XYLENE_EN

XYLENESafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH)Date of issue: 28.12.2007 Version: 1.0Revision date: 25.11.2010

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1. Identification of the substance/mixture and of the company/undertaking1.1. Product identifierChemical type : SubstanceName : XYLENE

EC index no : 601-022-00-9EC no : 215-535-7CAS No. : 1330-20-7REACH registration No. : 01-2119488216-32Local code : MOL_0202_003IUPAC : XyleneChemical name : Dimethylbenzene isomersFormula : C8H10Synonyms : Xylene S; Xilol S

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.2.1. Relevant identified usesIndustrial/Professional use spec. : intermediate

Polymer productionUse in laboratoriesExplosives manufacture&useRubber production and processingUse as a fuelUse in cleaning agentsUse in road and construction applicationsLubricantsManufacture of substancePolymer processingUse as a functional fluidsUse in agrochemicalsUses in coatingsUse in oil and gas field drilling and production operationsUse as release agents or binders

1.2.2. Uses advised againstNo relevant data available

1.3. Details of the supplier of the safety data sheetManufacturer: MOL Hungarian Oil and Gas PLC., RefiningAddress: 2443 Százhalombatta, POB.1. Telephone: +36-23-354-322, Fax:+36-23-553-122Distributor: MOL Hungarian Oil and Gas PLC.Address: 1117 Budapest, Október 23. u.18.Telephone, fax.: +36-1-209-0000The competent person responsible for Safety Data Sheet: [email protected]

1.4. Emergency telephone number

Country Official advisory body Address Emergency numberHUNGARY Országos Kémiai Biztonsági Intézet (National

Institute of Chemical Safety)Egészségügyi Toxikológiai Tájékoztató Szolgálat (HealthToxicological Information Service)

1437 Budapest PO Box 8391097Budapest, Nagyvárad tér 2

+36-80-20-11-99

HUNGARY Vegyipari Riasztási és Információs Központ(VERIK)FER TŰZOLTÓSÁG ÉS SZOLGÁLTATÓ KFT. (0-24 órás)

OLAJMUNKÁS ÚT. 2.2433Százhalombatta

+36-23-551-909

2. Hazards identification2.1. Classification of the substance or mixture

2.1.1. Classification according to Regulation (EC) No 1272/2008 [CLP/GHS]Flam. Liq. 3 H226Acute Tox. 4 (Dermal) H312Acute Tox. 4 (Inhalation) H332Acute Tox. 4 (Inhalation:vapour) H332Skin Irrit. 2 H315Eye Irrit. 2 H319Asp.Tox. 1 H304STOT SE 3 H335STOT RE 2 H373

XYLENESafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH)

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Full text of H-phrases: see section 16.

2.1.2. Classification according to Directive 67/548/EEC or 1999/45/ECR10Xn; R20/21Xi; R36/37/38Xn; R65Full text of R-phrases: see section 16.

2.1.3. Adverse physicochemical, human health and environmental effectsNo relevant data available

2.2. Label elements

2.2.1. Labelling according to Regulation (EC) No 1272/2008 [CLP/GHS]Hazard pictograms (CLP) :

GHS02

GHS07

GHS08

Signal word (CLP) : DangerHazard statements (CLP) : H226 - Flammable liquid and vapour

H304 - May be fatal if swallowed and enters airwaysH312 - Harmful in contact with skinH315 - Causes skin irritationH319 - Causes serious eye irritationH332 - Harmful if inhaledH335 - May cause respiratory irritationH373 - May cause damage to organs (lung, skin) through prolonged or repeated exposure(dermal, inhalation, oral)

Precautionary statements (CLP) : P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking.P243 - Take precautionary measures against static dischargeP260 - Do not breathe vapours.P280 - Wear eye protection, protective clothing, protective gloves.P301+P310 - If swallowed, immediately call a doctor.P331 - Do NOT induce vomitingP303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminatedclothing. Rinse skin with water/shower

2.2.2. Labelling according to Directive 67/548/EEC or 1999/45/ECHazard symbols :

Xn - Harmful

Xi - Irritating

R-phrases : R10 - Flammable.R20/21 - Harmful by inhalation and in contact with skin.R36/37/38 - Irritating to eyes, respiratory system and skin.R65 - Harmful: may cause lung damage if swallowed.

S-phrases : S2 - Keep out of the reach of children.S24/25 - Avoid contact with skin and eyes.

2.3. Other hazardsNo relevant data available


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3. Composition/information on ingredients3.1. Substances

Name Product identifier % (w/w)Concentration(range)

Classification according toDirective 67/548/EEC

Classification according toRegulation (EC) No 1272/2008[CLP/GHS]CAS No. EC no

xylene 1330-20-7 215-535-7 <= 100 R10Xn; R20/21Xi; R38

Flam. Liq. 3, H226Acute Tox. 4 (Dermal), H312Acute Tox. 4 (Inhalation), H332Skin Irrit. 2, H315

toluene 108-88-3 203-625-9 < 0,5 F; R11Repr. Cat. 3; R63Xn; R48/20-65Xi; R38R67

Flam. Liq. 2, H225Skin Irrit. 2, H315Repr. 2, H361dSTOT SE 3, H336STOT RE 2, H373Asp.Tox. 1, H304

benzene 71-43-2 200-753-7 < 0,1 F; R11Carc. Cat. 1; R45Muta. Cat. 2; R46T; R48/23/24/25Xn; R65Xi; R36/38

Flam. Liq. 2, H225Acute Tox. 3 (Oral), H301Acute Tox. 3 (Dermal), H311Skin Irrit. 2, H315Eye Irrit. 2, H319Muta. 1B, H340Carc. 1A, H350STOT RE 1, H372Asp.Tox. 1, H304

Full text of R-, H- and EUH-phrases: see section 16.

3.2. MixturesNot applicable


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4. First aid measures4.1. Description of first aid measuresFirst-aid measures general : Before attempting to rescue casualties, isolate area from all potential sources of ignition

including disconnecting electrical supply.Ensure adequate ventilation and check that a safe, breathable atmosphere is present beforeentry into confined spaces.Drench contaminated clothing with water before removing to avoid risk of sparks from staticelectricity.

First-aid measures after inhalation : if breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable forbreathing.If casualty is unconscious and:Not breathingEnsure that there is no obstruction to breathing and give artificial respiration by trainedpersonnel.If necessary, give external cardiac massage and obtain medical advice.BreathingPlace in the recovery position.Administer oxygen if necessary.Obtain medical attention if casualty has an altered state of consciousness or if symptoms do notresolve.

First-aid measures after skin contact : Remove contaminated clothing, contaminated footwear and dispose of safely.Wash affected area with soap and water.Seek medical attention if skin irritation, swelling or redness develops and persists.Do not wait for symptoms to develop.For minor thermal burns, cool the burnHold the burned area under cold running water for at least five minutes, or until the painsubsides.Body hypothermia must be avoided.

First-aid measures after eye contact : Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do soContinue rinsingIf irritation, blurred vision or swelling occurs and persists, obtain medical advice from aspecialist.

First-aid measures after ingestion : in case of ingestion, always assume that aspiration has occurred.The casualty should be sent immediately to hospitalDo not wait for symptoms to develop.Do not induce vomiting as there is high risk of aspiration.Do not give anything by mouth to an unconscious person.

4.2. Most important symptoms and effects, both acute and delayedSymptoms/injuries after inhalation : Inhalation of vapours may cause headache, nausea, vomiting and an altered state of

consciousness.Symptoms/injuries after skin contact : Symptoms: reddening, irritation.Symptoms/injuries after eye contact : Slight eye irritation.Symptoms/injuries after ingestion : Ingestion (swallowing) of this material may result in an altered state of consciousness and loss

of coordination.

4.3. Indication of any immediate medical attention and special treatment neededNo relevant data available

5. Firefighting measures5.1. Extinguishing mediaSuitable extinguishing media : Foam (trained personnel only). Water fog (trained personnel only). Dry chemical powder.

Carbon dioxide. Other inert gases (subject to regulations). Sand or earth.Unsuitable extinguishing media : Do not use direct water jets on the burning product;. they could cause splattering and spread

the fire. Simultaneous use of foam and water on the same surface is to be avoided as waterdestroys the foam.

5.2. Special hazards arising from the substance or mixtureReactivity : This substance is stable under all ordinary circumstances at ambient temperatures, and if

released into the environment.


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5.3. Advice for firefightersProtection during firefighting : In case of a large fire or in confined or poorly ventilated spaces, wear full fire resistant

protective clothing and self-contained breathing apparatus (SCBA) with a full face-pieceoperated in positive pressure mode.

Other information : Incomplete combustion is likely to give rise to a complex mixture of airborne solid and liquidparticulates, gases, including carbon monoxide. unidentified organic and inorganic compounds.

6. Accidental release measures6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnelProtective equipment : Small spillages: normal antistatic working clothes are usually adequate.

Large spillages: full body suit of chemically resistant and antistatic material.Work gloves providing adequate chemical resistance, specifically to aromatic hydrocarbons.Work helmet.Antistatic non-skid safety shoes or bootsGoggles and /or face shield, if splashes or contact with eyes is possible or anticipated.Respiratory protection:a half or full-face respirator with filter(s) for organic vapours/H2S, or a Self-contained BreathingApparatus (SCBA) can be used according to the extent of spill and predictable amount ofexposure. If the situation cannot be completely assessed, or if an oxygen deficiency ispossible, only SCBA’s should be used.

Emergency procedures : Stop or contain leak at the source, if safe to do soAvoid direct contact with released materialStay upwindIn case of large spillages, alert occupants in downwind areas.Keep non-involved personnel away from the area of spillage. Alert emergency personnelExcept in case of small spillages,The feasibility of any actions should always be assessed and advised, if possible, by a trained,competent person in charge of managing the emergency.Eliminate all ignition sources if safe to do so (e.g. electricity, sparks, fires, flaresIf required, notify relevant authorities according to all applicable regulationsIf necessary dike the product with dry earth, sand or similar non-combustible materials.Large spillages may be cautiously covered with foam, if available, to limit vapour cloudformation.Do not use direct jetsWhen inside buildings or confined spaces, ensure adequate ventilation.

6.1.2. For emergency respondersNo relevant data available

6.2. Environmental precautionsPrevent product from entering sewers, rivers or other bodies of water, or underground spaces (tunnels, cellars, etc.)Absorb spilled product with suitable non-combustible materials.Transfer collected product and other contaminated materials to suitable containers for recovery or safe disposal.In case of soil contamination, remove contaminated soil and treat in accordance with local regulations.In case of small spillages in closed waters, contain product with floating barriers or other equipmentCollect spilled product by absorbing with specific floating absorbentsIf possible, large spillages in open waters should be contained with floating barriers or other mechanical means.Contain spillage – ventilate area and allow to evaporate.The use of dispersants should be advised by an expert, and, if required, approved by local authorities.

6.3. Methods and material for containment and cleaning upFor containment : recommended measures are based on the most likely spillage scenarios for this material;

however, local conditions (wind, air temperature, wave/current direction and speed) maysignificantly influence the choice of appropriate actionsFor this reason, local experts should be consulted when necessary.Local regulations may also prescribe or limit actions to be taken.

6.4. Reference to other sectionsNo relevant data available


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7. Handling and storage7.1. Precautions for safe handlingPrecautions for safe handling : Obtain special instructions before use. Risk of explosive mixtures of vapour and air. Ensure that

all relevant regulations regarding explosive atmospheres, and handling and storage facilities offlammable products, are followed. Keep away from heat/sparks/open flames/hot surfaces. Donot eat, drink or smoke when using this product. Avoid contact with the hot product. Avoidrelease to the environment. Take precautionary measures against static electricity.Ground/bond containers, tanks and transfer/receiving equipment. Use explosion-proofelectrical/ventilating/lighting equipment. Use only non-sparking tools. The vapour is heavierthan air. Beware of accumulation in pits and confined spaces. Use only bottom loading oftankers, in compliance with European legislation. Do not use compressed air for filling,discharging, or handling operations. Avoid contact with skin and eyes. Do not ingest. Do notbreathe vapours. Use adequate personal protective equipment as required. For moreinformation regarding protective equipment and operational conditions see Exposure scenarios.Ensure that proper housekeeping measures are in place. Keep away from food and beverages.Wash the hands thoroughly after handling. Change contaminated clothes at the end of workingshift.

7.2. Conditions for safe storage, including any incompatibilitiesTechnical measures : Before entering storage tanks and commencing any operation in a confined area, check the

atmosphere for oxygen content and flammability. Light hydrocarbon vapours can build up in theheadspace of containers. These can cause flammability / explosion hazards. Open slowly inorder to control possible pressure release. Empty containers may contain flammable productresidues. Do not weld, solder, drill, cut or incinerate empty containers, unless they have beenproperly cleaned.

Storage conditions : Cleaning, inspection and maintenance of internal structure of storage tanks must be done onlyby properly equipped and qualified personnel as defined by national, local or companyregulations.

Storage temperature : 5-40 °CProhibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: (strong) acids. (strong) bases. halogens. heat sources.

oxidizing agents. peroxides.Storage area : Use and store only outdoors or in a well-ventilated area. Storage area layout, tank design,

equipment and operating procedures must comply with the relevant European, national or locallegislation. Storage installations should be designed with adequate bunds in case of leaks orspills. Store separately from oxidising agents.

Special rules on packaging : If the product is supplied in containers: Keep only in the original container or in a suitablecontainer for this kind of product. Keep containers tightly closed and properly labelled. Protectfrom the sunlight.

Packaging materials : Recommended materials: For containers, or container linings use materials specificallyapproved for use with this product. some synthetic materials may be unsuitable for containersor container linings depending on the material specification and intended use. Compatibilityshould be checked with the manufacturer.

7.3. Specific end use(s)This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates.in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the StrictlyControlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including theselection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is availableat each manufacturing site. Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributorand Downstream Processor/User of the Registrant’s intermediate.

8. Exposure controls/personal protection8.1. Control parameters

XYLENE (1330-20-7)Hungary AK-value 221 mg/m³Hungary CK-value 442 mg/m³Hungary Jellemző tulajdonság b - az ebből származó expozíciót csak a levegőben

megengedett koncentrációjuk mértékének megfelelőenveszik figyelembe

Hungary Reference EU3 - 2000/39/EK irányelvben közölt érték


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8.2. Exposure controlsAppropriate engineering controls : Where hot product is handled in confined spaces, effective local ventilation must be provided.Personal protective equipment : Gloves. Protective goggles. Protective clothing. Gas mask with filter type A.

Hand protection : Wear chemically resistant gloves (tested to EN374) in combination with specific activity training.Gloves must be periodically inspected and changed in case of wear, perforations orcontaminations.

Eye protection : If splashing is likely, full head and face protection (protective shield and/or safety goggles)should be used. If contact is likely, a protection (protective shield and/or safety goggles) shouldbe used.

Skin and body protection : Wear suitable coveralls to prevent exposure to the skin. Coveralls should be changed at theend of the work shift and cleaned as necessary to avoid transfer of product to clothes orunderwear.

Respiratory protection : to avoid respiratory tract irritation inhalation exposure should be kept to a minimum,. If exposurelevels cannot be determined or estimated with adequate confidence, or an oxygen deficiency ispossible, only SCBA’s should be used. If necessary, approved respiratory protection equipmentshall be used when handling hot product in confined spaces: enclosed face mask withcartridge/filter type “A” or self-contained breathing apparatus (SCBA). Change filter cartridge onrespirator daily.

Thermal hazard protection : None in normal conditions.Environmental exposure controls : Store finished products in closed containers (e.g., bulk tanks,, drums, cans);. Store all VOC-

containing wastes in closed, secure containers (e.g., bulk tanks, intermediate bulk containers,drums). Incinerate, absorb, or adsorb vapours stripped from solution whenever necessary. Usevapour recovery units when necessary. Carefully handle the substance to minimise releases.

Consumer exposure controls : Substance registered as Isolated intermediate under SCC). This substance is handled underStrictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-siteisolated intermediates. In case the substance is transported to other sites for further processing,the substance should be handled at these sites under the Strictly Controlled Conditions asspecified in REACH regulation Article 18(4). Site documentation to support safe handlingarrangements including the selection of engineering, administrative and personal protectiveequipment controls in accordance with risk-based management systems is available at eachmanufacturing site. Written confirmation of application of Strictly Controlled Conditions hasbeen received from every affected Distributor and Downstream Processor/User of theRegistrant’s intermediate.

9. Physical and chemical properties9.1. Information on basic physical and chemical propertiesAppearance : Liquid.Physical state : LiquidColour : Colourless.Odour : aromatic odour.Melting point : -47,4 °CBoiling point : 140 (137-143) °CFlash point : 30 °CExplosive limits (vol %) : 1-7,6 vol %Vapour pressure : 8,7-8,9 hPa 20°CDensity : 0,881-0,887 g/cm³ 15°CRelative gas density : 3,7Viscosity : ≥ 0,812 cP in 20°CpH : Not applicable

9.2. Other informationNo relevant data available

10. Stability and reactivity10.1. ReactivityThis substance is stable under all ordinary circumstances at ambient temperatures, and if released into the environment.

10.2. Chemical stabilityStable under normal conditions.


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10.3. Possibility of hazardous reactionsContact with strong oxidizers (peroxides, chromates, etc.) may cause a fire hazard.

10.4. Conditions to avoidThey may be ignited by heat, sparks, static electricity or flames.

10.5. Incompatible materialsA mixture with nitrates or other strong oxidisers (e.g. chlorates, perchlorates, liquid oxygen) may create an explosive mass.

10.6. Hazardous decomposition productsNo decomposition if stored normally.

11. Toxicological information11.1. Information on toxicological effectsAcute toxicity : Harmful in contact with skin. Harmful if inhaled. Harmful if inhaled.Skin corrosion/irritation : Causes skin irritation.Serious eye damage/irritation : Causes serious eye irritation.Aspiration hazard : May be fatal if swallowed and enters airways.Specific target organ toxicity (single exposure) : May cause respiratory irritation.Specific target organ toxicity (repeatedexposure)

: May cause damage to organs (lung, skin) through prolonged or repeated exposure (dermal,inhalation, oral).

XYLENE (1330-20-7)LD50 oral rat 4300 mg/kgLD50 dermal rabbit 4300 mg/kgLC50 inhalation rat (mg/l) 18,8-25,9 mg/l/4hATE (oral) 4300 mg/kgATE (dermal) 1100,00000 mg/kgATE (vapours) mg/l/4h

xylene (1330-20-7)ATE (dermal) 1100,00000 mg/kg

12. Ecological information12.1. ToxicityEcology - general : DANGEROUS FOR THE ENVIRONMENT.Ecology - air : Not dangerous for the ozone layer (1999/45/EC).

XYLENE (1330-20-7)LC50 fishes 1 10 mg/lEC50 Daphnia 1 165 mg/lEC50 other aquatic organisms 1 > 160 mg/l Pseudomonas putidaLC50 fishes 2 10-100 mg/l

12.2. Persistence and degradabilityXYLENE (1330-20-7)Persistence and degradability Product is biodegradable with difficulty.Chemical oyxgen demand (COD) 3000 g O²/g substance

12.3. Bioaccumulative potentialXYLENE (1330-20-7)Log Kow 3,14-3,18

12.4. Mobility in soilNo relevant data available

12.5. Results of PBT and vPvB assessmentNo relevant data available

12.6. Other adverse effectsNo relevant data available


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13. Disposal considerations13.1. Waste treatment methodsRegional legislation (waste) : 2000. évi XLIII. Törvény a hulladékgazdálkodásról (Hungarian law). 98/2001. (VI. 15.) Korm.

rendelet a veszélyes hulladékkal kapcsolatos tevékenységek végzésének feltételeiről(Hungarian regulation). DIRECTIVE 2008/98/EC OF THE EUROPEAN PARLIAMENT AND OFTHE COUNCILof 19 November 2008on waste and repealing certain Directives.

Waste treatment methods : Contain and dispose of waste according to local regulations. External recovery and recycling ofwaste should comply with applicable local and/or national regulations. External treatment anddisposal of waste should comply with applicable local and/or national regulations. Wherepossible (e.g. in the absence of relevant contamination), recycling of used substance is feasibleand recommended.

Sewage disposal recommendations : Do not empty into drains, dispose of this material and its container at hazardous or specialwaste collection point. Do not empty into drains; dispose of this material and its container in asafe way.

Waste disposal recommendations : Clear up spills immediately and dispose of waste safely. Dispose of waste or usedsacks/containers according to local regulations.

Additional information : (*) Hazardous waste according to Directive 91/689/EEC. Carefully handle the substance tominimise releases. European Waste Catalogue code(s) (Decision 2001/118/CE): The final userhas the responsibility for the attribution of the most suitable code, according to the actual use(s)of the material, contaminations or alterations.

Ecology - waste materials : Hazardous waste. Avoid any discharge of the product into waste water. Disposal in high-temperature incinerator (> 1200 °C).

EWC (EURAL) code : 07 01 04* - other organic solvents, washing liquids and mother liquors


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14. Transport information14.1 Overland transport (ADR)

UN-No. (ADR) : 1307

Class (ADR): : 3 - Flammable liquidsProper Shipping Name : XilenesPacking group (ADR) : IIIDanger labels (ADR) : 3 - Flammable liquid, N - Dangerous for the environment

Hazard identification number (Kemler No.) : 30Transport document description : UN 1307 Xilenes, 3 (N), III, (D/E)Classification code (ADR) : F1Tunnel restriction code (ADR) : D/EOrange plates :

14.2 Overland transport (RID)

UN-No. (RID) : 1307

Class (RID) : 3Proper Shipping Name : XilenesClassification code (RID) : F1Danger labels (RID) : 3 - Flammable liquid,N - Dangerous for the environment

Packing group (RID) : IIIOrange plates :

14.3 Inland waterway transport (ADN)UN-No. (ADN) : 1307Class (ADN) : 3 - Flammable liquidsProper Shipping Name : XilenesClassification code (ADN) : F1Packing group (ADN) : IIIDanger labels (ADN) : 3 - Flammable liquid, N - Dangerous for the environment

Dangers (ADN) : 3+N2


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14.4 Transport by sea (IMDG)UN-No. (IMDG) : 1307Class (IMDG) : 3 - Flammable liquidsProper Shipping Name : XilenesPacking group (IMDG) : IIIMarine pollutant : NoEmS : F-E; S-D

14.5 Air transport (ICAO-TI / IATA-DGR)UN-No. (ICAO) : 1307Class (ICAO) : 3Proper Shipping Name : Xilenes

15. Regulatory information15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1. EU-RegulationsAuthorisations and/or restrictions on use (Annex XVII):------

3. Liquid substances or mixtures, which are regarded as dangerousaccording to the definitions in Council Directive 67/548/EEC andDirective 1999/45/EC.

XYLENE - toluene - benzene - xylene

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5. Benzene benzene

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40. Substances meeting the criteria of flammability in Directive67/548/EEC and classified as flammable, highly flammable orextremely flammable regardless of whether they appear in Part 3 ofAnnex VI to Regulation (EC) No 1272/2008 or not.

XYLENE - toluene - benzene - xylene

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48. Toluene toluene

15.1.2. National regulationsRegional legislation : 1993. évi XCIII. törvény a munkavédelemről. 25/2000. (IX. 30.) EüM-SzCsM együttes rendelet a

munkahelyek kémiai biztonságáról. ESZCSM Regulation 33/2004 (XII. 27.) . Hungarian PublicAct No. XXV./2000 on chemical safety. REGULATION (EC) No 1272/2008 OF THEEUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,labelling and packaging of substances and mixtures(CLP). REGULATION (EC) No 1907/2006OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 18 December 2006concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).

15.2. Chemical safety assessmentNo relevant data available


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16. Other informationSDS changed items : All chapters were revised.Data sources : Data arise from reference works and literature. Data rely on practical experience.Abbreviations and acronyms : C&L - Classification and Labelling

CAS - Chemical Abtracts Service. See www.cas.org.CMR - Carcinogen, Mutagen and ReprotoxicCONCAWE - CONservation of Clean Air and Water in EuropeCSA - Chemical Safety AssessmentCSR - Chemical Safety ReportDMEL - Derived Minimal Effect LevelDNEL - Derived No-Effect LevelDSD - Dangerous Substance DirectiveEC - European CommissionEC number - European Chemical number: EINECS, ELINCS or NLPEC50 - half maximal effective concentrationECB - European Chemicals BureauECHA - European CHemicals AgencyEINECS - European Inventory of Existing Commercial SubstancesELINCS - European List of Notified Chemical SubstancesES - Exposure ScenariosESIS - European Substances Information SystemGHS - Globally Harmonised System for the Classification and Labelling of ChemicalsHSE - Health, Safety and EnvironmentInChI - IUPAC International Chemical IdentifierIOELV - Indicative Occupational Exposure Limit ValuesIUCLID - International Uniform ChemicaL Information DatabaseIUPAC - International Union of Pure and Applied ChemistryLC50 - Lethal Concentration, 50%LD50 - Lethal Dose, 50%LOAEL - Lowest Observed Adverse Effect LevelLOEL - Lowest Observed Effect LevelN.A. - not applicableN.D. - Not determinedNOAEL - No Observed Adverse Effect LevelNOEL - No Observed Effect LevelPBT - Persistent, bioaccumulative and toxicPNEC - Predicted no effect concentrationppm - parts per millionPPORD - Product and Process Oriented Research and DevelopmentQSAR - Quantitative Structure Activity RelationshipREACH - Registration, Evaluation and Authorization of CHemicalsRMM - Risk Management MeasuresSDS - Safety Data SheetTSCA - Toxic Substance Control Act (USA)VPVB - very persistent and very bioaccumulativew/w - Weight by weight

Training advice : Before handling, storing or using the present substance for the first time, employees must beinformed. Make sure that employees are aware of the intoxication risk. Poeple wearingbreathing apparatus must be appropriately trained. Special training for first aid necessary.

Full text of R-, H- and EUH-phrases:------

Acute Tox. 3 (Dermal) Acute toxicity (Dermal) Category 3

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Acute Tox. 3 (Oral) Acute toxicity (Oral) Category 3

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Acute Tox. 4 (Dermal) Acute toxicity (Dermal) Category 4

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Acute Tox. 4 (Inhalation) Acute toxicity (Inhalation) Category 4

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Acute Tox. 4 (Inhalation:vapour) Acute toxicity (Inhalation:vapour) Category 4

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Asp.Tox. 1 Aspiration hazard Category 1

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Carc. 1A Carcinogenicity Category 1A

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Eye Irrit. 2 Serious Eye Damage/Irritation Category 2

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Flam. Liq. 2 Flammable liquids Category 2

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Flam. Liq. 3 Flammable liquids Category 3

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Muta. 1B Germ cell mutagenicity Category 1B


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Repr. 2 Reproductive toxicity Category 2

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Skin Irrit. 2 Skin Corrosion/Irritation Category 2

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STOT RE 1 Specific target organ toxicity — repeated exposure Category 1

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STOT RE 2 Specific target organ toxicity — repeated exposure Category 2

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STOT SE 3 Specific target organ toxicity — single exposure Category 3

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STOT SE 3 Specific target organ toxicity — single exposure Category 3

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H225 Highly flammable liquid and vapour

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H226 Flammable liquid and vapour

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H301 Toxic if swallowed

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H304 May be fatal if swallowed and enters airways

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H311 Toxic in contact with skin

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H312 Harmful in contact with skin

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H315 Causes skin irritation

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H319 Causes serious eye irritation

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H332 Harmful if inhaled

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H335 May cause respiratory irritation

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H336 May cause drowsiness or dizziness

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H340 May cause genetic defects

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H350 May cause cancer

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H361d Suspected of damaging the unborn child.

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H372 Causes damage to organs through prolonged or repeated exposure

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H373 May cause damage to organs through prolonged or repeatedexposure

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R10 Flammable.

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R11 Highly flammable.

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R20/21 Harmful by inhalation and in contact with skin.

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R36/37/38 Irritating to eyes, respiratory system and skin.

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R36/38 Irritating to eyes and skin.

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R38 Irritating to skin.

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R45 May cause cancer.

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R46 May cause heritable genetic damage.

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R48/20 Harmful: danger of serious damage to health by prolonged exposurethrough inhalation.

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R48/23/24/25 Toxic: danger of serious damage to health by prolonged exposurethrough inhalation, in contact with skin and if swallowed.

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R63 Possible risk of harm to the unborn child.

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R65 Harmful: may cause lung damage if swallowed.

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R67 Vapours may cause drowsiness and dizziness.

Precautionary statements (CLP):- P210 Keep away from heat, hot surfaces, open flames, sparks. - No

smoking.


03.01.2011 EN (English) 14/14

- P233 Keep container tightly closed- P240 Ground/bond container and receiving equipment- P241 Use explosion-proof electrical, lighting, ventilating equipment.- P243 Take precautionary measures against static discharge- P260 Do not breathe vapours.- P271 Use only outdoors or in a well-ventilated area- P280 Wear eye protection, protective clothing, protective gloves.- P301+P310 If swallowed, immediately call a doctor.- P302+P352 IF ON SKIN: Wash with plenty of soap and water- P304+P340 IF INHALED: Remove to fresh air and keep at rest in a position

comfortable for breathing- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minuts. Remove

contact lenses, if present and easy to do. Continue rinsing- P312 Call a POISON CENTER/doctor/physician if you feel unwell- P331 Do NOT induce vomiting- P332+P313 If skin irritation occurs: Get medical advice/attention- P337+P313 If eye irritation persists: Get medical advice/attention- P370+P378 In case of fire: Use Carbon dioxide, Dry chemical powder, Foam

(trained personnel only), Sand or earth for extinction.- P403+P233 Store in a well-ventilated place. Keep container tightly closed- P403+P235 Store in a cool and well-ventilated place.- P405 Store locked up- P501 Dispose of contents/container to Law XLIII/2000., See Section 13..- P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated

clothing. Rinse skin with water/shower

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmentalrequirements only. It should not therefore be construed as guaranteeing any specific property of the product.

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