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    NO. MATRIKULASI :

    NO. KAD PENGENALAN :

    NO. TELEFON :

    E-MEL :

    PUSAT PEMBELAJARAN :

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    ISI KANDUNGAN

    1.0 Introducton 1

    1.1 Objective of study 1

    !.0 Pro"#rt#$ o% &'r(on A))otro"#$2

    2.1 Properties of Graphite 3

    2.2 Properties of Diamond 6

    *.0 T+# U$',# o% D'ond 'nd Gr'"+t# 10

    .0 &onc)u$on 17

    RUJUKAN 18

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    1.0 Introducton

    Although the !"#o$e%& o' #(%)o* !" e(%l!e% th(* +e e,-e#t !t !" "t!ll u**o+* u*t!l Ho+le%012345 e'!*e #(%)o* (" ( #he6!#(l ele6e*t +!th "&6)ol C (to6!# *u6)e% o' 3 (* ele#t%o*

    #o*'!gu%(t!o* o' 7He89s99p9. The *(6e #(%)o* o%!g!*(te '%o6 L(t!* carbo (* F%e*#h

    charbon6e(*!*g #h(%#o(l. :(%)o* !" the 'ou%th 6o"t ()u*(*t #he6!#(l ele6e*t !* the

    u*!$e%"e )& 6("". It !" (l"o the "e#o* ()u*(*t ele6e*t )& 6("" !* hu6(* )o&. :(%)o* h("

    )ee* *o+*"!*#e -%eh!"to%!# t!6e.;oo" 6(!*l& #o*"!"te o' #(%)o* h($e )ee* +!el& u"e

    'o% +(%6!*g (* #oo!*g '%o6 -%eh!"to%!# t!6e. D!(6o* (*othe% (llot%o-e o' #(%)o* h("

    )ee* t%e("u%e (" ge6"to*e" )e#(u"e o' %e6(%()le o-t!#(l #h(%(#te%!"t!#" (* +!el& (--l!e

    !* !*u"t%& )e#(u"e o' "u-e%!o% h(%*e"" (* goo the%6(l #o*u#t!$!t&.

    Peo-le '%o6 the e(%l& #!$!l!(t!o* h( !"#o$e%e #(%)o* (* the '!%"t *o+* u"e o' (#t!$(te

    #(%)o* (te" )(# to the A*#!e*t Eg&-t!(*" +ho ut!l!e !t" ("o%)e*t -%o-e%t!e" 'o% -u%!'&!*g

    o!l" (* 6e!#!*(l -u%-o"e". :e*tu%!e" l(te% the e(%l& o#e(*=go!*g $e""el" "to%e %!*!*g

    +(te% !* +ooe* )(%%el" the !*"!e o' +h!#h h( )ee* #h(%%e. B& the e(%l& 12th #e*tu%& )oth

    +oo (* )o*e #h(%#o(l +(" !* l(%ge="#(le u"e 'o% the e#olo%!(t!o* (* -u%!'!#(t!o* o' #(*e

    "ug(%. Ho+e$e% !t +(" *ot u*t!l the )eg!**!*g o' the F!%"t ;o%l ;(% th(t the -ote*t!(l o'

    (#t!$(te #(%)o* +(" %e(ll& #(-!t(l!e u-o*. The ($e*t o' g(" +(%'(%e *e#e""!t(te the

    e$elo-6e*t o' "u!t()le %e"-!%(to%& e$!#e" 'o% -e%"o**el -%ote#t!o*. G%(*ul(% (#t!$(te

    #(%)o* +(" u"e to th!" e* (" !*ee !t "t!ll !" to(&. B& the l(te 12?@" the%e +("

    #o*"!e%()le !*u"t%!(l="#(le u"e o' #(%)o* 'o% g("eou" (* l!u! -h("e (--l!#(t!o* (* *e+

    6(*u'(#tu%!*g -%o#e""e" h( )ee* e$elo-e to "(t!"'& the *ee" o' !*u"t%&. Du%!*g the

    122=124 +(% ( 'u%the% "!g*!'!#(*t e$elo-6e*t too -l(#e = the -%ou#t!o* o' 6o%e

    "o-h!"t!#(te #he6!#(ll& !6-%eg*(te #(%)o* 'o% e*t%(-6e*t o' )oth +(% (* *e%$e g("e".

    1.1 O(3#ct4# o% $tud5

    The 6(!* -u%-o"e o' th!" "tu& !" to '!* out the !"oto-e" o% the (llot%o-e" o' #(%)o* +h!#h !"

    !(6o* (* g%(-h!te. B& u"!*g the !*'o%6(t!o* o' the (llot%o-e" +e #(* (l"oC=

    !. Ie*t!'& the -h&"!#(l (* #he6!#(l -%o-e%t!e" o' the (llot%o-e"

    !!. L!"t o+* the 6(!* (--l!#(t!o*" o' the (llot%o-e"

    1

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    !.0 Pro"#rt#$ o% &'r(on A))otro"#$

    :(%)o* h(" "e$e%(l (llot%o-e" o% !''e%e*t 'o%6" !* +h!#h !t e,!"t". I*te%e"t!*gl& #(%)o*

    (llot%o-e" "-(* ( +!e %(*ge o' -h&"!#(l -%o-e%t!e" the h(%e"t *(tu%(ll& o##u%%!*g "u)"t(*#e

    0!(6o*5 (* o*e o' the "o'te"t *o+* "u)"t(*#e" 0g%(-h!te5 (%e )oth (llot%o-e". D!(6o* !"

    t%(*"-(%e*t the ult!6(te ()%("!$e (* #(* )e (* ele#t%!#(l !*"ul(to% (* the%6(l #o*u#to%

    #o*$e%"el& g%(-h!te !" o-(ue ( $e%& goo lu)%!#(*t ( goo #o*u#to% o' ele#t%!#!t& (* (

    the%6(l !*"ul(to%. Allot%o-e" o' #(%)o* (%e *ot l!6!te to !(6o*" (* g%(-h!te" )ut (l"o

    !*#lue )u#&)(ll" 0'ulle%e*e"5 (6o%-hou" #(%)o* gl(""& #(%)o* (* *(*otu)e".

    9

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    !.1 Pro"#rt#$ o% Gr'"+t#

    I. Ph&"!#(l P%o-e%t!e"

    G%(-h!te h(" ( l(&e%e (* -l(*(% "t%u#tu%e. I* e(#h l(&e% the #(%)o* (to6" (%e (%%(*ge !* (

    he,(go*(l l(tt!#e +!th ( l(tt!#e -(%(6ete% o' ?.149*6 +h!le the !"t(*#e )et+ee* -l(*e" !"

    ?. *6 6(!*g !t the "o'te"t *(tu%(l 6(te%!(l" +!th Moh" h(%*e"" o' 10Setto* 9??95.

    E(#h g%(-h!te l(&e% !" #o*"!"t" o' -u%esp9h&)%!!e #(%)o* (to6" (* $(* e% ;((l" 'o%#e

    hol" the l(&e%" togethe%.G%(-h!te !" 6(!*l& (--l!e !* !*u"t%& 'o% lu)%!#(t!o*. The 6!*e%(l

    g%(-h!te !" "teel g%(& to )l(# !* #olo% (* !" oo%le"". It !" o-(ue (* h(" ( "u) 6et(ll!#

    lu"te%. G%(-h!te !" $e%& "o't (* h(" ( g%e("& te,tu%e. It #(* )e )%oe* e("!l& (* le($e" (

    )l(# "t%e( o* the h(* +he* tou#he. Although g%(-h!te !" "o't (* 'le,!)le !t !" *ot el("t!#

    !* *(tu%e.

    G%(-h!te !" #%&"t(ll!*e !* *(tu%e ho+e$e% -e%'e#t #%&"t(l" o' g%(-h!te (%e %(%el& 'ou*. The

    #(%)o* (to6" !* g%(-h!te (%e (%%(*ge !* ( he,(go*(l 6(**e% !* ( -l(*(% #o*e*"e %!*g

    "&"te6. Th!" g!$e" the g%(-h!te #%&"t(l" ( he,(go*(l "h(-e. D!''e%e*t l(&e%" o' g%(-h!te (%e

    "t(#e togethe% (* hel )& +e( #o$(le*t 'o%#e" to 'o%6 ( g!(*t #o$(le*t "t%u#tu%e.

    G%(-h!te h(" ( h!gh 6elt!*g -o!*t ()o$e ??? l!e th(t o' !(6o* the othe% (llot%o-e o'

    #(%)o*. He*#e !t !" "t()le o$e% ( +!e %(*ge o' te6-e%(tu%e". A" the%e !" ( lot o' $(#(*t "-(#e)et+ee* the g%(-h!te "heet" hel )& the +e( #o$(le*t )o*" the e*"!t& o' g%(-h!te !" 9.?2

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    to 9. g/## +h!#h !" lo+e% th(* th(t o' !(6o*. The 6e("u%e "-e#!'!# g%($!t& o' g%(-h!te

    !" (--%o,!6(tel& 9.93 g/## ho+e$e% !t e-e*" u-o* the -u%!t& o' g%(-h!te. G%(-h!te +!th (

    h!ghe% ("h #o*te*t "ho+" ( "-e#!'!# g%($!t& h!ghe% th(* 9.93 +h!le *(tu%(l g%(-h!te h(" (

    lo+e% "-e#!'!# g%($!t& o% e*"!t& ue to the t%(--e -o%o"!t&

    G%(-h!te !" !*"olu)le !* +(te% (" +ell (" othe% o%g(*!# "ol$e*t". The%e (%e *o (tt%(#t!$e 'o%#e"

    th(t o##u% )et+ee* the "ol$e*t 6ole#ule" (* the #(%)o*" (to6" !* g%(-h!te (* "o !t '(!l" to

    !""ol$e !* (*& o' the o%g(*!# "ol$e*t". The%e !" $("t elo#(l!(t!o* o' ele#t%o*" +!th!* the

    #(%)o* l(&e%" o' g%(-h!te. The elo#(l!e ele#t%o*" (%e '%ee to 6o$e (* (%e ()le to #o*u#t

    ele#t%!#!t& thu" 6(!*g g%(-h!te ( goo #o*u#to% o' ele#t%!#!t&.

    4

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    II. :he6!#(l -%o-e%t!e"

    Pu%e g%(-h!te !" o*e o' the 6o"t #he6!#(ll& !*e%t 6(te%!(l". It !" %e"!"t(*t to 6o"t (#!"

    (l(l!e" (* #o%%o"!$e g("e". Ho+e$e% !6-u%!t!e" (%e (l6o"t (l+(&" -%e"e*t to "o6e eg%ee !*

    )oth *(tu%(l (* (%t!'!#!(l g%(-h!te" (* o'te* h($e (* !6-o%t(*t #(t(l&t!# e''e#t +!th %e"ult!*g

    !*#%e("e !* the #he6!#(l %e(#t!$!t&. The (*!"ot%o-& o' the g%(-h!te #%&"t(l !" %e'le#te !* !t"

    #he6!#(l )eh($!o%. Re(#t!o* +!th g("e" o% $(-o%" o##u%" -%e'e%e*t!(ll& (t (#t!$e "!te" !.e.

    the e* o' the )("(l -l(*e" o' the #%&"t(l +h!#h (%e the !g(g '(#e (* the (%6=#h(!% '(#e

    (* (t e'e#t "!te" "u#h (" !"lo#(t!o*" $(#(*#!e" (* "te-". Re(#t!o* +!th the )("(l -l(*e

    "u%'(#e" !" '(% "lo+e%. The %e("o* !" th(t the g%(-h!te #%&"t(l e,h!)!t" l(%ge !''e%e*#e" !*

    "u%'(#e e*e%g& !* the !''e%e*t #%&"t(llog%(-h!# !%e#t!o*" the"e e*e%g!e" (6ou*t to J/69 !*

    the -%!"6(t!# -l(*e )ut o*l& ?.11 J/69 !* the )("(l -l(*e. The"e !''e%e*#e" (##ou*t 'o% the

    !''e%e*t %(te o' %e(#t!o* !.e. "lo+ (t the )("(l -l(*e (* %(-! (t the ege 0o% -%!"6(t!#5

    "u%'(#e" 'ou* (t the te%6!*(t!o* o' the )("(l -l(*e" o% (t e'e#t" +!th!* the )("(l -l(*e.

    :o*"eue*tl& g%(-h!te 6(te%!(l" +!th l(%ge #%&"t(l" (* 'e+ e'e#t" h($e the )e"t #he6!#(l

    %e"!"t(*#e.

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    !.! Pro"#rt#$ o% D'ond

    D!(6o*" (%e 'o%6e +he* #(%)o* e-o"!t" (%e e,-o"e to h!gh -%e""u%e (* h!gh

    te6-e%(tu%e 'o% -%olo*ge -e%!o" o' t!6e. Dee- +!th!* the e(%th" #%u"t the%e (%e %eg!o*" th(t

    h($e ( h!gh e*ough te6-e%(tu%e 02??: to 14??:5 (* -%e""u%e 0 to 3 GP(5 th(t !t !"

    the%6o&*(6!#(ll& -o""!)le 'o% l!u!'!e #(%)o* to 'o%6 !*to !(6o*". D!(6o* #o*"!"t" o'

    -u%e sph&)%!!e #(%)o* (to6". It !" %e*o+*e 'o% !t" e,t%e6e h(%*e"" 0h(%e"t *(tu%(l

    6(te%!(l" +!th Moh" h(%*e"" o' 1? "!*#e (*t!u!t&5 o%!g!*(t!*g '%o6 the "t%o*g #o$(le*t

    )o*!*g )et+ee* #(%)o* (to6" (* 'o% !t" %el(t!$el& h!gh o-t!#(l !"-e%"!o* o' $!"!)le

    "-e#t%u6 #o$!*g 1. e (* the%6(l #o*u#t!$!t& 02??99?;/6/K 0;(le% 1225 .

    D!(6o* !" 6(!*l& (--l!e !* !*u"t%!(l #utt!*g (* -ol!"h!*g tool" )e"!e" (" the6o"t

    -o-ul(% ge6"to*e !* ou% l!'e.

    I. Ph&"!#(l P%o-e%t!e"

    Stu& )& ;(le% 01225 e'!*e !(6o* (" ( t%(*"-(%e*t #%&"t(l o' tet%(he%(ll& )o*e

    #(%)o* (to6" !* ( #o$(le*t *et+o% l(tt!#e 0"-5 th(t #%&"t(ll!e" !*to the !(6o* l(tt!#e

    +h!#h !" ( $(%!(t!o* o' the '(#e #e*te%e #u)!#"t%u#tu%e. D!(6o*" h($e )ee* 6o!'!e 'o%

    6(*& u"e" )e#(u"e o' the 6(te%!(l" e,#e-t!o*(l -h&"!#(l #h(%(#te%!"t!#". Mo"t *ot()le (%e !t"

    e,t%e6e h(%*e"" (* the%6(l #o*u#t!$!t& 02??99? ;61K15 (" +ell (" +!e)(*g(-

    (* h!gh o-t!#(l !"-e%"!o*. N(tu%(ll& o##u%%!*g !(6o*" h($e ( e*"!t& %(*g!*g '%o6 .1

    . g/#6 +!th -u%e !(6o* #lo"e to .9 g/#6. The #he6!#(l )o*" th(t hol the #(%)o*

    3

    http://en.wikipedia.org/wiki/Transparency_(optics)http://en.wikipedia.org/wiki/Crystalhttp://en.wikipedia.org/wiki/Tetrahedral-octahedral_honeycombhttp://en.wikipedia.org/wiki/Orbital_hybridisationhttp://en.wikipedia.org/wiki/Orbital_hybridisationhttp://en.wikipedia.org/wiki/Diamond_cubichttp://en.wikipedia.org/wiki/Face_centered_cubichttp://en.wikipedia.org/wiki/Bandgaphttp://en.wikipedia.org/wiki/Transparency_(optics)http://en.wikipedia.org/wiki/Crystalhttp://en.wikipedia.org/wiki/Tetrahedral-octahedral_honeycombhttp://en.wikipedia.org/wiki/Orbital_hybridisationhttp://en.wikipedia.org/wiki/Diamond_cubichttp://en.wikipedia.org/wiki/Face_centered_cubichttp://en.wikipedia.org/wiki/Bandgap
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    (to6" !* !(6o*" togethe% (%e +e(e% th(* tho"e !* g%(-h!te. I* !(6o*" the )o*" 'o%6

    (* !*'le,!)le th%ee=!6e*"!o*(l l(tt!#e +he%e(" !* g%(-h!te the (to6" (%e t!ghtl& )o*e !*to

    "heet" +h!#h #(* "l!e e("!l& o$e% o*e (*othe% 6(!*g the o$e%(ll "t%u#tu%e +e(e%.

    A##o%!*g to P. G. 09??5 +!th the Moh" "#(le o' 1? !(6o* !" the h(%e"t *o+* *(tu%(l

    6(te%!(l o* the Moh" "#(le o' 6!*e%(l h(%*e"" +he%e h(%*e"" !" e'!*e (" %e"!"t(*#e to

    "#%(t#h!*g (* !" g%(e )et+ee* 1 0"o'te"t5 (* 1? 0h(%e"t5. D!(6o*" h(%*e"" (* h!gh

    6elt!*g -o!*t 6(e !t u"e'ul 'o% #utt!*g tool" "u#h (" the !(6o*=t!--e !"#" u"e to #ut

    )%!#" (* #o*#%ete. He($&=ut& %!ll )!t" l!e tho"e u"e to %!ll th%ough %o#" !* the o!l

    e,-lo%(t!o* !*u"t%& (%e 6(e +!th !(6o*" "o th(t the& "t(& "h(%- 'o% lo*ge%.

    II. :he6!#(l P%o-e%t!e"

    D!(6o* !" ge*e%(ll& !*e%t to 6o"t #he6!#(l e*$!%o*6e*t" +!th the *ot()le e,#e-t!o* o'

    o,!(t!o*. I* -u%e o,&ge* the o*"et o' o,!(t!o* h(" )ee* "ho+* to "t(%t (t te6-e%(tu%e ("

    lo+ (" 9?: 'o% '!*el& !$!e -o+e%" (* to )e#o6e %(-! ()o$e 3??:. D!(6o* )u%*"

    )%!ghtl& !* (* o,&ge* et (t 9?:. D!(6o* !" %e"!"t(*t to (ll l!u! o%g(*!# (* !*o%g(*!#

    (#!" (t %oo6 te6-e%(tu%e. Ho+e$e% !t #(* )e et#he )& "e$e%(l #o6-ou*" !*#lu!*g "t%o*g

    o,!!e%" "u#h (" "o!u6 (* -ot(""!u6 *!t%(te" ()o$e ??: )& 'lu,e" o' "o!u6 (*

    -ot(""!u6 #hlo%(te" (* )& 6olte* h&%o,!e" "u#h (" N(OH. It !" %e"!"t(*t to (l(l!" (*

    "ol$e*t". At (--%o,!6(tel& 1???: !t %e(#t" %e(!l& +!th #(%)!e='o%6!*g 6et(l" "u#h (" Fe

    :o N! Al T( (* B.

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    &o"'r$on o% D'ond$ 'nd ,r'"+t#

    Pro"#rt#$ D'ond Gr'"+t#

    Ph&"!#(l (*

    :he6!#(l

    e%& h(% 0Moh" 1?5

    Ele#t%!#(l !*"ul(to%

    :olo%le""

    Mo%e e*"e 'o%6

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    e%& "o't 0Moh" < 15

    Ele#t%!#(l #o*u#to%

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    Le"" e*"e 'o%6

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    Ao%*6e*t

    Sol! lu)%!#(*t

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    :%u#!)le"

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    H!gh "t%e*gth #o6-o"!te"

    Q

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    !.* Ot+#r '))otro"#$ (5 c'r(on

    F,ur# 1 -Allot%o-e" o' #(%)o*. (From top left)D!(6o* G%(-h!te A6o%-hou" #(%)o*

    S-he%!#(l 'ulle%e*e Ell!-"o!(l 'ulle%e*e Tu)ul(% 'ulle%e*e

    2

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    *.0 T+# U$',# o% D'ond 'nd Gr'"+t#

    Gr'"+t#

    The te#h*olog& to 6(*u'(#tu% g%(-h!te !*to 6ole g%(-h!te !" $e%"(t!le !6-%o$e6e*t" !* the

    6(*u'(#tu%!*g te#h*!ue" (%e #o*t!*uou"l& 6(e (* the "#o-e o' (--l!#(t!o*" !" g%(u(ll&

    e,-(*!*g. Th!" e,-(*"!o* !" the !%e#t %e"ult o' ( "!e()le %e"e(%#h e''o%t #(%%!e out )&

    6(*& +o%e%" !* u*!$e%"!t!e" go$e%*6e*t l()o%(to%!e" (* !*u"t%&. I* the l("t t+e*t& &e(%"

    o% "o "e$e%(l 6(o% (--l!#(t!o*" o' 6ole g%(-h!te h($e e$elo-e !*to (* !6-o%t(*t

    #o6-le, (* !$e%"e !*u"t%!(l 6(%et. Be#(u"e o' th!" !$e%"!t& the #l(""!'!#(t!o* o' the"e

    (--l!#(t!o*" !" ( #%!t!#(l '(#to% !' ( -%o-e% -e%"-e#t!$e o' the !*u"t%& !" to )e o)t(!*e.

    . A"")c'ton$ n t+# M#t') Proc#$$n, Indu$tr5

    G(( 012215 -o!*t out th(t o*e the l(%ge"t u"e o' g%(-h!te !" (" ele#t%oe" !* the -%ou#t!o*

    o' "teel !* ele#t%!#=(%# 'u%*(#e" 6o"tl& 'o% the %e#l(6(t!o* o' 'e%%ou" "#%(-. Th!" !" )e#(u"e

    g%(-h!te ele#t%oe" h($e goo ele#t%!#(l #o*u#t!$!t& goo %e'%(#to%& -%o-e%t!e" (* lo+

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    6ole g%(-h!te '%o6 -et%oleu6 #oe.

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    . &+#c') '"")c'ton

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    -ho"-ho%u" (* #(l#!u6 #(%)!e !* (%# 'u%*(#e". G%(-h!te !" u"e (" (*oe" !* "o6e (ueou"

    ele#t%ol&t!# -%o#e""e" "u#h (" !* the -%ou#t!o* o' h(loge*" 0#hlo%!*e (* 'luo%!*e.5

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    4. T+#ronc A"")c'ton$ 8Po6#r $u"")59

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    A(6" S. F. (* L(*"t%("" 012215 M. I. A--l!#(t!o*" o' D!(6o* F!l6" (* Rel(teM(te%!(l" 0. Te*g et (l. e".5 1=3, Elsevier cience Publishers

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    Clarendon Press, O!ford.

    H(6!lto* R. F. G(%g. D. ;oo K. A. (* Hoo$e% D. S 0122?5 P%o#. R(& :o*'. ol. 4

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    J. ;(le% 01225 O-t!#(l ()"o%-t!o* (* lu6!*e"#e*#e !* !(6o*. Re-. P%og. Ph&". 4901?5

    13?L. ;e! P.K. Kuo R.L. Tho6(" T.R. A*tho*& ;.F. B(*hole% 01225 The%6(l #o*u#t!$!t&

    o' !"oto-!#(ll& 6o!'!e "!*gle #%&"t(l !(6o*. Ph&". Re$. Lett. 00945

    M(*tell :. L 0123Q5 :(%)o* (* G%(-h!te H(*)oo 21 =494 "nterscience Publishers,

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    Re( P. G. 09??5. Ge66olog&.(utter$orth)*einemann. --. 42?.

    Se(l M. 012Q25 I*te%!"#!-l!*(%& S#!e*#e Re$!e+, 14015C34=3

    S-(!* I. L 0125 !* :he6!"t%& (* Ph&"!#" o' :(%)o*, 0P. L.;(le% (* P. A. Th%o+e%

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    ;(le% J. 01225. O-t!#(l ()"o%-t!o* (* lu6!*e"#e*#e !* !(6o*.'eports on Pro+ress in

    Physics!01?5C 13?132.

    ;u R. L G(%(#(e* A. (* Kee P. 012215--l!#(t!o*" o' D!(6o* F!l6" (* Rel(te

    M(te%!(l"0. Te*g et (l. e".5 3=?Elsevier cience Publishers

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