Use the terms homologous series and functional group. Understand the terms hydrocarbon, saturated,...

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Use the terms homologous series and functional group. Understand the terms hydrocarbon, saturated, unsaturated. State that alkanes and cycloalkanes are saturated hydrocarbons. Explain the tetrahedral shape around each carbon atom present in an alkane. State the names of the first ten members of the alkane homologous series. Week 13 © Pearson Education Ltd 2008 This document may have been altered from the original

Transcript of Use the terms homologous series and functional group. Understand the terms hydrocarbon, saturated,...

• Use the terms homologous series and functional group.

• Understand the terms hydrocarbon, saturated, unsaturated.

• State that alkanes and cycloalkanes are saturated hydrocarbons.

• Explain the tetrahedral shape around each carbon atom present in an alkane.

• State the names of the first ten members of the alkane homologous series.

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Carbon is bonded to four hydrogen atoms in methane

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The double bond between the two carbon atoms in ethene counts as two bonds

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The –OH group is the functional group, responsible for the reactivity of the molecule

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Molecular models of methane, ethane, propane and butane

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Aliphatic and alicyclic alkanes

• Understand and be able to use the IUPAC rules of nomenclature for naming hydrocarbons.

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Butane

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2-Methylpentane

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4-Ethyl-3-methylheptane

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2,2-dimethylbutane

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But-1-ene

• Understand and use the IUPAC rules of nomenclature for naming compounds with functional groups.

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1- Chloropropane

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Pentan-3-ol

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Butanal

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2-Bromo-1-chlorobutane

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2-Methylpropan-1-ol

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1,1,2,2-Tetrachloroethane

• Understand and use the following terms: empirical formula; molecular formula; general formula; displayed formula.

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Butane

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Propan-2-ol

• Understand and use the term structural formula.

• Understand and use the term skeletal formula.

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Displayed and structural formulae for (a) propane and (b) 1-bromopropane

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Displayed and structural formulae for decanoic acid

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Displayed and skeletal formulae of hexane

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Displayed, structural and skeletal formulae for (a) pentane and (b) 3-methylpentane

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Displayed and skeletal formulae for (a) cyclopentane and (b) cyclohexane

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Aromatic hydrocarbons

• Draw skeletal formulae for simple molecules containing functional groups.

• Draw and interpret the skeletal formula for complex molecules.

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Skeletal formula for pent-2-ene

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Skeletal formula for butan-2-ol

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Skeletal formula for pentanoic acid

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Paracetamol

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Retinol, vitamin A

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Salbutamol

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• Describe structural isomers, stereoisomers and E/Z isomerism, including cis–trans isomerism.

• Determine possible structural formulae and/or stereoisomers from a molecular formula.

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Structural isomers of C4H10

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Structural isomers of C3H8O

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Structural isomers of C3H6O

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E and Z isomers of CICH=CHCI

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E and Z isomers of but-2-ene

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E and Z isomers

• Describe the different types of covalent bond fission – homolytic and heterolytic.

• Define the terms: nucleophile; electrophile; radical; addition; and substitution.

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Addition reaction

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Substitution reaction

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Elimination reaction