Cosnova SDB Flammable Products Englisch

/7Material Safety Data Sheet

According to 91/155 EECPrinting date 05.04.2006 Reviewed on 04.04.2006

DR

1 Identification of substance: Product details:

Trade name: Flammable Products:- Nail Polish- Nail Polish Removers (liquid)- Alcoholic Liquids and Alcohol containing Pump Spray

Application of the substance / the preparation Cosmetic products

Manufacturer/Supplier:cosnova GmbHAm Limespark 2D-65843 Sulzbach

Tel.: +49 (0)6196/76156-0Fax : +49 (0)6196/76156-59

Informing department:Quality AssuranceMr. Reifschneider

Emergency information:Tel.: 0049-6142-6970Fax : 0049-6142-697101

2 Composition/Data on components:

Chemical characterization Description: Solvent mixture with additives. Dangerous components:

CAS: 141-78-6EINECS: 205-500-4

ethyl acetate Xi, F; R 11-36-66-67 > 25%

CAS: 67-64-1EINECS: 200-662-2

acetone Xi, F; R 11-36-66-67 > 25%

CAS: 123-86-4EINECS: 204-658-1

n-butyl acetate R 10-66-67 < 50%

CAS: 79-20-9EINECS: 201-185-2

methyl acetate Xi, F; R 11-36-66-67 < 25%

CAS: 67-63-0EINECS: 200-661-7

propan-2-ol Xi, F; R 11-36-67 < 25%

Additional information For the wording of the listed risk phrases refer to section 16.

3 Hazards identification Hazard designation:

Xi IrritantF Highly flammable

Information pertaining to particular dangers for man and environmentThe product has to be labelled due to the calculation procedure of the "General Classification guideline forpreparations of the EU" in the latest valid version.At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent.Has a narcotizing effect.R 11 Highly flammable.R 36 Irritating to eyes.R 66 Repeated exposure may cause skin dryness or cracking.

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R 67 Vapours may cause drowsiness and dizziness.

4 First aid measures General information Instantly remove any clothing soiled by the product. After inhalation

Take affected persons into the open air and position comfortablySeek medical treatment in case of complaints.

After skin contact Instantly wash with water and soap and rinse thoroughly. After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. After swallowing Seek immediate medical advice. Information for doctor No particular measures are known - treat according to symptoms. The following symptoms may occur:

HeadacheDazedDizziness

Treatment If swallowed, gastric irrigation with added, activated carbon.

5 Fire fighting measures Suitable extinguishing agents

CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. For safety reasons unsuitable extinguishing agents Water with a full water jet. Protective equipment: Do not inhale explosion gases or combustion gases. Additional information

Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

6 Accidental release measures Person-related safety precautions:

Ensure adequate ventilationKeep away from ignition sources

Measures for environmental protection:Prevent material from reaching sewage system, holes and cellars.Do not allow to enter the ground/soil.

Measures for cleaning/collecting:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).Ensure adequate ventilation.

Additional information: Clean the accident area carefully.

7 Handling and storage

Handling Information for safe handling:

Keep containers tightly sealed.Store in cool, dry place in tightly closed containers.Ensure good ventilation/exhaustion at the workplace.Prevent formation of aerosols.Keep away from heat and direct sunlight.

Information about protection against explosions and fires:Keep ignition sources away - Do not smoke.Protect against electrostatic charges.Protect from heat.Highly volatile, flammable constituents are released during processing.Fumes can combine with air to form an explosive mixture.Flammable mixtures may be formed in empty containers.

Storage Requirements to be met by storerooms and containers:

Store only in the original container.(Contd. on page 3)

GB



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Provide solvent resistant, sealed floor.Provide floor trough without outlet.Do not store the product at temperatures below 5 C or above 25 C

Information about storage in one common storage facility:Store away from foodstuffs.Do not store together with oxidizing or spontaneously flammable materials.

Further information about storage conditions:Keep container tightly sealed.Store in cool, dry conditions in well sealed containers.Protect from heat and direct sunlight.

8 Exposure controls and personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace:

141-78-6 ethyl acetate (> 25%)WEL (Great Britain) Short-term value: 400 ppm

Long-term value: 200 ppm67-64-1 acetone (> 25%)WEL (Great Britain)

TLV (European Union)

Short-term value: 3620 mg/m, 1500 ppmLong-term value: 1210 mg/m, 500 ppmLong-term value: 1210 mg/m, 500 ppm

123-86-4 n-butyl acetate (< 50%)WEL (Great Britain) Short-term value: 966 mg/m, 200 ppm

Long-term value: 724 mg/m, 150 ppm79-20-9 methyl acetate (< 25%)WEL (Great Britain) Short-term value: 770 mg/m, 250 ppm

Long-term value: 616 mg/m, 200 ppm67-63-0 propan-2-ol (< 25%)WEL (Great Britain) Short-term value: 1250 mg/m, 500 ppm

Long-term value: 999 mg/m, 400 ppm Additional information: The lists that were valid during the compilation were used as basis.

Personal protective equipment General protective and hygienic measures

Keep away from foodstuffs, beverages and food.Wash hands during breaks and at the end of the work.Avoid contact with the eyes.Avoid contact with the eyes and skin.

Breathing equipment:In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longerexposure use breathing apparatus that is independent of circulating air.

Use breathing protection in case of insufficient ventilation.

Recommended filter device for short term use: Filter AX Protection of hands:

Protective gloves.

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/the chemical mixture.Selection of the glove material on consideration of the penetration times, rates of diffusion and thedegradation




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DR

Material of glovesThe selection of the suitable gloves does not only depend on the material, but also on further marks of qualityand varies from manufacturer to manufacturer. As the product is a preparation of several substances, theresistance of the glove material can not be calculated in advance and has therefore to be checked prior to theapplication.

Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protective gloves and has to beobserved.

For the permanent contact in work areas without heightened risk of injury (e.g. Laboratory) gloves madeof the following material are suitable:Nitrile rubber, NBRNeoprene glovesFluorocarbon rubber (Viton)Butyl rubber, BR

As protection from splashes gloves made of the following materials are suitable: PVC gloves Not suitable are gloves made of the following materials:

Strong glovesLeather gloves

Eye protection:

Tightly sealed safety glasses.

Body protection: Protective work clothing.

9 Physical and chemical properties:

General Information

Form: FluidColour: According to product specificationOdour: Characteristic

Change in conditionMelting point/Melting range: Not determinedBoiling point/Boiling range: < 100C

Flash point: < 21C

Self-inflammability: Product is not selfigniting.

Danger of explosion: Product is not explosive. However, formation of explosive air/steammixtures is possible.

Critical values for explosion:Lower: 2.1 Vol %Upper: 16.0 Vol %

Density Not determined

10 Stability and reactivity Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Materials to be avoided:

strong basesstrong acidsoxidizing agents

Dangerous reactionsForms explosive gas mixture with airExplosive

Dangerous products of decomposition:Inflammable gases/vapoursin the event of fire:




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DR

harmful and flammmable gases/vapours, which can form explosive mixtures with air

11 Toxicological information Acute toxicity: LD/LC50 values that are relevant for classification:

141-78-6 ethyl acetateOral LD50 5600 mg/kg (rat)

4935 mg/kg (rbt)Dermal LD50 18000 mg/kg (rab)Inhalative LC50/4 h 1600 mg/l (rat)67-64-1 acetoneOral LD50 3000 mg/kg (Mouse)

5800 mg/kg (rat)Dermal LD50 20000 mg/kg (rbt)Inhalative LCLo (4h) 16000 ppm (rat)

TCLo (4h) 12000 mg/l (Human)79-20-9 methyl acetateOral LD50 6970 mg/kg (rat)67-63-0 propan-2-olOral LD50 4570 mg/kg (rat)Dermal LD50 13400 mg/kg (rab)Inhalative LC50/4 h 30 mg/l (rat)

30 mg/l (rat) Primary irritant effect: on the skin: No irritant effect. on the eye: Irritant effect. Sensitization: No sensitizing effect known. Additional toxicological information:

The product shows the following dangers according to the calculation method of the General ECClassification Guidelines for Preparations as issued in the latest version:Irritant

12 Ecological information: Ecotoxical effects: Not determined Acquatic toxicity:

141-78-6 ethyl acetateEC10 (16h) 2.900 mg/l (Pseudomonas putida)EC50 (24h) 724 mg/l (daphnia)LC50(48h) 350 mg/l (fish)67-64-1 acetoneLC50 (14d) 7032 mg/l (Poecilia reticulata)

(96h) 8300 mg/l (Lepomis macrochirus (Sonnenbarsch))67-63-0 propan-2-olEC50 (48h) 13299 mg/l (Daphnia magna)EC50 (72h) > 1000 mg/l (Alge)LC50 (96h) 9640 mg/l (Pimephales promelas)

General notes:Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.




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Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewagesystem.

13 Disposal considerations

Product: Recommendation Must be specially treated under adherence to official regulations. European waste catalogue

08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OFCOATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS ANDPRINTING INKS

08 01 00 wastes from MFSU and removal of paint and varnish08 01 11 waste paint and varnish containing organic solvents or other dangerous substances

Uncleaned packagings: Recommendation: Disposal must be made according to official regulations.

14 Transport information

Land transport ADR/RID (cross-border)

ADR/RID-GGVS/E Class: 3 Flammable liquids. Kemler Number: 33 UN-Number: 1266 Packaging group: II Label 3 Designation of goods: 1266 PERFUMERY PRODUCTS, special provision 640D

Maritime transport IMDG:

IMDG Class: 3 UN Number: 1266 Label 3 Packaging group: II EMS Number: F-E,S-E Marine pollutant: No Correct technical name: PERFUMERY PRODUCTS

Air transport ICAO-TI and IATA-DGR:

ICAO/IATA Class: 3 UN/ID Number: 1266 Label 3 Packaging group: II Correct technical name: PERFUMERY PRODUCTS

GB

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DR

15 Regulatory information

Designation according to EC guidelines:The product has been classified and labelled in accordance with EC Directives / Ordinance on HazardousMaterials (GefStoffV)

Code letter and hazard designation of product:

Xi IrritantF Highly flammable

Risk phrases:11 Highly flammable.36 Irritating to eyes.66 Repeated exposure may cause skin dryness or cracking.67 Vapours may cause drowsiness and dizziness.

Safety phrases:7/9 Keep container tightly closed and in a well-ventilated place.16 Keep away from sources of ignition - No smoking.23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).24/25 Avoid contact with skin and eyes.26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.33 Take precautionary measures against static discharges.45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where

possible).60 This material and its container must be disposed of as hazardous waste.

National regulations

Technical instructions (air):Class Share in %NK 50-100

Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.

16 Other information:These data are based on our present knowledge. However, they shall not constitute a guarantee for anyspecific product features and shall not establish a legally valid contractual relationship.

Relevant R-phrases10 Flammable.11 Highly flammable.36 Irritating to eyes.66 Repeated exposure may cause skin dryness or cracking.67 Vapours may cause drowsiness and dizziness.

Department issuing data specification sheet:IGG-AD Ingenieurbro fr Gefahrstoff- und GefahrgutberatungBismarckstrae 10D-68623 LampertheimFax: 0049-(0)6206-58422 http://www.igg-ad.de

Contact:Dr. U. PrinzDipl.-Chem. H. Hinse

GB

Cosnova SDB Flammable Products Englisch

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