Download - Use the terms homologous series and functional group. Understand the terms hydrocarbon, saturated, unsaturated. State that alkanes and cycloalkanes are.

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• Use the terms homologous series and functional group.

• Understand the terms hydrocarbon, saturated, unsaturated.

• State that alkanes and cycloalkanes are saturated hydrocarbons.

• Explain the tetrahedral shape around each carbon atom present in an alkane.

• State the names of the first ten members of the alkane homologous series.

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Carbon is bonded to four hydrogen atoms in methane

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The double bond between the two carbon atoms in ethene counts as two bonds

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The –OH group is the functional group, responsible for the reactivity of the molecule

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Molecular models of methane, ethane, propane and butane

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Aliphatic and alicyclic alkanes

• Understand and be able to use the IUPAC rules of nomenclature for naming hydrocarbons.

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Butane

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2-Methylpentane

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4-Ethyl-3-methylheptane

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2,2-dimethylbutane

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But-1-ene

• Understand and use the IUPAC rules of nomenclature for naming compounds with functional groups.

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1- Chloropropane

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Pentan-3-ol

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Butanal

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2-Bromo-1-chlorobutane

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2-Methylpropan-1-ol

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1,1,2,2-Tetrachloroethane

• Understand and use the following terms: empirical formula; molecular formula; general formula; displayed formula.

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Butane

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Propan-2-ol

• Understand and use the term structural formula.

• Understand and use the term skeletal formula.

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Displayed and structural formulae for (a) propane and (b) 1-bromopropane

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Displayed and structural formulae for decanoic acid

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Displayed and skeletal formulae of hexane

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Displayed, structural and skeletal formulae for (a) pentane and (b) 3-methylpentane

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Displayed and skeletal formulae for (a) cyclopentane and (b) cyclohexane

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Aromatic hydrocarbons

• Draw skeletal formulae for simple molecules containing functional groups.

• Draw and interpret the skeletal formula for complex molecules.

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Skeletal formula for pent-2-ene

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Skeletal formula for butan-2-ol

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Skeletal formula for pentanoic acid

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Paracetamol

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Retinol, vitamin A

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Salbutamol

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• Describe structural isomers, stereoisomers and E/Z isomerism, including cis–trans isomerism.

• Determine possible structural formulae and/or stereoisomers from a molecular formula.

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Structural isomers of C4H10

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Structural isomers of C3H8O

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Structural isomers of C3H6O

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E and Z isomers of CICH=CHCI

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E and Z isomers of but-2-ene

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E and Z isomers

• Describe the different types of covalent bond fission – homolytic and heterolytic.

• Define the terms: nucleophile; electrophile; radical; addition; and substitution.

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Addition reaction

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Substitution reaction

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Elimination reaction