Understanding Contaminant Sources, Ground-Water Residence Times, and Flow Patterns in a Karstic...
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Transcript of Understanding Contaminant Sources, Ground-Water Residence Times, and Flow Patterns in a Karstic...
![Page 1: Understanding Contaminant Sources, Ground-Water Residence Times, and Flow Patterns in a Karstic Springshed Brian Katz, Rick Copeland, Tom Greenhalgh, Warren.](https://reader030.fdocuments.net/reader030/viewer/2022032721/56649cd85503460f949a0924/html5/thumbnails/1.jpg)
Understanding Contaminant Understanding Contaminant Sources, Ground-Water Sources, Ground-Water
Residence Times, and Flow Residence Times, and Flow Patterns in a Karstic Patterns in a Karstic
SpringshedSpringshed
Understanding Contaminant Understanding Contaminant Sources, Ground-Water Sources, Ground-Water
Residence Times, and Flow Residence Times, and Flow Patterns in a Karstic Patterns in a Karstic
SpringshedSpringshedBrian Katz, Rick Copeland, Tom Greenhalgh,Brian Katz, Rick Copeland, Tom Greenhalgh, Warren Zwanka, and Sam UpchurchWarren Zwanka, and Sam UpchurchBrian Katz, Rick Copeland, Tom Greenhalgh,Brian Katz, Rick Copeland, Tom Greenhalgh, Warren Zwanka, and Sam UpchurchWarren Zwanka, and Sam Upchurch
Suwannee River and Estuary Science WorkshopSuwannee River and Estuary Science WorkshopCedar Key, Florida, Cedar Key, Florida, September 23, 2004September 23, 2004
Suwannee River and Estuary Science WorkshopSuwannee River and Estuary Science WorkshopCedar Key, Florida, Cedar Key, Florida, September 23, 2004September 23, 2004
![Page 2: Understanding Contaminant Sources, Ground-Water Residence Times, and Flow Patterns in a Karstic Springshed Brian Katz, Rick Copeland, Tom Greenhalgh, Warren.](https://reader030.fdocuments.net/reader030/viewer/2022032721/56649cd85503460f949a0924/html5/thumbnails/2.jpg)
NITRATE IN SPRING WATERS, NITRATE IN SPRING WATERS, NORTHERN FLORIDANORTHERN FLORIDA
![Page 3: Understanding Contaminant Sources, Ground-Water Residence Times, and Flow Patterns in a Karstic Springshed Brian Katz, Rick Copeland, Tom Greenhalgh, Warren.](https://reader030.fdocuments.net/reader030/viewer/2022032721/56649cd85503460f949a0924/html5/thumbnails/3.jpg)
SOURCES OF NITRATE IN SPRING WATERS
Fannin Springs
![Page 4: Understanding Contaminant Sources, Ground-Water Residence Times, and Flow Patterns in a Karstic Springshed Brian Katz, Rick Copeland, Tom Greenhalgh, Warren.](https://reader030.fdocuments.net/reader030/viewer/2022032721/56649cd85503460f949a0924/html5/thumbnails/4.jpg)
Fannin Springshed Study
![Page 5: Understanding Contaminant Sources, Ground-Water Residence Times, and Flow Patterns in a Karstic Springshed Brian Katz, Rick Copeland, Tom Greenhalgh, Warren.](https://reader030.fdocuments.net/reader030/viewer/2022032721/56649cd85503460f949a0924/html5/thumbnails/5.jpg)
TYPICAL SPRING TYPICAL SPRING SYSTEMSYSTEM
Spring-water chemistry– reflects the temporal, spatial, and vertical integration of water from the aquifer system.
Can provide important clues about geochemical and hydrologic processes.
![Page 6: Understanding Contaminant Sources, Ground-Water Residence Times, and Flow Patterns in a Karstic Springshed Brian Katz, Rick Copeland, Tom Greenhalgh, Warren.](https://reader030.fdocuments.net/reader030/viewer/2022032721/56649cd85503460f949a0924/html5/thumbnails/6.jpg)
MULTIPLE CHEMICAL TRACER APPROACH
SOURCES OF NITRATE CONTAMINATION:SOURCES OF NITRATE CONTAMINATION: 15N/14N (15N and 18O of NO3)
GEOCHEMICAL PROCESS IDENTIFICATION:GEOCHEMICAL PROCESS IDENTIFICATION:18O, 2H, 13C, major ions, nutrients, dissolved gases, DOC
AGE OF SPRING WATERS:AGE OF SPRING WATERS: CFC-11, CFC-12, CFC-113; 3H/3He; SF6
![Page 7: Understanding Contaminant Sources, Ground-Water Residence Times, and Flow Patterns in a Karstic Springshed Brian Katz, Rick Copeland, Tom Greenhalgh, Warren.](https://reader030.fdocuments.net/reader030/viewer/2022032721/56649cd85503460f949a0924/html5/thumbnails/7.jpg)
Fannin Springs Study--Source Identification
Cropland farming:Cropland farming:
Herbicides and degradates (36 Herbicides and degradates (36 compounds)compounds)
Triazines, phenylureas, acetanilides, degradatesPesticides and degradates (66 compounds)
Animal wastesAnimal wastes
Antibiotics (37 compounds)Beta lactams, macrolides, quinolines,
sulfonamides, tetracyclines
![Page 8: Understanding Contaminant Sources, Ground-Water Residence Times, and Flow Patterns in a Karstic Springshed Brian Katz, Rick Copeland, Tom Greenhalgh, Warren.](https://reader030.fdocuments.net/reader030/viewer/2022032721/56649cd85503460f949a0924/html5/thumbnails/8.jpg)
Fannin Springs Study--Source Identification
Human wastewater compounds (67):Human wastewater compounds (67):
Alkylphenol ethoxylate nonionic surfactants and their degradates, food additives, fragrances, antioxidants, flame retardants, plasticizers, industrial solvents, disinfectants, fecal sterols, polycyclic aromatic hydrocarbons, high-use domestic pesticides
![Page 9: Understanding Contaminant Sources, Ground-Water Residence Times, and Flow Patterns in a Karstic Springshed Brian Katz, Rick Copeland, Tom Greenhalgh, Warren.](https://reader030.fdocuments.net/reader030/viewer/2022032721/56649cd85503460f949a0924/html5/thumbnails/9.jpg)
Nitrate Concentration, mg/L
![Page 10: Understanding Contaminant Sources, Ground-Water Residence Times, and Flow Patterns in a Karstic Springshed Brian Katz, Rick Copeland, Tom Greenhalgh, Warren.](https://reader030.fdocuments.net/reader030/viewer/2022032721/56649cd85503460f949a0924/html5/thumbnails/10.jpg)
15N/14N of Nitrate, per mil
![Page 11: Understanding Contaminant Sources, Ground-Water Residence Times, and Flow Patterns in a Karstic Springshed Brian Katz, Rick Copeland, Tom Greenhalgh, Warren.](https://reader030.fdocuments.net/reader030/viewer/2022032721/56649cd85503460f949a0924/html5/thumbnails/11.jpg)
Potassium Concentration, mg/L
![Page 12: Understanding Contaminant Sources, Ground-Water Residence Times, and Flow Patterns in a Karstic Springshed Brian Katz, Rick Copeland, Tom Greenhalgh, Warren.](https://reader030.fdocuments.net/reader030/viewer/2022032721/56649cd85503460f949a0924/html5/thumbnails/12.jpg)
Pesticides, emerging contaminants detected:
![Page 13: Understanding Contaminant Sources, Ground-Water Residence Times, and Flow Patterns in a Karstic Springshed Brian Katz, Rick Copeland, Tom Greenhalgh, Warren.](https://reader030.fdocuments.net/reader030/viewer/2022032721/56649cd85503460f949a0924/html5/thumbnails/13.jpg)
Ground-Water Age (yrs), 3H/3He, CFCs, SF6 methods
![Page 14: Understanding Contaminant Sources, Ground-Water Residence Times, and Flow Patterns in a Karstic Springshed Brian Katz, Rick Copeland, Tom Greenhalgh, Warren.](https://reader030.fdocuments.net/reader030/viewer/2022032721/56649cd85503460f949a0924/html5/thumbnails/14.jpg)
Conclusions
Predominant sources of nitrate Predominant sources of nitrate contamination in the Fannin springshed contamination in the Fannin springshed appear to originate from agricultural appear to originate from agricultural activities, based on the detection of activities, based on the detection of elevated potassium, herbicides and their elevated potassium, herbicides and their degradates, and nitrogen isotope ratios.degradates, and nitrogen isotope ratios.
However, other sources such as animal However, other sources such as animal wastes, and or septic tank effluent may wastes, and or septic tank effluent may account for elevated nitrogen isotope account for elevated nitrogen isotope ratios in some wells and Fannin Springs.ratios in some wells and Fannin Springs.
Predominant sources of nitrate Predominant sources of nitrate contamination in the Fannin springshed contamination in the Fannin springshed appear to originate from agricultural appear to originate from agricultural activities, based on the detection of activities, based on the detection of elevated potassium, herbicides and their elevated potassium, herbicides and their degradates, and nitrogen isotope ratios.degradates, and nitrogen isotope ratios.
However, other sources such as animal However, other sources such as animal wastes, and or septic tank effluent may wastes, and or septic tank effluent may account for elevated nitrogen isotope account for elevated nitrogen isotope ratios in some wells and Fannin Springs.ratios in some wells and Fannin Springs.