Using R.I.C.E. Tables and stoichiometry with limiting reactants

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USING R.I.C.E. TABLES AND STOICHIOMETRY WITH LIMITING REACTANTS

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Using R.I.C.E. Tables and stoichiometry with limiting reactants. RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up mathematical equations when necessary to solve for unknowns. - PowerPoint PPT Presentation

Transcript of Using R.I.C.E. Tables and stoichiometry with limiting reactants

Page 1: Using R.I.C.E. Tables and stoichiometry with limiting reactants

USING R.I.C.E. TABLES AND STOICHIOMETRY WITH LIMITING REACTANTS

Page 2: Using R.I.C.E. Tables and stoichiometry with limiting reactants

RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up mathematical equations when necessary to solve for unknowns.

R = reaction (balanced)I = initial conditions (before the reaction)C = change (remove reactants, form products)E = end conditions (after the reaction)

Page 3: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

Page 4: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

BEWARE: Moles goes into a RICE table and moles will come out. To find volume will require a final step.

Page 5: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R =

Page 6: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

Page 7: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I =

Page 8: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g

Page 9: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g0.625 mol ? 0 0

Page 10: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g0.625 mol ? 0 0

C =

Page 11: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g0.625 mol ? 0 0

C = -1x -3x +2x +2x

Page 12: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g0.625 mol ? 0 0

C = -1x -3x +2x +2xall the ethene will be burned, so x = 0.63 mol

Page 13: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g0.625 mol ? 0 0

C = -1x -3x +2x +2x-0.625 mol -1.875 mol +1.25 mol +1.25 mol

Page 14: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g0.625 mol ? 0 0

C = -1x -3x +2x +2x-0.625 mol -1.875 mol +1.25 mol +1.25 mol

E =

Page 15: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g0.625 mol ? 0 0

C = -1x -3x +2x +2x-0.625 mol -1.875 mol +1.25 mol +1.25 mol

E = 0 ?-1.875 mol 1.25 mol 1.25 mol

Page 16: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

How many moles of CO2 was formed?

Page 17: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

How many moles of CO2 was formed? 1.3 mol

Page 18: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

How many moles of CO2 was formed? 1.3 molWhat volume of CO2 was formed?

Page 19: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

How many moles of CO2 was formed? 1.3 molWhat volume of CO2 was formed?

1.25 mol x 22.4 L/mol = 28 L

Page 20: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

How many moles of CO2 was formed? 1.3 molWhat volume of CO2 was formed?

1.25 mol x 22.4 L/mol = 28 L

What other information do we already know?

Page 21: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

How many moles of CO2 was formed? 1.3 molWhat volume of CO2 was formed?

1.25 mol x 22.4 L/mol = 28 L

What other information do we already know?• Moles of O2 consumed• Moles of H2O produced

Page 22: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

Page 23: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

Page 24: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g 50. g0.625 mol 1.56 mol

Page 25: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g 50. g0.625 mol 1.56 mol

C = -1x -3x +2x +2xWHICH X TO USE? SMALLEST X!

Page 26: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g 50. g0.625 mol 1.56 mol

C = -1x -3x +2x +2xWHICH X TO USE? SMALLEST X!

If 0.625 = 1 x, then x = 0.625If 1.56 = 3 x, then x = 0.521 ← SMALLEST

Page 27: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g 50. g0.625 mol 1.56 mol

C = -1x -3x +2x +2x-0.521 mol -1.56 mol +1.04 mol 1.04 mol

Page 28: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g 50. g0.625 mol 1.56 mol

C = -1x -3x +2x +2x-0.521 mol -1.56 mol +1.04 mol 1.04 mol

E = 0.625 mol – 0.521 mol 1.56 mol – 1.56 mol 1.04 mol 1.04 mol

0.104 mol 0 1.04 mol 1.04 mol

Page 29: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

What volume of CO2 is actually produced?1.04 mols x 22.4 L/mol = 23 L

Page 30: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

What volume of CO2 is actually produced?1.04 mols x 22.4 L/mol = 23 L

What else do we know?• Moles of ethene left over• Moles of water actually produced

Page 31: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Why use a RICE table for limiting reactant problems?

How many RR tracks would it have taken?

Page 32: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Why use a RICE table for limiting reactant problems?

How many RR tracks would it have taken?2 to figure out which one is limiting

Page 33: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Why use a RICE table for limiting reactant problems?

How many RR tracks would it have taken?2 to figure out which one is limiting1 more to find amount of excess

Page 34: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Why use a RICE table for limiting reactant problems?

How many RR tracks would it have taken?2 to figure out which one is limiting1 more to find amount of excess1 more for each of the additional products

Page 35: Using R.I.C.E. Tables and stoichiometry with limiting reactants

Why use a RICE table for limiting reactant problems?

How many RR tracks would it have taken?2 to figure out which one is limiting1 more to find amount of excess1 more for each of the additional products

It is your choice. We did 1 RICE table vs 4 RR Tracks.RICE tables will be necessary later. For now, it is optional.