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PRE-FEASIBILITY REPORT

“Expansion of Manufacturing capacity of

Herbicides/Fungicides/Plant Growth Regulators (PGRs) from

635.125 MT/A to 1006.25 MT/A”

At: M/S. Godrej Agrovet Limited,

E-24, E-24(Part), E-23/1, Lote Parashuram MIDC, Tal: Khed Dist: Ratnagiri

Report prepared by:

Dr. Subbarao’s Environment Center (QCI NABET Accredited Consulting Organization)

Godrej Agrovet Ltd., Lote Parashuram, Khed (Tq.) Ratnagiri (Dst.) PRE FEASIBILITY REPORT

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CONTENTS

CONTENTS ........................................................................................................................................ 1

1. EXECUTIVE SUMMARY .............................................................................................................. 3

2. INTRODUCTION OF THE PROJECT / BACKGROUND INFORMATION .................................. 4

2.1 Identification of Project and Project proponent ......................................................................... 4

2.2 Brief description of nature of the project................................................................................... 4

2.3 Need for the project and its importance to the country and or region ......................................... 4

2.4 Demand-Supply gap ................................................................................................................. 4

2.5 Imports vs. Indigenous products ............................................................................................... 4

2.6 Export possibility ..................................................................................................................... 4

2.7 Employment Generation (Direct and Indirect) due to the project ............................................... 4

3. PROJECT DESCRIPTION .............................................................................................................. 5

3.1 Type of project including interlinked and inter dependent projects, if any. ................................ 5

3.2 Location: .................................................................................................................................. 5

General Location: ............................................................................................................................ 5

Specific Location and Project boundaries: ........................................................................................ 5

3.3 Details of alternate sites considered and the basis of selecting the proposed site (particularly the

environmental considerations gone into should be highlighted) ............................................................ 6

3.4 Size or magnitude of operation ................................................................................................. 6

3.5 Project description with process details .................................................................................... 6

3.6 Raw material required along with estimated quantity, likely source, marketing area of final

product, Mode of transport of raw material and finished product. ......................................................... 6

3.7 Resource optimization / recycling and reuse envisaged in the project, should be briefly outlined.

9

3.8 Availability of water its source, Energy / Power requirement and source................................. 10

3.9 Quantity of waste to be generated (liquid and solid) and scheme for their Management/Disposal

10

4. SITE ANALYSIS .......................................................................................................................... 11

4.1 Connectivity........................................................................................................................... 11

4.2 Land Form, Land use and Land ownership ............................................................................. 11

4.3 Existing land use pattern (agriculture, non-agriculture, forest, water bodies (including area

under CRZ)) ...................................................................................................................................... 11

4.4 Existing Infrastructure ............................................................................................................ 11

4.5 Soil Classification .................................................................................................................. 11

4.6 Climatic data from stationary sources ..................................................................................... 11


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4.7 Social Infrastructure available ................................................................................................ 11

5. PLANNING BRIEF....................................................................................................................... 12

5.1 Planning Concept (type of industries, facilities, transportation etc.) Town and country planning /

Development authority Classification................................................................................................. 12

5.2 Population Projection ............................................................................................................. 12

5.3 Land use planning (breakup along with green belt etc)............................................................ 12

5.4 Assessment of Infrastructure Demand (Physical and Social) ................................................... 12

5.5 Amenities / Facilities .............................................................................................................. 12

6. PROPOSED INFRASTRUCTURE ................................................................................................ 13

6.1 Industrial Area (Processing Area) ........................................................................................... 13

6.2 Residential Area (Non Processing Area) ................................................................................. 13

6.3 Green belt .............................................................................................................................. 13

6.4 Social Infrastructure ............................................................................................................... 13

6.5 Connectivity (Traffic and Transportation Road/Rail/Metro/Water ways etc.) .......................... 13

6.6 Drinking Water Management (Source and Supply of water) ................................................... 13

6.7 Sewerage System ................................................................................................................... 13

6.8 Industrial Waste Management ................................................................................................ 13

6.9 Solid Waste Management ....................................................................................................... 13

6.10 Power requirement & Supply / Source .................................................................................... 13

7. PROJECT SCHEDULE AND COST ESTIMATES ....................................................................... 14

7.1 Likely date of start of construction and likely date of completion (Time schedule for the project

to be given)........................................................................................................................................ 14

7.2 Estimated project cost along with analysis in terms of economic viability of the project .......... 14

8. ANALYSIS OF PROPOSAL (Final recommendations) ................................................................. 15

8.1 Financial and social benefits with special emphasis on the benefit to the local people including

tribal population, if any, in the area. ................................................................................................... 15

Annexure – I ...................................................................................................................................... 16

Process Flow Diagrams: .................................................................................................................... 16

Annexure – II .................................................................................................................................... 25

Quantity of waste to be generated (Solid, Liquid and Hazardous) ....................................................... 25

Annexure – III ....................................................................................................................................... 26

Photographs ....................................................................................................................................... 26


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1. EXECUTIVE SUMMARY

Godrej Agrovet Limited (GAVL) is a diversified, Research & Development focused agri-business

company, dedicated to improving the productivity of Indian farmers by innovating products and services that sustainably increase crop and livestock yields. It holds leading market positions in the different

businesses in which we operate - Animal Feed, Crop Protection, Oil Palm, Dairy and Poultry and

Processed Foods. In Decemeber 2013, GAVL took over M/s Gouldmohar Agrochem & Feeds Ltd which was formerly known as Bahar Agrochem & Feeds Ltd., which was established in 1986 & Commercial

production was started in 1987. The industry is located in Lote Parashuram MIDC area.

GAVL has an existing manufacturing capacity of 635.125 MT/A. and it proposes to expand its capacity to

1006.25 MT/A. The industry has a valid Consent to Operate from Maharashtra Pollution Control Board, valid upto 30/06/2021. The present application is for Environmental Clearance for the proposed

expansion of the products Herbicides/Fungicides/PGRs.

The present water requirement is 36 m3/ day which is taken from MIDC water supply. After expansion

the water requirement shall be 116 m3/ day which shall be taken from MIDC for which necessary

application is being submitted. The effluent quantity after expansion shall be 23 m3/ day, out of which 6

m3/ day is domestic effluent. The effluent is treated to the Consent conditions of the Maharashtra

Pollution Control Board and treated effluent is sent to CETP for further treatment and disposal, for which

necessary application is being made to MIDC. The domestic effluent shall be treated based on Root zone

technology and treated effluent shall be used for gardening / Green belt development.

In order to reduce the effluent generation, the industry proposes to concentrate the effluents in Multiple Effect Evaporator (MEE) and concentrated effluents are dried by Agitating Thin Film Dryer (ATFG) and

the dried solids are disposed along with Hazardous waste.

The Hazardous waste generated is sent to MWML, Mumbai (CHWTSDF) for further treatment and disposal.

The Non-Hazardous solid waste such as Drums/Containers are being decontaminated and sold to

authorized recyclers. Other solid waste material such as Paper, Wood and Plastics etc. are sold to recyclers/open market.

The industry has developed Green belt area of 3545 sq. m. covering 33 % of the total area. As per the

CPCB guidelines, total of 535 trees are required. Industry have already planted 200 trees in Green belt

area, also it has planted some of the trees along the roadside.

The industry implemented Rain Water Harvesting system and collecting around 1,25,000 liters of water

which is being used for Process operations.

The industry has carried out Risk Assessment studies and implemented all the measures to avoid any

accidents and provides protective safeguards to all the employees. Regular health checkups once in three

months for all employees and special care and medical aids are given to the needy people.

The industry has undertaken a number of social and cultural activities to the nearby local population and

proposes to reserve 2.5 % of the capital cost of the project as CSR activities.

The industry has provided online monitoring system and connected to CPCB/MPCB servers.


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2. INTRODUCTION OF THE PROJECT / BACKGROUND INFORMATION

2.1 Identification of Project and Project proponent

This project is of expansion in manufacturing capacity of Herbicides/Fungicides/PGRs from 635.125

MT/A to 1006.25 MT/A by M/S. Godrej Agrovet Pvt. Ltd., Lote Parashuram, Taluka: Khed, District:

Ratnagiri.

Project Proponent:

Name: M/S. Godrej Agrovet Limited, Lote Parashuram, Taluka: Khed, District: Ratnagiri.

Address: Plot no. – E-24, E-24 (Part) and E-23/1,

MIDC Lote Parashuram, Taluka: Khed, District: Ratnagiri.

Latitude: 17º 36’ 26” N, Longitude: 73º 29’ 28” E

Phone no.: (02356) - 272214

Mobile no.: (+91) - 9920834388

2.2 Brief description of nature of the project

GAVL manufactures herbicides / fungicides/ PGRs for different applications. It has an existing capacity

of 635.125 MT/A and proposes to expand to 1006.25 MT/A.

2.3 Need for the project and its importance to the country and or region

Herbicides play an important role in maintaining plant health. India being an agro based country, the use

of herbicides / fungicides/ PGRs is being widely practiced. Besides, there is a tremendous potential to

export herbicides / fungicides/ PGRs in third world countries. The use of herbicides / PGRs would help to

improve the growth and weed out the unwanted material which would hinder the plant yield. It is also

productive and profitable for farmers to use Herbicides/ Fungicides / PGRs instead of conventional ways

of farming.

2.4 Demand-Supply gap

There is huge demand for Herbicides in Indian as well as in International markets.

2.5 Imports vs. Indigenous products

Some of the products / raw material are imported for manufacture of indigenous products.

2.6 Export possibility

At present, many of the products are exported to third world countries and the demand for exporting is

increasing day by day.

2.7 Employment Generation (Direct and Indirect) due to the project

There could be direct employment opportunities for local people due to this expansion project. Also,

increased transportation and other activities would generate additional indirect employment opportunities.


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3. PROJECT DESCRIPTION

3.1 Type of project including interlinked and inter dependent projects, if any.

The project is not of interlinked and interdependent type.

3.2 Location:

General Location:

Figure 1 General Location

Specific Location and Project boundaries:

Figure 2 Specific Location and Project Boundary


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Table 1 Location and Project boundaries with coordinates

Description Latitude Longitude

South 17° 36' 24" N 73° 29' 23" E

North 17° 36' 28" N 73° 29' 24" E

East 17° 36' 27" N 73° 29' 29" E

South West 17° 36' 25" N 73° 29' 22" E

3.3 Details of alternate sites considered and the basis of selecting the proposed site (particularly

the environmental considerations gone into should be highlighted)

The existing site facilities are adequate for the proposed expansion. Also, existing site is well connected

to National Highway (66) and available with all the amenities. Hence, no alternate site is necessary to be

considered.

3.4 Size or magnitude of operation

The proposed change in existing production capacity is as follows:

Sr.

No.

Products Quantity (MT/A)

Present Proposed Total

1 Liquid Vipul, Vipul granules, Diamore Suruchi, Ruchira 36 0 36

2 Achook Nimin 36 0 36

3 Combined (PGR) like super shakti & Diamore combine

&double

12 0 12

4 Bumper Bountee 12 0 12

5 Dapcoat 24 0 24

6 Homobrassinolide (HBR) 0.6 0.9 1.5

7 GOD –HH001 Pyrithioback Sodium Tech. 40 20 60

8 Agroneem 200 0 200

9 Hitweed Pyrithiobac Sodium 10% 36 0 36

10 Neem oil Emulsifiable 24 0 24

11 Bispyribac Sodium Technical 40 20 60

Bispyribac Sodium Formulation 144.405 0 144.405

12 Florchlorfenuron Technical 20 30 50

Florchlorfenuron Formulation. 10.12 0 10.12

13 Quizalofap-P-Ethyl Technical 00 60 60

14 Thiophanate Methyl technical 00 60 60

15 Metribuzin Technical 00 60 60

16 Trifloxystrobin Technical 00 60 60

17 Dimethomorph Technical 00 60 60

TOTAL 635.125 370.9 1006.25

3.5 Project description with process details

Process flow sheet diagrams indicating manufacturing process and raw material requirement is attached

as an Annexure – I.

3.6 Raw material required along with estimated quantity, likely source, marketing area of final

product, Mode of transport of raw material and finished product.

Raw materials are available in open market. Final products are sold in both Indian and International

markets. Both raw materials and products are transported by road.


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Raw material quantities with respect to the finished products are as per the following:

Sr.

No.

Raw Materials

Present

MT/A

Proposed

MT/A

Total

MT/A

1 Homobrassinolide (batch size : 1.10 kg) 0.600 0.900 1.500

1. Stigmasterol 1.143 1.715 2.858

2. Methyl Ethyl Ketone (M.E.K.) 27.818 41.727 69.545

3. Triethylamine 0.777 1.165 1.942

4. Methanesulphonyl Chloride (Mesyl chloride) 0.327 0.491 0.818

5. Chromium trioxide (CrO3) 0.202 0.303 0.505

6. Sulfuric acid (H2SO4 ) 0.176 0.263 0.439

7. Magnesium sulphate-(MgSO4) 0.545 0.818 1.364

8. Dimethyl formamide (D.M.F.) 11.018 16.527 27.545

9. Molecular sieves 1.091 1.636 2.727

10.p-Toluene sulphonic acid (P.T.S.A.) 0.106 0.159 0.265

11.Sodium bromide (NaBr) 0.144 0.216 0.360

12.Ethylacetate (E.A) 75.273 112.909 188.182

13. Silica gel 20.509 30.764 51.273

14. Petroleum ether / n-Hexane (60-80

oC) 174.545 261.818 436.364

15. Tetrahydrofuran (T.H.F.) 10.255 15.382 25.636

16. Osmium tetroxide 0.027 0.041 0.068

17. t-Butanol 0.901 1.352 2.253

18. N-Methyl morpholine-N-oxide (N.M.O.) 0.648 0.972 1.620

19. Sodium bisulfite solution 1.091 1.636 2.727

20. Celite 545 0.545 0.818 1.364

21. Pyrimidine 2.302 3.453 5.755

22. Potassium hydroxide (KOH) 0.218 0.327 0.545

23. 4-Dimethylamino pyrimidine (D.M.A.P.) 0.158 0.237 0.395

24. Acetic anhydride 1.584 2.376 3.960

25. Ethylene dichloride (EDC) 16.364 24.545 40.909

26. Dichloromethane (CH2Cl2) 70.909 106.364 177.273

27. Trifluoroacetic anhydride ((CF3CO)2O 4.429 6.644 11.073

28. Hydrogen peroxide (H2O2) 1.211 1.816 3.027

29. Disodium hydrogen phosphate (Na2HPO4) 4.135 6.202 10.336

30. Methanol (CH3OH) 22.505 33.758 56.264

31. Potassium carbonate 1.527 2.291 3.818

32. Chloroform (CHCl3) 27.273 40.909 68.182

33. Acetone 21.818 32.727 54.545

34. Calcium chloride (CaCl2) 0.218 0.327 0.545

35. Sodium chloride (NaCl) 21.382 32.073 53.455

36. Sodium bicarbonate (NaHCO3) 0.665 0.998 1.664

37. Sodium sulphate ( Na2SO4) 14.182 21.273 35.455


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38. Hydrochloric acid ( Hcl) 7.855 11.782 19.636

2 PYRITHIOBAC SODIUM BATCH SIZE: 110kg 40.000 20 60.000

Step –I

1 2, 6 Dichloro benzonitrile 41.818 20.909 62.727

2 N-methyl pyrilidone 250.909 125.455 376.364

3 Sodium sulphide-60% 79.273 39.636 118.909

Step-II

1. Product of Step-I MCBN

2. Sodium sulphide-60% 14.545 7.273 21.818

3. Sodium hydroxide flakes 54.182 27.091 81.273

4. Water 236.364 118.182 354.545

5. Hydrochloric acid (1:1) 472.727 236.364 709.091

6. Dichloromethane 327.273 163.636 490.909

Step-III

1. Product of Step-II MCBA 40.000 20 60.000

2. 2-Methylsulfonyl 4,6-Dimethoxypyrimidine 381.819 190.909 572.728

3. Potassium carbonate 45.455 22.727 68.182

4. Tetra butyl ammonium bromide 0.909 0.455 1.364

5. Sodium sulphate 1.818 0.909 2.727

6. Hydrochloric acid (1:1) 109.091 54.545 163.636

Step-IV

1. Product of Step-III Pyrithiobac acid

2. Sodium carbonate 8.327 4.164 12.491

3. Methanol 290.909 145.455 436.364

3 CPPU (BATCH SIZE:0.9 Kgs) 20.000 30 50.000

1. 2-CPA 2.222 3.333 5.555

2. Dichloromethane 33.333 50.000 83.333

3. Phenyl Isocyanate 2.222 3.333 5.555

4. Petroleum ether 6.667 10.001 16.668

5. Methanol 6.667 10.001 16.668

6. Toluene 33.333 50.000 83.333

4 BIS PYRIBAC SODIUM (BATCH SIZE: 150 KG) 40.000 20 60.000

1. DHBA 27.200 13.6 40.800

2.Sodium Hydroxide prills 20.800 10.4 31.200

3. 2-Methylsulfonyl 4,6-Dimethoxypyrimidine 76.000 38.000 114.000

4. Tetra butyl ammonium bromide 533.000 266.500 799.500

5. Toluene 133.333 66.667 200.000

6. Ethyl acetate 146.667 73.334 220.001

5 Quizalofop ethyl Techanical 0 60 60

1. OHOP 0 44.34 44.34

2. Sulphuric acid 0 6.12 6.12

3. Ethanol 0 21.6 21.6

4. Etyl acetate 0 330 330


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5. Sodium bicarbonate 0 20.94 20.94

6. DCQ 0 41.58 41.58

7. Potssium carbonate 0 35.16 35.16

8. Acetonitrile 0 186 186

6 MetriBuzin Tech 0 60 60

t-Butyl methyl ketone 0 42 42

Thionyl Chloride 0 60 60

Dichloro methane 0 9 9

Dimethyl amine 0 60 60

20% NaOH in water( including Scrubber) 0 360 360

Thiocarbohydrazide 0 48 48

Methyl Bromide 0 42 42

Dichloro ethane 0 21 21

7 Dimethomorph tech 0 60 60

4-Chloro-3,4-Dimethoxy bezophenone 0 60 60

Catalyst Zn-Cu- V 0 0.6 0.6

N- Acetyl Morpholine 0 30 30

Toluene 0 9 9

Methanol 0 30 30

8 Thiophanate methyl Tech 0 60 60

Methyl Chloroformate 0 19.8 19.8

Sodium thiocyanate 0 17.4 17.4

Solvent -I(EDC) 0 15 15

O-phenylenediamine 0 22.8 22.8

Solvent -II(MDC) 0 9 9

9 Trifloxystrobin Tech 0 60 60

3-Trifluoromethy acetophenone 0 66 66

Ethanol 0 5 5

Hydroxylamine hydrochloride 0 30 30

2-methyl phenyl(oxo)acetic acid 0 60 60

20% NaOH in water( including Scrubber) 0 180 180

Terabutyl ammonium bromide 0 6 6

Dichloro ethane 0 21 21

Thionyl chloride 0 36 36

Methanol 0 9 9

Acetonitrile 0 7.5 7.5

N-Bromosuccinamide 0 51 51

Methyl isobutylketone 0 150 150

Potassium Carbonate 0 48 48

Water 0 120 120

3.7 Resource optimization / recycling and reuse envisaged in the project, should be briefly

outlined.

Maximum recycling and recovery of solvents is carried out in the manufacturing process


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3.8 Availability of water its source, Energy / Power requirement and source

Water permission is already available from the MIDC. At present, water requirement is 36 m3/ day and

after expansion, it shall be 116 m3/ day. Effluent quantity generated shall be increased from 15 m

3/ day to

23 m3/ day, out of which 6 m

3/ day shall be domestic effluent.

Table 2 Water budget

PRESENT (m3/day) PROPOSED (m

3/day) TOTAL (m

3/day)

CONSU

MPTION

LOSSES

/USED

EFFL

UENT

CONSU

MPTION

LOSSES

/USED

EFFL

UENT

CONSU

MPTION

LOSSES

/USED

EFFL

UENT

Domestic 08 04 04 4 2 02 12 06 06

Industrial 11 0.5 10.5 6 1 5 17 1.5 15.5

Boiler 05 4.5 0.5 50 49 1 55 53.5 1.5

Cooling 2 2 0 18 18 0 20 20 0

Gardening 10 10 00 2 2 0 12 12 0

TOTAL 36 21 15 80 72 8 116 93 23

3.9 Quantity of waste to be generated (liquid and solid) and scheme for their

Management/Disposal

Details of the waste generation are attached in this report as an Annexure - II


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4. SITE ANALYSIS

4.1 Connectivity

Existing Site is conveniently located in Lote Parashuram MIDC.

4.2 Land Form, Land use and Land ownership

Land is in MIDC area.

4.3 Existing land use pattern (agriculture, non-agriculture, forest, water bodies (including area

under CRZ))

Existing land comes under industrial estate. There is no reserved forest, eco sensitive areas, wild life

sanctuaries and CRZ within 10 km radius of industry.

4.4 Existing Infrastructure

Existing infrastructure is adequate for the proposed expansion.

4.5 Soil Classification

Soil observed in the study area is mostly Clayey Loam.

4.6 Climatic data from stationary sources

The wind direction is predominantly blowing from West to East. Normal temperature range is 10 ºC to

42ºC and the relative humidity varies from 50% to 85 %. The maximum rainfall observed is around 880

mm.

4.7 Social Infrastructure available

The factory situated in Lote Parashuram industrial area which has facilities of Gymkhana, Sports complex

and recreational club, restaurants. The entire MIDC area is well connected by 20 m wide roads. It has

national highway (NH-66) 1 km away.


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5. PLANNING BRIEF

5.1 Planning Concept (type of industries, facilities, transportation etc.) Town and country

planning / Development authority Classification

It is situated in Industrial area.

5.2 Population Projection

Not Applicable.

5.3 Land use planning (breakup along with green belt etc)

Sr. No. Description Area in Sq. m.

1 Built up area

a. Existing

b. Proposed

3108.43

849

2 Storage area

(Raw material, finished product and hazardous waste)

476.62

3 Internal Roads 1100

4 ETP 598

5 Parking 545

6 Greenbelt 3544.86

7 Vacant Land 520.09

Total 10742

5.4 Assessment of Infrastructure Demand (Physical and Social)

The existing infrastructure facilities for the proposed expansion project would be adequate. The social

infrastructure facilities are available in the MIDC area, which would be adequate.

5.5 Amenities / Facilities

Being situated in MIDC area, all the infrastructure facilities are available.


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6. PROPOSED INFRASTRUCTURE

6.1 Industrial Area (Processing Area)

Total of 849 sq. m. area shall be used for the proposed expansion activities.

6.2 Residential Area (Non Processing Area)

Not applicable

6.3 Green belt

Total area of 3544.86 sq. m. is provided, which approximately 33 % of total plot area. As per the CPCB

guidelines, there should be 1500 trees per hectare. GAVL needs to have 540 trees (0.3534 ha). GAVL

already planted 200 trees so far, remaining trees shall be planted along with the expansion.

6.4 Social Infrastructure

MIDC facilities.

6.5 Connectivity (Traffic and Transportation Road/Rail/Metro/Water ways etc.)

Not Applicable.

6.6 Drinking Water Management (Source and Supply of water)

MIDC

6.7 Sewerage System

CETP

6.8 Industrial Waste Management

CETP

6.9 Solid Waste Management

MWML, Mumbai (CHWTSDF)

6.10 Power requirement & Supply / Source

At present, Power requirement of 550 KVA is fulfilled by MSEDCL grids. After proposed expansion, it

shall be 1100 KVA. DG Set is used as a power backup of 200 KVA capacity, after expansion it shall be

500 KVA.


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7. PROJECT SCHEDULE AND COST ESTIMATES

7.1 Likely date of start of construction and likely date of completion (Time schedule for the

project to be given)

Construction shall be started once the Environmental Clearance is obtained. And the project shall be

completed within 1 year of receipt of Environmental Clearance.

7.2 Estimated project cost along with analysis in terms of economic viability of the project

The project cost estimated is around 10 crore rupees.


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8. ANALYSIS OF PROPOSAL (Final recommendations)

8.1 Financial and social benefits with special emphasis on the benefit to the local people

including tribal population, if any, in the area.

Employment opportunities are generated to local people and strengthening the financial condition of the

industry. The products are import substitution and savings in foreign exchange. Industry has earmarked

2.5 % of the total project cost for Corporate Social Responsibility (CSR) activities. Details of CSR

activities undertaken so far are given as under:


16

Annexure – I

Process Flow Diagrams:

Title: PROCESS FLOW DIAGRAM FOR PYRITHIOBAC SODIUM

Water: 1540

Kg

Solvent: 4100 Kg Recovered.

Solvent: 4400 Kg Sodium Sulphide: 1726

Kg

Chlorinated Benzonitrile (DCBN): 885

Kg

DEHALOGENATION: R1

Sodium Hydroxide: 3500

Kg

Water: 885 Kg HYDROLYSISR3 7951 Kg

HCL (25%): 2500 Kg ACIDIFICATION-1R213241 kg

Effluent: 3860Kg

Water (ICE): 1990 Kg

Potassium Carbonate: 840 Kg Water: 4400 Kg

Pyrimidine: 590 Kg

Methylene Chloride: 800 Kg

COUPLING

R415229 kg

WORK-UP SEPARATOR

9381 Kg

Water Wash: 3300 Lit

Effluent: 3300Kg

Tetra butyl Ammonium

Bromide: 18Kg

Acidification – 2 R2 18549 kg HCL (25%): 1550 Kg Water: 1770 Kg

Centrifuge Effluent: 21667Kg

Pyrithiobac Sodium Tech.

1000 Kg

Water Wash: 4118 Kg


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Title: PROCESS FLOW DIAGRAM FOR HOMOBRASSINOLIDE

MESSYLATION

67 kg

LACTONISATION626

Kg

ACETYLATION 540.19

Kg

625.319 Kg

HYDROXYLATION

526.05 kg

475.

REARRANGEMENT

495.5 Kg

OXIDATION

415.kg

SOLVOLYSIS

124 kg

HYDROLYSIS 541.44

Kg

Stigma sterol: 2 Kg. Triethyl Amine:

1.5 Kg, Messyl Chloride: 0.5 Kg

Methyl Ethyl Ketone (Recycled): 50 Kg

Effluent: 13 Kg

Chromium Tri Oxide: 250 gm ,

Sulphuric Acid : 322 Kg , Water : 0.75 Kg

8% Sodium Bicarbonate Sol. 10 Kg

Effluent: 72 Kg

Effluent: 40 Kg Di Methyl Formamide: 20 Kg, sodium

Bromide: 250gm, P-toluene Sulphonic

Acid: 250gm, Ethyl Acetate (Recycled): 50 Kg

Effluent: 40.5

Kg Tetra Hydro furon : 20 Kg , Osmium

Tetroxide : 50 gm, T-Butanol : 1.5 Kg

N-Methyl Morpholene N-Oxide: 1.5 Kg

Sodium bisulphite Soin: 2 Kg, Celite

545: 1 kg, Water: 5 Kg

Effluent: 45.05 Kg

Pyrimidine: 4 Kg , Acetic Anhydride: 2.90 Kg , Ethylene Di Chloride: 10 Kg

4 Dimethyl Ameno Pyrimidine: 290

gm.

Tri Fluro Acetic Anhidride: 8 Kg,

Hydrogen peroxide 2 Kg, Disodium

Hydrogen Phosphate: 8 Kg, Dichlormethane 80 Kg

Effluent: 42.19 Kg

Effluent: 134.82 kg

Effluent: 540.44 Kg

Methanol (Recovered) :10 Kg , Potassium Carbonate :1 Kg, Chloroform 5 Kg ,

10 Kg Water Wash, 3

Kg Bi carbonate wash

60 Kg Water Wash

40 Kg Water Wash

Water50 Kg Reactor washing

30 Kg Water for washing

10 Kg Water -5% HCL

wash

32 Kg Water For reactor wash, 5% HCL Wash, 10 Kg

20 Kg Water wash, 10 Kg Bi

Carbonate wash.

1000 gm

HOMOBRASSINOLIDE

20 Kg water

14.26 Kg Bi Carbonate wash.


18

Title: PROCESS FLOW SHEET DIAGRAM FOR BISPYRIBAC SODIUM TECHNICAL

Manufacturing Process: 2,6- dihydroxy benzoic acid undergo condensation reaction with Pyrimidine

(MSDP) compound in aromatic hydrocarbon to give Bispyribac sodium under alkaline condition. The

product is isolated by filtration at room temperature and washed with toluene, ethyl acetate and water.

The product is dried under vacuum.

Condensation Reaction 2380 Kg

Centrifuge 1250 Kg

Sodium Hydroxide

390 Kg

Pyrimidine

1490 Kg 2,6Dihydroxy Benzoic

acid 500 Kg

Crude Product 1250 KG Toluene for recycle

2020 Kg

Toluene for washing 2000 Kg

Effluent 1030 Kg

Crude Product 1230 KG Ethyl Acetate for

washing 1000 Kg

Residue

40 Kg Toluene for recycle

1980 Kg

Ethyl Acetate for recycle

1000 Kg

Toluene for recycle

970 Kg Residue

20 Kg

Crude Product 1230 KG Water washing 500 Kg

Effluent 630 Kg

Drying 1100 KG

Finished Product 1000 KG

Loss 100 Kg


19

Title: PROCESS FLOW SHEET DIAGRAM FOR FORCHLORFENURON TECHNICAL

Manufacturing Process: The technical grade product forchlorfenuron is obtained by the reaction of phenyl

isocynate with 2-chloro, 4-aminopyridine. The product form is then reflux with the solvents like dichloromethane

acetone and chloroform. Then water wash is given to get the finished product.

Mixing & Distillation 4550 Kg

2-Chloro-4-aminopyrimidine

1030 Kg

Dichloromethane

2500 Kg Phenyl Isocyanate

1020 Kg

Reflux for 7 Hr. &

Distillation 3300 Kg Acetone 1000 KG Rec. Acetone 900 KG

Reflux 2400 Kg

Rec. Dichloromethane

2250 KG

Chloroform 1000 KG Rec. Chloroform 950 KG

Solvent Distillation Crude Solvent 400 Kg

Rec Solvent

350 Kg

Residue

50 Kg

CRUDE PRODUCT 1050 Water Wash 1200 KG

Effluent 1250 Kg FINISHED PRODUCT

1000 Kg


20

Title: PROCESS FLOW DIAGRAM FOR QUIZALOFOP-P-ETHYL

ETHANOL

6050Kg

SULPHURIC ACID: 112

Kg

OPHP 812 Kg

REACTION 6974 kg

DISTILLATION

ETHYL

ACETATE 10320 REACTION MASS 1529 KG

REACTION MASS 10115 KG

REC. ETHANOL 5445

KG

HEATING 11849 KG

REC ETHYL

ACETATE

9804 KG

Sodium Bicarbonate

380 Kg + Water 7690

Kg

DCQ 1058 KG

STIRRING 15158 KG

Effluent: 9057Kg

REACTION MASS 2371 KG

POTASSIUM

CARBONATE 640

KG +

ACETONITRILE

13460 KG

DISTILLATION

DISTILLATION

REC

ACETONITRILE

12787 KG

ETHYL

ACETATE

13750 KG

DISTILLATION 16121 KG

REC ETHYL

ACETATE

13075 KG

REACTION MASS 3041 KG ETHANOL 9690

KG

DISTILLATION 12731 KG REC ETHANOL

9200KG

REACTION MASS 3041 KG WATER WASH 7690

KG

EFFLUENT 9731KG

FINAL PRODUCT 1000 KG


21

Title: Process flow diagram for Dimethomorph – Technical

1250 kg ETP

Condensation reaction

Reaction

N- Acetyl Morpholine

500 Kg

4-Chloro-3,4-Dimethoxy

benzophenone 1000 Kg

g

Methanol 10000 KG Methanol MLR 10300 KG

Toluene 3000 KG Rec. Toluene 3150 KG

Wet product 1060 kg

Zinc copper- vanadium

catalyst 10 Kg

g

Crude Dimethomorph 1510

kg+ Methanol 10000 kg

Crude Dimethomorph

1210 kg + 3000 kg

Toluene

Pure product 1000 kg

Dryer Loss 60 kg

Distillation: 2700 KG

Distillation 9500

KG

200 kg

loss

Residue

250 kg

Scrubber

500 kg

550 kg loss

1050 kg to ETP

Residue

250 kg

Scrubber


22

Title: Process flow diagram for Metribuzin – Technical

Manufacturing Process:- : Manufacturing of Metribuzin technical is three-step process.

In the first step, t-Butylmethylketone on chlorination with thionyl chloride dichloroethane, followed by reaction

with dimethylamine to give intermediate-A. In step-2 Intermediate –A reacted with thiocarbohydrazide to give Intermediate –B.

In step-3 Intermediate –B methylated with methyl bromide to give Metribuzin.

t-Butyl methyl ketone 700 kg

Chlorination, Intermediate A 1300 kg

Thionyl Chloride

1000 Kg

Dimetyl amine 1000 Kg Dichloromethane 3000 kg

Intermediate A, 2000 kg Thiocarbohydrazide

700 kg

Hydrolysis &CycIization

Intermediate B, 2800 kg

Methyl bromide 800 kg

Metribuzin 2000 kg

Recovered DCM 3400 kg

Effluent send to ETP 4000 kg

Caustic scrubber 2.0 Kl

Residue 150 kg

Residue 500

kg

Dichloroethane 7000kg

Recovered

Dichloroethane 7800 kg

Dichloroethane for

distillation 6650 kg

3.0kl effluent to ETP

Pure Metribuzin 1000 kg

Water 3000 kg for purification

Residue 350

kg

DCM for distillation

2850 kg


23

Product Name:- Thiophanate Methyl – Technical

Manufacturing Process:-

Manufacturing of Thiophanate methyl technical is two-step process.

In the first step, methyl chloroformate is reacted with sodium thiocyanate in an appropriate solvent at low temperature.

This reaction forms methoxy carbonyl isothiocyanate.

This is separated and is subsequently reacted with ortho phenylene diamine to form crude Thiophanate methyl.

Condensation 5685 kg

Reaction

Ethylene dichloride 5000

Kg

Methyl Chloroformate

360 Kg

g

Rec. EDC 5025 KG

Dichloromethane 3000

KG

Rec.

Dichloromethane

3040 KG

Addition reaction 1020Kg

Wet product 1020 kg

Sodium Thiocyanate

325 Kg

g

Separation

Crude 660 kg

O-phenylenediamine 400 kg

Pure product 1000 kg

Dryer Loss 20 kg

Distillation

2800 KG

Distillation 4750

KG

Residue

200 kg

Loss 100 kg

Residue

80 Kg

Scrubber


24

Title: Process flow Diagram for Trifloxystrobin Technical

Intermediate-I1280 kg

3-Trifluoromethy

acetophenone550Kg

Ethanol500 Kg

g Dichloromethane1050 kg

Thionyl chloride300 KG

Rec. Methanol 1050 kg

Intermedite-III2540

Intermedite-IV2340

Hydroxylamine

hydrochloride230 Kg

g Reaction

2340 kg

Intermediate-II2590 kg

Methanol 1000 kg

Crude product 1

1040 kg

Potassium Carbonate 200 kg

Methyl isobutylketone1000 kg

Dichloroethane1000 KG

Dichloroethane1000 KG

Terabutyl ammonium

bromide10 KG

2 methyl phenyl (oxo)

acetic acid 500 kg

Acetonitrile 1000 kg

Rec. Dichloromethane1100 kg

N-Bromosuccinamide

100 kg

Intermedite-II2490 kg

Rec ethanol 450

kg

Rec. Acetonitrile 1200 kg

Scrubber

2500 Lit Scrubber

Distillation

Mass 950 kg+

Loss 25

Distillation

DCE950 kg +

Loss 25 Kg

Residue

75kg

Distillation Mass 950 kg Loss 25 Kg

Kg

Residue

75 kg

Residue

125 kg

Distillation

950 kg +

Loss

150Kg Kg

Residue

100 kg

2600 Lit Effluent

ETP

Pure product 1000 kg Water 3500 lit. purification Effluent 3540 kg to

ETP

MIBK 1300 Kg

Residue

100 kg

Distillation

Mass 950 kg

++ Loss

250Kg

Solvent

Separation to

recycle


25

Annexure – II

Quantity of waste to be generated (Solid, Liquid and Hazardous)

PRODUCT

S LIST

Mfg. Qty MT/A Mfg. Qty KG/D Effluent Generation

in Lit / Day

Residue Generation In

KG/D

PR

ES

EN

T

PR

OP

OS

ED

TO

TA

L

PRES

ENT

PRO

POS

ED

TOT

AL

Efflu

ent

/T

PRES

ENT

PR

OP

OS

ED

TOT

AL

KG

PER

MT

PR

ES

EN

T

PR

OP

OS

ED

TO

TA

L

Homobrass

inolide

(HBR) 0.6 0.9 1.5 1.64

2.47 4.11 9284

50 557 836

1392.

675

0 0 0 0

GOD –

HH001

Pyrithiobac

k Sodium

Tech.

40 20

60

109.5

9

54.79 164.3

8 2882

7 1153 577

1729.

62

0 0 0 0

Bispyribac

Sodium

Technical 40 20 60

109.5

9

54.79 164.3

8 1760 70 35 105.6

60 7 3 10

Florchlorfe

nuron

Technical 20 30 50 54.79

82.19 136.9

9 1250 25 38 62.5

50 2.7

4 4 7

Quizalofap

-P-Ethyl

Technical 0 60 60 0.00

164.3

8

164.3

8 1879

6 0

112

8

1127.

76

0 0 0 0

Thiophana

te Methyl

technical 0 60 60 0.00

164.3

8

164.3

8 500 0 30 280

85 0 14 14

Metribuzin


164.3

8

164.3

8 7400 0 444 444 500 0 82 82

Trifloxystr

obin


164.3

8

164.3

8 6040 0 362 362

475 0 78 78

Dimethomo

rph

Technical

0 60

60 0.00

164.3

8

164.3

8 1500

0 90 90

500 0 82 82

Total 100

.6

370.

9

471.

5 276 1016

1291.

78

1805.

55

353

9 5595 9 264 273


26

Annexure – III

Photographs

Factory Main Gate Internal Roads

Green Belt

ETP RO Plant

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