SAFETY DATA SHEET - s3-ap-southeast-2.amazonaws.com · An exposure assessment may be needed to...
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Fixtech Pty Ltd – PO Box 568, Southport, QLD PH: +61 (0) 7 5530 1099, Fax: +61 (0) 7 5530 1322 Email: [email protected] Page 1 SDS: FM30 FAC240 SDS Established: March 2006 SDS Revised: an.01/06/2016 SAFETY DATA SHEET FM30-FAC240 Base 1.1 Identification of the substance or preparation: Product Name: FM30-FAC240; Fuel Master Base 1.2 Use of substance or preparation: Sealant for industrial and professional use only 1.3 Company undertaking identification: Fixtech Pty Ltd – Fixtech Marine Solutions Unit 1/20 Molendinar, Queensland 4214 Tel: +61 7 5530 1099 Fax: +61 7 5530 1322 Email: [email protected] 1.4 Emergency telephone: +61 7 5530 1099 Hazardous Ingredients CAS No. % by Wt Polysulfide rubber 68611-50-7 55-65 Calcium Carbonate 471-34-1 30 – 40 Titanium Dioxide 13463-67-7 1-5* 3-(Trimethoxysilyl)Propyl Glycidyl Ether 2530-83-8 0-3 Quartz Silica 14808-60-7 0-0.5* *The specific chemical identity and/or exact percentage of this composition have been withheld as a trade secret. 3.1 Hazard Classification: Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200 2. Composition/information on ingredients 1. Identification 3. Hazardous identification
Transcript of SAFETY DATA SHEET - s3-ap-southeast-2.amazonaws.com · An exposure assessment may be needed to...
FixtechPtyLtd–POBox568,Southport,QLD
PH:+61(0)755301099,Fax:+61(0)755301322Email:[email protected]:www.fixtech.com.au
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FM30-FAC240Base
1.1 Identificationofthesubstanceorpreparation: ProductName:FM30-FAC240;FuelMasterBase1.2 Useofsubstanceorpreparation: Sealantforindustrialandprofessionaluseonly1.3 Companyundertakingidentification:
FixtechPtyLtd–FixtechMarineSolutionsUnit1/20Molendinar,Queensland4214Tel:+61755301099Fax:+61755301322Email:[email protected]
1.4 Emergencytelephone: +61755301099
HazardousIngredients CASNo.
%byWt
Polysulfiderubber 68611-50-7 55-65CalciumCarbonate 471-34-1 30–40TitaniumDioxide 13463-67-7 1-5*3-(Trimethoxysilyl)PropylGlycidylEther 2530-83-8 0-3QuartzSilica 14808-60-7 0-0.5**Thespecificchemicalidentityand/orexactpercentageofthiscompositionhavebeenwithheldasatradesecret.
3.1HazardClassification: NotclassifiedashazardousaccordingtoOSHAHazardCommunicationStandard,29CFR 1910.1200
2.Composition/informationoningredients
1.Identification
3.Hazardousidentification
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FM30-FAC240Base3.2Labelelements:
Signalword: Notapplicable
Symbols: Notapplicable
Pictograms: Notapplicable
Hazardsnototherwiseclassified: None
4.1 General: -Incaseofdoubtorwithpersistingsymptoms,obtainmedicalattention
-Neverpassanythingthroughthemouthofanunconsciousperson4.2 Skincontact: -Immediatelywashwithsoapandwater -Removecontaminatedclothingandwashbeforereuse. -Ifsymptomspersistseekmedicaladvice4.3 Eyecontact: -Irrigatewitheyewashsolutionorcleanwater,holdingtheeyelidsapart,foratleast10minutes -Removecontactlensesifeasytodoso,continuerinsing -Seekmedicaladvice4.4 Afteringestion: -Rinsemouth -Ifyoufeelunwellseekmedicalattention4.5 Inhalation -Removepatientfromexposure,keepwarmandatrest.Ifunwellseekmedicaladvice4.5 Mostimportantsymptomsandeffects,bothacuteanddelayed -Seesection11.Informationontoxicologicaleffects4.6 Indicationofanyimmediatemedicalattentionandspecialtreatment: -Notapplicable
4.Firstaidmeasures
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5.1 Suitableextinguishingmedia: Incaseoffire:Useafirefightingagentsuitableforordinarycombustiblematerialsuchaswater orfoamtoextinguish.5.3 Specialhazardsarisingfromthesubstanceormixture: Noneinherentinthisproduct Hazardousdecompositionorby-products: Substance Condition Formaldehyde DuringCombustion CarbonDioxide DuringCombustion Carbonmonoxide DuringCombustion5.4 Specialprotectiveactionsforfirefighters: Nospecialprotectiveactionsforfirefightersareanticipated
6.1 Personalprecautions,protectiveequipmentandemergencyprocedures: Evacuatearea.Ventilatetheareawithfreshair.Forlargespills,orspillsinconfinedspaces, providemechanicalventilationtodisperseorexhaustvapoursinaccordancewithgood industrialhygienepractice.Warning!Amotorcouldbeanignitionsourceandcouldcause flammablegasesorvapoursinthespillareatoignite,burnorexplode.Refertoothersectionsof thisMSDSforinformationregardingphysicalandhealthhazards,respiratoryprotection, ventilation,andpersonalprotectiveequipment.6.2 Environmentalprecautions: Avoidreleasetotheenvironment.Forlargerspills,coverdrainsandbuilddikestoprevententry intosewersystemsorbodiesofwater.6.3 Methodsandmaterialforcontainmentandcleaningup: Containspill.Workingfromaroundtheedgesofthespillinward,coverwithbentonite, vermiculite,orcommerciallyavailableinorganicabsorbentmaterial.Mixinsufficientabsorbent untilitappearsdry.Remember,addinganabsorbentmaterialdoesnotremoveaphysical, health,orenvironmentalhazard.Collectasmuchofthespilledmaterialaspossible.Placeina closedcontainerapprovedfortransportationbyappropriateauthorities.Cleanupresiduewith anappropriatesolventselectedbyaqualifiedandauthorizedperson.Ventilatetheareawith freshair.ReadandfollowsafetyprecautionsonthesolventlabelandSDS.Sealthecontainer. Disposeofcollectedmaterialassoonaspossible.Note:Seesection8forPersonalProtectiveEquipment.
5.Firefightingmeasures
6.Accidentalreleasemeasures
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7.1 Handling:
Donotbreathdust/fume/gas/mist/vapous/spray.Donotgetineyes,onskin,oronclothing.Avoidcontactduringpregnancy/whilenursing.Donoteat.Drinkorsmokewhenusingthisproduct.Washthoroughlyafterhandling.Avoidreleasetotheenvironment.
7.2 Storage: -Storeinacool,dryplacewellventilatedplaceinoriginalcontainers -Storeawayfromacids.Storeawayfromstrongbases
8.1 Controlparameters: Occupationalexposurelimits: Ifacomponentisdisclosedinsection2butdoesnotappearinthetablebelow,anoccupational exposurelimitisnotavailableforthecomponentIngredient C.A.S.No. LimitType AdditionalcommentsTITANIUMDIOXIDE 13467-67-7 TWA:10mg/m3 A4:notclass.ashumancarcin.TITANIUMDIOXIDE 13467-67-7 TWA(asrespirabledust):5mg/m3 TITANIUMDIOXIDE 13467-67-7 TWA(astotaldust):15mg/m3 QUARTZSILICA 14808-60-7 TWA(respirablefraction):0.025mg/m3 A2:suspectedhumancarcin.QUARTZSILICA 14808-60-7 TWAconcentration(astotaldust):0.3
mg/m3;TWAconcentration(respirable):0.1mg/m3(2.4milliomsofparticlesperc.uft)
3-(TRMETHOXYSILYL)PROPYLGYCIDYLETHER
2530-83-8 TWA:5ppm
CALCIUMCARBONATE 471-34-1 TWA:10mg/m3;STEL:20 LIMESTONE 471-34-1 TWA(astotaldust):15mg/m3;TWA
(respirablefraction):5mg/m3
TWA : Time Weighted Average STEL : Short Term Exposure Limit CEIL : Ceiling 8.2 Exposurecontrols:8.2.1 Engineeringcontrols: Usegeneraldilutionventilationand/orlocalexhaustventilationtocontrolairborneexposures tobelowrelevantExposureLimitsand/orcontroldust/fume/gas/mist/vapors/spray.If ventilationisnotadequate,userespiratoryprotectionequipment.8.2.2 Personalprotectiveequipment(PPE): Eye/faceProtection:
7.Handlingandstorage
8.Exposurecontrols/personalprotection
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FM30-FAC240BaseNonerequired
Skin/handprotection:NochemicalprotectiveglovesarerequiredRespiratoryprotection:
Anexposureassessmentmaybeneededtodecideifarespiratorisrequired.Ifarespiratoris needed,userespiratorsaspartofafullrespiratoryprotectionprogram.Basedontheresultsof theexposureassessment,selectfromthefollowingrespiratortype(s)toreduceinhalation exposure:Halffacepieceorfullfacepieceair-purifyingrespiratorsuitablefororganicvaporsand particulates
Forquestionsaboutsuitabilityforaspecificapplication,consultwithyourrespirator manufacturer.
9.1 Generalinformation: PhysicalForm: Liquid Colour,Odour,Grade Sulphorousodour,Whitepaste Odourthreshold: Nodataavailable pH: Notapplicable Meltingpoint: Notapplicable Flashpoint: >=930C(testmethod:closedcup) Boilingpoint: Nodataavailable Evaporationrate: Nodataavailable Flammability(solid,gas): Notapplicable Flammablelimits(LEL): Nodataavailable Flammablelimits(UEL): Nodataavailable Vapourpressure: Negligible Vapourdensity: Nodataavailable Specificgravity: >=1.61(RefStd:Water=1) Solubilityinwater: Nil Solubility-nonwater Nodataavailable Partitioncoefficient:n-octanol/water: Nodataavailable Autoignitiontemperature: Nodataavailable Decompositiontemperature: Nodataavailable Viscosity: Nodataavailable Volatileorganiccompounds: 2g/l(testmethod:calculatedSCAQMDrule443.1) VOCLessH20&exemptsolvents: 2g/l(testmethod:calculatedSCAQMDrule443.1)
9.PhysicalandChemicalProperties
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10.1 Reactivity: Thismaterialisconsideredtobenonreactiveundernormaluseconditions.10.2 Chemicalstability: Stable10.3 Possibilityofhazardousreactions: Hazardouspolymerizationwillnotoccur.10.4 Conditionstoavoid: Noneknown10.5 Incompatiblematerials: Reducingagents Strongacids Strongbases10.6 Hazardousdecompositionproducts: Substance: NoneknownRefertosection5.2forhazardousdecompositionproductsduringcombustion.
TheinformationbelowmaynotbeconsistentwiththematerialclassificationinSection2ifspecificingredientclassificationsaremandatedbyacompetentauthority.Inaddition,toxicologicaldataoningredientsmaynotbereflectedinthematerialclassificationand/orthesignsandsymptomsofexposure,becauseaningredientmaybepresentbelowthethresholdforlabeling,aningredientmaynotbeavailableforexposure,orthedatamaynotberelevanttothematerialasawhole.11.1 Informationontoxilogicaleffects: Signs&symptomsofexposure: Basedontestdataand/orinformationonthecomponents,thismaterialmayproducethe followinghealtheffects: Inhalation: RespiratoryTractIrritation:Signs/symptomsmayincludecough,sneezing,nasal discharge,headache,hoarseness,andnoseandthroatpain Skincontact: Contactwithskinduringproductuseisnotexpectedtoresultinsignificantirritation
10.Stabilityandreactivity
11.Toxilogicalinformation
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FM30-FAC240Base Eyecontact:
Contactwiththeeyesduringproductuseisnotexpectedtoresultinsignificantirritation. Ingestion: GastrointestinalIrritation:Signs/symptomsmayincludeabdominalpain,stomachupset,nausea, vomitinganddiarrhea.Carcinogenicity:Ingredient C.A.S.No. ClassDescription RegulationSILICA,CRYSAIRRESP 14808-60-7 Knownhumancarcinogen NationalToxicologyProgramCarcinogensQUARTZSILICA 14808-60-7 Grp.1:Carcinogenictohumans Int.AgencyforResearchonCancerTITANIUMDIOXIDE 13463-67-7 Grp.2B:Possiblehumancarcinogen Int.AgencyforResearchonCancer Toxicologicaldata: Ifacomponentisdisclosedinsection3butdoesnotappearinatablebelow,eithernodataare availableforthatendpointorthedataarenotsufficientforclassification.AcuteToxicity:Name Route Species ValueOverallproduct Dermal Nodataavailable;calculatedATE>5000mg/kgOverallproduct Ingestion Nodataavailable;calculatedATE>5000mg/kgPOLYSULFIDERUBBER Dermal Rat LD50>7800mg/kgPOLYSULFIDERUBBER Ingestion Rat LD50>5000mg/lCALCIUMCARBONATE Dermal Rat LD50>2000mg/kgCALCIUMCARBONATE Inhalation
dust/mist4hrRat LC503.0mg/l
CALCIUMCARBONATE Ingestion Rat LD50>6450mg/kgTITANIUMDIOXIDE Dermal Rabbit LD50>10000mg/kgTITANIUMDIOXIDE Inhalation
dust/mist4hrRat LC50>6.82mg/l
TITANIUMDIOXIDE Ingestion Rat LD50>10000mg/kg3-(TRIMETHOXYSILYL)PROPYLGLYCIDYLETHER
Dermal Rabbit LD504000mg/kg
3-(TRIMETHOXYSILYL)PROPYLGLYCIDYLETHER
Inhalationdust/mist4hr
Rat LC50>5.3mg/l
3-(TRIMETHOXYSILYL)PROPYLGLYCIDYLETHER
Ingestion Rat LD507010mg/kg
QUARTZSILICA Dermal LD50estimatedtobe>5000mg/kgQUARTZSILICA Ingestion LD50estimatedtobe>5000mg/kgATE=acutetoxicityestimate
Skincorrosion/irritation:Name Species ValuePOLYSULFIDERUBBER Rabbit NosignificantirritationCALCIUMCARBONATE Rabbit NosignificantirritationTITANIUMDIOXIDE Rabbit Nosignificantirritation
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FM30-FAC240Base3-(TRIMETHOXYSILYL)PROPYLGLYCIDYLETHER Rabbit Mildirritant
QUARTZSILICA Professionaljudgement NosignificantirritationSeriousEyedamage/irritation:Name Species ValuePOLYSULFIDERUBBER Rabbit NosignificantirritationCALCIUMCARBONATE Rabbit NosignificantirritationTITANIUMDIOXIDE Rabbit Nosignificantirritation3-(TRIMETHOXYSILYL)PROPYLGLYCIDYLETHER Rabbit CorrosiveSkinsensitisation:Name Species ValuePOLYSULFIDERUBBER Humanandanimal NonesensitisingTITANIUMDIOXIDE Humanandanimal Nonesensitising3-(TRIMETHOXYSILYL)PROPYLGLYCIDYLETHER Guineapig Somepositivedataexist,butthedataarenot
sufficientforclassification
RespiratorySensitisation: Forthecomponent/components,eithernodataarecurrentlyavailableorthedataarenot sufficientforclassification.
Germcellmutagenicity:Name Route ValueTITANIUMDIOXIDE InVitro NotmutagenicTITANIUMDIOXIDE Invivo Notmutagenic3-(TRIMETHOXYSILYL)PROPYLGLYCIDYLETHER
Invivo Notmutagenic
3-(TRIMETHOXYSILYL)PROPYLGLYCIDYLETHER
InVitro Somepositivedataexist,butthedataarenotsufficientforclassification
QUARTZSILICA InVitro Somepositivedataexist,butthedataarenotsufficientforclassificationQUARTZSILICA Invivo Somepositivedataexist,butthedataarenotsufficientforclassificationCarcinogenicity:Name Route Species ValueTITANIUMDIOXIDE Ingestion Multipleanimalspecies NotCarcinogenicTITANIUMDIOXIDE Inhalation Rat Carcinogenic3-(TRIMETHOXYSILYL)PROPYLGLYCIDYLETHER Dermal Mouse NotCarcinogenicQUARTZSILICA Inhalation Human&animal Carcenogenic Reproductivetoxicity:Reproductiveand/ordevelopmentaleffects:
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FM30-FAC240BaseName Route Value Species TestResult Exposure
DurationCALCIUMCARBONATE Ingestion Nottoxictodevelopment Rat NOAEL625
MG/KG/dayPremating&duringgestation
3-(TRIMETHOXYSILYL)PROPYLGLYCIDYLETHER
Ingestion Nottoxictofemalereproduction
Rat NOAEL1000MG/KG/day
1generation
3-(TRIMETHOXYSILYL)PROPYLGLYCIDYLETHER
Ingestion Nottoxictomalereproduction Rat NOAEL1000MG/KG/day
1generation
3-(TRIMETHOXYSILYL)PROPYLGLYCIDYLETHER
Ingestion Somepositivedataexist,butthedataarenotsufficientforclassification
Rat NOAEL3000MG/KG/day
During organogenesis
Targetorgan(s):Specifictargetorgantoxicity-singleexposure:Name Route Target
Organ(s)Value Specie
sTestResult ExposureDuration
CALCIUMCARBONATE
Inhalation Respiratorysystem
Alldataarenegative Rat NOAEL0.812mg/l
90minutes
Specifictargetorgantoxicity-repeatedexposure:
Aspirationhazard: Forthecomponent/components,eithernodataarecurrentlyavailableorthedataarenot
Name Route TargetOrgan(s)
Value Species
TestResult ExposureDuration
CALCIUMCARBONATE
Inhalation Respiratorysystem
Somepositivedataexist,butthedataarenotsufficientforclassification
Human NOAELnotavailable
Occupationalexposure
TITANIUMDIOXIDE
Inhalation Respiratorysystem
Somepositivedataexist,butthedataarenotsufficientforclassification
Rat LOAEL0.010mg/l
2years
TITANIUMDIOXIDE
Inhalation Pulmonaryfibrosis
Alldataarenegative Human NOAELnotavailable
Occupationalexposure
QUARTZSILICA Inhalation Silicosis Causesdamagetoorgansthroughprolongedorrepeatedexposure
Human NOAELnotavailable
Occupationalexposure
3-(TRIMETHOXYSILYL)PROPYLGLYCIDYLETHER
Inhalation Heart,Endocrinesystem,bone,teeth,nails,and/orhair,Hematopoieticsystem,liver,immune,nervoussystems,kidney,bladder,respiratorysystem
Alldataarenegative Rat NOAEL1000mg/kg/day
28days
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FM30-FAC240Base sufficientforclassification.
PleasecontacttheaddressorphonenumberlistedonthefirstpageoftheSDSforadditionaltoxicologicalinformationonthismaterialand/oritscomponents.
12.1 Ecotoxicologicalinformation: PleasecontacttheaddressorphonenumberlistedonthefirstpageoftheSDSforadditional ecotoxicologicalinformationonthismaterialand/oritscomponents. Chemicalfateinformation: PleasecontacttheaddressorphonenumberlistedonthefirstpageoftheSDSforadditional chemicalfateinformationonthismaterialand/oritscomponents.
13.1 Disposalmethods: Disposeofcontents/containerinaccordancewiththelocal/regionalnational/internationalregulations.Priortodisposal,consultallapplicableauthoritiesandregulationstoinsureproperclassification.Disposeofwasteproductinapermittedindustrialwastefacility.Asadisposalalternative,incinerateinapermittedwasteincinerationfacility.Properdestructionmayrequiretheuseofadditionalfuelduringincinerationprocesses.Combustionproductswillincludehalogenacid(HCl/HF/HBr).Facilitymustbecapableofhandlinghalogenatedmaterials.Emptyandcleanproductcontainersmaybedisposedasnon-hazardouswaste.Consultyourspecificregulationsandserviceproviderstodetermineavailableoptionsandrequirements.EPAHazardousWasteNumber(RCRA):Notregulated
Productdescription: FM30-FAC240fueltanksealant236mlkitTransportprotectiveservice Maintaintemp.below270CFlashpoint(Closedcup) >930C
12.Ecologicalinformation
13.Disposalconsiderations
14.Transportinformation
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FM30-FAC240Base14.1 ClassificationofthesubstanceinaccordancewithUNrecommendations
UNNumber : UN3082 CLASS : 9
PACKAGINGGROUP : III
14.2 ADR(transportbyroad) NOTRESTRICTED,MARINEPOLLUTANTEXCEPTION
14.3 IMO(maritimetransport) NOTRESTRICTED,ASPERIMDGCODE2.10.2.7,MARINEPOLLUTANTEXCEPTION14.4 IATA(airfreight) NOTRESTRICTED,ASPERSPECIALPROVISIONA197,ENVIRONMENTALLYHAZARDOUS SUBSTANCEEXCEPTION
311/312Hazardcategories:FireHazard–NoPressureHazard–NoReactivityHazard–No ImmediateHazard–Yes DelayedHazard–YesSection313ToxicChemicalssubjecttothereportingrequirementsofthatsectionand40CFRpart372(EPCRA):
NFPA Hazard Classification �Health: 2 Flammability: 1 Instability: 0 Special Hazards: None
Thisdatacompletesthetechnicaldatasheetforuse,butdoesnotreplaceit.Thedatagivenhereisbasedoncurrentknowledgeandexperience.Thepurposeofthissafetydatasheetistodescribetheproductsintermsoftheirsafetyrequirements.Thedatadoesnotsignifyanywarrantywithregardstotheproductsproperties.
15.Regulatoryinformation
16.Otherinformation
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FM30-FAC240Base
TheinformationprovidedonthisMSDSiscorrecttothebestofourknowledge,informationandbeliefatthedateofitspublication.Theinformationgivenisdesignedonlyasaguideforsafehandling,use,processing,storage,transportation,disposalandreleaseandisnottobeconsideredasawarrantyorqualityspecification.Theinformationrelatesontothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedincombinationwithothermaterialorinanyprocess,unlessspecifiedinthetext.
