The WHO Recommended Classification of Pesticides by Hazard ...
Transcript of The WHO Recommended Classification of Pesticides by Hazard ...
The WHO Recommended Classification of Pesticides by Hazardand
Guidelines to Classification 2009
WHO Library Cataloguing-in-Publication Data
World Health Organization.
The WHO recommended classification of pesticides by hazard and guidelinesto classification: 2009.
1. Pesticides – toxicity. 2. Pesticides – classification. 3. Hazardous substances – classification. 4. Guidelines. I. International Programme on Chemical Safety. II. Title.
ISBN 978 92 4 154796 3 (NLM classification: WA 240)ISSN 1684-1042
© World Health Organization 2010
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THE WHO RECOMMENDED CLASSIFICATION OF PESTICIDES BY HAZARD AND GUIDELINES TO CLASSIFICATION 2009
The WHO Recommended Classification of Pesticides by Hazard was approved by the 28th World Health Assembly in 1975 and has since gained wide acceptance. When it was published in the WHO Chronicle, 29, 397-401 (1975), an annex, which was not part of the Classification, illustrated its use by listing examples of classification of some pesticidal active ingredients and their formulations. Later suggestions were made by Member States and pesticide registration authorities that further guidance should be given on the classification of individual pesticides. Guidelines were first issued in 1978, and have since been revised and reissued every few years.
Up until the present revision the original guidelines approved by the World Health Assembly in 1975 have been followed without amendment. In December, 2002 the United Nations Committee of Experts on the Transport of Dangerous Goods and on the Globally Harmonized System of Classification and Labelling of Chemicals (UNCETDG/GHS) approved a document called “The Globally Harmonized System of Classification and Labelling of Chemicals” with the intent to provide a globally-harmonized system1 (GHS) to address classification of chemicals, labels, and safety data sheets. The GHS (with subsequent revisions) is now being widely used for the classification and labeling of chemicals worldwide. For this revision of the Classification the WHO Hazard Classes have been aligned in an appropriate way with the GHS Acute Toxicity Hazard Categories for acute oral or dermal toxicity as the starting point for allocating pesticides to a WHO Hazard Class (with adjustments for individual pesticides where required). It is anticipated that few of the more toxic pesticides will change WHO Hazard Class as a result of this change. As has always been the case, the classification of some pesticides has been adjusted to take account of severe hazards to health other than acute toxicity (as described in Part II). The GHS Acute Toxicity Hazard Category for each pesticide is now presented alongside the existing information.
The document is arranged as follows:
Part I: Overarching principles for the classification of pesticides as recommended by the World Health Assembly. These principles continue to apply, but the World Health Assembly Resolution envisaged that the classification criteria might need to be developed with time and increasing experience. The guide-points originally proposed in 1975 are now being aligned with the corresponding Acute Toxicity Hazard Categories from the GHS.
Part II: Guidelines to Classification. Individual products are classified in a series of tables, according to the oral or dermal toxicity of the technical product. The tables are subject to review periodically.
The toxicity values are intended to be a guide only. Formulations should be separately classified using the methods set out on pages 4 (single technical product) and 7 (mixtures) and the table in Part I. To assist in the classification of formulations, an annex is provided giving numerical tables from which the classification may also be derived.
1 See http://www.unece.org/trans/danger/publi/ghs/ghs_rev03/03files_e.html.
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Comments on Part II of the document are welcome, together with proposals for new entries. These should be addressed to the International Programme on Chemical Safety, World Health Organization, 1211 Geneva 27, Switzerland, and should include supporting data on the compound being commented on or proposed.
This document is a revision of the document previously issued as ISBN 92 4 154663 8.
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PART I RECOMMENDED CLASSIFICATION OF PESTICIDES BY HAZARD
Extract from WHO Chronicle, 29: 397-401 (1975)In 1973, the WHO Executive Board asked the Director-General of WHO to take steps to develop a tentative classification of pesticides that would distinguish between the more and the less hazardous forms of each pesticide. A proposal for a WHO recommended classification of pesticides by hazard was accordingly prepared, taking into account the views of members of the WHO Expert Advisory Panel on Insecticides and other expert advisory panels with special competence and interest in pesticide technology, as well as the comments of WHO Member States and of two international agencies. This proposal was adopted by the Twenty-eighth World Health Assembly, which recommended the use of the classification by Member States, international agencies, and regional bodies.
The text below is reproduced from the Proposal2 which was adopted by the World Health Assembly in 1975.The hazard referred to in this Recommendation is the acute risk to health (that is, the risk of single or multiple exposures over a relatively short period of time) that might be encountered accidentally by any person handling the product in accordance with the directions for handling by the manufacturer or in accordance with the rules laid down for storage and transportation by competent international bodies.
Any classification based on biological data can never be treated as final. In the assessment of biological data, honest differences of opinion are inevitable and most borderline cases can be reclassified in an adjacent class. Variability or inconsistency in toxicity data due to differences in susceptibility of test animals, or to experimental techniques and materials used can also result in differing assessments. The classification criteria are guide-points intended to supplement but never to substitute for special knowledge, sound clinical judgement or experience with a compound. Reappraisal might be necessary from time to time.
Basis of classification
The classification distinguishes between the more and the less hazardous forms of each pesticide in that it is based on the toxicity of the technical compound and on its formulations. [In particular, allowance is made for the lesser hazards from solids as compared with liquids.]3
The classification is based primarily on the acute oral and dermal toxicity to the rat since these determinations are standard procedures in toxicology. Where the dermal LD50
4 value of a compound is such that it would place it in a more restrictive class than the oral LD50 value would indicate, the compound will always be classified in the more restrictive class. Provision is made for the classification of a particular compound to be adjusted if, for any reason, the acute hazard to man differs from that indicated by LD50 assessments alone.
2 Official Record of the World Health Organization 1975, No.223, Part 1, p.123 Note:- this distinction is not made in the GHS and no longer applies to the WHO Classification4 The LD50 value is a statistical estimate of the number of mg of toxicant per kg of bodyweight required to kill
50% of a large population of test animals.
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Application of the criteria for classification
(a) Where it is shown that for a particular compound the rat is not the most suitable test animal (for example, if another species is conspicuously more sensitive or more closely resembles man in its reaction) then the classification of that compound should take this into account.
(b) In practice, the majority of classifications will be made on the acute oral LD50 value. However, dermal toxicity must always be considered since it has been found that, under most conditions of handling pesticides, a high proportion of the total exposure is dermal. Classification based on dermal data in a class indicating a great risk is necessary when the dermal LD50 values indicate greater hazard than oral LD50 values.
(c) If the active ingredient produces irreversible damage to vital organs, is highly volatile, is markedly cumulative in its effect, or is found after direct observations to be particularly hazardous or significantly allergenic to man, then adjustments to the classification can be made by classifying the compound in a class indicating a higher hazard. Alternatively, if it can be shown that the preparation is less toxic or hazardous than expected from consideration of the LD50 values of the ingredient or ingredients, or for any other reason, adjustments should be made by classifying the compound in a class indicating a lower hazard.
(d) In certain special cases the acute oral or dermal LD50 values of the compound or formulation should not be used as the main basis for classification. In such cases (for example, aerosol preparations, other special formulations and fumigants), more appropriate criteria should be used.
(e) It is highly desirable that, whenever practicable, toxicological data for each formulation to be classified should be available from the manufacturer. However, if such data are not obtainable, then the classification may be based on proportionate calculations from the LD50 values of the technical ingredient or ingredients, according to the following formula:
LD50 active ingredient×100Percentage of active ingredient in formulation
If the formulation contains more than one ingredient (including solvents, wetting agents, etc.) of significant toxicity-enhancing properties, then the classification should correspond to the toxicity of the mixed ingredients.
(f) With a few exceptions, pesticides have low volatility and therefore no criteria are at present set out for volatility in this Recommendation. The inclusion of such criteria is unlikely to affect the classification of pesticides by hazard except in the case of volatile fumigants used in agriculture and food storage. On the other hand, when the criteria are applied to pesticide formulations based on solvents or to other chemicals, account must be taken of volatility and consequent inhalation toxicity.
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Effects of classification on labeling5
While no specific symbols to identify classes are included in the Recommendation, the following are the general implications of the classification as regards labelling.
The aim should be uniformity in the statement on the nature of the risk (by phrase and/or symbol) on the label of the product, irrespective of the country of origin or use. Labels of products classified in classes Ia and Ib should bear a symbol indicating a high degree of hazard (usually a type of skull and crossbones) and a signal word or phrase, e.g. POISON or TOXIC. The presentation of the symbol and word or phrase, in terms of colour, size and shape should ensure that they are given sufficient prominence on the label.
The text should be in the local language and for all formulations should include the approved name of the active ingredient or ingredients, the method of use, and precautions to be taken in use. For classes Ia and Ib, symptoms and immediate treatment of poisoning should also be included.
The detailed precautions necessary for the use of a pesticide depend on the nature of the formulation and the pattern of use and are best decided by a pesticide registration authority when accepting a commercial label.
There are international agreements on symbols to denote hazards from materials which are inflammable, corrosive, explosive, etc., and these should be consulted and used where appropriate.
Revised criteria for classification (introduced for 2009 update)The table showing the Recommended Criteria for Classification from the original World Health Assembly Proposal is not shown because it is no longer used. WHO now uses the Acute Toxicity Hazard Categories from the GHS6 as the starting point for classification. This change is consistent with the 1975 World Health Assembly Resolution which envisaged that the WHO Classification would be further developed with time in consultation with countries, international agencies and regional bodies. The GHS meets this requirement as a classification system with global acceptance following extensive international consultation.
WHO Class LD50 for the rat(mg/kg body weight)
Oral Dermal
Ia Extremely hazardous < 5 < 50Ib Highly hazardous 5–50 50–200II Moderately hazardous 50–2000 200–2000III Slightly hazardous Over 2000 Over 2000U Unlikely to present acute hazard 5000 or higher
Details of how the WHO Classification has been aligned with the GHS Acute Toxicity Hazard Categories are presented in Part II.
5 See International Code of Conduct on the Distribution and Use of Pesticides, FAO (2003), available at http://www.fao.org/docrep/005/Y4544E/y4544e00.HTM; also Guidelines on Good Labelling Practice for Pesticides, FAO (1995), available at http://www.fao.org/ag/AGP/AGPP/Pesticid/Code/Download/label.pdf
6 See http://www.unece.org/trans/danger/publi/ghs/ghs_rev03/03files_e.html. The categories for oral and dermal routes are used.
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PART II GUIDELINES TO CLASSIFICATION OF PESTICIDES BY HAZARD
The main section of the guidelines consists of five tables preceded by notes on their use. In the tables, active ingredients (technical grade) have been classified as follows:
Table 1 EXTREMELY HAZARDOUS (Class Ia) active ingredients (technical grade) of pesticides .............................................................................................................. 19
Table 2 HIGHLY HAZARDOUS (Class Ib) active ingredients (technical grade) of pesticides .............................................................................................................. 21
Table 3 MODERATELY HAZARDOUS (Class II) active ingredients (technical grade) of pesticides .................................................................................. 24
Table 4 SLIGHTLY HAZARDOUS (Class III) active ingredients (technical grade) of pesticides .............................................................................................................. 34
Table 5 Active ingredients unlikely to present acute hazard in normal use ......................... 39
The tables are arranged in alphabetical order.
In addition, the following tables show the details stated:
Table 6 Active ingredients not included in the Classification and believed to be obsolete or discontinued for use as pesticides ........................................................ 47
Table 7 Pesticides subject to the prior informed consent (PIC) procedure .......................... 51
Table 8 List of gaseous or volatile fumigants not classified under the WHO- Recommended classification of pesticides by hazard ............................................. 53
ANNEX How to find the hazard class of a formulation ......................................................... 54
INDEX by CAS number ........................................................................................................ 57
by name of active ingredient .................................................................................... 65
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NOTES ON THE USE OF THE TABLES IN CLASSIFICATION
The final classification of any product is intended to be by formulationThe classification given in the tables below is of active ingredients, and only forms the starting point for the final classification of an actual formulation. It is by far preferable that the final classification of a formulation should be based on toxicity data obtained on that formulation by the manufacturer: the criteria set out in the table of the Classification in Part I are then applied to this first-hand data. Only if this is not available should the formula be used, as shown in Part I on page 4 to extrapolate the LD50 of the formulation from that of the technical product. In this event, the single oral or dermal value of the LD50 given in the tables below should be used in the formula. See also the Annex on page 54.
The following important points should be noted.
1. While the classification deals only with the acute risk to health, evaluations of other effects, including cancer, have been completed for many compounds for registration purposes. Where other effects have been shown to occur in man, these are noted in the ‘Remarks’ column and may have in some cases resulted in an adjusted classification.
2. Wherever possible, the data are listed under internationally approved common names, or if such names are not at present available, under nationally approved names. Some other common names appear in the alphabetic index pp. 65-78. Trade names are not given since there are many of these.
3. A list of references that may be used for the identification of pesticides is given at the end of these introductory notes, and the manufacturer should always assist by specifying any existing approved or common names for his product.
4. It is not possible to include classification of mixtures of pesticides in the guidelines: very many of these are marketed with varying concentrations of active constituents. There are three possible approaches to the classification of mixtures - in order of preference:
(a) require the formulator to obtain reliable acute oral and dermal toxicity data for rats on the actual mixture as marketed: or
(b) classify the formulation according to the most hazardous constituent of the mixture as if that constituent was present in the same concentration as the total concentration of all active constituents: or
(c) apply the formula:
CT
CT
CT T
a
a
b
b
z
z m
+ + ≡… 100
Where C = the % concentrations of constituent A, B ... Z in the mixture T = the oral LD50 values of constituents A, B ...Z Tm = the oral LD50 value of the mixture.
The formula can also be used for dermal toxicities provided that this information is available on the same species for all constituents. The use of this formula does not take into account any potentiation or protective phenomena.
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5. In the tables below, single figures have been given as LD50 values for classification purposes, using the route as described in the table. Where several LD50 values have been published, the lowest deemed reliable is used. Where a sex difference occurs in LD50 values, the value for the more sensitive sex is used. A number of adjustments to Classification have been made in respect of some pesticides and these are explained. A borderline case has been classified in the more or less hazardous class after consideration of its toxicology and use experience.
6. In the former WHO Classification scheme pesticides were classified on the basis of the physical state of the technical product. A distinction between liquids and solids is no longer made.
7. In Table 5, a number of pesticides are listed as unlikely to present any acute hazard in normal use. The WHO classification is open-ended but it is clear that there must be a point at which the acute hazard posed by the use of these compounds is so low as to be negligible provided that the precautions are taken that should be used in dealing with any chemical. In compiling this table, it has been assumed that this point is an LD50 of 5000 mg/kg bw or greater (in line with the upper limit for classification in the GHS). However, it should not be overlooked that in formulations of these technical products, solvents or vehicles may present a greater hazard than the actual pesticide and therefore classification of a formulation in one of the higher hazard classes may be necessary.
8. The WHO Classification is not limited to chemical pesticides. Biological pesticides can also be included if a suitable evaluation is available (Bacillus thuringiensis is included based on Environmental Health Criteria Document 217).
9. The toxicity data for pyrethroids is highly variable according to isomer ratios, the vehicle used for oral administration, and the husbandry of the test animals e.g. fasting prior to dosing. The variability is reflected in the prefix ‘c’ before LD50 values. The single LD50 value chosen for classification purposes is generally based on administration in corn oil and can be much lower than that in aqueous solutions. This underlines the need for classification by formulation if the classification is to reflect true hazard.
ENTRIES AND ABBREVIATIONS USED IN THE TABLES
New information since the previous edition is indicated by italics.
Column 1: Common name. [ISO] denotes common name of the active ingredient approved by the International Organization for Standardization. Such names are, when available, preferred by WHO to all other common names. However, attention is drawn to the fact that some of these names may not be acceptable for national use in some countries. If the letters ISO appear within parentheses (ISO), this indicates that ISO has standardized (or is in the process of standardizing) the name of the base, but not the name of the derivative listed in column 1. For example, fentin acetate (ISO) indicates that fentin is an ISO name, but fentin acetate is not. ISO* denotes pending ISO approval of the name. C denotes chemical, trivial, or other common name.
Column 2: CAS Registry number: The number for the chemical, not those for e.g. different esters or salts are given.
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Column 3: UN number refers to the UN Recommendations on the transport of dangerous goods, Eleventh revision (1999). This is given only for active ingredients in Tables 1, 2, 3 or 4, since so few ingredients in Table 5 have UN numbers. The UN number refers only to the active ingredient; formulations are likely to have different numbers, since the ingredient may, for example, be dissolved in a solvent - and liquid products have different UN numbers, which depends on their flammability.
Column 4: Chemical type. Only a limited number of chemical types are shown. Most have some significance in the sense that they may have a common antidote, or may be confused in the nomenclature with other chemical types e.g. thiocarbamates are not cholinesterase inhibitors and do not have the same effects as carbamates. Chemical type is also a determinant of the UN numbering system. These chemical classifications are included only for convenience, and do not represent a recommendation on the part of the World Health Organization as to the way in which the pesticides should be classified. It should, furthermore, be understood that some pesticides may fall into more than one type.
AS Arsenic compound OP Organophosphorus compoundBP Bipyridylium derivative OT Organotin compoundC Carbamate PAA Phenoxyacetic acid derivativeCO Coumarin derivative PZ PyrazoleCU Copper compound PY PyrethroidHG Mercury compound T Triazine derivativeNP Nitrophenol derivative TC ThiocarbamateOC Organochlorine compound
Column 5: Physical state. Refers only to the active ingredient. L denotes liquid, including solids with a melting point below 50oC; oil denotes oily liquids and S solids, including waxes. The physical state may affect the exposure potential, and thus the absorbed amount of the chemical, and was taken into account when determining classification under the previous scheme.
Column 6: Main use. In most cases only a single use is given. This is only for identification purposes and does not exclude other uses.
AC acaricide L larvicideAP aphicide M molluscicideB bacteriostat (soil) MT miticideFM fumigant N nematocideF fungicide, other than for seed O other use for plant pathogens treatment PGR plant growth regulatorFST fungicide, for seed treatment R rodenticideH herbicide RP( ) repellant (species)I insecticide -S applied to soil: not used with herbicides IGR insect growth regulator or plant growth regulatorsIx ixodicide (for tick control) SY synergist
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Column 7: GHS: This column indicates the classification of the pesticide according to “The Globally Harmonized System of Classification and Labelling of Chemicals” (GHS)7. The value shown in the column is the Acute Toxic Hazard Category according to the GHS criteria, which in turn is derived from the acute toxicity estimate value for the substance. In the majority of cases the acute toxicity estimate will be the experimentally-derived LD50 value for oral exposure. A comparison of the criteria (as LD50 values) used for the different classes in the former WHO Scheme or for GHS categories is shown in the tables below. The GHS table shows only a simplified summary; for full details of classification according to GHS the official publication of the GHS should be consulted.
Former WHO Classification Scheme
Class LD50 for the rat (mg/kg body weight)
Oral DermalSolids Liquids Solids Liquids
Ia Extremely hazardous 5 or less 20 or less 10 or less 40 or lessIb Highly hazardous 5 - 50 20 - 200 10-100 40 – 400II Moderately hazardous 50 - 500 200 - 2000 100-1000 400 – 4000III Slightly hazardous Over 500 Over 2000 Over 1000 Over 4000
GHS Classification
GHS Category Classification criteria
Oral DermalLD50
a
(mg/kg bw)Hazard
StatementLD50
b
(mg/kg bw)Hazard Statement
Category 1 < 5 Fatal if swallowed < 50 Fatal in contact
with skin
Category 2 5 - 50 Fatal if swallowed 50 - 200 Fatal in contact
with skin
Category 3 50 - 300 Toxic if swallowed 200 - 1000 Toxic in contact
with skin
Category 4 300 - 2000 Harmful if swallowed 1000 - 2000 Harmful in contact
with skin
Category 5 2000 - 5000 May be harmful if swallowed 2000 - 5000 May be harmful in
contact with skina For oral data the rat is the preferred species, though data from other species may be appropriate when
scientifically justifiedb For dermal data the rat or rabbit are the preferred species, though data from other species may be appropriate
when scientifically justified
7 See http://www.unece.org/trans/danger/publi/ghs/ghs_rev03/03files_e.html. The categories for oral and dermal routes are used
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The former WHO Classification scheme applied different criteria to liquids and solids, but the GHS does not make a similar distinction and applies the same criteria. The GHS cut-off values for Category 2 and Category 3 are lower than the values which applied to liquids under the former WHO scheme, such that some liquids allocated to Class Ib would be placed in the lower GHS Category 3 (specifically pesticides with oral LD50 values in the range 50-200 mg/kg bw). In aligning the WHO scheme with the GHS criteria there was no intention to “lower” the classification of pesticides previously considered to be “Highly hazardous”. Therefore, the classification of this limited number of liquid pesticides has been adjusted such that they remain in Class Ib. The revised criteria for the WHO classification scheme are shown in Part I (page 5).
Column 8: LD50. The LD50 value is a statistical estimate of the number of mg of toxicant per kg of body weight required to kill 50% of a large population of test animals: the rat is used unless otherwise stated. Usually a single value, but sometimes a range is given. “c” preceding the value indicates that it is a value within a wider than usual range, adopted for classification purposes. When several different values are reported in the literature, the lowest is reported and used as the basis of classification, unless there are clear indications that a higher value is more reliable. Oral route values are used unless the dermal route values place the compound in a more hazardous class, or unless the dermal values are significantly lower than the oral values, although in the same class. Dermal LD50 values are indicated with the letter D.
Column 9: Remarks. This column is used to indicate cases in which the classification of a technical product has been adjusted (i.e., the oral LD50 value is not directly used as the basis of classification); Major irritant properties are also noted although they do not affect the classification. Sources of further information may also be given here: DS denotes a WHO/FAO Data Sheet on Pesticides, EHC an Environmental Health Criteria monograph, HSG a Health and Safety Guide, IARC IARC Monographs on the Evaluation of Carcinogenic Risks to Humans, ICSC an International Chemical Safety Card, JMPR an evaluation by the Joint FAO/WHO Meeting on Pesticide Residues and JECFA an evaluation by the the Joint FAO/WHO Expert Committee on Food Additives. These publications (with the exception of IARC Monographs) can be found on the IPCS web site (http://www.who.int/ipcs/).
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REFERENCES
Armstrong Lowe, D. and Stiles, A.R. (1973) Pesticides - nomenclature, specifications, analysis, use and residues in food, Bull. Wld. Hlth Org., 49, 169-204.
CICAD 6. Concise International Chemical Assessment Document 6 Biphenyl. Geneva, International Programme on Chemical Safety, 37 pp. 1999.
CICAD 13. Concise International Chemical Assessment Document 13 Triphenyltin compounds. Geneva, International Programme on Chemical Safety, 40 pp. 1999.
CICAD 40. Concise International Chemical Assessment Document 40 Formaldehyde. Geneva, In-ternational Programme on Chemical Safety, 75 pp. 2002.
CICAD 54. Concise International Chemical Assessment Document 40 Ethylene oxide. Geneva, In-ternational Programme on Chemical Safety, 57 pp. 2003.
CICAD 61. Concise International Chemical Assessment Document 61 Hydrogen cyanide and cyanides: Human health aspects. Geneva, International Programme on Chemical Safety, 67 pp. 2004.
DS. Pesticide Data Sheets. IPCS, Geneva, World Health Organization. See http://www.who.int/ipcs/publications/pds/en/index.html
Environmental Health Criteria 29 2,4-Dichlorophenoxyacetic Acid (2,4-D), Geneva, International Programme on Chemical Safety, 151 pp. 1984.
Environmental Health Criteria 34 Chlordane, Geneva, International Programme on Chemical Safety, 82 pp. 1984.
Environmental Health Criteria 38 Heptachlor, Geneva, International Programme on Chemical Safe-ty, 81 pp. 1984
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Environmental Health Criteria 40 Endosulfan, Geneva, International Programme on Chemical Safe-ty, 109 pp. 1984.
Environmental Health Criteria 41 Quintozene, Geneva, International Programme on Chemical Safe-ty, 38 pp. 1984
Environmental Health Criteria 42 Tecnazene, Geneva, International Programme on Chemical Safety, 23 pp. 1984.
Environmental Health Criteria 43 Chlordecone, Geneva, International Programme on Chemical Safety, 57 pp. 1984.
Environmental Health Criteria 44 Mirex, Geneva, International Programme on Chemical Safety, 70 pp. 1984.
Environmental Health Criteria 45 Campechlor, Geneva, International Programme on Chemical Safe-ty, 66 pp. 1984.
Environmental Health Criteria 63 Organophosphorus Insecticides, Geneva, International Programme on Chemical Safety, 181 pp. 1986.
Environmental Health Criteria 64 Carbamate Pesticides, Geneva, International Programme on Chemical Safety, 136 pp. 1986.
Environmental Health Criteria 66 Kelevan, Geneva, International Programme on Chemical Safety, 32 pp. 1984.
Environmental Health Criteria 67 Tetradifon, Geneva, International Programme on Chemical Safety, 47 pp. 1986.
Environmental Health Criteria 71 Pentachlorophenol, Geneva, International Programme on Chemi-cal Safety, 236 pp. 1987.
Environmental Health Criteria 73 Phosphine and Selected Metal Phosphides, Geneva, International Programme on Chemical Safety, 100 pp. 1988.
Environmental Health Criteria 76 Thiocarbamate Pesticides, Geneva, International Programme on Chemical Safety, 49 pp. 1988.
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Environmental Health Criteria 78 Dithiocarbamate Pesticides, Ethylenethiourea, and propylenethio-urea, Geneva, International Programme on Chemical Safety, 140 pp. 1988.
Environmental Health Criteria 79 Dichlorvos, Geneva, International Programme on Chemical Safe-ty, 157 pp. 1989.
Environmental Health Criteria 82 Cypermethrin, Geneva, International Programme on Chemical Safety, 154 pp. 1989.
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Environmental Health Criteria 87 Allethrins, Geneva, International Programme on Chemical Safety, 75 pp. 1989.
Environmental Health Criteria 90 Dimethoate, Geneva, International Programme on Chemical Safe-ty, 85 pp. 1989.
Environmental Health Criteria 92 Resmethrins; Geneva, International Programme on Chemical Safety, 79 pp. 1989.
Environmental Health Criteria 94 Permethrin; Geneva, International Programme on Chemical Safe-ty, 125 pp. 1990.
Environmental Health Criteria 95 Fenvalerate; Geneva, International Programme on Chemical Safe-ty, 121 pp. 1990.
Environmental Health Criteria 96 d-Phenothrin; Geneva, International Programme on Chemical Safety, 64 pp. 1990.
Environmental Health Criteria 97 Deltamethrin; Geneva, International Programme on Chemical Safety, 133 pp. 1990.
Environmental Health Criteria 98 Tetramethrin; Geneva, International Programme on Chemical Safety, 69 pp. 1990.
Environmental Health Criteria 99 Cyhalothrin; Geneva, International Programme on Chemical Safe-ty, 106 pp. 1990.
Environmental Health Criteria 121; Aldicarb; Geneva, International Programme on Chemical Safety, 130 pp. 1991.
Environmental Health Criteria 123 Alpha- and Beta Hexachlorocyclohexanes, Geneva, International Programme on Chemical Safety, 170 pp. 1992.
Environmental Health Criteria 124 Lindane; Geneva, International Programme on Chemical Safety, 208 pp. 1991.
Environmental Health Criteria 132 Trichlorfon; Geneva, International Programme on Chemical Safety, 162 pp. 1992.
Environmental Health Criteria 133 Fenitrothion; Geneva, International Programme on Chemical Safety, 184 pp. 1992.
Environmental Health Criteria 142 Alpha-cypermethrin; Geneva, International Programme on Chemical Safety, 112 pp. 1992.
Environmental Health Criteria 145 Methyl Parathion; Geneva, International Programme on Chemi-cal Safety, 244 pp. 1993.
Environmental Health Criteria 147 Propachlor, Geneva, International Programme on Chemical Safe-ty, 110 pp. 1993.
Environmental Health Criteria 148 Benomyl; Geneva, International Programme on Chemical Safety, 135 pp. 1993.
Environmental Health Criteria 149 Carbendazim; Geneva, International Programme on Chemical Safety, 132 pp. 1993.
Environmental Health Criteria 153 Carbaryl; Geneva, International Programme on Chemical Safety, 358 pp. 1993.
Environmental Health Criteria 158 Amitrole; Geneva, International Programme on Chemical Safety, 107 pp. 1994.
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Environmental Health Criteria 159 Glyphosate; Geneva, International Programme on Chemical Safety, 177 pp. 1994.
Environmental Health Criteria 166 Methyl bromide; Geneva, International Programme on Chemical Safety, 324 pp. 1995.
Environmental Health Criteria 175 Anticoagulant Rodenticides; Geneva, International Programme on Chemical Safety, 121 pp. 1995.
Environmental Health Criteria 176 1,2-dichloroethane (ethylene dichloride); (2nd edition), Geneva, International Programme on Chemical Safety, 148 pp. 1995.
Environmental Health Criteria 177 1,2-dibromoethane (ethylene dibromide); Geneva, International Programme on Chemical Safety, 146 pp. 1996.
Environmental Health Criteria 178 Methomyl; Geneva, International Programme on Chemical Safe-ty, 150 pp. 1996.
Environmental Health Criteria 182 Thallium, Geneva, International Programme on Chemical Safety, 274 pp. 1996.
Environmental Health Criteria 183 Chlorothalonil, Geneva, International Programme on Chemical Safety, 145 pp. 1996.
Environmental Health Criteria 184 Diflubenzuron, Geneva, International Programme on Chemical Safety, 164 pp. 1996.
Environmental Health Criteria 195 Hexachlorobenzene, Geneva, International Programme on Chem-ical Safety, 160 pp. 1997.
Environmental Health Criteria 198 Diazinon, Geneva, International Programme on Chemical Safety, 140 pp. 1998
Environmental Health Criteria 200 Copper, Geneva, International Programme on Chemical Safety, 360 pp. 1998.
Environmental Health Criteria 217 Bacillus thuringiensis, Geneva, International Programme on Chemical Safety, 105 pp. 1999.
Environmental Health Criteria 220 Dinitro-ortho-cresol, Geneva, International Programme on Chemical Safety, 87 pp. 2000.
Environmental Health Criteria 224 Arsenic and arsenic compounds (Second edition), Geneva, Inter-national Programme on Chemical Safety, 521 pp. 2001.
FAO (1985), Guidelines on good labelling practice for pesticides, Rome, Food and Agriculture Or-ganization of the United Nations, 36 pp.
FAO (1990), International Code of Conduct on the Distribution and Use of Pesticides: Rome, Food and Agriculture Organization of the United Nations, 34 pp.
HSGs. Health and Safety Guides, IPCS, Geneva, World Health Organization. See http://www.who.int/ipcs/publications/hsg/en/index.html
IARC 4. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans Volume 4 Some Aromatic Amines, Hydrazyne and Related Substances, N-Nitroso Compounds and Miscellaneous Alkylation Agents. Lyon, International Agency for Research on Cancer, 286 pp. 1974
IARC 7. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans Volume 12 Some Carbamates, Thiocarbamates and Carbazides. Lyon, International Agency for Research on Can-cer, 282 pp. 1976
IARC 41. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans Volume 41 Some Halogenated Hydrocarbons and Pesticide Exposures. Lyon, International Agency for Research on Cancer, 434 pp. 1986.
IARC 53. Monographs on the Evaluation of Carcinogenic Risks to Humans Volume 53 Occupational Exposures in Insecticide Application and some Pesticides. Lyon, International Agency for Re-search on Cancer, 612 pp. 1991.
IARC 62. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans Volume 6 Wood dust and formaldehyde. Lyon, International Agency for Research on Cancer, 405 pp. 1995.
15
IARC 63. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans Volume 63 Dry cleaning , Some Chlorinated Solvents and Other Industrial Chemicals. Lyon, International Agen-cy for Research on Cancer, 558 pp. 1995.
IARC 71. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans Volume 71 Re-evaluatio of some organic chemicals, hydrazine and hydrogen peroxide, Parts I-III1. Lyon, Inter-national Agency for Research on Cancer, 1586 pp. 1999.
IARC 73. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans Volume 73 some chemicals taht cause tumours of the kidney or urinary bladder in rodents and some other sub-stances. Lyon, International Agency for Research on Cancer, 674 pp. 1999.
IARC 79. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans Volume 79 some thyrotropic agents. Lyon, International Agency for Research on Cancer, 763 pp. 2001.
IARC 84. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans Volume 84 some drinking water disinfectants and contaminants, including arsenic. Lyon, International Agency for Research on Cancer, 512 pp. 2004.
IARC Suppl 7. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans Voverall evaluations of carcinogenicity: An updating of IARC Monographs volumes 1 to 42. Lyon, Inter-national Agency for Research on Cancer, 440 pp. 1987.
International Organization for Standardization (1981) Pesticides and other agrochemicals - common names, Geneva (ISO 1750). (Copies available only from national standards institutes).
ICSCs. International Chemical Safety Cards, IPCS, Geneva, World Health Organization. See http://www.ilo.org/public/english/protection/safework/cis/products/icsc/index.htm
JECFA (1996) Toxicological evaluation of certain veterinary drug residues in food prepared by the forty-seventh meeting of the Joint FAO/WHO Expert Committee on Food Additives (JECFA), WHO food additives series 38, Geneva, World Health Organization.
JECFA (1997) Toxicological evaluation of vertain veterinary drug residues in food prepared by the forty-eighth meeting of the Joint FAO/WHO Expert Committee on Food Additives (JECFA), WHO food additives series 39, Geneva, World Health Organization.
JECFA (2000a) Toxicological evaluation of vertain veterinary drug residues in food prepared by the fifty-second meeting of the Joint FAO/WHO Expert Committee on Food Additives (JECFA), WHO food additives series 43, Geneva, World Health Organization.
JECFA (2000b) Toxicological evaluation of vertain veterinary drug residues in food prepared by the fifty-fourth meeting of the Joint FAO/WHO Expert Committee on Food Additives (JECFA), WHO food additives series 45, Geneva, World Health Organization.
JECFA (2002) Toxicological evaluation of vertain veterinary drug residues in food prepared by the fifty-eighth meeting of the Joint FAO/WHO Expert Committee on Food Additives (JECFA), WHO food additives series 49, Geneva, World Health Organization.
JECFA (2003) Toxicological evaluation of vertain veterinary drug residues in food prepared by the sixtieth meeting of the Joint FAO/WHO Expert Committee on Food Additives (JECFA), WHO food additives series 51, Geneva, World Health Organization.
JMPR (1965a) Evaluation of the toxicity of pesticide residues in food. FAO Meeting Report, No. PL/1965/10/1; WHO/Food Add./27.65.
JMPR (1965b) Evaluation of the hazards to consumers resulting from the use of fumigants in the protection of food. FAO Meeting Report, No. PL/1965/10/2; WHO/Food Add./28.65.
JMPR (1967) Evaluation of some pesticide residues in food. FAO/PL:CP/15; WHO/Food Add./67.32.
JMPR (1969) 1968 Evaluation of some pesticide residues in food. FAO/PL:1968/M/9/1; WHO/Food Add./69.35.
JMPR (1971) 1970 Evaluations of some pesticide residues in food. AGP:1970/M/12/1; WHO/Food Add./71.42.
JMPR (1972) 1971 Evaluations of some pesticide residues in food. AGP:1971/M/9/1; WHO Pesti-cide Residues Series No. 1.
16
JMPR (1974) 1973 Evaluations of some pesticide residues in food. FAO/AGP/1973/M/9/1; WHO Pesticide Residues Series, No. 3.
JMPR (1978) Pesticide residues in food: 1977 evaluations. FAO Plant Production and Protection Paper 10 Sup.
JMPR (1979) Pesticide residues in food: 1978 evaluations. FAO Plant Production and Protection Paper 15 Sup.
JMPR (1980) Pesticide residues in food: 1979 evaluations. FAO Plant Production and Protection Paper 20 Sup.
JMPR (1982) Pesticide residues in food:1981 evaluations. FAO Plant Production and Protection Paper 42.
JMPR (1983) Pesticide residues in food: 1982 evaluations. FAO Plant Production and Protection Paper 49.
JMPR (1985a) Pesticide residues in food: 1983 evaluations. FAO Plant Production and Protection Paper 61.
JMPR (1985b) Pesticide residues in food – 1984. Report of the Joint Meeting on Pesticide Residues. FAO Plant Production and Protection Paper 62.
JMPR (1985c) Pesticide residues in food – 1984 evaluations. FAO Plant Production and Protection Paper 67.
JMPR (1986a) Pesticide residues in food – 1985. Report of the Joint Meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and a WHO Expert Group on Pesti-cide Residues. FAO Plant Production and Protection Paper 68.
JMPR (1986b) Pesticide residues in food – 1985 evaluations. Part II – Toxicology. FAO Plant Pro-duction and Protection Paper 72/2.
JMPR (1986c) Pesticide residues in food – 1986. Report of the Joint Meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and a WHO Expert Group on Pesti-cide Residues. FAO Plant Production and Protection Paper 77.
JMPR (1987a) Pesticide residues in food – 1986 evaluations. Part II – Toxicology. FAO Plant Pro-duction and Protection Paper 78/2.
JMPR (1987b) Pesticide residues in food – 1987. Report of the Joint Meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and a WHO Expert Group on Pesti-cide Residues. FAO Plant Production and Protection Paper 84.
JMPR (1988) Pesticide residues in food – 1987 evaluations. Part II – Toxicology. FAO Plant Produc-tion and Protection Paper 86/2.
JMPR (1989) Pesticide residues in food – 1988 evaluations. Part II – Toxicology. FAO Plant Produc-tion and Protection Paper 93/2.
JMPR (1990) Pesticide residues in food – 1989 evaluations. Part II – Toxicology. FAO Plant Produc-tion and Protection Paper 100/2.
JMPR (1991) Pesticide residues in food – 1990 evaluations. Part II – Toxicology. World Health Or-ganization (WHO/PCS/91.47).
JMPR (1992) Pesticide residues in food – 1991 evaluations. Part II – Toxicology. World Health Or-ganization (WHO/PCS/92.52).
JMPR (1993) Pesticide residues in food – 1992 evaluations. Part II – Toxicology. World Health Or-ganization (WHO/PCS/93.34).
JMPR (1994) Pesticide residues in food – 1993 evaluations. Part II – Toxicology. World Health Or-ganization (WHO/PCS/94.4).
JMPR (1995a) Pesticide residues in food – 1994. Report of the Joint Meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and a WHO Expert Group on Pesti-cide Residues. FAO Plant Production and Protection Paper, 127.
JMPR (1995b) Pesticide residues in food – 1994 evaluations. Part II – Toxicology. World Health Organization (WHO/PCS/95.2).
17
JMPR (1996a) Pesticide residues in food – 1995. Report of the Joint Meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and WHO Toxicological and Envi-ronmental Core Assessment Groups. FAO Plant Production and Protection Paper, 133.
JMPR (1996b) Pesticide residues in food – 1995 evaluations. Part II – Toxicological and Environ-mental. Geneva, World Health Organization (WHO/PCS/96.48).
JMPR (1997a) Pesticide residues in food – 1996. Report of the Joint Meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Core Assessment Group. FAO Plant Production and Protection Paper, 140.
JMPR (1997b) Pesticide residues in food – 1996 evaluations. Part II – Toxicological and Environ-mental. Geneva, World Health Organization (WHO/PCS/97.1).
JMPR (1998a) Pesticide residues in food – 1997. Report of the Joint Meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Core Assessment Group. FAO Plant Production and Protection Paper, 145.
JMPR (1998b) Pesticide residues in food – 1997 evaluations. Part II – Toxicological and Environ-mental. Geneva, World Health Organization (WHO/PCS/98.6).
JMPR (1999) Pesticide residues in food – 1998 evaluations. Part II – Toxicological. Geneva, World Health Organization (WHO/PCS/99.18).
JMPR (2000) Pesticide residues in food – 1999 evaluations. Part II – Toxicological and Environmen-tal. Geneva, World Health Organization (WHO/PCS/00.4).
JMPR (2001) Pesticide residues in food – 2000. Report of the Joint Meeting of the FAO Panel of Ex-perts on Pesticide Residues in Food and the Environment and the WHO Core Assessment Group. FAO Plant Production and Protection Paper 167.
JMPR (2002) Pesticide residues in food – 2001. Joint FAO/WHO Meeting on Pesticide Residues.Evaluations 2001. Part II Toxicological. IPCS International Programme on Chemical Safety & World Health Organization, Geneva
JMPR (2003a) Pesticide residues in food – 2002. Report 2002 of the Joint Meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Core Assessment Group. FAO Plant Production and Protection Paper 172.
JMPR (2003b) Pesticide residues in food – 2002. Joint FAO/WHO Meeting on Pesticide Residues.Evaluations 2002. Part II Toxicological. IPCS International Programme on Chemical Safety & World Health Organization, Geneva
JMPR (2004a) Pesticide residues in food – 2003. Report of the Joint Meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Core Assessment Group. FAO Plant Production and Protection Paper 176.
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JMPR (2005a) Pesticide residues in food – 2004. Report of the Joint Meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Core Assessment Group. FAO Plant Production and Protection Paper 178.
JMPR (2005b) Pesticide residues in food – 2005. Report of the Joint Meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Core Assessment Group. FAO Plant Production and Protection Paper 183.
JMPR (2006a) Pesticide residues in food – 2004. Joint Meeting of the FAO Panel of Experts on Pes-ticide Residues in Food and the Environment and the WHO Core Assessment Group. Evaluations 2004. Part II Toxicological. IPCS, World Health Organization, Geneva (WHO/PCS/06.1).
JMPR (2006b) Pesticide residues in food – 2005. Joint Meeting of the FAO Panel of Experts on Pes-ticide Residues in Food and the Environment and the WHO Core Assessment Group. Evaluations 2005. Part II Toxicological. IPCS, World Health Organization, Geneva.
JMPR (2006c) Pesticide residues in food – 2006. Report of the Joint Meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Core Assessment Group on Pesticide Residues. FAO Plant Production and Protection Paper 187.
18
JMPR (2007) Pesticide residues in food – 2007. Report of the Joint Meeting of the FAO Panel of Ex-perts on Pesticide Residues in Food and the Environment and the WHO Core Assessment Group on Pesticide Residues. FAO Plant Production and Protection Paper 191.
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19
Tabl
e 1.
Ext
rem
ely
haza
rdou
s (C
lass
Ia) t
echn
ical
gra
de a
ctiv
e in
gred
ient
s in
pes
ticid
es
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Ald
icar
b [I
SO]
116-
06-3
2757
CS
I-S
10.
93D
S 53
; EH
C 1
21; H
SG 6
4; IA
RC
53;
ICSC
94;
JMPR
199
3, 1
996a
Bro
difa
coum
[ISO
]56
073-
10-0
3027
CO
SR
10.
3D
S 57
; EH
C 1
75; H
SG 9
3
Bro
mad
iolo
ne [I
SO]
2877
2-56
-730
27C
OS
R1
1.12
DS
88; E
HC
175
; HSG
94
Bro
met
halin
[ISO
]63
333-
35-7
2588
SR
12
Cal
cium
cya
nide
[C]
592-
01-8
1575
SFM
239
Adj
uste
d cl
assi
ficat
ion;
see
note
1; I
CSC
407
Cap
tafo
l [IS
O]
2425
-06-
1S
F5
5000
Adj
uste
d cl
assi
ficat
ion;
see
note
2; H
SG 4
9; IA
RC
53;
ICSC
119
; JM
PR 1
978,
198
6a; s
ee n
ote
3
Chl
oret
hoxy
fos [
ISO
]54
593-
83-8
3018
OP
LI
11.
8Ex
trem
ely
haza
rdou
s by
skin
con
tact
(LD
50 =
12.
5 m
g/kg
); IC
SC 1
681
Chl
orm
epho
s [IS
O]
2493
4-91
-630
18O
PL
I2
7IC
SC 1
682
Chl
orop
haci
none
[ISO
]36
91-3
5-8
2588
SR
13.
1D
S 62
; EH
C 1
75
Dife
naco
um [I
SO]
5607
3-07
-530
27C
OS
R1
1.8
EHC
175
; HSG
95
Dife
thia
lone
[ISO
]10
4653
-34-
125
88S
R1
0.56
EHC
175
Dip
haci
none
[ISO
]82
-66-
625
88S
R1
2.3
EHC
175
Dis
ulfo
ton
[ISO
]29
8-04
-430
18O
PL
I1
2.6
DS
68; J
MPR
199
2, 1
997a
; IC
SC 1
408
EPN
21
04-6
4-5
2783
OP
SI
214
See
note
4; I
CSC
753
Etho
prop
hos [
ISO
]13
194-
48-4
3018
OP
LI-
S2
D26
DS
70; J
MPR
200
0; IC
SC 1
660;
[Ora
l LD
50 =
33
mg/
kg]
Floc
oum
afen
9003
5-08
-830
27S
R1
0.25
EHC
175
; IC
SC 1
267
Hex
achl
orob
enze
ne [I
SO]
118-
74-1
2729
OC
SFS
T5
D10
000
Adj
uste
d cl
assi
ficat
ion
(not
es 3
and
5);
IAR
C 7
9; IC
SC 8
95; E
HC
195
Mer
curic
chl
orid
e [I
SO]
7487
-94-
716
24H
GS
F-S
11
See
note
3; I
CSC
979
Mev
inph
os [I
SO]
2671
8-65
-030
18O
PL
I1
D4
DS
14; I
CSC
924
; JM
PR 1
998b
; [O
ral L
D50
= 3
.7 m
g/kg
]
Para
thio
n [I
SO]
56-3
8-2
3018
OP
LI
213
See
note
3; D
S 6;
HSG
74;
IAR
C 3
0, S
uppl
. 7; I
CSC
6; J
MPR
199
6b
Para
thio
n-m
ethy
l [IS
O]
298-
00-0
3018
OP
LI
214
See
note
3; D
S 7;
EH
C 1
45; H
SG 7
5; IC
SC 6
26; J
MPR
198
5c, 1
996b
20
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Phen
ylm
ercu
ry a
ceta
te [I
SO]
62-3
8-4
1674
HG
SFS
T2
24A
djus
ted
clas
sific
atio
n; se
e no
tes 3
and
6; I
CSC
540
Phor
ate
[ISO
]29
8-02
-230
18O
PL
I1
2D
S 75
; JM
PR 1
997b
, 200
5; IC
SC 1
060
Phos
pham
idon
1317
1-21
-630
18O
PL
I2
7Se
e no
te 3
; DS
74; I
CSC
189
; JM
PR 1
987b
C
AS
Nos
for E
and
Z is
omer
s 297
-99-
4 an
d 23
783-
98-4
Sodi
um fl
uoro
acet
ate
[C]
62-7
4-8
2629
SR
10.
2D
S 16
; IC
SC 4
84
Sulfo
tep
[ISO
]36
89-2
4-5
1704
OP
LI
15
ICSC
985
Tebu
pirim
fos [
ISO
*]96
182-
53-5
3018
OP
LI
11.
3Ex
trem
ely
haza
rdou
s by
skin
con
tact
(LD
50 9
.4 m
g/kg
in ra
ts)
Terb
ufos
[ISO
]13
071-
79-9
3018
OP
LI-
S1
c2JM
PR 1
991,
200
4
EHC
= E
nviro
nmen
tal
Hea
lth C
riter
ia M
onog
raph
; D
S =
Pest
icid
e D
ata
Shee
t; H
SG =
Hea
lth a
nd S
afet
y G
uide
; IA
RC
= I
AR
C M
onog
raph
s on
the
Eva
luat
ion
of
Car
cino
geni
c R
isks
to H
uman
s; IC
SC =
Inte
rnat
iona
l Che
mic
al S
afet
y C
ard;
JMPR
= E
valu
atio
n by
the
Join
t FA
O/W
HO
Mee
ting
on P
estic
ide
Res
idue
s.
Not
es to
Cla
ss Ia
1.
Cal
cium
cya
nide
is in
Cla
ss Ia
as i
t rea
cts w
ith m
oist
ure
to p
rodu
ce h
ydro
gen
cyan
ide
gas.
The
gas i
s not
cla
ssifi
ed u
nder
the
WH
O sy
stem
(see
Tab
le 8
).2.
C
apta
fol i
s car
cino
geni
c in
bot
h ra
ts a
nd m
ice.
3.
The
inte
rnat
iona
l tra
de o
f cap
tafo
l, he
xach
loro
benz
ene,
mer
cury
com
poun
ds, p
arat
hion
, par
athi
on-m
ethy
l, an
d ph
osph
amid
on is
regu
late
d by
the
Rot
terd
am c
onve
ntio
n on
Prio
r Inf
orm
ed C
onse
nt (s
ee h
ttp://
ww
w.pi
c.in
t/), w
hich
ent
ered
into
forc
e on
24
Febr
uary
200
4. S
ee T
able
7, p
. 51
4.
EPN
has
bee
n re
porte
d as
cau
sing
del
ayed
neu
roto
xici
ty in
hen
s.5.
H
exac
hlor
oben
zene
has
cau
sed
a se
rious
out
brea
k of
por
phyr
ia in
hum
ans.
The
use
and
prod
uctio
n of
hex
achl
orob
enze
ne is
sev
erel
y re
stric
ted
by th
e St
ockh
olm
co
nven
tion
on p
ersi
sten
t org
anic
pol
luta
nts,
whi
ch e
nter
ed in
to fo
rce
on 1
7 M
ay, 2
004.
See
http
://w
ww.
pops
.int/
6.
Phen
ylm
ercu
ry a
ceta
te is
hig
hly
toxi
c to
mam
mal
s and
ver
y sm
all d
oses
hav
e pr
oduc
ed re
nal l
esio
ns: t
erat
ogen
ic in
the
rat.
THE
FIN
AL
CLA
SSIF
ICAT
ION
OF
AN
Y P
RO
DU
CT
DEP
END
S O
N IT
S FO
RM
ULA
TIO
NSe
e Pa
ges 7
& 8
, and
the A
nnex
21
Tabl
e 2.
Hig
hly
haza
rdou
s (C
lass
Ib) t
echn
ical
gra
de a
ctiv
e in
gred
ient
s in
pes
ticid
es
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Acr
olei
n [C
]10
7-02
-810
92L
H2
29EH
C 1
27; H
SG 6
7; IA
RC
63;
ICSC
90
Ally
l alc
ohol
[C]
107-
18-6
1098
LH
364
Hig
hly
irrita
nt to
skin
and
eye
s; IC
SC 9
5; A
djus
ted
clas
sific
atio
n
(see
not
e 3)
Azi
npho
s-et
hyl [
ISO
]26
42-7
1-9
2783
OP
SI
212
DS
72; J
MPR
197
4A
zinp
hos-
met
hyl [
ISO
]86
-50-
027
83O
PS
I2
16D
S 59
; IC
SC 8
26; J
MPR
199
2, 2
009b
Bla
stic
idin
-S20
79-0
0-7
2588
SF
216
But
ocar
boxi
m [I
SO]
3468
1-10
-229
92C
LI
315
8JM
PR 1
986a
; Adj
uste
d cl
assi
ficat
ion
(see
not
e 3)
But
oxyc
arbo
xim
[ISO
]34
681-
23-7
2992
CL
I3
D28
8Ad
just
ed c
lass
ifica
tion
(see
not
e 3)
Cad
usaf
os [I
SO]
9546
5-99
-930
18O
PL
N,I
237
JMPR
199
2C
alci
um a
rsen
ate
[C]
7778
-44-
115
73A
SS
I2
20EH
C 1
8, 2
24; I
AR
C 8
4; IC
SC 7
65; J
MPR
196
9C
arbo
fura
n [I
SO]
1563
-66-
227
57C
SI
28
DS
56; I
CSC
122
; JM
PR 1
997b
, 200
3b, 2
009a
; See
not
e 2.
Chl
orfe
nvin
phos
[ISO
]47
0-90
-630
18O
PL
I2
31IC
SC 1
305;
JMPR
199
5b3-
Chl
oro-
1,2-
prop
aned
iol
[C]
96-2
4-2
2689
LR
311
2Ad
just
ed c
lass
ifica
tion
(see
not
es 1
and
3)
Cou
map
hos [
ISO
]56
-72-
427
83O
PS
AC
,MT
27.
1IC
SC 4
22; J
MPR
199
1C
oum
atet
raly
l [IS
O]
5836
-29-
330
27C
OS
R2
16C
yflut
hrin
[ISO
]68
359-
37-5
PYS
I2
c15
JMPR
200
8; S
ee n
ote
9, p
. 8Be
ta-c
yflut
hrin
[ISO
]68
359-
37-5
PYS
I2
c11
JMPR
200
8; S
ee n
ote
9, p
. 8Ze
ta-c
yper
met
hrin
[ISO
]52
315-
07-8
3352
PYL
I3
c86
See
note
9, p
. 8; H
SG 2
2; IC
SC 2
46; J
MPR
200
8; A
djus
ted
clas
sific
atio
n (s
ee n
ote
3)D
emet
on-S
-met
hyl [
ISO
]91
9-86
-830
18O
PL
I2
40D
S 61
, EH
C 1
97; I
CSC
705
; JM
PR 1
990
Dic
hlor
vos [
ISO
]62
-73-
730
18O
PL
I3
56Vo
latil
e, D
S 2;
EH
C 7
9; H
SG 1
8; IA
RC
20,
53;
ICSC
690
; JM
PR
1994
; Adj
uste
d cl
assi
ficat
ion
(see
not
e 3)
Dic
roto
phos
[ISO
]14
1-66
-230
18O
PL
I2
22IC
SC 8
72D
inot
erb
[ISO
]14
20-0
7-1
2779
NP
SH
225
22
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
DN
OC
[ISO
]53
4-52
-127
79N
PS
I-S,
H2
25JM
PR 1
965a
; EH
C 2
20; I
CSC
462
. See
not
e 2.
Edife
npho
s [IS
O]
1710
9-49
-830
18O
PL
F3
150
JMPR
198
2. A
djus
ted
clas
sific
atio
n (s
ee n
ote
3)Et
hiof
enca
rb [I
SO]
2997
3-13
-529
92C
LI
320
0JM
PR 1
983.
Adj
uste
d cl
assi
ficat
ion
(see
not
e 3)
Fam
phur
52-8
5-7
2783
OP
SI
248
Fena
mip
hos [
ISO
]22
224-
92-6
2783
OP
SN
215
DS
92; I
CSC
483
; JM
PR 1
998b
, 200
3bFl
ucyt
hrin
ate
[ISO
]70
124-
77-5
3352
PYL
I3
c67
JMPR
198
6b; s
ee n
ote
9, p
.8; A
djus
ted
clas
sific
atio
n (s
ee n
ote
3)Fl
uoro
acet
amid
e [C
]64
0-19
-725
88S
R2
13IC
SC 1
434.
See
not
e 2
Form
etan
ate
[ISO
]22
259-
30-9
2757
CS
AC
221
Fura
thio
carb
6590
7-30
-429
92C
LI-
S2
42H
epte
noph
os [I
SO]
2356
0-59
-030
18O
PL
I3
96Ad
just
ed c
lass
ifica
tion
(see
not
e 3)
Isox
athi
on [I
SO]
1885
4-04
-830
18O
PL
I3
112
Adju
sted
cla
ssifi
catio
n (s
ee n
ote
3)Le
ad a
rsen
ate
[C]
7784
-40-
916
17A
SS
L2
c10
EHC
18,
224
; IA
RC
84;
ICSC
911
; JM
PR 1
969
Mec
arba
m [I
SO]
2595
-54-
230
18O
PO
ilI
236
JMPR
198
7aM
ercu
ric o
xide
[ISO
]21
908-
53-2
1641
HG
SO
218
ICSC
981
; CIC
AD
50.
See
not
e 2
Met
ham
idop
hos [
ISO
]10
265-
92-6
2783
OP
SI
230
HSG
79;
ICSC
176
; JM
PR 1
991,
200
3b; S
ee n
ote
2M
ethi
dath
ion
[ISO
]95
0-37
-830
18O
PL
I2
25JM
PR 1
998b
; IC
SC 1
659
Met
hioc
arb
[ISO
]20
32-6
5-7
2757
CS
I2
20JM
PR 1
999
Met
hom
yl [I
SO]
1675
2-77
-527
57C
SI
217
DS
55, E
HC
178
; HSG
97;
ICSC
177
, JM
PR 1
989,
200
2M
onoc
roto
phos
[ISO
]69
23-2
2-4
2783
OP
SI
214
See
note
2; H
SG 8
0; IC
SC 1
81; J
MPR
199
6bN
icot
ine
[ISO
]54
-11-
516
54L
1D
50IC
SC 5
19O
met
hoat
e [I
SO]
1113
-02-
630
18O
PL
I2
50JM
PR 1
997a
Oxa
myl
[ISO
]23
135-
22-0
2757
CS
I2
6D
S 54
; JM
PR 1
986b
, 200
3bO
xyde
met
on-m
ethy
l [IS
O]
301-
12-2
3018
OP
LI
365
JMPR
199
0, 2
003b
; Adj
uste
d cl
assi
ficat
ion
(see
not
e 3)
Paris
gre
en [C
]12
002-
03-8
1585
AS
SL
222
Cop
per-a
rsen
ic c
ompl
exPe
ntac
hlor
ophe
nol [
ISO
]87
-86-
531
55S
I,F,H
2D
80Se
e no
te 2
; Irr
itant
to sk
in; E
HC
71;
HSG
19;
IAR
C 2
0, 5
3; IC
SC 6
9
23
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Prop
etam
phos
[ISO
]31
218-
83-4
3018
OP
LI
310
6Ad
just
ed c
lass
ifica
tion
(see
not
e 3)
Sodi
um a
rsen
ite [C
]77
84-4
6-5
1557
AS
SR
210
EHC
224
; IA
RC
84;
ICSC
160
3So
dium
cya
nide
[C]
143-
33-9
1689
SR
26
ICSC
111
8; C
ICA
D 6
1St
rych
nine
[C]
57-2
4-9
1692
SR
216
ICSC
197
Teflu
thrin
7953
8-32
-233
49PY
SI-
S2
c22
See
note
9, p
. 8Th
alliu
m su
lfate
[C]
7446
-18-
617
07S
R2
11D
S 10
, EH
C 1
82; I
CSC
336
Thio
fano
x [I
SO]
3919
6-18
-427
57C
SI-
S2
8Th
iom
eton
[ISO
]64
0-15
-330
18O
PO
ilI
312
0D
S 67
; IC
SC 5
80; J
MPR
198
0; A
djus
ted
clas
sific
atio
n (s
ee n
ote
3)Tr
iazo
phos
[ISO
]24
017-
47-8
3018
OP
LI
382
JMPR
199
4, 2
003b
; Adj
uste
d cl
assi
ficat
ion
(see
not
e 3)
Vam
idot
hion
[ISO
]22
75-2
3-2
3018
OP
LI
310
3JM
PR 1
989;
ICSC
758
; Adj
uste
d cl
assi
ficat
ion
(see
not
e 3)
War
farin
[ISO
]81
-81-
230
27C
OS
R2
10D
S 35
, EH
C 1
75; H
SG 9
6; IC
SC 8
21Zi
nc p
hosp
hide
[C]
1314
-84-
717
14S
R2
45D
S 24
, EH
C 7
3; IC
SC 6
02
EHC
= E
nviro
nmen
tal H
ealth
Crit
eria
Mon
ogra
ph; D
S= P
estic
ide D
ata S
heet
; HSG
= H
ealth
and
Safe
ty G
uide
; IA
RC
= IA
RC
Mon
ogra
phs o
n th
e Eva
luat
ion
of C
arci
noge
nic
Ris
ks to
Hum
ans;
ICSC
= In
tern
atio
nal C
hem
ical
Saf
ety
Car
d; JM
PR =
Eva
luat
ion
by th
e Jo
int F
AO
/WH
O M
eetin
g on
Pes
ticid
e R
esid
ues.
Not
es to
Cla
ss Ib
1.
3-C
hlor
o-1,
2-pr
opan
edio
l in
nonl
etha
l dos
age
is a
ster
ilant
for m
ale
rats
. Thi
s com
poun
d is
als
o kn
own
as a
lpha
chl
orhy
drin
.2.
Th
e in
tern
atio
nal
trade
of
carb
ofur
an, D
NO
C, fl
uoro
acet
amid
e, m
ercu
ry c
ompo
unds
, met
ham
idop
hos,
mon
ocro
toph
os a
nd p
enta
chlo
roph
enol
is
regu
late
d by
the
R
otte
rdam
con
vent
ion
on P
rior I
nfor
med
Con
sent
(see
http
://w
ww.
pic.
int/)
, whi
ch e
nter
ed in
to fo
rce
on 2
4 Fe
brua
ry 2
004.
See
Tab
le 7
, p. 5
1.3.
A
s a
prec
autio
nary
mea
sure
, the
cla
ssifi
catio
n of
cer
tain
liqu
id p
estic
ides
has
bee
n ad
just
ed to
avo
id th
ose
pest
icid
es b
eing
ass
igne
d to
a le
ss h
azar
dous
Cla
ss in
the
proc
ess o
f alig
ning
the W
HO
Cla
ssifi
catio
n w
ith th
e G
HS.
Det
ails
of h
ow th
e WH
O C
lass
ifica
tion
has b
een
alig
ned
with
the
GH
S A
cute
Tox
icity
Haz
ard
Cat
egor
ies a
re
desc
ribed
in th
e in
trodu
ctor
y no
tes f
or P
art I
I.
THE
FIN
AL
CLA
SSIF
ICAT
ION
OF
AN
Y P
RO
DU
CT
DEP
END
S O
N IT
S FO
RM
ULA
TIO
NSe
e Pa
ges 7
& 8
, and
the A
nnex
24
Tabl
e 3.
Mod
erat
ely
haza
rdou
s (C
lass
II) t
echn
ical
gra
de a
ctiv
e in
gred
ient
s in
pes
ticid
es
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Ace
phat
e [I
SO]
3056
0-19
-1O
PS
I4
945
JMPR
199
1, 2
003b
, 200
6b; I
CSC
748
Aci
fluor
fen
[ISO
]50
594-
66-6
SH
413
70St
rong
irrit
ant t
o ey
esA
lach
lor [
ISO
]15
972-
60-8
2588
SH
493
0Se
e no
te 1
; DS
86; I
AR
C 1
9, 3
6, 6
3; IC
SC 3
71A
lany
carb
[ISO
]83
130-
01-2
CS
I4
330
Alle
thrin
[ISO
]58
4-79
-2PY
Oil
I4
c685
See
note
9, p
age
8; E
HC
87;
HSG
24;
ICSC
212
; JM
PR 1
965a
Am
etry
n [I
SO]
834-
12-8
TS
H4
110
Am
itraz
[ISO
]33
089-
61-1
SA
C4
800
ICSC
98;
JMPR
199
9A
nilo
fos [
ISO
]64
249-
01-0
OP
SH
447
2A
zaco
nazo
le60
207-
31-0
SF
430
8A
zam
ethi
phos
[ISO
]35
575-
96-3
OP
SI
410
10A
zocy
clot
in [I
SO]
4108
3-11
-827
86O
TS
AC
380
JMPR
199
0, 1
995b
, 200
6bB
endi
ocar
b [I
SO]
2278
1-23
-327
57C
SI
355
DS
52B
enfu
raca
rb [I
SO]
8256
0-54
-129
92C
LI
320
5B
ensu
lide
[ISO
]74
1-58
-229
02L
H3
270
ICSC
383
Ben
sulta
p [I
SO]
1760
6-31
-4S
I4
1100
Ben
tazo
ne [I
SO]
2505
7-89
-0S
H4
1100
HSG
48;
ICSC
828
; JM
PR 1
999,
200
5B
ifent
hrin
8265
7-04
-333
49PY
SI
3c5
5JM
PR 1
993
Bila
nafo
s [IS
O]
7104
8-99
-2S
H3
268
Bio
alle
thrin
[C]
584-
79-2
PYL
I4
c700
See
note
2; n
ote
9, p
. 8; I
CSC
227
Bro
mox
ynil
[ISO
]16
89-8
4-5
2588
SH
319
0B
rom
ucon
azol
e11
6255
-48-
2S
F4
365
ICSC
126
4B
rono
pol
52-5
1-7
SB
325
4IC
SC 4
15B
utam
ifos [
ISO
]36
335-
67-8
OP
LH
463
0B
utra
lin [I
SO]
3362
9-47
-9S
H4
1049
25
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
But
roxy
dim
[ISO
]13
8164
-12-
2S
H4
1635
But
ylam
ine
[ISO
]13
952-
84-6
1992
LF
438
0Ir
ritan
t to
skin
; IC
SC 4
01; J
MPR
198
2, 1
985b
Car
bary
l [IS
O]
63-2
5-2
2757
CS
I3
c300
DS
3; E
HC
153
; HSG
78;
IAR
C 1
2, S
uppl
.7; I
CSC
121
; JM
PR
1997
b, 2
002
Car
bosu
lfan
[ISO
]55
285-
14-8
2992
CL
I3
250
JMPR
198
7a, 2
004
Car
tap
[ISO
]15
263-
53-3
SI
432
5EH
C 7
6; JM
PR 1
996a
Chl
oral
ose
[C]
1587
9-93
-3S
R4
400
Chl
orda
ne [I
SO]
57-7
4-9
2996
OC
LI
446
0Se
e no
tes 3
and
4; D
S 36
; EH
C 3
4; H
SG 1
3; IA
RC
79;
ICSC
740
; JM
PR 1
995a
Chl
orfe
napy
r [IS
O]
1224
53-7
3-0
SI,M
T4
441
Chl
orm
equa
t (ch
lorid
e) [I
SO]
999-
81-5
SPG
R4
670
ICSC
781
; JM
PR 2
000
Chl
oroa
cetic
aci
d [C
]79
-11-
817
51S
H4
650
Irrit
ant t
o sk
in a
nd e
yes;
dat
a re
fer t
o so
dium
salt;
ICSC
235
Chl
orph
oniu
m c
hlor
ide
[ISO
]11
5-78
-625
88S
PGR
317
8Ir
ritan
t to
skin
and
eye
sC
hlor
pyrif
os [I
SO]
2921
-88-
227
83O
PS
I3
135
DS
18; I
CSC
851
; JM
PR 2
000
Clo
maz
one
[ISO
]81
777-
89-1
LH
413
69C
oppe
r hyd
roxi
de [C
]20
427-
59-2
CU
SF
410
00C
oppe
r oxy
chlo
ride
[C]
1332
-40-
7C
US
F4
1440
Cop
per s
ulfa
te [C
]77
58-9
8-7
CU
SF
330
0IC
SC 7
514-
CPA
[ISO
]12
2-88
-3PA
AS
PGR
485
0C
upro
us o
xide
[C]
1317
-39-
1C
US
F4
470
ICSC
421
, EH
C 2
00C
yana
zine
[ISO
]21
725-
46-2
TS
H3
288
ICSC
391
Cya
noph
os [I
SO]
2636
-26-
2O
PL
I4
610
Cyh
alot
hrin
[ISO
]68
085-
85-8
3352
PYO
ilIx
3c1
44Se
e no
te 9
, p. 8
; EH
C 9
9; H
SG 3
8; IC
SC 8
58; J
MPR
198
5c;
JEC
FA 2
000b
Cyh
exat
in [I
SO]
1312
1-70
-5O
TS
AC
326
5EH
C 1
5; JM
PR 1
995b
, 200
6bC
ymox
anil
[ISO
]57
966-
95-7
SF
411
96
26
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Cyp
erm
ethr
in [I
SO]
5231
5-07
-833
52PY
LI
3c2
50Se
e no
te 9
, p. 8
; DS
58; E
HC
82;
HSG
22;
ICSC
246
; JEC
FA 1
996
Alp
ha-c
yper
met
hrin
[ISO
]67
375-
30-8
3349
PYS
I3
c79
See
note
9, p
8; E
HC
142
; JEC
FA 1
996;
JM
PR 2
008
Cyp
heno
thrin
[(1R
)-is
omer
s]
[ISO
]39
515-
40-7
3352
PYL
I4
318
Cyp
roco
nazo
le94
361-
06-5
SF
410
202,
4-D
[ISO
]94
-75-
733
45PA
AS
H4
375
DS
37; E
HC
29,
84;
HSG
5; I
AR
C 4
1, S
uppl
. 7; I
CSC
33;
JMPR
19
98b
Daz
omet
[ISO
]53
3-74
-4S
F-S
464
0Ir
ritan
t to
skin
and
eye
s; IC
SC 7
862,
4-D
B94
-82-
6S
H4
700
DD
T [I
SO]
50-2
9-3
2761
OC
SI
311
3Se
e no
tes 3
and
4; D
S 21
; EH
C 9
, 83;
IAR
C 5
3; IC
SC 3
4; JM
PR
1985
c, 2
001
Del
tam
ethr
in [I
SO]
5291
8-63
-533
49PY
SI
3c1
35Se
e no
te 9
, p. 8
; DS
50; E
HC
97;
HSG
30;
IAR
C 5
3; IC
SC 2
47;
JMPR
200
1D
iazi
non
[ISO
]33
3-41
-530
18O
PL
I4
300
DS
45, E
HC
198
; IC
SC 1
37; J
MPR
199
4, 2
002,
200
8D
icam
ba [I
SO]
1918
-00-
9S
H4
1707
ICSC
139
Dic
hlor
oben
zene
[C]
106-
46-7
SFM
450
0-50
00M
ixtu
re o
f iso
mer
s: o
rtho
(3) 9
5-50
-1, m
eta
(3) 5
41-7
3-1,
par
a (2
B)
106-
46-7
; IC
SC 3
7D
ichl
orop
hen
[ISO
]97
-23-
4O
CS
F4
1250
Dic
hlor
prop
[ISO
]75
47-6
6-2
SH
480
0IC
SC 3
8D
iclo
fop
[ISO
]40
483-
25-2
SH
456
5D
icof
ol [I
SO]
115-
32-2
OC
SA
C4
c690
DS
81; I
AR
C 3
0; IC
SC 7
52; J
MPR
199
3D
ifeno
cona
zole
[ISO
]11
9446
-68-
3S
F4
1453
JMPR
200
9bD
ifenz
oqua
t [IS
O]
4322
2-48
-625
88S
H4
470
Dim
epip
erat
e [I
SO]
6143
2-55
-1TC
SH
494
6D
imet
hach
lor [
ISO
]50
563-
36-5
SH
416
00D
imet
hipi
n [I
SO]
5529
0-64
-7S
H4
1180
JMPR
200
0, 2
005
27
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Dim
ethe
nam
id [I
SO]
8767
4-68
-8L
H4
371
LD50
of P
isom
er is
429
mg/
kg b
w; J
MPR
200
6bD
imet
hyla
rsin
ic a
cid
[C]
75-6
0-5
1572
AS
SH
413
50D
imet
hoat
e [I
SO]
60-5
1-5
2783
OP
SI
3c1
50D
S 42
; EH
C 9
0; H
SG 2
0; IC
SC 7
41; J
MPR
199
7b, 2
004
Din
icon
azol
e [I
SO]
8365
7-24
-3S
F4
639
Din
obut
on [I
SO]
973-
21-7
2779
NP
SA
C,F
314
0D
inoc
ap [I
SO]
3930
0-45
-3N
PS
AC
,F4
980
ICSC
881
; JM
PR 1
999
Dip
hena
mid
[ISO
]95
7-51
-7S
H4
970
ICSC
763
Diq
uat [
ISO
]27
64-7
2-9
2781
BP
SH
323
1Ir
ritan
t to
skin
and
eye
s and
dam
ages
nai
ls; D
S 40
; EH
C 3
9; H
SG
52; J
MPR
199
4; IC
SC 1
363
Dith
iano
n [I
SO]
3347
-22-
6S
F4
640
JMPR
199
3D
odin
e [I
SO]
2439
-10-
3S
F4
1000
JMPR
200
1En
dosu
lfan
[ISO
]11
5-29
-727
61O
CS
I3
80D
S 15
; EH
C 4
0; H
SG 1
7; IC
SC 7
42; J
MPR
199
9En
doth
al-s
odiu
m [(
ISO
)]12
5-67
-925
88S
H3
51EP
TC [I
SO]
759-
94-4
TCL
H4
1652
ICSC
469
Esfe
nval
erat
e [I
SO]
6623
0-04
-433
49PY
SI
387
JMPR
200
3b; I
CSC
151
6Et
hion
[ISO
]56
3-12
-230
18O
PL
I3
208
ICSC
888
; JM
PR 1
991
Fena
zaqu
in [I
SO]
1209
28-0
9-8
2588
SA
C3
134
Feni
troth
ion
[ISO
]12
2-14
-5O
PL
I4
503
DS
30; E
HC
133
; HSG
65;
ICSC
622
; JM
PR 2
001
Feno
buca
rb37
66-8
1-2
CS
I4
620
Feno
thio
carb
[ISO
]62
850-
32-2
CS
L4
1150
Fenp
ropi
din
[ISO
]67
306-
00-7
LF
414
40Fe
npro
path
rin [I
SO]
6425
7-84
-733
49PY
SI
3c6
6Se
e no
te 9
, p. 8
; JM
PR 1
994
Fenp
yrox
imat
e [I
SO]
1340
98-6
1-6
SAC
324
5H
ighl
y to
xic
by in
hala
tion
(LC
50 =
0.2
1-0.
36 m
g/l);
JM
PR 2
007
Fent
hion
[ISO
]55
-38-
930
18O
PL
I,L3
D58
6D
S 23
; IC
SC 6
55; J
MPR
199
8bFe
ntin
ace
tate
[(IS
O)]
900-
95-8
2786
OT
SF
312
5D
S 22
; EH
C 1
5; JM
PR 1
992;
CIC
AD
13
28
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Fent
in h
ydro
xide
[(IS
O)]
76-8
7-9
2786
OT
SF
310
8D
S 22
; EH
C 1
5; IC
SC 1
283;
JMPR
199
2; C
ICAD
13
Fenv
aler
ate
[ISO
]51
630-
58-1
3352
PYL
I4
c450
See
note
9, p
. 8; D
S 90
; EH
C 9
5, H
SG 3
4; IA
RC
53;
ICSC
273
; JM
PR 1
986c
Ferim
zone
[ISO
]89
269-
64-7
SF
472
5Fi
pron
il12
0068
-37-
325
88S
I3
92JM
PR 1
998b
, 200
1; IC
SC 1
503
Fluc
hlor
alin
[ISO
]33
245-
39-5
SH
415
50Fl
ufen
acet
[ISO
]14
2459
-58-
3S
H4
600
May
cau
se sk
in se
nsiti
zatio
nFl
uoro
glyc
ofen
7750
1-60
-1S
H4
1550
Flur
prim
idol
[ISO
]56
425-
91-3
SPG
R4
709
Flus
ilazo
le85
509-
19-9
SF
467
2JM
PR 1
996b
, 200
9bFl
utria
fol [
ISO
]76
674-
21-0
SF,
FST
411
40Fl
uxof
enim
[ISO
]88
485-
37-4
oil
H4
670
Fom
esaf
en [I
SO]
7217
8-02
-0O
CS
H4
1250
Fube
ridaz
ole
[ISO
]38
78-1
9-1
SF
433
6Fu
rala
xyl [
ISO
]57
646-
30-7
SF
494
0G
amm
a-H
CH
[ISO
], Li
ndan
e58
-89-
927
61O
CS
I3
88IC
SC 5
3; JM
PR 2
003b
; See
not
e 3
Glu
fosi
nate
[ISO
]53
369-
07-6
SH
416
25JM
PR 2
000
Gua
zatin
e10
8173
-90-
6S
FST
323
0LD
50 v
alue
refe
rs to
tria
ceta
te; J
MPR
199
8bH
alox
yfop
6980
6-34
-4S
H4
300
JMPR
199
6b, 2
008
(incl
udes
Hal
oxyf
op-R
and
est
ers)
HC
H [I
SO]
608-
73-1
2761
OC
SI
310
0Se
e no
tes 3
, 4 a
nd 5
; EH
C 1
23; I
AR
C 5
, 20,
42;
ICSC
487
; JM
PR
1974
Hex
azin
one
[ISO
]51
235-
04-2
SH
416
90H
ydra
met
hyln
on67
485-
29-4
SI
412
00Im
azal
il [I
SO]
3555
4-44
-025
88S
F3
227
ICSC
130
3; JM
PR 2
001,
200
2, 2
006b
Imid
aclo
prid
[ISO
]13
8261
-41-
3S
I4
450
JMPR
200
2; IC
SC 1
501
29
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Imin
octa
dine
[ISO
]13
516-
27-3
SF
330
0Ey
e irr
itant
Indo
xaca
rb [I
SO]
1735
84-4
4-6
SI
326
8JM
PR 2
006b
; LD
50 a
pplie
s to
3:1
mix
ture
of i
som
ers i
n co
mm
erci
al
use
Ioxy
nil [
ISO
]16
89-8
3-4
2588
SH
311
0IC
SC 9
00Io
xyni
l oct
anoa
te [(
ISO
)]38
61-4
7-0
SH
439
0Ip
robe
nfos
2608
7-47
-8S
F4
600
Isop
roca
rb [I
SO]
2631
-40-
527
57C
SI
440
3Is
opro
thio
lane
[ISO
]50
512-
35-1
SF
411
90Is
opro
turo
n [I
SO]
3412
3-59
-6S
H4
1800
Isou
ron
[ISO
]55
861-
78-4
SH
463
0La
mbd
a-cy
halo
thrin
2164
-08-
133
49PY
SI
3c5
6Se
e no
te 9
, p. 8
; EH
C 1
42; H
SG 3
8; J
MPR
200
9b; I
CSC
859
MC
PA [I
SO]
94-7
4-6
PAA
SH
470
0IA
RC
30,
41;
ICSC
54
MC
PA-th
ioet
hyl [
ISO
]25
319-
90-8
PAA
SH
479
0M
CPB
[ISO
]94
-81-
5S
H4
680
Mec
opro
p [I
SO]
7085
-19-
0S
H4
930
ICSC
55
Mec
opro
p-P
[ISO
]16
484-
77-8
SH
410
50M
eflui
dide
[ISO
]53
780-
34-0
SH
419
20M
epiq
uat [
ISO
]15
302-
91-7
SPG
R4
1490
Mer
curo
us c
hlor
ide
[C]
1011
2-91
-120
25H
GS
F3
210
See
note
3; I
CSC
984
; CIC
AD 5
0M
etal
axyl
[ISO
]57
837-
19-1
SF
467
0JM
PR 1
983,
200
3bM
etal
dehy
de [I
SO]
108-
62-3
SM
322
7D
S 93
Met
amitr
on [I
SO]
4139
4-05
-2S
H4
1183
ICSC
136
1M
etam
-sod
ium
[(IS
O)]
137-
42-8
2771
SF-
S3
285
Met
cona
zole
[ISO
]12
5116
-23-
6S
F4
660
Met
hacr
ifos [
ISO
]62
610-
77-9
OP
LI
467
8JM
PR 1
991
30
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Met
hasu
lfoca
rb [I
SO]
6695
2-49
-627
57S
F3
112
Met
hyla
rson
ic a
cid
[ISO
]12
4-58
-3A
SS
H4
1800
ICSC
755
; EH
C 2
24M
ethy
l iso
thio
cyan
ate
[ISO
]55
6-61
-625
88S
F-S
372
Skin
and
eye
irrit
ant;
see
note
6M
etol
carb
[ISO
]11
29-4
1-5
CS
I3
268
Met
ribuz
in [I
SO]
2108
7-64
-9S
H4
322
ICSC
516
Mol
inat
e [I
SO]
2212
-67-
1TC
LH
472
0M
yclo
buta
nil
8867
1-89
-0S
F4
1600
JMPR
199
3N
abam
[ISO
]14
2-59
-627
71S
F4
395
Goi
troge
nic
in ra
tsN
aled
[ISO
]30
0-76
-530
18O
PL
I4
430
DS
39; I
CSC
925
2-N
apth
ylox
yace
tic a
cid
[ISO
]12
0-23
-0S
PGR
460
0N
itrap
yrin
[ISO
]19
29-8
2-4
SB
-S4
1072
ICSC
165
8N
uarim
ol [I
SO]
6328
4-71
-9S
F4
1250
Oct
hilin
one
[ISO
]26
530-
20-1
SF
414
70O
xadi
xyl
7773
2-09
-3S
F4
1860
Pacl
obut
razo
l [IS
O]
7673
8-62
-0S
PGR
413
00JM
PR 1
989
Para
quat
[ISO
]19
10-4
2-5
2781
BP
SH
315
0Se
e no
te 7
; DS
4; E
HC
39;
HSG
51;
ICSC
5; J
MPR
198
7a, 2
004
Pebu
late
[ISO
]11
14-7
1-2
TCL
H4
1120
Pend
imet
halin
[ISO
]40
487-
42-1
SH
410
50Pe
rmet
hrin
[ISO
]52
645-
53-1
3352
PYL
I4
c500
See
note
9, p
. 8; D
S 51
; EH
C 9
4; H
SG 3
3; IA
RC
53;
ICSC
312
; JM
PR 2
000
Phen
thoa
te [I
SO]
2597
-03-
730
18O
PL
I4
c400
DS
48; J
MPR
198
5cPh
osal
one
[ISO
]23
10-1
7-0
2783
OP
SI
312
0IC
SC 7
97; J
MPR
199
8b, 2
002
Phos
met
[ISO
]73
2-11
-627
83O
PS
I,AC
311
3IC
SC 5
43; J
MPR
199
9, 2
004
Phox
im [I
SO]
1481
6-18
-3O
PL
I4
D19
75D
S 31
; JEC
FA 2
000a
Pipe
roph
os [I
SO]
2415
1-93
-730
18O
Poi
lH
432
4
31
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Pirim
icar
b [I
SO]
2310
3-98
-227
57C
SA
P3
147
JMPR
198
3, 2
005
Pirim
ipho
s-m
ethy
l [IS
O]
2923
2-93
-7O
PL
I4
1667
DS
49; J
MPR
199
3, 2
008
Pral
leth
rin [I
SO]
2303
1-36
-933
52PY
oil
I4
460
Proc
hlor
az [I
SO]
6774
7-09
-5S
F4
1600
JMPR
198
5aPr
ofen
ofos
[ISO
]41
198-
08-7
3018
OP
LI
435
8JM
PR 1
991,
200
8Pr
opac
hlor
[ISO
]19
18-1
6-7
SH
415
00D
S 78
; EH
C 1
47; H
SG 7
7; JM
PR 2
002
Prop
anil
[ISO
]70
9-98
-8S
H4
c140
0IC
SC 5
52Pr
opic
onaz
ole
[ISO
]60
207-
90-1
LF
415
20JM
PR 1
988,
200
5Pr
opox
ur [I
SO]
114-
26-1
2757
CS
I3
95D
S 25
; IC
SC 1
91; J
MPR
199
0Pr
osul
foca
rb [I
SO]
5288
8-80
-9TC
LH
418
20Pr
othi
ofos
[ISO
]34
643-
46-4
OP
LI
492
5Py
racl
ofos
[ISO
]77
458-
01-6
3018
OP
LI
323
7Py
razo
phos
[ISO
]13
457-
18-6
2784
SF
443
5JM
PR 1
993
Pyra
zoxy
fen
[ISO
]71
561-
11-0
SH
416
44Py
reth
rins [
C]
8003
-34-
7L
I4
500-
1000
See
note
8; D
S 11
; JM
PR 2
000,
200
4; IC
SC 1
475
Pyrid
aben
[ISO
]96
489-
71-3
SA
C4
820
Pyrid
aphe
nthi
on11
9-12
-0O
PS
I4
769
Pyro
quilo
n [I
SO]
5736
9-32
-1S
F4
320
Qui
nalp
hos [
ISO
]13
593-
03-8
2783
OP
SI
362
Qui
nocl
amin
e [I
SO]
2797
-51-
5S
H4
1360
Qui
zalo
fop
7657
8-12
-6S
H4
1670
Qui
zalo
fop-
p-te
fury
l [IS
O]
1197
38-0
6-6
LH
410
12R
oten
one
[C]
83-7
9-4
2588
SI
313
2-15
00Se
e no
te 9
; HSG
73;
ICSC
944
Sim
etry
n [I
SO]
1014
-70-
6T
SH
418
30So
dium
chl
orat
e [I
SO]
7775
-09-
914
95S
H4
1200
ICSC
111
7
32
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Spiro
xam
ine
[ISO
]11
8134
-30-
8L
F4
500
Der
mal
LD
50 1
068
mg/
kg; m
ay c
ause
skin
sens
itisa
tion
Sulfl
uram
id [I
SO]
4151
-50-
2S
I4
543
2,3,
6-TB
A [I
SO]
50-3
1-7
SH
415
00TC
A [I
SO] (
acid
)76
-03-
918
39S
440
0Se
e no
te 5
to T
able
4, p
. 38;
ICSC
586
Tebu
cona
zole
[ISO
]10
7534
-96-
3S
F4
1700
JMPR
199
5bTe
bufe
npyr
ad [I
SO]
1191
68-7
7-3
SM
T4
595
Tebu
thiu
ron
[ISO
]34
014-
18-1
SH
464
4Te
rbum
eton
[ISO
]33
693-
04-8
TS
H4
483
Tetra
cona
zole
[ISO
]11
2281
-77-
3O
ilF
410
31Th
iacl
oprid
1119
88-4
9-9
SI
439
6JM
PR 2
008
Thio
benc
arb
[ISO
]28
249-
77-6
TCL
H4
1300
Thio
cycl
am [I
SO]
3189
5-22
-4S
I4
310
Thio
dica
rb [I
SO]
5966
9-26
-027
57C
SI
366
JMPR
200
1Th
iram
[ISO
]13
7-26
-8S
F4
560
DS
71; E
HC
78;
IAR
C 1
2, 5
3; IC
SC 7
57; J
MPR
199
3; S
ee n
ote
3Tr
alko
xydi
m [I
SO]
8782
0-88
-0S
H4
934
Tral
omet
hrin
6684
1-25
-633
49PY
SI
3c8
5Tr
iadi
mef
on [I
SO]
4312
1-43
-3S
F4
602
JMPR
198
6b, 2
005
Tria
dim
enol
[ISO
]55
219-
65-3
SFS
T4
900
JMPR
199
0, 2
005
Tria
zam
ate
[ISO
]11
2143
-82-
525
88S
AP
350
-100
Tric
hlor
fon
[ISO
]52
-68-
6O
PS
I3
250
DS
27; E
HC
132
; HSG
66;
IAR
C 3
0, S
uppl
7; I
CSC
585
; JM
PR
1979
; JEC
FA 2
000b
, 200
3Tr
iclo
pyr [
ISO
]55
335-
06-3
SH
471
0Tr
icyc
lazo
le [I
SO]
4181
4-78
-2S
F4
305
Trid
emor
ph [I
SO]
8141
2-43
-3O
ilF
465
0Tr
iflum
izol
e99
387-
89-0
SF
469
5IC
SC 1
252
33
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Uni
cona
zole
[ISO
]83
657-
22-1
SPG
R4
1790
XM
C26
55-1
4-3
CS
I4
542
Xyl
ylca
rb24
25-1
0-7
CS
I4
380
Zira
m [I
SO]
137-
30-4
SF
414
00Ir
ritan
t to
skin
; DS
73; E
HC
78;
IAR
C 1
2, 5
3; IC
SC 3
48; J
MPR
19
97b
EHC
= E
nviro
nmen
tal H
ealth
Crit
eria
Mon
ogra
ph; D
S= P
estic
ide D
ata S
heet
; HSG
= H
ealth
and
Safe
ty G
uide
; IA
RC
= IA
RC
Mon
ogra
phs o
n th
e Eva
luat
ion
of C
arci
noge
nic
Ris
ks to
Hum
ans;
ICSC
= In
tern
atio
nal C
hem
ical
Saf
ety
Car
d; JE
CFA
= E
valu
atio
n by
the
Join
t FA
O/W
HO
Exp
ert C
omm
ittee
on
Food
Add
itive
s; JM
PR =
Eva
luat
ion
by
the
Join
t FA
O/W
HO
Mee
ting
on P
estic
ide
Res
idue
s.
Not
es to
Cla
ss II
1.
Ala
chlo
r was
pre
viou
sly
clas
sifie
d as
a C
lass
Ia p
estic
ide
due
to it
s ca
rcin
ogen
icity
in ra
ts. H
owev
er m
echa
nist
ic s
tudi
es h
ave
indi
cate
d th
at tu
mor
s ar
e in
duce
d by
a
mec
hani
sm n
ot re
leva
nt to
hum
ans.
2.
Bio
alle
thrin
, es
biot
hrin
, es
biol
, an
d es
depa
lléth
rine
are
mem
bers
of
a se
ries;
the
ir to
xici
ty v
arie
s co
nsid
erab
ly w
ithin
thi
s se
ries,
acco
rdin
g to
con
cent
ratio
ns o
f is
omer
s.3.
Th
e in
tern
atio
nal t
rade
of c
hlor
dane
, DD
T, G
amm
a-H
CH
(lin
dane
), H
CH
, mer
cury
com
poun
ds a
nd th
iram
is re
gula
ted
by th
e R
otte
rdam
con
vent
ion
on P
rior I
nfor
med
C
onse
nt (s
ee h
ttp://
ww
w.pi
c.in
t/), w
hich
ent
ered
into
forc
e on
24
Febr
uary
200
4. S
ee T
able
7, p
. 51.
4.
The
prod
uctio
n an
d us
e of
chl
orda
ne, D
DT,
Gam
ma-
HC
H (l
inda
ne) a
nd H
CH
(spe
cific
ally
alp
ha-H
CH
and
bet
a-H
CH
) are
stric
tly li
mite
d by
the
Stoc
khol
m c
onve
ntio
n on
per
sist
ent o
rgan
ic p
ollu
tant
s, w
hich
ent
ered
into
forc
e on
17
May
, 200
4 an
d ha
s sub
sequ
ently
bee
n am
ende
d. S
ee h
ttp://
ww
w.po
ps.in
t/.5.
H
CH
: The
LD
50 v
arie
s acc
ordi
ng to
the
mix
ture
of i
som
ers.
The
valu
e sh
own
has b
een
chos
en, a
nd th
e te
chni
cal p
rodu
ct p
lace
d in
Cla
ss II
, as a
resu
lt of
the
cum
ulat
ive
prop
ertie
s of t
he b
eta
isom
er.
6.
The
mel
ting
poin
t of m
ethy
l iso
thio
cyan
ate
(S) i
s 35°
C.
7.
Para
quat
has
serio
us d
elay
ed e
ffect
s if a
bsor
bed.
It is
of r
elat
ivel
y lo
w h
azar
d in
nor
mal
use
but
may
be
fata
l if t
he c
once
ntra
ted
prod
uct i
s tak
en b
y m
outh
or s
prea
d on
th
e sk
in.
8.
Mix
ture
of c
ompo
unds
pre
sent
in P
yret
hrum
cin
erae
foliu
m a
nd o
ther
flow
ers.
9.
Com
poun
ds fr
om ro
ots o
f Der
ris a
nd L
onch
ocar
pus s
pp.
THE
FIN
AL
CLA
SSIF
ICAT
ION
OF
AN
Y P
RO
DU
CT
DEP
END
S O
N IT
S FO
RM
ULA
TIO
NSe
e Pa
ges 7
& 8
, and
the A
nnex
34
Tabl
e 4.
Slig
htly
haz
ardo
us (C
lass
III)
tech
nica
l gra
de a
ctiv
e in
gred
ient
s in
pes
ticid
es
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Ace
toch
lor [
ISO
]34
256-
82-1
LH
529
50A
lloxy
dim
5563
4-91
-8S
H5
2260
Am
mon
ium
sulfa
mat
e77
73-0
6-0
SH
539
00A
ncym
idol
[ISO
]12
771-
68-5
SPG
R5
4500
Asu
lam
[ISO
]33
37-7
1-1
SH
540
00A
trazi
ne [I
SO]
1912
-24-
9T
SH
4c2
000
DS
82; H
SG 4
7; IA
RC
53;
ICSC
99
Baci
llus t
huri
ngie
nsis
(Bt)
6803
8-71
-1S
I5
>400
0EH
C 2
17B
enal
axyl
[ISO
]71
626-
11-4
SF
542
00JM
PR 1
988,
200
6B
enaz
olin
[ISO
]38
13-0
5-6
SH
532
00Ir
ritan
t to
skin
and
eye
sB
enfu
resa
te68
505-
69-1
SH
520
31B
iphe
nyl
92-5
2-4
SF
532
80IC
SC 1
06B
ispy
ribac
1254
01-7
5-4
SH
526
35B
orax
[ISO
]13
03-9
6-4
SF
545
00IC
SC 5
67B
upiri
mat
e [I
SO]
4148
3-43
-6S
F5
c400
0B
upro
fezi
n [I
SO]
6932
7-76
-0S
I5
2200
JMPR
199
2B
utac
hlor
2318
4-66
-9L
H5
3300
But
ylat
e [I
SO]
2008
-41-
5TC
LF
5>4
000
Car
boxi
n [I
SO]
5234
-68-
4S
FST
538
20C
hino
met
hion
at [I
SO]
2439
-01-
2S
AC
,F5
2500
JMPR
198
8C
hlor
idaz
on [I
SO]
1698
-60-
8S
H5
2420
Chl
orim
uron
9928
3-00
-8S
H5
4102
Chl
orpy
rifos
met
hyl [
ISO
]55
98-1
3-0
OP
SI
5>3
000
DS
33; J
MPR
199
3C
hlor
thal
-dim
ethy
l [IS
O]
1861
-32-
1S
H5
>300
0C
hloz
olin
ate
8433
2-86
-5S
F5
>400
0
35
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Cin
met
hylin
8781
8-31
-3L
H5
3960
Clo
fent
ezin
e [I
SO]
7411
5-24
-5S
AC
5>
3200
JMPR
198
7a, 2
006b
Clo
pyra
lid57
754-
85-5
SH
543
00Se
vere
irrit
ant t
o ey
es; I
CSC
443
Cyc
loat
e [I
SO]
1134
-23-
2TC
LH
4>2
000
Cyc
loxy
dim
1012
05-0
2-1
SH
539
00JM
PR 1
993
Cyr
omaz
ine
6621
5-27
-8S
L5
3300
JMPR
199
1D
iafe
nthi
uron
[ISO
]80
060-
09-9
SA
C5
2068
Dic
hlob
enil
[ISO
]11
94-6
5-6
SH
531
60IC
SC 8
67D
ichl
orm
id37
764-
25-3
LH
520
80D
iclo
ran
99-3
0-9
SF
540
00IC
SC 8
71; J
MPR
199
9D
ieth
ylto
luam
ide
[ISO
]13
4-62
-3L
RP
(inse
ct)
4c2
000
DS
80
Difl
uben
zuro
n35
367-
38-5
SL
5>4
640
DS
77, E
HC
184
; HSG
99;
JMPR
200
2D
ifluf
enic
an [I
SO]
8316
4-33
-4S
H4
>200
0D
imef
uron
[ISO
]34
205-
21-5
SH
4>2
000
Dim
etha
met
ryn
[ISO
]22
936-
75-0
TL
H5
3000
Dim
ethi
rimol
5221
-53-
4S
F5
2350
Dim
etho
mor
ph [I
SO]
1104
88-7
0-5
SF
535
00JM
PR 2
009b
Din
itram
ine
[ISO
]29
091-
05-2
SH
530
00D
iuro
n [I
SO]
330-
54-1
SH
534
00D
odem
orph
[ISO
]15
93-7
7-7
LH
545
00Em
pent
hrin
[(1R
) iso
mer
s] [I
SO]
5440
6-48
-3PY
Oil
I5
>228
0Es
proc
arb
[ISO
]85
785-
20-2
TCL
H4
>200
0Sk
in a
nd e
ye ir
ritan
tEt
heph
on16
672-
87-0
SPG
R5
>400
0JM
PR 2
004;
200
3bEt
ridia
zole
[ISO
]25
93-1
5-9
LF
420
00
36
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Fena
rimol
[ISO
]60
168-
88-9
SF
525
00JM
PR 1
996b
Fenb
ucon
azol
e11
4369
-43-
6S
F4
>200
0JM
PR 1
998
Fenb
utat
in o
xide
[ISO
]13
356-
08-6
OT
SM
T5
2630
EHC
15;
JMPR
199
3Fe
npro
pim
orph
6756
4-91
-4oi
lF
535
15JM
PR 1
995b
, 200
2, 2
005
Flam
prop
-M90
134-
59-1
SF
5>3
000
Flua
zifo
p-p-
buty
l [IS
O]
8306
6-88
-0L
H5
2451
Fluf
enox
uron
1014
63-6
9-8
SI
5>3
000
Flur
ochl
orid
one
6121
3-25
-0S
H5
4000
tau-
Fluv
alin
ate
1028
51-0
6-9
PYoi
lI
5>3
000
Skin
and
eye
irrit
ant
Fosa
min
e [I
SO]
2595
4-13
-6O
PS
H5
2400
Gly
phos
ate
[ISO
]10
71-8
3-6
SH
542
30EH
C 1
59, D
S 91
; IC
SC 1
60; J
MPR
198
7aH
alof
enoz
ide
1122
26-6
1-6
SI
528
50H
exac
onaz
ole
7998
3-71
-4S
F5
2180
JMPR
199
1H
ymex
azol
1000
4-44
-1S
FST
539
00Ip
rodi
one
[ISO
]36
734-
19-7
SF
535
00JM
PR 1
996b
Linu
ron
[ISO
]33
0-55
-2S
H5
4000
ICSC
130
0M
alat
hion
[ISO
]12
1-75
-530
82O
PL
I5
c210
0Se
e no
te 1
; DS
29; I
AR
C 3
0; IC
SC 1
72; J
MPR
199
8b,
2004
Met
azac
hlor
6712
9-08
-2S
H5
2150
Met
habe
nzth
iazu
ron
[ISO
]18
691-
97-9
SH
5>2
500
Met
hyld
ymro
n42
609-
73-4
SH
539
48M
etob
rom
uron
[ISO
]30
60-8
9-7
SH
525
00M
etol
achl
or [I
SO]
5121
8-45
-2L
H5
2780
ICSC
136
0M
etox
uron
1993
7-59
-8S
H5
>320
0M
onol
inur
on17
46-8
1-2
SH
522
50IC
SC 1
273
37
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
1-N
apht
hyla
cetic
aci
d86
-87-
3S
PGR
5c3
000
N-o
ctyl
bicy
cloh
epte
ne
dica
rbox
imid
e [C
]11
3-48
-4L
SY5
2800
Ofu
race
5881
0-48
-3S
F5
2600
Oxy
carb
oxin
[ISO
]52
59-8
8-1
SF
420
00Pe
ncon
azol
e66
246-
88-6
SF
521
20JM
PR 1
993
2-Ph
enyl
phen
ol [C
]90
-43-
7S
F5
2480
ICSC
669
; IA
RC
30;
JMPR
200
0Pi
mar
icin
7681
-93-
8S
F5
2730
See
note
2Pr
oben
azol
e27
605-
76-1
SF
520
30Pr
omet
on [I
SO]
1610
-18-
0T
SH
529
80Pr
omet
ryn
[ISO
]72
87-1
9-6
TS
H5
3150
Prop
argi
te [I
SO]
2312
-35-
8L
AC
522
00JM
PR 2
000
Pyrid
ate
[ISO
]55
512-
33-9
SH
5c2
000
Pyrif
enox
[ISO
]88
283-
41-4
LF
429
00Py
rimet
hani
l [IS
O]
5311
2-28
-0S
F5
4150
JMPR
200
9bPy
rithi
obac
sodi
um [I
SO]
1233
43-1
6-8
SH
532
00Q
uinc
lora
c84
087-
01-4
SH
526
80R
esm
ethr
in [I
SO]
1045
3-86
-8PY
SI
420
00Se
e no
te 3
; EH
C 9
2, D
S 83
, HSG
25;
ICSC
324
Seth
oxyd
im [I
SO]
7405
1-80
-2L
H5
3200
Spin
osad
[ISO
]16
8316
-95-
8S
I5
3738
For S
pino
syn
A a
nd D
, CA
S nu
mbe
rs a
re 1
3192
9-60
-7 a
nd
1319
29-6
3-0;
JMPR
200
2; IC
SC 1
502
Spiro
tetr
amat
[ISO
]20
3313
-25-
1S
I4
>20
00JM
PR 2
009a
Sulp
hur
7704
-34-
913
50S
F,I
5>3
000
Skin
and
muc
ous m
embr
ane
irrita
nt. S
ee n
ote
4; IC
SC 1
166
TCA
(sod
ium
salt)
[ISO
]65
0-51
-1S
H5
3200
ICSC
113
9; Ir
ritan
t to
skin
and
eye
s: se
e no
te 5
Tem
epho
s [IS
O]
3383
-96-
8O
PL
I5
4000
DS
8; IC
SC 1
99; J
MPR
200
8
38
Com
mon
nam
eC
AS
noU
N
noC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Terb
uthy
lazi
ne [I
SO]
5915
-41-
3T
SH
521
60Te
rbut
ryn
[ISO
]88
6-50
-0T
SH
524
00Te
trach
lorv
inph
os [I
SO]
2224
8-79
-9O
PS
I5
4000
Thia
bend
azol
e [I
SO]
148-
79-8
SF
533
30JE
CFA
199
7, 2
002
Thid
iazu
ron
5170
7-55
-2S
PGR
5>4
000
Tri-a
llate
[ISO
]23
03-1
7-5
TCL
H5
2165
HSG
89;
ICSC
201
Trie
tazi
ne [I
SO]
1912
-26-
1T
SH
528
30IC
SC 2
02Tr
itico
nazo
le [I
SO]
1319
83-7
2-7
SF
4>2
000
Und
ecan
-2-o
ne [C
]11
2-12
-9O
ilR
P, (d
ogs,c
ats)
525
00
EHC
= E
nviro
nmen
tal
Hea
lth C
riter
ia M
onog
raph
; D
S =
Pest
icid
e D
ata
Shee
t; H
SG =
Hea
lth a
nd S
afet
y G
uide
; IA
RC
= I
AR
C M
onog
raph
s on
the
Eva
luat
ion
of
Car
cino
geni
c R
isks
to H
uman
s; IC
SC =
Inte
rnat
iona
l Che
mic
al S
afet
y C
ard;
JEC
FA =
Eva
luat
ion
by th
e Jo
int F
AO
/WH
O E
xper
t Com
mitt
ee o
n Fo
od A
dditi
ves;
JMPR
=
Eval
uatio
n by
the
Join
t FA
O/W
HO
Mee
ting
on P
estic
ide
Res
idue
s.
Not
es to
Cla
ss II
I1.
M
alat
hion
: LD
50 v
alue
can
var
y ac
cord
ing
to im
purit
ies.
This
val
ue h
as b
een
adop
ted
for c
lass
ifica
tion
purp
oses
and
is th
at o
f a te
chni
cal p
rodu
ct c
onfo
rmin
g to
WH
O
spec
ifica
tions
.2.
Pi
mar
icin
: ant
ibio
tic, i
dent
ical
with
tenn
ecet
in a
nd n
atam
ycin
.3.
R
esm
ethr
in is
a m
ixtu
re o
f iso
mer
s, th
e tra
ns is
omer
(70-
80%
) als
o be
ing
know
n as
bio
resm
ethr
in a
nd th
e ci
s iso
mer
(20-
30%
) as c
ism
ethr
in. B
iore
smet
hrin
alo
ne is
of
muc
h lo
wer
toxi
city
(ora
l LD
50 >
7000
mg/
kg) a
nd is
the
subj
ect o
f DS
34. I
t app
ears
in T
able
5.
4.
Sulp
hur d
ust c
an sp
onta
neou
sly
igni
te u
nles
s dilu
ted
abou
t 50%
with
iner
t mat
eria
l.5.
TC
A: T
he d
ata
show
n re
fer t
o so
dium
tric
hlor
oace
tic a
cid.
In m
any
coun
tries
, the
sam
e te
rm (T
CA
) ref
ers t
o th
e fr
ee a
cid
(now
acc
epte
d by
ISO
): th
is is
a so
lid w
ith a
n or
al L
D50
of 4
00 m
g/kg
bw
and
if u
sed
as a
pes
ticid
e w
ould
be
plac
ed in
Cla
ss II
. It i
s hig
hly
corr
osiv
e to
skin
.
THE
FIN
AL
CLA
SSIF
ICAT
ION
OF
AN
Y P
RO
DU
CT
DEP
END
S O
N IT
S FO
RM
ULA
TIO
NSe
e Pa
ges 7
& 8
, and
the A
nnex
39
Tabl
e 5.
Tec
hnic
al g
rade
act
ive
ingr
edie
nts
of p
estic
ides
unl
ikel
y to
pre
sent
acu
te h
azar
d in
nor
mal
use
Com
mon
nam
eC
AS
noU
N n
oC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Acl
onife
n74
070-
46-5
SH
5>5
000
Acr
inat
hrin
[ISO
]10
1007
-06-
1PY
SM
T5
>500
0Am
inop
yral
id [I
SO]
1501
14-7
1-9
SH
5>
5000
JMPR
200
9bA
mitr
ole
[ISO
]61
-82-
5S
H5
5000
EHC
158
, DS
79; H
SG 8
5; IA
RC
79;
ICSC
631
; JM
PR 1
998b
Ant
hraq
uino
ne84
-65-
1S
RP
(bird
s)5
>500
0IC
SC 1
605
Azi
msu
lfuro
n [I
SO]
1201
62-5
5-2
SH
5>5
000
Azo
xyst
robi
n [I
SO]
1318
60-3
3-8
SF
5>5
000
JMPR
200
9aB
enflu
ralin
[ISO
]18
61-4
0-1
SH
5>1
0000
Ben
omyl
[ISO
]17
804-
35-2
SF
5>1
0000
EHC
148
, DS
87; H
SG 8
1; IC
SC 3
82; J
MPR
199
6b.
See
note
1B
enox
acor
[ISO
]98
730-
04-2
SH
5>5
000
This
mol
ecul
e is
not
an
activ
e su
bsta
nce
as su
ch b
ut is
a
“saf
ener
”B
ensu
lfuro
n-m
ethy
l83
055-
99-6
SH
5>5
000
Bife
naza
te [I
SO]
1498
77-4
1-8
SAC
5>
5000
JMPR
200
8B
ifeno
x [I
SO]
4257
6-02
-3S
H5
>640
0B
iore
smet
hrin
[ISO
]28
434-
01-7
PYL
I5
>700
0D
S 34
; EH
C 9
2; H
SG 2
5; IC
SC 2
29; J
MPR
199
2B
iterta
nol
5517
9-31
-2S
F5
>500
0JM
PR 1
999
Bosc
alid
[ISO
]18
8425
-85-
6S
F5
>50
00JM
PR 2
008
Bro
mac
il [I
SO]
314-
40-9
SH
552
00IC
SC 1
448
Bro
mob
utid
e74
712-
19-9
SH
5>5
000
Bro
mop
ropy
late
[ISO
]18
181-
80-1
SA
C5
>500
0JM
PR 1
994
Cap
tan
[ISO
]13
3-06
-2S
F5
9000
Irrit
ant t
o sk
in; D
S 9;
HSG
50;
IAR
C 3
0, S
uppl
7;
ICSC
120
; JM
PR 1
996b
, 200
5
40
Com
mon
nam
eC
AS
noU
N n
oC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Car
bend
azim
[ISO
]10
605-
21-7
SF
5>1
0000
DS
89; E
HC
149
; HSG
82;
ICSC
127
7; JM
PR 1
996b
, 20
06b
Car
beta
mid
e [I
SO]
1611
8-49
-3C
SH
5>1
0000
Car
prop
amid
[ISO
]10
4030
-54-
8L
F5
>500
0C
hlor
ansu
lam
met
hyl
1475
0-35
-4S
H5
>500
0C
hlor
antr
anili
prol
e [I
SO]
5000
08-4
5-7
SI
5>
5000
JMPR
200
9aC
hlor
fluaz
uron
7142
2-67
-8S
IGR
585
00C
hlor
otha
loni
l [IS
O]
1897
-45-
6S
F5
>100
00EH
C 1
83; H
SG 9
8; IA
RC
30;
ICSC
134
; JM
PR 1
993
Chl
orot
olur
on [I
SO]
1554
5-48
-9S
H5
>100
00IC
SC 1
327
Chl
orpr
opha
m [I
SO]
101-
21-3
CS
PGR
5>5
000
IAR
C 1
2; JM
PR 2
001;
ICSC
150
0C
hlor
sulfu
ron
6490
2-72
-3S
H5
5545
Cin
osul
furo
n [I
SO]
9459
3-91
-6S
H5
>500
0C
lom
epro
p84
496-
56-0
SH
5>5
000
Clo
xyfo
nac
3279
1-87
-0PA
AS
PGR
5>5
000
Cry
olite
[C]
1509
6-52
-3S
I5
>100
00C
yclo
prot
hrin
6393
5-38
-6PY
LI
5>5
000
Cyc
losu
lfam
uron
[ISO
(*)]
1368
49-1
5-5
SH
5>5
000
Cyh
alof
op [I
SO]
1220
08-8
5-9
SH
5>5
000
Dai
mur
on42
609-
52-9
SH
5>5
000
Dal
apon
75-9
9-0
SH
593
30D
amin
ozid
e [I
SO]
1596
-84-
5S
H5
8400
JMPR
199
3D
esm
edip
ham
[ISO
]13
684-
56-5
SH
5>9
600
Dic
hlofl
uani
d [I
SO]
1085
-98-
9S
F5
>500
0JM
PR 1
985a
Dic
lom
ezin
e62
865-
36-5
SF
5>1
0000
Dic
losu
lam
[ISO
]14
5701
-21-
9S
H5
>500
0D
ieth
ofen
carb
8713
0-20
-9S
F5
>500
0
41
Com
mon
nam
eC
AS
noU
N n
oC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Dik
egul
ac [I
SO]
1846
7-77
-1S
PGR
5>1
0000
Dim
etho
mor
ph [I
SO]
1104
88-7
0-5
SF
5>5
000
Dim
ethy
l pht
hala
te [C
]13
1-11
-3L
RP
(inse
ct)
582
00IC
SC 2
61
Dip
ropy
l iso
cinc
hom
erat
e [C
]37
37-2
2-2
LR
P (fl
y)5
5230
Dith
iopy
r [IS
O]
9788
6-45
-8S
H5
>500
0Et
halfl
ural
in [I
SO]
5528
3-68
-6S
H5
>100
00Et
hirim
ol [I
SO]
2394
7-60
-6S
FST
563
40Et
hofu
mes
ate
[ISO
]26
225-
79-6
SH
5>6
400
Ethy
l but
ylac
etyl
amin
opro
pion
ate
5230
4-36
-6L
RP
(inse
ct)
5>5
000
Etof
enpr
ox80
844-
07-1
SI
5>1
0000
JMPR
199
4Fa
mox
adon
e [I
SO(*
)]13
1807
-57-
3S
F5
>500
0JM
PR 2
004
Fenc
hlor
azol
e [I
SO]
1031
12-3
5-2
SH
5>5
000
Fenc
lorim
3740
-92-
9S
H5
>500
0Fe
nfur
am [I
SO]
2469
1-80
-3S
FST
5>1
0000
Fenh
exam
id [I
SO]
1268
33-1
7-8
SF
5>5
000
JMPR
200
6bFe
noxy
carb
7912
7-80
-3C
SI
5>1
0000
Fenp
iclo
nil
7473
8-17
-3S
FST
5>5
000
Ferb
am [I
SO]
1448
4-64
-1S
F5
>100
00D
S 94
; EH
C 7
8; IA
RC
12,
42;
ICSC
792
; JM
PR
1997
bFl
oras
ulam
1457
01-2
3-1
SH
5>5
000
Fluc
arba
zone
-sod
ium
1812
74-1
7-9
SH
5>
5000
Fluc
yclo
xuro
n [I
SO]
9405
0-52
-9S
AC
5>5
000
Flud
ioxo
nil [
ISO
]13
1341
-86-
1S
F5
>500
0JM
PR 2
006a
Flum
etra
lin62
924-
70-3
SPG
R5
>500
0
42
Com
mon
nam
eC
AS
noU
N n
oC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Flum
etsu
lam
[ISO
]98
967-
40-9
SH
5>5
000
Fluo
met
uron
[ISO
]21
64-1
7-2
SH
5>8
000
Flup
ropa
nate
756-
09-2
SH
5>1
0000
Flup
yrsu
lfuro
n [I
SO]
1447
40-5
4-5
SH
5>5
000
Flur
enol
[ISO
]46
7-69
-6S
PGR
5>5
000
Flur
idon
e [I
SO]
5975
6-60
-4S
H5
>100
00Fl
urox
ypyr
6937
7-81
-7S
H5
>500
0Fl
uthi
acet
1492
53-6
5-6
SH
5>5
000
Flut
olan
il66
332-
96-5
SF
5>1
0000
ICSC
126
5; JM
PR 2
003b
Folp
et13
3-07
-3S
F5
>100
00H
SG 7
2; IC
SC 1
56; J
MPR
199
6bFo
sety
l15
845-
66-2
SF
558
00G
ibbe
relli
c ac
id77
-06-
5S
PGR
5>1
0000
Hex
aflum
uron
[ISO
]86
479-
06-3
SI
5>5
000
ICSC
126
6H
exyt
hiaz
ox78
587-
05-0
SA
C5
>500
0JM
PR 1
992,
200
9aH
ydro
pren
e [I
SO]
4120
5-09
-8L
IGR
5>1
0000
2-H
ydro
xyet
hyl o
ctyl
sulp
hide
[C]
3547
-33-
9L
RP
(inse
ct)
585
30
Imaz
amet
habe
nzm
ethy
l [(I
SO)]
8140
5-85
-8S
H5
>500
0Im
azap
yr81
334-
34-1
SH
5>5
000
Irrit
ant t
o ey
esIm
azaq
uin
8133
5-37
-7S
H5
>500
0Im
azet
hapy
r81
335-
77-5
SH
5>5
000
Imib
enco
nazo
le [I
SO]
8659
8-92
-7S
F5
>500
0In
aben
fide
8221
1-24
-3S
PGR
5>1
0000
Ipro
valic
arb
1409
23-1
7-7
SF
5>5
000
Isox
aben
8255
8-50
-7S
H5
>100
00
43
Com
mon
nam
eC
AS
noU
N n
oC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Kas
ugam
ycin
1940
8-46
-9S
F5
>100
00Le
naci
l [IS
O]
2164
-08-
1S
H5
>100
00M
alei
c hy
draz
ide
[C]
123-
33-1
SPG
R5
6950
IAR
C 4
, 42;
JMPR
199
7b C
AS1
0071
-13-
3M
anco
zeb
8018
-01-
7S
F5
>800
0Ir
ritan
t to
skin
on
mul
tiple
exp
osur
e; D
S 94
; EH
C 7
8;
ICSC
754
; JM
PR 1
994
Man
dipr
opam
id [I
SO]
3747
26-6
2-2
SF
5>
5000
JMPR
200
9aM
aneb
[ISO
]12
427-
38-2
SF
567
50Ir
ritan
t to
skin
on
mul
tiple
exp
osur
e; D
S 94
; EH
C 7
8;
ICSC
173
; JM
PR 1
994
Mef
enac
et73
250-
68-7
SH
5>5
000
Mep
anip
yrim
[ISO
]11
0235
-47-
7S
F5
>500
0M
epro
nil [
ISO
]55
814-
41-0
SF
5>1
0000
Met
hopr
ene
[ISO
]40
596-
69-8
LIG
R5
>100
00D
S 47
; JM
PR 1
987b
, 200
2M
etho
xych
lor [
ISO
]72
-43-
5O
CS
I5
6000
DS
28; I
AR
C 5
, 20;
ICSC
130
6; JM
PR 1
978
Met
hozy
feno
zide
1610
50-5
8-4
SI
5>5
000
Der
mal
LD
50 >
500
0; JM
PR 2
004
Met
iram
9006
-42-
2S
F5
>100
00JM
PR 1
994
Met
osul
am13
9528
-85-
1S
H5
>500
0M
etsu
lfuro
n m
ethy
l74
223-
64-6
SH
5>5
000
2-(1
-Nap
hthy
l) ac
etam
ide
86-8
6-2
SPG
R5
6400
Nap
ropa
mid
e15
299-
99-7
SH
550
00N
apta
lam
132-
66-1
SPG
R5
8200
Neb
uron
[ISO
]55
5-37
-3S
H5
>100
00N
iclo
sam
ide
[ISO
]50
-65-
7S
M5
5000
DS
63N
icos
ulfu
ron
[ISO
]11
1991
-09-
4S
H5
>500
0Ir
ritan
t to
eyes
Nitr
otha
l-iso
prop
yl [I
SO]
1055
2-74
-6S
F5
6400
Nor
flura
zon
[ISO
]27
314-
13-2
SH
5>8
000
Nov
alur
on [I
SO]
1167
14-4
6-6
SI
5>
5000
JMPR
200
6b
44
Com
mon
nam
eC
AS
noU
N n
oC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Nov
iflum
uron
1214
51-0
2-3
SI
5>5
000
Der
mal
LD
50 >
500
0O
ryza
lin [I
SO]
1904
4-88
-3S
H5
>100
00O
xabe
trini
l74
782-
23-3
SH
5>5
000
Oxa
diaz
on [I
SO]
1966
6-30
-9S
H5
>800
0O
xine
-cop
per [
ISO
]10
380-
28-6
CU
SF
577
92O
xyflu
orfe
n [I
SO]
4287
4-03
-3S
H5
>500
0Pe
ncyc
uron
6606
3-05
-6S
F5
>500
0Pe
noxs
ulam
2197
14-9
6-2
SH
5>5
000
Der
mal
LD
50 >
500
0Pe
ntan
ochl
or23
07-6
8-8
SH
5>1
0000
Phen
med
ipha
m [I
SO]
1368
4-63
-4S
H5
>800
0Ph
enot
hrin
[ISO
]26
002-
80-2
PYL
I5
>500
0D
S 85
; EH
C 9
6; H
SG 3
2; IC
SC 3
13; J
MPR
198
9Ph
osph
orus
aci
d [C
]13
598-
36-2
LF
5>5
000
Phth
alid
e27
355-
22-2
SF
5>1
0000
Picl
oram
[ISO
]19
18-0
2-1
SH
582
00IC
SC 1
246
Pipe
rony
l but
oxid
e51
-03-
6O
ilSY
5>7
500
IAR
C 3
0; JM
PR 1
996b
; IC
SC 1
347
Pret
ilach
lor [
ISO
]51
218-
49-6
LH
561
00Pr
imis
ulfu
ron
[ISO
]11
3036
-87-
6S
H5
>505
0Pr
ocym
idon
e [I
SO]
3280
9-16
-8S
F5
6800
JMPR
199
0, 2
009b
Prod
iam
ine
[ISO
]29
091-
21-2
SH
5>5
000
Prop
amoc
arb
2457
9-73
-5S
F5
8600
JMPR
198
7aPr
opaq
uiza
fop
1114
79-0
5-1
SH
5>5
000
ICSC
127
1Pr
opaz
ine
[ISO
]13
9-40
-2T
SH
5>5
000
ICSC
697
Prop
ham
[ISO
]12
2-42
-9S
H5
5000
IAR
C 1
2; JM
PR 1
993
Prop
ineb
[ISO
]12
071-
83-9
SH
585
00D
S 94
; EH
C 7
8; JM
PR 1
994
Prop
yzam
ide
[ISO
]23
950-
58-5
SH
556
20
45
Com
mon
nam
eC
AS
noU
N n
oC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Prot
hioc
onaz
ole
[ISO
]17
8928
-70-
6S
F5
>62
00JM
PR 2
009a
Pyra
zoly
nate
[ISO
]58
011-
68-0
SH
595
50Py
razo
sulfu
ron
[ISO
]98
389-
04-9
SH
5>5
000
Pyrim
inob
ac13
6191
-56-
5S
H5
>500
0Py
ripro
xyfe
n [I
SO]
9573
7-68
-1S
I5
>500
0IC
SC 1
269;
JMPR
200
0Q
uinm
erac
[ISO
]90
717-
03-6
SH
5>5
000
Qui
noxy
fen
[ISO
]12
4495
-18-
7S
F5
>500
0JM
PR 2
008
Qui
ntoz
ene
[ISO
]82
-68-
8S
F5
>100
00EH
C 4
1; H
SG 2
3; IA
RC
5; J
MPR
199
6b; I
CSC
745
Rim
sulfu
ron
[C]
1229
31-4
8-0
SH
5>5
000
Sidu
ron
[ISO
]19
82-4
9-6
SH
5>7
500
Sim
azin
e [I
SO]
122-
34-9
TS
H5
>500
0IC
SC 6
99Sp
inet
oram
[ISO
]18
7166
-40-
1S
I5
>50
00JM
PR 2
009a
Sulfo
met
uron
7422
3-56
-6S
H5
>500
0Te
bufe
nozi
de11
2410
-23-
8S
I5
>500
0D
erm
al L
D50
> 5
000;
JMPR
199
7b, 2
004
Tebu
tam
3525
6-85
-0O
ilH
562
10Te
cnaz
ene
[ISO
]11
7-18
-0S
F5
>100
00EH
C 4
2; H
SG 1
2; JM
PR 1
995b
Teflu
benz
uron
8312
1-18
-0S
I5
>500
0JM
PR 1
995b
Terb
acil
[ISO
]59
02-5
1-2
SH
5>5
000
Tetra
difo
n [I
SO]
116-
29-0
SA
C5
>100
00EH
C 6
7; H
SG 1
1; IC
SC 7
47Te
tram
ethr
in [I
SO]
7696
-12-
0PY
SO
5>5
000
EHC
98;
HSG
31;
ICSC
334
Thife
nsul
furo
n-m
ethy
l79
277-
27-3
SH
5>5
000
Thifl
uzam
ide
1300
00-4
0-7
SF
5>5
000
Der
mal
LD
50 >
500
0Th
ioph
anat
e-m
ethy
l [IS
O]
2356
4-05
-8S
F5
>600
0JM
PR 1
996b
, 199
9, 2
008
Tioc
arba
zil
3675
6-79
-3TC
LH
510
000
Tolc
lofo
s-m
ethy
l [IS
O]
5701
8-04
-9S
F-S
5c5
000
JMPR
199
5b
46
Com
mon
nam
eC
AS
noU
N n
oC
hem
ty
pePh
ys
stat
eM
ain
use
GH
SL
D50
m
g/kg
Rem
arks
Toly
lflua
nid
[ISO
]73
1-27
-1S
F5
>500
0JM
PR 1
989,
200
3bTr
ansfl
uthr
in [I
SO]
1187
12-8
9-3
PYS
I5
>500
0Tr
iasu
lfuro
n82
097-
50-5
SH
5>5
000
Trib
enur
on [I
SO]
1060
40-4
8-6
SH
5>5
000
Trifl
oxys
trobi
n [I
SO]
1415
17-2
1-7
SF
5>
5000
JMPR
200
6aTr
iflum
uron
6462
8-44
-0S
PGR
5>5
000
Trifl
ural
in [I
SO]
1582
-09-
8S
H5
>100
00IA
RC
53;
ICSC
205
Trifl
usul
furo
n-m
ethy
l [IS
O]
1265
35-1
5-7
SH
5>5
000
Trifo
rine
[ISO
]26
644-
46-2
SF
5>6
000
JMPR
199
8bVa
lidam
ycin
3724
8-47
-8S
F5
>100
00V
incl
ozol
in [I
SO]
5047
1-44
-8S
F5
1000
0JM
PR 1
996b
Zine
b [I
SO]
1212
2-67
-7S
F5
>500
0D
S 94
; EH
C 7
8; IA
RC
12;
ICSC
350
; JM
PR 1
994
Zoxa
mid
e [I
SO]
1560
52-6
8-5
SF
5>
5000
JMPR
200
9b
EHC
= E
nviro
nmen
tal H
ealth
Crit
eria
Mon
ogra
ph; D
S= P
estic
ide D
ata S
heet
; HSG
= H
ealth
and
Safe
ty G
uide
; IA
RC
= IA
RC
Mon
ogra
phs o
n th
e Eva
luat
ion
of C
arci
noge
nic
Ris
ks to
Hum
ans;
ICSC
= In
tern
atio
nal C
hem
ical
Saf
ety
Car
d; JM
PR =
Eva
luat
ion
by th
e Jo
int F
AO
/WH
O M
eetin
g on
Pes
ticid
e R
esid
ues.
Not
es to
Tab
le 5
1.
The i
nter
natio
nal t
rade
of b
enom
yl is
regu
late
d by
the R
otte
rdam
conv
entio
n on
Prio
r Inf
orm
ed C
onse
nt (s
ee h
ttp://
ww
w.pi
c.in
t/), w
hich
ente
red
into
forc
e on
24 F
ebru
ary
2004
. See
Tab
le 7
, p. 5
1.
THE
FIN
AL
CLA
SSIF
ICAT
ION
OF
AN
Y P
RO
DU
CT
DEP
END
S O
N IT
S FO
RM
ULA
TIO
NSe
e Pa
ges 7
& 8
, and
the A
nnex
47
Acrylonitrile 107-13-1Aldoxycarb 1646-88-4Aldrin1,2 309-00-2Allidochlor 93-71-0Allyxycarb 6392-46-7Amidithion 919-76-6Aminocarb 2032-59-9Anilazine 101-05-3ANTU 86-88-4Aramite 140-57-8Arsenous oxide 1327-53-3Athidathion 19691-80-6Atraton 1610-17-9Aziprotryne 4658-28-0Azothoate 5834-96-8Barban 101-27-9Barium carbonate 513-77-9Benodanil 15310-01-7Benquinox 495-73-8Benzoximate 29104-30-1Benzoylprop-ethyl 33878-50-1Benzthiazuron 1929-88-0Binapacryl1 485-31-4Bis(tributyltin) oxide 56-35-9Bisthiosemi 39603-48-0Bromocyclen 1715-40-8Bromofenoxim 13181-17-4Bromophos 2104-96-3Bromophos-ethyl 4824-78-6Bufencarb 8065-36-9Butacarb 2655-19-8Butam 35256-85-0Butenachlor 87310-56-3Buthidazole 55511-98-3Buthiobate 51308-54-4
Butonate 126-22-7Butopyronoxyl 532-34-3Buturon 3766-60-7Calcium cyanamide 156-62-7Camphechlor1,2 8001-35-2Carbamorph 31848-11-0Carbanolate 671-04-5Carbon disulfide 75-15-0Carbophenothion 786-19-6Chlomethoxyfen 32861-85-1Chloramben 133-90-4Chloraniformethan 20856-57-9Chloranil 118-75-2Chloranocryl 2164-09-2Chlorbenside 103-17-3Chlorbufam 1967-16-4Chlorbicyclen 2550-75-6Chlorbormuron 13360-45-7Chlordecone 143-50-0Chlordimeform1 6164-98-3Chlorfenac 85-34-7Chlorfenethol 80-06-8Chlorfenprop-methyl 14437-17-3Chlorfenson 80-33-1Chlorfensulfide 22274-74-0Chlorflurenol 2536-31-4Chlormebuform 37407-77-5Chlormethiuron 28217-97-2Chlornitrofen 1836-77-7Chlorobenzilate1 510-15-6Chloroneb 2675-77-6Chloropropylate 5836-10-2Chloroxuron 1982-47-4Chlorquinox 3495-42-9Chlorphoxim 14816-20-7
Active ingredient CAS no Active ingredient CAS no
TABLE 6. ACTIVE INGREDIENTS BELIEVED TO BE OBSOLETE OR DISCONTINUED FOR USE AS PESTICIDES
Ingredients discontinued have been identified from the previous edition of this classification, from the Pesticide Manual (Pesticide Manual, 1991, 1994; 1997, 2003), and in some cases from the manufacturer. It is difficult, in some cases, to be sure whether or not all commercial activity in a substance has ceased; some of these materials are known to be still in use for non-agricultural purposes. IPCS will be grateful for details of any materials in this Section, which are still in commercial use. The common name and CAS number are indicated.
48
Chlorthiamid 1918-13-4Chlorthiophos 21923-23-9Cloethocarb 51487-69-5Clofop 26129-32-8Coumachlor 81-82-3Crimidine 535-89-7Credazine 14491-59-9Crotoxyphos 7700-17-6Crufomate 299-86-5Cyanofenphos 13067-93-1Cyanthoate 3734-95-0Cycloheximide 66-81-9Cycluron 2163-69-1Cyometrinil 63278-33-1Cypendazole 28559-00-4Cyprofuram 69581-33-5Cypromid 2759-71-9Delachlor 24353-58-0Demephion-O 682-80-4Demephion-S 2587-90-8Demeton-O 298-03-3Demeton-S 126-75-0Demeton-S-methylsulphon 17040-19-6Desmetryn 1014-69-3Dialifos 10311-84-9Di-allate 2303-16-4Diamidafos 1754-58-1Dibromochloropropane 96-12-8Dibutyl phthalate 84-74-2Dibutyl succinate 141-03-7Dichlofenthion 97-17-61,2-Dichloropropane 78-87-5Dichlozoline 24201-58-9Diclobutrazol 75736-33-3Dieldrin1,2 60-57-1Dienochlor 2227-47-0Diethatyl 38727-55-8Difenoxuron 14214-32-5Dimefox 115-26-4Dimethirimol 5221-53-4Dimetilan 644-64-4Dimexano 1468-37-7
Dinex 131-89-5Dinocton 32534-96-6Dinoseb1 88-85-7Dinoseb acetate1 2813-95-8Dioxabenzophos 3811-49-2Dioxacarb 6988-21-2Dioxathion 78-34-2Dipropetryn 4147-51-7Disul 149-26-8Ditalimfos 5131-24-8Drazoxolon 5707-69-7Eglinazine 6616-80-4Endothion 2778-04-3Endrin2 72-20-8EPBP 3792-59-4Erbon 136-25-4ESP (Oxydeprofos) 2674-91-1Etacelasil 37894-46-5Etaconazole 60207-93-4Ethidimuron 30043-49-3Ethiolate 2941-55-1Ethirimol 23947-60-6Ethoate-methyl 116-01-8Ethohexadiol 94-96-2Ethyleneglycol bis (trichloroacetate) 2514-53-6
Etrimfos 38260-54-7EXD 502-55-6Fenaminosulf 140-56-7Fenazaflor 14255-88-0Fenchlorphos 299-84-3Fenitropan 65934-95-4Fenoprop (Silvex) 93-72-1Fenoxaprop-ethyl 82110-72-3Fenson 80-38-6Fensulfothion 115-90-2Fenthiaprop 95721-12-3Fenuron 101-42-8Fenuron-TCA 4482-55-7Flamprop 58667-63-3Fluazifop 69335-91-7Flubenzimine 37893-02-0
Active ingredient CAS no Active ingredient CAS no
TABLE 6. ACTIVE INGREDIENTS BELIEVED TO BE OBSOLETE OR DISCONTINUED FOR USE AS PESTICIDES, continued
49
Fluenetil 4301-50-2Fluorodifen 15457-05-3Fluoromide 13577-71-4Fluotrimazole 31251-03-3Fluvalinate 69409-94-5Fonofos 944-22-9Formothion 2540-82-1Fosmethilan 83733-82-8Fosthietan 21548-32-3Furconazole-cis 112839-32-4Furmecyclox 60568-05-0Glyodin 556-22-9Glyphosine 2439-99-8Griseofulvin 126-07-8Halacrinate 34462-96-9Haloxydine 2693-61-0Heptachlor1,2 76-44-8Heptopargil 73886-28-9Hexachloroacetone 116-16-5Hexaflurate 17029-22-0Hydroxyquinoline sulfate 134-31-6Ipazine 1912-25-0IPSP 5827-05-4Isazofos 42509-80-8Isobenzan 297-78-9Isobornyl thiocyano acetate 115-31-1Isocarbamid 30979-48-7Isocil 314-42-1Isodrin 465-73-6Isofenphos 25311-71-1Isomethiozin 57052-04-7Isonoruron 28805-78-9Isopropalin 33820-53-0Isothioate 36614-38-7Isoxapyrifop 87757-18-4Jodfenphos 18181-70-9Karbutilate 4849-32-5Kelevan 4234-79-1Kinoprene 42588-37-4Leptophos 21609-90-5Lythidathion 2669-32-1
Malonoben 10537-47-0Mebenil 7055-03-0Mecarbinzid 27386-64-7Mecarphon 29173-31-7Medinoterb acetate 2487-01-6Menazon 78-57-9Mephospholan 950-10-7Methazole 20354-26-1Methiuron 21540-35-2Methoprotryne 841-06-5Methoxyethylmercury silicate1 64491-92-5
Methoxyphenone 41295-28-7Methoxymethyl mercurychloride1 123-88-6
Methylmercury dicyan-diamide1 502-39-6
Metobromuron 3060-89-7Metsulfovax 21542-18-6Mexacarbate 315-18-4Mipafox 371-86-8Mirex2 2385-85-5Monalide 7187-36-7Monuron 150-68-5Monuron-TCA 140-41-0Morfamquat 4636-83-3Myclozolin 54864-61-8Naphthalene 91-20-3Naphthalic anhydride 81-84-5Nitralin 4726-14-1Nitrilacarb 29672-19-3Nitrofen 1836-75-5Norbormide 991-42-4Noruron 2163-79-3Oxapyrazon 4489-31-0Oxydisulfoton 2497-07-6Parafluron 7159-99-1Perfluidone 37924-13-3Phenisopham 57375-63-0Phenkapton 2275-14-1Phenobenzuron 3134-12-1
Active ingredient CAS no Active ingredient CAS no
TABLE 6. ACTIVE INGREDIENTS BELIEVED TO BE OBSOLETE OR DISCONTINUED FOR USE AS PESTICIDES, continued
50
1 The international trade of aldrin, binapacryl, camphechlor (toxaphene), chlordimeform, chlorobenzilate, dieldrin, dinoseb and dinoseb salts, heptachlor, mercury compounds, and 2,4,5-T is regulated by the Rotterdam convention on Prior Informed Consent (see http://www.pic.int/), which entered into force on 24 February 2004, with subsequent amendments. See Table 7, p. 51.
2 The use and production of aldrin, camphechlor (toxaphene), chlordecone, dieldrin, endrin, heptachlor and mirex is prohibited or severely restricted by the Stockholm convention on persistent organic pollutants, which entered into force on 17 May, 2004, with subsequent amendments. See http://www.pops.int/
Phenylmercurydimethyl-dithiocarbamate1 32407-99-1
Phenylmercury nitrate1 8003-05-2Phosacetim 4104-14-7Phosdiphen 36519-00-3Phosfolan 947-02-4Pindone 83-26-1Piproctanyl 69309-47-3Pirimiphos-ethyl 23505-41-1Potassium cyanate 590-28-3Profluralin 26399-36-0Proglinazine 68228-20-6Promacyl 34264-24-9Promecarb 2631-37-0Propaphos 7292-16-2Propyl isome 83-59-0Prothiocarb 19622-08-3Prothoate 2275-18-5Proxan 108-25-8Pydanon 22571-07-9Pyracarbolid 24691-76-7Pyridinitril 1086-02-8Quinacetol sulfate 57130-91-3Quinonamid 27541-88-4Ryania 8047-13-0Sabadilla 8051-02-3Salicylanilide 87-17-2Schradan 152-16-9Scilliroside 507-60-8
Secbumeton 26259-45-0Sesamex 51-14-9Sodium fluoride 7681-49-4Sodium hexafluorosilicate 16893-85-9Sulfallate 95-06-7Sulfoxide 120-62-7Sulprofos 35400-43-2SWEP 1918-18-92,4,5-T1 93-76-5TDE 72-54-8TEPP 107-49-3Terbucarb 1918-11-2Tetrasul 2227-13-6Thiazafluron 25366-23-8Thicyofen 116170-30-0Thionazin 297-97-2Thiophanate 23564-06-9Thioquinox 93-75-4Triamiphos 1031-47-6Triapenthenol 76608-88-3Triarimol 26766-27-8Tricamba 2307-49-5Trichlamide 70193-21-4Trichloronat 327-98-0Tridiphane 58138-08-2Trifenmorph 1420-06-3Trimethacarb 12407-86-2Vernolate 1929-77-7
Active ingredient CAS no Active ingredient CAS no
TABLE 6. ACTIVE INGREDIENTS BELIEVED TO BE OBSOLETE OR DISCONTINUED FOR USE AS PESTICIDES, continued
51
Table 7. Pesticides subject to the Rotterdam Convention1
Class Pesticide CAS number
O Aldrin2 309-00-2
O Binapacryl 485-31-4
Ia Captafol 2425-06-1
II Chlordane2 57-74-9
O Chlordimeform 6164-98-3
O Chlorobenzilate 510-15-6
II DDT2 50-29-3
1,2-Dibromoethane (EDB) 106-93-4
O Dieldrin2 60-57-1
O Dinoseb and dinoseb salts 88-85-7
Ib DNOC and its salts (such as ammonium salt, potassium salt and sodium salt)
534-52-1; 2980-64-5; 5787-96-2; 2312-76-7
Ethylene dichloride 107-06-2
Ethylene oxide 75-21-8
Ib Fluoroacetamide 640-19-7
II HCH (mixed isomers) 608-73-1
O Heptachlor2 76-44-8
Ia Hexachlorobenzene2 118-74-1
II Lindane2 58-89-9
Mercury compounds, including inorganic mercury compounds, alkyl mercury compounds and alkyloxyalkyl and aryl mercury compounds
Ib Pentachlorophenol 87-86-5
O 2,4,5-T 93-76-5
O Camphechlor (Toxaphene) 8001-35-2
Dustable powder formulations containing a combination of benomyl at or above 7%, carbofuran at above 10%, thiram at or above 15%
17804-35-2; 1563-66-2;
137-26-8
Ib Methamidophos (soluble liquid formulations of the substance that exceed 600 g active ingredient/L)
10265-92-6
Ia Methyl-parathion (emulsifiable concentrates (EC) with 19.5%, 40%, 50%, 60% active ingredient and dusts containing 1.5%, 2% and 3% active ingredient
298-00-0
Ib Monocrotophos (all formulations) 6923-22-4
52
Ia Parathion (all formulations – aerosols, dustable powder (DP), emulsifiable concentrate (EC), granules (GR) and wettable powders (WP) of this substance are included, except capsule suspensions (CS)
56-38-2
Ia Phosphamidon (soluble liquid formulations of the substance that exceed 1000 g active ingredient/L)
13171-21-6 [mixture, (E) & (Z) isomers]
23783-98-4 [(Z)-isomer] 297-99-4 [(E)-isomer]
Tributyltin compounds, including: tributyltin oxide; tributyltin benzoate; tributyltin chloride; tributyltin fluoride; tributyltin linoleate; tributyltin methacrylate; tributyltin naphthenate
1 According to the Rotterdam Convention, export of a chemical can only take place with the prior informed consent of the importing Party. The Prior Informed Consent (PIC) procedure is a means for formally obtaining and disseminating the decisions of importing countries as to whether they wish to receive future shipments of a certain chemical and for ensuring compliance to these decisions by exporting countries. The aim is to promote a shared responsibility between exporting and importing countries in protecting human health and the environment from the harmful effects of such chemicals (further information can be found at: http://www.pic.int/). The Rotterdam Convention (which entered into force on 24 February 2004) built on the voluntary PIC procedure which was initiated by UNEP and FAO in 1989.
2 The use and production of aldrin, chlordane, DDT, dieldrin, heptachlor, hexachlorobenzene and lindane is prohibited or severely restricted by the Stockholm convention on persistent organic pollutants, which entered into force on 17 May, 2004. See http://www.pops.int/
53
TABLE 8. GASEOUS OR VOLATILE FUMIGANTS NOT CLASSIFIED UNDER THE WHO RECOMMENDED CLASSIFICATION OF PESTICIDES BY HAZARD
The Classification does not set out any criteria for air concentrations on which classification could be based. Most of these compounds are of high hazard and recommended exposure limits for occupational exposure have been adopted by national authorities in many countries.
Pesticide CAS number Remarks
Aluminium phosphide 20859-73-8 DS 46; EHC 73; HSG 28; JMPR 1967
Chloropicrin 76-06-2 JMPR 1965b
1,2-Dibromoethane 106-93-4 EHC 177; IARC 15
1,3-Dichloropropene 542-75-6 EHC 146; HSG 76; IARC 41
Ethylene dichloride 107-06-2 EHC 62, 176; HSG 55; IARC 20
Ethylene oxide 75-21-8 EHC 55; HSG 16; JMPR 1969; IARC 11, 36, 42
Formaldehyde 50-00-0 EHC 89; HSG 57
Hydrogen cyanide 74-90-8 JMPR 1965b
Magnesium phosphide 12057-74-8 EHC 73; HSG 28
Methyl bromide 74-83-9 DS 5; EHC 166; HSG 86; IARC 41, 45; JMPR 1967
Phosphine 7803-51-2 DS 46; EHC 73; HSG 28; JMPR 1967
Sulfuryl fluoride 2699-79-8 JMPR 2006b
EHC = Environmental Health Criteria Monograph; DS = Pesticide Data Sheet; HSG = Health and Safety Guide; IARC = IARC Monographs on the Evaluation of Carcinogenic Risks to Humans; ICSC = International Chemical Safety Card; JMPR = Evaluation by the Joint FAO/WHO Meeting on Pesticide Residues.
54
ANNEX
HOW TO FIND THE HAZARD CLASS OF A FORMULATION
The following tables A and B can be used to find the hazard class of a formulation. These should be used only if toxicity data is not available on the formulation itself; see the note at the top of page 7.
The tables should be used as follows:
Step 1: What is the approved name of the active ingredient in the pesticide? Use the index to find the entry in tables 1-5 of the Guidelines.
Step 2: From the entry in the Guidelines, what is the route of application used for the classification?
If the route is O (oral), use table A of this Annex. The same table is used for solids and liquids.
If the route is D (dermal), use table B of this Annex. The same table is used for solids and liquids.
Step 3: From the entry in the Guidelines, what is the LD50 of the active ingredient?
Using the table A or B, selected in Step 2, find the column along the top line which most nearly includes the LD50 figure.
Step 4: What is the concentration % of the active ingredient in the formulation?
Using the same table A or B, find the figure in the left hand column which most nearly includes this percentage figure.
Step 5: Find the square where the column selected in Step 3 crosses the line selected in Step 4. The number in this square is the approximate LD50 of the formulation.
Step 6: The hazard classes are shown by blocks of squares. The hazard class of the formulation is that of the block in which lies the square selected in Step 5.
These tables can also be used to find the hazard class of mixtures. First see page 7, para. 4 of the Guidelines and select the method to be used to arrive at the LD50 of the mixture. For method (b), use the above method from Step 1, using the name of the more or most toxic ingredient. For method (c), pass to Step 4 using the total percentages of all active ingredients in the mixture.
Tabl
e A
. LD
50 v
alue
s an
d cl
assi
ficat
ion
of fo
rmul
atio
ns w
hen
the
rout
e is
OR
AL
Firs
t row
= O
ral L
D50
of t
he a
ctiv
e in
gred
ient
Firs
t col
umn
= Pe
rcen
t con
cent
ratio
n of
the
activ
e in
gred
ient
in th
e fo
rmul
atio
n
C
lass
IaC
lass
IbC
lass
IIC
lass
III
13
510
1520
2530
3540
4550
6080
100
120
140
160
180
200
250
300
350
400
500
600
700
800
900
1000
1500
2000
2500
3000
3500
4000
4500
5000
100
13
510
1520
2530
3540
4550
6080
100
120
140
160
180
200
250
300
350
400
500
600
700
800
900
1000
1500
2000
2500
3000
3500
4000
4500
5000
951
35
1116
2126
3237
4247
5363
8410
512
614
716
818
921
126
331
636
842
152
663
273
784
294
710
5315
7921
0526
3231
5836
8442
1147
3790
13
611
1722
2833
3944
5056
6789
111
133
156
178
200
222
278
333
389
444
556
667
778
889
1000
1111
1667
2222
2778
3333
3889
4444
5000
851
46
1218
2429
3541
4753
5971
9411
814
116
518
821
223
529
435
341
247
158
870
682
494
110
5911
7617
6523
5329
4135
2941
1847
0680
14
613
1925
3138
4450
5663
7510
012
515
017
520
022
525
031
337
543
850
062
575
087
510
0011
2512
5018
7525
0031
2537
5043
7550
0075
14
713
2027
3340
4753
6067
8010
713
316
018
721
324
026
733
340
046
753
366
780
093
310
6712
0013
3320
0026
6733
3340
0046
6770
14
714
2129
3643
5057
6471
8611
414
317
120
022
925
728
635
742
950
057
171
485
710
0011
4312
8614
2921
4328
5735
7142
8650
0065
25
815
2331
3846
5462
6977
9212
315
418
521
524
627
730
838
546
253
861
576
992
310
7712
3113
8515
3823
0830
7738
4646
1560
25
817
2533
4250
5867
7583
100
133
167
200
233
267
300
333
417
500
583
667
833
1000
1167
1333
1500
1667
2500
3333
4167
5000
552
59
1827
3645
5564
7382
9110
914
518
221
825
529
132
736
445
554
563
672
790
910
9112
7314
5516
3618
1827
2736
3645
4550
26
1020
3040
5060
7080
9010
012
016
020
024
028
032
036
040
050
060
070
080
010
0012
0014
0016
0018
0020
0030
0040
0050
0045
27
1122
3344
5667
7889
100
111
133
178
222
267
311
356
400
444
556
667
778
889
1111
1333
1556
1778
2000
2222
3333
4444
403
813
2538
5063
7588
100
113
125
150
200
250
300
350
400
450
500
625
750
875
1000
1250
1500
1750
2000
2250
2500
3750
5000
353
914
2943
5771
8610
011
412
914
317
122
928
634
340
045
751
457
171
485
710
0011
4314
2917
1420
0022
8625
7128
5742
8630
310
1733
5067
8310
011
713
315
016
720
026
733
340
046
753
360
066
783
310
0011
6713
3316
6720
0023
3326
6730
0033
3350
0025
412
2040
6080
100
120
140
160
180
200
240
320
400
480
560
640
720
800
1000
1200
1400
1600
2000
2400
2800
3200
3600
4000
UN
LIK
ELY
205
1525
5075
100
125
150
175
200
225
250
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2500
3000
3500
4000
4500
5000
157
2033
6710
013
316
720
023
326
730
033
340
053
366
780
093
310
6712
0013
3316
6720
0023
3326
6733
3340
0046
67TO
PR
ESEN
T10
1030
5010
015
020
025
030
035
040
045
050
060
080
010
0012
0014
0016
0018
0020
0025
0030
0035
0040
0050
005
2060
100
200
300
400
500
600
700
800
900
1000
1200
1600
2000
2400
2800
3200
3600
4000
5000
AC
UTE
HA
ZA
RD
333
100
167
333
500
667
833
1000
1167
1333
1500
1667
2000
2667
3333
4000
4667
110
030
050
010
0015
0020
0025
0030
0035
0040
0045
0050
00IN
NO
RM
AL
US
E0.
520
060
010
0020
0030
0040
0050
000.
333
310
0016
6733
3350
000.
110
0030
0050
000.
0520
00
Tabl
e B
. LD
50 v
alue
s an
d cl
assi
ficat
ion
of fo
rmul
atio
ns w
hen
the
rout
e is
DER
MA
L
Firs
t row
= D
erm
al L
D50
of t
he a
ctiv
e in
gred
ient
Firs
t col
umn
= Pe
rcen
t con
cent
ratio
n of
the
activ
e in
gred
ient
in th
e fo
rmul
atio
n
C
lass
IaC
lass
IbC
lass
IIC
lass
III
15
1020
3040
5060
7080
9010
012
014
016
018
020
025
030
035
040
045
050
060
070
080
090
010
0015
0020
0025
0030
0035
0040
0045
0050
0010
01
510
2030
4050
6070
8090
100
120
140
160
180
200
250
300
350
400
450
500
600
700
800
900
1000
1500
2000
2500
3000
3500
4000
4500
5000
951
511
2132
4253
6374
8495
105
126
147
168
189
211
263
316
368
421
474
526
632
737
842
947
1053
1579
2105
2632
3158
3684
4211
4737
901
611
2233
4456
6778
8910
011
113
315
617
820
022
227
833
338
944
450
055
666
777
888
910
0011
1116
6722
2227
7833
3338
8944
4450
0085
16
1224
3547
5971
8294
106
118
141
165
188
212
235
294
353
412
471
529
588
706
824
941
1059
1176
1765
2353
2941
3529
4118
4706
801
613
2538
5063
7588
100
113
125
150
175
200
225
250
313
375
438
500
563
625
750
875
1000
1125
1250
1875
2500
3125
3750
4375
5000
751
713
2740
5367
8093
107
120
133
160
187
213
240
267
333
400
467
533
600
667
800
933
1067
1200
1333
2000
2667
3333
4000
4667
701
714
2943
5771
8610
011
412
914
317
120
022
925
728
635
742
950
057
164
371
485
710
0011
4312
8614
2921
4328
5735
7142
8650
0065
28
1531
4662
7792
108
123
138
154
185
215
246
277
308
385
462
538
615
692
769
923
1077
1231
1385
1538
2308
3077
3846
4615
602
817
3350
6783
100
117
133
150
167
200
233
267
300
333
417
500
583
667
750
833
1000
1167
1333
1500
1667
2500
3333
4167
5000
552
918
3655
7391
109
127
145
164
182
218
255
291
327
364
455
545
636
727
818
909
1091
1273
1455
1636
1818
2727
3636
4545
502
1020
4060
8010
012
014
016
018
020
024
028
032
036
040
050
060
070
080
090
010
0012
0014
0016
0018
0020
0030
0040
0050
0045
211
2244
6789
111
133
156
178
200
222
267
311
356
400
444
556
667
778
889
1000
1111
1333
1556
1778
2000
2222
3333
4444
403
1325
5075
100
125
150
175
200
225
250
300
350
400
450
500
625
750
875
1000
1125
1250
1500
1750
2000
2250
2500
3750
5000
UN
LIK
ELY
353
1429
5786
114
143
171
200
229
257
286
343
400
457
514
571
714
857
1000
1143
1286
1429
1714
2000
2286
2571
2857
4286
303
1733
6710
013
316
720
023
326
730
033
340
046
753
360
066
783
310
0011
6713
3315
0016
6720
0023
3326
6730
0033
3350
0025
420
4080
120
160
200
240
280
320
360
400
480
560
640
720
800
1000
1200
1400
1600
1800
2000
2400
2800
3200
3600
4000
TO P
RES
ENT
205
2550
100
150
200
250
300
350
400
450
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
3500
4000
4500
5000
157
3367
133
200
267
333
400
467
533
600
667
800
933
1067
1200
1333
1667
2000
2333
2667
3000
3333
4000
4667
1010
5010
020
030
040
050
060
070
080
090
010
0012
0014
0016
0018
0020
0025
0030
0035
0040
0045
0050
00A
CU
TE H
AZ
AR
D5
2010
020
040
060
080
010
0012
0014
0016
0018
0020
0024
0028
0032
0036
0040
0050
003
3316
733
366
710
0013
3316
6720
0023
3326
6730
0033
3340
0046
671
100
500
1000
2000
3000
4000
5000
IN N
OR
MA
L U
SE
0.5
200
1000
2000
4000
0.3
333
1667
3333
0.1
1000
5000
57
50-00-0 FM 5350-29-3 II 26, 5150-31-7 II 3250-65-7 U 4351-03-6 U 4452-51-7 II 2452-68-6 II 3252-85-7 Ib 2254-11-5 Ib 2255-38-9 II 2756-35-9 O 4756-38-2 Ia 20, 5256-72-4 Ib 2157-24-9 Ib 2357-74-9 II 25, 5158-89-9 II 28, 5160-51-5 II 2760-57-1 O 48, 5161-82-5 U 3962-38-4 Ia 20, 5162-73-7 Ib 2162-74-8 Ia 2063-25-2 II 2566-81-9 O 4872-20-8 O 4872-43-5 U 4372-54-8 O 5074-83-9 FM 5374-90-8 FM 5375-15-0 O 4775-21-8 FM 51, 5375-60-5 II 2775-99-0 U 4076-03-9 II 3276-06-2 FM 5376-44-8 O 49, 5176-87-9 II 2877-06-5 U 4178-34-2 O 4878-57-9 O 49
78-87-5 O 4879-11-8 III 3480-06-8 O 4780-33-1 O 4780-38-6 O 4881-81-2 Ib 2381-82-3 O 4881-84-5 O 4982-66-6 Ia 1982-68-8 U 4583-26-1 O 5083-59-0 O 5083-79-4 II 3184-65-1 U 3984-74-2 O 4885-34-7 O 4786-50-0 Ib 2186-86-2 U 4386-87-3 III 3786-88-4 O 4787-17-2 O 5087-86-5 Ib 22, 5188-85-7 O 48, 5190-43-7 III 3791-20-3 O 4992-52-4 III 3493-71-0 O 4793-72-1 O 4893-75-4 O 5093-76-5 O 50, 5194-74-6 II 2994-75-7 II 2694-81-5 II 2994-82-6 II 2694-96-2 O 4895-06-7 O 5096-12-8 O 4896-24-2 Ib 2197-17-6 O 4897-23-4 II 26
99-30-9 III 35101-05-3 O 47101-21-3 U 40101-27-9 O 47101-42-8 O 48103-17-3 O 47106-46-7 II 26107-02-8 Ib 21107-06-2 FM 51, 53107-13-1 O 47107-18-6 Ib 21107-49-3 O 50108-25-8 O 50108-62-3 II 29112-12-9 III 38113-48-4 III 37114-26-1 II 31115-26-4 O 48115-29-7 II 27115-31-1 O 49115-32-2 II 26115-78-6 II 25115-90-2 O 48116-01-8 O 48116-06-3 Ia 19116-16-5 O 49116-29-0 U 45117-18-0 U 45118-74-1 Ia 19, 51118-75-2 O 47119-12-0 II 31120-23-0 II 30120-62-7 O 50121-75-5 III 36122-14-5 II 27122-34-9 U 45122-42-9 U 44122-88-3 III 35123-33-1 U 43123-88-6 O 49, 51
Pesticide active ingredients, which occur in Tables 1-8, in CAS no order
For each active ingredient, the classification (Ia, Ib, II, III, or U (unlikely to pose an acute hazard in normal use, O (obsolete), FM (fumigant), and page number(s) are given.
CAS no Class Page CAS no Class Page CAS no Class Page
58
124-58-3 II 30125-67-9 II 27126-07-8 O 49126-22-7 O 47126-75-0 O 48131-11-3 U 41131-89-5 O 48132-66-1 U 43133-06-2 U 39133-07-3 U 42133-90-4 O 47134-31-6 O 49134-62-3 III 35136-25-4 O 48137-26-8 II 32, 51137-30-4 II 33137-42-8 II 29139-40-2 U 44140-41-0 O 49140-56-7 O 48140-57-8 O 47141-03-7 O 48141-66-2 Ib 21142-59-6 II 30143-33-9 Ib 23143-50-0 O 47148-79-8 III 38149-26-8 O 48150-68-5 O 49152-16-9 O 50156-62-7 O 47297-78-9 O 49297-97-2 O 50297-99-4 Ia 20, 52298-00-0 Ia 19, 51298-02-2 Ia 20298-03-3 O 48298-04-4 Ia 19299-84-3 O 48299-86-5 O 48
300-76-5 II 30301-12-2 Ib 22309-00-2 O 47, 51314-40-9 U 39314-42-1 O 49315-18-4 O 49327-98-0 O 50330-54-1 III 35330-55-2 III 36333-41-5 II 26371-86-8 O 49465-73-6 O 49467-69-6 U 42470-90-6 Ib 21485-31-4 O 47, 51495-73-8 O 47502-39-6 O 49, 51502-55-6 O 48507-60-8 O 50510-15-6 O 47, 51513-77-9 O 47532-34-3 O 47533-74-4 II 26534-52-1 Ib 22, 51535-89-7 O 48542-75-6 FM 53555-37-3 U 43556-22-9 O 49556-61-6 II 30563-12-2 II 27584-79-2 II 24584-79-2 II 24590-28-3 O 50592-01-8 Ia 19608-73-1 II 28, 51640-15-3 Ib 23640-19-7 Ib 22, 51644-64-4 O 48650-51-1 III 37671-04-5 O 47
682-80-4 O 48709-98-8 II 31731-27-1 U 46732-11-6 II 30741-58-2 II 24756-09-2 U 42759-94-4 II 27786-19-6 O 47834-12-8 II 24841-06-5 O 49886-50-0 III 38900-95-8 II 27919-76-6 O 47919-86-8 Ib 21944-22-9 O 49947-02-4 O 50950-10-7 O 49950-37-8 Ib 22957-51-7 II 27973-21-7 II 27991-42-4 O 49999-81-5 II 251014-69-3 O 481014-70-6 II 311031-47-6 O 501071-83-6 III 361085-98-9 U 401086-02-8 O 501113-02-6 Ib 221114-71-2 II 301129-41-5 II 301134-23-2 III 351194-65-6 III 351303-96-4 III 341314-84-7 Ib 231317-39-1 II 251327-53-3 O 471332-40-7 II 251420-06-3 O 501420-07-1 Ib 21
Pesticide active ingredients, which occur in Tables 1-8, in CAS no order, continued
For each active ingredient, the classification (Ia, Ib, II, III, or U (unlikely to pose an acute hazard in normal use, O (obsolete), FM (fumigant), and page number(s) are given.
CAS no Class Page CAS no Class Page CAS no Class Page
59
1468-37-7 O 481563-66-2 Ib 21, 511582-09-8 U 461593-77-7 U 411596-84-5 U 401610-17-9 O 471610-18-0 III 371646-88-4 O 471689-83-4 II 291689-84-5 II 241698-60-8 III 341715-40-8 O 471746-81-2 III 361754-58-1 O 481836-75-5 O 491836-77-7 O 471861-32-1 III 341861-40-1 U 391897-45-6 U 401910-42-5 II 301912-24-9 III 341912-25-0 O 491912-26-1 III 381918-00-9 II 261918-02-1 U 441918-11-2 O 501918-13-4 O 481918-16-7 II 311929-77-7 O 501929-82-4 II 301929-88-0 O 471967-16-4 O 471982-47-4 O 471982-49-6 U 452008-41-5 III 342032-59-9 O 472032-65-7 Ib 222079-00-7 Ib 212104-64-5 Ia 192104-96-3 O 47
2163-69-1 O 482163-79-3 O 492164-08-1 II 292164-08-1 U 432164-09-2 O 472164-17-2 U 422212-67-1 II 302227-13-6 O 502227-47-0 O 482275-14-1 O 492275-18-5 O 502275-23-2 Ib 232303-16-4 O 482303-17-5 III 382307-49-5 O 502307-68-8 U 442310-17-0 II 302312-35-8 III 372312-76-7 Ib 22, 512385-85-5 O 492425-06-1 Ia 19, 512425-10-7 II 332439-01-2 II 252439-10-3 II 272439-99-8 O 492487-01-6 O 492497-07-6 O 492514-53-6 O 482536-31-4 O 472540-82-1 O 492550-75-6 O 472587-90-8 O 482593-15-9 III 352595-54-2 Ib 222597-03-7 II 302631-37-0 O 502631-40-5 II 292636-26-2 II 252642-71-9 Ib 212655-14-3 II 33
2655-19-8 O 472669-32-1 O 492674-91-1 O 482675-77-6 O 472693-61-0 O 492699-79-8 FM 532759-71-9 O 482764-72-9 II 272778-04-3 O 482797-51-5 II 312813-95-8 O 482921-88-2 II 252980-64-5 Ib 22, 512941-55-1 O 483060-89-7 U 433134-12-1 O 493337-71-1 III 343347-22-6 II 273383-96-8 III 373495-42-9 O 473547-33-9 U 423689-24-5 Ia 203691-35-8 Ia 193734-95-0 O 483737-22-2 U 413740-92-9 U 413766-60-7 O 473766-81-2 II 273792-59-4 O 483811-49-2 O 483813-05-6 III 343861-47-0 II 293878-19-1 II 284104-14-7 O 504147-51-7 O 484151-50-2 II 324234-79-1 O 494301-50-2 O 494482-55-7 O 484489-31-0 O 49
Pesticide active ingredients, which occur in Tables 1-8, in CAS no order, continued
For each active ingredient, the classification (Ia, Ib, II, III, or U (unlikely to pose an acute hazard in normal use, O (obsolete), FM (fumigant), and page number(s) are given.
CAS no Class Page CAS no Class Page CAS no Class Page
60
4636-83-3 O 494658-28-0 O 474726-14-1 O 494824-78-6 O 474849-32-5 O 495131-24-8 O 485221-53-4 III 355234-68-4 III 345259-88-1 III 375598-13-0 III 345707-69-7 O 485787-96-2 Ib 22, 515827-05-4 O 495834-96-8 O 475836-10-2 O 475836-29-3 Ib 215902-51-2 U 455915-41-3 III 386164-98-3 O 47, 516392-46-7 O 476616-80-4 O 486923-22-4 Ib 22, 516988-21-2 O 487055-03-0 O 497085-19-0 II 297159-99-1 O 497187-36-7 O 497287-19-6 III 377292-16-2 O 507446-18-6 Ib 237487-94-7 Ia 197547-66-2 II 267681-49-4 O 507681-93-8 III 377696-12-0 U 457700-17-6 O 487704-34-9 III 377758-98-7 II 257773-06-0 III 347775-09-9 II 31
7778-44-1 Ib 217784-40-9 Ib 227784-46-5 Ib 237803-51-2 FM 538001-35-2 O 47, 518003-05-2 O 50, 518003-34-7 II 318018-01-7 U 438051-02-3 O 508065-36-9 O 479006-42-2 U 4310004-44-1 III 3610071-13-3 U 4310112-91-1 II 29, 5110265-92-6 Ib 22, 5110311-84-9 O 4810380-28-6 U 4410453-86-8 III 3710537-47-0 O 4910552-74-6 U 4310605-21-7 U 4012002-03-8 Ib 2212057-74-8 FM 5312071-83-9 U 4412122-67-7 U 4612407-86-2 O 5012427-38-2 U 4312771-68-5 III 3413067-93-1 O 4813071-79-9 Ia 2013121-70-5 II 2513171-21-6 Ia 20, 5213181-17-4 O 4713194-48-4 Ia 1913356-08-6 III 3613360-45-7 O 4713457-18-6 II 3113516-27-3 II 2913577-71-4 O 4913593-03-8 II 31
13598-36-2 U 4413684-56-5 U 4013684-63-4 U 4413952-84-6 II 2514214-32-5 O 4814255-88-0 O 4814437-17-3 O 4714484-64-1 U 4114491-59-9 O 4814750-35-4 U 4014816-18-3 II 3014816-20-7 O 4715096-52-3 U 4015263-53-3 II 2515299-99-7 U 4315302-91-7 II 2915310-01-7 O 4715457-05-3 O 4915545-48-9 U 4015845-66-2 U 4215879-93-3 II 2515972-60-8 II 2416118-49-3 U 4016484-77-8 II 2916672-87-0 III 3516752-77-5 Ib 2216893-85-9 O 5017029-22-0 O 4917040-19-6 O 4817109-49-8 Ib 2217606-31-4 II 2417804-35-2 U 39, 5118181-70-9 O 4918181-80-1 U 3918467-77-1 U 4118691-97-9 III 3618854-04-8 Ib 2219044-88-3 U 4419408-46-9 U 4319622-08-3 O 50
Pesticide active ingredients, which occur in Tables 1-8, in CAS no order, continued
For each active ingredient, the classification (Ia, Ib, II, III, or U (unlikely to pose an acute hazard in normal use, O (obsolete), FM (fumigant), and page number(s) are given.
CAS no Class Page CAS no Class Page CAS no Class Page
61
19666-30-9 U 4419691-80-6 O 4719937-59-8 III 3620354-26-1 O 4920427-59-2 II 2520856-57-9 O 4720859-73-8 FM 5321087-64-9 II 3021540-35-2 O 4921542-18-6 O 4921548-32-3 O 4921609-90-5 O 4921725-46-2 II 2521908-53-2 Ib 22, 5121923-23-9 O 4822224-92-6 Ib 2222248-79-9 III 3822259-30-9 Ib 2222274-74-0 O 4722571-07-9 O 5022781-23-3 II 2422936-75-0 III 3523031-36-9 II 3123103-98-2 II 3123135-22-0 Ib 2223184-66-9 III 3423505-41-1 O 5023560-59-0 Ib 2223564-05-8 U 4523564-06-9 O 5023783-98-4 Ia 19, 5123947-60-6 III 3523950-58-5 U 4424017-47-8 Ib 2324151-93-7 II 3024201-58-9 O 4824353-58-0 O 4824579-73-5 U 4424691-76-7 O 5024691-80-3 U 41
24934-91-6 Ia 1925057-89-0 II 2425311-71-1 O 4925319-90-8 II 2925366-23-8 O 5025954-13-6 III 3626002-80-2 U 4426087-47-8 II 2926129-32-8 O 4826225-79-6 U 4126259-45-0 O 5026399-36-0 O 5026530-20-1 II 3026644-46-2 U 4626718-65-0 Ia 1926766-27-8 O 5027314-13-2 U 4327355-22-2 U 4427386-64-7 O 4927541-88-4 O 5027605-76-1 III 3728217-97-2 O 4728249-77-6 II 3228434-01-7 U 3928559-00-4 O 4828772-56-7 Ia 1928805-78-9 O 4929091-05-2 III 3529091-21-2 U 4429104-30-1 O 4729173-31-7 O 4929232-93-7 II 3129672-19-3 O 4929973-13-5 Ib 2230043-49-3 O 4830560-19-1 II 2430979-48-7 O 4931218-83-4 Ib 2331251-03-3 O 4931848-11-0 O 47
31895-22-4 II 3232407-99-1 O 50, 5132534-96-6 O 4832791-87-0 U 4032809-16-8 U 4432861-85-1 O 4733089-61-1 II 2433245-39-5 II 2833629-47-9 II 2433693-04-8 II 3233820-53-0 O 4933878-50-1 O 4734014-18-1 II 3234123-59-6 II 2934205-21-5 III 3534256-82-1 III 3434264-24-9 O 5034462-96-9 O 4934643-46-4 II 3134681-10-2 Ib 2134681-23-7 Ib 2135256-85-0 O 4735256-85-0 U 4535367-38-5 III 3535400-43-2 O 5035554-44-0 II 2835575-96-3 II 2436335-67-8 II 2436519-00-3 O 5036614-38-7 O 4936734-19-7 III 3636756-79-3 U 4537248-47-8 U 4637407-77-5 O 4737764-25-3 III 3537893-02-0 O 4837894-46-5 O 4837924-13-3 O 5038260-54-7 O 4838727-55-8 O 48
Pesticide active ingredients, which occur in Tables 1-8, in CAS no order, continued
For each active ingredient, the classification (Ia, Ib, II, III, or U (unlikely to pose an acute hazard in normal use, O (obsolete), FM (fumigant), and page number(s) are given.
CAS no Class Page CAS no Class Page CAS no Class Page
62
39196-18-4 Ib 2339300-45-3 II 2739515-40-7 II 2639603-48-0 O 4740483-25-2 II 2640487-42-1 II 3040596-69-8 U 4341083-11-8 II 2441198-08-7 II 3141205-09-8 U 4241295-28-7 O 49, 5141394-05-2 II 2941483-43-6 III 3441814-78-2 II 3242509-80-8 O 4942576-02-3 U 3942588-37-4 O 4942609-52-9 III 3542609-73-4 U 4342874-03-3 U 4443121-43-3 II 3243222-48-6 II 2650471-44-8 U 4650512-35-1 II 2950563-36-5 II 2650594-66-6 II 2451218-45-2 III 3651218-49-6 U 4451235-04-2 II 2851308-54-4 O 4751487-69-5 O 4851630-58-1 II 2851707-55-2 III 3852304-36-6 U 4152315-07-8 II 2652315-07-8 Ib 2152645-53-1 II 3052888-80-9 II 3152918-63-5 II 2653112-28-0 III 37
53369-07-6 II 2853780-34-0 II 2954406-48-3 III 3554593-83-8 Ia 1954864-61-8 O 4955179-31-2 U 3955219-65-3 II 3255283-68-6 U 4155285-14-8 II 2555290-64-7 II 2655335-06-3 II 3255511-98-3 O 4755512-33-9 III 3755634-91-8 III 3455814-41-0 U 4355861-78-4 II 2956073-07-5 Ia 1956073-10-0 Ia 1956425-91-3 II 2857018-04-9 U 4557052-04-7 O 4957130-91-3 O 5057369-32-1 II 3157375-63-0 O 4957646-30-7 II 2857754-85-5 III 3557837-19-1 II 2957966-95-7 II 2558011-68-0 U 4558138-08-2 O 5058667-63-3 O 4858810-48-3 III 3759669-26-0 II 3259756-60-4 U 4260168-88-9 III 3660207-31-0 II 2460207-90-1 II 3160207-93-4 O 4860568-05-0 O 4961213-25-0 III 36
61432-55-1 II 2662610-77-9 II 2962850-32-2 II 2762865-36-5 U 4062924-70-3 U 4163278-33-1 O 4863284-71-9 II 3063333-35-7 Ia 1963935-38-6 U 4064249-01-0 II 2464257-84-7 II 2764491-92-5 O 4964628-44-0 U 4664902-72-3 U 4065907-30-4 Ib 2265934-95-4 O 4866063-05-6 U 4466215-27-8 III 3566230-04-4 II 2766246-88-6 III 3766332-96-5 U 4266841-25-6 II 3266952-49-6 II 3067129-08-2 III 3667306-00-7 II 2767375-30-8 II 2667485-29-4 II 2867564-91-4 III 3667747-09-5 II 3168038-71-1 III 3468085-85-8 II 2568228-20-6 O 5068359-37-5 Ib 2168505-69-1 III 3469309-47-3 O 5069327-76-0 III 3469335-91-7 O 4869377-81-7 U 4269409-94-5 O 4969581-33-5 O 48
Pesticide active ingredients, which occur in Tables 1-8, in CAS no order, continued
For each active ingredient, the classification (Ia, Ib, II, III, or U (unlikely to pose an acute hazard in normal use, O (obsolete), FM (fumigant), and page number(s) are given.
CAS no Class Page CAS no Class Page CAS no Class Page
63
69806-34-4 II 2870124-77-5 Ib 2270193-21-4 O 5071048-99-2 II 2471422-67-8 U 4071561-11-0 II 3171626-11-4 III 3472178-02-0 II 2873250-68-7 U 4373886-28-9 O 4974051-80-2 III 3774070-46-5 U 3974115-24-5 III 3574223-56-6 U 4574223-64-6 U 4374712-19-9 U 3974738-17-3 U 4174782-23-3 U 4475736-33-3 O 4876578-12-6 II 3176608-88-3 O 5076674-21-0 II 2876738-62-0 II 3077458-01-6 II 3177501-60-1 II 2877732-09-3 II 3078587-05-0 U 4279127-80-3 U 4179277-27-3 U 4579538-32-2 Ib 2379983-71-4 III 3680060-09-9 III 3580844-07-1 U 4181334-34-1 U 4281335-37-7 U 4281335-77-5 U 4281405-85-8 U 4281412-43-3 II 3281777-89-1 II 2582097-50-5 U 46
82110-72-3 O 4882211-24-3 U 4282558-50-7 U 4282560-54-1 II 2482657-04-3 II 2483055-99-6 U 3983066-88-0 III 3683121-18-0 U 4583130-01-2 II 2483164-33-4 III 3583657-22-1 II 3383657-24-3 III 3583733-82-8 O 4984087-01-4 III 3784332-86-5 III 3484496-56-0 U 4085509-19-9 II 2885785-20-2 III 3586479-06-3 U 4286598-92-7 U 4287130-20-9 U 4087310-56-3 O 4787674-68-8 II 2787757-18-4 O 4987818-31-3 II 2587820-88-0 II 3288283-41-4 III 3788485-37-4 II 2888671-89-0 II 3089269-64-7 II 2890035-08-8 Ia 1990134-59-1 III 3690717-03-6 U 4594050-52-9 U 4194361-06-5 II 2694593-91-6 U 4095465-99-9 Ib 2195721-12-3 O 4895737-68-1 U 4596182-53-5 Ia 20
96489-71-3 II 3197886-45-8 U 4198389-04-9 U 4598730-04-2 U 3998967-40-9 U 4299283-00-8 III 3499387-89-0 II 32101007-06-1 U 39101205-02-1 III 35101463-69-8 III 36102851-06-9 III 36103112-35-2 U 41104030-54-8 U 40104653-34-1 Ia 19106040-48-6 U 46107534-96-3 II 32108173-90-6 II 28110235-47-7 U 43110488-70-5 U 41111479-05-1 U 44111991-09-4 U 43111988-49-9 II 32112143-82-5 II 32112226-61-6 III 36112281-77-3 II 32112410-23-8 U 45112839-32-4 O 49113036-87-6 U 44114369-43-6 III 36116170-30-0 O 50116255-48-2 II 24116714-46-6 U 43118134-30-8 II 32118712-89-3 U 46119168-77-3 II 32119446-68-3 II 26119738-06-6 II 31120068-37-3 II 28120162-55-2 U 39120928-09-8 II 27
Pesticide active ingredients, which occur in Tables 1-8, in CAS no order, continued
For each active ingredient, the classification (Ia, Ib, II, III, or U (unlikely to pose an acute hazard in normal use, O (obsolete), FM (fumigant), and page number(s) are given.
CAS no Class Page CAS no Class Page CAS no Class Page
64
121451-02-3 U 44122008-85-9 U 40122453-73-0 II 25122931-48-0 U 45123343-16-8 III 37124495-18-7 U 45125116-23-6 II 29125401-75-4 III 34126535-15-7 U 46126833-17-8 U 41130000-40-7 U 45131341-86-1 U 41131807-57-3 U 41131860-33-8 U 39131929-60-7 U 45
131929-63-0 U 45131983-72-7 III 38134098-61-6 II 27136191-56-5 U 45136849-15-5 U 40138164-12-2 II 24138261-41-3 II 28139528-85-1 U 43140923-17-7 U 42141517-21-7 U 46142459-58-3 II 28144740-54-5 U 42145701-21-9 U 40145701-23-1 U 41149253-65-6 U 42
149877-41-8 U 39150114-71-9 U 39156052-68-5 U 46161050-58-4 U 43168316-95-8 III 37173584-44-6 II 29178928-70-6 U 45181274-17-9 U 41187166-40-1 U 45188425-85-6 U 39203313-25-1 III 37219714-96-2 U 44374726-62-2 U 43500008-45-7 U 40
Pesticide active ingredients, which occur in Tables 1-8, in CAS no order, continued
For each active ingredient, the classification (Ia, Ib, II, III, or U (unlikely to pose an acute hazard in normal use, O (obsolete), FM (fumigant), and page number(s) are given.
CAS no Class Page CAS no Class Page CAS no Class Page
65
Acephate II 24Acetochlor III 34Acifluorfen II 24Aclonifen U 39Acrinathrin U 39Acrolein Ib 21Acrylonitrile O 47Alachlor II 24Alanycarb II 24Aldicarb Ia 19Aldoxycarb O 47Aldrin O 47, 51Allethrin II 24Allidochlor O 47Alloxydim III 34Allyl alcohol Ib 21Allyxycarb O 47Alphachlorohydrin, see
3-Chloro-2,3-propanediol Ib 21
Alpha-cypermethrin II 24Aluminium phosphide FM 53Ametryn II 24Amidithion O 47Aminocarb O 47Aminopyralid U 39Aminotriazole, see Amitrole U 39Amitraz II 24Amitrole U 39Ammonium sulfamate III 34Ancymidol III 34Anilazine O 47Anilofos II 24Anthraquinone U 39ANTU O 47Aramite O 47Arsenous oxide O 47Asulam III 34Athidathion O 47Atraton O 47
Atrazine III 34Azaconazole II 24Azamethiphos II 24Azimsulfuron U 39Azidithion (Menazon) O 47Azinphos-ethyl Ib 21Azinphos-methyl Ib 21Aziprotryne O 47Azocyclotin II 24Azothoate O 47Azoxystrobine U 39Bacillus thuringiensis III 34Barban O 47Barium carbonate O 47Benalaxyl III 34Benazolin III 34Bendiocarb II 24Benefin, see Benfluralin U 39Benfluralin U 39Benfuracarb II 24Benfuresate III 34Benodanil O 47Benomyl U 39, 51Benoxacor U 39Benquinox O 47Bensulfuron-methyl U 39Bensulide II 24Bensultap II 24Bentazone II 24Benthrodine, see Benfluralin U 39Benzamidazole (Isoxaben) U 42Benzofos, see Phosalone II 30Benzoximate O 47Benzoylprop-ethyl O 47Benzthiazuron O 47BHC, see HCH II 28Bifenazate U 39Bifenox U 39Bifenthrin II 24
INDEX. CLASSIFICATION OF ACTIVE PESTICIDE INGREDIENTS
Ia = Extremely hazardous; Ib = Highly hazardous; II = Moderately hazardous;III = slightly hazardous; U = Unlikely to present acute hazard in normal use;FM = Fumigant, not classified; O = Obsolete as pesticide, not classified.
Common name Class Page Common name Class Page
66
Bilanafos II 24Binapacryl O 47, 51Bioallethrin II 24Bioresmethrin U 39Biphenyl III 34Bis(tributyltin) oxide O 47Bispyribac III 34Bisthiosemi O 47Bitertanol U 39Blasticidin-S Ib 21BMPC, see Fenobucarb II 27Borax III 34Boscalid U 39Brodifacoum Ia 19Bromacil U 39Bromadiolone Ia 19Bromethalin Ia 19Bromobutide U 39Bromocyclen O 47Bromofenoxim O 47Bromophos O 47Bromophos-ethyl O 47Bromopropylate U 39Bromoxynil II 24Bromuconazole II 24Bronopol II 24Bufencarb O 47Bupirimate III 34Buprofezin III 34Butacarb O 47Butachlor III 34Butam O 47Butamifos II 24Butenachlor O 47Buthidazole O 47Buthiobate O 47Butocarboxim Ib 21Butonate O 47Butopyronoxyl O 47
Butoxycarboxim Ib 21Butralin II 24Butroxydim II 25Buturon O 47Butylamine II 25Butylate III 34Cacodylic acid, see
Dimethylarsinic acid II 27
Cadusafos Ib 21Calcium arsenate Ib 21Calcium cyanamide O 47Calcium cyanide Ia 19Camphechlor O 47Captafol Ia 19, 51Captan U 39Carbamorph O 47Carbanolate O 47Carbaryl II 25Carbendazim U 40Carbetamide U 40Carbofos, see Malathion III 36Carbofuran Ib 21, 51Carbon disulfide O 47Carbophenothion O 47Carbosulfan II 25Carboxin III 34Carpropamid U 40Cartap II 25Chinomethionat III 34Chlomethoxyfen O 47Chloralose II 25Chloramben O 47Chlorantraniliprole U 40Chloraniformethan O 47Chloranil O 47Chloranocryl O 47Chloransulam methyl U 40Chlorbenside O 47Chlorbicyclen O 47
INDEX. CLASSIFICATION OF ACTIVE PESTICIDE INGREDIENTS, CONTINUED
Ia = Extremely hazardous; Ib = Highly hazardous; II = Moderately hazardous;III = slightly hazardous; U = Unlikely to present acute hazard in normal use;FM = Fumigant, not classified; O = Obsolete as pesticide, not classified.
Common name Class Page Common name Class Page
67
Chlorbromuron O 47Chlorbufam O 47Chlordane II 25, 51Chlordecone O 47Chlordimeform O 47, 51Chlorethoxyfos Ia 19Chlorfenac O 47Chlorfenapyr II 25Chlorfenethol O 47Chlorfenidin (Monuron) O 49Chlorfenprop-methyl O 47Chlorfenson O 47Chlorfensulfide O 47Chlorfenvinphos Ib 21Chlorfluazuron U 40Chlorflurecol, see
Chlorflurenol O 47
Chlorflurenol O 47Chloridazon III 34Chlorimuron III 34Chlormebuform O 47Chlormephos Ia 19Chlormequat (chloride) II 25Chlormethiuron O 47Chlornitrofen O 47Chloroacetic acid II 25Chlorobenzilate O 47, 51Chlorocholine chloride, see
Chlormequat (chloride) II 25
Alphachlorohydrin, see 3-Chloro-2,3-propanediol Ib 21
Chloroneb O 47Chlorophacinone Ia 19Chloropicrin FM 533-Chloro-1,2-propanediol Ib 21Chloropropylate O 47Chlorothalonil U 40Chlorotoluron U 40Chloroxuron O 47
Chlorphenamidine (Chlordimeform) O 47, 51
Chlorphonium chloride O 47Chlorphoxim O 47Chlorpropham U 40Chlorpyrifos II 25Chlorpyrifos methyl III 34Chlorquinox O 47Chlorsulfuron U 40Chlorthal-dimethyl III 34Chlorthiamid O 48Chlorthiophos O 48Chlozolinate III 34Cinmethylin III 35Cinosulfuron U 40Cismethrin, see Resmethrin III 37Citrex, see Dodine II 27Cloethocarb O 48Clofentezine III 35Clofop O 48Clomazone II 25Clomeprop U 40Clonitralide, see Niclosamide U 43Clopyralid III 35Cloxyfonac U 40CNA, see Dicloran III 35COMU (Cycluron) O 48Copper hydroxide II 25Copper oxychloride II 25Copper sulfate II 25Coumachlor O 48Coumaphos Ib 21Coumatetralyl Ib 214-CPA III 35Credazine O 48Crimidine O 48Crotoxyphos O 48Crufomate O 48Cryolite U 40
INDEX. CLASSIFICATION OF ACTIVE PESTICIDE INGREDIENTS, CONTINUED
Ia = Extremely hazardous; Ib = Highly hazardous; II = Moderately hazardous;III = slightly hazardous; U = Unlikely to present acute hazard in normal use;FM = Fumigant, not classified; O = Obsolete as pesticide, not classified.
Common name Class Page Common name Class Page
68
Cuprous oxide II 25CVP, see Chlorfenvinphos Ib 21Cyanazine II 25Cyanofenphos O 48CYAP, see Cyanophos II 25Cyanophos II 25Cyanthoate O 48Cycloate III 35Cycloheximide O 48Cycloprothrin U 40Cyclosulfamuron U 40Cycloxydim III 35Cycluron O 48Cyfluthrin Ib 21Beta-cyfluthrin Ib 21Cyhalofop U 40Cyhalothrin II 25Lambda-cyhalothrin II 25CYP (Cyanofenphos) O 48Cyhexatin II 25Cymoxanil II 25Cyometrinil O 48Cypendazole O 48Cypermethrin II 26Alpha-cypermethrin II 26Cyphenothrin [(1R)-isomers] II 26Cyproconazole II 26Cyprofuram O 48Cypromid O 48Cyromazine III 352,4-D II 26Daimuron U 40Dalapon U 40Daminozide U 40DAPA (Fenaminosulf) O 48Dazomet II 26DBCP
(Dibromochloro propane) O 48
DCBN (Chlorthiamid) O 48
2,4-DB II 26DDT II 26, 51DDVF, see Dichlorvos Ib 21DDVP, see Dichlorvos Ib 21DEET, see Diethyltoluamide III 35Dehydroacetic acid (Disul) O 48Delachlor O 48Delnav (Dioxathion) O 48Deltamethrin II 26Demephion-O O 48Demephion-S O 48Demeton-O O 48Demeton-S O 48Demeton-S-methyl Ib 21Demeton-S-methylsulphon O 482,4-DES (Disul) O 48Desmedipham U 40Desmetryn O 48Diafenthiuron III 35Dialifor (Dialifos) O 48Dialifos O 48Di-allate O 48Diallyldichloroacetamide, see
DichlormidIII 35
Diamidafos O 48Dibrom, See Naled II 30Diazinon II 26Dibromochloropropane O 481,2-Dibromoethane (EDB) FM 51, 53Dibutyl phthalate O 48Dibutyl succinate O 48Dicamba II 26Dichlobenil III 35Dichlofenthion O 48Dichlofluanid U 40Dichlorfenidim, see Diuron III 35Dichlormid III 35Dichlorobenzene II 26Dichlorophen II 26
INDEX. CLASSIFICATION OF ACTIVE PESTICIDE INGREDIENTS, CONTINUED
Ia = Extremely hazardous; Ib = Highly hazardous; II = Moderately hazardous;III = slightly hazardous; U = Unlikely to present acute hazard in normal use;FM = Fumigant, not classified; O = Obsolete as pesticide, not classified.
Common name Class Page Common name Class Page
69
Dichloropicolinic acid, see Clopyralid III 35
1,2-Dichloropropane O 481,3-Dichloropropene FM 51, 53Dichlorprop II 26Dichlorvos Ib 21Dichlozoline O 48Diclobutrazol O 48Diclofop II 26Diclomezine U 40Dicloran III 35Diclosulam U 40Dicofol II 26Dicrotophos Ib 21Dieldrin O 48, 51Dienochlor O 48Diethatyl O 48Diethofencarb U 40Diethyltoluamide III 35Difenacoum Ia 19Difenoconazole II 26Difenoxuron O 48Difenzoquat II 26Difethialone Ia 19Diflubenzuron III 35Diflufenican III 35Difolatan, see Captafol Ia 19, 51Dikegulac U 41Dimefox O 48Dimefuron III 35Dimepiperate II 26Dimethachlor II 26Dimethametryn III 35Dimethenamid II 27Dimethipin II 26Dimethirimol III 35Dimethoate II 27Dimethomorph U 41Dimethyl phthalate U 41
Dimethylarsinic acid II 27Dimetilan O 48Dimexano O 48Dinex O 48Diniconazole II 27Dinitramine III 35Dinobuton II 27Dinocap II 27Dinocton O 48Dinoseb O 48, 51Dinoseb acetate O 48, 51Dinoterb Ib 21Dioxabenzophos O 48Dioxacarb O 48Dioxathion O 48Diphacinone Ia 19Diphenamid II 27Diphenyl, see Biphenyl III 34Dipropetryn O 48Dipropyl isocinchomerate U 41Diquat II 27Disodium octaborate,
see Borax III 34
Disul O 48Disulfoton Ia 19Ditalimfos O 48Dithianon II 27Dithiopyr U 41Diuron III 35DMTP, see Methidathion Ib 22DNBP (Dinoseb) O 48, 51DNBPA (Dinoseb acetate) O 48, 51DNOC Ib 22, 51Dodemorph U 41Dodine II 27Doguanide, see Dodine II 27Drazoxolon O 48DSMA, see
Methylarsonic acid II 30
INDEX. CLASSIFICATION OF ACTIVE PESTICIDE INGREDIENTS, CONTINUED
Ia = Extremely hazardous; Ib = Highly hazardous; II = Moderately hazardous;III = slightly hazardous; U = Unlikely to present acute hazard in normal use;FM = Fumigant, not classified; O = Obsolete as pesticide, not classified.
Common name Class Page Common name Class Page
70
EDDP, see Edifenphos Ib 22Edifenphos Ib 22Eglinazine O 48Empenthrin [(1R) isomers] III 35Endosulfan II 27Endothal-sodium II 27Endothion O 48Endrin O 48EPBP O 48Ephirsulfonate see
Chlorfenson O 47
EPN Ia 19Epoxyethane, see
Ethylene oxide FM 51, 53
EPTC II 27Erbon O 48Esbiol, see Bioallethrin II 24Esbiothrin, see Bioallethrin II 24Esdeballéthrin, see
Bioallethrin II 24
Esfenvalerate II 27ESP (Oxydeprofos) O 48Esprocarb III 35Etacelasil O 48Etaconazole O 48Ethalfluralin U 41Ethephon III 35Ethidimuron O 48Ethiofencarb Ib 22Ethiolate O 48Ethion II 27Ethirimol U 41Ethoate-methyl O 48Ethofumesate U 41Ethohexadiol O 48Ethoprop, see Ethoprophos Ia 19Ethoprophos Ia 19Ethyl butylacetylaminopropionate U 41
Ethylene dichloride FM 51, 53
Ethylene oxide FM 51, 53Ethyleneglycol-
bis(trichloroacetate) O 48
Ethylthiometon, see Disulfoton Ia 19
Etofenprox U 41Etridiazole III 35Etrimfos O 48EXD O 48Famoxadone U 41Famphur Ib 22Fenaminosulf O 48Fenamiphos Ib 22Fenarimol III 36Fenazaflor O 48Fenazaquin II 27Fenbuconazole III 36Fenbutatin oxide III 36Fenchlorazole U 41Fenchlorphos O 48Fenclorim U 41Fenfuram U 41Fenhexamid U 41Fenidim, see Fenuron O 48Fenitropan O 48Fenitrothion II 27Fenobucarb II 27Fenoprop (Silvex) O 48Fenothiocarb II 27Fenoxaprop-ethyl O 48Fenoxycarb U 41Fenpiclonil U 41Fenpropathrin II 27Fenpropidin II 27Fenpropimorph III 36Fenpyroximate II 27Fenson O 48Fensulfothion O 48Fenthiaprop O 48
INDEX. CLASSIFICATION OF ACTIVE PESTICIDE INGREDIENTS, CONTINUED
Ia = Extremely hazardous; Ib = Highly hazardous; II = Moderately hazardous;III = slightly hazardous; U = Unlikely to present acute hazard in normal use;FM = Fumigant, not classified; O = Obsolete as pesticide, not classified.
Common name Class Page Common name Class Page
71
Fenthion II 27Fentin acetate II 27Fentin hydroxide II 28Fenuron O 48Fenuron-TCA O 48Fenvalerate II 28Ferbam U 41Ferimzone II 28Fipronil II 28Flamprop O 48Flamprop-M III 36Flocoumafen Ia 19Florasulam U 41Fluazifop O 48Fluazifop-p-butyl III 36Flubenzimine O 48Flucarbazone-sodium U 41Fluchloralin II 28Flucycloxuron U 41Flucythrinate Ib 22Fludioxinil U 41Fluenetil O 49Flufenacet II 28Flufenoxuron III 36Flumetralin U 41Flumetsulam U 42Fluometuron U 42Fluoroacetamide Ib 22, 51Fluorodifen O 49Fluoroglycofen II 28Fluoromide O 49Fluotrimazole O 49Flupropanate U 42Flupyrsulfuron U 42Flurecol-butyl, see Flurenol U 42Flurenol U 42Fluridone U 42Flurochloridone III 36Fluroxypyr U 42
Flurprimidol II 28Flusilazole II 28Fluthiacet U 42Flutolanil U 42Flutriafol II 28tau-Fluvalinate III 36Fluvalinate O 49Fluxofenim II 28Folpet U 42Fomesafen II 28Fonofos O 49Formaldehyde FM 53Formetanate Ib 22Formothion O 49Fosamine III 36Fosetyl U 42Fosfamid, see Dimethoate II 27Fosmethilan O 49Fosthietan O 49Fuberidazole II 28Furalaxyl II 28Furathiocarb Ib 22Furconazole-cis O 49Furmecyclox O 49Gamma-BHC, see
gammma-HCH II 28, 51
Gamma-HCH II 28, 51Gibberellic acid U 42Glufosinate II 28Glyodin O 49Glyphosate III 36Glyphosine O 49Griseofulvin O 49Guazatine II 28Halacrinate O 49Halofenozide III 36Haloxydine O 49Haloxyfop II 28HCH II 28, 51
INDEX. CLASSIFICATION OF ACTIVE PESTICIDE INGREDIENTS, CONTINUED
Ia = Extremely hazardous; Ib = Highly hazardous; II = Moderately hazardous;III = slightly hazardous; U = Unlikely to present acute hazard in normal use;FM = Fumigant, not classified; O = Obsolete as pesticide, not classified.
Common name Class Page Common name Class Page
72
Heptachlor O 49, 51Heptenophos Ib 22Heptopargil O 49Hexachloroacetone O 49Hexachlorobenzene Ia 19, 51Hexaconazole III 36Hexaflumuron U 42Hexaflurate O 49Hexazinone II 28Hexythiazox U 42Hydramethylnon II 28Hydrogen cyanide FM 53Hydroprene U 422-Hydroxyethyl-octyl sulphide U 42Hydroxyisoxazole, see
HymexazolIII 36
Hydroxyquinolinesulfate O 49Hymexazol III 36Imazalil II 28Imazamethabenzmethyl U 42Imazapyr U 42Imazaquin U 42Imazethapyr U 42Imibenconazole U 42Imidacloprid II 28Iminoctadine II 29Inabenfide U 42Iodofenphos (Jodfenphos) O 49Indoxacarb II 29Ioxynil II 29Ioxynil octanoate II 29Ipazine O 49IBP, see Iprobenfos II 29Iprobenfos II 29Iprodione III 36Iprovalicarb U 42IPSP O 49Isazofos O 49Isobenzan O 49
Isobornyl thiocyanoacetate O 49Isocarbamid O 49Isocil O 49Isodrin O 49Isofenphos O 49Isomethiozin O 49Isonoruron O 49Isoprocarb II 29Isopropalin O 49Isoprothiolane II 29Isoproturon II 29Isothioate O 49Isouron II 29Isoxaben U 42Isoxapyrifop O 49Isoxathion Ib 22Jodfenphos O 49Karbation, see Metam-sodium II 29Karbutilate O 49Kasugamycin U 43Kelevan O 49Keltane, see Dicofol II 26Kinoprene O 49Lambda-cyhalothrin II 29Lead arsenate Ib 22Lenacil U 43Leptophos O 49Lindane, see Gamma-HCH II 28, 51Linuron III 36Lythidathion O 49M74, see Disulfoton Ia 19Magnesium phosphide FM 53Malathion III 36Maldison, see Malathion III 36Maleic hydrazide U 43Malonoben O 49Mancozeb U 43Mandipropamid U 43Maneb U 43
INDEX. CLASSIFICATION OF ACTIVE PESTICIDE INGREDIENTS, CONTINUED
Ia = Extremely hazardous; Ib = Highly hazardous; II = Moderately hazardous;III = slightly hazardous; U = Unlikely to present acute hazard in normal use;FM = Fumigant, not classified; O = Obsolete as pesticide, not classified.
Common name Class Page Common name Class Page
73
MBCP (Leptophos) O 49MCC (SWEP) O 50MCPA II 29MCPA-thioethyl II 29MCPB II 29Mebenil O 49Mecarbam Ib 22Mecarbinzid O 49Mecarphon O 49Mecoprop II 29Mecoprop-P II 29Medinoterb acetate O 49Mefenacet U 43Mefluidide II 29Menazon O 49MEP, see Fenitrothion II 27Mepanipyrim U 43Mephospholan O 49Mepiquat II 29Mepronil U 43Mercapthphos (Demeton-O and Demeton-S ) O 48
Mercaptodimethur, see Methiocarb Ib 22
Mercuric chloride Ia 19, 51Mercuric oxide Ib 22, 51Mercurous chloride II 29, 51Metalaxyl II 29Metaldehyde II 29Metamitron II 29Metam-sodium II 29Metaphos, see
Parathion-methyl Ia 19
Metazachlor III 36Metconazole II 29Methabenzthiazuron III 36Methacrifos II 29Methamidophos Ib 22, 51Methasulfocarb II 30Methazole O 49
Methidathion Ib 22Methiocarb Ib 22Methiuron O 49Methomyl Ib 22Methoprene U 43Methoprotryne O 49Methoxychlor U 43Methoxyethylmercury silicate O 49, 51Methoxymethyl mercury
chloride O 49, 51
Methoxyphenone O 49Methozyfenozide U 43Methyl bromide FM 53Methyl isothiocyanate II 30Methylarsonic acid II 30Methyldymron III 36Methylmercapthphos teolovy,
see Demeton-S-methyl Ib 21
Methylmercury dicyandiamide O 49, 51Methyl-parathion Ia 19, 51Metilmerkaptophosoksid, see
Oxydemeton-methyl Ib 22
Metiram U 43Metobromuron U 43Metolachlor III 36Metolcarb II 30Metosulam U 43Metoxuron III 36Metribuzin II 30Metriltriazotion, see
Azinphos-methyl Ib 21
Metsulfovax O 49Metsulfuron methyl U 43Metsulfuron, see
Metsulfuron methyl U 43
Mevinphos Ia 19Mexacarbate O 49MICP, see Isoprocarb II 29Mipafox O 49Mirex2 O 49
INDEX. CLASSIFICATION OF ACTIVE PESTICIDE INGREDIENTS, CONTINUED
Ia = Extremely hazardous; Ib = Highly hazardous; II = Moderately hazardous;III = slightly hazardous; U = Unlikely to present acute hazard in normal use;FM = Fumigant, not classified; O = Obsolete as pesticide, not classified.
Common name Class Page Common name Class Page
74
Molinate II 30Monalide O 49Monocrotophos Ib 22, 51Monolinuron III 36Monuron O 49Monuron-TCA O 49Morfamquat O 49MPMC, see Xylylcarb II 33MPP, see Fenthion II 27MSMA, see
Methylarsonic acid II 30
Myclobutanil II 30Myclozolin O 49Nabam II 30NAC, see Carbaryl II 25Naled II 30Naphthalene O 49Naphthalic anhydride O 492-(1-Naphthyl) acetamide U 431-Naphthylacetic acid III 37Napropamide U 43Naptalam U 432-Napthyloxyacetic acid II 30Neburon U 43Niclosamide U 43Nicosulfuron U 43Nicotine Ib 22Nitralin O 49Nitrapyrin II 30Nitrilacarb O 49Nitrofen O 49Nitrothal-isopropyl U 43Norbormide O 49Norflurazon U 43Noruron O 49Novaluron U 43Noviflumuron U 44Nuarimol II 30Octhilinone II 30
N-octylbicycloheptene dicarboximide III 37
(Octylthio)ethanol, see 2-Hydroxyethyloctyl sulphide U 42
Ofurace III 37Omethoate Ib 22Oryzalin U 44Oxabetrinil U 44Oxadiazon U 44Oxadixyl II 30Oxamyl Ib 22Oxapyrazon O 49Oxine-copper U 44Oxycarboxin III 37Oxydemeton-methyl Ib 22Oxydisulfoton O 49Oxyfluorfen U 442,4 PA, see 2,4-D II 26Paclobutrazol II 30Palléthrin, see Allethrin II 24PAP, see Phenthoate II 30Paradichlorobenzene, see
Dichlorobenzene II 26
Parafluron O 49Paraquat II 30Parathion Ia 19, 52Parathion-methyl Ia 19, 51Paris green Ib 22Pebulate II 30Penconazole III 37Pencycuron U 44Pendimethalin II 30Penoxsulam U 44Pentachlorophenol Ib 22, 51Pentanochlor U 44Perfluidone O 49Permethrin II 30PHC, see Propoxur II 31Phenisobromolate, see
Bromopropylate U 39
INDEX. CLASSIFICATION OF ACTIVE PESTICIDE INGREDIENTS, CONTINUED
Ia = Extremely hazardous; Ib = Highly hazardous; II = Moderately hazardous;III = slightly hazardous; U = Unlikely to present acute hazard in normal use;FM = Fumigant, not classified; O = Obsolete as pesticide, not classified.
Common name Class Page Common name Class Page
75
Phenisopham O 49Phenkapton O 49Phenmedipham U 44Phenobenzuron O 49Phenothrin U 44Phenthoate II 30Phenylmercury acetate Ia 20, 51Phenylmercury dimethyl-
dithiocarbamate O 50, 51
Phenylmercury nitrate O 50, 512-Phenylphenol III 37Phorate Ia 20Phosacetim O 50Phosalone II 30Phosdiphen O 50Phosfolan O 50Phosmet II 30Phosphamidon Ia 20, 51Phosphine FM 53Phosphorus acid U 44Phoxim II 30Phthalide U 44Phthalofos, see Phosmet II 30Picloram U 44Pimaricin III 37Pindone O 50Piperonyl butoxide U 44Piperophos II 30Piproctanyl O 50Pirimicarb II 31Pirimiphos-ethyl O 50Pirimiphos-methyl II 31Polychlorocamphene
(Camphechlor) O 47, 51
Potassium cyanate O 50Prallethrin II 31Pretilachlor U 44Primisulfuron U 44Probenazole III 37Prochloraz II 31
Procymidone U 44Prodiamine U 44Profenofos II 31Profluralin O 50Proglinazine O 50Promacyl O 50Promecarb O 50Prometon III 37Prometryn III 37Pronamide, see Propyzamide U 44Propachlor II 31Propamocarb U 44Propanil II 31Propaphos O 50Propaquizafop U 44Propargite III 37Propazine U 44Propetamphos Ib 23Propham U 44Propiconazole II 31Propineb U 44Propoxur II 31Propyl isome O 50Propyzamide U 44Prosulfocarb II 31Prothiocarb O 50Prothioconazole U 45Prothiofos II 31Prothoate O 50Protiophos, see Prothiofos II 31Proxan O 50Pydanon O 50Pyracarbolid O 50Pyraclofos II 31Pyrazolynate U 45Pyrazon, see Chloridazon III 34Pyrazophos II 31Pyrazosulfuron U 45Pyrazoxyfen II 31
INDEX. CLASSIFICATION OF ACTIVE PESTICIDE INGREDIENTS, CONTINUED
Ia = Extremely hazardous; Ib = Highly hazardous; II = Moderately hazardous;III = slightly hazardous; U = Unlikely to present acute hazard in normal use;FM = Fumigant, not classified; O = Obsolete as pesticide, not classified.
Common name Class Page Common name Class Page
76
Pyrethrins II 31Pyridaben II 31Pyridaphenthion II 31Pyridate III 37Pyridinitril O 50Pyrifenox III 37Pyrimethanil III 37Pyriminobac U 45Pyriproxyfen U 45Pyrithiobac sodium III 37Pyroquilon II 31Quinacetol sulfate O 50Quinalphos II 31Quinclorac III 37Quinmerac U 45Quinoclamine II 31Quinomethionate, see
Chinomethionat III 34
Quinonamid O 50Quinoxyfen U 45Quintozene U 45Quizalofop II 31Quizalofop-p-tefuryl II 31Red squill (Scilliroside) O 50Reglon, see Diquat II 27Resmethrin III 37Rimsulfuron U 45Ronnel (Fenchlorphos) O 48Rotenone II 31Ryania O 50Ryanocline (Ryania) O 50Sabadilla O 50Salicylanilide O 50Salithion (Dioxabenzophos) O 48SAP, see Bensulide II 24Schradan O 50Scilliroside O 50Secbumeton O 50Sec-butylamine, see
Butylamine II 25
Sesamex O 50Sethoxydim III 37Sevin, see Carbaryl II 25Siduron U 45Silvex (Fenoprop) O 48Simazine U 45Simetryn II 31Sodium arsenite Ib 23Sodium borate, see Borax III 34Sodium chlorate II 31Sodium cyanide Ib 23Sodium fluoride O 50Sodium fluoroacetate Ia 20Sodium hexafluorosilicate O 50Spinetoram U 45Spinosad III 37Spirotetramat III 37Spiroxamine II 32Stirofox, see
Tetrachlorvinphos III 38
Strychnine Ib 23Sulfallate O 50Sulfluramid II 32Sulfometuron U 45Sulfotep Ia 20Sulfur, see Sulphur III 37Sulfoxide O 50Sulfuryl fluoride FM 53Sulphur III 37Sulprofos O 502,4,5-T O 50, 51tau-Fluvalinate III 372,3,6-TBA II 32TCA (acid) II 32TCA (sodium salt) III 37TDE O 50Tebuconazole II 32Tebufenozide U 45Tebufenpyrad II 32
INDEX. CLASSIFICATION OF ACTIVE PESTICIDE INGREDIENTS, CONTINUED
Ia = Extremely hazardous; Ib = Highly hazardous; II = Moderately hazardous;III = slightly hazardous; U = Unlikely to present acute hazard in normal use;FM = Fumigant, not classified; O = Obsolete as pesticide, not classified.
Common name Class Page Common name Class Page
77
Tebupirimfos Ia 20Tebutam U 45Tebuthiuron II 32Tecnazene U 45Tedion, see Tetradifon U 45Teflubenzuron U 45Tefluthrin Ib 23Temephos III 37TEPP O 50Terbacil U 45Terbucarb O 50Terbufos Ia 20Terbumeton II 32Terbuthylazine III 38Terbutryn III 38Tetrachlorvinphos III 38Tetraconazole II 32Tetradifon U 45Tetramethrin U 45Tetrasul O 50Thallium sulfate Ib 23Thiabendazole III 38Thiacloprid II 32Thiazafluron O 50Thiazfluorin, see Thiazafluron O 50Thicyofen O 50Thidiazuron III 38Thifensulfuron-methyl U 45Thifluzamide U 45Thiobencarb II 32Thiocyclam II 32Thiodan, see Endosulfan II 27Thiodicarb II 32Thiofanox Ib 23Thiofos, see Parathion Ia 19, 52Thiometon Ib 23Thionazin O 50Thiophanate O 50Thiophanate-methyl U 45
Thioquinox O 50Thioxamyl, see Oxamyl Ib 22Thiram II 32, 51Timet, see Phorate Ia 20Tiocarbazil U 45TMTD, see Thiram II 32, 51Tolclofos-methyl U 46Tolylfluanid U 46Tolylmethylcarbamate, see
Metolcarb II 30
Toxaphene (Camphechlor) O 47, 512,4,5-TP (Fenoprop) O 48Tralkoxydim II 32Tralomethrin II 32Transfluthrin U 46Triadimefon II 32Triadimenol II 32Tri-allate III 38Triamiphos O 50Triapenthenol O 50Triarimol O 50Triasulfuron U 46Triazamate II 32Triazophos Ib 23Triazotion,
see Azinphos-ethyl Ib 21
Tribenuron U 46Tricamba O 50Trichlamide O 50Trichlorfon II 32Trichloronat O 50Triclopyr II 32Tricyclazole II 32Tridemorph II 32Tridiphane O 50Trietazine III 38Trifenmorph O 50Trifloxystrobin U 46Triflumizole II 32Triflumuron U 46
INDEX. CLASSIFICATION OF ACTIVE PESTICIDE INGREDIENTS, CONTINUED
Ia = Extremely hazardous; Ib = Highly hazardous; II = Moderately hazardous;III = slightly hazardous; U = Unlikely to present acute hazard in normal use;FM = Fumigant, not classified; O = Obsolete as pesticide, not classified.
Common name Class Page Common name Class Page
78
Trifluralin U 46Triflusulfuron-methyl U 46Triforine U 46Trimethacarb O 50Triticonazole III 38Trizazotion, see
Azinphos-ethyl Ib 21
Undecan-2-one III 38Uniconazole II 33Validamycin U 46Vamidothion Ib 23
Vernolate O 50Vinclozolin U 46Warfarin Ib 23XMC II 33Xylylcarb II 33Zeta-cypermethrin Ib 21Zinc phosphide Ib 23Zineb U 46Ziram II 33Zoxamide U 46
INDEX. CLASSIFICATION OF ACTIVE PESTICIDE INGREDIENTS, CONTINUED
Ia = Extremely hazardous; Ib = Highly hazardous; II = Moderately hazardous;III = slightly hazardous; U = Unlikely to present acute hazard in normal use;FM = Fumigant, not classified; O = Obsolete as pesticide, not classified.
Common name Class Page Common name Class Page