NuOOQQ097 eder associates consulting engineers, p. c. · e eder associates consulting engineers, p....

e eder associatesconsulting engineers, p. c.

N u O O Q Q 0 9 7OFFICES

FEDERAL EXPRESS

May 1, 1992File #497-4

Mr. Michael A. GiffordWaste Management DivisionMichigan/Wisconsin Branch

USEPA Region V77 West Jackson-HSRW6JChicago, IL 60604

Re: Monitoring Well SVOC Data,National Presto Industries, Inc.Eau Claire, Wisconsin

Dear Mr. Gifford:

Enclosed are the raw data tables for the results of SVOC analysisof groundwater samples collected from monitoring wells during theNPI site Remedial Investigation. Also enclosed is the datavalidation report for SVOC analysis of monitoring well samplescollected in December 1991.

Please advise if you have any comments or questions.

Very truly yours,

EDER ASSOCIATES CONSULTING ENGINEERS, P.C.

William M. WarrenVice President

WMW:clt

cc: J. Boettcher, WDNR (tables only)R.A. Nauman, NPI (tables only)

#L0501.mg

315 W. HURON STREET. SUITE 240. ANN ARBOR. MICHIGAN 48103 • (313) 663-2144 • FAX (313) 747-653O

3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 D 3 3 3 3 3 3 3 < 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3

3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 D 3 3 3 D 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 < 3 3 3 3 3 3 3 - » 3 : 3 3 3 3 3 3o o o o o o o o o o o o o o o o g o o o o o o o o o e g o g o o o g o g g o o o o o w w o o o g o o i o o o o ^ o o n o o o o o o o

3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 * 3 3 3 3 3 3 3 3 3 3 3 3 3 3

3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 - > 3 3 D 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 - , 3 3 3 3 D 3 3 3 3 3 3 3 3 3 3 3 3 - , 3 3 3 3 3 3 3'

3 3 3 3 3 3 3 3 D 3 3 3 3 3 3 3 - » 3 3 3 3 3 D 3 3 3 3 3 3 3 3 3 3 3 3 3 D 3 D 3 3 3 3 3 3 3 3 3 D 3 < 3 3 3 3 3 3 3 - , 3 D 3 3 3 3 3

3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 - » 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 D 3 3 3 3 3 3 3 3 3

3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 l 3 3 3 3 3 3 3 3 3 3 3 3 3 3 D 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 - D 3 3 3 3 3 3 - , 3 3 3 3 3 3 3S S J J 2 J J 2 2 S S 5 S S J J w 3 2 S 2 2 2 S S 2 5 8 * 8 * * 2 8 * 8 8 2 2 2 2 * 8 8 2 2 * 8 2 * * * 2 2 2 S 5 S S < l l J 2 2 * J 2 2

3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 - 1 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 ^ 3 3 3 3 3 3 3 - 1 3 3 3 3 3 3 3o o o o o o o o o o o o o o e s o o o o o o o o o o o o q o o o o o o o q q o o o o o3582258233 S 8 2 2 2 8 o o Z o o o o o o o o o o o

• 5.c — x ^ Q ° O = p ' 3 . f 5 ;

s 8 > i 5 s • s ^ - 5 « ' 5 8 S * - , , 5 ' " M S? I « M f L• * * * • ' S e - S f c e c - X c• J t - * ' 4 J i J i J i ? S J i

<fcWIW-SVOC.WK1

Monitoring WUta - RMU>U of tomt-VbiuH* AnalyM of Qroundw*Mr SvnptM (*g/n.

Analytto by Wadtwerth UbomtarlM.

WELL:

DATE SAMPLED:

TEMTATfVELY IDEHTIREO COU POUNDS

Nattontf PTMIO InduttrtM, Inc. an*EMJ Ctwra, M«oon«ln.

UW-01 MW-38 MW-M UW-3B

I oinana iI ____

I UW-3A-HE |

01/1WM | 01/1WM | 01/ta/M

UW-3C | UW-4 |

01/1B/M t 01/1WM I 01/20/M I

NonanaD*can«Sulfur. moL(S»)3-ohloro-Cy ctoh« mn*2-Cyoloh«un*-l -on*1 , 2-dlch toro- yeton ««an •4-hy droxy -nMl-2-P*n (anon*N,N-ei 2-hydr Dod*o*namJd*2-*thyM-H«»flol

AJdol Condensation Produol

o -tr™"4 *Dod«canoio addTOTAL 2-<2-«lhovy«tnoxy)-Eth«nolUNKNOWN ACIDUNKNOWN ALDEHYDEUNKNOWN CYCLOOOOECANETOTAL UNKNOWN HYDROCARBONUNKNOWN PHTHALATETOTAL UNKNOWN

— 20J— 80J— 70J_ __ __

_ __ __ _

— —

- -

- -

_ _

— —— 400 J— —— 400 J— 10120 J_ _

20BJ BMJB

——_

20 J20 J8HJ200 J

—

—

-

-

_

——

300 J———

240 JB

———

30 J30 JB90 J——

—

-

-

___

——

20 J_

440 J

_

—100 J—_——

30 J

—

_

-

_

————aoj—

100 J

——

40 J_

——_

—20J

-

10 J

20 J——————10J 20 BJ

* At»o known H 2.2*-oxybb(1-Chloroprop«n«)

I * -* r

M!

C C C C C C C C C C C C C C C ' C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C g

Io S S o o o o o o o o o o o o Z o S S o S o S B o o o o o S S o o o o S S o S o S o o o S o o o o S o S o o o o S o o o S o o S o SC C C C C C C C C C C C C C C ' C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

IW W - « « « - - M W W W U - J 0 - « L , 0 - « - W M « M W M U O « U - W « M « « M C . U M W U « U « U U * *

C C C C C C C C C C C C C C C > C C c C C C c C ^ C C C C C c C c c C C c c C c c c c c c c c c c c C C C C C C C C C C C C C C C C g

I -cic

c c c c c c c c c c c c c c c > c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c €

i i --* -* -^ _ • _ . _ . - - - ^ ^ t l t * — tif - LI G

E E E E E E E E c E i E E E E S E E i E E E E E E E ^ |

cc c c c c c c c c c c c c c c S p C C c c c c c c c c : c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c ^

eE E E E E E E E E E E E E E E E E E E E E E |

S 3

Q:\MW-8VOC. WK1

Monitoring WtM - RMulM at S*ml- .Volute AflAlytM erf OroundwMw tanowt <*g/l).

Analyaia by Wadavonti Uboratork

WELL:

DATE SAMPLED:

Sullur, mol.(8l)

2-Cyotoh*Mfl»- 1 -on*1 .2-dlehtoro-Cydoh«Kan«4-nydroxy-4-fTMl-2-P*ntwton«N.N-bb(2-hydr OddwwnwnU*

S-m« thy t-2-H« xan on«Aldol Condan«kUon Product

Oodcowwlo *oklTOTAL 2-(2-«ihoKy«ihoxv)-€lh«nolUNKNOWN ACIDUNKNOWN ALDEHYDEUNKNOWN CYCLODOOECANETOTAL UNKNOWN HVDOOCAR8ONUNKNOWN PHTHALATETOTAL UNKNOWN

National PTMU InduatriM, Ino. 9MEMJ CUk», WMmonaM.

III 01/20M i oiraona i IO/IVM i IO/IHM i WIVM i IOMVU 10V12/W 10/12/U

TENTATIVELY IDENTIFIED COMPOUNDS

Nonan*

3BJ3J 3J

3J3J3J

3UJ<J

* Alto known M 2.2*-oxybl«41-Chloropropwi*)

aiuw-svoc.vuKi National PTMW lndu«trl«*. Inc. 3H«Eau Oak*. V«Mon*M.

Monitoring VtMUa - RMU!M o* 8a»nt-VoiaiiM Analy** <H QraundwMw tonptaa («/!).

Analytfe by Wad«

WELL

DATE SAW PLED:

Phanolbb(2-Chtoroainyl)athar2-Chlorophanol1.3-Olchlorobanzana1.4-Olchlorobanz*naBanzyl alcohol1,2-Otehlorobaniafia2-Uaihylphanolbta<2-Cnloroi«opropyl)atnaf *4-MathylphanolN-Nltroao-dl-n -propy iarnfnaHaxaohloroath an aNltrooanianakaophorona2-Nltrophanol2.4-Olmaihy Ip ha no*Banzok) acJdbla(2-Chkxoathoxy)(nathana2,4-Otohotorophanol1,2,4, -Trten loroban zan aNaphtnaiana4-CMoroanWn*Haxach lorobu tad la na4-Cn)oro-3-ma thy Iph anol2-Uainylnapntha>«naHauon lorocyolopan tad lana2.4,6-Trlchloraphano!2.4,5-Trtehkorophanol2-Chtofon aph tn aJ« na2-NltroanlllnaDimatnylphthalai*Aoanapthylana2, S-OI nl trotolu a na3-NllroanillnaAoanapthana2.4-Dlnitropnanol4~NltrophanolDlbanzofuran

Dlathylphthalala4-Ch loroprt an y l-p hany la lh«rFluoran*4-Nllroanllfn*4,8-Oin ltro-2-maih y Iph* notN-Nltroaod I p ha n y lamina4-Brofnoph any l-ph an y totnarHa xach loroban tan*Panuehlorop h*nol

Anthraoan*CwbazolaOl-n -B u ty I ph m alaiaRuoramhanaPyranaBu ty Iban zy Ip h th af aia3,3'-Otontofob«nzldlnaBan zo(a)an th raoan •Chrytanabta(2-ElhyttMDl-n-octylphlhalata

Banzo(a)pyr«naInd an o( 1,2.3-od )py r anaDlb« n z'a. h)«n th raca n*Ban zo(g, fi, i)pary tana

UW-6A

,2,10*1

10. U10. U10. Uto. u10. UNA

10. U10. U10. U10. U10. U10. U10. U10. U10. U10. UNA

10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U25. U10. U26. U10. U10. U10. U26. U10. U28. U28- U10. UM). U10. U10. Uto. u25. U26. U10. U10. U10. U2ft. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. Uto. uto. u10. U10. U

| UW-SB |

1 01/20/M |

tou10 Utoutou10 Utou10 U10 U10 U10 U10 U10 U10 U10 U10 Utousou10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Usou10 Usou10 U10 U10 Usou10 Usousou10 U10 U10 U10 U10 Usousou10 U10 U10 UsoutoutouNA10 U10 U10 U10 U20 U10 U10 U8UJ10 U10 U10 U10 U10 U10 UtOU

UW4B

1V11/H

3UJ3UJ3UJ3UJ3UJ3UJ3UJ3UJ3UJ3UJ3UJ3OJ3UJ3UJ3UJ3UJ14 UJ3UJ3UJ .3UJ3UJ3UJ3UJ3UJ3UJ3UJ3UJ14 UJ3UJ14 UJ3UJ3UJ3UJ14 UJ3UJ14 UJ

1 J3UJ3UJ-9J3UJ3UJ14 UJ14 UJ3UJ3UJ3UJ.•J3UJ3UJ

NA.7J3UJ3UJ3UJSUJ3UJ3UJ3UJ3UJ3UJ3UJ3UJSUJ3UJ3UJ

I UW-&B-RE |

| 10/1 1/M |

3U3U3U3U3U3U3U3U3U3U3U3U3U3U3U3U14 U3U3U3U3U3U3U3U3U3U3U14 U3U14 U3U3U3U14 U3U14 U

14 U

3U3U3U3U3U14 U14 U3U3U3U14 U3U3UNA3U3U3U3UOU3U3U3U3U3U3U3U3U3U3U

MW-6B

12f10/«1

10. U10. U10. U10. U10. UNA

10. U10. U10. U10. U10. U10. U10. U10. U10. U10. UNA

10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U28, U10. U26. U10. U10. U10. U26. U10. U25. U

25. U10. U10. U10. U10. U10. U28. U28. U10. Uto. u10. U25.U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U11. BJ10. U10. U10. U10. U10. U10. U10. U

1 UW-5B-flE

I IZMO/fll

10. U10. U10. U10. U10. UNA

10. U10. U10. U10. U10. U10. U10. U10. U10. U10. UNA

10. U10. U10. U10. U10. Uto. u10. U10. U10. U10. U26. U10. U26, U10. U10. U10. U25, U10. U26. U26. U10. U10. U10. U10. U10. U26. U26. U10. U10. U10. U26. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U11. BJto. u10. U10. U10. Uto. u10. Uto. u

OlMBrtt | 01/14/U

11 U11Unu11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 US4U11 U11U11U11 U11 U11 U11 U11 U11 U11 US4U

11US4U11 U11 U11 U64U11 U54U54U11 U11 U11 U11 U11 US4US4U11 U11 U11 U54U11 U11 UNA

11 Utl U11 Utl U22U11 U11 U3J

11 U11 U11 U11 UIt U11 U11 U

11 U11 Utl U3J

11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U56 U11 U11 U11 U11 UIt U11 U11 U11 U11 U11 US6U11 U56 U11 U11 U11 USAU11 U56 U

56U11 U11 U11 U11 U11 U56U5SU11 U11 U11 Uuu11 U11 U

NA11 U

11 U11 U11 U22U11 U11 U3J

n U11 U11 U11 UU UIt Utl U

O:\UW-6VOC. WKl

Monitoring Wtita - RMUIM of 8*ml-Votatte Antfytta at OrauMwMtr SvnptM (M/H.

Analyst by Wadawoflh UborUorlM.

WELL:

DATE SAMPLED:

TENTATrVELY IOENTIFIEO COMPOUNO8

National PTMM> IMutWtM. Irra. Sit*E«u CU«»,

MW-&A MW-U MW-4B

I 12/10/91 | 01/20/U

MW-M-RE | UW-OB | UW-4B-RE I UW-« | UW-7 |

10/1 Iffl* I 12/KW1 | 12nOr»1 | 01/18/M | 01/14/St I

Sulfur, mol.(SS)

S-m»(hyl-2-H* xanon*Aldol Cond*nMllon Produot

OounoleftcM

TOTAL 2-<2-«trioKy*lhaxy)-EthwiolUNKNOWN ACIDUNKNOWN ALDEHYDEUNKNOWN CYCLODOOECANETOTAL UNKNOWN HYDROCARBONUNKNOWN PHTHALATETOTAL UNKNOWN

I —I —I —

3J

4J

9J

3J

M.UJ

2*1J 16. J 20 BJ 20 BJ

nown u 2,2'-oxybi*(1-Criloroprof)Wi«>

a\UW-SVOC.WK1 Mto InduMriM. Ine. SIM, WaoonMn.

UontUring Vtfclto - RMuItt <* Swnl-Votull* AnarytM ot OraundwAttr SvnptM (M)")-

aworth LtbofMorhw.

WELL:

DATE SAMPLED:

Pnanolbla(3-ChloroainyO*tn«f2-Chkxophanol1 ,3-Olohlorobaniana1,4-OtohtorobanzanaBartzyl atoonol1,2-Otohlofobanzana2-MaUiylphanolbla(2-Chiorofaopropyr)aih«r *4-UatfiylphanolN-Nltfoao-dt-n-propylamlnaHaxaehtoroathan*Nltrobanzan*bophorona2-Nttrophanol2.4-OmalhylphanolBanzotoaoidbla(2-Cn lore* thoxy )ma than*2, 4-Diohokxopha nol1 ,2,4, -Trtah lorotoa nzan aNaphthalana4-CnloroanilinaHaxach lorobu tad iana4-Ch tor o-3-mathy Ipnanol2-UaitiylnapnthaJan«Haxaoh lorooyetopan tadlana2,4, 6-Trtoh lorophanol2.4, 6-Trteh lorophanol2-Ch kxonaph lhatan a2-NltroanlimaDimathylphthaJataAoanapthylana2,S-Dlnltrololuan«3-NitroanllinaAoanapthana2,4-Olnltrophanol4-NltrophanolDlbanzoturan2.4-DlnltrotoluanaDJaihyiphihaJaia4-Chkxoph an y l-p h an y la th arRuorana4-Nltroanmna4 , e-Dlnltro-2-m«tn y Iph an OlN-Nltroaod lp ha ny (ami na4-Bromop ha ny l-ph an y la th arHa xach loroba n zanaPantaoh lorophanolPhananthranaAnthracanaCaibazoiaDl-o-bu ty lp h m alataFlu or an tn anaPyranaBuiyloanzylphihalaia3. 3' -Dteh loroba n zkl 1 n aBa nzo(a»r) th raca naCnryaanabia(2-Eihylhaxyl)phihalataDi-n -octy 1 pn in oUiiaBa n zo(b)(1 u or an 1 h an aBan zoGO'1" °ran in anaBanzo(a)pyranalndano( 1 ,2,3-cd)pyranaDUMn z(a. h }an Iti raca naBanzo(g ,h , i)parylan«

UW-M

10/1 1/U

3U3U3U3U3USU3U3USU3U3U3U3U3U3U3U13 USU3USUSUSU3USUSUSUSU13USU13USU3U3U1SU31)13 U13U3U3U3U3U3U13 U13 U3U3U3U13U3U3UNA3U3U3U3USU3U3U2JU3U3U3USU3U3U3U

UW-a*-«

10/11/M

SUJ3UJ3UJ3UJ3UJSUJSUJSUJSUJSUJSUJSUJSUJSUJSUJSUJ13 UJ

SUJSUJSUJSUJSUJSUJSUJSUJSUJSUJ13 UJSUJ13USUJSUJSUJ13 UJ3UJ13 UJ13 UJ3UJ3UJ1 J

3UJ3UJ13 UJ13 UJSUJSUJSUJ13 UJSUJ3UJNA1 J

SUJSUJSUJSUJ3UJ3UJ2JU3UJ3UJSUJSUJ3U3U3U

| UW-10A |

| 10/21/87 |

10 U10 U10 U10 U10 U10U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Usou10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Usou10 Usou10 U10 U10 Usou10 Usousou10 U10 U10 U10 U10 U

SOURsou10 U10 U10 Usou10 U10 UNA10 U10 U10 U10 Usou10 U10 U10 U10 Utou10 U10 U10 U10 U10 U

UW-10A

01/20/M

11 U11 U

11 U11 U11 U11U11 U11 U11 U11 U11 U11 U11 U11 U11 U11U64U11U11U11U11U11U11U11U11U11 U11U54U11U64U11U11U11U64U11U64U54U11U11U11Ut lU11 U54U64U11 U11 U11 U54U11 U11 UNAtl U11U11 U11 U22U11 U11 U11 U11 U11 U11U11U11U11 U11 U

1 UW-10A-FB |

| Q1/20/M |

10 U10 U10 U10 U10 U10 U10 U10 Utoutou10 U10 U10 U10 Utou10US2U10 U10 U10 U10 U10 U10 U10U10 U10 U10 U62U10US2U10 U10 U10 US2U10 US2U52 U10 U10 U10 U10 U10 US2US2U10 U10 U10 US2U10 U10 UNA10 U10 U10 U10 U21 U10 U10 U10 U10 U10 U10 U10 U10 U10 Utou

MW-10A |

10/13/84 |

SUJSUJSUJSUJSUJSUJ3UJSUJSUJSUJSUJSUJSUJSUJSUJSUJ13 UJSUJSUJSUJSUJSUJSUJ3

SUJSUJSUJ13 UJSUJ13 UJ3UJ3UJSUJ13 UJSUJ13 UJ3J

3UJ1 J

3UJSUJ3UJ13 UJ13 UJ1 J

SUJ3UJ3J

SUJSUJNA.9JSUJ2J

SUJSUJ3UJ3UJ,8JU3UJ3UJSUJSUJSUJSUJSUJ

Mw-ioA-ne

10/20/88

3UJSUJSUJSUJSUJ3UJSUJ3UJ3UJSUJSUJSUJSUJ3UJ3UJSUJ13 UJSUJSUJ3UJ3UJ3UJSUJSUJSUJSUJ3UJ13 UJ3UJ13 UJSUJSUJSUJ13 UJSUJ13 UJ13 UJ3UJ3UJ3UJSUJ3UJ13 UJ13 UJSUJSUJ3UJ13 UJSUJ3UJNA3UJ3UJ3UJSUJSUJ3UJ3UJ3UJ3UJ3UJ3UJ3UJSUJ3UJ3UJ

1 UW-10B !

i ioni/i7 i

10 U10 U10 U10 U10 U10U10 U10 U10 U10 U10 U10 Utou10 U10 U10 Usou10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Usou10 Usou10 U10 U10 Usou10 Usousou10 U10 Utou10 U10 U

SOURsou10 U10 U10 Usou10 U10 UNA10 Utou10 U10 U20 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U

a:\UW-SVOC. WK1

Monitoring VMM - RMU!VoUUto Analytic erf OroundwMw SwnptM 0«/f>.

An*y«M by Vfed«worth UboritortM.

WELL:

DATE SAMPLED:

TENTATTVELY IDENTIFIED COMPOUNDS

Nontn*

iMttlM. Inc. 8H»Ecu CUr«. Wteoonwn.

I UW-OA | UW-OA-flE | MW-10A | MW-10A | MW-10A-FB | UW-1QA | MW-IOA-flC I UW-10B

| 1W11/M | 10/11/M | 1IW1/17 1 01/2Q/W 1 01/20/8* | 1Q/13/U | 10V20/M | KV21/S7

I

Sulhif. mol.{3*)3-chloro-Cyoioh* win •2-Cyotoh* xan*- 1 -or*i ,2-d»«hkxo-Cyctoh»x»ft»4-*>y d ro>y-4-m«l-2-P*n unon*

2-«thyl-i-H«xwiolS-m«thy(-2-H« xan on*Aided Cond«nMi)on Productoeunwth -Cy OowtrMHoxan •OeUnotawMOct*d»o*noki »oWOodAoanoto acktTOTAL 2-<2-«tnoxy«tnoxy)-Cfh«nolUNKNOWN ACIDUNKNOWN ALDEHYDEUNKNOWN CYCLOOODECANETOTAL UNKNOWN HYDBOCARBONUNKNOWN PHTHALAT6TOTAL UNKNOWN

3AJ

«J

3J

38J

SJ

* Atoo known M 2,2'-oxybk(1-Chlaropropan*)

O:\UW-SVOC.V*(1

Uonttoring W*H« - HMUIH of Swnt- .Voltttt* Analy** ot Oraundv««r SwnpWt Otg/l).

AnMyvto by VMdiworth UboraWriM.

WELL:

DATE SAMPLED:

Phanolbto<2-C2-Chloroph«nol

1 ,4-Otoh UroMnB*nzyt •loohot

bto<2-ChlorolMpropy<)«lh*r4-4iUthylpft«nolN-NUroM>-dl-n-propyl«mln«

Niirob«nz«n*(•ophoron*

2,4-Olm«tnylpn»nolttenzoloicid

2,4-Oteholofopt>«r>ol1 ,2,4, -Trtch kxob*n »n •Naphthaton*4-Chlofo«f>llln«H« MOh torot) u tad t«n«4-Ch loro-3-m«thy Ip h« no*a-*4» thy In «ph th «]««•H« «*oh loreoyeloptfltad l*n«2,4,0-Trtohkxopn«nol2,4.6-Trlehlofophanol2-Ch loronap h th«t«n«2-Nltro*nllln«DlfTwlhylphthaJAMAo«n«pihyl«n«2.6-Dlnltrololu«n«3-N!trowiil!n«Ac*napth«n«2.4-Olnilroph«nol4-NI1roph»nolDib*nzoluw>2,*-Otnitrot«u»n«

4-Ch tof op h» ny I -p n • ny *• ih • rF!u<x*n«4-NllroBfiilln*4 ,0-Dln Itro- 2-nw tny I ph*nolN-Nf troaod i ph • ny l«n ln«4-arontop h«H« xoc h kxob«n i

CvbuotaOl-n -b u ty ip h th •!• t*

Butylb«nzylpntft«lai«3. 3' -Dtcfi tor o6»n lid In •B*nzo<*)*n<Kr»c*n«Chryi*n»b l«(2 - E Ih y Ihi xy I )p h Ih •!«!•Dl-n -octy I phi h «J«I*8*nzo(b)lluorvilh«n«B*nzo(k)f1uor«n1ti«n*B«nio(«)pyr*n*lnd»no<1 ,

B« n

0*0/1).

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NutonalPr*«iEauCfeir*. '

UW-10B-O

10/21/17

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Usou10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Usou10 Usou10 U10 U10 Usou10 Usousou10 U10 U10Utoutou

SOURsoutou10 U10 Usou10 U10 UNAtou10 U10 U10 U20 U10 U10 U

10 U10 U10 U10 U10 U10 U10 UTOU

to IrtdudrtM, too. SIM

| UW-10B-F8 |

t 10/31/87 |

10 U10 U10 U10 U10 U10 Utoutou10 U10 U10 U10 Utou10 U10 Utousou10 U10 U10 U10 U10 U10 U10 Utou10 U10 Usou10 Usou10 U10 U10 Usou10 Usousou10 Utoutoutoutou

SOURsou10 U

10 U10 Usou10 U10 UNAtoutou10 U10 U20 U10 U10 U10 U10 U10 Utou10 U10 U10 U10 U

UW-10B

01/20/M

11U11U11U11 U11 Utl U11 U11 Utl Utl U11 U11 U11 U11 U11 U11 U54 U11 U11 U .It U11 U11U11U11 U11 U11 U11 US4U11 US4U11 U11 U11 US4U11 US4US4U11 U11 U11 Uit UIt U54U

64U11 U11 U11 U64U11 UIt UNA11 U11 U11 U11U22 U11 U11 U

15tl Utl U11 U11 U11 U11 U11 U

I MW-10B-O-U8O |1 ————— 1I 01/30/U |

NR23 UNA

23 UNR

23U23U23U23U23 UNR

23 U23 U23 U23 U23U110U23U23 UNR

23U23U23UNR

23 U23 U23 U110U23 U110U23 U23U23U110UNR

110UNR

23 UNR

23U23U23U110U110U23 U23U23UNR

23 U23UNA

23U23UNR

23 U4flU23U23U23U23U23Uau23U23U23U23U

UW-11A

01/1 S/M

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Usou10 U10 U10 U10 U10 U10 U10 U10 Utoutousou10 Usoutou10 U10 Usou10 Usousou10 U10 Utou10 U10 Usousou10 U10U10 UMU10 U10 UNA

10 U10 U10 U10 U20 U10 U10 U10 U10 U10 U10 Uto u10 U10 U10 U

UWM1B I MW-13A | UW-12B

01/K/M | 01M6VM

10 U10 U10 U10 U10U10 U10 U10U10U10 U10U10 Utou10 U10 U10 Usou10 U10 U10 U10 U10 U10 U10 U10 U10 U10 UMU10 UMU10 U10 U10 UMU10 UsouMU10 U10 U10 U10 U10 UMUMU10 U10 U10 UMU10 UtouNA10 U10 U10 U10 U20 Utou10 Utou10 U10 U10 U10 U10 Utou10 U

11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11U11US3U11 U11 U11 U11 U11U11 U11 U11 U11 U11 U53U11 US3U11 U11 U11 US3U11 U53U53 U11 U11 U11 U11 U11 U63U63 Utl U11 UIt U53 U11 U11 UNA

11 U11 U11 UU U21 U11 U11 U11 U11 U11 U11 U11 Un U11 U11 U

11 U11Uit U11 U11 Un U11 Uit U11 U11 U11 U11 U11 U11 Uit Uit U7J

11 Uit U11 U11 U11 U11 U11 Uit U11 U11 U53 U11 US3U11 U11 U11 U63 U11 US3US3U11 Uit UM Un UU U&3US3Un U11 Un U63U11 U11 UHA11 Uit Uit Uit U21 U11 Un U11

11 U11 U11 U11 U11 U11 U11 U

O:\MW-SVOC. WK1

Monitoring VJWta - RMUM ol Sarnt-VoUUt* Anatyt* ol OrournhnMr Simplaa <M/Q.

Analytta by Wadaworth LaborttoriM.

WELL:

DATE SAMPLED:

TENTATIVELY IDENTIRED COMPOUNDS

Nonan*

National PTMIO IMuitriM, (no. SlwEau Cl«ir«. Wwoonaln.

UW-10B-D | MW-108-FB I MW-10B | UW-10B-O-USO I UW-11A I UW-llB | UW-12A I UW-128

10V21/17 | 10/21M7 | 01/2WM I 01/20/M | 01/1B/M | 01/1VU I 01J16/M I 01/18/M

Sulfur. mol.(S8)4-ch loro-Cyoloh»jMn«2-Cyolonax«n«- 1 -on*1 ,2-d leh loro-Cyotoh •tun*4-nydrONy-*-m»(-2-P*nunon«

6-mcth y l-2-H« xanon*Aldol CondMMtlon Productocum«ih -Cy dot* irMiloun*

OcUd»c»nok) *cM

TOTAL 2-{2-»thoxy«thoxy)-eth«no(UNKNOWN AGIOUNKNOWN ALDEHYDEUNKNOWN CYCLODOOECANETOTAL UNKNOWN HYDROCARBONUNKNOWN PHTHALATETOTAL UNKNOWN 40 BJ 20 BJ 20 SJ 20 BJ

* Al«o known ai 2.2*-oxybk»(1-Chloropropvi*>

If^?*ifi4 >

C C C C C C C C C C C C C C C ' C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

C C C C C C C t - C C C C C C C ' C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C t - C C C C C C C C C C C C C C C C

c c c c c c c c c c c c c c c ' c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c

c c c c c e c ' - c c c c c c c ' c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c t - c c c c c c c c c c c c c c c c

o o o o O O o ^ o o O o o o o Z o o S o o o o b o o o o o S S o S o o O O O O o o o O o O O O o a S o o o o o o o S o o o S o S o Sc c c c c c c ' - c c c c c c c ' c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c

C C C C C C C C C C C C ? c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c

OSUIW-SVOC.WKI National PTMIO IndutiriM. Ino. SIMEau CUir*. Wtioonttn.

VoltttU AnMytta ot OraundwcWr SvnplM (pQ/l).

Anoly*ta by Wad«wcrth LaboratoriM.

WELL:

DATE SAMPLED:

TENTATIVELV IDENTIFIED COMPOUNDS

NonwMD«cwwSulfur, mol.(Sa>3-cMora-Cvetoh*mn»2-Cyotah«K*n»- 1 -on*

k>h«»n*t-2-P*n unon •

yW-138 I UWM6A

I OV1VH

I ______

UW-108 | MW-17B | UW-178 I MW-17B-RE ! UW-11 I

ot/i«« i of/wu i IWIO/M i KVIO/U i tonivu i

S-m»th y(-2-Aldol Cond*nMi»on Product

TOTAL 2-(2-*mo«y«tnoxy)-ElhanolUNKNOWN ACIDUNKNOWN ALDEHYDEUNKNOWN CYCLOOOOECANETOTAL UNKNOWN HYDROCARBONUNKNOWN PHTHALATETOTAL UNKNOWN

3J

10J

10 J

30 J

3J

20 BJ

• At»o known «• 2,2'-oiiybl«<l-Chtoroprop*n«)

Mf ? 1 S I *11 • 1115 0 2 ? "i! s!5

O |.

IIp j T j £ ) p > 5 y

!f3

ius H= 8fs I

.-iiinn• ' I l in 13 . I 3 Cft IIII2 i

2 5 & ??*5 ?

5 S e S2. * •< 8

t 5S . ?S 2 § I I551if I 57 7 g

Hf3 ? *

Ml3 2 2 s ' «* ft ft S • »

I 5* ft

3- »

I-3 1|8

I I I IIf!1*1* S f t IIII%

s

*

I * i *I i?a*|MiII ftl

• • f•* ^ •

3 S M

M2 A <

I H. i ¥

* ii _ - _

C C C C C C C C C C C C C C C > C c £ c C c £ c c c c c c C c c £ c C c £ c £ c C C C C C C C C c £ c C C C C C C C C C C C C C C C 8 »

§

_ _ _ _ _ _ _ _ o

C C C C C C C ^ C C C C C C t > C C c C C C c c C c 2 c C c c c C c c c C ^ C c c c C C C C C C C c C C C C C C C C C C C C C C C C

Ee

Kc c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c ' c c c c c c c c c c ' c c c c c

Ic c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c ' c c c c c c c c c c ' c c c c c

Ic c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c ' c c c c c c c c c c c c c c c 5

pi

£5Q ft

i12

a:UIW-*VOC.WK1

Uonttorlne VMM - RMUH* ol S*mi- ,VotatH* Analyita ol OraundwMM SwnciM Oe/1).

NMIond PTMIO InduvtrlM. ln«. Sh*

Analytli by Wada

WELL:

DATE SAMPLED:

TEffTATIVELY IDENTIFIED COMPOUNDS

NonamDMWMSuitor, mol.(SS)3-oh tore-CydotM wn«2-Cyeloh*nn*-i -on*1 ,2-dlchloro-Cyeloh«xan«4-hy d rox|f-«-m«t-2-P«n unon*N.N-bb<2-hydr2-«thyl-1-H«)unol

UW-1»-AE

I IQflOVUI ______

UW-24A

1Q/1Q/U

UW-24A-AE

1W1WM

UW-2S I UW-25-RE— • I '

10n2TM | 1W12/M

UW-3&A

12/0a»1 I 12/1 IflM

Aldol Condensation ProductooUm* th-Cydo»ir»tHo«*ii»

Dod»oanolo aoMTOTAL 2-(2-«Ihoxr»trK»(v)-Eth«nolUNKNOWN AGIOUNKNOWN ALDEHYDEUNKNOWN CYCLODODECANETOTAL UNKNOWN HYDROCARBONUNKNOWN PHTHALATETOTAL UNKNOWN

3J 3J

2.JN 2.JN

SJ

• Atao known u Z.

Q:\MW-SVOC. IftKI

UonRorlng W»Ht - R»*utU ol Swni-Voiaiito Analytic of Qroundwottr SamplM (*e/Q.

Anaiyifc by W»dMWth LaboralortM.

National PTMU InduitriM. live. SIMEau Oak*. VMMOn»tn.

WELL:

DATE SAMPLED:

Phanolbb(2-Chloro*thyl)*ih*f2-Chloroph*nol1 ,3-Dtoh lorob*n i*n*1 ,4-Otoh loroto*n i*n*B*nzyl alcohol1 ,2-Ok* loroMn z«n«2-U*thylph«nolbto<2-Chk>»ol*opfopyf)*in*r •4-M*thylph*nolM-NlUoao-dl-n-prooykamM*H* xachloro* than*NI1rob*nz*n*l*ophoron*2-Nltroph*nol2.4-Oim*lhylph*nolB*nioloaoldb l*(2-Ch tor o* ihoxy)m*th an*2,4-O)chotoroph*nol '1 ,2.4, -Trtoh loroMn z*n*N«phthal*n*4-ChloroanUln*HKaohlorobutadfen*4-Ch kxo-3-m* thy lph*nol2-U«Chylnaphttial*n*H« xaoh km>cyolop*n tad l*n*2,4,8-Trlohloroph*nol2.4,6-Trlohloroph«nol2-Ch kxonaphthal*n*2-NltroanlUn*Dtm«lhylphth*J*t»Ac*naplhyl«n«2, 0— Din itrotd u • n •3-NluoAnllln*Ao*napth«n*2, 4-Otri Itroph *nol4-Nltfoph*nolDfb*nzofuran2, 4- Din llrotolu* nmDtotnylphthalau4-Ch toroph *ny l-p h • n y k th *rFluoran*4-NIUoanllln*4,6-Dlnitro-2-m«thylph«nolN-Nitro*od Ip h*ny lamln*4-Bromoph *n y l-p h*ny 1* rh*rH*xaoh torob*n z*n*P*n uoh kxop n *nolPti*nantnr«n»Anthrac*n*Caibazol*Di t-butylphihal«t*Fluor an th*n*Pyt*n*Butylb*nzylphthalal*3, 3' -Olch lorob*n zid In •S»n zo(a)an (h rac*n •Chryftn*bl»(2-Eihylh«icy l)ph lhaiat*Dl-n -octy 1 ph th alawB* n zo(b)ll u or«n Ih «n •B* n io(k )f luoran th»n •B*nzo(«)pyr*n*lnd*no(i ,2,3-od)pyi»n»Ol b*n z< a. h Jan th rac* n«B*nzo<g,h.i)paryt*n*

uw^ue

12/11/91

10. U10. U10. U10. U10. UHA

10. U10. U10. Uto. u10. U10. U10. U10. U10. U10. UHA

10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U28. U10. U26. U10. U10. U10. U26. U10. U25. U26. U10. U10. U10. U10. U10. U26. U28. U10. U10. U10. U26, U10. U10. U10. U10. U10. U10. U10. U10. U10. Uto. u10. U10. U10. U10. U10. U10. U10. U10. U

MW-0*C

12M1/B1

10. U10. U10. U10. U10. UNA

10. U10. U10. U10. U10. U10. U10. Uto. u10. U10. UNA

10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U26. U10. U26. U10. U10. U10. U26. U10. U26. U26. U10. U10. U10. U10. U10. U28. U28. U10. U10. Uto. u26. U10. U10. U10. U10. U10. U10. U10. U

10. U10. U10. U12. BJ10. U10. U10. U

10. U10. U10. U10. U

I UW-3»C-flE

12/11/91 |

10. U10. U10. U10. U10. UHA

10. U10. U10. U10. U10. U10. U10. U10. Uto. u10. UNA

10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U28. U10. U28. U10. U10. U10. U26. U10. U26. U26. U10. U10. U10. U10. U10. U28. U26. U10. Uto. u10. U26. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. Uto. uto. u10. U10. U10. U

uw-*a* i——— 11&1V91 |

10. U10. U10. U

• 10. U10. UNA

10. U10. U10. U10. Uto. u10. U10. U10. U10. U10. UNA

10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U28. U10. U28. U10. U10. U10. U28. U10. U26. U28. U10. U10. U10. U10. U10. U26. U26, U10. Uto. u10. U28, U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U0.9 J10. U10. U10. U10. U10. U10. U10. U

UW-43B

12MW»1

10. U10. U10. U10. U10. UNA

10. U10. U10. U10. U10. U10. U10. U10. U10. U10. UNA

10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U26. U10. U26. U10. U10. U10. U26. U10. U26,1126. U10. U10. U10. U10. U10. U28. U26. U10. U10. U10. U25. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U0.6 J10. U10. U10. U10. U10. U10. U10. U

MW-42A |

12/13/91 |

10. U10. U10. U10. U10. UNA

10. U10. U10. U10. U10. U10. U10. U10. U10. U10. UNA

10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U28, Uto. u28. U10. U10. Uto. u26. U10. U26. U25, U10. U10. U10. U10. U10. U26. U28. U10. U10. U10. U26. U10. Uto. u10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. Uto. uto. u10. U10. U10. U

UW-628

12/13/B1

10. U10. U10. U10. U10. UHA

10. U10. U10. U10. U10. U10. U10. Uto. u10. U10. UHA

10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U28, U10. U28, U10. U10. U10. U28. U10. U28. U26. U10. U10. U10. U10. U10. U26, U28. U10. U10. U10. U25. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. Ua. j

10. U10. U10. U10. U10. U10. U10. U

I UW-428-flE

I 12M3/91

10. U10. J10.lt10. U10. UHA

10. U10. U10. U10. U10. U10. U10. U10. U10. U10. UHA

10. U10. U10. U10. U10. U10. U10. U10, U10. U10. U26. U10. U25. U10. U10. U10. U26. U10. U28. U26. U10. U10. U10. U10. U10. U

2S.U28. U10. U10. U10. U26. U10. U10. Uto. u10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. U10. Uto. u10. U10. U

O:\MW-8VOC. WKl

Uenttartng W*lto - AMUIM o( 8*mt-VoUtM* An*Jy*ta of Qraundmuw 9«mplM Ov/Q-

An«*r«ta by WMtworth UborMOriM.

WELL:

DATE SAMPLED:

NMtontf PTMIO IndutirtM, loo. SlttEau CUfa*. Wiocntin.

UW-3BC-AE I HW-40A MW-43B MW-«2A | UW-62B | MW-&2B-RE

TEHTATIVELY IO€NDFIED COMPOUNDS

Nonwt*

Sulfur,3-oh lero-Cy oW»»

Atdoi CondcniaUon Productoctwncth -Cy otatcff Mil

Oct*d«*no*o addOod»o«noto acidTOTAL 2-<2-«thoxy»lhoxy)-£th«iiolUNKNOWN ACIDUNKNOWN ALDEHYDEUNKNOWN CYCLODODECANETOTAL UNKNOWN HYDROCARBONUNKNOWN PHTHALATETOTAL UNKNOWN

45 JM.US.J

44 J

120 U

12J 303 J

• AJ*o known M 2.2>-oi(ybl*<1 -Chloropropwt*)

n 'o

n 'Oin 'oin 'oin -oin 'Oin'oin'oin 'oin 'oin 'oin 'oin 'oin "szn-oin~otn'oi

n -szn-oi

n'oin'oin'oin-»zn'szn'oin-stn'oi

n'oin'szn-oi

n'oi

n-OL1

n'oin'oin'oin'oin-oi

n-o!VN

n'oin-oin-oin'oi

n-S!

n'OL

n'oiVN

n'oin'oin'oin'oin'oi

I taaijzi I

n 'oin'oin -oin'oin'oin'oin'Oin'Oin'oin'oin'oin'oin'szn'oin-oin-oL

n'szn 'oi

n'oin'oin'oin'szn-szn'oin'szn'oi

n'oin'szn'oi

n'oi

n'oin'oin-oin-oin'OLn'oi

n'oiVN

n'OLfl *OLfl '01n'oin'oi

n'oi

n'oiVN

n'oin 'oin'oin'oin-oi

ie/u/zi

1 O-BC-MH

n'oin'oin'oin'oi

n'oi

n-oin'oin'oi

n'oin'oin'oin'oin'oin'oi

n'szn'oin'oin'oin'szn -92

n'oin'oin'oin'sz

n'oin'szn'oin'oin'oin'szn-oi

n'oin-oin'oin'oin-oin~oin'oin'oin'oi

VN

n'OLn'oi

n'oi

n'oiVN


I iwuffL II ———— iI BC-MH I

n'oin'oin'oin'oin'oin'oin'oin'oin~oin'oin'oin'oin'oin'oin'oin'oin'oin'szn'oin'oin'oin'szn'szn'oin-oin'oin'oin'oin'szn'szn'oin'szn'oin'oin-oin'szn'oin-szn'oin-oin'oimnn'OLn-oin'oin'Oin'oin'oiVN

n'oin'otn'oin'oin'oin'oin*oin'oin'oin-oiVN


Hill..

VC-MU

n'oin'oin'oin'oin'oin'oin'oin'oin'oin'oin'oin-oin'oin'oin'oin'oin-oin'oin*szn'OLn'oin'Oin'szn'szn'oin'oin'oin-oin-oin'szn'szn-oin-sen'oin'oin'oinwn'oin'szn'oin'oin'oin'OLn'OLn*oin'oin-oin-oin-oiVN

n'oin'OLn'Oin'oin-oin'oin'oin'oin'oin'oiVN


i i«uei i

1 3U-OW-MH 1

n'oin'oin'oin'otn'oin'oirroin'oin'oin'oin'oin'oin'oin'oin'oin'oin'oin'oin-szn'oin'otn'OLn'szn-szn "OLn'oin-oin'oin'oin-szn'szn'OLn'szn'oin'oin'oin-»n'oin'szn'oin'oim»n'oin'oin'oin'oin'oin'oin'oiVN

n'oin'oin'oin'oin'oin'oin'oin'oin'oin'oiVN

n'oin-oin'oin*oin'oi

IMiei 1——— 1OW-MFt 1

n'oi

n'oin'oin~oin'oin'oin 01n'oin'oin'oin'oin'oin'oin'oin'oin'oin-oin-szn'oin'oin'oin'szn'szn 'oin'oinpoin'oin'oin'szn'szn'oin'szn'oin'oin'oin-sen'oin-szn'oin-oin'oin'oin'oin-oin'oin'oin'oin'oiVN

n'oin'oin'oin'oin'Oin'oin-oin'oin'oin'oiVN

n'Oin'oin'oin'Oin'oi

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SUMMARY OF THE ANALYTICAL DATA VALIDATIONFor Samples Collected at theNational Presto Solvent Site

Semivolatile and PCB AnalysesWater Samples Received: December 13th & 18th, 1991Sample Delivery Group: MW34ALaboratory Reference Numbers:

MW34A 34318MW34B 34319MW5A 34321MW5B 34322MW38A 34323MW38B 34324RW3A 34325RW3B 34326RW3B Field Blank 34327RW3BD 34328RW2C 34329MW54A 34330MW54B 34331MW54C 34332MW38A 34333MW52A 35238MW52B 35239MW43A 35241MW43B 35242

Water samples were received for semivolatile organic and PCB analyses for theTCL analyte list. The analyses were performed according to the requirements of3/90 EPA CLP Statement of work.

Data Validation Summary

No problems were found with the data that would significantly affect theusability with the following exceptions:

Semivolatile Organics

Five samples (MW5B, RW3C, MW54C, MW38C and MW52B) hadsurrogate recoveries less than the acceptable quality assurance rangein the original analysis. These were re-extracted on December 27th,

fourteen days after receipt by the laboratory. All surrogates werewithin the acceptable range with the exception of two surrogatesassociated with samnle 54C.associated with sample 54C

All of the target compounds detected in both the initial and reanalysisof these five samples were negated due to the presence of thecompounds in the associated method blanks. The concentrations ofnon-target compounds reported in all five samples was generally tentimes greater in the initial analysis than in the reanalysis. The non-target data from the reanalyses may have been degraded due to thetime required for re-extractions.

All target compounds that were detected in the samples were negatedor qualified due to their presence in the associated method blank.

RGB's

Both TCX (33%) and DCS (20%) were less than the 60% advisory limit insample RW3A. The TCX recovery was within the acceptable range (70%)for the filed duplicate of this sample.

DCS recoveries were less than the advisory limit in samples MW34B(34%), MW43B (55%). and RW3BD (33%).

Very low concentrations of RGB's may have been overlooked in thesesamples.

No other problems were detected which would significantly affect the use ofthe data.

Sample Collection and Receipt

The samples which were received on 12/13 were collected from 12/9through 12/11. Those that were received on 12/18 were collected from12/13 through 12/16. All end users of the data should be aware of thetime between sample collection and receipt by the laboratory.

SEMIVOLATILE ORGANICS

A complete analytical data validation was performed based upon thefollowing parameters:

* - Chain of Custody* • Data Completeness* - GC/MS Tuning

- Holding Times- Calibrations

* - Laboratory Blanks* - Field Blanks

- Surrogate Recoveries* - Internal Standard Recoveries

- Matrix Spike / Matrix Spike Duplicate* - Compound Identification* - Compound Quantitation* - Method Detection Limits

* - Indicates that all criteria were met for this parameter.

Holding Times

All samples were originally extracted and analyzed within the requiredholding time from sample receipt. The five samples with low surrogaterecoveries were re-extracted on December 27th, fourteen days afterreceipt by the laboratory.

Calibrations

The initial calibration was performed three months prior to the analyses ofthe samples of this delivery group.

All initial and continuing calibration requirements were met with theexceptions of the % Difference requirements for a few of the targetcompounds. These are noted in detail in the data validation worksheets.None of these were detected in any of the samples of this delivery groupwith the exception of bis(2-ethylhexyl)phthalate. This compound wasnegated in the majority of the samples due to its presence in theassociated method blank. In the two instances where it was not negated,it was flagged with the "J" qualifier and footnoted with #15. Thiscompound will not affect the end use of the data.

Surrogate Recoveries

All surrogate recoveries were within the acceptable range with thefollowing exceptions:

Sample MW38C: There was no recovery of three of the four acidsurrogates in the original analysis. All surrogate recoveries werewithin the acceptable range when the sample was re-extracted andreanalyzed . A 30% recovery was obtained for the phenol-d5surrogate in the reanalysis. This was flagged with the "*" qualifier inthe surrogate summary form (page 2). This recovery is within thestandard acceptable QC range of 10% to 110%.

Samples MW52B, MW5B, and RW3C: The recovery of two acidsurrogates was below the acceptable quality assurance range for all ofthese samples in the original analyses. All surrogate recoveries werewithin the acceptable range when the samples were re-extracted andreanalyzed.

Sample MW54C: The recoveries of three of the four acid surrogateswere below the acceptable quality assurance limits in the originalanalysis of this sample. The samples were re-extracted andreanalyzed, but there was still no recovery of the phenol-d5 surrogate,and only a low recovery (13%) of the 2-chlorophenol-d4 surrogate.The problems with the surrogate recoveries may be due to problemswith the sample matrix. Low concentrations of acid extractablecompounds may not have been detected in this sample.

Matrix Spike / Matrix Spike Duplicate

Sample MW5A of this sample delivery group was used for the MS / MSD.All recoveries and RPD's were within the acceptable range.

Method Blanks

Two method blanks were associated with the initial extraction of thesamples of this delivery group. One method blank was associated withthe 12/27 re-extraction of the five samples with the poor surrogaterecoveries.

Four target compounds were generally detected in the three methodblanks (1,2-dichlorobenzene, 1,2,4-trichlorobenzene, di-n-butylphthalateand bis(2-ethylhexyl)phthalate). All were negated according to thegeneral ERA data validation guidelines when they were detected in thesamples (with the exceptions of two instances of high concentrations of

bls(2-ethylhexyl)phthalate)). These are noted in detail in the datavalidation summary table.

Field Blank

One field blank was collected on December 11th for the samples of thisdelivery group. Low concentrations of 1,2-dichlorobenzene, 1,2,4-trichlorobenzene, di-n-butylphthalate and bis(2-ethylhexyl)phthalate weredetected. All were negated since they were detected in the associatedmethod blank.

Sample Results

Concentrations reported on the sample quant sheets were concentratedby a factor of 2 over the reported value.

Sample RW3B and RW3BD were reported as having the same laboratoryreference number on FORM I. Separate GC/MS file numbers werereported and they were identified separately in the SDG narrative. Thelaboratory was not asked to reissue the forms.

Sample MW38C: There was no recovery for three of the four addsurrogates in the original analysis. All surrogate recoveries were withinthe acceptable range when the same was re-extracted and reanalyzed .A 30% recovery was obtained for the phenol-d5 surrogate in thereanalysis. This was flagged with the "*" qualifier in the surrogatesummary form (page 2). This recovery is within the standard acceptableQC range of 10% to 110%.

Samples MW52B, MW5B, and RW3C: The recoveries of two acidsurrogates were below the acceptable quality assurance range for all ofthese samples in the original analyses. All surrogate recoveries werewithin the acceptable range when the sample was re-extracted andreanalyzed.

Sample MW54C: The recoveries of three of the four acid surrogateswere below the acceptable quality assurance limits in the original analysisof this sample. The samples was re-extracted and reanalyzed but therewas still no recovery of the phenol-d5 surrogate, and a low recovery(13%) of the 2-chlorophenol-d4 surrogate. The problems with thesurrogate recoveries may be due to problems with the sample matrix.Low concentrations of acid extractable compounds may not have beendetected in this sample.

PCB ANALYSES


* - Data Completeness* - Holding Times

- Surrogate Recoveries* - Florisil Cartridge Performance Check* - Analytical Sequence

- Initial Calibration* - Absolute Retention Times* - Performance Evaluation Mixture* - Resolution Check Mixture* - Continuing Calibrations* - Instrument Blanks* - Preparation Blanks

- Field Blanks* - Matrix Spike / Matrix Spike Duplicate* - Compound Identification* - Compound Quantitation* - Method Detection Limits* - Sample Results


Only data from the primary column was reviewed since patterns of PCB's werenot detected in any of the samples.


Both TCX and DCB were used as surrogates, and recoveries weredetermined for both the primary and confirmation columns. All recoverieswere within the acceptable range in the primary column with the exceptionof:

Both TCX (33%) and DCB (20%) were less than the 60% advisory limitin sample RW3A. The TCX recovery was within the acceptable range(70%) for the filed duplicate of this sample.

DCB recoveries were less than the advisory limit in samples MW34B(34%), MW43B (55%), and RW3BD (33%).

Very low concentrations of PCB's may have been overlooked in thesesamples.


Sample MW38A of this sample delivery group was used for the MS /MSD. The sample was spiked with the six standard pesticide TCLcompounds. All recoveries and RPD's were within the acceptable range.Some of the concentrations obtained during the validation were slightlydifferent than those reported by the laboratory. The differences betweenthe two values were not significant.

Preparation Blanks

Two preparation blanks were extracted with the samples of this deliverygroup. One was associated with the samples extracted on 12/19 and theother with the samples extracted on 12/19. Arodors were not detected ineither of the blanks.

Data Summary TableNation* Praato SolvantSlto

PeeooUe end PCB AnetyeoeWater Sample* Receive* 1V13/Q1Sample Delivery Group: MW34A

Sample / Anaivte

MethodBlankCone.fPPB)

ReportedCone.(PPB)

QAVaUdattonReported

Cone.DacWon

QualHter* FootnotM

Sample HW3B Field Blank (Lab ft 34327)

Semlvolatile Organic*1,2-Dtchlorobenzene1,2,4-TnchtorobenzeneDi-n-butyl phlhalatebia(2-ethylhexyl)pnthataiB

Non-Target Semlvolatile Organic*None Detected

PCS'*None Detected

2 J0.6 J

1 J0.5 J

3BJ0.9 BJ

2BJ3 BJ

3 BJ0.9 BJ

2BJ3BJ

negatenegalanegatenegate

1111

SvnpleBMOaA (Lab #: 34318)

Samlvolatlle Organic*Di-n-butytphthataM

Non-Target Semlvolatile Organic*EtnanoJ, 2-{2-«tnoxy«thoxy)- (6.60)

PCB'*None Detected

1.0 J

ND

0.6 JB

2 JN

0.6 JB

2JN

negate

Sample MW348 (Lab #: 34319)

Semlvolatile Organic*None Detected

Non-Target SemlvotatHe Organic*Unknown (4.40)Ethanol, 2-(2-etnoxy«hoxy)- (6.60)

PCS'*None Detected

NDND

2 J2 JN

2 J2 JN

Sample MW38A (Lab #: 34323)

Semlvolatile Organic*1,2-Otchlorobenzene1,2,4-TrichtorobenzeneDi-n-butyl phthalatebis(2-ethylhexyl)phthaJate

2 J0.6 J

1 JO.S J

2 JB0.5 JB0.5 JB0.5 JB

2 JB0.5 JB0.5 JB0.5 JB

negatenegatenegatenegate

1111

Paget

Non-Target Senrtvoiattt* Organic*Unknown (22.00) [Sub*t Benzene]

PCB'eNone Detected

NO a j 6J

Sample MW38B (Lab*:34324)

Semlvolatlle Organic*None Detected

Non-Target Semlvolatlle Organic*None Detected

PCS'*None Detected

Sample MW38C (Lab #: 34333)

Semfvdattle Organic*bw(2-*thylhexy1)phthala»

Non-Target Semlvolatlle Organic*Unknown (6.9)Unknown (7.6)Unknown acid (8.6)Unknown (9.4)Unknown acid (10.5)Unknown (11.5)Unknown (13.2)Unknown (13.3)Unknown (13.6)Unknown (19.0)Unknown (19.9)Unknown (22.7)Unknown (25.9)

0.5 J 12 B 12 B J

NDNONDNDNONDNDNDNDNDNDNDND

32J280 J33 J53 J12 J3J7 J

10 J2 J8 J

10 J6 J5 J

481

32 J280 J33 J53J12 J3 J7 J

10 J2J8 J

10 J6 J5 J

qualify 3,15

Sample MW38C Re-Extracted 12/27

SemlvoJatil* Organic*1,2-Otehtorooenzene1,2,4-TrichiorobenzeneDi-n-butyl phttialatebis(2-ethythexyl)phthalate

Non-Target Semlvolatlle Organic*Unknown (6.0)Ethanol. 2-(2-ethoxyethoxy)- (6.4)Unknown acid (10.1)Unknown (11.2)Unknown (12.9)Unknown (18.6)Unknown (19.5)Unknown (22.3)Unknown (25.5)

PCS'*None Detected

2 J0.7 J

2 J1 J

2 BJ0.5 BJ0.6 BJ

8BJ

2BJ0.5 BJ0.6 BJ

8 BJ


1111

12 J50 J

NDNDNONDNONDND

14 JB68 JBN5 J2 J

12 J6 J6 J4 J2 J

37 Total

14 JB68 JBN5 J2J

12 J6 J6 J4 J2 J

negatenegate

Page 2

Sample MW43A (Lab*3*41)

SemtvohNHe Organioabis(2-etny1hexyl)phthala»

Non-Target Semivoladle Organic*None Detected

PCS'*None Detected

10 U 0.9 J 0.9 J qualify 15

9amptoMW43a (Lab #: 34342)

SwnrvoJatil* Organic*bis(2-ethytnexy1)pnlhalate

Non-Target Semlvolatll* Organic*None Detected

PCB'*None Detected

10 U 0.5 J 0.5 J qualify 15

Sample MWS2A (Lab ft 35238)

Semlvotatlle Organic*None Detected

Non-Target Semlvolatlle Organic*Unknown (5.3)Unknown (16.3)Unknown (22.7)

PCS'*None Detected

NDNDND

5 J5J2 J

5 J5 J2 J

Sample MW52B (Lab #: 35239)

Semlvoietlle Organic*bis(2-ethylhexyt)prithalato

Non-Target Semlvolatile Organic*Unknown (5.0)Unknown (6.3)Unknown (7.2)Unknown (9.2)Unknown (19.8)Unknown (22.7)

10 U 8 J 6 J

NDNDNDNDNDND

14J4 J

270 J4 J8J3J

14 J4 J

270 J4J8 J3 J

qualify 15

Sample MW52B Re-Extracted 12/27

Semlvolatile Organic*1,2-Dlchtorobenzene1,2,4-TnchlorobenzeneDi-n-butyl phthalatebia(2-etnythexyl)pnthalate

2 J0.7 J

2 J1 J

2BJ0.6 BJ

1 BJ7BJ

2 BJ0.6 BJ

1 BJ7BJ


1111

Pag* 3

Ethanoi, 2 -«hoxya«ioxy) (6.4)

PCB'sNone Detected

50 J 120JBN 120 JBN negate

Sample MWS4A (Lab* 34330)

Semlvolatlle Organloebi*<2-ethylhexyl)phthaiate

Non-Target Semlvolatlle Organic*EtttanoJ. 2-(2-ethoxyethoxy) (6.6)

PCB'sNone Detected

0.5 J

ND

2 BJ

3 JN

2 BJ

3 JN

negate

Sample MW54B (Lab fc 34331)

SemlvolatJIe Organic*None Detected

Non-Target Semfvolatile Organic*Unknown (22.9) [Substituted benzene]

PCS'*None Detected

ND 3 J 3 J

Sample MW54C (Lab #: 34332)

Semlvolatlle Organic*bis(2-ethy1hexyt)phthaJa»

Non-Target Semivolatlle Organic*Unknown (5.5)Unknown (7.0)Unknown (7.4)Unknown (8.4)Unknown (9.3)

Sample MW54C Re-Extracted

Semlvolatlle Organic*1,2-Dtehtorobenzene1,2,4-TrichtorobenzeneDi-n-butyl phttialatebis(2-ethy1hexyl)phthalate

Non-Target Semivolatlle Organic*Unknown (4.8)Etnanol, 2-(2-ethoxyethoxy) (6.3)Ethanol, 2-(2-ethoxyethoxy) (6.4)Unknown (7.0)Unknown (22.4)

PCS'*None Detected

0.5 J 1 BJ 1 BJ

NDNDNDNDND

28 J32 J

720 J3 J7 J

790

28J32 J

720 J3 J7J

negate

2 J0.7 J

2 J1 J

2 BJ0.7 BJ

1 BJ2 BJ

2 BJ0.7 BJ

1 BJ2 BJ


1111

NO50 J50 J

NDND

13 J26 JBN36 JBN

220 J7J

240 Total

13 J26 JBN36 JBN

220 J7J

negatenegate

11

Page 4

Sample MW5A (Ubftttttt)

SantfvotaHHa Organic*1,2-Qtohtarobenzan*O-n-butyl phtnalatotw(2-*thylh*xyl)prtth*i«e

Non-Target SemivoJatile Organic*Nona Detected

PCS'*None Detected

2 J1 J

0.5 J

2BJ0.5 BJ0.7 BJ

2BJ0.5 BJ0.7 BJ

negatenegatenegate

Sample MWS8 (Lab*:34322)

Semlvotatlle Organic*W«(2-«ttiylh«xyl}phthaJat*

Non-Targat Samivolatlla Organic*Unknown (5.2)Unknown (6.9)Unknown (7.3)Unknown (9.3)Unknown (13.5)Unknown (19.9)Unknown (21.6)

Sample MWSB Re-Extracted 12/27

Semivolatlle Organic*1,2-DtehtorobenzeneDi-n-outyl phthalatebis(2-ethylhexyl)phthalate

Non-Target Semivolatlle Organic*Unknown (6.0)Ethanol, 2-(2-ethoxyethoxy) (6.4)Unknown (19.5)

PCS'*None Detected

0.5 J

2 J2 J1 J

12 J50 J

NO

ii

2 BJ0.7 BJ11 B

13 JB84 JBN2 J

NDNONDNONDNDND

12 J26 J

230 J4J2 J4J3 J

281

12 J28 J

230 J4J2 J4J3J

26J0.7 BJ11 B J

13 JB84 JBN2 J

negatenegatequaltfy

negatenegate

11

3,15

Sample RW3A (Lab # 34325)

Samlvolatile Organic*1,2-Dichkxobenzene1,2,4-TrichlorobenzaneDi-n-butyl phthalatobis(2-elhylhexyl)phthalate

Non-Target Semivolatlle Organic*Aktol Condensation Product (4.1)Unknown (5.77)Unknown (5.S2)Unknown (5.95)Ethanol, 2-(2-ethoxyethoxy) (6.6)

2 J0.7 J

2 J1 J

3 BJ0.7 BJ0.6 BJ0.5 BJ

3 BJ0.7 BJ0.6 BJ0.5 BJ


1111

NDNDNDNDND

4 JA2 J3 J5 J4JN

4 JA2 J3 J5 J4JN

negate 79

PagaS

per*None Detected

SampleRW3B (Lao*

Samivolaflle Organic*

Non-Target Semlvolattlc Organic*Attoi Condenaatton Product (4.1)

PCB'sNone Detected

NO 2 JA 2 JA negate 79

Samp* RW3BD (Lab #: 34320)

SemivoJatHe Organic*1,2-Oichlorobenzene1,2,4-TrichlorotMnzene

Non-Targtt 3*mlvolatU« Organic*AkW Condensation Product (4.1)

PCB'tNon*D*tact*d

2 J0.6 J

ND

2BJ0.6BJ

4JA

2BJ0.6 BJ

4JA

nagatonegata

nagato 79

Sample RW3C (Lab fc 34329)

S*mlvolatll* Organic*bb(2-ethy1hexyl)phlhalatB

Non-Targ*t SemlvolatH* Organic*Unknown (5.0)Unknown (6.7)Unknown (7.3)Unknown (9.3)

Sampl*RW3C Re-Extracted 12/27

1,2-Oichlorobenzene1,2,4-TrichlorobenzeneDMi-butyl phthalatebia(2-ethylhexyt)phthalate

Non-Target Semlvoladl* Organic*Unknown (6.0)ethanol, 2-(2-e(hoxyetnoxy) (6.4)Unknown (19.5)

0.5 J

12 J50 J

NO

3BJ

13 JB73 JBN2 J

3BJ

NONDNDND

10 J21 J

150 J3 J

10 J21 J

150 J3 J

13 JB73 JBN2 J

negate

2 J0.7 J

2 J1 J

3 BJ0.5 BJ

1 BJ11 B

3 BJ0.5 BJ

1 BJ11 B


1111

negatenegate

Paged

DATA VALIDATION WORSHEETS

For the National Presto Solvent Site

Semivolatile Organic and PCB Analyses

Soil Samples Received: December 13th, 1991

Sample Delivery Group: MW34A

Laboratory Reference Numbers:

MW34A 34318MW34B 34319MW5A 34321MW5B 34322MW38A 34323MW38B 34324RW3A 34325RW3B 34326RW3B Field Blank 34327RW3BD 34328RW2C 34329MW54A 34330MW54B 34331MW54C 34332MW38A 34333MW52A 35238MW52B 35239MW43A 35241MW43B 35242

Site Name: National PrestoReviewed by: N. PotakDmtc Samples Received: 12/13/92

Page 2 of 13Laboratory: WadsworthDate Reviewed: 4/12/92

SEMIVOLATILE ORGAN1CSINITIAL CALIBRATION SUMMARY

(Page 1 of 2)

Instrument ID: EXTR03Tune File ID: DF0920A Acceptable: yes Time Requirements Met: yesCalibration File ID: SL0920 Date: 9/20/91 Page: 452Associated Samples: SBLK3, MW34A, MW34B, MW5AMS, MW5AMSD, MW5B, MW38A,MW38B, RW3A, RW3B, RW3BFB, RW3DB, RW3C, MW54A, MW54B, MW54C, MW38C, SBLK2,MW52A, MW52B, MW43A, MW43B, MW5A, SBLKl, MW5BRE, RW3CRE, MW54CRE,MW38CRE, MW52BRE

TCL COMPOUND LIST(%RSDs > 30% for CCC, all other TCL >35%, RRFs < 0.05 are noted below.

A summary of footnotes is attached as an addendum)%RSD RRF RRF

N-NitosodiphenylaninePhenol *Ana linebis(2-Ch!oroethyl)Ether2-Chlorophenol1.3-Dichlorobenzene1.4-Dichlorobenzene *Benzyl Alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-Propylamine #Hexachloroe thaneNitrobenzeneIsophorone2-Nitrophenol *2,4-DimethylphenolBenzoic Acidbis(2-Chloroethoxy)Methane2,4-Dichlorophenol *1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene *4-Chloro-3-Methylphenol *2-MethylnaphthaleneHexachlorocyclopentadiene #2,4,6-Trichlorophenol *2,4,5-Trichlorophenol2-Chloronaphthalene2-NitroanalineDimethyl PhthalateAcenaphthylene3-Nitroanaline

CCC's Acceptable: yesSPCC's Acceptable: yesAll Compounds Average RRF > 0.05: yesAll Compounds % RSD less than 35 %: no

%RSDAcenaphthene *2,4-Dinitrophenol #4-Nitrophcnol #Dibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiethylphthalate4-Chlorophenyl PhenyletherFluorene4-Nitroanaline4,6-Dinitro-2-MethylphenolN-Nitrosodiphenylamine *4-Bromophenyl-PhenyletherHexachlorobenzenePentachlorophenol *PhenanthreneAnthraceneDi-n-ButylphthalateRuoranthene *BenzidinePyreneButylbenzlphthalate3,3'-DichlorobenzidineBenzo(a)Anthracenebis(2-ethylhexyl)PhthalateChryseneDi-n-Octyl Phthalate *Benzo(b)FluorantheneBenzo(k)RuorantheneBenzo(a)Pyrene *Indeno(l,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid SurrogatesBase Neutral Surrogates

Footnote:Footnote:Footnote:Footnote: 15

36%

Site Name: National PrestoReviewed by: N. PotakDate Samples Received: 12/13/92


SEMIVOLATILE ORGANICSINITIAL CALIBRATION SUMMARY

(Page 2 of 2)

CALCULATION VERIHCATION:

(RRF - Ais/Ax*Cis/Cs)

Compounds: 4-Bromophenyt-phenyletherPPB (44T, 3S)20 85125/529660 * 2.000 - 0.32150 165232/450508 * 0.800 - 0.29380 146966/277958 * 0.500 - 0.264120 209802/276268 * 0.333 - 0.253160 209890/205123 * 0.250 - 0.256

AV. RRF - 0.277 %RSD- 10.5%

4-Methylphcnol(9T, IS)

193724/227412 * 2.000 - 1.704349476/187160 * 0.800 - 1.494278620/98550 * 0.500 - 1.414330240/76524 * 0.333 - 1.438306280/58988 * 0.250 - 1.298

AV. RRF - 1.470 %RSD - 10.2%

OVERALL ASSESSMENT AND COMMENTS: The areas of both the intend standards associatedwith the first two calibration standards were much greater than those of the other standards. This did notaffect the final RFs.



SEMIVOLATILE ORGANIC SCONTINUING CALIBRATION SUMMARY

(page 1 of 2)

Instrument ID: EXTR03Tune File ID: DF1223Calibration File ID: SML1223Initial Calibration File ID: SL0920Associated Samples: SBLK3

Acceptable: yesDate: 12/23/91Date: 9/20/91

Time Requirements Met: yesPage: 489Page: 452

TCL COMPOUND LIST(%Diff greater than 25% and RRFs less than 0.05 are noted below.

A summary of footnotes is attached as an addendum)

%RSD RRFN-NitosodiphenylaninePhenolAnalinebis(2-Chloroethyl)Ether2-Chlorophenol1.3-Dichlorobenzene1.4-DichlorobcnzeneBenzyl Alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-PropylamineHexachloroe thaneNitrobenzeneIsophorone2-Nitrophenol2,4-DimethylphenolBenzoic Acidbis(2-Chloroethoxy )Methane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene4-Chloro-3-Methylphenol2-MethylnaphthaleneHexachlorocyclopentadiene2,4,6-Trichlorophenol2,4,5 -Trichlorophenol2-Chloronaphtha lene2-NitroanalineDimethyl PhthalateAcenaphthylene3-Nitroanaline

27%

29%

%RSD RRFAcenaphthene2,4-Dinitrophenol4-NitrophenolDibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiethylphthalate4-Chlorophenyl PhenyletherFluorene4-NitroanaIine4,6-Dinitro-2-MethylphenolN-Nitrosodiphenylamine4-Bromophenyl-PhenyletherHexachlorobenzene (25%)PentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalateFluorantheneBenzidinePyreneButylbenzlphthalate3,3'-DichlorobenzidineBenzo(a)Anthracenebis(2-ethylhexyl)PhthalateChryseneDi-n-Octyl PhthalateBenzo(b)FluorantheneBenzo(k)FluorantheneBenzo(a)PyreneIndeno( l,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid Surrogates: 2,4,6-TribromophenolBase Neutral Surrogates

34%

no*'s % D Acceptable:Minimum RF's Acceptable: yesAll Compounds Average RRF > 0.05: yesAll Compounds %RSD less than 25%: no

Footnote: 18Footnote:Footnote:Footnote: 15

Site Name: National PrestoReviewed by: N. PoiakDmte Samples Received: 12/13/92


SEMIVOLATILE ORGANICSCONTINUING CALIBRATION SUMMARY

(page 2 of 2)

CALCULATION VERIFICATION:

(RRF • Ais/Ax*Cis/Cs)

Compounds: 1,2-DichlorobenzeoePPB

CCC: Hexachlorobenzenc

50 148298/81824* 0.800 - 1.450 74755/287036 * 0.800 - 0.208

% Difference: % Difference:(1.394 - 1.450) / 1.394 * 100 - -4.0172 (0.294 - 0.208) / 0.294 * 100

29.251

METHOD BLANK: SBLK1 ( Page 558)Associated with all reanalyses

Compound1,2-Dichlorobenzene1,2,4-TrichlorobenzeneDi-n-butylphthalatebis(2-elhy Ihexy OphthalateUnknown (6.0)Ethanol, 2-(2-eihoxvethoxy) (6.4)

ppb2.0J0.7J2.0Jl.OJ12J50J

CRDL10101010NANA

OVERALL ASSESSMENT AND COMMENTS: ok

Site Name: National PrestoReviewed by: N. PotakDale Samples.Received: 12/13/92

Page 6 of 13Laboratory: WadswortbDate Reviewed: 4/12/92


(page 1 of 2)

Instrument ID: EXTR03Tune File ID: DF1224 Acceptable: yes Time Requirements Met: yesCalibration File ID: SML 1224 Date: 12/24/91 Page: 491Initial Calibration File ID: SL0920 Date: 9/20/91 Page: 452Associated Samples: MW34A, MW34B, MW5AMS, MW5AMSD, MW5B, MW38A, MW38B,RW3A, RW3B, RW3BFB, RW3DB, RW3C, MW54A, MW54B, MW54C, MW38C, SBLK2

TCL COMPOUND LIST(%Diff greater than 25% and non SPCC RRFs less than 0.05 are noted below.


%RSD RRFN-NitosodiphenylaninePhenolAnalinebis(2-Chloroethyl)Ether2-Chlorophenol1.3-Dichlorobenzene1.4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-PropylamineHexachloroethaneNitrobenzeneIsophorone2-Nitrophenol2,4-DimethylphenolBenzole Acidbis(2-Chloroethoxy)Methane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene4-Chloro- 3-Methy (phenol2-MethylnaphthaleneHexachlorocyclopentadiene2,4,6-Trichlorophenol2,4,5-Trichlorophenol2-Chloronaphtha lene2-NitroanalineDimethyl PhthalateAcenaphthylene3-Nitroanaline

27%

%RSD RRFAcenaphthene2,4-Dinitrophenol4-Nitrophenol 38%Dibeuzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiethylphthalate4-Chlorophenyl PhenylctherFluorene4-Nitroanaline 30%4,6-Dinilro-2-MelhylphenolN-Nitrosodiphenylamine4-Bromophenyl-PhenyletherHexachlorobcnzene * 30%PentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalateFluorantheneBenzidinePyrene* 28%Butylbenzlphthalate 47%3,3'- DichlorobenzidineBe nzo( a) Anthracenebis(2-ethylhexyl)Phthalate 53%ChryseneDi-n-Octyl Phthalate 38%Benzo(b)FIuorantheneBenzo(k)FluorantheneBenzo(a)PyreneIndeno( 1,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid Surrogates: 2,4,6-Tribromophenol 34%Base Neutral Surrogates

no*'s % D Acceptable:Minimum RF's Acceptable: yesAM Compounds Average RRF > 0.05: yesAll Compounds % RSD less than 25 %: no


Site Name: National Presto Page 7 of 13Reviewed by: N. Potak Laboratory: WadsworthDate Samples Received: 12/13/92 Date Reviewed: 4/12/92


(page 2 of 2)



Compounds: Pyrene N-Nitroso-di-n-propylaminePPB

50 324856/145455* 0.800 - 1.787 74908/67389 * 0.800 - 0.889

% Difference: % Difference:(1.392 - 1.787) / 1,392 * 100 - -28.376 (0.732 - 0.889) / 0.732 * 100 - -21.448087

METHOD BLANK: SBLK2 ( Page 576)

Associated with samples MW43A, MW43B, MW52A, MW52B

Compound ppb CRDL1,2-Dichlorobenzene 0.6J 10Ethanol, 2-(2-ethoxyethoxy) (6.4) 2.0J NA


Site Nmme: National PrestoReviewed by: N. PotakDate Samples Received: 12/13/92

Page 8 of 13Laboratory: WadsworthDale Reviewed: 4/12/92

SEMIVOLATBLE ORGANIC SCONTINUING CALIBRATION SUMMARY

(page 1 of 2)

Instrument ID: EXTR03Tune File ID: DF1226 Acceptable: yesCalibration File ID:SML1226 Date: 12/26/91Initial Calibration File ID: SL0920 Date: 9/20/91Associated Samples: MW52A, MW52B, MW43A, MW43B




%RSD RRFN-NitosodiphenylaninePhenolAna linebis(2-Chloroethyl)Ether2-Chlorophenol1.3-Dichlorobenzene1.4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-Propylamine *32%Hexachloroethane * 27%NitrobenzeneIsophorone2-Nitrophenol2,4-DimethyIphenolBenzoic Acidbis(2-Chloroethoxy)Me thane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene4-Chloro-3-Methylphenol2-MethylnaphthaleneHcxachlorocyclopentadiene2,4,6-Trichlorophenol2,4,5-Trichlorophenol2-Chloronaphthalene2-NitroanalineDimethyl PbthalateAcenaphthylene3-Nitroanaline

*'s %D Acceptable:Minimum RF's Acceptable:All Compounds Average RRF > 0.05:

%RSD RRFAcenaphthene2,4-Dinitrophenol4-Nitrophenol 59%Dibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiethylphtbalate4-Chlorophcnyl PhenyletherFluorene4-Nitroanaline 28%4,6-Dinitro-2-MethylphenolN-Nitrosodiphenylamine4-Bromophenyl-Phenylether * 30%Hexachlotobenzene * 35%PentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalateFluorantheneBenzidinePyreneButylbenzlphthalate 34%3,3'-DichlorobenzidineBenzo(a)Anthracenebis(2-ethylhexyl)Phthalate 37%ChryseneDi-n-Octyl Phthalate 46%Benzo(b)FIuorantheneBenzo(k)FluorantheneBenzo(a)PyreneIndeno( 1,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid Surrogates: 2,4,6-Tribromophenol 39%Base Neutral Surrogates

no Footnote: 18yes Footnote:yes Footnote:

All Compounds % RSD less than 25 %: no Footnote: 15

Site Name: National Presto Page 9 of 13Reviewed by: N. Potak Laboratory: WadsworthDale Samples Received: 12/13/92 Date Reviewed: 4/12/92


(page 2 of 2)



Compounds: 4-Nitrophenol Di-n-OctylphthalatcPPB

50 20387/143893 * 0.800 - 0.113 205152/138002 * 0.800 - 1.189

% Difference: % Difference:(0.071 - 0.113) / 0.071 * 100 - -59.15493 (0.815 -1.189) / 0.815 * 100 - -45.8895


Associated with samples: MW34A, MW34B, MW5AMS, MW5AMSD, MW5B, MW38A,MW38B, RW3A, RW3B, RW3BFB, RW3DB, RW3C, MW54A, MW54B, MW54C, MW38C, MW5A

Compound ppb CRDL1,2-Dichlorobenzene 2.0J 101,2,4-Trichlorobenzene 0.6J 10Di-n-butylphthalate 1 .OJ 10bis(2-ethylhexyl)phthalate 0.5J 10


Site Name: National PrestoReviewed by: N. Potak .Dmte Samples Received: 12/13/92


SEMIVOLATILE ORGAN1CSCONTINUING CALIBRATION SUMMARY

1 of 2)

Instrument ID: EXTR03Tune File ID: DF1227Calibration File ID: SML1227Initial Calibration File ID: SL0920Associated Samples: MW5A





%RSD RRFN-NitosodiphenylaninePhenolAna linebis(2-Chloroethyl)Ether2-ChJorophenoI1.3-Dichlorobenzene1.4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-Propy lamineHexachloroethaneNitrobenzeneIsophorone2-Nitrophenol2,4-DimethyIphenolBenzoic Acidbis(2-Chloroethoxy)Melhane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene4-Chloro-3-Methylphenol2-MethylnaphthaleneHexachlorocyc lopentadiene2,4,6-Trichlorophenol2,4,5 -Trichlorophenol2-Chloronaphthalene2-NitroanalineDimethyl PhthalateAcenaphthylene3-Nitroanaline

26%

Acenaphthene2,4-Dinitropbenol4-NitrophenolDibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDicthylphthalate4-Chlorophenyl PhenyletherPluorene4-Nitroanaline4,6-Dinitro-2-MethylphenolN-Nitrosodipheny lamine4-Bromophenyl-PhenyletherHexachlorobenzenc *PentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalaleFluorantheneBenzidinePyreneButylbenzlphthalate3,3'-DichlorobenzidineBenzo<a)Anthracenebis(2-ethylhexyl)PhtnalateChryseneDi-n-Octyl PhthalateBenzo(b)FluorantheneBenzo(k)FluorantheneBenzo(a)PyreneIndeno( 1,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid SurrogatesBase Neutral Surrogates

%RSD RRF

34%75%

29%

50%

31%

30%

52%

37%

no*'s % D Acceptable:Minimum RF's Acceptable: yesAll Compounds Average RRF > 0.05: yesAll Compounds % RSD less than 25 %: no


Site Name: National Presto Page 11 of 13Reviewed by: N. Potak Laboratory: WadsworthDate Sample* Received: 12/13/92 Date Reviewed: 4/12/92


(page 2 of 2)



Compounds: Phenol FluoranthenePPB

50 147028/59385 * 0.800 - 1.981 316552/236076 * 0.800 - 1.073

% Difference: % Difference:(1.875-1.981) / 1.875* 100 --5.653333 (0.991- 1.073) / 0.991 * 100--8.2744

METHOD BLANK: ( Page )

Compound ppb <CRDL





(P«gelof2)

Instrument ID: EXTR03Tune File ID: DP1230A Acceptable: yes Time Requirements Met: yesCalibration File ID: SML1230 Date: 12/30/91 Page: 497Initial Calibration File ID: SL0920 Date: 9/20/91 Page: 452Associated Samples: SBLKl, MW5BRE, RW3CRE, MW54CRE, MW38CRE, MW52BRE



%RSD RRFN-NitosodiphenylaninePhenolAnalinebis(2-Chloroethyl)Ether2-Chlorophenol1.3-Dichlorobenzene1.4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzene2-Methylphcnolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-Propylaraine *28%Hexachloroethane * 26 %NitrobenzeneIsophorone2-Nitrophenol2,4-DimethylphenolBenzole Acidbis(2-Chloroethoxy)Methane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene4-Chloro-3-Methylphenol * 28 %2-MethylnaphthaleneHexachlorocyclopentadiene2,4,6-Trichlorophenol2,4,5-Trichlorophenol2-Chloronaphthalene2-Nitroanaline 38%Dimethyl PhthalateAcenaphthylene3-Nitroanaline

*'s %D Acceptable:Minimum RF's Acceptable:

%RSDAcenaphthene2,4-Dinitrophenol4-Nitrophenol 48%Dibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiethylphthalate4-Chlorophcny I Phcny IcihcrFluorene4-Nitroanaline 31 %4,6-Dinitro-2-MethylphenolN-Nitrosodiphenylamine4-Bromophenyl-Phenylether 27%Hexachlorobenzene * 32 %PentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalateFluorantheneBenzidlnePyreneButylbenzlphthalate 29%3,3'-DichlorobenzidineBenzo(a)Anthracenebis(2-eihylhexyI)Phthalate 32%ChryseneDi-n-Octyl Phthalate 38%Benzo(b)FluorantheneBenzo<k)FluorantheneBenzo(a)PyreneIndeno( 1,2>3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid Surrogates: 2,4,6-TribromophenolBase Neutral Surrogates

RRF

noyes

All Compounds Average RRF > 0.05: yesAll Compounds % RSD less than 25 %: no


Site Name: National Presto Page 13 of 13Reviewed by: N. Potak Laboratory: WadsworthDate Samples Received: 12/13/92 Date Reviewed: 4/12/92


(page2of2)



Compounds: 4-Chloro-3-methylphenol Benzo(gth4)pciylenePPB

50 84405/227428 * 0.800 - 0.297 146718/116292 * 0.800 - 1.009

% Difference: % Difference:(0.233 - 0.297) / 0.233 * 100 - -27.4678 (1.057 -1.009) /1.057 * 100 - 4.541154%

METHOD BLANK: ( Page)

Compound ppb <CRDL


SDG: MW34A

Pesticide Retention Time Verifications

alpha-BHCbeta-BHCdetta-BHCgamma-BHCHeptachkxAldrinHeptachlor EpoxideEndosutfan IDieldrin4.4'-DDEEndrinEndosutfan I4,4'-DDDEndosuKan Sutfate4,4-'DDTMethoxychlorEndrin KetoneEndrin Aldehydealpha-Chtordanegamma-Chlordane

Tetrachtoro-m-xyleneDecacachlorobiphenyl

MeanR.T.

6.9811.8912.688.519.19

10.1713.2214.2515.8815.5116.7218.9819.0523.3619.8124.2625.5921.1914.9714.62

4.0330.81

R.T.From

6.9311.8412.638.469.14

10.1213.1514.1815.8115.4416.6518.9118.9823.2919.7424.1925.5221.1214.9014.55

3.9830.71

WindowTo

7.0311.9412.738.569.24

10.2213.2914.3215.9515.5816.7919.0519.1223.4319.8824.3325.6621.2615.0414.69

4.0830.91

Pagel

SDG: MW34A

Performance Evaluation Mixture Verification

LAB*PEMA1

P1045A1

alpha BHCgamma- BHCbeta-BHCEndrin4.4'-DDTMethoxychlor

Date1217

Time7:38 pm

Page824

CF13.002,30014.358,3506.701,550

10.495,1507.212,7504.222,320

Area125,820123,19672,210

489,792662,643985.771

NonAmount

0.0100.0100.0100.0500.1000.250

CalcAmount

0.0100.0090.0110.0470.0920.233

RPD3.2%

14.2%-7.8%6.7%8.1%6.6%

Endrin Breakdown VerificationEA

% Breakdown Area

0% 0

EKArea

DOT Breakdown Verification

% Breakdown

0%

DDEArea

DDDArea

0

Page 2

SDG: MW34A


LAB*P1052A4

Date12/24

Time12:02pm

Page826

alpha BHCgamma-BHCbeta-BHCEndrin4.4'-DDTMethoxychlor

CF13,002.30014,358.3506,701,550

10.495,1507.212,7504,222.320

Area142,955140,13781.757

517,158732.362

1.056,382

NonAmount

0.0100.0100.0100.0500.1000.250

CalcAmount

0.0110.0100.0120.0490.1020.250

RPD-9.9%2.4%

-22.0%1.4%

-1.5%-0.1%

Endrin Breakdown VerificationEA EK

% Breakdown Area Area

0% 0 0


% Breakdown

0%

DDEArea

ODDArea

0

Page3

SDG: MW34A


LAB*P1052A5

Date12/25

Time2:28 pm

Page828

alpha BHCgamma-BHCbeta-BHCEndnn4,4'-DDTMethoxychlor

CF13.002.30014.358.3506.701.550

10.495,1507,212.7504.222,320

Area143.482140,29982,001

538.960853.036

1,248,663

NonAmount

0.0100.0100.0100.0500.1000.250

CalcAmount

0.0110.0100.0120.0510.1180.296

RPD-10.4%

2.3%-22.4%-2.7%

-18.3%-18.3%


% Breakdown Area

0% 0

EKArea


% Breakdown

0%

DDEArea

DDDArea

Page 4

SDG: MW34A

Initial Calibration Verification

TCMXalpha-BHCgamma-BHCHeptachtofEndosutfan IDieldrinEndrin4,4'-DDD4.4'-DDTMethoxychtorDCB

INDALArea ng CF

64,283 0.005 12.856.60068.006 0.005 13,601,20076,151 0.005 15,230.20077.543 0.005 15.508.60069,436 0.005 13,887,200

118.474 0.01 11.847.400113.475 0.01 11.347,50080,268 0.01 8,026,80082,602 0.01 8,260,200

218,712 0.05 4,374,24093,779 0.01 9,377,900

INDAUArea ng CF

235.444 0.02 11,772.200260.046 0.02 13,002,300287.167 0.02 14.358.350285,676 0.02 14,283,800255,612 0.02 12,780,600441,221 0.04 11,030,525419,806 0.04 10.495,150306,248 0.04 7,656,200288,510 0.04 7,212.750844,464 0.20 4,222.320412,059 0.04 10,301,475

INDAHArea ng CF

774,480 0.08 9,681,0001,031,249 0.08 12,890,6131.111,755 0.08 13.896,9381,029,788 0.08 12.872,350

928,077 0.08 11,600,9631,625,545 0.16 10,159,6561,516,633 0.16 9,478,9561.146,991 0.16 7,168,6941,076.862 0.16 6,724,1382,953,279 0.80 3,691,5991,386,101 0.16 8,663.131

MEAN11,436,60013,164.70414,495,16314.221,58312.756,25411,012.52710,440,5357.617.2317.399,0294,096,0539,447,502

%RSD14.12.94.79.39.07.79.05.7

10.68.88.7

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SDG: MW34A

Continuing Calibration Verification

INDALab#:

P1000A3Date Time Page12/25 1:15 am 892

TCMXalpha-BHCgamma-BHCHeptachlorEndosutfan IDietdrinEndrin4.4'-DDD4,4'-DDTMethoxychlorDCB

CF11.772.20013.002.30014.358.35014,283.80012.780.60011.030.52510,495,1507.656,2007,212.7504.222,320

10,301,475

NonArea Amount

245,230277.215305.351298.166268,951460,115437,325330,114273.377887.323427,079

0.0200.0200.0200.0200.0200.0400.0400.0400.0400.2000.040

CalcAmount

0.0?10.0210.0210.0210.0210.0420.0420.0430.0380.2100.041

RPD-4.2%-6.6%-6.3%-4.4%-5.2%-4.3%-4.2%-7.8%5.2%

-5.1%-3.6%

Page?

SDG: MW34A


INDBLabtf:

P1022A3Date12/25

Time1:57

Page896

INDB

TCMXAldrinbeta-BHCdetta-BHCHeptachtor Epoxidegamma-Chtofdanealpha-Chlordane4,4'-DDEEndosulfan IIEndrin AldehydeEndosutfan SufateEndrin KetoneDCB

CFn, 772,20012,856.7006,701.550

12,029.90012,775.10012,390,40012,953,25010,844,42510.402,6758,012,0009.470,3509.914,000

10.301,475

NonArea Amount

237,324272,552140,162257,906268,898260,198270,102460,215428,157309,191382,854406,398433.331

0.0200.0200.0200.0200.0200.0200.0200.0400.0400.0400.0400.0400.040

CalcAmount

0.0200.0210.0210.0210.0210.0210.0210.0420.0410.0390.0400.0410.042

RPD-0.8%-6.0%-4.6%-7.2%-5.2%-5.0%-4.3%-6.1%-2.9%3.5%

-1.1%-2.5%-5.2%

PageS

SDQ: MW34A

Florlsll Cartridge Check

Lab*: DateFLORCK1127 12/18

Time8:53

Page900

TCMXalpha-BHCgamma-BHCHeptachtorEndosutfan IDieklrinEndrin4.4'-DDD4,4'-DDTMethoxychbrDOB

CF11,772,20013.002.30014,358.35014,283,80012.780,60011.030,52510.495.1507.656.2007,212,7504,222,320

10.301.475

Area116,382142.071157.082163,969151,403243,412241,434163,095134.346494,486236.580

SpikeAdded

10.0010.0010.0010.0010.0020.0020.0020.0020.00

100.0020.00

SpikeRec9.89

10.9310.9411.4811.8522.0723.0021.3018.63

117.1122.97

%Rec

98.9%109.3%109.4%114.8%118.5%110.3%115.0%106.5%93.1%

117.1%114.8%

Page 9

SDG: MW34A

MS Verification

Sample MW38

TCMXgamma-BHCHeptachlorAWrinDteldrinEndrin4.4'-DDTDCB

CF11.772,20014,358,35014,283,80012,856.70011,030,52510,495,1507.212.750

10,301.475

Area197.419688.278616,262576,289

1.068,0041.031.705

704.783196,406

SpikeAdded

0.500.500.501.001.001.00

SpikeRec0.170.480.430.450.970.980.980.19

%Rec

#VALUEI95.9%86.3%89.6%96.8%98.3%97.7%

#VALUEI

56%40%40%52%56%38%

QCLimits

-123%- 131%-120%-126%-121%-127%

Page 10

SDG: MW34A

MSD Verification

Sample MW38

TCMXgamma-BHCHeptachkxAldrinDfeldrinEndrin4.4'-DDTDCB

CF11,772.20014,358.35014,283,80012,856,70011,030,52510,495,1507.212,750

10.301.475

Area105,916712,296662,303625,714

1,130.3941.110,542

741.530189,871

SpikeAdded

0.500.500.501.001.001.00

SpikeRec0.090.500.460.491.021.061.030.18

%Rec

#VALUEI99.2%92.7%97.3%

102.5%105.8%102.8%

#VALUEI

56%40%40%52%56%38%

QCLimits

-123%-131%-120%-126%-121%-127%

RPD

-3%-7%-8%-6%-7%-5%

QCLimits

152022182127

Page 11

SUMMARY OF THE ANALYTICAL DATA VALIDATIONFor Samples Collected at theNational Presto Solvent Site

Semivolatile and PCB AnalysesWater Samples Received: December 20,1991Sample Delivery Group: EC2-01Laboratory Reference Numbers:

EC2-01 35943RW16-D 35944RW16FB 35945RW1601 35946RW16B 35947RW16C 35948

Water samples were received for semivolatlle organic and PCB analyses for theTCL analyte list. The analyses were performed according to the requirements of3/90 EPA CLP Statement of work.

Data Validation Summary

No problems were found with the data that would significantly affect theusability of the data.

Sample Collection and Receipt

The samples which were received on 12/13 were collected from 12/9through 12/11. Those that were received on 12/18 were collected from12/13 through 12/16. All end users of the data should be aware of thetime between sample collection and receipt by the laboratory.

SEMIVOLATILE ORGANICS


* - Chain of Custody* - Data Completeness* - GC/MS Tuning* - Holding Times

- Calibrations* - Laboratory Blanks

- Field Blanks* - Surrogate Recoveries

- Internal Standard Recoveries- Matrix Spike / Matrix Spike Duplicate

* - Compound Identification* - Compound Quantitation* - Method Detection Limits

* - Indicates that alt criteria were met for this parameter.

Holding Times

AH samples were extracted and analyzed within the required holding timefrom sample receipt.

Calibrations

The initial calibration was performed three months prior to the analyses ofthe samples of this delivery group.

All initial and continuing calibration requirements were met with theexceptions of the % difference requirements for a few of the targetcompounds. These are noted in detail in the data validation worksheets.None of these were detected in any of the samples of this delivery groupwith the exception of bis(2-ethylhexy!)phthalate. This compound wasnegated in the majority of the samples due to its presence in theassociated method blank. In the two instances where it was not negated,it was flagged with the "J" qualifier and footnoted with #15. Thiscompound will not affect the end use of the data.


All surrogate recoveries were within the acceptable quality assurancelimits.


Sample RW1601 of this sample delivery group was used for the MS /MSD. All recoveries and RPD's were within the acceptable range with theexceptions of:

Compound_________MS MSD RPD

4-Chloro-3-methylphenol 19% 17%Acanaphthene 36% 26% 32%Pyrene 24% 14% 53%

It may have been possible that some low concentrations of TCLcompounds may not have been detected in some of the samples of thisdelivery group.

Internal Standards

The areas and retention times of all internal standards were within theacceptable range with the exceptions of the last two internal standards ofthe MS and MSD. These were just below the quality assurance limits.This may have been part of the reason for the low spike recoveries ofseveral of the TCL compounds in the MS and MSD.

Method Blanks

One method blank was associated with the extraction of the samples ofthis delivery group. Three target compounds were detected in the methodblank (1,2-dichlorobenzene, di-n-butylphthalate and bis(2-ethylhexyl)phthalate), Aii were negated according to the general EPA data validationguidelines when they were detected in the samples. These are noted indetail in the data validation summary table.

Field Blanks

One field blank was collected with the samples of this delivery group. Lowconcentrations of 1,2-dichlorobenzene, di-n-butylphthalate, and bis 2-ethyI)phthalate were detected. The 1,2-dichlorobenzene and di-n-butylphthalate were negated due to their presence in the method blank.

Sample Results

Concentrations reported on the sample quant sheets were concentratedby a factor of 2 over the reported value.

No problems were detected with the samples of this delivery group.

PCB ANALYSES


* - Data Completeness* - Holding Times

- Surrogate Recoveries* - Florisil Cartridge Performance Check* - Analytical Sequence* - Initial Calibration* - Absolute Retention Times* - Performance Evaluation Mixture* - Resolution Check Mixture* - Continuing Calibrations* - instrument Blanks .* - Preparation Blanks

- Field Blanks- Matrix Spike / Matrix Spike Duplicate

* - Compound Identification* - Compound Quantitation* - Method Detection Limits* - Sample Results


Only data from the primary column was reviewed since patterns of PCB's werenot detected in any of the samples.


Both TCX and DCS were both used as surrogates, and recoveries weredetermined for both the primary and confirmation columns.

All TCX recoveries were within the acceptable range in the primary andconfirmation columns.

All DCB recoveries were within the acceptable range for the primarycolumn with the one exception of the matrix spike duplicate of sampleRW1601. This is not significant since the DCB recoveries of both thesample itself and the matrix spike were within the acceptable range.

Two of the DCB recoveries were outside of the QC limits for theconfirmation column. This is not significant since no PCB patterns weredetected in the primary column.


Sample RW1601 of this sample delivery group was used for the MS /MSD. The sample was spiked with the six standard pesticide TCLcompounds. All recoveries and RPD's were reported to be within theacceptable range, but the recovery of the aldrin spike could not be verifiedduring the data validation. Recoveries of 129% and 122% were obtained.These are just above the quality control limit of 120%. This is not asignificant problem since all other spike recoveries were within theacceptable range.

Sample Results

No problems were found with any of the samples of this delivery group.

Data Summary TableNational Preeto Solvent Stte

Semlvolatlle and PCB Anatyae*Water Sample* Received: 12/20/V1Sample Delivery Group: EC2-01

Sample I Anatyte

MethodBlankCone.(PPB)

ReportedCone.(PPB)

QAValidationReported

Cone.Decision

Qualifier* Footnote*

RW16 Field Blank (Ub #: 35945)

Semivolatile Organic*1,2-DtchkxobenzeneDi-n-butyl phthaJatebis(2-ethytnexyl)phthaJate

Non-Target Semlvolatlle Organic*None Detected

PCS'*None Detected

0.9 J0.8 J10 U

0.5 BJ0.9 8J0.5 J

0.5 BJ0.9 BJ0.5 J

negatenegate

Sample EC2-01 (Lab #: 35943)

Semivolatile Organic*None Detected

Non-Target Semlvolatlle Organic*Sulfur, mol. (S8)

PCB1*None Detected

ND 3 JN 3JN

Sample RW1601 (Lab #: 35946)

Semlvolatlle Organic*None Detected

Non-Target Semlvolatlle Organic*Unknown (5.3)Ethanol. 2-(2-ethoxyethoxy)- (6.50)Unknown (16.3)Unknown (16.4)

PCS'*None Detected

NDNDNDND

10 J2 JN

12 J3 J

10 J2 JN

12 J3 J

Pagel

Sample RW16B (Lab *: 35947)

SemlvolatHe Organic*None Detected

Non-Target Semlvotatite Organic*Unknown (4.7)

PCB'tNone Detected

ND 7J 7 J

Sample RW16C (Lab #: 35948)

Semlvolatlle Organic*Phenolbis (2-ethylhexyt)pnthalate

Non-Target SemlvolatHe Organic*Unknown (4.7)Unknown (6.5)Unknown (7.2)Unknown (18.9)Unknown (19.8)Unknown (22.6)

PCS'*None Detected

10 U10 U

NDNDNDNDNDND

0.8 J0.7 J

9 J60 J

160 J5 J2 J3 J

0.8 J0.7 J

9 J60 J

160 J5 J2J3J

negate

Sample RW16D (Lab #: 35944)

Semlvolatlle Organic*bis(2-ethy1hexyl)prith»Jate

Non-Target Semlvolatlle Organic*Unknown (4.3)Unknown (4.4)Unknown (5.3)Unknown (16.3)Unknown (16.4)

PCB'sNone Detected

10 U

NDNDNDNDND

0.7 J

2J3 J

14 J12 J3 J

0.7 J

2 J3 J

14 J12 J3 J

negate

Pag* 2

DATA VALIDATION WORSHEETS

For the National Presto Solvent Site

Semivolatile Organic & PCB Analyses

Soil Samples Received: December 20th, 1991

Sample Delivery Group: EC201

Laboratory Reference Numbers:

EC2-01 35943RW16-D 35044RW16FB 35945RW1601 35946RW16B 35947RW16C 35948

Site Name: National Presto .Reviewed by: N. PotakDate Samples Received: 12/20/92

Page 2 of9Laboratory: WadsworthDate Reviewed: 4/15/92


(Page 1 of 2)

Instrument ID: EXTR03Tune File ID: DF0920A Acceptable: yes Time Requirements Met: yesCalibration File ID: SL0920 Date: 9/20/91 Page: 109Associated Samples: SBLKl, EC201, RW16D, RW16FB, RW1601, RW160IMS, RW1Q01MSD,RW16B,RW16C

TCL COMPOUND LIST(%RSDs > 30% for CCC, all other TCL >35%, RRFs < 0.05 are noted below.

A summary of footnotes is attached as an addendum)%RSD RRF RRF

N-NitosodiphenylaninePhenol *Analinebis(2-Chloroethyl)Ether2-ChJorophenol1.3-Dichlorobenzene1.4-Dichlorobenzene *Benzyl Alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-Propylamine #HexachloroethaneNitrobenzeneIsophorone2-Nitrophenol *2,4-DimethyiphenolBenzole Acidbis(2-Chloroethoxy)Methane2,4-Dichlorophenol *1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene *4-Chloro-3-Methylphenol *2-MethylnaphthaleneHexachlorocyclopentadiene #2,4,6-Trichlorophenol *2,4,5-Trichlorophenol2-Chloronaphthalene2-NitroanalineDimethyl PhthalateAcenaphthylene3-Nitroanaline

CCC's Acceptable: yesSPCC's Acceptable: yesAll Compounds Average RRF > 0.05: yesAll Compounds % RSD less than 35 %: no

%RSDAcenaphthene *2,4-Dinitrophenol #4-Nitrophenol #Dibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiethylphlhalate4-Chlorophenyl PhenyletherRuorene4-Nitroanaline4,6-Dinitro-2-MethylphenolN-Nitrosodiphenylamine *4-Bromophenyl-PhenyletherHexachlorobenzenePentachlorophenol *PhenanthreneAnthraceneDi-n-ButylphthalateRuoranthene *BenzidinePyreneButylbenzlphthalate3,3'-DichlorobenzidincBenzo(a)Anthracenebis(2-ethylhexyl)PhtnalateChryseneDi-n-Octyl Phthalate *Benzo(b)FluorantheneBenzo(k)FluonuitheneBenzo(a)Pyrene *Indeno( 1,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid SurrogatesBase Neutral Surrogates

Footnote:Footnote:Footnote:Footnote: 15

36%

Site Name: National PrestoReviewed by: N" PotakDate Samples Received: 12/20/92



(Page 2 of 2)



Compounds: 4-Bromophenyl-phenyletherPPB (44T, 3S) (9T, IS)20 85125/529660 * 2.000 - 0.32150 165232/450508 * 0.800 « 0.29380 146966/277958 * 0.500 - 0.264120 209802/276268 * 0.333 - 0.253160 209890/205123 * 0.250 * 0.256

4-MethyIphenol

AV. RRF - 0.277 %RSD- 10.5%

193724/227412 * 2.000 - 1.704349476/187160 * 0.800 - 1.494278620/98550 * 0.500 - 1.414330240/76524 * 0.333 - 1.438306280/58988 * 0.250 - 1.298

AV. RRF - 1.470 %RSD - 10.2%

OVERALL ASSESSMENT AND COMMENTS: The areas of both the interal standards associatedwith the first two calibration standards were much greater than those of the other standards. This did notaffect the final RFs.




(page 1 of 2)

Instrument ID: EXTR03Tune File ID: DF1226 Acceptable: yes Time Requirements Met: yesCalibration File ID: SMLI226 Date: 12/26/91 Page: 146Initial Calibration File ID: SL0920 Dale: 9/20/91 Page: 109Associated Samples: SBLK1, EC201, RW16D, RW16FB, RW1601, RW1601MS, RW1601MSD,RW16B,RW16C



%RSD RRFN-NitosodiphenylaninePhenolAnalinebis(2-Chloroethyl)Ether2-Chlorophenol1.3-Dichlorobenzene1.4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-Propylamine *32%Hexachloroethane * 27 %NitrobenzeneIsophorone2-Nitrophenol2,4-DimethylphenolBenzoic Acidbis(2-Chloroethoxy)Methane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene4-Chloro-3-Melhylphenol2-MethyhiaphthaleneHexachlorocyclopeniadiene2,4,6-Trichlorophenol2,4,5-Trichlorophenol2-Chloronaphthalene2-NitroanalineDimethyl PhthalateAcenaphtbylene3-Nitroanaline

*'s %D Acceptable:Minimum RF's Acceptable:All Compounds Average RRF > 0.05:

%RSD RRFAcenaphthene2,4-Dinitrophenol4-Nitrophenol 59%Dibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiethylphthalate4-ChloropbenyI PhenyletherFluorene4-Nitroanaline 28%4,6-Dinitro-2-MethylphenolN-Nitrosodiphcnylamine4-Bromophenyl-Phenylether * 30%Hexachlorobenzene * 35 %PentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalateFluorantheneBenzidinePyreneButylbenzlphthalate 34%3,3'-DicbJorobenzidineBenzo(a)Anthracenebis(2-elhylhexyl)Phtnalate 37%ChryseneDi-n-Octyl Phthalate 46%Benzo(b)FluorantheneBenzo(k)FluorantheneBenzo(a)PyreneIndeno( 1,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid Surrogates: 2,4,6-Tribromophenol 39%Base Neutral Surrogates

no Footnote: 18yes Footnote:yes Footnote:

All Compounds % RSD less than 25 %: no Footnote: 15

Site Name: National PrestoReviewed by: N. PottkDate Samples Received: 12/20/92



(page 2 of 2)



Compounds: 4-NitrophenolPPB

50

Di-n-Octylphlhalatc

20387/143893 * 0.800 - 0.113 205152/138002 * 0.800 - 1.189

% Difference: % Difference:(0.071 - 0,113) / 0.071* 100--59.15493 (0.815 - 1.189) / 0.815 * 100--45.8895


Compound1,2-DichlorobenzeneDi-n-butylphthalate

ppb0.9J0.8J

CRDL1010

OVERALL ASSESSMENT AND COMMENTS: see text

SUe Name: National PrestoReviewed by: N. PotakDate Samples Received: 12/20/92



(page 1 of 2)

Instrument ID: EXTR03Tune File ID: DF1227Calibration File ID: SML1227Initial Calibration File ID: SL0920Associated Samples: MW5A





%RSD RRFN-NitosodiphenylaninePhenolAna linebis(2-Chloroethyl)Ether2-Chlorophenol1.3-DichloTobenzene1.4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzcne2-Methylphenolbis(2-chloroisopyI)Ether4-MethylphenolN-Nitroso-Di-n-PropylamineHexachJoroc thaneNitrobenzeneIsopborooe2-Nilrophenol2,4-DimethylphenolBenzoic Acidbis(2-Chloroethoxy)Methane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChJoroanaIincHexachlorobutadiene4-Chloro-3-Methylphenol2-MethylnaphthaleneHexachlorocyclopentadienc2,4,6-Trichlorophenol2,4,5 -Trichlorophenol2-Chloronaphthalene2-NitroanaUneDimethyl PhthalateAcenaphthylene3-Nitroanaline

26%

Acenaphthene2,4-DinitrophenoI4-NitrophenolDibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDie thy Iphtha late4-Chlorophenyl PhenyletherBuorene4-Nitroanaline4,6-Dinitro-2-MethylphenolN-Nitrosodiphenylamine4-Bromopheny I-PhenyletherHexachlorobenzene *PentachlorophenolPhenanthreneAnthraceneDi-n-ButylpbthalateFluorantheneBenzidinePyreneButylbenzlphthalate3,3'-DichlorobenzidineBenzo(a)Anthracenebis(2-ethylhexyl)PhthalateChryseneDi-n-Octyl PhthalateBenzo(b)BuorantbeneBenzo(k)RuorantheneBenzo(a)PyreneIndeno( 1,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid SurrogatesBase Neutral Surrogates

%RSD RRF

34%75%

29%

50%

31%

30%

52%

37%

*'s %D Acceptable: no Footnote: 18Minimum RF's Acceptable: yes Footnote:All Compounds Average RRF > 0.05: yes Footnote:All Compounds % RSD less than 25 %: no Footnote: 15

Site Name: National Presto .Reviewed by: N. PotakDate Samples Received: 12/20/92



(page 2 of 2)



Compounds: PhenolPPB

Fluoranthene

50 147028/59385 * 0.800 - 1.981 316552/236076 * 0.800 - 1.073

% Difference: % Difference:(1.875 - 1.981) / 1.875 * 100 - -5.653333 (0.991 - 1.073) / 0.991 * 100 - -8.2744

METHOD BLANK:

Compound

( Page )

ppb <CRDL


Site Name: National PrestoReviewed by: N". PotakDate Samples Received: 12/20/92



(page 1 of 2)

Instrument ID: EXTR03Tune File ID: DF1230A Acceptable: yes Time Requirements Met: yesCalibration File ID: SML1230 Date: 12/30/91 Page: 497Initial Calibration File ID: SL0920 Date: 9/20/91 Page: 452Associated Samples: SBLK1, MW5BRE, RW3CRE, MW54CRE, MW38CRE, MW52BRE



%RSD RRFN-NitosodiphenylaninePhenolAnalinebis(2-Chloroethyl)Ether2-Chlorophenol1.3-Dichlorobenzene1.4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-chloroisopyl)Ether4-MethylphenolN-Nitroso-Di-n-Propylamine *28%Hexachlorocthanc * 26 %NitrobenzeneIsophorone2-Nitrophenol2,4-DimethylphenolBenzole Acidbis(2-Chloroethoxy)Methane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChloroanalineHexachlorobutadiene4-Chloro-3-Methylphenol * 28 %2-MethylnaphthaleneHexachlorocyclopentadiene2,4,6-Trichlorophcnol2,4,5-Trichlorophenol2-Chloronaphthalene2-Nitroanaline 38%Dimethyl PhthalateAcenaphthylene3-Nitroanaline

%RSDAcenaphthene2,4-Dinitrophenol4-Nitrophenol 48%Dibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiclhylphthalatc4-Chlorophenyl PhenyletherFluorene4-Nitroanaline 31%4,6-Dinitro-2-MethylphenolN-Nitrosodiphenylaniine4-Bromopbenyl-Phenylether 27%Hexachlorobenzene * 32%PentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalateFluorantheneBenzidinePyreneButylbenzlphthalate 29%3,3' -DichlorobenzidineBenzo(a)Anthracenebis(2-ethyIhexyl)Phthalate 32%ChryseneDi-n-Octyl Phthalate 38%Benzo(b)HuorantheneBenzo(k)FluorantheneBenzo(a)PyreneIndeno( 1,2,3-cd)PyreneDibenz(a)AnthraceneBenzo(a)PeryleneAcid Surrogates: 2,4,6-TribromophenolBase Neutral Surrogates

RRF

no*'s %D Acceptable:Minimum RF's Acceptable: yesAll Compounds Average RRF > 0.05: yesAll Compounds % RSD less than 25 %: no





(page 2 of 2)



Compounds: 4-Chloro-3-methylphenolPPB

50

Benzo(g,h,i)perylene

84405/227428 * 0.800 - 0.297 146718/116292 * 0.800 - 1.009

% Difference:(0.233 - 0.297) / 0.233 * 100 - -27.4678

% Difference:(1.057 - 1.009) / 1.057 * 100 - 4.541154%

METHOD BLANK:

Compound

( Page)

ppb <CRDL


SDG: EC201

Pesticide Retention Time Verifications

alpha-BHCbeta-BHCdetta-BHCgamma- BHCHeptachkxAWrinHeptachtor EpoxkteEndosulfan IDieMrin4.4'-DDEEndrinEndosulfan I4,4'-DDDEndosutfan Sutfate4,4-'DDTMethoxychtorEndrin KetoneEndrin Aldehydealpha-Chkxdanegamma-Chlordane

Tetrachloro-m-xyteneDecacachlofobiphenyl

MeanR.T.

6.9711.8812.678.509.18

10.1813.2214.2415.8715.5116.7118.9819.0423.3519.8025.2525.5921.1914.9714.62

4.0330.81

R.T.From

6.9211.8312.628.459.13

10.1313.1514.1715.8015.4416.6418.9118.9723.2819.7325.1825.5221.1214.9014.55

3.9630.71

WindowTo

7.0211.9312.728.559.23

10.2313.2914.3115.9415.5816.7819.0519.1123.4219.8725.3225.6621.2615.0414.69

4.1030.91

Page 1

SDG: EC201


LAB*P1053A1

Date1/2

Time18:26

Page274

alpha BHCgamma-BHCbeta-BHCEndrin4.4'-DOTMethoxychtor

CF14.223,70015.646,9007.116,200

10.821,2757.326,2004.377,525

Area145.659141.27181.626

533,984771.385

1.119.617

NonAmount

0.0100.0100.0100.0500.1000.250

CalcAmount

0.0100.0090.0110.0490.1050.256

RPD-2.4%9.7%

-14.7%1.3%

-5.3%-2.3%


% Breakdown Area

0% 0

EKArea


% Breakdown

0%

DDEArea

ODDArea

Page 2

SDG: EC201


LAB*P1052A2

Date1/3

Time4:52

Page278

alpha BHCgamma- BHCbeta-BHCEndrin4,4'-DDTMethoxychtor

CF14.223.70015,646.9007,116.200

10,821.2757,326.2004,377,525

Area145.922143.99082,002

531,325747,923

1,122,195

NonAmount

0.0100.0100.0100.0500.1000.250

CalcAmount

0.0100.0090.0120.0490.1020.256

RPD-2.6%8.0%

-15.2%1.8%

-2.1%-2.5%


% Breakdown Area

0% 0

EKArea


% Breakdown

0%

DDEArea

DDDArea

Page 3

SDG: EC201

Initial Calibration Verification

TCMXalpha-BHCgamma-BHCHeptachlorEndosutfan IDiefdrinEndrin4.4'-DDD4,4'-DDTMethoxychlorDCB

INDALArea ng CF

67,841 0.005 13,568,20073,773 0.005 14,754,60080.439 0.005 16,087.80081.779 0.005 16,355.80069.772 0.005 13,954.400

120,721 0.01 12.072,100114,764 0.01 11.476.40080,504 0.01 8,050,40093,319 0.01 9.331.900

222.494 0.05 4.449.880112,578 0.01 11.257,800

INDAMArea ng CF

258,382 0.02 12.919.100284,474 0.02 14.223.700312,938 0.02 15,646.900302,212 0.02 15.110,600267,222 0.02 13.361.100458,536 0.04 11.463,400432,851 0.04 10.821,275316,349 0.04 7,908.725293,048 0.04 7.326.200875,505 0.2 4,377.525426,539 0.04 10,663,475

INDAHArea ng CF

851,118 0.08 10.638.9751,136,851 0.08 14.210,6381.216,906 0.08 15,211.3251,110,973 0.08 13,887.163' 987.685 0.08 12,346.0631.724,643 0.16 10,779.0191.608,357 0.16 10,052.2311.222,668 0.16 7.641.6751.153,251 0.16 7,207,8193.161,132 0.8 3,951.4151,466,931 0.16 9,168,319

MEAN12.375,42514,396.31315.648.67515.117.85413,220.52111,438,17310.783.3027,866,9337.955,3064.259.607

10,363,198

%RSD12.42.22.88.26.25.76.62.6

15.06.3

10.4

Page 4

SDG: EC201

TCMXAHrinbeta-BHCdetta-BHCHeptachlor Epoxidegamma-Chlordanealpha-Chtordane4,4'-DDEEndosulfan IIEndrin AldehydeEndosulfan SufateEndrin KetoneDCB

INDBLArea ng CF

63,922 0.005 12,784,40073,138 0.005 14.627,60037,863 0.005 7,572,60065,935 0.005 13,187,00072,461 0.005 14,492,20069,426 0.005 13.885.20073,685 0.005 14.737.000

117.800 0.01 11.780.000111,310 0.01 11,131,00073,649 0.01 7.364.90098,211 0.01 9,821,10096.749 0.01 9,674.900

114,644 0.01 11,464,400

INDBMArea ng CF

232,688 0.02 11,634,400279,133 0.02 13,956,650142.324 0.02 7,116,200266,804 0.02 13,340,200273.867 0.02 13.693,350265,233 0.02 13,261,650271,204 0.02 13.560,200461.733 0.04 11.543,325427,589 0.04 10,689,725305,074 0.04 7,626,850385.248 0.04 9,631,200410.575 0.04 10,264,375433,347 0.04 10,833,675

INDBHArea ng CF

816.104 0.08 10.201,3001.046.537 0.08 13,081,713

509,425 0.08 6,367,8131,053,693 0.08 13,171.163

997,316 0.08 12.466,450981,009 0.08 12.262.613

1.003,831 0.08 12.547,8881,702,369 0.16 10.639,8061,579,268 0.16 9,870;4251,217,721 0.16 7.610,7561.425,746 0.16 8.910,9131,530,202 0.16 9,563,7631,487,991 0.16 9,299,944

MEAN11.540.03313.888,6547,018,871

13,232,78813,550,66713,136,48813,615,02911,321,04410,563,7177,534,1699,454,4049.834.346

10.532.673

%RSD11.25.68.70.77.56.28.05.36.11.95.13.8

10.6

PageS

SDG: EC201


INDALab*:

P1000A2Date1/3

Time18:47

Page

TCMXalpha-BHCgamma-BHCHeptachkxEndosutfan IDtetdrinEndrin4.4'-DDD4.4'-DDTMethoxychtorDCB

CF12,919.10014.223,70015,646,90015.110,60013,361.10011,463.40010,821,2757,908,7257,326,2004,377,525

10,663,475

NonArea Amount

246,530294.765324,153312,903273,413477,046456,726333,848330,942977,930440,640

0.0200.0200.0200.0200.0200.0400.0400.0400.0400.2000.040

CalcAmount

0.0190.0210.0210.0210.0200.0420.0420.0420.0450.2230.041

RPD4.6%

-3.6%-3.6%-3.5%-2.3%-4.0%-5.5%-5.5%

-12.9%-11.7%-3.3%

PageG

SOG: EC201


INDBLabtf:

P1022A2Date1/3

Time0.81

Page

INDB

TCMXAktrinbeta-BHCdelta-BHCHeptachkx Epoxidegamma-Chtordanealpha-Chkxdane4,4'-DDEEndosuKan IIEndrin AldehydeEndosutfan SufateEndrin KetoneDOB

CF12,919,10013,956.6507,116.200

13,340,20013,693.35013.261.65013.560.20011.543.32510,689,7257,626,8509,631,200

10,264,37510,663,475

NonArea Amount

239,483286,215142,858271,642280,711271,912281,692485,208444,218327,134398,043429,260449,186

0.0200.0200.0200.0200.0200.0200.0200.0400.0400.0400.0400.0400.040

CalcAmount

0.0190.0210.0200.0200.0200.0210.0210.0420.0420.0430.0410.0420.042

RPD7.3%

-2.5%-0.4%-1.8%-2.5%-2.5%-3.9%-5.1%-3.9%-7.2%-3.3%-4.6%-5.3%

Page?

SDG: EC201

Florist! Cartridge Check

TCMXalpha-BHCgamma-8 HCHeptachlorEndosulfan IDteWrinEndrin4,4'-DDD4,4'-DDTMethoxychlorDOB

CF12,919,10014.223,70015,646,90015,110,60013,361,10011,463,40010,821.2757,908.7257.326.2004,377,525

10,663,475

Area116,382142,071157,082163,969151,403243,412241,434163,095134,346494,486236,580

SpikeAdded

10.0010.0010.0010.0010.0020.0020.0020.0020.00

100.0020.00

SpikeRec9.019.99

10.0410.8511.3321.2322.3120.6218.34

112.9622.19

%Rec

90.1%99.9%

100.4%108.5%113.3%106.2%111.6%103.1%

91.7%113.0%110.9%

PageS

SDG: EC201

MS Verification

Sample RW1601

TCMXgamma-BHCHeptachk>rAWrinDtetdrinEndrin4,4'-DDTDOB

CF12,919.10015,646,90015,110,60013,956,65011,463,40010.821,2757.326.200

10.663,475

Area189,689693,158643,193894,575

1,084,3231,047,888

779,316127,868

SpikeAdded

0.500.500.501.001.001.00

SpikeRec0.150.440.430.640.950.971.060.12

%Rec

#VALUE!88.6%85.1%

• 128.2%94.6%96.8%

106.4%#VALUE!

QCLimits

56%-40%-40%-52%-56%-38%-

123%131%120%126%121%127%

The aktrin recovery calculated during the data validation did not agree with that reported by the laboratory.The 129% recovery is greater than the upper QC limit.

SDG: EC201

MSD Verificatton

Sample RW1601

TCMXgamma-BHCHeptachbrAkJrinDieldrinEndrin4.4'-DDTDCB

CF12,919,10015,646.90015,110.60013,956.65011,463,40010,821,2757,326.200

10,663.475

Area181,484668,619626,288848,094

1,031,2131,024,876

754,198113,504

SpikeAdded

0.500.500.501.001.001.00

SpikeRec0.140.430.410.610.900.951.030.11

%Rec

WALUEI85.5%

• 82.9%121.5%90.0%94.7%

102.9%#VALUE!

56%40%40%52%56%38%

QCLimits

- 123%-131%- 120%- 126%-121%- 127%

RPD

4%3%5%5%2%3%

QCLimits

152022182127

Page 10

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