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    Energy and Environment

    and Environment

    in a 10 kWth

    Pilot

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    Energy and Environment

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    Reduction

    Oxidation

    MexOy-1+1/2 O2 MexOy (1)

    MexOy+ CO/H2 MexOy-1+ CO2/H2O (4)

    MexOy+ volatiles MexOy-1+CO2+H2O (2)

    C + H2O CO + H2 (3)

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    Energy and Environment

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    Energy and Environment

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    Energy and Environment

    0 0.2 0.4 0.6 0.8 1Fuel conversion (-)

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    Energy and Environment

    O2,AR(t = 0) - O2,AR(t) ~ tN-1.e-t/(/N)

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    Energy and Environment

    #

    The particle circulation had a beneficial effect on the conversion of syngas

    Higher temperature had a beneficial effect on the rate of char conversion

    The volatiles account for 75% of the total demand of oxygen. This is causedby fuel addition system, giving a volatiles release above the bed

    It was possible to model the system and derive a correlation betweenmeasured operational data and actual circulation mass flow

    From modelling, the carbon capture of the system vs. the residence timecould be obtained and compared to experimental expressions. The twoapproaches showed good agreement