�
2020
I II
I.
ATP14S 14S
KCla e
A E
b ) 8 C A A 2 01
K 4 (
Abs280
1~2
Abs280
280 nm
pH
pH pH
d D CC D
(i)
2~3 (ii) 1
II. F ATP
(a)
FF
AATP
A
F
ATP
AATP B
ATPC D
(b)ATP CD
S 4
[ ] Z
α-
A D Li+
(a) F
(b) (i) ATP
(ii) (i) (b)
(a) RNA
(b) 60S 40S80S
RNA IRNA rRNA 45S
rRNA 28S 5.8S 18S rRNA 28S rRNA 5.8S rRNA 60S 18S rRNA 40S
60S (c) RNA III5S rRNA
80S
(a) A C
RNAA B
A RNADNA C B mRNA
(b) 60S 40S100S 1 2
(c) 5S rRNA RNA IIIRNA 1 RNA
mRNA
X RNA
X RNA2 3
X RNA
1 2 3
X RNA
3 4
I V
(a) (b)
(c)
(d)
(e)
DNA I (a) 1 5
1.
90% 2. CpG CpG
3. DNA 4. 2 3 5. N
1/(4N)
II (b) 1 4
4
2
1
III (c)
3 5
IV (d)
22 3
���
V (e)
DNADNA
2 DNA DNADNA
DNA ]
DNA DNA
2′ 3′ 3′ 2′ 2′ 5′ 5′ 2′ 3′ 5′ 5′ 3′ DNA RNA DNA DNA DNA
[
I II
)
RGCRGC )
RGC )
180 )
) a RGC )
)
)RGC )
b ) )
�� C
G C
( a ) )RGC
)( 1
RGC ●RGC ○
( b ) 1 2) )
) X) )
A B
A
)RGC )
)
) PI-PLCC )
) c ) )
�
B)
X )d )
��� C �
�
( c ) X 1
A ) X RGC
( d ) ) X )
( d ) ) X ) RGC)
)2 3
I III
I. i) ii)
8 Lewis
H2SO3
i) CH3NO ii) HNO3
i)ii)
i) 4-(1- ) ii) (E)-3- -2- -2- -1- II. i) v) AF
III. 1 5 1 2 1. C4H8Cl2 6 2. (1S,2S)-1- -2- E2 1-
3. 2
4.
pKa
5. Michael
CO2CH2CH3
CO2CH2CH3
CH3
O
マロン酸ジエチル メチルビニルケトン
I III I. 10
A D
[ ]
CrO3 KMnO4 H2, Pd/C Na2SO4 Na2CO3, H2O
HNO3, H2SO4
NaH HO(CH2)2OH CH3NO2
1 2 2 1H NMR
Ha δ (ppm) (0 ppm)
1~3 3~5 5~7 7~9 9~11 11~13 3 4 7 2
1 2 6 Hb 7 Hc 1H NMR
δ (ppm) 1 2
OHC CH
O
II. [ A ] [ B ] [ A ]
[ C ] [ B ] s [ D ] %[ C ] s [ E ]% s
[ F ] [ G ] 44 [ G ] 25
[ H ]
( RO- ) ( ROH )
ROH [ G ] [ G ] [ I ]
[ A ] [ I ]
[ ] ΔG0 ΔH0 Kd Ka Kb pKa pKb pH sd sd2 sd3 sp sp2 sp3
20 25 33 40 50 60 67 75
( ROH )
III. 11 6 5
5 3
I V
25
25 (s) (l)
(g)
2
I. 1.0×10 V 7.0 A 5.0×102 s
5.0 K
q J kJ
C
II. 1.0×10−2 mol
1.4 K 1 mol
ΔU
III.
NH2CH2COOH (s) + O2 (g) CO2 (g) + H2O (l) + N2 (g)
(g)
- Δνgas Δνgas =
IV. 1 mol ΔH
R T ΔH ΔU Δνgas
V.
ΔU ΔH
ΔU ΔH
pa
Va na T T
pa
Vb Va Vb / Va
p V V + dV
w p
pa q
Va Vb
.
x px 0 h
ℎ = 6.626 × 10!!" �x
�px
− ℏ!/2! !!!"! + ! ! ! ! = !" !
! ! m
ℏ = ℎ/2! ! ! E
0
! ! = 0 0 ≤ ! ≤ ! , ! ! = ∞ (! < 0, ! > !) ! 0 = ! ! =
! n
! = ! ! = !×N !" !!!"
!! !!
1 ! ! ! =
7 L ! = 0 ≤ ! ≤ ! ! ! = 0E ! = !!/2! = L
! = 1 E
1
[ ]
J s Js Js–1 ∆!!∆! ≥ ℎ/2! ∆!!∆! ≤ ℎ/2! ∆!!∆! ≥ ℎ/4! ∆!!∆! ≤ ℎ/4!0 1 h ° nL L/n
2nL 2L/n�sin !"#/! cos !"#/! tan !"#/!! ℎ! ℎ/! !/ℎ nh/L n/hL nh/2L n/2hL nh/8mL2 n2h2/8mL n2h/8mL2
n2h2/8mL n2h2/8mL2
MO MO
. MO ����������� HOMO
. MO LUMO
MO
.
1
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