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¡ w d %Ê'2 d - nmiri.city.nagoya.jp · ¤$Î/²1= e 6 Ñ É Û Ñ å µ w Ï Ü Ð î ç K S Ï...
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Transcript of ¡ w d %Ê'2 d - nmiri.city.nagoya.jp · ¤$Î/²1= e 6 Ñ É Û Ñ å µ w Ï Ü Ð î ç K S Ï...
1
2
(t=0.995mm)
3
(1)
(t=0.995mm)
4
(2)
d
5
6
7
8
9
10
11
12
13
14
15
16
17
18
XAFS
ppm
1)
2,3)
4,5)
TEM
X
XAFS 6)
XAFS
X
XAFS
X
X
100
X
2013
XAFS
XAFS ppm
XAFS
19
7,8)
1 2
2
2
1
2
1
XPS
XAFS S-K XAFS
1g/L
3g/L 0.2g/L
0.1g/L
45 pH 4.2
3A/dm2 10μm
SK
10A/dm2 50 10μm
(S) K XAFS BL6N1
S-K XAFS
1 2 1
~2460eV
2530eV~
0 1
2482eV
2481eV
2479eV
+6
1 S-K XAFS
20
2471eV 2
-2
0
2
3
K XAFS
1 X 2550eV X
70ppm
210ppm 1800ppm
2520ppm
3
XAFS 2471eV
2482eV
1 2482eV
SO4
2482eV
2471eV
1
-2~0
4
8)
K 2469eV 9)
p-d
2471eV
4)
2471eV
SK
4
5
K XAFS
100ppm 520ppm
5 S-K
3 S-K
21
300ppm
2481eV
3
2471eV
2471eV 2481eV
2471eV
2471eV 2484eV
6
8) 2484eV
6
XAFS
XAFS
-K-edge XAFS
22
23
24
25
PPC NC(mNC)
26
27
28
29
(t ) SEM
(t ) SEM
30
31
32
(002) (020) (200)
33
34
35
36
37
1-1
1-2
38
39
40
41
CP Pt
42
0
5000
10000
15000
20000
25000
30000
arb.
eV
43
44
Transverse crack
Splitting
SplittingTransverse crack
45
2bh3PL
46
47
48
49
20 30 40 50 60 70 80
Inte
nsity
a.u
.
/deg.
P25 30 mass%
P25 40 mass%
40 mass%
30 mass%
20 mass%
P25 20 mass%
Anatase Ca3SiO5Rutile Ca3Al2O6CaCO3
50
N n-C8H17 n-C8H17
NMe2
n
OCN NCO
O OOCN
OHO H
OHO
OMe
OH
LTI
nnPLA
PCL
PImip-Fl
PLA wt% PCL wt% LTI /phr / nma
PLA-1 100 0 0 421PCL-1 0 100 0 438
PLA-L1 100 0 0.5 412PCL-L1 0 100 0.5 429Blend-1 90 10 0 436Blend-2 85 15 0 436Blend-3 70 30 0 436
Blend-L1 90 10 0.5 422Blend-L2 85 15 0.5 426Blend-L3 70 30 0.5 433
51
Me2Si
NMe n OCN NCO
O OOCN
HOO
H
O
Me HO
HO
O
n
PLA PCL nPPhenaz LTI
PLA
wt%PCLwt%
PPhenaz/phr
LTI/ phr
/kJm-2
PPhenaz
52
3
3
V3 NaCl
3 y
100 3
Dw NaCl
Ds Dw Ds
* **
*** ****
3
3
3
53
54
55
56
NH
NH
O
O O
ORf Rf
A
B
OO R4
R1
OR2O O
OR3O
O
RfO N
H
HN O
Rf
O
O
C
*R1-R
4 Rf
Rf = -CH2CF2O(CF2CF2O)2CF2CF2CF2CF3
