SARDAR PATEL UNIVERSITY Programme: B.Sc (Chemistry ... - 4 Science.pdf · monosaccharides, simple...

SARDAR PATEL UNIVERSITY

Programme: B.Sc (Chemistry)

Semester: III

Syllabus with effect from: JUNE

2019

(30 +70 Marks, 4 hrs per week)

Subject Code: US03CCHE21 Total Credit: 4

Title Of Subject: Inorganic Chemistry

Unit Description in detail Weighting (%)

I ACID-BASE AND NON-AQUEOUS SOLVENT

ACIDS AND BASES Arrhenius concept-the water ion system, Lowry-Bronsted theory-the proton donor-

acceptor system, Conjugate acid-base pairs, Relative strength of acids and bases,

Periodic variations of acidic and basic properties, The leveling effect, leveling and

differentiating solvents, Utility and limitation of Bronsted concept, Utility and

limitation of Bronsted concept, The Lewis concept-the electron donor concept

system, Classification of Lewis acids, Classification of Lewis acids, Classification

of Lewis acids and bases in to Hard and Soft Acids and Bases, HSAB principle and

stability of the complex A:B, The Usanovich concept-the positive-negative system.

NON-AQUEOUS SOLVENT Classification of solvents, General properties of ionizing solvents(physical and

chemical), Chemical reactions, Liquid ammonia as non-aqueous solvent, Solubility

of substance in liq. NH3, Advantage and disadvantage of using liq. NH3 as a

solvent, Auto-ionization of liq. NH3, Chemical reactions occurring in liq. NH3,

Liquid sulphur dioxide as solvent, Chemical reactions occurring in liq. SO2

25%

2 VALANCE BOND THEORYAND ISOMERISM IN COORDINATION

COMPOUNDS Main assumption of VBT, Octahedral complexes- d2sp3 or sp3d2: [Fe(CN)6]4-,

[Fe(F)6]3-, Tetrahedral complexes- sp3: [Ni(CO)4], [Ni(Cl)4]2-, Square planar

complexes- dsp2: [Ni(CN)4]2-, Limitation VBT

Structural Isomerism: Conformation isomerism, Ionization isomerism, Hydrate

isomerism, Coordination isomerism, Linkage isomerism, Coordination position

isomerism, Ligand isomerism, Polymerization isomerism

Stereo isomerism: Geometrical isomerism, Geometrical isomerism in 4-

coordinated complex compounds, Geometrical isomerism in 6-coordinated

complex compounds, Distinguish between cis and trans isomers, Optical isomerism

in 4-coordinated complex compounds, Optical isomerism in 6-coordinated

complex compounds

25%

3 LANTHANIDES AND ACTINIDES LANTHANIDES: Definitions, Position of Lanthanides in periodic table, General

properties, Electronic configuration, Oxidation state and oxidation potential

Chemistry of +2, +3, and +4 state, Atomic and ionic radii: Lanthanide contraction,

Cause of Lanthanide contraction, Consequences of Lanthanide contraction, Color

and absorption spectra in Ln+3 ion, Magnetic properties Complex formation,

Extraction of Lanthanide from monazite, Separation of individual rare earth

elements by modern methods, Solvent extraction method Uses of Lanthanide

compounds

25%

ACTINIDES: Definition, Position of Actinides in periodic table, General

properties of Actinides and their comparison with Lanthanides, Electronic

configuration and nature of bonding in Actinide compounds, Oxidation state and

oxidation potential, Chemistry of +2, +3, +4, +5, +6, and +7 oxidation state,

Atomic and ionic radii: Actinide contraction, Color and absorption spectra of

Actinide ions, Magnetic properties, Complex formation, Separation of actinide

elements, Solvent extraction method, Ion exchange method.

4 CHEMISTRY OF METAL CARBONYL AND NITROSYLS METALLIC CARBONYLS: Classification of carbonyls, General methods of

preparations, General properties (physical & chemical), Structure and nature of M-

CO bonding in carbonyls, Effective atomic number (EAN) rule as applied to

metallic carbonyls, 18-electron rule as applied to metallic carbonyls, Some

carbonyls (preparation, properties and structure), Nickel tetracarbonyl, Ni(CO)4,

Iron pentacarbonyl, Fe(CO)5, Chromium hexacarbonyl, Cr(CO)6, Dimanganese

decacarbonyl, Mn2(CO)10, Dicobalt octacarbonyl, Co2(CO)8, Di-iron

enneacarbonyl, Fe2(CO)9, Tri-iron dodecacarbonyl, Fe3(CO)12,

METALLIC NITROSYLS: Some metallic nitrosyls, Sodium nitroprusside,

Na2[Fe2+(CN)5(NO+)], Nitroso ferrous sulphate, FeSO4.NO, Effective atomic

number (EAN) rule as applied to metallic nitrosyls,

25%

Reference Books:-

1. Selected Topic in Inorganic Chemistry, 8th-edition,By Wahid U. Malik, G. D. Tuli And R. D.

Madan

2 Advance Inorganic Chemistry (Volume –II) By: Satya Prakash, G. D. Tuli, . S.K. Basu, R. D. Madan



Semester: III

Syllabus with effect from: JUNE 2019



Title Of Subject : Physical Chemistry

Unit Description in etail Weighting (%)

I STATES OF MATTER

Gaseous state The Gas Laws, Kinetic Molecular Theory of Gases, Deviation of Real Gases From Ideal

Behavior, Effect of Temperature and Explanation for the deviation, Vander Waals

Equation of State, Discussion Of VanderWaal’s Equation, Critical Constants Of Gas,

Determination Of Critical Pressure, Temperature And Volume,Relation Between

VanderWaal’s Constant And Critical Constants, Numerical

Liquid state Vapour Pressure and Its Experimental Determination, Surface Tension and Its

Experimental Determination, Viscosity And Its Experimental Determination, Numerical.

25%

2 CHEMICAL THERMODYNAMICS Introduction, Terminology of Thermodynamics, state function, thermal equilibrium,

zeroth law of thermodynamics, Thermodynamic process, First law of thermodynamics,

Enthalpy, work, Thermochemistry, Molar heat at constant volume and constant pressure,

Kirchhoff’s equation, Criteria for spontaneous process, Reversible and Irreversible

process, Relation between qrev and qiir, Numerical

25%

3 COLLIGATIVE PROPERTIES OF DILUTE SOLUTIONS

Colligative Properties, Vapour Pressure Lowering, Determination of Molar Mass of

Solute, Measurement of Vapour Pressure Lowering

Osmosis and Osmotic Pressure, Derivation of Equation for calculating Osmotic Pressure,

Determination of Molar Mass, Measurement of Osmotic Pressure,

The Boiling Point Elevation, Derivation of Equation and Measurement of Boiling Point

Elevation

The Freezing Point Depression, Derivation of Equation For Molar Mass, Measurement

Of Freezing Point Depression, Numerical

25%

4 ELECTROLYTES IN SOLUTION Specific Conductance, Molar Conductance, Conductance and Electrolytic Dissociation,

Colligative Properties And Electrolytic Dissociation, Electrolysis Transference Numbers,

Ionic Mobilities, Applications, Ionic Strength, Dissociation Of Weak Electrolytes.

25%

Reference book:

1. Principles of Physical Chemistry by Puri, Sharma and Pathania. 38thed.

2. Essential of physical chemistry by Bahl, Bahl and Tuli. 25th edition.

3. Physical Chemistry by G.M.Barrow, 5thed.

4. Textbook of physical chemistry by P.L. Soni, O.P. Dharmarha, U. N. Dash

5. University chemistry by Bruce H Mahan

6. Principles of Physical chemistry, S H Marron, Karl F prutton

7. Physical Chemistry, Ira Levine


Programme: B.Sc

(Chemistry) Semester: III



Paper Code: US03CCHE23 Total Credit: 2

Title Of Paper: Inorganic Chemistry Praactical

Description in detail

1 Inorganic Mixture: Four radicals. It may include two positive Radicals and two

negative radicals.(At least Ten)

Cd+2

, Cu+2

, Bi+3

, Fe+2

, Zn+2

, Al+3

, Ni+2

, Mn+2

, Ba+2

, Sr+2

, Ca+2

, Mg+2

, NH4+, K

+, Cl

-,

Br-, I

-, NO3

-, CO3

-2 , S

-2, PO4

-3, BO3

-3, SO4

-2, CrO4

-2, Cr2O7

-2 etc.

2 Viva

Basic Text & Reference Books :-

� Vogel’s Testbook Of Qualitative Inorganic Analysis By G.Svehla

� Practical Chemistry By O.P.Pandey, D.N.Bajpai & S.Giri

� An Advanced Course In Practical Chemistry By Ghoshal, Mahapatra & Nad

age 1 of 1


Programme: B.Sc

(Chemistry) Semester: III




Title Of Paper: Analytical Practical


1 Volumetric Titration (By self preparation of solution of titrant):

Estimation of copper by iodometric method.

Determination of total hardness of water sample.

Determination of nickel by back titration.

Determination of nitrite by back titration. Estimation of Amide Estimation of Aniline Determine the Unsaturation

2 Preparation of standard solutions.

3 Paper chromatography.

4 Viva

� Vogel’s Testbook of Quanitative Chemical Analysis, 5th

Edition By G.H.Jeffery,

J.Basset, J.Mendham, R.C.Denney.



Page 1 of 1



Semester: IV

Proposed Syllabus with effect

from: JUNE 2019



Title Of Paper: Organic Chemistry


I Stereochemistry Stereochemistry and stereoisomerism, Optical activity, Plane-polarized light,

the polarimeter, Specific rotation, Production of Enantiomerism, Chirality, the

chiral centre, enantiomers, the racemic modification, Configuration,

Specification of configuration: R and S, Sequence rules, Diastereomers, Meso

structures, Specification of configuration : More than one chiral center,

Generation of a chiral center, Synthesis and optical activity, Reaction of chiral

molecules: Bond-breaking, Reaction of chiral molecules: Generation of

second chiral center, Reaction of chiral molecules with optically active

reagent. Resolution, Reaction of chiral molecules: Mechanism of free radical

chlorination.

Free rotation about C-C single bond. Conformation. Torsional strain

Conformation of n-butane Vander Waals repulsion, Factors affecting stability

of conformation, Conformation of cycloalkanes, Equatorial and axial bond in

cyclohexane.

25 %

II (A)Alcohols & Phenols

Alcohols

Structure of alcohols, Classification of alcohols, Addition of Grignard reagent,

Product of the Grignard synthesis, planning a Grignard synthesis, Synthesis using

alcohol, Limitation of Grignard synthesis, Reaction of alcohols, Alcohols as acids

and bases, Oxidation of alcohols.

Phenols

Rearrangement of hydroperoxides, Acidity of phenols, Kolbe

reaction. Synthesis of phenolic acids, Reimer-Tiemann reaction,

(B) Aldehydes And Ketones

Reaction. Nucleophilic addition, Addition of cyanide,, Addition of alcohols.

Acetal formation,, Acidity of α–hydrogens,, Base-promoted halogenation of

ketones, Acid-catalized halogenation of ketones: Enolization, Aldol

condensation, Dehydration of aldol products, Use of aldol condensation in

synthesis, Crossed aldol condensation.

© Amines:

Diazotization,Sandmayyer Reaction,Gattermann Reaction.

25 %

III Carbohydrates

Introduction, classification of carbohydrates, osazone formation, epimerization,

step up(Killani Fisher Synthesis) and step down(Ruff Degradation ) reactions of

monosaccharides, simple structures of glucose and fructose, Fischer’s proof of

configuration of D-glucose,Cyclic structure of D(+) dlucose.

Disaccharides, structure of (+) maltose, (+) cellobiose, (+) lactose

25 %

IV Chemical Reactivity and Molecular Structure: (Acid- Base Properties)

Acid-Bases, scale of acidity-basicity, Resonance effect, drawing of structures and

the condition for resonance, Effect of change of hybridization on acidity and

basicity, Inductive and electronic effects, steric effect and hydrogen bonding,

Lewis acid and bases, Keto – enol tautomerism . Difference between resonance

and tautomerism.

25 %

Basic Text & Reference Books :-

• A text book of organic chemistry by Arun Bahl and B. S. Bahl, 16th ed.

• Organic chemistry by Morrison and Boyd, 6th ed.

• Organic reaction mechanism by R.K.Bansal, 3rd ed.

• Organic chemistry by S.M.Mukherji, S.P.Singh and R.P.Kapoor. Vol. II.


B.Sc. (Chemistry) Semester: IV

Syllabus with effect from: 2019



Title Of Paper: Analytical Chemistry


I Titrimetric Methods In Analysis

Introduction, Definitions: Standard solutions, Equivalence Point, Indicators,

End point, Titration General Aspects of: Primary standards, Desirable

properties of standard solution. Volumetric calculations: Molarity, Normality,

percentage concentration, parts per million.

Neutralization Titration

Standard solution and acid‐base indicators. Titration curve for strong

acid‐strong baseSystematic equilibrium concentrations for SA‐SB titration.

Acid‐Base indicators, colour change range of an indicator, Indicator error.

Determination of Acetic acid in vinegar. Determination of Alkalinity of soda

ash.

25%

II Complexometric Titration

Introduction, terms involved in titration: complex, ligand, buffer solution,

chelating agents, chelates, Some Chelating agents, Stability of complexes:

stepwise formation constants. Complexometric titration curve. Equilibria

involved in EDTA titration, Indicators for EDTA titrations. Hardness of water.

Ca in Calcium Gluconate Sample. Numericals based on this titration.

25%

III Redox Titration

Introduction, Terms involved: oxidation, reduction. Single electrode potential,

formal potential, Nernst Equation, Titration curve for Iron(II) and cerium (IV).

Types of redox indicators and their selection. Structural chemistry of redox

indicators. Numericals: Calculation based on emf of electrode/cell, end point

calculations, equation constants.

25%

IV Water Pollutants Analysis Water pollution: Introduction. Classification of water pollutants, Sources of

water pollution. Origin of waste water, Effect of water pollutants, Water

analysis: colour, turbidity, total dissolved solids, conductivity, acidity,

alkalinity, hardness, chlorides, sulphates, fluorides. Drinking water standards.

25%

Basic Text & Reference Books:-

� Fundamentals of Analytical Chemistry, 7th

Edition by skoog, west, Holler.

� Quantitative Analysis 6th

Edition ‐ R.A. Day, Jr., A.L. Underwood.

� Analytical Chemistry –Dr. Alka Gupta, Pragati Prakashan.


Programme: B.Sc

(Chemistry) Semester: IV




Title Of Subject : Organic Chemistry Practical


1 Binary Organic Mixture: [Solid + Solid] Only water insoluble (At least Ten) Separation and identification of binary organic mixture : Solid + Solid [A/B/P/N] Solid Acid :Benzoic Acid,Salicylic Acid,And Cinnamic Acid

Solid Phenol:(α-napthol, β-napthol Solid Base :(O-m-& p-nitroaniline, Solid Neutral: p-dichlorbenzene,naphthalene,anthracene,benzamide,acetanilide,m-dinitrobenzene.

2 VIVA


� Vogel’s Testbook Of Qualitative Organic Analysis


Page 1 of 1


Programme: B.Sc

(Chemistry) Semester: IV




Title Of Subject : Applied Chemistry Practical


1 Gravimetric Analysis (single) 1.Ba as BaSO4

2.Fe as Fe2O3

3.Al as Al2O3

4.Ni as Ni(DMG)2

5.ZnCO3 as ZnO

6.BaCl2 ּ◌2H2O as BaCl2

2 VIVA


� Vogel’s Testbook of Quanitative Chemical Analysis, 5

th Edition By G.H.Jeffery,



Page 1 of 1


B.Sc (Chemistry) Semester: V

Syllabus with effect from:June-2020



Title of Subject: Organic Chemistry


I Heterocyclic Compounds

Heterocyclic systems, Structure of Pyrole, furan and thiophene, Source of Pyrole,

furan and thiophene, Electriphilic substitution in Pyrrole, furan and thiophene

Reactivity and orientation, Saturated five – membered heterocycle, Structure of

pyridine, Sources of pyridine compounds, Reactions of pyridine, Electrophilic

substitution in pyridine, Nucleophilic substitution in pyridine, Basicity of pyridine,

Reduction of pyridine, Quinoline. The skraup synthesis, Isoquinoline. The Bischler–

Napieralski synthesis. Knorr pyrrole synthesis, Vilsmeier-Haack reaction,

25%

II Reaction Mechanism Baeyer Villiger oxidation, Hofmann rearrangement, Mannich reaction, Curtius–

Schmidt rearrangement, Benzilic acid rearrangement, Sommlet rearrangement, Birch

reduction, Favorskii rearrangement, Benzoin condensation, Beckmann

rearrangement, Wittig reaction, Perkin reaction.

25%

III Dienes And Macromolecules

Dienes: Structure and properties, Stability of conjugated dienes, Resonance in

conjugated dienes, Hyperconjugation, Ease of formation of conjugated dienes,

Electrophilic addition to conjugated diene : 1,4- addition,1,2 Vs 1,4-addition, Rate

Vs equilibrium, Free-radical polymerization of diene, Polymer and polymerization,

Free radical vinyl polymerization, Co-polymerization, Ionic polymerization,

Coordination, polymerization, Step reaction, polymerization, Structure and

properties of macromolecules. Distinguishing features of addition and

condensation polymerization Copolymer, classification of

polymers, plastics and resins, Phase system for polymerization (like bulk, solution, emulsion and suspension polymerization).

25%

IV Terpenoids General introduction including nomenclature, General properties of terpenoids,

Isolation, Isoprene rule, Classification of terpenoids, General methods for the

determination of structure of terpenoids. Introduction, isolation and constitution of

Citral, α- terpineol, Camphor,B-carotene.

25%

Reference Books :-

1. Organic chemistry of natural products by Gurdeep Chatwal, Vol. II.

2. Organic Chemistry by Morrison and Boyd, 6th ed.

3. Synthetic organic chemistry by Gurdeep R. Chatwal

4. Reaction mechanism in Organic Chemistry by S. M. Mukherji.

5. Organic reaction mechanism by R.K. Bansal, 3rd

ed.

6. Org. Chem., Vol II, by I.L. Finar.

7. Principles of Org. synthesis, by ROC Norman.

8. Reaction mechanism in Organic Chemistry S. M. Mukherji and S. P. Singh.

9. Heterocyclic chemistry vol. II by R. R. Gupta, M. Kumar and V. Gupta


B.Sc (Chemistry) Semester-V

Syllabus with effect from:2020





I Symmetry

Introduction,Various types of symmetry elements, Point groups, Properties of point

groups, To determine the point group of a molecule, Representations of groups,The

character, Some important theorems concerning the irreducible representations and their

characters, Character table for point groups C2V and C3V.

25%

II Cristal Field Theory

Importance of CFT, Grouping of 5d orbitals, CFT applied for octahedral complexes,

Distribution of dn electrons (strong field and weak field), Factor influencing magnitude

of ∆0, Spectro chemical series, Mean paring energy and calculations, Calculation based

on CFSE, CFT for tetrahedral complexes, Distribution of dn electrons, Limitation of

CFT, Energy Level Diagram for [ CoF6]3-

and [Co(NH3)6]3+

25%

III (A) Thermodynamic and kinetic aspects of metal complexes stability of

complexes in aqueous solution

Definition of stability, Stability of complex ions in solution, Stepwise formation constants

and overall formation constants, Labile and inert octahedral complexes according to CFT,

Factors affecting the stability of complexes, Experimental determination of stability

constant and composition of a complex, Spectrophotometric method, Job’s method of

continuous variation, Potentiometric Bjerrum method.

(B) Ligand substitution reactions in octahedral complexes

Transition state or activated complex, Types of substitution reactions, Labile and inert

complexes, Acid hydrolysis reactions of six-coordinated, Acid hydrolysis reactions of six-

coordinated Co (III) ammine complexes, Base hydrolysis reactions of six-coordinated Co

(III) ammine complexes.

(C) Ligand substitution reaction in square-planar complexes

Trans effect, Application of trans effect, Theories of trans effect, Electrostatic polarized

theory bonding.

25%

IV Inorganic Polymers

Introduction, Classification of inorganic polymers, General properties of inorganic

polymers, Polymers containing boron: Preparation properties and structure of borazine

and substituted borazines, boron nitrites

Polymers containing silicon: Preparation properties and structure of silicones,

silicone resins, silicon fluids or oils, silicon rubbers, silicon greases Polymers

containing phosphorous: Preparation properties and structure of polyphosphonitrilic

chlorides, Vitreous polyphosphates

Polymers containing sulfur: Preparation properties and structure of nitrides of

sulfur, thiazyl halides, imides of sulphur.

25%

Basic Text & Reference Books :- 1.Advanced Inorganic Chemistry Volume I- 18th By Satya Prakash,G.D.Tuli, S.K.Basu, R.D.Madan

2. Basic Inorganic Chemistry ‐3rd

Edition By F. Albert Cotton, Geoffrey, Wilkinson & Paul L. Gaus

3. Advanced Inorganic Chemistry Volume: II (2007 Edition) By: Satyaprakash, Tuli, Basu and Madan

4. Selected Topic in Inorganic Chemistry, 8th

‐edition,By Wahid U. Malik, G. D. Tuli And R. D. Madan

5. Introductory Quantum Chemistry‐ 4th

Edition By A K Chandra


B.Sc (Chemistry) Semester: V

Syllabus with effect from: June-2020



Title Of Subject: Physical Chemistry


I ENTROPY AND SECOND LAW OF THERMODYNAMICS

Limitation of first law, spontaneous or irreversible process, cyclic process, Carnot

cycle, Carnot theorem, entropy the new state function, the concept of entropy, entropy

change in isothermal expansion of an ideal gas, entropy change in reversible and

irreversible change, the entropy change accompanying phase change, calculation of

entropy of an ideal gas with change in P, V and T, entropy of mixing of an ideal gas,

physical significance of entropy, work and free energy function, variation of free

energy change with T and P., Numerical.

25%

II CHEMICAL KINETICS

Third order reaction (a= b=c), Mechanism of Complex reaction, The equilibrium

approximation, Steady state approximation, Collision and Encounters, Effect of

temperature on reaction rate, Effect of Catalyst, The Arrhenius Equation, The theories

of reaction rate, The Lindemann theory of unimolecular reaction, Kinetics of Complex

reaction, Opposing or reversible reaction, Consecutive reactions, Chain reaction,

Activated Complex Theory (ACT) of Bimolecular reaction, Numerical

25%

III PHOTOCHEMISTRY

Introduction, Types of chemical reactions, Difference between Dark and

Photochemical reaction, Absorption of light, Laws of photochemistry, Quantum yield

( or ) Quantum efficiency, Deviation in the law of photochemical, Equivalence,

Reasons of high and low quantum yield, Factors affecting quantum yield,

Luminescence, Fluroescence and Phosphorescence, Numerical.

25%

IV SURFACE CHEMISTRY

Sorption, Adsorption Of Gases, Influence Of Temperature And Pressure, Nature Of

Adsorbent And Adsorbed Gas, Unimolecular Layers, Langmuir Adsorption Isotherm,

Types Of Adsorption, Vander Waals Adsorption, Chemisorption, Persorption,

Adsorption at Surfaces Of Solutions, Formation of Unimolecular Surface Film Of

Spreading Oils(Unimolecular Insoluble films), Adsorption By Solids From Solutions.

25 %

Reference Book:

1. Advanced Physical Chemistry by Gurdeep Raj.

2. Text book of physical chemistry by Samuel Glasstone.

3. Principles of Physical Chemistry by Puri, Sharma and Pathania. 38th ed.


5. Physical Chemistry by G.M.Barrow, 5th ed.




9. Physical Chemistry, Ira Levine/ 10. Physical Chemistry, Atkins


Programme: B.Sc (Chemistry) Semester: V

Syllabus with effect from:June-2020



Title Of Subject: Analytical Chemistry


I pHmetry- Introduction, types of indicator electrodes and reference electrodes,

types of titrations.

potentiometry- Introduction, types of titrations, graphical method for end point

determination.

Conductimetry- Introduction, types of conductance, effect of dilution,

conductivity cells, types of titration.

25%

II Chromatography-I

Introduction, classification, paper chromatography, thin layer chromatography,

column chromatography, ion exchange chromatography- experimental details for

all the techniques.

25%

III Chromatography-II

Gas Chromatography Introduction, Technique of Gas Liquid Chromatography, Apparatus of Gas

Liquid Chromatography ( Carrier Gas, Injection Port, Columns, The solid inert

support, The stationary liquid phase), Detectors, Thermal Conductivity

Detectors, Flame Ionization Detectors, Electron Capture Detectors.

High Performance Chromatography (Hplc) Introduction, Principle and Apparatus of HPLC( Solvent delivery system ,

Pumps , Sample Injection System, Columns, Column Packing materials,

Column packing ), Choice of supporting materials for separation, Detectors.

25%

IV Solvent Extration Methods

The Distribution Law, Extraction process, Liquid liquid extraction, Factor

affecting Extraction, Technique for Solvent Extraction, Quantitative treatment

of solvent Extraction eqillibria, Classification of Solvent Extraction system,

Types of extraction system, Advantage of Solvent Extraction system,

Application of Liquid extraction, Solvent extraction methods in Metallurgy,

Solid-Liquid Extraction.

25%

Reference Books :-

1. Instrumental methods of Chemical Analysis by B.K.Sharma

2. Instrumental methods of Chemical Analysis by Gurdeep R Chatwal

3. Quantitative Analysis by Skoog & West


Programme: B.Sc

(Chemistry) Semester: V




Title Of Subject : Organic Chemistry Practical


1 Organic Preparation

(a) Preparation of P‐Bromo Acetanilide from Acetanilide(Bromination)

(b) Preparation of P‐Nitro Acetanilide from Acetanilide (Nitration)

(c) Preparation of m‐nitroaniline from m‐dinitrobenzene (Reduction)

(d) Preparation of Benzoic acid from Benzaldehyde (Oxidation)

(e) Preparation of Iodoform

(f) Preparation of Di‐benzyl acetone from Benzaldehyde

(g) Preparation of Dyes‐ Modernt Yellow

2 VIVA


� Comprehensive practical organic chemistry Preparation and qualitative analysis by

V.K.Ahuwalia and Renu Aggarwal.

� Organic Preparation by Vogel

Page 1 of 1


Programme: B.Sc





Title Of Subject : Inorganic Chemistry Practical


1 Inorganic Mixtures (Min 10 Mix.)

Semi-micro Inorganic Qualitative Analysis Of Mixture Containing Three

Positive & Three Negative Radicals.

Cd+2, Cu+2, Bi+3, Sb+3, Pb+2, Fe+2, Fe+3, Zn+2, Al+3, Co+2, Ni+2, Mn+2, Ba+2,

Sr+2

, Ca+2

, Mg+2

, NH +, K

+, Cl

-, Br

-, I

-, NO

-, CO

-2 , S

-2, PO

-3, BO

-3, SO

-2, 4 3 3 4 3 4

CrO4‐2

, Cr2O7‐2

etc.

2 VIVA


� Vogel’s Testbook of Quantitative Chemical Analysis, 5th Edition By G.H.Jeffery,





Page 1 of 1


Programme: B.Sc





Title Of Subject : Physical Chemistry Practical


1 1. Chemical kinetics of a reaction between K2S2O8 and KI in an aqueous system. (a=b)

2. Chemical kinetics of a reaction between K2S2O8 and KI in

an aqueous system. (a ≠ b) 3. The study of Decomposition Rate of hydrogen peroxide

in presence of catalyst and catalyst with promoter. (a=b) 4. The study of Decomposition Rate of hydrogen peroxide

in presence of catalyst and catalyst with promoter. (a ≠ b) 5. The study of Rate of Reaction between hydrogen

peroxide and KI in an aqueous media. (a=b)

6. The study of Rate of Reaction between hydrogen

peroxide and KI in an aqueous media. (a ≠ b)

7. To determine the Rate Constant for the reaction between KBrO3 and KI in an aqeous media. (a=b)

8. To determine the Rate Constant for the reaction

between KBrO3 and KI in an aqeous media. (a ≠ b) 9. The Distribution coefficient of Benzoic acid distributed

between water and kerosene. 10.To study the Adsorption of acid on Activated charcoal. 11.To determine the Composition of a Binary liquid

mixture by Refractrometry.

2 VIVA


1. Experimental Physical Chemistry by R.C.Das & B.Behera

2. Advanced Physical Chemistry by J.B.Yadav

Page 1 of 1


Programme: B.Sc





Title Of Subject : Analytical Chemistry Practical


1 Estimation of Funcation Group

(1) Estimation of Carboxylic Acid

(2) Estimation of Ketone

(3) Estimation of Ester

(4) Estimation of Sap. Of Oil

(5) Estimation of Water

(6) Estimation of Milk etc

2 VIVA





Page 1 of 1


Programme: B.Sc (Chemistry) Semester: VI




Title Of Subject: Organic Chemistry


I Amino Acids And Proteins Proteins, Structure of amino acids, Amino acids as dipolar ions, Isoelectric

point of amino acids, Preparation of amino acids, Peptides. Geometry of the

peptide linkage, Determination of structure of peptide. Terminal residue

analysis. Synthesis of peptides, Structure of proteins, Peptide chain, Side chain.

Isoelectric point. Electrophoresis, Secondary structure of protein.

(B)Purine and Pyrimidines

Purines – Synthesis of Purines, Adenine and Guanine.

Pyrimidines – Synthesis of Pyrimidine, Uracil, Thymine and Cytosine.

25%

II Alkaloids

Introduction, function, classification, isolation and properties of alkaloids.

General methods employed for determining the structure of alkaloids.

Introduction, isolation, physiological action, properties, extraction,

constitution and synthesis of Nicotine, Papaverine.Conine,Atropine

25%

III 1. Synthetic Dyes:-Classification of Dyes‐ Anionic and Cationic

dyes, Mordant and Vat dyes, Reactive and Dispersed dyes, Synthesis of

Alizarin, Malachite green, Indigo, Congo red, Eosin.

2. Explosives:‐Preparation of RDX, PETN, Nitroglycerine, Tetryl.

3. Pesticides:‐Preparation of Aldrine, Malathion, Parathion,

Methoxychlor.

25%

IV Organic Photochemistry Principles of photochemistry. Photochemical energy. Electronic excitation,

excited states, modes of dissipation of energy (Jablonski diagram). Energy

transfer and photosensitization. Photochemistry of carbonyl compounds.

Photoreduction. Norrish type -I and -II reactions. Photochemical reactions of

cyclic ketones. Paterno-Buchi reaction. Photochemistry of α, β-unsaturated

ketones. Photochemistry of olefins. Cis-trans isomerification. Dimerization

reactions. Photo-Fries rearrangement. Barton reaction.

25%

Reference Books :-

• Org. Chem., Vol II, by I.L. Finar.

• Organic chemistry by A. Bahal & B. S. Bahal, 16th Ed..

• Organic Reaction Mechanism by S.M. Mukerji.

• Organic Reaction Mechanism by R.K. Bansal.

• Organic Chemistry by R.O.C. Norman.

• Organic chemistry of natural products by Gurdeep R. Chatwal, Vol. I.



Semester: VI

Proposed Syllabus with effect

from:2020

(30 +70 Marks, 4 hrs per

week)




I Wave Mechanics Wave equation, Interpretation of ᴪ and Heisenberg’s uncertainty principle, Properties of

ᴪ, Operators, Second postulate of quantum mechanics, Setting up operators for different

observable, Third postulate of quantum mechanics, Fourth postulate of quantum

mechanics, One dimensional box, Normalization and orthogonality, Characteristics of

the wave functions

25%

II ORGANO METALLIC CHEMISTRY Introduction, General methods of preparations, General properties, Organo metallic

compounds of alkali metals, Organo metallic compounds of beryllium, Organo metallic

compounds of magnesium, Organo metallic compounds of aluminum, Metal olefin

(alkene) complexes

Cyclopentadienyl complexes: Preparation of metallocenes and their derivatives, Some properties of ferrocene

molecule, Strcture and bonding in ferrocene molecule, Ionic cyclopentadienyl

compounds.

25%

III Term symbol Russel Saunders coupling and determination of Term symbols of the ground state.

Calculation of number of microstates. Pigeon hole diagram of p2 and d2

configurations. Hund’s rule. Hole formulation.

Electronic spectra of metal complexes

Electronic spectra of transition metal complexes, Laporte orbital and spin selection

rules. Orgel energy level diagram of d5 and combined diagrams of d1- d

9, d

2 – d

8,

d3 – d

7, d

4 – d

6 and their spectra. Jahn Teller distortion. Spectrochemical series.

25%

IV PRINCIPLES OF METALLURGY AND CHEMISTRY OF Pb,Fe,Ni,Cu &

Ag: Metals, Occurrence of metals, Mineral wealth of india, Metallurgy, Concentration and

ore, Calcinations and roasting, Standard electrode potentials and metallurgy,

Thermodynamics of metallurgy, Reducing behavior of carbon, Reduction of mineral to

metal, Refining of metals, Physical methods of refining, Chemical methods of refining,

Types of furnaces used,

25%

Pb: occurrence & extraction, properties & uses of lead, white lead,

Fe: occurrence and commercial forms of ion, manufacture of cast iron & steel,

Ni: occurrence & extraction, properties and uses of nickel,

Cu: occurrence & extraction electrolytic refining of copper, properties and uses of

copper,

Ag: occurrence & extraction, properties and uses of silver, preparation, properties and

uses of silver, nitrate, silvering of mirrors.

Reference Book:

1.Introductory Quantum Chemistry- 3rd

Edition,By A. K. Chandra

2. Textbook of Inorganic Chemistry -20thedition, Chapter-13 By P. L. Soni & Mohan Katyal

3. Advanced Inorganic Chemistry Volume II By Satya Prakash, G. D. Tuli, S. K. Basu, R. D. Madan

4. CONCISE INORGANICCHEMISTRY : 5TH EDITION BY: J.D.LEE

5 Basic Inorganic Chemistry- 3rd

Edition By F.Albert Cotton, Geoffery

Wilkinson & Paul L. Gaus


Programme: B.Sc (Chemistry) Semester: VI




Title Of Subject: Physical Chemistry


I ENTROPY AND THIRD LAW OF THERMODYNAMICS

Third law of thermodynamics, Molecular basis of Entropy, Translational Entropy,

Rotational Entropy, Vibrational Entropy, Molecular basis of the third law, Trouton’s

Rule, Free-Energy, Standard free energy of formation, Free energy and Pressure, Free

energy and the equilibrium constant, Free energy and Temperature, Free energy

function, Equilibria and Distributions,

Fugacity, Numerical.

25%

II ELECTROMOTIVE FORCE OF ELECTROCHEMICAL CELLS

Electrodes, cell emf, emf and free energy, Standard electrode potentials, emf and

activities, activity coefficients from emf’s, equilibrium constant from emf’s, electrode

concentration cells, electrolyte concentration cells, thermodynamic properties from cell

emf’s.

25%

III PHASE EQUILLIBRIA Introduction to Phase rule, Phase component and degree of freedom, Phase reactions,

condition for equilibrium between phase, derivation of phase rule, advantage and

limitations of phase rule, one component system, water system, the sulfur system,

experimental determination of transition point, two component system, types of two

component system, simple eutectic system, lead silver system, KI-Water system,

simple eutectic system having congruent melting point, zinc magnesium system,

eutectic system with incongruent melting point ,Numericals.

25%

IV COLLOIDAL STATE

Types of Colloidal system, Classifications of Colloids, Lyophobic and Lyophilic Sols,

Size range, Preparation and Properties of colloids solution, Dialysis, Electrodialysis,

Ultrafiltration, Electrical Double Layer, Electrophoresis, Electrosmosis, Importance and

Applications of Colloids, Numerical.

25%

Reference Book:

1. Advanced Physical Chemistry by Gurdeep Raj.

2. Text book of physical chemistry by Samuel Glasstone.

3. Principles of Physical Chemistry by Puri, Sharma and Pathania. 38thed.


5. Physical Chemistry by G.M.Barrow, 5th ed.




9. Physical Chemistry, Ira Levine

10. Physical Chemistry, Atkins



Semester: VI




Title Of Subject : Applied Chemistry


I Spectroscopy The nuclear magnetic resonance (NMR) spectrum. Number of signals, NMR

positions of signals. Chemical shift, NMR peak area and proton counting, NMR

Splitting of signals. Spin-spin coupling, NMR coupling constant,

Carbon – 13 NMR (CMR) spectroscopy CMR Splitting, CMR Chemical shift, NMR and CMR spectra of hydrocarbons,

NMR and CMR spectra of alkyl halides, NMR and CMR spectra of alcohols

and ethers, Spectroscopic analysis of aldehydes and ketones, Spectroscopic

analysis of Carboxylic acids, Spectroscopic analysis of amines and substituted

amides, Spectroscopic analysis of Carboxylic acid derivatives.

Problems based on above spectroscopic technique.

25%

II Drug

Introduction, Classification of drugs. Introduction and classification of following

selected class of drugs. Hypnotics, sedative and anticonvulsants, Histamine and

antihistaminic agents, Hematological agents, Antipyretic and analgesics, Mode of

action of antipyretic drug. Anthelmintics Antimalerial, Antiseptic,

Sulphanilamides, Mechanism of action of sulpha drug. Antitubercular and

antileprosy drugs. Synthesis and uses of following drugs (i) Nirvanol (ii) Phenobarbitone (iii)

Dimenhydrinate (iv) Novalgin (v) Phenylbutazone (vi) Hetrazan (vii)

Atenelol(viii) Chloroquine (ix) Lidocaine, (x) Sulphamethazine, (xi)

Sulphafurazole (xii) PAS (xiii) Acedapsone (xiv) Tolbutamide .

25%

III UNIT: II BIOINORGANIC CHEMISTRY

Introduction, The role of model systems, The alkali and alkaline earth metals, Metalloporphyrins, Iron-sulfur proteins, Hemerythrin, Oxygen supply and transport, The bioinorganic chemistry of cobalt: Vitamin B12,, Metalloenzymes, Nitrogen fixation.

25%

Reference Books :- � Organic Chemistry by Morrison and Boyd, 6

th ed.

� Organic Spectroscopy by P.S.Kalsi � Organic Spectroscopy by J R Dyer.

� Elementary Spectroscopy by Y R Sharma

� Synthetic Drugs 6th ed. by Gurdeep R. Chatwal.

� Medicinal chemistry 3rd

ed. by Ashutosh Kar.

� Basic Inorganic Chemistry‐ 3rd

Edition By F.Albert Cotton, Geoffery Wilkinson & Paul L. Gaus

� Textbook of Inorganic Chemistry‐ 20th

by P. L. Soni & Mohan Katyal

IV UNIT: IV HEAVY CHEMICALS

Sodium hydroxide Manufacture: Causticising process, electrolytic process (Nelson cell, Castner-

Kellner cell, Kellner-Solvay cell), Properties and uses NaOH.

Nitric acid Preparation of nitric acid in laboratory, Manufacture of nitric acid from nitre, from

air (Birkland and Eyde process), from ammonia (Ostwald’s process), Concentration

of nitric acid, Properties and uses of nitric acid.

Sulphuric acid

Manufacture: Lead chamber process, principal impurities present in the chamber

acid and their removal, Concentration of chamber acid, Cascade process, Gaillard

tower, Contact process, Properties and uses of sulphuric acid.

25%


Programme: B.Sc

(Chemistry) Semester: VI




Title Of Subject : Organic Chemistry Pratical


1 SEPARATION AND IDENTIFICATION OF TWO.COMPONENT ORGANIC MIXTURE

USING CHEMICAL AND PHYSICAL METHODS (WATER SOLUBLE, INSOLUBLE &

LIQUID + LIQUID)

Solid Acid: Benzoic acid, salicylic acid, cinnamic acid, phthalic acid ,o‐,m‐ chloro

benzoic acid,o‐,m—nitro benzoic acid, succinic acid oxalic acid,

Solid phenol:‐α naphthol,β‐naphthol,resorcinol,

Solid neutrals:‐ p‐dichlorobenzene, naphthalene, anthracene, benzamide,

acetanilide,m‐dinitrobenzene.

Solid Base:‐ o‐,m‐& p‐nitroaniline,p‐toluidene,

Liquid base:‐ aniline,

Neutral liquid:‐ ethyl acetate, methyl acetate, acetone, methyl alcohol

ethylalcohol,benzaldehyde,chlorbenzene,nitrobenzene,CHCl3, ,nitrobenzene,

acetohpenone

(Derivative of any one out of two compounds)

2 VIVA


� Comprehensive practical organic chemistry Preparation and qualitative analysis by

V.K.Ahuwalia and Renu Aggarwal.

� Organic Preparation by Vogel

Page 1 of 1


Programme: B.Sc





Title Of Subject : Inorganic Chemistry Practical


1 (a) Volumetric

• Estimation of Bi3+

by EDTA

• Estimation of Ca2+

and Mg2+

in mixture by EDTA Hardness

• Estimation of Chloride by silver nitrate (Mohr's Method)

• Estimation of Fe3+

by EDTA(Back Titration)

• Estimation of Cd2+

and Zn2+

in mixture by EDTA

(b) Inorganic Preparation

• sodium thio sulphate

• sodium cobalty nitrate

• hexa thio plumbs nitrate

2 VIVA


� Vogel’s Testbook of Quantitative Chemical Analysis, 5th Edition By G.H.Jeffery,





Page 1 of 1


Programme: B.Sc





Title Of Subject : Physical Chemistry Practical


1 Applications of pH metry

1. To determine Molarity of strong acid by titrating against

0.1 M NaOH solution.

2. To determine molarity and dissociation Constant of weak

monobasic acids like HAC by titrating against 0.1 M NaOH

solution.

3. To determine Molarity of each acid present in a Mixture

of strong acid and weak acid.

Applications of Potentiometry



5. To determine molarity and dissociation Constant of weak

monobasic acids like HAC titrating against 0.1 M NaOH

solution.

6. To determine Solubility and Solubility product of

sparingly soluble salt AgCl.

Applications of Conductometry



8. To determine Molarity of weak acid by titrating against


9. To determine Molarity of each acid present in a Mixture

of strong acid and weak acid.

10.To determine Cell Constant of a given conductivity cell

and solubility and solubility product of sparingly soluble

salt ( CaSO4 , PbSO4 )

11. To determine the Concentration of KMnO4 / K2Cr2O7 by

Colourimetry.

2 VIVA


3. Experimental Physical Chemistry by R.C.Das & B.Behera

4. Advanced Physical Chemistry by J.B.Yadav

Page 1 of 1


Programme: B.Sc





Title Of Subject : Analytical Chemistry Practical


1 Gravimetric Analysis (Mixture) eg. Remove of Cu

1.Ba as BaSO4 2.Fe as Fe2O3

3.Al as Al2O3

4.Ni as Ni(DMG)2

5.Mn as Mn2P2O7

Alloy Analysis

6.Brass Alloy 7.German Sliver Alloy

2 VIVA





Page 1 of 1

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