hiM~x ge 87 2020 J4 bB`NKlII. fnTnTl\K :$ 9cGPl* " cã$ 9@KVl^Ahe lX eF@KVl fo=ATP í 2EZjJn(6 # ) C...
Transcript of hiM~x ge 87 2020 J4 bB`NKlII. fnTnTl\K :$ 9cGPl* " cã$ 9@KVl^Ahe lX eF@KVl fo=ATP í 2EZjJn(6 # ) C...
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�
2020
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I II
I.
ATP14S 14S
KCla e
A E
b ) 8 C A A 2 01
K 4 (
Abs280
1~2
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Abs280
280 nm
pH
pH pH
d D CC D
(i)
2~3 (ii) 1
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II. F ATP
(a)
FF
AATP
A
F
ATP
AATP B
ATPC D
(b)ATP CD
S 4
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[ ] Z
α-
A D Li+
(a) F
(b) (i) ATP
(ii) (i) (b)
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(a) RNA
(b) 60S 40S80S
RNA IRNA rRNA 45S
rRNA 28S 5.8S 18S rRNA 28S rRNA 5.8S rRNA 60S 18S rRNA 40S
60S (c) RNA III5S rRNA
80S
(a) A C
RNAA B
A RNADNA C B mRNA
(b) 60S 40S100S 1 2
(c) 5S rRNA RNA IIIRNA 1 RNA
mRNA
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X RNA
X RNA2 3
X RNA
1 2 3
X RNA
3 4
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I V
(a) (b)
(c)
(d)
(e)
DNA I (a) 1 5
1.
90% 2. CpG CpG
3. DNA 4. 2 3 5. N
1/(4N)
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II (b) 1 4
4
2
1
III (c)
3 5
IV (d)
22 3
���
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V (e)
DNADNA
2 DNA DNADNA
DNA ]
DNA DNA
2′ 3′ 3′ 2′ 2′ 5′ 5′ 2′ 3′ 5′ 5′ 3′ DNA RNA DNA DNA DNA
[
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I II
)
RGCRGC )
RGC )
180 )
) a RGC )
)
)RGC )
b ) )
�� C
G C
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( a ) )RGC
)( 1
RGC ●RGC ○
( b ) 1 2) )
) X) )
A B
A
)RGC )
)
) PI-PLCC )
) c ) )
�
B)
X )d )
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��� C �
�
( c ) X 1
A ) X RGC
( d ) ) X )
( d ) ) X ) RGC)
)2 3
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I III
I. i) ii)
8 Lewis
H2SO3
i) CH3NO ii) HNO3
i)ii)
i) 4-(1- ) ii) (E)-3- -2- -2- -1- II. i) v) AF
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III. 1 5 1 2 1. C4H8Cl2 6 2. (1S,2S)-1- -2- E2 1-
3. 2
4.
pKa
5. Michael
CO2CH2CH3
CO2CH2CH3
CH3
O
マロン酸ジエチル メチルビニルケトン
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I III I. 10
A D
[ ]
CrO3 KMnO4 H2, Pd/C Na2SO4 Na2CO3, H2O
HNO3, H2SO4
NaH HO(CH2)2OH CH3NO2
1 2 2 1H NMR
Ha δ (ppm) (0 ppm)
1~3 3~5 5~7 7~9 9~11 11~13 3 4 7 2
1 2 6 Hb 7 Hc 1H NMR
δ (ppm) 1 2
OHC CH
O
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II. [ A ] [ B ] [ A ]
[ C ] [ B ] s [ D ] %[ C ] s [ E ]% s
[ F ] [ G ] 44 [ G ] 25
[ H ]
( RO- ) ( ROH )
ROH [ G ] [ G ] [ I ]
[ A ] [ I ]
[ ] ΔG0 ΔH0 Kd Ka Kb pKa pKb pH sd sd2 sd3 sp sp2 sp3
20 25 33 40 50 60 67 75
( ROH )
III. 11 6 5
5 3
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I V
25
25 (s) (l)
(g)
2
I. 1.0×10 V 7.0 A 5.0×102 s
5.0 K
q J kJ
C
II. 1.0×10−2 mol
1.4 K 1 mol
ΔU
III.
NH2CH2COOH (s) + O2 (g) CO2 (g) + H2O (l) + N2 (g)
(g)
- Δνgas Δνgas =
IV. 1 mol ΔH
R T ΔH ΔU Δνgas
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V.
ΔU ΔH
ΔU ΔH
pa
Va na T T
pa
Vb Va Vb / Va
p V V + dV
w p
pa q
Va Vb
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.
x px 0 h
ℎ = 6.626 × 10!!" �x
�px
− ℏ!/2! !!!"! + ! ! ! ! = !" !
! ! m
ℏ = ℎ/2! ! ! E
0
! ! = 0 0 ≤ ! ≤ ! , ! ! = ∞ (! < 0, ! > !) ! 0 = ! ! =
! n
! = ! ! = !×N !" !!!"
!! !!
1 ! ! ! =
7 L ! = 0 ≤ ! ≤ ! ! ! = 0E ! = !!/2! = L
! = 1 E
1
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[ ]
J s Js Js–1 ∆!!∆! ≥ ℎ/2! ∆!!∆! ≤ ℎ/2! ∆!!∆! ≥ ℎ/4! ∆!!∆! ≤ ℎ/4!0 1 h ° nL L/n
2nL 2L/n�sin !"#/! cos !"#/! tan !"#/!! ℎ! ℎ/! !/ℎ nh/L n/hL nh/2L n/2hL nh/8mL2 n2h2/8mL n2h/8mL2
n2h2/8mL n2h2/8mL2
MO MO
. MO ����������� HOMO
. MO LUMO
MO
.
1