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�3URGXFW�,GHQWLW\��&KU\VDO�&OHDU�5RVH�3UR�9DVH��,QWHQGHG�8VH��Cut�flower food for professional use 0DQXIDFWXUHU��Chrysal International BV� � P.O. Box 5300

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7HOHSKRQH: +31 (0)35-6955888 )D[: +31 (0)35-6955822 (PDLO: [email protected] (PHUJHQF\�,QIRUPDWLRQ: +31 (0)35-6955851 06'6�'DWH�RI�3UHSDUDWLRQ: ��10/09/08 ��+$=$5'6�,'(17,),&$7,21� This product is a liquid with a characteristic odor.

(0(5*(1&<�29(59,(:�CAUTION! May cause eye irritation. ��&20326,7,21�,1)250$7,21�21�,1*5(',(176��&RPSRQHQW� &$6�1R�� $PRXQW�Aliphatic acid Proprietary 1-5% Non-Hazardous Ingredients Mixture 95-99% ��),567�$,'�0($685(6� (\H��Immediately flush eyes with large quantities of water, holding the eyelids apart. Get medical attention if irritation persists. 6NLQ��If contact occurs,�wash thoroughly with soap and water. Get medical attention if irritation develops. ,QJHVWLRQ� This product is not acutely toxic. If swallowed, seek medical advice. ,QKDODWLRQ��Remove to fresh air. Get medical attention if symptoms persist�� ),5(�),*+7,1*�0($685(6� ([WLQJXLVKLQJ�0HGLD��Use media appropriate for surrounding fire. 8QXVXDO�)LUH�RU�([SORVLRQ�+D]DUGV��None known. 6SHFLDO�)LUH�)LJKWLQJ�,QVWUXFWLRQV� None required. Follow standard firefighting procedures. ([SORVLRQ�'DWD��VHQVLWLYLW\�WR�PHFKDQLFDO�LPSDFW�RU�VWDWLF�GLVFKDUJH��None known. +D]DUGRXV�&RPEXVWLRQ�3URGXFWV: Oxides of carbon. ��$&&,'(17$/�5(/($6(�0($685(6� Wipe up with absorbent material and place in container for disposal. Wash spill area with water. ��

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��+$1'/,1*�$1'�6725$*(� +DQGOLQJ� Avoid contact with the eyes. Avoid prolonged contact with skin. Wash thoroughly after handling. 6WRUDJH��Store as recommended on the product label.� ��(;32685(�&21752/6�3(5621$/�3527(&7,21� ([SRVXUH�*XLGHOLQHV�

Aliphatic acid None Established Non-Hazardous Ingredients None Established

(QJLQHHULQJ�&RQWUROV��Use with adequate general or local exhaust ventilation to minimize exposures levels.�5HVSLUDWRU\�3URWHFWLRQ��None normally required. 6NLQ�3URWHFWLRQ��Wear impervious gloves such as rubber if needed to avoid prolonged contact. �(\H�3URWHFWLRQ�� Safety goggles where splashing is possible. �2WKHU�� Appropriate protective clothing as needed to avoid prolonged contact. ��3+<6,&$/�$1'�&+(0,&$/�3523(57,(6� $SSHDUDQFH�$QG�2GRU� Liquid with a characteristic odor. �3K\VLFDO�6WDWH��Liquid %RLOLQJ�3RLQW��Not available �9DSRU�'HQVLW\��Same as water 9DSRU�3UHVVXUH��Same as water 6ROXELOLW\�,Q�:DWHU��Soluble� (YDSRUDWLRQ�5DWH��Same as water 6SHFLILF�*UDYLW\: 1.251 S+��Not established 0HOWLQJ�3RLQW� Not available 2FWDQRO�:DWHU�&RHIILFLHQW��Not determined )ODVKSRLQW� None� $XWRLJQLWLRQ�7HPSHUDWXUH��None�)ODPPDEOH�/LPLWV��/(/��Not applicable � 8(/: Not applicable� ��67$%,/,7<�$1'�5($&7,9,7<��6WDELOLW\��Stable under normal storage and handling conditions. ,QFRPSDWLELOLW\��None known. +D]DUGRXV�'HFRPSRVLWLRQ�3URGXFWV��Combustion of residue after the water has evaporated may produce oxides of carbon. +D]DUGRXV�3RO\PHUL]DWLRQ��Will not occur. ��72;,&2/2*,&$/�,1)250$7,21��+($/7+�+$=$5'6��,QJHVWLRQ��This product is not considered to be acutely toxic. Ingestion may cause mild irritation of the mucous membranes and intestinal tract. ,QKDODWLRQ��Not a normal route of exposure for this product. (\H: May cause�irritation.�6NLQ� May cause mild irritation on prolonged or repeated skin contact. &KURQLF��No adverse effects from chronic exposure are expected. &DUFLQRJHQLFLW\��None of the components is listed as a carcinogen or suspected carcinogen by ACGIH, IARC, NTP or OSHA.

Chrysal Clear Rose Pro Vase 10/09/08

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0HGLFDO�&RQGLWLRQV�$JJUDYDWHG�E\�([SRVXUH��Employees with pre-existing skin conditions may be more sensitive to the potential irritant effects. �3URGXFW�$FXWH�7R[LFLW\�9DOXHV: LD50 oral rat >2000 mg/kg, LD50 skin rabbit >2000 mg/kg (based on an assessment of the components) ��(&2/2*,&$/�,1)250$7,21� No ecotoxicity data is available. ��',6326$/�&216,'(5$7,216��Dispose in accordance with local, state and federal environmental regulations. ��75$163257�,1)250$7,21��'RW�+D]DUGRXV�0DWHULDOV�'HVFULSWLRQ��Proper Shipping Name: Not Regulated UN Number: None Hazard Class/Packing Group: None Labels Required: None ��5(*8/$725<�,1)250$7,21��&(5&/$��This product is not subject to CERCLA reporting requirements. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. �6$5$�+D]DUG�&DWHJRU\��Acute Health 6$5$��This product contains the following chemicals subject to Annual Release Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372): None (3$�76&$�,QYHQWRU\�� All of the ingredients in this product are listed on the EPA TSCA Inventory. �&DOLIRUQLD 3URSRVLWLRQ �� This products contain the following substances known to the State of California to cause cancer and/or reproductive harm: None��&$1$'$��This product has been classified under the CPR and this MSDS discloses information elements required by the CPR. &DQDGLDQ�&(3$: All the components of this product are listed on the Canadian DSL. &DQDGLDQ�:+0,6�&ODVVLILFDWLRQ��Class D-2-B (Toxic material causing other chronic effects – eye irritant) ��27+(5�,1)250$7,21��This above information is believed to be correct but does not propose to be all inclusive and shall be used only as a guide. Chrysal International BV makes no warranty, expressed or implied, with the respect to the use or reliance of this information. Chrysal International BV shall not be held liable for any damage resulting from handling or from contact with the above product.

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U.S. Department of LaborOccupational Safety and Health Administration(Non-Mandatory Form), Form ApprovedOMB No. 1218-0072

Section 1: Production Information

MSDS Name: Floralife® Clear Crowning Glory® SolutionIdentity: #3730 / 3740

Date Prepared: June 30, 2008 Company Identification: Crown Research and Chemical Corporation P.O. Box 12488 San Antonio, Texas 78212

Manufacturer’s Name: Floralife, Inc. 751 Thunderbolt Drive Walterboro, SC 29488 800-323-3689Emergency Number: 843-217-7609

Distributed by: Smithers-Oasis North America 919 Marvin Street Kent, OH 44240Phone Number: 330-673-5831 800-321-8286

For Chemical Emergency: Spill, Leak, Fire, Exposure, or Accident. Call CHEMTREC day or night. Domestic North America: 800-424-9300International Call: 703-527-3887 (collect calls accepted)

Section II: Hazard Ingredients/Identity Information

No hazardous ingredients known at this time. Section III: Physical / Chemical Characteristics

Boiling Point: 212˚ FSpecific Gravity (H2O = 1): >1 Vapor Pressure (17 mm Hg.): 68˚ FMelting Point: 32˚ F Vapor Density (AIR = 1): <1

Evaporation Rate (Butyl Acetate = 1): <1

Solubility in Water: 100% pH: 6 to 7Appearance and Odor: Clear liquid with slight acrylic odor

Section IV: Fire and Explosion Hazard Data

Flash Point (Method Used): Will not burnFlammable Limits: N/A LEL: N/A UEL: N/AExtinguishing Media: As appropriate for combustibles in the area. Special Fire Fighting Procedures: Wear self-contained breathing apparatus and full protective gear Unusual Fire and Explosion Hazards: Material can splatter above 100˚C / 212˚F. Polymer film can burn

Section V: Reactivity Data

Stability: Stable Conditions to Avoid: None known Incompatibility (Materials to Avoid): No known materials which are incompatible

Hazardous Decomposition or Byproducts: Thermal decomposition may yield acrylic monomers

HazardousPolymerization: N/A Will Not Occur Conditions to Avoid: N/A Section VI: Health Hazard Data

Route(s) of Entry: Inhalation: Slight Irritation Skin: Slight Irritation Ingestion: Slight Irritation

Health Hazards (Acute and Chronic): Any exposure to skin, ingestion or inhalation can result in an acute irritation. No chronic affects are known.

Inhalation of vapor or mist can cause headache-nausea-irritation to nose and throat.Carcinogen: NONTP: NOIARC Monographs: NO OSHA Regulated: NO Signs and Symptoms of Exposure: slight skin irritation.

Medical ConditionsGenerally Aggravated by Exposure: Watering of eyes, irritation of skin, headaches.

Emergency and First Aid Procedures: Wash thoroughly with fresh water for 15 min., if inhaled remove person to fresh air. If irritation persists, call physician.

Section VII: Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Released or Spilled: Evacuate area; Floor may be slippery: use care to avoid falling. Contain large spills immediately with inert materials (e.g. sand, earth).

Keep spills and cleaning runoff out of municipal sewers and open bodies of water.

Waste Disposal Method: Comply with Federal, State and Local regulations. If approved, drain neutralizedProduct to waste treatment plant, or transfer to waste disposal contractor. N/A

Precautions to be taken in Handling and Storing: none required when handling under normal conditions. When storing, keep from freezing and temperatures above 120˚ F.

Use in ventilated areas only.

Other Precautions: keep container closed when not in use. Keep from heat and direct sunlight. Keep from freezing. Section VIII: Control Measures

Respiratory Protection (Specify Type): none required under normal conditions. Respiratory mask should be used during spraying or misting operations. Ventilation: YES Local Exhaust: Mechanical (General): YES Special: Use in ventilated area Other: N/A

Protective Gloves: None required. Gloves may provide protection from permeation. Eye Protection: None required. Use chemical splash goggles Other Protective Clothing or Equipment: Aprons may be used Work / Hygienic Practices: Precautionary measures should always be taken when handling chemicals.

Section 1 – Chemical Product and Company IdentificationMSDS Name: Floralife Clear Professional® 2X ULTRA (Liquid)Product Numbers: 3500, 3501, 3502, 3503Company Identification:

Floralife, Inc.751 Thunderbolt DriveWalterboro, SC 29488Telephone Number: 843-538-3839Fax Number: 843-538-3949Emergency Number: 843-217-7609

Section 2 – Composition, Information on IngredientsIngredient NameHydroxytricarballylic acid

CAS Number Percent (%)77-92-9 5-10%

Section 3 – Hazards IdentificationEye Contact: May cause eye irritation.Skin Contact: May cause skin irritation.Inhalation Hazard: Inhalation of vapor or mist may cause irritation.Ingestion Hazard: May be harmful if swallowed.

Section 4 – First Aid MeasuresEye Contact: Rinse immediately with water for 15 minutes. Contact physician.Skin Contact: Remove contaminated clothing and wash with soap and water. Wash contaminated

clothing before reuse.Inhalation: Move to fresh air. If symptoms develop, call a physician.Ingestion: Drink 1 or 2 glasses of water. Seek medical advice.

Section 5 – Fire Fighting MeasuresFlammability Class: 0Flash Range: Not applicableExplosive Range: Not applicableFlammable Properties: Negligible fire hazard when exposed to heat or flame.Extinguishing Media: Use any appropriate means for extinguishing surrounding fire.Fire Fighting Instructions: No acute hazard, avoid breathing vapors or dust, keep upwind.

Section 6 – Accidental Release MeasuresClean up: Contain spill and absorb spill with clay or vermiculite and place in a suitable container for

disposal. Flush with soap and water.

Section 7 – Handling and StorageHandling: Handle and open containers with care.Storage: Store in a cool, dry place. Keep product in its original container and keep closed when not in use.

Section 8 – Exposure Controls, Personal ProtectionExposure Limits:None established. ACGIH:None established. NIOSH:None established. OSHA PELS:None established.Engineering Controls: Ordinary general and/or local ventilation is acceptable.Eyes: Use goggles when exposure hazards exist.Skin: Use protective gloves to avoid skin contact.Respirators: None under normal use.

Section 9 – Physical and Chemical PropertiesForm: LiquidAppearance/Color: Colorless to pale yellowOdor: SlightpH Value: No informationBoiling Range: No informationVapor Pressure: No informationMelting Point: No informationEvaporation Rate: No informationVapor Density: Non volatilePartition Coefficient:No information% Volatile by Weight: 0%Specific Gravity: (1.24-1.26)VOC: NoneMolecular Weight: MixtureHeavy Elements: None

Section 10 – Stability and ReactivityStability: This product is stable.Hazardous Polymerization:Hazardous polymerization will not occur.

Section 11 – Toxicological InformationNo toxicity data is available.

Section 12 – Ecological InformationNo data available.

Section 13 – Disposal ConsiderationsReview and observe all local, state and federal regulations for disposal.

Section 14 – Transportation InformationUS DOT Class Non-regulated

Section 15 – Regulatory InformationSARA Title III Section 313 Information: This product contains NONE of the substances subject to the reporting requirements of section 313 of Title III of the Superfund Amendments andReauthorization act.

Section 16 – Other InformationDISCLAIMER: The information in this MSDS has been gathered from standard reference materials.This information is offered for the users’ consideration, investigation and verification. Floralife, Inc. makes no warranty, expressed or implied, with respect to the use or reliance on thesame. This information should not be regarded as legal advice or regulation. It is the responsibility of the user to comply with all local, state and federal regulations and to consult the appropriate agency for information.

Date of Preparation: October 28, 2008



MSDS Name: Floralife® Crowning Glory® SolutionIdentity: #3731

Date Prepared: April 10, 2007 Company Identification: Crown Research and Chemical Corporation P.O. Box 12488 San Antonio, Texas 78212

Manufacturer Name: Floralife, Inc. 751 Thunderbolt Drive Walterboro, SC 29488 800-323-3689Emergency Number: 843-217-7609







Solubility in Water: 100%pH: 7.5 to 8.5 Appearance and Odor: Milky liquid with slight acrylic odor




Stability: Stable Conditions to Avoid: None known

Incompatibility (Materials to Avoid): No known materials which are incompatible


HazardousPolymerization: Will Not Occur Conditions to Avoid: N/A Section VI: Health Hazard Data









Waste Disposal Method: Comply with Federal, State and Local regulations. If approved, drain neutralizedProduct to waste treatment plant, or transfer to waste disposal contractor.






Section 1 – Chemical Product and Company IdentificationMSDS Name: Floralife Clear Professional® 2X ULTRA (Liquid)Product Numbers: 3500, 3501, 3502, 3503Company Identification:

Floralife, Inc.751 Thunderbolt DriveWalterboro, SC 29488Telephone Number: 843-538-3839Fax Number: 843-538-3949Emergency Number: 843-217-7609

Section 2 – Composition, Information on IngredientsIngredient NameHydroxytricarballylic acid

CAS Number Percent (%)77-92-9 5-10%

Section 3 – Hazards IdentificationEye Contact: May cause eye irritation.Skin Contact: May cause skin irritation.Inhalation Hazard: Inhalation of vapor or mist may cause irritation.Ingestion Hazard: May be harmful if swallowed.

Section 4 – First Aid MeasuresEye Contact: Rinse immediately with water for 15 minutes. Contact physician.Skin Contact: Remove contaminated clothing and wash with soap and water. Wash contaminated

clothing before reuse.Inhalation: Move to fresh air. If symptoms develop, call a physician.Ingestion: Drink 1 or 2 glasses of water. Seek medical advice.

Section 5 – Fire Fighting MeasuresFlammability Class: 0Flash Range: Not applicableExplosive Range: Not applicableFlammable Properties: Negligible fire hazard when exposed to heat or flame.Extinguishing Media: Use any appropriate means for extinguishing surrounding fire.Fire Fighting Instructions: No acute hazard, avoid breathing vapors or dust, keep upwind.

Section 6 – Accidental Release MeasuresClean up: Contain spill and absorb spill with clay or vermiculite and place in a suitable container for

disposal. Flush with soap and water.

Section 7 – Handling and StorageHandling: Handle and open containers with care.Storage: Store in a cool, dry place. Keep product in its original container and keep closed when not in use.

Section 8 – Exposure Controls, Personal ProtectionExposure Limits:None established. ACGIH:None established. NIOSH:None established. OSHA PELS:None established.Engineering Controls: Ordinary general and/or local ventilation is acceptable.Eyes: Use goggles when exposure hazards exist.Skin: Use protective gloves to avoid skin contact.Respirators: None under normal use.

Section 9 – Physical and Chemical PropertiesForm: LiquidAppearance/Color: Colorless to pale yellowOdor: SlightpH Value: No informationBoiling Range: No informationVapor Pressure: No informationMelting Point: No informationEvaporation Rate: No informationVapor Density: Non volatilePartition Coefficient:No information% Volatile by Weight: 0%Specific Gravity: (1.24-1.26)VOC: NoneMolecular Weight: MixtureHeavy Elements: None

Section 10 – Stability and ReactivityStability: This product is stable.Hazardous Polymerization:Hazardous polymerization will not occur.

Section 11 – Toxicological InformationNo toxicity data is available.

Section 12 – Ecological InformationNo data available.

Section 13 – Disposal ConsiderationsReview and observe all local, state and federal regulations for disposal.

Section 14 – Transportation InformationUS DOT Class Non-regulated

Section 15 – Regulatory InformationSARA Title III Section 313 Information: This product contains NONE of the substances subject to the reporting requirements of section 313 of Title III of the Superfund Amendments andReauthorization act.

Section 16 – Other InformationDISCLAIMER: The information in this MSDS has been gathered from standard reference materials.This information is offered for the users’ consideration, investigation and verification. Floralife, Inc. makes no warranty, expressed or implied, with respect to the use or reliance on thesame. This information should not be regarded as legal advice or regulation. It is the responsibility of the user to comply with all local, state and federal regulations and to consult the appropriate agency for information.

Date of Preparation: October 28, 2008



MSDS Name: Floralife® Crowning Glory® SolutionIdentity: #3731

Date Prepared: April 10, 2007 Company Identification: Crown Research and Chemical Corporation P.O. Box 12488 San Antonio, Texas 78212

Manufacturer Name: Floralife, Inc. 751 Thunderbolt Drive Walterboro, SC 29488 800-323-3689Emergency Number: 843-217-7609







Solubility in Water: 100%pH: 7.5 to 8.5 Appearance and Odor: Milky liquid with slight acrylic odor




Stability: Stable Conditions to Avoid: None known

Incompatibility (Materials to Avoid): No known materials which are incompatible


HazardousPolymerization: Will Not Occur Conditions to Avoid: N/A Section VI: Health Hazard Data









Waste Disposal Method: Comply with Federal, State and Local regulations. If approved, drain neutralizedProduct to waste treatment plant, or transfer to waste disposal contractor.






of 3 Floralife Crystal Clear® Fresh Flower Food (liquid)

Section 1 – Chemical Product and Company Identification MSDS Name: Floralife Crystal Clear® Fresh Flower Food (Liquid)

Product Numbers: 3170, 3176, 3282, 3288, 3290, 3295, 3297

Company Identification:

Floralife, Inc. 751 Thunderbolt Drive Walterboro, SC 29488 Telephone Number: 843-538-3839 Fax Number: 843-538-3949 Emergency Number: 843-217-7609

Section 2 – Composition, Information on Ingredients Ingredient Name Hydroxycarballylic acid

CAS Number 77-92-9

Percent (%) 1-5%

Section 3 – Hazards Identification Eye Contact: Skin Contact: Inhalation Hazard: Ingestion Hazard:

May cause eye irritation. May cause skin irritation. High doses may cause nasal or lung irritation. May cause stomach and/or throat irritation.

Section 4 – First Aid Measures Eye Contact: Skin Contact: Inhalation: Ingestion:

Wash with water for 15 minutes. Contact physician. Wash with water. Remove to fresh air. Seek medical advice.

Section 5 – Fire Fighting Measures Flammability Class: Flash Range: Explosive Range: Flammable Properties: Extinguishing Media: Fire Fighting Instructions:

0 N/A None Negligible fire hazard when exposed to heat or flame. Use any appropriate means for extinguishing surrounding fire. No acute hazard, avoid breathing vapors or dust, keep upwind.

Section 6 – Accidental Release Measures Clean up: Contain spill, wipe spill and place in a suitable container for

disposal. Flush with water


Section 7 – Handling and Storage Handling: Storage:

Handle and open containers with care. Store in a cool, dry place. Keep container closed when not in use.

Section 8 – Exposure Controls, Personal Protection Exposure Limits: Hydroxycarballylic Acid

ACGIH: None established.

NIOSH: None established.

OSHA PELS: None established.

Engineering Controls: Eyes: Skin: Respirators:

Ordinary general and/or local ventilation is acceptable. Use goggles when exposure hazards exist. Use protective gloves for prolonged or repeated contact. None under normal use.

Section 9 – Physical and Chemical Properties Form: Appearance/Color: Odor: pH Value: Boiling Range: Vapor Pressure: Melting Point: Evaporation Rate: Vapor Density: Partition Coefficient: % Volatile by Weight: Specific Gravity: VOC: Molecular Weight: Heavy Elements:

Liquid Colorless to pale yellow Slight No information No information No information No information No information Non volatile No information 0% 1.55939 None Mixture None

Section 10 – Stability and Reactivity Stability: Hazardous Polymerization:

This product is stable. Hazardous polymerization will not occur.

Section 11 – Toxicological Information No toxicity data is available. Section 12 – Ecological Information No data available.


Section 13 – Disposal Considerations Review and observe all local, state and federal regulations for disposal. Section 14 – Transportation Information US DOT Class Non-regulated Section 15 – Regulatory Information SARA Title III Section 313 Information: This product contains NONE of the substances subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization act. Section 16 – Other Information DISCLAIMER: The information in this MSDS has been gathered from standard reference materials. This information is offered for the users’ consideration, investigation and verification. Floralife, Inc. makes no warranty, expressed or implied, with respect to the use or reliance on the same. This information should not be regarded as legal advice or regulation. It is the responsibility of the user to comply with all local, state and federal regulations and to consult the appropriate agency for information. Date of Preparation: April 15, 2008

of 3 Floralife Crystal Clear® Fresh Flower Food (powder)

Section 1 – Chemical Product and Company Identification MSDS Name: Floralife Crystal Clear® Fresh Flower Food (Powder)

Product Numbers: 3035, 3036, 3037, 3038, 3030, 3031, 3032, 3055, 3065, 3083,

3050, 3042, 3099

Company Identification: Floralife, Inc. 751 Thunderbolt Drive Walterboro, SC 29488 Telephone Number: 843-538-3839 Fax Number: 843-538-3949 Emergency Number: 843-217-7609


CAS Number 77-92-9

Percent (%) 1-5%



















Powder White Slight No information No information No information No information No information Non volatile No information 0% 1.55939 None Mixture None




of 5 Floralife® D.C.D. Cleaner (liquid)

Section 1 – Chemical Product and Company Identification MSDS Name: Floralife® D.C.D. Cleaner (Liquid)

EPA Registration Number: 1839-95-32258

Product Numbers: 3308(S), 3310(S), 3312(S), 3330(S)

Company Identification: Floralife, Inc. 751 Thunderbolt Drive Walterboro, SC 29488 Telephone Number: 843-538-3839 Fax Number: 843-538-3949 Emergency Number: 843-217-7609 For Chemical Emergency: Spill, Leak, Fire, Exposure or Accident, Call CHEMTREC day or night: Domestic North America; 800-424-9300 International: 703-527-3887 (collect calls accepted)

Section 2 – Composition, Information on Ingredients Ingredient Name Sodium Carbonate Tetrasodium ethylenediamine tetra acetic acid Alkyl dimethyl ethylbenzyl ammonium chloride Alkyl dimethyl benzyl ammonium chloride

CAS Number 497-19-8 64-02-8 68956-79-6 68391-01-5

Percent (%) 1-5% 1-5% 1-5% 1-5%

Section 3 – Hazards Identification Emergency Overview: Eyes: Skin: Inhalation: Ingestion:

Clear liquid, Danger! Corrosive. May cause severe irritation or burns to the eyes and skin. This product may be severely irritating to the eyes and may cause skin burns. This product may be severely irritating to the skin and may cause burns. Exposure via inhalation not likely. High vapor or aerosol mist concentrations may be irritating to the nose, throat and upper respiratory tract. This product may be harmful if swallowed.

Section 4 – First Aid Measures Eye Contact: Skin Contact:

Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention or advice. For skin contact, flush with large amounts of water. If irritation persists, get medical attention. Immediately take off all contaminated clothing. Wash contaminated clothing before reuse.


Inhalation: Ingestion: Note to Physician:

If symptoms experienced, remove source of contamination or move victim to fresh air. If symptoms persist, get medical attention. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Seek medical attention. If the material is swallowed, get immediate medical attention or advice. Do not induce vomiting. If the product is ingested, probably mucosal damage may contraindicate the use of gastric lavage. Treat the affected person appropriately.

Section 5 – Fire Fighting Measures Flash Point: Extinguishing Media; Fire Fighting Equipment:

(> 93.9 Celcius) , > 201 F Dry chemical, foam, carbon dioxide, water fog. Fire fighters should wear full fire-fighting turn-out gear (full Bunker gear) including NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.

Section 6 – Accidental Release Measures Spill and Leak Procedures: Emergency Action: Small Spills: Large Spills:

Isolate spill or leak area immediately. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. Wear appropriate personal protective equipment during cleanup. Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Dike ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) Permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant regional office of the EPA.

Section 7 – Handling and Storage Handling Procedures:

Avoid contact with skin and eyes. Avoid breathing vapors or mists of this product. Wash thoroughly after handling. As with all chemicals, good industrial hygiene practices should be followed when handling this material.


Storage Procedures:

Keep the container tightly closed and in a cool, well-ventilated place. Avoid freezing or excessive heat. DO NOT CONTAMINATE WATER, FOOD, OR FEED BY STORAGE OR DISPOSAL.

Section 8 – Exposure Controls, Personal Protection Engineering Controls: Personal Protective Equipment: Eyes/Face: Skin: Respirators: General:

Use with adequate ventilation. Wear chemical goggles; face shield (if splashing is possible) Work clothing is sufficient to prevent all skin contact should be worn, such as coveralls and long sleeves. Use impervious gloves. Under normal conditions, respirator is not normally required. If irritation is experienced, a NIOSH-approved respirator should be worn. Eye wash fountain and emergency showers are recommended.

Section 9 – Physical and Chemical Properties Flash Point: Boiling Point: Specific Gravity: Vapor Density: Viscosity: Evaporation Rate: Solubility in Water: RVOC: pH Value: Freezing Point: Appearance and Odor:

(>93.9 C), > 201 (100 C), 212 F 1.041 g/ml 8.66 lb/gal Heavier than air <100 cps (@25 C) Slower than ethyl ether 0% 11.7 (13% solids in aqueous medium) (0 C), 32 F Clear liquid, citrus scent

Section 10 – Stability and Reactivity Stability: Conditions to Avoid: Incompatibility: Hazardous Polymerization:

This product is stable under normal conditions. Avoid strong oxidizing agents. This product may react with strong oxidizing agents. Under decomposition product may produce Nitrogen and Ammonia. Hazardous polymerization will not occur.


Section 11 – Toxicological Information Carcinogenicity: Not listed as carcinogenic according to IARC, NTP or OSHA. Other Toxicological Information: Available upon request. LD50 Value: Oral LD50 (rat) = > 500-5000 mg/kg Dermal LD50 (rabbit) = > 2000 < or equal to 20,000 mg/kg Sodium Carbonate (497-19-8): NIOSH-Selected LD50s and LC50s Inhalation LC50 Rat: 2300 mg/m3/2H; Inhalation LC50 Mouse: 1200 mg/m3/2H; Oral LD50 Rat: 4090 mg/kg; Oral LD50 Mouse: 6600 mg/kg Section 12 – Ecological Information Toxic to fish. Toxic to aquatic organisms. Section 13 – Disposal Considerations PESTICIDE DISPOSAL – Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide; spray mixture or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. CONTAINER DISPOSAL – Do not reuse empty container. Triple rinse empty container with water. Plastic containers may be disposed of in a sanitary landfill, incinerated or if allowed by local authorities, by burning. If burned, stay out of smoke. Offer for recycling if available. For containers 1 gallon or less: Do not reuse empty container. Wrap container and put in trash. Section 14 – Transportation Information US DOT Class Non-regulated Section 15 – Regulatory Information State regulations: This product may contain the following ingredients known to the State of California to cause cancer, birth defects or other reproductive harm: Nitrilotriacetic acid (NTA) CAS #139-13-9. Inventories: This product is considered a pesticide, and is therefore excluded from the United States TSCA Regulations. There is not calculable reportable quantity (RQ) for this product. Section 16 – Other Information DISCLAIMER: Nothing contained herein grants or extends a license, express or implied, in connection with patents, issued or pending, of the manufacturer or others. The information contained herein is based on the manufacturer’s owns study and the works of others. The manufacturer makes no warranties, expressed or implied, as to the accuracy, completeness, or adequacy of the information contained herein. The manufacturer shall not be held liable (regardless of fault) to the vendee’s employees, or anyone for any direct, special or


consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of such information. Date of Preparation: April 15, 2008

of 3 Floralife® Finishing Touch Spray (liquid)

Section 1 – Chemical Product and Company Identification MSDS Name: Floralife® Finishing Touch Spray (Liquid)

Product Numbers: 3700, 3720



Section 2 – Composition, Information on Ingredients No hazardous ingredients known at this time. Section 3 – Hazards Identification Eye Contact: Skin Contact: Inhalation Hazard: Ingestion Hazard:











Section 8 – Exposure Controls, Personal Protection Exposure Limits: None established.






Section 9 – Physical and Chemical Properties Form: Appearance/Color: Odor: pH Value: Boiling Range: Vapor Pressure: Melting Point: Evaporation Rate: Vapor Density: Partition Coefficient: % Volatile by Weight: % Volatile by Volume: VOC: Molecular weight: Heavy Elements:

Liquid Colorless to pale yellow Slight No information No information No information No information No information Non volatile No information 0% 0% None Mixture None




Section 13 – Disposal Considerations Review and observe all local, state and federal regulations for disposal. Section 14 – Transportation Information US DOT Class Non-regulated


Section 15 – Regulatory Information SARA Title III Section 313 Information: This product contains NONE of the substances subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization act. Section 16 – Other Information DISCLAIMER: The information in this MSDS has been gathered from standard reference materials. This information is offered for the users’ consideration, investigation and verification. Floralife, Inc. makes no warranty, expressed or implied, with respect to the use or reliance on the same. This information should not be regarded as legal advice or regulation. It is the responsibility of the user to comply with all local, state and federal regulations and to consult the appropriate agency for information.

of 3 Floralife® HotMelt GluStiks

Section 1 – Chemical Product and Company Identification MSDS Name: Floralife® HotMelt GluStiks

Product Numbers: 5130, 5155, 6110



Section 2 – Composition, Information on Ingredients No hazardous ingredients known at this time. Section 3 – Hazards Identification Eye Contact: Skin Contact: Inhalation Hazard: Ingestion Hazard: Carcinogenicity: Medical Conditions Aggravated By Long Term Exposure: Chronic Effects:

Vapors and fumes released at or above application temperature may cause irritation. Hot molten adhesive will burn and blister skin tissue. Vapors and fumes released at or above application temperature may cause irritation of the nose, throat and respiratory tract. Ingestion is not a likely route of exposure. Small amounts are not anticipated to be harmful. IARC, NTP and OSHA do not list this product as a carcinogen. No known effects on other illnesses. No anticipated chronic effects.

Section 4 – First Aid Measures Eye Contact: Skin Contact: Inhalation: Ingestion: Special Precautions/Procedures:

Hot molten adhesive will adhere to and burn eye and surrounding skin upon contact. Immediately flush affected area with cold water to cool adhesive. Do not pull solidified adhesive from eye. Seek medical attention. Hot molten adhesive will adhere to and burn skin upon contact. Immediately immerse affected area in ice water. Do not pull solidified adhesive from skin. Seek medical attention. If irritation occurs, remove to fresh air. Note to physician: This adhesive was determined by a toxicologist to be non-toxic. None.


Section 5 – Fire Fighting Measures Flash Point: Flash Point Method: Autoignition Temperature: Extinguishing Media: Unusual Fire Fighting or Explosion Hazards: Special Fire Fighting Instructions: Fire Fighting Equipment:

450 F (232 C) CC 800 F (427 C) Carbon Dioxide, Foam None None Because fire may produce thermal decomposition products, wear a self-contained breathing apparatus (SCBA) with a full face piece operated in pressure demand mode.











Section 9 – Physical and Chemical Properties Form: Appearance/Color: Odor: Vapor Pressure: Vapor Density: Specific Gravity: pH: Boiling Point: Melting Point: Viscocity: % Volatile: Evaporation Rate:

Solid Translucent/clear Slight n/a n/a 0.98 6.0 n/a 198 F (92 C) 28,000 centipoise @ 225 F Nil n/a


Section 10 – Stability and Reactivity Stability: Hazardous Polymerization: Incompatibilities: Hazardous Decomposition Products:

This product is stable. Hazardous polymerization will not occur. Strong oxidizing agents. Thermal oxidative decomposition of glue stick can produce carbon monoxide and /or carbon dioxide.


Section 13 – Disposal Considerations Review and observe all local, state and federal regulations for disposal. Section 14 – Transportation Information US DOT Class Non-regulated Section 15 – Regulatory Information SARA Title III Section 313 Information: This product contains NONE of the substances subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization act. Section 16 – Other Information DISCLAIMER: The information in this MSDS has been gathered from standard reference materials. This information is offered for the users’ consideration, investigation and verification. Floralife, Inc. makes no warranty, expressed or implied, with respect to the use or reliance on the same. This information should not be regarded as legal advice or regulation. It is the responsibility of the user to comply with all local, state and federal regulations and to consult the appropriate agency for information.

of 3 Floralife® Leafshine

Section 1 – Chemical Product and Company Identification

MSDS Name: Floralife® Leafshine (250 ml/750 ml aerosol)



Section 2 – Composition, Information on Ingredients

Ingredient Name Propane / Butane Isoparaffin Isopropanol

CAS Number 74-98-6 / 106-97-9 64741-65-7 67-63-0

Percent (%) 40-60% 15-25% 5-10%

Section 3 – Hazards Identification

Eye Contact: Skin Contact: Inhalation Hazard: Ingestion Hazard:


Section 4 – First Aid Measures

Eye Contact: Skin Contact: Inhalation: Ingestion:

Wash with water for 15 minutes. Contact physician. Wash with water. If irritation develops contact physician. Remove to fresh air. In case of irregular breathing, apply artificial respiration. If unconscious place in recovery position and seek medical advice. Rinse mouth. Seek medical advice. DO NOT INDUCE VOMITING.

Section 5 – Fire Fighting Measures

Flash Range: Explosive Range: Flammable Properties: Extinguishing Media: Fire Fighting Instructions:

< 32 F Do not expose to temperatures exceeding 122 F (50 C). Avoid excessive heat and sources of ignition. Alcohol resistant foam, CO2, dry powder, water spray. Do not use water jet as this will scatter the containers and spread the fire. Use self-contained breathing apparatus.

Section 6 – Accidental Release Measures

Clean up On soil: On water:

Physically collect containers. In case of liquid spills, absorb onto soil or sand and dispose of as Hazardous Waste. Physically collect containers.


Section 7 – Handling and Storage

Handling: Storage:

Keep away from children. Avoid sources of ignition. Do not smoke while using this product. Avoid contact with skin and eyes. Handle and open containers carefully. Use only in well ventilated area. Vapors are heavier than air so may spread along floors to a remote source of ignition. Store in a cool, dry place out of direct sunlight. Keep container closed when not in use.

Section 8 – Exposure Controls, Personal Protection

Exposure Limits: Butane Propane Isoparaffin Isopropanol

ACGIH: 1000 ppm 1000 ppm 100 ppm 200 ppm (8 hr. TWA) 400 ppm (STEL)

NIOSH: 800 ppm, 1900 mg/m3 TWA

OSHA PELS: 800 ppm 1000 ppm 100 ppm 400 ppm


Ensure good ventilation. None required under normal circumstances, but use goggles when splash hazards exist. None required under normal use. Wear rubber or PVC gloves for prolonged or repeated contact. None under normal use conditions. If workers are exposed to concentrations above the exposure limit they must use appropriate, certified respirators.

Section 9 – Physical and Chemical Properties

Form: Appearance/Color: Odor: Flash Point: Density:

Liquified Gas Aerosol Alcohol < 32 degrees F (< 0 degrees C) 0.65 g/ml

Section 10 – Stability and Reactivity

Stability: Conditions to Avoid: Materials to Avoid: Hazardous Polymerization:

This product is stable under normal recommended storage conditions. Avoid excessive heat and sources of ignition. Oxidizing agents. Hazardous polymerization will not occur.

Section 11 – Toxicological Information

No toxicity data is available but based on ingredients, is not considered hazardous to human health under normal circumstances of use. However, inhalation of vapors in high concentrations may lead to irritation of eyes, nose and respiratory tract.

Section 12 – Ecological Information

No data available but based on product ingredients, not considered hazardous to


the environment. Slightly endangering to water (sea).

Section 13 – Disposal Considerations

Review and observe all local, state and federal regulations for disposal. Dispose of product as hazardous waste. Do not incinerate or puncture packaging container.

Section 14 – Transportation Information

UN No. 1950, Classification Code: 5F Proper Shipping Name: Aerosols, flammable Hazard Label: Flammable gas (2.1) IMO-IMDG Class: 2 ICAO/IATA Classification: 2 Packing Group: Not applicable

Section 15 – Regulatory Information

SARA Title III Section 313 Information: This product contains none of the substances subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization act.

Section 16 – Other Information

DISCLAIMER: The information in this MSDS has been gathered from standard reference materials. This information is offered for the users’ consideration, investigation and verification. Floralife, Inc. makes no warranty, expressed or implied, with respect to the use or reliance on the same. This information should not be regarded as legal advice or regulation. It is the responsibility of the user to comply with all local, state and federal regulations and to consult the appropriate agency for information. Date of Preparation: January 1, 2008

of 3 Floralife® LoTemp GluStiks

Section 1 – Chemical Product and Company Identification MSDS Name: Floralife® LoTemp GluStiks

Product Numbers: 5910, 5920, 5955








Section 5 – Fire Fighting Measures Flash Point: Flash Point Method: Autoignition Temperature: Extinguishing Media: Unusual Fire Fighting or Explosion Hazards: Special Fire Fighting Instructions: Fire Fighting Equipment:

450 F (232 C) CC 800 F (427 C) Carbon Dioxide, Foam None None Because fire may produce thermal decomposition products, wear a self-contained breathing apparatus (SCBA) with a full face piece operated in pressure demand mode.











Section 9 – Physical and Chemical Properties Form: Appearance/Color: Odor: Vapor Pressure: Vapor Density: Specific Gravity: pH: Boiling Point: Melting Point: Viscocity: % Volatile: Evaporation Rate:

Solid Translucent/clear Slight n/a n/a 0.98 6.0 n/a 198 F (92 C) 28,000 centipoise @ 225 F Nil n/a


Section 10 – Stability and Reactivity Stability: Hazardous Polymerization: Incompatibilities: Hazardous Decomposition Products:

This product is stable. Hazardous polymerization will not occur. Strong oxidizing agents. Thermal oxidative decomposition of glue stick can produce carbon monoxide and /or carbon dioxide.



of 3 Floralife® Original Fresh Flower Food (liquid)

Section 1 – Chemical Product and Company Identification MSDS Name: Floralife® Original Fresh Flower Food (Liquid)

Product Numbers: 3186



Section 2 – Composition, Information on Ingredients Ingredient Name Hydroxytricarballylic acid

CAS Number 77-92-9

Percent (%) 1-5%


















Section 9 – Physical and Chemical Properties Form: Appearance/Color: Odor: pH Value: Boiling Range: Vapor Pressure: Melting Point: Evaporation Rate: Vapor Density: Partition Coefficient: % Volatile by Weight: Specific Gravity: VOC: Molecular weight: Heavy Elements:





of 3 Floralife® Original Fresh Flower Food (powder)

Section 1 – Chemical Product and Company Identification MSDS Name: Floralife® Original Fresh Flower Food (Powder)

Product Numbers: 3002, 3005, 3008, 3040, 3046, 3053, 3061, 3079, 3087, 3095,

3111


Section 2 – Composition, Information on Ingredients Ingredient Name Aluminum Sulfate

CAS Number 10043-01-3

Percent (%) 1-5%












Section 8 – Exposure Controls, Personal Protection Exposure Limits: Aluminum Sulfate






Section 9 – Physical and Chemical Properties Form: Appearance/Color: Odor: pH Value: Boiling Range: Vapor Pressure: Melting Point: Evaporation Rate: Vapor Density: Partition Coefficient: % Volatile by Weight: % Volatile by Volume: VOC: Molecular weight: Heavy Elements:

Powder White Slight No information No information No information No information No information Non volatile No information 0% 0% None Mixture None




of 3 Floralife® Pot Melt Glu Brickettes

Section 1 – Chemical Product and Company Identification MSDS Name: Floralife® Pot Melt Glu Brickettes

Product Numbers: 5930









0 n/a None Negligible fire hazard when exposed to heat or flame. Use any appropriate means for extinguishing surrounding fire. No acute hazard, avoid breathing vapors or dust, keep upwind.


disposal. Flush with water.









Section 9 – Physical and Chemical Properties Form: Appearance/Color: Odor: pH Value: Boiling Range: Vapor Pressure (mmHg): Melting Point: Evaporation Rate: Vapor Density: Partition Coefficient: % Volatile by Weight: % Volatile by Volume: VOC: Molecular Weight: Heavy Elements:

Solid White/Light Yellow Slight No information No information No information 190 F No information No information No information 0% 0% None No information No information

of 3 Floralife Quick Dip® Hydration Solution (liquid)

Section 1 – Chemical Product and Company Identification MSDS Name: Floralife Quick Dip® Hydration Solution (Liquid)

Product Numbers: 3780, 3782, 3783, 3785




CAS Number 77-92-9

Percent (%) 1-5%























Section 13 – Disposal Considerations Review and observe all local, state and federal regulations for disposal. Section 14 – Transportation Information US DOT Class Non-regulated


US DOT Class Non-regulated Section 15 – Regulatory Information SARA Title III Section 313 Information: This product contains NONE of the substances subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization act. Section 16 – Other Information DISCLAIMER: The information in this MSDS has been gathered from standard reference materials. This information is offered for the users’ consideration, investigation and verification. Floralife, Inc. makes no warranty, expressed or implied, with respect to the use or reliance on the same. This information should not be regarded as legal advice or regulation. It is the responsibility of the user to comply with all local, state and federal regulations and to consult the appropriate agency for information. Date of Preparation: April 15, 2008

of 3 Floralife® Sure Stik Adhesive

Section 1 – Chemical Product and Company Identification MSDS Name: Floralife® Sure Stik Adhesive




Section 2 – Composition, Information on Ingredients This msds is prepared to comply with OSHA Hazard Communication Standard 29 CFR 1910.1200. Unlisted ingredients are not ‘hazardous’ per this OSHA standard and are considered to be trade secrets. Sure Stik is a pressure sensitive tape, which is a mixture of rubber, oil, pigment and inert fillers. Section 3 – Hazards Identification Non-hazardous material. Normal chemical hygiene should be adequate to handle this material. Wash thoroughly after handling, avoid contact with eyes and skin. Do not ingest. Section 4 – First Aid Measures Eye Contact: Skin Contact: Ingestion:

Flush with water for 15 minutes, seek medical attention. Wash with soap and water. Contact physician. Do not induce vomiting.

Section 5 – Fire Fighting Measures Fire Fighting Instructions: Extinguish with CO2, foam or dry chemical.

Section 6 – Accidental Release Measures Spill or Leak Procedure: Sweep or scrape up and place in appropriate container for

disposal.


Handle with care. Store in a cool, dry place.

Section 8 – Exposure Controls, Personal Protection Engineering Controls: Eyes: Skin: Respirators:

Ordinary general and/or local ventilation is acceptable. Not normally required; although, the use of safety glasses is a good industrial practice. Not normally required. Wear gloves if prolonged contact is expected. Not normally required.


Section 9 – Physical and Chemical Properties Physical State: Specific Gravity: Viscosity: Flashpoint/Method: Appropriate extinguishers: Special fire fighting procedures: Unusual fire and explosion hazard:

Solid 1.70 @ 77 F N/A 425 F / COC CO2, foam, water or dry chemical Wear self-contained breathing apparatus when fighting fire. None known.

Section 10 – Stability and Reactivity Stability: Incompatibility: Hazardous Decomposition Products: Hazardous Polymerization:

This product is stable. Strong oxidizers. Carbon oxides and unidentified organic compounds when burning. Will not occur.

Section 11 – Toxicological Information Effect of over exposure: Eyes: Skin: Inhalation: Ingestion: Chronic: Existing Health Conditions Affected by Exposure: Carcinogentity:

Mechanical irritation. May cause mild irritation. Not applicable. May cause mild gastrointestinal irritation. No known effects. No known conditions are aggravated by exposure to this product. NTP? No IARC? No OSHA? No

Section 12 – Ecological Information No data available.

Section 13 – Disposal Considerations Review and observe all local, state and federal regulations for disposal. Section 14 – Transportation Information US DOT Non regulated: DOT Shipping Name: Caulking compound NOIBN Section 15 – Regulatory Information SARA Title III Section 313 Information: This product contains NONE of the substances subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization act.


Section 16 – Other Information DISCLAIMER: The information in this MSDS has been gathered from standard reference materials. This information is offered for the users’ consideration, investigation and verification. Floralife, Inc. makes no warranty, expressed or implied, with respect to the use or reliance on the same. This information should not be regarded as legal advice or regulation. It is the responsibility of the user to comply with all local, state and federal regulations and to consult the appropriate agency for information. Date of Preparation: April 15, 2008


Section 1 – Chemical Product and Company Identification MSDS Name: Floralife® Sure Stik Adhesive




Section 2 – Composition, Information on Ingredients This msds is prepared to comply with OSHA Hazard Communication Standard 29 CFR 1910.1200. Unlisted ingredients are not ‘hazardous’ per this OSHA standard and are considered to be trade secrets. Sure Stik is a pressure sensitive tape, which is a mixture of rubber, oil, pigment and inert fillers. Section 3 – Hazards Identification Non-hazardous material. Normal chemical hygiene should be adequate to handle this material. Wash thoroughly after handling, avoid contact with eyes and skin. Do not ingest. Section 4 – First Aid Measures Eye Contact: Skin Contact: Ingestion:

Flush with water for 15 minutes, seek medical attention. Wash with soap and water. Contact physician. Do not induce vomiting.

Section 5 – Fire Fighting Measures Fire Fighting Instructions: Extinguish with CO2, foam or dry chemical.

Section 6 – Accidental Release Measures Spill or Leak Procedure: Sweep or scrape up and place in appropriate container for

disposal.


Handle with care. Store in a cool, dry place.

Section 8 – Exposure Controls, Personal Protection Engineering Controls: Eyes: Skin: Respirators:

Ordinary general and/or local ventilation is acceptable. Not normally required; although, the use of safety glasses is a good industrial practice. Not normally required. Wear gloves if prolonged contact is expected. Not normally required.


Section 9 – Physical and Chemical Properties Physical State: Specific Gravity: Viscosity: Flashpoint/Method: Appropriate extinguishers: Special fire fighting procedures: Unusual fire and explosion hazard:

Solid 1.70 @ 77 F N/A 425 F / COC CO2, foam, water or dry chemical Wear self-contained breathing apparatus when fighting fire. None known.

Section 10 – Stability and Reactivity Stability: Incompatibility: Hazardous Decomposition Products: Hazardous Polymerization:

This product is stable. Strong oxidizers. Carbon oxides and unidentified organic compounds when burning. Will not occur.

Section 11 – Toxicological Information Effect of over exposure: Eyes: Skin: Inhalation: Ingestion: Chronic: Existing Health Conditions Affected by Exposure: Carcinogentity:

Mechanical irritation. May cause mild irritation. Not applicable. May cause mild gastrointestinal irritation. No known effects. No known conditions are aggravated by exposure to this product. NTP? No IARC? No OSHA? No

Section 12 – Ecological Information No data available.

Section 13 – Disposal Considerations Review and observe all local, state and federal regulations for disposal. Section 14 – Transportation Information US DOT Non regulated: DOT Shipping Name: Caulking compound NOIBN Section 15 – Regulatory Information SARA Title III Section 313 Information: This product contains NONE of the substances subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization act.


Section 16 – Other Information DISCLAIMER: The information in this MSDS has been gathered from standard reference materials. This information is offered for the users’ consideration, investigation and verification. Floralife, Inc. makes no warranty, expressed or implied, with respect to the use or reliance on the same. This information should not be regarded as legal advice or regulation. It is the responsibility of the user to comply with all local, state and federal regulations and to consult the appropriate agency for information. Date of Preparation: April 15, 2008

MATERIAL SAFETY DATA SHEET PAGE 1

HI-FLOAT Co., Inc. Emergency Medical Info:

13025 Middletown Industrial Blvd (502)244-0984/(502)244-6088

Louisville, KY 40223 Rocky Mountain Poison Control:

(502)244-0984 (303) 629-1123

Date: 3/1/05

-------------------------------------------------------------------------------------------------------------------------------------

IDENTIFICATION

-------------------------------------------------------------------------------------------------------------------------------------

Name: HI-FLOAT Balloon Treatment

SUPER HI-FLOAT Balloon Treatment

ULTRA HI-FLOAT Balloon Treatment

Major Components: water, polyvinyl, alcohol,dextrose monohydrate

CAS No.: 25213-24-5 (polyvinyl alcohol)

50-99-7 (dextrose monohydrate)

-------------------------------------------------------------------------------------------------------------------------------------

HAZARDOUS COMPONENTS

-------------------------------------------------------------------------------------------------------------------------------------

Materials: None Approximate %: N/A

-------------------------------------------------------------------------------------------------------------------------------------

PHYSICAL DATA:

-------------------------------------------------------------------------------------------------------------------------------------

Boiling Point, 760 mm Hg.: 212F (100C) Form: Viscous Liquid

Specific Gravity: 1.06 Odor: No chemical odor

Vapor Density: Same as water Melting Point: N/A

% Volatiles: 70-80 Vapor Pressure: Same as water

pH Information: 5-6 Solubility in Water: Infinite

Color: clear

-------------------------------------------------------------------------------------------------------------------------------------

FIRE AND EXPLOSION DATA

-------------------------------------------------------------------------------------------------------------------------------------

Flash Point: N/A Method: N/A Autoignition Temp.: N/A

Flammability Limits in Air - Upper: N/A Lower: N/A

Fire and Explosion Hazards: None

Extinguishing Media: Any

Special Fire Fighting Instructions: None

-------------------------------------------------------------------------------------------------------------------------------------

HAZARDOUS REACTIVITY

-------------------------------------------------------------------------------------------------------------------------------------

Instability: Stable

Incompatibility: Strong oxidizing agents

Decomposition: None

Polymerization: Will not occur

MATERIAL SAFETY DATA SHEET PAGE 2

HEALTH HAZARD INFORMATION

-------------------------------------------------------------------------------------------------------------------------------------

Exposure Limits: None established

Routes of Exposure and Effects: Inhalation: None

Skin: None

Eye: Non-irritating/minimally irritating

Ingestion: None

Effects of Overexposure: Acute: None

Chronic: None

First Aid: Handle material in accordance with good industrial hygiene. These practices include avoiding

unnecessary exposure and removal of the material from eyes, skin, and clothing. Flush affected areas with

water to remove.

-------------------------------------------------------------------------------------------------------------------------------------

PROTECTION INFORMATION

-------------------------------------------------------------------------------------------------------------------------------------

Ventilation: No special precautions required.

Skin: Does not present significant skin concern requiring special protection.

Eye: Avoid unnecessary eye contact. Glasses recommended.

Respirator: None

-------------------------------------------------------------------------------------------------------------------------------------

DISPOSAL PROCEDURES

-------------------------------------------------------------------------------------------------------------------------------------

Waste Disposal: Material is not a hazardous waste as defined in 40 CFR 261, "Identification and Listing of

Hazardous Waste". May be disposed of in sanitary landfill licensed to receive non-hazardous waste.

Disposal should be in accordance with local, state, and federal regulations.

-------------------------------------------------------------------------------------------------------------------------------------

SHIPPING PRECAUTIONS

-------------------------------------------------------------------------------------------------------------------------------------

Shipping Containers: Plastic bottles

DOT Name/Classification: Non-classified

-------------------------------------------------------------------------------------------------------------------------------------

All information presented herein is given in good faith and is based on sources and tests considered to be

reliable but users should not rely upon it absolutely for specific applications. It is the user's full responsibility

to accept risk for the safety, toxicity, handling, storage, and use of the product as well as to determine the suitability of the product for a specific purpose. This product is effective if used as instructed. With the exception of

this warranty, there are no other warranties, express or implied, including warranties of merchantability or fitness for a

particular purpose. HI-FLOAT Co., Inc. cannot be responsible for use of the product after purchase. Purchaser's

remedies shall be limited to refund of purchase price and, in no event shall HI-FLOAT be liable for any amount in

excess of the original purchase price of the product or for any incidental or consequential damages.

PIXIE SPARKLE T/5 CONCENTRATE INSTANT LEAF SHINE & CLEANER MSDS Page 1 of 9

MATERIAL SAFETY DATA SHEET Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS, Australian WorkSafe, and European Community Standards

PART I What is the material and what do I need to know in an emergency?

1. PRODUCT IDENTIFICATION TRADE NAME (AS LABELED): PIXIE SPARKLE T/5 CONCENTRATE INSTANT

LEAF SHINE & CLEANER CHEMICAL NAME/CLASS: Mineral Oil Emulsion U.N. NUMBER: Not Applicable U.N. DANGEROUS GOODS CLASS/SUBSIDIARY RISK: Not Applicable HAZCHEM CODE (AUSTRALIA): Not Applicable POISONS SCHEDULE NUMBER (AUSTRALIA): Not Applicable MATERIAL USE: Plant Cleaner SUPPLIER/MANUFACTURER'S NAME: TEITELBAUM BROTHERS, Inc. ADDRESS: 1940 Lehigh Avenue Glenview, IL 60025 U.S. EMERGENCY PHONE: 01 (847) 729-3490 (9 a.m.-5 p.m. Eastern U.S. Time) U.S. BUSINESS PHONE: 1/800-624-6883 DATE OF PREPARATION: March 25, 2002 DATE OF REVISION: March 10, 2005

2. COMPOSITION and INFORMATION ON INGREDIENTS EU LABELING AND CLASSIFICATION: This product does not meet the definition of any hazard class as defined by the European Community Council Directive 67/548/EEC or subsequent Directives.

EU HAZARD CALSSIFICATION: Not Applicable EU RISK PHRASES: Not Applicable EU SAFETY PHRASES: Not Applicable

CHEMICAL NAME CAS # EINECS # % w/v EU CLASSIFICATION FOR COMPONENTS

White Mineral Oil, USP Exposure limits are for Oil Mist, Mineral

8042-47-5 Unlisted > 80% HAZARD CLASSIFICATION: Not applicable. RISK PHRASES: Not applicable.

Water and other components each present in less than 1 percent concentration (0.1% concentration for potential carcinogens, reproductive toxins, respiratory tract sensitizers, and mutagens).

9063-38-1 Unlisted Balance HAZARD CLASSIFICATION: Not applicable. RISK PHRASES: Not applicable.

See Section 15 for full EU classification information of product and components. NOTE: ALL Canadian WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been

classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. All Australian WorkSafe and European Community required information is included. It is located in appropriate sections based on the ANSI Z400.1-1998 format.

3. HAZARD IDENTIFICATION

EMERGENCY OVERVIEW: This product is a milky-white, oily, practically odorless liquid. Health Hazards: The product is not expected to irritate contaminated skin, unless contact is prolonged. When used by immersing plants to be cleaned (as a dip), due to its high viscosity, this product should not produce mists or sprays. If used as a spray, inhalable mists or sprays may be created and cause irritation of the respiratory system if breathed. Repeated inhalations of mists or sprays cause adverse lung conditions. Ingestion of large quantity of the product may be harmful. Flammability Hazards: This product must be heated to an extremely high temperature, causing evaporation of water, before ignition could occur. Reactivity Hazards: This product is not reactive. Environmental Hazards: If large amounts of this product are released into the environment adverse effects may occur. Emergency Recommendations: Emergency responders must wear the personal protective equipment suitable for the situation to which they are responding.

SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of occupational overexposure are contact with skin and eyes. The symptoms of overexposure to this product, via route of entry, are as follows: INHALATION: Due to its high viscosity, when used as a dip, this product should not produce mists or sprays. If used as a spray, inhalation may cause coughing and irritate the nose, throat, and other tissues of the respiratory system. Repeated inhalation exposure may result in adverse lung conditions.

3. HAZARD IDENTIFICATION CONTACT WITH SKIN or EYES: Minor skin contact is not expected to cause adverse symptoms. Repeated or prolonged skin overexposure may cause irritation or dermatitis (dry, red skin). Eye contact with this product can mildly to moderately irritate the eye and cause pain, tearing, and redness. No permanent damage to the eye is expected to occur; discomfort should be relieved upon rinsing of the contaminated eye(s).


SKIN ABSORPTION: No component of this product is known to be absorbed via intact skin. INGESTION: Though not anticipated to be a significant route of occupational exposure, ingestion of large quantities of this product may cause headache, nausea, vomiting, and diarrhea. A hazard of aspiration into the lungs may occur after ingestion. Aspiration of liquids into the lungs will cause immediate pain and coughing and can result in the development of pneumonia and pulmonary edema. INJECTION: Accidental injection of this liquid (as may occur by a puncture with a contaminated object) may cause local pain, irritation, and redness. HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. In the event of overexposure, the following symptoms may be observed: ACUTE: Acute exposure to low concentration levels of this product via skin contact, eye contact and inhalation should not cause significant adverse health effects. Due to its high viscosity, under normal circumstances of use, this product should not produce mists or sprays. However, if use results in mists or sprays of product, inhalation may cause coughing and irritation of the respiratory system. Ingestion of large amounts may cause headache, nausea, and diarrhea.

HEALTH HAZARD

FLAMMABILITY HAZARD

PHYSICAL HAZARD

PROTECTIVE EQUIPMENT

1

EYES RESPIRATORY HANDS BODY

(BLUE)

(RED)

For Routine Industrial Use and Handling Applications

SEE SECTION 8

HAZARDOUS MATERIAL IDENTIFICATION SYSTEM

(YELLOW)

0

0

SEE SECTION 8

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard Aspiration into the lungs after ingestion can result in life-threatening

pulmonary edema or chemical pneumonia. CHRONIC: Chronic skin exposure to this product may cause irritation or dermatitis in susceptible individuals. There is recent evidence of carcinogenic potential, by repeated inhalation for the White Mineral Oil, USP component. While this is not an expected route of exposure to this product due to its high viscosity, this information is being provided to ensure all possible health information is provided. Refer to Section 11 (Toxicology Information) for additional data. TARGET ORGANS: ACUTE: Skin, respiratory system, eyes. CHRONIC: Skin, respiratory system.

PART II What should I do if a hazardous situation occurs?

4. FIRST-AID MEASURES Contaminated individuals must be taken for medical attention if any adverse effect occurs. Rescuers should be taken for medical attention if necessary. Take a copy of the label and MSDS to health professional with victim. SKIN EXPOSURE: If this product contaminates the skin, wash skin with running water and soap. Remove exposed or contaminated clothing, taking care not to contaminate eyes. The contaminated individual must seek medical attention if any adverse effect occurs. EYE EXPOSURE: If vapors, sprays, or mists of this product enter the eyes, open the contaminated individual’s eyes while under gently running water. Use sufficient force to open eyelids. Have the contaminated individual "roll" eyes. Minimum flushing is for 15 minutes. The contaminated individual must seek medical attention if any adverse effect occurs. INHALATION: If mists or sprays of this product are inhaled, remove the contaminated individual to fresh air. If necessary, remove or cover gross contamination to avoid exposure to rescuers. Seek medical attention if adverse effect occurs. INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. DO NOT INDUCE VOMITING, unless directed by medical personnel. Have victim rinse mouth with water if conscious. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or unable to swallow. If vomiting occurs, lean patient forward or place on left side (head-down position if possible) to maintain an open airway and prevent aspiration. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Preexisting skin and respiratory disorders may be aggravated by prolonged overexposures to this product. RECOMMENDATIONS TO PHYSICIANS: Treatment symptoms and eliminate exposure.

5. FIRE-FIGHTING MEASURES FLASH POINT: Not normally flammable.

1 HEALTH

FLAMMABILITY

REACTIVITY

OTHER

NFPA RATING

0

0

AUTOIGNITION TEMPERATURE: Not applicable. FLAMMABLE LIMITS (in air by volume, %): Lower (LEL): Not applicable. Upper (UEL): Not applicable. FIRE EXTINGUISHING MATERIALS:

Water Spray: YES (for cooling) Carbon Dioxide: YES

Foam: YES Dry Chemical: YES

Halon: YES Other: Any "ABC" Class. UNUSUAL FIRE AND EXPLOSION HAZARDS: When involved in a fire, this material may decompose and produce irritating vapors and toxic gases (e.g., carbon oxides and nitrogen oxides). Explosion Sensitivity to Mechanical Impact: Not sensitive.


Explosion Sensitivity to Static Discharge: Not sensitive. SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment. Due to the presence of colorants, the runoff water from these products can discolor contaminated objects. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas. If necessary, rinse fire-response equipment with soapy water before returning to service and dispose of rinsate appropriately.

See Section 16 for Definition of Ratings

6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE: Spill of this product may be slippery; caution should be use when cleaning up spills. For incidental spills (e.g., less than 1 L of liquid from a bottle), wear rubber gloves, splash goggles, and appropriate body protection. Trained personnel following pre-planned procedures should handle non-incidental releases (e.g., 10 L of liquid leaking from a crate of several containers). In the event of a non-incidental spill, clear the area and protect people. The minimum personal protective equipment for response to a non-incidental spill is as follows: rubber gloves, rubber boots, face shield, and Tyvek suit. The minimum level of personal protective equipment for releases in which the level of oxygen is less than 19.5% or is unknown must be Level B: triple-gloves (rubber gloves and nitrile gloves over latex gloves), chemical resistant suit and boots, hard hat, and Self-Contained Breathing Apparatus. Absorb spilled liquid with polypads or other suitable absorbent materials. Rinse area thoroughly with soapy water after liquid has dried. Decontaminate the area thoroughly. If necessary, discard all stained response equipment or rinse with soapy water before returning such equipment to service. Place all spill residues in an appropriate container and seal. Dispose of in accordance with applicable U.S. Federal, State, or local procedures, or appropriate standards of Canada, Australia, or EU Member States (see Section 13, Disposal Considerations).

PART III How can I prevent hazardous situations from occurring?

7. HANDLING and STORAGE WORK AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly after handling this product. Do not eat, drink, smoke, or apply cosmetics while handling this product. Avoid breathing sprays or mists generated by this product. Use in a well-ventilated location. Remove contaminated clothing immediately. Spills of product may be slippery and present a slip hazard. STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely. Keep container tightly closed when not in use. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Material should be stored in secondary containers or in a diked area as appropriate. Store containers away from incompatible chemicals (see Section 10, Stability and Reactivity). Post warning and “NO SMOKING” signs in storage and use areas, as appropriate. Inspect all incoming containers before storage to ensure containers are properly labeled and not damaged. Empty containers may contain residual liquid or vapors; therefore, empty containers should be handled with care. PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely, if necessary. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures and appropriate Canadian standards, those of EU Member States and Australia.


8. EXPOSURE CONTROLS - PERSONAL PROTECTION VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided in Section 2 (Composition and Information on Ingredients). Use local exhaust ventilation. Normal office ventilation conforming to the American Society of Heating, Refrigerating, and Air Conditioning Engineers (ASHRAE) Standards is adequate under normal circumstances of use. Persons using this product should consult a qualified Ventilation Engineer and/or Industrial Hygienist if concerns about exposures arise. If necessary, refer to Australian National Code of Practice for the Control of Workplace Hazardous Substances [NOHSC: 2007 (1994)] for further information. As with all products that contain chemicals, ensure proper decontamination equipment (e.g., eyewash/safety shower stations) are available near areas where this product is used as necessary. EXPOSURE LIMITS/GUIDELINES:

EXPOSURE LIMITS IN AIR

ACGIH-TLVs OSHA-PELs NIOSH-RELs NIOSH AIHA WEELs OTHER TWA STEL TWA STEL TWA STEL IDLH TWA STEL

CHEMICAL NAME CAS #

mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3

White Mineral Oil, USP Exposure limits are for Oil Mist, Mineral

8042-47-5 5 NIC = 0.2 (inhalable fraction)

10 NIC = 0.2 (inhalable fraction)

5 NE 5 10 2500 NE NE NE

Water and other components each present in less than 1 percent concentration (0.1% concentration for potential carcinogens, reproductive toxins, respiratory tract sensitizers, and mutagens).

None of the other components contribute significant additional hazards at the concentrations present in this product. All pertinent hazard information has been provided in this document, per the requirements of the Federal Occupational Safety and Health Administration Standard (29 CFR 1910.1200), U.S. State equivalent Standards; Canadian Workplace Hazardous Materials Identification System Standards (CPR 4); and the applicable Council Directives of the European Community and Australian Worksafe requirements.

NE = Not Established. NIC = Notice of Intended Change See Section 16 for Definitions of Terms Used

INTERNATIONAL OCCUPATIONAL EXPOSURE LIMITS: Currently, there are no international exposure limits for components of this product in greater than 1% concentration. RESPIRATORY PROTECTION: None needed under normal circumstances of use. If use of product produces inhalable mists or spray, use only respiratory protection authorized in the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134), equivalent U.S. State standards, Canadian CSA Standard Z94.4-93, the European Standard EN149, and EU member states, or the Australian Standard 1716-Respiratory Protective Devices and Australian Standard 1715-Selection, Use, and Maintenance of Respiratory Protective Devices. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is required under U.S. Federal OSHA’s Respiratory Protection Standard (1910.134-1998) or the regulations of various U.S. States, Canada, Australia, or EU Member States. If use leads to excessive mist or spray, it is recommended that the following NIOSH respiratory equipment guideline be followed for Oil Mists, Mineral. OIL MIST, MINERAL CONCENTRATION RESPIRATORY PROTECTIONUp to 50 mg/m3: Any Air-Purifying Respirator with a high-efficiency particulate filter, or any Supplied-Air

Respiratory (SAR). Up to 125 mg/m3: Any SAR operated in a continuous-flow mode, or any Powered, Air-Purifying Respirator (PAPR)

with a high-efficiency particulate filter. Up to 250 mg/m3: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any SAR

that has a tight-fitting facepiece and is operated in a continuous-flow mode, or any PAPR with a tight-fitting facepiece and a high-efficiency particulate filter, or any Self-Contained Breathing Apparatus (SCBA) with a Full Facepiece, or any SAR with a full facepiece.

Up to 2500 mg/m3: Any SAR operated in a pressure-demand or other positive-pressure mode. Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Any SCBA that has a full facepiece and

is operated in a pressure-demand or other positive-pressure mode, or any SAR that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination


8. EXPOSURE CONTROLS - PERSONAL PROTECTION (Continued) BODY PROTECTION: None needed under normal circumstances of use. Use body protection appropriate for task (e.g., rubber apron when cleaning equipment; Tyvek suit and rubber boots during non-incidental spill response). If necessary, refer to Australian Standard 3765-Clothing for Protection against Hazardous Chemicals for further information. If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce the soles of the feet or where employee’s feet may be exposed to electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136.

9. PHYSICAL and CHEMICAL PROPERTIES VAPOR DENSITY (air = 1): > 1 EVAPORATION RATE (n-BuAc = 1): > 1

SPECIFIC GRAVITY (water = 1): > 1 MELTING/FREEZING POINT: Not established. SOLUBILITY IN WATER: Insoluble. BOILING POINT: Not established. VAPOR PRESSURE: Not established. pH: Not applicable. ODOR THRESHOLD: Not applicable

COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not established. APPEARANCE, ODOR AND COLOR: This product consists of a milky-white, colorless, oily, practically odorless liquid. HOW TO DETECT THIS SUBSTANCE (warning properties): The oily appearance of this product may be a distinguishing characteristic.

10. STABILITY and REACTIVITY

STABILITY: Stable. DECOMPOSITION PRODUCTS: If exposed to extremely high temperatures, this product can decompose to generate carbon oxides and nitrogen oxides. MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong oxidizer, strong bases, and compounds that are incompatible with water. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Exposure to or contact with extremely high temperatures, incompatible chemicals.

PART IV Is there any other useful information about this material?

11. TOXICOLOGICAL INFORMATION

TOXICITY DATA: Specific toxicology data available for components greater than 1% in concentration are as follows. WHITE MINERAL OIL, U.S.P.: TDLo (Oral-Rat) 92 gm/kg/92 days-continuous: Liver: changes in liver weight; Blood: changes in leukocyte (WBC) count; Nutritional and Gross Metabolic:

weight loss or decreased weight gain SUSPECTED CANCER AGENT: The components of this product are not found on the following lists: FEDERAL OSHA Z LIST, NTP, IARC, and CAL/OSHA and therefore are not considered to be, nor suspected to be, a cancer-causing agent by these agencies. IRRITANCY OF PRODUCT: Prolonged skin contact will be mildly to moderately irritating. Contact with the eyes will be irritating. SENSITIZATION TO THE PRODUCT: The components of this product are not known to be skin or respiratory sensitizers. REPRODUCTIVE TOXICITY INFORMATION: Currently, there is no information concerning the effects of the components on this product in greater than 1% concentration in the product on the human reproductive system. Mutagenicity: No component of this product is reported to produce mutagenic effects in humans. Embryotoxicity: No component of this product is to produce embryotoxic effects in humans. Teratogenicity: No component of this product is reported to cause teratogenic effects in humans. Reproductive Toxicity: No component of this product is reported to cause reproductive effects in humans. A mutagen is a chemical that causes permanent changes to genetic material (DNA) such that the changes will propagate through generational lines. An embryotoxin is a chemical that causes damage to a developing embryo (i.e. within the first eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical that causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance that interferes in any way with the reproductive process.

BIOLOGICAL EXPOSURE INDICES: Currently, there are no Biological Exposure Indices (BEIs) established for the components of this product.

12. ECOLOGICAL INFORMATION

ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. ENVIRONMENTAL STABILITY: This product will eventually decompose into organic materials overtime in the environment.


12. ECOLOGICAL INFORMATION (Continued)

EFFECT OF MATERIAL ON PLANTS or ANIMALS: An adverse effect may occur if plants or animals are contaminated with a large amount of this product. EFFECT OF CHEMICAL ON AQUATIC LIFE: This product may be harmful to aquatic plant or animal life, especially if large volumes of this product are released into a body of water.

13. DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations or with regulations of Canada, Australia, or EU Member States. This product, if unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority. EPA WASTE NUMBER: Not applicable to wastes consisting only of this product.

14. TRANSPORTATION INFORMATION THIS PRODUCT IS NOT HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTATION.

PROPER SHIPPING NAME: Not Regulated HAZARD CLASS NUMBER and DESCRIPTION: Not Applicable UN IDENTIFICATION NUMBER: Not Applicable PACKING GROUP: Not Applicable DOT LABEL(S) REQUIRED: Not Applicable EMERGENCY RESPONSE GUIDEBOOK NUMBER, 2004: Not Applicable MARINE POLLUTANT: No component of this product is designated by the DOT to be a Marine Pollutant (per Appendix B to 49 CFR 172.101).

TRANSPORT CANADA, TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is not considered as dangerous goods, per regulations of Transport Canada. Refer to above U.S. DOT shipping information for shipments to Canada.

INTERNATIONAL AIR TRANSPORT ASSOCIATION SHIPPING INFORMATION (IATA): This material is not considered as dangerous goods by the International Air Transport Association.

INTERNATIONAL MARITIME ORGANIZATION SHIPPING INFORMATION (IMO): This product is not considered as dangerous goods by the International Maritime Organization.

EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD (ADR): This product is not considered by the United Nations Economic Commission for Europe to be dangerous goods.

AUSTRALIAN FEDERAL OFFICE OF ROAD SAFETY CODE FOR THE TRANSPORTATION OF DANGEROUS GOODS BY ROAD OR RAIL: This product is not considered as dangerous goods, per regulations of the Federal Office of Road Safety.

15. REGULATORY INFORMATION

ADDITIONAL UNITED STATES REGULATIONS: U.S. SARA REPORTING REQUIREMENTS: The components of this product are not subject to the reporting requirements of Sections 302, 304 and 313 of Title III of the Superfund Amendments and Reauthorization Act. U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for the components of this product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg) may apply, per 40 CFR 370.20. U.S. SARA HAZARD CATEGORIES: ACUTE: Yes; CHRONIC: Yes; FIRE: No; REACTIVE: No; SUDDEN RELEASE: No. U.S. CERCLA REPORTABLE QUANTITY (RQ): Not applicable. U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory. OTHER U.S. FEDERAL REGULATIONS: Not applicable. CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): No component of this product is on the California Proposition 65 lists. ANSI LABELING (Z129.1): CAUTION! CAN CAUSE EYE IRRITATION. INHALATION, INGESTION AND ASPIRATION INTO THE LUNGS MAY BE HARMFUL. PROLONGED SKIN CONTACT MAY CAUSE IRRITATION. KEEP OUT OF REACH OF CHILDREN. Use with adequate ventilation. Avoid contact of liquid with skin, eyes, and clothing. Avoid exposure to vapors, mists, or sprays. Wash thoroughly after handling. Wear appropriate hand and eye protection. FIRST-AID: In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. If inhaled, remove to fresh air. If swallowed, do not induce vomiting. Get medical attention if irritation develops or persists or if any other adverse effect occurs. IN CASE OF FIRE: Use water fog, dry chemical, or CO2, or alcohol foam. IN CASE OF SPILL: Absorb spill with inert materials (e.g., polypads, dry sand). Rinse area with soapy water. Consult Material Safety Data Sheet for additional information.


15. REGULATORY INFORMATION (Continued)

ADDITIONAL CANADIAN REGULATIONS: CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are listed on the DSL Inventory. CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITY SUBSTANCES LISTS: The components of this product are not on the CEPA Priority Substances Lists. CANADIAN WHMIS SYMBOLS: Not applicable.

EUROPEAN COMMUNITY INFORMATION: EU LABELING/CLASSIFICATION: This product does not meet the definition of a hazardous substance, as defined by the European Community Council Directive 67/548/EEC. EUROPEAN COMMUNITY ANNEX II HAZARD SYMBOL: Not applicable.

AUSTRALIAN INFORMATION FOR PRODUCT: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES (AICS) STATUS: The components of this product listed by CAS# in Section 2 (Composition and Information on Ingredients) are listed on the AICS. LIST OF DESIGNATED SUBSTANCES: Not applicable. STANDARD FOR THE UNIFORM SCHEDULING OF DRUGS AND POISONS: Not applicable. LABELING AND CLASSIFICATION: This product does not meet the definition of any hazard classification criteria, based a review of the regulation [NOHSC: 10005 (1994)]:

16. OTHER INFORMATION PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc. PO Box 3519, La Mesa, CA 91944-3519 619/670-0609 DATE OF PRINTING: January 9, 2006

The data in this Material Safety Data Sheet is true and accurate to the best of Teitelbaum Brothers, Inc.’s knowledge. However, since data, safety standards, and government regulations are subject to change conditions of handling, use, or misuse are beyond Teitelbaum Brothers, Inc. control, Teitelbaum Brothers, Inc. MAKES NO WARRANTY, EITHER EXPRESSED OR IMPLIED, WITH RESPECT TO THE COMPLETENESS OR CONTINUING ACCURACY OF THE INFORMATION CONTAINED HEREIN AND DISCLAIMS ALL LIABILITY FOR RELIANCE THEREON. The user is required to comply with all laws and regulations relating to the purchase, use, storage, and disposal of the product. User must be familiar with and follow generally accepted safe handling procedures of chemicals, and is solely responsible for any effects caused by its misuse or mixing of this chemical with any other substance.

DEFINITION OF TERMS A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following: CAS #: This is the Chemical Abstract Service Number that uniquely identifies each constituent. EXPOSURE LIMITS IN AIR: CEILING LEVEL: The concentration that shall not be exceeded during any part of the working exposure. DFG MAK Pregnancy Risk Group Classification: Group A: A risk of damage to the developing embryo or fetus has been unequivocally demonstrated. Exposure of pregnant women can cause damage of the developing organism, even when MAK and BAT (Biological Tolerance Value for Working Materials) values are observed. Group B: Currently available information indicates a risk of damage to the developing embryo or fetus must be considered to be probable. Damage to the developing organism cannot be excluded when pregnant women are exposed, even when MAK and BAT values are observed. Group C: There is no reason to fear a risk of damage to the developing embryo or fetus when MAK and BAT values are observed. Group D: Classification in one of the groups A-C is not yet possible because, although the data available may indicate a trend, they are not sufficient for final evaluation. IDLH-Immediately Dangerous to Life and Health: This level represents a concentration from which one can escape within 30-minutes without suffering escape-preventing or permanent injury. LOQ: Limit of Quantitation. MAK: Federal Republic of Germany Maximum Concentration Values in the workplace. NE: Not Established. When no exposure guidelines are established, an entry of NE is made for reference. NIC: Notice of Intended Change. NIOSH CEILING: The exposure that shall not be exceeded during any part of the workday. If instantaneous monitoring is not feasible, the ceiling shall be assumed as a 15-minute TWA exposure (unless otherwise specified) that shall not be exceeded at any time during a workday. NIOSH RELs: NIOSH’s Recommended Exposure Limits.

EXPOSURE LIMITS IN AIR (continued): PEL-Permissible Exposure Limit: OSHA’s Permissible Exposure Limits. This exposure value means exactly the same as a TLV, except that it is enforceable by OSHA. The OSHA Permissible Exposure Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated. The phrase, “Vacated 1989 PEL,” is placed next to the PEL that was vacated by Court Order. SKIN: Used when a there is a danger of cutaneous absorption. STEL-Short Term Exposure Limit: Short Term Exposure Limit, usually a 15-minute time-weighted average (TWA) exposure that should not be exceeded at any time during a workday, even if the 8-hr TWA is within the TLV-TWA, PEL-TWA or REL-TWA. TLV-Threshold Limit Value: An airborne concentration of a substance that represents conditions under which it is generally believed that nearly all workers may be repeatedly exposed without adverse effect. The duration must be considered, including the 8-hour. TWA-Time Weighted Average: Time Weighted Average exposure concentration for a conventional 8-hr (TLV, PEL) or up to a 10-hr (REL) workday and a 40-hr workweek. HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD RATINGS: This rating system was developed by the National Paint and Coating Association and has been adopted by industry to identify the degree of chemical hazards. HEALTH HAZARD: 0 (Minimal Hazard: No significant health risk, irritation of skin or eyes not anticipated. Skin Irritation: Essentially non-irritating. PII or Draize = “0”. Eye Irritation: Essentially non-irritating, or minimal effects which clear in < 24 hours [e.g. mechanical irritation]. Draize = “0”. Oral Toxicity LD50 Rat: < 5000 mg/kg. Dermal Toxicity LD50Rat or Rabbit: < 2000 mg/kg. Inhalation Toxicity 4-hrs LC50 Rat: < 20 mg/L.);


DEFINITIONS OF TERMS (Continued)

HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD RATINGS (continued): HEALTH HAZARD (continued): 1 (Slight Hazard: Minor reversible Injury may occur; slightly or mildly irritating. Skin Irritation: Slightly or mildly irritating. Eye Irritation: Slightly or mildly irritating. Oral Toxicity LD50 Rat: > 500-5000 mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 1000-2000 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 2-20 mg/L); 2 (Moderate Hazard: Temporary or transitory injury may occur. Skin Irritation: Moderately irritating; primary irritant; sensitizer. PII or Draize > 0, < 5. Eye Irritation: Moderately to severely irritating and/or corrosive; reversible corneal opacity; corneal involvement or irritation clearing in 8-21 days. Draize > 0, < 25. Oral Toxicity LD50 Rat: > 50-500 mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 200-1000 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 0.5-2 mg/L); 3 (Serious Hazard: Major injury likely unless prompt action is taken and medical treatment is given; high level of toxicity; corrosive. Skin Irritation: Severely irritating and/or corrosive; may destroy dermal tissue, cause skin burns, dermal necrosis. PII or Draize > 5-8 with destruction of tissue. Eye Irritation: Corrosive, irreversible destruction of ocular tissue; corneal involvement or irritation persisting for more than 21 days. Draize > 80 with effects irreversible in 21 days. Oral Toxicity LD50 Rat: > 1-50 mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 20-200 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 0.05-0.5 mg/L.); 4 (Severe Hazard: Life-threatening; major or permanent damage may result from single or repeated exposure. Skin Irritation: Not appropriate. Do not rate as a “4”, based on skin irritation alone. Eye Irritation: Not appropriate. Do not rate as a “4”, based on eye irritation alone. Oral Toxicity LD50 Rat: < 1 mg/kg. Dermal Toxicity LD50Rat or Rabbit: < 20 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: < 0.05 mg/L). FLAMMABILITY HAZARD: 0 (Minimal Hazard-Materials that will not burn in air when exposure to a temperature of 815.5°C [1500°F] for a period of 5 minutes.); 1 (Slight Hazard-Materials that must be pre-heated before ignition can occur. Material require considerable pre-heating, under all ambient temperature conditions before ignition and combustion can occur, Including: Materials that will burn in air when exposed to a temperature of 815.5°C (1500°F) for a period of 5 minutes or less; Liquids, solids and semisolids having a flash point at or above 93.3°C [200°F] (e.g. OSHA Class IIIB, or; Most ordinary combustible materials [e.g. wood, paper, etc.]; 2 (Moderate Hazard-Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. Materials in this degree would not, under normal conditions, form hazardous atmospheres in air, but under high ambient temperatures or moderate heating may release vapor in sufficient quantities to produce hazardous atmospheres in air, Including: Liquids having a flash-point at or above 37.8°C [100°F]; Solid materials in the form of course dusts that may burn rapidly but that generally do not form explosive atmospheres; Solid materials in a fibrous or shredded form that may burn rapidly and create flash fire hazards (e.g. cotton, sisal, hemp; Solids and semisolids that readily give off flammable vapors.); 3 (Serious Hazard- Liquids and solids that can be ignited under almost all ambient temperature conditions. Materials in this degree produce hazardous atmospheres with air under almost all ambient temperatures, or, unaffected by ambient temperature, are readily ignited under almost all conditions, including: Liquids having a flash point below 22.8°C [73°F] and having a boiling point at or above 38°C [100°F] and below 37.8°C [100°F] [e.g. OSHA Class IB and IC]; Materials that on account of their physical form or environmental conditions can form explosive mixtures with air and are readily dispersed in air [e.g., dusts of combustible solids, mists or droplets of flammable liquids]; Materials that burn extremely rapidly, usually by reason of self-contained oxygen [e.g. dry nitrocellulose and many organic peroxides]); 4 (Severe Hazard-Materials that will rapidly or completely vaporize at atmospheric pressure and normal ambient temperature or that are readily dispersed in air, and which will burn readily, including: Flammable gases; Flammable cryogenic materials; Any liquid or gaseous material that is liquid while under pressure and has a flash point below 22.8°C [73°F] and a boiling point below 37.8°C [100°F] [e.g. OSHA Class IA; Material that ignite spontaneously when exposed to air at a temperature of 54.4°C [130°F] or below [e.g. pyrophoric]); PHYSICAL HAZARD: 0 (Water Reactivity: Materials that do not react with water. Organic Peroxides: Materials that are normally stable even under fire conditions and will not react with water. Explosives: Substances that are Non-Explosive. Unstable Compressed Gases: No Rating. Pyrophorics: No Rating. Oxidizers: No “0” rating allowed. Unstable Reactives: Substances that will not polymerize, decompose, condense or self-react.);

HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD RATINGS (continued): PHYSICAL HAZARD (continued): 1 (Water Reactivity: Materials that change or decompose upon exposure to moisture. Organic Peroxides: Materials that are normally stable, but can become unstable at high temperatures and pressures. These materials may react with water, but will not release energy. Explosives: Division 1.5 & 1.6 substances that are very insensitive explosives or that do not have a mass explosion hazard. Compressed Gases: Pressure below OSHA definition. Pyrophorics: No Rating. Oxidizers: Packaging Group III; Solids: any material that in either concentration tested, exhibits a mean burning time less than or equal to the mean burning time of a 3:7 potassium bromate/cellulose mixture and the criteria for Packing Group I and II are not met. Liquids: any material that exhibits a mean pressure rise time less than or equal to the pressure rise time of a 1:1 nitric acid (65%)/cellulose mixture and the criteria for Packing Group I and II are not met. Unstable Reactives: Substances that may decompose, condense or self-react, but only under conditions of high temperature and/or pressure and have little or no potential to cause significant heat generation or explosive hazard. Substances that readily undergo hazardous polymerization in the absence of inhibitors.);2 (Water Reactivity: Materials that may react violently with water. Organic Peroxides: Materials that, in themselves, are normally unstable and will readily undergo violent chemical change, but will not detonate. These materials may also react violently with water. Explosives: Division 1.4 – Explosive substances where the explosive effect are largely confined to the package and no projection of fragments of appreciable size or range are expected. An external fire must not cause virtually instantaneous explosion of almost the entire contents of the package. Compressed Gases: Pressurized and meet OSHA definition but < 514.7 psi absolute at 21.1°C (70°F) [500 psig]. Pyrophorics: No Rating. Oxidizers: Packing Group II Solids: any material that, either in concentration tested, exhibits a mean burning time of less than or equal to the mean burning time of a 2:3 potassium bromate/cellulose mixture and the criteria for Packing Group I are not met. Liquids: any material that exhibits a mean pressure rise time less than or equal to the pressure rise of a 1:1 aqueous sodium chlorate solution (40%)/cellulose mixture and the criteria for Packing Group I are not met. Reactives: Substances that may polymerize, decompose, condense, or self-react at ambient temperature and/or pressure, but have a low potential for significant heat generation or explosion. Substances that readily form peroxides upon exposure to air or oxygen at room temperature); 3 (Water Reactivity: Materials that may form explosive reactions with water. Organic Peroxides: Materials that are capable of detonation or explosive reaction, but require a strong initiating source, or must be heated under confinement before initiation; or materials that react explosively with water. Explosives: Division 1.2 – Explosive substances that have a fire hazard and either a minor blast hazard or a minor projection hazard or both, but do not have a mass explosion hazard. Compressed Gases: Pressure > 514.7 psi absolute at 21.1°C (70°F) [500 psig]. Pyrophorics: No Rating. Oxidizers: Packing Group I Solids: any material that, in either concentration tested, exhibits a mean burning time less than the mean burning time of a 3.:2 potassium bromate/cellulose mixture. Liquids: Any material that spontaneously ignites when mixed with cellulose in a 1:1 ratio, or which exhibits a mean pressure rise time less than the pressure rise time of a 1:1 perchloric acid (50%)/cellulose mixture. Unstable Reactives: Substances that may polymerize, decompose, condense or self-react at ambient temperature and/or pressure and have a moderate potential to cause significant heat generation or explosion.); 4 (Water Reactivity: Materials that react explosively with water without requiring heat or confinement. Organic Peroxides: Materials that are readily capable of detonation or explosive decomposition at normal temperature and pressures. Explosives: Division 1.1 & 1.2-explosive substances that have a mass explosion hazard or have a projection hazard. A mass explosion is one that affects almost the entire load instantaneously. Compressed Gases: No Rating. Pyrophorics: Add to the definition of Flammability “4”. Oxidizers: No “4” rating. Unstable Reactives: Substances that may polymerize, decompose, condense or self-react at ambient temperature and/or pressure and have a high potential to cause significant heat generation or explosion.).


DEFINITIONS OF TERMS (Continued)

NATIONAL FIRE PROTECTION ASSOCIATION HAZARD RATINGS: HEALTH HAZARD: 0 (material that on exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials); 1 (materials that on exposure under fire conditions could cause irritation or minor residual injury); 2 (materials that on intense or continued exposure under fire conditions could cause temporary incapacitation or possible residual injury);3 (materials that can on short exposure could cause serious temporary or residual injury); 4 (materials that under very short exposure could cause death or major residual injury). FLAMMABILITY HAZARD: 0 Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. 1 Materials that must be preheated before ignition can occur. Materials in this degree require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur 2 Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. Materials in this degree would not under normal conditions form hazardous atmospheres with air, but under high ambient temperatures or under moderate heating could release vapor in sufficient quantities to produce hazardous atmospheres with air. 3 Liquids and solids that can be ignited under almost all ambient temperature conditions. Materials in this degree produce hazardous atmospheres with air under almost all ambient temperatures or, though unaffected by ambient temperatures, are readily ignited under almost all conditions. 4 Materials that will rapidly or completely vaporize at atmospheric pressure and normal ambient temperature or that are readily dispersed in air and will burn readily. INSTABILITY HAZARD: 0 Materials that in themselves are normally stable, even under fire conditions. 1 Materials that in themselves are normally stable, but that can become unstable at elevated temperatures and pressures. 2 Materials that readily undergo violent chemical change at elevated temperatures and pressures. 3 Materials that in themselves are capable of detonation or explosive decomposition or explosive reaction, but that require a strong initiating source or that must be heated under confinement before initiation. 4 Materials those in themselves are readily capable of detonation or explosive decomposition or explosive reaction at normal temperatures and pressures.

FLAMMABILITY LIMITS IN AIR: Much of the information related to fire and explosion is derived from the National Fire Protection Association (NFPA). Flash Point - Minimum temperature at which a liquid gives off sufficient vapors to form an ignitable mixture with air. Autoignition Temperature: The minimum temperature required to initiate combustion in air with no other source of ignition. LEL - the lowest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. UEL - the highest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source.

TOXICOLOGICAL INFORMATION: Human and Animal Toxicology: Possible health hazards as derived from human data, animal studies, or from the results of studies with similar compounds are presented. Definitions of some terms used in this section are: LD50 - Lethal Dose (solids & liquids) which kills 50% of the exposed animals; LC50 - Lethal Concentration (gases) which kills 50% of the exposed animals; ppm concentration expressed in parts of material per million parts of air or water; mg/m3 concentration expressed in weight of substance per volume of air; mg/kg quantity of material, by weight, administered to a test subject, based on their body weight in kg. Other measures of toxicity include TDLo, the lowest dose to cause a symptom and TCLo the lowest concentration to cause a symptom; TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic effects. Cancer Information: The sources are: IARC - the International Agency for Research on Cancer; NTP - the National Toxicology Program, RTECS - the Registry of Toxic Effects of Chemical Substances, OSHA and CAL/OSHA. IARC and NTP rate chemicals on a scale of decreasing potential to cause human cancer with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used. Other Information: BEI - ACGIH Biological Exposure Indices, represent the levels of determinants which are most likely to be observed in specimens collected from a healthy worker who has been exposed to chemicals to the same extent as a worker with inhalation exposure to the TLV. ECOLOGICAL INFORMATION: EC is the effect concentration in water. BCF = Bioconcentration Factor, which is used to determine if a substance will concentrate in lifeforms which consume contaminated plant or animal matter. TLm = median threshold limit; Coefficient of Oil/Water Distribution is represented by log Kow or log Koc and is used to assess a substance’s behavior in the environment. REGULATORY INFORMATION: U.S. and CANADA: This section explains the impact of various laws and regulations on the material. EPA is the U.S. Environmental Protection Agency. ACGIH: American Conference of Governmental Industrial Hygienists, a professional association which establishes exposure limits. NIOSH is the National Institute of Occupational Safety and Health, which is the research arm of the U.S. Occupational Safety and Health Administration (OSHA). WHMIS is the Canadian Workplace Hazardous Materials Information System. DOT and TC are the U.S. Department of Transportation and the Transport Canada, respectively. Superfund Amendments and Reauthorization Act (SARA); the Canadian Domestic/Non-Domestic Substances List (DSL/NDSL); the U.S. Toxic Substance Control Act (TSCA); Marine Pollutant status according to the DOT; the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA or Superfund); and various state regulations. This section also includes information on the precautionary warnings which appear on the material’s package label. OSHA - U.S. Occupational Safety and Health Administration. EUROPEAN: EU is the European Union (formerly known as the EEC, European Economic Community). EINECS: This the European Inventory of Now-Existing Chemical Substances. The ARD is the European Agreement Concerning the International Carriage of Dangerous Goods by Road and the RID are the International Regulations Concerning the Carriage of Dangerous Goods by Rail. AUSTRALIAN: AICS is the Australian Inventory of Chemical Substances. NOHSC: National Occupational Health & Safety Code.



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SO-014

SMITHERS-OASIS NORTH AMERICA

919 MARVIN AVENUE • P.O. BOX NUMBER 118 • KENT, OHIO 44240

MATERIAL SAFETY DATA SHEET

Oasis® Clear Solution, Liquid

NORTH AMERICAN HEADQUARTERS TELEPHONE 330-673-5831 • CUSTOMER SERVICE 800-321-8286 • FAX 800-447-0813

PARTICIPATING MEMBER A.F.M.C., SAFE ENDOWMENT AND W.F & F.S.A

SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

IDENTITY

Wet Cut Flower Nutrient

DATE PREPARED

6/23/03

SYNONYMS, CHEMICAL NAMES, COMMON NAMES

Fresh Cut Flower Food

USE:

Fresh Cut Flower Nutrition

MANUFACTURER'S NAME

Smithers-Oasis

TELEPHONE NUMBER – INFORMATION

(330) 673-5831

ADDRESS

919 Marvin Avenue

P.O. Box 118

Kent, OH 44240 USA

TELEPHONE NUMBER - EMERGENCY

Transportation emergency: CHEMTREC: 800-424-9300

International Transportation: CHEMTREC: 703-527-3887

Rocky Mountain Poison Control Center: 303-623-5716

SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS

HAZARDOUS COMPONENTS OSHA PEL ACGIH TLV %

Citric Acid (CAS# 77-92-9) None established. None established 1-2 %

Remaining components, if any, are not hazardous or hazardous components are present at less than 1%

(0.1% for carcinogens).

EMERGENCY OVERVIEW

Aqueous clear liquid with no odor.

Irritating to eyes. May be irritating to skin.

SECTION 3 –HAZARDS IDENTIFICATION

PRIMARY ROUTE(s) OF EXPOSURE:

Inhalation; skin; eyes; ingestion.

IRRITATION DATA:

Irritating to eyes. May be irritating to skin.

INHALATION:

ACUTE: May cause nasal and/or respiratory irritation.

CHRONIC: None known.

SKIN CONTACT:

ACUTE: May cause irritation. Skin absorption is unlikely. No evidence of sensitization.

CHRONIC: Prolonged and repeated contact may result in irritation.

EYE CONTACT:

ACUTE: Direct contact is irritating.


2 of 4


6/23/03

INGESTION:

ACUTE: May cause gastric disturbance.


MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE

Persons with pre-existing skin or eye conditions may be at increased risk from exposure.

SECTION 4 - EMERGENCY AND FIRST AID PROCEDURES

INHALATION: Remove from exposure to fresh air immediately. If breathing has stopped, give artificial

respiration. Oxygen may be given if breathing is difficult. Seek medical attention.

SKIN CONTACT: Remove contaminated clothing and shoes. Wash affected area with soap and water until no

evidence of the chemical remains. Seek medical attention if irritation develops.

EYE CONTACT: Flush thoroughly with water for at least 15 minutes, occasionally lifting the upper and lower

lids, until no evidence of the chemical remains. Seek medical attention.

INGESTION: Treat symptomatically and supportively. Seek medical attention if irritation develops.

SECTION 5 - FIRE FIGHTING MEASURES

FLASH POINT FLAMMABLE LIMITS LEL: Not applicable

None UEL: Not applicable

AUTOIGNITION TEMPERATURE: Not known.

EXTINGUISHING MEDIA

This is a water based product and will not support combustion. On dried product, use water spray, foam,

carbon dioxide, or dry chemical powder.

SPECIAL FIRE FIGHTING PROCEDURES

Firefighters should wear full protective NIOSH approved self contained breathing apparatus.

UNUSUAL FIRE AND EXPLOSION HAZARDS

None known.

SECTION 6 - ACCIDENTAL RELEASE MEASURES

Wear suitable protective equipment. Mop up or absorb on inert material such as vermiculite or sand. Place in

suitable container for disposal. Flush cleaned area with water.

SECTION 7 – HANDLING AND STORAGE

HANDLING:

FOR INTENDED USE AS FRESH FLOWER NUTRIENT ONLY.

Do not ingest

Do not get into eyes.

Avoid prolonged or repeated skin contact.

Observe good personal and industrial hygiene practices.

Keep out of the reach of children.

STORAGE:

Store in a cool, dry well ventilated area.

Avoid freezing.

SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION

RESPIRATORY PROTECTION

Where airborne concentrations may exceed guidelines for permissible air concentrations, choose a respirator in

accordance with OSHA Respirator Standard 29 CFR 1910.134.

3 of 4


6/23/03

VENTILATION

Use general dilution or local exhaust ventilation to maintain exposure below the exposure limits.

PROTECTIVE GLOVES

Choose appropriate gloves in accordance with OSHA Personal Protective Equipment Standard 29 CFR

1910.132.

EYE PROTECTION

Safety glasses with side shields or choose in accordance with OSHA 29 CFR 1910.133.

OTHER PROTECTIVE CLOTHING OR EQUIPMENT

Appropriate protective clothing to minimize repeated and prolonged skin contact with this material.

RECOMMENDED EXPOSURE LIMITS

OSHA and ACGIH have not set exposure limits for this material or its components.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

BOILING POINT Not available SPECIFIC GRAVITY Not available

pH 1.8 FREEZING POINT 32º F

VAPOR PRESSURE (mm Hg) Not available % SOLIDS 48 %

VAPOR DENSITY (Air = 1) Not available EVAPORATION RATE Same as water

SOLUBILITY Soluble in water.

APPEARANCE AND ODOR: Aqueous clear liquid with no odor.

SECTION 10 - STABILITY AND REACTIVITY

STABILITY Unstable Conditions to Avoid

Stable X Stable at normal room temperature.

INCOMPATIBILITY (Materials to Avoid)

Strong oxidizing agents. Avoid mixing with oxidizing solutions such as concentrated bleach.

HAZARDOUS DECOMPOSITION PRODUCTS

Very high temperature, i.e. combustion conditions, may release toxic and/or hazardous gases.

HAZARDOUS May Occur Conditions to Avoid

POLYMERIZATION Will Not Occur X None known.

SECTION 11 - TOXICOLOGICAL INFORMATION

This formulation has not been tested for acute toxicity. It is expected to have a low order of acute toxicity.

Carcinogenicity: Not listed by IARC, NTP, or OSHA

Reproductive data: None known

Fetotoxicity: None known

SECTION 12 - ECOLOGICAL INFORMATION

This formulation has not been tested for environmental effects.

Do not contaminate ponds or streams.

SECTION 13 - DISPOSAL CONSIDERATIONS

Dispose in accordance with all applicable federal, state, and local environmental regulations.

If discarded in its original form, this material is regulated by Resource Conservation and Recovery Act (RCRA)

as a D002 (corrosive) hazardous waste.

4 of 4


6/23/03

SECTION 14 – TRANSPORT INFORMATION

PROPER SHIPPING NAME DOT CLASSIFICATION DOT UN/NA Not regulated Not applicable. Not applicable

Material is not regulated as a DOT Marine Pollutant

SECTION 15 – REGULATORY INFORMATION

OSHA: This material may be classified as hazardous under OSHA regulations.

TSCA: All components are listed on the TSCA 8(b) inventory.

SARA Title III - Toxic chemicals list 40 CFR 372.65: None

SARA HAZARD CATEGORIES:

Acute Health Hazard Chronic Health Hazard Fire Hazard Reactive Hazard Sudden Release of Pressure

Yes No No No No

CERCLA Hazardous Substances List 40 CFR 302: None

RCRA Hazardous Waste Codes 40 CFR 261.24, 261.33 : D002

CANADA:

WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations.

Controlled Product Hazard: Class D, Division 2, Subdivision B

Ingredients which may require reporting under the WHMIS IDL are:

Citric acid CAS# 77-92-9

CANADIAN ENVIRONMENTAL PROTECTION ACT: All components are on the Domestic Substances List

(DSL).

SECTION 16 – OTHER INFORMATION

HMIS Ratings:

Health 1

Flammability 0

Reactivity 0

where 0=minimal, 1=slight, 2=moderate, 3=serious, 4=severe

European Union: R-36 Irritating to the Eyes

S-2 Keep out of the Reach of Children

S-25 Avoid Contact with Eyes

The information and recommendations set forth herein are made in good faith and are believed to be accurate as of

the date of preparation. Smithers-Oasis makes no warranty, either expressed or implied, with respect to this

information and disclaims all liability from reliance on it.

Issued by Smithers-Oasis Safety and Environmental Department.

2 of 5 Oasis® Floral Foam

6/8/09

SECTION 3 – COMPOSITION, INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS CAS# %

Acid catalysts Proprietary 8-12 %

Barium sulfate 7727-43-7 2-3 %

Heptane 142-82-5 < 1.5 %

Formaldehyde 50-00-0 < 0.15 %

Other components, if any, are not hazardous or hazardous components are present at less than 1% (0.1% for carcinogens).

SECTION 4 - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove from exposure to fresh air. If breathing has stopped, give artificial respiration. Oxygen may be given if

breathing is difficult. Get medical attention. SKIN CONTACT: Wash affected area with soap and water until no evidence of the material remains. Get medical attention if

irritation develops. EYE CONTACT: Flush thoroughly with water for at least 15 minutes, occasionally lifting the upper and lower lids, until no evidence

of the material remains. Get medical attention if irritation develops. If wearing contact lens, remove immediately and flush eyes as above.

INGESTION: Do not induce vomiting. Treat symptomatically and supportively. If a large quantity is ingested, get medical attention since there could be a problem with physical blockage.

SECTION 5 - FIRE FIGHTING MEASURES Flash Point: Not applicable. Flammable Limits UEL: Not applicable. Flammable Limits LEL: Not applicable. Autoignition Temperature: ~600°F. Extinguishing Media: Water spray, foam, carbon dioxide, or dry chemical. Special Fire Fighting Procedures: Avoid breathing smoke. Firefighters should wear full protective NIOSH approved self-contained breathing apparatus. Unusual Fire and Explosion Hazards: Finished foam will support combustion if it is ignited by direct contact with an open flame or exposed to temperatures in the range of 600°F. If foam is placed in a microwave for an extended period, it will begin to burn. Combustion occurs at the center of the brick and due to the insulating effect of the foam, can proceed unnoticed until an appreciable heat buildup occurs. SECTION 6 - ACCIDENTAL RELEASE MEASURES Wear suitable protective equipment. Reclaim or place in suitable container for disposal. SECTION 7 - HANDLING AND STORAGE Store in a cool, dry well ventilated area, out of direct sunlight. Foam stored in stagnant or hot enclosures may result in off gassing of residual formaldehyde gas. Wash thoroughly after handling. Observe good personal and industrial hygiene procedures. When foam is soaked or used in water, some low levels of residual formaldehyde may accumulate in tub water. Repeated skin immersion in water containing formaldehyde has caused skin rashes, particularly in sensitive persons. It is recommended that impervious latex or chemical resistant gloves be worn and water tubs be emptied regularly. SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION RESPIRATORY PROTECTION

A dust mask is recommended if dust is excessive. Where airborne concentrations may exceed guidelines for permissible air concentrations, choose a respirator in accordance with OSHA Respirator Standard 29 CFR 1910.134.

VENTILATION Use general dilution ventilation to maintain exposure below the exposure limits.

PROTECTIVE GLOVES Use barrier cream or choose appropriate gloves in accordance with OSHA Subpart I Personal Protective Equipment Hand Protection Standard 29 CFR 1910.138.

EYE PROTECTION Safety glasses are recommended or choose in accordance with OSHA Eye and Face Protection Standard 29 CFR 1910.133.


6/8/09

OTHER PROTECTIVE CLOTHING OR EQUIPMENT Not normally required.

RECOMMENDED EXPOSURE LIMITS OSHA and ACGIH have not set exposure limits for this material. .

COMPONENTS OSHA PEL ACGIH TLV

Formaldehyde CAS# 50-00-0

0.75 ppm TWA 2 ppm STEL

0.3 ppm CEILING

Acid catalysts: inorganic acid CAS # Propriatary

1 mg/m3 TWA 1 mg/m3 TWA 3 mg/m3 STEL

Barium sulfate CAS# 7727-43-7

15 mg/m3 TWA as Ba (Total dust) 5 mg/m3 TWA as Ba (Respirable fraction)

10 mg/m3 TWA

Heptane 500 ppm TWA 400 ppm TWA 500 ppm STEL

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: Green, fine-celled thermoset phenolic plastic foam Odor: None. Odor Threshold: Not applicable. Physical State: Solid pH: 3.0 in 5% slurry Melting/Freezing Point:: Not available Boiling Point:: Not applicable Flash Point: Not applicable. Evaporation Rate: Not applicable Flammability: Will burn. Upper Explosive Limits: Not applicable. Lower Explosive Limits: Not applicable. Vapor Pressure: Not applicable Vapor Density: Not applicable Specific Gravity or Relative Density: Not available Solubility: Not soluble Oil/Water Coefficient: Not applicable Autoignition Temperature: Not kn9own. Decomposition Temperature: Not known. SECTION 10 - STABILITY AND REACTIVITY CHEMICAL STABILITY: Stable. CONDITIONS TO AVOID: Stable at normal room temperature. INCOMPATIBLE MATERIALS: Normally unreactive. HAZARDOUS DECOMPOSITION PRODUCTS: Smoke, oxides of carbon, and possible trace amounts of formaldehyde, phenol, cresols, xylenols, and sulfur dioxide. POSSIBILITY OF HAZARDOUS REACTIONS: Will not occur. SECTION 11 – TOXICOLOGICAL INFORMATION Toxicity studies on a similar compound indicate that the Oral LD50 (rat): >5000 mg/kg Primary Dermal Irritation Study in Albino Rabbits on a similar compound: Non irritant Inhalation LC50 (rat): 103 gm/m3/4H Heptane TDLo (rat): 60 gm/kg/3W Heptane: Changes in liver weight TDLo (rat): 260 gm/kg/13W: Heptane: Changes in bladder weight; Changes in brain and coverings. Carcinogenicity: Formaldehyde has been classified as a Group 2A carcinogen by IARC, is reasonably anticipated to be a human carcinogen by NTP, and is a suspected human carcinogen by ACGIH. Carbon black has been classified as an IARC2B carcinogen. Tumorigenic data (RTECS) Formaldehyde; barium sulfate; carbon black Reproductive data (RTECS): Formaldehyde Mutagenic data (RTECS): Formaldehyde; barium sulfate; green dye Teratology data (RTECS): Formaldehyde


6/8/09

SECTION 12 - ECOLOGICAL INFORMATION This formulation has not been tested for environmental effects. It is a thermoset plastic and is not biodegradable.


Dispose in accordance with all applicable federal, state, and local environmental regulations. Recycling is recommended. It can be cut up and used as a soil conditioner. Since it dries faster than regular soils, it can be used to aerate tightly packed clay type soils. If discarded in its original form, material is not regulated by Resource Conservation and Recovery Act (RCRA) as a hazardous waste. Passes TCLP test requirements.

SECTION 14 - TRANSPORT INFORMATION Material is not regulated as a DOT Marine Pollutant Proper Shipping Name: Not regulated. Hazard Class: Not applicable. ID Number: Not applicable. Packing Group: Not applicable. Marine Pollutant: Not regulated by 49 CFR 172.101. SECTION 15 - REGULATORY INFORMATION OSHA: This material may be classified as hazardous under OSHA regulations. TSCA: All components are listed or exempt from listing on the TSCA 8(b) inventory. DSL: All components are listed or exempt from listing. EINECS: All components are listed or exempt from listing. SARA Title III - Toxic chemicals list 40 CFR 372.65 Formaldehyde CAS# 50-00-0 <0.2 % Barium sulfate is exempt from reporting under the category “Barium compounds” (59FR33208). SARA Hazard Categories: Acute Health Hazard Chronic Health Hazard Fire Hazard Reactive Hazard Sudden Release of Pressure

Yes Yes No No No CERCLA Toxic Chemicals List 40 CFR 302: Formaldehyde RQ: 100# A spill in excess of 66,000 pounds would require reporting to the National Response Center based on the maximum residual content of formaldehyde in the foam. CALIFORNIA PROPOSITION 65: The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of 1986. This product contains chemicals known to the State of California to cause cancer or other reproductive harm. SECTION 16 – OTHER INFORMATION HMIS Ratings: Health 1 Flammability 1 Reactivity 0 where 0=minimal, 1=slight, 2=moderate, 3=serious, 4=severe European Risk Phrases: R: 20, 45 Key/Legend: ACGIH: American Conference of Governmental Industrial Hygienists ACGIH TLV: ACGIH Threshold Limit Values


6/8/09

CAS: Chemical Abstract Service CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act CFR: Code of Federal Regulations CNS: Central Nervous System CPR: Controlled Product Regulations DSL: Domestic Substances List EINECS: European Inventory of Existing Commercial Chemical Substances IARC: International Agency for Research on Cancer IDL: Ingredient Disclosure List NIOSH: National Institute of Occupational Safety and Health OSHA: Occupational Safety and Health Administration OSHA PEL: OSHA Permissible Exposure Limits RCRA:: Resource Conservation and Recovery Act RTECS: Registry of Toxic Effects of Chemical Substances SARA: Superfund Amendments and Reauthorization Act TSCA: Toxic Substances Control Act TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Information System The information and recommendations set forth herein are made in good faith and are believed to be accurate as of the date of preparation. Smithers-Oasis makes no warranty, either expressed or implied, with respect to this information and disclaims all liability from reliance on it.

of 5 SO-0013

SMITHERS-OASIS NORTH AMERICA 919 MARVIN STREET • P.O. BOX NUMBER 790 • KENT, OHIO 44240

MATERIAL SAFETY DATA SHEET

Oasis® Floral Foam

NORTH AMERICAN HEADQUARTERS TELEPHONE 330-673-5831 • CUSTOMER SERVICE 800-321-8286 • FAX 800-447-0813 PARTICIPATING MEMBER A.F.M.C., SAFE ENDOWMENT AND W.F & F.S.A

SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION IDENTITY

OASIS® Floral Foam DATE PREPARED 6/08/2009

SYNONYMS, CHEMICAL NAMES, COMMON NAMES OASIS® Floral Foam

USE: Arrangement of cut flowers

MANUFACTURER'S NAME

Smithers-Oasis TELEPHONE NUMBER - INFORMATION

330-673-5831 ADDRESS

919 Marvin Street P.O. Box 790 Kent, OH 44240 USA

EMERGENCY TELEPHONE NUMBER Transportation emergency: CHEMTREC: 800 424-9300 International Transportation: CHEMTREC: 703-527-3887

Rocky Mountain Poison and Drug Center: 303- 623-5716 SECTION - 2 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Green fine-celled thermoset phenolic plastic foam.

May be irritating to eyes, skin, and respiratory tract. May contain formaldehyde and/or carbon black. Prolonged exposure may cause cancer.

PRIMARY ROUTE(s) OF EXPOSURE:

Contact and Inhalation of dust. IRRITATION DATA:

May cause irritation to skin, eyes, and respiratory tract. INHALATION: ACUTE: Dust or fumes may cause irritation to the nasal passages, lacrimation, olfactory changes, and pulmonary changes.

Inhalation of heptane fumes may irritate the respiratory tract producing light headedness, dizziness, muscle incoordination, CNS depression and narcosis.

CHRONIC: Prolonged exposure to formaldehyde and/or carbon black may cause cancer. SKIN CONTACT: ACUTE: May cause irritation. CHRONIC: May cause dermatitis. Frequent or prolonged exposure to formaldehyde can cause hypersensitivity leading to contact

dermatitis. EYE CONTACT: ACUTE: Contact may be irritating. CHRONIC: May cause conjunctivitis. INGESTION: ACUTE: May cause mouth irritation due to local pH effect. Swallowing formaldehyde may cause violent vomiting and diarrhea.

Aspiration of heptane into lungs can produce severe lung damage. CHRONIC: Prolonged exposure may cause symptoms similar to acute effects. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE

None known.


6/8/09

SECTION 3 – COMPOSITION, INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS CAS# %

Acid catalysts Proprietary 8-12 %

Barium sulfate 7727-43-7 2-3 %

Heptane 142-82-5 < 1.5 %

Formaldehyde 50-00-0 < 0.15 %

Other components, if any, are not hazardous or hazardous components are present at less than 1% (0.1% for carcinogens).

SECTION 4 - EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove from exposure to fresh air. If breathing has stopped, give artificial respiration. Oxygen may be given if

breathing is difficult. Get medical attention. SKIN CONTACT: Wash affected area with soap and water until no evidence of the material remains. Get medical attention if

irritation develops. EYE CONTACT: Flush thoroughly with water for at least 15 minutes, occasionally lifting the upper and lower lids, until no evidence

of the material remains. Get medical attention if irritation develops. If wearing contact lens, remove immediately and flush eyes as above.

INGESTION: Do not induce vomiting. Treat symptomatically and supportively. If a large quantity is ingested, get medical attention since there could be a problem with physical blockage.

SECTION 5 - FIRE FIGHTING MEASURES Flash Point: Not applicable. Flammable Limits UEL: Not applicable. Flammable Limits LEL: Not applicable. Autoignition Temperature: ~600°F. Extinguishing Media: Water spray, foam, carbon dioxide, or dry chemical. Special Fire Fighting Procedures: Avoid breathing smoke. Firefighters should wear full protective NIOSH approved self-contained breathing apparatus. Unusual Fire and Explosion Hazards: Finished foam will support combustion if it is ignited by direct contact with an open flame or exposed to temperatures in the range of 600°F. If foam is placed in a microwave for an extended period, it will begin to burn. Combustion occurs at the center of the brick and due to the insulating effect of the foam, can proceed unnoticed until an appreciable heat buildup occurs. SECTION 6 - ACCIDENTAL RELEASE MEASURES Wear suitable protective equipment. Reclaim or place in suitable container for disposal. SECTION 7 - HANDLING AND STORAGE Store in a cool, dry well ventilated area, out of direct sunlight. Foam stored in stagnant or hot enclosures may result in off gassing of residual formaldehyde gas. Wash thoroughly after handling. Observe good personal and industrial hygiene procedures. When foam is soaked or used in water, some low levels of residual formaldehyde may accumulate in tub water. Repeated skin immersion in water containing formaldehyde has caused skin rashes, particularly in sensitive persons. It is recommended that impervious latex or chemical resistant gloves be worn and water tubs be emptied regularly. SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION RESPIRATORY PROTECTION

A dust mask is recommended if dust is excessive. Where airborne concentrations may exceed guidelines for permissible air concentrations, choose a respirator in accordance with OSHA Respirator Standard 29 CFR 1910.134.

VENTILATION Use general dilution ventilation to maintain exposure below the exposure limits.

PROTECTIVE GLOVES Use barrier cream or choose appropriate gloves in accordance with OSHA Subpart I Personal Protective Equipment Hand Protection Standard 29 CFR 1910.138.

EYE PROTECTION Safety glasses are recommended or choose in accordance with OSHA Eye and Face Protection Standard 29 CFR 1910.133.


6/8/09

OTHER PROTECTIVE CLOTHING OR EQUIPMENT Not normally required.

RECOMMENDED EXPOSURE LIMITS OSHA and ACGIH have not set exposure limits for this material. .

COMPONENTS OSHA PEL ACGIH TLV

Formaldehyde CAS# 50-00-0

0.75 ppm TWA 2 ppm STEL

0.3 ppm CEILING

Acid catalysts: inorganic acid CAS # Propriatary

1 mg/m3 TWA 1 mg/m3 TWA 3 mg/m3 STEL

Barium sulfate CAS# 7727-43-7

15 mg/m3 TWA as Ba (Total dust) 5 mg/m3 TWA as Ba (Respirable fraction)

10 mg/m3 TWA

Heptane 500 ppm TWA 400 ppm TWA 500 ppm STEL

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: Green, fine-celled thermoset phenolic plastic foam Odor: None. Odor Threshold: Not applicable. Physical State: Solid pH: 3.0 in 5% slurry Melting/Freezing Point:: Not available Boiling Point:: Not applicable Flash Point: Not applicable. Evaporation Rate: Not applicable Flammability: Will burn. Upper Explosive Limits: Not applicable. Lower Explosive Limits: Not applicable. Vapor Pressure: Not applicable Vapor Density: Not applicable Specific Gravity or Relative Density: Not available Solubility: Not soluble Oil/Water Coefficient: Not applicable Autoignition Temperature: Not kn9own. Decomposition Temperature: Not known. SECTION 10 - STABILITY AND REACTIVITY CHEMICAL STABILITY: Stable. CONDITIONS TO AVOID: Stable at normal room temperature. INCOMPATIBLE MATERIALS: Normally unreactive. HAZARDOUS DECOMPOSITION PRODUCTS: Smoke, oxides of carbon, and possible trace amounts of formaldehyde, phenol, cresols, xylenols, and sulfur dioxide. POSSIBILITY OF HAZARDOUS REACTIONS: Will not occur. SECTION 11 – TOXICOLOGICAL INFORMATION Toxicity studies on a similar compound indicate that the Oral LD50 (rat): >5000 mg/kg Primary Dermal Irritation Study in Albino Rabbits on a similar compound: Non irritant Inhalation LC50 (rat): 103 gm/m3/4H Heptane TDLo (rat): 60 gm/kg/3W Heptane: Changes in liver weight TDLo (rat): 260 gm/kg/13W: Heptane: Changes in bladder weight; Changes in brain and coverings. Carcinogenicity: Formaldehyde has been classified as a Group 2A carcinogen by IARC, is reasonably anticipated to be a human carcinogen by NTP, and is a suspected human carcinogen by ACGIH. Carbon black has been classified as an IARC2B carcinogen. Tumorigenic data (RTECS) Formaldehyde; barium sulfate; carbon black Reproductive data (RTECS): Formaldehyde Mutagenic data (RTECS): Formaldehyde; barium sulfate; green dye Teratology data (RTECS): Formaldehyde


6/8/09

SECTION 12 - ECOLOGICAL INFORMATION This formulation has not been tested for environmental effects. It is a thermoset plastic and is not biodegradable.


Dispose in accordance with all applicable federal, state, and local environmental regulations. Recycling is recommended. It can be cut up and used as a soil conditioner. Since it dries faster than regular soils, it can be used to aerate tightly packed clay type soils. If discarded in its original form, material is not regulated by Resource Conservation and Recovery Act (RCRA) as a hazardous waste. Passes TCLP test requirements.

SECTION 14 - TRANSPORT INFORMATION Material is not regulated as a DOT Marine Pollutant Proper Shipping Name: Not regulated. Hazard Class: Not applicable. ID Number: Not applicable. Packing Group: Not applicable. Marine Pollutant: Not regulated by 49 CFR 172.101. SECTION 15 - REGULATORY INFORMATION OSHA: This material may be classified as hazardous under OSHA regulations. TSCA: All components are listed or exempt from listing on the TSCA 8(b) inventory. DSL: All components are listed or exempt from listing. EINECS: All components are listed or exempt from listing. SARA Title III - Toxic chemicals list 40 CFR 372.65 Formaldehyde CAS# 50-00-0 <0.2 % Barium sulfate is exempt from reporting under the category “Barium compounds” (59FR33208). SARA Hazard Categories: Acute Health Hazard Chronic Health Hazard Fire Hazard Reactive Hazard Sudden Release of Pressure

Yes Yes No No No CERCLA Toxic Chemicals List 40 CFR 302: Formaldehyde RQ: 100# A spill in excess of 66,000 pounds would require reporting to the National Response Center based on the maximum residual content of formaldehyde in the foam. CALIFORNIA PROPOSITION 65: The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of 1986. This product contains chemicals known to the State of California to cause cancer or other reproductive harm. SECTION 16 – OTHER INFORMATION HMIS Ratings: Health 1 Flammability 1 Reactivity 0 where 0=minimal, 1=slight, 2=moderate, 3=serious, 4=severe European Risk Phrases: R: 20, 45 Key/Legend: ACGIH: American Conference of Governmental Industrial Hygienists ACGIH TLV: ACGIH Threshold Limit Values


6/8/09

CAS: Chemical Abstract Service CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act CFR: Code of Federal Regulations CNS: Central Nervous System CPR: Controlled Product Regulations DSL: Domestic Substances List EINECS: European Inventory of Existing Commercial Chemical Substances IARC: International Agency for Research on Cancer IDL: Ingredient Disclosure List NIOSH: National Institute of Occupational Safety and Health OSHA: Occupational Safety and Health Administration OSHA PEL: OSHA Permissible Exposure Limits RCRA:: Resource Conservation and Recovery Act RTECS: Registry of Toxic Effects of Chemical Substances SARA: Superfund Amendments and Reauthorization Act TSCA: Toxic Substances Control Act TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Information System The information and recommendations set forth herein are made in good faith and are believed to be accurate as of the date of preparation. Smithers-Oasis makes no warranty, either expressed or implied, with respect to this information and disclaims all liability from reliance on it.

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