e eder associatesconsulting engineers, p. c.
N u O O Q Q 0 9 7OFFICES
FEDERAL EXPRESS
May 1, 1992File #497-4
Mr. Michael A. GiffordWaste Management DivisionMichigan/Wisconsin Branch
USEPA Region V77 West Jackson-HSRW6JChicago, IL 60604
Re: Monitoring Well SVOC Data,National Presto Industries, Inc.Eau Claire, Wisconsin
Dear Mr. Gifford:
Enclosed are the raw data tables for the results of SVOC analysisof groundwater samples collected from monitoring wells during theNPI site Remedial Investigation. Also enclosed is the datavalidation report for SVOC analysis of monitoring well samplescollected in December 1991.
Please advise if you have any comments or questions.
Very truly yours,
EDER ASSOCIATES CONSULTING ENGINEERS, P.C.
William M. WarrenVice President
WMW:clt
cc: J. Boettcher, WDNR (tables only)R.A. Nauman, NPI (tables only)
#L0501.mg
315 W. HURON STREET. SUITE 240. ANN ARBOR. MICHIGAN 48103 • (313) 663-2144 • FAX (313) 747-653O
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 D 3 3 3 3 3 3 3 < 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 D 3 3 3 D 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 < 3 3 3 3 3 3 3 - » 3 : 3 3 3 3 3 3o o o o o o o o o o o o o o o o g o o o o o o o o o e g o g o o o g o g g o o o o o w w o o o g o o i o o o o ^ o o n o o o o o o o
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 * 3 3 3 3 3 3 3 3 3 3 3 3 3 3
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 - > 3 3 D 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 - , 3 3 3 3 D 3 3 3 3 3 3 3 3 3 3 3 3 - , 3 3 3 3 3 3 3'
3 3 3 3 3 3 3 3 D 3 3 3 3 3 3 3 - » 3 3 3 3 3 D 3 3 3 3 3 3 3 3 3 3 3 3 3 D 3 D 3 3 3 3 3 3 3 3 3 D 3 < 3 3 3 3 3 3 3 - , 3 D 3 3 3 3 3
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 - » 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 D 3 3 3 3 3 3 3 3 3
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 l 3 3 3 3 3 3 3 3 3 3 3 3 3 3 D 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 - D 3 3 3 3 3 3 - , 3 3 3 3 3 3 3S S J J 2 J J 2 2 S S 5 S S J J w 3 2 S 2 2 2 S S 2 5 8 * 8 * * 2 8 * 8 8 2 2 2 2 * 8 8 2 2 * 8 2 * * * 2 2 2 S 5 S S < l l J 2 2 * J 2 2
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 - 1 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 ^ 3 3 3 3 3 3 3 - 1 3 3 3 3 3 3 3o o o o o o o o o o o o o o e s o o o o o o o o o o o o q o o o o o o o q q o o o o o3582258233 S 8 2 2 2 8 o o Z o o o o o o o o o o o
• 5.c — x ^ Q ° O = p ' 3 . f 5 ;
s 8 > i 5 s • s ^ - 5 « ' 5 8 S * - , , 5 ' " M S? I « M f L• * * * • ' S e - S f c e c - X c• J t - * ' 4 J i J i J i ? S J i
<fcWIW-SVOC.WK1
Monitoring WUta - RMU>U of tomt-VbiuH* AnalyM of Qroundw*Mr SvnptM (*g/n.
Analytto by Wadtwerth UbomtarlM.
WELL:
DATE SAMPLED:
TEMTATfVELY IDEHTIREO COU POUNDS
Nattontf PTMIO InduttrtM, Inc. an*EMJ Ctwra, M«oon«ln.
UW-01 MW-38 MW-M UW-3B
I oinana iI ____
I UW-3A-HE |
01/1WM | 01/1WM | 01/ta/M
UW-3C | UW-4 |
01/1B/M t 01/1WM I 01/20/M I
NonanaD*can«Sulfur. moL(S»)3-ohloro-Cy ctoh« mn*2-Cyoloh«un*-l -on*1 , 2-dlch toro- yeton ««an •4-hy droxy -nMl-2-P*n (anon*N,N-ei 2-hydr Dod*o*namJd*2-*thyM-H«»flol
AJdol Condensation Produol
o -tr™"4 *Dod«canoio addTOTAL 2-<2-«lhovy«tnoxy)-Eth«nolUNKNOWN ACIDUNKNOWN ALDEHYDEUNKNOWN CYCLOOOOECANETOTAL UNKNOWN HYDROCARBONUNKNOWN PHTHALATETOTAL UNKNOWN
— 20J— 80J— 70J_ __ __
_ __ __ _
— —
- -
- -
_ _
— —— 400 J— —— 400 J— 10120 J_ _
20BJ BMJB
——_
20 J20 J8HJ200 J
—
—
-
-
_
——
300 J———
240 JB
———
30 J30 JB90 J——
—
-
-
___
——
20 J_
440 J
_
—100 J—_——
30 J
—
_
-
_
————aoj—
100 J
——
40 J_
——_
—20J
-
10 J
20 J——————10J 20 BJ
* At»o known H 2.2*-oxybb(1-Chloroprop«n«)
I * -* r
M!
C C C C C C C C C C C C C C C ' C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C g
Io S S o o o o o o o o o o o o Z o S S o S o S B o o o o o S S o o o o S S o S o S o o o S o o o o S o S o o o o S o o o S o o S o SC C C C C C C C C C C C C C C ' C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C
IW W - « « « - - M W W W U - J 0 - « L , 0 - « - W M « M W M U O « U - W « M « « M C . U M W U « U « U U * *
C C C C C C C C C C C C C C C > C C c C C C c C ^ C C C C C c C c c C C c c C c c c c c c c c c c c C C C C C C C C C C C C C C C C g
I -cic
c c c c c c c c c c c c c c c > c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c €
i i --* -* -^ _ • _ . _ . - - - ^ ^ t l t * — tif - LI G
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cc c c c c c c c c c c c c c c S p C C c c c c c c c c : c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c ^
eE E E E E E E E E E E E E E E E E E E E E E |
S 3
Q:\MW-8VOC. WK1
Monitoring WtM - RMulM at S*ml- .Volute AflAlytM erf OroundwMw tanowt <*g/l).
Analyaia by Wadavonti Uboratork
WELL:
DATE SAMPLED:
Sullur, mol.(8l)
2-Cyotoh*Mfl»- 1 -on*1 .2-dlehtoro-Cydoh«Kan«4-nydroxy-4-fTMl-2-P*ntwton«N.N-bb(2-hydr OddwwnwnU*
S-m« thy t-2-H« xan on«Aldol Condan«kUon Product
Oodcowwlo *oklTOTAL 2-(2-«ihoKy«ihoxv)-€lh«nolUNKNOWN ACIDUNKNOWN ALDEHYDEUNKNOWN CYCLODOOECANETOTAL UNKNOWN HVDOOCAR8ONUNKNOWN PHTHALATETOTAL UNKNOWN
National PTMU InduatriM, Ino. 9MEMJ CUk», WMmonaM.
III 01/20M i oiraona i IO/IVM i IO/IHM i WIVM i IOMVU 10V12/W 10/12/U
TENTATIVELY IDENTIFIED COMPOUNDS
Nonan*
3BJ3J 3J
3J3J3J
3UJ<J
* Alto known M 2.2*-oxybl«41-Chloropropwi*)
aiuw-svoc.vuKi National PTMW lndu«trl«*. Inc. 3H«Eau Oak*. V«Mon*M.
Monitoring VtMUa - RMU!M o* 8a»nt-VoiaiiM Analy** <H QraundwMw tonptaa («/!).
Analytfe by Wad«
WELL
DATE SAW PLED:
Phanolbb(2-Chtoroainyl)athar2-Chlorophanol1.3-Olchlorobanzana1.4-Olchlorobanz*naBanzyl alcohol1,2-Otehlorobaniafia2-Uaihylphanolbta<2-Cnloroi«opropyl)atnaf *4-MathylphanolN-Nltroao-dl-n -propy iarnfnaHaxaohloroath an aNltrooanianakaophorona2-Nltrophanol2.4-Olmaihy Ip ha no*Banzok) acJdbla(2-Chkxoathoxy)(nathana2,4-Otohotorophanol1,2,4, -Trten loroban zan aNaphtnaiana4-CMoroanWn*Haxach lorobu tad la na4-Cn)oro-3-ma thy Iph anol2-Uainylnapntha>«naHauon lorocyolopan tad lana2.4,6-Trlchloraphano!2.4,5-Trtehkorophanol2-Chtofon aph tn aJ« na2-NltroanlllnaDimatnylphthalai*Aoanapthylana2, S-OI nl trotolu a na3-NllroanillnaAoanapthana2.4-Dlnitropnanol4~NltrophanolDlbanzofuran
Dlathylphthalala4-Ch loroprt an y l-p hany la lh«rFluoran*4-Nllroanllfn*4,8-Oin ltro-2-maih y Iph* notN-Nltroaod I p ha n y lamina4-Brofnoph any l-ph an y totnarHa xach loroban tan*Panuehlorop h*nol
Anthraoan*CwbazolaOl-n -B u ty I ph m alaiaRuoramhanaPyranaBu ty Iban zy Ip h th af aia3,3'-Otontofob«nzldlnaBan zo(a)an th raoan •Chrytanabta(2-ElhyttMDl-n-octylphlhalata
Banzo(a)pyr«naInd an o( 1,2.3-od )py r anaDlb« n z'a. h)«n th raca n*Ban zo(g, fi, i)pary tana
UW-6A
,2,10*1
10. U10. U10. Uto. u10. UNA
10. U10. U10. U10. U10. U10. U10. U10. U10. U10. UNA
10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U25. U10. U26. U10. U10. U10. U26. U10. U28. U28- U10. UM). U10. U10. Uto. u25. U26. U10. U10. U10. U2ft. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. Uto. uto. u10. U10. U
| UW-SB |
1 01/20/M |
tou10 Utoutou10 Utou10 U10 U10 U10 U10 U10 U10 U10 U10 Utousou10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Usou10 Usou10 U10 U10 Usou10 Usousou10 U10 U10 U10 U10 Usousou10 U10 U10 UsoutoutouNA10 U10 U10 U10 U20 U10 U10 U8UJ10 U10 U10 U10 U10 U10 UtOU
UW4B
1V11/H
3UJ3UJ3UJ3UJ3UJ3UJ3UJ3UJ3UJ3UJ3UJ3OJ3UJ3UJ3UJ3UJ14 UJ3UJ3UJ .3UJ3UJ3UJ3UJ3UJ3UJ3UJ3UJ14 UJ3UJ14 UJ3UJ3UJ3UJ14 UJ3UJ14 UJ
1 J3UJ3UJ-9J3UJ3UJ14 UJ14 UJ3UJ3UJ3UJ.•J3UJ3UJ
NA.7J3UJ3UJ3UJSUJ3UJ3UJ3UJ3UJ3UJ3UJ3UJSUJ3UJ3UJ
I UW-&B-RE |
| 10/1 1/M |
3U3U3U3U3U3U3U3U3U3U3U3U3U3U3U3U14 U3U3U3U3U3U3U3U3U3U3U14 U3U14 U3U3U3U14 U3U14 U
14 U
3U3U3U3U3U14 U14 U3U3U3U14 U3U3UNA3U3U3U3UOU3U3U3U3U3U3U3U3U3U3U
MW-6B
12f10/«1
10. U10. U10. U10. U10. UNA
10. U10. U10. U10. U10. U10. U10. U10. U10. U10. UNA
10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U28, U10. U26. U10. U10. U10. U26. U10. U25. U
25. U10. U10. U10. U10. U10. U28. U28. U10. Uto. u10. U25.U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U11. BJ10. U10. U10. U10. U10. U10. U10. U
1 UW-5B-flE
I IZMO/fll
10. U10. U10. U10. U10. UNA
10. U10. U10. U10. U10. U10. U10. U10. U10. U10. UNA
10. U10. U10. U10. U10. Uto. u10. U10. U10. U10. U26. U10. U26, U10. U10. U10. U25, U10. U26. U26. U10. U10. U10. U10. U10. U26. U26. U10. U10. U10. U26. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U11. BJto. u10. U10. U10. Uto. u10. Uto. u
OlMBrtt | 01/14/U
11 U11Unu11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 US4U11 U11U11U11 U11 U11 U11 U11 U11 U11 US4U
11US4U11 U11 U11 U64U11 U54U54U11 U11 U11 U11 U11 US4US4U11 U11 U11 U54U11 U11 UNA
11 Utl U11 Utl U22U11 U11 U3J
11 U11 U11 U11 UIt U11 U11 U
11 U11 Utl U3J
11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U56 U11 U11 U11 U11 UIt U11 U11 U11 U11 U11 US6U11 U56 U11 U11 U11 USAU11 U56 U
56U11 U11 U11 U11 U11 U56U5SU11 U11 U11 Uuu11 U11 U
NA11 U
11 U11 U11 U22U11 U11 U3J
n U11 U11 U11 UU UIt Utl U
O:\UW-6VOC. WKl
Monitoring Wtita - RMUIM of 8*ml-Votatte Antfytta at OrauMwMtr SvnptM (M/H.
Analyst by Wadawoflh UborUorlM.
WELL:
DATE SAMPLED:
TENTATrVELY IOENTIFIEO COMPOUNO8
National PTMM> IMutWtM. Irra. Sit*E«u CU«»,
MW-&A MW-U MW-4B
I 12/10/91 | 01/20/U
MW-M-RE | UW-OB | UW-4B-RE I UW-« | UW-7 |
10/1 Iffl* I 12/KW1 | 12nOr»1 | 01/18/M | 01/14/St I
Sulfur, mol.(SS)
S-m»(hyl-2-H* xanon*Aldol Cond*nMllon Produot
OounoleftcM
TOTAL 2-<2-«trioKy*lhaxy)-EthwiolUNKNOWN ACIDUNKNOWN ALDEHYDEUNKNOWN CYCLODOOECANETOTAL UNKNOWN HYDROCARBONUNKNOWN PHTHALATETOTAL UNKNOWN
I —I —I —
3J
4J
9J
3J
M.UJ
2*1J 16. J 20 BJ 20 BJ
nown u 2,2'-oxybi*(1-Criloroprof)Wi«>
a\UW-SVOC.WK1 Mto InduMriM. Ine. SIM, WaoonMn.
UontUring Vtfclto - RMuItt <* Swnl-Votull* AnarytM ot OraundwAttr SvnptM (M)")-
aworth LtbofMorhw.
WELL:
DATE SAMPLED:
Pnanolbla(3-ChloroainyO*tn«f2-Chkxophanol1 ,3-Olohlorobaniana1,4-OtohtorobanzanaBartzyl atoonol1,2-Otohlofobanzana2-MaUiylphanolbla(2-Chiorofaopropyr)aih«r *4-UatfiylphanolN-Nltfoao-dt-n-propylamlnaHaxaehtoroathan*Nltrobanzan*bophorona2-Nttrophanol2.4-OmalhylphanolBanzotoaoidbla(2-Cn lore* thoxy )ma than*2, 4-Diohokxopha nol1 ,2,4, -Trtah lorotoa nzan aNaphthalana4-CnloroanilinaHaxach lorobu tad iana4-Ch tor o-3-mathy Ipnanol2-UaitiylnapnthaJan«Haxaoh lorooyetopan tadlana2,4, 6-Trtoh lorophanol2.4, 6-Trteh lorophanol2-Ch kxonaph lhatan a2-NltroanlimaDimathylphthaJataAoanapthylana2,S-Dlnltrololuan«3-NitroanllinaAoanapthana2,4-Olnltrophanol4-NltrophanolDlbanzoturan2.4-DlnltrotoluanaDJaihyiphihaJaia4-Chkxoph an y l-p h an y la th arRuorana4-Nltroanmna4 , e-Dlnltro-2-m«tn y Iph an OlN-Nltroaod lp ha ny (ami na4-Bromop ha ny l-ph an y la th arHa xach loroba n zanaPantaoh lorophanolPhananthranaAnthracanaCaibazoiaDl-o-bu ty lp h m alataFlu or an tn anaPyranaBuiyloanzylphihalaia3. 3' -Dteh loroba n zkl 1 n aBa nzo(a»r) th raca naCnryaanabia(2-Eihylhaxyl)phihalataDi-n -octy 1 pn in oUiiaBa n zo(b)(1 u or an 1 h an aBan zoGO'1" °ran in anaBanzo(a)pyranalndano( 1 ,2,3-cd)pyranaDUMn z(a. h }an Iti raca naBanzo(g ,h , i)parylan«
UW-M
10/1 1/U
3U3U3U3U3USU3U3USU3U3U3U3U3U3U3U13 USU3USUSUSU3USUSUSUSU13USU13USU3U3U1SU31)13 U13U3U3U3U3U3U13 U13 U3U3U3U13U3U3UNA3U3U3U3USU3U3U2JU3U3U3USU3U3U3U
UW-a*-«
10/11/M
SUJ3UJ3UJ3UJ3UJSUJSUJSUJSUJSUJSUJSUJSUJSUJSUJSUJ13 UJ
SUJSUJSUJSUJSUJSUJSUJSUJSUJSUJ13 UJSUJ13USUJSUJSUJ13 UJ3UJ13 UJ13 UJ3UJ3UJ1 J
3UJ3UJ13 UJ13 UJSUJSUJSUJ13 UJSUJ3UJNA1 J
SUJSUJSUJSUJ3UJ3UJ2JU3UJ3UJSUJSUJ3U3U3U
| UW-10A |
| 10/21/87 |
10 U10 U10 U10 U10 U10U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Usou10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Usou10 Usou10 U10 U10 Usou10 Usousou10 U10 U10 U10 U10 U
SOURsou10 U10 U10 Usou10 U10 UNA10 U10 U10 U10 Usou10 U10 U10 U10 Utou10 U10 U10 U10 U10 U
UW-10A
01/20/M
11 U11 U
11 U11 U11 U11U11 U11 U11 U11 U11 U11 U11 U11 U11 U11U64U11U11U11U11U11U11U11U11U11 U11U54U11U64U11U11U11U64U11U64U54U11U11U11Ut lU11 U54U64U11 U11 U11 U54U11 U11 UNAtl U11U11 U11 U22U11 U11 U11 U11 U11 U11U11U11U11 U11 U
1 UW-10A-FB |
| Q1/20/M |
10 U10 U10 U10 U10 U10 U10 U10 Utoutou10 U10 U10 U10 Utou10US2U10 U10 U10 U10 U10 U10 U10U10 U10 U10 U62U10US2U10 U10 U10 US2U10 US2U52 U10 U10 U10 U10 U10 US2US2U10 U10 U10 US2U10 U10 UNA10 U10 U10 U10 U21 U10 U10 U10 U10 U10 U10 U10 U10 U10 Utou
MW-10A |
10/13/84 |
SUJSUJSUJSUJSUJSUJ3UJSUJSUJSUJSUJSUJSUJSUJSUJSUJ13 UJSUJSUJSUJSUJSUJSUJ3
SUJSUJSUJ13 UJSUJ13 UJ3UJ3UJSUJ13 UJSUJ13 UJ3J
3UJ1 J
3UJSUJ3UJ13 UJ13 UJ1 J
SUJ3UJ3J
SUJSUJNA.9JSUJ2J
SUJSUJ3UJ3UJ,8JU3UJ3UJSUJSUJSUJSUJSUJ
Mw-ioA-ne
10/20/88
3UJSUJSUJSUJSUJ3UJSUJ3UJ3UJSUJSUJSUJSUJ3UJ3UJSUJ13 UJSUJSUJ3UJ3UJ3UJSUJSUJSUJSUJ3UJ13 UJ3UJ13 UJSUJSUJSUJ13 UJSUJ13 UJ13 UJ3UJ3UJ3UJSUJ3UJ13 UJ13 UJSUJSUJ3UJ13 UJSUJ3UJNA3UJ3UJ3UJSUJSUJ3UJ3UJ3UJ3UJ3UJ3UJ3UJSUJ3UJ3UJ
1 UW-10B !
i ioni/i7 i
10 U10 U10 U10 U10 U10U10 U10 U10 U10 U10 U10 Utou10 U10 U10 Usou10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Usou10 Usou10 U10 U10 Usou10 Usousou10 U10 Utou10 U10 U
SOURsou10 U10 U10 Usou10 U10 UNA10 Utou10 U10 U20 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U
a:\UW-SVOC. WK1
Monitoring VMM - RMU!VoUUto Analytic erf OroundwMw SwnptM 0«/f>.
An*y«M by Vfed«worth UboritortM.
WELL:
DATE SAMPLED:
TENTATTVELY IDENTIFIED COMPOUNDS
Nontn*
iMttlM. Inc. 8H»Ecu CUr«. Wteoonwn.
I UW-OA | UW-OA-flE | MW-10A | MW-10A | MW-10A-FB | UW-1QA | MW-IOA-flC I UW-10B
| 1W11/M | 10/11/M | 1IW1/17 1 01/2Q/W 1 01/20/8* | 1Q/13/U | 10V20/M | KV21/S7
I
Sulhif. mol.{3*)3-chloro-Cyoioh* win •2-Cyotoh* xan*- 1 -or*i ,2-d»«hkxo-Cyctoh»x»ft»4-*>y d ro>y-4-m«l-2-P*n unon*
2-«thyl-i-H«xwiolS-m«thy(-2-H« xan on*Aided Cond«nMi)on Productoeunwth -Cy OowtrMHoxan •OeUnotawMOct*d»o*noki »oWOodAoanoto acktTOTAL 2-<2-«tnoxy«tnoxy)-Cfh«nolUNKNOWN ACIDUNKNOWN ALDEHYDEUNKNOWN CYCLOOODECANETOTAL UNKNOWN HYDBOCARBONUNKNOWN PHTHALAT6TOTAL UNKNOWN
3AJ
«J
3J
38J
SJ
* Atoo known M 2,2'-oxybk(1-Chlaropropan*)
O:\UW-SVOC.V*(1
Uonttoring W*H« - HMUIH of Swnt- .Voltttt* Analy** ot Oraundv««r SwnpWt Otg/l).
AnMyvto by VMdiworth UboraWriM.
WELL:
DATE SAMPLED:
Phanolbto<2-C2-Chloroph«nol
1 ,4-Otoh UroMnB*nzyt •loohot
bto<2-ChlorolMpropy<)«lh*r4-4iUthylpft«nolN-NUroM>-dl-n-propyl«mln«
Niirob«nz«n*(•ophoron*
2,4-Olm«tnylpn»nolttenzoloicid
2,4-Oteholofopt>«r>ol1 ,2,4, -Trtch kxob*n »n •Naphthaton*4-Chlofo«f>llln«H« MOh torot) u tad t«n«4-Ch loro-3-m«thy Ip h« no*a-*4» thy In «ph th «]««•H« «*oh loreoyeloptfltad l*n«2,4,0-Trtohkxopn«nol2,4.6-Trlehlofophanol2-Ch loronap h th«t«n«2-Nltro*nllln«DlfTwlhylphthaJAMAo«n«pihyl«n«2.6-Dlnltrololu«n«3-N!trowiil!n«Ac*napth«n«2.4-Olnilroph«nol4-NI1roph»nolDib*nzoluw>2,*-Otnitrot«u»n«
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10/21/17
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t 10/31/87 |
10 U10 U10 U10 U10 U10 Utoutou10 U10 U10 U10 Utou10 U10 Utousou10 U10 U10 U10 U10 U10 U10 Utou10 U10 Usou10 Usou10 U10 U10 Usou10 Usousou10 Utoutoutoutou
SOURsou10 U
10 U10 Usou10 U10 UNAtoutou10 U10 U20 U10 U10 U10 U10 U10 Utou10 U10 U10 U10 U
UW-10B
01/20/M
11U11U11U11 U11 Utl U11 U11 Utl Utl U11 U11 U11 U11 U11 U11 U54 U11 U11 U .It U11 U11U11U11 U11 U11 U11 US4U11 US4U11 U11 U11 US4U11 US4US4U11 U11 U11 Uit UIt U54U
64U11 U11 U11 U64U11 UIt UNA11 U11 U11 U11U22 U11 U11 U
15tl Utl U11 U11 U11 U11 U11 U
I MW-10B-O-U8O |1 ————— 1I 01/30/U |
NR23 UNA
23 UNR
23U23U23U23U23 UNR
23 U23 U23 U23 U23U110U23U23 UNR
23U23U23UNR
23 U23 U23 U110U23 U110U23 U23U23U110UNR
110UNR
23 UNR
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23 U23UNA
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UW-11A
01/1 S/M
10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Usou10 U10 U10 U10 U10 U10 U10 U10 Utoutousou10 Usoutou10 U10 Usou10 Usousou10 U10 Utou10 U10 Usousou10 U10U10 UMU10 U10 UNA
10 U10 U10 U10 U20 U10 U10 U10 U10 U10 U10 Uto u10 U10 U10 U
UWM1B I MW-13A | UW-12B
01/K/M | 01M6VM
10 U10 U10 U10 U10U10 U10 U10U10U10 U10U10 Utou10 U10 U10 Usou10 U10 U10 U10 U10 U10 U10 U10 U10 U10 UMU10 UMU10 U10 U10 UMU10 UsouMU10 U10 U10 U10 U10 UMUMU10 U10 U10 UMU10 UtouNA10 U10 U10 U10 U20 Utou10 Utou10 U10 U10 U10 U10 Utou10 U
11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11U11US3U11 U11 U11 U11 U11U11 U11 U11 U11 U11 U53U11 US3U11 U11 U11 US3U11 U53U53 U11 U11 U11 U11 U11 U63U63 Utl U11 UIt U53 U11 U11 UNA
11 U11 U11 UU U21 U11 U11 U11 U11 U11 U11 U11 Un U11 U11 U
11 U11Uit U11 U11 Un U11 Uit U11 U11 U11 U11 U11 U11 Uit Uit U7J
11 Uit U11 U11 U11 U11 U11 Uit U11 U11 U53 U11 US3U11 U11 U11 U63 U11 US3US3U11 Uit UM Un UU U&3US3Un U11 Un U63U11 U11 UHA11 Uit Uit Uit U21 U11 Un U11
11 U11 U11 U11 U11 U11 U11 U
O:\MW-SVOC. WK1
Monitoring VJWta - RMUM ol Sarnt-VoUUt* Anatyt* ol OrournhnMr Simplaa <M/Q.
Analytta by Wadaworth LaborttoriM.
WELL:
DATE SAMPLED:
TENTATIVELY IDENTIRED COMPOUNDS
Nonan*
National PTMIO IMuitriM, (no. SlwEau Cl«ir«. Wwoonaln.
UW-10B-D | MW-108-FB I MW-10B | UW-10B-O-USO I UW-11A I UW-llB | UW-12A I UW-128
10V21/17 | 10/21M7 | 01/2WM I 01/20/M | 01/1B/M | 01/1VU I 01J16/M I 01/18/M
Sulfur. mol.(S8)4-ch loro-Cyoloh»jMn«2-Cyolonax«n«- 1 -on*1 ,2-d leh loro-Cyotoh •tun*4-nydrONy-*-m»(-2-P*nunon«
6-mcth y l-2-H« xanon*Aldol CondMMtlon Productocum«ih -Cy dot* irMiloun*
OcUd»c»nok) *cM
TOTAL 2-{2-»thoxy«thoxy)-eth«no(UNKNOWN AGIOUNKNOWN ALDEHYDEUNKNOWN CYCLODOOECANETOTAL UNKNOWN HYDROCARBONUNKNOWN PHTHALATETOTAL UNKNOWN 40 BJ 20 BJ 20 SJ 20 BJ
* Al«o known ai 2.2*-oxybk»(1-Chloropropvi*>
If^?*ifi4 >
C C C C C C C C C C C C C C C ' C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C
C C C C C C C t - C C C C C C C ' C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C t - C C C C C C C C C C C C C C C C
c c c c c c c c c c c c c c c ' c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c
c c c c c e c ' - c c c c c c c ' c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c t - c c c c c c c c c c c c c c c c
o o o o O O o ^ o o O o o o o Z o o S o o o o b o o o o o S S o S o o O O O O o o o O o O O O o a S o o o o o o o S o o o S o S o Sc c c c c c c ' - c c c c c c c ' c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c
C C C C C C C C C C C C ? c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c
OSUIW-SVOC.WKI National PTMIO IndutiriM. Ino. SIMEau CUir*. Wtioonttn.
VoltttU AnMytta ot OraundwcWr SvnplM (pQ/l).
Anoly*ta by Wad«wcrth LaboratoriM.
WELL:
DATE SAMPLED:
TENTATIVELV IDENTIFIED COMPOUNDS
NonwMD«cwwSulfur, mol.(Sa>3-cMora-Cvetoh*mn»2-Cyotah«K*n»- 1 -on*
k>h«»n*t-2-P*n unon •
yW-138 I UWM6A
I OV1VH
I ______
UW-108 | MW-17B | UW-178 I MW-17B-RE ! UW-11 I
ot/i«« i of/wu i IWIO/M i KVIO/U i tonivu i
S-m»th y(-2-Aldol Cond*nMi»on Product
TOTAL 2-(2-*mo«y«tnoxy)-ElhanolUNKNOWN ACIDUNKNOWN ALDEHYDEUNKNOWN CYCLOOOOECANETOTAL UNKNOWN HYDROCARBONUNKNOWN PHTHALATETOTAL UNKNOWN
3J
10J
10 J
30 J
3J
20 BJ
• At»o known «• 2,2'-oiiybl«<l-Chtoroprop*n«)
Mf ? 1 S I *11 • 1115 0 2 ? "i! s!5
O |.
IIp j T j £ ) p > 5 y
!f3
ius H= 8fs I
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2 5 & ??*5 ?
5 S e S2. * •< 8
t 5S . ?S 2 § I I551if I 57 7 g
Hf3 ? *
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C C C C C C C C C C C C C C C > C c £ c C c £ c c c c c c C c c £ c C c £ c £ c C C C C C C C C c £ c C C C C C C C C C C C C C C C 8 »
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_ _ _ _ _ _ _ _ o
C C C C C C C ^ C C C C C C t > C C c C C C c c C c 2 c C c c c C c c c C ^ C c c c C C C C C C C c C C C C C C C C C C C C C C C C
Ee
Kc c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c ' c c c c c c c c c c ' c c c c c
Ic c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c ' c c c c c c c c c c ' c c c c c
Ic c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c ' c c c c c c c c c c c c c c c 5
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Uonttorlne VMM - RMUH* ol S*mi- ,VotatH* Analyita ol OraundwMM SwnciM Oe/1).
NMIond PTMIO InduvtrlM. ln«. Sh*
Analytli by Wada
WELL:
DATE SAMPLED:
TEffTATIVELY IDENTIFIED COMPOUNDS
NonamDMWMSuitor, mol.(SS)3-oh tore-CydotM wn«2-Cyeloh*nn*-i -on*1 ,2-dlchloro-Cyeloh«xan«4-hy d rox|f-«-m«t-2-P«n unon*N.N-bb<2-hydr2-«thyl-1-H«)unol
UW-1»-AE
I IQflOVUI ______
UW-24A
1Q/1Q/U
UW-24A-AE
1W1WM
UW-2S I UW-25-RE— • I '
10n2TM | 1W12/M
UW-3&A
12/0a»1 I 12/1 IflM
Aldol Condensation ProductooUm* th-Cydo»ir»tHo«*ii»
Dod»oanolo aoMTOTAL 2-(2-«Ihoxr»trK»(v)-Eth«nolUNKNOWN AGIOUNKNOWN ALDEHYDEUNKNOWN CYCLODODECANETOTAL UNKNOWN HYDROCARBONUNKNOWN PHTHALATETOTAL UNKNOWN
3J 3J
2.JN 2.JN
SJ
• Atao known u Z.
Q:\MW-SVOC. IftKI
UonRorlng W»Ht - R»*utU ol Swni-Voiaiito Analytic of Qroundwottr SamplM (*e/Q.
Anaiyifc by W»dMWth LaboralortM.
National PTMU InduitriM. live. SIMEau Oak*. VMMOn»tn.
WELL:
DATE SAMPLED:
Phanolbb(2-Chloro*thyl)*ih*f2-Chloroph*nol1 ,3-Dtoh lorob*n i*n*1 ,4-Otoh loroto*n i*n*B*nzyl alcohol1 ,2-Ok* loroMn z«n«2-U*thylph«nolbto<2-Chk>»ol*opfopyf)*in*r •4-M*thylph*nolM-NlUoao-dl-n-prooykamM*H* xachloro* than*NI1rob*nz*n*l*ophoron*2-Nltroph*nol2.4-Oim*lhylph*nolB*nioloaoldb l*(2-Ch tor o* ihoxy)m*th an*2,4-O)chotoroph*nol '1 ,2.4, -Trtoh loroMn z*n*N«phthal*n*4-ChloroanUln*HKaohlorobutadfen*4-Ch kxo-3-m* thy lph*nol2-U«Chylnaphttial*n*H« xaoh km>cyolop*n tad l*n*2,4,8-Trlohloroph*nol2.4,6-Trlohloroph«nol2-Ch kxonaphthal*n*2-NltroanlUn*Dtm«lhylphth*J*t»Ac*naplhyl«n«2, 0— Din itrotd u • n •3-NluoAnllln*Ao*napth«n*2, 4-Otri Itroph *nol4-Nltfoph*nolDfb*nzofuran2, 4- Din llrotolu* nmDtotnylphthalau4-Ch toroph *ny l-p h • n y k th *rFluoran*4-NIUoanllln*4,6-Dlnitro-2-m«thylph«nolN-Nitro*od Ip h*ny lamln*4-Bromoph *n y l-p h*ny 1* rh*rH*xaoh torob*n z*n*P*n uoh kxop n *nolPti*nantnr«n»Anthrac*n*Caibazol*Di t-butylphihal«t*Fluor an th*n*Pyt*n*Butylb*nzylphthalal*3, 3' -Olch lorob*n zid In •S»n zo(a)an (h rac*n •Chryftn*bl»(2-Eihylh«icy l)ph lhaiat*Dl-n -octy 1 ph th alawB* n zo(b)ll u or«n Ih «n •B* n io(k )f luoran th»n •B*nzo(«)pyr*n*lnd*no(i ,2,3-od)pyi»n»Ol b*n z< a. h Jan th rac* n«B*nzo<g,h.i)paryt*n*
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12/11/91
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10. U10. U10. U10. U10. UNA
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10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U26. U10. U26. U10. U10. U10. U26. U10. U26. U26. U10. U10. U10. U10. U10. U28. U28. U10. U10. Uto. u26. U10. U10. U10. U10. U10. U10. U10. U
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12/11/91 |
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10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U28. U10. U28. U10. U10. U10. U26. U10. U26. U26. U10. U10. U10. U10. U10. U28. U26. U10. Uto. u10. U26. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. Uto. uto. u10. U10. U10. U
uw-*a* i——— 11&1V91 |
10. U10. U10. U
• 10. U10. UNA
10. U10. U10. U10. Uto. u10. U10. U10. U10. U10. UNA
10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U28. U10. U28. U10. U10. U10. U28. U10. U26. U28. U10. U10. U10. U10. U10. U26. U26, U10. Uto. u10. U28, U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U0.9 J10. U10. U10. U10. U10. U10. U10. U
UW-43B
12MW»1
10. U10. U10. U10. U10. UNA
10. U10. U10. U10. U10. U10. U10. U10. U10. U10. UNA
10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U26. U10. U26. U10. U10. U10. U26. U10. U26,1126. U10. U10. U10. U10. U10. U28. U26. U10. U10. U10. U25. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U0.6 J10. U10. U10. U10. U10. U10. U10. U
MW-42A |
12/13/91 |
10. U10. U10. U10. U10. UNA
10. U10. U10. U10. U10. U10. U10. U10. U10. U10. UNA
10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U28, Uto. u28. U10. U10. Uto. u26. U10. U26. U25, U10. U10. U10. U10. U10. U26. U28. U10. U10. U10. U26. U10. Uto. u10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. Uto. uto. u10. U10. U10. U
UW-628
12/13/B1
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10. U10. U10. U10. U10. U10. U10. Uto. u10. U10. UHA
10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U28, U10. U28, U10. U10. U10. U28. U10. U28. U26. U10. U10. U10. U10. U10. U26, U28. U10. U10. U10. U25. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. Ua. j
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I 12M3/91
10. U10. J10.lt10. U10. UHA
10. U10. U10. U10. U10. U10. U10. U10. U10. U10. UHA
10. U10. U10. U10. U10. U10. U10. U10, U10. U10. U26. U10. U25. U10. U10. U10. U26. U10. U28. U26. U10. U10. U10. U10. U10. U
2S.U28. U10. U10. U10. U26. U10. U10. Uto. u10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. Uto. u10. U10. U
O:\MW-8VOC. WKl
Uenttartng W*lto - AMUIM o( 8*mt-VoUtM* An*Jy*ta of Qraundmuw 9«mplM Ov/Q-
An«*r«ta by WMtworth UborMOriM.
WELL:
DATE SAMPLED:
NMtontf PTMIO IndutirtM, loo. SlttEau CUfa*. Wiocntin.
UW-3BC-AE I HW-40A MW-43B MW-«2A | UW-62B | MW-&2B-RE
TEHTATIVELY IO€NDFIED COMPOUNDS
Nonwt*
Sulfur,3-oh lero-Cy oW»»
Atdoi CondcniaUon Productoctwncth -Cy otatcff Mil
Oct*d«*no*o addOod»o«noto acidTOTAL 2-<2-«thoxy»lhoxy)-£th«iiolUNKNOWN ACIDUNKNOWN ALDEHYDEUNKNOWN CYCLODODECANETOTAL UNKNOWN HYDROCARBONUNKNOWN PHTHALATETOTAL UNKNOWN
45 JM.US.J
44 J
120 U
12J 303 J
• AJ*o known M 2.2>-oi(ybl*<1 -Chloropropwt*)
n 'o
n 'Oin 'oin 'oin -oin 'Oin'oin'oin 'oin 'oin 'oin 'oin 'oin "szn-oin~otn'oi
n -szn-oi
n'oin'oin'oin-»zn'szn'oin-stn'oi
n'oin'szn-oi
n'oi
n-OL1
n'oin'oin'oin'oin-oi
n-o!VN
n'oin-oin-oin'oi
n-S!
n'OL
n'oiVN
n'oin'oin'oin'oin'oi
I taaijzi I
n 'oin'oin -oin'oin'oin'oin'Oin'Oin'oin'oin'oin'oin'szn'oin-oin-oL
n'szn 'oi
n'oin'oin'oin'szn-szn'oin'szn'oi
n'oin'szn'oi
n'oi
n'oin'oin-oin-oin'OLn'oi
n'oiVN
n'OLfl *OLfl '01n'oin'oi
n'oi
n'oiVN
n'oin 'oin'oin'oin-oi
ie/u/zi
1 O-BC-MH
n'oin'oin'oin'oi
n'oi
n-oin'oin'oi
n'oin'oin'oin'oin'oin'oi
n'szn'oin'oin'oin'szn -92
n'oin'oin'oin'sz
n'oin'szn'oin'oin'oin'szn-oi
n'oin-oin'oin'oin-oin~oin'oin'oin'oi
VN
n'OLn'oi
n'oi
n'oiVN
n'oin'oin'oin'oin'oi
I iwuffL II ———— iI BC-MH I
n'oin'oin'oin'oin'oin'oin'oin'oin~oin'oin'oin'oin'oin'oin'oin'oin'oin'szn'oin'oin'oin'szn'szn'oin-oin'oin'oin'oin'szn'szn'oin'szn'oin'oin-oin'szn'oin-szn'oin-oin'oimnn'OLn-oin'oin'Oin'oin'oiVN
n'oin'otn'oin'oin'oin'oin*oin'oin'oin-oiVN
n'oin'oin'oin'oin'oi
Hill..
VC-MU
n'oin'oin'oin'oin'oin'oin'oin'oin'oin'oin'oin-oin'oin'oin'oin'oin-oin'oin*szn'OLn'oin'Oin'szn'szn'oin'oin'oin-oin-oin'szn'szn-oin-sen'oin'oin'oinwn'oin'szn'oin'oin'oin'OLn'OLn*oin'oin-oin-oin-oiVN
n'oin'OLn'Oin'oin-oin'oin'oin'oin'oin'oiVN
n'oin'oin'oin'oin'oi
i i«uei i
1 3U-OW-MH 1
n'oin'oin'oin'otn'oin'oirroin'oin'oin'oin'oin'oin'oin'oin'oin'oin'oin'oin-szn'oin'otn'OLn'szn-szn "OLn'oin-oin'oin'oin-szn'szn'OLn'szn'oin'oin'oin-»n'oin'szn'oin'oim»n'oin'oin'oin'oin'oin'oin'oiVN
n'oin'oin'oin'oin'oin'oin'oin'oin'oin'oiVN
n'oin-oin'oin*oin'oi
IMiei 1——— 1OW-MFt 1
n'oi
n'oin'oin~oin'oin'oin 01n'oin'oin'oin'oin'oin'oin'oin'oin'oin-oin-szn'oin'oin'oin'szn'szn 'oin'oinpoin'oin'oin'szn'szn'oin'szn'oin'oin'oin-sen'oin-szn'oin-oin'oin'oin'oin-oin'oin'oin'oin'oiVN
n'oin'oin'oin'oin'Oin'oin-oin'oin'oin'oiVN
n'Oin'oin'oin'Oin'oi
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SUMMARY OF THE ANALYTICAL DATA VALIDATIONFor Samples Collected at theNational Presto Solvent Site
Semivolatile and PCB AnalysesWater Samples Received: December 13th & 18th, 1991Sample Delivery Group: MW34ALaboratory Reference Numbers:
MW34A 34318MW34B 34319MW5A 34321MW5B 34322MW38A 34323MW38B 34324RW3A 34325RW3B 34326RW3B Field Blank 34327RW3BD 34328RW2C 34329MW54A 34330MW54B 34331MW54C 34332MW38A 34333MW52A 35238MW52B 35239MW43A 35241MW43B 35242
Water samples were received for semivolatile organic and PCB analyses for theTCL analyte list. The analyses were performed according to the requirements of3/90 EPA CLP Statement of work.
Data Validation Summary
No problems were found with the data that would significantly affect theusability with the following exceptions:
Semivolatile Organics
Five samples (MW5B, RW3C, MW54C, MW38C and MW52B) hadsurrogate recoveries less than the acceptable quality assurance rangein the original analysis. These were re-extracted on December 27th,
fourteen days after receipt by the laboratory. All surrogates werewithin the acceptable range with the exception of two surrogatesassociated with samnle 54C.associated with sample 54C
All of the target compounds detected in both the initial and reanalysisof these five samples were negated due to the presence of thecompounds in the associated method blanks. The concentrations ofnon-target compounds reported in all five samples was generally tentimes greater in the initial analysis than in the reanalysis. The non-target data from the reanalyses may have been degraded due to thetime required for re-extractions.
All target compounds that were detected in the samples were negatedor qualified due to their presence in the associated method blank.
RGB's
Both TCX (33%) and DCS (20%) were less than the 60% advisory limit insample RW3A. The TCX recovery was within the acceptable range (70%)for the filed duplicate of this sample.
DCS recoveries were less than the advisory limit in samples MW34B(34%), MW43B (55%). and RW3BD (33%).
Very low concentrations of RGB's may have been overlooked in thesesamples.
No other problems were detected which would significantly affect the use ofthe data.
Sample Collection and Receipt
The samples which were received on 12/13 were collected from 12/9through 12/11. Those that were received on 12/18 were collected from12/13 through 12/16. All end users of the data should be aware of thetime between sample collection and receipt by the laboratory.
SEMIVOLATILE ORGANICS
A complete analytical data validation was performed based upon thefollowing parameters:
* - Chain of Custody* • Data Completeness* - GC/MS Tuning
- Holding Times- Calibrations
* - Laboratory Blanks* - Field Blanks
- Surrogate Recoveries* - Internal Standard Recoveries
- Matrix Spike / Matrix Spike Duplicate* - Compound Identification* - Compound Quantitation* - Method Detection Limits
* - Indicates that all criteria were met for this parameter.
Holding Times
All samples were originally extracted and analyzed within the requiredholding time from sample receipt. The five samples with low surrogaterecoveries were re-extracted on December 27th, fourteen days afterreceipt by the laboratory.
Calibrations
The initial calibration was performed three months prior to the analyses ofthe samples of this delivery group.
All initial and continuing calibration requirements were met with theexceptions of the % Difference requirements for a few of the targetcompounds. These are noted in detail in the data validation worksheets.None of these were detected in any of the samples of this delivery groupwith the exception of bis(2-ethylhexyl)phthalate. This compound wasnegated in the majority of the samples due to its presence in theassociated method blank. In the two instances where it was not negated,it was flagged with the "J" qualifier and footnoted with #15. Thiscompound will not affect the end use of the data.
Surrogate Recoveries
All surrogate recoveries were within the acceptable range with thefollowing exceptions:
Sample MW38C: There was no recovery of three of the four acidsurrogates in the original analysis. All surrogate recoveries werewithin the acceptable range when the sample was re-extracted andreanalyzed . A 30% recovery was obtained for the phenol-d5surrogate in the reanalysis. This was flagged with the "*" qualifier inthe surrogate summary form (page 2). This recovery is within thestandard acceptable QC range of 10% to 110%.
Samples MW52B, MW5B, and RW3C: The recovery of two acidsurrogates was below the acceptable quality assurance range for all ofthese samples in the original analyses. All surrogate recoveries werewithin the acceptable range when the samples were re-extracted andreanalyzed.
Sample MW54C: The recoveries of three of the four acid surrogateswere below the acceptable quality assurance limits in the originalanalysis of this sample. The samples were re-extracted andreanalyzed, but there was still no recovery of the phenol-d5 surrogate,and only a low recovery (13%) of the 2-chlorophenol-d4 surrogate.The problems with the surrogate recoveries may be due to problemswith the sample matrix. Low concentrations of acid extractablecompounds may not have been detected in this sample.
Matrix Spike / Matrix Spike Duplicate
Sample MW5A of this sample delivery group was used for the MS / MSD.All recoveries and RPD's were within the acceptable range.
Method Blanks
Two method blanks were associated with the initial extraction of thesamples of this delivery group. One method blank was associated withthe 12/27 re-extraction of the five samples with the poor surrogaterecoveries.
Four target compounds were generally detected in the three methodblanks (1,2-dichlorobenzene, 1,2,4-trichlorobenzene, di-n-butylphthalateand bis(2-ethylhexyl)phthalate). All were negated according to thegeneral ERA data validation guidelines when they were detected in thesamples (with the exceptions of two instances of high concentrations of
bls(2-ethylhexyl)phthalate)). These are noted in detail in the datavalidation summary table.
Field Blank
One field blank was collected on December 11th for the samples of thisdelivery group. Low concentrations of 1,2-dichlorobenzene, 1,2,4-trichlorobenzene, di-n-butylphthalate and bis(2-ethylhexyl)phthalate weredetected. All were negated since they were detected in the associatedmethod blank.
Sample Results
Concentrations reported on the sample quant sheets were concentratedby a factor of 2 over the reported value.
Sample RW3B and RW3BD were reported as having the same laboratoryreference number on FORM I. Separate GC/MS file numbers werereported and they were identified separately in the SDG narrative. Thelaboratory was not asked to reissue the forms.
Sample MW38C: There was no recovery for three of the four addsurrogates in the original analysis. All surrogate recoveries were withinthe acceptable range when the same was re-extracted and reanalyzed .A 30% recovery was obtained for the phenol-d5 surrogate in thereanalysis. This was flagged with the "*" qualifier in the surrogatesummary form (page 2). This recovery is within the standard acceptableQC range of 10% to 110%.
Samples MW52B, MW5B, and RW3C: The recoveries of two acidsurrogates were below the acceptable quality assurance range for all ofthese samples in the original analyses. All surrogate recoveries werewithin the acceptable range when the sample was re-extracted andreanalyzed.
Sample MW54C: The recoveries of three of the four acid surrogateswere below the acceptable quality assurance limits in the original analysisof this sample. The samples was re-extracted and reanalyzed but therewas still no recovery of the phenol-d5 surrogate, and a low recovery(13%) of the 2-chlorophenol-d4 surrogate. The problems with thesurrogate recoveries may be due to problems with the sample matrix.Low concentrations of acid extractable compounds may not have beendetected in this sample.
PCB ANALYSES
A complete analytical data validation was performed based upon thefollowing parameters:
* - Data Completeness* - Holding Times
- Surrogate Recoveries* - Florisil Cartridge Performance Check* - Analytical Sequence
- Initial Calibration* - Absolute Retention Times* - Performance Evaluation Mixture* - Resolution Check Mixture* - Continuing Calibrations* - Instrument Blanks* - Preparation Blanks
- Field Blanks* - Matrix Spike / Matrix Spike Duplicate* - Compound Identification* - Compound Quantitation* - Method Detection Limits* - Sample Results
* - Indicates that all criteria were met for this parameter.
Only data from the primary column was reviewed since patterns of PCB's werenot detected in any of the samples.
Surrogate Recoveries
Both TCX and DCB were used as surrogates, and recoveries weredetermined for both the primary and confirmation columns. All recoverieswere within the acceptable range in the primary column with the exceptionof:
Both TCX (33%) and DCB (20%) were less than the 60% advisory limitin sample RW3A. The TCX recovery was within the acceptable range(70%) for the filed duplicate of this sample.
DCB recoveries were less than the advisory limit in samples MW34B(34%), MW43B (55%), and RW3BD (33%).
Very low concentrations of PCB's may have been overlooked in thesesamples.
Matrix Spike / Matrix Spike Duplicate
Sample MW38A of this sample delivery group was used for the MS /MSD. The sample was spiked with the six standard pesticide TCLcompounds. All recoveries and RPD's were within the acceptable range.Some of the concentrations obtained during the validation were slightlydifferent than those reported by the laboratory. The differences betweenthe two values were not significant.
Preparation Blanks
Two preparation blanks were extracted with the samples of this deliverygroup. One was associated with the samples extracted on 12/19 and theother with the samples extracted on 12/19. Arodors were not detected ineither of the blanks.
Data Summary TableNation* Praato SolvantSlto
PeeooUe end PCB AnetyeoeWater Sample* Receive* 1V13/Q1Sample Delivery Group: MW34A
Sample / Anaivte
MethodBlankCone.fPPB)
ReportedCone.(PPB)
QAVaUdattonReported
Cone.DacWon
QualHter* FootnotM
Sample HW3B Field Blank (Lab ft 34327)
Semlvolatile Organic*1,2-Dtchlorobenzene1,2,4-TnchtorobenzeneDi-n-butyl phlhalatebia(2-ethylhexyl)pnthataiB
Non-Target Semlvolatile Organic*None Detected
PCS'*None Detected
2 J0.6 J
1 J0.5 J
3BJ0.9 BJ
2BJ3 BJ
3 BJ0.9 BJ
2BJ3BJ
negatenegalanegatenegate
1111
SvnpleBMOaA (Lab #: 34318)
Samlvolatlle Organic*Di-n-butytphthataM
Non-Target Semlvolatile Organic*EtnanoJ, 2-{2-«tnoxy«thoxy)- (6.60)
PCB'*None Detected
1.0 J
ND
0.6 JB
2 JN
0.6 JB
2JN
negate
Sample MW348 (Lab #: 34319)
Semlvolatile Organic*None Detected
Non-Target SemlvotatHe Organic*Unknown (4.40)Ethanol, 2-(2-etnoxy«hoxy)- (6.60)
PCS'*None Detected
NDND
2 J2 JN
2 J2 JN
Sample MW38A (Lab #: 34323)
Semlvolatile Organic*1,2-Otchlorobenzene1,2,4-TrichtorobenzeneDi-n-butyl phthalatebis(2-ethylhexyl)phthaJate
2 J0.6 J
1 JO.S J
2 JB0.5 JB0.5 JB0.5 JB
2 JB0.5 JB0.5 JB0.5 JB
negatenegatenegatenegate
1111
Paget
Non-Target Senrtvoiattt* Organic*Unknown (22.00) [Sub*t Benzene]
PCB'eNone Detected
NO a j 6J
Sample MW38B (Lab*:34324)
Semlvolatlle Organic*None Detected
Non-Target Semlvolatlle Organic*None Detected
PCS'*None Detected
Sample MW38C (Lab #: 34333)
Semfvdattle Organic*bw(2-*thylhexy1)phthala»
Non-Target Semlvolatlle Organic*Unknown (6.9)Unknown (7.6)Unknown acid (8.6)Unknown (9.4)Unknown acid (10.5)Unknown (11.5)Unknown (13.2)Unknown (13.3)Unknown (13.6)Unknown (19.0)Unknown (19.9)Unknown (22.7)Unknown (25.9)
0.5 J 12 B 12 B J
NDNONDNDNONDNDNDNDNDNDNDND
32J280 J33 J53 J12 J3J7 J
10 J2 J8 J
10 J6 J5 J
481
32 J280 J33 J53J12 J3 J7 J
10 J2J8 J
10 J6 J5 J
qualify 3,15
Sample MW38C Re-Extracted 12/27
SemlvoJatil* Organic*1,2-Otehtorooenzene1,2,4-TrichiorobenzeneDi-n-butyl phttialatebis(2-ethythexyl)phthalate
Non-Target Semlvolatlle Organic*Unknown (6.0)Ethanol. 2-(2-ethoxyethoxy)- (6.4)Unknown acid (10.1)Unknown (11.2)Unknown (12.9)Unknown (18.6)Unknown (19.5)Unknown (22.3)Unknown (25.5)
PCS'*None Detected
2 J0.7 J
2 J1 J
2 BJ0.5 BJ0.6 BJ
8BJ
2BJ0.5 BJ0.6 BJ
8 BJ
negatenegatenegatenegate
1111
12 J50 J
NDNDNONDNONDND
14 JB68 JBN5 J2 J
12 J6 J6 J4 J2 J
37 Total
14 JB68 JBN5 J2J
12 J6 J6 J4 J2 J
negatenegate
Page 2
Sample MW43A (Lab*3*41)
SemtvohNHe Organioabis(2-etny1hexyl)phthala»
Non-Target Semivoladle Organic*None Detected
PCS'*None Detected
10 U 0.9 J 0.9 J qualify 15
9amptoMW43a (Lab #: 34342)
SwnrvoJatil* Organic*bis(2-ethytnexy1)pnlhalate
Non-Target Semlvolatll* Organic*None Detected
PCB'*None Detected
10 U 0.5 J 0.5 J qualify 15
Sample MWS2A (Lab ft 35238)
Semlvotatlle Organic*None Detected
Non-Target Semlvolatlle Organic*Unknown (5.3)Unknown (16.3)Unknown (22.7)
PCS'*None Detected
NDNDND
5 J5J2 J
5 J5 J2 J
Sample MW52B (Lab #: 35239)
Semlvoietlle Organic*bis(2-ethylhexyt)prithalato
Non-Target Semlvolatile Organic*Unknown (5.0)Unknown (6.3)Unknown (7.2)Unknown (9.2)Unknown (19.8)Unknown (22.7)
10 U 8 J 6 J
NDNDNDNDNDND
14J4 J
270 J4 J8J3J
14 J4 J
270 J4J8 J3 J
qualify 15
Sample MW52B Re-Extracted 12/27
Semlvolatile Organic*1,2-Dlchtorobenzene1,2,4-TnchlorobenzeneDi-n-butyl phthalatebia(2-etnythexyl)pnthalate
2 J0.7 J
2 J1 J
2BJ0.6 BJ
1 BJ7BJ
2 BJ0.6 BJ
1 BJ7BJ
negatenegatenegatenegate
1111
Pag* 3
Ethanoi, 2 -«hoxya«ioxy) (6.4)
PCB'sNone Detected
50 J 120JBN 120 JBN negate
Sample MWS4A (Lab* 34330)
Semlvolatlle Organloebi*<2-ethylhexyl)phthaiate
Non-Target Semlvolatlle Organic*EtttanoJ. 2-(2-ethoxyethoxy) (6.6)
PCB'sNone Detected
0.5 J
ND
2 BJ
3 JN
2 BJ
3 JN
negate
Sample MW54B (Lab fc 34331)
SemlvolatJIe Organic*None Detected
Non-Target Semfvolatile Organic*Unknown (22.9) [Substituted benzene]
PCS'*None Detected
ND 3 J 3 J
Sample MW54C (Lab #: 34332)
Semlvolatlle Organic*bis(2-ethy1hexyt)phthaJa»
Non-Target Semivolatlle Organic*Unknown (5.5)Unknown (7.0)Unknown (7.4)Unknown (8.4)Unknown (9.3)
Sample MW54C Re-Extracted
Semlvolatlle Organic*1,2-Dtehtorobenzene1,2,4-TrichtorobenzeneDi-n-butyl phttialatebis(2-ethy1hexyl)phthalate
Non-Target Semivolatlle Organic*Unknown (4.8)Etnanol, 2-(2-ethoxyethoxy) (6.3)Ethanol, 2-(2-ethoxyethoxy) (6.4)Unknown (7.0)Unknown (22.4)
PCS'*None Detected
0.5 J 1 BJ 1 BJ
NDNDNDNDND
28 J32 J
720 J3 J7 J
790
28J32 J
720 J3 J7J
negate
2 J0.7 J
2 J1 J
2 BJ0.7 BJ
1 BJ2 BJ
2 BJ0.7 BJ
1 BJ2 BJ
negatenegatenegatenegate
1111
NO50 J50 J
NDND
13 J26 JBN36 JBN
220 J7J
240 Total
13 J26 JBN36 JBN
220 J7J
negatenegate
11
Page 4
Sample MW5A (Ubftttttt)
SantfvotaHHa Organic*1,2-Qtohtarobenzan*O-n-butyl phtnalatotw(2-*thylh*xyl)prtth*i«e
Non-Target SemivoJatile Organic*Nona Detected
PCS'*None Detected
2 J1 J
0.5 J
2BJ0.5 BJ0.7 BJ
2BJ0.5 BJ0.7 BJ
negatenegatenegate
Sample MWS8 (Lab*:34322)
Semlvotatlle Organic*W«(2-«ttiylh«xyl}phthaJat*
Non-Targat Samivolatlla Organic*Unknown (5.2)Unknown (6.9)Unknown (7.3)Unknown (9.3)Unknown (13.5)Unknown (19.9)Unknown (21.6)
Sample MWSB Re-Extracted 12/27
Semivolatlle Organic*1,2-DtehtorobenzeneDi-n-outyl phthalatebis(2-ethylhexyl)phthalate
Non-Target Semivolatlle Organic*Unknown (6.0)Ethanol, 2-(2-ethoxyethoxy) (6.4)Unknown (19.5)
PCS'*None Detected
0.5 J
2 J2 J1 J
12 J50 J
NO
ii
2 BJ0.7 BJ11 B
13 JB84 JBN2 J
NDNONDNONDNDND
12 J26 J
230 J4J2 J4J3 J
281
12 J28 J
230 J4J2 J4J3J
26J0.7 BJ11 B J
13 JB84 JBN2 J
negatenegatequaltfy
negatenegate
11
3,15
Sample RW3A (Lab # 34325)
Samlvolatile Organic*1,2-Dichkxobenzene1,2,4-TrichlorobenzaneDi-n-butyl phthalatobis(2-elhylhexyl)phthalate
Non-Target Semivolatlle Organic*Aktol Condensation Product (4.1)Unknown (5.77)Unknown (5.S2)Unknown (5.95)Ethanol, 2-(2-ethoxyethoxy) (6.6)
2 J0.7 J
2 J1 J
3 BJ0.7 BJ0.6 BJ0.5 BJ
3 BJ0.7 BJ0.6 BJ0.5 BJ
negatenegatenegatenegate
1111
NDNDNDNDND
4 JA2 J3 J5 J4JN
4 JA2 J3 J5 J4JN
negate 79
PagaS
per*None Detected
SampleRW3B (Lao*
Samivolaflle Organic*
Non-Target Semlvolattlc Organic*Attoi Condenaatton Product (4.1)
PCB'sNone Detected
NO 2 JA 2 JA negate 79
Samp* RW3BD (Lab #: 34320)
SemivoJatHe Organic*1,2-Oichlorobenzene1,2,4-TrichlorotMnzene
Non-Targtt 3*mlvolatU« Organic*AkW Condensation Product (4.1)
PCB'tNon*D*tact*d
2 J0.6 J
ND
2BJ0.6BJ
4JA
2BJ0.6 BJ
4JA
nagatonegata
nagato 79
Sample RW3C (Lab fc 34329)
S*mlvolatll* Organic*bb(2-ethy1hexyl)phlhalatB
Non-Targ*t SemlvolatH* Organic*Unknown (5.0)Unknown (6.7)Unknown (7.3)Unknown (9.3)
Sampl*RW3C Re-Extracted 12/27
1,2-Oichlorobenzene1,2,4-TrichlorobenzeneDMi-butyl phthalatebia(2-ethylhexyt)phthalate
Non-Target Semlvoladl* Organic*Unknown (6.0)ethanol, 2-(2-e(hoxyetnoxy) (6.4)Unknown (19.5)
0.5 J
12 J50 J
NO
3BJ
13 JB73 JBN2 J
3BJ
NONDNDND
10 J21 J
150 J3 J
10 J21 J
150 J3 J
13 JB73 JBN2 J
negate
2 J0.7 J
2 J1 J
3 BJ0.5 BJ
1 BJ11 B
3 BJ0.5 BJ
1 BJ11 B
negatenegatenegatenegate
1111
negatenegate
Paged
DATA VALIDATION WORSHEETS
For the National Presto Solvent Site
Semivolatile Organic and PCB Analyses
Soil Samples Received: December 13th, 1991
Sample Delivery Group: MW34A
Laboratory Reference Numbers:
MW34A 34318MW34B 34319MW5A 34321MW5B 34322MW38A 34323MW38B 34324RW3A 34325RW3B 34326RW3B Field Blank 34327RW3BD 34328RW2C 34329MW54A 34330MW54B 34331MW54C 34332MW38A 34333MW52A 35238MW52B 35239MW43A 35241MW43B 35242
Site Name: National PrestoReviewed by: N. PotakDmtc Samples Received: 12/13/92
Page 2 of 13Laboratory: WadsworthDate Reviewed: 4/12/92
SEMIVOLATILE ORGAN1CSINITIAL CALIBRATION SUMMARY
(Page 1 of 2)
Instrument ID: EXTR03Tune File ID: DF0920A Acceptable: yes Time Requirements Met: yesCalibration File ID: SL0920 Date: 9/20/91 Page: 452Associated Samples: SBLK3, MW34A, MW34B, MW5AMS, MW5AMSD, MW5B, MW38A,MW38B, RW3A, RW3B, RW3BFB, RW3DB, RW3C, MW54A, MW54B, MW54C, MW38C, SBLK2,MW52A, MW52B, MW43A, MW43B, MW5A, SBLKl, MW5BRE, RW3CRE, MW54CRE,MW38CRE, MW52BRE
TCL COMPOUND LIST(%RSDs > 30% for CCC, all other TCL >35%, RRFs < 0.05 are noted below.
A summary of footnotes is attached as an addendum)%RSD RRF RRF
N-NitosodiphenylaninePhenol *Ana linebis(2-Ch!oroethyl)Ether2-Chlorophenol1.3-Dichlorobenzene1.4-Dichlorobenzene *Benzyl Alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-Propylamine #Hexachloroe thaneNitrobenzeneIsophorone2-Nitrophenol *2,4-DimethylphenolBenzoic Acidbis(2-Chloroethoxy)Methane2,4-Dichlorophenol *1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene *4-Chloro-3-Methylphenol *2-MethylnaphthaleneHexachlorocyclopentadiene #2,4,6-Trichlorophenol *2,4,5-Trichlorophenol2-Chloronaphthalene2-NitroanalineDimethyl PhthalateAcenaphthylene3-Nitroanaline
CCC's Acceptable: yesSPCC's Acceptable: yesAll Compounds Average RRF > 0.05: yesAll Compounds % RSD less than 35 %: no
%RSDAcenaphthene *2,4-Dinitrophenol #4-Nitrophcnol #Dibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiethylphthalate4-Chlorophenyl PhenyletherFluorene4-Nitroanaline4,6-Dinitro-2-MethylphenolN-Nitrosodiphenylamine *4-Bromophenyl-PhenyletherHexachlorobenzenePentachlorophenol *PhenanthreneAnthraceneDi-n-ButylphthalateRuoranthene *BenzidinePyreneButylbenzlphthalate3,3'-DichlorobenzidineBenzo(a)Anthracenebis(2-ethylhexyl)PhthalateChryseneDi-n-Octyl Phthalate *Benzo(b)FluorantheneBenzo(k)RuorantheneBenzo(a)Pyrene *Indeno(l,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid SurrogatesBase Neutral Surrogates
Footnote:Footnote:Footnote:Footnote: 15
36%
Site Name: National PrestoReviewed by: N. PotakDate Samples Received: 12/13/92
Page 3 of 13Laboratory: WadsworthDate Reviewed: 4/12/92
SEMIVOLATILE ORGANICSINITIAL CALIBRATION SUMMARY
(Page 2 of 2)
CALCULATION VERIHCATION:
(RRF - Ais/Ax*Cis/Cs)
Compounds: 4-Bromophenyt-phenyletherPPB (44T, 3S)20 85125/529660 * 2.000 - 0.32150 165232/450508 * 0.800 - 0.29380 146966/277958 * 0.500 - 0.264120 209802/276268 * 0.333 - 0.253160 209890/205123 * 0.250 - 0.256
AV. RRF - 0.277 %RSD- 10.5%
4-Methylphcnol(9T, IS)
193724/227412 * 2.000 - 1.704349476/187160 * 0.800 - 1.494278620/98550 * 0.500 - 1.414330240/76524 * 0.333 - 1.438306280/58988 * 0.250 - 1.298
AV. RRF - 1.470 %RSD - 10.2%
OVERALL ASSESSMENT AND COMMENTS: The areas of both the intend standards associatedwith the first two calibration standards were much greater than those of the other standards. This did notaffect the final RFs.
Site Name: National PrestoReviewed by: N. PotakDate Samples Received: 12/13/92
Page 4 of 13Laboratory: WadsworthDate Reviewed: 4/12/92
SEMIVOLATILE ORGANIC SCONTINUING CALIBRATION SUMMARY
(page 1 of 2)
Instrument ID: EXTR03Tune File ID: DF1223Calibration File ID: SML1223Initial Calibration File ID: SL0920Associated Samples: SBLK3
Acceptable: yesDate: 12/23/91Date: 9/20/91
Time Requirements Met: yesPage: 489Page: 452
TCL COMPOUND LIST(%Diff greater than 25% and RRFs less than 0.05 are noted below.
A summary of footnotes is attached as an addendum)
%RSD RRFN-NitosodiphenylaninePhenolAnalinebis(2-Chloroethyl)Ether2-Chlorophenol1.3-Dichlorobenzene1.4-DichlorobcnzeneBenzyl Alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-PropylamineHexachloroe thaneNitrobenzeneIsophorone2-Nitrophenol2,4-DimethylphenolBenzoic Acidbis(2-Chloroethoxy )Methane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene4-Chloro-3-Methylphenol2-MethylnaphthaleneHexachlorocyclopentadiene2,4,6-Trichlorophenol2,4,5 -Trichlorophenol2-Chloronaphtha lene2-NitroanalineDimethyl PhthalateAcenaphthylene3-Nitroanaline
27%
29%
%RSD RRFAcenaphthene2,4-Dinitrophenol4-NitrophenolDibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiethylphthalate4-Chlorophenyl PhenyletherFluorene4-NitroanaIine4,6-Dinitro-2-MethylphenolN-Nitrosodiphenylamine4-Bromophenyl-PhenyletherHexachlorobenzene (25%)PentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalateFluorantheneBenzidinePyreneButylbenzlphthalate3,3'-DichlorobenzidineBenzo(a)Anthracenebis(2-ethylhexyl)PhthalateChryseneDi-n-Octyl PhthalateBenzo(b)FluorantheneBenzo(k)FluorantheneBenzo(a)PyreneIndeno( l,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid Surrogates: 2,4,6-TribromophenolBase Neutral Surrogates
34%
no*'s % D Acceptable:Minimum RF's Acceptable: yesAll Compounds Average RRF > 0.05: yesAll Compounds %RSD less than 25%: no
Footnote: 18Footnote:Footnote:Footnote: 15
Site Name: National PrestoReviewed by: N. PoiakDmte Samples Received: 12/13/92
Page 5 of 13Laboratory: WadsworthDate Reviewed: 4/12/92
SEMIVOLATILE ORGANICSCONTINUING CALIBRATION SUMMARY
(page 2 of 2)
CALCULATION VERIFICATION:
(RRF • Ais/Ax*Cis/Cs)
Compounds: 1,2-DichlorobenzeoePPB
CCC: Hexachlorobenzenc
50 148298/81824* 0.800 - 1.450 74755/287036 * 0.800 - 0.208
% Difference: % Difference:(1.394 - 1.450) / 1.394 * 100 - -4.0172 (0.294 - 0.208) / 0.294 * 100
29.251
METHOD BLANK: SBLK1 ( Page 558)Associated with all reanalyses
Compound1,2-Dichlorobenzene1,2,4-TrichlorobenzeneDi-n-butylphthalatebis(2-elhy Ihexy OphthalateUnknown (6.0)Ethanol, 2-(2-eihoxvethoxy) (6.4)
ppb2.0J0.7J2.0Jl.OJ12J50J
CRDL10101010NANA
OVERALL ASSESSMENT AND COMMENTS: ok
Site Name: National PrestoReviewed by: N. PotakDale Samples.Received: 12/13/92
Page 6 of 13Laboratory: WadswortbDate Reviewed: 4/12/92
SEMIVOLATILE ORGANICSCONTINUING CALIBRATION SUMMARY
(page 1 of 2)
Instrument ID: EXTR03Tune File ID: DF1224 Acceptable: yes Time Requirements Met: yesCalibration File ID: SML 1224 Date: 12/24/91 Page: 491Initial Calibration File ID: SL0920 Date: 9/20/91 Page: 452Associated Samples: MW34A, MW34B, MW5AMS, MW5AMSD, MW5B, MW38A, MW38B,RW3A, RW3B, RW3BFB, RW3DB, RW3C, MW54A, MW54B, MW54C, MW38C, SBLK2
TCL COMPOUND LIST(%Diff greater than 25% and non SPCC RRFs less than 0.05 are noted below.
A summary of footnotes is attached as an addendum)
%RSD RRFN-NitosodiphenylaninePhenolAnalinebis(2-Chloroethyl)Ether2-Chlorophenol1.3-Dichlorobenzene1.4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-PropylamineHexachloroethaneNitrobenzeneIsophorone2-Nitrophenol2,4-DimethylphenolBenzole Acidbis(2-Chloroethoxy)Methane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene4-Chloro- 3-Methy (phenol2-MethylnaphthaleneHexachlorocyclopentadiene2,4,6-Trichlorophenol2,4,5-Trichlorophenol2-Chloronaphtha lene2-NitroanalineDimethyl PhthalateAcenaphthylene3-Nitroanaline
27%
%RSD RRFAcenaphthene2,4-Dinitrophenol4-Nitrophenol 38%Dibeuzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiethylphthalate4-Chlorophenyl PhenylctherFluorene4-Nitroanaline 30%4,6-Dinilro-2-MelhylphenolN-Nitrosodiphenylamine4-Bromophenyl-PhenyletherHexachlorobcnzene * 30%PentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalateFluorantheneBenzidinePyrene* 28%Butylbenzlphthalate 47%3,3'- DichlorobenzidineBe nzo( a) Anthracenebis(2-ethylhexyl)Phthalate 53%ChryseneDi-n-Octyl Phthalate 38%Benzo(b)FIuorantheneBenzo(k)FluorantheneBenzo(a)PyreneIndeno( 1,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid Surrogates: 2,4,6-Tribromophenol 34%Base Neutral Surrogates
no*'s % D Acceptable:Minimum RF's Acceptable: yesAM Compounds Average RRF > 0.05: yesAll Compounds % RSD less than 25 %: no
Footnote: 18Footnote:Footnote:Footnote: 15
Site Name: National Presto Page 7 of 13Reviewed by: N. Potak Laboratory: WadsworthDate Samples Received: 12/13/92 Date Reviewed: 4/12/92
SEMIVOLATILE ORGANICSCONTINUING CALIBRATION SUMMARY
(page 2 of 2)
CALCULATION VERIFICATION:
(RRF - Ais/Ax*Cis/Cs)
Compounds: Pyrene N-Nitroso-di-n-propylaminePPB
50 324856/145455* 0.800 - 1.787 74908/67389 * 0.800 - 0.889
% Difference: % Difference:(1.392 - 1.787) / 1,392 * 100 - -28.376 (0.732 - 0.889) / 0.732 * 100 - -21.448087
METHOD BLANK: SBLK2 ( Page 576)
Associated with samples MW43A, MW43B, MW52A, MW52B
Compound ppb CRDL1,2-Dichlorobenzene 0.6J 10Ethanol, 2-(2-ethoxyethoxy) (6.4) 2.0J NA
OVERALL ASSESSMENT AND COMMENTS: ok
Site Nmme: National PrestoReviewed by: N. PotakDate Samples Received: 12/13/92
Page 8 of 13Laboratory: WadsworthDale Reviewed: 4/12/92
SEMIVOLATBLE ORGANIC SCONTINUING CALIBRATION SUMMARY
(page 1 of 2)
Instrument ID: EXTR03Tune File ID: DF1226 Acceptable: yesCalibration File ID:SML1226 Date: 12/26/91Initial Calibration File ID: SL0920 Date: 9/20/91Associated Samples: MW52A, MW52B, MW43A, MW43B
Time Requirements Met: yesPage: 493Page: 452
TCL COMPOUND LIST(%Diff greater than 25% and non SPCC RRFs less than 0.05 are noted below.
A summary of footnotes is attached as an addendum)
%RSD RRFN-NitosodiphenylaninePhenolAna linebis(2-Chloroethyl)Ether2-Chlorophenol1.3-Dichlorobenzene1.4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-Propylamine *32%Hexachloroethane * 27%NitrobenzeneIsophorone2-Nitrophenol2,4-DimethyIphenolBenzoic Acidbis(2-Chloroethoxy)Me thane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene4-Chloro-3-Methylphenol2-MethylnaphthaleneHcxachlorocyclopentadiene2,4,6-Trichlorophenol2,4,5-Trichlorophenol2-Chloronaphthalene2-NitroanalineDimethyl PbthalateAcenaphthylene3-Nitroanaline
*'s %D Acceptable:Minimum RF's Acceptable:All Compounds Average RRF > 0.05:
%RSD RRFAcenaphthene2,4-Dinitrophenol4-Nitrophenol 59%Dibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiethylphtbalate4-Chlorophcnyl PhenyletherFluorene4-Nitroanaline 28%4,6-Dinitro-2-MethylphenolN-Nitrosodiphenylamine4-Bromophenyl-Phenylether * 30%Hexachlotobenzene * 35%PentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalateFluorantheneBenzidinePyreneButylbenzlphthalate 34%3,3'-DichlorobenzidineBenzo(a)Anthracenebis(2-ethylhexyl)Phthalate 37%ChryseneDi-n-Octyl Phthalate 46%Benzo(b)FIuorantheneBenzo(k)FluorantheneBenzo(a)PyreneIndeno( 1,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid Surrogates: 2,4,6-Tribromophenol 39%Base Neutral Surrogates
no Footnote: 18yes Footnote:yes Footnote:
All Compounds % RSD less than 25 %: no Footnote: 15
Site Name: National Presto Page 9 of 13Reviewed by: N. Potak Laboratory: WadsworthDale Samples Received: 12/13/92 Date Reviewed: 4/12/92
SEMIVOLATILE ORGANICSCONTINUING CALIBRATION SUMMARY
(page 2 of 2)
CALCULATION VERIFICATION:
(RRF - Ais/Ax*Cis/Cs)
Compounds: 4-Nitrophenol Di-n-OctylphthalatcPPB
50 20387/143893 * 0.800 - 0.113 205152/138002 * 0.800 - 1.189
% Difference: % Difference:(0.071 - 0.113) / 0.071 * 100 - -59.15493 (0.815 -1.189) / 0.815 * 100 - -45.8895
METHOD BLANK: SBLK3 ( Page 589)
Associated with samples: MW34A, MW34B, MW5AMS, MW5AMSD, MW5B, MW38A,MW38B, RW3A, RW3B, RW3BFB, RW3DB, RW3C, MW54A, MW54B, MW54C, MW38C, MW5A
Compound ppb CRDL1,2-Dichlorobenzene 2.0J 101,2,4-Trichlorobenzene 0.6J 10Di-n-butylphthalate 1 .OJ 10bis(2-ethylhexyl)phthalate 0.5J 10
OVERALL ASSESSMENT AND COMMENTS: ok
Site Name: National PrestoReviewed by: N. Potak .Dmte Samples Received: 12/13/92
Page 10 of 13Laboratory: WadsworthDate Reviewed: 4/12/92
SEMIVOLATILE ORGAN1CSCONTINUING CALIBRATION SUMMARY
1 of 2)
Instrument ID: EXTR03Tune File ID: DF1227Calibration File ID: SML1227Initial Calibration File ID: SL0920Associated Samples: MW5A
Acceptable: yesDate: 12/27/91Date: 9/20/91
Time Requirements Met: yesPage: 495Page: 452
TCL COMPOUND LIST(%Diff greater than 25% and non SPCC RRFs less than 0.05 are noted below.
A summary of footnotes is attached as an addendum)
%RSD RRFN-NitosodiphenylaninePhenolAna linebis(2-Chloroethyl)Ether2-ChJorophenoI1.3-Dichlorobenzene1.4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-Propy lamineHexachloroethaneNitrobenzeneIsophorone2-Nitrophenol2,4-DimethyIphenolBenzoic Acidbis(2-Chloroethoxy)Melhane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene4-Chloro-3-Methylphenol2-MethylnaphthaleneHexachlorocyc lopentadiene2,4,6-Trichlorophenol2,4,5 -Trichlorophenol2-Chloronaphthalene2-NitroanalineDimethyl PhthalateAcenaphthylene3-Nitroanaline
26%
Acenaphthene2,4-Dinitropbenol4-NitrophenolDibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDicthylphthalate4-Chlorophenyl PhenyletherPluorene4-Nitroanaline4,6-Dinitro-2-MethylphenolN-Nitrosodipheny lamine4-Bromophenyl-PhenyletherHexachlorobenzenc *PentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalaleFluorantheneBenzidinePyreneButylbenzlphthalate3,3'-DichlorobenzidineBenzo<a)Anthracenebis(2-ethylhexyl)PhtnalateChryseneDi-n-Octyl PhthalateBenzo(b)FluorantheneBenzo(k)FluorantheneBenzo(a)PyreneIndeno( 1,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid SurrogatesBase Neutral Surrogates
%RSD RRF
34%75%
29%
50%
31%
30%
52%
37%
no*'s % D Acceptable:Minimum RF's Acceptable: yesAll Compounds Average RRF > 0.05: yesAll Compounds % RSD less than 25 %: no
Footnote: 18Footnote:Footnote:Footnote: 15
Site Name: National Presto Page 11 of 13Reviewed by: N. Potak Laboratory: WadsworthDate Sample* Received: 12/13/92 Date Reviewed: 4/12/92
SEMIVOLATILE ORGANICSCONTINUING CALIBRATION SUMMARY
(page 2 of 2)
CALCULATION VERIFICATION:
(RRF - Ais/Ax*Cis/Cs)
Compounds: Phenol FluoranthenePPB
50 147028/59385 * 0.800 - 1.981 316552/236076 * 0.800 - 1.073
% Difference: % Difference:(1.875-1.981) / 1.875* 100 --5.653333 (0.991- 1.073) / 0.991 * 100--8.2744
METHOD BLANK: ( Page )
Compound ppb <CRDL
OVERALL ASSESSMENT AND COMMENTS: ok
Site Name: National PrestoReviewed by: N. PotakDate Samples Received: 12/13/92
Page 12 of 13Laboratory: WadsworthDate Reviewed: 4/12/92
SEMIVOLATILE ORGANICSCONTINUING CALIBRATION SUMMARY
(P«gelof2)
Instrument ID: EXTR03Tune File ID: DP1230A Acceptable: yes Time Requirements Met: yesCalibration File ID: SML1230 Date: 12/30/91 Page: 497Initial Calibration File ID: SL0920 Date: 9/20/91 Page: 452Associated Samples: SBLKl, MW5BRE, RW3CRE, MW54CRE, MW38CRE, MW52BRE
TCL COMPOUND LIST(%Diff greater than 25% and non SPCC RRFs less than 0.05 are noted below.
A summary of footnotes is attached as an addendum)
%RSD RRFN-NitosodiphenylaninePhenolAnalinebis(2-Chloroethyl)Ether2-Chlorophenol1.3-Dichlorobenzene1.4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzene2-Methylphcnolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-Propylaraine *28%Hexachloroethane * 26 %NitrobenzeneIsophorone2-Nitrophenol2,4-DimethylphenolBenzole Acidbis(2-Chloroethoxy)Methane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene4-Chloro-3-Methylphenol * 28 %2-MethylnaphthaleneHexachlorocyclopentadiene2,4,6-Trichlorophenol2,4,5-Trichlorophenol2-Chloronaphthalene2-Nitroanaline 38%Dimethyl PhthalateAcenaphthylene3-Nitroanaline
*'s %D Acceptable:Minimum RF's Acceptable:
%RSDAcenaphthene2,4-Dinitrophenol4-Nitrophenol 48%Dibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiethylphthalate4-Chlorophcny I Phcny IcihcrFluorene4-Nitroanaline 31 %4,6-Dinitro-2-MethylphenolN-Nitrosodiphenylamine4-Bromophenyl-Phenylether 27%Hexachlorobenzene * 32 %PentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalateFluorantheneBenzidlnePyreneButylbenzlphthalate 29%3,3'-DichlorobenzidineBenzo(a)Anthracenebis(2-eihylhexyI)Phthalate 32%ChryseneDi-n-Octyl Phthalate 38%Benzo(b)FluorantheneBenzo<k)FluorantheneBenzo(a)PyreneIndeno( 1,2>3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid Surrogates: 2,4,6-TribromophenolBase Neutral Surrogates
RRF
noyes
All Compounds Average RRF > 0.05: yesAll Compounds % RSD less than 25 %: no
Footnote: 18Footnote:Footnote:Footnote: 15
Site Name: National Presto Page 13 of 13Reviewed by: N. Potak Laboratory: WadsworthDate Samples Received: 12/13/92 Date Reviewed: 4/12/92
SEMIVOLATILE ORGANICSCONTINUING CALIBRATION SUMMARY
(page2of2)
CALCULATION VERIFICATION:
(RRF - Ais/Ax*Cis/Cs)
Compounds: 4-Chloro-3-methylphenol Benzo(gth4)pciylenePPB
50 84405/227428 * 0.800 - 0.297 146718/116292 * 0.800 - 1.009
% Difference: % Difference:(0.233 - 0.297) / 0.233 * 100 - -27.4678 (1.057 -1.009) /1.057 * 100 - 4.541154%
METHOD BLANK: ( Page)
Compound ppb <CRDL
OVERALL ASSESSMENT AND COMMENTS: ok
SDG: MW34A
Pesticide Retention Time Verifications
alpha-BHCbeta-BHCdetta-BHCgamma-BHCHeptachkxAldrinHeptachlor EpoxideEndosutfan IDieldrin4.4'-DDEEndrinEndosutfan I4,4'-DDDEndosuKan Sutfate4,4-'DDTMethoxychlorEndrin KetoneEndrin Aldehydealpha-Chtordanegamma-Chlordane
Tetrachtoro-m-xyleneDecacachlorobiphenyl
MeanR.T.
6.9811.8912.688.519.19
10.1713.2214.2515.8815.5116.7218.9819.0523.3619.8124.2625.5921.1914.9714.62
4.0330.81
R.T.From
6.9311.8412.638.469.14
10.1213.1514.1815.8115.4416.6518.9118.9823.2919.7424.1925.5221.1214.9014.55
3.9830.71
WindowTo
7.0311.9412.738.569.24
10.2213.2914.3215.9515.5816.7919.0519.1223.4319.8824.3325.6621.2615.0414.69
4.0830.91
Pagel
SDG: MW34A
Performance Evaluation Mixture Verification
LAB*PEMA1
P1045A1
alpha BHCgamma- BHCbeta-BHCEndrin4.4'-DDTMethoxychlor
Date1217
Time7:38 pm
Page824
CF13.002,30014.358,3506.701,550
10.495,1507.212,7504.222,320
Area125,820123,19672,210
489,792662,643985.771
NonAmount
0.0100.0100.0100.0500.1000.250
CalcAmount
0.0100.0090.0110.0470.0920.233
RPD3.2%
14.2%-7.8%6.7%8.1%6.6%
Endrin Breakdown VerificationEA
% Breakdown Area
0% 0
EKArea
DOT Breakdown Verification
% Breakdown
0%
DDEArea
DDDArea
0
Page 2
SDG: MW34A
Performance Evaluation Mixture Verification
LAB*P1052A4
Date12/24
Time12:02pm
Page826
alpha BHCgamma-BHCbeta-BHCEndrin4.4'-DDTMethoxychlor
CF13,002.30014,358.3506,701,550
10.495,1507.212,7504,222.320
Area142,955140,13781.757
517,158732.362
1.056,382
NonAmount
0.0100.0100.0100.0500.1000.250
CalcAmount
0.0110.0100.0120.0490.1020.250
RPD-9.9%2.4%
-22.0%1.4%
-1.5%-0.1%
Endrin Breakdown VerificationEA EK
% Breakdown Area Area
0% 0 0
DOT Breakdown Verification
% Breakdown
0%
DDEArea
ODDArea
0
Page3
SDG: MW34A
Performance Evaluation Mixture Verification
LAB*P1052A5
Date12/25
Time2:28 pm
Page828
alpha BHCgamma-BHCbeta-BHCEndnn4,4'-DDTMethoxychlor
CF13.002.30014.358.3506.701.550
10.495,1507,212.7504.222,320
Area143.482140,29982,001
538.960853.036
1,248,663
NonAmount
0.0100.0100.0100.0500.1000.250
CalcAmount
0.0110.0100.0120.0510.1180.296
RPD-10.4%
2.3%-22.4%-2.7%
-18.3%-18.3%
Endrin Breakdown VerificationEA
% Breakdown Area
0% 0
EKArea
DOT Breakdown Verification
% Breakdown
0%
DDEArea
DDDArea
Page 4
SDG: MW34A
Initial Calibration Verification
TCMXalpha-BHCgamma-BHCHeptachtofEndosutfan IDieldrinEndrin4,4'-DDD4.4'-DDTMethoxychtorDCB
INDALArea ng CF
64,283 0.005 12.856.60068.006 0.005 13,601,20076,151 0.005 15,230.20077.543 0.005 15.508.60069,436 0.005 13,887,200
118.474 0.01 11.847.400113.475 0.01 11.347,50080,268 0.01 8,026,80082,602 0.01 8,260,200
218,712 0.05 4,374,24093,779 0.01 9,377,900
INDAUArea ng CF
235.444 0.02 11,772.200260.046 0.02 13,002,300287.167 0.02 14.358.350285,676 0.02 14,283,800255,612 0.02 12,780,600441,221 0.04 11,030,525419,806 0.04 10.495,150306,248 0.04 7,656,200288,510 0.04 7,212.750844,464 0.20 4,222.320412,059 0.04 10,301,475
INDAHArea ng CF
774,480 0.08 9,681,0001,031,249 0.08 12,890,6131.111,755 0.08 13.896,9381,029,788 0.08 12.872,350
928,077 0.08 11,600,9631,625,545 0.16 10,159,6561,516,633 0.16 9,478,9561.146,991 0.16 7,168,6941,076.862 0.16 6,724,1382,953,279 0.80 3,691,5991,386,101 0.16 8,663.131
MEAN11,436,60013,164.70414,495,16314.221,58312.756,25411,012.52710,440,5357.617.2317.399,0294,096,0539,447,502
%RSD14.12.94.79.39.07.79.05.7
10.68.88.7
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SDG: MW34A
Continuing Calibration Verification
INDALab#:
P1000A3Date Time Page12/25 1:15 am 892
TCMXalpha-BHCgamma-BHCHeptachlorEndosutfan IDietdrinEndrin4.4'-DDD4,4'-DDTMethoxychlorDCB
CF11.772.20013.002.30014.358.35014,283.80012.780.60011.030.52510,495,1507.656,2007,212.7504.222,320
10,301,475
NonArea Amount
245,230277.215305.351298.166268,951460,115437,325330,114273.377887.323427,079
0.0200.0200.0200.0200.0200.0400.0400.0400.0400.2000.040
CalcAmount
0.0?10.0210.0210.0210.0210.0420.0420.0430.0380.2100.041
RPD-4.2%-6.6%-6.3%-4.4%-5.2%-4.3%-4.2%-7.8%5.2%
-5.1%-3.6%
Page?
SDG: MW34A
Continuing Calibration Verification
INDBLabtf:
P1022A3Date12/25
Time1:57
Page896
INDB
TCMXAldrinbeta-BHCdetta-BHCHeptachtor Epoxidegamma-Chtofdanealpha-Chlordane4,4'-DDEEndosulfan IIEndrin AldehydeEndosutfan SufateEndrin KetoneDCB
CFn, 772,20012,856.7006,701.550
12,029.90012,775.10012,390,40012,953,25010,844,42510.402,6758,012,0009.470,3509.914,000
10.301,475
NonArea Amount
237,324272,552140,162257,906268,898260,198270,102460,215428,157309,191382,854406,398433.331
0.0200.0200.0200.0200.0200.0200.0200.0400.0400.0400.0400.0400.040
CalcAmount
0.0200.0210.0210.0210.0210.0210.0210.0420.0410.0390.0400.0410.042
RPD-0.8%-6.0%-4.6%-7.2%-5.2%-5.0%-4.3%-6.1%-2.9%3.5%
-1.1%-2.5%-5.2%
PageS
SDQ: MW34A
Florlsll Cartridge Check
Lab*: DateFLORCK1127 12/18
Time8:53
Page900
TCMXalpha-BHCgamma-BHCHeptachtorEndosutfan IDieklrinEndrin4.4'-DDD4,4'-DDTMethoxychbrDOB
CF11,772,20013.002.30014,358.35014,283,80012.780,60011.030,52510.495.1507.656.2007,212,7504,222,320
10.301.475
Area116,382142.071157.082163,969151,403243,412241,434163,095134.346494,486236.580
SpikeAdded
10.0010.0010.0010.0010.0020.0020.0020.0020.00
100.0020.00
SpikeRec9.89
10.9310.9411.4811.8522.0723.0021.3018.63
117.1122.97
%Rec
98.9%109.3%109.4%114.8%118.5%110.3%115.0%106.5%93.1%
117.1%114.8%
Page 9
SDG: MW34A
MS Verification
Sample MW38
TCMXgamma-BHCHeptachlorAWrinDteldrinEndrin4.4'-DDTDCB
CF11.772,20014,358,35014,283,80012,856.70011,030,52510,495,1507.212.750
10,301.475
Area197.419688.278616,262576,289
1.068,0041.031.705
704.783196,406
SpikeAdded
0.500.500.501.001.001.00
SpikeRec0.170.480.430.450.970.980.980.19
%Rec
#VALUEI95.9%86.3%89.6%96.8%98.3%97.7%
#VALUEI
56%40%40%52%56%38%
QCLimits
-123%- 131%-120%-126%-121%-127%
Page 10
SDG: MW34A
MSD Verification
Sample MW38
TCMXgamma-BHCHeptachkxAldrinDfeldrinEndrin4.4'-DDTDCB
CF11,772.20014,358.35014,283,80012,856,70011,030,52510,495,1507.212,750
10.301.475
Area105,916712,296662,303625,714
1,130.3941.110,542
741.530189,871
SpikeAdded
0.500.500.501.001.001.00
SpikeRec0.090.500.460.491.021.061.030.18
%Rec
#VALUEI99.2%92.7%97.3%
102.5%105.8%102.8%
#VALUEI
56%40%40%52%56%38%
QCLimits
-123%-131%-120%-126%-121%-127%
RPD
-3%-7%-8%-6%-7%-5%
QCLimits
152022182127
Page 11
SUMMARY OF THE ANALYTICAL DATA VALIDATIONFor Samples Collected at theNational Presto Solvent Site
Semivolatile and PCB AnalysesWater Samples Received: December 20,1991Sample Delivery Group: EC2-01Laboratory Reference Numbers:
EC2-01 35943RW16-D 35944RW16FB 35945RW1601 35946RW16B 35947RW16C 35948
Water samples were received for semivolatlle organic and PCB analyses for theTCL analyte list. The analyses were performed according to the requirements of3/90 EPA CLP Statement of work.
Data Validation Summary
No problems were found with the data that would significantly affect theusability of the data.
Sample Collection and Receipt
The samples which were received on 12/13 were collected from 12/9through 12/11. Those that were received on 12/18 were collected from12/13 through 12/16. All end users of the data should be aware of thetime between sample collection and receipt by the laboratory.
SEMIVOLATILE ORGANICS
A complete analytical data validation was performed based upon thefollowing parameters:
* - Chain of Custody* - Data Completeness* - GC/MS Tuning* - Holding Times
- Calibrations* - Laboratory Blanks
- Field Blanks* - Surrogate Recoveries
- Internal Standard Recoveries- Matrix Spike / Matrix Spike Duplicate
* - Compound Identification* - Compound Quantitation* - Method Detection Limits
* - Indicates that alt criteria were met for this parameter.
Holding Times
AH samples were extracted and analyzed within the required holding timefrom sample receipt.
Calibrations
The initial calibration was performed three months prior to the analyses ofthe samples of this delivery group.
All initial and continuing calibration requirements were met with theexceptions of the % difference requirements for a few of the targetcompounds. These are noted in detail in the data validation worksheets.None of these were detected in any of the samples of this delivery groupwith the exception of bis(2-ethylhexy!)phthalate. This compound wasnegated in the majority of the samples due to its presence in theassociated method blank. In the two instances where it was not negated,it was flagged with the "J" qualifier and footnoted with #15. Thiscompound will not affect the end use of the data.
Surrogate Recoveries
All surrogate recoveries were within the acceptable quality assurancelimits.
Matrix Spike / Matrix Spike Duplicate
Sample RW1601 of this sample delivery group was used for the MS /MSD. All recoveries and RPD's were within the acceptable range with theexceptions of:
Compound_________MS MSD RPD
4-Chloro-3-methylphenol 19% 17%Acanaphthene 36% 26% 32%Pyrene 24% 14% 53%
It may have been possible that some low concentrations of TCLcompounds may not have been detected in some of the samples of thisdelivery group.
Internal Standards
The areas and retention times of all internal standards were within theacceptable range with the exceptions of the last two internal standards ofthe MS and MSD. These were just below the quality assurance limits.This may have been part of the reason for the low spike recoveries ofseveral of the TCL compounds in the MS and MSD.
Method Blanks
One method blank was associated with the extraction of the samples ofthis delivery group. Three target compounds were detected in the methodblank (1,2-dichlorobenzene, di-n-butylphthalate and bis(2-ethylhexyl)phthalate), Aii were negated according to the general EPA data validationguidelines when they were detected in the samples. These are noted indetail in the data validation summary table.
Field Blanks
One field blank was collected with the samples of this delivery group. Lowconcentrations of 1,2-dichlorobenzene, di-n-butylphthalate, and bis 2-ethyI)phthalate were detected. The 1,2-dichlorobenzene and di-n-butylphthalate were negated due to their presence in the method blank.
Sample Results
Concentrations reported on the sample quant sheets were concentratedby a factor of 2 over the reported value.
No problems were detected with the samples of this delivery group.
PCB ANALYSES
A complete analytical data validation was performed based upon thefollowing parameters:
* - Data Completeness* - Holding Times
- Surrogate Recoveries* - Florisil Cartridge Performance Check* - Analytical Sequence* - Initial Calibration* - Absolute Retention Times* - Performance Evaluation Mixture* - Resolution Check Mixture* - Continuing Calibrations* - instrument Blanks .* - Preparation Blanks
- Field Blanks- Matrix Spike / Matrix Spike Duplicate
* - Compound Identification* - Compound Quantitation* - Method Detection Limits* - Sample Results
* - Indicates that all criteria were met for this parameter.
Only data from the primary column was reviewed since patterns of PCB's werenot detected in any of the samples.
Surrogate Recoveries
Both TCX and DCS were both used as surrogates, and recoveries weredetermined for both the primary and confirmation columns.
All TCX recoveries were within the acceptable range in the primary andconfirmation columns.
All DCB recoveries were within the acceptable range for the primarycolumn with the one exception of the matrix spike duplicate of sampleRW1601. This is not significant since the DCB recoveries of both thesample itself and the matrix spike were within the acceptable range.
Two of the DCB recoveries were outside of the QC limits for theconfirmation column. This is not significant since no PCB patterns weredetected in the primary column.
Matrix Spike / Matrix Spike Duplicate
Sample RW1601 of this sample delivery group was used for the MS /MSD. The sample was spiked with the six standard pesticide TCLcompounds. All recoveries and RPD's were reported to be within theacceptable range, but the recovery of the aldrin spike could not be verifiedduring the data validation. Recoveries of 129% and 122% were obtained.These are just above the quality control limit of 120%. This is not asignificant problem since all other spike recoveries were within theacceptable range.
Sample Results
No problems were found with any of the samples of this delivery group.
Data Summary TableNational Preeto Solvent Stte
Semlvolatlle and PCB Anatyae*Water Sample* Received: 12/20/V1Sample Delivery Group: EC2-01
Sample I Anatyte
MethodBlankCone.(PPB)
ReportedCone.(PPB)
QAValidationReported
Cone.Decision
Qualifier* Footnote*
RW16 Field Blank (Ub #: 35945)
Semivolatile Organic*1,2-DtchkxobenzeneDi-n-butyl phthaJatebis(2-ethytnexyl)phthaJate
Non-Target Semlvolatlle Organic*None Detected
PCS'*None Detected
0.9 J0.8 J10 U
0.5 BJ0.9 8J0.5 J
0.5 BJ0.9 BJ0.5 J
negatenegate
Sample EC2-01 (Lab #: 35943)
Semivolatile Organic*None Detected
Non-Target Semlvolatlle Organic*Sulfur, mol. (S8)
PCB1*None Detected
ND 3 JN 3JN
Sample RW1601 (Lab #: 35946)
Semlvolatlle Organic*None Detected
Non-Target Semlvolatlle Organic*Unknown (5.3)Ethanol. 2-(2-ethoxyethoxy)- (6.50)Unknown (16.3)Unknown (16.4)
PCS'*None Detected
NDNDNDND
10 J2 JN
12 J3 J
10 J2 JN
12 J3 J
Pagel
Sample RW16B (Lab *: 35947)
SemlvolatHe Organic*None Detected
Non-Target Semlvotatite Organic*Unknown (4.7)
PCB'tNone Detected
ND 7J 7 J
Sample RW16C (Lab #: 35948)
Semlvolatlle Organic*Phenolbis (2-ethylhexyt)pnthalate
Non-Target SemlvolatHe Organic*Unknown (4.7)Unknown (6.5)Unknown (7.2)Unknown (18.9)Unknown (19.8)Unknown (22.6)
PCS'*None Detected
10 U10 U
NDNDNDNDNDND
0.8 J0.7 J
9 J60 J
160 J5 J2 J3 J
0.8 J0.7 J
9 J60 J
160 J5 J2J3J
negate
Sample RW16D (Lab #: 35944)
Semlvolatlle Organic*bis(2-ethy1hexyl)prith»Jate
Non-Target Semlvolatlle Organic*Unknown (4.3)Unknown (4.4)Unknown (5.3)Unknown (16.3)Unknown (16.4)
PCB'sNone Detected
10 U
NDNDNDNDND
0.7 J
2J3 J
14 J12 J3 J
0.7 J
2 J3 J
14 J12 J3 J
negate
Pag* 2
DATA VALIDATION WORSHEETS
For the National Presto Solvent Site
Semivolatile Organic & PCB Analyses
Soil Samples Received: December 20th, 1991
Sample Delivery Group: EC201
Laboratory Reference Numbers:
EC2-01 35943RW16-D 35044RW16FB 35945RW1601 35946RW16B 35947RW16C 35948
Site Name: National Presto .Reviewed by: N. PotakDate Samples Received: 12/20/92
Page 2 of9Laboratory: WadsworthDate Reviewed: 4/15/92
SEMIVOLATILE ORGANICSINITIAL CALIBRATION SUMMARY
(Page 1 of 2)
Instrument ID: EXTR03Tune File ID: DF0920A Acceptable: yes Time Requirements Met: yesCalibration File ID: SL0920 Date: 9/20/91 Page: 109Associated Samples: SBLKl, EC201, RW16D, RW16FB, RW1601, RW160IMS, RW1Q01MSD,RW16B,RW16C
TCL COMPOUND LIST(%RSDs > 30% for CCC, all other TCL >35%, RRFs < 0.05 are noted below.
A summary of footnotes is attached as an addendum)%RSD RRF RRF
N-NitosodiphenylaninePhenol *Analinebis(2-Chloroethyl)Ether2-ChJorophenol1.3-Dichlorobenzene1.4-Dichlorobenzene *Benzyl Alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-Propylamine #HexachloroethaneNitrobenzeneIsophorone2-Nitrophenol *2,4-DimethyiphenolBenzole Acidbis(2-Chloroethoxy)Methane2,4-Dichlorophenol *1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene *4-Chloro-3-Methylphenol *2-MethylnaphthaleneHexachlorocyclopentadiene #2,4,6-Trichlorophenol *2,4,5-Trichlorophenol2-Chloronaphthalene2-NitroanalineDimethyl PhthalateAcenaphthylene3-Nitroanaline
CCC's Acceptable: yesSPCC's Acceptable: yesAll Compounds Average RRF > 0.05: yesAll Compounds % RSD less than 35 %: no
%RSDAcenaphthene *2,4-Dinitrophenol #4-Nitrophenol #Dibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiethylphlhalate4-Chlorophenyl PhenyletherRuorene4-Nitroanaline4,6-Dinitro-2-MethylphenolN-Nitrosodiphenylamine *4-Bromophenyl-PhenyletherHexachlorobenzenePentachlorophenol *PhenanthreneAnthraceneDi-n-ButylphthalateRuoranthene *BenzidinePyreneButylbenzlphthalate3,3'-DichlorobenzidincBenzo(a)Anthracenebis(2-ethylhexyl)PhtnalateChryseneDi-n-Octyl Phthalate *Benzo(b)FluorantheneBenzo(k)FluonuitheneBenzo(a)Pyrene *Indeno( 1,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid SurrogatesBase Neutral Surrogates
Footnote:Footnote:Footnote:Footnote: 15
36%
Site Name: National PrestoReviewed by: N" PotakDate Samples Received: 12/20/92
Page 3 of9Laboratory: WadsworthDate Reviewed: 4/15/92
SEMIVOLATILE ORGANICSINITIAL CALIBRATION SUMMARY
(Page 2 of 2)
CALCULATION VERIFICATION:
(RRF - Ais/Ax*Cis/Cs)
Compounds: 4-Bromophenyl-phenyletherPPB (44T, 3S) (9T, IS)20 85125/529660 * 2.000 - 0.32150 165232/450508 * 0.800 « 0.29380 146966/277958 * 0.500 - 0.264120 209802/276268 * 0.333 - 0.253160 209890/205123 * 0.250 * 0.256
4-MethyIphenol
AV. RRF - 0.277 %RSD- 10.5%
193724/227412 * 2.000 - 1.704349476/187160 * 0.800 - 1.494278620/98550 * 0.500 - 1.414330240/76524 * 0.333 - 1.438306280/58988 * 0.250 - 1.298
AV. RRF - 1.470 %RSD - 10.2%
OVERALL ASSESSMENT AND COMMENTS: The areas of both the interal standards associatedwith the first two calibration standards were much greater than those of the other standards. This did notaffect the final RFs.
Site Name: National PrestoReviewed by: N. PotakDate Samples Received: 12/20/92
Page 4 of 9Laboratory: WadsworthDate Reviewed: 4/15/92
SEMIVOLATILE ORGANICSCONTINUING CALIBRATION SUMMARY
(page 1 of 2)
Instrument ID: EXTR03Tune File ID: DF1226 Acceptable: yes Time Requirements Met: yesCalibration File ID: SMLI226 Date: 12/26/91 Page: 146Initial Calibration File ID: SL0920 Dale: 9/20/91 Page: 109Associated Samples: SBLK1, EC201, RW16D, RW16FB, RW1601, RW1601MS, RW1601MSD,RW16B,RW16C
TCL COMPOUND LIST(%Diff greater than 25% and non SPCC RRFs less than 0.05 are noted below.
A summary of footnotes is attached as an addendum)
%RSD RRFN-NitosodiphenylaninePhenolAnalinebis(2-Chloroethyl)Ether2-Chlorophenol1.3-Dichlorobenzene1.4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-Propylamine *32%Hexachloroethane * 27 %NitrobenzeneIsophorone2-Nitrophenol2,4-DimethylphenolBenzoic Acidbis(2-Chloroethoxy)Methane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene4-Chloro-3-Melhylphenol2-MethyhiaphthaleneHexachlorocyclopeniadiene2,4,6-Trichlorophenol2,4,5-Trichlorophenol2-Chloronaphthalene2-NitroanalineDimethyl PhthalateAcenaphtbylene3-Nitroanaline
*'s %D Acceptable:Minimum RF's Acceptable:All Compounds Average RRF > 0.05:
%RSD RRFAcenaphthene2,4-Dinitrophenol4-Nitrophenol 59%Dibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiethylphthalate4-ChloropbenyI PhenyletherFluorene4-Nitroanaline 28%4,6-Dinitro-2-MethylphenolN-Nitrosodiphcnylamine4-Bromophenyl-Phenylether * 30%Hexachlorobenzene * 35 %PentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalateFluorantheneBenzidinePyreneButylbenzlphthalate 34%3,3'-DicbJorobenzidineBenzo(a)Anthracenebis(2-elhylhexyl)Phtnalate 37%ChryseneDi-n-Octyl Phthalate 46%Benzo(b)FluorantheneBenzo(k)FluorantheneBenzo(a)PyreneIndeno( 1,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid Surrogates: 2,4,6-Tribromophenol 39%Base Neutral Surrogates
no Footnote: 18yes Footnote:yes Footnote:
All Compounds % RSD less than 25 %: no Footnote: 15
Site Name: National PrestoReviewed by: N. PottkDate Samples Received: 12/20/92
Page 5 of 9Laboratory: WadsworthDate Reviewed: 4/15/92
SEMIVOLATILE ORGANICSCONTINUING CALIBRATION SUMMARY
(page 2 of 2)
CALCULATION VERIFICATION:
(RRF - Ais/Ax*Cis/Cs)
Compounds: 4-NitrophenolPPB
50
Di-n-Octylphlhalatc
20387/143893 * 0.800 - 0.113 205152/138002 * 0.800 - 1.189
% Difference: % Difference:(0.071 - 0,113) / 0.071* 100--59.15493 (0.815 - 1.189) / 0.815 * 100--45.8895
METHOD BLANK: SBLK1 ( Page 163)
Compound1,2-DichlorobenzeneDi-n-butylphthalate
ppb0.9J0.8J
CRDL1010
OVERALL ASSESSMENT AND COMMENTS: see text
SUe Name: National PrestoReviewed by: N. PotakDate Samples Received: 12/20/92
Page 6 of9Laboratory: WadsworthDate Reviewed: 4/15/92
SEMIVOLATILE ORGANIC SCONTINUING CALIBRATION SUMMARY
(page 1 of 2)
Instrument ID: EXTR03Tune File ID: DF1227Calibration File ID: SML1227Initial Calibration File ID: SL0920Associated Samples: MW5A
Acceptable: yesDate: 12/27/91Date: 9/20/91
Time Requirements Met: yesPage: 495Page: 452
TCL COMPOUND LIST(%Diff greater than 25% and non SPCC RRFs less than 0.05 are noted below.
A summary of footnotes is attached as an addendum)
%RSD RRFN-NitosodiphenylaninePhenolAna linebis(2-Chloroethyl)Ether2-Chlorophenol1.3-DichloTobenzene1.4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzcne2-Methylphenolbis(2-chloroisopyI)Ether4-MethylphenolN-Nitroso-Di-n-PropylamineHexachJoroc thaneNitrobenzeneIsopborooe2-Nilrophenol2,4-DimethylphenolBenzoic Acidbis(2-Chloroethoxy)Methane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChJoroanaIincHexachlorobutadiene4-Chloro-3-Methylphenol2-MethylnaphthaleneHexachlorocyclopentadienc2,4,6-Trichlorophenol2,4,5 -Trichlorophenol2-Chloronaphthalene2-NitroanaUneDimethyl PhthalateAcenaphthylene3-Nitroanaline
26%
Acenaphthene2,4-DinitrophenoI4-NitrophenolDibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDie thy Iphtha late4-Chlorophenyl PhenyletherBuorene4-Nitroanaline4,6-Dinitro-2-MethylphenolN-Nitrosodiphenylamine4-Bromopheny I-PhenyletherHexachlorobenzene *PentachlorophenolPhenanthreneAnthraceneDi-n-ButylpbthalateFluorantheneBenzidinePyreneButylbenzlphthalate3,3'-DichlorobenzidineBenzo(a)Anthracenebis(2-ethylhexyl)PhthalateChryseneDi-n-Octyl PhthalateBenzo(b)BuorantbeneBenzo(k)RuorantheneBenzo(a)PyreneIndeno( 1,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid SurrogatesBase Neutral Surrogates
%RSD RRF
34%75%
29%
50%
31%
30%
52%
37%
*'s %D Acceptable: no Footnote: 18Minimum RF's Acceptable: yes Footnote:All Compounds Average RRF > 0.05: yes Footnote:All Compounds % RSD less than 25 %: no Footnote: 15
Site Name: National Presto .Reviewed by: N. PotakDate Samples Received: 12/20/92
Page 7 of9Laboratory: WadsworthDate Reviewed: 4/15/92
SEMIVOLATILE ORGANIC SCONTINUING CALIBRATION SUMMARY
(page 2 of 2)
CALCULATION VERIFICATION:
(RRF - Ais/Ax*Cis/Cs)
Compounds: PhenolPPB
Fluoranthene
50 147028/59385 * 0.800 - 1.981 316552/236076 * 0.800 - 1.073
% Difference: % Difference:(1.875 - 1.981) / 1.875 * 100 - -5.653333 (0.991 - 1.073) / 0.991 * 100 - -8.2744
METHOD BLANK:
Compound
( Page )
ppb <CRDL
OVERALL ASSESSMENT AND COMMENTS: ok
Site Name: National PrestoReviewed by: N". PotakDate Samples Received: 12/20/92
Page 8 of 9Laboratory: WadsworthDate Reviewed: 4/15/92
SEMIVOLATILE ORGANICSCONTINUING CALIBRATION SUMMARY
(page 1 of 2)
Instrument ID: EXTR03Tune File ID: DF1230A Acceptable: yes Time Requirements Met: yesCalibration File ID: SML1230 Date: 12/30/91 Page: 497Initial Calibration File ID: SL0920 Date: 9/20/91 Page: 452Associated Samples: SBLK1, MW5BRE, RW3CRE, MW54CRE, MW38CRE, MW52BRE
TCL COMPOUND LIST(%Diff greater than 25% and non SPCC RRFs less than 0.05 are noted below.
A summary of footnotes is attached as an addendum)
%RSD RRFN-NitosodiphenylaninePhenolAnalinebis(2-Chloroethyl)Ether2-Chlorophenol1.3-Dichlorobenzene1.4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-Propylamine *28%Hexachlorocthanc * 26 %NitrobenzeneIsophorone2-Nitrophenol2,4-DimethylphenolBenzole Acidbis(2-Chloroethoxy)Methane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene4-Chloro-3-Methylphenol * 28 %2-MethylnaphthaleneHexachlorocyclopentadiene2,4,6-Trichlorophcnol2,4,5-Trichlorophenol2-Chloronaphthalene2-Nitroanaline 38%Dimethyl PhthalateAcenaphthylene3-Nitroanaline
%RSDAcenaphthene2,4-Dinitrophenol4-Nitrophenol 48%Dibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiclhylphthalatc4-Chlorophenyl PhenyletherFluorene4-Nitroanaline 31%4,6-Dinitro-2-MethylphenolN-Nitrosodiphenylaniine4-Bromopbenyl-Phenylether 27%Hexachlorobenzene * 32%PentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalateFluorantheneBenzidinePyreneButylbenzlphthalate 29%3,3' -DichlorobenzidineBenzo(a)Anthracenebis(2-ethyIhexyl)Phthalate 32%ChryseneDi-n-Octyl Phthalate 38%Benzo(b)HuorantheneBenzo(k)FluorantheneBenzo(a)PyreneIndeno( 1,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid Surrogates: 2,4,6-TribromophenolBase Neutral Surrogates
RRF
no*'s %D Acceptable:Minimum RF's Acceptable: yesAll Compounds Average RRF > 0.05: yesAll Compounds % RSD less than 25 %: no
Footnote: 18Footnote:Footnote:Footnote: 15
Site Name: National PrestoReviewed by: N. PotakDate Samples Received: 12/20/92
Page 9 of9Laboratory: WadsworthDate Reviewed: 4/15/92
SEMIVOLATILE ORGANICSCONTINUING CALIBRATION SUMMARY
(page 2 of 2)
CALCULATION VERIFICATION:
(RRF - Ais/Ax*Cis/Cs)
Compounds: 4-Chloro-3-methylphenolPPB
50
Benzo(g,h,i)perylene
84405/227428 * 0.800 - 0.297 146718/116292 * 0.800 - 1.009
% Difference:(0.233 - 0.297) / 0.233 * 100 - -27.4678
% Difference:(1.057 - 1.009) / 1.057 * 100 - 4.541154%
METHOD BLANK:
Compound
( Page)
ppb <CRDL
OVERALL ASSESSMENT AND COMMENTS: ok
SDG: EC201
Pesticide Retention Time Verifications
alpha-BHCbeta-BHCdetta-BHCgamma- BHCHeptachkxAWrinHeptachtor EpoxkteEndosulfan IDieMrin4.4'-DDEEndrinEndosulfan I4,4'-DDDEndosutfan Sutfate4,4-'DDTMethoxychtorEndrin KetoneEndrin Aldehydealpha-Chkxdanegamma-Chlordane
Tetrachloro-m-xyteneDecacachlofobiphenyl
MeanR.T.
6.9711.8812.678.509.18
10.1813.2214.2415.8715.5116.7118.9819.0423.3519.8025.2525.5921.1914.9714.62
4.0330.81
R.T.From
6.9211.8312.628.459.13
10.1313.1514.1715.8015.4416.6418.9118.9723.2819.7325.1825.5221.1214.9014.55
3.9630.71
WindowTo
7.0211.9312.728.559.23
10.2313.2914.3115.9415.5816.7819.0519.1123.4219.8725.3225.6621.2615.0414.69
4.1030.91
Page 1
SDG: EC201
Performance Evaluation Mixture Verification
LAB*P1053A1
Date1/2
Time18:26
Page274
alpha BHCgamma-BHCbeta-BHCEndrin4.4'-DOTMethoxychtor
CF14.223,70015.646,9007.116,200
10.821,2757.326,2004.377,525
Area145.659141.27181.626
533,984771.385
1.119.617
NonAmount
0.0100.0100.0100.0500.1000.250
CalcAmount
0.0100.0090.0110.0490.1050.256
RPD-2.4%9.7%
-14.7%1.3%
-5.3%-2.3%
Endrin Breakdown VerificationEA
% Breakdown Area
0% 0
EKArea
DOT Breakdown Verification
% Breakdown
0%
DDEArea
ODDArea
Page 2
SDG: EC201
Performance Evaluation Mixture Verification
LAB*P1052A2
Date1/3
Time4:52
Page278
alpha BHCgamma- BHCbeta-BHCEndrin4,4'-DDTMethoxychtor
CF14.223.70015,646.9007,116.200
10,821.2757,326.2004,377,525
Area145.922143.99082,002
531,325747,923
1,122,195
NonAmount
0.0100.0100.0100.0500.1000.250
CalcAmount
0.0100.0090.0120.0490.1020.256
RPD-2.6%8.0%
-15.2%1.8%
-2.1%-2.5%
Endrin Breakdown VerificationEA
% Breakdown Area
0% 0
EKArea
DOT Breakdown Verification
% Breakdown
0%
DDEArea
DDDArea
Page 3
SDG: EC201
Initial Calibration Verification
TCMXalpha-BHCgamma-BHCHeptachlorEndosutfan IDiefdrinEndrin4.4'-DDD4,4'-DDTMethoxychlorDCB
INDALArea ng CF
67,841 0.005 13,568,20073,773 0.005 14,754,60080.439 0.005 16,087.80081.779 0.005 16,355.80069.772 0.005 13,954.400
120,721 0.01 12.072,100114,764 0.01 11.476.40080,504 0.01 8,050,40093,319 0.01 9.331.900
222.494 0.05 4.449.880112,578 0.01 11.257,800
INDAMArea ng CF
258,382 0.02 12.919.100284,474 0.02 14.223.700312,938 0.02 15,646.900302,212 0.02 15.110,600267,222 0.02 13.361.100458,536 0.04 11.463,400432,851 0.04 10.821,275316,349 0.04 7,908.725293,048 0.04 7.326.200875,505 0.2 4,377.525426,539 0.04 10,663,475
INDAHArea ng CF
851,118 0.08 10.638.9751,136,851 0.08 14.210,6381.216,906 0.08 15,211.3251,110,973 0.08 13,887.163' 987.685 0.08 12,346.0631.724,643 0.16 10,779.0191.608,357 0.16 10,052.2311.222,668 0.16 7.641.6751.153,251 0.16 7,207,8193.161,132 0.8 3,951.4151,466,931 0.16 9,168,319
MEAN12.375,42514,396.31315.648.67515.117.85413,220.52111,438,17310.783.3027,866,9337.955,3064.259.607
10,363,198
%RSD12.42.22.88.26.25.76.62.6
15.06.3
10.4
Page 4
SDG: EC201
TCMXAHrinbeta-BHCdetta-BHCHeptachlor Epoxidegamma-Chlordanealpha-Chtordane4,4'-DDEEndosulfan IIEndrin AldehydeEndosulfan SufateEndrin KetoneDCB
INDBLArea ng CF
63,922 0.005 12,784,40073,138 0.005 14.627,60037,863 0.005 7,572,60065,935 0.005 13,187,00072,461 0.005 14,492,20069,426 0.005 13.885.20073,685 0.005 14.737.000
117.800 0.01 11.780.000111,310 0.01 11,131,00073,649 0.01 7.364.90098,211 0.01 9,821,10096.749 0.01 9,674.900
114,644 0.01 11,464,400
INDBMArea ng CF
232,688 0.02 11,634,400279,133 0.02 13,956,650142.324 0.02 7,116,200266,804 0.02 13,340,200273.867 0.02 13.693,350265,233 0.02 13,261,650271,204 0.02 13.560,200461.733 0.04 11.543,325427,589 0.04 10,689,725305,074 0.04 7,626,850385.248 0.04 9,631,200410.575 0.04 10,264,375433,347 0.04 10,833,675
INDBHArea ng CF
816.104 0.08 10.201,3001.046.537 0.08 13,081,713
509,425 0.08 6,367,8131,053,693 0.08 13,171.163
997,316 0.08 12.466,450981,009 0.08 12.262.613
1.003,831 0.08 12.547,8881,702,369 0.16 10.639,8061,579,268 0.16 9,870;4251,217,721 0.16 7.610,7561.425,746 0.16 8.910,9131,530,202 0.16 9,563,7631,487,991 0.16 9,299,944
MEAN11.540.03313.888,6547,018,871
13,232,78813,550,66713,136,48813,615,02911,321,04410,563,7177,534,1699,454,4049.834.346
10.532.673
%RSD11.25.68.70.77.56.28.05.36.11.95.13.8
10.6
PageS
SDG: EC201
Continuing Calibration Verification
INDALab*:
P1000A2Date1/3
Time18:47
Page
TCMXalpha-BHCgamma-BHCHeptachkxEndosutfan IDtetdrinEndrin4.4'-DDD4.4'-DDTMethoxychtorDCB
CF12,919.10014.223,70015,646,90015.110,60013,361.10011,463.40010,821,2757,908,7257,326,2004,377,525
10,663,475
NonArea Amount
246,530294.765324,153312,903273,413477,046456,726333,848330,942977,930440,640
0.0200.0200.0200.0200.0200.0400.0400.0400.0400.2000.040
CalcAmount
0.0190.0210.0210.0210.0200.0420.0420.0420.0450.2230.041
RPD4.6%
-3.6%-3.6%-3.5%-2.3%-4.0%-5.5%-5.5%
-12.9%-11.7%-3.3%
PageG
SOG: EC201
Continuing Calibration Verification
INDBLabtf:
P1022A2Date1/3
Time0.81
Page
INDB
TCMXAktrinbeta-BHCdelta-BHCHeptachkx Epoxidegamma-Chtordanealpha-Chkxdane4,4'-DDEEndosuKan IIEndrin AldehydeEndosutfan SufateEndrin KetoneDOB
CF12,919,10013,956.6507,116.200
13,340,20013,693.35013.261.65013.560.20011.543.32510,689,7257,626,8509,631,200
10,264,37510,663,475
NonArea Amount
239,483286,215142,858271,642280,711271,912281,692485,208444,218327,134398,043429,260449,186
0.0200.0200.0200.0200.0200.0200.0200.0400.0400.0400.0400.0400.040
CalcAmount
0.0190.0210.0200.0200.0200.0210.0210.0420.0420.0430.0410.0420.042
RPD7.3%
-2.5%-0.4%-1.8%-2.5%-2.5%-3.9%-5.1%-3.9%-7.2%-3.3%-4.6%-5.3%
Page?
SDG: EC201
Florist! Cartridge Check
TCMXalpha-BHCgamma-8 HCHeptachlorEndosulfan IDteWrinEndrin4,4'-DDD4,4'-DDTMethoxychlorDOB
CF12,919,10014.223,70015,646,90015,110,60013,361,10011,463,40010,821.2757,908.7257.326.2004,377,525
10,663,475
Area116,382142,071157,082163,969151,403243,412241,434163,095134,346494,486236,580
SpikeAdded
10.0010.0010.0010.0010.0020.0020.0020.0020.00
100.0020.00
SpikeRec9.019.99
10.0410.8511.3321.2322.3120.6218.34
112.9622.19
%Rec
90.1%99.9%
100.4%108.5%113.3%106.2%111.6%103.1%
91.7%113.0%110.9%
PageS
SDG: EC201
MS Verification
Sample RW1601
TCMXgamma-BHCHeptachk>rAWrinDtetdrinEndrin4,4'-DDTDOB
CF12,919.10015,646,90015,110,60013,956,65011,463,40010.821,2757.326.200
10.663,475
Area189,689693,158643,193894,575
1,084,3231,047,888
779,316127,868
SpikeAdded
0.500.500.501.001.001.00
SpikeRec0.150.440.430.640.950.971.060.12
%Rec
#VALUE!88.6%85.1%
• 128.2%94.6%96.8%
106.4%#VALUE!
QCLimits
56%-40%-40%-52%-56%-38%-
123%131%120%126%121%127%
The aktrin recovery calculated during the data validation did not agree with that reported by the laboratory.The 129% recovery is greater than the upper QC limit.
SDG: EC201
MSD Verificatton
Sample RW1601
TCMXgamma-BHCHeptachbrAkJrinDieldrinEndrin4.4'-DDTDCB
CF12,919,10015,646.90015,110.60013,956.65011,463,40010,821,2757,326.200
10,663.475
Area181,484668,619626,288848,094
1,031,2131,024,876
754,198113,504
SpikeAdded
0.500.500.501.001.001.00
SpikeRec0.140.430.410.610.900.951.030.11
%Rec
WALUEI85.5%
• 82.9%121.5%90.0%94.7%
102.9%#VALUE!
56%40%40%52%56%38%
QCLimits
- 123%-131%- 120%- 126%-121%- 127%
RPD
4%3%5%5%2%3%
QCLimits
152022182127
Page 10
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