1

2

(t=0.995mm)

3

(1)

(t=0.995mm)

4

(2)

d

5

6

7

8

9

10

11

12

13

14

15

16

17

18

XAFS

ppm

1)

2,3)

4,5)

TEM

X

XAFS 6)

XAFS

X

XAFS

X

X

100

X

2013

XAFS

XAFS ppm

XAFS

19

7,8)

1 2

2

2

1

2

1

XPS

XAFS S-K XAFS

1g/L

3g/L 0.2g/L

0.1g/L

45 pH 4.2

3A/dm2 10μm

SK

10A/dm2 50 10μm

(S) K XAFS BL6N1

S-K XAFS

1 2 1

~2460eV

2530eV~

0 1

2482eV

2481eV

2479eV

+6

1 S-K XAFS

20

2471eV 2

-2

0

2

3

K XAFS

1 X 2550eV X

70ppm

210ppm 1800ppm

2520ppm

3

XAFS 2471eV

2482eV

1 2482eV

SO4

2482eV

2471eV

1

-2~0

4

8)

K 2469eV 9)

p-d

2471eV

4)

2471eV

SK

4

5

K XAFS

100ppm 520ppm

5 S-K

3 S-K

21

300ppm

2481eV

3

2471eV

2471eV 2481eV

2471eV

2471eV 2484eV

6

8) 2484eV

6

XAFS

XAFS

-K-edge XAFS

22

23

24

25

PPC NC(mNC)

26

27

28

29

(t ) SEM

(t ) SEM

30

31

32

(002) (020) (200)

33

34

35

36

37

1-1

1-2

38

39

40

41

CP Pt

42

0

5000

10000

15000

20000

25000

30000

arb.

eV

43

44

Transverse crack

Splitting

SplittingTransverse crack

45

2bh3PL

46

47

48

49

20 30 40 50 60 70 80

Inte

nsity

a.u

.

/deg.

P25 30 mass%

P25 40 mass%

40 mass%

30 mass%

20 mass%

P25 20 mass%

Anatase Ca3SiO5Rutile Ca3Al2O6CaCO3

50

N n-C8H17 n-C8H17

NMe2

n

OCN NCO

O OOCN

OHO H

OHO

OMe

OH

LTI

nnPLA

PCL

PImip-Fl

PLA wt% PCL wt% LTI /phr / nma

PLA-1 100 0 0 421PCL-1 0 100 0 438

PLA-L1 100 0 0.5 412PCL-L1 0 100 0.5 429Blend-1 90 10 0 436Blend-2 85 15 0 436Blend-3 70 30 0 436

Blend-L1 90 10 0.5 422Blend-L2 85 15 0.5 426Blend-L3 70 30 0.5 433

51

Me2Si

NMe n OCN NCO

O OOCN

HOO

H

O

Me HO

HO

O

n

PLA PCL nPPhenaz LTI

PLA

wt%PCLwt%

PPhenaz/phr

LTI/ phr

/kJm-2

PPhenaz

52

3

3

V3 NaCl

3 y

100 3

Dw NaCl

Ds Dw Ds

* **

*** ****

3

3

3

53

54

55

56

NH

NH

O

O O

ORf Rf

A

B

OO R4

R1

OR2O O

OR3O

O

RfO N

H

HN O

Rf

O

O

C

*R1-R

4 Rf

Rf = -CH2CF2O(CF2CF2O)2CF2CF2CF2CF3