Volume 22 Issue 3 December 2014 newnsa ndern fFneAC.

107
Nandini Chemical Journal, December,2014 Page 1 newnsa ndern fFneAC. Volume 22 Issue 3 December 2014 Dedicated to the cause of chemical industry * CRUDE PRICE FALL - WILL THE EUPHORIA FOR CONSUMING COUNTRIES BE SHORT LIVED? * FOCUS ON HFO 1234 yf - NEXT GENERATION REFRIGERANT * ACRYLONITRILE - PRODUCT PROFILE * POLYCARBONATE – GLOBAL SCENARIO * SPOTLIGHT ON SPECIALITY CHEMICAL - ETFBO * PHOSGENE – PRODUCT PROFILE * NON PHOSGENE ROUTES TO ELIMINATE USE OF PHOSGENE

Transcript of Volume 22 Issue 3 December 2014 newnsa ndern fFneAC.

Page 1: Volume 22 Issue 3 December 2014 newnsa ndern fFneAC.

Nandini Chemical Journal, December,2014 Page 1

newnsa ndern

fFneAC.

Volume 22 Issue 3 December 2014

Dedicated to the cause of chemical industry

* CRUDE PRICE FALL - WILL THE EUPHORIA

FOR CONSUMING COUNTRIES BE SHORT LIVED?

* FOCUS ON HFO 1234 yf - NEXT GENERATION REFRIGERANT

* ACRYLONITRILE - PRODUCT PROFILE

* POLYCARBONATE – GLOBAL SCENARIO

* SPOTLIGHT ON SPECIALITY CHEMICAL - ETFBO

* PHOSGENE – PRODUCT PROFILE

* NON PHOSGENE ROUTES TO ELIMINATE USE OF PHOSGENE

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duct Profile77

VOLUME XXII DECEMBER 2014 ISSUE 3

Publisher: Nandini Institute of Chemical Industries

Editor - Publisher N.S.Venkataraman

Editorial & Administrative Office:

M 60/1, IV Cross Street, Besant Nagar, Chennai-600 090

India

Phone: 43511945,/43540719/24916037 Fax: (91-44) 24916037

E-mail Address:

[email protected] [email protected]

Website:

www.nandinichemical.com

Annual Subscription Rates: Inland : Rs.1200/- 12 issues Overseas: US $ 100 12 issues US $ 180 24 issues

Subscription Charges payable in

advance in favour of Nandini Institute of Chemical

Industries

Views expressed in this journal are not necessarily of the Editor - Publisher

CONTENTS 03 Talk of the month

Crude price fall - will the euphoria for consuming countries be short lived?

05 Shutting down sick PSUs

– Is it a step forward or backward ?

06 Coal to liquid project abandoned in Odisha

A counter productive development

08 Cold cracking technology to process heavy crude oil

13 Proceedings of Seminar on

how to make Clean India Campaign successful?

15 Overview of municipal waste scenario in India

20 Bio digester technology to treat human waste

22 Uncertainties facing TAPI pipeline project

23 Safety and accident page

24 Plant closures

25 Anti dumping page

26 Switch Over from naphtha to ethane

as feed stock - Global trend

27 Focus on HFO 1234 yf - Next generation refrigerant

30 Carbon fiber – Updates

31 Update on gas / oil exploration

33 Acrylonitrile - Product profile

37 Polycarbonate – Global scenario

42 Spotlight on speciality chemical - ETFBO

44 Phosgene – Product profile

48 Non phosgene routes to eliminate use of phosgene

52 Solvay’s plans for soda ash

53 News round up – International

55 Technology development

58 China news

59 News round up – India

61 Agro chemical page

61 Global palm oil scenario

64 Pharma page

64 Cannabis chemicals slow down cancer

66 Energy page

66 Prospects for nuclear energy

68 Installed rooftop solar capacity potential in India

69 Proposed solar park in India

70 Environmental page

70 Proposed amendment to montreal protocol on HFC

72 Target to cut co2 emissions

74 Tender

75 Price details

76 Ex factory prices in China

During the month of October 2014

81 Chemicals imported at the Chennai port

During the month of September 2014

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TALK OF THE MONTH

CRUDE PRICE FALL - WILL THE EUPHORIA

FOR CONSUMING COUNTRIES BE SHORT LIVED?

Some agencies say that the so called recession in Japan and Europe and fall in demand in China could have resulted in crude price fall. However, the credible explanation appears to be that the price fall have been caused due to steady increase in the production of crude in USA in recent months , as a result of the spectacular increase in the investment in shale gas fields, which has resulted in the global supply scenario of crude moving to surplus . U S remains as one of the largest consumers of crude oil in the world. Until recently, US has been substantially importing its crude oil requirement , not wanting to exploit its own resources. With the production of crude in USA significantly going up, the import level of crude by USA is likely to come down steadily in the coming months. Further, the export of crude from USA is now banned but there are demand by US oil companies that US government should remove this ban. In such case, not only import of crude oil by US will decrease but the export also will take place that would nearly flood the global oil market.

Around a year back, nobody really expected that the price of crude oil would fall below 70 USD per barrel. Now many explanations are being advanced for such crude price fall and also guesses are being made as to what extent the price fall would take place and how long it would persist. The question being debated is whether the global crude oil price would

stabilise at around 60 USD per barrel.

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CRUDE PRICE FALL - WILL THE EUPHORIA FOR CONSUMING COUNTRIES BE SHORT LIVED?

The fact today is that the actual global production of crude is more than the global demand. In the past , whenever such situation has developed , the oil producing countries used to reduce the production to ensure that the supply situation would remain tight. This is not happening now , as several oil producing regions such as Venezuela, Russia, Iraq, Iran are largely dependent on income from export of crude and cannot afford to reduce the crude production , whatever may be the compulsions. Saudi Arabia also does not want to reduce the crude production when others would not do so, as it would result in loss of market share for Saudi Arabia.

In recent years, it has been seen that the price of the crude in the world market is significantly influenced by the speculators , who are not consumers but traders. They buy and sell crude anticipating the price behaviour and profit potential. The current situation is that the speculators have understood that the global market is likely to have substantial oversupply in the coming months, that would result in price pressure and therefore , the speculators do not want to burn their fingers by buying oil anticipating any windfall in profit. As the speculators become hesitant and tend to withdraw to some extent, the demand for oil really come down in the speculative market. This inevitably lead to price fall. The situation is grim for shale oil producers in north America, as they would break even only at price of 80 dollars per barrel and above, as they have invested huge amount in drilling and the cost of operations are going up. Any price less than $ 80 per barrel would hurt them severely. At the same time, Saudi Arabia, another large oil producer appears to think that it would be comfortable with the price of 60 USD per barrel. Perhaps, by not reducing the oil production and reconciling for the price of $ 60 per barrel, Saudi Arabia wants to make it difficult for the crude producers in North America and drive them out of the market to some extent, if possible. The likely future scenario would be that the oil producers in North America would try to come to sort of agreement with the other oil producing countries to hike the price of crude in the global market. Certainly, the governments in USA and West Europe would try to make this possible. China , a large consumer of oil is trying to make the best out of the situation by importing more crude when the price is low and building the stock. However, this can have only a limited impact in the global market, as there are limits for storage capacity. The biggest beneficiaries of crude price fall are the large importing countries like India and China and other non oil producing countries like Sri Lanka. However, as of now , it appears that the consuming countries have no particular strategy to convert the present crude price fall into their advantage. While they are having an euphoria now due to the crude price fall, such euphoria may be short lived, as sooner or later, perhaps sooner than later , the crude price would rise to USD 80 per barrel and more due to the manoeuvre of the oil producing countries. However, the speculators who operate from the gallery will have the last laugh as they scheme and skillfully plan , without the type of botheration and risk that oil producing countries have. An investigative and well researched analysis of the global crude price trend has now been released by Nandini Consultancy , Singapore. www.nandinichemical.com)

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SHUTTING DOWN SICK PSUs IS IT A STEP FORWARD OR BACKWARD ?

While Government of India has proposed to close down some sick and unviable public sector units, there are quiet a number of other units such as fertilizer plants that remain closed for long time. Continued closure of these units help no one.

It is necessary to quickly identify all such units and wipe them away from the scene, if there would be no possibility of revival. Several of such units are occupying large area of land and have extensive facilities both for process plant as well as utilities.. It would be appropriate to scrap such plants and auction away the equipment at scrap value if necessary and then put the land and building for construction of new projects appropriate to the site. In India today, there is considerable scarcity of land for setting up industrial estates.Land acquisition moves are causing social and political issues resulting in litigation and delay .Further, most of such newly acquired land for industrial projects are agricultural land and it is debatable question as to whether agricultural land should be converted to site for industrial projects. Closing and completely scraping the loss incurring public sector units which are beyond revival is long over due. There is more to gain by closing these units rather than persisting with them due to lack of firm decisions and policies.

Government data shows that there are 61 sick central public sector enterprises that had 1.53 lakh employees as on March 31, 2013. The government has been paying the salaries of all these employees largely through the budget.

It is reported that Government of India has begun the process of shutting some of the sick public sector undertakings. The list of six firms for closure under the department of heavy industry includes Hindustan Photo Films, HMT Bearings, HMT Chinar Watches, Tungbhadra Steel, Hindustan Cable and the iconic HMT Watches. In the second round, 15 more loss-making firms will be under consideration, including British India Corporation, IDPL and their subsidiaries. The Cabinet note seeking closure of the six companies proposes to offer a voluntary retirement scheme (VRS) option at the 2007 pay scale for around 3,600 employees in these firms, along with additional benefits.This could amount to a total package of `Rs.1,000 crore.

It is counter productive to take a view that the public sector units should continue to be operated irrespective of the standard of efficiency and profitability in operation. Operation of such units only result in wastage of resources due to poor efficiency and loss to the government.

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COAL TO LIQUID PROJECT ABANDONED IN ODISHA A COUNTER PRODUCTIVE DEVELOPMENT

The prospects for CTL project have generated much interest in the country, as it is aimed at enhancing energy security by reducing dependence on imported crude.

The two CTL projects that have been initiated belong to Tata group and Jindal Steel

and Power. Now that Jindal has decided to give up the project, the hope rests only with proposed project of Tata group.

Government of India amended the Coal Mines (Nationalisation) Act in July 2007 to include coal to liquid (CTL) industry as an end user for allocation of captive coal blocks, so that low rank, high ash coal, which are abundantly

found in India, can be converted into liquid fuels.

Inspite of such government initiatives, the CTL projects in the country have been moving at snail‘s pace.

Jindal Steel and Power is now reported to have scrapped plans to set up a USD 10 billion CTL project at Angul in Odisha, following the Supreme Court‘s

cancellation of Ramchandi coal mine allotted to it. The CTL project was linked with the coal block.

JSPL was allotted Ramchandi Promotional Coal Block with an estimated reserve of 1,500 million metric tonne on February 27, 2009 for the project.

Jindal‘s CTL project was supposed to produce 80,000 barrels per day of crude from coal using German firm Lurgi's technology. The project cost also include

setting up of a 1,350 MW power plant and mine development expenses.

Scrapping of the CTL project by Jindal Steel and Power is a big setback for plans for the development of CTL projects in India.

CTL project of Tata group

The Tatas tied up with Sasol, as Sasol

has proven technology operating at it‘s two commercial scale CTL plants in South Africa, with total capacity of

1,60,000 barrels per day.

The Tata‘s project involves setting up a 30-million metric tonne per annum opencast coal mine for the coal to liquid

(CTL) plant, which has a capacity of 80,000 barrels per day and houses a

captive 1,100-MW power plant.

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COAL TO LIQUID PROJECT ABANDONED IN ODISHA -A COUNTER PRODUCTIVE DEVELOPMENT

The Odisha state government has delayed granting the project a prospecting

licence deed (PL deed) by more than a year.

All subsequent milestones, such as forest clearance, environmental clearance and mining lease, depend on the PL deed and, hence, a PL execution order from the state government is extremely important for further developing the coal block.

The finalisation of a detailed configuration of the CTL plant and its product slate

depends on a detailed understanding of the coal properties for CTL end use and this can be done only after the PL deed is executed.

Though the block was allocated in February 2009, the PL order was issued by the Odisha government only on March 15, 2012. Strategic Energy Technology Systems (SETSPL), a joint venture of Tata group companies and South African firm Sasol, filed an application with the project monitoring group at the Cabinet secretariat to help resolve the issues over its proposed Rs.60,000-crore coal to liquid project in Odisha.

China has made great progress in setting up CTL projects, which has been possible due to sustained and consistent support given by the Government of China. While

China has obtained technology and engineering services for CTL projects from abroad, indigenous technology development efforts in China are significant .

Unfortunately, India still remains as non starter with regard to CTL projects and therefore, India is losing great opportunities. While the Jindal Steel and Power has

taken it‘s decision to give up it‘s CTL projects, the fact is that it has already made substantial progress. Government of India should immediately explore the possibility of reviving this project. This calls for dynamic and pragmatic approach

from the Government of India in tune with the ground realities.

Need for strong government support for CTL project

Government of India should recognize that the promotion of CTL projects in India

in a massive way is the key for rapid development of downstream chemical

projects in the country. As there is no immediate feasibility of stepping up the production of crude oil and natural gas

which are used as feedstock for petrochemical industry, rapid

development of CTL project is the sure way to forge ahead in a manner appropriate to India‘s present scenario.

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COLD CRACKING TECHNOLOGY TO PROCESS HEAVY CRUDE OIL P.N.Devarajan, E-mail: [email protected]

Heavy crude oil – current scenario

* In reservoirs, crude becomes ―heavy‖ as a result of bio degradation, in which lighter ends are consumed by bacterial activity, leaving heavier hydrocarbons behind.

* Poor geologic reservoir sealing exposes the hydrocarbon to surface contaminants, I ncluding organic life and contributes to the above process. * There are two main types of heavy crude oil:

(i) High sulphur crudes ( more than 1% by weight) (ii) Low sulphur crudes ( less than 1% by weight) * Heavy crude oils provide challenge for the economics of petroleum refining. * Most heavy oil production processes are slow; it heats slowly and flows slowly out of the

reservoir.

* The two main current technologies for extracting heavy crude oil are cyclic steam stimulation

and steam flooding.

* The lighter grades of crude oil produce the best yields of end products. However, lighter grades of crude are fast depleting. * Depletion of light oil reserves are shifting the focus of the oil industry towards heavy crude oil * Oil refineries are increasingly having to process heavy and ultra heavy crude. * Heavier crude oil have too much carbon and not enough hydrogen. Processing of heavy crude oil requires high capital cost, operating cost and results in harmful emission. Existing processing technologies do not effectively address the issue. * Oil industry has been eagerly awaiting emergence of new innovative and cost effective technologies for processing heavier crude oil.

Mr.P.N.Devarajan was conferred special award on the occasion. Highlights of the speech delivered by Mr.P.N.Devarajan is given in this article

Mr.P.N.Devarajan a renowned chemical engineer and former Chairman of Hindustan Organic Chemical delivered lecture on ―Cold Cracking technology to process heavy crude oil‖ at Chennai on 8th November,2014, in an award function organised by Chemical Industries Association. Mr.P.N.Devarajan spoke on importance of developing technology for heavy crude oil in the light of depleting availability of lighter grade of crude oil.

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COLD CRACKING TECHNOLOGY TO PROCESS HEAVY CRUDE OIL Heavy crude oil – Current scenario Total world oil reserves

Global heavy oil scenario

S.No.

Oil type

Region

Current reserve (billion barrel)

1 Tar sands Alberta, Canada 179

2 Ultra heavy crude Orinoco Belt, Venezuela 513

3 Shale oil West Coast, USA 1,200

Technology development – Pristec Inc * Pristec, an innovation based global company, is offering technology solution to convert heavy crude into light synthetic crude. * The technology is practiced at room temperature and atmospheric pressure and without the need of hydrogen environments, thus reducing CAPEX and OPEX steeply. * The process is known as activation by a special technique developed at Pristec AG in Vienna, Austria and at Pristec America in New York, USA. * The testing has been done by a third party on parameters, which confirms the properties achieved as that of light crude. * This can be done at different location like the oil field, the oil tankage terminals and installations and in the refinery before feeding the crude to CDU. * In summary, it is a crude feed preparation technology enabling high level of refining economy from end to end.

Oil sands bitumen 30%

Extra heavy oil 25%

Heavy oil 15%

Conventional oil 30%

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COLD CRACKING TECHNOLOGY TO PROCESS HEAVY CRUDE OIL Solution by cold cracking technology * Using applied quantum mechanics, Pristec has developed a cold cracking technology that constitutes a novel, highly innovative way to process heavy crude. * Pristec‘s technology is based on ‗cold cracking‘, incorporating the principles of resonance energy advanced electro magnetic and vacuum energy. * Cold cracking technology subjects the crude oil to specific frequencies and destabilizes its molecular bond structure. * The energy inputs required for cold cracking technology is much less than conventional cracking. * Using these principles, cold cracking technology creates `activation‘ of the long chained molecules of the heavy crude. * Activation is the precise stimulation of the electron system of specific elements and molecular bond types. * The atoms of hydrogen, carbon and sulphur in the heavy oil are activated and cause changes in their molecular structure. * Cold cracking technology significantly reduces the temperatures at which long chain molecules tend to crack. * Cold cracking technology reduces CO2 as well as SO2 emission levels in the process due to operation at room temperature and pressure and non catalytic profile. Objectives and impact of the cold cracking technology 1. They increase the proportion of light products like gasoline and diesel in the output;

they reduce density of the crude to make it lighter.

2. They reduce the crude‘s viscosity to make it more fluid for easier transportation.

3. They minimize low value components like vacuum residue, bitumen and wax

4. Cold cracking technology is the first in the world to remove sulphur in

elemental form, by use of C-S activator, which is currently being optimized and engineered,

so as to permit its easy isolation and removal of sulphur from the crude at the very early stages

before the CDU.

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COLD CRACKING TECHNOLOGY TO PROCESS HEAVY CRUDE OIL Three types of crackers Hydrogen cold cracking unit It increases the light fraction content of heavy oils. Make in situ hydrogen available for the subsequent processes. Carbon cold cracking unit It cracks up long hydrocarbon molecules and are most effective on residue and extra heavy crude. Carbon cold cracking units can produce light crude from heavier crudes and the impact can be achieved at oil well, crude oil tank farms and at the refineries. Sulphur cold cracking unit It destabilizes sulphur components in the molecular structure of crude.Sulphur is cracked to form elemental sulphur and being much heavier than the crude, allows for separation and safe and economic disposal. Cold cracking technology’s role in Upstream In oil exploration, it can help improve the volume and quality of the extracted oil and help to increase $/Bbl. of sales revenue by decreased production costs. Mid stream In transportation, the viscosity improvement helps to save huge energy costs for pumping and heating as well as the avoidance of high cost of additives currently used. Down stream In refining, cold cracking units can substitute conventional thermal and catalytic cracking and desulfurization units at amazingly low capital and low operating expenditures. Refinery GRM – Gross Refiner Margin ($/Bbl) goes up with incremental investment sustainability – rapid pay back of investment – environmentally friendly For existing refineries using partly heavy crude that are seeking to improve their GRM, cold cracking technology implementation is an opportunity, which can increase the use of heavy crude to a higher proportion in the crude feed mix. Thus, feedstock cost is reduced, increasing distillate production and reducing fuel oil production.

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COLD CRACKING TECHNOLOGY TO PROCESS HEAVY CRUDE OIL Financial simulation * Selling price of diesel is $125 /Bbl * Selling price of fuel oil is $100 / Bbl * 20% additional yield of middle distillate will generate ―additional GRM of $5 per barrel of

crude‖ ($125 - $100) x 20% * If Indian refineries adopt cold cracker technology to process their heavy crude feed

(i) additional revenue of about 450 million USD by 2016\

(ii) Subsequently would yield 700 million USD by 2018 Summary In summary, it enables the refineries to invest lower capex and opex in cold cracker technology and cut down on heavy investments on conventional and currently practiced technology and manage any incremental load with existing secondary and tertiary processes like hydrogen generation and hydro treating, since capacity to do so will be released on the advent of cold cracking technology.

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GLOBAL LICENSORS OF TECHNOLOGY, CONSULTANTS AND

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PUBLICATION AVAILABLE IN CD

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NANDINI CONSULTANCY CENTRE, CHENNAI – 600 090

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E-mail: [email protected],

[email protected]

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PROCEEDINGS OF THE SEMINAR ON

“HOW TO MAKE CLEAN INDIA CAMPAIGN SUCCESSFUL?”

Observations:

Lack of cleanliness in public places may be a sociological problem in India. Such conditions have existed in India for last several decades .

* While the government of India has announced Clean India Campaign , it has

not evolved an integrated strategy to handle the waste in eco friendly and appropriate manner.

* Integrated waste management programme can be developed only by developing appropriate technologies for the production of derivative products using

waste as feed stock. * The people can be motivated to collect waste , if they would get value for

the waste, which is possible by making useful products from waste.

Chemical Industries Association, an apex body representing cross section of

chemical and allied industries and based in Chennai organised a seminar at Chennai on 22nd November,2014 on ―How to make Clean India campaign

successful?‖ Seminar was well attended by engineers, IT professionals, social activists

and teaching community.

Highlights of the observations and recommendations made in the seminar are given below.

* The mind set of the people must be changed and they should be sensitized, which is now being done by

Modi government and India has a very long way to go.

* Governments at various levels are responsible for unclean conditions today

in public places, much more than the people.

* The so called celebrities and politicians sweeping for a few minutes

in front of camera may bring the campaign to ridicule, if it continues.

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PROCEEDINGS OF THE SEMINAR ON HOW TO MAKE CLEAN INDIA CAMPAIGN SUCCESSFUL?

Recommendations : * Cleanliness in public and private life must be introduced as a compulsory

subject in the school curriculam, just like mathematics.

* Bio toilet facilities must be built in public places including every bus stop and railway stations.

* Government must encourage and recognise the formation of pressure groups amongst local communities consisting of motivated persons , so that

pressures can be brought on the government departments to do the job efficiently and effectively.

* Government should

encourage and motivate R&D activities to evolve processes for utilising waste

by producing value added products. Several such

projects are in operation abroad. For example, apart from power and industrial

water, several chemicals such as methanol can be

produced from waste. India presently imports around

12 lakh tonnes of methanol per annum and several methanol projects from

waste can be set up in different parts of India.

* Industries set up

using waste as feed stock should be given special

subsidies and tax benefits. * Awards must be

instituted by government of India for individuals and

organisations developing technologies for treating

waste in profitable manner.

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PROCEEDINGS OF THE SEMINAR ON HOW TO MAKE CLEAN INDIA CAMPAIGN SUCCESSFUL?

OVERVIEW OF MUNICIPAL WASTE SCENARIO IN INDIA Composition of MSW Municipal solid waste consist of biodegradable waste, recyclable waste (such as glass, metal and packaging), inerts (such as bricks) and hazardous waste (such as hospital waste).

(in percentage) Paper Rubber, leather and synthetics Glass Metals Total Compostable matter Inerts

1 to 5.6 0.7 to 0.8 0.5 to 0.6 0.3 to 4 43 to 45 42 to 44

3 to 8.8 0.7 to 0.8 0.3 to 0.4 0.3 to 4 38 to 41 43 to 45

4 to 13.2 0.7 to 0.8 0.4 to 0.5 0.4 to 0.5 26 to 39 45 to 46

17 to 18 0.4 to 0.5 0.4 to 0.5 0.5 to 0.6 55 to 57 48 to 50

6 to 12.9 0.2 to 0.3 0.9 to 1 0.7 to 0.80 27 to 31 53 to 54

Period Waste generation in urban areas in metric tonne per day

2011 1,70,000

2021 (Estimated) 2,76,342

Pattern of utilisation of municipal waste

Description Percentage of MSW treated out of total generation

Generated 100%

Collected 68%

Treated 19%

Untreated (Waste disposed off at dump sites / landfill sites)

81%

Generation and growth of waste As per 2011 census, 31.16 % population of India i.e. 377 million people live in 7,935 urban areas with 4041 municipal authorities. Total quantity of waste :

170,000 metric tonne per day Currently handled each day

About 62 million metric tonne per year in the urban areas

Volume of waste is expected to increase at 5% per year on account of increase in the population and change in lifestyle of the people.

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PROCEEDINGS OF THE SEMINAR ON HOW TO MAKE CLEAN INDIA CAMPAIGN SUCCESSFUL?

Number of Urban Local Bodies having treatment/ processing facilities Number of Urban Local Bodies having treatment/ processing facilities: 626

Product Number of plants

Conventional composting 279

Vermi composting facilities 138

Biomethanation 172

Refuse Derived fuel (RDF) 29

Waste to Energy 8

* RDF pellets are produced after initial treatment of MSW/garbage Indian energy generation potential from MSW Indian energy generation potential from MSW: About 1725 MW

Source Generation potential

Urban waste 1500 MW

Sewage 225 MW

SEWAGE TO PROCESS WATER (NON POTABLE) Case study -Rashtriya Chemicals & Fertilizers Ltd., Mumbai * Sewage Treatment Plant (STP) treats around 22.75 MLD of sewage generated by Mumbai City and produces about 13 MLD of process water,which is being used in its plants as process water. STP meets about 50% of process requirement of its Trombay unit of RCF.

* RCF pay for the sewage and is around Rs 3 per m3.

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PROCEEDINGS OF THE SEMINAR ON HOW TO MAKE CLEAN INDIA CAMPAIGN SUCCESSFUL?

Power from MSW List of municipal & urban waste based power projects taken up by Ministry of New and Renewable Energy Resources (MNRE)

Project promoters Location Capacity

(MW) Technology Present Status

M/s. Timarpur Okhla Waste Management Pvt Ltd. (TOWMCL) (Promoted by Jindal Urban Infrastructure Ltd.)

New Delhi 16 Combustion Commissioned

M/s. RDF Power Projects Ltd. Hyderabad 11 Combustion Commissioned in 2014

M/s East Delhi Waste processing Company (P) Ltd. (Promoted by DIAL, IL&FS Energy Dev. Co. Ltd. (IEDCL) and SELCO International Ltd.)

Gazipur, Delhi 12 Combustion Under implementation

M/s. Rochem Separation Systems (India) Pvt. Ltd., Mumbai

Pune 10 Gasification Under implementation

M/s. Delhi MSW Solutions Ltd. (promoted by Ramky Enviro Engineers Ltd., Hyderabad)

Bawana, Delhi

24 Combustion Under

implementation

Essel Pallavapuram Tambaram MSW Pvt. Ltd.

Chennai 3 Combustion

(300 tonnes per day MSW)

Under implementation. Project cost –

Rs. 100 Crores

M/s Srinivasa Gayatri Resource Recovery Ltd.

Bangalore 8 Combustion Under planning

M/s. Solapur Bio Energy Systems Pvt. Ltd., Navi Mumbai

Solapur 3 Biomethanation Under planning

IOT Mabagas Ltd. Namakkal, Tamilnadu

4 Power from

poultry droppings

Operating

Subhashri Bio Energies Pvt. Ltd. Thiruchengode,

Tamilnadu 2.4

Power from poultry

droppings Operating

CHEMICALS FROM MUNICIPAL WASTE Downstream possibilities * Waste can be converted to useful products using following conversion pathways. * Thermochemical conversion * Biochemical conversion,

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PROCEEDINGS OF THE SEMINAR ON HOW TO MAKE CLEAN INDIA CAMPAIGN SUCCESSFUL? * Thermochemical conversion, characterized by higher temperature and conversion rates, is best suited for lower moisture feedstock and is generally less selective for products. * On the other hand, biochemical technologies are more suitable for wet wastes which are rich in organic matter.

SYNTHESIS GAS FROM MSW Synthesis gas (Syngas) is a mixture comprising of carbon monoxide, carbon dioxide, and hydrogen. Applications of synthesis gas * As a fuel source to manufacture steam or electricity * As an intermediate in generating synthetic natural gas * As an intermediate in the industrial synthesis of ammonia and fertilizer * As a raw material gas that can be used to synthesize basic chemical building blocks like

methanol Project parameters * Basis: 1 tonne of MSW with organic content of 50% * Production of synthesis gas: 420 – 465 cubic metre Methanol from MSW/Synthesis gas Methanol project in Canada Name of the company Enerkem Location Edmonton, AB Raw material used Municipal solid waste Plant capacity 38 million litres per year This project help the city of Edmonton divert 90% of the residential waste stream from landfill.

Thermochemical processes

Biochemical processes

Waste

Incineration Electricity

Gasification

Pyrolysis

Fermentation

Anaerobic Digestion

Synthesis gas (Syngas)

Heavy oil

Ethanol

Biogas

Downstream possibilities

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Nandini Chemical Journal, December,2014 Page 19

PROCEEDINGS OF THE SEMINAR ON HOW TO MAKE CLEAN INDIA CAMPAIGN SUCCESSFUL?

Synthesis gas from RDF/MSW Process technology supplied by selected technology suppliers for production of

syngas/power from MSW/RDF is given below:

Crude synthesis gas from MSW/RDF

Process technology Source of technology

Low temperature gasification Entech Renewable Energy Solutions, Australia

Fluidized bed gasification Outotec Energy Products, USA

Clean synthesis gas from MSW/RDF/ crude synthesis gas

Process technology

Source of technology

Plasma arc gasification Westinghouse Plasma Corporation, USA (subsidiary of Alter NRG, Canada)

Plasma gasification and vitrification technology Solena Fuels, USA

Thermal gasification followed by plasma gasification

Plasco Energy Corp Inc., Canada

Plasma gasification for the purification of syngas The Europlasma Group, France

High temperature gasification combined with pyrolysis

Chinook Sciences Ltd., UK & USA

Power from synthesis gas

Process technology

Source of technology

Remarks

Low temperature gasification Entech Renewable Energy Solutions, Australia

The output is crude syngas which will be used to generate power.

Fluidized bed gasification Outotec Energy Products, USA

Plasma arc gasification for MSW Westinghouse Plasma Corporation, USA (subsidiary of Alter NRG, Canada)

The output is clean syngas which will be used to generate power.

Plasma gasification and vitrification technology

Solena Fuels, USA

Thermal gasification followed by plasma gasification

Plasco Energy Corp

Plasma gasification for the purification of syngas

The Europlasma Group, France

Gasification combined with pyrolysis Chinook Sciences Ltd., UK, USA

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Nandini Chemical Journal, December,2014 Page 20

BIO DIGESTER TECHNOLOGY TO TREAT HUMAN WASTE

The bio digester technology has been developed by Gwalior based Defence Research and Development Establishment (DRDE) and Tezpur based Defence Research Laboratory (DRL), with an objective for resolving the problems of

un decomposed human waste.

The innovation degrades and converts the human waste into usable water and gas in an eco friendly manner. The generated gas can be utilised for energy/cooking and water for irrigation purposes. The process involves the bacteria which feed

upon the faecal matter inside the tank, through anaerobic process, which finally degrades the matter and releases methane gas that can be used for cooking, along

with the treated water. UK based NRI industrialist Lord Swaraj Paul‘s Caparo Group has joined hands with

DRDO to install environment friendly bio digester toilets across India. The toilets cost only R15,000 each and are cheaper if built for clusters. It was in 2012 that

DRDO had launched bio digester, christened as bio-toilets from Dhamra near the Wheeler Island test facility, from where it used to test launch long-range missiles like Agni and AAD interceptors.

The bio digester technology was used to decompose biological waste generated by

soldiers deployed in high altitude regions such as Siachen and Ladakh. The ELOOs can effectively function in extreme conditions and temperature ranging from -6 degree centigrade to 50 degree centigrade.

To suit different geographical requirements, DRDO has also made various design

modifications in the bio-digester toilets. For example, to avoid choking of toilets in Indian Railways because of people throwing non biodegradable plastics, like bottles, a special lid has been constructed. On pushing the flush, the flap opens and the

bottles fall on the track. The excreta enters through a separate opening into the digester tank.

The Bio digester tank has several chambers to provide more surface area to hasten bio degradation. The chambers increase retention time of the waste in places,

where water table is high like in Lakshwadeep or homes and offices where people flush frequently. In glaciers where the temperature is as low as minus 40 degree

centigrade, the toilet is fitted with solar panels of 240 watt to keep the excreta warm for processing.

Design changes are also being worked for toilets in houseboats in Srinagar to avoid water contamination.

Delhi Urban Shelter Improvement Board (DUSIB), the body which has to provide

toilets to slum dwellers in all clusters in the city, has procured 10-seater mobile toilet vans with DRDO developed bio digester technology

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Nandini Chemical Journal, December,2014 Page 21

ALL INDIA ESSAY COMPETITION FOR COLLEGE STUDENTS ON

“VALUE ADDED PRODUCTS FROM SEWAGE / MSW”

Nandini Chemical Journal (www.nandinichemical.com), is organizing All India essay

competition for college students on

“Value added products for production from sewage / municipal solid waste and appropriate technologies”.

Obviously, waste should be considered as source of wealth and energy and

appropriate value added products should be produced from waste, which would

be a win win situation. There is urgent need to identify the appropriate value

added products and suitable technology for manufacturing.

Nandini Chemical Journal is organizing the above All India competition, to give

opportunities to college students all over India to study the subject in depth and

provide their suggestions and recommendations.

The essay should be written in English with maximum of 2000 words and should

clearly identify the appropriate products with justification and discuss about the

existing technologies and R&D opportunities, considering the suitability for

Indian conditions.

Eligibility & prize: All students studying in Indian universities at under

graduate, post graduate and doctoral level can participate in the essay

competition.Five prizes would be awarded to the best of entries.

Last date & address details :

Last date for submission of essay is 30th December, 2014. Essay should be

sent either by post or email to the following address:

Nandini Chemical Journal,

M-60/1, 4th Cross Street,

Besant Nagar,Chennai-600090.

Tel.: 91-44-43540719 / 43511945 / 24916037,

Email:- [email protected] / [email protected].

The Prime Minister‘s call for Clean India

Campaign has created a flurry of

activities in the country towards

achieving cleanliness in public places.

While high enthusiasm has been

generated among countrymen, question

still remains as to how large quantity of

waste would finally be handled in cost

effective manner without disturbing the

ecological balance.

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Nandini Chemical Journal, December,2014 Page 22

UNCERTAINTIES FACING TAPI PIPELINE PROJECT

Turkmenistan has the world‘s fourth largest proven gas reserves, and the pipeline will allow

the landlocked country to diversify its gas export markets.

The TAPI pipeline will export up to 33 billion cubic metres of natural gas annually from giant

gas field, Galkynysh in Turkmenistan, to Afghanistan, Pakistan and India over 30 years.

The member countries want to complete the gas pipeline network by 2017. The envisaged

1,800 km pipeline (about 144 km in Afghanistan and 800 km in Pakistan) will have capacity

to transport 90 mmscmed of gas -38 mmscmd each for India and Pakistan and the

remaining 14 mmscmd for Afghanistan.

A statement issued by the Asian Development Bank (ADB), which is the transaction advisor

for the TAPI gas pipeline said that state concerns, Turkmengas, Afghan Gas Enterprise,

Inter State Gas Systems (Private) Ltd and GAIL (India) Ltd will own equal shares in the

company. In November 2013, the ADB was appointed transaction advisor for the TAPI gas

pipeline project.

The company has been incorporated as a Special Purpose Vehicle in the Isle of Man; a

British Crown dependency, located in the Irish Sea. This SPV would be responsible for

finance, design, construction, operation and maintenance of the TAPI pipeline.

Challenges

GAIL India is of the view that the complex geopolitical and security issues involved in the

TAPI pipeline project make the task of building and operating the pipeline for over 30 years

extremely challenging. Since none of the four TAPI entities has such credentials, building

the project through a consortium — formed either with equal shareholding or under the

leadership of Turkmengas — does not seem feasible.

As of now, no multinational company has shown interest in building the pipeline. The main

reason for their reluctance is the reluctance of Turkmenistan to give them a stake in its

upstream Galkyanysh gas field, from where gas is to be sourced for the pipeline.

Turkmenistan‘s new conditions

The fate of the Turkmenistan-Afghanistan-Pakistan-India (TAPI) gas pipeline hangs in the

balance even as construction is expected to begin next year.

That is because Turkmenistan has argued that its current laws do not permit grant of

production sharing rights for onshore blocks to foreign companies. This has halted

negotiations and restricted the number of foreign companies coming forward to build the

pipeline.

Afghanistan, Pakistan India and

Government owned gas companies of

Turkmenistan, have estblished a company

that will build, own and operate the

planned 1,800 kilometer

Turkmenistan-Afghanistan-Pakistan-India

(TAPI) natural gas pipeline.

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Nandini Chemical Journal, December,2014 Page 23

SAFETY AND ACCIDENT PAGE

Fire at Dabur India skin care product factory at Baddi, Himachal Pradesh Dabur India‘s skin care products factory in Baddi, Himachal Pradesh, was damaged by a fire recently and production has begun in alternative facilities. Just over a year ago ,the company had launched its latest skin care product, a gel based facial skin bleach, development by Dabur‘s in house R&D team, featuring oxygen and aloe vera.

***** Accident at DuPont Chemical plant in Texas,USA Four workers at the Dupont plant in La Porte, Texas, have been killed, while one worker has been injured, following a chemical leak at the facility. The accident occurred on November 22 when methyl mercaptan, a toxic chemical used during the manufacturing process of insecticides and fungicides, was released. Dupont said the leak started when a valve on a container of methyl mercaptan did not function. Following the accident, an investigating team from the US Chemical Safety Board (CSB) has started its investigation.

***** Sivakasi factory blast Four persons died and six others suffered burn injuries in a blast in an aluminum powder factory in Ettakkapatti village near Sivakasi in Tamil Nadu on 2nd December ,2014. Preliminary investigation revealed that friction while grinding the aluminium powder triggered in the blast.Aluminium powder is an important raw material used in fire works manufacturing.

*****

Cracker factory blast in Tamil Nadu Two persons were killed in a blast in a cracker factory near M. Pudhupatti in Tamil Nadu. The workers were mixing chemicals for making aerial fireworks at a shed in Supreme Pyro Techniques Fireworks, when friction reportedly caused the blast.

***** Coal mine fire kills 26 in China A fire at a Chinese coal mine killed 26 workers in November 2014, state media reported, the latest fatal incident to hit the accident-prone industry. The blaze at the mine in the northeastern province of Liaoning also left 50 people injured, the official Xinhua news agency said, quoting the state-owned Fuxin Coal Corporation.

*****

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Nandini Chemical Journal, December,2014 Page 24

PLANT CLOSURES

Mitsubishi Gas Chemical to quit PTA business Mitsubishi Gas Chemical (MGC) will quit the purified terephthalic acid (PTA) business at the end of March 2015.

MGC and Toyobo are partners in Mizushima Aroma, an equally owned joint venture that operates a 260,000 metric tonne per year PTA facility at Mizushima, Japan, which will close.

Poor margins, caused in part by capacity building up in China and declining PTA prices, are the reasons for the withdrawal.

The plant currently supplies the domestic polyester market, which Mizushima Aroma is planning to quit.

Existing PTA capacity in Japan is about 900,000 metric tonne per year. The other PTA producers there are Mitsui Chemicals, with a plant at Iwakuni that has about 400,000

metric tonne per year of capacity and Toray Industries, with a plant at Okazaki designed for about 250,000 metric tonne per year.

Mizushima Aroma sources its para -xylene ( p -xylene) feedstock from a 350,000 metric tonne per year plant at Mizushima owned 51% by JX Nippon Oil & Energy and 49% by MGC. The future of the p -xylene facility when the PTA plant closes is unclear. JX

Nippon Oil & Energy, as the majority partner, will make a decision on the plant‘s future. MGC is concentrating on meta -xylene ( m -xylene), which it uses at a purified

isophthalic acid (PIA) plant. MGC‘s m -xylene plant, also at Mizushima, is designed to produce 150,000 metric tonne per year. It feeds MGC‘s 70,000- metric tonne per year PIA plant at the same site.

***** Styrolution to shut down polystyrene plant in Sweden

As part of restructuring of its polystyrene business in Europe, the Middle East and Africa (EMEA), Styrolution, a joint venture between BASF and Ineos, will close its 80 kilo metric tonne polystyrene production site located in Trelleborg, Sweden. The closure of

the facility is scheduled to occur by the end of 2014. Styrolution will continue to serve customers from its polystyrene sites located in

Antwerp, Belgium and Wingles, France. The planned closure is aimed at bolstering the long term economic sustainability of

Styrolution‘s polystyrene business in EMEA by further enhancing cost structures and maximising utilisation of its production assets in Antwerp and Wingles.The polystyrene

market in Europe has been characterised by decreasing demand, overcapacity and underutilisation.These market dynamics have also affected Styrolution‘s polystyrene business in the region, making it necessary for the company to take this difficult step.

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ANTI DUMPING PAGE Final duties on Chinese refrigerants The US Department of Commerce (Commerce Department) on 15 October, released its proposed final resolution regarding antidumping duties and countervailing duties 2014, on Chinese refrigerant gases imported into the United States. The proposed final resolution rules that imports from China of refrigerant gas R-134a, or hydrofluorocarbon-134-a, should be subject to antidumping duties of 280.67% and countervailing duties averaging 11.14%. The US International Trade Commission (ITC) will vote on the resolution. An affirmative vote will impose the duties for at least five years and negative vote would end the process, according to ITC. In October 2013, Mexichem, submitted two legal processes with the ITC against Chinese imports of refrigerant gases—one claiming antidumping duties and the second claiming countervailing duties. Mexichem says that after the preliminary resolution in December 2013, when the ITC unanimously ruled that the industry had suffered injury, the company requested that the Commerce Department pursue the required investigations to establish the resultant compensation duties. In April 2014, the Commerce Department released the preliminary resolution that Chinese imports should be subject to countervailing duties averaging 16.39%.In May, the department preliminarily resolved that Chinese imports should be subject to antidumping duties of 187.48%. After the April 2014 ruling, Mexichem submitted an emergency procedure which ―might achieve that the compensation duties become retroactive since the end of February 2014 for the additional imported volume.‖

***** Import of met coke from China Faced with Chinese dumping, met coke manufacturers in India have raised an alarm of a potential threat to Rs. 15,000-crore worth of bank exposure to the sector. Calling for an increase in import duty on met coke to at least 20 per cent, the Indian Met Coke Manufacturers' Association (IMCOM) expressed concerns over dwindling plant utilisation and increasing imports. China, which had imposed 40 per cent export duty on its met coke exports till December 2012, completely removed it thereby opening the doors for Indian importers with cheaper met coke. At present rates, domestic met coke is $ 40 per metric tonne costlier than imported met coke. India's overall met coke consumption, mostly by steel companies, has remained stagnant at around 35 million metric tonne per annum, out of which about 20 to 25 million metric tonne per annum is the captive capacities, which are unaffected by imports. The installed capacity of merchant met coke is about 10 million metric tonne per annum, but plant utilisation has declined to about 30 to 35 per cent across the sector. The total investment made in the met coke facilities is worth Rs. 30,000 crore. Plant utilisation of met coke will fall further. Most of the manufacturers including Gujarat NRE have gone for debt restructuring .

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SWITCH OVER FROM NAPHTHA TO ETHANE AS FEED STOCK GLOBAL TREND

Versalis (Milan) has confirmed plans to enhance the feedstock flexibility of the company‘s Dunkirk, France, steam cracker to enable the plant to consume low cost ethane imported from the United States. The Dunkirk cracker would be able to consume ethane for up to 50% of its ethylene output by 2016. The cracker‘s ethylene capacity of 500,000 metric tonne per year will remain unchanged and the project requires an investment of $127 to 190 million. Versalis is evaluating its C4 supply demand balances in the Mediterranean region before deciding whether to convert the Brindisi cracker to consume US ethane. The Brindisi cracker currently receives feedstock from a refinery at Taranto, Italy, operated by Versalis‘s parent ENI (Rome). Versalis‘s parent ENI (Rome). Versalis currently has two butadiene plants. They are at Ravenna, Italy; and Brindisi. Cracking ethane at Dunkirk and reducing the plant‘s naphtha consumption mean that the cracker‘s output of crude C4s will drop. Versalis has decided not to go ahead with plans to build a butadiene plant at Dunkirk. Versalis announced plans earlier to build a 100,000 metric tonne per year butadiene plant at Dunkirk for start up in late 2016.

A growing list of petrochemical companies are converting coastal crackers in Europe to consume ethane imported from the United States. Borealis, Ineos, and Sabic have each announced plans to ship US ethane to European crackers. Total is considering similar plans. The first wave of Europe‘s ―going lighter‖ feedstock strategy was mainly through LPG and the second wave is through cracking imported ethane.

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E-mail : [email protected], [email protected]

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Nandini Chemical Journal, December,2014 Page 27

FOCUS ON HFO 1234 yf - NEXT GENERATION REFRIGERANT

Lower global warming emissions

HFO-1234yf is being adopted because its global warming emissions are lower than those of incumbent MAC refrigerants, including R-143a. EU authorities have

instituted MAC standards that mandate R-134a be phased out because of its high global warming emissions. In the United States, the standards are voluntary, but automakers are switching to HFO-1234yf anyway.

Concerns

The holdout has been Germany‘s Daimler, the maker of Mercedes, who has

expressed flammability concerns about HFO-1234yf. Daimler says that HFO-1234yf has ignited when dispersed at high temperatures to

engine components, conditions the automaker says could occur in a head on collision. However, tests by EU and German authorities—while not denying that

HFO-1234yf could be flammable under extreme circumstances—have found the risk level to be very low and not necessitating regulatory intervention.

―These tests showed no ignition of refrigerants and very low hydrogen fluoride (HF) release despite the very high temperatures in the engine compartment,‖ the

European commission said earlier this year.

The refrigerant R-1234yf, also known as hydrofluoroolefin (HFO)-1234yf, is used in car air conditioning systems.

HFO-1234yf, a next-generation fluorocarbon refrigerant, will be used in

7 million automobiles by 2015, since refrigerants currently used in mobile air-conditioning (MAC) systems are phased out in the US and Europe, according

to DuPont. HFO-1234yf is currently the only commercially available refrigerant with

global warming potential sufficiently low enough to comply with the requirements of the MAC directive.

The substance is largely a replacement for R-134a, which has been used in MAC applications since chlorofluorocarbon-based refrigerants were phased

out under the Montreal Protocol.

HFO-1234-yf is being adopted by nearly all of world‘s top automakers, and DuPont expects that it will be in 3 million cars by the end of this year.

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FOCUS ON HFO 1234 yf –NEXT GENERATION REFRIGERANT

Joint developers DuPont and Honeywell, who jointly developed HFO-1234yf, maintain that the substance

is safe.

DuPont is planning a second phase of the plant, which will double capacity and come

onstream by the end of 2014. Project in China

While the substance was developed in anticipation of European MAC rules, production was located in China because of the need to quickly ramp up.

When the product was approved to conform to the MAC standard … China was the only place they could get the plant up quickly enough.

DuPont‘s plans DuPont is planning capacity expansions, which are on track. DuPont says that it has

sufficient supply to meet it‘s customers‘ projected demand and are prepared to make additional investments when long-term demand justifies it.

Honeywell‘s plans

In December 2013, Honeywell announced the construction of HFO-1234yf plant at Geismar, LA, as part of a $300-million program to expand capacity for the product worldwide. The plant is expected to be operational by 2016.

Demand driver

HFO-1234yf adoption in the US is driven by the newly strict Corporate Average Fuel Economy standards in addition to MAC standards and manufacturing considerations. The US light vehicle fleet must average 54.5 miles per gallon of gasoline by 2025.

Fluorocarbons players

DuPont is North America‘s largest maker of fluorocarbons, including HFO-1234yf and other substances, with 37% of annual production of 476,000 metric tonne.

Refrigeration and air conditioning are the largest end uses for fluorocarbons, although they are also often used as polymer precursors.

In Western Europe, the largest fluorocarbons maker is Solvay, with 31% of the 330,000-metric tonne market, followed closely by Arkema, with 30% of the market.

Production is concentrated in China. DuPont‘s joint venture

with Changshu 3F Zhonghao New Chemical Materials produces 3,000 metric tonne per year of HFO-1234yf in China, with European automotive customers using much of

that production.

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FOCUS ON HFO 1234 yf -–NEXT GENERATION REFRIGERANT

EU PROBES DUPONT- HONEYWELL REFRIGERANT COLLABORATION

R-1234yf

Honeywell and DuPont are the only two suppliers of HFO-1234yf to automakers. The cooperation between the two companies on production of HFO-1234yf has

reduced their decision making independence and restricted competition, according to the commission‘s provisional findings. The restrictions include a limitation of available quantities of HFO-1234yf that would have otherwise been brought to the

market as well as a limitation of related technical development, the commission says.

The commission says that it is concerned that a series of agreements concluded between Honeywell and DuPont in 2010 related to production and the development

of production processes for HFO-1234yf may have hindered competition on the market for the refrigerant.

View of DuPont

DuPont says that it has complied with applicable laws in developing and commercializing HFO-1234yf. DuPont says that it will fight this move of European

Commission every step of the way, as it has no basis in law or fact.

DuPont and Honeywell developed HFO-1234yf jointly in response to the MAC directive, according to DuPont. ―The regulatory time frame was short considering the significant challenges of developing and commercializing a refrigerant that

meets all the automotive industry‘s needs. This short time frame was a primary reason for DuPont and Honeywell working jointly‖.

HFO-1234yf would not have been successfully developed without DuPont and Honeywell working together, DuPont says.

The European Commission has issued a statement of objections to Honeywell and DuPont, citing the commission‘s preliminary view that a cooperation

started in 2010 to develop and produce refrigerant R-1234yf may have breached EU antitrust rules.

A statement of objections is a formal step in commission investigations into suspected violations of EU antitrust rules.

READ NANDINI CHEMICAL JOURNAL AND FORGE AHEAD

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Nandini Chemical Journal, December,2014 Page 30

CARBON FIBER - UPDATES Carbon fiber precursor plant in France Toray Industries has held a ceremony to mark the completion of a new polyacrylonitrile (PAN) manufacturing plant at Lacq, France. The product is used as precursor in the production of carbon fiber.

The subsidiary will also supply various Toray production bases, including the advanced materials subsidiary in South Korea, contributing to the group wide business expansion. Worldwide demand for PAN based carbon fibers exceeded 40,000 metric tonne per year in 2013 and is expected to continue growing by more than 15% per year. In addition to Toray‘s high performance regular tow carbon fiber Torayca, the company in February acquired Zoltek (St. Louis) and fully entered the large tow carbon fiber business, enabling it to respond to growing demand by supplying products that meet various market needs.

***** Carbon fiber plant in France Hexcel is expanding its carbon fiber production capacity through new polyacrylonitrile (PAN) and carbon fiber lines at Roussillon, France. The $250-million facility is part of Hexcel‘s ongoing, worldwide investment to create a diversified global supply chain to support aerospace customers‘ growing demand for carbon fiber composites. The new plant will occupy a 37-acre site at the Osiris Chemicals Industry Platform, which is close to Hexcel‘s weaving and prepreg manufacturing facilities near Lyon, France. Carbon fiber from the new plant will be supplied to Hexcel customers, including Airbus for the A350 XWB and Safran for the CFM LEAP engine. The construction of the new plant will begin by mid-2015. The unit is expected to be operational in early 2018. In recent years, Hexcel has increased its PAN and carbon fiber capacities through targeted expansions at existing facilities. Hexcel is currently investing in ongoing precursor and carbon fiber expansions at its facilities in the United States and installing its resin mixing and filming technology, first developed in Europe, in the country. Hexcel uses its own PAN and carbon fiber technology. The company currently operates a PAN plant at Decatur, AL; and carbon fiber facilities at Salt Lake City and Illescas, Spain.

The completed precursor plant is part of Toray‘s investment plan announced in March 2012 to expand carbon fiber production capacity at its four global production sites in Japan, the United States, France and South Korea. The new plant is the third PAN production base at the group, adding to facilities in Japan and the United States. It enables Toray‘s subsidiary for carbon fiber in Europe to integrate production, switching to precursor produced at its own plant from material imported from Japan, which will boost the company‘s cost competitiveness.

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UPDATE ON GAS / OIL EXPLORATION

Delay in ONGC drilling of HTHP fields

ONGC‘s plans to produce oil and gas from ‗high temperature, high pressure‘ fields (HTHP fields) will take at least another year to reach fruition.

It has been two years since ONGC set up a ‗Centre for Delivery‘ for generating oil and gas from ‗high temperature, high pressure (HTHP)‘ reservoirs. These tough to

tame reservoirs are estimated to hold about 350 million metric tonne of oil and gas, though yield is likely to be only a seventh of the figure.

In HTHP reservoirs, oil and gas lie embedded in sand and rocks at very high temperatures or pressure. Earlier, there was no technology to prodce hydrocarbons

from such fields, but companies have now developed the technology. The ‗Centre for Delivery‘ is based in Chennai.

ONGC plans to drill five wells ―in the near future‖, two in the Cauvery basin and

three in the Krishna-Godavari basin. However, industry sources say that even 2015-16 may be too optimistic. Tenders

have been issued calling for partners and consultants in the Cauvery basin, the first may be near Bhuvanagiri, which is both high pressure and ‗tight‘ (where

hydrocarbons lurk in hard rock and have to be fracked out). The oil-bearing zone is a lucractive 400 metres thick, and occurs at a depth of 3.3km.

Another at Periyakudi was discovered three years ago. This one, nearly 5 km down, features all three major challenges high temperature, high pressure and

tight. But the oil bearing zone is over half a kilometre thick. The third is a tight reservoir at Pallivaramangalam. In the K-G basin, three are on

land Bantumilli, Kottalanga and Mandapetta and one in the shallow waters off Yanam.

***** Polymer injection in Mangala field to enhance oil recovery

Cairn India has initiated polymer injection at the ‗Mangala‘ field to enhance recovery of oil. ―Mangala enhanced oil recovery (EOR) project is among the largest

polymer flood EOR programmes in the world. The polymer injection activity would gradually be ramped up.

Polymer flooding, also known as chemical flooding or chemical EOR, is one of the preferred EOR technologies used for improving oil recovery,particularly in older and

declining oil wells/oil reservoirs. In polymer flooding, polymers are used to make the water injected into the injection well oil reservoirs more viscous.

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UPDATE ON GAS / OIL EXPLORATION Cairn India has recognised the potential for chemical EOR at an early stage of development in its Mangala, Bhagyam and Aishwariya (MBA) fields. The reservoir quality, oil properties and ambient temperature make these fields ideal for the application of chemical flooding EOR methods such as polymer or alkaline surfactant polymer (ASP) flooding. The chemical EOR programme has a potential to enhance recoveries from the Mangala, Bhagyam and Aishwariya fields by around 300 mmbbls. The Mangala ASP pilot programme, the next phase of EOR has also yielded excellent results so far, suggesting better mobilisation of oil post polymer flooding. This will enable the company to further unlock the potential of the prolific Rajasthan block and help contribute significantly towards the nation‘s energy security.

***** Sale price of KG basin gas by GSPC Gujarat State Petroleum Corporation (GSPC) has agreed to sell natural gas produced from its Deen Dayal West (DDW) field in the Krishna-Godavari basin at a government approved price of $5.61/mBtu. This clears the uncertainty that the Gujarat based explorer wants a much higher gas price of $8.5 per mBtu against revised government approved price of $5.61 from November 1. GSPC has reportedly spent more than $2 to 3 billion to develop the acreage and also came across several hurdles to drill the area in the Bay of Bengal. Intitial estimated production were pegged at 5 to 6 mscmd, which could go upto 15 mscmd upon development of additional wells. The prolific find — KG-8 — later renamed as Deen Dayal is pegged to hold 1.8 trillion cubic feet (tcf) of reserves, which was also certified by upstream regulator Directorate General of Hydrocarbons (DGH). The block was bagged in 2003. GSPC is the operator with 80% stake, while UK‘s Jubilant and Canada‘s GeoGlobal Resources each have 10% share.

153 YEAR OIL WELL IN PITTSBURG, USA THAT IS STILL PUMPING ON

About 70 miles north of Pittsburgh in USA, a pothole pocked dirt road along the side of a warehouse leads to a solitary oil well. McClintock No. 1, the world‘s oldest continually producing oil well, is still going after 153 years, quietly churning out about 1/10 of a barrel a day from a small spot in a clearing of trees. Crude bubbles up from this 625-foot well. On its best days, McClintock yielded about 175 barrels. The well‘s output today is sold to a fuel company to make motor oil, but that is not really why it‘s still in operation.. ―It‘s definitely not economically viable right now. It‘s about the status.‖

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ACRYLONITRILE - PRODUCT PROFILE Appearance Clear and free from suspended matter

Chemical formula: C3H3N

CAS No. 107-13-1

Application Acrylonitrile is used as feedstock for the production of products such as acrylamide, acrylic fibers, adiponitrile, ABS and SAN resins, nitrile rubber Indian scenario Reliance Industries Ltd., is the only producer of acrylonitrile in India

Installed capacity: 41,000 metric tonne per annum Indian demand: Around 1,40,000 metric tonne per annum

Indian import

Period

(April to March)

Import

(Quantity in metric tonne)

2009-2010 64693

2010-2011 72617

2011-2012 77356

2012-2013 81963

2013-2014 100861

Global scenario At present, the world total production capacity of acrylonitrile is 6.4 million metric tonne per year. The enterprises with large production capacity are INEOS Group, with production capacity of 1.043 million metric tonne per year, Ascend Performance Materials, Inc. of America, with production capacity of 520,000 metric tonne per year, Japan Asahi Kasei of 500,000 metric tonne per year. The world acrylonitrile demand is about 6 million metric tonne. The major world acrylonitrile consuming regions are Asia, Europe and North America. Asia is the world's largest acrylonitrile consumption region, accounting for about 59% of the world's total consumption. In European region, the acrylonitrile consumption accounts for about 20% and in the American region, acrylonitrile consumption accounts for about 11%.

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ACRYLONITRILE - PRODUCT PROFILE Global import

Country

Period

2009 2010 2011 2012 2013

Quantity in metric tonne

Belgium 40,829 62,771 60,043 63,602 88,892

China 451,007 445,787 541,665 555,444 547,582

Egypt 23,295 39,853 11,230 19,252 21,611

France 68,900 82,507 86,934 83,419 82,868

Germany 67,832 66,006 57,145 58,843 64,662

Hungary 17,610 16,482 23,265 21,192 14,094

India 82,612 68,339 74,613 81,337 93,034

Korea, Republic of 82,462 84,784 87,084 113,472 100,032

Malaysia 57,230 96,143 80,900 69,396 90,988

Mexico 75,310 81,830 54,869 62,287 59,901

Netherlands 20,139 20,759 61,756 41,216 33,641

Peru 28,256 34,372 31,549 26,144 29,500

Portugal 51,126 43,786 47,611 54,182 45,393

Taipei, Chinese 91,541 113,981 107,834 107,433 97,820

Thailand 139,335 141,060 137,412 70,461 68,002

United Arab Emirates 8,483 2,100 14,756 7,790 11,686

United Kingdom 18,756 40,522 30,583 9,588 15,847

Others 37,045 86,068 87,454 42,084 95,263

Total 1,361,768 1,527,150 1,596,703 1,487,142 1,560,816

Global export

Country

Period

2009 2010 2011 2012 2013

Quantity in metric tonne

Belgium 4,282 12,266 18,475 14,941 27,039

Belarus 29,634 19,695 25,878 21,464 21,016

Brazil 42,342 57,990 38,530 51,454 44,155

Germany 67,448 91,149 117,339 62,150 54,742

Japan 262,168 212,336 288,087 128,966 100,741

Korea, Republic of 172,349 179,016 185,399 201,085 306,053

Mexico 7,653 43,672 22,431 15,647 22,673

Netherlands 27383 32672 10795 3217 183,911

Russian Federation 98,597 99,476 128,711 139,567 119,655

Taipei, Chinese 93,605 105,954 113,438 155,337 175,752

Turkey 3,556 18,890 13,962 18,133 10,480

United Kingdom 165,002 220,290 160,282 217,049 173,619

USA 504933 624188 528722 616344 447227

Others 9488 28933 25767 30466 48283

Total 1,488,440 1,746,527 1,677,816 1,675,820 1,735,346

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ACRYLONITRILE - PRODUCT PROFILE Process Acrylonitrile is produced by ammoxidation of propylene. Propyelne, ammonia and air are reacted in a fluidised bed reactor to produce acrylonitrile with acetonitrole and hydrogen cyanide as by products. The original catalyst consisted of bismuth phosphomolybdate on silica, but recent catalyst developments have improved yields and can boost capacity of existing plants by 20%. BP Amco Chemicals, Asahi Chemicals, and Mitsubishi Chemicals are working on a new generation propane based technology. Since the price of propane is lower than that of propylene, producers have focused on the research on propane ammoxidation process for producing acrylonitrile. Issues and lawsuit in China Ineos Group AG claims there are at least three new acrylonitrile factories being built in China that are illegally using its technology and it defended its high-stakes lawsuit against Chinese state owned petrochemical company Sinopec, by saying that it feared a wave of copycat factories there would threaten the future of its business. Ineos, which claims that its technology provides the basis of 90 percent of the world‘s acrylonitrile production, accused Sinopec in a lawsuit in China of violating Ineos intellectual property and misusing trade secrets to construct new facilities in China. It also suggested that the outcome of the legal battle could have major commercial implications, since most of the world‘s new acrylonitrile production through 2020 will be in China. Scenario in China

In 2013, China‘s total capacity to make acrylonitrile reached around 1.388 million metric tonne per annum and the total output reached around 1,2824 million metric tonne. In 2013, China‘s apparent consumption of acrylonitrile was 1.83 million metric tonne, being slightly more than that in 2012. China‘s consumption mix of acrylonitrile was around 48% for acrylic fiber, 28% for ABS/SAN, 14% for acrylamide, 5% for polyether polyols and around 5% for others including acrylonitrile-butadiene rubber.

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ACRYLONITRILE - PRODUCT PROFILE Major acrylonitrile producers in China, 2013 (kilo metric tonne per annum)

Producer Capacity Output Location

PetroChina Jilin Petrochemical Company 420 304.6 Jilin, Jilin Province

Shanghai Secco Petrochemical Co. Ltd., 260 288.7 Shanghai

Sinopec Anqing Petrochemical Co.Ltd.,Acrylic Fiber Plant 210 184.2 Anqing, Anhui Province

Sinopec Shanghai Petrochemical Co. Ltd., 130 128.4 Shanghai

PetroChina Fushun Petrochemical Co. Ltd., 90 76.8 Fushun, Liaoning Province

PetroChina Daqing Petrochemical Co. Ltd., 80 81.8 Daqing, Heilongjiang Province

PetroChina Daqing Refining & Chemical Co. Ltd., 80 80.6 Daqing, Heilongjiang Province

Sinopec Qilu Company 80 106.5 Zibo, Shandong Province

PetroChina Lanzhou Petrochemical Co. Ltd., 30 21.5 Lanzhou, Gansu Province

Shandong Qitai Petrochemical Co. Ltd., 8 9.3 Zibo, Shandong Province

Total 1388 1282.4

China‘s new/planned acrylonitrile projects (kilo metric tonne per annum)

Producer Capacity Remarks

Shanghai Secco Petrochemical Co. Ltd., 260 The project will be put into operation by the end of 2014

China Blue Chemical Ltd., 200 Being located in Hainan Province and undetermined

China Wanda Group 260 The first phase 130 kt/a will start up in October 2014

Guangxi Keyuan New Materials Co. Ltd., 200 The project will be put into production in 2014

Shandong Keluer Chemicals Co. Ltd., 260 -

Bohai INEOS Chemical (Tianjin) Co. Ltd., 260 The project will be put into operation by 2016

Total 1440

China‘s supply and demand for acrylonitrile during 2008-2013 (Kilo metric tonne) Year Output Import volume Export volume Apparent

consumption Self-sufficiency in

%

2008 942 285 6 1,221 76.6

2009 967 451 0.0 1,418 68.2

2010 1,090 446 0.0 1,536 68.9

2011 1,111.2 541.7 0.0 1,652.9 67.0

2012 1,158.2 555.4 0.0 1,713.6 67.6

2013 1,282.4 547.6 0.0 1,830.0 70.0

In general, China‘s demand for acrylonitrile will be close to 2 million metric tonne in 2014 and will increase at an average annual rate of 7% to 8% in the next few years. Acrylonitrile project in Middle East region Saudi Basic Industries Corporation (Sabic), and its Japanese partners, Mitsubishi Corporation (Mitsubishi) and Asahi Kasei Chemicals Corporation (Asahi) signed a joint venture to build the first acrylonitrile and sodium cyanide plant in the Middle-East. Sabic, Mitsubishi and Asahi established in April 2011 the joint venture Saudi Japanese Acrylonitrile Company (SHROUQ) in Saudi Arabia.In order to benefit from existing infrastructures. The joint venture partners selected Sabic site at Al-Jubail Industrial City in the Eastern Province of Saudi Arabia to erect this first Acrylonitrile project. Capacity : - 200,000 metric tonne per year of acrylonitrile and 40,000 metric tonne per year of sodium cyanide. After the completion of this new acrylonitrile plant, capacity of Asahi will reach 1.4 million metric tonne per year.

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POLYCARBONATE – GLOBAL SCENARIO

Properties and its significance

Property Significance

Impact strength

Makes it useful for long service life under extreme,

heavy duty conditions.

Dimensional stability

Qualifies it for use in precision engineered

components, where close tolerances are required.

Transparency

Approximate that of the light transformation of

acrylics and glass.

Burning properties

Difficult to ignite and usually extinguishes on

removal from flame which is yellow and sooty.

Unmodified unfilled grades typically have a UL94 V-2 rating and filled grades UL94 V-1.

Flame retardant grades may be rated UL94 V-0 and UL95-5-V

Self extinguishing properties

Makes it useful in applications involving high temperature use, where safety hazards may exist.

Solubility

Dissolves in solvents of similar solubility parameter, which have proton donating ability (eg.

chloroethane and dichloromethane, chloroform and 1,1,2-trichloroethane).

Chemical and solvent resistance

Somewhat limited resistance to hydrolysing agents.

Not resistant to caustic soda, caustic potash, ammonia and many aromatic amines.

Some resistance to dilute mineral acids.

Key processing properties

Tends to pick up small amount of water (upto 0.3%) and thus it is important to keep material very dry before processing.

Polycarbonate is an amorphous engineering thermoplastic, which combines superior mechanical, optical, thermal and electrical properties offered separately

by metals, glass and other plastics.

Polycarbonate is available in different grades and can be extruded, blow and injection moulded. Polycarbonate is also used in compounds or blended with

other polymers. CAS No. 25037-45-0

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POLYCARBONATE – GLOBAL SCENARIO

Commercial Grades

Unreinforced Standard Grade Unreinforced Flame Retardant Grade Glass Reinforced grade

Special grade

Application Polycarbonate resin is used as moulds, sheets, blends, films and compounds in the

following sector

* Electronic, Electrical and Instrumentation industry * Optical storage devices * Automobile sector

* Safety and security appliances * Writing instruments

* Construction sector * Household and domestic ware

* Lighting * Medical devices

Emerging applications

Emerging applications of polycarbonates include plastic glazing, inhalers, orthopedic devices.

Bayer MaterialScience has developed and launched two new products based on polycarbonate that meet the requirements for use in furniture.

Plastic glazing for cars

GE Plastics and Bayer have formed a joint venture, Exatec, to develop the market for plastics glazing.

Several car manufacturers such as Opel have begun to use polycarbonate panels. Several plastics moulding companies also specialise in making plastics glazing for

cars.

Automotive windscreens

The industry is investing much effort in using polycarbonate in automotive

windscreens. Although widespread use is still years away, this is potentially a fast growth area.

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POLYCARBONATE – GLOBAL SCENARIO

Indian import

Period

(April to March)

Import in metric tonne

2009 to 2010 54,315.

2010 to 2011 105,264

2011 to 2012 116,028

2012 to 2013 122,742

2013 to 2014 123,433

There is no production of polycarbonate resin in India.

Global import / export

Period

(January to December)

Import in metric tonne

Export in metric tonne

2009 3,170,662 2,859,659

2010 3,761,189 3,054,779

2011 3,496,490 2,988,117

2012 3,913,109 3,362,588

2013 3,828,282 3,031,152

Global importers

Country

2009

2010

2011

2012

2013

Quantity in metric tonne

China 1,027,276 1,265,529 1,228,114 1,375,483 1,378,620

Hong Kong, China 346,316 426,011 339,005 325,377 315,070

Singapore 52,020 62,162 75,756 196,775 175,083

Taipei, Chinese 163,321 170,997 168,435 197,668 166,740

Mexico 347,977 167,550 124,817 148,654 154,304

Germany 105,671 125,395 140,394 167,195 148,409

Italy 104,298 128,068 123,408 124,569 122,137

India 44,133 98,291 106,578 119,881 122,071

Korea, Republic of 79,490 100,127 100,285 91,727 93,630

Japan 86,694 104,095 86,718 75,874 70,706

Others 813,466 1,112,964 1,002,980 1,089,906 1,081,512

Total 3,170,662 3,761,189 3,496,490 3,913,109 3,828,282

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POLYCARBONATE – GLOBAL SCENARIO

Global exporters

Country 2009 2010 2011 2012 2013

Quantity in metric tonne

Korea, Republic of 313,211 336,017 365,560 434,776 484,463

United States of America 270,433 388,306 395,091 431,562 400,041

Thailand 370,248 382,171 388,977 380,728 346,382

Singapore 212,854 245,100 252,842 350,141 328,906

Taipei, Chinese 198,162 224,962 208,562 233,782 267,373

Spain 234,693 278,921 248,723 228,971 241,787

Netherlands 194,862 184,481 208,875 230,814 224,985

China 214,671 295,427 237,969 211,730 208,858

Japan 158,276 180,132 162,549 182,637 161,439

Saudi Arabia 0 366 66,889 193,709 161,156

Others 692,249 538,896 452,080 483,738 205,762

Total 2,859,659 3,054,779 2,988,117 3,362,588 3,031,152

Global supply scenario

The global polycarbonate market is growing 3.2% this year and total demand is expected to reach 3.7 million metric tonne per annum. Capacity will be growing above 5% over the next five years, creating opportunities for buyers to negotiate price reductions. Demand for polycarbonate is now very much driven by developments in China. Asia now represents 59% of total demand. The United States is just 14%. Five new polycarbonate plants are being built in China and one in Korea. Global consumption by end use sector

Electronics 21%

Sheet/Flim 18%

Optical media 16%

Other applications 45%

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POLYCARBONATE – GLOBAL SCENARIO

Major PC producers in China in 2013 (kilo metric tonne per annum)

Producer

Capacity

Sinopec Mitsubishi Chemical Polycarbonate (Beijing) Co. Ltd. 60

Bayer MaterialScience (China) Co., Ltd. 200

Teijin Polycarbonate Co., Ltd. 147

Lingyou Engineering Plastics (Shanghai) Co. Ltd., 80

Total 487

PC projects newly constructed or planned in China (kilo metric tonne per annum)

Enterprise

New capacity

Expected time for starting production

Ningbo Zhenyang Chemical Co. Ltd., 100 March 2014

Luxi Chemical Group Co., Ltd., 65 2016

Sinopec SABIC Tianjin Petrochemical Co., Ltd., 260 2017

Bayer MaterialScience (China) Co. Ltd., 200 2017

Yangquan Coal Industry Group Qingdao Hengyuan Chemical Co. Ltd.,

100 2016-2017

Lihuayi Group Weiyuan Chemical Co. Ltd., 60 2016-2017

Globe Joint Chemical Co., Ltd. 130

Yantai Wanhua Polyurethane Co., Ltd., 100

The new capacity comes on top of a SABIC polycarbonate expansion in Saudi Arabia in 2011.

Process outline

Most polycarbonate is produced via routes that use phosgene and bisphenol-A. Several producers have commercialized processes that use non phosgene routes

and several of the new polycarbonate plants employ non phosgene processes.

Prognosis

In recent times, substantial increase in demand has taken place in the optical storage media.

The growth in the automobile sector and construction activities also would ensure steady growth in demand for polycarbonate resins and sheets as well as blends.

While a number of new applications are emerging, the growth in demand would even become more vibrant, if strong application development efforts would be

initiated by the manufacturers.

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SPOTLIGHT ON SPECIALITY CHEMICAL ETFBO

Chemical name: 4-ethoxy-1,1,1-trifluoro-3-butene-2-one

Common name: ETFBO

CAS number: 59938-06-6

Molecular formula: C6H7F3O2

Boiling point: 150 deg.C

Relative density: 1.2155 g/ml

Purity: Min 98%

Appearance: ETFBO is a flammable, yellow liquid with an etherical

odour Stability: ETFBO is unstable in water, where it rapidly reacts to give

aldehydes and hydrogen fluorides

It has a boiling temperature of 159 deg.C and low volatility

Toxicity:

ETFBO is very toxic after short term exposure by inhalation and harmful after oral

exposure. After repeated exposure via inhalation, adverse effects in the respiratory tract were observed at very low concentrations.

ETFBO is irritating to the eyes and the skin. It may cause allergic skin reactions.

ETFBO does not cause genetic effects.

Uses: ETFBO is used as an intermediate in chemical synthesis.

ETFBO is a building block that boosts the efficiency of active ingredient molecules

and makes them more easily biodegradable. Large active ingredient molecules for pharmaceutical products and agrochemicals

are put together from smaller, so-called synthetic building blocks. ETFBO is such a synthetic building block, which contributes both fluorine and a complex molecular

structure to the active ingredient molecule at the same time. Packing:

PE lined metal drums; samples in glass bottles

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SPOTLIGHT ON SPECIALITY CHEMICAL -ETFBO

ETFBO plant in Germany, installed by Solvay

Solvay has inaugurated a 4-ethoxy-1,1,1-trifluoro-3-butene-2-one (ETFBO) manufacturing plant in Bad Wimpfen, Germany.

In Bad Wimpfen, Solvay produces a wide range of special fluorine chemicals.

The so called CF3 chemistry has been an important pillar for the site since the 1980s, when the production process for trifluoroacetyl chloride (TFAC) was

developed. Today, it is a high revenue product and a raw material for ETFBO.

To begin with, only small amount were synthesised for research purposes in Bad Wimpfen. These were then successfully tested in co operation with selected customers.

After that, ETFBO was produced at the industrial scale in a multi purpose facility.

The rapidly growing demand now makes a dedicated ETFBO facility viable.

Built with an investment of €5m, the facility will produce 1,000 metric tonne of the ETFBO

compound each year and will expand Solvay's portfolio of fluorinated organic intermediates.

Solvay in Bad Wimpfen is the most important

site for the production of these fluorinated speciality chemicals and the only ETFBO supplier worldwide.

In Bad Wimpfen, Solvay produces a wide range

of special fluorine chemicals.

ALL INDIA DIRECTORIES Nandini Consultancy Centre Pvt. Ltd. have brought out the following publications on chemical industries. * All India Directories * Statewise Directories In the above directories address,phone number,fax number,e-mail and website of several manufacturers along with the activity details and new projects under planning / implementation are provided. All the above directories are updated every day and you would be receiving the most updated publication.

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Nandini Chemical Journal, December,2014 Page 44

PHOSGENE – PRODUCT PROFILE

Synonyms : CG; carbon dichloride oxide; carbon oxychloride; Chloroformyl chloride; dichloroformaldehyde; dichloromethanon

If this compound is handled with extensive care and all necessary precautions are taken to avoid inhalation, the problem can be overcome.

Uses and application

Phosgene is used for producing many polycarbonates and isocyanates. Toluene diisocyanate, methylene diphenyl diisocyanate are the two most important

derivatives of phosgene.

* Phosgene is a versatile reagent used in many well known applications including the synthesis of complex heterocycles peptides and protecting groups, phenobarbitone.

* Phosgene is gaining increasing importance in the manufacture of key

intermediates for the synthesis of oral antibiotic becampicilline and in the phosgenation of aldehydes and epoxides. A new hexa alkyl quanidinium chloride catalyst has been developed which can be used in the synthesis of acid chlorides,

dementhylation of aryl methyl esters and regeneration of triphenyl phosphine which is used in vitamin synthesis.

CAS No.: 75-44-5 Molecular Formula: COCl2

Appearance: Colourless gas

Solubility: Decomposes in water Soluble in benzene, toluene, acetic

acid, decomposes in alcohol and acid

Toxicity Phosgene is highly toxic and

symptoms of its inhalation are noticed slowly.it mainly leads to respiratory

disorders such as suffocation, which is a major restraint for the growth of the phosgene industry.

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PHOSGENE – PRODUCT PROFILE

Diethylcarbamoyl chloride

Diethylcarbamoyl chloride is a derivative of phosgene and is used to hydrolyze water insoluble compounds and is used in the pharmaceutical industry.

Process

Industrially, phosgene is produced by passing purified carbon monoxide and chlorine gas through a bed of porous activated carbon, which serves as catalyst.

CO + Cl2 → COCl2 (ΔHrxn = −107.6kJ/mol)

The reaction is exothermic and therefore, the reactor must be cooled. Typically,

the reaction is conducted between 50 and 150 deg.C. Above 200 deg. C, phosgene reverts to carbon monoxide and chlorine.

Because of safety issues, phosgene is often produced and consumed within the same plant and extraordinary measures are introduced to ensure safe handling of

the product.

Restrictions under OPCW Phosgene is listed on schedule 3 of the Chemical Weapons Convention:

All production sites manufacturing more than 30 metric tonne per year of phosgene must be declared to the OPCW.

Although less dangerous than many other chemical weapons, such as sarin, phosgene is still regarded as a viable chemical warfare agent because it is so easy

to manufacture when compared to the production requirements of more technically advanced chemical weapons such as the first generation nerve agent tabun.

Global consuming region

Western Europe has been the leading consumer of phosgene followed by North America and China.

Global producers

PPG, Dow and VanDeMark Chemical are the major US based phosgene producers.

There are a few other producers in different countries.

VanDeMark Chemical (Lockport, NY),USA The company makes phosgene and phosgene derivatives in the form of over

30 chemical compounds.

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PHOSGENE – PRODUCT PROFILE

VanDeMark Chemical (Lockport, NY), acquired Isochem‘s Framochem (Kazincbarcika, Hungary) subsidiary, rejoining the US and European phosgene

operations of the former SNPE (Paris). Isochem is owned by private equity firm Aurelius (Munich), which acquired the

business from state owned SNPE in 2010. SNPE owned VanDeMark from 1999 to 2007.

With combined total of 22,000 metric tonne per year of phosgene capacity, the combined company will be one of the world‘s largest producers of fine chemicals

focusing on phosgenation chemistry. Framochem operates six multi purpose production lines at Kazincbarcika.

VanDeMark produces for the merchant market, as well as its own on site requirements for pharmaceutical intermediates.

Jiangsu Jialong Chemical Co., Ltd.,China

Phosgene capacity of the company is 6000 metric tonne per annum . The company

has a leading position in the Chinese market with market share of 42% for phosgene based esters and ranks the second with market share of 37% for furanphenol, Jiangsu Jialong is located in Xuzhou, Jiangsu province

Hodogaya Chemical,Japan

Hodogaya Chemical was established in 1916. Later, the company began to manufacture phosgene, an ingredient used in the manufacture of polyurethane and

other high performance resin materials.

Paushak Limited, India Paushak is a specialty chemicals company belonging to the Alembic group. Located

near Vadodara, Gujarat, Paushak is involved in the production of phosgene gas and phosgene based specialty Chemicals / intermediates.

Atul Ltd,India

Phosgene chemistry is a core competency of Atul‘s Pharmaceuticals and intermediates division.

Atul Ltd is leading producer of sulfonyl urea herbicides and producer of phosgene and phosgene based intermediates.

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PHOSGENE – PRODUCT PROFILE

The company, is into various agro chemical products and launched Metoxuron, a phosgene based pesticide.

Atul Ltd and Stamicarbon B.V. the DSM Licensing Center (DLC) have signed long term contract for exclusive manufacture and supply of a polymer performance

additive based on phosgene chemistry.

Stamicarbon has patented the application of this specialty/performance chemical for use in polyamides. Atul has established the manufacturing process based on initial guidelines given by Stamicarbon.

Atul manufactures the specialty chemical and DSM will market it worldwide under

their brand. Demand

Phosgene continues to find increasing use as the demand for fine chemicals increases from pharmaceuticals and agrochemicals manufacturers.

Toluene diisocyanate (TDI) and methylene diphenyl diisocyanate (MDI) account for 80% of phosgene‘s demand. Flexible polyurethane foams constitute by far the

largest market for TDI.

PUBLICATION ON ALGAE BIOFUEL GLOBAL OVERVIEW AND INDIA’S OPPORTUNITIES

The publication, which has been edited based on extensive study and research,

discusses the various recent developments across the world with regard to algae and its

derivative products. The book alsohighlights algae and its derivatives as an appropriate

investment opportunity in India.

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Tel:91-44-43540719, 43511945, 24916037,

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Page 48: Volume 22 Issue 3 December 2014 newnsa ndern fFneAC.

Nandini Chemical Journal, December,2014 Page 48

PHOSGENE – PRODUCT PROFILE

NON PHOSGENE ROUTES TO ELIMINATE USE OF PHOSGENE

Polycarbonate

Polycarbonate production is based on reacting phosgene with phenol to produce diphenyl carbonate (DPC), which is then reacted with bisphenol A (BPA) to produce

the polymer and liberate phenol for reuse.

The non phosgene route developed by various licensors involve the same overall approach, where polymerisation relies on the transesterification of DPC (diphenyl carbonate) with BPA. This is more commonly termed as the melt process, as the

two stage polymerisation takes place in the absence of solvents.

Commercial processes for DPC production (non phosgene route) is given below

Name of the company Process adopted / developed

Sabic Innovative Plastics Oxidative carbonylation of methanol to yield dimethyl carbonate (DMC). The DMC undergoes trans esterification with phenol to give DPC

Bayer DMC is made by carbonylation of methyl nitrite

Mitsubishi Gas Chemical Urea is reacted with n-butanol to give dibutyl carbonate The dibutyl carbonate undergoes trans esterification with phenol to give DPC.

The non phosgene process for polycarbonate (PC) production developed by

Asahi Kasei is the world's first to use carbon dioxide as starting material. The new process eliminates the hazards associated with the use of carbon

monoxide, phosgene and methylene chloride as process materials. The process features high productivity and yield, little by product, less contaminated process

water requiring treatment and low impurities in product PC. High purity ethylene glycol (EG) is a co product of the process.

Because of safety issues concerning phosgene use, several companies have commercialized processes that use non-phosgene routes.

With the increasing demand for safer and cleaner chemical processes, the hazardous phosgene route has to be improved or essentially being replaced by

eco friendly technologies with CO2 as the alternative C1 starting material.

Already, several of the newer polycarbonate plants employ the non phosgene processes. Long-term non-phosgene for polycarbonate seems the way to go, not only for safety concerns, but because significantly less capital is employed.

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PHOSGENE – PRODUCT PROFILE

Plants Licensed by Asahi Kasei for polycarbonate by non phosgene route

Licensee

Location

Capacity

(metric tonne per annum)

Chimei-Asahi Corp. Tainan, Taiwan 65,000

Chimei-Asahi Corp. Tainan, Taiwan 75,000

OAO Kazanorgsintez Kazan, Russia 65,000

Honam Petrochemical Corp Yeosu, Korea 65,000

Cheil Industries Inc Yeosu, Korea 65,000

Non phosgene route for diphenyl carbonate

GE produces diphenyl carbonate (DPC) which is produced from carbon monoxide, methanol and oxygen using Enichem Technology.

Mitsubishi has technology for making DPC from di-n-butyl carbonate, which is be produced from urea and n-butyl alcohol.

Asahi/Chi Mei produces DPC from DMC, which is produced by methanolysis of

ethylene carbonate. Dimethyl carbonate (DMC) from CO2

DMC is an ambient liquid and currently used in the production of polycarbonates

and lithium batteries. In the future, it is expected that DMC and its derivatives will be used as additive to gasoline and diesel.

DMC is produced from phosgene and non phosgene route. Phosgene route involves the reaction of phosgene and methanol, with hydrochloric acid as

byproduct. DMC has been produced by the reaction of methanol with phosgene in a concentrated sodium hydroxide solution. However, owing to the high toxicity and the severe corrosivity of phosgene, this process has been abandoned gradually.

Currently, DMC is produced mainly by oxidative carbonylation of methanol (non

phosgene route). The synthesis can be carried out in both liquid and gas phases.

Non phosgene route (developed by Polimeri / Lummus) involves the reaction of carbon monoxide, methanol and oxygen. Carbon dioxide is produced as by product. The CO2 is sent to a CO generation unit and recycled back to the process.

The process avoids the safety and waste product issues associated with

conventional phosgene based DMC processes.

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PHOSGENE – PRODUCT PROFILE The demand for DMC has grown strongly in recent times because of its green

properties. It is used increasingly as a substitute for toxic products such as phosgene as well as traditional methylation agents. Other applications include as a

solvent for coatings, an octane booster in petrol and as a component of diesel.

Akzo Nobel Industrial Chemicals (ANIC)

Akzo Nobel developed a production route using CO2 as raw material.

The conversion process involves reacting CO2 with hydrogen to produce methanol. Methanol is then converted into DMC using CO2. At present, the company conducts pilot study and intends to scale up the design to 50,000 to 100,000 metric

tonne per annum.

The DMC process consists of a combination of new catalysts and new reactor technology. VITO in Flanders and SINTEF in Norway joined Akzo Nobel as partners in developing the technology.

SINTEF has the high throughput screening facilities needed to test the large number

of catalysts and this led to 240 unique catalysts, 40 of which are now being tested in depth.

Both the European Union and the Dutch government are also contributing financially to the R&D efforts.

King Saud University, Saudi Arabia

Recently, direct synthesis of DMC from CO2 and CH3OH has been reported as a most attractive route due to the low cost of CO2 and the environmentally benign

process. However, DMC yield in this route is relatively low due to the fact that CO2

is thermodynamically stable and kinetically inert and due to the deactivation of catalysts induced by water formation in the reaction process.

Scientists studied the reaction over Cu–Ni/graphite nano composite catalyst in

gaseous phase and obtained 10.13% of CH3OH conversion and 89.04% of DMC selectivity at 105 deg C.

The other group of scientists studied the synthesis of DMC from gaseous methanol and CO2 over H3PO4 modified V2O5 catalyst with various molar ratios H3PO4 / V2O5

(P/V). The best conversion (1.95%) and selectivity of DMC (92.12%) was obtained at 130 deg C on the catalyst H3PO4 / V2O5 (P/V = 0.20).

The scientists from King Saud university studied synthesis of DMC from CH3OH and CO2 in gas phase system under atmospheric pressure, using Co1.5PW12O40 as a

catalyst. It was found that both CH3OH conversion and DMC yield decreased with increasing temperature, owing to the decreased CO2 adsorption on the catalyst at

high temperatures.

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PHOSGENE – PRODUCT PROFILE

The optimal reaction conditions for the synthesis of DMC are lower temperature and high space velocity.

Mitsubishi Heavy Industry (MHI)

MHI is developing two step process using CO2 and methanol to produce dimethly carbonate (DMC).

Non phosgene route for cyclic carbonate from CO2

The cycloaddition of epoxides with CO2 is one of the most promising and eco friendly phosgene free methods for the manufacture of cyclic carbonates since this

would be a highly efficient and full atom efficiency process with high selectivity. Five membered cyclic carbonates, as one of the most important classes of

heterocycles starting from CO2, have found wide applications such as electrolytic elements of lithium secondary batteries, polar aprotic solvents, monomers for

synthesizing biodegradable polycarbonate, chemical ingredients for preparing pharmaceutical or agricultural chemicals and alkylating agents.

Phosgene Free carbamoylation of aniline via dimethyl carbonate

Organic carbamates are versatile compounds employed as pesticides, fungicides and herbicides, dyes, pharmaceuticals, cosmetics and in the synthesis of

polyurethanes, in addition to being used as protecting groups. Industrially, carbamates are synthesized predominantly through the reaction of the parent amine with phosgene (i.e., chloroformate) . This process is toxic and produces

unwanted waste.

Probably the most promising phosgene free synthetic approach for carbamoylation of aniline is the one involving dimethyl carbonate (DMC) chemistry.

MOLASSES & STARCH BASED CHEMICAL PROJECTS

PUBLICATION AVAILABLE IN CD

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E-MAIL: [email protected], [email protected]

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SOLVAY’S PLANS FOR SODA ASH

Devnya plan

Devnya, Solvay‘s largest synthetic soda ash production plant in Europe and one of the largest such plants globally, will be equipped with a new steam boiler whose

energy efficiency will reduce carbon dioxide emissions and improve the site‘s environmental performance. The facility‘s capacity will remain 1.5 million metric

tonne per year. Solvay‘s soda ash and derivatives business has reported sales of €1.4 billion this

year, a slight increase on 2013.

Closure of plant in Portugal

The company, as part of its restructuring, closed down a 230,000 metric tonne per year soda ash unit at Povoa, Portugal, in February,2014.

Facility in USA

Solvay‘s Green River, WY, soda ash facility, the company‘s only trona plant, will be expanded by 150,000 metric tonne per year, to 2.65 million metric tonne per year, by the beginning of 2015. The increase is dedicated to export markets.

Sodium bicarbonate facility

Solvay operates two sodium bicarbonate facilities in the United States and produces the material at all its European soda ash plants.

Solvay will complete 100,000 metric tonne per year sodium bicarbonate facility at

Map Ta Phut in mid-2015. The plant will serve Asia‘s food, feed, and health markets, as well as the flue gas treatment industry.

Two largest European facilities of

Solvay, at Devnya and Torrelavega, Spain, are both situated on coasts and

are the main units for supplying overseas as well as their respective local markets. Other Solvay plants in

Europe—at Bernburg and Rheinberg, Germany; Dombasle, France; and

Rosignano, Italy—cater to their

respective domestic markets.

Solvay, the world‘s leading producer of soda ash, has announced plans to

invest in its plant at Devnya, Bulgaria, to improve energy efficiency.

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NEWS ROUND UP – INTERNATIONAL

Phosphine plant in USA Cytec Industries has announced the mechanical completion of the Welland, ON, phosphine manufacturing plant. This facility will double Cytec‘s phosphine and derivative manufacturing capacity.

***** Activated carbon capacity expansion Cabot and Westmoreland Coal (Englewood, CO) are doubling capacity of activated carbon, to 70 million lbs, at their jointly owned site at Bienfait, SK. The new capacity will be online in 2016.

***** New methionine complex in Singapore Germany‘s Evonik has announced that its new methionine complex in Singapore came on stream on November 4,2014 after two years in construction. This plant has capacity of 150,000 metric tonne per annum , bringing Evonik‘s methionine capacity worldwide up to 580,000 metric tonne per annum. Evonik markets DL-methionine under the ‗MetAmino‘ brand name. The company has spent over €500-mn on the complex. ‗MetAmino‘ and all strategically important precursors will be produced in the new methionine complex. The feed additive ‗MetAmino‘ ensures more balanced nutrition of poultry and swine, conserving resources and the environment and thus making a valuable contribution to sustainability in food production. In addition, Evonik is investing in amino acid specialities with high growth rates.

Evonik is the only company in the world that produces and markets the four most important amino acids that are required in advanced animal feed: ‗MetAmino‘ (DL-methionine), ‗Mepron‘ (DL-methionine for ruminants), DL-Methionine for ‗Aquaculture‘, ‗Biolys‘ (L-lysine source). ‗ThreAmino‘ (L-threonine), and ‗TryAmino‘ (L-tryptophan).

***** Evonik’s German plant for polybutadienes Evonik Indutries has opened a new plant for hydroxyl terminated polybutadiene (HTPB) in Marl, Germany. The Group invested a mid double digit million euro amount in the plant, which has a production capacity of several thousand metric tonnes per year.

Ammonia plant in USA Linde will build an ammonia plant for J.R. Simplot (Boise) adjacent to Simplot‘s phosphate fertilizer complex at Rock Springs, WY. The 600- metric tonne per day plant will supply Simplot‘s Rock Springs complex as well as its Pocatello, ID, phosphate fertilizer production site. The plant will take about two years to complete.

*****

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NEWS ROUND UP – INTERNATIONAL

Polylactic acid plant in Thailand Dutch biotechnology company, Corbion Purac is taking the next step in the bioplastics value chain by setting up a 75000 metric tonne per annum polylactic acid (PLA) plant in Thailand (estimated €60-mn capex). The announcement forms part of Carbion‘s updated strategic direction for 2015-2018 Corbion will also continue exploring strategic alliances as part of its PLA growth strategy, in order to enhance the business opportunities while mitigating the associated risks. Corbion Purac will continue selling lactides to both existing and new PLA polymerisation customers. Lactide sales for the coatings and adhesives markets will also continue.

***** Chemtura to expand ADPA antioxidant capacity... Chemtura will increase capacity for its Naugalube alkylated diphenyl amine (ADPA) liquid antioxidants at three sites ―to prevent predicted future shortages of antioxidants in the automotive petroleum additive industry worldwide.‖ By 2015, the company will increase capacity at its Elmira, ON, site by 20%; its Latina, Italy, site by 25%; and its Kaohsiung, Taiwan, site by 10%.

Antioxidant demand is being driven particularly by Corporate Average Fuel Economy standards, which are moving the industry toward downsized turbo charged engines with higher power densities, Chemtura says.

*****

In addition to the sites in the United States, China, and Israel, this acquisition complements Nilit‘s global nylon 6,6 manufacturing operations.

*****

Evonik will market HTPB under the brand name ‗Polyvest HT‘ and with it the company is extending its polybuytadienes product portfolio by a further functionalised grade. Polyvest HT‘ is primarily used in sealing compounds for insulating glass windows as well as in adhesives for automotive construction. With the Marl production site, the company have a backward integration in butadiene.

*****

Invista’s nylon plant at Americana, Brazil Nilit (Migdal HaEmek, Israel), a manufacturer of nylon 6,6 for thermoplastics and apparel applications, has signed an agreement to acquire Invista‘s Americana, Brazil, manufacturing site with intent to continue the site‘s nylon 6,6 operations. Nilit is an integrated nylon-6,6 business engaged worldwide in fibers for the textile industry and engineering plastics for the automotive and

electrical industries.

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TECHNOLOGY DEVELOPMENT

Each year, more than 700 million metric tonne of rice is harvested worldwide and the disposal of the rice husks is an environmental challenge.

***** BASF invest in developing highly repellent slippery surfaces BASF Venture Capital has led a $3 million Series A financing with a $1.5 million investment in SLIPS Technologies Inc. based in Cambridge, Massachusetts.The Swiss entrepreneur and private investor Hansjörg Wyss has also participated in the financing . SLIPS Technologies develops customized, highly repellent slippery surfaces for customers in all industries including energy, packaging, consumer, automotive and environmental. The company‘s ground breaking technology platform was created by Prof. Joanna Aizenberg and her team at the Wyss Institute for Biologically Inspired Engineering in Cambridge, Massachusetts, and the Harvard University School of Engineering and Applied Sciences in Cambridge, Massachusetts . Alongside the investment, BASF has signed a joint development agreement with SLIPS Technologies to develop SLIPS coated thermoplastics with primary focus on thermoplastic polyurethanes (TPUs). TPUs are used in a variety of applications such as sports and leisure footwear, industrial cables as well as specialty films. ―By collaborating with SLIPS Technologies, we will develop and commercialize TPUs with new and exciting properties‖ says BASF. SLIPS delivers solutions for creating exceptionally repellent and robust self cleaning surfaces on metals, plastics, optics, textiles and ceramics.

***** New method found to turn sawdust into petrol Scientists at Katholieke Universiteit Leuven (KU Leuven) in Belgium used a new chemical process to convert the cellulose in sawdust into hydrocarbon chains. These hydrocarbons can be used as an additive in gasoline or as a component in plastics, researchers said. Cellulose is the main substance in plant matter and is present in all non edible plant parts of wood, straw, grass, cotton and old paper.

"At the molecular level, cellulose contains strong carbon chains. We sought to conserve these chains, but drop the oxygen bonded to them, which is undesirable in high grade gasoline," said Professor Bert Sels.

Silica from rice husk The Goodyear Tire & Rubber Company (Akron,OH) has found silica derived from rice husk ash performs equally to traditional sources in reducing rolling resistance in tiers. The company is negotiating with potential suppliers to purchase the otherwise waste product.

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TECHNOLOGY DEVELOPMENT The new method to derive these hydrocarbon chains from cellulose was developed by researcher Beau Op de Beeck. "This is a new type of bio refining, and we currently have a patent pending for it. We have also built a chemical reactor in our lab: we feed sawdust collected from a sawmill into the reactor and add a catalyst a substance that sets off and speeds the chemical reaction," said Dr Bert Lagrain.

"The green hydrocarbon can also be used in the production of ethylene, propylene and benzene the building blocks for plastic, rubber, insulation foam, nylon, coatings and so forth," Sels added.The research was published in the journal Energy & Environmental Science.

***** Canadian research body, to test fibre tech at Aditya Birla group unit Canada‘s Centre for Research and Innovation in Bio Economy, an independent research organisation, has teamed up with an Ontario based biochemical producer, Greenfield Specialty Alcohols, to test a new fibre extraction technology at Aditya Birla Group‘s Terrace Bay, a pulp mill. Aditya Birla Group had acquired Terrace Bay Pulp, a North American paper grade pulp company, for $110 million in 2012. The Indian firm plans to convert it into a specialty pulp operation to be used to make rayon for textiles. Known as AV Terrace Bay, the acquisition had given the Indian company access to the surrounding woodlands to produce dissolving wood pulp, a critical ingredient for its viscose staple fibre (VSF) business. The Ontario pulp mill is now being used as a testing ground for a prototype technology designed to extract and separate sugar from wood and improve fibre recoveries. Centre for Research and Innovation in Bio-Economy, with $25 million in funding provided by the Government of Ontario, has decided to invest $1.3 million in the project, while Greenfield is to match the investment as part of the $2.7 million project. Work in India At Aditya Birla Science and Technology Company (ABSTC) in Taloja,in Maharashtra the Fibre Science Laboratory works in collaboration with the Group‘s fibre businesses to focus on development of new products and technologies for cellulosic fibres and value added acrylic fibres.

The Grasim Forestry Research Institute at Harihar houses the facility for manufacture of both VSF and rayon grade pulp.

"With the right temperature and pressure, it takes about half a day to convert the cellulose in the wood shavings into saturated hydrocarbon chains, or alkanes," Lagrain said. "Essentially, the method allows us to make a 'petrochemical' product using biomass - thus bridging the worlds of bio-economics and petro chemistry," he added.

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TECHNOLOGY DEVELOPMENT Moreover, even as the Birla Research Institute for Applied Sciences at Nagda in Madhya Pradesh is accelerating improvements in new fibre production technologies, the Textile Research and Application Development Centre at Kharach in Gujarat, has ushered in novel applications for fibres.

*****

Though the technology is still young, the inventors believe that this can provide a solution to air conditioning rooms, which now costs a lot of energy. Published in Nature, a paper by Aaswath Raman et al. describes the new material and its properties. At a thickness of about 1.8 microns, the material is thinner than an aluminium foil. It is made up of seven layers of hafnium oxide and silicon dioxide, each of differing thicknesses, on top of a thin layer of silver. It is designed to reflect both infrared light (which cannot be seen) and visible sunlight. What is special is that the material reflects light at the frequency which is not absorbed by atmospheric gases. This is known as the atmospheric window. When light with a frequency between 8 and 13 microns is beamed into the atmosphere, it goes unabsorbed and escapes into outer space. This is the frequency window at which the material reflects the infrared and visible light which strikes it. By this method, the material can cool the interior by almost 5 degrees Celsius. Though radiative cooling happens in the 8 to 13 micron window, atmospheric gases do absorb radiation at about 10 microns. Since absorption at 10 micron band can also warm up the atmosphere, of what advantage is this process? Certainly, most surfaces exposed to the sky radiate their heat out as thermal radiation — one could also call [it] ‗thermal light‘, since this is the heat all objects emit away as light at wavelengths that correspond to the object‘s temperature. The entire goal of the work is to harness this effect on the surface, specifically during the day, and not to cool the atmosphere itself in anyway.

***** Biodiesel technology The Danish enzymes maker Novozymes announced the launch of the first commercial enzyme technology to convert waste oil from fast food restaurants and factories into biodiesel for cars and lorries.Conventional biodiesel is created by using natural materials such as rapeseed and converting its oils into diesel fuel but such feedstocks are more expensive than waste."Biodiesel producers can thereby reduce their raw material costs," Novozymes said in a press release.

*****

New material for cooling surfaces Stanford University engineers have invented an ultra thin multilayered material which can reflect sunlight from, say, buildings and thereby lower the temperature of the building.

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CHINA NEWS Coal based energy project China Kingho Energy Group Co., Ltd., a privately owned energy groups engaged in the

production for coal based clean energies and refined coal chemicals, on September 25 signed a memorandum of understanding (MOU) with KazMunaiGas, Kazakh state run oil and gas company.

Under the MOU, both sides will jointly construct a ―coal based clean energy comprehensive utilization project‖ in Kazakhstan.

***** Indirect Coal to Liquids Project

Shaanxi Future Energy Chemical Corp. announced on September 30 that the construction of its one million metric tonne per annum indirect coal to liquids project in Yulin City of Shaanxi Province was approved by the National Development and Reform

Commission (NDRC).

The total investment in the project (including the matched coal mines) is over RMB22 billion. The project features higher diesel selectivity (30% higher than other domestic enterprises) and a lower catalyst consumption (30% lower than other domestic

enterprises). The project is expected to start commissioning by the end of 2014 and start production

in the first half of 2015. Shaanxi Future Energy Chemical Corp. is a 50:25:20 joint venture among Yankuang

Group, Yanzhou Coal Mining Co., Ltd. and Shaanxi Yanchang Petroleum Group. *****

Acrylic acid JV in China

Arkema has finalized the creation of Sunke, a joint venture with Jurong Chemical (Yancheng, China), the leading acrylic acid manufacturer in China.

Arkema will have a majority stake in the jv, which will comprise the assets of Jurong Chemical‘s acrylic acid production site at Taixing, China, which opened in 2012. Taixing

complex is China‘s biggest production site for acrylic acid and has an installed capacity of 320,000 metric tonne per year, consisting of two world scale production lines.

The first stage of the transaction has been finalized, and, as a result, Arkema now has access to 160,000 metric tonne per year of acrylic acid capacity in Asia—half of the Taixing site‘s installed production—for a price of $240 million.

A third; 160,000 metric tonne per year production line is expected to start up at the Taixing site in the first quarter of 2015. Arkema will then have an option to access

320,000 metric tonne per year of acrylic acid two thirds of the site‘s capacity for an additional $235 million.

Arkema manufactures acrylic acid in France and the United States.

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NEWS ROUND UP - INDIA

No licence needed for explosive used by mining sector

To help the mining, cement and construction sectors, the Government of India said that no licence under the Industries (Development & Regulation) Act, 1951 would be necessary for mine owners to manufacture ammonium nitrate fuel oil (ANFO)

explosives.

―This will help mine owners using ANFO to continue mining operations and will help the development of cement industry as well as the construction sector,‖ the Department of Industrial Policy and Promotion (DIPP) said in a statement.

ANFO manufacturers were required to take licence for possession and use of

blasting accessories — booster, safety fuse, detonating fuse and detonators under Explosive Rules, 2008 for which a firm has to obtain No Objection Certificate from district authorities and also from Director General of Mines Safety.

Monthly returns are filed by the licence holders under the Explosive Rules to district

authorities as well as Petroleum & Explosives Safety Organization. ANFO explosive is prepared by mixing ammonium nitrate with fuel oil in an

aluminium or wooden tray with hand mixing and immediately charging into the bore holes in the adjacent quarry or mines for blasting.

No packaging, storage, sale or transportation of ANFO is involved in the conventional manufacturing and using process.

The licencees prepare ANFO for their own use and on the spot captive consumption

for blasting purposes in metalliferous mines/quarries, the statement said. *****

Cold storage warehouses at LNG terminals

Petronet LNG, India‘s biggest liquefied natural gas (LNG) importer, is carrying out

feasibility studies on harnessing ‗cold energy‘ for commercial usage by setting up power generation units or specialised cold storage warehouses, at its LNG terminals. The concept, popular in Japan and China, is being experimented in India,

where the possibility to set up cold storages near LNG terminals has been explored.

In an LNG terminal, the imported gas is received at cryogenic conditions (minus 1600 celsius). It is stored in specially designed storage tanks and re gasified using

various sources of heat. During re gasification, there is a reasonable potential for recovery of ‗cold energy.‘ A few possible ways could be an air separation unit to generate liquid industrial gases such as liquid nitrogen, oxygen and argon,

cryogenic power, warehousing, production of dry ice and integration with adjacent power plants.

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NEWS ROUND UP - INDIA

In case of power generation, cold energy gives additional efficiency of 5-10%. It could be integrated with a power plant in the vicinity of the terminal, or with a

power station within the facility. But unless there is a long-term power purchase agreement (PPA), it may not be viable.

Finnish firm to build biorefinery in India

Chempolis has signed a partnership agreement with Numaligarh Refinery Ltd. to

jointly build a biorefinery using Chempoli's formicobio tech. *****

Cold storage facility in India – Status report

According to a report by the Institution of Mechanical Engineers (IME), a

professional organisation of the UK. investment in India‘s cold chain is projected to be $15 billion over the next five years

Based on 2012 statistics, it said that India needs to expand its cold storage infrastructure in an affordable, reliable and sustainable way to increase the

contribution of agriculture to the economy. The report said that approximately 60 per cent of the total number of facilities are

located only in Uttar Pradesh, Gujarat, West Bengal and Punjab. Only 4 million of the 104 million metric tonne of fresh produce is transported through a cold chain.

Cold storage for potatoes in West Bengal account for around 80 percent.

As West Bengal is one of the top producers in the country, private sector has contributed about 85 percent of the investment in cold storage infrastructure in the

State.

New cold storage facility for onion, carrot, beetroot and apple are now being proposed.The organization found that cold storages are used only for 10 to 11 percent of fruits and vegetables produced in India. The storage capacity needs to

increase 40 percent to avoid wastage, the report said.

In addition, cold energy could be used for specialised cold storages. These are not normal warehouses they require storage at cryogenic conditions and used to

store drugs/vaccines.

―In spite of such potential, only a small portion of cold energy is recovered during the regasification process. As LNG terminal integrated cold storage units exist in

Japan and China, the technical feasibility of such projects already exists globally.‖

*****

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AGRO CHEMICAL PAGE

GLOBAL PALM OIL SCENARIO

Global output

Despite initial apprehensions about the adverse effects of El Nino, which triggered a

rally earlier in 2014, world palm oil production in 2013 to 2014 is up 3.5 million metric tonne to a new high of 63.3 million tonnes. This was the result of new plantings between 2005 and 2011. Those young trees have now matured into a

robust high yielding phase.

These factors have seen crude palm oil prices drop some 15 per cent in recent months. In taking a call on palm oil price trends, the focus is invariably on the world‘s largest producers and exporters, Indonesia and Malaysia.

Smaller producers in Thailand (2.2 million metric tonne) and Columbia (one million

metric tonne). are becoming increasingly important to the global equation. The soyabean factor

Apart from output in 2014, other key drivers of palm oil prices are demand for

biodiesel, crude oil prices, weather events, currency dynamics and the outlook for other soft oils.

The price differential between crude palm oil and soft oils that used to be in the region of $150 a tonne is at just half that level currently. For palm oil to retain

market share, its discount to soft oils should continue to remain high. The outlook for soyabean oil, in this context, is turning positive. Dry conditions

faced by Brazil in October are causing some anxiety about soyabean plantings, particularly the yield. One can expect supply response to prices.

A rebound in global oilseeds and vegetable oil production for two

years in a row — 2013 and 2014 — has resulted in a market surplus. As a result, the global inventory of

four major oils — palm, soya, rapeseed and sunseed — stands

expanded. Palm oil has shown the highest level of inventory increase. Malaysian stocks have risen above

the psychological level of two million metric tonne.

Recent developments in the global vegetable oils market have provided a likely

direction for palm oil prices in the first quarter of 2015.

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AGRO CHEMICAL PAGE

If the apprehended supply response were to combine with some adverse weather event, it will lead to tightness in soyaoil prices, which will also affect palm oil. Crude

oil prices have considerably softened in recent weeks. If the current price levels of crude oil sustains, it would be negative for palm oil, as

diversion for biodiesel will slow.

At the same time, palm oil will enter the biological down cycle in 2015 which, in turn, means output growth may not be as healthy as in the previous two years. This will lead to a drawdown in inventory over time.

Overall, the palm oil market is likely to face several pulls and pressures in the

coming months. If weather in South America improves in the coming days, the price rally seen in October will peter out.

But other factors remaining unchanged, over the next four months, crude palm oil is likely to trade in a range of 2,150 to 2,350 Malaysian ringgit a metric tonne.

*****

India has in the past blocked efforts to patent naturally occurring turmeric and tulsi

(basil) etc, and has even set up a digital traditional library to document known uses of these products. And the reason for that is because a patent gives the patent holder a monopoly on the sale and manufacture of the product for a fixed period of

time.

The BCM-95 product works as a preventive, as it targets ß-amyloid, that is seen in large quantities in people with Alzheimer‘s and is seen as one of the reasons for the

disease. BCM95 - a mixture of curcumin, the yellow colouring substance of turmeric and an

essential oil from the spice is already available in India. But it is sold as a supplement and does not make therapeutic claims.

US patent on turmeric extract

Kerala-based Arjuna Natural Extracts

Ltd, has received a patent in the United States on BCM-95, a turmeric extract formulation that could be used

to target Alzheimer‘s disease.

The product is a re-blend of two ingredients in turmeric, but in a ratio that is not seen in naturally occurring

turmeric. It is a reblend of curcuminoid and an essential oil of

turmeric.

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AGRO CHEMICAL PAGE The product has been peer reviewed and is also being studied for various indications including arthritis, diabetes, depression, cancer prevention and treatment, adjutant with chemotherapy and cancer radiation, liver and gastro intestinal diseases etc.

The product has already undergone human clinical trials in patients with Alzheimer‘s

disease at Chinese University of Hong Kong and is found to be beneficial in arresting the progress of the disease. It is also undergoing two other human clinical trials in patients with Alzheimer‘s disease and subjects at risk of developing Alzheimer‘s disease

in Australia. The Department of Biotechnology in India had sanctioned around Rs.14 crore for a

clinical study of BCM95 in the treatment of mouth cancer. Arjuna Natural Extracts Ltd.,also applied for patent for the uses of amla extracts for

reducing cholesterol, pomegranate extracts for treating heart disease and extracts of Boswsellia Serrata (Indian Frankincense) for prevention of arthritis and inflammation.

*****

Castor price behaviour After a subdued period of trading well below Rs.4,000 a quintal due to inventory

overhang, castor seed prices have begun to look up in the last two months, thanks to the improved market outlook. But prices have largely remained bound in the range between Rs. 4,600 and Rs.4,700.

Clearly, seed availability is tightening as evidenced by castor seed production trends and castor oil export over the last two years. From 22 lakh tonnes (lt) in 2011 to 2012,

seed production declined to 19.6 lt the following year and then to 16.9 lt in 2013\ to 2014.

At the same time, castor oil exports have maintained a robust pace. From 4 lt in 2011 to 2012, shipments increased to 4.3 lt the following year and then to 4.7 lt in 2013 to 2014. In the first six months of the current fiscal, castor oil exports totalled

2.4 lt. The market fundamentals clearly point to tightness in availability, which is reflected in

somewhat higher prices beneficial to farmers. India is the world‘s dominant producer of castor seed and exporter of castor oil,

enjoying as much as 80 per cent market share. The world market has seen prices as high as $2,800 a metric tonne and as low as $1,200 in recent years.

But high prices are the exception rather than the norm. India holds a near monopoly position; and yet obtains export prices that hardly reflect this near monopoly. Questions are now being raised about the prices at which export deals are signed. Are Indian

exporters throwing away a valuable industrial oil at low prices that in turn denies seed growers remunerative prices?

*****

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Nandini Chemical Journal, December,2014 Page 64

PHARMA PAGE

CANNABIS CHEMICALS SLOW DOWN CANCER

Usually, the rate of survival for such patients five years after diagnosis, is just 10%. Specialists at St George's, University of London, studied the treatment of brain cancer tumours in the laboratory and discovered that the most effective treatment was to combine active chemical components of the cannabis plant, which are called cannabinoids. Cannabinoids are the active chemicals in cannabis and are also known more specifically as phytocannabinoids. There are 85 known cannabinoids in the cannabis plant. The new research is now the first to show a drastic effect when combining THC and CBD with irradiation. Tumours growing in the brains of mice were drastically slowed down when THC/CBD was used with irradiation. Dr Wai Liu, lead researcher on the project, said "The results are extremely exciting. The tumours were treated in a variety of ways, either with no treatment, the cannabinoids alone and irradiation alone or with both the cannabinoids and irradiation at the same time. Those treated with both irradiation and the cannabinoids saw the most beneficial results and a drastic reduction in size. In some cases, the tumours effectively disappeared in the animals. This augurs well for further research in humans in the future‖.

"The benefits of the cannabis plant elements were known before but the drastic reduction of brain cancers if used with irradiation is something new and may well prove promising for patients who are in gravely serious situations with such cancers in the future."

The research team are discussing the possibility of combining cannabinoids with

irradiation in a human clinical trial.

The cannabis plant is known for its medicinal properties and has been used to relieve symptoms associated with cancer, HIV/AIDS, multiple sclerosis, anorexia, anxiety, depression, and numerous other illnesses and conditions. Cannabis is a controlled substance in the UK and is most commonly known as a recreational drug.

Chemicals found in Cannabis extracts have been found to dramatically slow down the growth of notoriously difficult brain cancer tumours. Two active chemical components found in cannabis plants, tetrahydrocannabinol (THC) and cannabidiol (CBD) were tested as part of research into the treatment of brain cancer tumours by British scientists.

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PHARMA PAGE

Scientists find alternative to antibiotics

In a major breakthrough, scientists have developed the first effective alternative to antibiotics that may aid the fight against drug resistant infections.

The treatment marks "a new era in the fight against antibiotic resistant bacteria", according to Mark Offerhaus, chief executive of the biotechnology company Micreos,

which is behind the advance. The treatment attacks infections in an entirely different way from conventional

drugs and, unlike them, exclusively targets the Staphylococcus bacteria responsible for MRSA, and leaves other microbes unaffected. The approach is inspired by

naturally occurring viruses that attack bacteria using enzymes called endolysins. It uses a 'designer' endolysin, Staphefekt, which the scientists engineered to latch on to the surface of bacteria cells and tear them apart.

In a small patient trial, the drug was shown to be effective at eradicating the superbug Methicillin-resistant Staphylococcus aureus

(MRSA).

Researchers said it is unlikely that the infection could develop resistance against the

new treatment, which is already available as a cream for skin infections. They hope to develop a pill or an injectable version of the

drug within five years.

GERMANY BANS DRUG MADE AT RANBAXY’S DEWAS PLANT Drugmaker Ranbaxy Laboratories Ltd has been barred by from exporting the antibiotic cephalosporin to Germany from its plant in Dewas, Madhya Pradesh, for not complying with standard manufacturing practices. Germany‘s regulator issued a ―non-compliance‖ report for the plant where Ranbaxy made the antibiotic, after an inspection in June, the European Medicines Agency said on its website in a notice dated November 26. During the inspection, the regulator found deficiencies related to operation of drug manufacturing rooms and procedures related to sterilisation of equipment at the Dewas site, the notice said. The Dewas factory and Ranbaxy‘s other India-based plants are also barred from exporting to the United States after the US Food and Drug Administration inspections found those plants violated standard manufacturing practices

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Nandini Chemical Journal, December,2014 Page 66

ENERGY PAGE

PROSPECTS FOR NUCLEAR ENERGY

Almost 200 of the 434 reactors which were operational at the end of 2013 will retire

and the respective countries would have to spend a mammoth $100 billion to decommission the plants. A vast majority of them would be in the European Union, the United States, Russia and Japan, the report said.

Also, the cumulative total of spent nuclear fuel would also double to more than 7 lakh metric tonne over the projection period.

Unfortunately, even 60 years after the first reactor started functioning, no country

has opened a permanent disposal facility to isolate the most long lived and highly radioactive waste produced by commercial reactors. All countries that have ever produced radioactive waste should have an obligation to develop a solution for

permanent disposal of the waste and regulators and utilities should ensure adequate funds are set aside to cover these future expenses, the report said.

In spite of the challenges it currently faces, nuclear power has specific characteristics that underpin the commitment of many countries to maintain it as a future option. Nuclear plants can contribute to the

reliability of the power system. For countries that import energy, it can reduce their dependence on foreign supplies and limit their exposure to

fuel price movements in international markets. Nuclear power is one of the few options available at scale to reduce

carbon-dioxide emissions, while providing or displacing other forms of base load generation. It has avoided the release of an estimated 58 giga tonnes

of CO2 since 1971, or almost two years of total global emissions at current rates.

It is estimated that global nuclear power generation will increase by 60% from 392 GW in 2013 to more than 620 GW by 2040 to meet a 37%

increase in power demand, according to the latest `World Energy Outlook‘ released by Paris-based International Energy Agency (IEA).

Considering the relatively

limited experience of countries till date in dismantling and

decontaminating reactors and restoring sites for other uses,

the projected cost could be a conservative estimate.

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Nandini Chemical Journal, December,2014 Page 67

ENERGY PAGE

New capacity additions are expected in four countries. China would account for 45% while India, Korea and Russia collectively would make up a further 30%.The

increase in China 132 GW would exceed the current installed capacity of the US and Russia combined.

The number of countries operating nuclear reactors also will increase from 31 in 2013 to 36 in 2040. Uranium resources alone are more than sufficient to provide

fuel to satisfy these projections the report said. Still, the share of nuclear power in the global power mix would remain well below

the historic peak of 18% reached in 1996. As of now, nuclear energy accounts for only 11% of the total power generation in the world.

*****

Status of underground mining of coal in India

Once the mainstay of coal production in India; the contribution of under ground (UG) mines in total production has declined to a mere 7 per cent in the four

decades after coal nationalisation. The need to step up production, the administered pricing of fuel, coupled with the failure to bring in new underground

technologies, led Coal India Limited (CIL) to focus on the open cast mining. Between 1975 and 2014, CIL‘s UG production came down from 70 million metric

tonne to 36 million metric tonne. Including Singareni Collieries (SCCL) and a couple of captive producers, the total production is 40 million metric tonne (including

metallurgical coal used in the steel sector). The share of UG mines in India is far below the global average. UG mines contribute

20 per cent of production (over 400 million metric tonne) in Australia, nearly 40 per cent in the US (over 1,000 million metric tonne) and 86 per cent in China (over

3,500 million metric tonne). Considering Indian conditions, underground mines should contribute 25 per cent of coal production here.

The prospects for UG mines are good in Chhattisgarh, Jharkhand and Madhya Pradesh, where the reserves are mostly under forest cover. These resources can be

extracted without disturbing the flora and fauna too much. For a country that has 10 times higher population density than the US and

2.5 times of China, India have already stretched itself a bit too far, for 500 million metric tonne open cast production.

Revenue earning opportunity should encourage CIL to take UG mining more seriously.

Free market pricing of UG coal will help the country tap huge reserves of 800

million metric tonne of high calorific value (6000-7000 GCV) coal in Assam and Meghalaya.

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Nandini Chemical Journal, December,2014 Page 68

ENERGY PAGE

INSTALLED ROOFTOP SOLAR CAPACITY POTENTIAL IN INDIA

The story is different when it comes to industries. Factories have large, flat roofs which are free for use, and there is practically no issue of shadows falling on them.

Factory owning companies are also amenable to long term contracts. In states like Tamil Nadu, (which, incidentally, tops the list of rooftop installations

in the country, with 50 MW), industries are in pressing need for energy security too.

Chennai based Super Auto Forge, a Rs. 400 crore auto components manufacturer, put up a 600 kW rooftop system a year ago.

*****

Solar rooftop units should be

positioned such that no shadow falls on the panels, not just while being

erected, but also in the future. Commercial and residential establishments generally do not have

the space or prefer not to freeze the space available for solar plants.

SunEdison and Azure Power won a mandate in Gujarat to put up 2.5 MW

each of solar power plants on rooftops in the city of Gandhinagar.

The companies had to lease residential rooftops, put up solar plants and sell the power to the state

utility. SunEdison found that people were not willing to give up their

space for long number of years, though they were willing to consider signing for fewer years, say, five

years.

India‘s rooftop solar market potential is at a staggering 100,000 MW, but

puts installed capacity at just 285 MW, a minuscule number compared to the potential.

The India focused report comes from the German-headquartered solar consultancy, Bridge-to-India. The consultancy‘s Founder and Director,

Tobias Engelmeier, estimates that India will have 1,500 MW of rooftop solar power by 2018, though many experts doubt this.

Page 69: Volume 22 Issue 3 December 2014 newnsa ndern fFneAC.

Nandini Chemical Journal, December,2014 Page 69

ENERGY PAGE

PROPOSED SOLAR PARK IN INDIA

The Union ministry of new and renewable energy (MNRE) has identified locations for 12 of the 25 solar parks ,which the government plans to set up to increase solar power generation in the country

A solar park is a concentrated zone where in the government will provide land and

basic infrastructure for setting up the plant as well as evacuation of power.

Andhra Pradesh has proposed to have a 2,500 mw park, Telangana 1,000 mw, Madhya Pradesh is keen to have two parks of 750 mw each, Karnataka a 750-mw

park, Rajasthan has identified land to set up projects as big as 4,000 to 5,000 mw and Odisha and Punjab to have around 3,000 mw each.

India already has two solar parks, with one each in Gujarat and Rajasthan as models for the parks to be constructed as part of the scheme. The new parks

would be based on a similar model. The solar parks will be developed in collaboration with state governments. Solar

Energy Corporation of India will be the implementation agency on behalf of the Centre.

Developers, on the otherhand, will have to enter into power purchase agreements

with distribution companies before setting up the plant. At present, the country generates 3,000 mw through solar power plants.

As part of its plan to increase solar power generation in the

country to 100,000 mw by 2022, the government aims to

set up 25 solar parks with a total capacity of around

20,000 mw in the next five years.

Each park will house a plant with a capacity ranging from

500 mw to 1,000 mw. The locations are in Adhra

Pradesh, Telangana, Madhya Pradesh,Karnataka, Rajasthan,

Odisha and Punjab.

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Nandini Chemical Journal, December,2014 Page 70

ENVIRONMENTAL PAGE

PROPOSED AMENDMENT TO MONTREAL PROTOCOL ON HFC

Marking a significant change in position, India maintained silence on the issue of amending the Montreal Protocol to bring greenhouse gas hydrofluorocarbons (HFCs) under it, at the 10th Joint Meeting of the Parties to the Vienna Convention and the 26th

Meeting of the Parties to the Montreal Protocol. Even as West Asian oil producing countries, led by Saudi Arabia and Kuwait, expressed

reservations against the proposed amendment and asked for the deletion of this agenda, India did not join the opposing voices.

Last year, India had led these nations in protesting such an amendment to UNs Montreal Protocol, which is an international agreement on phasing out of ozone depleting substances.

India and USA have entered into an agreement for cleaner energy under which the US would give India $1 billion to finance renewable energy and research. This deal,

however, came bundled with a promise of dialogue on HFCs at the Montreal Protocol talks.

This change in stance could have a huge effect on India's refrigeration and coolant industry, which includes airconditioners, and is estimated at over Rs. 15,000 crore. If HFCs were brought under the Montreal Protocol, compulsory transitions from the

current use of HFCs to the new, proprietary gases are likely to create a monopoly for the patent holders.

As the debate is still on, a breakthrough on the issue of HFCs is highly unlikely as oil producing gulf countries participating in a key UN conference here continued their

strong opposition to the U.S. led nations‘ proposal to amend the Montreal Protocol to phase down the harmful greenhouse gas.They said that the issue should be discussed under the United Nations Framework Convention on Climate Change (UNFCCC).

Montreal Protocol is a UN treaty signed in 1987 to ban ozone-depleting substances like chlorofluorocarbons (CFCs) and hydrochloroflurocarbons (HFCFs) which were used in refrigerators and air conditioners.

HFCs were brought into replace the ozone-depleting substances but it was proved later that the ozone friendly gas has a potent warming effect.

During the past six conferences, it was India which had led the Gulf States to block the use of the Montreal Protocol to phase out HFCs.

The change in Indian stand comes in the wake of a joint Indo-US statement on HFCs this year under which both the nations had agreed to discuss the harmful

greenhouse gas under the Montreal Protocol. The Gulf countries argued that there were no alternatives to HFCs.

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ENVIRONMENTAL PAGE

Sensing that evolving a consensus on setting up of a contact group is not easy, the U.S. proposed to setting up of an informal group to discuss the mandate of the contact group and not to discuss the amendment proposal.

China said that the Montreal Protocol has a role to play and everyone should work on consensus.

***** Norms for online effluents monitoring

The Central Pollution Control Board (CPCB) has issued guidelines for installation and operation of real time effluent quality monitoring system by fertiliser plants and 16 other categories of industries considered as ―highly polluting.‖

Apart from these specified industries, the grossly polluting industries discharging directly/indirectly into river Ganga or its tributraies, Common Effluent Treatment Plants

(CETPs) and Sewage Treatment Plants (STPs), Common Biomedical Waste and Common Hazardous Waste Incinerators have to install real time effluent quality monitoring systems. According to the guidelines dated 7th November 2014, the

installation of the system has to be completed by 31st March 2015.

―Online analysers are a better tool to extend in time information on compliance of ETP and CETP to the prescribed norms to regulator. The real time measurement for important parameters will give detailed information continuously, which laboratory

instruments fail to give as random once in a month or quarter information is too less to understand discharge compliance,‖ the notice said.

*****

e-waste recycling efforts in India Karnataka government tied up with the Centre for Materials for Electronics Technology

(C-MET) and e-waste recycler e-Parisaraa to set up a 100-metric tonne per annum integrated processing plant for recovering precious metals from electronic goods like printed circuit boards.

According to a study by the electronic hardware industry apex body Manufacturers Association of Information Technology (MAIT), around 500,000 metric tonne of e-waste

is generated across India every year, thanks to growing consumption and disposal of electronic products and consumer durables.

Though an additional 100,000 metric tonne of e-waste enters the country through illegal imports annually, only 40 percent of it gets recycled due to inadequate and poor infrastructure which is mostly in the informal sector.

The Hyderabad based C-MET is an autonomous scientific society, formed by the central government under the Department of Electronics and IT (DeitY), to assist states in

setting up e-waste processing units in the country. *****

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Nandini Chemical Journal, December,2014 Page 72

ENVIRONMENTAL PAGE

TARGET TO CUT CO2 EMISSIONS

The UNEP report published is based on the idea that the planet has a finite ‗carbon budget‘. Since emissions surged in the late 19th century, some 1,900 Gigatonnes (Gt) of CO2 and 1,000 Gt of other greenhouse gases have already been emitted, leaving less than 1,000 Gt of CO2 left to emit before locking the planet in to dangerous temperature rises of more than 2 degree C above pre industrial levels. All scenarios in the UNEP report now require some degree of ‗negative CO2 emissions‘ in the second half of the century, through technologies such as carbon capture and storage or, possibly, controversial, planetary wide engineering of the climate known as geo engineering. UNEP is ―extremely interested‖ in the subject and is planning a report in the months ahead.Consideration should also be given to compensatory schemes for investors in fossil fuels companies to address the ‗stranded assets‘ issue. The EU has not, however, supported UNEP‘s call for zero greenhouse gas emissions by 2100 .

*****

The world must cut CO2 emissions to zero by 2070 at the latest to keep global warming below dangerous levels and prevent a global catastrophe, the U.N. warns. By 2100, all greenhouse gas emissions — including methane, nitrous oxide and ozone, as well as CO2 — must fall to zero, the United Nationals Environment Programme (UNEP) report says or the world will face what Inter governmental Panel on Climate Change (IPCC) scientists have described as ―severe, widespread and irreversible‖ effects from climate change.

TECHNOLOGY TO REDUCE EFFLUENTS IN LEATHER INDUSTRY Scientists at Central Leather Research Institute (CLRI )have developed a technology in leather processing that may put an end to the pollution caused by effluents discharged from tanneries. The dry tanning technology uses a biodegradable compound instead of water. Along with the compound, which was developed in the CLRI lab, a tanning agent (chromium sulphate) is used. The process leaves no effluents as both the compound and the tanning agent are absorbed by the leather. Scientists claim the new technology saves about 40 per cent of the processing time, and the amount of tanning agent required is half of what is used in the conventional process. At present, tanneries in the country use about 15 million litres of water everyday (five to eight litres for a kilo of skin) during the tanning process. Besides, up to 100g of chromium sulphate per kg of skin is used along with water. This apart, a large amount of salt and acid are used in pickling, a conditioning process prior to tanning. The salt, water, unutilized acid and tanning agent are later discharged as effluents. For every kg of leather, roughly 40 litres of effluent is produced. The tannery effluent, with its high level of salinity, has been a major pollutant of groundwater. The new technology not only does away with the use of water, but also with the pickling process.About 2,300 tonnes of skin are processed in tanneries in the country every day and about 230 tonnes of salt is used during the conditioning process

Page 73: Volume 22 Issue 3 December 2014 newnsa ndern fFneAC.

Nandini Chemical Journal, December,2014 Page 73

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Page 74: Volume 22 Issue 3 December 2014 newnsa ndern fFneAC.

Nandini Chemical Journal, December,2014 Page 74

TENDER

S. NO

NAME OF THE COMPANY

PRODUCT NAME

QUANTITY IN

MT / KL

TENDER NO.

& DATE

1. Tamil Nadu Newsprint And

Papers Ltd Kagithapuram-639 136 Karur District,Tamil Nadu

Hydrogen peroxide 50% Non ferric alum (Al2O3 16.5%)

2720 tonne

250 tonne

1415 13005321

1415 13005325

2 The Fertilisers and Chemicals Travancore Ltd Petrochemical Division Administrative Building Udyogamandal, Kochi Kerala Pin:683 501

Anhydrous ammonia

15000 tonne±5%

MAT-RM-A-68 Dt.6.28.11.2014

3

Karnataka Co operative Milk Producers‘ Federation Ltd KMF Complex,Dr.M.H.Marigowda Road,Bangalore-560 029

DORB Rice polish Rape seed DOC Coconut DOC Cotton seed DOC Soya DOC Ground nut DOC Cotton seed cake Ground nut cake Wheat bran Wheat bran flakes Iodised salt Common salt Calcite powder

2800 tonne 4250 tonne 6050 tonne 3350 tonne 4900 tonne 250 tonne 3750 tonne 3750 tonne 3750 tonne 3750 tonne 3750 tonne 170 tonne 550 tonne 780 tonne

KMF/CFRM-233/2014-15/IND1825 Dt.24.11.2014

4

The Mysore Paper Mills Ltd Materials Division, Paper Town, Bhadravati-577 302 Karnataka

Precipitated calcium carbonate Direct green dye Wet ground calcium carbonate Pigment dyes (Violet and blue) Optical brighteniner agent AKD sizing chemical Caustic soda lye

3000 tonne

300 kgs

50 tonne

60000 tonne

70 tonne

30000 tonne

4395 tonne

1381-14/FMT/PCP (IND 385)

1375-14/FMT/PDO (IND 384)

1412-14/FMT/PCP (IND 386)

1442-14/FMT/PCZ (IND 391)

1448-14/FMT/PCZ (IND 392)

1449-14/FMT/PCZ (IND 393)

1445-14/FMT/PCY (IND 394)

5 Southern Railway Podanur-641 023

Polycarbonate black Slug copper

61140459 61140461

6 Steel Authorityof India Ltd Bokaro Steel Plant Bokaro Steel City-827001 Jharkhand

Caustic soda lye pure grade IS 252 Resin based grouting material for blast furnace

Corrigendum to BSL/PUR/OTE/P08/P145

Corrigendum to

BSL/PUR/GT/14/0382

7 Karnataka Soaps & Detergents Ltd Sandal City, P B No,5531, Bangalore-Pune High way,Bangalore-560055

Palm fatty acid distillate Palm kernel fatty acid distillate Acid slurry-96% (LABSA)

2000 tonne

750 tonne

125 tonne

8 Indian Oil IBP Division, (BG Explosives)

Low density ammonium nitrate (LDAN)

270 tonne ± 10%

BGE/LDAN/DOC/5/2015/01

9 Tamilnadu Newsprint And Papers Ltd Kagithapuram-639 136 Karur Dist

Gypsum 2000 tonne 1415 33000431

10 Ministry of Defence Research & Development Organisation Solidstate Physics Laboratory Lucknow Road, Timarpur, Delhi-110 054

Liquid nitrogen (Purity 99.999%)

500000 Cubic mtr

SSPL/15ATT059/14-15

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Nandini Chemical Journal, December,2014 Page 75

PRICE DETAILS

KOGAS in South Korea has been diverting some of its long term contractual obligations. Similarly, utility buyers in Japan are well balanced now. The demand from Taiwan and China, too, has been relatively slow. This has disturbed the supplydemand balance. Recent spot LNG contracts were struck at prices as low as $10.5 per mmbtu, nearly 45% down from year ago period and 25% down from those struck in October 2014. These contracts are for delivery after two months; hence, contracts in November related to deliveries in January 2015. There are indications the trend will continue well in future.

*****

LNG price in Asia The Spot LNG prices have crashed in Asia late and is expected to fall further notwithstanding the onset of winter, which traditionally drives prices higher. The drop in LNG prices is not just an outcome of drop in oil prices, but also a strategic shift in the demand-supply balance and augurs well for Indian consumers.

NANDINI CONSULTANCY (S) PTE.LTD.,SINGAPORE Nandini Consultancy (S) Pte. Ltd., Singapore provides services to chemical and allied industries all over the world in market research, export trade promotion,technology appraisal, identification of project opportunities for investment and data base services. Nandini Consultancy,Singapore is the overseas arm of Nandini Consultancy Centre,India, a renowned firm of chemical engineers and project consultants based at Chennai, serving the chemical industry for over 20 years.

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Page 76: Volume 22 Issue 3 December 2014 newnsa ndern fFneAC.

Nandini Chemical Journal, December,2014 Page 76

EX FACTORY PRICES IN CHINA DURING THE MONTH OF OCTOBER 2014

Product

Producer Price (RMB per

tonne) 2-Ethylhexyl acrylate Shanghai Huayi Group 13300

2-Ethylhexyl acrylate Jiangsu Juron 13200

2-Ethylhexyl acrylate Formosa Ningbo 13000

ABS PetroChina Jilin Petrochem 13750

ABS Taita Chemical (Ningbo) 13400

ABS Zhenjiang Chimei 15100

ABS Shinho (Changzhou) 14600

Acetone (Industrial grade A) Sinopec Shanghai Petrochem 8300

Acetone (Industrial grade A) Sinopec Beijing Yanhua 8350

Acrylic acid (Industrial grade A) Bluestar Shenyang Paraffin 10600

Acrylic acid (Industrial grade A) Shanghai Huayi Group 9600

Acrylonitrile (Industrial grade A) Sinopec Anqing Petrochem 14800

Acrylonitrile (Industrial grade A) PetroChina Jilin Petrochem 14750

Acrylonitrile (Industrial grade A) Sinopec Shanghai Petrochem 14800

Acrylonitrile (Industrial grade A) PetroChina Fushun Petrochem 14700

Aniline (Industrial grade A) Nanjing Chemical Industry 10700

Aniline (Industrial grade A) SP Chemicals Taixing Co 10100

Aniline (Industrial grade A) Jilin Connell Chem 9900

Aromatics, heavy Sinopec Zhenhai Refining 6500

Aromatics, heavy CNOOC Huizhou Refinery 7950

Aromatics, heavy Sinopec Maoming Petrochem 5500

Aromatics, heavy PetroChina Liaoyang Petrochem 8200

Butadiene (Industrial grade A) Sinopec Yangzi Petrochem 10300

Butadiene (Industrial grade A) Sinopec Guangzhou Petrochem 10800

Butadiene (Industrial grade A) PetroChina Liaoyang Petrochem 11050

Butadiene (Industrial grade A) Sinopec Shanghai Petrochem 10300

Butyl acetate (Industrial grade A) Shandong Jinyimeng Biochem 8600

Butyl acetate (Industrial grade A) Shanghai Orient Salt 8700

Butyl acetate (Industrial grade A) Guangdong Jiangmen Qianxin 9000

Butyl acetate (Industrial grade A) Guangzhou Solvent Plant 9000

Butyl acrylate (Industrial grade A) PetroChina Jilin Petrochem 13000

Butyl acrylate (Industrial grade A) Bluestar Shenyang Paraffin 10600

Butyl acrylate (Industrial grade A) Shanghai Huayi Group 10600

C5 Sinopec Yangzi Petrochem 5900

C5 PetroChina Fushun Petrochem 6250

C5 Sinopec Qilu Petrochem 6200

C5 Sinopec Maoming Petrochem 6300

C5 Sinopec Beijing Yanhua 6200

C5 Panjin Ethylene Industry 5200

C5 Sinopec Tianjin Petrochem 6200

C9 Sinopec Qilu Petrochem 4850

C9 Sinopec Tianjin Petrochem 4750

C9 Sinopec Yangzi Petrochem 4600

C9 Sinopec Beijing Yanhua 4850

C9 Sinopec Zhongyuan Ethylene 4600

C9 Sinopec Maoming Petrochem 4600

C9 CNGC Liaoning Huajin 4800

C9 BASF-YPC CO.Ltd 4600

Caprolactam (99%) Sinopec Baling Petrochem 16800

Caprolactam (99%) Sinopec Nanjing Dongfang 18260

Caustic soda, 32% diaphragm Jinxi Chemical 750

Caustic soda, 32% diaphragm Huanghua Chlor-Alkali Co 500

Caustic soda, 32% diaphragm Shandong Binzhou Chemical 510

Caustic soda, 32% diaphragm Shandong Haihua Group 500

Caustic soda, 32% diaphragm Tianjin Dagu Chemical 2100

Chlorine, liquid (99.6%) Guangzhou Hoton Chemical 700

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Nandini Chemical Journal, December,2014 Page 77

EX FACTORY PRICES IN CHINA DURING THE MONTH OF OCTOBER 2014

Product

Producer

Price (RMB per

tonne) Chlorine, liquid (99.6%) Inner Mongolia Wuhai 500

Chlorine, liquid (99.6%) Shandong Haihua Group 1000

Chlorine, liquid (99.6%) Tianjin Chemical 800

Chlorine, liquid (99.6%) Kaifeng Dongda 800

Chlorine, liquid (99.6%) Ningxia Yinglite 650

Chlorine, liquid (99.6%) Shanxi Yushe (96%, diaphragm) 600

Compound fertilizer (45%, Chlorine based) Shandong Shikefeng 1900

Compound fertilizer (45%, Chlorine based) Hubei Yangfeng 2250

Compound fertilizer (45%, Chlorine based) Hongri Acron 2050

Compound fertilizer (45%, Chlorine based) Jiangsu Zhongdong 1900

Compound fertilizer (45%, sulphur based) Hongri Acron 2350

Compound fertilizer (45%, sulphur based) Hubei Yangfeng 2250

Compound fertilizer (45%, sulphur based) Shenzhen Batian 3150

Compound fertilizer (45%, sulphur based) Zhejiang Juhua Group 11600

DAP (diammonium phosphate, 64%) Guizhou Kailin (67%) 2650

DAP (diammonium phosphate, 64%) Yunnan Red Phosphorus 2650

DAP (diammonium phosphate, 64%) Yunnan Yunfeng 2650

DAP (diammonium phosphate, 64%) Guanxi Luzhai Fertiliser 2650

DAP (diammonium phosphate, 64%) Guizhou Wengfu Group 2650

Di-ethylene glycol (Industrial grade) Sinopec Maoming Petrochem 9300

Di-ethylene glycol (Industrial grade) Tianjin United Petrochemical 9250

Di-ethylene glycol (Industrial grade) Sinopec Beijing Yanhua 9150

DMF (di methyl formamide) Zhangqin Riyue Chemical 4800

DMF (di methyl formamide) Hualu Hengsheng Group 4800

DMF (di methyl formamide) Zhejiang Jiangshan Chemical Co 5100

DMF (di methyl formamide) Anyang Jiutian Fine Chem 4800

DOP (Dioctyl phthalate) (Industrial grade) Qilu Plasticizers Co 10500

DOP (Dioctyl phthalate) (Industrial grade) Shijiazhuang Bailong 10600

DOP (Dioctyl phthalate) (Industrial grade) Shandong Bohuai Chemical 14000

DOP (Dioctyl phthalate) (Industrial grade) UPC Group Zhenjiang 10700

DOP (Dioctyl phthalate) (Industrial grade) Dongguan Shenghe Chem 10900

Epichlorohydrin (Industrial grade A) Shandong Bohui Chemical 14000

Epichlorohydrin (Industrial grade A) Jiangsu Yangnong Chemical Group 13000

EPS (expandable polystyrene, flame retardant grade) Jiangyin Hupao Textile 12800

EPS (expandable polystyrene, flame retardant grade) Taita Chemical (Zhongshan) 13000

EPS (expandable polystyrene, flame retardant grade) Wuxi Xingda Group 12700

EPS (expandable polystyrene, flame retardant grade) Suzhou Changle 17000

EPS (expandable polystyrene, flame retardant grade) Jiangsu Litian 12600

Ethyl acetate (Industrial grade A) Jiangsu Sopo 6850

Ethyl acetate (Industrial grade A) Yankuang Cathay Coal Chem 6500

Ethyl acetate (Industrial grade A) Guangdong Jiangmen Qianxin 7100

Ethyl acetate (Industrial grade A) Guangzhou Solvent Plant 6900

Ethylene oxide (Industrial grade A) Sinopec Beijing Eastern Petrochemical 11000

Ethylene oxide (Industrial grade A) Sinopec Yangzi Petrochem 10800

Ethylene oxide (Industrial grade A) Sinopec Maoming Petrochem 10900

Ethylene oxide (Industrial grade A) Sinopec Beijing Yanhua 11000

Ethylene oxide (Industrial grade A) Sinopec Tianjin Petrochem 10950

Ethylene oxide (Industrial grade A) PetroChina Jilin Petrochem 10900

Ethyl vinyl acetate (EVA) BASF-YPC CO.Ltd 13800

Glacial acetic acid (98%) Shanghai Wujing Chemical 3600

Glacial acetic acid (98%) Yankuang Cathay Coal 3400

HDPE, Drawing PetroChina 12100

HDPE, Drawing Sinopec 12100

HDPE, film PetroChina 12000

HDPE, film PetroChina 11950

HDPE, film Sinopec 12200

Hydrochloric acid (31%) Shandong Haihua Group 220

Hydrochloric acid (31%) Tianjin Chemical 160

Hydrochloric acid (31%) Kaifeng Dongda 200

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Nandini Chemical Journal, December,2014 Page 78

EX FACTORY PRICES IN CHINA DURING THE MONTH OF OCTOBER 2014

Product

Producer

Price (RMB per

tonne) Hydrochloric acid (31%) Shanxi Yushe (96%, diaphragm) 240

Iso butene Binzhou Yuhua Group 13500

Iso butyl alcohol (Industrial grade) Sinopec Qilu Petrochem 8100

Iso propyl alcohol PetroChina Jinzhou Petrochem 9600

Iso propyl alcohol Dongying Hi tech Spring Chemical 9900

LDPE, Film PetroChina 12400

LDPE, Film Sinopec 12500

LLDPE, Film PetroChina 11850

LLDPE, Film Sinopec 11900

LPG (liquefied petroleum gas) Guangzhou Wechem 7600

LPG (liquefied petroleum gas) Shandong Dongming Wusheng 6030

LPG (liquefied petroleum gas) Sinopec Beijing Yanhua 6250

LPG (liquefied petroleum gas) Sinopec Yangzi Petrochem 5910

LPG (liquefied petroleum gas) North China Oilfields 6120

LPG (liquefied petroleum gas) Sinopec Maoming Petrochem 5910

LPG (liquefied petroleum gas) Fujian Refining & Petrochem 5930

Lube oil, base Sinopec Maoming Petrochem 8420

Lube oil, base PetroChina Dalian Petrochem 8750

Lube oil, base Sinopec Shanghai Gaoqiao 9100

MAP (mono ammonia phosphate, 56% powder) Hubei Yihua Chemical 2100

MAP (mono ammonia phosphate, 56% powder) Guizhou Kailin (67%) 2100

MAP (mono ammonia phosphate, 56% powder) Chongqing Win Win Group 2050

MDI, Pure Yantai Wanhua Polyurethane Co 23400

Methyl acrylate Bluestar Shenyang Paraffin 12000

Methyl acrylate Kaitai Industry Co 12100

Methyl ethyl ketone (industrial grade) Zhongjie Petrochemical 10650

Methyl ethyl ketone (industrial grade) PetroChina Lanzhou Petrochem 10300

Methyl ethyl ketone (industrial grade) PetroChina Fushun Petrochem 10300

Mono ethylene glycol (Terylon grade) Sinopec Beijing Eastern Petrochemical 7100

Mono ethylene glycol (Terylon grade) PetroChina Jilin Petrochem 6520

Mono ethylene glycol (Terylon grade) Sinopec Beijing Eastern Petrochemical 7000

Mono ethylene glycol (Terylon grade) Sinopec Maoming Petrochem 7100

Mono ethylene glycol (Terylon grade) PetroChina Jilin Petrochem 6520

Mono ethylene glycol (Terylon grade) Sinopec Beijing Yanhua 7000

n-Butyl alcohol (grade A) PetroChina Daqing Petrochem 8300

n-Butyl alcohol (grade A) Sinopec Qilu Petrochem 8500

Octyl alcohol (industrial grade A) PetroChina Daqing Petrochem 9350

Octyl alcohol (industrial grade A) Sinopec Qilu Petrochem 9400

o-xylene (petroleum) Sinopec Zhenhai Refining 8450

o-xylene (petroleum) Sinopec Yangzi Petrochem 8450

o-xylene (petroleum) PetroChina Jilin Petrochem 8150

o-xylene (petroleum) PetroChina Liaoyang Petrochem 8200

o-xylene (petroleum) Sinopec Qilu Petrochem 8350

Paraffin (56#) Sinopec Shanghai Gaoqiao 8830

Paraffin (56#) Sinopec Maoming Petrochem 8880

Paraffin (56#) Nanyang Paraffin Company 8450

Paraffin (56#) PetroChina Fushun Petrochem 8090

Paraffin (56#) Sinopec Beijing Yanhua 8300

PET Chip (semi de lustering) Jiangsu Sanfangxiang Group 9600

PET Chip (semi de lustering) Sinopec Yizheng Chemical 11000

PET Chip (bottle grade) Oriental Petrochemical (Shanghai) 9800

PET Chip (bottle grade) Xiamen Taron Petrochemical 9700

PET Chip (bottle grade) Sinopec Yizheng Chemical 9750

PET Chip (bottle grade) Zhuhai Yuhua 9500

Petroleum coke (2#B) Shandong Lijin Petrochem 1170

Petroleum coke (2#B) Sinopec Wuhan Petrochem 1170

Phenol (industrial grade A) Sinopec Shanghai Petrochem 11900

Phenol (industrial grade A) Sinopec Beijing Yanhua 11700

Phenol (industrial grade A) PetroChina Jilin Petrochem 11140

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Nandini Chemical Journal, December,2014 Page 79

EX FACTORY PRICES IN CHINA DURING THE MONTH OF OCTOBER 2014

Product

Producer

Price (RMB per

tonne) Phenol (industrial grade A) Bluestar Harbin Petrochem 12300

Phosphorus ore Guizhou Xinxin Group 580

Phosphorus ore Mabian Shunan Phosphorous 340

Phosphorus ore Yunnan Phosphorus Chemical 450

Phosphorus ore Hebei Fanshan Mine (34%) 800

Phosphorus, yellow Phosphate Ind of Wengfu Group 14650

Phosphorus, yellow Guizhou Kailin 14600

Phosphorus, yellow Qianneng Tianhe Phosphorus 14500

Phosphorus, yellow Sichuan Chuantou (CTEC) 14350

Phosphorus, yellow Mabian Shunan Phosphorous 14200

Phthalic anhydride (industrial grade) Shandong Hongxin Chemical 8400

Phthalic anhydride (industrial grade) Shijiazhuang Bailong 8450

Polyester staple Sinopec Yizheng Chemical 10000

Polyester staple Sinopec Luoyang Petrochem 10100

Polyester staple Sinopec Tianjin Petrochem 10000

Polyether flexible foam Tianjin Dagu Chemical 15000

Polyether flexible foam Fujian Meizhouwan Chlor Alkali 14700

Polyether flexible foam Sinopec Shanghai Gaoqiao 14600

Polypropylene, drawing PetroChina 11500

Polypropylene, drawing Sinpec 11300

Polypropylene, injection PetroChina 11850

Polypropylene, injection Sinopec 11300

Polypropylene, copolymer PetroChina 11350

Polypropylene, copolymer Sinopec 11250

Polystyrene, (GPPS) Sinopec Guangzhou Petrochem 11650

Polystyrene, (GPPS) Shanghai Secco Petrochem 12000

Polystyrene, (GPPS) Zhanjiang Xinzhongmei 12000

Polystyrene, (HIPS) Zhenjiang Chimei 12300

Polystyrene, (HIPS) Shanghai Secco Petrochem 12500

Polystyrene, (HIPS) Zhanjiang Xinzhongmei 12500

Polystyrene, (HIPS) BASF-YPC CO.Ltd 13000

Polystyrene, (HIPS) Zhenjiang Chimei 13200

Polyvinyl alcohol (1799) Shanxi Samwei Group 14600

Polyvinyl alcohol (1799) Anhui Wanwei Group 14300

Polyvinyl alcohol (1799) Sinopec Sichuan Vinylon 12100

Propylene (industrial grade A) PetroChina Jinzhou Petrochem 10000

Propylene (industrial grade A) Sinopec Tianjin Petrochem 10150

Propylene (industrial grade A) Xianyang Auxiliary Factory 9950

Propylene (industrial grade A) Zhongyuan Oilfield 10350

Propylene (industrial grade A) Shandong Huifeng Petroleum & Chem 10400

Propylene oxide (industrial grade A) Shandong Binzhou Chemical 14800

Propylene oxide (industrial grade A) Tianjin Dagu Chemical 14700

Propylene oxide (industrial grade A) Jinhua Chemical Group 14800

PTA (Pure terephthalic acid, industrial grade A) Hualian Sunshine 7400

PTA (Pure terephthalic acid, industrial grade A) Xiamen Xianglu Chemical Fiber Co 7400

PTA (Pure terephthalic acid, industrial grade A) Sinopec Yangzi Petrochem 7300

Pure benzene (petroleum) Sinopec Qilu Petrochem 8500

Pure benzene (petroleum) Sinopec Yangzi Petrochem 8500

Pure benzene (petroleum) Sinopec Maoming Petrochem 8500

Pure benzene (petroleum) Sinopec Shanghai Petrochem 8500

Pure benzene (petroleum) Sinopec Tianjin Petrochem 8500

Pure benzene (petroleum) PetroChina Urumqui Petrochem 8600

PVC (calcium carbide based) Yibin Tianyuan Group 6200

PVC (calcium carbide based) Hunan Zhuhou Chemical 6250

PVC (ethylene based) Shanghai Chlor Alkali 7400

PVC (ethylene based) Tianjin Dagu Chemical 6650

PVC (ethylene based) Tianjin LG (ethylene based) 6950

p-xylene (petroleum) Sinopec Yangzi Petrochem 6950

p-xylene (petroleum) Sinopec Zhenhai Refining 9400

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Nandini Chemical Journal, December,2014 Page 80

EX FACTORY PRICES IN CHINA DURING THE MONTH OF OCTOBER 2014

Product

Producer

Price (RMB per

tonne) Salt, crude (industrial grade A) Shandong Weifang Salt Works 230

Salt, crude (industrial grade A) Nanpu Salt works 330

Salt, crude (industrial grade A) Hunan Salt Work 330

Salt, crude (industrial grade A) Dalian Jinzhou Salt Works 350

Salt, crude (industrial grade A) Qinghai Salt Works 200

SBS (dry) Sinopec Baling Petrochem 13500

SBS (dry) Sinopec Beijing Yanhua 12900

Soda ash, dense Shandong Haihua Group 1500

Soda ash, dense Guangdong Nanfang Soda Ash 1530

Soda ash, dense Tianjin Soda Ash Works 1400

Soda ash, dense Dalian Dahua Group 1380

Soda ash, dense Qinghai Soda Industry 1100

Solvent oil (200#) Yangzhou Petrochemical 8410

Styrene monomer (industrial grade A) Panjin Ethylene Industry 11210

Styrene monomer (industrial grade A) Sinopec Guangzhou Petrochem 11250

Styrene monomer (industrial grade A) PetroChina Jinxi Petrochem 11100

Styrene monomer (industrial grade A) Sinopec Beijing Yanhua 11050

Styrene monomer (industrial grade A) Sinopec Qilu Petrochem 11050

Sulphur (industrial grade A) Sinopec Jinling Petrochem 1140

Sulphur (industrial grade A) Sinopec Tianjin Petrochem 1280

Sulphur (industrial grade A) Hainan Refinery 1500

Sulphur (industrial grade A) Sinopec Wuhan Petrochem 1190

Sulphur (industrial grade A) Sinopec Guangzhou Petrochem 1240

Sulphur (industrial grade A) Sinopec Yangzi Petrochem 1190

Sulphur (industrial grade A) Sinopec Beijing Yanhua 1130

Sulphur (industrial grade A) Sinopec Qilu Petrochem 1300

Sulphur (industrial grade A) WEPEC 1150

Sulphur (industrial grade A) Shanghai Jinshan Petrochem 1300

Sulphur (industrial grade A) Sinopec Qingdao Refinery 1300

Sulphur (industrial grade A) Fujian Refining & Petrochem 1300

Sulphuric acid (industrial grade A) Guangdong Shanguan Metallurgy Works 150

Sulphuric acid (industrial grade A) Hunan Zhuhou Chemical 220

Sulphuric acid (industrial grade A) Jinxi Zinc Plant 260

Sulphuric acid (industrial grade A) Jiangxi Copper Corp 220

TDI Gansu Yinguang Chemical 18000

TDI Cangzhou Dahua Co 18000

TDI Yantai Juli Isocyanic Ester 18000

Toluene (petroleum) Sinopec Guangzhou Petrochem 7950

Toluene (petroleum) Sinopec Qilu Petrochem 7900

Toluene (petroleum) Sinopec Shanghai Petrochem 7750

Toluene (petroleum) Sinopec Beijing Yanhua 7900

Urea Cangzhou Dahua Co 1560

Urea Shanxi Lanhua Sci-Tech 1530

Urea Liaoning Huajin Group 1550

Urea Shandong Luxi Chemical 1590

Urea Fujian Sanming Chemical 1750

Urea Sichuan Meifeng Chemical 1680

Urea Linzhou Chemical Group 1650

Urea Hainan Fudao 1650

Vinyl acetate(99.5%) Sinopec Southern China 8100

Vinyl acetate(99.5%) Sinopec Shanghai Petrochem 8000

Vinyl acetate(99.5%) Sinopec Sichuan Vinylon 8100

Xylene, mixed (petroleum) Panjin Ethylene Industry 7860

Xylene, mixed (petroleum) Sinopec Guangzhou Petrochem 8100

Xylene, mixed (petroleum) BASF-YPC CO.Ltd 7750

Xylene, mixed (petroleum) Shijiazhuang Refinery 8000

Xylene, mixed (petroleum) Sinopec Wuhan Petrochem 7850

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Nandini Chemical Journal, December,2014 Page 81

CHEMICALS IMPORTED AT THE CHENNAI PORT DURING THE MONTH OF SEPTEMBER 2014

NAME OF THE CHEMICAL

QTY

UNIT

VALUE IN

RS.

COUNTRY

CATEGORY: ORGANIC CHEMICALS

1 - octanol 680 Kgs 343539 Germany

1-(hydroxymethyl] cyclopropane acetonitrile 1000 Kgs 6495563 China

1,1-cyclohexane diacetic acid monoamide 30000 Kgs 17337054 China

1,1-cyclohexanediacetic acid mono amide 30000 Kgs 16819530 China

1,1-dimethyl benzyl carbinol 3420 Kgs 1580297 China

1,2-benzoisothiazolin-3-one 7000 Kgs 3329404 China

1,2-dimethoxy ethane 14400 Kgs 2735915 China

1,2-dimethoxy ethane 1620 Kgs 307790.5 China

1,2-dimethoxy ethane 11340 Kgs 2154533 China

1-bromo-3-chloro propane 20000 Kgs 3764250 France

1-chloro-6,6-dimethyl-2-hepten-4-yne 800 Kgs 4068325 China

1-chloro-6,6-dimethyl-2-hepten-4-yne 1000 Kgs 5085407 China

1-chloro-6,6-dimethyl-2-hepten-4-yne 1000 Kgs 5064650 China

2,2,2-trifluoro ethanol 5000 Kgs 1971520 China

2,2-dibromo-3-nitrilopropionamide 5000 Kgs 1732150 China

2,2-dibromo-3-nitrilopropionamide 5000 Kgs 1732150 China

2,3-dichloro benzoyl chloride 10000 Kgs 2248765 China

2,3-dichloro-5,6 -dicyano benzoquinone 442 Kgs 1850920 China

2,5-dihydroxy-1,4-dithiane 8000 Kgs 4490460 China

2-cyano acetamide 1000 Kgs 335158.4 China

2-cyano-4-bromomethylbiphenyl 400 Kgs 320372 China

2-cyano-4-bromomethylbiphenyl 400 Kgs 320372 China

2-mercapto benzothiazole 17000 Kgs 3330637 China

2-methyl-2-propyl-1,3-propanediol 9000 Kgs 4634046 China

2-n-propyl-4-methyl-6(1-methylbenzimidazole-2-yl)benzimidazole 424.7 Kgs 1745257 China

2-piperidineethanol (cas no 1484-84-0) 800 Kgs 2267248 China

3,4-dihydroxy 5 nitrobenzaldehyde 700 Kgs 2371985 China

3,5,5-trimethyl hexanol (nonanol) 13600 Kgs 2379625 Japan

3-isobutyl glutaric acid 3000 Kgs 2957280 China

3-methoxy-1- propanol 99 pct min [ 5130 Kgs 2284904 China

4 bromomethyl-2-cyano biphenyl (br-otbn) 2000 Kgs 1435210 China

4,4-dihydroxydiphenyl sulfone 70% 15000 Kgs 1940715 China

4-bromo methyl-2-cyano biphenyl 5000 Kgs 3860252 China

4-bromo methyl-2-cyano biphenyl 5000 Kgs 3860252 China

4-bromomethyl-1,2-dihydroquinoline-2-one 1000 Kgs 1268181 China

4-chloro 2 trifluoroacetylaniline hcl (e-2) 15180 Kgs 28402160 China

5-chloro-2,3-difluoropyridine (dfp) 99 pct min 5000 Kgs 7855275 China

6-apa (6-amino penicillanic acid) 9200 Kgs 14563110 China

6-apa (6-amino penicillanic acid) 9200 Kgs 14563110 China

6-apa (6-amino penicillanic acid) 9200 Kgs 14563110 China

7-amino cephalosporanic acid (7-aca) 10000 Kgs 39282688 Germany

7-amino cephalosporanic acid (7-aca) ( 10000 Kgs 38814300 Germany

7-hydroxy -3,4 dihydro -2(h)-quinol inone 405 Kgs 1683689 China

8 hydroxy quinoline 10000 Kgs 6900320 China

8 hydroxy quinoline 99% min 12000 Kgs 9168023 China

Amino acid powder fertilizer (organic fertilizer) 15000 Kgs 663528.2 China

Benzyl chloroformate 12600 Kgs 4525747 USA

Butyl acrylate 59720 Kgs 6427823 Malaysia

Calcium carboxymethyl cellulose(usp,bp,ep,kp) 7200 Kgs 5482286 Korea

Calcium carboxymethyl cellulose(usp,bp,ep,kp) 4000 Kgs 2957028 Korea

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Nandini Chemical Journal, December,2014 Page 82

NAME OF THE CHEMICAL

QTY

UNIT

VALUE IN

RS.

COUNTRY

CHEMICALS IMPORTED

Calcium carboxymethyl cellulose(usp,bp,ep,kp) 500 Kgs 380714.3 Korea

Calcium carboxymethyl cellulose(usp,bp,ep,kp) 500 Kgs 380714.3 Korea

Calcium carboxymethyl cellulose(usp,bp,ep,kp) 2000 Kgs 1522857 Korea

Calcium chloride desiccant 360 Pcs 198153.8 China

Calcium cmc (chemicals) 100 Kgs 129911.3 Japan

Calcium gluconate - granular / lumps 24 Mts 2898134 China

Calcium gluconate - granular / lumps 24 Mts 2898134 China

Calcium hydroxide composition 27000 Kgs 350760.4 China

Calcium ligno sulphonate 24000 Kgs 813252 South africa

Calcium metacilicate for foundry mould 1995.84 Kgs 188689.7 USA

Chloro sulphonyl isocyanate 6000 Kgs 2126833 China

Chloro sulphonyl isocyanate 6000 Kgs 2126833 China

Cosmonate t-80 (tolylene di isocyanate)- 20 Mts 2894512 Japan

Csa binder(calcium sulfo aluminate cement) 18 Mts 432047.7 China

Cyclopropyl acetylene 2940 Kgs 9781204 China

Cysteamine hcl 20000 Kgs 4146238 China

Cytidine-5'-monophosphate 4000 Kgs 1.9E+07 China

Cytosine 5000 Kgs 5876938 China

Calcium meta silicate 50 Kgs 16544.43 Japan

Calcium meta silicate 6000 Kgs 1559415 Japan

Di isocyanate 18000 Kgs 2639372 China

Diphenylmethane-4,4'-diisocyanate 15750 Kgs 2277429 China

Di isopropyl ether 11200 Kgs 1497369 China

Dicyanodiamide (dicyandiamide) 20000 Kgs 1996164 China

Diethanolamine pure 860 Kgs 77782.3 Germany

Diethyl acetamidomalonate 1500 Kgs 1252716 China

Dimethyl formamide 16000 Kgs 922187 Saudi arabia

Dimethyl formamide 99.9 pct minimum 5130 Kgs 303497.2 China

Dimethyl formamide 99.9 pct minimum 4940 Kgs 292256.6 China

Dimethyl formamide 99.9 pct minimum 10070 Kgs 595753.8 China

Dimethyl formamide 99.9 pct minimum 5130 Kgs 303497.2 China

Dimethyl formamide,adc list no:572 7000 Kgs 419788.3 Saudi arabia

Dimethyl phosphite liquid (dimethyl phosphite (dmp) 98% min) 19200 Kgs 2803501 China

Dimethyl sulfoxide 99.90 percent 2.1 Mts 182796.3 China

Dipotassium hydrogen orthophosphate 12000 Kgs 1347138 China

Dipotassium hydrogen orthophosphate 24000 Kgs 2672460 China

Dipotassium hydrogen orthophosphate 12000 Kgs 1331588 China

Dipotassium hydrogen orthophosphate 12000 Kgs 1336230 China

Dipotassium hydrogen orthophosphate 12000 Kgs 1349320 China

Dipotassium hydrogen orthophosphate 12000 Kgs 1349320 China

Dipotassium hydrogen orthophosphate 12000 Kgs 1356816 China

Dipotassium hydrogen orthophosphate 12000 Kgs 1336230 China

Dipotassium hydrogen orthophosphate) 24000 Kgs 2694276 China

Dl-methionine 99 percent feed grade 20000 Kgs 4312700 Japan

Epp beads black (expanded polypropylene beads) 1776 Kgs 579922.6 Korea

Ethylene glycol - 1097.5 Kgs 149493.9 Japan

Ethylene vinyl acetate copolymer (eva 1316) 32 Mts 3647312 Korea

Eugenol rectified (2-methoxy-4-(2-propenyl)phenol) 1600 Kgs 1977011 Indonesia

Ethylene vinyl acetate 100 Kgs 23589.97 Korea

Formic acid 85% , 20160 Kgs 844599.2 Germany

Formic acid 85% , 20160 Kgs 844599.2 Germany

Formic acid 85% 20400 Kgs 804380.2 Germany

Glacial acrylic acid 13872 Kgs 1454906 USA

Granulated magnesium 66 Mts 11062220 China

Hydrophilic pyrogenic silica 2400 Kgs 815767 Germany

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Nandini Chemical Journal, December,2014 Page 83

NAME OF THE CHEMICAL

QTY

UNIT

VALUE IN

RS.

COUNTRY

CHEMICALS IMPORTED

Hexamethyl disilane (hmd) 3640 Kgs 3580354 China

Hexamethyl disilane (hmd) 3640 Kgs 3565740 China

Hydrated sodium calcium aluminosilicate - 24000 Kgs 749622 Argentina

Hydrobromic acid 3600 Kgs 229001 Jordan

Hydrophilic pyrogenic silica graco:fa1193 (amorphous) 300 Kgs 92112 China

Hydrophilic pyrogenic silica graco:fa1193 (amorphous) 300 Kgs 92112 China

Hydroxy ethyl cellulose / hec-d100000 3000 Kgs 988840.5 China

Hydroxy propyl methyl cellulose e15 usp36 10500 Kgs 4481938 China

Hydroxy propyl methyl cellulose k 100m usp36 8886.83 Kgs 3848331 China

Hydroxy propyl methyl cellulose k 100m usp36 9193.41 Kgs 3981091 China

Hydroxy propyl methyl cellulose k 100m usp36 2919.76 Kgs 1264366 China

Hydroxylammonium sulphate 20000 Kgs 2428040 Germany

Polymethylolcarbamide 10401 Kgs 630563.2 China

Polymethylolcarbamide 9599 Kgs 581941.8 China

Isocyanate ia- 1840 Kgs 385528.5 Korea

Isoeugenol s 915 (aromatic chemical) 200 Kgs 357377 Indonesia

Isoeugenol tech (2-methoxy-4-propenylphenol) 1000 Kgs 1611014 Indonesia

Isopropyl isocyanate 200 Kgs 423998 China

Lactose monohydrate /pharmatose 200m/ usp. Nf.ph.eur.jp 16000 Kgs 2473207 Netherlands

Lactose monohydrate n.f 9785 Kgs 620939.5 Canada

Lactose monohydrate n.f 9785 Kgs 620939.5 Canada

Lauric acid 48 Mts 4133443 Indonesia

Lauric acid 48 Mts 4133443 Indonesia

Lexan polycarbonate lenses ls1 natural 111h 10000 Kgs 1540250 Netherlands

Lexan polycarbonate lenses ls1 natural 111h 10000 Kgs 1540250 Netherlands

Lexan polycarbonate lenses ls2 natural 111h 21000 Kgs 3247781 Spain

Lexan polycarbonates pk2870 111 10952 Kgs 1680958 USA

Locron l liq (aluminium hydroxy chloride) 5040 Kgs 487938 Germany

L-pyroglutamic acid 1200 Kgs 539703.6 China

Methacrylic acid 20000 Kgs 3105498 China

Methacrylic acid) 720 Kgs 271478.3 China

Methane sulfonyl chloride (msc) 6000 Kgs 808537.3 China

Methane sulphonic acid 10000 Kgs 1669278 China

Methane sulphonic acid 3500 Kgs 584247.1 China

Methanol 1760 Kgs 109766.8 Korea

Methyl aceto acetate 20000 Kgs 2397791 Switzerland

Methyl dihydro jasmonate 3200 Kgs 1543458 China

Methyl dihydro jasmonate 3200 Kgs 1543458 China

Methylene chloride 15638 Kgs 696532 China

Methylene chloride 19578 Kgs 872023.7 China

Methylene chloride 7984 Kgs 355615.3 China

Methylhydrazine 98% [organic chemical] 3 Kgs 96600.28 Germany

Microcrystalline cellulose usp/nf(vivapur 102) 500 Kgs 110205 Germany

Modified polyisocyanate solution coronate ls 19200 Kgs 3028788 Japan

Monoethanolamine pure 1680 Kgs 161124.7 Germany

Monosodium glutamate 44 Mts 3353309 China

Monosodium glutamate 46 Mts 3471724 China

Monosodium glutamate 44 Mts 3198291 China

Monosodium glutamate 10000 Kgs 1033104 China

Monosodium glutamate 22 Mts 1599146 China

Monosodium glutamate 44 Mts 3196080 China

N-(2-amino-4,6-dichloro-5-pyrimidinyl) formamide;(fadcp) 6150 Kgs 19973855 China

N,n diethyl 2 cyano acetamide 1100 Kgs 1213101 China

N,n-carbonyl diimidazole 500 Kgs 654606.3 China

N,n-dicyclohexyl carbodiimide [ 600 Kgs 264049.4 China

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Nandini Chemical Journal, December,2014 Page 84

NAME OF THE CHEMICAL

QTY

UNIT

VALUE IN

RS.

COUNTRY

CHEMICALS IMPORTED

N,n-dimethyl acetamide [ dimethyl acetamide] 30400 Kgs 2350545 China

N,n-dimethyl acetamide [ dimethyl acetamide] 30400 Kgs 2350545 China

N,n-dimethyl acetamide [ dimethyl acetamide] 15200 Kgs 1180089 China

N,n-dimethyl acetamide-[adc list s.no:1068] 30.4 Mts 2350545 China

N,o-bis(trimethylsilyl)acetamide (bsa) 4600 Kgs 2504194 China

N,o-bis(trimethylsilyl)acetamide (bsa) 4600 Kgs 2493973 China

N-butyl chloride 16700 Kgs 2057774 Germany

N-butyl chloride 16700 Kgs 2057774 Germany

Nitromethane 36000 Kgs 5135305 China

N-methyl piperazine 7200 Kgs 2661552 China

N-methyl pyrrolidine (nmp) 1500 Kgs 1506365 China

N-methyl pyrrolidone 16800 Kgs 2942233 China

Nonyl phenol 15.2 Mts 1732473 Taiwan

N-ethyl-n-(3-methylphenyl)propionamide 5 Kgs 9783.55 Switzerland

Ortho-cyanophenol 96% min 14000 Kgs 10177972 China

Para amino phenol (pap) 72 Mts 14593995 China

Para amino phenol (pap) 72 Mts 14593995 China

Polycarbonate 15 Kgs 23945.38 Korea

Polycarbonate 15 Kgs 23553.67 Korea

Polycarbonates 125 Kgs 42568.36 Korea

Polycarbonates 150 Kgs 51063.62 Korea

Pentaerythritol, mono grade - pmsc1 20000 Kgs 2084766 Saudi arabia

Pharmatose 200m lactose monohydrate usp/nf 20000 Kgs 3172865 Netherlands

Pharmatose 350m ,lactose monohydrate 20000 Kgs 2931273 Netherlands

Polyacrylamide nuoerfloc a-7952 17500 Kgs 1994624 China

Polybor disodium octaborate tetrahydrate 16.329 Mts 1313199 USA

Polybor disodium octaborate tetrahydrate 16.329 Mts 1313199 USA

Polybor disodium octaborate tetrahydrate 16.329 Mts 1313199 USA

Polybor disodium octaborate tetrahydrate 16.329 Mts 1313199 USA

Polycarbonate 2 Mts 437986.5 Thailand

Polycarbonate film 907 Kgs 311659.7 Israel

Polycarbonate makrolon 9000 Kgs 2217960 Thailand

Polycarbonate sheet 3349 Kgs 662980.5 Korea

Polycarbonate sheet 2928 Kgs 615853.6 Korea

Polycarbonate sheet 712.8 Kgs 141105.3 Korea

Polycarbonate sheet 893 Kgs 187826.9 Korea

Polycarbonate sheet 848.4 Kgs 167950.5 Korea

Polycarbonate sheet 1425.6 Kgs 282210.5 Korea

Polycarbonate sheet 550 Kgs 1464786 Japan

Polycarbonates 11000 Kgs 2060445 Netherlands

Polycarbonates 16000 Kgs 3662098 Korea

Polyethylene copolymers grade 24750 Kgs 2679420 Singapore

Polyformaldehyde - acetal co-polymer 22000 Kgs 1811152 China

Polyformaldehyde - acetal co-polymer 22000 Kgs 1811152 China

Polyglykol 8000 pf 2000 Kgs 1448128 Germany

Polyisocyanate aknate 17600 Kgs 2710840 Korea

Polyisocyanate aknate 17600 Kgs 2710840 Korea

Polymethane polyphenyl isocyanate 60 Mts 6642790 China

Polymethane polyphenyl isocyanate 40 Mts 4428527 China

Polymethylene polyphenyl polyisocyanate 20 Mts 2501366 Japan

Polyvinyl chloride film 4500 Kgs 869163.1 Korea

Polyvinyl chloride film 4500 Kgs 869163.1 Korea

Polyvinyl chloride rigid film 678 Kgs 56391.63 China

Polyvinyl chloride rigid film 10860 Kgs 802901.5 China

Polyvinyl chloride rigid film 8276 Kgs 586367 China

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VALUE IN

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CHEMICALS IMPORTED

Polyacetal copolymer 3000 Kgs 552425 Korea

Potassium caprylate 400 Kgs 214403 Malaysia

Potassium humate 25000 Kgs 781980.7 China

Potassium humate 20 Mts 650607.9 China

Potassium humate 100 Kgs 3127.92 China

Potassium humate 24900 Kgs 778852.7 China

Potassium humate 25000 Kgs 778788.9 China

Potassium humate 95% fertilizer 15000 Kgs 990619 China

Potassium humate 95% fertilizer 15000 Kgs 990619.5 China

Potassium humate organic manure 5.2 Mts 259231 China

Potassium titanate 4000 Kgs 2523727 Japan

Potassium titanate 8000 Kgs 4978088 Japan

Potassium titanate 344 100 Kgs 113122.4 Japan

Potassium titanate 574 30 Kgs 17197.04 Japan

Potassium titanate fibre 4000 Kgs 2499245 Japan

Potassium titanate fibre 4000 Kgs 2499245 Japan

Propionic acid (ol) 20000 Kgs 1509445 Sweden

Propionic acid pure 20000 Kgs 1519303 Germany

Propionic acid pure 20000 Kgs 1519303 Germany

Propylene glycol usp/ep- 17200 Kgs 1934025 Thailand

Prepolymerised diphenylmethane diisocyanate) 17625 Kgs 1835131 Netherlands

Prepolymerised diphenylmethane diisocyanate) 17625 Kgs 1835131 Netherlands

Prepolymerised diphenylmethane diisocyanate) 17625 Kgs 1835131 Netherlands

Prepolymerised diphenylmethane diisocyanate) 17625 Kgs 1835131 Netherlands

Prepolymerised diphenylmethane diisocyanate) 17625 Kgs 1835131 Netherlands

Prepolymerised diphenylmethane diisocyanate) 17625 Kgs 1835131 Netherlands

Prepolymerised diphenylmethane diisocyanate) 17625 Kgs 1835131 Netherlands

Prepolymerised diphenylmethane diisocyanate) 17625 Kgs 1835131 Netherlands

S(+)-2- amino butyramide hcl 13000 Kgs 17290569 China

S(+)-2-amino butyramide hcl 5000 Kgs 7224999 China

S(+)-2-amino butyramide hcl 5200 Kgs 7578496 China

S(+)-2-amino butyramide hcl 5000 Kgs 7195509 China

(S)+2-aminobutyramide- hcl 8000 Kgs 13238539 China

(S)-2-amino butyramide hcl 7000 Kgs 9772861 China

Secondary butanol(sec-butanol) 19040 Kgs 1812369 Brazil

Sodium acid pyrophosphate 20 Mts 1626710 Thailand

Sodium acid pyrophosphate 20 Mts 1585399 Thailand

Sodium acid pyrophosphate (food grade) 1 Mts 86254 Thailand

Sodium alginate 18000 Kgs 6903855 China

Sodium azide 11000 Kgs 4269573 China

Sodium borohydride 1000 Kgs 1251617 China

Sodium borohydride 2000 Kgs 2513587 China

Sodium borohydride 6000 Kgs 7356840 USA

Sodium borohydride 8000 Kgs 1E+07 USA

Sodium borohydride 8000 Kgs 1E+07 USA

Sodium borohydride 8000 Kgs 1E+07 USA

Sodium borohydride 2000 Kgs 2474500 USA

Sodium borohydride 2000 Kgs 2452280 USA

Sodium borohydride granules (sb200(tm), 400 Kgs 546309 USA

Sodium carboxy methyl cellulose / cmc 6000 3000 Kgs 591456 China

Sodium carboxy methyl cellulose / cmc 9000 3000 Kgs 545248.5 China

Sodium carboxy methyl cellulose intermediate 76000 Kgs 8170718 China

Sodium carboxy methyl cellulose intermediate 66000 Kgs 9454055 China

Sodium carboxy methyl cellulose intermediate 66000 Kgs 9454055 China

Sodium carboxy methyl cellulose intermediate 40000 Kgs 5828306 China

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CHEMICALS IMPORTED

Sodium carboxy methyl cellulose intermediate 76000 Kgs 8170718 China

Sodium carboxy methyl cellulose intermediate 57000 Kgs 6128039 China

Sodium carboxy methyl cellulose intermediate 100000 Kgs 14324325 China

Sodium carboxy methyl cellulose intermediate 80000 Kgs 1.1E+07 China

Sodium carboxy methyl cellulose -intermediate 88000 Kgs 12605406 China

Sodium citrate 2500 Kgs 249109.8 Spain

Sodium citrate 500 Kgs 90496.2 Spain

Sodium citrate. 1000 Kgs 121458.2 Spain

Sodium diacetate 15000 Kgs 896425.5 China

Sodium erythorbate 5000 Kgs 1374307 China

Sodium erythorbate 5000 Kgs 1374307 China

Sodium erythorbate 5000 Kgs 1374307 China

Sodium formate 45000 Kgs 887184 China

Sodium formate 20000 Kgs 425109 Spain

Sodium gluconate 26000 Kgs 1185652 China

Sodium gluconate technical grade 25 Mts 1146003 China

Sodium hexa meta phosphate 500 Kgs 192283.3 France

Sodium ligno sulphonate 24000 Kgs 672781.2 Sweden

Sodium ligno sulphonate 26 Mts 664875.7 China

Sodium lignosulphonate 24.12 Mts 292456 South africa

Sodium naphthalene sulphonate formaldehyde 28000 Kgs 1414495 China

Sodium naphthalene sulphonate formaldehyde 28000 Kgs 1400765 China

Sodium salt of poly-naphthalene sulfonic acid 19500 Kgs 983149.8 China

Sodium salt of poly-naphthalene sulfonic acid 19500 Kgs 979136.9 China

Sodium silicate powder 18 Mts 723339.1 China

Sodium thiocyanate 10 Mts 1176751 China

Sulfamide 2000 Kgs 1725684 China

Sulfamide 3000 Kgs 2643994 China

Sulfur hexafluoride (sf6 gas) purity 99.995 % in cylinder 10000 Kgs 4504209 China

Sulphonated methyl esters (palmfonate 6718) 126 Mts 8213106 Malaysia

Tertiary butyl acetate 3300 Kgs 542640.8 China

Tertiary butyl acetate 6780 Kgs 1114880 China

Tertiary butyl alcohol (tba) 12400 Kgs 1566126 Japan

Tetrahydrofuran 14400 Kgs 2439756 Japan

Tetrahydrofuran (thf) 14400 Kgs 2556653 Germany

Tetrakis hydroxymethyl phosphonium sulfate 75%(leather chemical) 1000 Kgs 126608.6 China

Texanol (tm) ester alcohol 16000 Kgs 2168672 Singapore

Tgic (triglycidyl isocyanurate) 2500 Kgs 816333 China

Thiophene-2-ethanol 3500 Kgs 3946121 China

Thiophenol 5000 Kgs 1678873 China

Toluene di isocyanate cosmonate 1245 Kgs 176420.2 Japan

Toluene di isocyanate cosmonate 18755 Kgs 2657640 Japan

Toluene di isocyanate cosmonate 20000 Kgs 2845675 Japan

Toluene di isocyanate cosmonate t-80 20 Mts 2814744 Japan

Toluene di isocyanate cosmonate t-80 10400.5 Kgs 1473782 Japan

Toluene di isocyanate cosmonate t-80 9599.5 Kgs 1360278 Japan

Toluene di isocyanate cosmonate t-80 20 Mts 2814744 Japan

Toluene di isocyanate cosmonate t-80 1245 Kgs 176420.2 Japan

Toluene di isocyanate cosmonate t-80 18755 Kgs 2657640 Japan

Toluene di isocyanate cosmonate t-80 20000 Kgs 2868905 Japan

Toluene diisocyanate cosmonate t-80 20000 Kgs 2834060 Japan

Tolene di isocyanate 1250 Kgs 183164 Germany

Toluene di isocyanate tdi 80/20) 20000 Kgs 2834060 China

Toluene di isocyanate tdi 80/20) 20000 Kgs 2834060 China

Tpgda-tripropylene glycol diacrylate-uv resins 9600 Kgs 1697479 China

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CHEMICALS IMPORTED

Trichloroisocyanuric acid 90% 7 Mts 694344.7 China

Trichloroisocyanuric acid 90% 13 Mts 1233432 China

Vanillin (organic chemicals) 1350 Kgs 980197 China

Xenoy polycarbonates 199.58 Kgs 47439.7 USA

CATEGORY: INORGANIC CHEMICALS

Activated carbon 4005 Kgs 978093.1 France

Activated carbon 2025 Kgs 514994 France

Activated carbon 12355 Kgs 3044766 France

Activated carbon 1505 Kgs 370892.2 France

Activated carbon 2025 Kgs 514994 France

Activated carbon 12355 Kgs 3044766 France

Activated carbon 1505 Kgs 370892 France

Activated carbon 20000 Kgs 2381126 China

Activated carbon 17500 Kgs 2587620 China

Activated carbon 17500 Kgs 2587620 China

Activated carbon 18000 Kgs 1785458 China

Activated carbon 18000 Kgs 1785458 China

Activated carbon 36000 Kgs 3460018 China

Activated carbon 36000 Kgs 3460018 China

Activated carbon 10 Kgs 1799.01 China

Activated carbon 10 Kgs 1799.01 China

Activated carbon 6000 Kgs 1737737 USA

Activated carbon 6000 Kgs 1737737 USA

Activated carbon 13200 Kgs 3217345 USA

Activated carbon 13200 Kgs 3217345 USA

Activated colloidal calcium carbonate - n-sp 16000 Kgs 552025.6 Malaysia

Barium nitrate 50000 Kgs 1957320 China

Barium sulphate 7000 Kgs 257913.6 China

calcined alumina 60000 Kgs 2772450 Japan

Calcined alumina 4000 Kgs 381982 Germany

Calcined alumina 25000 Kgs 2102441 Germany

Calcined alumina 25000 Kgs 1293810 Germany

Calcined alumina 25000 Kgs 1340018 Germany

Calcined alumina 20000 Kgs 1072014 Germany

Calcined alumina 25000 Kgs 1340018 Germany

Calcined alumina 2800 Kgs 1349013 Germany

Calcined alumina 4082.5 Kgs 1438711 Germany

Calcined alumina 816.5 Kgs 534234.5 Germany

Calcined alumina 1500 Kgs 909363.6 Germany

Calcined Alumina powder 192 Kgs 116500.8 Japan

Calcium carbonate 500 Kgs 12522.93 Thailand

Calcium carbide 22.5 Mts 858806.2 China

Calcium carbide 22.5 Mts 858806.2 China

Calcium carbide 45 Mts 1725964 China

Calcium carbide 22.5 Mts 869941.4 China

Calcium carbide 45 Mts 1753802 China

Calcium carbide 22.5 Mts 872725.2 China

Calcium carbide 45 Mts 1767721 China

Calcium carbide 22.5 Mts 887960.3 China

Calcium carbide 22.5 Mts 859459.5 China

Calcium carbide 45 Mts 1663470 China

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CHEMICALS IMPORTED

Calcium carbide 67.5 Mts 2619965 China

Calcium carbide 22.5 Mts 801238.1 China

Calcium carbide 45 Mts 1718919 China

Calcium carbide 22.5 Mts 873321.8 China

Calcium carbide 22.5 Mts 873322 China

Calcium carbide 22.5 Mts 873321.8 China

Calcium carbide 67.5 Mts 2652178 China

Calcium carbide 45 Mts 1768119 China

Calcium carbide 45 Mts 1683923 China

Calcium carbide 22.5 Mts 852528.4 China

Calcium carbide (size 25-50mm) 22.5 Mts 914908.5 China

Calcium carbide ( 45 Mts 1571661 China

Calcium carbide ( adc. S.l.no. 374 ) 45 Mts 1746644 China

Calcium carbide (adc sl no.374) 22.5 Mts 873321.8 China

Calcium carbide (size 50-80mm) gas yield (295l/kg) 45 Mts 1774680 China

Calcium carbide (size:50-80mm) (adc noc list s.no.374) 22.5 Mts 880252.9 China

Calcium carbide dust 43.2 Mts 628782.9 China

Calcium carbide dust size:0-1mm 43.2 Mts 620141.6 China

Calcium carbide dust size:0-1mm 22.5 Mts 256451.6 China

Calcium carbide size : 25 - 50 mm 22500 Kgs 876900.9 China

Calcium carbide size : 25 -50 mm 22500 Kgs 876900.9 China

Calcium carbide size : 50 - 80mm 67.5 Mts 2619965 China

Calcium carbide size : 50 - 80mm " b '' grade 22.5 Mts 874117.1 China

Calcium carbide size : 50 -80 mm ( 67500 Kgs 2588946 China

Calcium carbide size 25-50 mm 225 Mts 9230224 China

Calcium carbide size 25-50 mm 22.5 Mts 866390.6 China

Calcium carbide size 25-50 mm 112.5 Mts 4505658 China

Calcium carbide size 40-80 mm 315 Mts 12903669 Indonesia

Calcium carbide size: 45 Mts 1768119 China

Calcium carbide size: 15 - 25mm 22.5 Mts 873321.8 China

Calcium carbide size: 50-80mm 67500 Kgs 2601797 China

Calcium carbide size; 4 - 25mm 22.5 Mts 873322 China

Calcium carbide, size:25-50mm, gas yeild: 295l/kg 67500 Kgs 2672460 China

Calcium carbonate 24 Mts 261307 Malaysia

Calcium carbonate 120 Mts 1024443 Malaysia

Calcium carbonate 96 Mts 856005.5 Malaysia

Calcium carbonate 13750 Kgs 209787.2 France

Calcium carbonate 10000 Kgs 152573 France

Calcium carbonate 13750 Kgs 209787.2 France

Calcium carbonate 10000 Kgs 152573 France

Calcium carbonate 2100 Kgs 213478.7 Malaysia

Calcium carbonate omyalite 75t-ip 120 Mts 1299113 Malaysia

Calcium carbonate omyalite 75t-ip 120 Mts 1299113 Malaysia

Calcium carbonate omyalite 75t-ip 120 Mts 1293810 Malaysia

Calcium carbonate powder 50 Mts 394304 Malaysia

Calcium carbonate (caco3) 10000 Kgs 261059.8 Korea

Calcium carbonate (caco3) 10000 Kgs 261059.8 Korea

Calcium carbonate (not for medical use) 3150 Kgs 322069.6 Japan

Calcium carbonate (technical grade) 16000 Kgs 483022 Taiwan

Calcium carbonate 1qc 45564 Kgs 493273 Thailand

Calcium carbonate 1qc 55546 Kgs 601338 Thailand

Calcium carbonate 1qc 48890 Kgs 529280 Thailand

Calcium carbonate 24 mts omyalite 75t-ip - 24 Mts 260240.6 Malaysia

Calcium carbonate 50 1000 Kgs 57272.7 Japan

Calcium carbonate 56 13000 Kgs 228327.2 Japan

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CHEMICALS IMPORTED

Calcium carbonate coco3 filler efpp 1001 25000 Kgs 737463.9 Vietnam

Calcium carbonate kz kal 2061 240 Mts 2048886 Malaysia

Calcium carbonate kz kal 2061 120 Mts 1024443 Malaysia

Calcium carbonate kz kal 2061 24.83 Mts 215046 Malaysia

Calcium carbonate kz kal 2061 23.17 Mts 200670 Malaysia

Calcium carbonate neolight ss 6 Mts 193801.6 Malaysia

Calcium carbonate omyacarb 120 Mts 1143219 Malaysia

Calcium carbonate omyacarb 24 Mts 232007.1 Malaysia

Calcium carbonate omyacarb 24 Mts 232007.1 Malaysia

Calcium carbonate omyacarb 24 Mts 207009.6 Malaysia

Calcium carbonate omyacarb 1t-ip 96 Mts 1009596 Malaysia

Calcium carbonate omyacarb 2t-ip 168 Mts 1600507 Malaysia

Calcium carbonate omyacarb 2t-ip 72 Mts 682897.5 Malaysia

Calcium carbonate omyacarb 2t-ip 144 Mts 1336230 Malaysia

Calcium carbonate omyacarb 2t-ip 120 Mts 1143219 Malaysia

Calcium carbonate omyacarb 2t-ip 192 Mts 1781640 Malaysia

Calcium carbonate omyacarb 2t-ip 192 Mts 1774368 Malaysia

Calcium carbonate omyacarb 2t-ip 120 Mts 1138553 Malaysia

Calcium carbonate omyafilm 723-bi 48 Mts 472134.6 Malaysia

Calcium carbonate powder 75 Mts 598519.7 Malaysia

Calcium carbonate powder 100000 Kgs 933876.3 Malaysia

Calcium carbonate powder 100000 Kgs 807676.8 Malaysia

Calcium carbonate powder 50 Mts 402106 Malaysia

Calcium carbonate powder 100 Mts 794769 Malaysia

Calcium carbonate powder 50 Ton 397384.5 Malaysia

Calcium carbonate powder 25 Mts 231037.5 Malaysia

Calcium carbonate powder 50 Mts 400465 Malaysia

Calcium carbonate powder 50000 Kgs 423301.3 Vietnam

Calcium carbonate powder 104000 Kgs 712759 Vietnam

Calcium carbonate powder 125000 Kgs 1009596 Malaysia

Calcium carbonate powder 75 Mts 603405.6 Malaysia

Calcium carbonate powder 100 Mts 794769 Malaysia

Calcium carbonate powder zancarb 2ts 100 Mts 791840 Malaysia

Calcium carbonate powder kz kal 2061 72 Mts 628847 Malaysia

Calcium carbonate powder msha2pl 26000 Kgs 197829.7 Vietnam

Calcium carbonate powder msha2s 25000 Kgs 207371.9 Vietnam

Calcium carbonate powder msha3 156 Mts 1086061 Vietnam

Calcium carbonate powder msha3 156 Mts 1086061 Vietnam

Calcium carbonate powder msha3 ( ) 104000 Kgs 726457 Vietnam

Calcium carbonate powder zancarb 25000 Kgs 203568 Malaysia

Calcium carbonate powder zancarb 1t 25 Mts 231984.4 Malaysia

Calcium carbonate powder zancarb 2t 75 Mts 609068 Malaysia

Calcium carbonate powder zancarb 2t 150 Mts 1197039 Malaysia

Calcium carbonate powder zancarb 2t 50 Mts 402106.3 Malaysia

Calcium carbonate powder zancarb 2t 75 Mts 603159.4 Malaysia

Calcium carbonate powder zancarb 2ts 100 Mts 788608 Malaysia

Calcium carbonate powder-msha3 400000 Kgs 2834060 Vietnam

Calcium carbonate sm700 120 Mts 717140.4 Malaysia

Calcium carbonate sm700 120 Mts 606242.4 Malaysia

Calcium carbonate sm-700 120 Mts 742350 Malaysia

Calcium hydroxide 18 Mts 302567 Malaysia

Calcium hydroxide 800 Kgs 20490.09 Japan

Calcium hydroxide composition 27000 Kgs 350760 China

Calcium hydroxide composition 27000 Kgs 350760 China

Calcium hydroxide composition 27000 Kgs 350760.4 China

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CHEMICALS IMPORTED

Calcium hydroxide composition 27000 Kgs 350760.4 China

Calcium hydroxide composition Super expansive mortar (cracking) 27000 Kgs 349328.7 China

Calcium hydroxide composition Super expansive mortar (cracking) 27000 Kgs 349328.7 China

Calcium hydroxide composition Super expansive mortar (cracking) 27000 Kgs 349328.7 China

Calcium hydroxide composition Super expansive mortar (cracking) 27000 Kgs 350760.4 China

Calcium hydroxide composition Super expansive mortar (cracking) 27000 Kgs 349328.7 China

Calcium hydroxide nicc 3000 200 Kgs 160186 Japan

Calcium nitrate 25 Mts 526765.5 China

Calcium nitrate - for agriculture use only 200000 Kgs 3773613 China

Calcium nitrate - for agriculture use only 200000 Kgs 3773613 China

Calcium nitrate - nitrogenous fertiliser 120 Mts 3142110 Norway

Calcium nitrate - nitrogenous fertiliser 120 Mts 3180743 Norway

Calcium nitrate fertilizer grade[ 100% water soluble fertilizer] 250000 Kgs 4717016 China

Calcium oxide 1800 Kgs 214910 Korea

calcium sulphate 2 Mts 33405.75 China

Carbon black 1600 Kgs 583925.4 Netherlands

Carbon black 19200 Kgs 1372178 Korea

Carbon black 6600 Kgs 696848.9 France

Carbon black 800 Kgs 291962.7 Netherlands

Carbon black 19000 Kgs 2171631 Czech republic

Carbon black 19000 Kgs 2171631 Czech republic

Carbon black 19000 Kgs 2171631 Czech republic

Carbon black 17000 Kgs 1889376 France

Carbon black 17000 Kgs 2126844 France

Carbon black 17000 Kgs 2126844 France

Carbon black 16000 Kgs 1963076 Czech republic

Carbon black - n339 44000 Kgs 2792724 China

Carbon black - n220 44000 Kgs 3009634 China

Carbon black (carbon black n550) 9600 Kgs 845782.1 Korea

Carbon black (carbon black n774) 10400 Kgs 916263.9 Korea

Carbon black corax hp 1107 (origin: korea) 17600 Kgs 1949716 Korea

Carbon black corax n326 25000 Kgs 2463276 Italy

Carbon black corax n330 21000 Kgs 2119282 Italy

Carbon black corax n375 19000 Kgs 1917446 Italy

Carbon black emperor 1200 500 kg bag 25 kg 1000 Kgs 924150 USA

Carbon black grade: vulcan 3 10000 Kgs 800930 Indonesia

Carbon black hafl n326 200000 Kgs 14968200 Korea

Carbon black monarch 1300 12.5k bag 525 kg 2100 Kgs 2151606 USA

Carbon black monarch 700 8kg bag 240 kg 240 Kgs 80585.88 USA

Carbon black monarch 700 8kg bag 240 kg 240 Kgs 80585.88 USA

Carbon black monarch 800 10 kg bag 400 kg 400 Kgs 122973.6 USA

Carbon black n234 9900 Kgs 820667.9 Korea

Carbon black n234 9900 Kgs 820667.9 Korea

Carbon black n234 9900 Kgs 820667.9 Korea

Carbon black n234 9900 Kgs 820667.9 Korea

Carbon black n234 9900 Kgs 820667.9 Korea

Carbon black n234 9900 Kgs 820667.9 Korea

Carbon black n234 9900 Kgs 820667.9 Korea

Carbon black n234 9900 Kgs 820667.9 Korea

Carbon black n234 9900 Kgs 820667.9 Korea

Carbon black n234 9900 Kgs 820667.9 Korea

Carbon black n234 9900 Kgs 820667.9 Korea

Carbon black n326 200000 Kgs 15168382 Korea

Carbon black regal 250r 10 kg bag 560 kg 1120 Kgs 207009.6 USA

Carbon black regal 350r 10 kg bag 560 kg 560 Kgs 116615.4 USA

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CHEMICALS IMPORTED

Carbon black regal 400 r 10 kg bag 450 kg 450 Kgs 126978.2 USA

Coated ground calcium carbonate grade 54 Mts 349584.8 Vietnam

Coated ground calcium carbonate grade 216 Mts 1321507 Vietnam

Coated ground calcium carbonate grade ms 175 Mts 1100666 Vietnam

Coated calcium carbonate 130 Mts 811625 Malaysia

Coated calcium carbonate 36 Mts 1111198 Malaysia

Coated calcium carbonate 130 Mts 958709.7 Malaysia

Coated calcium carbonate grade 260 Mts 1815316 Vietnam

Coated calcium carbonate iokalit 10 c 52.65 Mts 480077.4 Greece

Coated calcium carbonate iokalit 15 c 79.65 Mts 628729.6 Greece

Coated calcium carbonate iokalit 15 c 297 Mts 2433657 Greece

Coated calcium carbonate iokalit extra fine 1 Mts 7893.66 Greece

Coated calcium carbonate iokalit extra fine 1.25 Mts 26954.38 Greece

Coated calcium carbonate jv 2plc 156000 Kgs 1155340 Vietnam

Coated calcium carbonate jv 3c 260000 Kgs 1813412 Vietnam

Coated calcium carbonate jv 3c 130000 Kgs 906691 Vietnam

Coated calcium carbonate powder 156 Mts 976444.2 Malaysia

Coated calcium carbonate pwd k (ascom 30t) not for medical use 104 Mts 640152.1 Egypt

Coated calcium carbonate tkn 1c 26000 Kgs 239549.4 Malaysia

Coated calcium carbonate tkn 2c 52000 Kgs 404872.3 Malaysia

Coated calcium carbonate tkn 3c 26 Mts 160552.4 Malaysia

Coated calcium carbonate tkn 3c 26 Mts 162516.9 Malaysia

Colloidal calcium carbonate - pai ian hua ccr-501 20000 Kgs 532017.5 Taiwan

Dicalcium phosphate anhydrous 1000 Kgs 232498.7 Germany

Dicalcium phosphate dihydrate 3000 Kgs 191153.6 China

Ground calcined alumina grade ga4r 20 Mts 770125 France

Hydrated lime (high purity calcium hydroxide) 90 Mts 849703 Malaysia

Hydrated lime (high purity calcium hydroxide) 180 Mts 1699404 Malaysia

Hydrated lime (high purity calcium hydroxide) 180 Mts 1699407 Malaysia

Hydrated lime (high purity calcium hydroxide) 90 Mts 857437 Malaysia

Hydrated lime (high purity calcium hydroxide) 180 Mts 1714871 Malaysia

Hydrated lime (high purity calcium hydroxide) 180 Mts 1714871 Malaysia

Hydrated lime (high purity calcium hydroxide) 139.62 Mts 1317568 Malaysia

Hydrated lime (high purity calcium hydroxide) 40.38 Mts 381058.7 Malaysia

Hydrated lime (high purity calcium hydroxide) 48.63 Mts 458912.4 Malaysia

Hydrated lime (high purity calcium hydroxide) 131.37 Mts 1239715 Malaysia

Hydrated lime (high purity calcium hydroxide) 1.63 Mts 15382.02 Malaysia

Hydrated lime (high purity calcium hydroxide) 88.37 Mts 833932 Malaysia

Hydrated lime (high purity calcium hydroxide) 90 Mts 853935.8 Malaysia

Hydrated lime (high purity calcium hydroxide) 180 Mts 1707871 Malaysia

Hydrogen peroxide 48.9 Mts 1477714 Indonesia

Insolube sulphur 18000 Kgs 2550654 USA

Insolube sulphur 18000 Kgs 2550654 USA

Insolube sulphur- 18000 Kgs 2550654 USA

Insolube sulphur- 18000 Kgs 2550654 USA

Lithium carbonate 18000 Kgs 7629782 China

Mod#hjs-21 activated carbon - 10 pcs - 10 ctn 90 Kgs 8625.09 China

Mod#hjs-21 activated carbon - 10 pcs - 10 ctn 90 Kgs 8625.09 China

Molybdenum disulfide 415 220 Kgs 644242.5 Japan

Mono ammonium phosphate(12-61-00),100%water soluble fertilizer 25 Mts 1198586 China

Mono potassium phosphate 20 Mts 1552749 China

Mono potassium phosphate 200000 Kgs 15032588 China

Monocalcium phosphate feed grade 300 Mts 8445391 China

Nitrogen calcium compound fertilizer 100 Mts 1983842 China

Palladium chloride solution(50 grams/litre) 27.38 Kgs 1464282 Germany

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CHEMICALS IMPORTED

Potassium carbonate 24 Mts 1596053 Thailand

Potassium carbonate 24 Mts 1609082 Thailand

Potassium carbonate (adc list slno:1297) 20000 Kgs 1564894 Korea

Potassium carbonate 99% 24 Mts 1573782 Thailand

Potassium carbonate fine powder 99.5 pct minimum 20 Mts 1456824 Korea

Potassium carbonate powder 20000 Kgs 1540250 Korea

Potassium carbonate powder 99.5 pct min. 1 Mts 78085.63 Korea

Potassium carbonate powder 99.5 pct min. 20 Mts 1540250 Korea

Potassium carbonate powder 99.5 pct min. 3 Mts 234256.9 Korea

Potassium carbonate powder 99.5 pct min. 20 Mts 1540250 Korea

Potassium chlorate 50000 Kgs 3141447 China

Potassium chlorate 50000 Kgs 3141447 China

Potassium chlorate 50000 Kgs 3128633 China

Potassium chlorate 50000 Kgs 3128633 China

Potassium chlorate 50000 Kgs 3128633 China

Potassium chlorate 50000 Kgs 3128633 China

Potassium chlorate 50000 Kgs 3128633 China

Potassium chlorate 50000 Kgs 3128633 China

Potassium chlorate 50000 Kgs 3128633 China

Potassium chlorate 25000 Kgs 1564316 China

Potassium chlorate 25000 Kgs 1564316 China

Potassium chloride 267.9 Mts 5392576 Jordan

Potassium chloride 77200 Kgs 4495857 Sweden

Potassium chloride 99 percent kcl technical industrial use 388840 Kgs 8504534 Germany

Potassium chloride 99% fine grade 50150 Kgs 1101354 Germany

Potassium chloride 99% fine grade 130 Kgs 2854.95 Germany

Potassium chloride 99% fine grade 45380 Kgs 996598.7 Germany

Potassium chloride 99% fine grade 31400 Kgs 689581.3 Germany

Potassium chloride 99% fine grade 4470 Kgs 98166.51 Germany

Potassium chloride 99% fine grade 292771 Kgs 6429599 Germany

Potassium chloride 99% fine grade 3200 Kgs 70275.8 Germany

Potassium chloride 99% fine grade 47050 Kgs 1033274 Germany

Potassium chloride 99% fine grade 23385 Kgs 513562.4 Germany

Potassium chloride 99% fine grade 830 Kgs 18227.79 Germany

Potassium chloride 99% fine grade 20580 Kgs 451961.2 Germany

Potassium chloride 99% fine grade 830 Kgs 18227.79 Germany

Potassium chloride for industrial use 172.14 Mts 3469250 Jordan

Potassium chloride for industrial use 219.54 Mts 4421272 Jordan

Potassium chloride for insdustrial use 316.88 Mts 6402417 Jordan

Potassium chloride ph.eur 1000 Kgs 285100.1 UK

Potassium chloride w/anticaking 275 Kgs 71443.9 Germany

Potassium hydroxide 20000 Kgs 1436776 Korea

Potassium hydroxide 38547 Kgs 2779583 China

Potassium hydroxide 11453 Kgs 825863.6 China

Potassium hydroxide 20000 Kgs 1417030 Korea

Potassium hydroxide 25000 Kgs 1802723 China

Potassium hydroxide 20000 Kgs 1417030 Korea

Potassium hydroxide flakes (koh) 10 Mts 685921 Korea

Potassium hydroxide flakes 90 percent- 40 Mts 2735484 Taiwan

Potassium hydroxide flakes(koh 90.7%)- 20000 Kgs 1429352 Korea

Potassium nitrate 25 Mts 1492433 Jordan

Potassium nitrate (for agriculture use) 408 Mts 2.3E+07 Thailand

Potassium nitrate 100% water soulble fertilizer, 24 Mts 1287265 China

Potassium nitrate(13-00-45)100%water soluble fertilizer 25 Mts 1424731 Jordan

Potassium nitrate(13-00-45)100%water soluble fertilizer,( 25 Mts 1417030 Jordan

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UNIT

VALUE IN

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CHEMICALS IMPORTED

Potassium sulphate (00-00-50) 100%water souluble fertilizer 25 Mts 1169391 China

Potassium sulphate powder (sop) 100 Mts 4035455 Taiwan

Potassium sulphate(00:00:50) 100%water soluble fertilizer,( 25 Mts 1098059 Jordan

Potassium sulphate(00-00-50)100%water soluble fertilizer 50 Mts 2341180 Jordan

Silicone in primary forms 6000 Kgs 617300 Thailand

Silicone in primary forms 2340 Kgs 268870 Thailand

Silver nitrate solution 664.259 Kgs 3524871 Germany

Silver nitrate solution 1356 Kgs 7139440 Germany

Silver nitrate solution 1356 Kgs 7294598 Germany

Silver nitrate solution(25% w/v silver nitrate) 1339.56 Kgs 7108325 Germany

Silver nitrate solution(25%w/v silver nitrate) 708.182 Kgs 3757947 Germany

Sodium bicarbonate 110 Mts 1796487 China

Sodium bicarbonate 61737.5 Kgs 859328.1 China

Sodium bicarbonate 26014.3 Kgs 362094.7 China

Sodium bicarbonate 20248.2 Kgs 281836 China

Sodium bicarbonate 110 Mts 1814085 China

Sodium bicarbonate 44165 Kgs 588020.5 China

Sodium bicarbonate 23335 Kgs 310686.3 China

Sodium bicarbonate 110 Mts 1814085 China

Sodium bicarbonate 27.5 Mts 472702.7 China

Sodium bicarbonate 13620.7 Kgs 215667.2 China

Sodium bicarbonate 73768.7 Kgs 1168037 China

Sodium bicarbonate 42909.6 Kgs 679421.2 China

Sodium bicarbonate 15156.6 Kgs 239986.8 China

Sodium bicarbonate 43544.3 Kgs 689470.1 China

Sodium bicarbonate 150 Mts 2398376 China

Sodium bicarbonate 150 Mts 2398376 China

Sodium bicarbonate 55000 Kgs 888036.2 China

Sodium bicarbonate 55 Mts 945405.5 China

Sodium carbonate dense 400000 Kgs 6314760 China

Sodium carbonate dense 125.78 Mts 2154076 Romania

Sodium carbonate dense 2.01 Mts 34422.8 Romania

Sodium carbonate dense 2.01 Mts 34422.8 Romania

Sodium carbonate dense 36.21 Mts 620123.2 Romania

Sodium carbonate dense 750000 Kgs 11823447 China

Sodium carbonate dense 500000 Kgs 7762860 Italy

Sodium carbonate dense 434666 Kgs 6748503 Bulgaria

Sodium carbonate dense 650 Kgs 10091.72 Bulgaria

Sodium carbonate dense 63434 Kgs 984858.5 Bulgaria

Sodium carbonate dense 500000 Kgs 7525384 Bulgaria

Sodium carbonate dense 500000 Kgs 7525384 Bulgaria

Sodium carbonate dense 500000 Kgs 7762860 Italy

Sodium carbonate dense 300000 Kgs 4657716 Italy

Sodium carbonate dense (soda ash) 495000 Kgs 7107850 Kenya

Sodium chlorate fc08 bb 115 Mts 4888754 Finland

Sodium chlorate fc08 bb 115 Mts 4888754 Finland

Sodium percarbonate coated 15 Mts 508282.5 China

Sodium percarbonate tablet 9 Mts 343783.8 China

Sodium tripolyphosphate 58822.8 Kgs 3389876 Russia

Sodium tripolyphosphate 559.7 Kgs 32254.72 Russia

Sodium tripolyphosphate 3792.48 Kgs 218555.2 Russia

Sodium tripolyphosphate 56475 Kgs 3254573 Russia

Sodium tripolyphosphate (stpp na5p3o10) white dense. 92 Mts 5181596 Tunisia

Sodium tripolyphosphate 94 pcnt 50 Mts 2988085 China

Titanium dioxide 180 Kgs 187004 Germany

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UNIT

VALUE IN

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CHEMICALS IMPORTED

Titanium dioxide rutile 15 Mts 2412638 Saudi arabia

Titanium dioxide rutile 10 Mts 1608425 Saudi arabia

Titanium dioxide rutile 5 Mts 800930 Saudi arabia

Titanium dioxide rutile 20 Mts 3216850 Saudi arabia

Titanium dioxide rutile 10 Mts 1601860 Saudi arabia

Titanium dioxide rutile 8000 Kgs 1286861 Australia

Titanium dioxide rutile 20000 Kgs 3265330 Australia

Titanium dioxide rutile 4000 Kgs 643430.6 Australia

Titanium dioxide rutile 20000 Kgs 3305478 Australia

Titanium dioxide rutile 7000 Kgs 1167606 Australia

Titanium dioxide rutile 7000 Kgs 1167606 Australia

Titanium dioxide rutile 6000 Kgs 1000805 Australia

Titanium dioxide rutile 240000 Kgs 4.3E+07 Taiwan

Titanium dioxide rutile 200000 Kgs 3.5E+07 Taiwan

Titanium dioxide rutile 20000 Kgs 2697205 China

Titanium dioxide rutile 20000 Kgs 2697205 China

Titanium dioxide rutile 60 Mts 1E+07 Australia

Titanium dioxide rutile 60 Mts 10063675 Australia

Titanium dioxide rutile 40 Mts 6616914 Australia

Titanium dioxide rutile blr-699 graco:pt0665 20000 Kgs 2592039 China

Titanium dioxide rutile blr-699 graco:pt0665 20000 Kgs 2592039 China

Titanium dioxide rutile blr-699 graco:pt0665 20000 Kgs 2592039 China

Titanium dioxide rutile blr-699 graco:pt0665 20000 Kgs 2581459 China

Titanium dioxide rutile blr-699 graco:pt0665 20000 Kgs 2581459 China

Titanium dioxide rutile blr-699 graco:pt0665 20000 Kgs 2581459 China

Titanium dioxide rutile blr-699 graco:pt0665 20000 Kgs 2581459 China

Titanium dioxide rutile ti pure r900 20000 Kgs 3588025 Taiwan

Titanium dioxide rutile tioxide 5000 Kgs 749622 Malaysia

Titanium dioxide rutile tioxide 10045 Kgs 1739945 Malaysia

Titanium dioxide rutile tioxide 20000 Kgs 3450160 Malaysia

Titanium dioxide rutile ti-pure r104 1000 Kgs 191208.2 USA

Titanium dioxide rutile ti-pure r-104 20000 Kgs 3868704 USA

Titanium dioxide rutile ti-pure r-105 10000 Kgs 1873904 Singapore

Titanium dioxide rutile ti-pure r-105 10000 Kgs 1873904 Singapore

Titanium dioxide rutile tipure r706 60000 Kgs 1.2E+07 Taiwan

Titanium dioxide rutile tipure r706 40000 Kgs 7639640 Taiwan

Titanium dioxide rutile tipure r900 20000 Kgs 3573380 Taiwan

Titanium dioxide rutile ti-pure r931 60000 Kgs 10764075 USA

Titanium dioxide rutile ti-pure r931 40000 Kgs 7146760 USA

Titanium dioxide rutile ti-pure r931 40000 Kgs 7146760 USA

Titanium dioxide rutile ti-pure r931 40000 Kgs 7146760 USA

Titanium dioxide rutile type r-60 20000 Kgs 2765999 China

Titanium dioxide tio2 off grade 20133 Kgs 2967185 Singapore

Tricalcium phosphate 8250 Kgs 1080604 Germany

Tricalcium phosphate - c 13-09 6750 Kgs 993960.8 Germany

Trisodium phosphate - n 13-01 1050 Kgs 84569 Germany

Trisodium phosphate - n 13-01 1050 Kgs 84569.04 Germany

Trisodium phosphate technical grade 25 Mts 492880 China

Zinc phosphate 1000 Kgs 97593.32 Korea

Zinc phosphate 250 Kgs 24398.2 Korea

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CHEMICALS IMPORTED

CATEGORY: DRUGS

9-deoxo-9a-aza-hemoerythromycin 1000 Kgs 4639688 China

9-deoxo-9a-aza-hemoerythromycin 3450 Kgs 20595573 China

9-deoxo-9a-aza-hemoerythromycin 500 Kgs 2972683 China

Ac-di-sol sd-711 nf i (croscarmellose sodium) 2000 Kgs 1538212 Ireland

Avilamycin 10600 Kgs 9122244 United kingdom

Azithromycin ip 500 Kgs 2822477 China

Azithromycin ip/usp 875 Kgs 5402143 China

Azithromycin ip/usp 675 Kgs 4167367 China

Azithromycin ip/usp 200 Kgs 1234776 China

Azithromycin ip/usp 600 Kgs 3770532 China

Azithromycin ip/usp 1000 Kgs 6284220 China

Ceftriaxone sodium ( non sterile) 3000 Kgs 12143331 China

Ceftriaxone sodium ( non sterile) 7000 Kgs 2.8E+07 China

Chloroform(trichloromethane) 46.4 Mts 1143482 Russia

Crosscarmellose sodium/primellose/ usp.nf.ph.eur.jp 1890 Kgs 1614500 Netherlands

D-calcium pantothenate feed grade - 1350 Kgs 1348757 China

D-calcium pantothenate bp/usp/ip 3000 Kgs 2023131 China

Erythromycin stearate bp 1600 Kgs 4337344 Thailand

Erythromycin stearate bp 2400 Kgs 6506016 Thailand

Kollidon (r) 25 (polyvinyl pyrrolidone) 2000 Kgs 2182863 USA

Kollidon (r) 30 (polyvinyl pyrrolidone) 5000 Kgs 4927033 USA

Kollidon 30 ( polyvinylpyrrolidone ) 6000 Kgs 6099390 USA

Lincomycin hcl 11% premix 10000 Kgs 4348934 China

Lincomycin hcl 11% premix( 10000 Kgs 4596384 China

Lincomycin hcl 11% premix( 10000 Kgs 4348934 China

Lincomycin hydrochloride 2300 Bou 9467387 China

Maduramycin-0.75% and nicarbazin-8% animal feed supplement(zamax) 16000 Kgs 2078580 China

Metamizole sodium ep 7.0/analgin 10000 Kgs 5298460 China

Naproxen sodium 2600 Kgs 6112015 China

Paracetamol b.p 34000 Kgs 7813380 China

Paracetamol bp 102000 Kgs 24356504 China

Paracetamol bp 51000 Kgs 12128545 China

Paracetamol bp 17000 Kgs 3854322 China

Paracetamol bp/ep 51000 Kgs 12128545 China

Paracetamol bp/usp 16 Mts 3781965 China

Penicillin g potassium first crystal 25000 Kgs 20290900 China

Penicillin g potassium first crystal 25000 Kgs 2E+07 China

Penicillin g potassium first crystal 47475 Kgs 36503926 China

Penicillin g potassium first crystal 50000 Kgs 40913080 China

Penicillin g potassium first crystal 47475 Kgs 36952744 China

Penicillin v potassium compacted ep 1825 Kgs 4627094 Slovak republic

Penicillin v potassium ip 1050 Kgs 2280658 Australia

Penicillin v potassium ip 2950 Kgs 6407564 Australia

Phenoxy methyl penicillin potassium 1650 Kgs 2948039 China

Plasdone k-29/32 (povidone k 30) (polyvinyl pyrollidine) 3942.1 Kgs 3164632 USA

Plasdone k-29/32 (povidone k 30) (polyvinyl pyrollidine) 4041.9 Kgs 3244750 USA

Plasdone k-90 (povidone 90d) (polyvinyl pyrrolidone) 2994 Kgs 2789040 USA

Poly vinyl poly pyrrolidone (pvpp) 2820 Kgs 825266 Canada

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CHEMICALS IMPORTED

Poly vinyl poly pyrrolidone (pvpp) 2820 Kgs 825266 Canada

Polyplasdone xl (crospovidone) (polyvinyl pyrrolidone) 1996 Kgs 2020456 USA

Polyvinyl pyrrolidone k-90(pvp k-90) 7920 Kgs 7221678 Canada

Polyvinyl pyrrolidone k-90(pvp k-90) 7110 Kgs 6483097 Canada

Polyvinyl pyrrolidone k-90(pvp k-90) 7920 Kgs 7221678 Canada

Polyvinyl pyrrolidone k-90(pvp k-90) 7110 Kgs 6483097 Canada

Primellose croscarmellose sodium usp/nf 8820 Kgs 8131405 Germany

Pvp k 30 usp 36 (polyvinyl pyrolidone) 16000 Kgs 7868910 China

Pvpp (polyvinyl poly pyrrolidone) 10710 Kgs 3177929 Canada

Pyrrolidine pure,adc list no:1332 2720 Kgs 1040172 Germany

Pyrrolydine 5100 Kgs 2188660 Netherlands

Resorcinol 16000 Kgs 5076664 Japan

Resorcinol 5043 Kgs 1620098 Japan

Resorcinol 10957 Kgs 3520012 Japan

Resorcinol (1,3-dihydroxybenzene) 1000 Kgs 294893.2 Japan

Resorcinol (1,3-dihydroxybenzene) 5000 Kgs 1474433 Japan

Resorcinol (1,3-dihydroxybenzene-) 7000 Kgs 2004964 Japan

Resorcinol (1,3-dihydroxybenzene-) 9000 Kgs 2577810 Japan

Sodium starch glycolate 3000 Kgs 831735 Taiwan

Sodium starch glycolate 1000 Kgs 277245 Taiwan

Sodium starch glycolate 3000 Kgs 831735 Taiwan

Sodium starch glycolate (explosol a) 1440 Kgs 413982.7 Brazil

CATEGORY: DYESTUFF

3402-ca (liquid dyes) 120 Kgs 82129.86 Spain

Alpalux w arancio ( liquid dyes) 200 Kgs 130783.6 Italy

Alpalux w blu ( liquid dyes) 150 Kgs 87007.21 Italy

Alpalux w bordeaux ( liquid dyes) 150 Kgs 91414.24 Italy

Alpalux w bruno ( liquid dyes) 200 Kgs 130783.6 Italy

Alpalux w nero ( liquid dyes) 300 Kgs 101487.4 Italy

Alpalux w verde ( liquid dyes) 50 Kgs 31436.76 Italy

Avival arancio (liquid dyes) 25 Kgs 21659.94 Italy

Avival blu brillante (liquid dyes) 25 Kgs 26544.04 Italy

Avival bruno (liquid dyes) 50 Kgs 42470.46 Italy

Avival giallo (liquid dyes) 25 Kgs 20173.47 Italy

Avival nero (liquid dyes) 25 Kgs 12741.14 Italy

Avival verde (liquid dyes) 25 Kgs 18474.65 Italy

Dianix orange un-se 01 ( dyes) 100 Kgs 69619.3 Singapore

Dianix red cc ( dyes) 50 Kgs 98267.95 Singapore

Dianix royal blue cc ( dyes) 50 Kgs 77012.5 Singapore

Levafix brilliant yellow ca gran (dyes) 200 Kgs 301889 Singapore

Miketon p black pbsf u/c ( dyes) 200 Kgs 138006.4 Singapore

Moderlan dark brown b (dyes) 1350 Kgs 1269236 Thailand

Modernil black jet (dyes) 2700 Kgs 1987356 Thailand

Modernil black nat conc (dyes) 2025 Kgs 1490517 Thailand

Moderzol black ecr (dyes) 675 Kgs 663843.6 Thailand

Nero hdm (dyes) 4000 Kgs 4042076 Italy

Solve 47 b [ liquid dyes ] 100 Kgs 76610.92 Italy

Hv nero conc [ liquid dyes ] 300 Kgs 209180.3 Italy

Nero hdm (dyes) 4000 Kgs 4042076 Italy

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CHEMICALS IMPORTED

CATEGORY: FABRIC, FIBRE & YARN

Nylon 6 chips ( zisamide pa6 chips) tp4407 bright b grade 16000 Kgs 2308193 Taiwan

Nylon 6 chips ( zisamide pa6 chips) tp6603 bright a grade 45000 Kgs 7018844 Taiwan

Nylon 6 chips (zisamide pa6 chips) 8 Mts 1158599 Taiwan

Nylon 6 chips (zisamide pa6 chips) 8 Mts 1158599 Taiwan

Nylon 6 chips tp6603 bright a grade ( zisamide pa6 chips) 9000 Kgs 1422940 Taiwan

Nylon 6 chips tp6603 bright a grade ( zisamide pa6 chips) 250 Kgs 39526.1 Taiwan

Nylon 6 chips tp6603 bright a grade ( zisamide pa6 chips) 10000 Kgs 1581044 Taiwan

Nylon 6 chips tp6603 bright a grade ( zisamide pa6 chips) 10000 Kgs 1581044 Taiwan

Nylon 6 chips tp6603 bright a grade ( zisamide pa6 chips) 15750 Kgs 2490145 Taiwan

Nylon 6 chips- zisamide pa6 chips tp4407 bright a grade 12000 Kgs 1855693 Taiwan

Nylon 6 chips- zisamide pa6 chips tp4407 bright a grade 3000 Kgs 463923.3 Taiwan

Nylon 6 chips- zisamide pa6 chips tp4407 bright a grade 15 Mts 2319617 Taiwan

CATEGORY: METAL

Aluminium alloy ingots rdl rm 01 25000 Kgs 3712003 Malaysia

Bismuth ingot 209 Kgs 298221.3 Korea

Bismuth ingot 2.5 Kgs 3567.16 Korea

Bismuth ingot 760.3 Kgs 1084869 Korea

Bismuth ingot 3 Kgs 4280.96 Korea

Calcium metal 10 Mts 2332216 China

Calcium metal (ca : 98.57%; size : 50-150mm (90% min.) 10 Mts 2322697 China

Calcium metal (ca: 98.5%min, size: 50-150mm) 10 Mts 2350775 China

Calcium metal (ca: 98.5%min, size: 50-150mm) 10 Mts 2350775 China

Calcium metal (ca: 98.5%min, size: 50-200mm) 10 Mts 2354209 China

Calcium metal (ca: 98.5%min, size: 50-200mm) 10 Mts 2354209 China

Calcium metal granule 5250 Kgs 1455556 China

Calcium metal granules 1200 Kgs 300112.4 China

Pure lead 99.97% min in ingots 178.605 Mts 25943127 Australia

Pure lead 99.97% min in ingots 75.112 Mts 10910334 Australia

Pure lead 99.97% min in ingots 14.814 Mts 2151796 Australia

Pure lead 99.97% min in ingots 110 Mts 15977962 Australia

Remelted lead ingots 143.3 Mts 17815637 UAE

Remelted lead ingots 142.82 Mts 17755961 UAE

Silicon metal 25000 Kgs 3459250 China

Silicon metal 553 grade 48 Mts 6339669 China

Silicon metal 441 grade 24 Mts 3281187 China

Sodium metal 12000 Kgs 1558935 China

Sodium metal 12000 Kgs 1570458 China

Sodium metal 12000 Kgs 1558935 China

Sodium metal 12000 Kgs 1552572 China

Sodium metal 12000 Kgs 1552572 China

Sodium metal 12000 Kgs 1558935 China

Sodium metal 12000 Kgs 1570458 China

Sodium metal 12000 Kgs 1558935 China

Sodium metal 12000 Kgs 1552572 China

Sodium metal 12000 Kgs 1552572 China

Sodium metal 12000 Kgs 1558935 China

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VALUE IN

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CHEMICALS IMPORTED

Sodium metal 12000 Kgs 1570458 China

Sodium metal 12000 Kgs 1558935 China

Sodium metal 12000 Kgs 1552572 China

Sodium metal 12000 Kgs 1552572 China

Sodium metal (2kg ingots) 18600 Kgs 2410383 China

Sodium metal (2kg ingots) 18600 Kgs 2410383 China

Sodium metal (2kg ingots) 18600 Kgs 2410383 China

Sodium metal (2kg ingots) 18600 Kgs 2410383 China

Sodium metal (2kg ingots) 18600 Kgs 2410383 China

Sodium metal (2kg ingots) 18600 Kgs 2410383 China

Zinc ingots [lme rged high grade 99.95%] 24.636 Mts 4018302 Australia

CATEGORY: PAINT

3102-ca (pigment) 30 Kgs 28489.06 Spain

3103-ca (pigment) 30 Kgs 27092.54 Spain

3104-ca (pigment) 30 Kgs 33516.54 Spain

3106-ca (pigment) 30 Kgs 36817.41 Spain

3107-ca (pigment) 30 Kgs 39407.33 Spain

3136-ca (pigment) 30 Kgs 60177.43 Spain

3138-ca (pigment) 30 Kgs 74625.09 Spain

9125-pc ( pigment) 240 Kgs 54616.87 Spain

9201 pc (pigments) 975 Kgs 333071.5 Spain

Bayferrox 4910(iron oxide pigment) 3200 Kgs 268915.5 China

Bayferrox 4910(iron oxide pigment) 3200 Kgs 268915.5 China

Bayferrox 4910(iron oxide pigment) 3200 Kgs 272221.9 China

Bayferrox red 4125(iron oxide pigment 4000 Kgs 342798.3 China

Bayferrox red 4125(iron oxide pigment 4000 Kgs 342798.3 China

Bayferrox red 4125(iron oxide pigment 5000 Kgs 433765.6 China

Bayferrox red 4130(iron oxide pigment) 3000 Kgs 258207.4 China

Bayferrox red 4130(iron oxide pigment) 3000 Kgs 258207.4 China

Bayferrox red 4130(iron oxide pigment) 3000 Kgs 261382.1 China

Bayferrox red 4140(iron oxide pigment) 3000 Kgs 275581.7 China

Bayferrox red 4140(iron oxide pigment) 3000 Kgs 275581.7 China

Bayferrox red 4140(iron oxide pigment) 2000 Kgs 185980 China

Bayferrox yellow 4920(iron oxide pigment 4800 Kgs 382080.3 China

Bayferrox yellow 4920(iron oxide pigment 4800 Kgs 382080.3 China

Catiofin black cc liq(pigments) 150 Kgs 35389.64 Italy

Colanyl yellow h3g 500 (pigments) 360 Kgs 419860 Germany

Colanyl yellow h3g 500 (pigments) 510 Kgs 594801.4 Germany

Cra56427 (raw materials for manufacturers of paint) 1140 Kgs 192445 Korea

Cresablanc rhe ( white pigments for textile ) 2030 Kgs 546802.1 Spain

Cresablanc rx ( white pigments for textile )( 420 Kgs 128941.8 Spain

Cresablanc us 2005 ( white pigments for textile ) 2800 Kgs 608989.3 Spain

Cresablanc us 2005 ( white pigments for textile ) 195 Kgs 37028.72 Spain

Crt00848 (raw materials for manufacturers of paint) 1900 Kgs 311376.9 Korea

Duasyn fluoreszent - m009181)(3 can) (pigments) 2 Kgs 8733.83 Korea

Ecopaque yellow 12 105 (pigment) 105 Kgs 209287 Germany

Emulter 2000e waterborne anti-corrosion paint 720 Kgs 402520.8 Japan

Ferric oxide pigment 110e (iron oxide) 6.25 Mts 413009.7 China

Ferric oxide pigment 120e (iron oxide) 6.25 Mts 413009.7 China

Ferric oxide pigment 130e (iron oxide) 6.25 Mts 413009.7 China

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CHEMICALS IMPORTED

Ferric oxide pigment 190-2 (iron oxide) 6.25 Mts 413009.7 China

Gold pearl pigment lb 300 (100 drums) 2500 Kgs 1055071 China

Irgazin red k 3840 sq ( old cromophtal red 1030-p ) (pigment) 1000 Kgs 1108980 USA

Isopur black pigment paste 400 Kgs 134104 Germany

Isopur- black pigment paste 180 Kgs 109721.8 Germany

Isopur- comp a-pigment paste 300 Kgs 195670.5 Germany

Ke - color - bl ( pigment ) ) 10 Kgs 38482.73 Japan

Ke - color - br ( pigment ) ) 10 Kgs 38482.73 Japan

Ke-color - w pigment 10 Kgs 38482.73 Japan

L-520ar aluminum paste (14dd13553) (pigment) 60 Kgs 38517.72 USA

Lemon gold pearl pigment lb 353 b 2000 Kgs 844057 China

Neosan 2000 black liq (pigments) 2640 Kgs 440296 Italy

Neosan 2000 black liq (pigments) 2670 Kgs 445299.3 Italy

Neosan 2000 blue liq ( pigments ) 240 Kgs 65995.58 Italy

Neosan 2000 citron liq(pigments) 120 Kgs 117151.9 Italy

Neosan 2000 light brown liq 0040 (pigments) 120 Kgs 19232.44 Italy

Neosan 2000 magenta liq (pigments) 330 Kgs 321630.8 Italy

Neosan 2000 red brown liq 0040(pigments) 160 Kgs 34624.9 Italy

Neosan lucido deep black liq 0030(pigments) 60 Kgs 21477.85 Germany

Nero 6n pigment 540 Kgs 155857.6 Italy

Paint (finished paint) (pu9350) 93 Ltr 43488.65 Korea

Paint (finished paint) (pu9350q) 15120 Kgs 3409448 Korea

Pa-tcr3080 aluminum paste (pa-52-4688) (pigment) 124.74 Kgs 272636 USA

Perrindo violet v4050 (7p53-9951) (pigment) 36.287 Kgs 53773.2 USA

Phthalo blue (25l52-1588) (pigment) 108.862 Kgs 64078.78 USA

Pigment red 3bl 300 Kgs 1192523 China

Pigments (k-pigment ochre) 300 Kgs 49059.47 Italy

Powder coating paint (ex8816-tribogrey) 2000 Kgs 437431 Korea

Pp-25-824 (60) (camotex) (pigments) 60 Kgs 8544.71 Singapore

Pp-25-824 (60) (camotex) (pigments) 840 Kgs 119845 Singapore

Pp-25-824 (60) (camotex) (pigments) 840 Kgs 119845 Singapore

Pp-25-824 (60) (camotex) (pigments) 2280 Kgs 325293.5 Singapore

Pp-25-824 (60) (camotex) (pigments) 86 Kgs 12269.84 Singapore

Pp-25-824 (60) (camotex) (pigments) 83 Kgs 11841.82 Singapore

Pp-25-824 (60) (camotex) (pigments) 1271 Kgs 181336.9 Singapore

Pp-25-824 (60) (camotex) (pigments) 60 Kgs 15863.6 Singapore

Pp-25-824 (60) (camotex) (pigments) 120 Kgs 17120.71 Singapore

Pp-25-832 (10) (camotex)(pigments) 10 Kgs 1802.56 Singapore

Pp-25-832 (10)(camotex) (pigments) 10 Kgs 1802.56 Singapore

Pp-25-832 (10)(camotex) (pigments) 10 Kgs 1712.93 Singapore

Pp-25-884(60)(comotex) (pigment) 120 Kgs 25740.93 Singapore

Pp-25-884(60)(comotex) (pigment) 120 Kgs 25740.93 Singapore

Pp-25-884(60)(comotex) (pigment) 240 Kgs 51481.86 Singapore

Pp-25-884(60)(comotex) (pigment) 1080 Kgs 231668.4 Singapore

Pp-25-884(60)(comotex) (pigment) 120 Kgs 25740.93 Singapore

Pp-25-884(60)(comotex) (pigment) 1140 Kgs 244538.8 Singapore

Pp-39-126 camotex(pigments) 540 Kgs 182207.1 Netherlands

Pp marine a pa(pigments) 30 Kgs 11153.84 Italy

Roda cor ni black 14 (pigment) 30 Kgs 30230.5 Italy

Roda kp black super (pigment) 360 Kgs 94891.67 Italy

Roda kp brown (pigment) 30 Kgs 10396.6 Italy

Roda kp red (pigment) 30 Kgs 28674.91 Italy

Roda lite black 07 (pigment) 150 Kgs 30593.49 Italy

Roda lite white 07 (pigment) 70 Kgs 25166.17 Italy

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NAME OF THE CHEMICAL

QTY

UNIT

VALUE IN

RS.

COUNTRY

CHEMICALS IMPORTED

Solaris bianco (pigment) 250 Kgs 62506.86 Italy

Soleda iride caramel (pigment) 120 Kgs 21002.3 Italy

Soleda k arancio (pigment) 120 Kgs 49505.43 Italy

Soleda k bianco (pigment) 240 Kgs 65207.15 Italy

Soleda k bruno scuro (pigment) 240 Kgs 62606.87 Italy

Soleda k nero es (pigment) 450 Kgs 96760.61 Italy

Soleda k ocra (pigment) 180 Kgs 45905.04 Italy

Soleda k scarlatto (pigment) 60 Kgs 47755.24 Italy

Soleda k verde (pigment) 30 Kgs 17001.86 Italy

Soleda k violetto (pigment) 30 Kgs 40879.48 Italy

Soleda lux bordo (pigment) 300 Kgs 128514.1 Italy

Soleda lux brown (pigment) 300 Kgs 47505.21 Italy

Soleda lux dark brown (pigment) 120 Kgs 25002.74 Italy

Soleda lux fuxia (pigment) 120 Kgs 69907.67 Italy

Soleda lux lemon (pigment) 300 Kgs 73758.09 Italy

Soleda lux orange (pigment) 150 Kgs 58756.45 Italy

Soleda lux red (pigment) 150 Kgs 51505.65 Italy

Sp k top nero extra (pigment) 600 Kgs 109873.1 Italy

Sp k top nero extra(pigments) 90 Kgs 19917.9 Italy

Sparkle silver premier 354 aluminum paste ( (pigment) 460 Kgs 473123.9 USA

Sparkle silver premier 354 aluminum paste) (pigment) 40 Kgs 41141.21 USA

Sparkle silver premier 554 aluminum paste (pigment) 400 Kgs 483278 USA

Special black 2611(pigments) 75 Kgs 17815.88 Italy

Spk top ocra (pigments) 60 Kgs 21020.18 Italy

Titanium dioxide pigmental grade rutile 10000 Kgs 1302468 Ukraine

Titanium dioxide pigmental grade rutile 10000 Kgs 1302468 Ukraine

Titanium dioxide rutile tioxide tr92 (pigments) 10045 Kgs 1739945 Malaysia

Titanium dioxide rutile tioxide tr92 (pigments) 10000 Kgs 1725080 Malaysia

Titanium dioxide rutile tioxide tr92 (pigments) 5000 Kgs 749622 Malaysia

Titanium dioxide rutile tioxide tr92 (pigments) 20090 Kgs 3479889 Malaysia

Tpk black (pigment) 180 Kgs 28812.8 Italy

Ultramarine blue ep-25(inorganic pigments) 500 Kgs 117810 Romania

Vc blacks [ pigment] 900 Kgs 157342 Italy

Vc white [ pigment ] 60 Kgs 16253.5 Italy

Violet 23 (29p46-8067) (pigment) 206.838 Kgs 94840.04 USA

Yellow oxide 920(iron oxide pigment) 4800 Kgs 305351.6 China

Yellow primer tint (54s8821) (pigment) 54.431 Kgs 20294.49 USA

CATEGORY: PLASTIC

Bi axially oriented polypropylene film 1232.88 Kgs 250660.5 Australia

Expanded polypropylene beads ( arpro5118-45p w ) 707 Kgs 253673.4 Singapore

Expanded polypropylene beads ( arpro5237-15p w) 1089.2 Kgs 350379.3 Singapore

Expanded polypropylene beads (arpro5118-45p w) 1134 Kgs 405221.3 Singapore

Expanded polypropylene beads (arpro5118-45p w) 563.5 Kgs 201360 Singapore

Hdpe (high density polyethylene) u050 10000 Kgs 1288265 Korea

Hdpe (high density polyethylene) u050 10000 Kgs 1288265 Korea

Hdpe black blow grade extruder 24910 Kgs 1543556 Kuwait

Hdpe blue reprocess granules 50000 Kgs 4127870 Taiwan

Hdpe borstar mb6561 1.375 Mts 139777.7 UAE

Hdpe borstar mb6561 1.375 Mts 139777.7 UAE

Hdpe granules grade 6888 24750 Kgs 2531247 Qatar

Hdpe granules grade 6888 15604 Kgs 1595862 Qatar

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UNIT

VALUE IN

RS.

COUNTRY

CHEMICALS IMPORTED

Hdpe granules grade 6888 9146 Kgs 935385.2 Qatar

Hdpe granules grade hta001hd 17000 Kgs 1696739 Saudi arabia

Hdpe nature reprocess granules 25000 Kgs 2187155 Taiwan

Hdpe recycled granules 17 Mts 1109775 Malaysia

Hdpe reprocess granuels 24.92 Mts 1613797 Kuwait

Hdpe reprocess granuels 24.79 Mts 1605407 Kuwait

High density polyethylene (hdpe) - borstar he3366 16500 Kgs 1657001 UAE

High density polyethylene (hdpe) - borstar he6062 11000 Kgs 1121610 UAE

High density polyethylene (marlex hhm 5502 bn) (hdpe granules) 69300 Kgs 6964097 Saudi arabia

High density polyethylene (marlex hhm 5502 bn) (hdpe granules) 10700 Kgs 1075265 Saudi arabia

High density polyethylene grade: f00851 49500 Kgs 4977102 Saudi arabia

High density polyethylene grade: fi0750 49500 Kgs 4977102 Saudi arabia

High density polyethylene grade: fi0750 24750 Kgs 2519658 Saudi arabia

High density polyethylene granules h5604f film prime grade 18.25 Mts 1922694 Thailand

High density polyethylene hb111r 25900 Kgs 3210886 Japan

High density polyethylene hb111r 25900 Kgs 3210886 Japan

High density polyethylene marlex hxm 50100 32000 Kgs 3214752 Qatar

High density polyethylene marlex hxm tr-571 48 Mts 4880262 Qatar

High density polyethylene marlex hxm tr-571 48 Mts 4880262 Qatar

High density polyethylene marlex hxm tr-571 48 Mts 4880262 Qatar

High density polyethylene marlex hxm tr-571 48000 Kgs 4910878 Qatar

High density polyethylene marlex hxm tr-571 48 Mts 4880262 Qatar

High density polyethylene marlex hxm tr-571 48 Mts 4880262 Qatar

High density polyethylene marlex hxm tr-571 48 Mts 4880262 Qatar

High density polyethylene marlex hxm tr-571 48000 Kgs 4910878 Qatar

High density polyethylene marlex hxm tr-571 48000 Kgs 4910878 Qatar

Ldpe granules grade 2427k 48000 Kgs 5022349 Saudi arabia

Ldpe granules grade 955 35000 Kgs 3913775 Korea

Ldpe granules) low density polyethylene grade: d777c( 17250 Kgs 1991902 Thailand

Ldpe lotrene fb5026 16500 Kgs 1765865 Qatar

Ldpe reprocessed granules 135 Mts 8750820 Malaysia

Ldpe reprocessed granuls 32 Mts 2051879 Malaysia

Ldpe reprocessed plastic granules 27.5 Mts 1745103 Malaysia

Ldpe sabic hp 2023n 49500 Kgs 5037596 Saudi arabia

Ldpe sabic hp0823j 6.875 Mts 723018 Saudi arabia

Ldpe sabic hp0823n 8.25 Mts 862517.9 Saudi arabia

Ldpe sabic hp2023n 148.5 Mts 14913009 Saudi arabia

Ldpe sabic hp4024w 9.625 Mts 994362.4 Saudi arabia

Linear low density polyethylene 24700 Kgs 2891357 Sweden

Linear low density polyethylene 33 Mts 3395327 UAE

Linear low density polyethylene 12000 Kgs 1588885 China

Linear low density polyethylene 8000 Kgs 1069832 China

Low density polyethylene 24.75 Mts 2500750 Spain

Linear low density polyethylene 16.5 Mts 1776072 Singapore

Linear low density polyethylene 16.5 Mts 1776072 Singapore

Linear low density polyethylene 16.5 Mts 1768823 Singapore

Linear low density polyethylene 16.5 Mts 1776072 Singapore

Linear low density polyethylene (lldpe sabic 118w) 16.5 Mts 1697664 Saudi arabia

Linear low density polyethylene (lldpe sabic 118w) 16.5 Mts 1697664 Saudi arabia

Linear low density polyethylene (lldpe) grade 4800 Kgs 839589 Italy

Linear low density polyethylene (lldpe)'lotrene'q1018h 51750 Kgs 5324490 Qatar

Linear low density polyethylene (lldpe0 lotrene q1018n ( 34.5 Mts 3528405 Qatar

Linear low density polyethylene grade: 48000 Kgs 5270091 Singapore

Lldpe 118w 16.5 Mts 1717995 Saudi arabia

Lldpe borstar fb1350 13.75 Mts 1423191 UAE

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UNIT

VALUE IN

RS.

COUNTRY

CHEMICALS IMPORTED

Lldpe borstar fb1370 1.375 Mts 140624.8 UAE

Lldpe enable 3505hh 24.75 Mts 2805719 Singapore

Lldpe exceed 1018ha 24.75 Mts 2836216 Singapore

Lldpe exceed 1018ha (ethylene copolymers) 15.125 Mts 1723925 Singapore

Lldpe exceed 1018ka 15.125 Mts 1723925 Singapore

Lldpe exceed 1018ka 49.5 Mts 5672433 Singapore

Lldpe exceed 1018ka 15.125 Mts 1723925 Singapore

Lldpe exceed 1018ka 15.125 Mts 1723925 Singapore

Lldpe exceed 1018ka (ethylene copolymers) 15.125 Mts 1723925 Singapore

Lldpe exceed 1018ka (ethylene copolymers) 10.872 Mts 1239174 Singapore

Lldpe exceed 1018ka (ethylene copolymers) 4.253 Mts 484750.6 Singapore

Lldpe exceed 2018kb 15.125 Mts 1733243 Singapore

Lldpe exxonmobil ll1001kw 72 Mts 7750134 Singapore

Lldpe recycled granules 25 Mts 1587300 Thailand

Lldpe recycled granules 27 Mts 1742565 Malaysia

Lldpe recycled granules 54 Mts 3528651 Malaysia

Lldpe recycled granules 28 Mts 1812379 Vietnam

Lldpe recycled granules 54 Mts 3481956 Malaysia

Lldpe recycled granules 26 Mts 1676616 Thailand

Linear low density polyethylene 24.75 Mts 2592453 Saudi arabia

Linear low density polyethylene 49500 Kgs 5194850 Saudi arabia

Linear low density polyethylene 8.75 Mts 918481.8 Saudi arabia

Linear low density polyethylene 16500 Kgs 1738714 Saudi arabia

Linear low density polyethylene 16500 Kgs 1738714 Saudi arabia

Linear low density polyethylene 16500 Kgs 1738714 Saudi arabia

Low density polyethylene 16500 Kgs 1758657 Qatar

Low density polyethylene 17250 Kgs 1803447 Qatar

Low density polyethylene 24750 Kgs 2592241 Saudi arabia

Nylon-6 chips bright high density a grade afc-3003s( 19 Mts 3195711 Thailand

Linear Low density polyethylene 33 Mts 2095612 Thailand

High density polyethylene 33 Mts 3364830 UAE

Linear low density polyethylene 33 Mts 3537646 Singapore

Linear low density polyethylene 33 Mts 3572559 Singapore

Polypropylene 6000 Kgs 909363.6 Thailand

Polypropylene 3000 Kgs 577039.3 Thailand

Polypropylene co polymers 120 Mts 12819809 Singapore

Polypropylene copolymers 15822 Kgs 1690292 Singapore

Polypropylene copolymers 32178 Kgs 3437632 Singapore

Polypropylene 24750 Kgs 2500750 UAE

Polypropylene 7500 Kgs 726488 Korea

Polypropylene 30000 Kgs 1859918 Thailand

Polypropylene 16500 Kgs 1641752 UAE

Polypropylene 6875 Kgs 711595.5 UAE

Polypropylene 1275 Kgs 131968.6 UAE

Polypropylene 250 Kgs 58703.36 China

Polypropylene 15000 Kgs 939069 Thailand

Polypropylene - 200 Kgs 20208.08 UAE

Polypropylene - v12s038be pp granules 6000 Kgs 812873.3 United kingdom

Polypropylene (aw564natural) 75 Kgs 10663.34 Thailand

Polypropylene (trek-2-t (b-01)) 75 Kgs 17333.8 Thailand

Polypropylene (trek-2-t (gy-138)) 75 Kgs 14045.54 Thailand

Polypropylene adstif ea5076 14000 Kgs 1502022 Korea

Polypropylene adstif ea5076 13000 Kgs 1431498 Korea

Polypropylene bj368mo bag 11 Mts 1104667 UAE

Polypropylene black glass filled 20% hostacom g2 u02 black 3000 Kgs 929682.7 Germany

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QTY

UNIT

VALUE IN

RS.

COUNTRY

CHEMICALS IMPORTED

Polypropylene clyrell ec5082 1000 Kgs 121402 Korea

Polypropylene copolymer ( bj356ai ) 1125 Kgs 115068 UAE

Polypropylene copolymer ( bj356ai ) 47000 Kgs 4807287 UAE

Polypropylene copolymer ( bj356ai ) 1375 Kgs 140638.7 UAE

Polypropylene copolymer (b 380g) 21511 Kgs 2306713 Korea

Polypropylene copolymer (b 380g) 12489 Kgs 1339247 Korea

Polypropylene copolymer (bx 3800) 5836 Kgs 644725.2 Korea

Polypropylene copolymer (bx 3800) 28164 Kgs 3111385 Korea

Polypropylene copolymer (bx 3920) 26266 Kgs 2918724 Korea

Polypropylene copolymer (bx 3920) 44188 Kgs 4910248 Korea

Polypropylene copolymer (bx 3920) 18119 Kgs 2013415 Korea

Polypropylene copolymer (bx 3920) 4165 Kgs 462822.1 Korea

Polypropylene copolymer (bx 3920) 26262 Kgs 2918280 Korea

Polypropylene copolymer (ea 5076) 30451 Kgs 3273770 Korea

Polypropylene copolymer (ea 5076) 3549 Kgs 381551 Korea

Polypropylene copolymer (ep 300c) 17000 Kgs 1817187 Korea

Polypropylene copolymer (ep 540v) 34000 Kgs 3655321 Korea

Polypropylene copolymer (hm980in) 16000 Kgs 1661006 Korea

Polypropylene copolymer grade 51000 Kgs 5404429 Thailand

Polypropylene co-polymers 0.875 Mts 91185.33 UAE

Polypropylene co-polymers 11.5 Mts 1198436 UAE

Polypropylene d-10: gsf-79 (pp-gf-25) - black 11000 Kgs 1926052 Thailand

Polypropylene epalex 7489 hs uv2 7e50 x 2000 kgs 2000 Kgs 468672 Australia

Polypropylene exxtral bmv21210000 24 Mts 2783813 Singapore

Polypropylene exxtral bmv212w30602 zct mid grey 48 Mts 5834871 Singapore

Polypropylene grade 16000 Kgs 1691564 Singapore

Polypropylene grade: 24750 Kgs 2500750 UAE

Polypropylene grade: 24750 Kgs 2500750 UAE

Polypropylene grade: pp h4120 32000 Kgs 3051537 Saudi arabia

Polypropylene grade:rd265cf 24750 Kgs 2500750 UAE

Polypropylene granules 99000 Kgs 9745125 Saudi arabia

Polypropylene hj311mo bag 5.5 Mts 547250.8 UAE

Polypropylene moplen hp 500n 17 Mts 1691503 South africa

Polypropylene moplen hp456j 5000 Kgs 498186.3 Saudi arabia

Polypropylene moplen hp500n 5000 Kgs 498186 Saudi arabia

Polypropylene pp h1030 48 Mts 4752890 Saudi arabia

Polypropylene purell rp 271g 12 Mts 1378832 Thailand

Polypropylene reprocessed granules 31000 Kgs 1934857 Malaysia

Polypropylene reprocessed granules 31000 Kgs 1934857 Malaysia

Polypropylene reprocessed granules 31000 Kgs 1934857 Malaysia

Polypropylene s2202k 300 Kgs 41032.26 Korea

Polypropylene strip (for packing) 1888004 pcs 192 Kgs 119176.1 China

Polypropylene strip (for packing) 2400000 pcs 128 Kgs 75747.52 China

Polypropylene titanpro 6331 16500 Kgs 1829817 Malaysia

Polypropylene(l2k70bkgr(l2kb70e)) 75 Kgs 17567.63 Korea

Polypropylene 1000 Kgs 118798.9 Korea

Polypropylene 2000 Kgs 235951 Korea

Polypropylene 1000 Kgs 118798.9 Korea

Polypropylene 2000 Kgs 241369.3 Korea

Polypropylene 2000 Kgs 239696.4 Korea

Polypropylene 1000 Kgs 75407.6 Korea

Polypropylene 6000 Kgs 442277 Korea

Polypropylene 17000 Kgs 2462661 Korea

Polypropylene 49500 Kgs 4681019 Saudi arabia

Polypropylene 700 Kgs 171049.8 United kingdom

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QTY

UNIT

VALUE IN

RS.

COUNTRY

CHEMICALS IMPORTED

Polypropylene 1000 Kgs 361895.6 United kingdom

Polypropylene 500 Kgs 148470 United kingdom

Propafilm bi axially oriented polypropylene film 2202.48 Kgs 447792.8 Australia

Propafilm bi axially oriented polypropylene film 1761.6 Kgs 358156.2 Australia

Propafilm bi axially oriented polypropylene film type 4917.24 Kgs 954295.8 Australia

Regrind lldpe 25.73 Mts 1619090 UAE

Reprocessed lldpe granules 51.5 Mts 3359415 Thailand

Reprocessed ldpe granules 78000 Kgs 5062801 Malaysia

Reprocessed lldpe granules 31 Mts 2013624 Singapore

Reprocessed lldpe granules 25000 Kgs 1612642 Singapore

Reprocessed lldpe plastic granules 50 Mts 3274935 Thailand

Reprocessed lldpe plastic granules 54 Mts 3464673 Malaysia

Reprocessed lldpe plastic granules 26 Mts 1702966 Taiwan

Reprocessed lldpe plastic granules 54 Mts 3536930 Malaysia

Reprocessed lldpe plastic granules 54 Mts 3498943 Malaysia

Reprocessed lldpe plastic granules 50 Mts 3261568 Thailand

Reprocessed lldpe plastic granules 54 Mts 3465299 Malaysia

Reprocessed polypropylene granules 26 Mts 1641907 Malaysia

Reprocessed polypropylene granules 26 Mts 1641907 Malaysia

CATEGORY: RESIN’

Abs resin gp-toyolac 100-x01 black 6000 Kgs 853702.5 Malaysia

Acrylic resin ( durasol(tm) 374 2340 Kgs 557319.3 Thailand

Acrylonitrile butadiene styrene resin 6000 Kgs 1094966 Korea

Acrylonitrile butadiene styrene resin starex abs resinvh-0800/w95647 6000 Kgs 1094966 Korea

Alnovol pn 160/past ( phenolic resin) 2000 Kgs 733689.3 Germany

Alnovol pn 160/past ( phenolic resin) 1000 Kgs 366845 Germany

Alnovol pn 160/past ( phenolic resin) 1000 Kgs 366845 Germany

Alnovol pn 160/past ( phenolic resin) 2000 Kgs 733689.3 Germany

D10751857 - zytel (r) 101l nc010 nylon resin [nylon chips] 7000 Kgs 1259308 USA

D10751857 - zytel (r) 101l nc010 nylon resin [nylon chips] 7000 Kgs 1259308 USA

D10786445 - zytel (r) 45hsb nc010 nylon resin 2000 Kgs 449753 USA

D10792925 - zytel (r) 70g13hs1l bk031 nylon resin 2000 Kgs 403344 Korea

D10810516 - zytel (r) 70g33l nc010 nylon resin 3000 Kgs 467619.9 China

D10906520 - zytel (r) 103hsl nc010 nylon resin [nylon chips] 2000 Kgs 415251.4 USA

D10906520 - zytel (r) 103hsl nc010 nylon resin [nylon chips] 2000 Kgs 415251.4 USA

D10906520 - zytel (r) 103hsl nc010 nylon resin [nylon chips] 2000 Kgs 415251.4 USA

D10906520 - zytel (r) 103hsl nc010 nylon resin [nylon chips] 2000 Kgs 415251.4 USA

D10924154 - zytel (r) st801aw bk195 nylon resin 1000 Kgs 274780.6 USA

D11088712 - zytel (r) fr50 bk153j nylon resin 2000 Kgs 572973 China

D11354641 - zytel (r) 135f nc010 nylon resin 1000 Kgs 213786.7 USA

D14284349 - 612 nylon resin 151 nc010w-518 - nylon 612 resin 5502 Kgs 3541039 China

D14568553 - 610 resin-low viscosity 0603 dxr - nylon 610 resin 16000 Kgs 4695163 China

Db-8000 resin(s) (614gp-29768)(acryl resin paint 1616 Kgs 441153.9 Korea

Db-8000 resin(s) (614gp-29769)(acryl resin paint 2416 Kgs 659546.9 Korea

Db-8000 resin(s) (614gp-29770)(acryl resin paint 2448 Kgs 668282.6 Korea

Dowlex high density *2045g polyethylene resin 24750 Kgs 2755974 Singapore

Elite* 5401 g enhanced polyethylene resin 24750 Kgs 2755974 Singapore

Enhanced polyethylene resin elite 5401 g ( lldpe ) 16.5 Mts 1850148 Thailand

Enhanced polyethylene resin elite 5400 g ( lldpe ) 8.25 Mts 925074.2 Thailand

Hb-65 - polyvinyl chloride (blend resin) 6000 Kgs 682962 Korea

Hb-65 - polyvinyl chloride (blend resin) 8000 Kgs 910616 Korea

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UNIT

VALUE IN

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COUNTRY

CHEMICALS IMPORTED

Hdda-hexanediol diacrylate-uv resins 400 Kgs 88471.96 China

High density polyethylene hb111r (raw material for resin 14000 Kgs 1798427 Japan

High density polyethylene hb111r (raw material for resin) 53900 Kgs 6923944 Japan

High density polyethylene resin h5604f film 18250 Kgs 1922694 Thailand

Infino polycarbonate resin 5000 Kgs 742350 Korea

Infino polycarbonate resin 15200 Kgs 2219439 Korea

Infino polycarbonate resin 12000 Kgs 2254926 Korea

Infino polycarbonate resin 21586.3 Kgs 3125340 Korea

Infino polycarbonate resin 12414 Kgs 1797299 Korea

Infino polycarbonate resin sc- 5000 Kgs 742350 Korea

Infino polycarbonate resin sc-1220r 7000 Kgs 1013485 Korea

Kch-12 - polyvinyl chloride (paste resin) 2800 Kgs 382805.2 Korea

Kch-12 - polyvinyl chloride (paste resin) 3500 Kgs 478506.4 Korea

Kch-15 - polyvinyl chloride (paste resin) 5600 Kgs 765610.3 Korea

Kh-10 - polyvinyl chloride (paste resin) 5600 Kgs 758681.7 Korea

K-resin styrene butadiene copolymer kr99hg 19.5 Mts 2730732 Korea

Liner low density polyethylene adtex ft71a (raw materialfor resin) 2100 Kgs 505311.7 Japan

Lldpe (linear low density polyethylene) resin 17500 Kgs 1854461 Indonesia

Lupoy (ns5000cr ka02) (polycarbonate resin) 1000 Kgs 283772.1 Korea

Marlex high density polyethylene resin hhm 5502bn 22.0694 Mts 2203252 Saudi arabia

Marlex high density polyethylene resin hhm 5502bn 6.4641 Mts 645329.7 Saudi arabia

Marlex high density polyethylene resin hhm 5502bn 83.4665 Mts 8332701 Saudi arabia

Marlex high density polyethylene resin hhm 5502bn 16000 Kgs 1641534 Saudi arabia

Marlex high density polyethylene resin hhm tr-144 96 Mts 9643127 Saudi arabia

Marlex high density polyethylene resin hhm tr-144 20.8598 Mts 2095351 Saudi arabia

Marlex high density polyethylene resin hhm tr-144 9.774 Mts 981790.8 Saudi arabia

Marlex high density polyethylene resin hhm tr-144 1.3662 Mts 137233.7 Saudi arabia

Marlex high density polyethylene resin hhm tr-144 96 Mts 9643117 Saudi arabia

Marlex high density polyethylene resin hhm tr-144 80 Mts 8035931 Saudi arabia

Marlex high density polyethylene resin hhm tr-144 64 Mts 6428744 Saudi arabia

Marlex high density polyethylene resin hhm tr-144 32 Mts 3214372 Saudi arabia

Methylated melamine resin mr-603lf graco:rn6277 8000 Kgs 918259.7 Taiwan

Methylated melamine resin mr-603lf graco:rn6277 8000 Kgs 933017.8 Taiwan

nylon compound chip (nylonresin) polyamide resin 2000 Kgs 904429.8 Thailand

Nylon resin - zytel (r) 1000 Kgs 289709.5 Germany

Nylon resin (om) (primary forms) 600 Kgs 168530 Korea

Nylon resin (ryn) (primary forms) 1000 Kgs 280883.5 Korea

Nylon resin, (zytel 45hsb nc010 25 kg bag-d10786445) 1000 Kgs 343127.3 USA

Pa1302 - polyvinyl chloride (blend resin) 3000 Kgs 404580.8 Korea

Paraloid b44 100% graco:rc0194 (acrylic resin) 4352 Kgs 1723044 USA

Pmma resin grade : ih830c (4006) (poly methyl methacrylate) 8250 Kgs 1325092 Korea

Pmma resin grade : ih830c (4006) (poly methyl methacrylate) 750 Kgs 120463 Korea

Pmma resin grade :ih830c (4006) (polymethyl methacrylate) 9000 Kgs 1445555 Korea

Pmma resin grade :ih830c (np) (polymethyl methacrylate) 5250 Kgs 756878.9 Korea

Pmma resin grade :ih830c (np) (polymethyl methacrylate) 5250 Kgs 756878.9 Korea

Pmma resin grade: hi855m(np)(polymethyle methacrylate) 100 Kgs 22241.21 Korea

Pmma resin grade: hi855m(np)(polymethyle methacrylate) 100 Kgs 22241.21 Korea

Pmma resin grade: ih830c (2001) (polymethyl methacrylate) 250 Kgs 40154.32 Korea

Pmma resin grade: ih830c (2001) (polymethyl methacrylate) 400 Kgs 64246.91 Korea

Polyacetal resin duracon (r) m90-44 cf 2001 natural 12000 Kgs 1057228 Malaysia

Polyacetal resin duracon (r) m90-45 cf 2001 natural 4000 Kgs 855146.8 Malaysia

Polyacetal resin kepital f25-03 nat 17.175 Mts 1423214 Korea

Polyacetal resin kepital fg2025 nat 0.5 Mts 68695.15 Korea

Polyacetal resin kepital mb-s315 0.2 Mts 46823.6 Korea

Polyamide resin type:rilsan besn black p40 tl 6959 Kgs 3622887 China

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UNIT

VALUE IN

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COUNTRY

CHEMICALS IMPORTED

Polyamide resin type:rilsan besn black p40 tl 1441 Kgs 750191.1 China

Polycarbonate -red orange (7025l-1 clr09) resin 307 Kgs 149644.7 Japan

Polycarbonate resin 16000 Kgs 2410163 Thailand

Polycarbonate resin 16000 Kgs 2410163 Thailand

Polycarbonate resin 9000 Kgs 1354942 Thailand

Polycarbonate resin 17000 Kgs 2502957 Korea

Polycarbonate resin infino sc-1220r ( 17000 Kgs 2502957 Korea

Polycarbonate resin infino sc-1220r (coo/no.060-14-00038) 17000 Kgs 2502957 Korea

Polycarbonate resin panlite / mn3600ha/blk/pb(d) 13000 Kgs 2450846 Singapore

Polycarbonate resin panlite / mn3600ha/blk/pb(d) 3000 Kgs 565579.8 Singapore

Polycarbonate resin panlite l1225z100 natural ( 16000 Kgs 2365622 Singapore

Polymethyl methacrylate resin 17500 Kgs 2603337 Korea

Polymethyl methacrylate sumipex acrylic resin (grade lg) 2350.35 Kgs 311330.9 Singapore

Polymethyl methacrylate sumipex acrylic resin (grade lg) 3649.65 Kgs 483438.1 Singapore

Polymethyl methacrylate sumipex acrylic resin (grade lg) 2350.35 Kgs 311330.9 Singapore

Polymethyl methacrylate sumipex acrylic resin (grade lg) 3649.65 Kgs 483438.1 Singapore

Polymethyl methacrylate sumipex acrylic resin (grade lg2s) 993.4 Kgs 131587.3 Singapore

Polymethyl methacrylate sumipex acrylic resin (grade lg2s) 2655.5 Kgs 351751.5 Singapore

Polymethyl methacrylate sumipex acrylic resin (grade lg2s) 2351.1 Kgs 311430.2 Singapore

Polymethyl methacrylate sumipex acrylic resin (grade lg2s) 993.4 Kgs 131587.3 Singapore

Polymethyl methacrylate sumipex acrylic resin (grade lg2s) 2655.5 Kgs 351751.5 Singapore

Polymethyl methacrylate sumipex acrylic resin (grade lg2s) 2351.1 Kgs 311430.2 Singapore

Polymethyl methacrylate sumipex acrylic resin (grade me) 6000 Kgs 794769 Singapore

Polymethyl methacrylate sumipex acrylic resin (grade me) 6000 Kgs 794769 Singapore

Polymethyl methacrylate sumipex acrylic resin grade 21000 Kgs 2878727 Singapore

Polypropylene resin 6331 17000 Kgs 1829893 Taiwan

Polypropylene resin 6331 17000 Kgs 1829893 Taiwan

Polypropylene resin black (h100t) 2562.89 Kgs 174528.7 Thailand

Polypropylene resin black (h100t) 15943.7 Kgs 1085737 Thailand

Polypropylene resin black (h100t) 40228.5 Kgs 2739494 Thailand

Polypropylene resin black (h100t) 18765 Kgs 1277865 Thailand

Polypropylene resin desp pp grade 5 Mts 575321.3 Korea

Polypropylene resin desp pp grade 5 Mts 575321.3 Korea

Polypropylene resin desp pp grade 3 Mts 345192.8 Korea

Polypropylene resin desp pp grade 7 Mts 805449.8 Korea

Polypropylene resin desp pp grade no: 6 Mts 687567.6 Korea

Polypropylene resin desp pp grade no:mt42iba p5 13 Mts 1489730 Korea

Polypropylene resin desp pp grade no:mt42iba p5 7 Mts 802162.2 Korea

Polypropylene resin desp pp grade no:mt42tbi p5 2 Mts 229189.2 Korea

Polypropylene resin desp pp grade no:mt62cs1 p5 6 Mts 687567.6 Korea

Polypropylene resin desp pp grade no:mt62cs1 p5 1 Mts 114594.6 Korea

Polypropylene resin desp pp grade no:mt62cs5 p5 15 Mts 1718919 Korea

Polypropylene resin desp pp grade no:mt62cs5 p5 10 Mts 1145946 Korea

Polypropylene resin noblen gph5157 11750 Kgs 2316536 Japan

Polypropylene resin pp-11270-kp6063wt 1200 Kgs 129381 China

Polyvinyl chloride resin suspension grade : s-65(powder form) 64000 Kgs 4513488 Taiwan

Polyvinyl chloride resin suspension grade : s-65(powder form) 64000 Kgs 4513488 Taiwan

Polyvinyl chloride resin suspension grade : s-65(powder form) 64000 Kgs 4513488 Taiwan

Polyvinyl chloride resin suspension grade : s-65d(powder form) 90000 Kgs 6347093 Taiwan

Polyvinyl chloride resin suspension grade : s-65d(powder form) 90000 Kgs 6347093 Taiwan

Polyvinyl chloride resin suspension grade : s-65d(powder form) 54000 Kgs 3808256 Taiwan

Polyvinyl chloride resin suspension grade: 76000 Kgs 5314479 Korea

Polyvinyl chloride resin suspension grade:ls100e(powderform) 72000 Kgs 4946051 Korea

Polyvinyl chloride resin suspension grade:ls100h(powderform 57000 Kgs 4065576 Korea

Polyvinyl chloride resin suspension grade:ls100h(powderform) 57000 Kgs 4065576 Korea

Page 107: Volume 22 Issue 3 December 2014 newnsa ndern fFneAC.

Nandini Chemical Journal, December,2014 Page 107

NAME OF THE CHEMICAL

QTY

UNIT

VALUE IN

RS.

COUNTRY

CHEMICALS IMPORTED

Polyvinyl chloride resin suspension grade:ls100h(powderform)( 57000 Kgs 3985859 Korea

Pvc resin suspension grade s65d 10308 Kgs 726953.7 Taiwan

Pvc resin suspension grade s65d 20307 Kgs 1432116 Taiwan

Pvc resin suspension grade s65d 108000 Kgs 7616511 Taiwan

Pvc resin suspension grade s65d 3385 Kgs 238721 Taiwan

Pvc resin suspension grade s-65d 34000 Kgs 2388004 Taiwan

S polyvinyl chloride resin suspension grade: 192000 Kgs 13130323 Japan

S polyvinyl chloride resin suspension grade: tk-1000(powder form 208000 Kgs 14224517 Japan

Sukorez su-400, (hydrocarbon resin) 14 Mts 2580904 Korea

Sumilite resin grade: valodur 3001 (phenolic resin) 12000 Kgs 1609082 Indonesia

Tmpta-trimethylolpropane triacrylate-uv resins 6000 Kgs 1090497 China

Trirex (3022r-sm 3318ae ) (polycarbonate resin) 1500 Kgs 561307.5 Korea

Trirex (3025u wh3432ab) (polycarbonate resin) 5500 Kgs 1564177 Korea

Trirex (3025u wh3432ac) (polycarbonate resin) 5500 Kgs 1564177 Korea

Zytel(r) e51hsb nc010 25kg bag nylon resin 10000 Kgs 2376483 USA

Zytel(r) e51hsb nc010 25kg bag nylon resin 10000 Kgs 2376483 USA

CATEGORY: WAX

Alexwax 600 (fully refined paraffin wax) 80000 Kgs 7288951 Egypt

Fully refined paraffin wax 16 Mts 1469853 China

Fully refined paraffin wax m.p. 58/60 deg.c.( 61.5 Mts 5178062 China

Fully refined paraffin wax m.p. 58/60 deg.c.(kunlun brand) 61.5 Mts 5136134 China

Fully refined paraffin wax m.p. 58/60 deg.c.(kunlun brand) 61.5 Mts 5115170 China

Fully refined paraffin wax 125/130 7840 Kgs 937514.8 Japan

Fully refined paraffin wax 125/130 15680 Kgs 1910908 Japan

Fully refined paraffin wax 125/130 7840 Kgs 951554.1 Japan

Fully refined paraffin wax 125/130 15680 Kgs 1910908 Japan

Fully refined paraffin wax 125/130 15680 Kgs 1885949 Japan

Fully refined paraffin wax 140/145 15680 Kgs 1862408 Japan

Fully refined paraffin wax 140/145 7840 Kgs 927403 Japan

Fully refined paraffin wax 140/145 15680 Kgs 1838082 Japan

Fully refined paraffin wax 58/60 21 Mts 1916191 China

Fully refined paraffin wax 58/60 42 Mts 3855554 China

Fully refined paraffin wax 58/60 5000 Kgs 459143.5 China

Fully refined paraffin wax 58/60 42000 Kgs 3855554 China

Fully refined paraffin wax grade:125/130 15680 Kgs 1926507 Japan

Fully refined paraffin wax grade:140/145 15680 Kgs 1877611 Japan

Paraffin wax (oil content 0.5%) 21 Mts 1963375 China

Paraffin wax (oil content 0.5%) 21 Mts 1963375 China

Paraffin wax fully refined # 66 20 Mts 1891427 China

Shell gtl sarawax sx60s - paraffin wax 40000 Kgs 3289980 Malaysia

Wax ozo ace-0017 ( paraffin wax) 1280 Kgs 805195 Japan

Microcrystalline wax - multiwax w-445 (iso tank cntr) 19720 Kgs 2598448 USA