citrus County Heat Balance CCCOO-ME-M-FD-01 Revision C

4.6 Cycle Chemistry Guidelines for Combined Cycle/ Heat Recovery Steam Generators (HRSGs), EPRI, March 2006 Figure 3-2: Seen in Attachment 3

4.7 Ammonia Addition Table: Seen in Attachment 4

5.0 CALCULATION Cooling Tower Chemical Addition Calculations

5.1 Per Reference 4.4, the density of the chemicals and maximum tanker truck delivery weight are as follows.

Maximum Tanker Truck Weight Sodium Hypochlorite Bromine Sodium Bisulfite Dispersant Biopenetrant

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49500 pounds 9.86 pounds/gallon 12.2 pounds/gallon 11.4 pounds/gallon 9.4 pounds/gallon 8.4 pounds/gallon·



5.2 Cooling Tower Sodium Hypochlorite

----------------------~---- -- -


Page 5 of15 Revision B

Sodium Hypochlorite will be added to the cooling tower basin to be used as an oxidizing biocide. This will be injected in intermittently over a period of 10 minutes.

Cooling water volume -Chlorine feed Bleach concentration Bleach Specific Gravity Bleach weight per dose Bleach volume per dose

Sodium _Hypochlorite usage per cooling tower per day Total sodium hypochlorite usage per day for two cooling towers Duration of sodium hypochlorite injection Flow rate required for chemical feed Specify max pump flow rate

Maximum tanker size Storage required for 30 days usage per cooling tower Refill Size per Design Criteria 2.5 Size of storage tank considering tanker size (per tower)

Days usage with full tank

5.3 Cooling Tower Bromine

1,200,000 gallons 8 parts per million

10% 1.175

800.64 pounds 81. 70 gallons

81. 70 gallons 163.40 gallons

30 minutes 2·.12 gallons per minute

6 gallons per minute

5020 gallons 2451 gallons per 30 days 2500 gallons 5000 gallons

61.2 days

Bromine will be added to the cooling tower basin to enhance the biocidal capabilities of the sodium hypcichlorite. This will be injected in intermittently over a period of 30 minutes.

Stochiometic ratio of NaBr to NaOCI Sodium Hypochlorite use per injection

Bromine usage per cooling tower per day

Total bromine usage per day for two cooling towers

Duration of sodium hypochlorite injection Flow rate required for chemical feed

Specify pump flow rate

Maximum tanker size Storage required for 30 days usage per cooling tower

Refill Size per Design Criteria 2.5 Size of storage tank considering for tanker size (per tower)


Copyright © 2015, Fluor Coiporation. AH Rights Reserved. CCCOO-CA-M-Y A.00.00-0 l _RB.xlsx

0.3 81.70 gallons

24.51 gallons

49.02 gallons

30 minutes 0.82 gallons per minute

1.6 gallons per minute

4057 gallons 735 gallons per 30 days

1000 gallons 2000 gallons

81.6 days


Duke Energy Florida Citrus County Combined Cycle Project Contract ASVI

5.4 Cooling Tower Dispersant



Dispersant will be added to the cooling tower basin to dissipate any biological formation. Per Reference 4.1, the recommended dispersant usage rate per cooling tower is 30 gallons per day. This will be injected continuously during the day.

Dispersant usage per cooling tower per day Total dispersant usage per day for two cooling towers Duration of dispersant injection Flow rate required for chemical feed Specify pump flow rate



5.5 Cooling Tower Biopenetrant

30 gallons 60 gallons 24 hours

1.25 gallons per hour 1.5 gallons per hour



100.0 days

Biopenetrant will be added to the cooling tower basin to increase biocidal effictiveness. Per Reference 4.1, the recommended biopenetrant usage rate per cooling tower is 5 gallons per day. This will be injected in intermittently over a period of 30 minutes.

Biopenetrant usage per cooling tower per day Total biopenetrant usage per day for two cooling towers Duration of biopenetrant injection Flow rate required for chemical feed Specify pump flow rate



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0.5 hours 10 gallons per hour 12 gallons per hour

5893 gallons 150 gallons per 30 days 500 gallons

1000 gallons

200.0 days



Makeup Chemical Addition Calculations . 5.6 Makeup Sodium Hypochlorite


Page 7 of15 Revision B

Sodium Hypochlorite will be added to the cooling tower makeup water to be used as an oxidizing biocide. This will be injected in intermittently over a period of 30 minutes every other day.

Cooling water volumetric flow rate Chlorine feed Bleach concentration Bleach Specific Gravity Bleach weight per dose Bleach volume per dose

Sodium Hypochlorite usage per injection Duration of sodium hypochlorite injection Flow rate required for chemical feed Specify pump flow rate

Maximum tanker size Storage required for 30 days usage

Refill Size per Design Criteria 2.5 Size of storage tank considering tanker size and deliveries Days usage with full tank

5.7 Makeup Bromine

28,012 gallons per minute 5 parts per million

10%.

1.175 11.68 pounds per minute


35.76 gaUons 30 minutes

1.19 gallons per minute .1.5 gallons per minute



279.6 days

Bromine will be added to the cooling tower makeup water to increase biocide effectiveness. This will be injected in intermittently over a period of 30 minutes every other day during hypochlorite injection.

Stochiometfc ratio of NaBr to NaOCI Sodium Hypochlorite use per injection Bromine usage per cooling tower per injection Duration of bromine injection Flow rate required for chemical feed Specify pump flow rate

Maximum tanker size Storage required for 30 days usage

Refill Size pe.r Design Criteria 2.5 Size of storage tank considering tanker size and deliveries


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0.3 35. 76 gallons 10. 73 gallons

30 minutes 0.36 gallons per minute




372.9 days.·


i


5.8 Discharge Dechlorination



Sodium Bisulfite will be added to the discharge canal to remove any chlorine residuals from water treatment Per Assumption 3.3, the chlorine residual is 1 ppm. A factor of safety of 5 will be added to this residual to ensure that dechlorination meets all code requirements Per Design Criteria, 2.3 the minimum required declorination per chlorine residual is 3.6 ppm per 1 ppm chlorine' The sodium bisulfite will be added during chlorination

Per Reference 4.2, the Case 14 blowdown and dilution flowrates are as follows Slowdown 21547 gallons per minute Dilution 43093 gallons per minute Discharge Total 64640 gallons per minute

Maximum Required Dechlorination Flow Rate Chlorine Residual Factor of Safety for chlorine residual Bleach Specific Gravity Bleach Residual Mass Flow Rate Bleach Residual Volumetric Flow Rate Sodium Bisulfite per Chlorine Residual Sodium Bisulfite Required Sodium Bisulfite Specific Gravity Sodium Bisulfite Feed Rate Time of Dechlorination Dose Number of Dechlorinations per day Maximum Bisulfite Feed Daily

Maximum flow rate required for chemical feed Specify pump flow rate Minimum flow rate required for chemical feed Minimum flowrate@ 10:1 turndown

Maximum tanker size Storage required for 30 days usage Refill Size per Design Criteria 2.5 Size of storage tank considering tanker size and deliveries


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64,640 gallons per minute 1 part per million 5

1.175 2.70 pounds per minute 0.28 gallons per minute

3.6 pounds NaHS03 per pound Cl2 9.70 pounds per minute 1.37 0.85 gallons per minute

30 minutes 2 Dechlorinations per Day

51.0 Gallons

0.85 gallons per minute 1 gallons per minute

0.28 gallons per minute 0.1 gallons per minute

4342 gallons 1529 gallons per 30 days 2000 gallons 4000 gallons

78.5 days



Project Calculation CCCOO-CA-M-YA.00.00-01 27Apr20I6


Condensate and HRSG Chemcial Addition Calculations 5.9 Condensate Ammonia Addition

Condensate Flow Rate per Ref 4.5 Case 14 1,848,500 lb/hr

PPM Ammonia Required for Desired pH (Attachment 4)

10"-6 factor

2.2 # ammonia per million# h20

0.000001

Ammonia Concentration

Specific Gravity

Density

Flow Rate Required

Select pump flow rate

Gallons per Day Required per Unit

Gallons per Day Required Plant

Gallons per Month Condensate Addition Whole Plant

Size of tank considering tanker size and design criteria 2.6


5.10 HRSG Phosphate Chemical Addition

HP Phosphate

HP Blowdown Flow Rate per Ref 4.5 Case 71

0.19

0.9

7.506 lb/gal

2.85 gph

3 gallons per hour

68.44 gpd

136.87 gpd

4106 gallons per month

2000 gallons

14.6 days

8,462 lb/hr

HP Drum Pressure 2407.9 psia

Select Max Phosphate Required (Attachment 3) 2 # phosphate per million# h20

10"-6 factor 0.000001

Phosphate Concentration (Assumption 3.6) 0.05

Phosphate will be multiplied by 4 since the phosphate:sodium ratio in trisodium phosphate is 1:3

Trisodium Phosphate Factor 4

Density 9 lb/gal

Flow Rate Required per HRSG 0.150 gph

Flow Rate Required per Block 0.301 gph

Select HP metering pump flow rate


0.35 gallons per hour





IP Phosphate

IP Blowdown Flow Rate per Ref 4.5 Case 71 1,120 lb/hr

IP Drum Pressure 598.6 psia

Select Max Phosphate Required (Attachment 3) 4 # phosphate per million# h20

10"-6 factor 0.000001

Phosphate Concentration (Assumption 3.6) 0.05

Phosphate will be multiplied by 4 since the phosphate:sodium ratio in trisodium phosphate is 1:3

Trisodium Phosphate Factor 4

Density 9 lb/gal

Flow Rate Required per HRSG 0.0398 gph

Flow Rate Required per Block 0.0796 gph

Select IP metering pump flow rate 0.1 gallons per hour

Gallons per Day Required per HRSG

Gallons per Day Required per Block

Size of Storage Tank (per block)

Days Usage with full tank

6.0 CONCLUSION

4.57 gpd

9.13 gpd

800 gallons

87.6 days

6.1. The following table gives pump flow rates as well as tank sizes for the chemical addition system.

Summary Chemical Service Pump Flow Rate Tank Size Days Storage with Tank Sodium Hypochlorite Cooling Tower Sodium Bromide Cooling Tower Biopenetrant Cooling Tower Dispersant Cooling Tower Sodium Hypochlorite Makeup Sodium Bromide Makeup Dechlorination Discharge Ammonia Condensate HP Phosphate HP Drum IP Phosphate IP Drum


6 gpm 5000 gallons 61.2 Days 1.6 gpm 2000 gallons 81.6 Days 12 gph 1000 gallons 200.0 Days 1.5 gph 3000 gallons 100.0 Days 1.5 gpm 5000 gallons 279.6 Days 0.5 gpm 2000 gallons 372.9 Days

1 gpm 4000 gallons 78.5 Days 3 gph 2000 Gallons 14.6 Days

0.35 gph 800 Gallons 87.6 Days 0.1 gph Shared with HP 87.6 Days




Attachment 1 - Page 11 of 15 Revision B

CHEMICAL ADDITION SYSTEM SIZING CALCULATIONS - Attachment 1

NALCO An Ecolab Company Water Treatment Proposal

ef_~DUKE ~ ENERGY"'

Citrus County Combined Cycle Station

Plant of: Duke Energy Citrus County Combined Cycle Station Date: 07/02/15 Address: Power Line Street Plant : Citms Comity

City: Crystal River State: Florida Zip: _3_4_4_28 _____ Count1y: USA Attention: _J;...e_n_-_Ri_·c_h_a_rd_s_o_n __________________________ _

Copy lo: _F_lt_1o_r_C_'c_m_1.._p_m~w'------------------------------Nalco Copy to: Brandt Anton, Chris Bain ------~------------------------------

The following water treatment proposal is provided for the cooling water systems at Duke Energy's Citms County combined cycle station. Attaclunent

Cooling Towers: We recommend the following treatment chemicals for each cooling tower system. The calculated usage rates are for one cooling tower system. The recommended bulk tank sizing is based upon one tank fann that can supply chemicals to both cooling tower systems.

l. Chlorine Dioxide Biocide Treatment Nalco reconm1ends installing one chlorine dioxide generator for each cooling tower. If the cooling towers are located within a close proximity of each other, one chlorine dioxide generator can be utilized for both cooling towers. Sulfuric acid and Purate chemicals will be utilized by the generator to create the chlorine dioxide biocide treatment. One, 6,000 gallon sulfuric acid tank will be required. The approximate usage rate for the 93% sulfmic acid is 8 gallons per day. Nalco will supply the one 6,000 gallon tank for the Purate chemical. The approximate usage rate of Purate chemical is 12 gallons per day.

2. Bleach/Bromine Biocide Treatment (In place of Chlorine Dioxide) If the bleach and bromine system is utilized in place of the chlorine dioxide system, the estimated bleach usage rate is 150 gallons per day and the estimated bromine usage rate is 15 gallons per day. Tank size recommendation: 7,000 gallon bleach tank, 3,000 gal bromine tank.

3. Dechlorination Nalco product 7408. This product will neutralize any chlorine residual that will be discharged from each cooling tmver. This should be feed at 3.6ppm per lppm of free chlorine residual. At a 4ppm dosage rate for 90 minutes per day, the estimated usage rate is IO gallons per day. Tank size recommendation: 2,500 gallons.

4. Dispersant Nalco product 3DT12I. Nalco's recommendation is to feed this product on a continuous basis at 2ppm. This product can be fed directly from the measurement on the 3D Trasar unit. The north plant is hialing this product at 3ppm during the biocide addition, per the change in their NPDES pennit. At a dosage rate of 2ppm, continuous feed, the estimated usage rate is 30 gallons per day. Tank size recommendation: 7,000 gallons.

5. Biopenetrant Nalco 73551. This product will he fed dtiring the biocide injection to help loosen any biofilms that may have accumulated on the fill or other surfaces. The estimated usage rate is 5 gallons per day. Tank size recommendation: 275 gallµn tote.

Si ned: Ellie Palomo 813 767-0334 Tille: Senior Account Mana er District: WH-104 Nalco Com an 1601 Diehl Road Na ervllle Illinois 60563-1198

Dear Customer· If you ate not 100% satisfied with Nalco. please call our Complaint Hotline: (Phone) 1-800-732-5572; (Fax) 1-800-732-5573; (e-mail) [email protected]

Copyright© 2015, Fluor Corporation All Rights Reserved. CCCOO-CA-M-Y A.00.00-0 l_ RB.xlsx Mechanical Engineering



NALCO An Ecolab Company Water Treatment Proposal



(-,DUKE ~ ENERGY"

Citrus County Combined Cycle Station

Plant of: _D_u_k_e_E_1_1e_r.,..g.:...y_C_i_a_·u_s_C_ot_m_t.,,.y_C_o_m_b_ir_1e_d_C.,,.y_c_le_S_ta_t1_· o_n____ Date: _07_/_0_2_/_l 5 ___ _ Address: _P_ov._·e_r_L_i_ne_S_t1_·e_e_t_________________ Plant : _C_it_ru_s_C_,o_u_n~ty,___

City: Crystal River State: Florida Zip: _3_4_4_2_8 _____ Country: USA Attention: Jeff Richardson -------------------------------------Copy to: _F_lt_1o_r_C_o_1_n~p_a_n~y ____________________________ _

Nalco Copy to: _B_r_a_nd_t_A_n_to_n~, _C_h_r_is_B_a_in _________________________ _

Make Up Water Linc to the Cooling Towers: Nalco recommends bleach and bromine biocide treatment for the 14,500ft long intake make up water line to the cooling towers. One bulk tank of bleach and one bulk tank of bromine, along with a chemical skid, will be required for this application. At a feed rate of 30 minutes per day, every other day. the estimated usage rate of bleach is 150 gallons per application. The estimated usage rate of bromine is 15 gallons per application. Tank size recommendation: 7,000 gallon bleach tank, 3,000 gallon bromine tank. The annual chemical cost is approximately$ 65,618.

3D Trasar We recommend the installation of one 3D Trasar controller on each cooling tower system. The units require 115V AC 20 amp power, a %" pressurized inlet, and a %" and W' outlet (to iower pressure to allow flow through unit). The 3D Trasar device directly measures the Nalco 30 Trasar product residuals, pH, conductivity, ORP, turbidity, and 2 different inline corrosion measurements. The 30 Trasar can directly control the chemical feed pumps for the 30T products or the signals can be sent via 8 different 4-20 mA outputs lo the control room so that the DCS can control the pumps.

Auxiliarv Cooling Water Svstems: Nitrite chemical is recommended for the scale and corrosion control for these systems. One 300 gallon tank should be installed for each auxiliary cooling water system. One chemical feeder (pol feeder) should also be installed for the periodic addition of biocide chemicals. One PVC con-osion coupon rack should be installed for the measurement of corrosion and surface microbiological activity.

Signed: Ellie Palomo 813 767-0334 Title: Senior Account Mana er District: WH-104 Nalco Com an 1601 Diehl Road Na erville Illinois 60563-1198

Dea'.. Customer - If you are not "l00% satisfied with Nalco. please call our Complaint Hotline: (Phone) 1-800·732-5572; (Fax) 1-800-732·5573; (e-mail)

Copyright© 2015, Fluor Corporatioll All Rights Reserved. CCCOO-CA-M-Y A.00.00-0 l _ RB.xlsx Mechanical Engineering



From: Palomo, Ellie [mailto:[email protected]] Sent: Monday, July 06, 2015 7:50 AM To: Richardson, Jeff Cc: Anton, Brandt Subject: FW: Nalco Product Weights


Attachment 2 - Page 13 of 15 RevisionB

0• Exercise caution. This is an EXTERNAL email. DO NOT open attachments or click links from unknown senders or unexpected

email.*** Jeff,

FYI, the current bulk deliveries at the Crystal River station range from 45,000 to 49,500 pounds; the average is around 48,000 pounds per truck load. For the bromine and sodium bisulfite, we have those delivered on the same truck so that we are able to fill up the truck and manage those smaller bulk tanks, 2,500 gallons and 3,000 gallons, respectively. Those bulk tanks are a little too small because It gives us a small delivery window especially when the daily usage rates can change. Give me a call if you have any questions.

Thanks.

Sincerely,

Ellie Palomo Senior Account Manager Nalco Company Cell: 813-767-0334

From: Palomo, Ellie Sent: Sunday, July OS, 2015 8:01 PM To: Richardson, Jeff ([email protected]) Cc: Anton, Brandt Subject: Nalco Product Weights

Jeff,

In response to your voicemail from Thursday afternoon, here are the pounds/gallon weights for the proposed products at Citrus County:

Product Pounds/Gallon

Bleach 12.5% 9.86

Bromine 12.2

Sodium Bisulfite 11.4

3DT121 9.4

73551 8.4

Purate 11.S

Sulfuric Acid 93% 15.3

Please contact me if you need anything else.

Thanks.

Sincerely, Ellie Palomo Senior Account Manager Nalco Company Cell: 813-767-0334

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Cycles witlz Dmm HRSGs on Piwsp!w.Ie Cootinuum (PC(l,) and PC(H))

e ~ o;D c;i s;; Q.





This table summarizes ammonia required to attain a certain pH Target pH for this application is 9.6, or 2.2 mg/I of NH3

r·· - --·---- -· - - -- - -- --- -- ---- .... ----- - --··---- ·- ------ --- ---

i NH3 I

equivalent, Undissociated I ipH pOH [OH]=fNH4l mall NH31 i 8.0 6.0 1.000E-06 0.017 5.637E-08 ; 8.1 5.9 1.259E-06 0.021 8.934E-08 : 8.2 5.8 1.585E-06 0.027 1.416E-07

8.3 5.7 1.995E-06 0.034 2.244E-07 l 8.4 5.6 2.512E-06 0.043 3.557E-07

8.5 5.5 3.162E-06 0.054 5.637E-07 i 8.6 5.4 3.981E-06 0.068 8.934E-07 ; 8.7 5.3 5.012E-06 0.085 1.416E-06 i 8.8 5.2 6.310E-06 0.107 2.244E-06 i 8.9 5.1 7.943E-06 0.135 3.557E-06 i 9.0 5.0 1.000E-05 0.170 5.637E-06

9.1 4.9 1.259E-05 0.214 8.934E-06 9.2 4.8 1.585E-05 0.269 1.416E-05 9.3 4.7 1.995E-05 0.339 2.244E-05

: 9.4 4.6 2.512E-05 0.427 3.557E-05 ! 9.5 4.5 3.162E-05 0.538 5.637E-05

9.6 4.4 3.981E-05 0.677 8.934E-05 ' 9.7 4.3 5.012E-05 0.852 1.416E-04 ' 9.8 4.2 6.310E-05 1.073 2.244E-04

9.9 4.1 7.943E-05 1.350 3.557E-04 I 10.0 4.0 1.000E-04 1.700 5.637E-04 ; 10.1 3.9 1.259E-04 2.140 8.934E-04 ; 10.2 3.8 1.585E-04 2.694 1.416E-03 ; 10.3 3.7 1.995E-04 3.392 2.244E-03 i 10.4 3.6 2.512E-04 4.270 3.557E-03 l 10.5 3.5 3.162E-04 5.376 5.637E-03 ! 10.6 3.4 3.981E-04 6.768 8.934E-03 : 10.7 3.3 5.012E-04 8.520 1.416E-02 : 10.8 3.2 6.310E-04 10.726 2.244E-02 i 10.9 3.1 7.943E-04 13.504 3.557E-02 I 11.0 3.0 1.000E-03 17.000 5.637E-02 : 11.1 2.9 1.259E-03 21.402 8.934E-02 -----·-····- . --·-- ----·---- ·-- --------- -- -----~--- •s-•··· ·- ------·-----

Copyright© 2015, Fluor Corporation. All Rights Reserved. CCCOO-CA-M-Y A.00.00-0 l _RB.xlsx

- ··-- - ---- - - .. - - - -------------· ...

Undissociated NH3 equivalent, NH3 Total_, mq/1 lmg/1 ;

9.583E-04 0.018 1.519E-03 0.023 2.407E-03 0.029 3.815E-03 0.038 6.046E-03 0.049 9.583E-03 0.063· 1.519E-02 0.083' 2.407E-02 0.109: 3.815E-02 0.145' 6.046E-02 0.195: 9.583E-02 0.266. 1.519E-01 0.366; 2.407E-01 0.510' 3.815E-01 0.721· 6.046E-01 1.032; 9.583E-01 1.496,

1.519E+OO 2.196: 2.407E+OO 3.259' 3.815E+OO 4.888 6.046E+OO 7.397 9.583E+OO 11.283 1.519E+01 17.328, 2.407E+01 26.765! 3.815E+01 41.542; 6.046E+01 64_734: 9.583E+01 101.205 1.519E+02 158.646 2.407E+02 249.231'. 3.815E+02 392.227: 6.046E+02 618.141: 9.583E+02 975.286: 1.519E+03 1540.183: ---·----·-------·---- -- ---·--------


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