QUANTITATIVE ANALYSIS OF THE DEFORMATIONAL HISTORY AND TIMING OF

THE SIERRA MADERA IMPACT STRUCTURE, WEST TEXAS

By

SARAH ANN HUSON

A dissertation submitted in partial fulfillment of the requirements for the degree of

DOCTOR OF PHILOSOPHY

WASHINGTON STATE UNIVERSITY School of Earth and Environmental Science

MAY 2009

© Copyright by SARAH HUSON, 2009

All Rights Reserved

© Copyright by SARAH HUSON, 2009

All Rights Reserved

To the Faculty of Washington State University:

The members of the Committee appointed to examine the dissertation of SARAH

ANN HUSON find it satisfactory and recommend that it be accepted.

___________________________________

Michael C. Pope, Ph.D., Chair

__________________________________ F. F. Foit, Ph.D.

_________________________________ D. R. Gaylord, Ph.D.

_________________________________ A. J. Watkinson, Ph.D.

ii

ACKNOWLEDGMENTS

I would like to thank my advisor, Mike Pope, for giving me the chance to work on

this exciting project. Mike is a great advisor and I appreciate the opportunity I had to

work with him. I also want to thank the members of my committee, John Watkinson,

Nick Foit, and David Gaylord. They did their fair share of carrying rocks while in Texas

as well as offering advice especially on how to cover up dents in field vehicles.

I also owe thanks to Scotty Cornelius for helping me with microprobe work and

Charles Knaack for hiring me on as a tech assistant when my funding from NASA was

delayed. Also, I would also like to thank Ray Donelick for the apatite fission track

dating, James Donnelly from the core facility at UT Austin for help with collecting

unshocked core samples for XRD analysis, Dave Katz for sending carbonate samples

from the Mission Canyon Formation for XRD analysis, and Bruce Arey from the Pacific

Northwest National Lab for his assistance with SEM analyses. Paul Olin and Zsuzsanna

Balogh-Brunstad were extremely helpful office-mates and provided needed distractions

from time to time and for that, I am extremely appreciative.

I would like to thank the members of the Lyda family who live on the property

where I conducted my field work. Also, I am extremely grateful to Glenn Lang who was

very instrumental in getting me access to the property and without whose efforts this

research could not have taken place.

Finally, and most importantly, I would like to thank my mother, Donna, and

sister, Rachael, who have been unwavering in their support all these years. Rick

Laughlin, your support and advice are unmatched and I thoroughly thank you.

iii

QUANTITATIVE ANALYSIS OF THE DEFORMATIONAL HISTORY AND

TIMING OF THE SIERRA MADERA IMPACT STRUCTURE, WEST TEXAS

Abstract

by Sarah Ann Huson, Ph.D. Washington State University

May 2009 Chair: Michael C. Pope

The Sierra Madera impact structure is a 12.9 km diameter, well-eroded remnant of

a complex impact crater located in West Texas. The crater was last studied in the early

1970’s and is an excellent site for deformation and timing studies using modern research

techniques.

In this dissertation, Chapter 1 provides an introduction to the Sierra Madera

structure including previous geologic research regarding the crater, stratigraphy and

structure/crater formation. Chapter 2 lists deformational features documented within the

central uplift of the crater and assigns temperature and shock pressure values to the

conditions of crater formation. Chapter 3 details the use of X-ray diffraction as a possible

method to determine shocked rocks from terrestrially deformed rocks. Chapter 4

documents the use of the fission-track method to assign a radiometric age to the impact

event. Chapter 5 is a field guide for the impact crater.

iv

TABLE OF CONTENTS

Page

ACKNOWLEDGMENTS……………………………………………………..…………iii

ABSTRACT…………………………………………………………..………………….iv

LIST OF FIGURES………………………………………………..………...………….viii

LIST OF TABLES……………………………………………………………...…...……xi

CHAPTER 1: Introduction …………………..…………………………………………1

Introduction………………………………………………………………..2

Previous research at Sierra Madera………………………………………..2

Geologic history of area…………….……………………………………..6

Stratigraphy…...…………………………………………………………...8

Structure………….………………………………………………………12

Chapter summaries……………………………………………………….16

References..................................................................................................19

CHAPTER 2: Deformational feature and impact generated breccia from the Sierra

Madera impact structure, West Texas……………………….......……23

Introduction................................................................................................24

Geologic setting.........................................................................................26

Methods……………………...……………………………………...……29

Deformational features…..………………………………………...……..30

Target rocks……………………………………………………...30

Impact generated breccia………………………..……………….38

Discussion.………………………………………………...……….…….45

v

Conclusions………………………………………………………...…….50

Acknowledgements………………………………………………...…….50

References……………………………………………………...………...51

CHAPTER 3: Rietveld analysis of X-ray powder diffraction patterns as a potential

tool for the identification of impact deformed carbonate rocks..........58

Introduction………………………………………………………...….…59

Geologic setting…..………………………………………………...……61

Experimental…………………………….………………………….....…63

Results……………...……………………………………………….....…70

Discussion……………………………………………………………..…75

Conclusions……………………………………………………..……......79

Acknowledgements………………………………………………..…......80

References………………………………………………………..………81

CHAPTER 4: Fission track age for the Sierra Madera impact structure……..……88

Introduction………………………………………………………..……..89

Geologic setting….………………………………………………..……..90

Methods….………………………………………………………..….…..92

Sample description………………………………………………..….…..92

Results…………………..…………………………………………...…...94

Discussion………………………………………………………….….…94

Conclusions……………………………………………………….…….100

Acknowledgements……………………………………………….…….100

References………………………………………………………….…...101

vi

CHAPTER 5: Field guide to the Sierra Madera impact structure………….……..104

Introduction…………………………………………………………..…109

Location and background……….………………………………….…...110

Stratigraphy……..………………………………………………….…...113

Brief regional geologic history…...………………………………....….117

Past Studies…………………………...…………………………….…..118

Current and future research…………………………………………..…119

Field trip stops and descriptions……………………………………..…122

References……………………………………………………………....137

APPENDICES

A. X-ray analysis data for Sierra Madera and Mission Canyon Fm calcite

samples……………………………………………………………….143

B. X-ray analysis data for Sierra Madera and Mission Canyon Fm

dolomite samples…………………………………………………….276

C. Single peak FWHM values for calcite-rich Sierra Madera and Mission

Canyon Formation samples…………………………………………..403

D. Single peak FWHM values for dolomite-rich Sierra Madera and

Mission Canyon Formation samples………………………………...408

E. Rietveld parameters for all X-ray diffraction samples………………414

F. Rietveld data for Sierra Madera and Mission Canyon Fm calcite

samples……………………………………………………………….416

G. Rietveld data for Sierra Madera and Mission Canyon Fm dolomite

vii

samples……………………………………………………………….420

H. Electron microprobe data for calcite-rich and dolomite-rich X-ray

diffraction samples…………………………………………………...424

viii

LIST OF FIGURES

Page

1.1. Location of the Sierra Madera impact crater………………………………….….…..3

1.2. Geologic map of Sierra Madera...…………………………………………….………4

1.3. Stratigraphic column of rocks exposed at Sierra Madera……...……………………..9

1.4. Stages of crater development for a complex crater…………………………..……...13

1.5. Cross section of Sierra Madera………………………………………………...……15

2.1. Geologic map of Sierra Madera impact crater……………..…………………..……27

2.2. Photomicrographs of sandstone deformation from the Sierra Madera impact

structure…………………………………………………………………………….31

2.3. Possible surface deformation in zircon……………………………………...………33

2.4. Shatter cone deformation…………...…………………………………………..…...35

2.5. Geologic map of the central uplift of the Sierra Madera impact crater……………..37

2.6. Geologic map of the central uplift of the Sierra Madera impact crater showing

location of breccia types………………….………………………….…...………..40

2.7. Monomict impact generated breccia from Sierra Madera……………...…...………42

2.8. Polymict breccia outcrop and hand sample photographs……………………...……44

2.9. Complex impact crater showing impactites locations………………………………49

3.1. Geologic map of Sierra Madera and stratigraphic column for rocks exposed at Sierra

Madera ……………………………………...………………………...……………62

3.2. Location of Mission Canyon Formation samples and General stratigraphic column of

the Mission Canyon Formation.…………………………………....………..………64

3.3. X-ray powder diffraction patterns of calcite and dolomite samples from the Sierra

ix

Madera impact structure and Lower Mississippian Mission Canyon

Formation.……………………………………………………...………………......69

3.4. Single peak profiling using FWHM values for Sierra Madera and Mission Canyon

Formation samples……………….…………..………….……………………..……73

3.5. Rietveld refinement analysis for Sierra Madera and Mission Canyon Formation

samples.………………………...………………………………...………….………74

4.1. Geologic map of the Sierra Madera impact structure…………………………….....91

4.2. Shatter cone from the Gilliam Limestone at the Sierra Madera impact crater…...…93

4.3. Age comparison diagram……………………………………………………………96

4.4. Complex impact crater showing impactites locations………………………………98

5.1. Location of impact craters in Texas…………….....…………………………….…111

5.2. Location of the Sierra Madera structure near Fort Stockton, Texas…………....….112

5.3. Stratigraphic column of rocks that outcrop in the central uplift and crater rim of the

Sierra Madera impact structure.……………..…………………..….……..…….…114

5.4. Scanning electron micrographs of shocked zircon surface textures.………………121

5.5. World’s largest roadrunner, Paisano Pete, Fort Stockton, TX ………………..…...123

5.6. Geologic map of the Sierra Madera impact structure and location map for the field

trip………………………………….…...………………………………………….125

5.7. Sierra Madera impact crater...………………………………………………….…..126

5.8. Site locations for Stop 2……...…………………………………………………….126

5.9. Overlapping shatter cones from the Gilliam Formation and a shatter cone from the

Upper Hess Formation.………………………. …………..……...………………..128

5.10. Weathered out block of Gilliam Limestone with a fractured appearance.….........129

x

5.11. Solution collapse breccia in the Tessey Limestone …………………...…………129

5.12. Monolithic breccia in the Gilliam Limestone.…...………………………...……..131

5.13. Slickensides in a sandstone unit of the Gilliam Limestone.……………………...131

5.14. Polymict breccia outcrop …………………………………….……………...…...133

5.15. Site location for Stop 3………………………………………….………………..135

5.16. Gently dipping Lower Cretaceous rocks exposed on the north crater rim of Sierra

Madera …...……………...………….…………………………………...……….135

xi

xii

LIST OF TABLES

Page

2.1. Stratigraphic units exposed within and surrounding Sierra Madera impact crater….28

2.2. Comparison of Breccia Types at Sierra Madera………………...…………….…….39

3.1. X-ray Powder Diffraction Samples……………………………………………...….65

3.2. Electron microprobe analytical data…………………………………………….…..68

4.1. Fission track data……….……………………………………………………….…..95

CHAPTER ONE

INTRODUCTION

Abstract

This first chapter serves as an introduction to the Sierra Madera impact structure and the

topics presented in this dissertation. The geographic location of the field area is followed by a

brief discussion of the previous geologic research. A geologic history of the region covers the

major events that have shaped the Sierra Madera region from Precambrian to Recent. The

stratigraphy section provides a detailed account of the type and depositional history of rocks

exposed within the Sierra Madera impact structure. The structure section focuses on basic

impact crater formation processes and the structural components found within the Sierra Madera

impact crater.

1

Introduction

The Sierra Madera impact crater is a 12.9 km diameter, well-eroded, well-exposed

complex impact crater located ~30 kilometers south of Fort Stockton, Texas (Figure 1.1). Of the

>200 impact craters positively identified on the Earth, it is one of ~60 craters hosted in

carbonate-rich sedimentary rocks (Grieve and Robertson 1979; Grieve and Pesonen, 1996) and

one of four impact structures located in Texas. In addition to carbonates, Sierra Madera also

includes interbedded siliciclastic target rocks (Figure 1.2) making it an ideal place to

comparatively study quartz-carbonate deformation produced during an impact event. Similarly,

the size of the crater is between other craters hosted in carbonate rocks, namely, Haughton (24

km), Ries (24 km), Steinheim (3.8 km), and Barringer (Meteor) Crater (1.2 km). Therefore,

study of the Sierra Madera crater provides important information for understanding the

continuum of carbonate deformation produced by meteorite craters.

The objectives of this research were to document shock deformation and determine the

timing of the impact event. Modern research techniques were used to identify pressure and

temperature conditions during the event as well as attempt to assign a radiometric age to the

structure.

Previous Research at Sierra Madera

Sierra Madera was first mapped by King (1930) who noted a circular zone of intensely

deformed, uplifted Permian strata near the northern end of the Glass Mountains. Boon and

Albritton in 1937 suggested a meteorite impact origin due to the damped wave form of the

structure and lack of volcanic material. However, an impact origin was not firmly established

until 1959 with the discovery of shatter cones at the site making Sierra Madera the fifth structure

2

Figure 1.1. Location map of the Sierra Madera impact crater. Also shown are the major

structural features of the region, including the Delaware Basin, and extent of the Capitan

Reef Formation exposed in mountain ranges surrounding the basin. The solid line represents

the mapped extent of the reef. The dashed line represents the approximate location of the

reef. Modified from Hill (1996).

3

Figure 1.2. Geologic map of Sierra Madera. Modified from Wilshire et al. (1972). Dashed line

represents location for cross section in Figure 1.5.

4

in the world where shatter cones were found (Dietz, 1960; Eggleton and Shoemaker, 1961). A

gravity-magnetic study revealed negative gravity and positive magnetic anomalies (Van Lopik

and Geyer, 1963). While indicating the absence of a buried meteorite the results still support the

impact origin of Sierra Madera since negative gravity anomalies are typical in impact craters due

to the intensely shattered rock produced during cratering events (Van Lopik and Geyer, 1963).

The structure was first considered to be the 3.2 km diameter well-eroded remnant of a

simple crater (Boon and Albritton, 1937). Polymict breccia outcrops were thought to occur as a

single lens-shaped mass within the center of the central uplift and the structure was tentatively

compared to Meteor Crater in Arizona (Eggleton and Shoemaker, 1961). The theory was revised

with later fieldwork that concluded Sierra Madera was the eroded remnant of a complex crater,

currently containing a ~6 km diameter central uplift surrounded by a ~12 km diameter rim and

ring depression. These studies documented shock deformational features such as impact

generated breccias, shatter cones, planar deformation features (PDFs) in quartz, grain fracturing,

and deformed quartz and carbonate minerals and also produced a detailed geologic map of the

structure (Howard and Offield, 1968; Wilshire and Howard, 1968; Wilshire et al., 1971; Howard

et al., 1972, Wilshire et al., 1972).

One hypothesis postulates the impact event occurred when the region was covered by 1-2

miles of water (Kelly, 1966). A water-impact event would deform rocks immediately below the

point of impact while leaving the rim moderately undisturbed thus explaining the highly

deformed rocks of the central uplift and relatively flat-lying rocks of the crater rim.

The Sierra Madera structure was proposed along with the Manson structure in Iowa as a

possible crater for the K-T boundary event before Chicxulub was discovered (French, 1984).

However, Sierra Madera was considered unlikely due to its relatively small size and lack of

5

characteristic K/T boundary clastic material (French, 1984). Recently a modeling study was

conducted to reproduce the current crater diameter and associated deformational features (Goldin

et al., 2006). Not all of the features of the crater were reproducible with the diameters chosen,

the most prominent being the lack of overturned beds on the crater rim, however, a water-impact

model was not tested.

Currently, Sierra Madera is located within an actively producing gas field. Two

exploration wells were drilled in the central uplift in 1921, the Stanley Thomas Elsinore No. 1

(total depth 2,238 m) and Phillips’ Elsinore No. 1 (total depth 3,687 m; Wilshire et al., 1972;

Constant, 1978). The Stanley Thomas Elsinore No. 1 well blew out and was abandoned in 1940.

Drilling in other locations on the crater resumed in 1977 and continues to the present (Constant,

1978; Donofrio, 1998).

Geologic History of Area

The geologic history of the Delaware Basin region is divided into eight phases (Hill,

1996). During the Precambrian (1300-850 Ma) the Delaware Basin developed as an

intracratonic basin. Granitic basement rock was broken by high-angle faulting during the

Grenville orogeny. These faults became areas of regional weakness and were reactivated during

later deformational events. The Passive Margin Phase (850 – 310 Ma) represents a time when

the region experienced little tectonic activity. Deposition occurred in a slowly subsiding area

known as the Tobosa Basin and was characterized by epicontinental seas with periods of

subaerial exposure and karstification (Hill, 1996). During the Late Devonian the Tobosa Basin

was uplifted, tilted, and eroded. Deposition continued until the Collision Phase (310-265 Ma).

At this time, Precambrian zones of weakness were reactivated during the Marathon-Ouachita

6

orogeny and the Tobosa Basin was divided into the Midland and Delaware Basins separated by

the Central Basin Platform (Hill, 1996). The Permian Basin Phase (265-230 Ma) is characterized

by basin subsidence and reef growth. During the Permian the Delaware Basin rapidly subsided

and filled with carbonate material and clastics shed off highland areas including the Central

Basin Platform. By the middle of the Guadalupian the Midland Basin was isolated from normal

marine circulation and filled in while extensive reefs developed at the shelf margin in the

Delaware Basin as exemplified by the Capitan Formation in Guadalupe Mountains National Park

(Hill, 1996). During the Early Ochoan the Delaware Basin connection to the open ocean was

closed resulting in a decline of reef building and the end of normal marine carbonate deposition.

Ochoan age deposits are characterized by red beds, evaporites, and fossil poor limestone. The

Stable Platform Phase (230-80 Ma) was a period of tectonic stability. From the Triassic to Early

Cretaceous the area remained exposed with deposition in terrestrial environments and subsequent

erosion. During the Early Cretaceous an epicontinental sea transgressed the area depositing

shallow marine sediments for the last time in the region. The sea remained until the end of the

Cretaceous at which time the area was affected by the Laramide orogeny. The Laramide Phase

(80-40 Ma) resulted in uplift, tilting and arching in the Delaware Basin (Hill, 1996). Volcanic

Phase (40-30 Ma) marked a transition from Laramide compression to Basin and Range extension

and crustal thinning. Intrusive and extrusive volcanism occurred in the Glass Mountains and

Davis-Barilla Mountains and throughout Mexico and western New Mexico. During the Basin

and Range Phase (30-0 Ma) north-northwest trending high-angle normal block faulting resulted

in the uplift of the Guadalupe, Apache, Delaware and Glass Mountains (Hill, 1996) and created

the present landscape we see today.

7

Stratigraphy

The Delaware Basin of west Texas and southern New Mexico was a major marine basin

throughout the Permian (Hill, 1996). The rocks at Sierra Madera and other parts of the basin

record a gradual filling in of the basin capped by widespread evaporitic conditions by the end of

the Permian. The Triassic and Jurassic were marked by uplift and erosion and rocks of these

ages outcrop discontinuously. Triassic and Jurassic rocks have not been identified at Sierra

Madera. The Cretaceous is marked by a transgression represented by fluvial to shallow water

marine deposits.

Below is a description and stratigraphic column (Figure 1.3) of rocks outcropping within

the central uplift and along the crater rim of the Sierra Madera impact structure. Descriptions are

compiled from Wilshire et al. (1972), Hill (1996), and the author.

Hess Formation – The Permian (Leonardian) Hess Formation is a 730 - 850 meters thick, fine-

grained, medium to thick bedded limestone and dolostone with interfingering sandstone,

siltstone, and shale. Sediments were deposited in a shallow water lagoon. Common fossils

include fusulinids, brachiopods, and bryozoa. There is a gradual up section decrease in clastic

material and increase in dolomite in this unit. At Sierra Madera 365 - 430 meters of Hess

Formation outcrop at the surface and the unit gradually increases in thickness to the north

(Wilshire et al., 1972).

Cathedral Mountain Formation – The Permian (Leonardian) Cathedral Mountain Formation is a

0-24 meter thick conglomerate containing chert and quartz pebbles in a dolomite matrix. Beds of

cross-bedded coarse, quartz sandstone occur locally within the Cathedral Mountain Formation

8

Figure 1.3. Stratigraphic column of rocks exposed at Sierra Madera.

9

(Wilshire et al., 1972). This unit grades up conformably into the lower part of the Word

Formation. The depositional environment for the Cathedral Mountain Formation is debated as

being a shallow water deltaic complex (Wardlaw et al., 1990) or basinal where clastics are

derived from debris flows or turbidity currents (Ross, 1986).

Word Formation – The Permian (Early to Middle Guadalupian) Word Formation is divided into

two members: the lower Limestone Member and the upper Sandstone Member. The lowermost

member of the Word Formation is an unnamed limestone unit 0-76 meters thick (Wilshire et al.,

1972). It contains thin to thick bedded limestone, with crinoid and fusulinind fossils, and some

interbedded finely crystalline dolomite. The upper Sandstone Member of the Word Formation

(0-10 meters thick) consists of interbedded coarse grained sandstone with silicified crinoid stems

and silty to fine-grained sandstone with calcite cement. Locally this unit grades laterally to a

sandy dolomite. The depositional setting for the Word Formation is controversial and is

proposed to be basinal with turbidity currents moving clastics off the shelf (Ross, 1986) or a

shallow water lagoon (Rohr et al., 1982; Wardlaw et al., 1990).

Vidrio Formation - The Permian (Middle Guadalupian) Vidrio Formation (60-230 meters thick)

consists of thick to massively bedded dark dolomite with sparse fossils. Dolomitization has

destroyed the original fabric of the rock and many fossils. Chert nodules are common. The

Vidrio represents initial reef development in the Delaware Basin. Reefs of the Vidrio were early

precursors to major reef building in the Late Guadalupian (Hill, 1996).

10

Gilliam Limestone – The Permian (Late Guadalupian) Gilliam Limestone is a 213-290 meters

thick, dolomite and calcite cemented fine-grained sandstone deposited in a lagoonal and back

reef setting (Hill, 1996). Sandstone layers in this unit pinch out laterally and are discontinuous.

This unit grades conformably into the Vidrio Limestone Member of the Word Formation.

Tessey Limestone – The Permian (Ochoan) Tessey Limestone is a 0-120 meters thick, gray

brown dolomite with sparse fossils. In some locations the unit is identified by areas of solution

collapse breccia composed of laminated small (cm-size) to large (several meter-size) fragments

of Tessey Limestone cemented mosaic-like with calcite and/or dolomite cement. Deposition

occurred in a hypersaline basin that underwent periods of subtidal to supratidal deposition and

subaerial exposure (Haneef and Wardlaw, 2000). Meteoric dissolution created karst features and

collapse breccias (Hill, 1996). These breccias occur mostly on the east side of the central uplift

(Wilshire et al., 1972).

Fredericksburg and Lower Washita Groups – The Fredericksburg Group rocks are Early

Cretaceous (Middle Comanchean) in age. They represent the youngest rocks exposed at Sierra

Madera on the crater rim. The Maxon Sandstone occurs at the base of the Fredericksburg Group

(Hill, 1996). It is a 15-30 meter thick red-brown, fine- to coarse-grained sandstone cemented

with silica cement. The Maxon Sandstone can be differentiated from other sandstone units at

Sierra Madera because of its silica cement and a thin quartz pebble layer at the base of the unit

(Wilshire et al., 1972). At Sierra Madera the Maxon Sandstone unconformably overlies the

Tessey Limestone. The Edwards Limestone (40-60 meters thick) is a platy light gray and brown

limestone. The Kiamichi Formation (~15 meters thick) is a thin bedded light gray limestone.

11

The Cretaceous (Late Comanchean) Washita Group consists of platy to massive, medium-

grained, shaly limestone. The Fredericksburg and Washita Groups represent deposition in a

fluvial/deltaic to shallow marine setting (Hill, 1996) and are not differentiated at Sierra Madera

due to poor exposures and lack of stratigraphic control.

Structure

Complex Crater Formation

The formation of a complex impact crater is divided into three separate stages (Figure

1.4). During the Contact and Compression Stage the projectile contacts the target surface and a

shock wave (compressional) begins to radiate spherically outward from a central point (French,

1998). As the shock wave travels away from the contact point, it is followed by a rarefaction

(tensional) wave which unloads intense shock pressure by fracturing and brecciating the

underlying target rock. Simultaneously, a rarefaction wave is reflected back into the projectile

which will cause it to break up and vaporize (Melosh, 1989).

The Excavation Stage begins when material is ejected from the expanding crater

(Melosh, 1989). The shock wave continues to move material outward and down. Material

ejected from the crater blankets the surface of the surrounding target rock. This stage ends when

target material ceases to be ejected from the crater resulting in a maximum-sized open bowl

shaped depression, called the transient cavity (French, 1998; Melosh, 1989).

The Modification Stage occurs when the target material in the center of the transient

cavity rises to form a central uplift, similar to the rebounded central peak of a depression formed

by a rain drop hitting a liquid surface (Melosh, 1989). Additionally, the transient crater rim

collapses in towards the central uplift under the influence of gravity forming a series of ring

12

Figure 1.4. Stages of crater development for a complex crater. Modified from French (1998).

13

grabens (French, 1998).

Sierra Madera Structure

Sierra Madera is divided into three structurally different regions; the uplifted crater rim

encloses the ring depression and peaks of the central uplift (Figure 1.2). In general the crater is a

bowl-shaped structure with deformation gradually lessening ~2500 meters beneath the central

uplift (Figure 1.5; Wilshire, 1972).

Rim – The crater rim at Sierra Madera is a ~0.8 km wide well-eroded feature. Strata

exposed on the rim include the Permian Gilliam and Tessey Formations and the Cretaceous

Maxon Sandstone and lower most Fredericksburg Formation. These units are generally flat lying

or dip between 5-20° however they can increase to 80° near faults (Wilshire et al., 1972). The

crater rim is truncated by normal faults with the down-thrown side towards the central uplift.

Mild folding of the lower Cretaceous Fredericksburg Group occurs on the northwest and eastern

sides of the rim. Fold axes parallel the crater rim boundaries.

Ring depression – The ring depression is a ~1.5 km wide feature encircling the central

uplift. Oil and gas drilling records indicate lower Cretaceous rocks are covered by Quaternary

alluvium (Wilshire et al., 1972). No breccia or melt rocks have been reported in the drilling

data however rocks are intensely deformed with dips near vertical (Wilshire et al., 1972). On the

eastern side of the depression, lower Cretaceous rocks are exposed gradually merging with strata

from the central uplift. Strata generally dip 5-20° and are deformed by small discontinuous folds

with axes parallel to the boundaries of the depression. Ring normal faults with the down-thrown

side towards the center of the crater separate the depression from the crater rim (Wilshire et al.,

1972).

14

Figure 1.5. Cross section of Sierra Madera. Modified from Wilshire et al. (1972).

15

Central Uplift – The central uplift of Sierra Madera is a ~7 km wide, circular zone of

intensely folded and faulted peaks rising ~250 meters above the ring depression. Units exposed

within the central uplift include the Permian Hess Formation, Cathedral Mountain Formation,

Word Formation, Gilliam Formation, Tessey Limestone and the Cretaceous Maxon Sandstone

and lower Fredericksburg and Washita Groups. Stratigraphic uplift of the centrally located Hess

Formation is ~1200 meters (Wilshire et al., 1972). Strata dip from 15° to vertical and overturned

with no apparent relationship between angle of dip and proximity to the center of the structure.

Most faults within the central uplift are high-angle normal or reverse however low-angle thrusts

and at least one strike-slip fault have been documented (Wilshire et al., 1972).

Chapter Summaries

Chapter Two: Deformational features and impact generated breccia from the Sierra Madera

impact structure, west Texas, will be submitted to GSA Bulletin.

In this study, impact deformed rocks from the Sierra Madera impact crater were re-

examined applying modern research techniques and the current knowledge of cratering products

to better understand deformational products associated with a smaller to medium-sized diameter

carbonate crater and to provide data in a critical intermediate size/energy range for which

information currently is lacking. This study presents new descriptions of impact-generated

breccia, the possible identification of zircon deformation, and descriptions of a shatter cone

weathering texture in host limestone. Additionally, information regarding the temperature and

pressure conditions during the impact event is presented with a discussion relating the above

deformational features to the modern crater erosional level for the Sierra Madera impact

structure.

16

Chapter Three: X-ray powder diffraction Rietveld analysis as a tool for the identification of

impact deformed rocks, submitted to Meteoritics and Planetary Sciences.

In this study XRD patterns of calcite and dolomite from the Sierra Madera impact crater

were compared to those of unshocked carbonate samples from the Mississippian Mission Canyon

Formation of the northern Rockies, United States and to unshocked/undeformed mineral

standards. The objective was to determine if XRD patterns of the shocked carbonates can be

distinguished from XRD patterns of carbonates that were deformed solely by terrestrial processes

(e.g. burial or tectonism). This study has implications for using XRD pattern analysis as a tool

for the identification of shock metamorphic processes where conventional impact characteristics

(i.e., shatter cones and PDFs in minerals) are lacking or poorly developed.

Chapter Four: Fission track age for the Sierra Madera Impact Structure, may be submitted to

Geology.

The object of this study was to determine the age of the Sierra Madera impact event using

radiometric age-dating techniques. The relative age of the Sierra Madera impact crater is known

from stratigraphic and structural relationships; however, an absolute date for the impact is not

known. Deformational features (i.e. shattercones and PDFs in quartz grains) within Sierra

Madera indicate post-impact temperatures ranged from 100°C to at least 150°C and the structure

was not deformed by a thermal event subsequent to its formation. Therefore, low-temperature

(<125°C) dating techniques are ideal for studying the timing of this impact event.

17

Chapter Five: Field Guide to the Sierra Madera Impact Structure.

This document was written as a guide for participating members of the Impact in the

Field Studies Group annual field trip in 2006. The trip was held in conjunction with the 37th

Annual Lunar and Planetary Science Conference in Houston, Texas.

18

References

Boon, J. D., and Albritton, C. C., Jr., 1937, Meteorite scars in ancient rocks: Field and

Laboratory, v. 5, no. 2, p. 53-64.

Constant, F., 1978, The Elsinore; Pikes Peak, East; and Sierra Madera fields of Pecos County,

Texas, in Gilbertson, R., ed., Energy quest for the Southwest: West Texas Geological

Society, v. 78-69 SWS, p. 61-70.

Dietz, R. S., 1960, Meteorite impact suggested by shatter cones in rock: Science, v. 131, no.

3416, p. 1781-1784.

Donofrio, R.R., 1998, North American impact structures hold giant field potential: Oil and Gas

Journal, May, p. 69-83.

Eggleton, R. E. and Shoemaker, E. M., 1961, Breccia at Sierra Madera, in Short papers in the

geologic and hydrologic sciences: U.S. Geol. Survey Prof. Paper 424-D, p. D151-D153.

French, B. M., 1998, Traces of Catastrophe: A Handbook of Shock-Metamorphic Effects in

Terrestrial Meteorite Impact Structures: LPI Contributions No. 954, Lunar and Planetary

Institute, Houston, 120 p.

French, B. M., 1984, Impact event at the Cretaceous-Tertiary boundary: A possible site: Science,

v. 226, no. 4672, p. 353.

19

Goldin, T. J., Wünnermann, K., Melosh, H. J., and Collins, G. S., 2006, Hydrocode modeling of

the Sierra Madera impact structure: Meteoritics and Planetary Science, v. 41, no. 12,

p.1947-1958.

Grieve, R. A. F. and Pesonen, L. J., 1996, Terrestrial impact craters: Their spatial and temporal

distribution and impacting bodies: Earth, Moon, and Planets, v. 72, p. 357-376.

Grieve, R. A. F. and Robertson, P. B., 1979, The terrestrial cratering record. 1, Current status of

observations: Icarus, v. 38, p. 212-229.

Haneef, M. and Wardlaw, B. R., 2000, Lithofacies and depostional history of the Tessey

Formation, Frenchman Hills, West Texas, in Wardlaw, B. R., Grant, R. E., and Rohr, D.

M., eds., 2000, The Guadalupian Symposium: Smithsonian Contributions to the Earth

Sciences, v. 32, p. 373-380.

Hill, C.A., 1996, Geology of the Delaware Basin Guadalupe, Apache, and Glass Mountains New

Mexico and West Texas: SEPM, Permian Basin section, Publ. 96-39, 480 p.

Howard, K. A. and Offield, T. W., 1968, Shatter cones at Sierra Madera, Texas: Science, v. 162,

no. 3850, p. 261-265.

20

Howard, K. A., Offield, T. W., and Wilshire, H. G., 1972, Structure of Sierra Madera, Texas, as

a guide to central peaks of lunar craters: Geological Society of America Bulletin, v. 83, p.

2795-2808.

Kelly, A. O., 1966, A water-impact hypothesis for the Sierra Madera Structure in Texas:

Meteoritics, v. 3, no. 2, p. 79-82.

King, P. B., 1930, The geology of the Glass Mountains, Texas, Part I, Descriptive geology:

Texas University, Bulletin 3038, 167 p.

Melosh, H. J., 1989, Impact Cratering: A Geologic Process: Oxford University, New York,

245 p.

Rohr, D. M., Miller, J. M., Davis, R. A., and Mamay, S. H., 1982, An Upper Permian

(Guadalupian) flora from the Glass Mountains area, Brewster County, West Texas (abs):

Geol. Soc. Am., Abs. with Prog., v. 14, p. 602.

Ross, C. A., 1986, Paleozoic evolution of southern margin of Permian Basin: Geol. Soc. Am.,

Bull., v. 97, p. 536-554.

Van Lopik, J. R. and Geyer, R. A., 1963, Gravity and magnetic anomalies of the Sierra Madera,

Texas “dome”: Science, v. 142, no. 3588, p. 45-47.

21

Wardlaw, B. R., Davis, R. A., Rohr, D. M., and Grant, R. E., 1990, Leonardian-Wordian

(Permian) deposition in the northern Del Norte Mountains, West Texas: U.S. Geol. Surv.,

Bull., 1881, pp. A1-14.

Wilshire, H. G. and Howard, K. A., 1968, Structural pattern in central uplifts of cryptoexplosion

structures as typified by Sierra Madera: Science, v. 162, no. 3850, p. 258-261.

Wilshire, H. G., Howard, K. A., and Offield, T. W., 1971, Impact breccias in carbonate rocks,

Sierra Madera, Texas: Geological Society of America Bulletin, v. 82, p. 1009-1018.

Wilshire, H. G., Offield, T. W., Howard, K. A., and Cummings D., 1972, Geology of the Sierra

Madera Crytoexplosion Structure, Pecos County, Texas: U.S. Geol. Survey Prof. Paper

599-H, p. 1-49.

22

CHAPTER TWO

DEFORMATIONAL FEATURES AND IMPACT GENERATED BRECCIA FROM THE

SIERRA MADERA IMPACT STRUCTURE, WEST TEXAS

Abstract

Deformational features from the Sierra Madera impact structure, west Texas were studied

to determine shock temperature and shock pressure values during the formation of this crater.

Sandstone, limestone and polymict impact generated breccia samples occur within the central

uplift. Sandstone samples here contain several deformational features including toasted quartz

grains and planar deformation features (PDFs). Zircon mineral grains separated from the

sandstone samples may show evidence of shock deformation. Both sandstone and carbonate

within the central uplift contain shatter cones whereas polymict impact generated breccia

samples contain shatter cone fragments. Most high temperature features associated with less

eroded structures were lacking; however, some small (millimeter-size) possible devitrified glass

clasts within polymict breccias were found at several locations. Lower pressure and temperature

features such as shatter cones, toasted quartz, a jigsaw texture between quartz grains, and quartz

grains with multiple PDFs pressure conditions during the impact were 5.5 to 20 GPa with a post-

shock temperature range of 350 to >1000° C. Deformational conditions during the impact event

were almost certainly higher; however, erosion presumably removed most of the overlying

evidence subsequent to crater formation.

23

Introduction

A significant amount of information regarding shock deformation in meteorite impacted

target rocks and impact generated deposits has been collected from impact cratering studies over

the last 40 to 50 years. We know, for example, craters can contain a variety of shocked and

unshocked clasts derived from underlying basement rocks and surface cover (Metzler et al.,

1988; Stöffler et al., 1988). These clasts may be included in multiple, complex breccia units

associated with impact events. For instance, the Devonian Alamo breccia contains nine different

types of breccias formed during, and immediately subsequent to, the impact event (Warme,

2004). Mechanisms forming these breccias include: the impact event, debris falling into the

excavated crater, repeated tsunamis, and the failure of the pre-existing carbonate platform margin

due to the meteorite impact (Warme and Kuehner, 1998; Warme, 2004).

Additionally, recent studies have identified planar deformational features (PDFs) in

zircon mineral grains (Bohor et al., 1993; Glass and Liu, 2001). PDFs are closed, narrow,

parallel features of highly amorphous material generally oriented parallel to crystallographic

planes within the host mineral (French, 1998). They commonly occur in quartz but also occur in

other silicate minerals such as zircon. In addition to PDFs, granular surface textures in zircon

mineral grains were identified from larger (>~90 km diameter) impact structures (i.e. Sudbury,

Chicxulub, Manicouagan, Chesapeake Bay; Bohor et al., 1993; Glass and Liu, 2001). However,

these features are not yet documented in smaller diameter craters. Finally, the study of shatter

cone fracturing and orientations within impact craters indicates the formation of these features is

more complicated than once thought (Wieland et al., 2006).

Many impact cratering studies have concentrated on understanding deformation in

siliciclastic minerals because of the relative abundance of quartz at the Earth’s surface (French,

24

1998). Yet, not all impact craters contain quartz-bearing rocks. Therefore, pressure and

temperature deformation results based on quartz are not applicable to all impact structures since

~30% of all terrestrial impact structures formed primarily in carbonate rocks (Grieve and

Robertson 1979; Grieve and Pesonen, 1996). Consequently, in structures containing little

siliciclastic material it is often more difficult to determine the deformational history of an impact.

However, impact craters containing both siliciclastic and carbonate rocks can provide a bridge to

understand deformation to both rock types. Well-studied carbonate and mixed siliciclastic and

carbonate craters include Meteor Crater (diameter < 2 km) in Arizona (Kieffer et al., 1976; Burt

et al., 2005) the Steinheim and Ries structures in Germany (diameters of 3.8 km and 24 km,

respectively) and the Haughton structure in Canada (diameter of 24 km; Graup, 1999; Skála and

Jakeš, 1999; Osinski and Spray, 2001; Osinski, 2007).

Studies of carbonate-rich craters have also focused on cratering products. For example,

carbonate rocks in impact craters can contain high-temperature melts (Graup, 1999; Osinski and

Spray, 2001; Tuchscherer et al., 2004). For instance, the Ries and Haughton craters, both

containing carbonate sedimentary rocks as part of the target rock succession and having similar

diameters of ~24 km, demonstrate textural evidence of carbonate-silicate liquid immiscibility

(Graup, 1999; Osinski and Spray, 2001; Tuchscherer et al., 2004).

The Sierra Madera impact structure is a well-exposed complex crater with a diameter of

12.9 km, last studied in the late 1960s (Wilshire et al., 1972). Target rocks at Sierra Madera are

predominantly carbonate with a few interbedded siliciclastic units. Impact deformed rocks from

the Sierra Madera impact crater were re-examined to better understand deformational products

associated with a smaller to medium-sized diameter carbonate crater by providing data in a

critical intermediate size/energy range for which information currently is lacking. We present

25

new descriptions of impact generated breccia, the possible identification of zircon deformation,

and descriptions of shatter cones. Using these features we determined the temperature and

pressure conditions during the impact event. Additionally, we relate the occurrence and

distribution of the deformational features to the current crater erosional level for this impact

structure.

Geologic Setting

The Sierra Madera impact structure near Fort Stockton, Texas, is a well-exposed, eroded

remnant of a complex impact crater (Figure 2.1; Eggleton and Shoemaker, 1961; Wilshire and

Howard, 1968; Howard et al., 1972; Wilshire et al., 1972). The central uplift at Sierra Madera is

composed of steeply dipping, folded, and faulted Upper Paleozoic to Cretaceous carbonate and

siliciclastic rocks. Upper Permian carbonate and siliciclastic strata include the Hess, Cathedral

Mountain, Word and Vidrio formations, and the Gilliam and Tessey Limestones (Table 2.1).

Lower Cretaceous rocks of the Fredericksburg and Lower Washita Groups are exposed along the

eastern margin of the central uplift. The Permian Hess Formation, the oldest stratigraphic unit

exposed in the central uplift, was displaced vertically at least 790 meters during the excavation

and modification stage of crater development (Wilshire et al., 1972). Impact generated polymict

and monolithic breccias occur within the central uplift of the crater. The crater rim at Sierra

Madera is composed of Lower Cretaceous carbonate and siliciclastic rocks of the Fredericksburg

and Lower Washita Groups. On the southwest side of the rim, rocks from the Upper Permian

Gilliam and Tessey Limestones are exposed. Cretaceous strata occur ~30-60 meters above the

alluvium-filled ring depression. Strata on the rim generally dip 0-5° radially, though at some

locations dip can be as great as 30°. Post-impact erosion removed an estimated 610 meters of

26

Figure 2.1. A) Geologic map of Sierra Madera impact crater (modified from Wilshire et al.

1972). Dashed box in center indicates region shown in Figures 5 and 6. B) Stratigraphic

column for rocks exposed at Sierra Madera.

27

Strat. Unit Description Alluvium 0-15 meters of unconsolidated boulder to silt size, angular to rounded clasts of dolomite, limestone Quaternary limestone, chert, and sandstone, locally well-cemented as caliche (Wilshire et al., 1972). Fredericksburg The lower part of the Fredericksburg consists of the Maxon sandstone, a 15-30 meter thick red- and Lower brown, fine- to coarse-grained silica cemented sandstone. The Edwards Limestone (40-60 meters Washita thick) is a platy light gray and brown limestone. The Kiamichi Formation (~15 meters thick) is a Groups thin bedded light gray limestone. The lower Washita Group consists of platy to massive, medium- Lower grained, shaly limestone. The Fredericksburg and Washita Groups represent deposition in a Cretaceous fluvial/deltaic to shallow marine setting (Hill, 1996) and are not differentiated at Sierra Madera due to poor exposures and lack of stratigraphic control. Tessey 0-120 meters thick, gray brown dolomite with sparse fossils. In some locations this unit contains Limestone areas of solution-collapse breccia composed of laminated small (cm-size) to large (several meter- Upper Permian size) fragments of limestone cemented mosaic-like with calcite and/or dolomite cement. This

unit is unconformable with the underlying Gilliam Limestone. Deposition occurred in a hypersaline basin that underwent periods of subtidal to supratidal deposition and subaerial exposure (Haneef and Wardlaw, 2000). Meteoric dissolution created karst features and collapse breccias (Hill, 1996). These breccias occur on the east side of the central uplift (Wilshire et al., 1972).

Gilliam 213-290 meters thick, light-colored dolomite interbedded with calcite cemented fine-grained Limestone sandstone; sandstone layers pinch our laterally and are discontinuous. This unit is conformable Upper Permian with the Vidrio Formation. The Gilliam Limestone was deposited in a lagoonal and back reef

setting (Hill, 1996). Vidrio 60-230 meters thick massive to thick-bedded dark dolomite with sparse fossils. Rounded chert Formation nodules are common often and gray-colored with an orange weathering rind. The original rock Lower Permian fabric and fossils were of this unit are difficult to characterize and interpret thus the depositional

environment at Sierra Madera is unknown. However, in other parts of the Delaware Basin the Vidrio Formation records initial reef development, though the reef facies is not seen at Sierra Madera (Hill, 1996).

Word 0-86 meter thick dolomitized limestone divided into two members. The lowermost member Formation is an unnamed limestone unit 0-76 meters thick (Wilshire et al., 1972). It contains thin to thick Lower Permian bedded limestone, with crinoid and fusulinind fossils, and some interbedded finely crystalline dolomite. The upper Sandstone Member (0-10 meters thick) consists of interbedded coarse grained sandstone with silicified crinoid stems and silty to fine-grained sandstone with calcite cement. Locally this unit grades laterally to a sandy dolomite. The depositional setting for the Word Formation is controversial being either basinal with turbidity currents moving clastics off the shelf (Ross, 1986) or a shallow water lagoon (Rohr et al., 1982; Wardlaw et al., 1990). Cathedral 0-24 meter thick conglomerate containing chert and quartz pebbles in a dolomite matrix (Wilshire Mountain et al., 1972). Beds of cross-bedded coarse, quartz sandstone occur locally as lenses. This unit Formation grades conformably upward into the lower part of the Word Formation. The depositional Lower Permian environment was a shallow water deltaic complex (Wardlaw et al., 1990) or basinal where clastics are derived from debris flows or turbidity currents (Ross, 1986). Hess 730 - 850 meters thick, fine-grained, medium- to thick-bedded limestone and dolostone inter- Formation bedded with sandstone, siltstone, and shale. Sediments were deposited in a shallow water lagoon Lower Permian Common fossils include fusulinids, brachiopods, and bryozoa. There is a gradual up section decrease in clastic material and increase in dolomite in this unit. At Sierra Madera 365-430 meters occur at the surface and the unit gradually increases in thickness to the north (Wilshire et al., 1972).

Table 2.1. Stratigraphic units exposed within and surrounding Sierra Madera impact crater.

28

material on the crater rim eliminating the overturned strata characteristic on rims of younger

craters such as at Meteor Crater, AZ (Wilshire et al., 1972).

Methods

We mapped, sampled, and carefully described impact generated breccias from Sierra

Madera to determine their distribution and formation processes. Characteristics such as textural

differences, clast composition, possible melt products or glasses, deformational features in

minerals, and flow features within breccias are described. Additionally, deformational studies of

the target rock include shatter cone outcrop characteristics and fracture patterns as well as

deformation in quartz and other minerals. Thin section samples of shatter cones, target rocks and

impact generated breccias from the central uplift of Sierra Madera were analyzed using a

petrographic microscope. Selected thin sections were analyzed for evidence of melt features

using plane light and scanning electron microscopy (SEM). Carbon coated, polished thin section

slides were analyzed using SEM with backscatter electron (BSE) imagery and energy dispersive

spectrometry (EDS) to identify silica-rich phases from carbonate material. The SEM used in this

study is housed at the Pacific Northwest National Laboratory in Richland, WA.

We also document possible shock-induced surface textures on zircons from Permian

sandstones within the central uplift of the Sierra Madera crater. Zircon grains separated from

sandstone located in the central uplift of the Sierra Madera impact structure were studied for

shock deformation features and to determine the age of shock deformation (e.g. with fission track

analyses). Sandstone samples were collected from the Maxon Sandstone, sandstone beds of the

Permian Gilliam Limestone and the sandstone member of the Permian Word Formation. Zircon

grains (<100 µm) were separated using a Gemini table, magnetic separator and heavy liquid

29

(methelyene iodide) after the mineral separation techniques of Donelick et al. (2005). Fractions

for light microscopy were mounted in epoxy, polished, and studied under high magnification

using both transmitted and reflected light. Zircon fractions for SEM analysis were etched with a

saturated solution of NaOH at 70°C for 1.5 hours to reveal shock features after Bohor et al.

(1993). These grains were mounted on SEM stubs and carbon-coated prior to SEM analysis.

Deformational features

Target Rocks

Quartz deformation in carbonate cemented sandstones at Sierra Madera

There are four sandstone units exposed the at Sierra Madera impact crater, from oldest to

youngest they are; the Permian Cathedral Mountain Formation, a sandstone member of the

Permian Word Formation, sandstone within the Permian Gilliam Limestone and the Cretaceous

Maxon Sandstone. All units contain shock-induced deformation features within quartz grains

(Figure 2.2).

The Cathedral Mountain Formation is characterized by 0.1-0.2 mm quartz grains within a

carbonate matrix. Typically, quartz grains are not in contact with one another. Deformation in

these quartz grains include grain fracturing, grain partitioning and quartz grains with undulose

extinction. Planar deformation features (PDFs) and decorated PDFs (PDFs with fluid inclusions

along the PDF planes) occur in 5-10% of the quartz grains. Less than 5 % of quartz grains with

PDFs are “toasted” quartz having a grainy brown appearance due to an increase in fluid

inclusions in some shock metamorphosed quartz grains (e.g. Short and Gold, 1996; Whitehead et

al., 2002).

30

Figure 2.2. Photomicrographs of sandstone deformation from the Sierra Madera impact

structure. A) Toasted quartz from the Word Formation. See arrows. Note darkened, blotchy

appearance and PDFs in the grain (see lower half of grain). B) Symplectic texture between

quartz grains from the sand-rich unit of the Gilliam Limestone. Note areas of high

birefringence. C) Jigsaw texture between quartz grains from the Maxon Sandstone. D)

Decorated PDFs in quartz from the Maxon Sandstone. Photomicrograph a is plane polarized

light. Photomicrographs b, c, and d are cross polarized light.

31

Similar to the Cathedral Mountain Formation, the sandstone member of the Word

Formation is a carbonate matrix supported rock with 0.1-1.6 mm size quartz grains. Grain

fracturing and suturing along long contacts is common as well as undulose extinction and grain

partitioning. PDFs occur in less than 10% of quartz grains. Between 5-10% of those grains

containing PDFs also have a toasted appearance (Figure 2.2A).

The sandstone of the Gilliam Limestone contains the most shock features within

sandstone at Sierra Madera. Silty sand units within Gilliam are characterized by 0.04-0.1 mm

size quartz grains and are grain supported. The grains are closely packed and carbonate material

is reduced to a microbreccia. This texture was termed “jigsaw” by Kieffer (1971) indicating an

interlocking of grains. Quartz grains are highly fractured, commonly have undulose extinction,

and contain grain partitioning. Symplectic regions between quartz grains were identified by high

birefringence and opaque regions in plane light (Figure 2.2B). Decorated PDFs and PDFs occur

in 15% of quartz grains; 5% of quartz grains with PDFs are toasted.

The Cretaceous Maxon Sandstone of the Lower Fredericksburg Group is characterized by

0.04-1.2 mm size inclusion-rich quartz grains with carbonate cement. The sand grains in this unit

have a jigsaw texture of interlocking quartz grains similar to those in the Gilliam Limestone

sandstone bed (Figure 2.2C). Quartz grains typically also have undulose extinction, fractures,

and grain partitioning. 5% of quartz grains have decorated PDFs (Figure 2.2D) with >5 % of

these being toasted.

Zircon deformation

Zircon mineral grains separated from sandstone with the central uplift of Sierra Madera

also display evidence of shock damage (Figure 2.3). Parallel features on polished grain mounts

32

Figure 2.3. Possible surface deformation in zircon. A) Light microscopic image of planar

deformation feature-like (PDF) lineations from a polished zircon embedded in epoxy. b and

c) SEM images of zircon surface textures from Sierra Madera. B) Possible surface

expression of planar deformation features. C) Granular surface texture with remnant patches

of the original smooth surface.

33

of zircon grains were documented Permian sandstones from Sierra Madera using transmitted

light microscopy (Figure 2.3A; Huson et al., 2005). The lineations occur in the interior of the

zircon grains and were tentatively called planar elements since they were not measured and

compared to the crystallographic planes in zircon. These features were not abundant and occur

in less than 5% of the samples studied.

Zircon mineral surfaces also were studied using SEM to document shock-induced

deformation. Three types of surface textures were documented on rounded and euhedral zircon

grains; 1) unshocked, 2) PDF-like lineations, and 3) a granular texture. Most zircon mineral

surfaces were unshocked and showed no signs of shock deformation. Less than 5% of the zircon

surfaces studied showed either PDF-like lineations or a granular texture (Figure 2.3B, C). These

surface features are similar to those reported for the K/T boundary ejecta layer and Chesapeake

Bay impact structure (Bohor et al., 1993; Glass and Liu, 2001).

Shatter cones

Shatter cones are unique impact produced fracture surfaces characterized by diverging

striations from cone apex to base. They have two basic morphologies, a flat striated surface of

cones that overlap like shingles and complete to partial 3-dimensional cones (Dietz, 1968;

French, 1998; Wieland et al., 2006;).

Shatter cones were discovered at Sierra Madera in 1959 (Dietz, 1960; Kelly, 1966) and

they occur in abundance within a 2 km radius from the center of the central uplift (Howard and

Offield, 1968; Wilshire et al, 1972). Shatter cones occur in all Permian carbonates but are most

common in the Gilliam Limestone, Vidrio, Word, and Hess Formations (Figure 2.4). They also

occur within the sandstone member of the Word Formation, sand units within the Gilliam

34

Figure 2.4. Shatter cone deformation. A) Shatter cone in sandstone from the Gilliam Limestone. Scale bar is

in cm. B) Photograph and line-drawing of curved, irregular shatter cone from the Gilliam Limestone. Sample

is 8.5 cm in width. C) Distinct weathering fracture pattern of Gilliam Limestone sample containing cm-scale

shatter cones. Lens cap is 5 cm in width. D) Photograph and line-drawing of shattercones oriented in opposite

directions within the Hess Formation. Arrows point in direction of cone apex. Sample is 4 cm in length. E)

Photomicrograph showing a toasted quartz grain (outlined) adjacent to non-deformed quartz grain (right) from

the Word Formation. Note three directions of PDFs within grain (arrows) and over all darkening of grain.

Plane polarized light. F) Photomicrographs of diaplectic glass in quartz (arrows) from the Word Formation.

Left panel viewed under plane polarized light. Right panel viewed under cross polarized light. Note inclusions

in grain when in plane polarized light. Additional quartz grains with inclusions (non-glass) are located on the

right side of the frame.

35

Limestone and are weakly developed in the Cathedral Mountain Formation (Figure 2.4A). Cone

fragments are also reported at a depth of ~3657 m beneath the central uplift (Howard and

Offield, 1968; Wilshire et al., 1972). Cone sizes range from 1 cm to ~ 45 cm in height and 0.5

cm to ~20 cm in diameter (Wilshire et al., 1972). Both cone morphologies, flat surfaces and 3-

dimensional cones, occur at Sierra Madera (Wilshire et al., 1972) and while straight striations

and typical shatter cone morphologies are most common at Sierra Madera, curved striations and

irregular cones and also present (Figure 2.4B). Shatter cones are not uniformly developed in all

units of the central uplift and may occur at one location but not occur in the same formation at a

different location.

Small centimeter-sized shatter cones within the Gilliam Limestone have a distinct

weathering fracture pattern (Figure 2.4C). When broken, blocks of this unit contain many small

complete shatter cones. The fractured appearance results from weathering along shatter cone

planes although the exact relationship is not well understood.

Reorientation of beds containing shatter cones to their original position at Sierra Madera

indicates shatter cones generally point towards the center of this impact crater. However; it is

not uncommon for cone apices to be oriented in directions other than toward the crater center

(Figure 2.5). Additionally, some shatter cones are oriented in different, sometimes opposite

directions within the same sample (Figure 2.4D).

Thin sections of shatter cones are composed of fine-grained carbonate and silt to sand

sized quartz grains. Quartz deformation from shatter cones samples include PDFs, grain

fracturing, and toasting (Figure 2.4E). Additionally, diaplectic quartz glass may also occur in

quartz-rich shatter cones (Figure 2.4F). Diaplectic glass forms when a shock wave passes

through a mineral grain and shatters the bonds between the atoms. Deformational features such

36

Figure 2.5. Geology map of the central uplift of the Sierra Madera impact crater. Numbers

next to arrows indicate the cone axis orientation of shatter cones in beds restored to

horizontal position. Includes data from Wilshire et al. (1972) and this study.

37

38

as twinning or brecciation are not obvious within the carbonate material.

Carbonate Rocks

Deformation in carbonate-rich rocks is not apparent in all rocks found within the central

uplift of Sierra Madera. In thin section, most carbonate rocks are fine-grained and contain

deformed fossil and microfossil fragments. Solution features such as stylolites are common in

the Word Formation. All carbonate formations at Sierra Madera contain shatter cones.

Deformation in carbonate rocks was studied using X-ray diffraction (XRD; see Chapter 3).

Shocked carbonate-rich rocks from the central uplift were compared with unshocked rocks from

outside the crater using XRD peak patterns and Rietveld refinement of full-width at half-

maximum (FWHM) peak values. It was possible to distinguish impact shocked rocks from

comparable unshocked rocks since shocked samples have broader peak patterns and greater

Rietveld FWHM values for higher 2θ values (see Chapter 3).

Impact Generated Breccia

Four breccias units occur within the Sierra Madera impact structure; impact generated

monomict and polymict breccias, an evaporite collapse breccia within the Tessey Limestone, and

modern day caliche (Table 2.2). Impact generated breccias were identified at the Sierra Madera

impact structure (Figure 2.6) by Wilshire et al. (1972). The first, called a “monolithic breccia”,

is characterized by an in situ shattering of rock of a single lithology. The second breccia, termed

“mixed breccia”, contains clasts of two or more lithologies in a fine-grained carbonate matrix.

This study uses the terms “monolithic impact breccia” and “polymict impact breccia” to refer to

Wilshire et al’s (1972) breccia types after the terminology of Stöffler and Grieve (1994).

Table 2.2. Comparison of Breccia Types at Sierra Madera.

Bre

ccia

M

atri

x/

Size

Ran

ge

Cla

st

Cla

st

Out

crop

D

istr

ibut

ion

Shoc

k

Typ

e D

escr

iptio

n C

emen

t of

Cla

sts

Typ

es

Shap

e Sh

ape

of O

utcr

ops

Indi

cato

r In

terp

reta

tion

Mon

omic

t In

tens

ely

Fine

- M

illim

eter

V

ery

Rou

nded

Ir

regu

lar

Ran

dom

N

one

Shoc

k w

ave

indu

ced

sh

atte

red

grai

ned

to

loca

lized

an

d

in

situ

frac

turin

g w

ith

clas

ts o

f a

mat

rix,

cent

imet

er

an

gula

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39

Figure 2.6. Geologic map of the central uplift of Sierra Madera showing location of breccia

types. Modified from Wilshire et al. (1972).

40

Evaporite collapse breccia in the Tessey Limestone is characterized by mosaic-like

cementing of angular, laminated dolomite clasts. Deposition occurred in a hypersaline basin that

underwent periods of subtidal to supratidal deposition and subaerial exposure (Haneef and

Wardlaw, 2000). Meteoric dissolution created karst features and collapse breccias (Hill, 1996).

The evaporite collapse breccia in the Tessey Limestone is distinguishable from monomict impact

breccia by the presence of detrital quartz within the matrix and widespread occurrence outside of

the crater (Wilshire et al., 1972; Hill, 1996).

Caliche, common in arid regions of the southwest United States, is a carbonate crust that

cements material in slope wash and ephemeral stream channels. At Sierra Madera, it can be

easily confused with polymict impact generated breccia because both breccia types contain clasts

of several compositions. However in thin section, the cement in caliche is layered, reflecting

numerous, slow cementation events within the matrix and surrounding clasts over time whereas

the cement/matrix in polymict impact breccia is massive.

Monomict

Monomict impact generated breccias occur in all Permian carbonate formations and the

Lower Cretaceous Maxon Sandstone within the central uplift of Sierra Madera. Irregular zones

of brecciation are randomly distributed throughout the central uplift (Figure 2.6). At some

locations breccias show little clast rotation and appear as fractured bedrock. In other locations,

the breccia contains a large amount of matrix material producing rough and irregular outcrops

(Figure 2.7A and B). Monomict impact generated breccia thin sections are characterized by

intensely shattered clasts within a dark fine-grained matrix (Figure 2.7C-F). Shattered clasts are

41

Figure 2.7. Monomict impact generated breccia from Sierra Madera. Monomict impact breccia is

characterized by fracturing and internal shattering of clasts with fine-grained material between larger

coherent clasts. A) Monomict breccia with little clast rotation and small amounts of matrix between

clasts. Scale bar is in centimeters. B) Monomict breccia with a large amount of matrix between

clasts. Note irregular rough appearance of outcrop. Field book 15 cms long. C-F) Photomicrographs

of monomict impact breccia. Samples include the Vidrio Formation (C), Word Formation (D and E),

and Tessey Limestone (F). Samples c and e show evidence of flow in the fine-grained material. All

photomicrographs imaged under plane polarized light.

42

either broken in place with matrix-filled cracks between well-defined fragments or clasts show

some movement with less distinct edges and the surrounding matrix contains internal flow

foliation (Figure 2.7C and E). The dark fine-grained material within monomict impact breccia

was previously identified as mylonite (Wilshire et al., 1972).

Polymict

Impact generated polymict breccia occurs in all formations in the central uplift of Sierra

Madera (Figure 2.8A). Outcrops may or may not be associated with faults and occur parallel or

perpendicular to bedding (Wilshire et al., 1972). The three-dimensional configuration of breccia

in the subsurface is not well understood. For example, it is not known if the outcrops are

connected by a network of pipes or if each outcrop is a single occurrence of breccia. Polymict

breccia occurs only within the central uplift of Sierra Madera. The largest outcrop by area

occurs on the western flank of one of the northern ridges of the central uplift (Figure 2.6).

Small (5-15 cm in diameter) injection dikes of polymict breccia intrude into host

limestone (Figure 2.8B). Clasts within the dikes are rounded to sub-angular and smaller in size

than clasts within tabular breccia sheets. Dike material contains less clastic material and the

carbonate matrix has a finer texture than the host rock (Figure 2.8C).

Polymict breccia at Sierra Madera contains clasts derived from all rocks exposed at the

surface of the structure in a tan to reddish fine-grained carbonate matrix. Clast size ranges from

millimeter to meter-sized. Depending on the location of the breccia, one outcrop may be

enriched with clasts from a particular formation when compared to other breccia outcrops.

Carbonate clasts within the polymict breccia contain small fractures filled with a fine-grained

dark material. Sandstone clasts within the polymict breccia contain toasted quartz and quartz

43

Figure 2.8. Polymict breccia outcrop and hand sample photographs. A) Typical polymict breccia outcrop. Note

hammer for scale. B) Injection dike of polymict breccia into the Hess Fm outlined in white. Field book (right

side of photo) is 15 cm in length. C) Photomicrograph of injection dike-host rock boundary. Plane light. D)

Polymict breccia with shatter cones in chert clast. Scale bar is 5 cm. E) Photomicrograph of melted sandstone

clast within a polymict breccia. Note contorted layering and chaotic nature of clast material. Plane light. F)

Photomicrograph of melted sandstone clast within a polymict breccia. Note flow within clast. Plane light. G)

Photomicrograph of a dark brown, opaque possibly devitrified silica glass clast within a polymict breccia

sample. Plane light. H) Fine-grained carbonate melt or “quenched” material. Lens cap is 5 cm in diameter.

44

grains have multiple PDFs. Shatter cones occur in some limestone and chert clasts within

polymict breccia (Figure 2.8D). Quartz grains within shatter cones contain multiple PDFs and

are highly toasted. Polymict breccias also contain sandstone clasts that are melted and the

resulting clasts contain flow features (Figure 2.8E and F). Possible devitrified silica glass within

polymict breccia occurs as clear or light brown to partially opaque irregular blebs (Figure 2.8G).

These clasts do not occur in all polymict breccia samples/locations. When possible devitrified

silica glass is present as fragments within polymict breccia, it occurs as less than 5% of the

clasts. Carbonate melt or “quenched” material was possibly identified at one location within the

central uplift of Sierra Madera (Figure 2.8H). This material is a fine-grained dark orange

carbonate. In thin section, the material contains small clasts that are unmelted and partially

melted. Partially melted clasts are identified by having a coarse crystalline texture that gradually

becomes more aggregate-like. When rapidly quenched, carbonate material forms either a

holocrystalline material or an aggregate of fine-grained carbonate (Graup, 1999).

Discussion

Zircon Data

Preliminary SEM work on zircon mineral grains from the Sierra Madera impact structure

led to the possible identification of two different impact related surface textures. Less than 5%

of the zircon surfaces studied showed either PDF-like lineations or a granular texture. Similar

surface textures were reported from the ejecta layer of the Chesapeake Bay structure and the

distal ejecta of the Chicxulub structure (Bohor et al., 1993: Glass and Liu, 2001).

Documentation of shock-induced surface textures on zircon grains from the Sierra Madera crater

45

is first report of these features from a <90 km diameter impact structure and may provide more

constraints on the pressures and temperatures in which these features form.

Shatter cone Data

The distinct weathering pattern of shatter cones within the Gilliam Limestone may be

similar to the multiply-striated joint surfaces (MSJS) at the Vredefort structure, where the

authors associated striated surfaces and jointing to the occurrence of shatter cone formation

(Wieland et al., 2006, Nicolaysen and Reimold, 1999). If the weathering pattern in the Gilliam

Limestone from Sierra Madera is similar to MSJS from Vredefort, these features correspond to a

cm-size joint or fracture pattern within the rock. While Sierra Madera has a post-impact regional

joint pattern (Wilshire et al., 1972) a joint or fracture pattern related to the impact event within

the crater has not been determined.

Previous researchers have favored a relatively late formation of shatter cones with

regards to MSJS (Nicolaysen and Reimold, 1999). At Sierra Madera, shatter cones also occur as

fragments within polymict breccia indicating these features form early, during the

contact/compression stage of impact crater development. Additionally, multiple directions of

shatter cones and irregular cone shapes indicate the method of formation for these features is

complex. Both full and partial 3-D cones as well as the overlapping, shingle morphologies are

present within the central uplift at Sierra Madera. It was not within the scope of this study to

determine the timing of shatter cone formation however shatter cone observations at Sierra

Madera indicate it would be an interesting location for such research.

46

What do the deformational features reveal about temperature and pressure conditions during the

impact event?

When rapidly quenched, carbonate material forms either a holocrystalline material or an

aggregate of fine-grained carbonate (Graup, 1999). It is therefore difficult to use carbonate

material as the sole means for determining pressure and temperature conditions during an impact

event. However, using the shock classification scheme for impact metamorphosed sandstones

developed by Kieffer (1971) and modified by Osinski (2007), we can assign shock pressure

values to CaCO3 cemented sandstones at Sierra Madera and apply those values to the adjacent

carbonate units. Impact metamorphosed sandstones at Sierra Madera give a shock pressure

range from 5.5-20 GPa based on the presence of “toasted” quartz, a “jigsaw” interlocking texture

between quartz grains, and multiple sets of planar deformation features (PDFs) within quartz

grains. This shock pressure range corresponds to a post-shock temperature range of 350-

>1000°C (Osinski, 2007). Most likely the host rocks at the current erosional level Sierra Madera

were not exposed to shock pressures as great as 20 GPa based on the low amount of diaplectic

glass within sandstone units.

Sandstone units at Sierra Madera have a range of deformational features that do not

increase towards the center of the central uplift or towards the region of expected highest shock.

For example, the Cathedral Mountain Fm contains less deformational features than the sandstone

from the Gilliam Limestone even though it is more centrally located in the central uplift. This

may indicate shock pressure and temperature conditions were not distributed evenly during the

impact event.

47

What do these features tell us about the amount of deformation observed to the final

crater/erosional level within the crater?

The presence of cm-size injection dikes at Sierra Madera may indicate this structure is

deeply eroded since breccia dikes are common in deeply eroded craters (Lambert, 1981). An

additional indicator of a deeply eroded structure is the absence of an impact melt sheet within the

ring depression. At Sierra Madera, evidence of an impact melt sheet was not found during this

study or previous studies (Wilshire et al., 1972). The melt sheet was eroded or is buried under

sediment within the ring depression in the crater. However, the eroded crater rim, the presence

of injection dikes, suevite-like breccia and monolithic breccia within the central uplift and lack

of abundant high-temperature deformational features indicates the current surface at Sierra

Madera is below the level at which the impact melt sheet would occur (Figure 2.9; French,

1998). Additionally, past research suggests erosion may have removed an estimated 610 m of

overlying material at Sierra Madera (Wilshire et al., 1972). Therefore, pressure and temperature

estimates reported above (5.5-20 GPa pressure range and post-shock temperature range of 350-

>1000° C) should be considered low estimates of deformational conditions.

If the crater was not deeply eroded, an alternate theory is that the Sierra Madera structure

may have formed underwater (Kelly, 1966). A water-impact event would deform rocks

immediately below the point of impact while leaving the crater rim moderately undisturbed thus

explaining the highly deformed rock of the central uplift and relatively flat-lying rocks of the

crater rim (Kelly, 1966).

48

Figure 2.9. Complex impact crater showing impactite locations. Modified from French

(1998). Dashed line in final complex crater indicates current erosional surface at Sierra

Madera.

49

Conclusions

Deformational features within the host rocks and impact generated breccias were used to

determine pressure and temperature conditions during the Sierra Madera impact event.

According to the presence of toasted quartz, a jigsaw texture between quartz grains, and quartz

grains with multiple PDFs pressure conditions during the impact were 5.5-20 GPa with a post-

shock temperature range of 350->1000° C. Based on the projected lower erosional level within

the Sierra Madera impact structure, it is possible deformational conditions during the time of

impact were greater. However, a water-impact may also explain the lack of high temperature

deformational features at Sierra Madera.

Acknowledgments

The authors would like to thank the Lyda and Lang Families for granting access to the

property for sample collection. Also, the SEM used for the zircon work was made available by

the Pacific Northwest National Laboratory in Richland, WA. This research was supported by

NASA Grant NNX06AE69G. Additional funding was provided by the Barringer Crater

Company.

50

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Dietz, R. S., 1968, Shatter cone in cryptoexplosion structures, in French, B. M., and Short, N.

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Howard, K. A. and Offield, T. W., 1968, Shatter cones at Sierra Madera, Texas: Science, v. 162,

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Lambert, P., 1981, Breccia dikes: geological constraints on the formation of complex craters, In,

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57

CHAPTER THREE

RIETVELD ANALYSIS OF X-RAY POWDER DIFFRACTION PATTERNS AS A

POTENTIAL TOOL FOR THE IDENTIFICATION OF IMPACT DEFORMED

CARBONATE ROCKS.

Abstract

Previous X-ray powder diffraction (XRD) studies revealed that shock deformed

carbonates and quartz have broader XRD patterns than those of unshocked samples. Entire XRD

patterns, single peak profiles and Rietveld refined parameters of carbonate samples from the

Sierra Madera impact crater, west Texas, unshocked equivalent samples from 95 miles north of

the crater, and the Mission Canyon Formation of southwest Montana and western Wyoming

were used to evaluate the use of X-ray powder diffraction as a tool for distinguishing impact

deformed rocks from unshocked and tectonically deformed rocks. At Sierra Madera dolostone

and limestone samples were collected from the crater rim (lower shock intensity) and the central

uplift (higher shock intensity). Unshocked equivalent dolostone samples were collected from

well cores drilled outside of the impact crater. Carbonate rocks of the Mission Canyon

Formation were sampled along a transect across the tectonic front of the Sevier and Laramide

orogenic belts.

Whereas calcite subjected to significant shock intensities at the Sierra Madera impact

crater can be differentiated from tectonically deformed calcite from the Mission Canyon

Formation using Rietveld refined peak profiles, weakly shocked calcite from the crater rim

appears to be indistinguishable from the tectonically deformed calcite. In contrast, Rietveld

analysis readily distinguishes shocked Sierra Madera dolomite from unshocked equivalent

58

dolostone samples from outside the crater and tectonically deformed Mission Canyon Formation

dolomite.

Introduction

The physical record of impact craters on the surface of the Earth dates from 3.5 Ga

(Grieve 1998) and it is thought that impact cratering was an essential process even earlier in

Earth’s history (Ryder 2002). Putative impact craters commonly are identified by the presence

of meteorite fragments, siderophile element anomalies, and specific shock deformational features

including shatter cones, planar deformation features (PDFs) in minerals, diaplectic glass, and

melting features (French 1998). Circular or nearly circular geomorphic structures lacking these

distinctive features of suspected impact origin often are the subject of controversy (i.e. the

Silverpit structure; Stewart and Allen 2002; Underhill 2004; Reimold 2007).

Currently, there are ~170 confirmed terrestrial impact craters listed the Earth Impact

Database (www.unb.ca/passc/ImpactDatabase). Methods used to confirm circular structures on

the Earth’s surface as meteorite craters vary with target rock type, age, bolide size, and amount

of material removed by erosion. However, exposure to short-lived shock pressure is a unique

characteristic of the target rocks at all impact craters. Therefore, a method of identifying

minerals/rocks subjected to shock metamorphism, but lacking the usual shock deformational

features, would be extremely useful for distinguishing suspected impact craters from non-impact

generated structures. Past studies, X-ray diffraction (XRD) and petrographic, often focused on

both experimentally and naturally shocked silicate minerals due to the abundance and robust

nature of these minerals at the Earth’s surface (Hörz, 1968; Short, 1968; Hörz and Quaide 1973;

Grieve et al. 1996). An X-ray powder diffraction method for evaluating shock deformation

59

levels within impact craters formed in carbonate host rocks was developed by Skála and Jakeš

(1999). A broadening (i.e. increase in peak width) and reduction in intensity of CuKα X-ray

diffraction peaks in the 2θ° range 56-62° was observed in impact-shocked carbonate from the

Kara Crater (~65 km diameter) in Russia and the Steinheim Basin (3.8 km diameter) in Germany

when compared to those of unshocked standards (Skála and Jakeš 1999). Furthermore, peak

broadening and loss of peak intensity increased with increasing shock pressure (Skála and Jakeš

1999). However, carbonate samples from the Meteor Crater (1.2 km diameter), Arizona and

nearby Canyon Diablo did not show XRD peak broadening with expected increasing shock

effects from crater rim to crater center. These results were attributed to a non-uniform

distribution of shock pressure or smaller sized crater (Burt and Pope 2001; Burt et al. 2005). In

an effort to resolve this discrepancy, carbonate and siliciclastic samples from the Sierra Madera

impact structure (12 km diameter) in Texas were analyzed using XRD techniques adopted from

Skála and Jakeš (1999). Preliminary studies of the Sierra Madera carbonates indicated increased

peak broadening in shatter cone samples (Huson et al. 2006a; Huson et al. 2006b).

In the present study XRD patterns of calcite and dolomite from the Sierra Madera impact

crater are compared to those of unshocked equivalent carbonate samples from outside the crater,

unshocked carbonate samples from the Mississippian Mission Canyon Formation of the northern

Rockies, United States and to unshocked/undeformed mineral standards. The objective is to

determine if XRD patterns of the shocked carbonates can be distinguished from XRD patterns of

carbonates that were deformed solely by terrestrial processes (e.g. burial or tectonism). This

study has implications for using XRD pattern analysis as a tool for the identification of shock

metamorphic processes where conventional impact characteristics (i.e., shatter cones and PDFs

60

in minerals) are lacking or poorly developed, especially since ~30% of all terrestrial impact

structures formed primarily in carbonate rocks (Grieve and Robertson 1979).

Geologic Settings

Sierra Madera impact structure

The Sierra Madera impact structure, located near Fort Stockton, Texas, is a well-exposed,

eroded remnant of a complex, 12 km diameter impact crater (Eggleton and Shoemaker 1961;

Wilshire and Howard 1968; Howard et al. 1972; Wilshire et al. 1972). The central uplift is

composed of steeply dipping, folded, and faulted Upper Permian strata (Fig. 3.1). Lower

Cretaceous rocks occur along the eastern margin of the central uplift. The Permian Hess

Formation, the oldest stratigraphic unit exposed in the central uplift, was displaced vertically at

least 790 m during the excavation and modification stage of crater development (Wilshire et al.

1972). The crater rim at Sierra Madera is composed of eroded Lower Cretaceous carbonate and

siliciclastic rocks with exception of the southwest side where stream incision has exposed Upper

Permian strata. Rim strata are exposed ~30-60 m above the alluvium-filled ring depression and

generally dip 0-5° radially, though at some locations the dip can be as great as 30°. Post-impact

erosion has removed an estimated 600 m of material from the crater rim (Wilshire et al. 1972).

Past studies at Sierra Madera documented shock deformation features including shatter cones in

siltstone and fine-grained sandstone, PDFs in quartz, grain fracturing, impact-induced

brecciation, and deformed carbonate minerals (Dietz 1960; Eggleton and Shoemaker 1961;

Howard and Offield 1968; Wilshire et al. 1972; Huson et al. 2005).

61

Fig. 3.1. A) Geologic map of Sierra Madera (modified from Wilshire et al. 1972). 1 = Kwf CR, 2 = Kwf CC, 3

= Kwf AA, 4 = Kwf ZZ, 5 = Kwf NN, 6 = PtUU, 7 = Pg B1, 8 = Mlb 22-2, 9 = Pwls 22-1, 10 = Pwv O1, 11 =

Ph C1. B) Stratigraphic column for rocks exposed at Sierra Madera.

62

Unshocked Equivalent Dolostone Samples

Ninety-five miles north of the Sierra Madera impact crater, the equivalent dolomitic

Queen and Yates Formations were deposited on the northern edge of the Delaware Basin during

the late Permian. These formations were deposited in a shallow shelf and later evaporitic

environment as the Delaware Basin gradually became restricted (Hill 1996).

Mission Canyon Formation

The Lower Mississippian (Late Osagean-Middle Meramecian) Mission Canyon

Formation in western Wyoming and southwestern Montana records shallow water carbonate

deposition along a broad, carbonate shelf that deepened westward, forming during the Antler

Orogeny ([Late Devonian to Early Mississippian]; Fig. 3.2; Sando 1976; Smith and Dorobek

1993). This unit was subsequently altered by Late Mississippian karstification and

dolomitization and documents deep to shallow burial from west to east (Sando 1988; Smith and

Dorobek 1993). Additional deformation of Paleozoic-Mesozoic strata of southwestern Montana

and western Wyoming occurred during the Cretaceous-Paleogene Sevier and Laramide orogenies

(Snoke 1993).

Experimental

Sample Collection and Preparation

Fine-grained dolostone and limestone samples were collected from the central uplift and

eroded crater rim of the Sierra Madera impact crater (Fig. 3.1; Table 3.1). Unshocked samples of

the dolomitic Queen and Yates Formations, equivalent to the Upper Word and Gilliam

Limestone at Sierra Madera, were collected from the Austin Core Facility in Austin, Texas. The

63

Fig. 3.2. A) Location of Mission Canyon Formation samples. 1 = Shoshone Canyon (SH), 2

= Sheep Mtn (SM), 3 = Benbow Mine (BM), 4 = UPR, 5 = Church Buttes (CB). Gray arrow

indicates increasing burial depth and deformation for all samples sites from east to west. B)

General stratigraphic column of the Mission Canyon Formation.

64

Sedimentary Deformational Sample Composition Characteristics Features 1 Lithology 2 Sierra Madera Samples Crater Rim

Kwf AA Calcite Rare fossil fragments, fine-grained --- MS Kwf CC Calcite Fossils, fine-grained matrix --- WS Kwf CR Calcite Fine-grained F MS

Central Uplift Kwf ZZ Calcite Fossil fragments, fine-grained matrix --- WS Kwf NN Calcite Fine-grained --- MS Pt UU Dolomite Matrix supported breccia B Mono Pg B1 Dolomite Fine-grained F, SC MS Mlb 22-1 Dolomite Matrix supported breccia B Mono Pwv O1 Dolomite Fine-grained SC MS Pwls 22-1 Dolomite Fossils, fine-grained matrix --- WS-PS Ph C1 Dolomite Fine-grained SC MS

Unshocked Equivalent Samples Queen/Word Dolomite Fine-grained --- MS Yates/Gilliam Dolomite Fine-grained --- MS Mission Canyon Samples Shoshone Canyon

SH 202 Dolomite Recrystallized Fc DS SH 234 Calcite Fine-grained --- LS

Sheep Mountain

SM 307 Dolomite Fine-grained --- DS SM 421 Calcite Fine-grained --- LS

Benbow Mine

BM 454 Dolomite Fine-grained --- DS BM 579 Calcite Fine-grained --- LS

UPR

UPR 77183 Dolomite Fine-grained Fc DS Church Buttes

CB 725 Calcite Medium-fine grained --- LS CB 751 Dolomite Fine-grained --- DS CB 770 Dolomite Fine-grained --- DS

1 F= fractures; Fc = fractures filled with coarse calcite; B = brecciation; SC = shatter cones. 2 MS = mudstone; WS = wackestone; WS-PS = wackestone-packstone; Mono = monomict breccia; DS = dolostone;

LS = limestone. 3 Contains visible sulfur.

Table 3.1. X-ray Powder Diffraction Samples.

65

cores were located in the North Ward-Estes Oil Field in Ward County, Texas, 95 miles north of

the Sierra Madera impact crater. The authors were not able to obtain unshocked calcite-rich

samples from outside the crater.

Fine-grained samples of dolostone and limestone also were collected from the Mission

Canyon Formation of the Madison Limestone Group of southwest Montana and western

Wyoming (Fig. 3.2; Table 3.1). Three optically clear samples of quartz, Iceland spar, and

dolomite from Washington State University’s School of Earth and Environmental Sciences

(WSU SEES) mineral collection served as unshocked standards for comparison. All samples

were ground under isopropyl alcohol using a mortar and pestle and the powders were passed

through a 27 μm mesh sieve.

Sample Compositional Characterization

Since compositional differences can lead to XRD peak position and breadth variability

(Fiquet et al. 1994), the magnesium, iron, and calcium content of all calcite and dolomite

samples were analyzed using a Cameca electron microprobe in the WSU SEES GeoAnalytical

Laboratory. No other elements were observed in more than trace amounts.

All samples used in this study were also examined petrographically to determine if there

were noticeable compositional differences between sample sets that may lead to preferential

groupings. In calcite-rich samples, both Sierra Madera and Mission Canyon Formation samples

contain micritic limestone with bioclasts, peloids and intraclasts. Abundances of allochems vary

within each sample. Dolomite-rich samples have less variability, with both Sierra Madera and

Mission Canyon Formation samples containing fine-grained dolomite and no allochems. The

unshocked Queen and Yates Formation samples contain fine-grain dolomite with allochems.

66

There is no indication of an enrichment of allochems or changes in grain size for either calcite-

rich or dolomite-rich samples that would group samples preferentially.

Polished grain mounts of the coarser size (45-63 μm) fraction of each sample used for

XRD analysis were carbon coated and analyzed; sample compositions are presented in Table 3.2.

The experimental parameters were; 15 kV acceleration voltage, 15 nA beam current, 4 μ beam

diameter and 10 s dwell time on peak and background. The calibration standards (analytical line

and spectrometer crystal) were; calcite (CaKα, PET), Obendorf dolomite (MgKα, TAP), and

Irugtut siderite (FeKα, LiF).

X-ray Powder Diffraction Analysis

XRD patterns were collected using CuKα radiation and a Siemens Kristalloflex

Diffractometer equipped with a graphite diffracted beam monochromator and a scintillation

detector. A combination of beam divergence and receiving slits yielding an instrument profile

breadth of 0.083° 2θ for the 311 reflection of silicon powder were used (Foit 1992). The <27 µm

powders were sifted onto a vaseline-coated, quartz zero background plate to reduce preferred

orientation of the grains (Foit 1992). The diffractometer was operated at 35 kV and 30 mA and

the samples were step-scanned over the range 15°-120° 2θ using a 0.02° 2θ step and dwell time

of 10 sec. Although the samples were scanned from 15°-120° 2θ, only the portion of the scan

covering 55-69° 2θ is shown in Fig. 3.3 to highlight peak broadening differences. XRD powder

patterns for all samples were compared to dolomite or calcite standard patterns.

67

Oxide wt % 1 Sample Name MgO FeO CaO CO2 Total Oxide wt %

CALSTD 0.00 0.02 56.88 43.76 100.66 Sierra Madera Samples

Kwf ZZ 0.56 0.09 53.66 44.46 98.76 Kwf NN 0.50 0.01 55.49 44.03 100.03 Kwf CR 0.39 0.00 55.89 43.96 100.24 Kwf AA 0.40 0.06 54.60 44.25 99.30 Kwf CC 0.27 0.02 55.81 43.98 100.08

Mission Canyon Samples SH 234 0.39 0.01 56.97 43.76 101.14 BM579 0.30 0.00 55.86 43.98 100.14 CB 725 0.20 0.01 53.84 44.53 98.57 SM 421 0.30 0.01 55.08 44.18 99.56

DOLSTD 21.72 0.08 30.61 47.67 100.08 Sierra Madera Samples Ph C1 20.60 0.01 31.72 47.55 99.88 Mlb 22-1 20.22 0.03 32.02 47.51 99.79 Pwls 22-1 20.58 0.04 29.94 48.02 98.58 Pwv O1 20.64 0.06 30.28 47.92 98.90 Pg B1 21.43 0.39 30.45 47.51 99.91 Pt UU 21.35 0.87 30.40 47.51 100.13

Mission Canyon Samples SM 307 20.95 0.05 31.48 47.55 100.04 BM 454 21.24 0.01 31.22 47.60 100.07 CB 770 21.22 0.02 31.27 47.58 100.09 CB 751 21.31 0.02 31.22 47.58 100.14 SH 202 21.02 0.07 31.24 47.60 99.93 UP 7718 21.51 0.02 31.03 47.61 100.16 Unshocked Equivalent Samples Yates 21.47 0.31 29.72 NA 99.38 Queen 21.36 0.37 30.14 NA 99.64 1 Calculated from stoichiometry.

Table 3.2. Electron microprobe analytical data.

68

Fig. 3.3. X-ray powder diffraction patterns of calcite and dolomite samples from the Sierra Madera impact

structure and Lower Mississippian Mission Canyon Formation. A) Calcite-rich samples compared with the

calcite standard (CALSTD). B) Dolomite-rich samples compared with the dolomite standard (DOLSTD). All

scans were arranged from least (bottom of chart) to most (top of chart) broadened. See Table 1 for sample

descriptions.

69

Diffraction Peak Profile Analysis

XRD Peak broadening due to shock deformation was analyzed using both single peak

profiling and Rietveld refinement of peak shape parameters, both of which were carried out

using Jade 8.0 software (Materials Data Corporation). With single peak profiling, the peak full

width half maximum (FWHM) values are not appreciably affected by small variations in sample

composition, therefore they are potentially useful for distinguishing weakly from more intensely

shocked samples. Peak broadening can also be analyzed by Rietveld crystal structure refinement

(Young, 1993) of the peak shape parameters (Skála and Jakeš, 1999). XRD peak FWHM values

are a function of the diffraction angle theta and three least squares refineable parameters U, V,

and W (Caglioti, 1958):

(FWHM)2 = UTan2 theta + Vtan theta + W

The values of FWHM, which are related to the amount of shock-induced deformation, were

calculated over the range 15°-120° 2θ. Single peak and Rietveld refined FWHMs were then

fitted with a fourth order polynomial.

Results

Diffraction Patterns: Limestone

XRD patterns of calcite-rich Mission Canyon Formation samples are compared with

calcite-rich Sierra Madera samples (Fig. 3.3A). Samples obtained from the central uplift of

Sierra Madera display more peak broadening than those from the crater rim with an almost

complete disappearance of peaks at 58° and 63° in sample Kwf NN. Although XRD peaks of

70

Mission Canyon Formation sample SH 234 (Fig. 3.3A) are broader than crater rim samples from

Sierra Madera (Kwf CR, Kwf AA, and Kwf CC), in general, calcite-rich Sierra Madera samples

show more peak broadening than calcite-rich Mission Canyon Formation samples. Some Sierra

Madera and Mission Canyon samples contain extra peaks. Samples Kwf NN, Kwf ZZ, Kwf AA

and SM 421 contain minor quartz peaks while samples SH 234 and CB 725 contain minor

anhydrite peaks (Fig. 3.3).

Diffraction Patterns: Dolomite

Of the fourteen unshocked samples collected from the Austin Core Facility only two, one

from the Queen Formation and one from the Yates Formation, are dolomite. The remaining 12

samples contained dolomite with significant amounts of quartz and anhydrite and are therefore

not compared to the shocked samples from Sierra Madera. XRD patterns of dolomite-rich Sierra

Madera samples are compared with two unshocked equivalent samples of the Queen and Yates

Formations (Fig. 3.3B). Shocked samples from Sierra Madera have more peak broadening than

the unshocked Queen and Yates samples. For example, note broadening between sample

Yates/Gil and Pwls 22-1 in the 60° and 67.5° regions.

Samples from Sierra Madera show an increase in peak broadening towards the central

uplift of the impact structure. For some samples (Pwls 22-1, Ph C1, and Pwv O1) peak

broadening is great enough to result in almost a complete disappearance of the three peaks in the

64° to 66° 2θ range.

For Mission Canyon Formation samples, patterns of samples from locations close to the

Antler Orogenic front have less peak broadening than those from farther away. For example, the

peaks for sample UP 7718 (location 4; Fig. 3.2A) are sharper than those for sample SM 307

71

(location 2); especially note the three peaks in the 64° to 66° region. In general, dolomitic Sierra

Madera samples have considerably more peak broadening than Mission Canyon Formation and

unshocked Queen and Yates samples.

Single Peak Profiling – Full Width Half Maximum (FWHM)

The FWHM curves (Fig. 3.4A, B) that deviate most from the standard curves (CALSTD

and DOLSTD) are those that experienced higher shock (shatter cones, monomict impact breccias

and samples from the crater rim). Unshocked Queen and Yates samples plot close to the

standard curves for lower (below ~105) 2θ values. Also the majority of the Mission Canyon

Formation samples tend to plot between the scans of the standards and those of the Sierra

Madera samples (with the exception of BM 454 and SH 234; Fig. 3.4A, B). However, some

samples (CB 725 and Mlb 22-1, for example) have a convex curve instead of the expected

concave curve as seen in the calcite and dolomite standards.

Rietveld Refinement of Peak Shape Parameters

FWHM curves (Fig. 3.5A) for calcite-rich Mission Canyon Formation samples SH 234

and BM 579 overlap calcite-rich Sierra Madera crater rim samples Kwf CR and Kwf AA/Kwf

CC, respectively. FWHM values obtained from Rietveld crystal structure refinements increase

with shock intensity for all calcite-rich Sierra Madera samples. FWHM values of shocked

dolomite from the central uplift of Sierra Madera are distinctly higher than tectonically deformed

dolomite from unshocked Queen and Yates samples as well as samples from the Mission Canyon

Formation (Fig. 3.5B). Additionally, FWHM values for shocked Sierra Madera samples follow a

pattern of progressive broadening from crater rim to central uplift. Sierra Madera samples with

72

Fig. 3.4. Single peak profiling using FWHM values for Sierra Madera and Mission Canyon

Formation samples. A) Calcite values compared with a calcite standard, CALSTD. B)

Dolomite values compared with a dolomite standard, DOLSTD.

73

Fig. 3.5. Rietveld refinement analysis for Sierra Madera and Mission Canyon Formation

samples. A) Calcite values compared with a calcite standard, CALSTD. B) Dolomite values

compared with a dolomite standard, DOLSTD.

74

shock features (shatter cones, monomict breccia) have uniformly higher FWHM values than

those without shock features.

Discussion

All XRD peak patterns deviate from those of the calcite and dolomite standards. This is

particularly true for calcite and dolomite from the central uplift of Sierra Madera. Several factors

contribute to XRD peak profiling variability including Mg content (Gavish and Friedman 1973),

grinding time of powder (Burns and Bredig 1956; Gavish and Friedman 1973), grain size of

powder (Langford et al. 2000; Klug and Alexander 1974), and phase transformations (Burns and

Bredig 1956; Fiquet et al. 1994; Merrill and Bassett 1975). The above mentioned factors were

considered when preparing samples for this study. The Mg, Fe, and Ca contents of all carbonate

samples were measured (Table 3.2) and while all samples deviate slightly from the calcite and

dolomite stoichiometric values, there is no correlation between composition and variability in

XRD peak profiles or Rietveld refined FWHM curves. The grain size of the powder used was

<27 μm since a larger crystallite size can lead to inaccurate and imprecise intensity

measurements (Bish and Reynolds 1989). Phase transformations (e.g., calcite to aragonite due to

grinding; Burns and Bredig 1956) were not a factor since XRD powder patterns for samples from

Sierra Madera show no peaks other than those of dolomite, calcite, and in few cases, quartz and

anhydrite (Fig. 3.3). Quartz is a common mineral in nearshore carbonate rocks. The Mission

Canyon Formation contains anhydrite and other evaporitic minerals due to evaporitic tidal flat

depositional environments (Dorobek et al. 1993).

Single peak profile patterns of calcite and dolomite samples from all samples, while

useful at lower 2θ values, are complex and indicate little relationship to shock intensity at higher

75

2θ values. This is because weaker high angle reflections are poorly estimated by the profile

shape function. High angle reflections from shocked material may disappear from the pattern

since these reflections are often low intensity and shocking decreases the degree of the

crystallinity (Skála and Jakeš 1999). While single peak profiling may be useful at lower 2θ

values, at higher values, especially above ~80° 2θ, the method is unreliable.

More useful for this study was the Rietveld refinement of peak shape parameters.

Rietveld refinement of peak shape parameters yields better resolution of overlapping diffraction

peaks and a more precise measure of the 2θ angular dependence of peak FWHM, thus, providing

a better measure of the degree of shock deformation (Skála and Jakeš 1999).

Rietveld results for the mildly shocked calcite samples from the crater rim overlap with

those of Mission Canyon Formation calcite samples whereas, those of the central uplift are

distinguishable from MCF samples. Dolomite samples from Sierra Madera also show increasing

Rietveld refined FWHM values as the central uplift is approached reflecting increasing

deformation of the dolomite crystal structure with increasing shock pressure (Skála and Jakeš

1999). Noticeably, Sierra Madera samples plot well above unshocked equivalent dolomite-rich

samples from outside of the crater. Therefore, XRD with Rietveld refinement analysis indicates

that it may not always be possible to distinguish calcite-rich samples subjected to terrestrial

tectonic processes from those mildly shocked in an impact event. However, with exposure to

increasing shock pressures within the central uplift of the crater, impact shocked rocks are

readily distinguishable from unshocked rocks from outside of the crater and other terrestrially

deformed rocks.

Interestingly, Mission Canyon Formation samples do not indicate a systematic variation

in Rietveld-refined FWHMs with distance from the Sevier and Laramide orogenic fronts. With

76

Mission Canyon Formation samples, due to deformation associated with increasing compression

and burial depth, peak broadening was expected to increase as sample locations approach the

tectonic front of the Sevier and Laramide Orogenies (Fig. 3.2). The ideal and expected order for

sample locations, from least to most peak broadening, is Sheep Mountain (SM), Benbow Mine

(BM), Shoshone Canyon (SH) to Church Buttes (CB). However, observed XRD patterns for

Mission Canyon Formation samples indicate that peak breadth increases in the order SM 421 to

CB 725 to BM 579 to SH 234. The fronts of these orogens may be more complicated, with

deformation unequally distributed along thrust fronts or out of phase thrusting may have

occurred. Similarly, tectonic forebulge vs. foreland basin events overprinted burial deformation

of the Antler orogeny, increasing the complexity of the deformational history in the area.

Additionally, secondary alteration of the Mission Canyon Formation associated with burial and

recrystallization (Smith and Dorobek 1993) may also have affected XRD parameters, however,

precipitation of secondary dolomite, one potential cause of the unexpected order, can be ruled

out since it should result in peak profiles more similar to those of the standard.

Hydrothermal and secondary alteration in Sierra Madera

Hydrothermal and secondary alteration in rocks may affect XRD peak patterns due to

modification of the original rock material. Evidence of fluorite crystals occurring in some

polymict breccia outcrops (Wilshire et al. 1972) indicate hydrothermal alteration occurred as a

post-impact process at Sierra Madera. However, it is not uncommon for impact craters to

interact with the hydrosphere either as a disruption of the local water table or on a larger scale

such as an ocean basin (Osinski et al. 2001). Rocks at Sierra Madera were not deformed after the

impact event (Wilshire et al. 1972). Therefore, hydrothermal alteration that occurred at Sierra

77

Madera was directly related to the impact event and not due to a subsequent deformational

process.

Shock pressures and XRD broadening

Using the shock classification scheme for impact metamorphosed sandstones developed

by Kieffer (1971) and modified by Osinski (2007), we can assign shock pressure values to

CaCO3 cemented sandstones at Sierra Madera and apply those values to the adjacent carbonate

units.

Impact metamorphosed sandstones at Sierra Madera give a shock pressure range from

5.5-20 GPa based on the presence of “toasted” quartz, a “jigsaw”, interlocking texture between

quartz grains, and multiple sets of planar deformation features (PDFs) within quartz grains. The

presence of shatter cones in porous sandstone indicates a shock pressure range of 3-10 GPa

(Osinski 2007). Since well developed shatter cones in porous sandstone will not form above

shock pressures of 10 GPa, most likely the rocks at Sierra Madera were not exposed to shock

pressures as great as 20 GPa. This shock pressure range corresponds to a post-shock temperature

range of 350->1000° C (Osinski 2007).

Sandstone beds within the Gilliam Limestone have the greatest amount of deformational

features and therefore, one would assume XRD peak patterns from the adjacent limestone would

be the broadest of all Sierra Madera samples. However, the broadest XRD peak patterns come

from the Hess Formation located within the center of the central uplift (Fig. 3). While the

adjacent quartz-rich Cathedral Mountain Formation and sandstone beds within the Word

Formation contain shock features (multiple sets of PDFs and the generation of quartz

microbreccia), these units are matrix-supported, not grain-supported like the sandstone beds

78

within the Gilliam Limestone. Without the interaction between quartz grains, higher shock

pressure indicators, such as symplectic regions between grains, are not present within the

Cathedral Mountain Formation and Word Formation. Therefore, shock features within these two

quartz-rich units do not accurately indicate the highest shock pressures to which these rocks or

the adjacent limestones were exposed. Nevertheless, the presence of shatter cones within the

Hess, Cathedral Mountain, and Word Formations indicate rocks from the central uplift of Sierra

Madera were exposed to shock pressures in the range of 3-10 GPa, however the actual pressure

range of formation is probably narrower (Osinski 2007; French 1998; Baratoux and Melosh

2003; Wieland et al 2006).

Conclusions

Rietveld refined parameters (especially XRD peak FWHM) potentially can be used to

distinguish impact-shocked rocks from unshocked equivalent rocks from outside the crater.

However, this study suggests that when comparing shocked rocks to those exposed to mild

tectonic deformation, shock pressures must reach at least 5.5 to 20 GPa to make this distinction

since only samples from the central uplift of Sierra Madera have significantly higher FWHM

values (peak broadening) than the tectonically deformed Mission Canyon Formation samples.

Similarly, it is not known how a sample exposed to intense tectonic deformation compares to a

shocked sample. The Mission Canyon Formation was never exposed to intense forces associated

with direct convergent boundary contact. Instead the formation was only associated with the

distal edge of two orogenies, the Sevier and Laramide. If the XRD patterns of less intensely

deformed Mission Canyon Formation calcites and dolomites are indistinguishable from those

exposed to lower shock levels along the crater rim of Sierra Madera, it is conceivable that

79

minerals severely deformed by tectonic processes will also be indistinguishable from higher

shocked rocks from the central uplift of an impact crater. Therefore, a study of more highly

shocked rocks from a different impact structure and similar rock types from a more intense

tectonic setting should be carried out to further determine the usefulness of Rietveld analysis and

x-ray diffraction as a tool for the characterization of impact deformed rocks.

Acknowledgements:

The authors would like to thank David Katz of the University of Miami for providing

Mission Canyon Formation samples and James Donnelly at the Austin Core Facility in Austin

Texas for allowing SAH access to collect unshocked carbonate samples from cores located north

of Sierra Madera. Additional thanks goes to Glenn Lang and the Lyda Family who provided

access to the Sierra Madera impact structure. This manuscript benefited from constructive

reviews by E. Buchner, R. Skála, P. Buchanan and W.U. Riemold. This work was supported by

NASA Grant NNX06AE69G and funding provided by the Barringer Crater Company.

80

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zircon as an indicator of peak impact pressures from the Sierra Madera impact crater,

West Texas (abstract #2048). 36th Lunar and Planetary Science Conference. CD-ROM.

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87

CHAPTER FOUR

FISSION TRACK AGE FOR THE SIERRA MADERA IMPACT STRUCTURE

Abstract

Samples for fission track analysis were collected from the central uplift of the Sierra

Madera impact crater. Apatite mineral grains were separated from three sets of samples: 1)

weakly deformed sandstone adjacent to polymict, impact-generated breccia, 2) sand-rich

polymict breccia and sandstone clasts from polymict breccia, and 3) shatter cones formed in

sandstone. Including poorly constrained samples, those with less than 10 apatite grains analyzed

in the separate, the fission track age ranges from 157 +/- 8 to 26.3 +/- 8.9 Ma. Well constrained

apatite fission track ages, those with 10 or more apatite grains in the separate, range from 147 +/-

11 to 106 +/- 10 Ma. Most of the youngest well constrained ages are older than the estimated

maximum crater age based on regional stratigraphy (Late Cretaceous to Early Tertiary for the

deposition and partial consolidation of the Lower Washita Group) indicating these grains were

not completely reset during the impact event. One age might match the maximum crater age

(sample PgssG3 with an age of 106 +/- 10 Ma), however, it does not correspond to recent

paleomagnetic ages determined for Sierra Madera of 70 to 50 Ma (Dennie et al., 2007). Due to

the eroded nature of the crater, it is possible that most of the mineral grains with completely reset

isotopic values were removed by erosion. However, the presence of possible devitrified silica

glass as clasts within polymict impact generated breccia indicates some breccia outcrops likely

reached the conditions necessary for resetting isotopic values within apatite mineral grains.

Sampling of glass-rich polymict breccia outcrops for apatite may yet yield the correct fission

track age for the Sierra Madera impact structure.

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Introduction

Age determination of impact cratering events is essential for understanding impact flux

over time, extinction events, and effects on global climate (Rampino and Haggerty, 1994). One

technique, the fission track method, is well-known for dating impact craters (Wagner and Van

Den Haute, 1992). Fission track dating requires temperatures of at least 80°C in apatite for track

annealing and the resetting of isotopic ratios (Deutsch and Schärer, 1994). Additionally, shock

pressures of ~2 to 10 GPa erased most fission tracks in apatite from the Hardhat and Sedan

nuclear detention localities and pressures over 40 GPa erase all tracks (Fleischer et al., 1974).

These temperatures and pressures are easily produced during an impact event. At Marquez

Dome impact structure, Texas, fission track analysis of apatite from sand-rich breccia dikes

produced an age of 58 +/- 2 Ma (McHone and Sorkhabi, 1994). Likewise, apatite fission track

analyses of fallback suevite at the Ries crater produced an age of 14.7 +/- 0.4 Ma (Wagner and

Van den haute, 1992). As a low temperature technique, apatite fission track dating is an

advantageous dating method for crater studies where smaller impact structures lack evidence of

high temperature deformational features such as melt glass.

The relative age of the Sierra Madera impact crater from stratigraphic and structural

relationships is between 100-2 Ma (Wilshire et al., 1972). Recent paleomagnetic studies narrow

the age of this impact event to ~70-50 Ma (Dennie et al., 2007). Deformational features (i.e.

shattercones and PDFs in quartz grains) at the Sierra Madera crater indicate post-impact

temperatures ranged from 100°C to at least 150°C (Wilshire et al., 1972). Additionally, the

structure was not deformed by a thermal event subsequent to its formation (Wilshire et al., 1972).

Therefore, low-temperature (<125°C) dating techniques are ideal for studying the timing of this

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impact event. This study uses fission track analysis of apatite mineral grains to determine a

radiometric age for the Sierra Madera impact crater.

Geologic Setting

The Sierra Madera impact structure, 12 km diameter in west Texas is a well-exposed,

eroded remnant of a complex impact crater (Eggleton and Shoemaker, 1961; Wilshire and

Howard, 1968; Howard et al., 1972; Wilshire et al., 1972). The central uplift of Sierra Madera is

composed of steeply dipping and folded Upper Permian strata (Figure 4.1). Lower Cretaceous

rocks outcrop along the eastern margin of the central uplift. The Permian Hess Formation, the

oldest stratigraphic unit exposed in the central uplift, was displaced vertically at least 790 m

during the excavation and modification stage of crater development (Wilshire et al., 1972). The

crater rim at Sierra Madera is composed of Lower Cretaceous carbonate and siliciclastic rocks

that commonly are eroded. On the southwest side of the rim, Upper Permian rocks are exposed.

Cretaceous strata are ~30-60 m above the alluvium-filled ring depression. Strata on the rim

generally dip 0-5° radially though at some locations dip can be as great as 30°. Erosion removed

an estimated 610 m of material on the crater rim eliminating the overturned flap of strata

characteristic in younger crater rims (i.e., Meteor Crater, AZ; Wilshire et al., 1972). Past studies

at Sierra Madera documented shock deformation features such as shattercones in siltstones and

fine-grained sandstones, planar deformation features (PDFs) in quartz, grain fracturing, breccias,

and deformed quartz and carbonate minerals (Dietz, 1960; Eggleton and Shoemaker, 1961;

Howard and Offield, 1968; Wilshire et al., 1972; Chapter 2 of this thesis).

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Figure 4.1. Geologic map of the central uplift of the Sierra Madera impact structure (modified from

Wilshire et al. (1972)). 1 = PgA, 2 =PcmF, 3 = PgssK, 4 = PwssG, 5 = KbB, 6 = KbC, 7 = KbE, 8 =

Pg W1, 9 = Hp mb A3, 10 = Mb E3, 11 = Pwss D3, 12 = Ph dike E1, 13 = MbRR, 14 = Pgss K, 15 =

PgssG3. Circles indicate weakly deformed sandstone samples. Squares indicate sandstone clasts

sampled from within polymict breccia. Triangles indicate shatter cones in sandstone.

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Methods

Apatite grains for fission track analysis were separated by crushing, sieving, magnetic

and heavy liquid methods using techniques described in Appendix 1 of Donelick et al. (2005).

Samples were irradiated at Washington State University’s Triga Reactor. Fission track analyses

were measured at Apatite to Zircon, Inc. in Potlatch, Idaho. Samples were described using

petrographic thin sections.

Sample description

The central uplift of the Sierra Madera impact crater contains the most intensely

deformed rocks in this structure and therefore apatite with the greatest probability of having reset

isotopic values in this area (Wilshire et al., 1972; Huson et al., 2007). Samples for apatite fission

track analysis were collected from: 1) sandstone with weakly developed deformational features,

2) sandstone clasts in polymict breccia, and 3) shatter cones in sandstone.

The first group of samples was collected from sandstone with weakly developed

deformational textures such as long contacts between grains and sutured quartz grains in thin

section. Planar deformation features, distinctive parallel planar regions, occur in two of the

seven sandstone samples (PcmF and PwssG).

The second group of samples consist of sand-rich polymict breccia and sandstone clasts

within polymict breccia. In thin section, the breccia contained evidence of possible silica

glass clasts (Huson et al., 2007) and planar deformation features (PDFs) in quartz grains.

The third group consisted of shatter cones in the Gilliam Sandstone. Shatter cones are

unique impact-produced fracture surfaces characterized by diverging striations from cone apex to

base (Figure 4.2). Shock intensities needed to create well developed shatter cones in a porous

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Figure 4.2. Shatter cone from the Gilliam Limestone at the Sierra Madera impact crater.

93

sandstone range from 3- ~10 GPa (Osinski, 2007). Quartz grains within the sandstone are less

than 0.1 mm in size, highly fractured and closely packed with a jigsaw texture. Planar

deformational features (PDFs) were identified in less than 15% of the quartz grains.

Results

Of the fifteen samples analyzed, eight are poorly constrained with samples bearing less

than 10 apatite grains (Table 4.1). Seven remaining apatite separates collected from sandstone

adjacent to polymict breccia, sand-rich polymict breccia, and shatter cones in sandstone yield

ages ranging from 147 +/- 11 to 106 +/- 10 Ma. Sand-rich polymict breccia samples yielded

ages of 26.3 +/- 8.9 to 157 +/- 8 Ma. The youngest ages in this sample set are poorly constrained

with samples providing less than 10 grains per sample. Sandstone adjacent to polymict breccia

samples yielded ages of 34.0 +/- 19.8 to 147 +/- 11 Ma with the youngest ages poorly

constrained. Apatite separates from shatter cones in sandstone contain the youngest well-

constrained ages, 106 +/- 10 and 123 +/- 9 Ma.

Discussion

All samples from the Sierra Madera impact structure analyzed in this study indicate

fission tracks within apatite mineral grains were partially reset. All Permian age target rocks

yield Late Jurassic to Early Cretaceous fission track ages. The oldest ages come from samples of

sandstone adjacent to polymict breccia and sand-rich polymict breccia, whereas shatter cone

samples yielded the youngest ages. The range for all well constrained samples is 147 +/- 11 to

106 +/- 10 Ma. The youngest well constrained ages agree with the Late Cretaceous estimated

maximum age of the crater (Figure 4.3, sample PgssG3; Wilshire et al., 1972). Noticeably, well

94

Sample Description Original Age of Apatite Apatite Fission Name Host Rocks Grains Track Age (Ma) Sandstone adjacent to Polymict Breccia PgA Gilliam SS Permian 37 139.0 +/- 7 PcmF Cathedral Mtn Permian 6 128.0 +/- 25 PgssK Gilliam SS Permian 15 147.0 +/- 11 PwssG Word SS Permian 4 83.0 +/- 13.9 KbB Maxon SS Cretaceous 1 71.0 +/- 20.7 KbC Maxon SS Cretaceous 1 34.0 +/- 19.8 KbE Maxon SS Cretaceous NA NA Sand-rich Polymict Breccia PgW1 Gilliam SS Permian 36 157 +/- 8 HP MB A3 Polymict breccia with Permian 3 26.3 +/- 8.9 Cath. Mtn clasts MBE3 Sand-rich polymict Permian 9 56.7 +/- 11.3 Breccia PwssD3 Sand-rich polymict Permian 12 132 +/- 12 Breccia Ph dike E1 Hess injection dike Permian 2 68.6 +/- 26.0 MBRR Polymict breccia Permian 25 140.0 +/- 9 Shatter cones in Sandstone PgssF3 Gilliam SS Permian 31 123 +/- 9 PgssG3 Gilliam SS Permian 17 106 +/- 10

Table 4.1. Fission track data.

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Figure 4.3. Age comparison diagram. Comparison of fission track ages from this study with

the paleomagnetic age of Dennie (2007) and the stratigraphic and structural ages of Wilshire

et al. (1972). Fission track ages are represented by a small filled circle with error bars. Gray

circles with error bars represent samples with less than 10 apatite grains. An “X” indicates

the depositional ages for each sample. Question marks indicate an unknown depositional age

for a sample.

96

constrained fission track results from this study are not comparable with the recent

paleomagnetic age range of 50 to 70 Ma (Dennie et al., 2007). One conclusion is that the

majority of high pressure and high temperature deformational features and samples ideal for

apatite fission track dating were removed from Sierra Madera due to the deep erosional level of

the structure (Figure 4.4). Wilshire et al (1972) estimated 610 m of overlying material was

removed from Sierra Madera by comparing deformational features within the crater to a range of

eroded natural craters and experimental nuclear craters. Therefore, fission dating of mineral

grains from such a well-eroded impact structure may not yield the correct age for the impact

event.

Alternatively, the shock pressure and temperature conditions may not be evenly

distributed at Sierra Madera (see Chapter 2). Sandstone units at Sierra Madera have a range of

deformational features that do not increase towards the center of the central uplift or towards the

region of expected highest shock. For example, the Cathedral Mountain Formation contains

fewer deformational features than the sandstone from the Gilliam Limestone even though it is

more centrally located in the central uplift. Uneven shock distribution can lead to the sampling

of units that were not exposed to the highest shock conditions, resulting in incorrect fission track

ages for the impact event.

Temperatures of at least 80°C are required for fission-track annealing in apatite (Deutsch

and Schärer, 1994). At Sierra Madera some polymict breccia samples contain possible

devitrified silica melt glass. Quartz is stable at atmospheric pressures up to 870°C (Deer et al.,

1999). The presence of melted sandstone clasts and possible devitrified silica melt glass within

some polymict breccia outcrops may indicate temperatures within the breccias were locally great

enough to reset isotopic abundances within apatite mineral grains. These breccias were injected

97

Figure 4.4. Ideal complex impact crater showing impactite locations. Modified from French

(1998). Dashed line indicates current erosional surface at Sierra Madera.

98

downward into the target rocks during the impact event and might be the only remaining sites for

high temperature deformational features since the crater was eroded to a lower level. Better

sampling of sandstone clasts or sand-rich zones from known polymict breccia outcrop containing

devitrified silica melt glass may lead to the determination of a radiometric age for this structure.

Shock pressure can also erase fission tracks within apatite mineral grains (Fleischer et al.,

1974). Pressures needed to reset most apatite mineral grains of a sample range from 2-10 GPa

grains leading to partially reset ages. At 40 GPa all fission tracks in an apatite sample are erased

(Fleischer et al., 1974). Shatter cone samples from the Sierra Madera impact structure were

expected to yield ages correlating to timing of the impact event. However, shatter cones form in

a range of 3 to ~10 GPa in porous sandstone (Osinski, 2007). Therefore, apatite mineral grains

within shatter cones from Sierra Madera were likely not completely reset and samples contain a

mixture of partially reset and unaffected ages which do not reflect the age of the impact event.

The usefulness of fission track dating for smaller diameter impact craters is varied. At

the 12.7 km diameter Marquez Dome, Texas, fission track analyses of sandy breccia dikes

produced an age of 58.3 +/- 3.1 Ma and agreed well with the known stratigraphic age of 58 +/- 2

Ma (McHone and Sorkhabi, 1994). At the 13 km diameter Kentland impact crater, Indiana,

fission track analyses yielded an age of 184 +/- 13 Ma and were not comparable to the <97 +/- 10

Ma paleomagnetic age (Weber et al., 2005). Like the Sierra Madera crater both structures have

similar diameters (12-13 km) and are hosted in sedimentary rocks. Marquez Dome is hosted in

Cretaceous marls and shale whereas the Kentland structure is hosted in deformed Ordovician to

Mississippian carbonates and shale with one prominent sandstone unit (the St. Peters Sandstone;

McHone and Sorkhabi, 1994; Weber et al., 2005). In all three studies, apatites were collected

from sand-rich units. At this time it is unclear why fission track age dating methods worked at

99

Marquez Dome and not at Kentland or Sierra Madera. It is possible that both the Kentland crater

and Sierra Madera are simply too eroded to obtain accurate fission tracks ages.

Conclusions

Apatite fission track age dates analyses of samples from the central uplift of the Sierra

Madera impact crater do not document a short-lived thermal event within the known

stratigraphic age of this crater. Erosion most likely removed the majority of high pressure and

high temperature deformational features required for fission track analysis. However, the

presence of possible devitrified silica glass within some polymict breccia outcrops indicates

temperatures associated with these samples should have reset isotopic abundances within apatite

mineral grains. Re-sampling of sand-rich polymict breccias from locations known to contain

possible devitrified silica glass may provide a fission track age for Sierra Madera.

Acknowledgements

The authors would like to thank the Lyda and Lang Families for granting access to the

property for sample collection. This research was supported by NASA Grant NNX06AE69G.

Additional funding was provided by the Barringer Crater Company.

100

References

Deer, W. A., Howie, R. A., and Zussman, J., 1999, An Introduction to the Rock Forming

Minerals, 2nd ed.: John Wiley and Sons, New York, 696 p.

Dennie, D., Elmore, R. D., Huson, S. A., and Madden, M. E., 2007, Paleomagnetism of the

Sierra Madera impact structure, Texas: Geological Society of America Abstracts with

Programs, v. 39, no. 6, p. 372.

Deutsch, A. and Schärer, U., 1994, Dating terrestrial impact events: Meteoritics, v. 29, p. 301-

322.

Dietz, R. S., 1960, Meteorite impact suggested by shatter cones in rock: Science, v. 131, no.

3416, p. 1781-1784.

Donelick R. A., O’Sullivan, P. B., and Ketcham, R. A., 2005, Apatite fission track analysis, in

Low temperature thermochronology: Techniques, Interpretations, and Applications:

Reviews in Mineralogy and Geochemistry, vol. 58, p 49-94.

Eggleton, R. E. and Shoemaker, E. M., 1961, Breccia at Sierra Madera, in Short papers in the

geologic and hydrologic sciences: U.S. Geol. Survey Prof. Paper 424-D, p. D151-D153.

101

Fleischer, R. L., Woods, R. T., Hart Jr., H. R., Price, P. B., and Short N. M., 1974, Effect of

shock on fission track dating of apatite and sphene crystals from the Hardhat and Sedan

underground nuclear explosions: Journal of Geophysical Research, v. 79, no. 2, p. 339-

342.

Howard, K. A. and Offield, T. W., 1968, Shatter cones at Sierra Madera, Texas: Science, v. 162,

no. 3850, p. 261-265.

Howard, K. A., Offield, T. W., and Wilshire, H. G., 1972, Structure of Sierra Madera, Texas, as

a guide to central peaks of lunar craters: Geological Society of America Bulletin, v. 83, p.

2795-2808.

Huson S. A., Pope M. C, Foit F. F. Jr., and Watkinson A. J., 2007, Immiscibility features

between silica-rich and carbonate-rich material in breccia from the Sierra Madera Impact

Structure, 38th Lunar and Planetary Science Conference, Abstract, no. 1817.

McHone, J. F. and Sorkhabi, R. B., 1994, Apatite fission-track age of Marquez Dome impact

structure, Texas: 25th Lunar and Planetary Science Conference, Abstract, p. 881-882.

Osinski, G. R., 2007, Impact metamorphism of CaCO3-bearing sandstones at the Haughton

structure, Canada: Meteoritics and Planetary Science, v. 42, p. 1945-1960.

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Rampino M. R. and Haggerty, B. M., 1994, Extraterrestrial impact and mass extinctions of life,

in Gehrels, T., ed., Hazards due to comets and asteroids: University of Arizona Press,

Tucson, p. 827-857.

Wagner, G. and Van Den Haute, P., 1992, Fission Track Dating: Dordrecht, Kluwer Academic

Publishers, p. 217-225.

Weber, J. C., Poulos, C., Donelick, R. A., Pope, M. C., and Heller, N., 2005, The Kentland

Impact Crater, Indiana (USA): An apatite fission-track age determination attempt, in

Koeberl, C. and Henkel, H., eds, Impact Tectonics: Berlin and Heidelberg, Springer, p.

447-466.

Wilshire, H. G. and Howard, K. A., 1968, Structural pattern in central uplifts of cryptoexplosion

structures as typified by Sierra Madera: Science, v. 162, no. 3850, p. 258-261.

Wilshire, H. G., Offield, T. W., Howard, K. A., and Cummings D., 1972, Geology of the Sierra

Madera Crytoexplosion Structure, Pecos County, Texas: U.S. Geol. Survey Prof. Paper

599-H, p. 1-49.

103

CHAPTER FIVE

FIELD GUIDE TO THE SIERRA MADERA IMPACT STRUCTURE

Abstract

This document was provided as a handout for the participants of the Impact in the Field

Studies Group annual field trip in association with the Lunar and Planetary Science Conference

in 2005. The trip took two days and left from San Antonio, Texas. The trip consisted of an

overview of the crater and a detailed look of shatter cones and impact generated breccia from

within the central uplift of the structure.

104

105

Field Guide to the Sierra Madera Impact Structure

Edited by S. A. Huson1 M. C. Pope1

Written by S. A. Huson1

in association with the 37th Annual Lunar and Planetary Science Conference

Houston, Texas

March 11-12, 2006

1 Department of Geology Washington State University

Pullman, Washington 99164-2812

106

107

Contents Introduction 109 Location 110 Stratigraphy 113 Brief Geologic History 117 Past Studies 118 Current and Future Studies 119 Trip Stops and Descriptions Saturday: San Antonio to Fort Stockton to Sierra Madera 122

Stop 1: Crater Rim near Gas Plant 124 Stop 2: East side of Central Uplift 124 Shatter cones from the Central Uplift 127 Stop 2a: Solution Collapse Breccia in the Tessey Limestone 127 Stop 2b: Monomict Breccia in the Gilliam Limestone 130 Stop 2c: Deformation in sandstone of the Gilliam Limestone 130 Stop 2d: Stanley Thomas Elsinore No. 1 well derrick 130 Stop 2e: Polymict Breccia at Phillips’ Elsinore No. 1 well 132 Stop 2f: Madera Peak (time and weather permitting) 132

Sunday: Sierra Madera to Fort Stockton to San Antonio 134 Stop 3: North side of Central Uplift 134 Stop 4: North side of Crater Rim 134

References 137 Cover: Oblique angle digital aerial photograph of the Sierra Madera impact structure. View is to

the northwest. Photo credit: Tom Jones NASA Astronaut Corps.

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Introduction

Welcome to the 2006 Impact Field Studies Group field trip to the Sierra Madera impact

structure! Upon arrival to the Fort Stockton area we will spend the next 24 hours exploring the

structure. Saturday we’ll explore the east side of the central uplift with a trip to the top of

Madera Peak (elev. 1400 m). Sunday will be devoted to the north side of both the central uplift

and the crater rim.

Sierra Madera is Spanish for “wooded hills” and as you will see the central uplift of the

structure is covered with juniper trees. Sierra Madera is located in west Texas and contains

Chihuahuan Desert flora and fauna. Local vegetation consists primarily of oak, juniper, sparse

grasses, some mesquite, scrub brush, creosote bushes and several varieties of cactus. Local

fauna include rattlesnake, deer, mountain lion, javelina, jack rabbit, road runner, tarantulas, and

many bird species.

Please take care when hiking over slopes with loose rock. Make sure to carry an ample

supply of water (two or more liters each day) as the day-time high temperatures may reach 90°F

(32°C).

Thank you for your interest in Sierra Madera! Your participation will be greatly

appreciated. If you have any comments or questions, please let us know!

Sarah A. Huson, Field Trip Leader

Mark F. Thompson, IFSG Field Trip Coordinator

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Location and Background

The Sierra Madera impact structure is one of four impact structures located in Texas

(Figure 5.1). Sierra Madera is located ~20 miles south of Fort Stockton and ~30 miles north of

Marathon, Texas (Figure 5.2). Sierra Madera is 12 km in diameter and is a well-exposed

remnant of a complex impact crater. It was last studied during the late 1960’s and early 1970’s

by Wilshire et al. (1972). After the first lunar landings Sierra Madera was used as a field training

site for astronauts to see impact generated breccias and shattercones (Margolin, 2000). The

structure is one of ~60 impact craters that formed in predominately carbonate host rocks (Grieve

and Shoemaker, 1994). In addition to carbonates, Sierra Madera also includes interbedded

siliciclastic target rocks making it an ideal place to comparatively study quartz-carbonate

deformation produced during an impact event. Similarly, the size of the crater is between other

craters hosted in carbonate rocks, namely, Haughton (24 km), Ries (24 km), Steinheim (3.8 km),

and Barringer (Meteor) Crater (1.2 km). Therefore, study of the Sierra Madera crater may

provide important information for understanding the continuum of carbonate deformation

produced by meteorite impacts. Currently, the Sierra Madera structure has not been

radiometrically age dated. This is due to the lack of obvious high-temperature deformation

features such as melt rocks and glass formation. However, recent work on carbonate craters

reveals melt features from these structures may be subtle (Osinski and Spray, 2001). Based on

stratigraphic and structural relationships, the Sierra Madera impact occurred sometime during the

Late Cretaceous to Early Tertiary (Wilshire et al., 1972). The objective of this field trip is to

introduce you to the stratigraphy, structure and deformation of the Sierra Madera impact crater.

110

Figure 5.1. Location of impact craters in Texas, Bee Bluff (BB), Marquez Dome (MD),

Odessa (O), and Sierra Madera (SM). The Sierra Madera structure occurs near Fort Stockton,

Texas. Dashed box in Texas map is outline of Figure 2.

111

Figure 5.2. Location of the Sierra Madera structure near Fort Stockton, Texas.

112

Stratigraphy

The Delaware Basin of west Texas and southern New Mexico was a major marine basin

throughout the Permian (Hill, 1996). The rocks at Sierra Madera and other parts of the basin

record a gradual filling in of the basin capped by widespread evaporitic conditions by the end of

the Permian. The Triassic and Jurassic were marked by uplift and erosion and rocks of these

ages outcrop discontinuously. Triassic and Jurassic rocks have not been identified at Sierra

Madera. The Cretaceous is marked by a transgression represented by fluvial to shallow water

marine deposits.

Below is a description and stratigraphic column (Figure 5.3) of rocks outcropping within

the central uplift and along the crater rim of the Sierra Madera impact structure. Descriptions are

compiled from Wilshire et al. (1972), Hill (1996), and the author. The entire Permian section

will be seen on the first afternoon of the trip whereas Cretaceous units will be examined the

following morning.

Hess Formation – The Permian (Leonardian) Hess Formation is a 730 - 850 meters thick, fine-

grained, medium to thick bedded limestone and dolostone with interfingering sandstone,

siltstone, and shale. Sediments were deposited in a shallow water lagoon. Common fossils

include fusulinids, brachiopods, and bryozoa. There is a gradual up section decrease in clastic

material and increase in dolomite in this unit. At Sierra Madera 365 - 430 meters of Hess

Formation outcrop at the surface and the unit gradually increases in thickness to the north

(Wilshire et al., 1972).

113

Figure 5.3. Stratigraphic column of rocks that outcrop in the central uplift and crater rim of

the Sierra Madera impact structure. Column was drawn using the maximum thickness of the

unit (thickness in parentheses.)

114

Cathedral Mountain Formation – The Permian (Leonardian) Cathedral Mountain Formation is a

0-24 meter thick conglomerate containing chert and quartz pebbles in a dolomite matrix. Beds of

cross-bedded coarse, quartz sandstone occur locally within the Cathedral Mountain Formation

(Wilshire et al., 1972). This unit grades up conformably into the lower part of the Word

Formation. The depositional environment for the Cathedral Mountain Formation is debated as

being a shallow water deltaic complex (Wardlaw et al., 1990) or basinal where clastics are

derived from debris flows or turbidity currents (Ross, 1986).

Word Formation – The Permian (Early to Middle Guadalupian) Word Formation is divided into

two members: the lower Limestone Member and the upper Sandstone Member. The lowermost

member of the Word Formation is an unnamed limestone unit 0-76 meters thick (Wilshire et al.,

1972). It contains thin to thick bedded limestone, with crinoid and fusulinind fossils, and some

interbedded finely crystalline dolomite. The upper Sandstone Member of the Word Formation

(0-10 meters thick) consists of interbedded coarse grained sandstone with silicified crinoid stems

and silty to fine-grained sandstone with calcite cement. Locally this unit grades laterally to a

sandy dolomite. The depositional setting for the Word Formation is controversial and is

proposed to be basinal with turbidity currents moving clastics off the shelf (Ross, 1986) or a

shallow water lagoon (Rohr et al., 1982; Wardlaw et al., 1990).

Vidrio Formation - The Permian (Middle Guadalupian) Vidrio Formation (60-230 meters thick)

consists of thick to massively bedded dark dolomite with sparse fossils. Dolomitization has

destroyed the original fabric of the rock and many fossils. Chert nodules are common. The

115

Vidrio Formation represents initial reef development in the Delaware Basin. Reefs of the Vidrio

were early precursors to major reef building in the Late Guadalupian (Hill, 1996).

Gilliam Limestone – The Permian (Late Guadalupian) Gilliam Limestone is a 213-290 meters

thick, dolomite and calcite cemented fine-grained sandstone deposited in a lagoonal and back

reef setting (Hill, 1996). Sandstone layers in this unit pinch out laterally and are discontinuous.

This unit grades conformably into the Vidrio Limestone Member of the Word Formation.

Tessey Limestone – The Permian (Ochoan) Tessey Limestone is a 0-120 meters thick, gray

brown dolomite with sparse fossils. In some locations the unit is identified by areas of solution

collapse breccia composed of laminated small (cm-size) to large (several meter-size) fragments

of Tessey Limestone cemented mosaic-like with calcite and/or dolomite cement. Deposition

occurred in a hypersaline basin that underwent periods to subtidal to supratidal deposition and

subaerial exposure (Haneef and Wardlaw, 2000). Meteoric dissolution created karst features and

collapse breccias (Hill, 1996). These breccias occur mostly on the east side of the central uplift

(Wilshire et al., 1972).

Fredericksburg and Lower Washita Groups – The Fredericksburg Group rocks are Early

Cretaceous (Middle Comanchean) in age. They represent the youngest rocks exposed at Sierra

Madera on the crater rim. The Maxon Sandstone occurs at the base of the Fredericksburg Group

(Hill, 1996). It is a 15-30 meter thick red-brown, fine- to coarse-grained sandstone cemented

with silica cement. The Maxon Sandstone can be differentiated from other sandstone units at

Sierra Madera because of its silica cement and a thin quartz pebble layer at the base of the unit

116

(Wilshire et al., 1972). At Sierra Madera the Maxon Sandstone unconformably overlies the

Tessey Limestone. The Edwards Limestone (40-60 meters thick) is a platy light gray and brown

limestone. The Kiamichi Formation (~15 meters thick) is a thin bedded light gray limestone.

The Cretaceous (Late Comanchean) Washita Group consists of platy to massive, medium-

grained, shaly limestone. The Fredericksburg and Washita Groups represent deposition in a

fluvial/deltaic to shallow marine setting (Hill, 1996) and are not differentiated at Sierra Madera

due to poor exposures and lack of stratigraphic control.

Brief Regional Geologic History

The geologic history of the Delaware Basin region is divided into eight phases (Hill,

1996). During the Precambrian (1300-850 Ma) the Delaware Basin developed as an

intracratonic basin. Granitic basement rock was broken by high-angle faulting during the

Grenville orogeny. These faults became areas of regional weakness and were reactivated during

later deformational events. The Passive Margin Phase (850 – 310 Ma) represents a time when

the region experienced little tectonic activity. Deposition occurred in a slowly subsiding area

known as the Tobosa Basin and was characterized by epicontinental seas with periods of

subaerial exposure and karstification (Hill, 1996). During the Late Devonian the Tobosa Basin

was uplifted, tilted, and eroded. Deposition continued until the Collision Phase (310-265 Ma).

At this time, Precambrian zones of weakness were reactivated during the Marathon-Ouachita

orogeny and the Tobosa Basin was divided into the Midland and Delaware Basins separated by

the Central Basin Platform (Hill, 1996). The Permian Basin Phase (265-230 Ma) is characterized

by basin subsidence and reef growth. During the Permian the Delaware Basin rapidly subsided

and filled with carbonate material and clastics shed off highland areas including the Central

117

Basin Platform. By the middle of the Guadalupian the Midland Basin was isolated from normal

marine circulation and filled in while extensive reefs developed at the shelf margin in the

Delaware Basin as exemplified by the Capitan Formation in Guadalupe Mountains National Park

(Hill, 1996). During the Early Ochoan the Delaware Basin connection to the open ocean was

closed resulting in a decline of reef building and the end of normal marine carbonate deposition.

Ochoan age deposits are characterized by red beds, evaporites, and fossil poor limestone. The

Stable Platform Phase (230-80 Ma) was a period of tectonic stability. From the Triassic to Early

Cretaceous the area remained exposed with deposition in terrestrial environments and subsequent

erosion. During the Early Cretaceous an epicontinental sea transgressed across this area

depositing shallow marine sediments for the last time in the region. The sea remained until the

end of the Cretaceous at which time the area was affected by the Laramide orogeny. The

Laramide Phase (80-40 Ma) resulted in uplift, tilting and arching in the Delaware Basin (Hill,

1996). Volcanic Phase (40-30 Ma) marked a transition from Laramide compression to Basin and

Range extension and crustal thinning. Intrusive and extrusive volcanism occurred in the Glass

Mountains and Davis-Barilla Mountains and throughout Mexico and western New Mexico.

During the Basin and Range Phase (30-0 Ma) north-northwest trending high-angle normal block

faulting resulted in the uplift of the Guadalupe, Apache, Delaware and Glass Mountains (Hill,

1996) and created the present landscape we see today.

Past Studies

Sierra Madera was first mapped by King (1930). A meteorite impact origin was

established in 1959 with the discovery of shatter cones at the site making Sierra Madera the fifth

structure in the world where shatter cones were found (Dietz, 1960; Eggleton and Shoemaker,

118

1961). No meteoritic material has been documented at the crater. A gravity-magnetic study

revealed negative gravity and positive magnetic anomalies associated with breccia zones further

supporting the meteorite impact theory (Van Lopik and Geyer, 1963). The structure was first

considered to be the well-eroded remnant of a 3.2 km diameter simple crater. Polymict breccia

outcrops were thought to occur as a single lens-shaped mass and the structure was tentatively

compared to Meteor Crater in Arizona (Eggleton and Shoemaker, 1961). This theory was

revised with later fieldwork that concluded Sierra Madera was the eroded remnant of a complex

crater, 12 km in diameter (Wilshire et al., 1972). This study documented shock deformational

features such as impact generated breccias, shatter cones, planar deformation features (PDFs) in

quartz, grain fracturing, and deformed quartz and carbonate minerals. The study also produced a

detailed geologic map of the structure.

The Sierra Madera structure was proposed along with the Manson structure in Iowa as a

possible crater for the K-T boundary event before Chicxulub was discovered (French, 1984).

However, Sierra Madera was considered unlikely due to its relatively small size and lack of

characteristic K/T boundary clastic material (French, 1984). Recently a modeling study was

conducted to determine the pre-erosion diameter of the crater (Goldin et al., 2005).

Current and Future Research

Current research at the Sierra Madera impact structure occurs in two main areas: a

deformation study and an age determination study. We are using x-ray diffraction (XRD)

patterns of carbonate minerals to determine shock pressure values at Sierra Madera. With

increasing shock pressures XRD peak patterns of calcite should broaden and dampen (Skála and

Jakeš, 1999). Shocked carbonate samples from the Steinheim crater in Germany show a marked

119

change when compared to a calcite standard. Carbonate samples from the central uplift of Sierra

Madera show little to moderate broadening and therefore using the terminology of Skála and

Jakeš (1999), carbonate minerals from Sierra Madera are associated with low to moderate shock

values (8-30 GPa; Huson et al., 2005: Huson and Pope, 2005). We are currently working to

narrow this range by using XRD to identify high temperature polymorphs of quartz.

Deformation was also studied using several microscopy techniques (petrographic,

reflected, and scanning electron microscopy). Our goal was to identify deformation features in

order to assign an overall peak shock pressure to the impact event. Using petrographic

microscopy we documented silt-sized quartz grains with two sets of planar deformation features

(PDFs) from shatter cone samples. In polymict breccias we identified subtle flow textures in

breccia matrix, shattered rock fragments and carbonate grains with cusp-like features similar to

melt structures (Graup, 1999). Using reflected and transmitted light microscopy we studied the

fracture patterns of whole zircon grains. Zircon samples from Sierra Madera have surface

textures similar to surface textures of shocked zircons from larger impact structures (Figure 5.4).

The age of the Sierra Madera structure ranges from Late Cretaceous to Early Tertiary

based on stratigraphic and structural relationships (Wilshire and Howard, 1968, Wilshire et al.,

1972). We are using apatite fission track methods, a low-temperature age-dating technique, to

determine the age radiometrically. Low-temperature methods are being used since melt rocks

and/or high-temperature alteration products are not yet documented at Sierra Madera. Therefore,

there is no evidence for high-temperature resetting of isotope values. Currently, both dating

methods have yielded a range of Jurassic ages. We suspect these early Mesozoic ages reflect

uplift and cooling of the Paleozoic sediments during Early Mesozoic rifting of Pangea and are

currently working to resolve this problem.

120

A 4μm

B 2μm

Figure 5.4. Scanning electron micrographs of shocked zircon surface textures. A) K-T

boundary layer zircon (Bohor et al., 1993), B) Sierra Madera zircon.

121

Future research is planned for a continuation of the SEM zircon study after this season’s

fieldwork. Additional research will include studying the carbonate-silica interface from quartz

grains in shatter cones in carbonate material and polymict breccias to look for possible

immiscibility features indicating both quartz and carbonate materials were melted. This

technique was used to identify carbonate melt rocks at larger diameter craters (i.e. Haughton;

Osinski and Spray, 2001) and if evidence for melting can be established, higher temperature age

dating techniques can be used to determine the age of the impact event. Finally, a three-

dimensional subsurface study will be attempted using available well-logs in order to reconstruct

cratering induced deformation at depth.

Field Trip Stops and Descriptions

Saturday: San Antonio to Fort Stockton to Sierra Madera

From San Antonio we’ll head east on Interstate 10 towards Fort Stockton. Three major

geologic features we’ll drive over are the Balcones fault zone, Texas Hill Country, and the

Edwards Plateau. The Edwards Plateau is a region of flat-lying Cretaceous limestone uplifted

~10 Ma ago due to movement of the Balcones fault located on the eastern edge of the plateau

(Spearing, 1991). Hill Country was created due to extensive stream activity eroding into the

eastern scarp of the Edwards Plateau. The Balcones fault zone is located just west of San

Antonio, Hill Country extends from San Antonio to Kerrville and the Edwards Plateau stretches

from Kerrville to Fort Stockton. Fort Stockton is located in a flat gravelly area known as the

Stockton Plateau (Spearing, 1991). Fort Stockton is also the home of the world’s largest

concrete road runner, Paisano Pete (Figure 5.5).

122

Figure 5.5. World’s largest roadrunner, Paisano Pete, Fort Stockton, TX.

123

Hill Country and the eastern side of the Edwards Plateau contain a number of caves

collectively called the Texas Caverns. These caves formed from groundwater dissolution of

lower Cretaceous limestone (Spearing, 1991).

As we drive west, the overall shape of mesas forming the eroded eastern edge of the

Edwards Plateau will differ from western edge mesas. Due to higher amounts of rainfall in east

Texas, mesas in the east have rounded edges whereas in drier west Texas they have sharper

edges (Spearing, 1991).

Stop 1: Crater Rim near Gas Plant. Since we are going to be on private property permission

to enter the property for any trip must be obtained from the land owner.

The trip starts on the northwest part of the crater rim (Figure 5.6). From here facing

southeast there is a good view of the subtle crater rim of horizontal to gently dipping, Lower

Cretaceous carbonates and sandstone on your left, the alluvium covered ring depression in the

mid-ground, and the peaks of the central uplift of Sierra Madera in the background. This is a

great location for photos of the entire central uplift (Figure 5.7).

Stop 2: East side of Central Uplift

We will enter the property on the north side of the ring depression and drive on ranch

roads to the first outcrop stop (Figure 5.8). At this stop we will walk though all Permian strata

outcropping at Sierra Madera. Also, we will see all three main breccia types that occur at Sierra

Madera; the Tessey solution collapse breccia, impact-generated monomict breccia and impact-

generated polymict breccia.

124

Figure 5.6. Geologic map of the Sierra Madera impact structure and location map for the field trip. Numbers

and dashed lines indicate trip stops. Dashed-dotted line marks limit of abundant shatter cones. Modified from

Wilshire et al. (1972).

2

4

3

1

125

Figure 5.7. Sierra Madera impact crater. View is looking southeast towards the central

uplift. Picture taken from the crater rim near the gas plant.

2f

2e 2d

2b2a

2c

1 km

Figure 5.8. Site locations for Stop 2. Dashed line is approximate limit of abundant shatter

cones. For a description of symbols see Figure 5.6.

126

Shatter cones from the Central Uplift

Shatter cones were discovered at Sierra Madera in 1959 (Dietz, 1960 and Kelly, 1966).

They occur in abundance within a 2 km radius from the center of the central uplift (Figure 5.6;

Howard and Offield, 1968; Wilshire et al, 1972). Shatter cones occur in every formation that

outcrops at the surface at Sierra Madera; however, they may occur in a certain formation at one

location but may not be present in the same formation at a different location. Cone fragments are

also reported at a depth of ~3657 m beneath the central uplift (Howard and Offield, 1968;

Wilshire et al., 1972). Cone sizes range from 1 cm to ~ 45 cm (Wilshire et al., 1972).

Shatter cones occur as overlapping “shingles” and as whole cones (Figure 5.9). Small

shatter cones (cm-sized) commonly occur within the Gilliam Limestone. When weathered these

blocks of limestone sometimes have a fractured appearance (Figure 5.10) however when broken

they contain many small cones. The karst originates from weathering along shatter cone planes.

We will see shatter cones throughout Stops 2 and 3.

Stop 2a: Solution Collapse Breccia in the Tessey Limestone.

Collapse breccia in the Tessey is one of three breccia types at Sierra Madera. At Sierra

Madera and other locations in the Delaware Basin the Tessey is brecciated due to the dissolution

of evaporites and collapse of small caves during the Latest Permian (Figure 5.11). Collapse

breccia is characterized by irregular and angular clasts of Tessey Limestone cemented together

with calcite and/or dolomite. This breccia is distinctly different from impact-generated

monomict breccias at Sierra Madera in that the cementing calcite or dolomite is coarse and

visibly different from the Tessey clasts. Also, bedding is not preserved. Collapse breccias in the

Tessey are common in other areas of the Delaware Basin.

127

A

B

A

B

Figure 5.9. A) Overlapping shatter cones from the Gilliam Formation. Scale is in

centimeters. Photo by M. Pope. B) Shatter cone from the Upper Hess Formation. Lens cap

is ~5 cm.

128

Figure 5.10. Weathered out block of Gilliam Limestone with a fractured appearance. If

broken with a hammer small centimeter-sized shatter cones parallel fractures. Lens cap is ~5

cm.

Figure 5.11. Solution collapse breccia in the Tessey Limestone. Angular clasts of Tessey

Limestone cemented mosaic-like with coarse calcite. Lens cap is ~5 cm.

129

Stop 2b: Monomict Breccia in the Gilliam Limestone.

Monomict breccia at Sierra Madera formed when shock waves generated by the impact

shattered pre-existing target rock. At most locations breccias show little clast rotation (Figure

5.12). They occur in most Permian carbonate formations and the Lower Cretaceous Maxon

Sandstone. Thin section analyses of carbonate monomict breccia reveal clasts intensely

shattered and invaded by thin veinlets of mylonite (Wilshire et al., 1972). Characteristics to

identify monomict breccias from Tessey solution collapse breccias are a lack of visible cement

and in most cases original bedding is preserved. However, since both breccia types may look

similar identification may be problematic in the Tessey Formation.

Stop 2c: Deformation in sandstone of the Gilliam Limestone.

Impact-induced folding and faulting can easily be seen by tracing sandstone units of the

Gilliam Limestone. These units contain fine-grained, angular quartz cemented by calcite.

Where blocks are incorporated as clasts in polymict breccia quartz grains commonly contain

PDFs. The first part of this stop is at an outcrop of a sandstone containing slickensides formed

from movement on an impact-generated fault (Figure 5.13). The second part of the stop is a

different sandstone outcrop in the Gilliam Limestone. Here, the contact between sandstone and

the overlying carbonate unit is irregular and the sandstone has several carbonate clasts

incorporated into it.

Stop 2d: Stanley Thomas Elsinore No. 1 well derrick.

Sierra Madera is located within an actively producing gas field. Two exploration wells

were drilled in the central uplift in 1921, the Stanley Thomas Elsinore No. 1 (total depth

130

Figure 5.12. Monomict breccia in the Gilliam Limestone. Scale bar is in centimeters. Photo

by M. Pope.

Figure 5.13. Slickensides in a sandstone unit of the Gilliam Limestone. Pencil points north,

the direction of fault movement. Pencil is ~15 cm.

131

2,238 m) and Phillips’ Elsinore No. 1 (total depth 3,687 m; Wilshire et al., 1972; Constant,

1978). The Stanley Thomas Elsinore No. 1 well blew out and was abandoned in 1940. Drilling

in other locations on the crater resumed in 1977 and continues to the present (Constant, 1978;

Donofrio, 1998).

Stop 2e: Polymict Breccia at Phillips’ Elsinore No. 1 well.

Impact generated polymict breccia outcrops in all formations in the central uplift of

Sierra Madera. Outcrops may or may not be associated with faults and occur parallel or

perpendicular to bedding. The configuration of breccia in the subsurface is not well understood.

For example, are outcrops connected by a network of pipes or is each outcrop a single

occurrence of breccia?

Polymict breccia at Sierra Madera contains clasts derived from all rocks exposed at the

surface of the structure in a tan to reddish matrix (Figure 5.14). Depending on the location of the

breccia, one outcrop may be enriched with a particular formation when compared to other

breccia outcrops. Breccia at this location commonly contains chert clasts possibly derived from

the Vidrio Formation and Gilliam sandstone clasts. Shatter cones are present in limestone clasts.

In some cases shatter cones appear to have formed in breccia matrix but they may be part of a

large carbonate block with similar characteristics as the matrix. Other features from this outcrop

include visibly deformed claystone clasts and in some areas a vesicular-like texture.

Stop 2f: Madera Peak.

The highest point of the central uplift is Madera Peak, elevation 1400 m. This stop is

optional due to time restrictions. It takes about 2 hours to hike to the top and back to the vans.

132

Figure 5.14. Polymict breccia outcrop. Notice yellowish color of matrix. Arrow points to

large sandstone clast.

133

There is a spectacular view from Madera Peak to the Glass Mountains in the southwest and the

Davis-Barilla Mountains to the west. This stop will be contingent on time and weather

conditions.

Sunday: Sierra Madera to Fort Stockton to San Antonio

Stop 3: North side of Central Uplift

Today we will revisit the central uplift and explore another polymict breccia outcrop

(Figure 5.15). This is the largest polymict breccia outcrop at Sierra Madera. Characteristics of

this outcrop are similar to the polymict breccia of Stop 2e. The matrix is tan, fine-grained

carbonate material clasts are derived from local formations, and some carbonate clasts contain

shatter cones. There are also several important differences between the breccia of this stop and

the breccia from Stop 2e. At this outcrop there is a greater occurrence of Gilliam Limestone

clasts and not as much Vidrio derived chert. Also missing is the vesicular-like texture and areas

of reddish colored matrix.

Stop 4: North side of Crater Rim

The crater rim at Sierra Madera is well-eroded and composed of limestone and sandstone

of the Lower Cretaceous Fredericksburg and Washita Groups (Figure 5.6). Cretaceous strata are

~30-60 m above the alluvium-filled ring depression. Strata on the crater rim generally dip 0-5

degrees though at some locations dip can be as great as 30 degrees (Figure 5.16). At this stop

Lower Cretaceous carbonate rocks dip ~10 degrees north. Overturned strata common on

younger impact crater rims, does not occur at Sierra Madera. Long terrestrial exposure and

relatively low deposition rates in this area of West Texas are two factors why this feature is not

134

3

2e

1 km

Figure 5.15. Site location for Stop 3. Dashed line marks approximate limit of abundant

shatter cones. For a description of symbols see Figure 5.6.

Figure 5.16. Gently dipping Lower Cretaceous rocks exposed on the north crater rim of

Sierra Madera. Field book for scale (see circle).

135

preserved. Comparison with other craters suggests ~600 m of material was eroded from Sierra

Madera (Wilshire et al., 1972).

136

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Donofrio, R.R., 1998, North American impact structures hold giant field potential: Oil and Gas

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137

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138

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139

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599-H, p. 1-49.

140

Notes

141

142

Notes

APPENDIX A X-ray analysis data for Sierra Madera and Mission Canyon Fm calcite samples.

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

15 129 174 129 174 137 156 184 114 166 14515.02 142 177 129 158 142 156 161 107 141 13415.04 161 184 130 164 153 150 147 115 181 13415.06 147 162 134 150 137 173 193 113 156 12415.08 145 190 132 148 146 156 148 114 170 13915.1 126 164 136 171 161 174 163 134 164 129

15.12 133 173 135 145 167 148 154 135 209 12515.14 133 159 149 143 154 160 163 119 179 14215.16 129 162 139 156 177 138 173 124 177 16615.18 145 178 117 164 179 177 159 119 186 12915.2 142 168 145 172 167 190 158 125 210 123

15.22 140 161 132 175 163 173 170 136 167 14015.24 135 180 136 159 156 165 138 123 192 11915.26 140 159 130 162 128 147 164 106 180 13715.28 122 169 133 157 168 146 169 127 160 12315.3 142 201 138 144 164 174 176 112 174 126

15.32 141 156 155 173 152 168 148 106 157 14315.34 135 189 131 173 164 158 156 92 168 11115.36 143 173 134 169 164 162 197 107 158 14215.38 152 170 134 155 169 162 181 122 160 13615.4 135 160 130 165 162 154 171 129 186 131

15.42 120 172 154 151 163 160 185 98 158 15015.44 134 164 141 154 164 159 165 94 183 14515.46 125 177 129 178 164 169 178 118 156 12515.48 131 155 143 141 173 151 184 109 192 14415.5 155 154 111 179 165 156 177 115 177 121

15.52 154 175 125 158 163 177 158 108 185 11715.54 140 179 138 165 179 194 138 100 143 14615.56 141 164 139 172 163 156 151 100 172 11515.58 130 191 129 166 143 174 173 102 177 13815.6 135 181 129 161 174 177 161 103 162 123

15.62 129 183 129 156 167 173 162 134 197 12115.64 131 191 163 174 158 152 172 102 177 13515.66 131 189 122 163 192 178 194 124 196 14015.68 140 174 137 160 169 170 156 107 166 15015.7 156 163 154 157 176 159 163 103 192 153

15.72 135 175 158 173 175 170 160 122 154 14515.74 141 207 138 152 164 163 158 120 163 11915.76 143 169 129 195 150 146 185 115 193 14415.78 156 181 137 167 163 156 157 116 181 131

144

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

15.8 134 175 140 167 163 163 167 99 187 14315.82 134 172 144 163 143 177 159 93 157 14115.84 144 184 157 162 169 192 174 102 156 15515.86 134 165 141 175 144 164 158 102 179 13715.88 135 194 147 177 158 171 187 104 138 15315.9 144 195 152 155 185 162 164 103 194 139

15.92 116 182 152 167 163 163 165 102 177 14715.94 132 163 155 185 163 181 181 102 167 14315.96 139 163 127 157 157 174 180 111 190 14915.98 157 168 150 171 168 184 153 99 197 141

16 144 183 132 171 147 178 166 99 168 12316.02 135 192 147 188 170 155 169 101 191 14216.04 146 177 111 167 185 191 179 103 189 14316.06 114 201 139 171 155 191 172 109 179 15016.08 135 207 132 192 162 174 180 89 173 13916.1 143 182 132 170 173 148 186 88 168 124

16.12 138 189 130 152 186 174 178 102 180 13016.14 136 176 137 170 160 190 163 108 207 14016.16 162 229 136 179 175 162 175 109 135 14816.18 121 193 142 163 170 170 190 98 170 15016.2 124 206 156 175 189 146 173 95 182 135

16.22 123 179 146 152 169 189 161 96 193 15716.24 127 190 167 170 168 150 202 108 178 13216.26 153 181 121 155 165 183 153 116 157 13216.28 149 178 155 178 167 180 177 128 182 12816.3 126 195 130 160 151 194 196 88 187 156

16.32 146 190 124 173 157 181 173 108 155 15016.34 123 212 145 167 162 187 162 88 189 15216.36 149 176 133 177 166 179 206 106 195 13916.38 137 183 152 162 181 165 189 83 178 15316.4 142 182 134 168 188 210 157 105 188 132

16.42 170 182 150 165 142 179 171 94 197 13316.44 149 180 145 174 173 177 184 104 182 15016.46 135 178 138 194 168 190 180 104 177 15216.48 147 183 128 213 175 179 181 106 177 13316.5 150 178 138 190 199 156 180 107 174 141

16.52 153 174 143 213 157 168 173 103 168 14416.54 150 181 143 167 170 190 178 102 166 13016.56 134 205 148 179 195 188 159 100 182 12716.58 148 169 135 160 167 161 177 114 172 136

145

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

16.6 136 180 147 174 178 169 182 104 177 13816.62 132 180 141 186 181 177 186 112 174 13016.64 148 216 141 199 183 206 190 79 178 12816.66 140 188 146 196 162 162 229 93 215 12516.68 149 193 150 178 197 172 191 112 181 15216.7 143 194 136 180 180 186 187 106 179 151

16.72 160 202 138 190 184 206 196 84 167 14416.74 156 197 144 195 188 191 182 106 186 16216.76 134 189 124 162 186 182 181 114 189 13316.78 149 195 142 163 198 186 184 111 164 15216.8 147 193 128 179 170 178 184 94 192 121

16.82 139 182 136 177 205 181 198 124 186 13516.84 135 192 161 165 159 181 181 96 194 14816.86 148 191 132 201 170 182 158 105 181 14216.88 145 175 128 167 185 170 185 104 186 11116.9 130 198 137 196 158 160 195 100 206 146

16.92 143 202 155 169 195 190 181 106 169 15216.94 137 228 153 169 172 170 219 109 191 15916.96 145 208 151 209 160 190 188 95 164 11416.98 121 225 185 172 178 183 188 89 181 147

17 135 207 128 193 173 172 173 105 182 12817.02 145 223 143 162 190 175 194 81 157 14817.04 141 218 157 181 168 178 178 93 190 16617.06 120 207 126 192 198 181 203 99 195 17317.08 132 161 136 165 197 176 201 96 167 15317.1 134 183 144 193 178 195 195 119 172 163

17.12 150 215 157 175 173 186 169 95 193 14217.14 149 215 141 153 188 204 174 118 163 16817.16 142 171 177 187 167 160 190 109 186 14917.18 152 198 148 184 170 191 191 131 175 14617.2 147 199 161 191 183 171 187 98 173 126

17.22 130 210 164 185 160 191 211 97 198 15717.24 143 207 151 186 187 182 190 112 179 14117.26 146 186 163 175 176 193 200 105 208 14217.28 148 188 125 206 194 204 205 116 180 13717.3 140 188 154 199 199 173 200 104 205 137

17.32 148 188 143 207 180 190 177 105 195 15417.34 144 169 151 184 191 185 196 98 177 13817.36 134 192 149 193 201 173 200 96 196 13317.38 152 196 141 195 188 193 164 82 181 158

146

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

17.4 131 188 173 162 190 182 189 102 176 14117.42 158 224 151 188 182 191 192 96 175 13817.44 127 208 153 187 182 203 202 113 190 16217.46 122 201 153 192 196 177 180 92 194 15817.48 132 216 148 190 168 196 198 116 178 15917.5 135 200 134 161 178 189 197 119 198 148

17.52 143 183 156 202 180 215 180 98 163 14717.54 153 206 164 168 186 189 188 81 195 14917.56 162 206 150 195 201 218 189 107 192 15717.58 160 210 136 175 184 165 170 113 213 14917.6 143 227 142 180 194 219 182 102 178 143

17.62 150 172 137 190 170 184 219 104 207 13917.64 136 222 151 169 208 193 220 84 206 14717.66 144 214 151 213 171 212 199 102 192 16517.68 143 205 153 207 194 167 208 113 191 16317.7 144 218 162 187 179 171 182 104 204 125

17.72 155 222 160 189 195 189 183 123 223 14817.74 142 207 167 152 189 198 195 98 180 15517.76 149 188 146 201 199 194 192 113 196 13717.78 124 211 151 190 191 179 195 103 199 14617.8 135 207 130 168 202 163 195 109 224 145

17.82 157 208 147 211 186 207 192 93 184 16717.84 130 192 165 188 185 201 195 100 193 14217.86 130 215 148 203 216 201 180 87 200 14117.88 147 241 130 201 191 206 208 100 196 16317.9 145 196 145 175 184 204 211 103 195 133

17.92 121 207 173 209 189 193 198 104 190 15217.94 131 229 157 181 198 182 193 100 184 15417.96 147 205 131 189 192 183 215 101 188 15217.98 137 192 146 181 166 199 178 103 200 151

18 128 224 156 178 198 211 183 82 171 15118.02 150 199 160 194 187 217 210 106 191 14818.04 128 213 164 181 203 190 197 112 169 16118.06 148 210 148 166 233 199 196 98 170 14218.08 153 209 165 166 181 189 194 116 200 16318.1 152 212 153 185 217 185 201 108 176 140

18.12 127 197 135 206 198 186 188 99 177 14018.14 131 181 154 176 152 199 190 103 224 13318.16 137 227 141 196 193 187 208 112 189 14318.18 136 229 129 182 191 188 173 97 199 156

147

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

18.2 159 204 151 198 171 172 194 102 221 17918.22 143 198 144 195 181 190 154 109 189 13318.24 154 205 140 177 198 168 204 104 185 16218.26 147 215 155 191 183 172 206 117 187 11918.28 155 216 138 171 173 202 189 105 184 14818.3 142 197 143 198 163 201 200 92 189 149

18.32 134 183 155 199 178 192 208 94 199 14818.34 167 213 168 168 179 174 210 97 174 13518.36 135 192 141 169 175 205 183 112 189 16018.38 141 196 120 174 156 175 229 117 201 14718.4 132 211 155 212 195 215 197 106 232 146

18.42 147 208 157 211 182 182 197 84 202 16918.44 136 220 165 188 170 175 205 117 202 14418.46 147 177 151 184 180 197 189 106 186 13118.48 152 191 138 185 198 187 188 110 206 14818.5 149 230 149 189 184 171 184 91 190 133

18.52 134 176 147 190 178 201 206 93 176 15318.54 151 202 146 174 171 184 179 104 179 14418.56 126 219 152 183 170 196 178 94 193 12518.58 132 200 140 171 190 184 166 90 179 14618.6 131 210 142 164 180 187 185 84 170 147

18.62 155 229 136 157 207 180 207 105 200 14718.64 157 206 141 182 185 146 189 90 200 15718.66 126 215 136 173 189 188 188 103 201 14818.68 126 225 155 177 170 218 175 99 167 14718.7 113 216 135 167 211 193 171 99 180 132

18.72 142 208 143 150 173 197 214 99 147 14818.74 142 202 119 181 183 197 183 86 179 13618.76 114 202 160 179 178 185 191 100 163 14018.78 141 213 137 181 190 173 193 122 185 12818.8 142 211 131 180 162 179 177 95 164 142

18.82 131 218 145 175 181 170 176 97 193 15418.84 120 203 156 190 195 203 199 82 168 12718.86 147 230 150 185 209 177 169 98 197 14218.88 147 228 130 163 183 166 159 91 175 15218.9 133 213 135 201 168 174 177 98 188 178

18.92 134 193 152 158 156 186 176 88 171 14818.94 109 206 158 154 171 161 150 109 204 13618.96 145 220 119 159 177 180 167 98 182 12918.98 138 205 124 187 171 192 177 85 160 135

148

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

19 129 193 130 170 180 173 181 90 169 14119.02 129 195 131 177 171 164 193 112 174 15719.04 147 212 156 178 174 184 193 85 175 14119.06 165 185 137 165 208 182 180 88 180 15919.08 137 193 127 182 191 175 182 103 171 14119.1 134 175 139 175 172 181 175 92 166 123

19.12 125 198 140 193 181 162 193 101 195 14119.14 132 200 151 173 169 166 164 95 145 14019.16 133 185 136 186 192 169 192 90 165 14519.18 118 216 154 175 139 179 204 81 191 13919.2 122 206 130 194 172 175 177 96 188 151

19.22 131 187 132 178 186 191 174 102 175 15019.24 146 187 152 162 197 198 159 70 187 11819.26 157 188 117 174 177 163 183 103 191 14519.28 126 204 137 187 189 207 192 84 163 15219.3 136 172 159 182 158 168 146 101 185 145

19.32 143 209 153 163 161 190 193 101 189 16019.34 126 187 139 177 157 187 176 93 173 13919.36 139 196 162 162 167 170 161 101 163 14819.38 140 189 118 181 169 167 177 73 181 14219.4 149 193 124 166 173 168 180 76 149 128

19.42 131 190 131 182 150 165 163 95 166 13519.44 129 197 122 193 148 175 168 83 177 13619.46 130 208 138 168 174 180 178 81 200 12719.48 126 182 138 161 165 160 164 101 171 12019.5 143 213 142 159 156 187 202 86 168 125

19.52 130 208 136 177 156 183 165 83 154 15119.54 127 181 121 179 178 191 189 93 165 12719.56 120 216 135 174 181 165 183 81 172 14919.58 127 176 127 184 165 177 182 94 164 11819.6 143 178 141 168 169 178 159 105 176 144

19.62 136 201 121 186 178 156 171 83 169 13919.64 139 197 136 193 195 173 161 104 130 13919.66 135 195 155 203 173 169 178 90 180 13519.68 124 171 141 177 178 176 180 101 169 13719.7 123 161 133 171 171 153 172 74 141 131

19.72 113 184 136 190 167 192 164 95 162 13619.74 104 204 126 157 178 195 186 87 185 13919.76 140 194 128 209 160 149 187 94 156 13419.78 138 203 146 203 186 197 171 82 168 135

149

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

19.8 115 174 127 210 177 176 174 96 177 14819.82 116 192 126 177 179 173 141 88 153 12019.84 134 208 136 212 157 168 144 82 161 13519.86 124 217 135 195 195 185 161 90 152 12119.88 132 221 148 222 169 180 172 80 138 10319.9 142 237 127 194 182 196 170 95 144 128

19.92 133 223 133 189 204 169 178 76 153 13119.94 122 199 134 193 186 208 159 100 159 13219.96 122 213 134 212 168 190 160 83 164 11419.98 117 220 134 210 170 152 163 106 147 129

20 132 178 145 173 180 165 177 99 154 12920.02 112 205 130 158 186 159 160 106 176 14420.04 111 210 137 178 179 165 174 91 172 12620.06 111 190 126 182 164 167 139 96 138 12520.08 123 193 148 197 185 168 175 73 156 14320.1 128 218 131 161 171 168 161 85 144 110

20.12 123 189 148 201 172 180 159 87 155 13720.14 121 211 140 173 183 161 158 89 174 10920.16 130 194 125 145 157 164 159 93 154 13320.18 124 166 128 174 159 164 151 79 136 13420.2 95 179 140 165 179 178 165 95 149 130

20.22 146 206 113 162 164 159 173 75 139 12720.24 112 191 139 163 151 174 163 104 146 11720.26 141 181 122 178 156 181 150 73 149 12020.28 107 200 124 188 174 182 150 86 144 11920.3 129 171 151 203 172 174 164 80 143 111

20.32 119 206 124 185 161 174 156 82 165 12120.34 114 224 133 190 170 192 141 64 158 10020.36 110 217 105 168 165 171 161 84 145 11420.38 120 204 138 171 170 175 142 87 138 10120.4 110 201 154 189 173 180 154 95 144 130

20.42 124 225 124 166 182 165 159 84 156 11720.44 105 221 113 185 172 147 161 82 150 14220.46 94 180 147 181 171 158 129 84 128 11920.48 109 191 143 172 166 166 147 94 150 13920.5 106 208 142 188 171 158 143 92 122 140

20.52 106 203 155 195 160 176 145 85 161 11520.54 128 183 129 179 157 151 126 100 165 11020.56 103 187 149 181 168 138 158 97 143 12120.58 127 174 130 172 187 166 136 91 144 103

150

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

20.6 110 168 136 178 164 160 154 88 149 12820.62 121 183 151 201 155 155 157 105 146 12120.64 123 181 144 196 158 153 129 91 151 10820.66 98 233 149 191 190 152 119 113 171 13020.68 117 214 142 184 183 166 156 115 134 10320.7 118 222 166 194 191 145 173 133 127 123

20.72 124 217 190 230 179 176 153 158 144 11620.74 114 239 208 271 196 172 162 161 135 12620.76 124 248 248 275 200 201 206 189 133 11820.78 141 260 292 297 206 180 207 185 134 11620.8 134 344 310 353 213 219 169 195 164 124

20.82 134 325 382 429 228 191 204 198 140 11520.84 123 392 440 528 200 194 215 183 143 10820.86 129 434 511 528 222 252 149 181 147 12420.88 120 442 469 459 245 228 159 150 136 12720.9 104 438 389 444 257 206 157 150 136 111

20.92 112 361 339 318 207 199 141 142 151 10520.94 112 304 243 264 187 204 140 128 137 11520.96 105 265 178 212 199 151 148 113 132 10420.98 105 223 127 162 167 165 153 88 131 115

21 101 199 130 173 164 160 153 88 121 10821.02 107 190 118 155 174 167 145 81 127 12221.04 110 198 155 183 161 167 128 73 143 10521.06 94 183 127 189 178 149 142 78 138 12821.08 124 191 116 171 172 167 146 86 153 12121.1 101 177 120 171 160 164 145 95 132 97

21.12 115 210 98 179 155 154 145 74 134 11721.14 95 203 119 167 175 154 128 81 136 10321.16 110 180 132 182 159 182 133 97 139 10521.18 94 195 110 166 178 147 163 77 143 11321.2 101 199 108 166 176 164 138 76 134 118

21.22 112 180 104 172 180 159 132 79 126 10621.24 114 184 113 162 176 156 135 86 127 10221.26 104 200 134 143 191 155 140 88 145 10721.28 127 216 111 163 181 150 141 90 132 11121.3 114 203 130 148 195 162 132 77 112 112

21.32 104 214 111 146 181 154 134 80 124 12221.34 106 180 107 165 179 166 131 71 145 11721.36 111 197 109 160 188 150 150 71 129 10221.38 97 187 115 182 162 150 149 78 152 110

151

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

21.4 133 165 112 167 174 157 132 76 125 11921.42 113 188 90 162 160 152 145 73 129 9821.44 102 200 98 175 155 151 122 87 141 10621.46 106 190 115 155 170 150 130 87 148 11221.48 90 169 115 130 154 144 123 81 141 9021.5 100 195 105 140 160 141 109 76 136 92

21.52 113 172 110 139 140 146 122 69 123 10121.54 117 159 125 139 140 132 132 88 117 10421.56 96 172 97 162 151 144 129 72 113 10521.58 103 170 111 163 164 161 129 74 120 9921.6 91 148 108 146 135 137 129 82 97 102

21.62 91 166 99 142 133 145 124 66 131 11421.64 102 182 102 155 154 126 123 78 125 8821.66 109 141 131 143 108 142 109 93 125 10321.68 86 160 97 148 143 126 141 76 117 10621.7 88 152 96 136 141 138 114 73 102 99

21.72 89 135 119 129 121 154 137 74 147 10021.74 110 151 98 110 112 110 132 76 126 8521.76 90 145 89 143 94 108 126 64 135 11321.78 98 129 96 125 136 112 115 78 120 11221.8 104 155 104 129 127 144 120 69 117 114

21.82 100 148 100 131 136 120 115 77 117 9721.84 101 160 91 122 127 129 122 66 116 8821.86 106 141 94 135 135 137 113 68 117 10521.88 89 139 95 108 130 134 158 68 135 9221.9 107 150 108 139 134 126 133 80 132 106

21.92 83 166 103 140 117 108 103 76 137 10021.94 76 163 112 121 145 135 107 74 109 10921.96 106 128 115 126 105 124 128 65 110 8921.98 103 124 85 110 140 110 102 62 122 86

22 98 140 102 128 135 111 114 73 119 9722.02 88 129 113 114 121 115 121 71 145 10022.04 92 134 91 128 139 111 118 89 152 10322.06 94 151 101 129 134 104 112 94 108 10422.08 97 127 105 110 96 139 115 71 113 9322.1 86 130 93 141 111 143 118 74 135 101

22.12 86 137 96 116 114 127 117 77 130 8222.14 89 131 89 116 139 114 120 67 121 10322.16 107 153 99 101 124 108 113 64 123 9122.18 91 127 89 144 133 109 114 50 128 89

152

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

22.2 82 128 118 118 116 130 120 80 129 10422.22 105 141 92 119 124 133 111 62 108 9122.24 103 124 98 116 116 115 104 48 99 11322.26 87 146 105 118 137 120 134 75 98 8722.28 88 124 111 124 140 118 122 69 115 9022.3 85 118 105 123 132 116 122 84 100 98

22.32 88 137 93 133 130 95 127 72 95 10022.34 104 119 98 124 143 128 98 60 114 10022.36 98 132 106 120 124 120 112 72 111 9922.38 99 133 85 129 123 125 139 64 115 9622.4 90 119 110 134 139 114 102 81 118 97

22.42 88 144 81 135 94 112 115 81 115 9822.44 90 144 103 114 120 119 134 83 98 9222.46 77 144 94 133 130 117 111 76 130 9622.48 95 122 92 121 117 117 108 89 129 9922.5 106 158 87 105 114 114 111 86 139 108

22.52 112 145 122 141 105 134 136 63 129 11522.54 115 145 105 133 124 129 118 91 128 12122.56 101 146 101 158 124 139 129 80 149 10622.58 112 160 131 145 119 151 142 88 131 11422.6 105 166 102 130 141 144 123 88 165 114

22.62 122 149 137 165 138 141 146 89 123 12322.64 124 168 129 168 154 137 142 108 168 12622.66 144 157 120 152 137 169 159 102 167 15322.68 134 170 145 176 169 178 157 129 177 15722.7 165 175 127 164 140 169 184 120 168 137

22.72 164 182 148 207 185 185 189 121 197 15722.74 176 197 182 219 194 174 190 128 180 19622.76 178 218 222 235 239 215 173 154 211 18722.78 213 248 181 207 224 218 228 150 200 21322.8 232 226 236 249 218 228 230 173 221 213

22.82 260 273 268 289 278 245 271 181 290 20822.84 311 287 242 305 285 273 269 221 307 27022.86 340 305 292 334 332 304 314 223 377 30722.88 383 328 340 403 338 329 334 273 418 33922.9 452 335 348 458 415 419 402 310 462 414

22.92 579 392 387 560 453 428 441 347 488 48322.94 685 452 500 586 538 543 564 407 621 54522.96 760 548 603 734 627 588 583 458 687 58022.98 995 632 722 807 792 716 698 645 829 788

153

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

23 1216 785 838 1001 970 926 834 800 977 97723.02 1415 857 1020 1218 1066 1074 1021 1024 1142 111323.04 1715 1074 1193 1474 1391 1280 1175 1315 1274 136323.06 1894 1246 1417 1556 1515 1476 1308 1445 1521 154823.08 1916 1386 1550 1612 1643 1600 1484 1660 1558 168223.1 1645 1451 1527 1486 1585 1598 1387 1787 1420 1711

23.12 1206 1478 1367 1267 1498 1408 1292 1686 1160 150223.14 947 1366 1160 963 1233 1253 1033 1434 894 124123.16 556 1136 887 690 959 933 838 1162 638 98423.18 408 916 679 508 684 677 661 771 431 77023.2 278 711 528 333 533 557 500 528 352 502

23.22 222 554 383 295 385 354 399 353 282 36423.24 170 430 292 290 249 314 292 290 217 28623.26 176 325 231 195 237 235 245 196 180 26323.28 175 272 213 219 220 229 230 164 163 20123.3 151 248 194 216 180 181 187 131 179 197

23.32 148 239 183 193 172 174 194 140 128 17323.34 112 195 160 170 158 172 165 134 139 15823.36 119 216 141 130 182 167 148 120 147 13023.38 106 184 143 126 152 140 134 103 115 13423.4 98 146 134 118 149 111 134 113 123 133

23.42 92 156 137 130 126 136 126 92 110 11123.44 83 155 117 98 126 113 119 91 103 11823.46 94 136 106 121 124 104 122 92 122 10223.48 85 149 111 112 124 105 123 90 107 11123.5 93 142 114 121 133 108 118 84 95 88

23.52 96 142 100 128 122 111 119 74 87 9423.54 87 130 90 118 132 128 100 66 91 9423.56 109 120 101 113 119 114 122 77 118 8523.58 86 126 80 111 104 121 106 70 112 8723.6 89 116 100 112 118 118 116 71 90 92

23.62 74 117 103 109 120 104 119 81 95 10523.64 88 119 108 119 112 101 108 69 98 9123.66 75 118 95 111 126 120 97 64 100 8623.68 73 132 98 111 117 107 104 70 106 9023.7 96 112 101 114 119 97 122 54 101 92

23.72 98 103 83 111 106 119 94 69 114 8523.74 92 147 99 101 108 85 93 66 106 9923.76 103 115 87 105 97 110 122 69 90 7723.78 91 131 81 134 99 113 106 65 101 88

154

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

23.8 84 135 88 104 127 107 110 61 105 9523.82 85 121 80 106 105 98 110 81 102 7923.84 93 126 87 111 107 99 100 73 93 10023.86 78 116 71 112 108 104 90 77 95 9223.88 75 121 84 107 110 81 93 55 115 7523.9 92 130 93 100 90 98 103 71 132 79

23.92 88 114 81 96 103 103 99 71 102 7723.94 81 122 98 106 111 97 94 64 112 8023.96 70 117 78 99 119 111 92 72 135 10123.98 80 137 97 96 106 114 94 77 132 87

24 69 125 73 101 94 100 90 61 152 8024.02 94 126 105 89 94 86 74 57 139 8824.04 89 131 91 118 109 77 93 70 147 8524.06 82 113 71 97 113 102 103 74 126 7924.08 82 112 76 122 103 96 92 68 142 7724.1 78 111 72 101 92 115 88 63 150 76

24.12 73 108 75 107 102 87 105 56 135 8124.14 89 116 76 101 87 83 78 76 91 8924.16 88 101 92 111 108 89 104 67 112 8824.18 75 122 92 79 89 83 101 70 86 8324.2 64 82 87 92 88 110 101 55 112 71

24.22 81 121 85 90 86 87 78 63 105 9624.24 67 119 70 104 97 108 99 49 87 6324.26 69 94 84 109 100 105 83 72 95 7924.28 78 94 89 89 92 97 85 67 85 6524.3 50 104 77 97 105 94 81 63 96 74

24.32 67 107 76 98 89 101 93 55 92 7624.34 71 102 87 103 98 79 108 57 96 7524.36 74 93 81 87 83 110 75 66 72 7524.38 79 90 82 112 91 107 86 55 100 8324.4 73 101 91 114 79 89 64 71 102 74

24.42 79 89 72 94 93 112 96 57 78 9124.44 83 113 84 86 86 104 86 56 85 7324.46 74 109 63 102 95 82 100 66 80 6524.48 67 121 97 94 80 90 94 67 79 6724.5 80 99 83 103 102 89 81 54 92 80

24.52 73 116 96 98 78 97 92 69 94 8624.54 90 96 83 104 113 79 85 70 71 7124.56 73 101 75 115 90 101 76 61 80 8324.58 65 106 85 77 87 66 83 63 72 62

155

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

24.6 77 106 98 97 97 76 98 65 104 7224.62 62 115 87 92 115 80 89 63 93 7824.64 69 111 83 101 175 91 85 55 72 6924.66 77 102 85 102 207 88 77 59 87 8924.68 61 95 78 101 126 84 92 61 83 7624.7 71 104 76 104 106 103 97 72 89 79

24.72 70 124 83 110 160 96 103 60 79 8824.74 56 123 64 105 119 103 77 62 97 8024.76 70 115 74 97 102 92 83 40 76 7024.78 69 121 86 117 119 111 72 57 78 8024.8 76 133 88 105 96 108 91 57 91 74

24.82 84 140 86 113 111 104 87 68 76 7424.84 75 169 80 124 118 138 85 40 95 6524.86 64 155 83 134 126 123 88 73 92 5824.88 60 183 70 108 135 133 75 55 82 8224.9 75 210 79 135 112 143 74 65 91 73

24.92 71 197 68 126 129 135 94 55 109 7024.94 58 165 63 141 132 132 88 66 98 7724.96 87 205 56 104 117 105 96 58 95 6924.98 76 177 62 104 118 129 71 42 78 69

25 65 132 80 104 100 98 79 63 135 7125.02 75 111 63 109 81 93 80 54 119 6825.04 62 108 79 111 80 109 85 48 115 7625.06 86 107 78 104 89 91 76 66 105 8625.08 71 110 64 95 111 87 72 63 118 6425.1 79 100 87 96 82 97 83 55 111 70

25.12 64 87 75 91 103 88 86 60 158 7625.14 66 104 86 96 88 105 82 69 155 7325.16 87 78 82 90 69 88 99 55 150 6425.18 74 100 72 90 86 82 87 51 178 6925.2 68 96 73 76 83 70 70 57 193 78

25.22 78 105 79 97 81 80 89 62 224 7425.24 55 106 61 84 78 77 97 62 239 7625.26 81 106 61 110 97 92 84 54 289 7325.28 87 107 66 105 101 95 74 57 326 7125.3 70 88 80 90 92 78 74 61 374 76

25.32 65 113 82 90 77 87 75 57 580 7025.34 59 81 72 108 114 96 66 65 779 6925.36 55 91 66 96 95 83 75 50 880 7325.38 72 79 83 106 96 91 83 55 1143 73

156

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

25.4 68 85 69 102 61 89 91 75 1337 7825.42 62 91 62 99 92 79 63 57 1397 6925.44 67 94 84 90 93 72 76 58 1338 8625.46 64 71 75 91 88 74 90 60 1372 7225.48 80 93 84 102 78 92 74 62 1185 5825.5 82 86 72 96 88 88 67 64 964 68

25.52 66 87 65 97 108 68 78 68 720 5725.54 48 83 75 105 75 96 81 64 509 5925.56 74 81 69 76 93 93 80 60 392 6525.58 73 71 63 94 72 100 86 49 232 6125.6 80 87 75 80 78 86 97 68 210 72

25.62 67 75 65 73 78 106 72 45 163 7825.64 62 87 65 79 82 71 81 51 129 6225.66 77 101 78 81 105 95 79 43 131 6525.68 68 95 71 89 67 91 75 54 132 7225.7 78 78 80 78 85 79 94 56 115 83

25.72 51 88 69 73 69 79 79 58 115 6525.74 76 75 91 71 76 88 87 48 91 7425.76 64 81 68 79 85 98 65 53 102 6825.78 71 91 73 75 81 85 83 51 105 6525.8 72 104 78 81 92 83 74 50 77 63

25.82 73 77 68 96 66 70 86 47 90 7425.84 63 85 63 79 71 96 74 38 66 7625.86 73 82 70 78 91 81 87 45 96 7725.88 62 82 66 88 74 91 75 64 76 6625.9 64 81 58 84 77 98 59 64 78 67

25.92 54 73 75 76 81 89 86 61 67 7625.94 64 84 68 84 84 79 67 53 92 7625.96 62 80 79 93 93 74 79 59 73 6925.98 55 88 69 90 89 86 72 49 85 72

26 80 105 77 89 76 78 56 70 78 8526.02 54 87 73 80 65 69 80 62 76 8426.04 68 105 67 94 83 85 79 50 79 6926.06 63 91 80 100 71 89 74 57 80 6826.08 55 96 72 84 68 86 68 61 77 7526.1 75 77 81 85 80 79 74 57 65 65

26.12 78 100 72 98 94 84 80 69 79 7326.14 64 102 84 96 75 97 72 70 72 8326.16 81 109 90 114 85 106 97 61 71 6726.18 72 100 85 108 106 66 80 50 82 74

157

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

26.2 64 110 73 116 86 71 70 53 68 6326.22 77 107 103 105 96 89 75 77 96 6026.24 68 118 92 106 89 80 74 58 66 6426.26 70 108 107 132 100 74 71 85 69 7926.28 65 124 121 125 98 97 78 97 77 6926.3 58 114 120 147 85 88 70 92 80 73

26.32 79 135 144 145 90 92 75 99 76 7426.34 75 131 139 164 95 94 83 101 67 8126.36 69 135 169 175 94 99 84 98 85 6426.38 56 167 184 164 107 86 90 122 69 5726.4 76 186 217 186 108 103 88 126 79 62

26.42 62 190 241 209 102 96 88 105 79 7026.44 80 221 255 247 109 102 87 138 78 7026.46 71 245 290 308 123 108 79 116 81 6026.48 73 254 379 322 132 124 100 143 65 5626.5 82 345 392 410 149 158 88 114 70 73

26.52 97 334 518 495 153 161 102 169 83 7026.54 91 446 697 643 210 160 100 191 81 6826.56 79 569 924 920 240 201 113 250 94 8226.58 88 767 1245 1182 344 258 101 369 86 9126.6 74 955 1461 1562 374 329 119 591 88 102

26.62 96 1139 1702 1826 460 401 106 786 75 8326.64 87 1396 1770 1796 532 536 132 902 70 11726.66 78 1440 1783 1541 565 583 134 880 74 11426.68 101 1537 1564 1270 539 422 115 771 60 11326.7 92 1238 1214 957 434 302 137 601 76 97

26.72 70 1030 898 609 297 249 99 475 79 8226.74 74 846 673 386 258 214 90 333 66 5626.76 71 596 382 265 179 156 113 201 65 8826.78 61 410 232 193 136 105 79 137 62 8026.8 75 290 170 159 120 91 101 119 79 61

26.82 59 261 147 140 97 86 77 92 66 5526.84 58 158 159 129 108 77 65 81 67 5326.86 66 131 121 133 88 93 84 67 71 4926.88 63 111 120 110 100 80 76 77 85 6926.9 59 129 107 103 87 79 74 71 84 70

26.92 62 104 73 105 93 57 74 79 81 6326.94 66 124 87 87 80 75 75 68 55 5826.96 63 96 70 90 72 86 72 69 76 6426.98 70 106 69 101 88 91 72 47 61 82

158

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

27 54 88 100 88 80 73 76 62 75 6727.02 57 79 69 84 76 63 76 59 68 6427.04 52 81 87 88 69 94 77 47 62 7727.06 72 77 80 96 92 77 79 60 65 6527.08 67 77 84 90 89 77 89 61 70 5627.1 47 96 74 75 87 72 58 57 83 74

27.12 81 71 85 84 79 85 73 52 72 7327.14 71 77 74 93 87 81 71 42 60 6227.16 72 94 68 67 89 81 63 50 73 6027.18 59 73 76 88 85 68 90 56 64 5927.2 76 78 88 85 75 80 75 48 67 70

27.22 60 91 78 71 94 76 73 61 77 6227.24 66 75 68 79 67 68 67 55 61 5627.26 58 93 69 81 58 82 72 70 62 6627.28 70 81 61 86 81 62 81 45 71 5727.3 59 85 66 69 74 73 76 55 71 69

27.32 73 66 64 63 98 70 98 65 67 5327.34 68 84 78 81 77 73 69 56 72 7127.36 63 72 73 88 84 76 65 65 63 6427.38 60 97 75 89 91 74 74 50 73 6827.4 57 92 72 80 79 69 72 64 64 67

27.42 63 72 51 88 75 76 71 48 80 6327.44 41 70 63 88 69 78 70 49 57 5727.46 62 87 70 91 91 71 78 73 77 7227.48 72 83 66 84 91 61 57 55 68 6427.5 50 69 80 81 87 77 70 45 70 61

27.52 61 85 66 78 89 70 76 54 73 6927.54 59 78 62 92 104 82 80 54 70 5227.56 64 86 62 87 85 72 68 54 64 8127.58 52 77 72 99 83 66 98 50 71 7827.6 68 67 82 75 84 83 75 55 70 88

27.62 50 85 83 72 77 65 86 49 65 5627.64 63 78 83 91 76 85 72 68 91 6227.66 66 63 82 97 88 69 76 52 81 6727.68 62 89 75 90 83 69 83 48 72 7127.7 71 79 73 79 96 79 89 56 90 68

27.72 57 87 77 91 100 63 82 50 82 7027.74 66 72 84 88 72 80 84 52 62 7227.76 62 82 76 91 77 85 83 54 73 8627.78 66 75 74 73 101 71 83 53 67 68

159

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

27.8 72 78 91 95 84 84 70 57 64 6127.82 62 85 66 68 98 78 77 44 70 6427.84 63 61 61 89 94 79 89 60 68 6627.86 66 71 67 75 94 59 84 61 73 6227.88 61 75 74 95 98 70 84 65 68 6027.9 70 78 68 75 106 72 90 51 64 62

27.92 65 86 59 73 83 75 92 45 65 7127.94 84 91 80 77 101 64 95 67 92 4627.96 73 85 72 70 84 95 101 60 82 6027.98 81 88 82 103 76 79 127 63 63 70

28 75 83 85 76 85 63 119 64 81 6328.02 73 99 64 96 64 80 111 66 64 5828.04 67 88 68 73 92 81 168 57 59 6428.06 52 69 69 77 83 78 171 56 62 6128.08 56 76 71 89 79 76 154 43 68 7828.1 72 93 73 104 87 88 184 64 66 70

28.12 78 82 76 80 93 69 205 51 87 7628.14 70 79 77 68 69 86 275 54 68 6828.16 66 89 80 94 96 76 306 55 75 6128.18 64 102 75 97 90 90 328 55 70 7828.2 69 83 71 77 77 99 440 50 88 64

28.22 77 91 84 93 81 75 541 58 78 7928.24 68 101 95 87 78 88 575 66 91 7228.26 57 117 85 99 88 90 567 65 76 6828.28 75 88 87 87 83 82 584 67 82 8328.3 66 87 94 86 95 78 535 73 79 74

28.32 56 93 114 90 83 94 456 57 92 6428.34 74 90 104 78 74 95 409 54 76 6228.36 73 98 93 87 94 87 349 49 69 6228.38 67 88 95 106 111 85 248 55 92 5328.4 70 105 105 86 82 68 236 55 96 76

28.42 62 87 84 100 92 89 158 64 78 8428.44 65 98 69 83 89 96 168 59 78 8428.46 79 85 86 83 85 91 121 59 84 8228.48 79 107 96 78 87 96 133 73 94 7128.5 78 94 96 118 96 99 109 73 90 89

28.52 92 108 89 88 102 107 136 60 93 9128.54 81 108 86 96 101 77 112 73 84 6928.56 85 89 85 96 110 95 111 62 109 7528.58 116 107 79 95 114 114 89 65 97 106

160

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

28.6 81 122 83 104 98 102 117 60 135 10328.62 85 114 104 108 104 104 106 76 133 9828.64 76 116 84 103 105 117 110 74 106 11428.66 102 116 92 120 122 105 121 69 124 6828.68 94 115 121 127 114 98 113 93 100 11828.7 117 129 112 123 112 93 107 90 119 98

28.72 130 114 113 131 128 105 128 93 106 12028.74 137 142 141 133 124 137 148 97 111 10728.76 142 157 129 130 140 131 143 107 118 12728.78 163 128 125 160 138 139 157 101 145 12028.8 147 163 144 154 154 145 148 103 149 150

28.82 164 158 174 170 175 149 169 124 141 13028.84 184 176 175 191 218 184 197 156 180 15928.86 195 196 200 217 191 209 194 170 157 17228.88 223 191 202 249 252 218 205 160 188 19928.9 254 236 206 215 244 220 232 189 225 200

28.92 290 249 254 263 290 246 248 193 232 26728.94 278 255 246 293 269 289 278 187 219 24828.96 355 302 252 362 319 307 313 276 301 28428.98 375 335 330 353 344 320 299 288 365 345

29 407 303 336 441 371 380 422 320 382 36829.02 529 359 387 511 478 434 433 369 433 44629.04 564 478 449 529 499 480 493 421 445 50929.06 646 514 508 600 615 613 542 502 573 53829.08 785 552 607 670 717 605 625 526 650 63329.1 839 680 684 819 870 704 766 654 755 774

29.12 945 704 772 907 878 791 810 740 799 90329.14 1123 819 840 1088 1001 828 924 794 907 101729.16 1314 995 1065 1228 1195 1040 1042 933 1076 111429.18 1519 1124 1240 1411 1302 1214 1210 1042 1206 125629.2 1712 1302 1397 1618 1576 1413 1343 1254 1532 1537

29.22 2068 1487 1585 1973 1852 1592 1652 1505 1763 174829.24 2610 1771 2052 2417 2197 2053 1970 1743 2243 213829.26 3394 2152 2551 2882 2797 2373 2377 2183 2751 281129.28 4397 2468 2998 3581 3343 2973 2969 2864 3421 330729.3 5688 3035 3839 4446 4149 3978 3718 3743 4337 4310

29.32 7540 3933 4767 5803 5311 4849 4766 4691 5710 535429.34 9896 4874 6039 7464 6806 6312 6260 5957 7410 704729.36 13061 5969 7612 9702 8805 8175 7619 7465 9816 894829.38 16096 7593 9523 12167 11154 10376 9528 9510 12136 11381

161

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

29.4 17918 9397 11900 14485 13703 12590 11465 12316 13993 1396529.42 18801 11529 13308 15869 15874 14506 12996 15638 14917 1617529.44 16496 12963 14401 15227 16537 15199 13718 18396 14643 1709129.46 12100 14364 14247 13160 15434 14984 13650 19055 12581 1653029.48 9503 14117 13291 10801 12820 13176 12381 17545 10402 1429729.5 7784 12813 11332 8593 10556 11009 10369 14227 8175 11896

29.52 5016 11110 9305 6627 8176 8863 8469 11130 6008 917829.54 2856 9012 7340 4748 6007 6694 6605 8626 4143 691329.56 1845 6931 5411 3261 4225 4822 4932 5827 2741 497729.58 1292 5244 3986 2306 2890 3431 3640 3602 1913 333529.6 1197 3816 2907 1714 2109 2457 2546 2249 1314 2349

29.62 963 2725 2111 1372 1596 1731 1832 1560 1066 176929.64 903 2086 1606 1085 1254 1362 1525 1181 884 137929.66 704 1510 1300 862 1067 1150 1266 1015 787 102329.68 529 1341 1030 782 909 926 1065 884 630 91929.7 457 1158 828 613 726 851 882 711 535 770

29.72 389 910 677 535 623 640 725 595 446 63829.74 298 754 551 462 531 545 625 511 355 54829.76 293 641 494 379 435 481 505 399 304 47629.78 227 543 425 316 384 381 419 342 265 36629.8 202 434 360 275 348 350 393 271 245 294

29.82 175 401 274 254 304 291 327 229 195 28229.84 165 332 246 259 227 269 284 193 169 24429.86 172 317 237 216 241 270 241 171 155 23429.88 173 285 235 200 216 213 232 153 131 16629.9 144 246 192 178 208 182 216 160 148 164

29.92 117 206 169 184 172 155 197 144 146 18429.94 142 200 165 178 167 168 180 128 122 16229.96 117 212 171 163 154 159 189 126 126 13829.98 110 190 146 160 195 149 198 111 112 133

30 95 184 134 156 161 162 149 122 123 13530.02 104 173 134 144 147 154 164 90 119 12930.04 105 168 120 132 154 138 153 126 104 11930.06 104 149 113 123 150 131 142 100 116 10930.08 100 132 123 122 122 136 131 96 90 7930.1 94 162 102 132 162 138 118 85 88 109

30.12 88 148 121 126 140 111 118 87 101 12230.14 96 131 110 117 123 93 120 71 99 11630.16 87 144 136 103 111 121 110 83 99 10030.18 102 142 98 108 124 117 113 91 97 111

162

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

30.2 89 123 100 103 110 91 122 68 91 10230.22 97 115 111 100 94 93 98 85 90 8530.24 81 134 110 91 99 95 118 79 81 9530.26 97 114 89 96 113 96 99 88 92 7930.28 74 129 96 108 96 85 110 57 103 9830.3 84 103 93 106 91 95 91 84 107 80

30.32 79 95 98 86 104 90 96 58 86 8830.34 69 105 79 98 96 97 90 88 76 10130.36 77 92 91 87 95 90 100 82 88 7430.38 82 118 84 88 107 112 100 56 80 7830.4 69 99 74 106 91 69 85 56 92 66

30.42 96 112 98 99 82 89 93 66 100 8130.44 82 91 74 93 84 107 89 55 95 7430.46 91 106 69 96 94 94 93 76 80 8130.48 79 99 77 112 72 71 88 55 96 7430.5 76 104 79 77 94 80 90 53 93 93

30.52 73 117 101 96 83 95 79 74 119 7630.54 66 105 83 85 106 75 83 58 104 8130.56 67 120 75 86 100 86 83 70 111 7630.58 62 115 83 87 94 73 91 56 109 7230.6 77 118 66 92 82 106 92 50 128 90

30.62 67 104 62 84 90 80 78 68 118 7230.64 84 114 85 75 98 78 93 74 119 8630.66 81 96 82 87 80 105 86 63 127 7230.68 73 117 82 68 90 75 108 66 157 7830.7 65 137 70 81 90 85 62 75 196 64

30.72 70 129 82 96 106 72 81 74 210 8930.74 69 165 68 94 93 79 90 62 201 7530.76 70 149 84 93 92 91 63 64 256 9230.78 65 162 87 105 98 89 75 74 312 6530.8 64 192 84 103 101 75 79 64 347 73

30.82 76 213 70 106 101 87 107 87 403 6130.84 87 199 98 98 93 82 92 73 513 7130.86 85 205 76 105 101 85 95 87 610 7830.88 91 208 85 91 98 90 111 90 683 8830.9 89 214 86 118 97 84 111 88 875 98

30.92 76 201 83 111 88 104 94 83 1052 9030.94 78 181 74 83 115 90 94 88 982 9830.96 86 202 80 109 87 68 100 85 1022 9230.98 83 210 92 119 108 97 96 94 988 84

163

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

31 76 178 74 110 87 99 104 92 867 7331.02 92 204 94 91 101 94 109 91 693 8431.04 82 179 90 100 106 87 92 83 575 9731.06 73 177 88 113 76 80 100 82 489 9131.08 86 138 80 101 101 87 92 83 390 7731.1 96 139 84 108 84 82 113 81 305 96

31.12 68 152 78 97 90 80 89 96 274 8431.14 96 117 90 91 84 92 114 79 219 9331.16 110 108 93 101 97 82 96 82 236 8731.18 91 126 97 119 105 81 102 91 191 8531.2 88 103 95 130 100 94 92 95 200 91

31.22 98 126 93 111 104 99 103 75 195 10231.24 89 113 97 108 106 124 102 77 185 11231.26 106 132 116 136 126 120 111 97 229 9631.28 120 132 110 129 128 134 116 113 287 12831.3 162 159 137 140 144 136 121 103 357 124

31.32 170 137 139 180 160 138 146 129 505 15031.34 206 154 141 181 184 139 157 117 633 16331.36 228 160 155 228 238 186 183 176 694 21231.38 293 174 196 264 227 221 210 215 753 25831.4 392 197 218 312 287 240 247 248 735 283

31.42 523 239 293 370 335 311 304 327 688 34631.44 593 296 341 401 362 373 350 386 630 40131.46 492 337 343 414 465 337 345 475 625 44931.48 461 340 407 402 425 345 379 502 511 40631.5 398 375 386 356 375 379 325 479 449 418

31.52 292 358 348 300 347 340 318 451 360 37531.54 271 367 319 236 267 291 277 375 285 33531.56 195 312 278 211 281 256 237 290 209 25631.58 141 303 226 168 199 216 218 238 181 19431.6 103 215 192 163 165 188 189 177 151 174

31.62 87 188 177 134 145 147 142 139 136 14731.64 90 157 160 111 131 142 119 120 125 11431.66 90 137 131 113 124 116 105 89 108 10531.68 62 125 103 87 81 99 110 85 100 9431.7 61 124 93 90 97 106 109 76 99 86

31.72 79 115 71 75 77 64 93 66 80 9531.74 62 110 76 79 100 77 77 77 68 8531.76 63 98 84 100 78 81 87 73 86 9431.78 63 86 73 89 95 74 68 72 82 81

164

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

31.8 71 103 85 76 77 79 76 47 70 7631.82 66 70 57 67 76 65 79 58 73 5431.84 58 71 58 83 92 49 75 60 68 6431.86 79 89 77 68 72 62 70 55 81 5931.88 57 77 72 60 60 67 80 55 79 5131.9 59 83 60 63 62 74 91 56 95 59

31.92 63 81 49 76 68 86 94 50 87 4631.94 53 63 79 82 70 73 85 54 90 5631.96 62 64 77 71 70 55 78 54 100 6931.98 58 78 65 72 78 67 65 59 99 54

32 59 75 67 65 80 68 57 49 96 5332.02 54 76 66 72 82 78 81 47 99 5332.04 69 79 74 63 92 63 63 50 91 5632.06 48 80 54 64 58 72 74 54 89 7232.08 62 87 58 72 79 74 70 51 98 5432.1 47 82 53 65 49 75 68 53 74 62

32.12 57 72 71 65 70 59 60 55 81 5632.14 49 62 66 73 66 57 61 43 63 4532.16 49 77 72 59 66 52 58 49 68 4432.18 52 70 63 56 61 70 76 39 65 6032.2 65 71 56 50 68 64 56 53 62 74

32.22 61 68 63 68 63 64 58 42 56 4732.24 67 72 56 65 76 80 63 46 65 4432.26 53 74 72 69 68 60 65 49 83 7032.28 64 80 60 75 78 70 55 40 60 5332.3 65 65 55 70 75 65 66 46 56 66

32.32 54 67 57 68 71 74 56 43 67 5132.34 62 73 49 69 65 68 57 54 52 5432.36 48 81 69 71 57 80 75 41 64 5332.38 48 59 60 59 82 72 65 45 65 5932.4 53 70 62 66 70 65 66 40 67 69

32.42 51 70 55 58 66 46 56 49 46 7132.44 43 81 67 60 64 82 66 64 53 5532.46 48 67 64 58 76 71 73 45 47 6632.48 56 58 67 75 65 55 46 51 62 6232.5 51 63 73 62 60 72 64 33 49 57

32.52 43 70 54 50 57 64 56 54 42 5832.54 59 68 45 55 77 66 57 49 68 7032.56 47 62 62 73 78 73 70 52 62 4732.58 52 68 57 57 65 61 64 36 57 56

165

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

32.6 43 63 60 68 52 62 66 48 57 6132.62 55 55 59 73 67 56 60 53 59 5832.64 64 61 38 72 57 76 52 51 57 6532.66 62 73 61 67 71 60 56 40 63 6032.68 44 84 67 61 59 73 69 44 50 4332.7 72 56 57 65 58 67 50 55 64 48

32.72 65 68 65 64 61 52 60 55 61 6432.74 57 54 57 61 58 62 59 54 59 4432.76 63 72 70 72 67 65 69 49 58 5832.78 44 59 65 67 66 65 54 69 65 6432.8 54 70 52 61 62 56 66 52 60 61

32.82 56 71 48 76 71 51 60 62 70 5632.84 48 64 60 75 59 58 52 41 64 6032.86 55 68 61 58 60 55 68 44 59 5432.88 65 62 56 74 71 58 67 59 64 5732.9 49 51 52 64 69 86 61 48 51 50

32.92 38 64 60 78 77 69 53 37 58 6732.94 49 56 53 68 75 42 69 48 58 3832.96 50 74 53 68 65 71 60 61 56 5132.98 61 65 48 64 83 55 52 51 61 56

33 55 70 67 67 64 59 61 45 57 4433.02 49 62 52 63 61 70 54 44 63 6433.04 50 55 69 74 59 74 78 48 56 4933.06 58 63 54 71 72 61 60 45 64 4033.08 58 67 60 81 66 73 48 42 62 6233.1 53 52 61 72 67 67 66 50 70 47

33.12 38 75 63 76 71 82 66 45 51 4433.14 54 73 66 70 86 60 58 56 63 6033.16 53 70 67 67 72 69 65 36 57 6033.18 45 72 66 66 76 71 75 39 65 4633.2 58 57 48 60 71 79 72 45 77 54

33.22 59 64 52 68 78 60 55 41 61 5833.24 60 74 70 77 76 75 74 40 69 5333.26 53 73 45 80 74 52 71 50 62 5833.28 64 74 65 56 77 68 56 45 47 5833.3 58 80 46 70 77 69 61 56 51 60

33.32 50 63 41 68 82 79 55 45 65 4233.34 60 63 63 60 73 62 61 31 66 5633.36 43 82 54 63 84 65 59 48 74 6333.38 57 72 48 76 88 68 66 35 82 49

166

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

33.4 59 70 51 64 72 57 59 42 79 7133.42 48 70 68 70 82 67 57 46 71 6033.44 43 68 65 57 69 62 53 57 76 5633.46 52 58 56 48 70 56 54 43 75 4933.48 55 84 66 59 82 65 58 49 103 5933.5 49 70 41 57 67 63 73 52 111 43

33.52 56 79 52 70 73 55 51 45 113 6333.54 48 72 60 59 76 59 56 38 87 5533.56 66 57 63 83 65 55 81 43 116 4433.58 58 80 41 58 68 68 49 41 101 5133.6 56 69 73 51 74 63 54 42 98 50

33.62 65 76 59 80 57 61 57 55 92 3533.64 65 72 59 66 58 59 57 50 78 5333.66 50 74 45 63 64 55 54 60 71 4133.68 58 59 59 69 69 66 62 53 72 4633.7 43 55 59 68 74 51 72 47 71 65

33.72 56 72 56 82 84 59 56 43 63 5233.74 43 58 66 60 66 54 57 56 63 6033.76 44 68 66 56 63 57 60 51 72 5833.78 46 60 65 70 72 66 55 55 83 5833.8 52 62 65 67 40 49 54 50 54 58

33.82 38 53 67 60 67 59 52 36 49 4933.84 45 65 63 81 59 58 50 47 67 5733.86 51 64 54 56 67 66 58 44 71 5433.88 46 69 54 64 65 51 57 40 59 5533.9 50 53 48 59 60 65 50 44 61 60

33.92 38 65 47 58 58 59 89 43 56 5333.94 55 63 47 71 54 53 53 40 72 5733.96 59 73 54 58 53 59 58 44 58 4133.98 51 59 40 77 63 53 59 38 60 42

34 53 64 62 68 83 70 55 40 44 5834.02 49 68 55 66 58 58 54 53 61 5634.04 42 69 55 71 51 60 66 51 55 5834.06 54 65 64 61 61 68 61 37 61 4634.08 53 47 55 69 64 55 66 36 53 6334.1 44 60 53 65 75 62 66 38 53 64

34.12 49 69 45 54 71 60 41 49 58 5434.14 46 63 43 61 56 63 60 42 53 4834.16 59 68 65 58 61 67 55 39 54 6234.18 49 81 52 60 73 84 47 35 48 54

167

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

34.2 43 60 50 73 53 53 58 45 49 4734.22 59 77 46 56 74 54 64 46 59 6134.24 41 68 61 53 58 67 67 52 56 5034.26 42 75 50 70 72 72 67 51 71 4334.28 49 65 50 51 70 47 63 43 63 5634.3 50 62 52 62 70 75 56 45 52 62

34.32 57 58 56 70 66 56 69 55 58 5134.34 49 66 52 74 74 53 67 44 48 5434.36 48 52 47 81 58 69 75 39 59 5334.38 51 44 72 68 64 69 59 46 48 5434.4 54 60 53 69 62 73 55 50 66 46

34.42 49 63 58 82 55 58 58 42 55 4434.44 60 73 52 64 63 59 51 42 63 4034.46 44 61 51 65 72 65 53 52 53 5034.48 57 62 61 87 70 61 63 38 68 4334.5 51 67 48 64 65 56 66 45 53 34

34.52 48 70 69 72 54 63 57 46 63 6034.54 62 59 67 78 62 64 49 44 47 4434.56 62 69 58 75 85 62 49 48 59 4634.58 47 60 52 68 63 68 57 38 60 5034.6 60 63 47 78 72 58 54 34 54 55

34.62 53 73 60 71 55 64 62 42 63 4734.64 39 84 66 78 75 65 54 52 52 5534.66 51 63 63 70 81 73 49 44 53 4534.68 61 75 54 89 89 53 54 42 60 4034.7 57 73 55 65 79 65 68 51 59 63

34.72 54 74 61 82 62 61 56 42 54 6434.74 53 68 55 77 78 52 59 39 42 4434.76 54 74 61 86 85 63 67 35 45 6334.78 57 66 55 90 79 55 73 52 59 5634.8 64 67 57 85 87 87 48 42 60 56

34.82 54 51 61 77 80 68 67 48 66 4934.84 60 63 58 86 82 85 50 38 52 4734.86 47 85 52 80 72 63 65 37 51 5634.88 54 71 53 86 92 66 58 39 55 5634.9 47 78 63 91 83 72 67 48 47 64

34.92 53 74 60 105 73 76 73 47 55 5734.94 63 79 59 87 88 74 56 53 52 5934.96 56 75 50 101 67 73 54 40 54 6034.98 53 81 66 99 88 79 71 38 65 55

168

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

35 55 81 63 88 85 78 72 58 57 6735.02 75 94 67 72 78 74 57 56 62 5635.04 40 94 57 90 82 98 52 47 55 4735.06 49 76 71 105 81 97 63 45 54 5635.08 51 98 65 101 92 85 74 41 57 6535.1 49 76 45 79 73 70 50 51 67 55

35.12 56 77 63 84 73 77 60 37 73 6035.14 62 85 67 100 79 63 74 41 67 6235.16 48 103 66 83 73 71 69 30 83 5835.18 48 82 64 76 81 81 69 59 72 5635.2 62 78 66 73 67 91 71 58 72 50

35.22 64 82 63 75 75 64 64 54 72 6935.24 68 87 55 84 66 73 71 38 93 6635.26 68 94 51 76 95 76 76 44 89 6135.28 69 81 52 71 81 77 76 52 101 5535.3 64 80 66 69 76 79 68 64 106 67

35.32 77 82 72 77 73 73 73 48 108 7535.34 68 104 74 66 99 92 79 53 91 5535.36 55 86 64 83 81 81 89 54 103 7035.38 65 95 64 93 69 86 84 64 118 4935.4 77 106 71 85 89 90 72 56 79 63

35.42 63 102 81 103 84 97 89 62 105 7335.44 63 110 83 96 95 95 71 55 107 7135.46 76 98 85 96 91 98 67 59 88 6635.48 81 91 81 107 101 83 104 51 83 8235.5 71 125 80 92 94 79 84 62 71 85

35.52 115 110 86 96 93 95 74 75 98 7335.54 77 113 83 100 121 85 93 69 87 7935.56 69 111 95 104 109 107 92 81 110 7535.58 83 96 91 125 114 103 105 69 89 9735.6 97 116 85 108 119 104 114 84 101 96

35.62 98 127 122 140 149 132 125 96 127 11135.64 120 137 124 150 153 138 128 110 130 12635.66 148 134 131 145 148 130 135 121 129 14335.68 155 147 135 184 180 130 145 117 150 14035.7 169 151 171 179 178 148 169 147 143 160

35.72 189 156 171 219 190 165 171 137 164 16335.74 216 198 207 233 251 180 169 167 200 18935.76 244 204 203 241 212 179 196 209 212 20735.78 271 237 228 288 271 213 225 221 218 236

169

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

35.8 317 249 275 313 298 264 234 251 290 25635.82 437 291 284 358 373 303 301 258 364 32835.84 531 328 359 451 431 359 351 349 326 39535.86 620 415 432 547 480 465 436 379 492 46235.88 751 422 502 637 599 569 497 534 595 60235.9 1105 541 608 821 787 665 682 750 795 787

35.92 1446 719 822 1083 982 880 861 908 1026 108235.94 1912 892 1045 1344 1283 1147 1112 1243 1336 127835.96 2188 1077 1315 1604 1525 1390 1326 1711 1649 156835.98 2415 1374 1577 1871 1817 1638 1552 2154 1864 1886

36 2131 1563 1754 1854 1941 1846 1640 2901 1896 203736.02 1656 1764 1746 1824 1887 1854 1659 3354 1824 209936.04 1359 1778 1780 1458 1704 1747 1535 3073 1534 189636.06 1242 1683 1676 1350 1520 1617 1427 2280 1293 165336.08 1126 1562 1400 1053 1270 1397 1260 1892 1163 139936.1 808 1441 1285 891 1136 1180 1093 1799 866 1171

36.12 561 1191 1033 759 921 990 844 1633 706 91736.14 338 1019 902 589 726 795 685 1123 537 80636.16 258 827 640 475 581 582 563 793 400 53836.18 203 685 551 325 426 444 457 493 280 44336.2 209 484 413 291 344 352 336 353 255 319

36.22 158 423 340 209 295 290 269 272 229 26436.24 175 317 287 224 234 245 228 207 203 24236.26 135 268 232 193 206 216 230 188 188 19136.28 110 270 189 163 167 194 204 144 208 17236.3 101 192 176 134 168 131 199 129 172 149

36.32 96 159 171 144 155 148 124 105 142 14636.34 87 181 144 153 157 126 149 113 158 12736.36 88 171 131 146 141 124 133 107 172 9836.38 74 124 125 108 148 119 123 87 144 9836.4 67 131 102 124 112 106 119 84 108 84

36.42 76 141 117 120 127 97 106 86 104 8236.44 61 126 116 133 101 106 92 104 108 7536.46 72 143 152 133 110 111 75 94 79 8236.48 65 153 139 123 114 85 84 125 84 7636.5 52 153 127 153 138 93 88 124 75 63

36.52 69 139 165 159 122 106 89 123 70 6436.54 69 155 192 186 118 93 76 116 85 7636.56 59 153 203 198 108 107 68 152 82 6336.58 76 161 175 139 118 90 73 170 81 84

170

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

36.6 46 166 135 156 117 88 76 147 71 6236.62 54 143 147 133 102 83 82 98 62 7436.64 68 119 137 147 119 85 85 85 86 6836.66 54 133 127 145 104 83 85 83 62 5136.68 56 98 99 93 104 77 67 89 65 5236.7 39 106 90 101 92 75 72 56 55 57

36.72 51 110 93 86 96 74 76 63 62 6336.74 51 70 49 92 79 64 65 62 56 7436.76 66 83 66 78 83 69 81 61 55 5236.78 49 84 71 87 86 69 56 54 58 6336.8 57 79 58 68 82 65 62 60 60 63

36.82 38 73 61 89 88 81 63 51 45 6536.84 57 77 69 76 96 67 58 44 64 5036.86 57 79 56 74 110 78 61 51 59 5636.88 47 76 65 75 81 61 60 56 45 5236.9 58 75 75 93 70 61 66 48 52 67

36.92 53 86 62 76 68 63 49 47 54 6636.94 65 86 67 75 80 71 68 44 51 5336.96 46 86 55 72 89 56 56 50 66 5636.98 57 76 71 78 74 81 81 42 59 44

37 59 74 53 69 100 60 57 52 48 6037.02 55 66 50 73 81 70 56 44 60 5537.04 52 79 51 67 83 66 55 54 57 6337.06 49 67 60 90 74 63 61 31 61 6137.08 70 76 66 73 88 63 57 53 63 5037.1 57 57 62 74 63 69 66 44 71 52

37.12 53 71 52 92 65 67 55 41 70 4637.14 54 67 60 83 73 53 50 55 52 5637.16 52 71 67 60 73 56 62 55 91 5737.18 59 67 62 55 73 71 75 54 66 4737.2 48 81 74 75 77 65 72 51 68 61

37.22 51 78 54 68 66 67 68 46 82 5237.24 51 75 77 65 65 72 69 57 79 4737.26 57 75 54 66 55 68 69 54 73 5137.28 52 75 56 66 64 57 68 43 98 5237.3 58 89 52 87 55 65 73 49 124 59

37.32 79 78 40 60 62 73 72 40 108 5737.34 52 82 55 62 72 54 64 45 119 6437.36 65 65 65 62 74 50 72 69 173 5037.38 50 73 59 78 84 56 44 56 147 56

171

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

37.4 40 91 56 57 70 71 47 52 133 6237.42 63 74 47 68 70 52 63 50 126 4337.44 45 86 54 79 70 77 56 47 112 6237.46 49 69 46 62 48 60 55 47 126 6137.48 52 79 62 68 65 64 65 54 109 6737.5 57 76 57 58 52 64 68 45 75 70

37.52 43 66 54 59 55 61 58 47 78 5937.54 51 62 61 74 59 63 60 43 67 4737.56 41 65 46 79 70 82 52 47 59 4237.58 62 76 53 88 56 68 64 49 55 5337.6 58 62 46 67 71 48 59 38 63 55

37.62 49 85 58 75 69 65 60 42 45 4237.64 48 70 62 72 56 73 66 42 71 4637.66 44 70 58 52 66 74 65 46 64 5737.68 65 72 64 53 82 57 56 52 62 4837.7 58 83 59 72 74 74 62 49 63 55

37.72 48 66 66 85 73 59 73 43 58 6537.74 63 76 54 55 61 74 61 45 74 5437.76 48 81 56 73 77 80 65 40 57 5237.78 59 68 55 72 67 72 72 49 49 6037.8 47 74 57 73 66 68 51 41 60 55

37.82 47 74 47 72 77 54 52 47 60 5137.84 58 73 57 67 59 68 68 35 69 4137.86 53 69 70 62 73 61 69 43 57 5637.88 44 68 51 70 77 55 60 41 51 6537.9 70 69 55 65 72 55 58 43 60 53

37.92 57 74 57 68 65 57 51 39 69 5137.94 47 63 56 55 64 53 54 55 64 5037.96 48 68 65 64 87 71 66 34 58 6537.98 48 66 66 65 57 65 61 44 47 49

38 64 73 67 66 60 61 61 45 46 4938.02 51 75 59 79 79 67 60 47 63 5738.04 63 52 62 73 55 64 73 47 69 4238.06 57 72 57 65 60 62 63 42 66 4938.08 55 62 61 60 67 62 67 34 53 5838.1 42 53 72 57 65 56 76 45 52 52

38.12 58 62 45 81 58 56 53 57 65 4738.14 55 78 53 60 82 71 65 56 60 4938.16 52 72 48 69 77 68 65 43 60 5838.18 47 84 52 73 61 63 53 46 60 57

172

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

38.2 50 64 64 85 67 62 64 41 55 4538.22 59 75 51 68 73 67 58 41 66 5438.24 41 86 69 76 71 79 74 32 52 5138.26 54 58 55 78 70 70 57 48 64 5038.28 61 87 53 73 66 81 56 45 57 5438.3 54 92 50 85 65 59 57 52 70 65

38.32 48 77 55 73 84 74 57 42 60 6538.34 56 100 56 94 65 78 61 36 65 6538.36 59 94 62 92 93 91 63 49 77 6238.38 51 87 60 70 95 77 63 54 55 5938.4 49 125 62 71 87 95 47 41 72 62

38.42 52 106 78 64 82 81 72 51 90 5538.44 47 112 57 85 87 83 74 58 86 5838.46 43 94 54 91 90 79 72 37 91 6738.48 62 103 63 99 95 76 84 51 75 7138.5 51 112 58 86 87 92 70 47 108 52

38.52 66 118 65 86 96 97 73 46 99 7038.54 55 122 57 76 97 75 63 50 112 5938.56 83 119 79 90 86 86 71 61 112 4438.58 70 91 80 88 97 86 57 66 158 5938.6 66 118 58 82 83 86 73 50 189 66

38.62 50 102 77 84 89 74 57 47 227 7638.64 71 95 59 81 72 94 79 48 258 6838.66 67 106 62 91 82 85 61 66 266 6838.68 68 98 73 96 71 66 82 59 216 7438.7 61 105 74 81 75 75 77 54 192 75

38.72 63 91 69 98 77 68 90 71 188 8138.74 87 108 82 78 103 92 95 69 155 8738.76 50 83 88 79 86 81 89 84 164 8038.78 79 86 89 81 83 82 84 65 134 7038.8 72 80 86 103 104 70 85 54 112 75

38.82 77 91 74 84 96 101 83 69 116 8438.84 71 97 75 102 78 91 82 56 106 8938.86 84 99 81 110 89 88 93 81 83 9938.88 96 102 84 105 85 96 69 56 106 8838.9 69 111 105 106 123 109 72 82 94 83

38.92 100 112 92 100 100 97 93 71 94 7638.94 88 95 104 106 113 93 105 75 95 9138.96 96 111 97 117 119 115 86 74 121 9638.98 102 117 72 114 127 107 118 92 100 109

173

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

39 107 132 95 135 112 105 114 88 101 11839.02 110 114 111 148 144 128 118 101 123 12039.04 122 153 115 181 144 122 139 98 144 13739.06 164 156 152 141 146 144 145 107 116 12039.08 172 172 139 181 185 148 164 123 158 16939.1 184 182 184 186 180 180 175 141 151 176

39.12 209 196 166 227 227 205 203 164 174 18339.14 214 191 197 271 214 208 219 161 189 19239.16 242 212 178 265 269 227 215 204 221 21639.18 248 256 231 297 252 263 227 226 213 26239.2 283 280 270 280 305 273 286 250 281 257

39.22 339 305 302 357 336 323 300 266 325 31439.24 427 379 355 435 417 339 351 300 344 37639.26 498 415 395 460 466 384 442 354 462 46539.28 686 430 448 579 565 477 461 437 488 56039.3 816 541 572 690 682 614 592 570 664 666

39.32 1151 626 678 918 847 684 677 668 800 81739.34 1465 784 899 1202 1040 929 917 875 1157 111939.36 2217 914 1088 1515 1385 1161 1113 1135 1466 140439.38 3050 1203 1322 1967 1814 1519 1487 1644 1868 177239.4 3558 1494 1679 2304 2153 1840 1813 2055 2280 2245

39.42 3627 1835 2091 2622 2467 2261 2175 2676 2635 257639.44 3197 2097 2313 2660 2673 2451 2283 3579 2683 278239.46 2380 2278 2451 2455 2603 2478 2301 4076 2441 282739.48 2003 2439 2420 2146 2414 2358 2235 3650 2130 261539.5 2005 2428 2192 1923 2162 2149 2005 2885 1861 2249

39.52 1663 2181 1965 1737 1806 1876 1676 2314 1579 203339.54 1288 2003 1749 1392 1638 1597 1523 2128 1391 174239.56 874 1766 1546 1164 1411 1391 1313 1882 1136 142739.58 606 1544 1253 872 1095 1174 1119 1618 839 123039.6 437 1255 1098 711 833 873 954 1073 637 948

39.62 320 1022 837 542 678 655 717 710 453 68939.64 290 799 666 418 493 519 566 488 350 49139.66 226 608 519 338 413 445 453 372 313 40639.68 181 503 394 311 339 401 380 298 267 35739.7 173 433 343 254 316 271 306 270 215 288

39.72 170 390 311 219 235 269 295 208 190 25339.74 129 292 268 198 219 221 217 177 161 20939.76 139 266 206 186 186 212 201 142 124 17639.78 113 237 198 169 203 190 204 140 145 144

174

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

39.8 112 206 172 139 172 184 177 117 124 14439.82 107 192 171 138 180 153 153 106 119 12439.84 97 169 126 139 145 127 145 104 100 12339.86 91 161 142 123 137 134 121 86 89 9639.88 78 168 117 134 119 96 124 80 100 11739.9 101 120 115 106 111 122 106 81 84 94

39.92 82 134 90 98 111 85 117 76 91 9639.94 74 147 92 106 136 98 108 78 60 9539.96 68 143 95 103 87 82 107 78 56 8939.98 76 115 117 117 99 95 111 75 90 86

40 66 119 83 89 91 87 86 77 73 6640.02 64 103 102 102 82 83 85 62 77 7840.04 78 97 89 86 84 93 98 72 78 7440.06 76 99 90 115 91 96 105 67 66 8140.08 73 86 85 71 82 101 84 70 73 7140.1 85 89 88 86 98 71 80 68 71 67

40.12 64 82 86 91 86 95 82 51 72 8840.14 61 96 80 99 81 95 81 50 62 8140.16 60 92 67 87 87 81 82 70 70 7040.18 68 74 78 106 76 79 72 60 76 8240.2 60 92 84 100 78 82 69 67 69 56

40.22 58 94 90 89 77 89 87 59 72 7640.24 65 113 97 126 94 84 87 65 76 6740.26 51 126 84 107 97 82 81 77 72 6440.28 66 115 118 133 85 79 65 87 78 5440.3 63 121 119 115 103 62 72 92 67 69

40.32 60 86 91 127 91 81 63 91 60 6340.34 54 113 132 88 90 83 62 87 70 6840.36 45 108 102 105 100 73 81 74 67 5940.38 60 98 83 105 71 81 66 61 73 5240.4 56 104 75 86 77 70 62 79 71 60

40.42 64 93 80 88 92 79 60 69 63 6240.44 55 79 73 93 63 63 64 67 69 5540.46 57 88 58 65 84 71 71 59 73 6040.48 61 85 68 48 77 63 66 66 64 5640.5 52 106 68 82 74 60 80 52 71 70

40.52 73 71 58 80 70 62 73 71 79 5940.54 62 77 71 81 81 87 71 49 75 4640.56 59 88 54 71 78 62 72 62 82 6640.58 71 71 62 70 61 78 46 47 76 58

175

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

40.6 52 82 53 79 60 59 57 52 94 7340.62 41 63 63 54 76 61 53 45 92 5640.64 59 62 71 73 52 57 79 38 86 5640.66 35 61 59 50 58 57 71 42 117 7040.68 55 56 70 75 74 62 70 40 124 6440.7 57 81 63 65 61 61 71 54 128 58

40.72 41 69 70 56 63 58 44 34 132 6040.74 46 71 64 75 69 61 60 55 173 5340.76 54 63 60 74 61 61 68 33 261 6140.78 55 93 57 77 59 66 65 56 301 5440.8 57 91 58 64 69 69 68 49 332 55

40.82 56 66 64 62 71 77 68 47 318 6440.84 53 79 53 54 73 70 73 57 402 5740.86 44 75 58 70 64 46 61 37 362 6640.88 45 78 63 70 82 53 67 42 279 6040.9 56 89 63 71 56 66 60 52 244 48

40.92 61 79 60 63 63 66 60 43 219 5740.94 48 81 72 68 70 69 74 40 209 5040.96 52 99 60 81 77 81 68 55 215 6340.98 69 94 68 72 59 67 63 46 190 64

41 55 83 64 73 62 69 75 51 168 6241.02 79 101 68 72 61 77 52 53 179 6041.04 64 106 60 69 69 59 64 43 192 6941.06 60 87 59 82 77 75 65 49 242 6041.08 55 111 60 84 70 56 74 52 272 6941.1 74 93 62 60 72 63 53 56 283 55

41.12 53 117 50 77 66 56 63 58 336 6441.14 59 86 64 72 91 70 73 73 339 6141.16 54 96 60 82 80 72 85 56 298 5641.18 60 117 62 75 71 80 65 50 293 5741.2 42 81 47 72 68 84 77 53 259 55

41.22 54 92 51 92 68 74 62 45 244 7441.24 71 90 64 61 94 77 51 59 196 6241.26 56 88 64 60 64 59 57 55 250 5641.28 52 76 65 77 91 63 66 42 205 6441.3 52 89 64 65 65 63 77 46 270 56

41.32 57 89 61 51 76 68 66 38 275 4741.34 55 77 53 80 55 74 53 50 245 5241.36 48 84 74 64 79 60 65 53 157 6141.38 43 72 49 77 79 59 53 62 129 50

176

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

41.4 55 87 56 72 64 55 73 46 120 4341.42 50 83 52 67 67 60 58 41 154 6041.44 56 75 58 55 79 76 59 44 150 4941.46 54 74 63 58 74 68 69 38 101 4841.48 54 58 73 72 78 80 63 57 83 5241.5 52 61 57 66 73 48 58 46 81 55

41.52 67 83 52 75 78 76 64 45 63 5741.54 63 69 52 67 56 55 59 53 68 5041.56 58 64 62 69 66 59 63 47 75 6141.58 54 81 54 57 67 64 62 52 69 4541.6 51 85 60 73 64 64 69 64 64 56

41.62 64 60 60 66 67 59 53 43 64 6041.64 68 74 52 75 75 66 75 49 71 7141.66 65 75 62 68 86 61 49 34 79 6541.68 65 64 61 55 72 51 59 45 57 5941.7 55 74 60 63 88 76 59 51 76 67

41.72 44 67 56 62 68 69 57 34 63 4641.74 51 67 61 66 72 63 59 64 65 6441.76 52 67 44 74 64 58 58 52 65 7041.78 47 57 73 69 57 53 59 50 75 4741.8 58 77 66 78 76 66 63 47 59 48

41.82 45 64 69 67 64 61 60 57 64 5541.84 65 65 62 68 75 56 56 43 51 4941.86 44 81 59 74 66 67 55 45 61 4141.88 55 81 58 69 64 58 62 59 64 6641.9 54 71 65 62 69 68 58 46 76 60

41.92 51 72 67 64 66 69 70 47 45 6741.94 56 62 46 76 75 57 67 39 52 6841.96 49 79 58 60 62 61 51 44 66 5441.98 48 88 62 78 70 68 71 43 53 50

42 57 61 73 56 65 65 60 42 72 5042.02 53 80 53 63 64 57 74 49 70 5642.04 49 62 65 63 58 78 50 41 59 5342.06 48 84 57 52 61 69 61 49 68 6642.08 52 63 48 60 72 77 56 45 58 6342.1 54 65 59 76 63 74 81 60 58 68

42.12 66 64 46 71 74 69 72 47 56 7042.14 56 66 70 83 67 66 71 55 62 5242.16 60 85 62 89 65 63 68 34 55 6742.18 49 95 56 74 72 67 69 51 55 67

177

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

42.2 62 87 56 91 82 61 74 46 76 6342.22 67 90 63 67 68 55 67 57 59 6342.24 65 90 83 71 78 77 68 52 68 5642.26 67 72 84 77 81 74 54 58 67 6642.28 65 83 79 80 79 73 71 49 71 5542.3 50 79 64 77 79 75 76 46 86 67

42.32 64 89 69 83 88 76 79 69 57 5742.34 58 122 65 83 79 68 67 61 61 5042.36 63 90 83 90 96 85 69 73 62 5842.38 66 102 107 118 82 88 51 72 68 6842.4 58 106 101 129 94 67 80 111 85 76

42.42 69 110 107 146 90 82 89 104 66 7542.44 60 129 143 137 94 89 84 118 76 8342.46 81 121 173 127 98 80 68 104 58 8242.48 87 145 156 112 89 93 74 89 82 6142.5 65 114 122 130 104 80 65 103 70 70

42.52 79 105 109 128 104 83 87 86 51 7242.54 72 108 104 118 89 81 75 88 77 7742.56 76 102 116 98 104 75 69 89 88 6042.58 84 96 106 108 84 86 64 73 55 7442.6 71 98 120 104 71 103 71 70 66 70

42.62 80 104 86 80 68 71 74 73 80 6742.64 72 88 80 101 83 91 105 68 87 9542.66 79 102 88 87 98 97 83 68 78 8742.68 78 81 86 98 92 72 80 73 91 8242.7 73 100 88 111 97 95 89 80 86 98

42.72 71 94 82 103 91 95 84 72 81 8342.74 98 114 111 94 95 107 114 78 94 8242.76 124 123 92 102 116 109 93 85 90 11142.78 103 121 99 117 110 108 101 68 109 11142.8 126 116 116 123 136 101 88 82 132 116

42.82 138 119 121 129 127 135 117 113 140 13842.84 147 151 113 163 147 128 119 119 144 13642.86 165 115 132 162 152 149 129 127 163 15442.88 187 155 152 175 169 149 128 153 155 15342.9 181 168 178 186 166 203 164 147 190 170

42.92 244 173 169 217 200 184 199 166 202 18042.94 235 192 199 218 218 214 231 197 208 19042.96 293 199 224 259 246 208 264 212 227 24342.98 299 222 223 284 282 234 232 215 240 240

178

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

43 354 244 253 323 303 266 277 287 293 31943.02 449 294 325 376 357 321 310 328 355 36143.04 597 335 358 494 472 341 407 365 451 44743.06 729 402 448 502 536 444 459 447 566 56443.08 1007 489 556 774 669 598 591 561 724 69343.1 1358 596 741 1003 987 736 730 765 963 880

43.12 1930 837 998 1361 1158 957 999 1006 1293 124943.14 2543 1002 1340 1722 1503 1274 1254 1420 1680 158843.16 2864 1269 1691 2010 1954 1720 1588 1888 2056 197643.18 2671 1580 1936 2211 2228 1976 1811 2455 2520 231443.2 2123 1800 2088 2221 2389 2075 1914 2782 2371 2309

43.22 1625 1917 2054 1869 2132 2068 1793 2756 2082 226443.24 1542 2029 2076 1706 1946 1959 1732 2382 1808 206643.26 1450 1837 1875 1500 1650 1655 1523 2025 1502 172243.28 1347 1704 1680 1333 1519 1518 1443 1686 1420 150443.3 1059 1572 1627 1231 1412 1373 1256 1555 1335 1388

43.32 748 1348 1357 1031 1072 1231 1059 1463 1101 124743.34 468 1244 1183 786 934 981 976 1268 815 98243.36 323 1071 930 585 746 728 699 896 648 74543.38 271 851 752 423 505 591 595 651 473 54943.4 238 691 593 371 428 470 454 449 359 412

43.42 193 522 451 288 317 397 404 337 289 35543.44 171 468 398 225 284 318 306 295 246 25843.46 141 372 317 231 258 273 257 214 209 22043.48 119 324 250 180 193 231 215 174 173 20343.5 122 238 208 177 161 199 201 159 154 164

43.52 104 235 186 156 168 160 174 160 150 14443.54 89 176 152 142 149 164 150 129 123 13343.56 87 182 145 129 143 130 127 111 110 12643.58 83 169 140 116 147 135 138 117 105 9443.6 96 159 123 111 100 117 106 79 103 117

43.62 97 119 88 99 99 100 104 86 78 9243.64 92 122 106 115 107 114 96 72 107 8943.66 73 110 91 112 88 93 111 71 93 9743.68 72 105 93 83 91 103 95 83 83 9143.7 66 98 80 97 86 103 80 76 81 84

43.72 75 107 81 85 98 85 101 70 90 7943.74 62 100 80 73 82 94 87 56 105 8343.76 66 92 86 86 91 80 87 65 99 8943.78 63 104 81 89 73 82 85 54 132 67

179

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

43.8 58 92 76 72 82 83 93 58 116 9143.82 80 87 89 76 105 80 72 54 123 8343.84 74 74 61 87 68 78 72 55 108 7243.86 66 95 62 65 81 68 76 75 107 7043.88 49 86 79 80 85 76 70 48 101 5843.9 65 85 59 58 62 67 68 48 75 68

43.92 54 72 67 67 73 70 67 67 82 5743.94 56 90 61 75 69 53 66 59 94 6643.96 69 71 65 77 53 66 75 56 88 6243.98 68 81 76 73 80 65 69 55 86 65

44 62 74 80 60 71 85 83 53 71 5844.02 75 64 57 79 75 74 70 65 65 6244.04 59 84 66 71 76 74 68 53 58 5444.06 67 69 68 57 70 63 84 48 74 7244.08 57 79 72 70 68 52 64 66 69 5844.1 67 65 76 77 91 78 64 66 55 54

44.12 62 73 55 68 67 60 72 55 57 6344.14 67 78 53 59 77 63 67 49 55 4444.16 67 76 57 58 74 66 71 51 54 6744.18 63 75 65 70 64 66 74 47 48 6044.2 77 62 70 58 69 53 71 44 56 51

44.22 50 84 59 56 84 75 66 61 76 5344.24 46 69 77 67 59 55 49 49 67 5344.26 68 79 54 77 70 60 62 46 54 6144.28 59 72 45 60 64 76 83 45 70 5844.3 47 68 49 52 65 78 69 56 52 55

44.32 56 71 83 59 73 68 65 58 72 5944.34 63 84 57 57 74 75 71 46 65 7444.36 68 79 57 49 68 73 61 43 56 6544.38 59 68 58 60 69 68 84 58 71 6544.4 57 83 61 61 61 74 62 47 61 59

44.42 70 51 62 65 71 66 72 53 55 5644.44 61 63 60 63 85 67 57 50 52 5944.46 58 80 61 75 68 48 45 65 54 5044.48 43 67 68 64 62 70 70 55 76 5744.5 64 81 58 67 66 57 75 40 70 61

44.52 57 68 54 48 74 64 42 45 62 5644.54 58 69 67 53 65 60 55 52 62 4644.56 69 86 54 70 56 53 77 54 63 6744.58 64 66 71 61 65 71 57 47 55 56

180

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

44.6 52 73 57 58 51 75 72 53 69 4944.62 57 67 62 68 58 62 65 54 67 5444.64 55 83 52 60 63 84 65 52 67 6244.66 53 75 62 63 67 66 60 45 77 6244.68 63 72 61 64 64 56 61 58 63 5944.7 53 76 70 76 67 64 56 47 71 74

44.72 74 62 58 62 45 63 64 53 84 5744.74 68 77 61 54 69 66 72 57 65 5444.76 57 88 66 65 58 62 63 55 78 5944.78 55 82 69 57 67 70 63 55 104 5844.8 52 86 51 65 72 59 53 42 76 52

44.82 46 72 59 68 79 50 71 49 118 5144.84 65 67 79 77 76 57 56 49 134 6644.86 67 63 53 67 85 66 61 56 160 6844.88 52 98 75 75 85 60 73 68 148 5544.9 49 71 48 62 56 68 71 58 207 50

44.92 70 74 47 65 64 67 71 66 219 5544.94 55 79 52 63 59 70 51 83 200 5744.96 63 91 51 75 59 53 62 53 188 5844.98 57 77 75 69 57 61 58 68 212 61

45 81 88 59 79 77 65 60 64 155 5445.02 65 63 53 68 75 80 76 55 177 5745.04 63 68 66 62 49 64 63 49 117 7145.06 52 71 51 63 65 67 58 68 132 5445.08 57 59 64 69 76 62 69 66 104 5845.1 62 74 73 63 72 67 70 61 126 59

45.12 48 69 50 67 68 71 59 48 83 7345.14 55 76 63 80 64 65 47 63 83 4745.16 65 79 57 65 57 68 59 60 94 6045.18 51 74 56 77 76 62 66 50 82 6345.2 55 66 57 63 69 55 60 61 85 45

45.22 55 69 54 86 78 63 54 39 74 6145.24 54 71 63 67 82 65 68 63 72 4745.26 54 73 54 71 69 71 59 53 75 5645.28 55 69 73 68 74 78 50 54 88 5845.3 52 88 56 56 72 62 61 52 74 64

45.32 47 80 60 60 69 53 59 42 64 6145.34 56 65 66 80 69 48 58 52 70 5745.36 52 71 59 67 59 44 68 53 88 5345.38 63 72 45 64 65 67 49 56 84 55

181

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

45.4 54 71 63 66 76 53 56 71 102 4345.42 53 84 57 75 57 61 59 45 96 5945.44 63 73 58 81 64 64 63 51 114 5445.46 54 92 73 77 68 63 57 52 154 5245.48 76 67 65 86 69 73 67 61 120 4945.5 53 72 60 72 65 62 83 55 118 49

45.52 55 80 68 64 78 66 66 40 103 6845.54 43 79 70 68 75 61 73 52 106 6045.56 73 81 64 72 68 60 67 35 85 4945.58 67 77 50 72 76 55 56 58 110 5445.6 63 72 69 61 75 58 79 58 89 57

45.62 57 87 65 83 85 63 64 53 80 6545.64 60 73 56 76 63 64 65 46 75 5545.66 53 89 60 67 81 58 53 46 72 6745.68 56 79 78 87 74 61 63 63 70 5245.7 65 81 77 92 80 63 56 67 65 56

45.72 56 93 96 101 78 86 68 67 50 7145.74 68 85 89 98 84 80 67 74 58 5745.76 55 93 96 103 82 67 68 127 58 6345.78 60 117 116 102 100 99 65 125 59 6445.8 66 91 98 103 83 72 64 132 71 71

45.82 73 109 104 97 98 72 68 115 65 6345.84 59 99 102 84 76 66 62 80 56 6745.86 64 78 89 98 72 63 67 77 61 5945.88 64 87 72 88 69 74 78 86 66 8345.9 57 75 76 78 86 78 77 88 61 62

45.92 43 94 92 73 73 82 66 62 73 7145.94 53 79 62 75 60 68 68 67 51 4945.96 57 87 70 70 80 76 64 53 74 5945.98 58 78 73 66 60 60 72 64 69 64

46 47 59 71 65 79 65 58 53 54 5646.02 61 77 66 75 54 56 89 67 54 5046.04 64 87 69 72 71 58 65 53 60 5646.06 55 70 70 83 80 62 71 54 71 6646.08 52 82 57 56 73 58 67 63 64 6646.1 58 75 66 71 81 71 65 64 78 70

46.12 52 82 63 67 57 67 66 57 65 5746.14 56 66 71 76 80 77 62 53 65 5646.16 52 70 50 67 63 54 53 61 66 5946.18 70 78 54 59 69 64 63 59 81 66

182

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

46.2 65 69 72 69 72 81 71 73 58 5446.22 56 78 53 71 75 72 72 56 68 7346.24 62 67 68 72 84 70 69 62 61 6846.26 64 80 56 71 81 58 79 59 67 6446.28 56 78 52 67 69 63 67 61 64 5846.3 60 71 68 66 78 91 86 67 77 64

46.32 52 65 68 73 81 66 76 57 62 5946.34 81 70 57 78 77 71 87 57 59 7246.36 55 76 60 81 93 80 83 55 71 7846.38 59 96 71 79 81 77 84 58 58 8046.4 62 95 73 71 74 72 77 65 75 64

46.42 81 92 73 65 76 76 81 64 65 7446.44 82 83 77 63 70 81 90 67 74 7446.46 59 92 84 75 95 69 85 75 79 7946.48 84 82 67 85 76 68 97 68 69 5946.5 77 95 76 97 81 86 86 78 71 73

46.52 81 91 66 90 76 78 105 81 75 6746.54 66 77 71 86 87 94 93 78 83 7346.56 85 110 72 106 95 80 94 77 77 8146.58 73 94 83 91 100 103 88 72 68 8046.6 86 108 83 99 106 94 117 72 77 84

46.62 96 99 74 120 98 84 100 70 66 8346.64 84 106 56 95 88 108 116 82 90 7546.66 86 113 89 106 106 99 119 81 94 11046.68 89 105 91 104 122 92 150 71 71 8846.7 93 125 110 115 130 107 123 90 85 73

46.72 94 97 91 115 116 90 148 80 114 8846.74 102 126 97 99 146 103 145 96 116 9546.76 99 107 112 104 113 112 167 83 99 10446.78 120 121 130 136 107 117 174 103 112 10146.8 122 115 102 112 133 130 184 98 155 130

46.82 148 132 121 136 125 142 215 99 148 13246.84 142 143 139 157 163 119 217 98 152 13246.86 142 140 138 160 164 132 261 143 165 13946.88 151 140 154 186 186 130 291 167 186 17346.9 195 156 156 159 193 130 394 156 163 166

46.92 201 181 150 190 186 146 562 162 172 17046.94 230 169 176 206 194 190 831 162 219 18546.96 253 212 195 248 236 204 835 175 212 22146.98 262 216 228 260 254 231 778 198 233 253

183

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

47 312 225 243 290 306 241 728 246 258 29247.02 379 261 250 308 331 278 740 264 344 31547.04 493 328 295 399 412 330 764 345 353 39547.06 661 356 358 507 484 391 842 388 494 45947.08 924 430 438 579 543 536 823 539 582 55947.1 1145 466 517 683 649 607 838 670 707 683

47.12 1147 526 593 806 806 647 872 907 725 79447.14 1103 620 713 820 791 760 924 972 772 88247.16 926 708 726 873 846 804 917 1065 771 88547.18 796 682 758 831 831 790 827 1059 640 87247.2 742 765 776 773 803 753 814 909 657 765

47.22 746 752 732 721 741 733 743 829 631 80547.24 804 687 721 691 750 690 732 789 611 76047.26 647 749 722 717 725 666 627 740 585 70547.28 588 699 637 650 698 658 631 710 579 67147.3 549 649 667 646 626 626 638 715 527 630

47.32 542 663 649 622 677 595 581 651 541 62647.34 539 634 624 557 629 527 570 558 524 62047.36 695 600 623 605 647 606 565 551 560 67147.38 849 610 634 658 727 530 632 548 588 61847.4 1013 641 685 706 765 634 680 629 696 790

47.42 1399 660 707 867 967 747 677 723 849 89247.44 1967 810 831 1082 1150 888 873 910 1063 102047.46 2568 887 1008 1349 1445 1113 1086 1111 1341 136747.48 3231 1070 1154 1758 1743 1383 1298 1504 1627 170947.5 3537 1283 1488 2036 2063 1627 1614 1880 1804 1903

47.52 3410 1448 1622 2161 2219 1894 1781 2304 2029 220847.54 2669 1660 1777 2174 2137 2005 1889 2738 2024 233647.56 2173 1891 1902 2001 2105 2028 1867 2815 1914 221347.58 1824 1891 1904 1801 1984 2029 1770 2826 1628 223547.6 1770 1914 1873 1688 1819 1944 1730 2649 1470 1975

47.62 1821 1825 1796 1600 1561 1673 1551 2192 1309 173647.64 1624 1725 1719 1446 1477 1601 1422 1952 1243 154547.66 1295 1569 1499 1246 1299 1480 1310 1682 1091 150847.68 846 1436 1294 1075 1247 1280 1188 1570 936 125347.7 571 1307 1194 946 985 1085 981 1455 771 1071

47.72 446 1144 1049 773 832 978 892 1191 628 87847.74 374 1009 920 635 655 796 712 914 491 75547.76 297 871 745 543 507 648 601 662 398 57647.78 240 750 621 447 474 533 495 559 345 527

184

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

47.8 221 624 558 362 423 453 415 432 283 38247.82 228 521 454 358 330 400 350 313 235 32747.84 215 470 389 262 316 319 351 269 217 29547.86 173 379 348 246 298 287 311 265 220 23947.88 192 380 336 203 238 292 277 235 174 25247.9 161 273 254 238 240 231 256 189 171 236

47.92 143 280 258 191 220 213 219 185 159 20947.94 166 267 226 176 195 193 205 185 175 22247.96 125 253 187 193 182 193 188 153 126 16847.98 153 231 189 184 195 210 199 126 135 163

48 140 214 178 154 216 194 210 158 145 18848.02 146 211 173 177 177 170 171 140 147 13648.04 131 217 178 184 190 163 176 142 144 15548.06 150 225 179 182 192 160 184 139 122 15548.08 142 192 191 188 193 151 188 128 150 17048.1 163 199 176 180 193 186 132 144 149 152

48.12 178 193 183 203 206 168 178 148 156 15148.14 172 193 155 195 199 193 161 134 159 17648.16 193 220 205 186 196 190 200 172 159 20048.18 197 214 200 229 213 155 204 174 200 20748.2 223 228 212 251 253 204 204 187 213 192

48.22 239 232 230 230 255 196 222 211 231 24648.24 260 251 240 263 280 254 231 215 222 26748.26 281 269 232 266 275 256 270 233 236 28848.28 307 260 261 330 329 265 285 248 280 30548.3 337 278 314 339 349 308 305 284 271 359

48.32 363 326 296 356 397 307 331 283 315 35948.34 491 349 328 400 413 349 377 299 404 42448.36 500 397 398 484 473 382 397 381 447 48848.38 623 417 452 589 576 473 487 419 550 55948.4 850 508 563 667 767 556 548 520 687 651

48.42 1110 582 661 826 898 711 735 663 863 87048.44 1561 722 762 1118 1082 829 863 949 1151 108448.46 2243 870 1044 1334 1461 1094 1104 1190 1493 145448.48 3079 1097 1251 1708 1724 1399 1398 1650 1848 175048.5 3706 1334 1492 2079 2137 1704 1765 1984 2149 2123

48.52 3460 1593 1799 2113 2277 2020 1959 2384 2325 236348.54 2788 1795 1907 2079 2437 2195 2102 2653 2358 237348.56 2303 1972 2025 1872 2273 2163 2022 2636 2132 234148.58 1827 2017 2007 1831 2066 2074 1973 2502 1896 2275

185

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

48.6 1696 1983 1900 1633 1870 1976 1882 2202 1674 206348.62 1791 1919 1868 1516 1689 1807 1638 1916 1611 179148.64 1665 1785 1655 1445 1581 1641 1500 1717 1505 161348.66 1323 1603 1487 1253 1453 1498 1387 1623 1334 147848.68 1004 1491 1415 1155 1264 1310 1245 1480 1197 140748.7 677 1366 1253 961 1084 1196 1085 1258 1080 1165

48.72 487 1196 1146 758 898 1012 986 974 835 92448.74 351 1002 907 597 687 802 715 774 656 72548.76 305 869 787 492 552 696 610 610 536 56448.78 240 704 660 435 475 518 517 430 420 47848.8 214 613 501 321 405 462 422 396 357 406

48.82 200 494 415 284 311 355 354 273 345 30148.84 175 418 344 242 270 320 287 230 299 28348.86 169 331 331 223 241 292 262 202 252 26148.88 147 304 278 206 224 230 238 208 186 20748.9 136 288 223 182 188 213 233 146 178 169

48.92 140 234 211 172 162 198 198 132 138 16348.94 94 231 210 161 162 151 184 138 135 17048.96 110 205 181 137 175 144 134 113 156 13148.98 119 180 156 123 136 138 146 90 121 119

49 88 158 153 112 128 106 119 83 128 10649.02 87 165 139 116 123 135 143 104 136 11249.04 71 147 141 106 122 109 105 100 112 12249.06 87 146 144 109 105 115 112 89 99 9649.08 73 110 104 102 86 108 118 76 116 11549.1 87 115 126 101 91 110 118 84 128 77

49.12 89 132 92 93 84 94 105 83 169 8049.14 89 116 89 103 91 85 97 70 180 9649.16 74 129 85 96 81 87 87 63 200 8949.18 76 107 92 84 99 87 91 77 163 8549.2 71 112 86 89 83 74 91 57 124 100

49.22 85 97 86 84 97 88 87 73 118 8549.24 69 113 70 75 88 77 76 60 159 6949.26 72 92 74 85 85 74 73 70 136 7849.28 77 96 82 87 88 83 79 76 154 7649.3 68 81 75 77 88 85 76 75 132 82

49.32 66 91 73 69 102 89 86 48 119 7649.34 62 85 81 85 66 79 80 60 91 6949.36 56 90 87 78 88 67 63 55 120 7449.38 70 98 71 67 68 63 70 61 87 69

186

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

49.4 77 101 70 77 75 75 76 47 86 6449.42 54 93 68 72 81 68 63 45 77 6649.44 72 82 80 71 71 64 71 49 111 5049.46 50 72 65 70 76 72 58 55 77 7349.48 53 93 66 61 69 60 60 57 81 5449.5 63 67 69 59 70 58 74 68 59 52

49.52 72 76 74 62 75 67 78 56 67 4649.54 64 62 55 72 67 50 59 49 61 6449.56 62 71 59 79 63 59 63 50 50 5549.58 54 79 65 60 70 71 69 43 59 7049.6 57 65 51 67 60 55 51 51 63 65

49.62 52 60 52 60 61 68 71 53 77 5349.64 58 66 69 59 77 51 70 30 62 5149.66 49 77 60 59 81 54 59 48 61 6249.68 48 80 65 67 84 49 58 52 58 4149.7 44 86 65 58 67 67 76 59 48 66

49.72 61 73 55 63 66 54 66 54 53 5749.74 50 68 54 70 69 59 55 55 58 5349.76 65 78 51 72 61 59 49 52 60 6349.78 58 66 45 76 87 57 54 57 58 6949.8 48 66 57 64 69 54 51 49 53 49

49.82 66 69 67 72 74 55 66 56 49 4749.84 60 74 52 60 62 54 60 64 69 3649.86 57 66 65 53 65 51 57 43 54 4949.88 66 83 67 73 68 72 48 63 46 4349.9 58 68 48 66 59 56 60 46 50 62

49.92 45 64 70 60 66 56 52 48 48 5449.94 45 77 63 72 66 56 55 49 54 5149.96 57 78 56 66 70 65 55 54 60 6149.98 49 92 68 60 65 51 55 63 64 44

50 54 98 69 81 71 65 50 59 54 3750.02 54 99 90 96 64 62 66 72 51 4950.04 53 119 92 108 74 75 48 82 56 3750.06 55 124 131 162 81 53 50 66 45 5450.08 54 147 155 190 111 69 56 94 67 5250.1 65 158 207 196 109 67 62 99 59 49

50.12 67 168 223 228 97 95 56 179 72 5850.14 42 169 244 192 116 78 64 252 56 4950.16 58 198 173 169 116 86 63 277 53 6950.18 41 145 145 151 120 73 44 191 58 52

187

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

50.2 69 144 113 143 100 65 56 142 64 4550.22 56 130 150 137 90 65 58 126 66 3450.24 59 139 126 122 100 74 60 109 66 5550.26 34 122 156 122 95 73 49 101 65 4750.28 60 111 132 133 80 68 59 146 66 5450.3 59 109 95 94 68 62 64 112 67 57

50.32 47 90 92 82 60 61 55 89 81 5950.34 57 89 68 61 70 55 48 72 62 5950.36 42 73 58 70 79 51 54 65 85 4950.38 36 81 67 57 63 60 56 77 75 4750.4 51 76 64 71 58 53 44 54 88 46

50.42 60 82 57 48 72 50 45 46 114 5750.44 45 72 54 58 57 48 44 47 133 4550.46 41 66 66 67 63 49 42 68 124 4650.48 56 73 53 67 65 55 51 51 146 6750.5 61 81 66 62 59 58 44 50 155 47

50.52 54 63 51 56 70 66 46 50 133 6250.54 44 81 54 63 73 57 67 48 140 5050.56 38 73 62 49 67 52 53 51 176 4950.58 43 80 60 58 60 56 52 56 166 3950.6 42 94 51 48 69 47 44 51 144 40

50.62 46 67 57 56 61 52 52 51 135 5650.64 39 60 60 59 59 58 55 49 147 3850.66 43 71 47 66 69 57 48 50 115 4850.68 49 68 60 59 73 39 59 37 129 4250.7 46 81 53 55 67 62 48 52 118 47

50.72 38 80 65 53 58 45 41 51 103 4350.74 48 73 50 51 65 47 39 48 88 5050.76 51 70 55 56 48 59 59 56 105 4750.78 40 78 46 44 58 71 47 57 98 4650.8 44 68 52 61 69 43 38 47 76 54

50.82 62 56 56 45 69 46 50 49 100 4550.84 48 68 51 51 65 55 50 27 81 4450.86 47 66 43 50 74 63 53 46 77 4150.88 44 72 48 56 64 53 55 47 86 4550.9 36 70 51 55 56 56 65 36 102 52

50.92 48 64 54 47 49 52 64 45 89 4050.94 43 70 54 42 67 41 40 38 128 5350.96 58 69 53 54 60 59 51 40 131 5650.98 41 61 53 55 49 52 51 55 129 48

188

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

51 40 83 56 45 50 55 43 53 151 4851.02 41 70 39 61 64 47 47 42 161 5351.04 31 72 62 72 53 52 61 52 187 3851.06 45 75 50 56 59 50 44 54 191 5051.08 46 60 51 61 64 57 36 47 205 4751.1 58 77 50 53 61 56 59 42 170 46

51.12 49 49 49 57 60 46 50 39 188 5051.14 51 68 42 76 57 58 48 40 170 3751.16 61 71 51 60 56 46 51 34 154 5051.18 59 54 54 60 57 50 42 44 143 5251.2 53 57 40 54 59 60 57 44 137 46

51.22 52 57 40 47 49 51 44 45 139 5051.24 46 55 60 60 60 46 52 46 116 6051.26 59 50 51 60 57 62 56 42 105 5051.28 42 66 53 43 54 43 50 41 86 3551.3 38 45 37 58 48 41 46 37 88 56

51.32 51 58 45 62 48 55 48 47 93 4551.34 37 73 47 37 46 33 66 47 76 5451.36 46 51 50 51 52 44 52 53 67 5351.38 39 59 39 47 47 62 54 42 72 4051.4 50 61 33 57 61 62 45 30 58 43

51.42 36 62 42 40 38 40 43 33 61 4251.44 56 47 39 44 40 53 48 39 46 4351.46 42 50 33 50 37 55 53 37 62 4751.48 37 60 46 55 57 42 54 34 68 4551.5 41 60 35 54 56 56 45 55 48 56

51.52 46 48 54 49 43 48 42 37 64 4951.54 36 51 54 51 45 38 41 40 56 3851.56 51 62 45 51 56 45 42 44 54 4051.58 48 84 56 50 56 46 42 26 60 4251.6 40 45 42 47 50 50 63 43 48 46

51.62 48 60 53 50 52 53 42 38 58 4951.64 33 50 40 48 39 49 56 38 53 4851.66 43 48 47 48 50 39 50 24 41 3851.68 52 45 43 49 62 41 36 41 60 3851.7 38 38 48 41 57 46 48 34 54 57

51.72 54 46 53 44 41 43 56 53 46 3651.74 47 50 38 43 41 47 56 34 55 3351.76 42 56 48 49 59 45 35 44 43 4551.78 48 39 51 45 51 50 44 33 43 45

189

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

51.8 49 65 46 47 43 52 48 38 39 3151.82 53 63 40 52 45 47 47 42 66 4651.84 37 49 65 40 43 44 45 32 47 2751.86 50 56 42 51 44 44 41 40 49 3851.88 47 51 41 37 43 59 46 28 49 4151.9 43 58 46 51 53 50 36 42 49 45

51.92 45 51 41 54 47 63 49 33 61 3751.94 44 53 51 54 41 45 41 47 41 3751.96 36 49 50 47 44 60 48 53 43 5451.98 62 50 44 57 49 52 39 50 54 41

52 40 46 46 47 43 50 53 37 63 2952.02 43 55 65 51 47 37 40 35 47 4252.04 49 46 58 53 57 38 39 40 48 3452.06 50 45 61 48 49 56 51 49 60 4152.08 51 51 34 39 52 54 53 28 68 5252.1 35 48 40 47 41 38 52 23 63 45

52.12 36 57 48 45 45 34 35 36 74 5652.14 51 39 49 55 40 45 47 52 92 3952.16 52 46 55 36 45 46 50 35 92 3352.18 45 43 40 45 50 44 55 30 107 2952.2 40 52 51 43 58 39 42 44 117 38

52.22 36 50 35 36 46 48 54 44 154 4552.24 36 65 50 52 39 41 57 41 147 4352.26 47 52 45 39 39 44 52 29 171 5352.28 47 47 41 43 41 56 54 36 167 4552.3 48 47 35 43 38 49 42 38 130 36

52.32 35 50 34 54 45 55 45 42 135 4852.34 49 51 53 50 40 37 45 34 139 5252.36 40 49 38 56 52 52 40 33 96 4552.38 39 38 52 50 51 39 56 44 118 3952.4 42 41 47 59 54 53 38 33 105 49

52.42 35 52 55 46 44 49 47 38 107 5052.44 32 46 46 49 44 41 50 38 95 4152.46 49 51 42 53 43 47 52 42 86 4752.48 50 55 40 41 50 51 35 36 75 3752.5 41 44 64 34 48 43 46 29 57 41

52.52 38 50 31 48 39 40 63 42 49 4352.54 44 53 50 47 52 45 40 43 40 3852.56 40 46 47 50 43 52 47 38 54 3652.58 48 48 39 47 50 32 50 46 46 50

190

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

52.6 36 52 38 48 54 48 49 31 51 3852.62 36 43 40 46 57 37 42 35 50 2952.64 45 44 42 40 52 43 37 37 57 3652.66 40 51 31 55 48 44 37 30 38 4652.68 41 53 45 46 43 42 50 36 38 2852.7 48 35 54 54 47 36 36 41 42 47

52.72 37 35 46 39 48 49 50 31 45 4752.74 55 56 43 38 50 44 39 40 40 4252.76 39 44 45 33 42 39 41 42 52 3352.78 52 47 41 46 34 49 42 31 54 4652.8 38 49 45 46 54 44 47 42 43 39

52.82 44 51 50 44 42 41 45 53 51 4352.84 36 52 39 46 63 42 48 37 61 3652.86 39 38 40 54 53 48 38 39 51 3452.88 43 42 31 46 47 41 51 47 30 4252.9 48 55 34 49 49 36 37 45 42 45

52.92 40 47 35 43 43 50 45 32 37 3652.94 46 50 36 53 40 46 55 45 51 4052.96 48 46 63 54 52 39 36 41 39 4352.98 39 67 39 32 51 48 45 26 47 34

53 32 58 39 50 54 46 48 47 38 4253.02 47 47 52 49 48 46 46 32 45 3753.04 34 55 40 55 58 49 36 38 41 3553.06 43 40 43 45 61 58 54 34 48 5353.08 49 54 37 47 51 54 47 34 36 4153.1 42 51 47 47 42 45 58 41 39 46

53.12 50 42 40 53 62 45 37 35 37 4053.14 45 53 43 55 49 42 43 31 48 2853.16 48 59 42 43 49 49 49 37 35 3353.18 40 42 49 41 52 50 43 27 32 4153.2 34 57 38 51 48 38 41 27 34 36

53.22 49 48 47 52 44 42 30 36 45 4053.24 38 68 39 47 42 51 42 41 35 4453.26 37 49 57 29 58 45 50 49 44 4953.28 39 54 40 37 54 34 39 28 39 4653.3 43 48 43 51 44 45 43 40 40 45

53.32 32 47 36 57 52 54 36 28 46 3953.34 38 49 43 44 56 46 24 29 43 3053.36 41 50 45 64 48 45 46 32 44 5453.38 45 46 34 47 44 50 53 44 35 49

191

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

53.4 30 54 47 51 65 41 43 27 37 2753.42 43 51 34 52 47 46 54 38 49 3453.44 39 51 37 49 55 28 40 36 40 3953.46 36 48 50 43 63 30 53 37 27 5153.48 40 40 38 44 50 48 51 36 42 5253.5 39 57 37 47 50 36 49 40 33 42

53.52 46 38 49 44 39 59 48 35 51 3853.54 39 54 33 36 62 48 44 33 32 4353.56 38 40 35 52 64 42 42 47 48 4353.58 36 40 47 47 42 52 40 29 46 3453.6 27 55 43 39 48 47 41 39 40 48

53.62 46 48 45 37 46 44 41 41 50 3853.64 41 51 49 48 53 50 45 39 49 4453.66 39 46 41 47 59 49 32 27 41 3753.68 33 43 32 39 64 37 31 40 36 3453.7 36 36 49 49 51 50 31 36 38 32

53.72 35 54 32 44 38 50 42 32 45 3453.74 42 37 34 47 47 56 39 33 37 4253.76 44 50 47 46 50 40 50 23 48 3753.78 40 38 55 58 34 48 39 34 48 3253.8 33 42 37 39 53 50 35 36 43 40

53.82 37 41 24 42 45 39 41 45 43 3753.84 36 50 50 51 48 44 57 29 21 2553.86 33 43 32 45 38 34 34 39 41 3453.88 50 51 44 51 58 57 41 41 46 3653.9 51 46 51 49 54 40 46 38 43 37

53.92 37 53 39 44 43 41 49 32 45 4353.94 31 60 38 57 47 38 52 44 46 4553.96 29 48 38 49 45 48 38 36 49 3953.98 53 52 45 53 42 33 43 31 37 40

54 40 51 47 47 51 31 36 32 29 3954.02 34 55 36 53 53 46 53 38 39 4654.04 60 55 38 53 55 50 45 33 39 4654.06 38 50 34 38 40 36 44 47 40 3754.08 46 49 50 50 54 44 34 25 43 4654.1 31 42 52 46 49 52 41 47 46 36

54.12 38 50 52 58 42 46 37 33 41 4454.14 47 57 39 39 44 38 29 40 51 2954.16 39 48 36 54 32 53 50 34 35 3754.18 40 50 38 41 47 42 44 32 47 45

192

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

54.2 43 36 32 53 63 46 41 21 51 4754.22 49 43 43 47 38 54 49 49 40 5254.24 38 49 38 46 50 58 41 40 39 3754.26 34 61 38 41 55 52 31 39 42 3454.28 40 45 44 43 52 49 41 34 43 4854.3 31 49 40 33 42 43 36 31 43 32

54.32 36 54 45 56 36 42 40 32 54 2754.34 29 74 37 55 45 34 47 29 42 4454.36 42 60 31 44 51 44 39 41 58 3154.38 37 39 52 48 51 52 47 41 49 3954.4 34 48 41 53 50 33 44 33 36 34

54.42 38 48 54 39 48 39 50 29 55 4054.44 36 68 41 44 43 45 50 28 42 3554.46 35 67 51 42 43 37 52 41 38 4754.48 42 44 33 48 44 46 34 40 44 4354.5 35 54 42 47 66 45 38 47 35 34

54.52 24 44 33 36 41 34 45 43 36 3354.54 43 52 39 53 54 46 41 28 52 3454.56 49 41 33 65 50 48 54 43 60 3554.58 48 49 58 50 53 51 42 39 34 3754.6 43 54 44 55 53 46 41 36 38 37

54.62 47 60 32 57 64 49 33 39 34 4254.64 38 57 46 50 43 44 42 38 47 3054.66 45 56 52 48 54 37 39 29 36 3654.68 40 51 44 54 61 55 51 38 38 4654.7 46 55 51 70 52 43 36 53 47 46

54.72 39 57 39 55 49 44 48 39 43 2454.74 43 59 40 64 40 35 48 36 42 4354.76 53 59 52 52 55 50 39 39 49 4554.78 36 58 58 69 52 43 42 68 38 3854.8 44 70 49 80 46 40 40 75 45 42

54.82 42 67 58 75 57 37 47 76 46 3554.84 43 89 78 71 68 54 41 94 35 4554.86 47 90 98 114 62 45 48 88 49 4354.88 46 95 81 87 63 64 37 91 40 3754.9 42 94 93 72 58 48 50 95 44 46

54.92 56 75 79 71 67 52 43 88 40 4454.94 51 64 82 77 61 49 34 62 37 3554.96 48 75 74 83 49 50 51 60 43 2554.98 49 88 67 74 59 53 50 68 48 39

193

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

55 53 59 69 69 49 44 31 76 42 4755.02 60 68 69 74 57 49 36 57 41 3555.04 47 64 64 53 54 47 53 40 42 4455.06 44 65 66 54 52 47 38 47 44 4655.08 33 72 53 54 46 46 35 43 45 4355.1 33 50 67 78 53 59 29 44 47 34

55.12 39 50 44 57 48 49 53 48 47 3855.14 39 46 41 53 48 49 34 31 33 4655.16 35 60 38 43 50 39 50 33 36 3655.18 37 64 40 67 45 54 56 46 46 4455.2 35 61 33 57 47 44 37 39 50 31

55.22 40 61 61 61 46 49 54 50 42 4555.24 36 57 46 47 49 55 57 40 51 3555.26 41 70 61 72 59 43 62 47 44 3655.28 36 71 66 75 59 57 45 45 40 3055.3 41 65 57 65 49 59 34 67 56 37

55.32 39 73 62 53 63 67 56 74 45 4555.34 42 64 72 67 65 52 43 80 34 4955.36 35 83 67 73 44 54 42 70 57 3955.38 37 65 72 50 54 51 60 57 53 3455.4 35 67 69 79 56 48 38 35 47 35

55.42 45 67 48 54 61 52 53 39 41 3955.44 47 69 50 52 54 50 56 47 53 3155.46 45 55 61 54 50 44 58 66 50 3455.48 50 67 56 50 56 52 64 50 57 4055.5 32 76 48 59 57 57 75 44 53 43

55.52 41 58 53 41 58 35 44 43 59 3855.54 47 51 49 49 64 61 52 42 47 4355.56 48 50 45 43 56 54 58 31 77 3755.58 49 50 48 55 52 50 55 49 73 3455.6 49 58 48 49 54 48 72 33 88 34

55.62 44 49 50 43 57 51 70 46 101 4055.64 44 51 58 45 45 50 68 43 115 4155.66 28 50 44 62 51 40 97 38 92 3855.68 46 40 47 57 54 31 136 43 117 3855.7 52 49 42 45 50 45 138 39 136 45

55.72 36 45 42 63 50 48 150 36 177 4055.74 46 43 63 36 48 42 195 37 174 4555.76 42 52 60 53 58 53 252 32 139 5155.78 45 51 69 63 59 48 267 47 137 39

194

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

55.8 38 55 46 41 54 47 261 38 119 3455.82 49 47 56 53 52 41 213 38 102 4055.84 47 62 45 48 53 53 170 40 92 4455.86 34 54 48 60 45 45 156 41 115 3855.88 54 29 51 42 48 33 131 34 112 3455.9 53 41 54 54 50 51 146 35 106 49

55.92 56 53 55 54 44 44 137 40 98 4055.94 56 61 57 50 44 51 154 29 93 4355.96 50 53 47 56 35 54 128 44 64 4455.98 49 56 35 51 60 53 99 38 68 46

56 48 50 34 53 54 45 84 36 58 4756.02 57 47 49 51 52 44 95 38 51 3756.04 66 53 45 53 50 62 87 45 57 4056.06 45 60 44 57 56 54 53 39 47 3756.08 55 48 55 58 54 43 58 54 63 5256.1 51 59 38 56 57 59 63 51 48 37

56.12 47 49 60 55 72 49 52 48 56 6356.14 54 65 57 68 59 67 65 34 59 5156.16 55 64 56 54 69 56 57 34 52 6856.18 51 48 65 58 65 57 63 40 58 5956.2 47 69 57 69 61 56 51 52 68 52

56.22 67 77 51 79 54 71 53 41 59 6456.24 61 71 54 56 54 65 65 42 57 6156.26 70 68 67 80 64 67 57 53 60 5256.28 75 66 59 73 73 75 57 58 62 6956.3 87 56 63 95 82 69 77 61 67 55

56.32 75 82 70 73 84 89 81 74 77 8656.34 70 81 64 92 82 97 58 71 76 7856.36 81 74 62 92 99 96 81 78 87 7756.38 90 88 64 96 87 85 94 81 84 9156.4 90 82 82 96 101 87 112 92 104 78

56.42 114 83 83 110 120 99 116 87 96 9756.44 133 109 111 101 120 103 111 101 121 11356.46 159 125 106 138 151 105 147 140 127 11656.48 188 138 125 142 162 154 127 144 164 16556.5 285 142 158 209 169 145 196 177 204 197

56.52 402 166 190 237 246 185 198 253 290 24856.54 546 173 221 295 334 256 228 300 323 27656.56 555 242 247 387 333 317 269 417 415 34956.58 502 242 292 418 418 354 331 516 424 433

195

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

56.6 405 327 333 388 383 382 351 617 432 42056.62 320 364 331 365 454 388 392 604 388 42756.64 242 380 313 322 403 372 349 535 343 37956.66 278 367 305 279 366 320 306 465 299 33156.68 285 324 317 277 307 314 284 375 260 33356.7 275 311 275 277 304 312 251 312 278 308

56.72 312 296 267 247 308 281 252 328 255 28956.74 275 266 248 232 267 268 231 356 255 26656.76 189 232 233 219 263 228 249 336 212 24756.78 155 223 235 200 245 251 230 265 198 23856.8 135 224 200 191 208 217 190 240 170 195

56.82 104 218 198 170 205 191 180 203 151 16156.84 92 209 156 144 165 166 151 172 113 11956.86 84 181 152 106 145 142 134 134 104 15256.88 88 156 128 114 109 120 111 112 77 13256.9 82 153 123 111 114 97 100 82 88 121

56.92 107 140 105 107 98 107 100 95 85 9456.94 72 130 109 108 112 90 91 73 76 8756.96 92 109 96 101 89 93 84 83 77 9456.98 66 128 109 105 97 76 90 98 81 110

57 64 113 93 97 103 96 99 88 84 8657.02 79 99 103 86 105 87 79 79 84 11757.04 99 111 86 104 126 102 93 76 86 9857.06 105 89 95 97 96 97 93 96 80 9157.08 98 115 114 113 120 92 110 90 112 10857.1 125 117 104 107 119 81 99 110 109 109

57.12 129 144 111 130 125 105 116 112 96 12757.14 134 116 114 125 144 114 97 119 121 11857.16 134 140 115 142 159 139 116 121 141 13557.18 137 137 133 165 124 143 135 109 126 14457.2 168 149 168 155 180 122 136 148 160 135

57.22 179 139 142 161 194 174 158 156 174 16957.24 221 162 190 183 214 173 170 177 173 19157.26 223 167 171 226 210 203 178 178 168 21257.28 313 215 213 252 251 222 212 208 230 24357.3 419 234 229 284 293 237 256 272 296 275

57.32 463 267 258 398 355 309 279 344 345 36657.34 737 305 329 461 421 365 388 381 487 51657.36 1023 366 451 627 584 487 466 581 560 64957.38 1426 460 534 774 698 632 590 748 741 741

196

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

57.4 1641 529 625 869 836 676 693 975 834 86357.42 1280 626 729 929 960 831 788 1249 974 98957.44 1081 684 867 840 948 888 809 1449 936 100657.46 774 825 805 790 925 891 815 1449 766 94857.48 607 838 800 738 854 832 780 1255 715 86057.5 573 817 778 627 704 802 739 967 673 780

57.52 656 731 772 604 656 667 628 794 588 71057.54 765 674 659 571 655 652 606 756 553 65257.56 740 650 643 627 593 685 562 739 538 66557.58 571 589 587 547 606 545 513 809 498 61757.6 462 564 593 505 561 511 517 796 493 576

57.62 317 541 554 445 491 472 433 666 402 48657.64 238 497 466 337 414 442 430 531 316 41257.66 184 452 443 302 326 378 345 382 283 33057.68 163 373 366 280 281 311 284 319 213 30457.7 123 306 314 208 214 262 249 232 182 252

57.72 121 312 298 169 181 211 188 202 149 19857.74 128 262 226 157 169 174 184 152 128 16157.76 94 223 176 138 157 167 155 130 138 15257.78 84 185 186 127 117 146 152 108 128 12657.8 97 174 158 118 137 134 138 111 114 152

57.82 94 162 133 132 114 110 137 93 109 11957.84 67 133 123 123 113 116 88 106 101 12157.86 92 118 113 123 103 88 92 91 102 9957.88 53 119 99 88 125 112 94 77 91 9557.9 75 113 91 91 103 96 105 72 80 88

57.92 77 108 105 88 105 87 96 68 83 8857.94 80 105 103 86 92 96 94 78 64 9557.96 83 100 94 91 93 76 93 82 98 8457.98 101 103 89 96 95 76 100 71 98 95

58 120 109 84 100 106 92 84 89 98 9358.02 134 105 99 102 131 99 101 81 117 10058.04 219 107 100 98 126 102 90 113 129 12558.06 268 119 105 132 147 125 107 128 125 11958.08 226 99 129 129 163 140 117 158 148 14958.1 215 138 112 153 148 142 121 168 130 126

58.12 197 117 128 149 157 143 97 192 147 15458.14 91 136 123 133 150 138 134 169 123 15258.16 115 143 144 127 144 154 125 156 134 14358.18 109 134 136 114 129 131 124 126 108 132

197

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

58.2 136 138 142 117 117 103 109 122 114 11158.22 162 135 111 89 101 114 110 135 120 10558.24 119 125 132 107 133 84 113 108 136 9858.26 120 104 128 111 105 102 107 134 130 11358.28 88 116 88 99 92 107 87 111 76 9358.3 64 110 92 87 86 103 83 113 75 86

58.32 61 99 100 76 89 79 89 79 65 8058.34 46 101 93 88 78 93 75 68 65 8858.36 54 97 93 69 76 77 76 70 59 5858.38 35 90 77 71 58 75 72 60 51 7858.4 39 91 75 65 67 71 63 49 60 54

58.42 57 91 59 59 73 62 67 41 51 5458.44 47 69 59 72 61 69 53 37 47 5658.46 44 67 58 58 58 54 49 47 40 4958.48 28 72 54 50 51 47 66 43 59 6058.5 56 61 52 48 62 54 47 44 39 46

58.52 38 65 54 50 53 54 47 48 61 5158.54 46 59 62 50 46 48 47 31 45 4658.56 48 58 43 47 70 44 43 42 52 3358.58 36 48 48 51 47 43 60 28 41 4558.6 29 52 49 42 44 55 49 53 58 50

58.62 37 54 50 38 52 40 60 38 54 4558.64 46 61 50 49 55 48 46 40 48 4758.66 39 52 48 45 54 34 41 40 39 3658.68 54 50 42 38 51 41 42 33 45 4258.7 41 43 30 27 46 41 37 34 58 41

58.72 50 50 52 39 49 43 52 34 35 5058.74 48 50 55 36 41 65 43 48 48 4858.76 31 41 39 53 46 54 37 25 45 3158.78 39 51 43 54 54 33 47 38 55 4358.8 44 66 41 49 51 40 43 41 44 33

58.82 34 47 45 52 39 52 38 38 62 5158.84 44 49 61 53 44 33 51 39 65 4858.86 39 56 50 33 57 44 51 38 78 5058.88 24 45 47 48 47 44 38 39 68 2958.9 47 52 34 44 36 44 48 42 79 45

58.92 51 43 37 43 30 34 60 41 92 4658.94 43 45 53 52 43 46 52 42 107 3058.96 46 44 38 45 46 48 42 32 143 4858.98 37 43 38 41 46 47 46 41 123 35

198

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

59 49 47 37 43 48 44 35 47 106 4359.02 29 53 39 40 46 39 45 32 94 3659.04 40 48 43 49 47 39 40 32 88 3259.06 33 46 44 51 50 37 39 36 89 4059.08 38 50 28 51 35 41 31 25 100 3959.1 49 38 37 44 57 45 38 34 72 37

59.12 37 52 45 44 53 42 41 42 93 3759.14 34 64 31 50 45 43 47 29 74 4059.16 49 38 42 50 46 50 37 38 59 3259.18 39 41 35 45 44 44 38 34 62 3659.2 37 41 47 50 47 48 45 34 61 38

59.22 33 37 32 49 49 36 40 33 44 4659.24 35 47 42 42 46 45 40 39 49 3759.26 35 41 31 49 57 45 43 33 58 4059.28 28 48 37 40 54 45 35 28 48 3559.3 49 42 30 52 65 30 49 35 39 46

59.32 33 48 40 42 44 48 41 31 58 3759.34 45 51 40 38 43 43 40 34 47 4559.36 38 50 48 53 39 32 35 36 49 3859.38 50 38 38 49 51 48 40 26 45 4159.4 46 60 36 40 43 51 45 40 35 42

59.42 39 49 36 41 41 44 41 30 51 4359.44 41 55 47 50 45 36 33 43 62 4459.46 36 46 52 47 41 46 50 38 41 4159.48 38 48 49 48 42 44 46 40 29 3959.5 34 53 36 50 49 45 49 41 50 42

59.52 39 52 41 55 36 27 52 34 54 4259.54 42 36 40 40 51 51 42 41 54 2859.56 35 58 41 47 54 48 41 32 48 3559.58 31 47 52 56 38 45 55 35 34 4359.6 34 46 45 46 43 31 40 38 44 43

59.62 37 53 46 48 46 42 38 39 48 3959.64 36 56 36 36 44 44 41 41 59 4159.66 44 64 40 51 51 45 49 49 50 3359.68 45 62 42 37 64 50 51 43 52 4459.7 35 48 38 47 55 50 43 38 61 34

59.72 44 58 40 62 57 53 45 40 54 3959.74 41 61 45 55 54 47 38 41 76 5059.76 42 75 55 59 46 40 40 31 81 4859.78 37 64 74 61 47 44 48 43 99 39

199

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

59.8 34 64 62 76 64 38 39 49 93 4559.82 35 73 58 68 48 48 42 32 99 3959.84 43 77 76 73 54 60 45 47 104 4159.86 30 85 79 105 62 46 46 56 94 4059.88 44 108 67 131 68 70 44 63 81 4159.9 40 102 103 139 67 54 40 69 92 34

59.92 36 117 129 150 73 55 44 69 88 3559.94 36 121 131 159 78 79 70 96 89 4559.96 66 121 143 147 74 61 53 149 82 4759.98 52 106 130 125 73 57 44 143 68 61

60 42 89 103 109 78 56 60 135 60 5560.02 53 96 81 77 59 50 68 100 82 4060.04 49 89 95 90 71 56 67 78 67 6160.06 30 90 97 100 63 60 50 54 62 4560.08 48 100 94 110 54 61 44 67 51 5760.1 49 84 97 99 61 77 46 81 49 50

60.12 58 85 105 106 70 48 46 93 44 4260.14 42 82 82 72 57 58 46 78 53 4260.16 57 61 87 80 75 61 54 56 44 4960.18 44 86 78 69 62 63 60 84 45 4560.2 51 58 61 62 61 48 47 61 53 62

60.22 54 59 43 58 65 53 49 56 48 6860.24 45 75 55 77 53 53 52 61 53 5460.26 58 61 52 76 69 61 72 60 54 6160.28 62 69 59 61 69 58 69 62 54 5560.3 83 60 69 63 64 66 66 58 65 61

60.32 63 63 59 67 71 54 56 51 70 5660.34 68 63 70 70 76 66 81 61 63 7760.36 83 77 70 69 83 77 57 76 63 5960.38 88 78 72 86 92 64 79 80 84 7760.4 94 86 79 74 88 80 80 89 82 92

60.42 85 83 72 89 88 78 87 81 78 6860.44 92 94 91 102 108 88 81 96 103 7760.46 109 77 89 96 112 78 97 92 97 9460.48 108 96 89 111 110 99 101 105 91 9660.5 113 109 98 98 124 99 89 117 115 106

60.52 139 125 129 127 144 94 114 115 129 11960.54 148 115 115 115 163 133 131 134 145 14860.56 190 154 133 162 168 132 156 140 176 14360.58 273 142 139 182 210 185 154 206 196 200

200

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

60.6 368 183 179 246 260 192 210 248 278 26660.62 480 194 203 319 315 261 234 363 343 33060.64 690 241 275 403 408 337 314 448 472 42660.66 815 318 336 527 525 416 352 581 562 57060.68 860 355 399 601 579 491 437 716 637 57660.7 662 442 434 549 611 567 488 904 663 652

60.72 482 455 482 567 642 578 569 906 582 64560.74 367 496 501 519 547 495 514 921 528 55260.76 332 482 492 450 516 489 502 786 441 51460.78 340 466 474 440 428 441 436 666 403 48160.8 405 463 411 391 436 423 401 600 370 420

60.82 491 434 405 394 428 450 366 570 425 38660.84 444 377 391 365 421 417 368 480 385 41160.86 361 360 393 374 398 403 359 494 388 38360.88 346 376 375 392 400 406 351 490 371 38660.9 291 414 366 291 350 335 346 510 344 363

60.92 310 369 328 308 345 352 301 476 308 35360.94 321 370 319 308 339 311 298 421 302 32560.96 451 299 316 320 302 294 274 399 304 34460.98 586 300 327 295 317 287 301 379 306 360

61 885 294 312 352 324 312 287 409 347 33961.02 754 323 302 344 315 326 293 400 338 34961.04 505 315 274 308 327 260 314 462 312 34061.06 309 278 296 299 303 312 270 474 305 33061.08 265 288 287 277 266 272 252 412 251 31661.1 237 274 274 255 252 291 224 382 251 246

61.12 262 270 267 214 257 210 221 292 239 26461.14 298 243 234 232 212 235 216 265 211 22161.16 399 249 223 218 235 222 211 259 201 23261.18 420 245 230 222 231 227 211 254 210 19461.2 284 210 219 192 249 212 202 264 188 222

61.22 223 211 219 207 213 214 215 238 153 22961.24 201 202 181 175 203 186 184 285 169 19661.26 162 173 171 172 208 197 169 235 178 20261.28 183 198 223 163 185 181 177 247 148 16661.3 221 191 176 209 168 184 157 206 213 184

61.32 332 210 212 222 204 238 178 200 208 22661.34 379 203 202 249 222 203 191 228 235 21861.36 446 191 216 252 260 226 217 298 240 27761.38 470 206 266 257 275 270 222 337 259 300

201

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

61.4 375 194 261 271 257 252 247 362 279 31161.42 294 227 265 265 292 267 275 390 254 30061.44 207 250 250 269 261 268 236 358 245 27861.46 191 208 244 221 233 231 239 302 238 24861.48 182 240 240 194 226 224 216 295 213 24261.5 207 222 222 198 201 209 185 248 206 207

61.52 247 219 215 158 196 202 193 235 179 19661.54 232 192 216 207 207 196 151 222 156 20061.56 222 174 189 200 201 179 157 236 148 19461.58 178 184 192 163 170 163 145 230 180 17261.6 130 170 168 136 178 190 147 188 125 162

61.62 82 163 166 142 155 172 129 170 134 15161.64 92 160 142 122 133 127 134 151 106 14861.66 69 173 137 112 116 146 124 124 93 10461.68 65 132 136 97 112 113 106 118 75 12161.7 63 122 112 93 110 105 101 81 82 81

61.72 60 93 116 102 90 95 86 78 66 9861.74 58 95 97 67 93 85 68 62 79 8761.76 56 113 101 69 79 80 76 44 51 6361.78 60 76 79 62 66 72 64 60 57 8061.8 52 76 66 79 68 84 74 60 72 54

61.82 54 84 72 61 66 62 55 45 62 5261.84 48 75 52 74 64 63 70 60 55 7261.86 47 82 57 59 68 55 58 45 57 4861.88 44 68 60 63 62 60 62 44 53 5261.9 46 60 56 59 64 52 53 50 47 44

61.92 29 58 55 63 52 68 63 45 45 4661.94 44 54 52 57 58 52 45 32 46 5761.96 41 59 49 45 63 47 58 42 53 4861.98 38 56 56 59 65 47 50 44 47 39

62 57 56 52 58 53 61 47 49 54 3662.02 44 57 46 47 50 43 52 39 42 5062.04 47 61 44 67 57 45 41 43 48 4162.06 38 43 45 53 38 54 37 39 40 4762.08 49 58 49 47 47 49 42 30 53 4862.1 50 51 39 51 67 44 41 39 57 41

62.12 33 44 46 55 36 47 49 45 53 4962.14 38 58 44 62 46 46 35 40 52 4362.16 47 67 45 47 58 38 34 29 62 3462.18 45 50 48 47 45 49 40 31 56 45

202

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

62.2 37 70 46 45 44 52 37 32 55 3862.22 48 60 70 54 49 51 49 45 66 4362.24 41 64 37 53 57 41 42 53 67 4062.26 37 66 44 52 55 60 49 38 71 3362.28 46 58 50 50 44 63 36 40 88 3462.3 36 60 46 62 66 62 35 38 69 45

62.32 37 66 56 64 62 50 54 33 59 3162.34 40 61 49 56 57 53 50 33 65 4162.36 37 51 46 45 54 45 41 31 51 3862.38 41 66 36 52 39 51 40 49 51 5062.4 35 74 51 40 72 48 40 28 45 38

62.42 38 71 53 57 54 55 42 32 60 4262.44 33 73 45 53 56 53 46 37 53 4762.46 38 47 49 59 57 51 49 31 57 3162.48 40 73 51 58 66 40 59 39 45 3562.5 47 65 37 53 44 57 44 41 42 39

62.52 44 46 41 49 52 42 46 41 43 4162.54 32 73 39 54 53 47 33 36 38 4662.56 41 37 43 45 46 42 47 34 47 3962.58 27 52 44 50 49 42 46 43 40 3962.6 45 53 51 47 54 41 41 43 51 48

62.62 40 53 44 62 63 61 35 36 45 4662.64 46 59 42 38 43 55 40 44 57 4762.66 40 56 44 55 62 49 52 39 47 4962.68 45 49 39 50 62 42 47 38 46 5462.7 46 58 55 52 64 48 38 45 59 50

62.72 42 64 54 46 56 45 62 44 45 4262.74 61 55 45 59 62 48 51 50 52 5062.76 49 58 57 61 57 58 50 40 50 5362.78 57 61 52 70 70 53 52 53 52 6462.8 52 56 57 58 63 48 54 53 51 46

62.82 55 74 75 48 52 44 46 55 49 5862.84 59 51 62 61 77 55 58 53 65 6462.86 59 74 56 72 71 54 65 68 82 7262.88 69 58 74 70 78 59 60 46 61 8362.9 72 60 73 72 69 67 76 67 73 73

62.92 88 66 78 79 87 75 68 77 71 8762.94 98 70 71 81 89 79 99 78 92 9162.96 120 80 74 111 112 70 98 73 84 9462.98 147 98 84 100 109 92 81 87 101 132

203

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

63 233 112 90 153 116 103 102 127 159 12163.02 319 113 118 164 162 130 135 157 198 15863.04 318 128 134 165 191 136 149 193 187 17663.06 349 139 144 206 207 171 155 266 200 19363.08 300 174 149 239 219 191 181 292 229 25063.1 217 175 161 230 231 208 174 356 235 226

63.12 178 178 192 195 216 191 198 284 225 22563.14 155 174 150 213 200 192 173 253 189 21063.16 141 175 174 163 165 178 167 209 189 18663.18 161 173 160 157 160 165 165 179 177 15663.2 168 165 164 156 149 159 133 178 142 179

63.22 195 182 139 183 171 149 145 172 136 16663.24 184 158 130 131 161 145 130 156 144 15563.26 149 161 141 162 161 151 152 171 153 16463.28 118 168 128 105 145 135 126 189 141 13963.3 82 153 130 124 141 118 125 177 126 112

63.32 86 128 113 109 108 131 111 114 105 9063.34 59 136 111 78 102 111 101 134 94 8163.36 51 108 117 80 105 107 96 92 93 9563.38 67 96 102 83 90 82 69 71 94 6763.4 60 107 92 76 80 91 89 83 111 65

63.42 43 92 82 77 86 79 75 58 94 6963.44 63 84 72 69 52 66 65 60 89 6963.46 51 85 66 69 57 67 59 63 98 6763.48 43 83 89 61 72 62 62 52 87 5163.5 57 82 68 53 54 59 52 50 92 56

63.52 44 64 53 65 41 49 66 52 81 4863.54 42 56 35 56 59 57 44 59 81 4063.56 58 65 62 50 59 46 46 42 82 4063.58 34 61 64 52 63 56 56 37 69 3663.6 46 54 59 59 55 55 52 41 62 46

63.62 36 61 65 52 41 48 47 42 65 5763.64 33 79 44 58 61 50 42 42 61 5663.66 48 59 32 59 44 44 57 33 60 4863.68 36 57 49 57 52 45 47 39 57 5163.7 48 58 60 38 50 50 49 27 44 40

63.72 42 43 42 62 43 48 45 34 56 3763.74 45 47 55 46 57 59 50 41 47 5263.76 45 47 35 58 53 56 46 32 36 3863.78 40 52 40 52 44 55 54 34 60 52

204

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

63.8 52 47 46 48 57 71 42 45 48 5163.82 50 65 45 52 46 48 46 43 48 4963.84 58 57 39 45 42 53 51 35 51 3963.86 59 59 43 40 58 44 48 40 65 4063.88 42 51 43 54 50 35 45 36 47 5163.9 50 75 45 56 50 53 51 42 31 46

63.92 47 56 53 67 45 63 41 38 37 3763.94 47 60 55 66 59 51 46 52 47 4763.96 41 52 57 58 55 46 48 48 36 4563.98 42 63 53 57 48 60 46 39 45 44

64 54 61 79 64 54 56 48 42 34 4264.02 39 67 72 61 67 54 43 46 42 5164.04 36 59 54 46 54 48 57 39 42 4564.06 41 65 58 63 62 41 50 53 38 4264.08 42 52 66 52 61 49 55 42 45 3964.1 56 62 47 57 66 56 45 34 46 51

64.12 40 82 62 51 61 53 46 39 45 5064.14 52 58 51 67 54 48 42 38 34 4264.16 35 70 60 73 57 53 48 42 40 5064.18 45 52 67 76 50 49 57 45 69 5464.2 50 59 56 64 55 55 44 45 54 56

64.22 54 61 60 57 72 50 58 49 56 5464.24 49 71 54 70 67 67 57 38 47 5464.26 47 69 58 71 71 56 51 50 55 5264.28 69 83 41 64 86 62 63 56 57 6764.3 78 69 68 60 79 80 86 56 75 63

64.32 71 69 60 67 73 74 84 62 76 5564.34 71 62 64 91 81 85 63 59 69 6764.36 78 68 70 76 82 65 72 68 79 8564.38 82 83 76 80 86 76 66 69 81 7764.4 111 76 91 97 103 81 73 77 87 79

64.42 96 86 73 107 94 68 103 84 98 8764.44 80 96 86 107 114 97 101 80 108 10264.46 112 98 104 101 122 103 92 108 112 11664.48 126 101 97 105 137 102 99 93 115 11064.5 136 100 102 119 122 101 104 109 113 126

64.52 144 120 117 147 148 122 137 129 146 12864.54 188 107 125 167 174 142 121 167 177 14164.56 216 138 157 202 183 149 127 169 185 20764.58 298 146 129 248 222 159 161 190 237 239

205

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

64.6 467 189 212 311 316 233 220 267 292 28064.62 577 216 221 379 362 281 262 387 388 37164.64 808 269 266 467 450 378 323 556 472 43364.66 843 304 359 501 549 464 409 656 543 50664.68 747 373 402 573 649 474 455 778 565 62364.7 649 486 416 557 631 554 477 803 595 648

64.72 465 510 449 515 615 570 519 782 535 61264.74 344 522 487 460 530 504 511 626 445 58464.76 307 532 488 387 472 487 443 602 399 47764.78 281 497 427 362 462 420 379 456 364 48364.8 359 457 394 350 408 409 332 439 341 393

64.82 404 426 386 390 356 391 369 470 330 40764.84 423 393 348 349 372 383 359 433 307 38164.86 431 379 314 334 435 348 359 461 329 40364.88 340 347 325 311 333 353 307 449 345 39264.9 223 380 347 304 385 337 326 386 271 293

64.92 189 347 291 242 286 313 279 329 238 31564.94 138 328 284 243 251 287 236 290 188 25464.96 127 294 272 196 207 227 194 235 182 22564.98 106 246 228 169 178 182 182 167 138 172

65 90 223 204 138 139 173 164 146 133 15765.02 83 194 135 126 140 146 142 135 112 11365.04 67 175 147 105 136 106 110 109 91 10365.06 62 154 144 97 96 118 129 101 109 10165.08 87 154 128 94 106 107 102 100 107 11265.1 81 136 90 103 87 105 102 82 79 101

65.12 64 114 105 102 83 100 84 73 95 8865.14 58 127 95 74 104 80 86 80 83 10065.16 62 94 84 86 79 90 74 67 71 7365.18 65 98 90 78 71 78 76 63 82 8365.2 75 99 91 79 75 85 69 65 84 62

65.22 68 95 76 67 77 54 75 76 80 7265.24 56 77 66 70 74 73 76 59 77 7865.26 67 77 85 80 62 83 59 53 66 7765.28 62 74 65 84 75 75 65 53 69 5865.3 90 90 82 76 73 73 70 68 55 70

65.32 78 65 68 73 97 56 72 63 77 6765.34 69 73 64 96 77 79 78 59 87 9465.36 85 67 85 103 77 80 76 71 93 8465.38 80 82 87 87 77 68 75 68 95 80

206

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

65.4 70 81 99 85 76 87 83 74 118 8665.42 92 78 85 88 82 78 75 94 146 8965.44 91 95 90 93 99 78 75 83 144 7865.46 86 76 109 107 109 88 87 84 140 10265.48 112 76 93 114 132 104 103 89 145 12565.5 129 107 111 129 136 123 95 120 173 132

65.52 159 117 129 135 159 112 107 151 165 13865.54 216 123 131 174 185 126 139 171 199 19865.56 312 132 165 225 197 137 164 197 234 18865.58 314 166 197 243 246 180 181 286 274 23265.6 322 154 170 288 291 192 188 412 306 304

65.62 301 192 223 290 285 220 235 463 335 32365.64 251 216 227 278 302 276 287 710 345 34265.66 208 239 247 291 307 230 253 821 371 30665.68 155 233 277 281 307 257 261 680 323 30965.7 168 242 254 224 262 247 241 482 270 318

65.72 157 215 253 230 267 244 229 415 239 30165.74 157 248 247 213 239 216 207 351 251 24665.76 186 213 246 188 220 191 211 280 200 22865.78 190 215 193 215 209 202 194 281 204 22065.8 188 197 230 199 247 203 167 309 222 231

65.82 139 207 201 187 224 199 170 372 225 21565.84 130 196 192 173 197 192 207 454 207 20465.86 108 162 180 176 178 176 153 358 163 18365.88 72 160 172 153 159 140 151 287 143 16465.9 66 164 190 125 131 152 139 188 134 167

65.92 60 163 134 117 118 135 128 157 120 12465.94 54 157 140 94 113 115 117 161 99 11665.96 61 135 125 102 112 102 84 118 95 9665.98 54 110 124 79 78 96 93 79 77 82

66 40 113 92 82 78 83 89 73 91 8666.02 50 105 96 70 86 65 69 70 74 8766.04 48 92 90 74 60 61 70 67 79 6866.06 40 70 74 76 66 50 70 55 68 6866.08 34 77 76 70 65 68 51 48 66 5566.1 43 73 61 62 56 60 68 49 73 39

66.12 51 68 64 60 51 64 63 53 52 6466.14 37 88 64 54 53 60 49 44 51 5666.16 49 57 55 51 52 58 45 48 55 5366.18 40 55 57 41 44 46 51 23 53 42

207

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

66.2 38 60 52 40 54 46 48 57 57 4366.22 46 75 64 48 62 41 58 44 54 4866.24 48 60 40 50 53 51 48 41 51 4966.26 53 41 41 47 49 40 50 36 57 5066.28 57 58 40 43 49 36 46 42 42 5566.3 42 60 45 48 39 37 32 38 47 53

66.32 43 49 42 49 46 42 53 39 45 4566.34 39 50 45 39 48 44 42 41 41 5066.36 25 58 42 44 55 48 36 34 47 3566.38 29 55 50 54 37 33 41 29 46 5266.4 32 50 43 49 33 45 42 39 42 39

66.42 27 45 47 55 38 38 32 20 40 4566.44 40 32 34 38 53 29 41 32 34 4466.46 52 49 26 65 43 33 49 39 50 3966.48 40 51 38 49 32 42 45 29 43 2866.5 47 52 44 42 49 48 29 30 48 32

66.52 38 41 45 46 48 34 42 38 41 3666.54 36 49 30 39 36 46 36 33 39 3066.56 37 39 39 47 43 38 48 35 42 3866.58 33 50 35 36 41 38 32 32 37 3666.6 31 44 26 39 41 49 38 37 43 35

66.62 42 48 35 27 46 39 39 30 38 3866.64 39 49 42 42 30 44 35 42 26 3466.66 39 46 36 52 43 34 32 24 44 3466.68 30 41 36 34 34 33 41 37 37 3466.7 48 53 36 42 40 41 44 30 46 36

66.72 41 44 44 35 34 48 39 31 51 3666.74 32 45 27 43 45 38 31 43 42 2466.76 30 40 33 37 45 34 46 38 49 3466.78 32 46 29 36 23 38 34 25 45 3366.8 39 37 40 44 24 40 38 28 58 34

66.82 33 30 41 38 41 37 29 30 50 3366.84 33 39 31 36 49 38 32 34 51 3966.86 32 42 41 48 37 40 39 27 45 2666.88 33 38 43 35 50 25 31 37 58 2466.9 35 38 28 32 37 34 41 37 46 35

66.92 29 42 29 38 30 42 49 31 54 2566.94 32 40 29 35 41 46 34 31 57 3866.96 46 40 39 46 48 33 35 24 56 2866.98 29 43 29 42 40 34 38 31 64 38

208

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

67 33 49 47 47 40 29 26 36 58 3767.02 35 33 28 37 45 40 38 31 50 4367.04 36 40 32 40 39 38 40 36 53 3767.06 36 50 34 49 52 36 41 37 52 3867.08 30 41 43 36 36 38 41 37 59 3267.1 30 43 30 37 35 46 32 34 52 38

67.12 35 46 48 41 41 38 30 37 47 3167.14 42 43 38 29 37 50 37 26 62 4067.16 37 44 35 37 50 34 46 36 62 3467.18 38 39 32 44 33 28 33 37 47 3467.2 36 38 38 38 36 40 36 32 43 32

67.22 39 41 32 38 36 39 45 29 56 5367.24 40 42 31 39 37 44 43 34 46 4867.26 44 32 29 41 37 35 39 31 42 3067.28 42 44 39 46 44 38 43 28 54 4067.3 28 52 37 38 40 34 39 31 81 28

67.32 32 42 38 33 42 46 35 41 61 4967.34 38 43 45 48 38 33 41 27 92 2767.36 29 42 40 34 37 41 39 43 70 2967.38 33 49 30 45 51 41 26 40 65 3467.4 39 52 37 34 33 37 33 39 81 29

67.42 42 41 42 46 47 50 31 39 70 3567.44 35 47 43 38 45 48 49 32 63 3567.46 26 40 42 41 40 39 33 34 66 3567.48 29 47 37 35 37 35 38 35 67 3467.5 38 47 36 37 41 31 47 32 72 33

67.52 38 48 48 52 43 33 53 41 44 3667.54 30 49 41 45 42 35 28 35 53 3467.56 32 42 36 44 37 40 45 38 52 3967.58 42 43 46 57 47 42 32 36 52 4167.6 35 50 52 60 41 44 47 40 54 32

67.62 31 61 46 39 42 39 41 56 45 2967.64 40 54 37 53 42 43 36 34 52 3567.66 35 80 63 67 40 41 29 38 36 2767.68 44 65 62 80 51 36 42 55 44 3667.7 29 81 78 71 62 41 37 59 40 36

67.72 29 96 82 74 57 40 42 99 41 4067.74 45 98 74 76 58 55 44 130 50 2967.76 35 106 73 63 63 36 39 142 30 4067.78 27 88 71 60 37 48 46 86 32 30

209

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

67.8 32 68 50 58 44 42 42 84 37 2767.82 47 64 52 53 39 44 37 68 43 3867.84 24 44 47 56 39 40 47 49 31 3567.86 35 54 61 64 39 47 43 53 35 4067.88 26 68 71 78 50 45 45 52 30 2767.9 46 72 65 53 56 28 33 52 37 35

67.92 27 70 58 62 52 36 45 72 28 3567.94 29 76 74 62 42 61 37 70 43 3467.96 38 59 77 50 51 43 47 75 34 3267.98 29 70 52 50 54 42 30 63 32 37

68 32 65 50 60 50 38 36 55 38 3768.02 36 51 59 68 43 31 39 57 24 3468.04 33 67 76 81 53 28 38 47 41 3168.06 35 71 60 92 66 39 36 70 45 4168.08 28 76 68 82 61 56 35 70 28 2968.1 32 88 76 97 70 43 46 112 38 37

68.12 36 85 84 102 67 57 39 143 36 3268.14 40 80 84 97 55 57 36 191 35 3768.16 40 86 82 83 46 47 42 236 41 3768.18 34 85 85 82 62 43 44 162 35 3768.2 33 68 83 69 61 37 34 122 41 26

68.22 33 77 82 80 52 42 37 98 33 3268.24 28 75 59 85 54 37 39 91 38 3168.26 40 94 82 95 55 49 36 88 44 3768.28 37 74 90 86 68 62 35 110 32 4268.3 44 83 101 85 66 55 44 138 32 41

68.32 35 80 91 89 43 33 47 139 35 3468.34 29 82 87 75 70 53 44 151 39 3968.36 27 74 69 55 51 48 46 136 39 3968.38 28 72 62 62 37 33 29 110 36 3768.4 33 73 56 51 48 46 42 83 38 28

68.42 38 70 39 69 53 45 49 53 34 2768.44 43 63 68 60 52 40 38 62 39 4168.46 26 62 59 65 41 37 41 59 39 2668.48 32 64 60 55 48 49 52 50 41 2968.5 30 50 51 48 49 49 52 40 35 44

68.52 25 55 50 43 52 31 39 37 33 3468.54 35 52 57 47 52 35 43 47 33 3968.56 35 40 61 42 40 41 46 40 42 3568.58 36 50 42 56 39 54 52 35 34 40

210

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

68.6 31 47 39 37 40 55 54 41 42 2368.62 32 46 46 38 32 38 72 41 39 4168.64 35 40 33 56 45 50 66 39 40 3468.66 30 37 44 35 40 42 64 28 40 4368.68 44 40 29 32 46 40 65 27 44 3268.7 35 43 45 48 39 40 55 27 37 34

68.72 42 49 36 33 42 34 42 26 35 3268.74 38 36 36 39 39 39 50 36 35 4368.76 40 40 47 28 25 43 50 44 38 3068.78 30 42 38 46 34 32 45 34 39 4968.8 45 40 36 42 58 42 61 42 33 40

68.82 40 30 41 44 33 49 43 35 35 3568.84 37 37 35 46 35 45 58 33 45 2568.86 50 52 46 43 49 48 53 33 49 3968.88 46 35 38 49 36 49 48 36 37 3968.9 43 37 28 35 42 37 49 39 43 55

68.92 45 52 40 51 44 43 51 37 45 4668.94 43 39 35 49 46 46 45 50 49 5068.96 49 45 51 54 58 42 59 44 47 4268.98 45 52 45 59 55 41 58 32 49 56

69 49 48 44 57 51 59 48 46 53 3669.02 56 58 62 59 45 42 52 43 48 5669.04 53 53 59 44 49 34 55 35 59 5769.06 57 50 54 52 53 51 54 47 51 6269.08 81 67 46 71 57 42 52 52 66 7269.1 76 60 53 73 77 57 39 67 81 55

69.12 98 79 65 94 102 68 62 64 88 7769.14 141 73 84 92 98 81 83 84 93 8569.16 183 88 73 95 103 93 91 81 114 8669.18 214 89 79 145 118 92 92 132 129 12669.2 181 83 85 124 155 110 98 162 140 153

69.22 157 106 104 149 133 127 125 166 162 16369.24 117 104 129 134 146 118 132 174 118 12569.26 104 129 106 122 116 122 121 181 114 14869.28 87 112 113 119 126 121 109 159 113 12169.3 87 129 115 109 114 124 118 138 112 119

69.32 78 115 111 100 101 101 94 100 90 9969.34 103 126 110 101 103 93 71 86 92 9869.36 107 105 97 99 92 107 75 89 95 11669.38 103 98 115 99 83 89 100 91 81 85

211

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

69.4 71 103 104 88 108 101 74 100 92 10769.42 82 91 84 90 74 107 81 111 113 10169.44 81 76 86 84 106 73 93 93 91 9069.46 47 83 74 86 78 93 92 87 80 9969.48 48 78 94 80 76 81 75 94 66 9169.5 51 98 84 65 79 80 52 86 61 69

69.52 43 91 70 74 81 58 62 66 64 5969.54 48 71 74 55 62 69 71 52 46 5169.56 45 62 60 41 65 59 65 42 45 6169.58 49 62 48 47 56 60 62 48 51 5269.6 54 64 52 49 54 55 45 34 52 47

69.62 38 54 56 55 54 46 47 43 43 4369.64 43 56 38 49 59 49 49 38 41 5869.66 41 52 55 46 52 54 48 42 41 4169.68 48 61 49 51 42 42 52 37 51 4069.7 45 50 54 60 47 45 52 42 38 48

69.72 33 48 48 42 46 52 52 32 54 3969.74 50 63 55 40 63 46 33 34 35 4269.76 47 57 39 50 39 32 39 25 45 3969.78 52 61 35 39 35 46 39 40 37 3369.8 25 42 53 41 55 49 56 33 51 49

69.82 52 55 36 46 54 46 30 30 38 3969.84 46 48 43 44 44 41 42 28 43 4769.86 44 50 47 61 41 34 52 37 47 3969.88 42 39 49 64 40 58 48 40 46 5869.9 57 56 33 54 46 38 38 37 60 48

69.92 53 59 46 52 61 56 51 53 28 4569.94 52 49 45 40 64 47 40 33 48 5369.96 47 52 40 60 61 56 44 43 42 4369.98 58 60 54 55 62 57 53 41 56 58

70 49 56 37 55 57 52 63 50 56 5370.02 59 60 53 54 56 50 61 45 57 5470.04 72 56 57 46 63 60 55 57 67 5170.06 66 52 62 53 62 61 59 57 83 6770.08 66 50 53 61 70 55 69 61 70 6170.1 89 70 57 71 67 67 66 70 83 57

70.12 106 79 71 75 85 66 67 80 90 7370.14 111 72 69 106 94 77 68 70 100 9170.16 145 62 75 115 103 90 87 96 106 8770.18 182 78 77 109 134 86 89 86 130 111

212

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

70.2 245 100 97 108 126 109 105 127 135 11570.22 330 116 114 164 159 121 113 156 138 15270.24 373 122 149 163 162 132 140 171 153 16970.26 365 130 127 157 194 160 165 216 185 18170.28 352 170 124 157 189 176 147 244 175 20070.3 234 138 148 147 200 166 150 207 182 191

70.32 193 149 146 146 183 167 154 217 186 18070.34 154 145 157 121 188 145 128 156 154 18170.36 133 179 137 136 154 169 123 189 149 15870.38 124 138 125 121 115 141 117 140 124 16070.4 170 162 157 126 147 128 141 138 134 139

70.42 168 136 122 127 154 138 122 132 134 11570.44 196 129 127 110 147 127 116 139 138 13370.46 165 123 128 119 131 117 111 122 108 13170.48 144 134 125 111 149 122 127 123 129 12870.5 110 115 100 114 113 118 110 129 122 126

70.52 81 118 110 92 106 114 100 132 109 11970.54 63 103 129 79 98 92 88 127 107 10770.56 61 87 95 83 90 92 94 103 95 8070.58 50 92 105 79 83 78 80 80 79 9670.6 63 99 105 83 75 88 68 77 76 64

70.62 56 95 86 69 63 71 64 81 84 7570.64 45 92 80 56 64 57 61 62 64 5070.66 48 59 80 64 63 79 62 43 67 5370.68 39 69 60 53 55 54 45 51 55 5170.7 40 72 67 58 63 54 36 51 59 51

70.72 47 54 53 40 38 53 54 40 61 4470.74 43 62 52 50 52 44 57 51 38 5270.76 30 58 59 44 51 49 43 32 48 3670.78 40 53 36 55 54 43 52 38 45 4870.8 36 55 37 61 44 33 49 33 41 40

70.82 48 49 55 46 45 34 55 37 45 4570.84 49 51 45 40 37 47 34 38 43 3670.86 43 51 44 41 47 42 38 30 43 3570.88 45 53 43 48 30 40 51 31 40 3470.9 37 47 41 53 43 43 44 29 32 39

70.92 38 43 43 45 44 23 48 31 33 3170.94 33 46 46 40 43 41 33 34 43 4370.96 33 55 39 37 38 37 26 34 28 3670.98 37 44 38 41 29 34 37 32 30 35

213

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

71 32 39 42 47 30 47 41 23 40 3771.02 27 43 29 42 35 44 53 30 39 3071.04 32 42 30 35 39 29 43 34 41 3571.06 34 39 37 34 45 30 29 35 40 4671.08 35 47 30 32 39 31 26 27 33 3471.1 33 42 25 40 42 32 41 31 36 31

71.12 37 45 37 39 24 34 39 35 34 2871.14 45 42 42 29 38 38 29 42 32 3571.16 31 36 37 44 37 31 36 31 25 3071.18 43 57 27 38 45 35 36 33 44 3371.2 26 39 45 45 29 45 31 25 37 37

71.22 37 31 37 46 33 46 30 44 34 2971.24 36 32 42 48 36 42 46 25 27 3371.26 37 28 35 44 33 36 37 30 43 2671.28 38 43 30 40 44 35 36 34 47 2271.3 31 46 32 48 41 37 31 25 49 32

71.32 45 40 36 43 40 33 42 24 50 3371.34 32 47 37 33 46 31 29 28 41 3471.36 36 37 35 38 26 30 37 29 56 4471.38 32 32 32 42 35 31 32 31 78 3571.4 29 32 24 44 41 44 32 35 66 38

71.42 31 37 33 54 55 35 50 28 90 4671.44 33 30 38 34 35 35 49 25 64 3571.46 40 37 38 39 43 50 35 41 58 2271.48 36 43 39 31 47 27 35 35 60 3271.5 29 48 28 35 39 40 51 29 58 33

71.52 36 40 39 34 35 35 41 28 41 3371.54 26 31 39 37 30 40 32 20 59 3571.56 39 42 37 43 46 27 38 26 51 3571.58 34 31 28 36 40 42 41 29 54 3071.6 36 38 42 41 47 35 43 28 58 40

71.62 32 38 30 52 37 29 27 21 66 3571.64 32 44 39 37 46 36 33 28 53 4071.66 27 47 29 32 42 45 41 37 65 3771.68 46 44 27 31 33 35 41 37 40 3771.7 37 37 38 41 40 37 36 29 60 34

71.72 44 39 31 37 36 27 31 33 42 4571.74 33 38 29 43 39 28 39 29 41 3771.76 34 42 32 37 43 37 32 33 42 3371.78 35 32 31 46 38 50 32 30 40 32

214

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

71.8 30 41 32 41 41 38 43 33 43 3271.82 37 43 27 37 50 37 32 32 36 4071.84 26 39 43 49 46 36 36 24 39 3471.86 24 37 31 41 33 42 42 23 41 3271.88 46 32 32 41 36 42 38 36 34 3071.9 37 60 37 49 44 35 31 28 37 33

71.92 46 43 28 41 53 37 30 24 29 4071.94 18 52 30 47 35 42 44 23 40 3271.96 40 40 28 49 43 41 31 31 32 3971.98 36 43 35 37 41 40 38 41 41 48

72 46 46 32 43 34 32 35 44 30 2572.02 24 45 51 35 41 31 48 30 37 3372.04 34 40 31 34 38 37 38 34 28 4272.06 39 50 35 42 33 37 42 33 45 3472.08 39 48 26 40 41 41 43 33 39 4072.1 37 42 31 40 54 26 35 45 35 33

72.12 36 51 36 50 45 32 45 29 27 3672.14 39 49 42 55 51 33 52 32 33 4472.16 23 46 47 40 45 37 39 32 35 4272.18 37 34 31 57 52 37 29 34 30 4672.2 34 46 35 54 55 38 43 34 40 31

72.22 41 47 51 46 48 52 37 27 35 3872.24 34 38 34 39 34 33 42 47 26 3672.26 34 44 39 41 58 46 35 30 43 3472.28 45 40 46 41 42 42 34 37 25 3872.3 38 50 32 45 47 45 43 26 32 36

72.32 27 44 33 42 54 37 40 32 37 3972.34 36 51 38 47 48 51 51 35 41 4472.36 35 47 43 43 43 40 46 37 40 3972.38 35 43 37 39 47 34 44 39 40 4972.4 45 51 46 49 41 44 47 42 38 40

72.42 50 52 40 47 46 43 48 40 43 3572.44 47 42 44 44 50 58 42 36 46 3672.46 41 49 41 50 44 40 41 36 43 4272.48 41 47 37 44 53 52 46 35 46 5172.5 52 40 41 64 47 58 45 43 39 49

72.52 46 46 49 47 50 41 50 35 46 4172.54 65 65 56 39 58 59 46 53 55 5072.56 62 62 46 50 52 38 45 50 47 4172.58 61 47 56 55 62 54 46 49 59 49

215

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

72.6 58 58 70 61 62 47 42 38 65 5772.62 67 51 51 80 74 54 70 54 72 7572.64 56 51 52 81 50 58 62 55 72 5272.66 69 68 56 63 73 58 67 51 50 4572.68 69 48 58 75 58 61 59 65 78 5972.7 86 87 52 70 88 67 79 54 85 70

72.72 66 74 61 65 81 67 75 53 78 8472.74 73 85 63 90 87 89 84 68 69 7072.76 103 82 83 96 94 85 97 61 83 8972.78 115 89 83 113 111 79 81 86 103 10072.8 141 86 79 114 132 103 101 110 117 118

72.82 169 104 84 112 143 125 128 120 159 14972.84 258 109 113 170 153 127 118 150 200 16172.86 360 123 130 170 190 163 136 186 238 21272.88 398 126 135 192 206 186 162 216 243 22472.9 381 156 150 208 218 191 181 267 267 220

72.92 374 184 153 237 249 229 211 289 288 26572.94 257 195 172 247 225 255 204 287 262 24872.96 212 216 183 211 228 219 227 269 242 23072.98 146 217 206 186 208 219 202 257 230 239

73 140 204 177 193 213 202 202 249 213 20673.02 139 224 203 168 187 221 175 200 167 21273.04 165 193 198 160 170 196 174 213 173 18973.06 180 200 157 178 177 177 151 163 176 18873.08 196 184 180 198 155 179 118 185 196 20073.1 206 179 144 178 192 185 128 156 143 186

73.12 189 196 145 193 167 168 140 186 184 16273.14 133 189 151 155 154 161 155 181 168 19973.16 119 161 133 156 159 157 140 145 127 15973.18 106 134 138 111 151 159 135 155 140 14873.2 75 139 124 111 134 148 132 129 109 118

73.22 75 143 145 119 110 162 91 93 102 11073.24 66 139 128 113 86 126 114 105 84 12873.26 71 118 110 103 109 115 94 76 94 11073.28 72 123 112 98 85 105 94 91 83 8573.3 48 97 101 73 83 89 67 67 83 83

73.32 59 109 85 88 86 103 73 62 68 6773.34 57 94 83 56 74 70 80 59 52 7073.36 50 96 88 83 72 71 63 60 55 7173.38 60 73 91 77 72 77 67 54 48 61

216

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

73.4 49 82 57 62 61 68 62 47 53 5573.42 56 91 85 90 64 64 64 61 44 6673.44 56 88 73 84 86 68 64 53 59 4573.46 48 98 75 74 77 58 59 67 46 6173.48 47 80 77 66 72 56 54 71 47 6073.5 49 83 56 73 63 56 68 51 47 59

73.52 52 89 62 61 69 60 63 68 61 6173.54 63 62 43 52 60 55 55 60 60 6773.56 66 57 49 67 54 58 49 64 65 6073.58 69 75 63 72 64 68 52 62 65 6073.6 88 75 74 83 74 70 54 44 63 78

73.62 106 79 76 73 69 71 68 54 67 6273.64 125 69 81 84 100 73 49 85 73 6773.66 132 79 85 103 96 77 69 107 87 8473.68 135 81 72 93 82 93 89 116 117 8673.7 119 96 92 103 98 89 80 121 107 108

73.72 105 88 100 100 99 99 78 122 100 9373.74 89 96 88 98 104 95 74 118 82 9973.76 82 95 81 105 100 74 93 107 82 8073.78 71 81 82 65 90 79 89 85 71 8673.8 59 94 71 79 78 70 80 82 62 71

73.82 67 80 75 77 77 67 66 85 60 7473.84 60 84 69 64 84 91 61 59 53 7073.86 81 81 68 75 78 73 72 73 61 6673.88 85 78 73 67 75 76 84 66 64 6873.9 84 74 71 59 63 74 62 83 76 79

73.92 75 74 61 78 81 75 85 74 60 6973.94 63 65 51 74 65 70 65 60 51 6373.96 58 84 70 53 68 61 60 53 61 6073.98 53 66 61 63 73 67 63 65 69 50

74 42 68 60 54 76 77 58 48 62 6574.02 26 64 60 61 50 53 46 47 57 5874.04 53 60 55 61 49 55 60 45 63 6374.06 33 54 56 55 57 56 54 41 46 4274.08 36 58 61 51 51 61 43 42 53 4074.1 32 48 41 39 41 58 48 44 57 47

74.12 49 70 47 44 48 42 53 40 59 3074.14 28 54 48 44 42 49 56 40 91 4274.16 36 63 38 48 56 39 58 34 109 3574.18 45 58 48 45 32 58 39 35 85 42

217

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

74.2 47 48 39 54 33 40 41 35 83 4874.22 44 43 47 46 52 46 29 34 81 3974.24 32 41 52 40 51 50 41 29 71 3374.26 36 49 33 35 46 42 50 25 82 3774.28 32 52 42 42 45 40 41 34 69 3974.3 40 48 43 40 39 39 49 39 67 34

74.32 34 45 40 35 50 40 41 36 59 3674.34 40 54 66 37 39 30 51 33 62 3674.36 41 49 51 29 41 43 41 30 76 4974.38 41 40 38 34 36 44 54 39 66 3374.4 38 49 47 37 39 43 41 30 69 37

74.42 42 51 36 39 42 43 42 30 53 3874.44 45 46 38 58 47 43 46 30 62 4274.46 32 43 39 50 47 38 36 33 57 3574.48 35 53 49 38 46 42 44 45 56 4374.5 27 48 32 50 48 42 43 26 47 36

74.52 37 45 31 29 55 44 44 21 43 3274.54 47 41 38 42 32 38 28 28 46 3274.56 37 44 39 37 39 50 35 36 49 4074.58 30 44 32 40 32 28 38 36 33 2874.6 34 38 46 58 39 47 37 37 49 34

74.62 43 54 29 37 42 48 41 40 59 4574.64 40 57 49 42 45 36 34 37 47 4874.66 38 49 27 44 50 43 30 24 55 4674.68 39 54 36 37 45 29 40 34 54 4574.7 33 51 39 36 41 46 36 36 38 44

74.72 48 43 43 45 45 47 47 39 44 3374.74 36 42 47 46 47 36 33 28 39 3974.76 60 36 43 29 39 35 41 30 46 4674.78 27 29 43 29 60 42 38 33 46 3574.8 39 41 32 44 27 34 41 26 47 37

74.82 33 50 44 43 31 44 30 30 39 3074.84 30 54 43 35 45 47 46 29 45 4274.86 39 42 30 45 38 45 36 29 46 3674.88 45 48 34 36 45 30 43 29 45 2974.9 29 42 30 48 37 40 34 33 39 39

74.92 33 46 37 42 29 47 37 34 55 4074.94 44 38 40 45 41 33 32 35 53 3274.96 33 52 37 43 40 43 28 23 43 3674.98 24 44 34 34 40 37 40 23 42 37

218

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

75 45 41 37 28 35 43 34 29 48 3675.02 24 48 38 33 49 39 45 30 35 4175.04 35 51 53 48 37 39 41 30 30 4575.06 37 42 31 37 37 32 51 35 46 3275.08 33 40 50 56 42 39 31 29 36 4275.1 33 46 35 40 44 44 31 33 44 35

75.12 44 37 37 35 53 33 36 29 38 3075.14 46 38 43 52 38 40 46 30 35 4075.16 30 37 41 42 43 53 24 35 36 3175.18 29 40 45 47 39 46 39 28 41 3875.2 41 41 31 45 39 36 43 42 27 47

75.22 38 48 45 56 42 43 50 34 35 3975.24 34 35 31 42 33 42 38 31 37 4475.26 32 46 29 46 33 27 46 29 35 3675.28 39 52 26 35 38 37 38 33 22 5175.3 35 50 37 36 31 38 34 30 36 35

75.32 50 39 47 38 35 45 48 30 36 2475.34 44 53 37 49 43 43 44 31 32 4175.36 37 46 39 42 30 41 42 32 33 4475.38 31 40 31 37 37 40 43 40 33 3675.4 26 41 53 34 46 40 40 24 44 35

75.42 43 39 33 45 40 36 36 43 35 3875.44 35 48 48 48 35 38 41 26 46 4075.46 41 52 32 40 38 30 42 38 35 3975.48 34 34 59 38 25 38 39 35 36 4375.5 26 39 41 37 44 45 49 40 33 41

75.52 35 54 36 52 55 50 48 18 37 3475.54 36 48 50 57 41 40 39 27 38 3375.56 39 44 40 54 54 45 47 42 35 3775.58 42 62 46 63 50 48 38 35 41 4675.6 30 77 77 72 50 39 40 39 48 28

75.62 39 63 63 71 43 47 45 28 37 2575.64 33 82 68 73 46 52 39 31 31 3675.66 47 53 76 48 48 35 42 50 43 3775.68 46 58 53 47 41 40 44 29 35 3875.7 42 58 49 57 43 47 52 28 45 43

75.72 38 38 60 60 51 50 52 36 43 5275.74 41 60 41 58 43 40 51 27 37 4175.76 48 51 42 53 53 42 55 39 32 3975.78 44 57 49 60 27 38 69 28 37 35

219

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

75.8 40 59 48 51 39 34 89 55 30 3875.82 43 54 62 53 44 38 88 41 36 2975.84 44 68 38 52 51 46 76 33 41 3475.86 49 53 38 59 45 40 75 32 35 2975.88 38 60 56 63 52 42 57 35 42 4475.9 38 55 53 56 50 49 59 54 46 43

75.92 35 38 56 52 54 43 46 40 56 4175.94 37 52 61 39 43 53 75 38 49 3675.96 37 58 44 42 58 48 44 41 36 4775.98 51 58 45 48 53 40 52 36 43 41

76 35 51 52 53 52 40 56 35 41 4276.02 48 50 42 44 52 53 66 36 46 3776.04 49 54 53 49 54 63 72 52 56 6176.06 57 51 51 47 40 60 59 41 38 4576.08 45 58 53 56 71 55 63 35 36 5076.1 52 44 42 61 62 59 72 45 64 47

76.12 51 54 54 55 60 50 67 48 49 5676.14 62 59 55 64 61 64 68 58 53 5776.16 79 63 58 56 66 66 53 44 67 5776.18 90 63 60 72 78 55 62 57 73 7176.2 87 57 63 86 85 75 64 62 70 84

76.22 115 66 85 78 103 82 78 75 90 7776.24 150 71 70 95 104 96 102 104 118 10076.26 178 73 117 114 114 93 94 113 125 11576.28 192 90 110 128 134 107 111 147 129 12276.3 172 104 100 121 127 117 107 151 160 124

76.32 121 103 119 140 144 110 131 148 129 13676.34 109 108 128 126 152 126 127 155 119 13176.36 90 111 122 105 131 129 134 154 107 11076.38 75 135 106 108 122 123 116 127 104 11476.4 76 99 121 100 106 110 100 114 98 98

76.42 75 96 107 98 81 103 106 103 85 8876.44 81 113 124 87 89 97 105 99 77 11076.46 104 105 105 86 95 108 103 85 87 7876.48 110 94 104 92 98 109 104 90 89 8276.5 91 97 97 99 107 98 88 102 90 90

76.52 99 91 128 99 86 99 90 96 83 10876.54 94 93 78 90 103 95 93 88 97 9176.56 71 101 90 76 96 104 78 112 87 8676.58 62 89 88 76 88 92 99 69 65 83

220

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

76.6 54 102 81 73 90 68 95 96 67 8376.62 51 101 77 80 75 70 82 68 75 7176.64 55 86 69 56 71 74 74 71 50 7276.66 48 77 89 73 69 69 62 58 56 6176.68 48 74 73 60 58 66 79 65 47 5476.7 52 78 64 61 72 72 61 36 60 60

76.72 60 66 59 57 59 59 51 40 57 4576.74 53 56 55 54 62 57 72 48 55 5276.76 57 68 48 44 60 66 55 54 48 4376.78 51 56 69 53 61 46 53 48 49 5076.8 58 46 60 59 64 50 52 62 52 40

76.82 37 66 44 62 65 63 49 55 65 6376.84 45 66 70 63 57 48 55 50 63 4176.86 55 56 55 68 69 33 56 51 49 5376.88 44 71 56 70 74 55 50 44 53 6576.9 57 53 48 65 70 70 60 39 64 55

76.92 62 75 64 62 36 58 53 50 68 5876.94 70 59 50 57 80 57 50 51 80 5876.96 58 79 43 74 80 70 62 54 64 6876.98 61 65 55 74 84 68 75 33 85 66

77 77 76 62 81 83 72 79 66 88 6777.02 73 67 80 63 79 66 73 88 89 6477.04 101 67 63 64 99 75 71 75 110 9677.06 105 79 75 98 92 93 98 91 103 9377.08 140 76 80 92 135 84 88 108 105 9877.1 195 93 98 100 121 103 107 129 134 134

77.12 240 86 101 136 159 105 116 155 170 14677.14 321 105 94 126 163 121 111 190 180 14177.16 359 112 98 150 155 138 137 252 188 15377.18 305 122 104 178 170 158 138 247 202 18577.2 249 135 121 197 182 149 162 244 207 202

77.22 176 122 131 142 189 146 157 234 189 20277.24 139 136 130 149 186 153 180 246 198 18977.26 132 157 148 178 166 145 127 216 163 17877.28 101 151 139 145 156 134 135 172 152 15177.3 110 165 139 129 119 139 134 178 160 156

77.32 127 141 116 118 135 157 113 151 139 15277.34 153 131 150 135 123 137 130 157 140 13677.36 166 147 129 127 139 113 119 147 121 14577.38 191 138 129 119 133 126 113 128 131 125

221

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

77.4 158 139 125 125 136 107 133 157 144 12477.42 139 114 114 128 127 110 123 158 139 12877.44 104 126 109 114 112 119 113 146 126 11277.46 99 123 111 106 115 121 114 136 114 11677.48 79 121 101 115 96 82 107 118 105 9177.5 56 110 100 105 91 100 96 94 85 104

77.52 53 90 123 71 87 102 89 99 78 8377.54 65 96 132 81 74 78 94 96 86 7477.56 47 97 100 94 83 86 82 88 54 6077.58 44 84 102 83 70 90 72 75 57 6677.6 41 77 68 78 70 80 59 87 64 56

77.62 46 74 97 71 60 82 61 89 57 6277.64 40 79 86 74 64 50 56 115 53 4577.66 53 89 106 52 71 51 50 112 52 5677.68 43 65 73 57 64 57 52 102 47 4377.7 50 72 65 52 43 57 51 105 44 42

77.72 43 73 78 49 48 62 52 65 53 4377.74 41 75 59 43 50 42 48 66 37 4177.76 34 59 51 49 73 48 48 47 41 3677.78 51 51 42 66 50 47 39 49 43 3977.8 37 56 64 46 39 36 40 38 40 41

77.82 32 55 43 32 40 50 49 42 46 3777.84 41 40 60 46 45 47 35 41 47 4077.86 39 54 51 44 47 42 34 60 41 4177.88 30 40 52 47 49 45 48 74 32 3877.9 39 48 58 47 32 38 36 66 27 46

77.92 52 45 44 54 47 45 44 70 32 3977.94 44 57 52 36 44 39 36 61 33 4777.96 37 44 42 45 33 36 44 37 37 4077.98 36 45 44 47 51 40 56 27 45 38

78 46 47 41 43 42 37 40 39 31 3378.02 44 61 42 38 46 39 38 26 34 3778.04 35 41 54 29 39 43 54 39 32 2978.06 41 37 41 36 57 31 43 37 37 3578.08 34 47 48 41 44 43 49 34 44 3778.1 32 43 43 38 39 34 47 32 40 28

78.12 35 43 31 43 44 29 42 26 33 3478.14 40 38 34 40 42 50 46 44 28 3778.16 37 43 38 34 33 42 44 27 37 2778.18 34 33 39 45 36 44 40 35 42 36

222

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

78.2 34 39 44 45 39 36 45 38 30 3178.22 30 45 35 25 35 50 32 34 38 4478.24 34 38 35 34 38 43 33 32 36 4178.26 34 39 38 44 45 44 44 40 29 4178.28 44 30 34 35 45 50 49 31 43 3378.3 35 36 32 45 32 33 30 27 36 34

78.32 37 36 31 37 30 38 37 28 40 3878.34 31 42 48 51 33 36 37 27 31 3078.36 41 50 44 34 37 26 47 36 39 3478.38 36 40 28 31 48 32 37 23 40 3378.4 42 44 42 46 50 35 39 38 40 36

78.42 34 40 44 32 21 48 48 35 41 3178.44 35 29 42 35 27 34 41 30 35 4278.46 28 41 33 39 38 51 35 41 35 3478.48 30 43 36 45 38 44 40 37 61 2878.5 44 39 39 29 37 37 40 32 45 37

78.52 34 35 29 33 35 32 41 28 51 4278.54 34 44 35 35 40 40 33 25 56 2678.56 43 36 32 33 45 38 25 41 70 3178.58 40 30 41 36 40 29 38 31 70 3978.6 21 36 36 34 37 39 46 37 69 34

78.62 37 39 35 26 27 46 42 38 85 2978.64 39 35 24 33 31 38 35 26 84 3478.66 36 47 45 37 38 39 38 34 88 2678.68 21 29 43 32 34 51 32 25 51 3778.7 27 40 25 28 45 38 37 38 47 38

78.72 30 39 45 38 34 33 28 37 48 3778.74 43 33 35 31 32 38 35 33 54 2978.76 36 45 33 30 42 35 41 32 46 3878.78 31 38 32 38 36 46 44 34 43 4178.8 30 53 34 47 36 38 31 28 67 32

78.82 33 35 29 42 30 34 47 36 54 2578.84 27 38 33 35 44 33 29 29 58 2878.86 36 43 39 39 42 40 39 39 47 3078.88 28 39 35 43 45 30 35 24 53 3578.9 29 37 33 28 35 39 32 41 53 35

78.92 32 36 41 32 36 36 30 31 35 3578.94 33 36 44 34 35 41 29 31 45 2978.96 29 37 32 46 34 29 36 33 40 3278.98 43 47 40 40 40 38 30 33 29 33

223

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

79 37 34 36 41 45 47 38 35 44 3979.02 23 42 33 30 36 40 33 39 35 3479.04 36 40 28 31 30 36 28 25 49 4779.06 27 39 38 24 38 29 33 29 39 4479.08 31 41 29 31 40 34 41 32 41 3679.1 33 53 26 44 39 43 35 26 31 38

79.12 30 36 38 42 42 29 31 32 40 2679.14 24 43 31 40 45 36 35 33 39 2779.16 42 33 43 41 26 35 58 19 41 3479.18 33 38 31 41 41 36 31 23 40 2679.2 36 52 35 38 32 39 33 36 25 24

79.22 30 34 36 34 31 35 38 29 41 2379.24 34 41 35 39 35 35 40 24 29 2679.26 41 31 27 34 41 34 41 36 38 3079.28 36 42 29 28 36 42 30 25 32 2879.3 38 28 29 33 30 34 44 20 38 42

79.32 28 44 37 37 31 38 24 38 32 4079.34 35 34 31 37 42 21 43 27 35 3879.36 36 35 36 38 34 32 48 31 30 2479.38 31 36 41 38 40 21 30 20 33 2779.4 32 36 38 36 48 43 41 37 40 33

79.42 26 44 39 32 37 48 40 36 37 3679.44 42 37 40 44 41 39 35 38 35 2979.46 34 35 40 42 36 43 47 26 40 4079.48 32 45 37 45 32 39 40 25 46 3379.5 38 50 37 29 32 35 35 44 36 31

79.52 29 44 31 40 37 35 33 31 40 3479.54 32 37 28 29 32 40 37 39 41 3979.56 33 41 36 47 31 42 28 33 42 3679.58 25 42 34 31 34 35 37 43 36 3479.6 34 49 40 37 35 44 30 16 41 30

79.62 37 40 33 41 33 36 39 35 46 3079.64 32 39 33 29 20 28 33 30 32 4079.66 36 46 32 51 30 34 31 31 47 4079.68 32 41 35 29 47 53 30 39 46 4379.7 37 39 30 54 37 35 33 35 38 31

79.72 38 34 43 42 37 38 29 30 54 3979.74 33 47 43 45 43 36 30 34 51 2579.76 35 45 42 58 46 31 38 39 42 3979.78 29 50 58 54 47 41 30 41 34 31

224

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

79.8 33 51 38 51 44 45 52 48 49 3079.82 37 42 46 48 39 39 34 58 59 2779.84 38 40 49 72 57 45 41 55 50 3479.86 43 53 80 50 57 46 32 110 56 3979.88 28 63 79 51 43 43 47 228 49 2879.9 30 49 73 53 50 37 24 236 58 33

79.92 32 45 62 50 44 33 44 243 51 3979.94 32 43 47 56 33 36 25 146 35 3679.96 35 50 55 62 40 40 32 89 34 2679.98 29 50 60 53 50 40 26 50 33 35

80 34 54 45 48 42 34 28 52 36 3780.02 36 48 49 51 39 38 39 45 30 3180.04 46 48 55 47 51 38 36 48 42 2780.06 38 58 59 48 33 47 42 49 46 3580.08 31 58 40 45 42 40 39 59 32 3180.1 39 43 53 47 36 36 27 77 46 26

80.12 36 58 51 50 39 36 47 94 36 3880.14 40 40 45 46 40 48 35 119 49 3180.16 46 37 44 48 42 44 26 107 41 3080.18 30 48 48 38 39 35 32 77 45 3280.2 43 44 55 32 48 37 34 58 41 35

80.22 35 45 40 37 42 37 42 44 27 3180.24 54 37 32 47 40 37 30 49 45 4380.26 29 46 43 41 52 45 37 35 38 3580.28 37 46 33 32 33 43 55 35 42 3680.3 31 51 30 40 46 40 30 34 39 38

80.32 33 52 44 48 38 44 36 26 44 3680.34 44 52 46 41 45 32 55 26 42 4380.36 37 42 40 34 39 49 34 36 35 3980.38 30 36 34 37 30 36 39 40 29 3680.4 35 52 34 25 39 46 45 33 39 30

80.42 37 36 38 40 48 45 45 36 39 4080.44 43 38 42 33 47 40 41 28 32 3580.46 47 46 33 34 34 32 37 27 45 2980.48 31 45 43 39 40 46 43 30 37 3680.5 37 38 37 38 39 39 32 33 52 43

80.52 35 45 32 44 52 46 38 36 35 3680.54 35 40 37 33 40 42 34 34 39 3480.56 38 39 33 29 48 34 37 39 31 4580.58 44 43 44 42 32 45 43 32 35 49

225

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

80.6 39 38 40 54 35 37 32 46 42 3780.62 36 44 44 41 42 31 41 46 41 4180.64 34 29 42 48 41 38 47 36 44 4180.66 42 30 27 40 37 30 37 30 34 3780.68 42 51 31 51 44 41 43 43 35 4380.7 32 56 43 34 50 46 38 46 43 59

80.72 40 52 31 42 47 48 46 44 44 3880.74 38 52 26 49 64 46 52 36 40 4680.76 47 50 45 43 59 35 49 42 41 4580.78 48 33 50 45 35 44 52 36 33 4780.8 44 50 39 48 44 42 49 37 48 46

80.82 64 40 45 57 51 36 41 28 46 4880.84 56 55 36 55 66 41 46 47 53 3980.86 61 39 42 54 45 62 48 48 46 5380.88 70 60 54 57 55 53 46 54 59 6880.9 113 51 44 57 56 62 58 60 53 63

80.92 118 64 50 85 57 76 59 63 68 7880.94 117 66 67 74 93 59 69 70 70 8280.96 92 66 79 74 86 76 69 85 101 8480.98 91 65 61 67 87 57 77 81 87 91

81 62 87 66 83 90 70 72 104 68 9081.02 57 69 83 103 82 65 86 98 67 8481.04 65 71 67 93 81 68 54 103 72 6981.06 60 82 90 86 73 90 79 90 74 7081.08 61 81 88 74 85 74 65 82 62 7581.1 54 84 87 83 76 65 76 92 68 71

81.12 64 78 81 88 62 62 59 80 57 6681.14 68 86 95 82 76 65 65 89 69 6381.16 83 83 79 90 86 68 67 84 86 6581.18 89 97 96 78 70 64 73 79 81 6381.2 84 82 81 109 102 65 63 108 82 66

81.22 95 89 75 95 84 66 95 66 82 7281.24 79 77 65 73 75 77 81 82 67 6581.26 62 80 75 94 90 84 74 91 64 7681.28 67 86 66 91 82 75 81 76 66 6981.3 75 81 81 87 89 72 77 77 69 56

81.32 62 81 75 90 90 93 75 84 78 5881.34 83 102 80 98 87 68 68 103 69 6381.36 79 93 100 105 91 74 68 93 83 6881.38 107 97 86 115 81 64 79 106 88 70

226

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

81.4 109 91 99 116 122 84 86 102 92 8281.42 128 101 104 119 108 84 86 176 97 9381.44 152 116 130 118 117 85 101 197 98 11881.46 187 97 129 150 154 104 102 278 108 11681.48 250 118 123 163 174 119 115 236 135 15181.5 301 129 164 176 196 120 119 257 159 142

81.52 307 135 147 200 222 144 147 257 192 18381.54 295 126 171 218 210 160 146 261 205 20081.56 247 148 149 218 201 168 186 255 207 18681.58 180 165 148 198 224 185 174 282 200 20081.6 145 173 195 207 229 165 177 278 186 203

81.62 129 174 173 158 186 177 159 235 148 19381.64 119 155 149 172 171 159 166 239 175 15581.66 87 163 158 172 171 162 161 204 142 16181.68 126 155 174 151 167 151 138 200 106 15181.7 112 180 166 140 170 150 132 197 97 134

81.72 154 147 168 130 140 141 150 198 123 12581.74 165 139 150 144 153 134 131 182 129 12881.76 158 139 152 130 128 138 121 167 146 14581.78 159 128 142 120 157 142 131 149 127 14481.8 127 134 135 126 146 123 102 144 111 134

81.82 106 118 117 127 130 117 105 155 123 14881.84 91 126 129 125 143 116 107 141 125 13481.86 82 122 126 80 112 131 104 127 95 12181.88 76 106 86 108 125 100 94 122 94 8381.9 57 108 105 87 89 101 89 94 73 95

81.92 51 100 105 88 91 93 100 100 63 7281.94 52 96 120 75 79 104 92 84 76 8381.96 61 96 87 78 78 90 69 72 70 6981.98 59 97 88 71 87 83 74 54 72 61

82 54 61 96 73 78 61 66 72 68 7882.02 67 83 86 65 52 57 63 57 62 4882.04 61 87 77 64 72 62 73 57 57 6782.06 79 71 74 67 83 73 46 75 65 6282.08 89 80 58 63 62 59 64 69 60 7482.1 79 83 67 54 85 65 66 61 73 74

82.12 79 68 49 68 55 70 56 81 61 5882.14 58 71 65 62 68 62 51 73 68 6382.16 68 60 65 75 78 69 48 81 66 6882.18 69 69 80 54 73 64 55 52 61 69

227

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

82.2 57 65 75 73 57 73 65 68 61 5982.22 53 62 54 64 70 63 54 64 70 6082.24 48 76 65 54 67 53 46 61 61 5682.26 43 62 65 45 63 68 53 58 51 5982.28 44 50 57 63 67 54 50 52 47 5782.3 49 60 49 38 49 57 47 49 36 64

82.32 62 69 54 64 55 66 55 57 49 5082.34 46 63 55 45 51 61 59 59 57 6182.36 49 54 60 65 48 56 50 51 52 5282.38 55 61 51 50 55 46 64 66 44 5782.4 43 49 57 40 54 38 46 61 63 54

82.42 60 72 62 48 57 42 56 59 55 4882.44 42 63 37 47 43 53 48 36 65 5282.46 43 62 50 45 64 57 51 43 59 4882.48 47 50 41 38 60 40 41 49 49 4082.5 31 70 30 50 44 54 56 41 56 45

82.52 41 50 44 47 46 38 54 43 73 6082.54 44 54 46 53 45 58 48 37 47 3982.56 41 59 54 50 54 30 46 40 64 4382.58 35 44 46 50 42 54 41 41 54 3782.6 43 37 45 61 54 43 39 38 52 43

82.62 39 54 44 48 48 38 56 29 77 4782.64 52 33 42 44 44 47 44 36 69 3782.66 38 54 42 46 34 38 55 43 58 4582.68 39 49 44 46 54 34 47 40 73 4182.7 43 39 36 39 46 49 33 42 73 38

82.72 37 50 37 33 51 38 46 31 58 5082.74 40 47 28 44 32 50 51 34 85 6082.76 40 31 47 37 42 55 36 56 64 3882.78 49 46 38 33 39 36 47 38 52 5382.8 46 50 52 42 43 34 48 33 78 39

82.82 49 50 38 42 45 42 37 40 53 3282.84 34 41 40 45 40 36 47 47 67 4082.86 42 40 48 40 41 34 38 42 74 4382.88 33 52 44 39 42 42 41 44 59 3982.9 47 42 45 34 42 40 38 34 64 47

82.92 32 58 40 48 43 41 49 30 41 3782.94 32 45 41 63 47 37 44 36 59 3282.96 49 56 49 48 50 52 43 30 75 5082.98 34 48 37 34 45 54 38 49 52 49

228

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

83 31 67 28 40 40 54 55 31 46 3683.02 43 55 48 41 38 36 40 35 57 5083.04 49 47 49 37 42 32 41 29 58 4283.06 40 50 48 49 43 39 45 48 53 4683.08 37 51 46 44 44 38 36 36 61 5283.1 53 37 31 49 35 38 41 38 49 30

83.12 50 51 31 52 51 44 48 32 51 3383.14 54 49 61 45 45 50 44 41 50 4883.16 51 57 38 37 49 39 48 52 43 4683.18 52 40 42 38 52 32 47 40 44 3983.2 42 55 31 42 39 55 44 36 45 34

83.22 44 53 39 54 43 40 58 46 51 4683.24 51 41 45 35 55 57 46 40 50 4383.26 50 50 50 57 56 40 46 44 42 5183.28 39 44 50 50 47 48 36 39 53 4983.3 64 53 49 47 45 44 58 42 50 43

83.32 67 69 46 58 52 47 40 60 44 5383.34 41 61 50 65 75 45 43 46 67 5883.36 49 59 51 51 43 53 56 43 57 5583.38 51 58 71 63 65 57 48 54 62 6783.4 55 58 49 63 62 45 63 51 59 58

83.42 66 61 56 61 76 53 60 57 62 6583.44 51 43 58 63 79 54 57 62 48 6783.46 75 53 62 69 80 65 69 67 51 7783.48 67 54 68 80 60 61 61 57 68 6883.5 82 82 62 69 74 59 64 67 68 72

83.52 67 72 64 67 83 59 67 69 65 6283.54 86 74 85 72 96 77 56 75 76 7783.56 89 81 72 67 88 81 67 71 79 9183.58 96 83 77 94 89 83 94 110 107 9483.6 90 79 91 101 112 87 95 102 85 101

83.62 111 80 86 101 110 86 91 91 116 12383.64 156 95 97 99 128 98 103 122 124 11783.66 174 110 112 137 119 114 135 150 132 13383.68 234 110 114 132 155 110 130 158 174 14983.7 282 126 144 173 160 143 154 164 176 196

83.72 460 137 117 191 198 163 165 246 203 23983.74 569 168 188 220 238 182 195 278 218 24583.76 564 178 197 277 247 231 202 376 284 29883.78 585 215 190 309 313 234 226 403 283 352

229

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

83.8 556 203 241 316 316 275 247 431 307 33783.82 424 276 279 299 338 273 253 522 301 33083.84 300 259 246 302 331 273 285 537 274 32983.86 230 287 277 277 308 283 258 495 254 30983.88 174 243 264 287 252 286 262 416 238 26383.9 156 283 242 218 232 214 234 385 190 245

83.92 165 267 234 198 257 250 208 316 202 24383.94 186 244 237 197 205 233 205 297 174 22983.96 219 229 221 186 205 198 211 239 187 21883.98 254 231 223 188 189 185 166 248 211 201

84 299 208 195 193 187 180 157 250 170 19684.02 321 211 200 204 193 198 181 273 197 20984.04 301 203 210 206 207 210 155 270 190 20884.06 237 201 200 201 201 209 169 280 200 20984.08 194 176 219 190 189 208 193 272 182 16884.1 152 211 192 155 183 181 154 285 170 180

84.12 111 171 188 170 183 178 177 231 138 17884.14 83 201 180 152 128 144 140 221 125 14384.16 82 154 150 117 141 149 141 169 122 13684.18 86 133 173 97 114 109 109 151 87 13984.2 59 173 143 106 123 115 97 110 103 100

84.22 65 139 125 107 96 106 116 112 92 9584.24 65 113 118 92 94 101 83 97 95 8384.26 59 100 121 76 87 91 76 82 90 8584.28 63 128 116 79 89 96 85 77 76 7684.3 60 98 88 81 84 81 68 65 58 80

84.32 50 89 81 73 94 90 69 68 66 6784.34 61 90 92 76 72 63 82 73 77 5984.36 56 80 82 67 70 86 75 64 65 7484.38 51 91 74 55 64 65 75 71 55 6584.4 61 92 80 84 81 61 64 52 60 60

84.42 56 78 59 60 56 58 75 51 58 5684.44 56 85 67 60 66 60 70 47 64 6884.46 53 76 59 68 63 50 62 52 55 5484.48 67 66 64 64 66 52 66 42 46 5984.5 52 55 65 68 69 52 63 52 60 47

84.52 63 84 63 53 84 59 61 55 66 5784.54 61 66 64 52 55 56 54 52 62 5284.56 46 58 60 58 66 58 54 53 71 6084.58 55 66 55 58 68 70 59 58 46 60

230

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

84.6 50 55 68 56 70 79 73 49 68 5784.62 68 77 57 60 76 79 46 57 79 6584.64 67 82 61 67 80 94 59 61 69 7584.66 73 76 60 85 81 75 77 90 84 8784.68 68 66 71 71 78 69 70 88 74 8284.7 89 68 71 85 82 81 70 71 87 91

84.72 122 72 87 96 83 70 75 96 94 8584.74 171 86 94 98 134 98 90 92 82 10684.76 222 96 80 122 112 81 89 121 136 14384.78 280 95 95 132 148 113 96 152 163 15284.8 247 131 111 128 148 146 115 194 156 169

84.82 242 128 104 145 200 135 135 208 168 17284.84 214 121 123 162 171 151 134 196 154 19884.86 194 115 108 151 169 140 137 241 142 17784.88 131 145 111 140 180 153 142 211 164 17684.9 116 131 135 130 149 166 134 191 156 148

84.92 90 122 118 120 135 123 128 177 121 13984.94 86 144 134 125 120 108 151 177 113 12284.96 99 145 122 110 104 129 113 150 94 12384.98 97 126 126 110 110 127 128 118 107 100

85 97 140 101 115 126 95 98 112 105 9385.02 140 128 112 80 94 111 99 128 112 11085.04 134 116 100 92 110 111 115 139 116 10985.06 144 129 89 119 111 114 99 124 107 12285.08 127 109 117 106 119 104 111 113 109 11485.1 108 98 97 96 97 87 85 110 93 109

85.12 116 100 104 102 118 104 115 105 107 10385.14 80 99 100 96 110 104 92 121 97 10485.16 72 81 86 102 74 91 101 111 84 11085.18 54 94 86 94 84 91 86 119 96 8785.2 66 103 90 80 67 90 90 74 76 69

85.22 47 83 75 65 72 61 77 81 67 7885.24 59 79 81 76 63 85 73 79 72 8685.26 52 91 62 70 63 69 65 61 66 6785.28 48 69 64 62 61 59 58 68 58 5385.3 39 67 61 57 47 67 47 50 55 47

85.32 36 59 66 56 53 55 46 61 46 5285.34 41 63 60 70 45 52 56 39 47 5985.36 41 64 51 50 53 55 49 36 48 5085.38 48 50 50 38 57 62 39 49 52 50

231

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

85.4 56 55 66 45 37 44 42 55 41 6285.42 33 52 47 50 53 46 48 43 40 4285.44 36 65 52 58 52 45 44 37 44 3485.46 34 42 63 43 33 43 48 36 37 3385.48 39 49 53 37 46 49 58 42 48 4385.5 37 40 45 54 41 34 49 37 42 31

85.52 31 53 45 53 53 39 38 38 38 4285.54 48 43 38 48 45 49 32 47 41 3685.56 37 53 45 44 44 46 37 36 33 4785.58 35 38 43 38 37 39 54 34 36 4185.6 44 38 38 37 52 36 53 25 34 35

85.62 24 39 42 33 51 34 39 40 40 3985.64 39 48 49 46 44 36 41 38 28 3685.66 48 51 36 40 42 26 37 34 43 3785.68 35 50 33 39 32 30 37 28 36 4085.7 33 47 36 39 34 44 31 30 31 49

85.72 50 38 27 38 41 37 35 30 35 4085.74 38 49 30 58 27 36 36 35 36 3685.76 37 48 31 44 29 33 45 34 37 4185.78 39 42 35 37 41 40 52 41 41 4185.8 38 40 35 42 47 31 37 35 39 35

85.82 39 38 35 54 49 45 28 32 34 4085.84 31 28 45 37 36 45 49 37 33 3385.86 42 49 43 47 42 42 25 34 36 3285.88 36 36 33 29 33 38 37 20 39 3885.9 35 26 35 37 39 33 36 31 46 37

85.92 30 38 43 29 42 42 57 40 36 3585.94 29 47 43 52 33 28 42 28 40 3885.96 47 45 46 49 33 37 48 48 40 3085.98 27 44 38 40 48 42 38 34 46 44

86 35 47 37 43 50 37 38 38 48 3886.02 35 46 51 38 38 44 28 26 28 3186.04 37 41 38 29 49 31 40 36 33 2286.06 37 24 34 44 36 37 36 32 47 3586.08 43 36 33 52 40 41 39 27 33 3886.1 38 35 28 33 36 33 49 34 30 30

86.12 33 47 48 28 36 36 32 30 38 3686.14 33 32 41 32 42 31 43 35 27 3386.16 26 41 30 46 37 26 37 38 50 4386.18 30 43 43 48 35 29 42 35 39 44

232

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

86.2 27 44 33 47 53 42 32 29 23 4386.22 39 56 35 38 37 37 42 44 45 3586.24 34 37 33 42 35 42 41 32 44 3886.26 43 32 44 46 39 47 44 38 37 3586.28 46 56 28 45 39 39 41 33 45 3986.3 48 52 53 38 39 36 41 29 43 40

86.32 44 41 35 52 44 45 48 34 46 4186.34 29 62 38 37 51 41 38 31 41 3686.36 57 46 44 45 48 44 56 41 57 5686.38 46 47 51 38 62 50 61 58 48 4886.4 72 41 49 53 64 38 46 47 58 55

86.42 69 41 50 57 78 46 48 51 44 4486.44 57 59 49 63 53 46 46 48 74 4786.46 82 52 54 60 65 49 47 71 60 6586.48 61 58 53 56 68 57 56 67 56 7286.5 66 48 68 56 49 51 57 91 65 62

86.52 48 54 41 55 75 59 64 74 51 6186.54 54 46 56 67 57 48 69 69 65 6086.56 44 55 50 65 73 55 55 83 68 4886.58 40 57 48 53 64 56 65 54 60 5886.6 38 62 52 33 55 55 59 43 51 46

86.62 43 51 42 41 50 57 53 67 57 4786.64 57 63 51 53 44 50 41 51 55 4986.66 47 42 49 48 39 58 50 52 50 5286.68 52 55 53 63 56 60 54 54 60 5786.7 43 58 51 58 58 52 54 46 46 49

86.72 54 44 50 54 43 46 44 56 47 4986.74 51 69 48 52 47 46 46 66 50 5886.76 44 40 57 49 55 45 54 42 58 4686.78 36 52 61 53 50 41 52 63 58 5086.8 30 44 40 57 47 40 52 62 44 54

86.82 40 44 41 50 50 64 58 42 60 4986.84 30 43 59 57 43 60 30 50 43 3086.86 34 53 50 49 43 54 41 41 51 4386.88 36 43 28 50 46 53 45 38 49 4686.9 37 47 48 44 49 43 51 39 37 34

86.92 38 42 51 40 64 46 49 42 34 2686.94 41 56 40 50 30 42 35 37 37 4086.96 26 53 44 40 44 36 39 36 41 4386.98 33 48 43 31 37 31 37 30 46 33

233

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

87 24 42 44 35 39 45 42 28 51 4687.02 45 36 43 43 37 47 41 27 47 3187.04 33 46 35 39 33 41 57 36 27 4587.06 37 39 36 44 35 41 27 33 38 3687.08 32 36 34 29 44 29 46 22 46 5087.1 35 45 34 40 31 33 36 37 35 33

87.12 34 34 44 53 29 39 50 26 41 2687.14 42 42 35 35 33 30 41 30 33 3387.16 36 42 41 39 33 43 45 33 35 4387.18 33 48 35 24 36 31 44 27 44 3987.2 37 36 37 33 37 33 54 25 41 28

87.22 33 33 43 34 43 34 40 25 33 4387.24 36 35 38 37 30 35 53 30 40 4387.26 35 36 34 30 28 36 75 32 34 2987.28 43 41 37 37 38 44 73 37 34 2287.3 33 46 47 32 32 43 86 32 38 28

87.32 35 37 38 37 42 34 121 35 41 3187.34 32 44 38 27 40 34 122 33 28 2887.36 37 42 61 35 42 40 117 26 39 3287.38 29 41 34 41 52 41 123 34 36 4487.4 19 38 29 43 30 29 103 30 38 39

87.42 31 48 35 36 44 38 78 43 35 3787.44 31 45 42 39 47 36 64 26 47 2487.46 32 41 29 47 28 37 64 27 39 2387.48 24 40 35 45 39 43 58 40 37 3387.5 29 33 36 35 37 43 56 23 35 37

87.52 32 27 36 32 41 42 48 25 47 4187.54 34 34 45 42 36 43 64 33 33 3087.56 30 33 37 46 25 38 56 31 35 2887.58 27 34 33 36 42 33 65 33 39 3187.6 36 36 44 39 34 29 72 24 29 25

87.62 40 41 33 36 33 27 94 27 36 3387.64 40 36 33 33 35 33 45 27 33 3087.66 35 32 28 30 43 38 51 28 35 3387.68 42 30 25 28 30 41 47 32 40 3687.7 40 43 41 37 33 33 46 23 30 36

87.72 42 35 34 33 40 37 49 35 43 2787.74 37 35 32 37 34 33 56 34 41 3487.76 39 40 41 38 38 24 41 45 43 3687.78 30 42 31 36 31 38 30 35 49 26

234

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

87.8 29 34 30 33 28 23 47 17 50 3887.82 28 37 34 32 36 33 43 43 40 2287.84 32 35 29 42 29 31 35 24 48 3287.86 32 36 36 38 32 41 36 34 59 2487.88 20 31 33 38 32 28 45 35 59 3487.9 35 33 22 45 40 28 44 32 60 27

87.92 25 40 39 34 36 46 33 25 48 3287.94 39 32 32 37 28 38 39 24 58 2487.96 35 34 28 37 46 26 20 36 54 3287.98 31 30 30 27 35 43 25 33 45 34

88 34 43 35 50 27 27 37 20 43 3188.02 38 40 31 39 28 42 34 28 52 4188.04 25 45 32 50 35 38 34 23 47 3488.06 30 37 27 46 30 31 29 38 46 3188.08 41 36 39 30 44 36 44 21 52 2888.1 27 24 32 37 39 47 27 18 59 28

88.12 27 36 29 40 29 29 42 31 53 2888.14 33 41 37 25 31 31 35 30 48 3988.16 28 28 36 26 35 47 34 35 53 3288.18 34 34 43 30 44 37 29 28 49 2788.2 24 43 39 27 42 32 31 26 40 37

88.22 31 27 38 34 40 25 35 22 60 3288.24 28 38 32 36 36 39 42 22 60 2988.26 33 31 26 41 23 23 30 22 67 2288.28 36 32 35 33 39 42 51 22 63 3988.3 31 31 29 35 36 27 29 31 85 26

88.32 34 35 35 42 31 38 34 27 67 3988.34 31 30 36 24 36 33 31 36 83 2088.36 35 30 40 26 28 42 29 29 73 2588.38 36 38 30 34 35 30 28 29 74 2688.4 30 28 36 35 34 35 35 30 69 42

88.42 33 31 42 38 32 33 33 34 65 2688.44 28 34 24 26 27 51 27 31 64 3188.46 45 36 26 38 36 35 29 30 56 3288.48 30 25 25 37 36 47 33 25 70 3088.5 31 45 32 28 36 38 33 22 54 37

88.52 27 35 31 36 40 33 41 32 48 3388.54 34 27 30 28 30 34 31 24 52 3188.56 41 30 25 37 39 43 27 29 52 3488.58 29 29 28 29 35 32 31 27 57 43

235

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

88.6 39 43 22 41 28 36 46 25 46 3288.62 37 23 30 37 36 35 44 31 48 3488.64 38 32 45 38 44 28 39 28 46 2688.66 40 37 35 39 33 33 33 28 53 3888.68 38 27 30 42 31 38 41 31 52 2888.7 23 30 35 39 29 38 33 33 41 31

88.72 30 34 40 37 48 25 26 29 32 3588.74 33 39 25 36 41 38 28 35 50 3388.76 29 53 34 37 26 31 34 18 47 3488.78 27 35 27 31 44 39 31 35 39 4188.8 35 42 36 49 33 42 44 32 39 25

88.82 32 43 37 32 34 37 39 35 44 3488.84 23 31 46 32 31 36 40 29 38 2688.86 26 53 30 29 41 31 35 27 42 3688.88 19 34 33 29 38 24 25 27 44 3688.9 27 35 30 39 36 46 24 32 28 35

88.92 33 35 37 41 32 40 30 17 37 3388.94 39 38 28 32 33 37 38 31 39 2288.96 35 32 32 23 32 28 37 21 32 2988.98 26 43 31 46 26 40 31 36 34 34

89 25 41 33 25 33 53 38 34 32 3089.02 26 26 26 45 30 24 23 24 45 3289.04 34 39 27 31 41 37 38 37 32 2189.06 25 40 28 43 19 32 50 27 29 3689.08 23 45 35 25 25 22 33 23 32 3289.1 45 34 39 42 32 33 32 30 38 27

89.12 37 33 21 34 27 42 36 23 41 3089.14 40 31 29 33 26 27 36 33 42 2289.16 45 42 36 22 26 30 32 23 44 2489.18 35 38 22 40 28 39 45 37 30 1989.2 35 43 39 28 35 33 42 29 47 31

89.22 32 26 36 41 24 25 35 27 45 3889.24 26 33 32 36 41 29 32 22 40 3689.26 43 44 27 42 32 31 32 30 41 2889.28 30 46 26 36 26 32 36 22 40 3789.3 42 37 22 40 39 33 36 31 39 27

89.32 37 29 33 31 42 38 41 28 43 2889.34 34 37 28 54 26 39 33 33 31 3989.36 27 45 14 35 32 28 38 28 30 3789.38 23 42 38 31 41 33 29 26 55 36

236

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

89.4 27 31 22 36 36 35 33 25 42 4089.42 39 37 31 43 33 38 46 21 38 3489.44 24 33 26 44 37 26 32 27 30 2689.46 28 37 31 38 22 35 34 22 39 3689.48 26 38 45 47 34 28 35 35 42 3489.5 32 40 39 35 30 33 35 34 47 37

89.52 23 39 34 32 31 33 32 30 45 2689.54 29 59 27 36 37 41 39 40 36 3289.56 30 30 38 36 35 30 34 24 29 3289.58 29 33 30 31 25 37 36 32 41 2889.6 34 35 35 38 35 31 39 26 33 35

89.62 35 41 21 40 31 38 21 23 43 3189.64 36 34 33 44 37 39 50 27 45 4189.66 46 33 41 35 32 35 20 28 47 3089.68 37 30 39 44 34 30 33 20 31 3389.7 20 37 32 37 27 34 27 40 47 26

89.72 43 31 33 29 29 32 39 30 31 3789.74 38 30 35 45 40 44 31 38 38 2689.76 37 35 31 27 34 30 35 28 27 2589.78 37 49 28 28 39 27 36 31 36 3089.8 37 33 33 36 39 33 35 30 25 34

89.82 38 28 31 28 32 36 41 36 36 2789.84 37 34 39 30 23 34 43 29 34 4689.86 35 35 42 38 40 31 27 28 31 2589.88 40 33 30 30 25 34 43 29 29 4589.9 41 34 35 32 44 34 40 32 35 28

89.92 33 33 36 33 41 34 42 24 35 3189.94 26 38 24 36 33 30 31 20 30 2789.96 33 33 33 44 44 36 25 33 42 4089.98 30 27 29 30 44 30 45 31 39 38

90 35 35 36 45 38 35 33 30 32 3290.02 27 42 38 43 28 46 36 31 47 2890.04 38 39 39 39 29 25 33 35 34 3690.06 38 37 36 31 39 23 43 26 33 3190.08 32 40 32 33 37 29 39 36 38 3690.1 34 38 38 26 33 33 31 34 29 34

90.12 35 27 31 35 44 43 38 33 42 2590.14 32 34 45 40 31 36 28 33 34 2490.16 39 37 40 39 36 39 37 30 40 3190.18 37 35 34 38 35 31 44 33 38 30

237

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

90.2 23 45 32 30 28 39 40 30 34 4490.22 36 30 35 44 47 37 42 32 37 2090.24 32 34 41 37 33 25 34 27 31 3490.26 35 39 36 31 35 27 40 42 44 3090.28 31 33 19 33 30 31 43 31 29 4190.3 32 42 35 33 41 34 32 33 45 30

90.32 39 31 41 41 31 48 29 26 28 3390.34 27 40 28 27 37 34 27 34 47 3690.36 29 42 28 44 30 36 37 28 35 3090.38 31 28 31 30 39 29 36 26 30 3290.4 30 35 35 32 37 40 28 34 32 40

90.42 39 33 36 39 29 28 25 30 33 3490.44 27 39 39 34 35 35 30 24 42 2990.46 29 38 33 38 28 35 30 25 35 4190.48 40 34 30 28 31 34 36 20 45 3790.5 37 37 43 25 31 42 43 27 30 28

90.52 36 41 30 32 43 47 47 26 36 3790.54 41 34 45 38 41 37 29 35 32 3690.56 34 44 32 45 34 41 43 33 30 3590.58 31 35 36 35 32 36 37 32 41 4490.6 35 32 49 35 32 26 32 39 26 34

90.62 37 34 38 27 27 34 33 27 32 3490.64 37 32 49 32 41 38 31 36 22 3890.66 36 37 36 37 42 32 45 26 36 3890.68 31 43 49 38 38 36 30 32 25 4390.7 32 48 55 45 33 28 43 28 36 37

90.72 38 54 46 44 49 43 33 27 37 2790.74 37 41 49 51 42 48 35 49 32 3990.76 35 53 59 43 32 41 34 44 36 4590.78 29 50 51 41 42 46 45 57 36 3690.8 25 49 48 59 32 41 43 57 43 35

90.82 43 44 47 42 33 42 35 58 33 3290.84 33 55 67 57 35 37 29 54 33 3290.86 32 53 52 44 34 33 46 53 32 3190.88 46 42 40 46 51 42 34 40 39 2990.9 37 48 49 37 39 37 39 43 46 30

90.92 35 53 53 47 43 46 34 55 35 3990.94 29 39 40 30 35 35 39 31 40 4390.96 36 43 44 43 36 33 33 32 40 4690.98 38 44 56 37 42 38 26 33 38 27

238

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

91 28 42 32 35 36 41 28 49 32 3291.02 39 40 35 33 41 44 42 34 33 3891.04 48 41 38 47 46 37 37 42 22 3091.06 27 50 41 48 35 29 34 37 42 3991.08 34 37 51 24 29 35 37 34 54 4291.1 46 49 33 46 36 36 37 51 37 31

91.12 40 43 44 39 28 44 37 39 45 4691.14 40 43 43 36 38 31 28 47 49 3791.16 34 39 45 32 28 40 33 50 41 3491.18 28 38 43 38 27 28 40 30 50 2291.2 43 39 30 39 27 34 41 35 34 30

91.22 30 36 35 30 47 43 37 20 22 3391.24 29 31 48 35 36 38 43 29 22 2991.26 32 31 42 32 27 38 29 25 36 4091.28 34 39 39 39 32 26 26 25 36 3791.3 36 37 39 39 29 35 30 30 24 32

91.32 36 37 37 32 31 44 36 27 29 3491.34 38 40 37 33 39 32 50 33 42 3491.36 26 38 57 35 39 30 39 23 35 3491.38 42 46 34 31 28 30 30 37 42 3391.4 33 42 33 33 42 36 41 31 34 46

91.42 35 31 45 35 30 42 37 35 48 3291.44 38 48 34 28 37 28 40 33 41 3191.46 31 37 38 37 44 30 33 24 33 3691.48 40 34 28 35 30 35 35 29 44 3991.5 26 43 38 36 33 35 24 28 37 34

91.52 35 44 32 41 39 32 44 39 36 3791.54 32 35 32 37 34 31 39 35 43 3591.56 34 42 25 39 41 35 43 38 37 3291.58 38 47 33 40 35 46 41 37 30 4091.6 38 42 36 40 33 31 37 25 42 35

91.62 41 36 32 36 30 48 35 24 42 3291.64 40 34 35 40 37 41 45 37 41 2891.66 35 35 41 36 35 38 34 29 32 3291.68 30 34 49 34 46 38 36 33 32 3191.7 45 38 40 33 40 45 26 36 37 51

91.72 26 42 32 40 22 26 43 34 34 1791.74 28 30 36 40 34 26 37 38 40 3091.76 40 32 49 42 34 37 35 23 40 2791.78 38 41 36 48 35 40 36 30 32 31

239

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

91.8 41 37 35 40 31 31 31 23 37 2891.82 25 27 36 30 38 48 34 34 40 4191.84 36 38 30 31 51 38 39 29 37 4191.86 39 38 32 44 29 42 34 26 31 3391.88 28 44 42 39 38 38 39 38 35 4091.9 32 50 37 50 29 38 38 29 33 42

91.92 38 34 37 36 45 31 52 28 29 4091.94 27 34 39 42 57 53 36 33 35 3191.96 44 39 41 39 31 34 40 32 46 3991.98 47 30 41 34 45 28 32 28 36 33

92 43 40 40 40 38 40 43 42 32 3892.02 26 38 34 42 33 36 31 26 33 3392.04 36 55 45 36 39 36 37 24 28 3492.06 43 31 37 41 36 40 31 24 40 3492.08 34 35 38 31 37 35 38 31 38 3592.1 40 32 41 47 37 35 36 35 42 34

92.12 44 42 49 34 31 45 30 34 31 3192.14 41 33 32 45 41 43 37 39 47 3592.16 31 39 36 45 21 29 36 25 42 4592.18 31 43 47 49 38 39 31 26 47 4492.2 30 49 31 32 44 41 27 51 44 35

92.22 46 42 37 36 31 38 50 34 35 4292.24 32 54 35 22 45 36 37 28 44 2992.26 31 46 35 29 46 29 48 32 40 4292.28 35 51 30 26 37 50 47 35 38 4192.3 39 35 27 53 38 39 31 34 42 28

92.32 44 39 37 44 37 42 44 29 36 3892.34 26 40 37 47 29 34 41 31 38 3492.36 41 45 44 43 41 47 32 23 32 3292.38 29 39 41 35 44 36 30 36 38 3792.4 39 37 38 40 50 45 37 28 35 43

92.42 32 34 46 37 51 37 37 30 40 3392.44 35 25 47 43 42 43 53 46 41 4192.46 39 40 45 43 38 40 40 40 36 4892.48 38 40 34 31 31 37 39 34 33 2892.5 38 54 32 46 39 46 53 44 56 33

92.52 29 47 35 43 33 35 40 33 51 3492.54 36 44 47 40 46 33 45 31 40 3792.56 45 52 33 31 47 33 39 36 40 3892.58 38 35 40 48 38 36 41 31 46 43

240

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

92.6 56 56 52 43 43 42 36 21 30 3992.62 35 36 38 39 46 38 37 27 38 5192.64 40 46 49 44 51 33 31 44 41 3192.66 44 48 42 50 45 39 34 40 50 5192.68 39 60 43 44 45 43 39 29 43 4892.7 41 36 34 47 41 44 45 38 34 49

92.72 40 37 41 46 62 40 41 50 49 3892.74 40 46 46 55 53 37 41 31 56 5192.76 37 48 42 40 44 32 42 46 49 5392.78 48 52 51 53 46 45 42 47 40 4192.8 60 59 41 61 42 43 39 34 42 38

92.82 45 62 44 55 39 42 41 43 39 3892.84 52 47 45 52 43 49 40 34 33 5092.86 46 46 38 51 48 38 41 62 48 5192.88 44 42 52 56 49 43 45 39 48 3692.9 59 47 46 48 69 50 49 52 45 46

92.92 63 41 43 64 49 52 46 50 50 5792.94 71 42 61 75 61 42 46 56 50 5692.96 75 40 43 56 67 39 48 55 61 5592.98 88 46 52 69 69 66 54 58 78 69

93 92 61 62 62 61 55 47 68 83 7793.02 103 59 59 71 74 67 65 71 92 7893.04 117 64 85 77 85 64 56 93 75 8593.06 115 52 57 77 105 83 75 98 85 9393.08 96 51 56 79 91 66 88 101 88 8593.1 89 74 67 101 98 72 65 104 97 101

93.12 86 76 83 84 89 79 67 100 85 7693.14 80 75 73 93 74 78 90 96 87 10293.16 69 65 86 74 87 81 59 88 96 9693.18 50 71 69 76 84 78 68 81 87 7293.2 60 97 78 80 75 98 69 94 65 84

93.22 50 67 74 72 79 63 69 72 70 7893.24 63 72 65 71 72 65 75 57 86 7193.26 60 79 68 71 74 74 48 83 77 7193.28 74 80 71 61 57 70 67 82 72 5993.3 80 65 73 83 65 67 80 73 63 69

93.32 65 84 68 64 71 77 69 75 58 5693.34 73 64 56 51 69 56 62 68 64 5893.36 84 75 62 75 79 58 68 73 69 7893.38 60 68 51 67 69 76 60 65 70 79

241

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

93.4 52 67 66 55 56 66 56 53 76 7693.42 57 51 62 71 75 64 65 61 65 7393.44 57 70 62 68 61 52 72 68 62 5393.46 44 67 63 53 45 64 54 49 57 6493.48 46 71 48 60 57 63 62 67 54 5293.5 53 65 53 59 55 52 61 52 51 54

93.52 43 64 62 66 55 47 55 52 46 5593.54 43 55 56 55 62 60 53 60 41 4593.56 42 61 66 49 45 45 48 39 59 4693.58 39 72 42 52 48 49 66 54 52 4393.6 44 75 53 60 48 52 58 58 41 50

93.62 36 55 51 57 40 49 56 46 51 6593.64 44 53 51 32 51 48 46 52 34 3193.66 31 41 58 43 52 55 54 44 40 3993.68 39 48 43 53 50 41 47 48 46 4993.7 33 57 48 42 52 44 52 46 40 39

93.72 38 38 42 47 38 58 52 51 39 4393.74 30 39 49 44 44 50 35 38 54 4193.76 42 36 43 54 42 38 55 43 43 4393.78 34 52 48 48 49 45 63 40 40 4193.8 56 48 49 46 54 44 47 40 31 40

93.82 43 42 49 44 44 38 49 39 48 5593.84 47 52 55 37 35 45 51 38 44 3693.86 50 51 43 43 38 49 43 40 45 3893.88 33 49 52 39 54 46 45 40 39 4593.9 45 54 48 45 43 53 51 27 47 41

93.92 50 40 37 47 41 53 50 42 38 4293.94 39 55 44 40 58 42 57 45 47 4293.96 38 53 51 53 39 43 50 40 39 5493.98 47 54 39 52 52 46 65 43 26 37

94 35 44 49 50 45 43 36 36 48 4194.02 37 62 39 62 40 35 45 40 48 3694.04 44 52 51 37 47 48 56 42 38 4194.06 41 44 53 46 45 52 42 47 33 4194.08 45 45 56 34 43 55 53 36 46 4694.1 61 55 59 51 53 30 61 46 48 35

94.12 64 39 41 51 31 44 63 47 48 4294.14 39 57 58 52 46 38 60 50 48 5894.16 57 43 57 42 58 51 62 41 38 5994.18 42 45 43 55 50 40 70 46 52 43

242

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

94.2 39 61 60 53 52 48 84 37 41 4794.22 53 44 53 53 45 46 55 42 46 5394.24 39 53 50 52 66 53 56 42 47 5294.26 47 51 61 48 46 43 65 49 48 5494.28 53 57 53 61 60 46 58 41 49 4994.3 58 49 61 40 51 51 68 47 44 44

94.32 43 47 39 40 58 39 51 50 64 4994.34 58 67 59 43 67 58 64 53 60 4894.36 63 55 52 64 68 48 74 48 63 6994.38 77 50 58 46 54 65 57 53 61 6494.4 61 60 61 67 60 61 58 55 61 45

94.42 62 70 57 52 68 45 69 52 48 7194.44 70 50 49 71 73 60 62 49 75 7194.46 83 75 50 79 84 67 75 51 63 7194.48 79 66 56 80 77 60 71 62 45 6994.5 65 84 82 78 72 74 77 63 64 71

94.52 71 80 66 97 100 67 87 69 67 8894.54 77 86 92 86 87 63 71 92 74 8794.56 87 71 89 90 86 60 80 65 74 8094.58 108 81 87 104 105 78 64 95 82 8894.6 149 112 91 95 103 108 101 117 103 108

94.62 152 111 94 98 133 109 100 134 104 9794.64 215 107 142 131 148 107 117 166 128 11794.66 254 134 148 145 186 108 118 152 136 16694.68 338 153 167 153 186 169 109 175 163 20494.7 380 198 175 208 216 126 138 228 196 214

94.72 369 188 143 223 251 186 167 269 202 21194.74 329 167 169 221 263 205 180 286 234 25594.76 249 183 187 223 255 204 196 289 227 25894.78 188 229 204 245 278 211 198 326 236 24494.8 175 204 199 230 290 208 208 297 218 226

94.82 142 218 207 203 233 208 191 291 203 21094.84 170 193 223 195 256 188 196 270 197 19994.86 152 192 190 188 191 187 160 206 187 20294.88 198 212 218 194 225 185 172 221 163 19294.9 199 206 230 177 176 193 178 255 175 218

94.92 251 217 194 196 225 188 174 205 183 20694.94 345 213 228 183 224 181 152 245 180 22394.96 386 200 228 250 260 210 182 251 209 26594.98 513 222 223 242 279 235 206 299 259 275

243

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

95 571 237 256 306 312 241 225 335 260 30395.02 524 264 250 282 347 238 262 363 298 37795.04 409 264 252 346 352 292 271 397 316 33495.06 279 268 244 314 329 296 269 411 342 36295.08 242 282 278 321 337 283 303 381 307 36295.1 187 276 249 288 313 264 252 362 303 320

95.12 159 218 271 235 275 253 240 330 246 29295.14 130 259 266 215 259 222 219 278 212 24395.16 124 245 263 208 189 210 230 262 200 21495.18 120 258 246 171 211 215 202 205 198 19395.2 126 264 228 186 165 192 162 182 170 195

95.22 138 225 210 146 166 197 154 171 143 17795.24 150 225 224 163 169 177 147 200 152 15395.26 176 192 184 156 160 148 140 160 148 15995.28 204 162 206 164 153 162 148 150 154 15395.3 233 179 160 161 184 151 142 178 165 179

95.32 194 164 148 156 183 167 155 158 186 13795.34 170 170 186 172 158 145 135 164 167 17695.36 148 163 177 148 182 152 147 176 179 16195.38 120 157 148 154 146 153 151 176 144 17195.4 101 151 152 127 131 162 140 156 144 131

95.42 88 145 159 127 131 131 126 136 113 13495.44 86 134 138 126 127 115 134 148 109 14595.46 83 152 160 116 122 116 127 119 117 11595.48 57 141 131 89 96 102 113 105 113 10495.5 80 125 112 94 101 106 77 108 70 91

95.52 71 99 106 79 71 94 92 75 82 8395.54 63 103 119 85 80 83 73 80 82 6695.56 61 113 100 68 76 87 70 72 60 5395.58 38 97 87 86 80 73 90 77 74 7995.6 57 84 85 74 71 83 68 78 74 74

95.62 67 101 77 77 70 71 74 58 61 9095.64 68 71 83 63 59 86 72 58 61 5495.66 51 74 83 66 63 58 63 56 71 5795.68 51 66 85 59 69 64 71 66 64 6795.7 48 72 73 50 54 54 73 66 62 67

95.72 66 68 77 59 51 68 76 58 53 4895.74 43 77 58 51 80 63 65 48 61 6695.76 54 76 64 70 65 48 62 58 58 4495.78 50 67 70 78 50 57 62 52 51 53

244

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

95.8 49 66 61 73 70 60 66 51 59 5795.82 61 57 64 53 56 63 62 50 55 6095.84 43 69 59 65 52 52 66 50 52 5895.86 69 73 61 59 74 52 49 58 76 7495.88 73 69 64 70 74 65 66 59 74 5795.9 68 59 63 60 58 58 43 64 45 60

95.92 65 74 70 48 70 66 63 57 47 6095.94 54 57 58 52 75 61 64 39 61 7895.96 72 56 59 65 69 62 54 59 68 5295.98 66 76 57 54 60 74 62 50 85 77

96 74 57 65 66 73 76 64 69 76 6596.02 94 67 58 71 71 67 56 73 66 6796.04 89 76 87 85 77 74 78 85 81 5796.06 135 74 64 98 89 78 73 81 76 7496.08 132 71 69 82 95 68 83 96 97 7396.1 208 86 76 97 95 65 91 81 92 98

96.12 248 82 106 107 101 91 86 97 93 9996.14 319 87 90 113 101 82 74 134 105 12596.16 294 107 82 111 124 110 101 137 130 11396.18 231 94 90 129 119 99 93 158 112 12296.2 193 107 100 110 130 118 100 186 127 124

96.22 170 103 94 128 136 118 100 176 119 11996.24 114 93 106 124 122 119 107 167 123 12596.26 106 105 90 123 130 105 116 158 122 12496.28 98 87 73 103 101 119 111 177 107 9996.3 90 100 110 109 111 112 105 127 95 97

96.32 71 110 111 116 112 102 122 120 91 10296.34 103 90 90 94 116 95 100 116 98 8596.36 96 96 89 70 95 84 90 116 94 10796.38 93 81 122 96 105 96 89 110 85 9896.4 99 88 108 83 90 102 87 109 86 94

96.42 120 101 87 78 81 89 77 84 97 8596.44 161 109 73 94 94 110 88 87 80 10696.46 175 106 97 90 89 102 98 96 95 8396.48 130 95 78 101 90 89 83 87 80 8496.5 122 97 86 82 97 77 78 100 104 79

96.52 120 88 88 83 86 91 81 102 87 9196.54 101 105 71 83 87 77 74 119 79 9396.56 76 82 75 80 65 84 79 98 72 8896.58 64 88 84 79 74 86 98 120 81 84

245

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

96.6 77 76 88 88 68 68 80 90 78 6596.62 59 68 78 68 77 67 85 88 75 6696.64 60 82 65 81 86 75 57 82 65 6696.66 48 80 86 62 78 72 58 89 88 7496.68 49 70 65 76 70 57 59 62 44 5796.7 42 75 71 53 62 66 64 62 74 59

96.72 53 65 65 60 56 63 67 70 63 5096.74 37 76 53 75 53 67 49 61 53 5696.76 64 44 61 45 51 56 50 52 55 6496.78 46 60 64 63 72 63 52 57 48 6296.8 39 60 62 46 47 49 54 47 46 46

96.82 44 63 45 49 59 59 61 49 46 4796.84 47 65 75 61 51 57 56 41 44 4896.86 47 42 41 46 58 55 39 50 47 4396.88 52 69 64 55 56 45 43 45 58 5296.9 37 56 55 51 43 42 64 39 55 59

96.92 44 68 60 39 44 51 57 47 48 5196.94 39 52 54 44 48 46 41 38 56 3596.96 38 63 47 42 57 51 46 35 51 3996.98 33 66 41 50 44 54 44 49 52 45

97 38 41 51 45 48 57 43 51 42 4897.02 56 50 51 47 47 33 54 36 60 5597.04 54 49 47 47 40 30 49 47 56 4697.06 40 35 50 53 37 40 34 47 44 4997.08 35 52 56 44 43 52 45 47 51 4497.1 45 64 35 54 43 41 28 37 28 46

97.12 29 60 31 42 44 43 43 39 48 4897.14 34 44 55 36 41 47 27 37 43 4697.16 43 48 57 48 48 54 46 49 48 3697.18 38 57 48 38 38 41 59 33 48 5197.2 46 42 38 33 49 51 37 37 37 52

97.22 51 37 42 42 43 41 56 33 42 3497.24 45 53 48 39 46 39 53 33 42 3997.26 38 34 50 45 45 42 46 38 43 4497.28 39 52 48 43 49 36 43 42 32 4797.3 46 44 43 41 46 39 39 37 55 46

97.32 36 51 55 50 51 54 44 40 38 5097.34 34 42 59 40 51 42 37 50 54 2997.36 49 47 47 29 56 45 39 48 40 4097.38 43 62 41 43 51 35 39 41 40 48

246

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

97.4 45 40 51 48 43 42 28 36 48 3797.42 41 33 54 51 52 48 36 36 34 3397.44 52 45 49 39 45 34 46 27 43 5097.46 45 45 42 34 46 37 44 34 41 3597.48 47 46 43 44 40 42 54 33 41 3897.5 46 51 40 38 48 44 44 46 55 55

97.52 54 58 34 51 46 41 56 42 37 4597.54 52 57 43 57 56 47 54 30 42 4897.56 36 61 45 41 45 47 62 53 52 5497.58 43 49 55 47 47 47 40 38 52 4297.6 46 35 39 42 54 51 52 58 37 54

97.62 43 55 39 35 36 39 46 42 46 4897.64 54 46 41 62 47 57 43 39 51 6697.66 47 56 55 48 66 49 43 55 43 4897.68 68 67 42 66 61 49 50 54 62 4297.7 71 40 43 45 67 38 53 52 59 70

97.72 63 62 51 46 60 42 53 47 46 7397.74 55 62 47 44 55 58 51 56 64 5297.76 58 41 53 59 50 47 58 60 53 5897.78 39 52 53 53 44 67 47 54 42 5297.8 48 50 46 51 56 53 63 60 61 54

97.82 37 49 48 54 47 44 54 56 58 6297.84 41 50 44 65 55 49 38 47 42 5497.86 37 51 51 56 54 65 57 48 42 5497.88 56 54 42 56 66 57 47 39 45 4997.9 47 62 61 52 44 57 56 40 44 52

97.92 33 49 38 47 48 49 44 49 35 5197.94 39 62 46 63 62 54 48 47 43 6997.96 49 43 46 57 73 56 51 44 51 4497.98 45 53 46 59 46 63 56 36 46 55

98 47 56 46 45 49 39 46 54 44 5398.02 53 43 46 43 56 46 42 45 45 4398.04 56 60 38 46 59 56 46 45 46 5198.06 55 59 45 65 60 38 48 52 51 4998.08 53 61 45 52 49 44 55 46 48 4298.1 47 49 46 62 59 44 34 52 52 46

98.12 45 55 63 59 55 50 53 55 51 5298.14 33 51 54 39 49 50 51 41 51 4498.16 43 40 36 55 49 48 44 40 45 3898.18 51 54 53 40 49 48 40 42 41 48

247

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

98.2 46 54 43 53 55 57 48 49 55 5498.22 42 47 38 50 51 45 51 35 67 5198.24 53 59 51 50 45 46 42 47 39 4098.26 37 48 54 59 45 43 44 47 47 5798.28 55 64 56 61 51 57 47 40 51 5098.3 38 51 40 47 51 42 45 48 38 38

98.32 47 52 37 52 48 51 59 43 42 5198.34 50 48 39 48 39 51 61 40 48 4298.36 44 47 33 51 46 39 48 48 47 5598.38 52 52 54 53 62 45 52 50 51 6198.4 51 50 65 41 55 44 43 33 56 32

98.42 56 49 50 54 42 46 50 37 41 5498.44 44 54 50 67 47 36 37 45 33 4498.46 53 55 48 45 54 61 51 47 45 5498.48 46 53 50 63 43 45 54 59 39 3698.5 48 59 48 56 44 46 62 46 52 44

98.52 52 51 63 52 40 39 54 50 46 5198.54 49 60 46 60 47 42 38 44 38 6098.56 51 57 52 47 65 42 57 44 52 4798.58 49 44 44 57 49 57 53 48 34 4298.6 47 56 52 51 61 55 39 47 59 52

98.62 65 57 61 54 66 53 53 57 54 5298.64 57 58 63 56 53 51 55 51 54 5098.66 64 52 53 71 43 50 70 40 56 4198.68 52 62 41 53 69 41 56 50 37 5998.7 52 56 47 77 59 50 55 62 58 59

98.72 58 62 57 71 73 55 50 45 53 4098.74 48 58 60 70 52 56 54 59 42 5598.76 56 69 68 60 48 69 71 64 63 5898.78 70 53 58 70 64 60 72 58 45 5898.8 63 67 70 63 67 49 57 58 50 68

98.82 49 60 59 70 62 58 46 58 66 4698.84 54 57 59 54 86 53 68 58 45 4798.86 65 62 55 73 65 54 63 75 69 5698.88 78 67 65 84 82 69 69 83 57 6298.9 71 67 61 73 59 74 56 77 67 64

98.92 87 58 62 74 83 74 64 66 62 7798.94 89 63 70 75 79 58 64 71 74 6698.96 107 78 88 73 99 89 71 74 96 7198.98 86 78 77 75 87 67 62 88 85 80

248

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

99 124 88 76 90 102 80 80 84 90 8199.02 127 100 73 75 101 65 98 83 88 10499.04 154 86 93 109 108 72 101 103 107 11499.06 187 88 93 89 104 80 84 124 101 11899.08 250 97 94 132 142 106 90 127 131 12199.1 347 102 92 131 116 113 102 158 122 133

99.12 402 120 99 134 195 123 119 180 150 14099.14 396 117 118 171 153 127 125 202 154 15499.16 374 126 129 151 185 153 122 240 186 17399.18 318 112 112 171 174 151 157 269 164 20799.2 244 84 132 167 191 162 156 250 173 192

99.22 191 142 141 150 167 145 161 268 192 19699.24 170 129 132 173 151 150 151 288 178 18699.26 145 124 128 145 168 161 165 233 172 15599.28 110 151 150 171 159 158 160 235 166 16499.3 98 135 125 133 139 126 167 235 149 160

99.32 116 131 154 148 137 155 134 189 141 13099.34 91 141 135 140 113 133 142 180 132 12399.36 106 138 128 146 115 126 122 169 112 12199.38 129 124 136 104 113 125 113 151 130 11899.4 143 129 128 102 109 117 113 134 100 132

99.42 154 131 138 112 117 141 113 146 104 11199.44 176 135 126 111 120 112 123 131 99 13099.46 210 128 116 127 141 140 112 144 104 13099.48 206 113 120 137 111 121 101 144 124 12999.5 169 106 118 99 110 107 128 149 136 115

99.52 144 139 114 122 100 132 105 188 121 12799.54 120 121 113 95 119 102 112 145 109 11699.56 97 130 92 121 101 110 102 138 124 12499.58 92 120 97 115 89 102 112 136 116 9999.6 73 113 113 96 109 100 100 130 107 106

99.62 74 83 86 104 83 99 91 126 93 8999.64 76 101 114 107 88 92 91 99 69 8399.66 68 105 98 84 80 88 89 106 78 7299.68 60 100 93 86 81 98 101 102 74 9899.7 61 104 83 98 79 85 98 97 78 86

99.72 73 87 91 75 69 84 61 81 76 7599.74 42 101 73 72 72 74 62 75 63 7199.76 37 89 79 66 69 83 62 77 72 5599.78 48 82 63 69 71 90 63 79 79 67

249

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

99.8 58 74 74 67 58 54 56 73 81 5699.82 42 85 52 72 47 71 52 54 64 6499.84 45 80 71 57 60 56 62 53 59 5999.86 48 68 72 66 59 50 56 59 64 5399.88 54 65 73 45 50 61 56 54 64 6599.9 47 74 67 56 59 70 75 43 60 59

99.92 37 64 68 50 51 48 47 37 53 4599.94 42 68 47 53 49 46 51 48 49 5399.96 35 58 45 45 49 68 58 42 49 5599.98 48 45 51 64 59 62 47 40 64 54

100 49 66 50 49 43 55 59 40 55 48100.02 45 52 61 51 59 51 55 47 52 63100.04 40 53 58 49 52 66 52 50 60 44100.06 43 67 44 44 54 40 48 46 51 39100.08 50 49 53 52 53 37 36 40 60 44100.1 42 57 41 45 47 52 51 43 46 46

100.12 43 52 43 51 50 41 56 37 46 54100.14 50 53 38 51 55 44 45 37 45 44100.16 38 49 47 53 41 46 56 46 48 38100.18 43 64 55 51 57 41 61 33 54 49100.2 47 49 44 68 44 38 62 40 46 49

100.22 31 69 45 44 47 56 50 34 35 46100.24 54 53 41 47 58 51 60 34 45 37100.26 44 54 43 40 39 50 41 40 48 45100.28 41 49 45 52 48 50 52 35 53 42100.3 31 50 54 59 47 43 36 41 67 31

100.32 40 48 60 42 49 55 46 50 46 40100.34 38 64 51 60 47 50 49 41 51 33100.36 52 58 36 46 58 43 53 45 70 49100.38 35 48 54 35 53 37 46 39 45 39100.4 35 60 49 39 58 58 52 41 51 47

100.42 48 44 44 59 36 47 56 41 53 46100.44 48 53 47 31 43 56 47 38 53 45100.46 37 53 42 57 47 56 52 41 26 40100.48 45 46 43 52 37 48 44 39 60 47100.5 37 59 52 54 35 56 55 42 57 44

100.52 37 45 47 67 41 46 49 43 48 37100.54 37 61 42 52 38 49 46 36 54 40100.56 49 45 39 42 39 47 35 35 45 58100.58 42 46 40 44 39 34 33 50 43 50

250

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

100.6 39 37 32 46 56 42 53 41 59 49100.62 41 52 45 49 57 58 38 34 56 34100.64 41 45 35 46 50 47 52 39 50 33100.66 49 52 45 50 39 43 53 40 55 49100.68 40 60 42 43 34 46 48 43 50 36100.7 33 57 43 47 30 39 58 31 66 30

100.72 32 46 40 40 39 40 48 43 62 37100.74 56 59 55 36 50 39 43 41 50 49100.76 38 46 38 40 53 57 50 35 50 48100.78 39 43 35 53 55 53 50 42 51 48100.8 36 42 39 56 45 36 43 53 59 46

100.82 41 60 34 44 38 51 51 42 40 44100.84 41 44 64 55 33 50 51 35 58 44100.86 46 47 44 45 59 37 52 42 45 40100.88 44 50 44 45 49 45 49 34 53 45100.9 45 58 41 45 48 44 50 35 62 46

100.92 60 46 40 46 48 49 50 41 48 45100.94 43 54 52 39 56 47 59 27 42 44100.96 37 48 36 48 40 55 50 40 65 41100.98 38 38 51 39 38 46 47 40 51 44

101 52 41 49 50 45 63 41 42 63 42101.02 38 51 52 33 49 60 54 43 74 47101.04 35 43 37 45 50 45 48 32 45 42101.06 52 55 40 40 39 38 44 43 67 39101.08 46 46 35 51 42 58 59 25 57 40101.1 44 46 45 61 57 43 47 44 49 55

101.12 35 52 46 46 44 50 47 42 71 43101.14 39 66 50 47 41 40 44 48 72 40101.16 47 38 47 46 49 53 56 27 73 41101.18 50 51 42 45 34 48 43 36 62 40101.2 47 50 57 43 47 35 49 35 58 41

101.22 46 34 42 40 39 46 43 35 59 41101.24 45 40 37 36 59 49 40 29 60 50101.26 37 46 33 57 50 43 45 54 51 39101.28 44 48 55 43 40 47 35 35 49 56101.3 46 49 37 40 36 54 46 40 55 45

101.32 46 45 39 44 51 54 49 39 54 54101.34 41 46 48 40 47 40 43 26 57 45101.36 46 56 55 35 57 47 49 39 41 42101.38 49 44 46 41 43 44 38 43 46 45

251

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

101.4 52 41 46 37 40 40 46 39 42 50101.42 45 50 30 65 35 50 45 36 47 50101.44 47 49 36 38 51 44 37 38 50 54101.46 47 46 42 37 52 39 41 41 42 45101.48 42 50 41 51 31 50 39 42 54 38101.5 50 59 48 47 46 45 44 35 52 54

101.52 36 45 49 43 53 35 44 40 48 46101.54 45 54 42 41 44 47 41 36 48 40101.56 55 46 40 43 42 38 46 28 50 32101.58 57 37 46 46 48 51 42 43 62 35101.6 50 44 55 40 38 46 47 32 54 46

101.62 37 50 45 49 42 40 71 38 56 50101.64 40 38 33 43 37 48 51 49 35 42101.66 54 57 43 45 39 49 37 47 35 46101.68 61 37 47 51 40 47 54 43 57 43101.7 39 42 50 44 43 57 39 36 52 41

101.72 46 59 56 58 49 45 45 42 41 48101.74 35 49 47 37 51 58 59 32 48 46101.76 37 50 42 45 40 47 40 43 52 40101.78 39 41 41 51 35 42 44 41 44 38101.8 53 49 49 38 52 55 40 38 53 51

101.82 52 44 43 44 48 47 41 45 44 41101.84 37 41 50 45 51 36 37 45 50 44101.86 42 50 44 45 58 47 56 44 53 42101.88 37 51 48 58 54 46 50 34 44 36101.9 63 50 59 57 51 48 42 35 51 49

101.92 59 48 45 46 63 63 46 33 40 39101.94 48 51 47 58 40 46 47 57 34 51101.96 48 53 59 31 47 62 55 46 61 45101.98 51 52 38 61 49 48 50 39 42 44

102 47 55 47 47 53 46 57 45 54 51102.02 50 46 52 49 57 52 45 52 52 59102.04 60 42 58 51 54 50 53 39 47 47102.06 48 52 55 46 53 55 57 43 44 50102.08 54 35 50 48 54 54 42 44 61 48102.1 57 60 49 41 54 46 45 46 57 43

102.12 67 58 47 45 61 43 55 46 65 63102.14 57 61 61 61 52 46 62 37 58 56102.16 87 64 63 58 63 54 54 80 55 52102.18 84 67 76 61 74 50 56 54 65 45

252

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

102.2 80 67 58 60 73 77 69 73 59 45102.22 70 43 63 52 57 56 60 60 73 66102.24 73 79 61 61 65 52 71 59 60 74102.26 67 70 62 69 69 71 66 58 68 66102.28 71 52 75 73 63 76 60 56 72 62102.3 65 85 63 49 71 59 45 64 94 65

102.32 57 81 55 66 60 72 53 73 78 61102.34 70 64 60 62 63 64 63 75 104 68102.36 51 74 62 57 64 60 77 81 82 53102.38 60 68 63 71 62 57 65 72 68 60102.4 54 65 62 63 51 68 54 64 84 61

102.42 60 71 67 61 59 62 71 52 54 56102.44 40 76 59 69 67 40 67 61 67 52102.46 59 68 59 57 49 75 52 61 55 56102.48 58 63 64 61 58 62 58 52 59 65102.5 61 69 43 51 47 55 67 54 64 43

102.52 51 56 66 72 51 57 61 59 69 62102.54 66 69 74 70 62 63 66 65 63 64102.56 61 52 63 59 67 57 46 53 59 70102.58 70 73 69 70 58 72 58 70 89 57102.6 50 67 57 51 65 71 72 53 73 59

102.62 68 56 55 72 57 62 65 47 74 62102.64 56 61 77 59 68 67 58 49 66 66102.66 53 64 75 72 51 67 57 61 69 64102.68 67 60 64 60 55 66 72 56 66 76102.7 78 61 63 69 79 52 60 51 78 56

102.72 68 63 61 57 62 55 70 48 73 63102.74 73 63 66 73 52 74 56 68 85 56102.76 83 60 83 58 81 59 63 72 62 56102.78 85 75 73 77 67 68 49 74 76 71102.8 71 46 66 74 74 77 80 70 78 70

102.82 91 69 75 72 78 84 65 66 75 69102.84 100 67 68 79 79 72 90 78 86 96102.86 116 75 70 82 84 74 73 98 89 87102.88 145 86 83 101 94 71 87 90 72 90102.9 192 80 95 111 116 94 71 112 87 98

102.92 211 68 104 101 106 102 84 108 89 121102.94 187 84 97 109 126 100 98 132 99 109102.96 180 86 89 109 126 120 96 125 107 114102.98 119 87 82 129 132 119 94 150 108 112

253

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

103 135 83 98 110 109 109 91 152 144 132103.02 96 76 91 125 99 108 99 148 117 127103.04 108 81 84 110 124 108 106 140 111 116103.06 82 116 102 108 115 98 98 138 94 101103.08 89 93 85 84 118 102 93 139 93 93103.1 70 100 103 105 98 92 77 114 87 96

103.12 84 96 119 101 77 85 93 104 72 105103.14 84 113 92 73 96 85 75 97 66 106103.16 87 95 95 89 106 107 101 103 77 81103.18 62 100 99 75 87 86 67 83 82 103103.2 86 95 77 94 87 71 86 85 83 78

103.22 76 90 89 76 91 95 87 94 91 75103.24 87 84 79 87 90 99 86 87 74 81103.26 119 86 108 99 77 101 88 66 78 74103.28 117 108 88 103 92 88 72 97 78 89103.3 96 72 81 71 98 73 96 76 67 90

103.32 89 79 79 91 83 71 71 78 75 91103.34 79 65 85 104 105 68 87 92 83 93103.36 85 95 100 94 96 93 88 94 86 103103.38 69 86 79 91 80 65 71 103 73 108103.4 74 95 89 94 92 86 86 96 75 81

103.42 70 87 81 64 65 83 80 95 70 84103.44 57 89 69 77 72 83 67 87 77 72103.46 86 72 78 88 81 84 90 83 80 68103.48 80 74 81 71 82 85 97 72 62 71103.5 103 96 85 67 84 86 85 79 73 60

103.52 104 92 83 64 74 71 84 92 78 74103.54 114 79 85 75 82 84 81 72 66 66103.56 103 58 85 66 68 65 80 76 72 81103.58 76 75 86 79 62 66 87 81 78 73103.6 68 86 66 83 79 57 64 75 68 75

103.62 81 89 73 62 71 74 74 57 74 73103.64 64 67 85 72 72 68 83 80 67 82103.66 70 80 87 85 82 84 61 74 62 78103.68 74 77 68 80 70 61 74 73 65 61103.7 64 71 59 50 61 72 59 56 67 67

103.72 66 72 72 62 69 65 68 59 57 65103.74 54 57 67 66 67 80 68 74 74 68103.76 67 62 66 71 67 61 90 60 75 60103.78 67 56 79 82 60 69 68 45 77 57

254

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

103.8 75 71 68 73 57 67 69 44 43 75103.82 63 85 62 72 65 75 69 52 62 65103.84 74 81 55 64 80 67 67 54 52 69103.86 93 80 61 88 65 53 53 61 62 65103.88 83 71 71 71 71 61 74 68 69 72103.9 73 57 66 63 85 77 63 79 66 77

103.92 90 77 76 66 79 70 68 76 75 81103.94 89 74 81 65 67 64 79 53 77 68103.96 74 66 65 82 92 77 85 73 74 63103.98 71 80 60 84 84 59 72 89 73 81

104 96 70 74 83 86 47 68 77 68 82104.02 102 83 79 75 90 81 68 72 84 84104.04 112 84 83 84 66 94 58 75 85 83104.06 131 62 85 108 106 71 71 94 84 107104.08 134 80 82 88 76 69 80 96 96 100104.1 171 95 88 99 108 77 70 106 104 82

104.12 169 81 95 85 92 73 111 122 101 118104.14 160 78 81 97 98 93 76 107 113 95104.16 122 91 89 97 115 100 80 102 94 104104.18 112 89 80 92 98 115 93 118 101 115104.2 94 91 94 93 90 90 103 111 86 85

104.22 83 99 102 97 87 101 89 94 85 94104.24 66 90 72 89 72 88 88 116 74 84104.26 61 95 77 79 81 80 79 105 88 86104.28 70 82 78 79 89 100 109 109 91 115104.3 81 87 93 79 92 97 82 99 78 77

104.32 70 100 87 80 88 70 95 82 70 86104.34 74 95 84 87 80 98 80 84 77 83104.36 67 89 79 80 85 96 68 79 61 87104.38 68 84 86 55 74 82 70 91 74 65104.4 76 75 70 64 75 69 60 68 75 80

104.42 70 77 82 88 91 79 75 72 72 74104.44 89 86 97 89 77 73 63 86 60 67104.46 106 78 81 84 64 99 62 81 80 91104.48 105 81 79 68 66 73 61 80 67 70104.5 82 65 75 69 87 79 69 86 81 74

104.52 77 76 78 70 71 72 57 80 79 70104.54 62 87 79 60 72 74 78 67 57 86104.56 65 70 67 69 66 85 67 92 59 88104.58 48 84 72 58 79 84 81 72 87 76

255

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

104.6 56 73 57 68 57 82 66 70 73 80104.62 59 70 75 73 80 66 73 78 77 68104.64 57 53 59 59 76 66 68 65 58 72104.66 64 61 68 58 55 71 74 64 59 65104.68 60 87 61 70 65 63 68 69 62 67104.7 52 73 77 54 70 62 63 64 59 63

104.72 69 81 58 51 66 71 63 54 59 59104.74 57 50 68 56 67 50 66 60 57 60104.76 43 57 57 60 60 64 70 56 42 63104.78 62 63 58 57 58 60 56 44 55 60104.8 49 58 64 53 59 67 56 48 55 53

104.82 50 74 59 63 62 55 52 48 61 57104.84 36 40 50 38 52 55 58 51 59 62104.86 50 66 58 42 37 41 57 47 56 42104.88 45 69 56 49 53 72 54 53 63 58104.9 44 57 53 50 46 60 50 46 50 53

104.92 49 71 53 55 55 41 59 46 55 58104.94 49 44 59 47 52 69 59 64 61 52104.96 54 50 54 50 62 45 50 47 50 55104.98 48 57 61 62 52 56 53 56 41 54

105 49 65 65 51 59 45 44 45 42 46105.02 50 47 50 58 53 46 45 41 49 40105.04 39 54 48 63 53 51 56 44 51 50105.06 40 51 52 41 60 50 58 41 52 45105.08 49 50 50 40 52 40 55 44 50 41105.1 50 58 57 56 48 44 40 36 71 54

105.12 56 68 64 36 52 61 46 35 53 58105.14 47 47 41 45 48 38 55 37 58 69105.16 44 56 46 65 43 42 60 45 65 46105.18 52 51 49 54 65 48 57 51 56 52105.2 52 62 59 55 50 60 50 44 48 57

105.22 46 48 60 30 58 50 49 45 70 51105.24 38 44 44 51 49 53 61 43 62 53105.26 51 48 44 46 60 43 53 38 57 53105.28 49 54 59 53 46 52 37 43 62 53105.3 52 53 65 61 49 47 59 38 47 43

105.32 50 49 59 39 50 51 50 46 56 35105.34 51 52 49 44 51 46 61 43 50 64105.36 61 48 67 44 45 48 64 56 54 55105.38 39 59 52 52 48 50 48 45 55 52

256

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

105.4 48 53 60 62 69 50 57 51 54 56105.42 57 42 47 42 48 56 49 50 75 51105.44 70 37 53 59 52 61 57 44 61 64105.46 57 44 54 58 65 50 72 55 55 55105.48 57 37 48 55 53 46 57 50 43 49105.5 57 54 44 49 45 56 55 55 58 51

105.52 60 60 68 47 63 54 46 48 65 50105.54 54 62 48 67 51 59 71 41 52 49105.56 62 71 52 65 60 62 69 49 52 50105.58 56 54 51 69 62 62 66 42 50 48105.6 67 62 61 58 54 45 70 55 70 62

105.62 65 59 62 59 76 53 69 51 61 63105.64 73 74 65 66 63 73 79 53 74 66105.66 85 63 70 71 52 62 66 60 63 55105.68 85 74 68 75 68 75 81 55 74 75105.7 80 64 53 59 73 61 99 56 75 68

105.72 89 74 69 80 57 68 87 81 77 67105.74 97 80 63 68 82 69 106 75 88 90105.76 92 58 60 99 65 60 115 74 87 79105.78 110 74 77 93 96 94 107 86 86 59105.8 127 84 74 108 85 87 102 106 101 98

105.82 141 82 75 116 87 88 114 100 111 87105.84 135 103 93 110 119 93 122 124 118 108105.86 138 95 97 116 117 89 111 131 131 120105.88 128 87 88 119 127 127 122 129 117 120105.9 110 97 106 111 132 101 110 141 123 127

105.92 95 117 85 116 150 104 120 144 115 124105.94 104 91 103 127 117 92 118 115 109 115105.96 105 112 121 111 124 99 131 118 114 106105.98 117 122 107 101 143 112 104 142 113 97

106 103 119 129 122 111 109 106 155 105 105106.02 110 94 110 128 116 117 111 145 135 110106.04 139 113 97 128 115 124 108 124 131 126106.06 173 134 104 127 122 130 140 116 130 124106.08 207 117 121 131 133 131 133 159 117 140106.1 272 104 112 132 148 133 136 151 149 138

106.12 264 135 132 122 108 123 139 163 128 127106.14 277 135 127 160 157 128 143 186 145 152106.16 235 105 100 146 158 120 139 215 179 138106.18 213 140 137 157 143 133 145 231 154 133

257

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

106.2 182 113 122 147 144 145 136 238 160 144106.22 145 139 103 137 127 154 151 214 159 163106.24 135 121 132 153 136 126 144 219 161 140106.26 100 128 131 151 138 140 142 185 159 142106.28 104 113 122 127 132 131 140 191 158 126106.3 103 145 117 131 121 124 100 177 157 133

106.32 104 130 133 123 130 129 117 162 124 155106.34 91 103 117 126 129 111 115 175 122 109106.36 86 129 109 115 122 134 113 142 106 117106.38 94 133 121 119 122 110 106 129 111 116106.4 104 106 118 107 131 114 115 112 99 106

106.42 93 105 113 102 105 131 104 117 99 99106.44 111 115 115 102 98 109 93 100 107 100106.46 112 103 114 106 98 90 102 120 92 111106.48 151 96 96 119 124 104 98 102 109 89106.5 133 106 102 96 119 102 90 145 106 107

106.52 145 101 108 106 100 92 96 122 110 100106.54 109 94 120 96 107 94 73 129 103 104106.56 102 103 134 111 86 114 85 123 96 103106.58 94 112 99 98 86 107 81 124 77 100106.6 102 99 82 101 86 83 82 113 103 76

106.62 78 98 94 94 99 93 70 121 100 94106.64 65 86 92 97 92 77 83 104 80 77106.66 66 87 85 89 76 96 86 107 101 79106.68 68 93 79 78 93 77 68 85 73 71106.7 47 90 92 75 81 75 81 94 85 72

106.72 63 66 92 86 72 64 61 77 68 74106.74 57 87 91 72 71 80 68 77 74 59106.76 55 70 73 68 70 76 79 76 65 65106.78 56 79 80 57 65 78 74 68 73 76106.8 62 66 76 57 69 76 55 65 60 67

106.82 52 64 67 70 62 66 75 63 66 67106.84 50 72 81 57 62 56 66 53 61 61106.86 54 84 77 68 67 63 70 44 50 68106.88 46 79 69 61 63 50 51 63 60 67106.9 52 62 69 63 61 60 70 50 82 67

106.92 44 63 70 75 55 49 61 53 66 53106.94 44 59 80 60 53 67 55 46 64 57106.96 41 68 67 63 66 53 50 50 58 49106.98 47 51 62 58 58 59 49 43 57 60

258

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

107 51 59 47 50 62 55 44 46 48 46107.02 51 61 53 50 41 38 52 56 47 59107.04 58 56 56 51 55 54 45 47 46 54107.06 48 49 63 59 54 52 56 53 47 51107.08 51 51 55 72 56 77 44 47 60 56107.1 53 62 55 44 53 45 59 46 63 48

107.12 51 55 66 46 53 54 54 52 59 54107.14 49 52 45 52 54 56 56 59 50 53107.16 63 58 67 51 63 56 61 48 45 47107.18 38 51 53 37 52 49 49 56 68 51107.2 64 52 65 56 61 41 58 59 56 52

107.22 54 83 52 61 55 49 56 51 55 48107.24 59 55 55 61 53 58 59 53 61 54107.26 83 51 51 68 55 43 52 64 71 55107.28 69 51 44 66 90 51 55 64 72 61107.3 82 53 55 58 78 49 57 73 58 57

107.32 101 52 67 59 70 64 54 69 59 53107.34 83 51 45 66 79 51 64 77 70 61107.36 60 56 56 63 59 57 59 74 69 67107.38 78 71 63 67 74 62 72 87 75 74107.4 72 68 53 43 70 76 72 69 77 62

107.42 50 86 47 65 53 66 75 81 72 76107.44 53 59 63 75 70 58 70 73 58 65107.46 44 67 55 55 62 65 61 65 73 78107.48 55 57 70 69 67 59 60 77 67 71107.5 56 73 72 63 64 69 62 71 73 78

107.52 70 63 63 80 74 52 73 75 52 55107.54 39 66 60 58 54 74 63 78 42 69107.56 55 66 65 54 62 63 52 70 68 71107.58 57 52 51 49 60 61 53 73 64 56107.6 64 72 59 48 76 68 53 65 63 53

107.62 57 68 53 47 67 61 59 53 55 66107.64 61 61 66 77 44 45 51 60 51 63107.66 56 59 49 57 61 65 51 65 48 49107.68 62 63 49 62 48 56 55 43 56 73107.7 60 65 52 61 51 60 52 65 61 59

107.72 47 63 51 62 70 57 73 48 63 54107.74 68 64 50 59 44 48 60 59 69 63107.76 61 56 62 61 56 61 33 54 57 47107.78 51 57 59 47 53 54 50 66 61 55

259

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

107.8 50 55 51 56 59 44 71 55 51 60107.82 47 51 55 64 57 59 43 51 52 56107.84 47 66 57 57 59 48 49 54 43 57107.86 43 42 58 53 61 68 35 67 52 47107.88 64 56 51 68 51 58 58 44 53 73107.9 42 65 66 53 63 55 64 58 46 46

107.92 39 60 48 51 67 56 75 53 48 46107.94 62 51 65 54 51 51 50 43 49 57107.96 56 60 59 48 52 52 45 62 56 64107.98 55 51 51 62 61 58 59 64 53 50

108 54 66 43 52 57 69 36 59 65 51108.02 68 58 54 58 61 56 46 53 60 52108.04 66 72 58 42 55 60 40 68 62 54108.06 59 48 51 45 57 40 49 47 58 53108.08 39 63 56 50 63 63 58 56 45 52108.1 59 66 48 48 46 61 37 59 59 61

108.12 41 62 53 50 48 58 55 42 47 59108.14 56 57 46 50 44 46 53 42 53 55108.16 42 53 64 47 56 59 50 43 60 44108.18 39 42 53 57 65 58 53 50 53 49108.2 43 43 54 54 49 49 58 53 53 41

108.22 33 42 61 56 52 51 55 41 40 48108.24 39 46 53 52 56 63 44 48 42 48108.26 56 50 50 49 46 37 53 49 46 49108.28 50 50 58 48 44 51 44 31 40 47108.3 40 56 48 36 54 61 43 48 56 59

108.32 46 64 51 37 41 42 49 39 42 62108.34 53 36 58 48 42 37 49 61 49 51108.36 65 55 43 51 48 44 57 41 49 48108.38 44 54 37 50 41 59 55 55 45 44108.4 61 42 63 49 51 48 52 42 52 48

108.42 53 53 36 47 48 45 39 37 49 52108.44 46 49 47 47 48 48 44 40 49 42108.46 40 39 36 41 39 46 48 47 46 44108.48 47 59 41 40 47 54 46 35 48 49108.5 60 52 49 48 48 39 58 52 50 56

108.52 31 57 43 62 43 55 58 54 49 52108.54 43 42 30 47 43 41 38 54 55 36108.56 55 53 46 46 41 60 40 54 49 36108.58 40 54 46 48 33 50 57 39 51 38

260

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

108.6 35 38 45 55 48 40 43 41 48 47108.62 47 42 47 35 52 44 54 33 35 42108.64 35 52 34 43 41 42 39 37 36 52108.66 43 51 44 42 43 38 43 48 40 47108.68 48 47 48 43 44 53 44 47 43 51108.7 38 48 43 34 53 45 45 37 41 32

108.72 56 41 41 58 42 45 39 25 44 36108.74 34 41 36 42 41 55 38 36 53 34108.76 37 45 42 37 36 40 44 37 49 39108.78 42 51 48 44 54 49 40 41 39 43108.8 44 43 46 43 61 45 54 47 38 52

108.82 51 36 41 55 44 43 53 37 44 40108.84 43 52 53 50 34 52 57 29 46 48108.86 49 53 39 43 42 36 48 38 33 35108.88 37 48 45 41 43 46 42 47 39 36108.9 38 45 49 44 42 39 45 44 29 51

108.92 48 41 51 52 45 42 42 39 47 37108.94 36 46 46 47 42 42 41 50 49 48108.96 40 45 37 39 51 40 41 38 45 48108.98 35 50 47 34 49 41 46 45 61 37

109 42 50 44 47 42 47 54 31 52 41109.02 38 45 41 40 48 47 58 45 48 37109.04 45 59 54 35 49 49 39 45 42 41109.06 51 53 47 50 49 46 49 37 47 37109.08 58 43 42 40 50 53 53 30 52 50109.1 43 48 44 44 46 58 51 31 54 57

109.12 34 44 52 43 41 49 47 39 42 40109.14 54 58 54 39 45 41 53 28 45 44109.16 49 49 36 56 55 47 46 46 44 56109.18 49 55 34 38 61 47 46 44 52 48109.2 59 47 41 58 50 42 49 52 43 57

109.22 57 47 38 55 56 47 36 41 55 53109.24 55 59 39 52 46 46 58 39 53 46109.26 57 56 49 65 69 47 45 47 47 52109.28 58 46 46 57 43 51 47 47 39 52109.3 40 57 58 57 56 51 52 43 40 43

109.32 63 58 39 56 62 50 60 52 54 55109.34 71 69 52 55 54 58 57 55 42 53109.36 62 44 42 73 71 67 63 51 60 59109.38 78 75 51 54 69 49 71 64 59 68

261

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

109.4 79 60 61 68 67 56 57 58 66 44109.42 97 63 62 63 63 62 65 75 67 60109.44 94 71 70 67 85 64 68 71 66 79109.46 112 83 58 73 92 64 73 92 81 68109.48 123 67 75 87 91 58 77 92 92 78109.5 168 74 63 94 103 75 86 105 99 109

109.52 204 75 82 99 123 93 87 110 137 114109.54 229 91 99 103 114 92 84 167 123 128109.56 216 93 86 114 118 88 92 155 121 133109.58 196 97 89 143 130 102 95 142 127 144109.6 132 105 98 133 151 128 123 167 142 158

109.62 111 113 88 121 135 111 98 180 121 137109.64 101 99 102 118 135 126 111 159 123 128109.66 97 119 99 133 116 124 109 162 129 126109.68 95 112 108 107 124 110 109 149 110 123109.7 97 110 126 102 112 127 104 150 106 107

109.72 70 106 114 98 108 128 107 121 98 106109.74 84 102 98 97 116 88 95 114 91 104109.76 66 101 118 81 88 101 90 113 79 90109.78 80 114 124 94 80 106 86 134 83 98109.8 58 90 124 98 97 100 101 103 77 81

109.82 67 94 101 102 79 90 105 97 85 75109.84 67 114 97 85 79 91 73 97 85 82109.86 74 96 84 82 88 83 82 100 85 71109.88 98 86 89 70 96 99 79 116 85 89109.9 87 79 87 77 78 93 76 101 73 83

109.92 118 82 75 87 88 97 73 122 79 89109.94 120 77 73 84 87 75 75 85 85 98109.96 125 97 81 85 89 81 87 89 84 91109.98 119 81 87 105 78 83 68 116 99 97

110 88 94 85 112 100 90 74 103 70 114110.02 68 79 107 71 84 83 68 102 77 82110.04 68 83 84 85 89 93 82 86 85 84110.06 62 89 81 79 88 91 83 96 96 92110.08 71 100 70 84 88 79 73 94 58 82110.1 65 87 88 72 81 84 89 87 73 78

110.12 56 94 91 74 77 64 82 87 65 70110.14 56 75 76 72 85 71 83 98 86 71110.16 66 83 78 98 77 85 73 70 60 71110.18 49 74 80 59 70 74 74 85 68 66

262

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

110.2 46 80 67 69 73 47 61 90 68 57110.22 54 70 73 65 60 79 56 61 70 68110.24 48 72 66 75 44 50 57 64 59 68110.26 59 73 77 68 64 67 60 52 63 64110.28 62 63 52 63 63 81 58 61 64 61110.3 68 75 73 66 75 67 41 70 63 60

110.32 65 60 52 65 78 51 59 61 50 75110.34 53 59 58 75 78 67 65 56 58 63110.36 74 70 64 57 74 73 59 81 53 54110.38 84 66 73 57 77 74 47 64 78 71110.4 105 67 65 75 81 68 58 67 57 67

110.42 113 76 68 68 97 71 71 71 77 81110.44 120 61 60 72 82 59 65 99 83 78110.46 153 77 60 73 69 77 82 84 62 86110.48 146 74 67 90 100 68 81 77 82 92110.5 106 71 75 76 73 68 79 98 93 83

110.52 94 84 69 82 90 75 81 101 104 89110.54 93 56 87 86 94 96 78 103 94 84110.56 82 71 83 83 77 82 81 97 81 89110.58 81 74 75 99 68 75 88 101 86 89110.6 52 71 80 82 90 83 79 87 68 71

110.62 61 60 81 99 80 76 82 78 64 88110.64 63 55 69 69 81 78 67 60 70 86110.66 33 61 79 73 75 66 72 76 73 68110.68 43 67 57 54 63 64 71 69 64 66110.7 40 72 65 68 59 82 53 68 79 67

110.72 50 72 65 69 59 51 54 71 61 66110.74 62 61 63 51 68 55 71 60 71 53110.76 50 60 60 51 62 70 53 55 63 66110.78 50 66 64 66 70 55 67 67 67 66110.8 77 75 59 64 70 68 62 60 60 51

110.82 70 51 69 61 80 66 76 59 76 62110.84 84 74 64 66 69 56 54 59 58 56110.86 84 58 55 56 64 51 64 62 64 58110.88 89 56 58 74 63 61 72 60 60 66110.9 61 54 58 51 68 68 66 80 62 62

110.92 77 63 68 60 58 57 75 73 69 53110.94 75 76 61 56 75 59 62 72 66 64110.96 64 51 57 66 52 47 68 68 60 67110.98 49 75 67 51 44 57 62 62 59 61

263

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

111 47 71 47 58 54 59 63 62 59 44111.02 37 58 52 66 52 60 48 69 40 49111.04 48 67 61 44 64 74 63 64 50 52111.06 35 55 55 63 54 60 42 62 43 56111.08 32 57 43 43 54 47 43 63 59 50111.1 48 59 54 48 46 59 40 46 47 40

111.12 43 53 53 63 51 49 58 53 47 42111.14 47 52 41 53 52 42 41 47 62 53111.16 49 41 58 51 54 45 35 38 37 41111.18 26 52 55 33 32 43 46 37 44 40111.2 37 40 44 54 53 41 45 41 39 41

111.22 33 39 39 42 55 43 45 41 38 36111.24 42 39 50 47 43 48 42 31 33 37111.26 39 45 45 35 49 37 43 37 34 43111.28 36 31 42 47 55 43 45 39 40 29111.3 39 45 40 37 38 35 39 39 37 34

111.32 38 42 50 37 53 46 44 31 41 55111.34 26 48 50 33 49 45 30 38 47 37111.36 38 43 44 45 46 27 38 33 38 39111.38 39 42 37 33 50 52 39 31 41 42111.4 39 40 45 44 40 35 32 31 42 43

111.42 21 44 37 45 44 40 35 33 27 38111.44 36 39 34 38 26 43 36 43 44 31111.46 28 39 45 30 34 47 45 24 51 27111.48 37 42 38 40 45 46 48 31 37 39111.5 30 35 43 38 37 42 37 31 43 33

111.52 26 33 48 34 39 43 34 28 46 40111.54 30 40 43 27 40 41 42 40 34 32111.56 29 37 30 43 35 26 39 38 37 31111.58 36 41 35 42 44 32 43 31 48 38111.6 34 38 36 30 38 49 37 36 38 35

111.62 35 33 48 33 28 27 40 24 34 37111.64 42 51 43 42 27 51 25 27 36 22111.66 24 34 40 54 44 44 34 30 43 39111.68 28 40 39 32 36 28 41 37 37 27111.7 44 42 37 29 40 40 31 30 27 37

111.72 30 41 28 38 31 38 36 38 29 28111.74 33 38 32 36 43 39 34 34 26 39111.76 42 41 32 43 36 40 39 30 30 19111.78 30 38 42 37 38 54 38 28 42 38

264

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

111.8 31 33 37 31 41 24 32 31 42 34111.82 49 39 35 32 41 44 30 26 21 34111.84 28 49 37 26 31 29 40 31 30 27111.86 28 43 23 38 40 37 47 33 44 26111.88 34 37 37 32 38 38 38 31 29 34111.9 39 48 40 33 37 35 38 49 29 29

111.92 31 44 44 40 41 40 36 29 25 30111.94 43 35 24 42 42 27 32 30 42 30111.96 43 21 36 31 40 32 30 35 34 39111.98 38 30 34 36 19 38 29 30 20 36

112 38 33 36 30 44 40 36 22 38 28112.02 38 43 32 24 34 32 27 29 35 39112.04 27 29 29 36 41 29 23 34 34 28112.06 33 33 35 27 31 41 35 29 42 29112.08 36 35 34 34 37 39 28 33 34 32112.1 34 24 31 35 43 40 30 27 25 25

112.12 35 34 29 28 41 40 38 27 40 34112.14 33 38 47 39 32 39 38 36 41 32112.16 34 44 42 34 31 31 37 27 39 28112.18 34 41 27 27 27 33 28 26 33 42112.2 32 39 27 35 34 33 42 35 40 34

112.22 35 33 34 38 40 32 31 39 30 32112.24 32 34 33 28 34 24 29 25 43 34112.26 30 47 38 40 31 29 41 39 43 32112.28 28 31 29 25 36 36 34 26 28 19112.3 32 44 31 29 36 33 39 25 39 26

112.32 25 41 42 29 34 39 34 39 46 37112.34 36 35 32 36 31 32 31 33 41 29112.36 31 41 38 29 26 26 38 29 47 39112.38 16 36 31 28 37 40 26 29 39 26112.4 31 38 23 30 34 27 33 37 36 28

112.42 40 43 20 42 30 30 44 26 49 35112.44 26 37 31 25 28 32 33 27 53 32112.46 25 42 28 33 51 25 39 37 48 41112.48 43 45 33 35 33 36 32 31 46 29112.5 30 35 37 41 26 35 23 32 38 37

112.52 34 42 32 23 32 39 46 41 37 37112.54 41 31 33 42 29 40 30 38 38 41112.56 39 33 36 25 34 32 34 37 47 26112.58 34 42 34 31 30 42 46 29 41 31

265

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

112.6 37 34 37 39 36 35 37 26 46 35112.62 26 33 28 40 26 40 27 24 38 36112.64 27 24 34 31 42 27 35 24 35 32112.66 36 29 21 22 36 24 27 25 43 24112.68 35 30 28 38 43 27 34 39 30 37112.7 36 33 34 32 28 35 34 33 39 34

112.72 37 47 36 36 34 22 32 29 39 36112.74 27 31 36 41 41 42 38 24 57 34112.76 39 29 28 32 32 26 43 29 37 33112.78 29 33 32 33 31 38 29 44 33 35112.8 27 27 45 38 29 37 35 24 45 27

112.82 30 30 38 35 37 22 34 30 34 29112.84 27 29 28 37 39 30 44 38 47 27112.86 33 40 38 28 29 39 38 24 30 32112.88 36 39 29 37 38 31 38 25 43 25112.9 28 33 22 34 44 32 40 32 63 30

112.92 26 38 34 32 32 28 41 32 59 38112.94 35 38 22 32 35 36 52 39 53 40112.96 29 35 28 23 30 29 46 22 45 31112.98 35 30 34 32 38 28 39 27 53 39

113 22 28 32 32 38 34 43 28 54 28113.02 32 37 37 26 33 32 42 33 39 34113.04 27 28 42 33 34 37 48 39 45 41113.06 26 43 41 40 41 34 37 28 46 24113.08 33 32 34 33 24 40 60 27 41 30113.1 38 36 34 42 31 51 49 27 52 35

113.12 37 47 37 31 43 36 44 31 42 27113.14 22 33 26 23 45 22 44 36 36 37113.16 36 38 20 35 33 24 44 32 50 33113.18 28 34 31 33 31 34 39 42 44 42113.2 30 29 36 44 33 29 43 30 44 33

113.22 35 35 28 48 33 37 42 36 50 39113.24 27 35 30 41 36 34 37 22 53 28113.26 28 40 30 32 34 21 33 34 44 23113.28 34 37 37 39 31 31 37 30 29 23113.3 35 37 46 40 33 28 35 43 38 21

113.32 36 40 39 35 47 30 35 26 40 28113.34 25 34 46 38 35 31 43 40 37 31113.36 39 41 40 25 30 29 49 33 38 38113.38 29 40 43 30 43 30 37 28 34 36

266

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

113.4 29 32 31 37 33 27 40 33 43 30113.42 28 33 39 36 34 36 51 30 37 32113.44 32 37 36 39 29 30 40 39 43 35113.46 37 39 42 32 32 31 44 23 42 20113.48 25 35 29 31 38 34 38 40 39 26113.5 29 41 35 40 32 23 49 31 39 38

113.52 26 40 41 45 28 37 41 28 37 30113.54 35 39 17 32 32 41 33 34 26 32113.56 21 31 36 37 26 33 28 29 34 38113.58 34 39 27 31 37 42 35 30 32 43113.6 35 36 34 20 40 38 44 29 26 38

113.62 40 34 33 33 26 28 31 31 34 36113.64 34 30 30 30 30 24 33 30 27 41113.66 38 37 23 37 31 30 36 26 35 23113.68 33 29 31 39 32 30 31 37 34 35113.7 35 34 41 32 27 32 22 23 27 41

113.72 24 28 40 33 34 32 40 26 26 21113.74 31 37 35 32 33 29 27 34 38 31113.76 36 36 30 41 26 43 33 41 30 28113.78 47 36 42 39 29 38 40 33 39 27113.8 39 32 32 30 39 42 32 24 40 30

113.82 27 35 34 44 38 37 39 34 41 29113.84 39 44 45 51 32 34 45 27 37 38113.86 42 39 31 36 39 43 38 32 33 30113.88 30 49 45 38 38 32 28 30 37 27113.9 45 29 31 44 31 42 33 44 46 35

113.92 30 50 31 41 51 32 39 33 42 36113.94 42 46 30 37 40 33 39 30 33 28113.96 51 35 48 37 38 41 33 41 41 43113.98 58 43 48 35 45 38 40 45 37 35

114 45 35 42 43 40 32 36 38 36 35114.02 74 43 33 41 52 41 33 44 45 41114.04 62 38 46 58 47 30 29 53 54 35114.06 66 44 44 47 53 31 40 57 53 56114.08 53 40 48 45 48 41 41 44 51 51114.1 55 35 38 52 49 43 41 50 48 39

114.12 43 50 54 46 57 36 44 48 42 35114.14 39 40 44 45 39 40 44 50 58 51114.16 44 43 46 40 37 41 54 47 43 36114.18 46 49 42 54 44 43 44 51 40 37

267

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

114.2 33 49 54 39 37 43 39 43 39 38114.22 45 41 37 45 45 43 38 62 56 30114.24 39 54 51 50 50 29 38 37 37 29114.26 43 42 43 49 38 54 45 36 43 43114.28 38 55 43 54 38 35 46 39 28 47114.3 26 48 53 52 46 52 42 30 40 34

114.32 40 43 50 47 45 42 29 35 49 32114.34 38 50 42 49 39 61 28 42 33 29114.36 35 47 51 56 52 39 34 48 47 35114.38 44 48 63 41 44 44 26 49 31 32114.4 37 34 69 57 30 38 40 47 42 28

114.42 42 48 56 52 40 44 40 63 37 35114.44 44 42 59 51 54 42 38 70 46 48114.46 46 42 48 45 42 45 40 82 51 34114.48 43 43 57 49 46 31 45 74 33 38114.5 44 38 57 45 27 39 39 79 29 33

114.52 42 54 59 44 38 38 36 60 36 35114.54 39 40 44 45 44 42 36 60 42 41114.56 45 48 59 51 48 39 46 48 40 32114.58 23 49 34 55 50 34 40 48 44 26114.6 26 46 47 46 41 38 36 57 43 42

114.62 34 41 55 38 46 34 34 60 42 36114.64 35 40 36 41 36 39 38 48 35 31114.66 45 42 41 47 32 34 34 52 40 36114.68 33 37 42 47 33 48 37 42 32 24114.7 47 46 44 27 38 38 37 39 42 30

114.72 23 45 56 41 28 38 38 41 32 28114.74 41 43 35 36 28 36 37 31 31 29114.76 40 54 48 42 39 41 31 41 31 34114.78 27 30 38 39 32 44 32 30 36 28114.8 39 43 38 47 59 36 31 32 38 34

114.82 38 32 40 52 37 44 24 34 34 36114.84 27 44 41 38 43 34 26 31 27 33114.86 27 46 54 45 42 28 30 25 38 35114.88 37 32 56 43 32 40 33 47 33 38114.9 27 47 43 34 41 42 26 50 33 45

114.92 27 42 50 49 38 37 30 35 28 26114.94 22 30 46 44 42 27 34 47 34 33114.96 29 44 43 46 39 24 36 54 24 32114.98 35 37 34 36 27 33 35 46 33 24

268

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

115 25 34 35 47 29 34 37 43 31 36115.02 45 36 49 44 42 37 39 29 28 32115.04 32 49 27 31 34 29 33 35 34 33115.06 39 27 35 42 32 29 33 35 33 41115.08 23 35 39 37 37 33 32 34 28 33115.1 29 35 31 30 35 34 28 38 34 37

115.12 36 32 40 34 32 38 27 27 32 29115.14 33 40 36 37 38 27 37 31 44 31115.16 26 28 35 30 42 33 45 37 36 29115.18 28 34 39 29 33 32 30 18 28 32115.2 33 46 42 40 39 34 27 30 31 41

115.22 25 41 39 33 29 34 28 41 37 37115.24 34 38 32 30 31 40 40 42 37 22115.26 26 49 34 22 26 35 27 31 31 29115.28 32 31 29 36 32 24 32 37 31 31115.3 33 36 43 41 53 28 24 39 29 22

115.32 39 27 29 33 43 37 38 31 30 40115.34 25 33 37 23 27 34 34 24 33 33115.36 31 53 28 23 41 30 42 22 31 23115.38 35 36 32 43 32 34 34 34 36 30115.4 36 34 35 32 26 33 32 37 32 34

115.42 30 27 28 35 46 34 30 29 31 36115.44 39 44 42 30 30 36 32 35 37 32115.46 28 46 24 33 39 33 35 36 27 31115.48 29 42 36 32 32 36 45 37 33 30115.5 26 39 37 32 24 22 32 41 35 38

115.52 29 40 35 31 28 36 23 39 38 42115.54 24 37 33 25 36 41 26 46 35 36115.56 33 27 39 30 36 39 31 30 36 35115.58 43 32 44 39 35 37 38 34 25 32115.6 35 38 18 43 40 30 33 22 30 34

115.62 40 33 31 33 26 28 34 31 25 33115.64 38 28 34 31 28 33 26 36 41 35115.66 25 37 25 45 26 34 25 37 36 44115.68 36 30 41 38 31 31 30 31 23 31115.7 33 34 34 45 30 43 37 32 31 42

115.72 29 35 44 38 45 36 36 28 34 32115.74 29 40 25 35 34 36 38 38 37 29115.76 29 30 34 31 30 29 32 28 43 40115.78 33 37 27 32 37 32 35 32 29 27

269

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

115.8 35 32 18 42 29 30 38 33 47 24115.82 29 43 34 34 31 37 46 30 30 24115.84 35 16 34 39 35 34 33 32 38 40115.86 34 39 29 39 42 32 34 32 58 26115.88 27 32 29 34 24 36 36 27 32 40115.9 25 20 37 39 34 30 39 39 36 31

115.92 34 31 28 46 33 34 39 26 43 27115.94 28 40 23 34 31 26 41 27 47 29115.96 33 30 35 44 34 35 23 22 49 29115.98 31 39 24 39 38 23 36 36 52 44

116 33 37 26 32 39 26 40 26 37 31116.02 25 40 28 29 45 31 42 21 39 31116.04 37 33 34 46 42 37 36 23 42 39116.06 32 28 26 33 35 37 34 29 45 38116.08 34 41 37 34 34 32 30 34 25 27116.1 31 38 29 33 46 29 42 42 45 34

116.12 32 35 34 28 30 31 22 21 31 23116.14 35 38 29 41 37 38 27 26 41 40116.16 31 34 30 27 42 32 44 25 29 33116.18 31 40 31 34 26 38 33 32 21 25116.2 28 51 41 29 37 36 39 30 35 27

116.22 35 38 30 36 47 30 31 36 38 30116.24 34 40 35 33 34 39 28 39 39 28116.26 26 28 26 36 31 32 35 29 27 28116.28 43 44 32 31 35 25 32 30 39 34116.3 39 38 20 26 26 27 37 24 47 29

116.32 29 34 28 31 37 38 39 29 24 28116.34 27 41 29 28 37 45 37 30 39 35116.36 28 29 38 30 36 33 49 17 33 30116.38 30 33 33 43 33 35 30 23 29 19116.4 29 39 34 28 25 39 33 36 33 29

116.42 25 27 27 37 46 23 29 31 40 33116.44 29 29 24 38 45 33 27 25 37 37116.46 25 26 30 36 39 33 42 35 34 41116.48 40 33 30 25 28 26 34 29 24 32116.5 31 36 26 36 32 34 25 28 22 31

116.52 31 30 27 35 30 36 31 32 35 33116.54 46 44 43 33 36 33 35 35 37 27116.56 36 36 28 22 31 29 36 27 29 41116.58 41 32 38 26 32 32 29 29 37 29

270

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

116.6 33 26 29 29 32 24 43 34 30 35116.62 27 38 37 31 33 29 36 28 30 38116.64 32 39 33 42 33 31 42 38 30 31116.66 23 28 42 29 35 36 29 33 26 29116.68 23 34 26 34 31 35 18 34 37 29116.7 30 36 22 37 33 21 29 30 39 25

116.72 35 38 36 35 47 35 29 24 37 33116.74 37 31 31 26 41 23 30 28 21 36116.76 34 31 30 36 43 33 38 30 42 31116.78 37 54 36 34 29 31 26 36 32 46116.8 33 39 40 38 28 34 33 22 31 26

116.82 37 37 30 36 36 26 25 26 21 38116.84 33 46 39 31 36 34 36 30 27 45116.86 46 39 41 31 30 35 31 39 37 23116.88 42 30 31 31 41 35 36 36 31 50116.9 37 32 29 40 40 22 33 25 42 25

116.92 28 38 28 29 33 32 37 34 35 42116.94 29 37 32 23 45 29 52 34 20 41116.96 29 44 30 33 40 22 38 38 24 33116.98 27 41 25 42 44 36 29 31 34 34

117 33 27 34 37 35 38 35 23 31 39117.02 29 28 33 38 33 40 34 30 35 34117.04 31 40 42 31 31 26 36 32 39 36117.06 36 33 41 29 45 25 32 32 23 40117.08 28 33 26 44 37 47 38 29 43 25117.1 30 31 40 27 26 22 34 31 28 28

117.12 30 39 29 36 39 23 32 33 46 33117.14 44 31 16 39 43 36 37 33 41 31117.16 31 23 36 32 39 38 35 36 33 43117.18 25 32 35 34 36 37 42 28 38 42117.2 35 31 33 36 40 43 31 35 30 36

117.22 31 45 37 40 34 39 24 28 47 47117.24 36 29 31 34 34 36 31 31 44 38117.26 40 42 36 40 43 32 30 30 41 32117.28 28 40 49 47 41 39 34 39 45 32117.3 21 35 45 50 31 30 37 34 28 40

117.32 30 37 22 37 37 28 36 30 30 31117.34 30 33 40 34 44 28 36 27 29 42117.36 36 41 23 38 39 40 36 36 29 29117.38 40 49 41 40 39 23 35 27 27 30

271

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

117.4 31 39 43 37 41 41 39 24 48 31117.42 28 35 39 41 31 39 38 40 41 27117.44 29 47 37 35 44 29 28 31 33 38117.46 24 35 44 31 34 32 36 29 44 28117.48 33 36 31 39 39 38 28 32 35 32117.5 39 47 32 43 43 35 45 34 50 39

117.52 35 43 45 50 31 42 36 43 38 54117.54 50 46 32 34 41 32 35 23 37 35117.56 43 44 43 50 38 32 47 37 39 47117.58 42 36 31 40 49 29 41 27 41 35117.6 31 39 38 35 50 34 35 49 48 37

117.62 41 34 42 63 47 32 37 47 48 26117.64 30 39 32 33 38 27 40 35 37 40117.66 46 36 42 51 42 25 41 49 55 36117.68 43 41 38 44 50 40 38 41 51 42117.7 46 39 42 36 40 37 39 37 41 34

117.72 48 47 35 39 41 47 42 58 54 53117.74 52 50 44 42 39 48 31 43 57 50117.76 45 33 44 29 42 43 46 43 59 55117.78 48 43 49 47 44 57 30 33 38 42117.8 46 40 64 56 55 38 45 36 46 61

117.82 68 64 45 40 55 44 41 41 52 45117.84 70 48 47 45 46 57 46 55 51 57117.86 80 52 47 52 53 58 56 58 49 51117.88 80 48 56 52 64 54 66 63 56 74117.9 95 49 60 66 66 61 40 66 65 62

117.92 93 40 52 55 72 54 69 87 65 62117.94 97 54 44 67 70 67 65 86 61 66117.96 107 43 55 67 56 55 56 69 66 66117.98 79 48 56 59 62 52 59 83 61 62

118 68 49 53 74 83 58 70 77 84 64118.02 65 58 67 65 80 56 56 78 71 57118.04 67 64 53 65 73 65 64 70 74 64118.06 72 54 68 65 59 78 60 83 80 57118.08 51 67 60 58 59 61 54 57 62 66118.1 54 55 74 50 72 60 47 84 63 66

118.12 57 70 60 80 71 67 69 70 53 58118.14 58 72 50 70 70 65 54 87 62 67118.16 43 55 59 76 47 53 49 60 60 53118.18 64 63 60 77 60 73 56 66 62 36

272

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

118.2 50 59 56 73 63 78 66 56 66 64118.22 48 60 54 70 81 56 70 61 58 52118.24 41 68 74 62 74 47 45 59 54 52118.26 63 69 44 67 56 68 51 65 56 64118.28 52 64 53 74 55 53 52 55 61 58118.3 47 52 70 45 68 56 56 69 63 53

118.32 36 59 56 53 60 51 50 65 56 64118.34 60 61 53 61 58 50 57 70 65 53118.36 57 60 59 57 63 53 72 72 46 47118.38 56 71 52 61 65 69 44 56 63 59118.4 53 61 63 45 59 57 47 61 58 49

118.42 71 59 66 62 69 61 49 59 54 65118.44 61 64 50 75 62 52 47 80 55 52118.46 61 61 46 59 65 58 52 72 67 58118.48 63 75 43 49 54 74 59 56 42 56118.5 61 63 58 62 56 52 62 62 61 57

118.52 50 56 61 67 62 68 47 60 53 49118.54 50 51 60 71 62 55 61 57 57 60118.56 55 58 58 47 63 51 63 58 42 39118.58 50 52 59 53 73 62 46 66 46 59118.6 44 58 62 81 58 50 53 54 57 54

118.62 49 44 63 54 69 44 54 53 56 73118.64 60 61 57 71 63 52 49 58 56 69118.66 72 69 60 56 68 54 56 63 58 71118.68 77 61 68 70 68 64 60 73 65 65118.7 80 62 53 70 71 51 56 72 59 67

118.72 99 59 58 66 75 64 56 74 47 71118.74 124 65 76 76 67 70 59 82 76 76118.76 122 59 51 67 65 67 71 81 80 87118.78 108 66 72 72 73 61 62 81 85 86118.8 94 53 69 69 90 75 73 89 77 85

118.82 92 61 61 70 90 72 61 91 85 87118.84 93 61 59 91 65 57 65 110 90 91118.86 61 74 71 90 78 79 72 84 96 90118.88 79 57 48 74 94 53 69 88 84 80118.9 59 81 55 80 88 66 81 91 74 75

118.92 59 53 67 76 65 82 71 86 83 64118.94 70 60 60 84 74 77 65 108 82 63118.96 56 60 78 85 76 70 56 75 82 72118.98 64 65 67 74 66 73 70 111 91 71

273

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

119 51 74 70 82 75 63 69 86 90 73119.02 70 63 67 58 60 61 66 65 94 77119.04 50 76 70 68 59 60 64 92 89 53119.06 75 63 71 63 61 54 64 74 73 74119.08 68 64 69 67 79 60 62 64 93 64119.1 78 74 58 60 82 49 85 75 73 74

119.12 91 78 62 58 64 54 68 84 71 65119.14 84 60 59 75 80 81 61 66 72 77119.16 100 72 82 76 85 55 59 84 73 87119.18 111 63 56 75 87 74 69 101 76 70119.2 139 88 77 62 75 67 65 93 79 71

119.22 146 63 74 66 84 71 75 116 92 85119.24 161 60 72 91 83 83 89 122 92 88119.26 133 70 70 82 87 68 56 99 96 96119.28 133 73 89 83 78 88 67 155 82 90119.3 95 73 72 84 85 74 83 132 84 93

119.32 95 74 64 69 98 95 85 133 102 103119.34 82 79 79 72 112 70 84 131 84 101119.36 68 80 74 78 72 90 61 120 82 95119.38 70 88 67 71 81 95 59 131 88 94119.4 76 67 79 90 92 100 76 121 83 85

119.42 63 100 65 71 89 75 73 105 86 86119.44 59 81 77 78 73 75 87 128 88 84119.46 64 60 76 70 57 95 70 105 74 67119.48 62 73 78 67 72 70 71 85 73 84119.5 48 71 81 63 65 74 71 96 65 68

119.52 47 80 79 71 74 72 73 90 75 70119.54 47 72 84 68 57 70 70 83 62 72119.56 52 71 78 57 68 59 76 82 58 66119.58 53 74 68 62 51 68 49 69 64 54119.6 57 56 73 72 68 74 62 84 51 62

119.62 65 57 82 67 42 62 52 78 55 68119.64 51 66 53 70 61 56 56 84 47 52119.66 63 61 76 51 65 67 53 56 56 76119.68 77 76 55 60 44 53 49 59 56 63119.7 72 66 67 60 59 52 74 67 46 71

119.72 77 73 63 49 60 52 57 67 41 64119.74 76 61 65 59 57 77 56 86 66 60119.76 65 66 51 61 46 57 54 69 52 65119.78 74 51 64 55 63 65 48 82 51 62

274

Degrees 2 Theta

CAL- STD

Kwf NN

Kwf ZZ

Kwf AA

Kwf CC

Kwf CR

SH 234

SM 421

CB 725

BM 579

119.8 56 51 67 71 57 66 55 83 51 68119.82 46 52 51 55 56 70 53 70 67 60119.84 57 71 58 59 54 61 52 80 57 61119.86 46 55 59 64 67 67 54 69 47 47119.88 43 59 45 48 65 60 55 73 42 56119.9 45 50 52 66 49 50 51 65 76 50

119.92 35 47 42 53 48 50 53 60 42 58119.94 43 53 65 55 60 55 44 57 52 52119.96 47 64 65 55 61 63 62 51 56 47119.98 52 59 52 46 59 45 54 60 43 51

120 37 51 51 53 57 44 47 53 40 39

275

APPENDIX B X-ray analysis data for Sierra Madera and Mission Canyon Fm dolomite samples.

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

15 203 161 158 166 178 136 191 157 143 158 137 137 133 229 11915.02 182 147 143 161 168 159 188 174 121 156 130 137 155 199 16215.04 193 153 152 152 166 135 191 133 147 164 134 137 140 209 11115.06 183 151 139 184 160 142 203 156 128 168 121 128 174 200 14215.08 184 171 132 149 164 158 201 157 160 151 137 150 149 238 150

15.1 167 138 163 153 176 175 208 173 137 145 144 148 141 210 14515.12 179 189 158 185 173 135 204 162 138 140 138 120 182 238 14215.14 166 140 158 164 181 149 195 213 154 173 121 136 180 235 13315.16 214 152 150 169 202 172 198 179 144 170 151 123 124 230 12415.18 198 134 158 160 183 190 221 156 160 183 126 144 190 227 150

15.2 195 165 139 167 179 164 197 157 155 177 145 153 202 216 13615.22 211 154 167 177 160 159 239 165 156 163 153 128 179 240 14615.24 200 139 152 183 183 165 241 173 144 142 135 135 178 230 14115.26 211 170 169 196 154 175 205 155 161 186 126 150 189 231 16215.28 210 149 158 177 170 146 209 174 157 190 161 143 175 236 148

15.3 217 148 149 182 185 173 225 160 161 173 151 134 170 229 17015.32 200 154 155 192 171 160 223 170 165 171 129 128 160 257 14115.34 188 156 159 184 158 144 235 167 155 154 155 149 184 252 14815.36 210 164 165 201 176 152 204 159 164 162 133 158 155 240 12515.38 202 146 143 201 174 147 196 178 164 177 152 128 187 257 155

15.4 212 169 132 192 179 187 224 166 151 189 137 126 184 241 13615.42 185 169 162 182 205 158 200 168 171 164 128 171 193 247 14115.44 197 147 170 161 176 170 196 170 167 167 141 135 161 252 13915.46 195 149 158 187 185 195 216 166 152 188 133 122 177 219 13915.48 208 161 152 169 203 195 232 146 155 182 150 159 180 241 145

15.5 205 172 147 175 192 169 170 157 141 193 168 154 192 230 14115.52 221 188 169 203 216 178 202 171 172 168 142 133 211 252 15115.54 212 149 158 190 187 166 219 172 172 179 137 128 192 243 16615.56 205 143 148 198 169 168 204 153 148 201 129 130 194 247 13715.58 184 176 147 185 187 174 211 203 163 181 144 174 176 264 152

15.6 206 145 170 161 155 157 221 157 160 175 127 144 188 258 12415.62 217 162 133 184 172 168 191 163 192 187 138 129 192 234 14415.64 213 170 160 172 173 182 205 143 160 176 137 147 180 245 15515.66 194 147 154 184 187 166 227 182 147 180 119 147 179 237 15615.68 243 140 150 166 189 168 196 162 148 173 151 129 189 225 152

15.7 215 174 156 159 185 163 194 158 164 200 131 147 201 259 14315.72 197 158 156 205 157 179 235 162 169 176 152 139 166 276 15415.74 229 172 177 179 198 178 230 180 175 178 146 144 201 243 12815.76 218 175 190 224 197 151 213 148 123 192 156 134 173 267 14515.78 198 175 168 164 201 192 209 159 144 165 158 138 176 257 144

15.8 210 168 175 181 199 182 210 184 157 185 115 154 193 254 12615.82 200 172 166 196 168 154 220 163 184 171 132 147 167 257 153

277

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

15.84 191 146 169 188 187 191 206 159 152 180 131 160 184 262 14215.86 219 156 141 188 193 148 207 137 154 160 133 142 183 251 12115.88 224 161 174 216 209 186 214 170 157 177 138 118 177 301 127

15.9 194 169 152 165 197 159 234 193 171 183 141 130 185 246 14515.92 225 184 178 200 172 173 193 165 159 185 110 157 203 260 13115.94 236 188 184 193 183 186 224 177 161 204 132 153 185 261 14015.96 217 171 168 204 185 166 200 183 145 186 149 131 193 242 13115.98 204 164 155 194 177 166 209 163 171 168 149 157 201 281 140

16 219 179 158 216 175 171 206 155 182 187 129 160 172 280 15316.02 255 151 150 176 171 167 234 159 181 193 127 141 170 272 14316.04 203 161 161 213 194 201 204 183 162 183 146 131 183 249 14616.06 221 153 149 179 191 167 208 154 182 184 174 154 197 276 14816.08 226 161 158 190 199 166 205 179 144 181 122 140 193 283 136

16.1 198 176 137 173 161 179 219 157 161 182 148 148 188 262 14516.12 204 159 160 185 204 178 221 133 186 184 177 144 179 257 13416.14 214 173 157 184 172 163 206 164 146 188 144 129 154 260 14516.16 213 163 168 188 167 179 217 159 173 192 139 130 181 266 13316.18 221 168 158 223 177 184 228 163 165 198 114 145 202 271 141

16.2 217 168 183 216 191 164 227 160 162 162 135 141 184 261 13916.22 220 152 188 203 176 165 204 161 159 175 141 149 214 277 13616.24 232 192 145 208 201 152 240 148 144 202 124 149 184 285 13616.26 231 168 172 180 182 171 187 166 144 181 165 149 222 287 14316.28 230 185 160 207 197 193 192 150 162 186 129 132 197 258 158

16.3 229 171 173 214 185 188 254 160 180 182 151 138 172 305 15616.32 193 164 184 182 210 157 206 158 186 191 147 137 212 258 14716.34 204 187 163 206 202 206 222 157 142 192 133 165 184 270 13516.36 225 168 157 191 210 186 227 168 185 176 132 147 217 254 13616.38 226 178 153 220 198 178 245 141 168 201 145 131 192 289 156

16.4 215 191 185 182 181 207 246 166 161 183 121 156 216 269 13616.42 221 177 184 178 187 170 230 185 167 184 152 163 206 289 17316.44 233 195 168 202 220 202 251 172 190 174 139 142 232 291 15516.46 222 191 166 205 205 167 241 213 179 174 151 153 204 289 14816.48 252 172 146 214 187 214 209 190 131 217 142 146 190 299 150

16.5 225 182 174 226 235 193 233 205 194 214 159 134 216 293 17916.52 262 194 181 193 216 216 239 190 152 195 148 163 192 301 15616.54 211 177 180 227 210 181 229 169 191 223 137 155 211 293 16216.56 239 190 186 206 213 181 255 163 197 212 160 172 214 315 16216.58 259 181 173 215 222 198 250 169 169 199 166 141 222 314 166

16.6 249 186 156 226 217 193 246 172 179 185 157 141 224 293 16116.62 253 183 169 225 198 187 262 170 179 209 120 172 211 314 15716.64 232 171 162 236 203 182 245 164 183 191 132 141 236 296 14516.66 235 195 167 216 214 200 244 154 196 177 126 149 205 317 160

278

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

16.68 234 151 184 238 218 172 238 166 181 179 128 143 208 291 11816.7 243 178 185 200 195 185 222 147 207 195 147 133 191 320 133

16.72 249 180 183 232 207 178 256 161 153 192 138 151 187 294 14316.74 218 197 156 212 193 195 220 166 178 205 152 126 199 269 12216.76 226 217 175 211 212 184 228 161 176 177 132 144 196 302 13016.78 258 167 174 221 180 174 250 157 167 178 106 153 195 287 139

16.8 202 182 188 214 200 164 251 131 163 174 149 140 200 272 13016.82 218 180 166 198 180 171 219 150 188 186 143 128 188 286 13516.84 205 169 179 195 183 176 193 160 171 206 130 138 193 279 15816.86 218 185 164 226 228 162 217 152 169 179 123 148 193 289 13416.88 233 178 178 203 187 191 247 181 179 189 147 141 212 299 134

16.9 226 179 156 174 167 194 238 148 146 199 123 138 194 299 12516.92 215 181 173 204 210 179 224 148 152 164 123 130 219 285 14116.94 203 157 173 191 195 187 226 165 168 173 118 151 172 270 12916.96 229 191 173 206 216 172 234 164 155 191 112 142 174 316 12716.98 193 187 179 199 195 187 251 147 168 179 139 158 223 268 139

17 213 188 170 173 180 183 246 174 175 170 134 121 192 289 12617.02 233 189 177 200 194 172 235 148 156 180 122 136 204 268 11517.04 216 167 171 213 194 192 235 161 150 188 103 121 216 286 12017.06 230 175 179 201 203 164 255 160 154 192 146 122 184 270 12617.08 219 193 184 200 190 197 230 160 157 169 153 147 220 313 141

17.1 224 172 163 223 208 178 253 131 171 166 124 120 204 280 13417.12 211 181 193 194 189 151 207 164 159 183 134 161 202 284 14017.14 221 183 174 210 216 155 209 159 176 189 118 134 198 311 11817.16 245 179 154 225 242 180 246 167 164 184 126 148 196 301 13617.18 218 170 160 208 209 177 245 168 151 203 133 163 215 299 144

17.2 224 203 216 223 199 175 222 177 144 184 130 146 215 289 12417.22 195 202 180 218 195 161 248 170 168 202 113 124 203 299 11617.24 243 170 202 222 209 187 220 158 162 214 129 167 234 297 10317.26 230 165 185 218 190 186 234 153 179 187 99 170 191 329 14017.28 265 165 171 191 180 188 241 157 178 181 118 137 200 304 124

17.3 258 176 181 203 214 197 251 169 153 176 138 130 204 322 13417.32 235 190 182 221 200 217 249 168 181 176 116 157 212 311 12217.34 232 163 180 220 206 183 243 167 188 172 126 160 187 301 16117.36 242 177 174 193 195 212 250 166 156 186 139 128 213 295 14017.38 213 176 176 219 205 165 231 171 167 221 120 141 192 297 134

17.4 215 164 193 192 184 176 235 146 157 187 140 141 195 310 12417.42 225 211 170 232 203 193 240 159 167 184 140 133 205 323 14217.44 265 189 166 216 204 168 239 152 158 184 127 145 174 287 13017.46 251 193 183 223 202 181 212 156 166 180 117 155 211 327 12717.48 240 188 165 207 215 181 248 162 161 197 140 148 218 318 117

17.5 222 185 180 213 208 159 235 154 161 179 117 140 209 346 148

279

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

17.52 231 190 194 202 219 183 260 140 150 183 116 130 206 297 13017.54 259 203 191 214 220 171 225 164 174 177 136 149 193 322 13617.56 227 180 213 212 213 204 261 173 151 188 108 149 181 310 12417.58 209 198 188 209 212 177 232 151 175 195 122 134 206 288 110

17.6 230 199 194 228 193 184 248 172 177 185 145 136 229 310 10517.62 244 198 199 198 181 198 228 184 170 194 124 153 195 316 12317.64 259 210 185 218 211 167 243 154 171 219 129 136 196 272 13517.66 261 195 221 228 206 194 244 145 197 203 122 132 220 301 11117.68 255 202 196 203 237 170 249 164 182 164 113 132 192 287 126

17.7 197 233 202 215 185 191 242 158 198 201 122 154 195 321 14517.72 241 222 222 249 223 192 209 177 166 222 121 148 186 277 14417.74 232 187 220 231 216 197 238 158 140 197 102 145 202 308 13217.76 222 194 237 206 211 192 249 160 141 191 126 119 211 334 14317.78 271 222 203 202 223 216 235 165 163 209 128 132 202 281 130

17.8 247 203 202 209 215 184 257 157 187 195 120 140 239 332 13317.82 230 207 194 221 216 173 243 152 182 188 136 174 197 317 11017.84 231 199 194 223 206 186 249 184 180 188 145 147 211 316 14217.86 241 206 217 208 199 185 239 167 177 181 132 120 191 295 12717.88 230 189 202 221 205 220 251 142 159 170 141 146 196 337 121

17.9 227 202 194 218 221 185 221 188 164 191 126 145 181 336 12617.92 242 179 220 196 219 173 221 140 173 186 134 143 206 294 13817.94 244 175 204 196 235 152 242 171 174 220 130 130 202 287 14017.96 248 199 208 197 210 193 236 140 156 197 138 140 180 310 13417.98 227 162 169 222 202 172 248 177 195 178 122 160 205 324 130

18 259 187 207 225 193 192 248 147 177 184 124 132 200 315 13718.02 220 174 201 217 194 191 255 151 158 206 143 140 181 291 12018.04 222 213 205 203 205 215 216 135 177 194 115 141 179 319 12818.06 241 185 169 233 184 187 268 173 152 179 146 148 200 318 13418.08 262 175 173 214 208 189 205 170 182 172 138 129 219 308 141

18.1 234 182 201 207 213 208 234 148 142 165 140 158 199 317 12418.12 217 188 158 208 214 195 252 152 181 206 144 147 210 290 13618.14 216 191 186 206 218 158 243 187 176 204 125 120 207 278 12418.16 262 182 207 204 215 207 224 178 146 205 107 135 176 277 13618.18 242 161 189 208 208 201 257 146 167 177 113 137 210 302 127

18.2 270 195 186 193 192 167 244 160 167 177 142 131 186 318 14318.22 246 182 197 231 201 166 243 145 154 177 130 146 191 300 12318.24 228 175 195 210 194 197 252 130 176 176 123 136 207 306 14018.26 232 189 197 196 204 185 254 160 169 182 140 122 195 329 12718.28 213 197 193 229 214 173 234 154 183 218 139 160 202 303 112

18.3 217 195 185 234 180 184 234 168 148 191 150 151 202 303 13618.32 232 174 209 196 209 215 231 177 168 170 133 138 185 324 13218.34 220 200 214 206 203 186 264 139 149 184 149 130 166 281 130

280

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

18.36 219 193 181 212 193 179 234 158 186 178 155 138 203 299 13618.38 253 196 195 208 206 195 246 145 158 176 151 144 194 299 148

18.4 241 164 202 189 190 186 252 179 148 183 140 116 212 332 12518.42 249 177 163 258 219 185 249 141 169 173 121 133 205 299 14218.44 258 151 181 200 210 185 219 158 148 202 130 130 199 308 13418.46 262 178 159 239 203 171 234 162 148 173 136 153 193 301 13418.48 229 209 203 206 183 158 241 172 171 212 102 130 214 305 135

18.5 237 184 215 201 199 191 257 147 180 179 118 131 203 290 13018.52 245 186 191 245 215 164 229 159 176 191 109 137 216 307 14218.54 221 197 169 195 191 171 224 157 166 195 130 145 201 312 15718.56 247 173 185 238 193 163 229 140 163 177 116 124 210 325 11618.58 227 164 200 211 211 177 223 161 168 196 118 121 213 315 117

18.6 209 166 194 200 197 198 251 142 174 193 126 143 215 270 13818.62 221 172 212 227 212 167 223 154 143 172 147 164 205 307 12018.64 229 176 207 214 201 196 232 150 187 189 109 137 206 317 13218.66 246 183 191 215 190 179 251 171 168 193 144 166 224 292 13718.68 234 205 188 245 203 157 242 169 160 190 130 134 185 315 146

18.7 214 172 199 212 198 205 227 133 170 176 121 136 220 281 11418.72 253 215 213 189 205 190 257 143 173 201 128 119 185 326 14418.74 215 167 203 189 195 178 233 156 152 196 121 127 220 290 13818.76 222 188 199 198 186 165 223 150 184 185 120 143 179 314 12918.78 235 191 194 212 199 169 230 151 193 156 152 137 176 319 120

18.8 226 212 205 218 217 174 269 167 152 184 123 157 207 281 14218.82 234 167 205 231 164 182 211 149 166 157 104 115 198 295 14018.84 221 201 208 208 206 154 226 156 177 167 118 112 174 307 16318.86 260 173 202 209 203 155 230 157 147 177 118 150 227 338 15218.88 210 190 216 225 165 172 206 139 178 172 104 142 176 331 144

18.9 195 192 193 198 185 165 234 148 162 184 131 115 205 362 15518.92 233 180 223 220 168 180 215 136 169 167 114 146 190 325 15118.94 210 217 212 224 190 181 236 142 143 154 131 137 193 308 17618.96 235 188 193 187 190 188 223 155 174 173 130 160 186 327 17618.98 220 181 195 207 191 162 250 143 170 178 118 123 216 298 222

19 238 171 227 189 183 180 243 141 144 177 118 137 193 292 23819.02 227 181 217 213 198 180 246 170 152 199 122 136 202 338 24419.04 208 185 202 209 181 173 203 152 139 158 130 133 178 314 21019.06 225 191 228 210 197 158 220 152 140 159 108 135 203 304 20519.08 232 199 262 212 192 174 240 153 148 183 84 117 200 292 163

19.1 210 190 254 213 172 177 236 144 141 179 101 145 208 296 15819.12 238 178 210 213 193 173 235 146 177 155 107 134 189 262 14919.14 231 185 273 198 201 175 219 167 154 186 109 121 184 282 13019.16 234 174 264 223 191 195 211 138 147 161 101 127 212 316 13919.18 223 185 286 209 217 165 220 186 130 166 109 121 180 285 138

281

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

19.2 223 201 266 210 172 182 212 156 163 161 113 131 179 293 12519.22 239 219 286 209 192 156 231 148 180 162 110 142 167 310 12519.24 219 213 382 161 175 197 224 147 153 169 99 123 173 299 10119.26 205 188 363 206 200 172 213 136 174 175 112 152 169 295 12119.28 228 212 363 217 191 166 202 147 180 164 99 135 187 290 118

19.3 216 215 379 190 167 178 229 142 167 178 113 137 179 291 12119.32 238 202 363 212 198 178 219 140 181 156 123 151 202 327 12619.34 196 194 423 193 206 168 229 171 153 173 132 137 174 281 14419.36 235 192 415 193 193 185 221 149 155 147 108 124 190 297 13219.38 226 192 369 218 165 163 219 156 194 175 133 117 180 304 115

19.4 223 215 380 202 221 167 198 146 157 172 116 131 198 280 12319.42 199 201 381 225 190 178 213 170 165 174 112 122 193 264 9219.44 196 185 357 232 202 173 192 145 168 181 102 132 215 287 11019.46 238 211 422 200 197 166 215 155 170 168 101 130 197 253 11419.48 206 188 402 211 189 159 219 144 164 153 114 126 166 266 109

19.5 221 184 417 188 175 167 237 134 155 169 106 119 204 276 11319.52 209 217 419 197 201 168 210 146 172 176 138 140 185 291 12519.54 216 216 395 207 190 166 245 135 188 167 96 122 180 265 11519.56 203 224 425 194 202 165 224 162 160 152 123 110 180 277 12019.58 208 231 406 190 164 158 243 169 159 143 118 110 191 284 120

19.6 184 188 419 190 176 204 221 149 163 159 122 154 193 242 13419.62 196 233 435 193 204 178 207 181 161 176 122 133 171 261 10419.64 216 223 456 189 187 167 247 143 179 170 122 120 146 283 11319.66 212 260 451 189 188 164 232 137 179 184 128 124 165 298 12919.68 216 245 464 185 217 182 257 154 174 157 112 121 195 290 125

19.7 231 248 485 194 191 162 249 165 172 160 105 140 187 259 10419.72 216 216 466 197 197 181 241 157 171 159 93 129 186 256 11719.74 220 237 461 197 216 170 266 177 177 168 101 122 190 276 10119.76 191 218 478 233 219 165 253 158 142 150 129 119 164 286 12819.78 215 237 481 185 210 167 294 177 178 163 114 137 176 275 125

19.8 188 236 451 229 188 178 267 154 174 143 136 142 183 260 12119.82 220 230 465 189 201 165 228 150 170 167 117 136 184 281 12019.84 222 221 469 185 225 175 239 153 191 180 107 125 142 270 11919.86 220 233 459 174 197 184 257 156 176 174 95 105 185 267 11919.88 212 231 402 182 237 186 264 136 167 170 100 123 184 260 141

19.9 187 231 408 195 203 182 245 132 169 156 123 127 187 242 10819.92 204 226 371 184 204 193 220 145 175 172 110 119 171 276 12219.94 230 205 376 180 210 179 217 165 173 157 114 121 169 257 11819.96 191 198 368 206 197 175 202 125 164 168 109 108 178 253 12019.98 248 192 368 190 228 166 233 138 166 153 124 128 173 257 117

20 186 197 324 191 185 178 229 129 148 154 88 136 185 244 10720.02 210 192 321 194 213 181 202 128 163 156 101 135 169 253 105

282

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

20.04 188 170 327 194 208 179 194 136 171 172 101 113 190 250 11520.06 206 162 315 199 200 168 232 147 168 187 112 108 154 252 13920.08 181 179 293 198 162 188 219 137 161 154 111 130 189 264 130

20.1 177 175 313 183 168 136 216 125 157 145 131 116 150 239 10820.12 162 184 274 201 183 150 231 146 176 153 94 126 167 243 11620.14 208 195 307 201 180 165 208 134 158 150 96 106 167 254 10220.16 190 176 269 179 197 162 216 144 140 153 115 143 157 263 11120.18 226 191 271 214 188 146 226 139 147 163 115 117 163 260 113

20.2 202 173 297 159 191 158 214 131 162 159 112 108 163 240 10420.22 193 166 293 169 193 176 208 149 174 168 114 107 161 239 11720.24 187 179 259 203 191 158 222 145 164 154 106 119 152 242 10320.26 179 161 293 191 187 166 187 137 136 152 106 109 168 279 12120.28 187 173 239 188 181 154 193 141 153 146 93 132 165 226 118

20.3 207 183 269 176 204 171 210 126 161 153 125 125 202 252 10320.32 205 144 248 170 213 160 200 138 159 187 103 128 168 244 11720.34 182 174 261 189 201 135 186 155 145 149 106 103 171 239 8220.36 191 154 263 188 194 173 188 126 168 164 115 112 168 287 12320.38 180 167 239 185 186 139 223 136 146 156 103 133 185 214 103

20.4 204 164 260 183 180 166 200 134 151 155 117 123 196 243 10820.42 182 163 257 179 199 177 226 135 145 156 82 103 175 233 8720.44 181 146 272 203 169 162 229 136 172 153 128 111 163 249 12420.46 184 155 266 164 196 179 220 158 146 150 107 118 154 252 12120.48 189 145 250 198 204 138 209 133 157 161 100 116 165 225 129

20.5 189 155 270 169 174 152 224 142 176 167 128 114 170 249 11020.52 180 156 262 172 185 153 222 126 137 138 104 104 145 253 10920.54 168 180 241 170 201 175 208 141 152 126 127 117 197 258 9820.56 177 176 285 174 195 144 240 131 146 133 99 110 179 229 11720.58 183 158 242 169 187 151 209 129 190 146 117 98 154 245 100

20.6 186 174 273 166 216 168 235 128 154 183 105 112 155 253 12220.62 186 171 252 165 201 163 215 162 164 144 104 130 150 275 12320.64 182 181 283 156 229 142 210 143 142 164 122 123 146 250 12120.66 181 202 273 201 213 171 227 130 151 161 100 105 144 246 15720.68 193 205 301 180 181 175 244 143 157 156 129 108 141 256 146

20.7 179 211 306 190 218 202 246 152 172 176 125 119 162 284 13820.72 199 227 349 180 215 194 276 154 186 192 118 119 164 266 15620.74 188 232 403 236 253 203 252 152 159 159 131 102 157 298 18520.76 192 284 392 206 267 205 294 145 151 186 151 104 144 286 16820.78 182 327 441 204 283 215 328 166 150 173 166 136 164 250 173

20.8 190 352 522 216 312 216 343 127 159 192 134 119 160 243 21020.82 168 343 580 255 387 250 398 138 168 220 143 118 153 221 23420.84 202 369 660 233 390 299 374 146 179 207 163 98 161 274 28520.86 200 387 563 232 374 283 442 116 204 178 138 120 173 279 291

283

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

20.88 192 337 482 235 394 276 385 121 198 171 111 132 139 263 27020.9 164 261 404 207 341 250 398 138 187 145 135 100 153 271 232

20.92 202 250 384 206 318 231 349 128 188 169 127 102 142 274 19220.94 184 242 328 197 260 223 284 156 161 152 112 117 164 281 17620.96 182 217 317 192 232 181 242 121 137 132 93 111 150 248 13620.98 158 186 285 194 220 167 211 146 165 159 104 111 143 244 122

21 188 179 279 165 209 125 195 123 134 140 95 115 143 245 12521.02 164 178 276 190 191 167 205 133 171 158 94 109 133 255 12921.04 173 171 228 183 199 157 176 141 144 142 108 111 177 246 10821.06 173 165 234 157 208 153 198 125 155 166 117 100 179 192 11321.08 174 165 245 151 226 148 207 150 154 164 97 115 130 242 108

21.1 167 143 185 167 232 153 183 146 137 143 98 110 152 213 9721.12 158 135 187 177 211 143 188 127 146 135 90 118 130 231 10621.14 148 132 221 157 203 167 192 128 151 146 105 91 149 209 10721.16 140 139 174 161 202 154 191 118 129 157 113 95 149 257 10621.18 153 135 220 153 215 179 183 132 139 167 89 110 140 233 122

21.2 150 110 192 158 216 135 171 133 135 135 87 112 125 209 11421.22 172 135 212 161 213 144 209 120 150 138 103 114 146 212 10221.24 174 125 193 168 218 167 198 133 141 129 92 105 142 217 8721.26 154 126 185 171 209 143 182 128 136 142 103 86 147 218 11321.28 176 140 203 163 218 138 191 131 151 154 106 92 153 192 102

21.3 164 155 202 160 200 147 206 119 137 127 99 110 163 222 10721.32 162 132 207 189 195 118 186 148 144 150 110 123 139 196 11521.34 196 144 215 182 211 143 189 114 144 140 102 96 142 225 10421.36 185 118 190 180 181 153 161 126 147 166 94 92 144 243 8921.38 144 144 179 195 212 150 184 122 170 142 102 90 151 217 101

21.4 182 138 186 167 194 158 159 127 142 143 103 87 162 226 12121.42 191 133 214 182 173 177 212 130 148 120 94 117 142 261 11521.44 182 147 189 183 230 148 208 120 136 119 106 110 152 226 10721.46 163 131 201 175 179 128 206 101 126 140 86 106 137 208 9821.48 161 129 185 153 161 137 199 134 145 154 113 123 148 204 94

21.5 148 139 182 147 160 141 191 128 109 128 117 103 128 191 10021.52 139 116 192 168 164 128 164 133 165 107 96 86 143 197 9221.54 155 152 197 158 140 126 178 128 115 124 75 89 118 204 8921.56 175 134 205 160 170 127 203 144 137 157 104 98 119 206 9121.58 161 126 162 153 176 149 172 130 129 128 111 111 147 189 104

21.6 172 133 201 149 188 119 193 132 132 138 110 133 134 203 12121.62 151 134 178 158 136 136 180 130 154 120 110 107 144 204 10221.64 164 147 187 155 161 146 188 132 130 132 112 85 147 211 10321.66 167 107 193 161 151 127 156 147 125 128 103 88 148 171 11421.68 141 107 213 162 153 149 139 173 119 156 121 98 148 191 119

21.7 165 145 186 140 166 160 179 159 154 154 117 102 148 201 117

284

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

21.72 178 152 197 147 167 154 198 161 157 142 116 126 132 208 11421.74 166 151 201 161 180 134 220 188 155 169 106 140 149 225 11621.76 172 135 224 194 167 161 173 193 165 164 145 122 157 193 14121.78 198 154 206 200 160 169 178 211 145 171 132 101 163 255 141

21.8 205 161 212 169 147 142 188 228 148 174 136 117 171 244 14821.82 168 164 209 184 192 143 190 256 155 190 150 149 146 215 16721.84 188 173 207 200 207 183 215 291 178 183 175 161 173 248 15821.86 203 181 255 192 226 199 205 347 175 200 185 151 179 266 18921.88 215 213 262 248 217 172 240 332 201 225 200 166 245 298 196

21.9 260 244 257 222 237 233 278 359 204 243 225 203 223 286 21921.92 299 264 309 228 272 247 313 379 256 286 279 202 277 333 27121.94 308 333 343 299 309 279 308 378 239 397 336 260 275 348 28821.96 345 346 392 336 366 290 348 372 273 383 374 317 331 380 38721.98 382 432 516 348 412 343 377 333 359 428 422 352 384 447 522

22 472 456 651 394 392 390 398 297 373 528 456 382 481 508 53522.02 548 392 684 474 433 401 419 255 401 568 468 386 542 542 50922.04 619 385 597 501 483 479 437 203 441 504 440 357 589 546 44422.06 676 312 561 558 438 481 415 178 467 407 352 241 589 584 36522.08 563 223 480 575 474 425 351 159 411 305 255 182 543 562 250

22.1 472 204 362 515 405 376 308 129 366 270 181 146 477 421 19122.12 389 164 294 421 297 302 266 132 333 185 150 110 374 373 14322.14 282 152 264 306 260 272 237 109 274 184 140 112 314 297 11822.16 221 130 217 262 192 193 212 113 226 155 124 89 177 244 11322.18 199 128 193 212 180 145 178 125 175 146 111 104 179 205 99

22.2 175 119 189 196 162 163 177 114 170 135 110 100 154 202 12322.22 160 139 188 169 153 137 176 125 147 128 117 110 165 197 11922.24 153 138 172 160 143 168 143 105 161 120 89 99 149 194 11522.26 149 108 184 138 133 162 163 119 149 127 107 98 133 189 10722.28 130 128 204 172 130 116 141 113 150 125 110 91 147 178 114

22.3 151 109 192 183 131 132 149 100 144 110 108 87 128 188 11822.32 157 128 178 145 122 115 133 102 112 127 99 95 133 186 11322.34 162 114 173 130 129 104 135 108 127 129 94 102 111 174 9022.36 150 120 181 133 135 112 157 111 119 121 96 90 121 159 9622.38 123 123 176 135 150 111 156 92 125 105 105 76 128 174 101

22.4 129 124 169 115 135 122 142 127 110 127 104 91 127 175 10422.42 153 121 181 134 128 105 144 96 101 125 74 81 110 161 8922.44 118 128 197 140 152 110 153 108 105 109 100 99 121 157 7722.46 114 139 190 130 120 122 147 108 118 112 103 81 123 177 10322.48 127 123 202 113 141 119 139 132 119 112 90 84 120 177 81

22.5 141 109 201 126 124 126 130 103 120 106 81 95 107 176 9822.52 130 135 176 128 116 132 155 124 117 119 108 90 110 152 9422.54 130 109 180 129 124 126 156 109 102 110 84 78 117 171 85

285

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

22.56 126 121 170 102 128 101 139 127 90 109 77 89 126 164 8522.58 151 105 178 142 131 122 147 109 111 116 102 90 118 176 84

22.6 130 103 166 123 131 114 148 92 100 104 103 92 125 151 7822.62 132 112 182 106 130 124 142 116 96 102 100 106 113 159 9722.64 119 101 176 138 127 103 132 125 109 100 80 68 108 170 9622.66 133 107 139 107 133 110 153 102 120 96 92 76 107 153 7922.68 140 101 187 118 135 117 146 120 111 97 98 81 110 156 115

22.7 116 103 172 135 129 126 116 108 129 92 78 104 130 162 9322.72 137 92 169 117 119 110 133 102 126 89 90 96 120 150 10722.74 125 136 183 133 115 119 119 109 110 102 89 89 104 167 9222.76 122 117 185 115 112 126 141 133 115 108 89 91 106 176 8422.78 137 120 189 116 159 123 143 137 118 102 89 115 141 171 91

22.8 111 111 198 131 127 103 119 125 114 96 88 80 117 169 8822.82 127 109 199 112 118 110 142 144 114 120 128 99 98 187 10322.84 138 118 198 113 114 103 140 146 136 125 102 84 121 169 10022.86 123 114 212 115 116 120 153 143 109 119 88 87 107 172 10722.88 145 105 209 111 141 113 150 159 127 131 121 98 128 183 119

22.9 159 115 224 112 125 127 140 194 127 127 111 93 122 197 11322.92 117 123 192 115 161 121 161 179 108 126 112 91 123 197 12222.94 156 122 211 109 128 113 147 182 133 108 91 89 129 184 12322.96 126 139 212 141 120 129 164 203 117 126 121 94 120 169 11622.98 146 129 193 117 137 123 142 185 119 115 120 114 128 181 118

23 133 100 197 116 128 118 183 163 147 121 160 121 121 155 13523.02 149 122 188 132 165 132 145 172 164 150 146 128 112 195 11623.04 141 109 220 114 157 139 171 164 143 179 150 107 115 184 13723.06 116 115 201 136 172 150 147 165 156 158 161 116 121 168 14923.08 128 91 191 137 162 158 182 155 174 171 170 105 112 170 158

23.1 128 122 185 131 156 174 186 129 156 148 124 106 98 155 15623.12 125 96 188 134 153 165 178 149 213 157 140 129 97 159 13823.14 138 108 161 137 158 170 184 120 215 138 97 109 107 177 14123.16 118 110 143 157 165 207 195 103 208 125 106 95 113 146 13423.18 124 95 188 119 132 180 160 139 212 118 103 79 129 141 102

23.2 144 97 183 158 135 190 173 110 223 114 90 85 87 171 10223.22 129 134 191 136 123 171 157 140 214 93 85 92 97 151 10623.24 115 126 156 131 125 208 145 112 190 120 84 91 103 139 9423.26 111 129 172 107 130 173 135 123 179 83 79 103 109 147 11623.28 127 142 177 115 123 175 130 117 182 110 95 92 105 155 106

23.3 132 116 199 117 131 143 146 113 155 80 85 80 102 140 9123.32 126 120 180 103 118 137 142 124 147 101 90 79 103 144 10123.34 87 163 179 123 115 126 116 124 140 100 83 82 116 154 11623.36 109 168 213 114 108 136 142 105 143 94 74 84 118 163 9323.38 126 145 205 128 112 113 124 120 125 128 105 70 87 147 88

286

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

23.4 119 156 191 132 105 117 141 125 150 104 92 66 107 142 7623.42 122 199 237 115 108 110 147 114 114 103 93 79 120 151 8123.44 126 177 248 126 115 109 137 127 125 94 99 100 118 137 9023.46 123 209 262 112 111 104 150 135 136 94 107 107 106 149 9523.48 105 195 230 100 120 125 128 127 109 125 97 68 113 145 97

23.5 116 177 246 125 123 134 125 127 107 109 92 61 111 169 11323.52 133 180 269 118 138 112 139 140 121 142 88 61 105 146 9823.54 128 166 263 135 119 127 138 141 111 124 109 89 90 143 9423.56 133 180 282 112 137 119 139 132 126 126 112 90 130 137 9123.58 143 143 261 147 136 130 149 129 116 110 89 108 113 145 76

23.6 132 149 265 131 122 113 141 147 119 132 116 96 116 144 11223.62 113 140 224 119 150 129 153 160 118 135 106 96 135 167 12923.64 128 115 222 126 109 131 159 145 116 114 109 95 123 149 9923.66 134 139 193 149 151 131 156 178 128 126 128 111 130 149 12023.68 133 135 207 158 147 140 177 211 122 140 122 116 117 156 130

23.7 133 151 233 140 148 131 186 204 147 160 128 127 126 184 13023.72 156 149 215 150 179 147 176 211 150 187 130 123 162 192 15523.74 143 140 203 167 162 150 196 244 137 170 158 92 140 203 15023.76 169 159 235 191 198 170 215 263 178 163 178 103 157 192 15223.78 177 166 257 179 191 182 228 311 155 208 167 139 176 196 162

23.8 211 190 251 191 207 165 256 296 190 196 204 147 179 213 20023.82 201 175 232 198 203 228 260 405 231 229 203 184 160 247 20523.84 221 213 255 215 238 200 287 414 236 232 235 180 233 252 22223.86 252 233 254 257 242 252 300 473 234 275 275 207 226 250 27123.88 266 252 260 278 285 296 390 537 255 290 358 233 275 287 332

23.9 309 298 302 298 318 291 407 577 289 328 402 272 273 320 34523.92 325 305 318 307 399 366 446 627 368 370 463 322 327 398 45723.94 379 338 302 416 457 398 490 648 413 457 583 385 372 435 50523.96 449 438 370 440 491 431 585 667 485 605 625 432 431 504 59423.98 551 591 448 524 564 523 667 620 551 683 785 562 522 619 786

24 625 665 522 610 678 588 731 590 597 898 871 649 644 684 92424.02 816 717 602 670 745 730 847 540 687 1043 944 739 811 837 106524.04 936 800 597 827 807 767 798 472 764 1160 1010 734 936 934 111824.06 1102 703 642 886 892 779 847 403 758 1105 946 720 1102 965 100624.08 1225 604 674 894 923 818 800 396 818 926 769 565 1190 975 791

24.1 1206 505 564 925 858 816 691 280 787 670 616 386 1228 981 65724.12 1112 347 505 898 780 741 604 250 753 519 462 242 1036 750 45424.14 824 295 435 827 585 645 497 204 696 397 265 156 874 729 33024.16 662 240 358 708 486 579 431 205 603 276 256 122 675 552 21124.18 451 199 363 609 373 439 337 176 500 203 177 144 447 379 172

24.2 347 154 360 514 287 366 291 142 425 171 159 148 326 303 15324.22 239 169 330 352 223 299 262 135 310 145 131 135 281 231 139

287

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

24.24 197 137 305 306 205 249 213 134 306 147 141 118 193 198 12524.26 191 159 299 253 192 208 240 118 252 128 96 95 197 180 12924.28 169 111 314 230 138 168 186 107 213 143 117 94 165 201 120

24.3 152 119 285 174 149 156 174 113 179 119 89 87 130 182 10324.32 139 108 291 177 129 142 180 109 162 101 104 101 145 153 10824.34 147 147 239 132 136 134 172 114 148 111 84 100 131 138 8924.36 132 114 230 157 116 128 142 109 126 104 101 91 100 148 8324.38 123 101 181 127 122 124 151 96 124 107 75 64 122 154 94

24.4 104 123 199 149 127 108 150 95 132 110 87 81 109 123 8324.42 123 132 158 108 100 107 167 90 118 81 94 62 107 135 9824.44 106 81 192 120 106 109 189 97 100 101 90 85 112 136 8524.46 105 112 190 92 105 131 151 92 96 88 70 67 88 130 9424.48 128 96 162 115 120 104 142 90 115 102 83 96 88 115 97

24.5 119 123 148 116 114 106 143 99 104 96 72 73 109 134 8024.52 91 108 172 103 102 90 130 99 117 101 104 72 90 138 7824.54 103 124 176 121 106 90 112 86 103 90 88 64 101 130 7624.56 98 97 170 87 125 98 114 78 104 69 82 82 103 130 7724.58 116 99 170 105 110 101 123 99 75 93 82 81 92 120 95

24.6 93 99 174 114 102 97 117 110 83 99 81 104 105 122 7724.62 111 97 155 93 102 111 120 89 104 86 77 70 80 122 7524.64 113 99 157 115 122 85 126 90 99 99 77 60 85 127 8524.66 101 104 167 110 97 100 122 87 77 98 77 55 109 113 8324.68 113 101 171 98 99 90 116 91 106 89 70 61 103 120 82

24.7 112 79 166 88 126 85 101 99 103 100 71 79 107 106 9024.72 93 115 174 93 103 84 127 90 90 74 86 75 93 114 9124.74 107 95 168 99 114 104 129 90 87 87 87 64 94 152 10924.76 111 92 141 102 115 96 115 92 96 75 85 58 97 134 8024.78 113 82 166 80 91 78 108 84 104 96 82 69 115 118 76

24.8 106 98 190 107 112 90 98 87 113 98 84 72 85 122 8224.82 99 98 170 79 132 84 117 101 93 76 92 80 98 123 7824.84 110 94 159 84 170 88 102 81 96 95 73 63 96 134 10224.86 76 95 153 80 124 99 112 98 88 102 63 71 109 147 10524.88 104 86 151 92 154 92 118 81 102 85 69 55 96 125 85

24.9 98 105 173 103 157 95 130 74 114 81 63 67 100 150 8024.92 85 97 166 96 179 99 111 99 97 102 79 75 97 126 8224.94 96 95 177 113 137 90 116 90 121 75 74 78 108 121 8424.96 114 82 160 91 135 82 124 89 101 83 77 68 109 147 6824.98 104 110 170 88 109 84 121 80 92 79 74 73 94 129 95

25 99 105 195 109 107 91 93 87 92 88 67 89 76 144 8125.02 87 120 197 108 101 103 113 80 98 87 74 60 82 140 8625.04 91 100 205 91 98 83 97 75 89 82 84 77 102 151 7025.06 92 106 196 112 129 99 119 73 101 83 66 59 88 156 84

288

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

25.08 97 115 251 105 85 94 91 86 85 90 76 60 86 141 6325.1 95 125 248 91 94 85 106 121 113 107 84 65 97 149 74

25.12 96 114 224 106 92 73 119 96 98 76 69 73 107 155 9025.14 101 122 233 108 97 101 109 100 99 75 79 55 69 170 8925.16 99 109 229 94 100 99 125 73 104 87 56 56 91 187 8625.18 95 136 200 98 82 101 95 83 86 87 64 67 85 156 95

25.2 114 126 226 81 102 75 123 100 101 84 73 79 93 203 8325.22 94 115 254 86 107 91 109 82 106 96 74 78 100 195 8925.24 105 115 264 99 83 102 101 91 91 73 70 71 85 219 9125.26 102 109 280 107 94 83 106 76 100 77 83 52 65 219 9625.28 115 125 251 89 105 81 116 81 111 74 65 65 83 273 91

25.3 98 96 263 85 96 73 133 95 96 77 63 52 96 308 11425.32 87 104 284 89 91 82 120 89 94 97 83 77 96 355 9325.34 96 113 273 104 115 74 122 84 80 81 79 66 92 392 13325.36 96 103 255 80 97 86 109 78 95 84 78 82 78 512 16025.38 104 117 291 96 78 76 105 71 85 87 61 60 82 555 182

25.4 114 132 299 84 94 76 95 64 97 82 79 71 84 698 19625.42 76 125 288 93 96 98 99 82 100 76 87 54 81 710 17825.44 97 129 302 83 102 81 125 95 97 91 70 74 91 764 20825.46 93 135 265 104 102 96 117 85 94 84 83 53 90 869 17225.48 105 125 254 108 97 98 105 82 103 90 77 65 100 949 160

25.5 89 114 251 89 101 88 117 88 90 66 82 61 98 828 12925.52 107 127 274 118 87 102 98 96 76 82 67 75 92 724 9925.54 87 138 256 101 107 82 107 83 97 96 62 57 87 577 11525.56 96 163 245 91 89 102 108 81 102 74 61 62 88 481 12625.58 88 120 261 103 112 90 106 83 86 91 67 57 94 344 107

25.6 93 132 240 93 91 78 113 90 82 72 67 68 84 362 10125.62 87 119 211 88 88 92 100 86 96 62 74 67 98 192 7925.64 86 141 231 87 102 78 117 79 102 90 72 65 97 208 10425.66 78 125 203 81 93 94 90 84 88 72 67 62 96 172 8825.68 86 147 217 84 89 82 89 67 95 80 75 73 103 173 89

25.7 101 120 204 81 83 92 87 73 87 76 69 54 89 136 9325.72 82 145 215 93 95 75 100 81 77 100 65 72 95 115 7325.74 110 102 185 110 91 97 105 77 92 81 71 78 108 155 9925.76 99 95 178 86 82 83 103 84 92 90 51 55 97 134 7825.78 97 95 159 100 100 92 112 86 92 75 72 59 76 131 90

25.8 89 89 180 100 82 88 106 55 78 78 64 66 93 119 9125.82 90 77 170 81 92 75 101 68 83 88 65 69 93 114 11425.84 88 65 181 95 92 79 99 69 90 70 68 77 107 138 8525.86 90 86 158 96 72 79 87 59 86 77 68 64 102 140 7525.88 76 98 160 82 102 106 122 74 85 84 52 48 109 110 72

25.9 85 91 188 82 86 94 103 74 94 87 59 65 111 120 73

289

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

25.92 91 94 170 100 105 90 102 65 80 86 49 64 101 129 8425.94 92 94 149 94 90 86 101 81 88 93 70 63 95 110 8025.96 100 89 145 98 82 80 114 74 88 82 73 63 91 115 7325.98 76 79 141 80 91 108 91 69 81 79 77 77 86 131 82

26 90 89 151 84 90 80 121 78 72 60 64 49 74 117 6726.02 104 74 163 85 100 90 99 70 78 82 66 51 94 100 7726.04 90 78 171 95 106 92 115 90 96 106 74 54 79 114 8226.06 110 100 161 79 97 90 106 81 96 107 60 54 82 112 8326.08 85 77 179 86 102 93 119 72 86 81 69 79 77 114 71

26.1 83 102 163 86 81 96 102 92 83 97 72 73 79 113 7326.12 94 93 165 94 103 104 96 85 90 70 62 54 84 110 8026.14 88 91 178 75 100 105 108 91 96 85 67 68 77 118 7826.16 106 95 171 92 100 85 96 95 89 85 73 53 75 114 6326.18 78 89 174 86 91 104 101 103 87 72 80 75 76 124 91

26.2 89 100 179 82 106 98 108 118 104 83 77 47 85 106 9026.22 93 100 207 101 101 107 130 83 88 74 71 57 91 130 7826.24 93 98 185 95 106 128 113 80 97 85 60 64 83 116 7926.26 89 104 196 96 129 117 119 94 92 94 79 56 73 111 8826.28 112 137 212 89 116 93 147 97 90 93 78 70 88 131 76

26.3 100 93 195 93 112 97 135 86 69 77 57 70 70 132 9226.32 108 93 219 119 131 113 162 99 85 86 55 76 85 115 9526.34 97 109 213 74 134 105 143 129 123 101 86 62 91 118 8326.36 85 131 244 98 137 124 135 111 94 81 74 59 71 109 10726.38 90 127 269 99 125 128 163 118 88 102 90 46 66 114 116

26.4 117 131 285 103 151 140 200 132 91 96 93 53 88 131 11726.42 103 150 345 131 138 145 187 158 102 107 84 61 91 118 16526.44 118 176 352 116 188 146 217 173 96 107 79 76 80 129 19326.46 109 196 468 128 177 148 245 201 103 102 105 63 89 138 25626.48 133 209 610 146 209 143 300 193 124 122 104 77 79 156 268

26.5 116 258 802 149 273 187 348 201 106 153 102 81 91 179 42226.52 121 340 834 139 289 252 442 257 144 186 140 61 75 197 46926.54 145 478 1001 171 364 296 450 256 163 201 139 96 80 262 55026.56 173 623 1240 186 498 356 638 229 169 259 185 91 100 291 60126.58 166 693 1410 231 626 445 830 249 168 351 143 125 101 291 847

26.6 150 830 1614 290 758 560 1115 251 248 423 166 135 123 316 99426.62 199 835 1808 316 860 680 1423 241 268 517 196 124 145 395 140626.64 248 652 1663 364 973 811 1650 169 289 486 207 136 150 413 174026.66 225 556 1629 421 1032 764 1611 140 322 410 197 63 117 451 124826.68 195 483 1523 382 975 671 1481 122 272 300 152 77 117 428 775

26.7 172 358 1222 328 795 522 1167 104 249 253 152 53 99 332 73126.72 165 257 871 319 598 423 930 86 217 179 108 55 95 239 53926.74 101 250 726 248 449 305 649 86 198 141 107 70 103 226 273

290

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

26.76 100 204 598 238 322 203 430 94 121 95 79 55 104 151 14226.78 91 208 476 172 198 138 300 88 121 90 78 74 96 131 110

26.8 88 217 416 142 142 119 181 66 110 76 71 72 113 110 12626.82 105 195 399 108 140 127 167 94 109 92 70 75 83 113 10826.84 97 183 365 98 119 106 141 71 99 104 79 78 109 111 11326.86 67 178 302 94 103 91 132 84 103 90 66 56 86 114 9726.88 90 162 305 107 106 94 140 85 100 88 72 48 91 109 93

26.9 75 130 257 122 103 87 135 54 94 71 87 57 83 106 9026.92 83 144 258 87 111 91 112 77 70 86 63 49 92 121 11126.94 75 124 241 90 95 91 112 66 100 87 69 53 82 110 9826.96 93 132 217 120 115 86 118 93 76 81 58 56 82 107 9026.98 79 133 242 104 78 67 123 72 98 76 77 61 78 108 105

27 79 139 215 93 99 75 99 88 93 71 66 74 88 124 8027.02 79 142 227 67 94 74 85 75 87 61 63 61 86 121 8327.04 88 140 219 82 96 86 94 75 106 74 71 56 93 104 10527.06 86 163 264 89 97 79 106 74 76 78 76 44 89 125 10327.08 70 139 201 88 95 68 81 95 91 66 80 44 58 118 123

27.1 89 130 203 84 81 81 95 77 89 60 69 61 95 126 10127.12 84 120 237 84 90 89 103 74 88 65 52 62 79 111 10427.14 83 119 223 84 87 72 118 75 79 90 75 55 92 99 10327.16 87 122 219 90 77 78 101 77 103 82 75 57 80 104 7827.18 89 89 180 94 94 100 105 91 105 71 61 50 69 126 85

27.2 83 107 220 81 87 87 100 78 86 75 72 55 76 109 8127.22 86 107 210 101 78 84 84 64 78 77 54 52 85 92 9527.24 76 103 193 73 73 85 105 74 80 69 61 46 68 99 8827.26 78 103 175 115 101 77 97 81 78 77 73 59 69 95 8527.28 97 108 191 85 93 85 111 87 105 74 55 59 71 93 72

27.3 71 112 227 99 88 75 119 81 77 68 74 63 85 117 8027.32 98 125 241 74 79 78 95 81 95 71 52 59 75 108 9127.34 83 145 269 94 93 61 92 61 96 91 61 56 81 103 9927.36 87 123 249 91 78 90 93 79 76 75 70 54 59 132 8227.38 82 140 277 93 86 82 91 70 88 78 84 62 75 112 82

27.4 91 166 274 95 76 72 107 67 74 84 73 62 74 109 9527.42 71 150 269 87 83 72 106 74 96 71 66 52 75 127 11027.44 88 171 284 95 79 88 107 69 75 66 76 61 60 104 11327.46 83 170 283 89 80 99 75 84 80 81 70 59 84 116 11127.48 82 158 281 88 86 83 96 91 76 76 75 65 75 111 116

27.5 81 163 289 94 84 75 91 76 106 56 75 74 80 124 10427.52 88 165 268 95 85 83 113 78 71 69 61 47 63 116 11527.54 81 161 266 78 86 73 87 67 82 60 63 65 81 122 9127.56 74 155 233 94 89 66 95 85 80 98 70 54 64 114 10227.58 66 175 280 69 104 91 87 79 72 70 77 69 86 103 83

291

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

27.6 70 164 274 92 91 72 103 71 86 85 57 46 88 103 7827.62 78 171 328 97 84 82 110 79 87 66 76 56 84 94 7527.64 73 142 323 108 100 69 89 76 102 79 76 71 69 97 9127.66 78 135 305 82 72 69 99 81 75 72 71 50 75 115 6427.68 74 159 338 78 97 78 93 60 90 74 68 61 76 101 74

27.7 66 151 353 101 73 83 107 91 91 80 80 66 66 91 7327.72 101 139 358 76 88 86 100 64 84 77 62 60 79 110 7427.74 74 147 329 83 87 73 96 81 84 72 65 62 74 88 6727.76 80 148 352 80 101 72 103 70 79 89 70 66 72 94 6027.78 86 125 381 83 77 84 103 61 81 76 84 57 70 100 77

27.8 80 133 346 76 88 82 114 72 88 65 70 70 77 95 8727.82 70 119 389 87 88 91 111 82 83 73 65 53 79 84 9127.84 92 128 395 77 76 85 102 73 86 70 71 71 70 94 9327.86 69 146 468 75 84 85 108 77 90 75 76 62 87 100 7327.88 93 135 464 87 99 81 108 86 92 109 66 52 77 95 87

27.9 73 164 575 87 75 77 94 71 78 70 69 71 75 87 10027.92 96 125 577 85 92 68 109 73 101 77 60 75 74 107 10227.94 80 147 529 94 88 76 96 77 80 75 70 48 70 99 9527.96 99 135 466 85 90 79 92 67 98 82 71 66 94 101 9727.98 89 107 394 74 78 82 117 83 82 86 62 53 83 105 99

28 95 103 375 83 95 76 99 62 92 66 63 62 65 93 9328.02 75 94 282 75 74 78 98 77 107 80 54 67 65 96 13728.04 70 102 316 99 77 83 106 87 89 72 69 63 71 124 11028.06 94 96 273 88 96 73 98 75 82 72 62 55 88 109 9928.08 83 93 254 91 89 75 98 80 76 83 63 67 74 103 83

28.1 70 90 268 82 85 76 91 75 90 93 66 56 90 111 9928.12 85 73 269 83 71 68 102 87 84 87 73 57 80 106 9128.14 78 99 270 98 67 75 103 74 98 86 59 62 80 90 8528.16 70 91 276 82 78 89 102 92 92 94 73 75 76 100 7128.18 81 86 269 77 84 94 98 84 76 112 64 75 69 104 81

28.2 91 91 282 71 86 87 99 69 79 112 76 79 66 93 9128.22 84 85 252 84 86 73 111 69 86 100 59 63 85 102 6628.24 89 81 253 65 95 82 86 87 79 106 83 57 72 103 7128.26 87 88 225 74 72 79 88 82 80 100 82 51 72 94 7528.28 82 88 211 80 83 103 76 93 72 93 60 56 78 96 63

28.3 80 84 190 97 97 78 90 68 93 85 79 60 66 99 8528.32 76 90 202 86 80 75 104 80 83 80 98 70 68 86 9028.34 88 74 195 73 90 81 99 69 90 77 80 63 73 114 7828.36 73 91 181 81 75 63 88 77 85 86 75 61 85 93 6728.38 75 71 219 81 64 90 99 69 85 87 76 77 61 97 71

28.4 78 55 180 77 87 79 106 77 93 80 63 58 66 69 7928.42 104 71 181 83 84 85 82 86 84 75 64 71 81 92 80

292

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

28.44 91 84 191 96 83 63 97 93 113 75 65 51 80 114 8528.46 85 86 207 76 81 75 101 94 97 92 69 69 74 96 6628.48 80 74 216 86 72 70 94 66 84 85 78 91 79 116 74

28.5 82 74 206 73 92 82 104 72 101 69 80 68 81 82 7628.52 72 65 187 83 83 77 97 77 89 55 78 55 68 85 8228.54 66 74 185 76 75 69 114 86 102 85 76 62 77 96 6628.56 79 80 175 88 82 69 106 90 91 71 82 72 74 110 7228.58 93 65 157 74 80 91 88 83 104 86 64 76 82 120 77

28.6 76 65 165 82 82 79 109 73 114 82 65 83 77 110 10328.62 82 58 168 91 100 56 104 81 121 88 76 79 99 120 8128.64 96 64 186 92 73 85 114 90 113 55 82 60 98 95 8428.66 83 66 158 81 87 83 121 94 120 64 77 59 94 101 7928.68 78 59 138 69 92 82 106 83 101 82 71 58 102 120 84

28.7 93 74 152 94 81 73 110 92 87 84 73 61 109 112 9428.72 98 68 147 74 105 90 105 85 106 75 88 70 69 109 10228.74 71 82 168 76 72 75 113 88 88 82 70 74 90 95 9028.76 94 58 155 86 88 83 105 100 105 83 74 96 98 110 9228.78 88 57 146 77 91 96 129 93 103 89 73 78 88 110 83

28.8 86 50 141 91 96 89 115 110 92 81 74 73 97 105 8428.82 89 75 156 82 100 77 102 95 86 71 81 74 92 122 8528.84 94 70 146 70 96 67 121 111 102 86 90 85 97 115 10128.86 95 75 144 89 83 70 115 123 85 65 81 92 91 106 8228.88 89 69 170 85 91 92 103 113 104 79 84 82 80 112 84

28.9 94 68 139 74 73 90 112 123 79 84 84 85 77 111 9928.92 110 77 148 74 98 96 121 111 108 95 70 71 89 107 13428.94 82 59 145 100 102 96 126 127 110 88 80 68 99 124 10828.96 90 75 153 89 94 77 133 148 108 91 94 83 98 101 13428.98 78 72 173 89 95 98 103 146 110 96 105 97 89 106 133

29 112 71 145 95 94 80 136 166 125 91 109 87 78 105 14329.02 99 56 140 75 110 95 127 174 93 102 100 108 87 127 13429.04 113 61 152 79 85 99 120 186 130 107 127 103 110 111 10529.06 116 69 135 95 100 94 141 204 116 108 119 105 81 111 12329.08 113 67 140 89 104 85 144 236 140 110 139 93 91 125 101

29.1 121 72 133 91 98 100 137 245 122 107 115 127 99 107 11329.12 139 57 144 90 121 128 145 294 135 123 127 122 103 97 12229.14 135 71 143 91 106 119 157 319 145 121 109 147 96 127 12229.16 109 97 132 86 104 102 156 410 160 152 126 172 100 107 14129.18 132 70 146 90 124 119 183 441 164 157 143 173 95 100 143

29.2 147 62 140 109 154 145 170 556 176 144 150 155 104 108 12429.22 131 58 137 100 141 152 188 579 181 172 191 138 113 115 14629.24 139 76 137 92 147 150 207 694 182 195 209 165 94 128 14329.26 161 77 139 114 164 156 210 755 196 179 195 197 106 125 181

293

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

29.28 159 67 135 116 157 164 227 781 218 209 221 209 109 143 19329.3 164 78 138 103 201 183 270 927 216 238 232 293 132 150 215

29.32 199 75 134 143 263 225 273 914 239 326 278 282 118 133 25629.34 204 85 137 149 269 220 291 960 294 414 341 320 113 150 32229.36 216 67 121 167 295 260 342 890 349 485 403 404 129 179 35129.38 254 84 141 186 337 305 373 811 332 631 550 425 130 141 477

29.4 226 72 154 190 413 338 433 719 468 715 903 503 127 177 49429.42 252 72 141 238 510 384 520 690 532 764 933 478 158 175 50029.44 245 85 154 199 518 445 607 594 632 641 728 414 142 187 54729.46 227 87 145 252 548 533 626 511 698 577 585 364 141 178 56429.48 209 88 132 284 526 576 687 473 866 441 588 280 150 142 616

29.5 204 94 144 273 502 740 745 380 981 358 439 215 127 150 51729.52 215 82 153 298 431 762 809 380 1066 298 312 162 141 147 39929.54 192 92 146 267 373 879 713 381 1129 242 237 129 148 174 32529.56 166 65 154 261 283 961 688 353 1207 170 223 171 150 132 26829.58 122 93 122 270 277 948 648 365 1112 167 186 188 112 127 187

29.6 168 91 148 254 251 857 548 307 1147 178 152 161 110 132 15529.62 141 94 145 208 200 901 515 290 987 160 162 119 128 147 13429.64 152 101 142 209 175 846 420 273 943 122 138 127 109 147 12329.66 143 121 148 160 165 738 391 243 885 122 138 103 96 141 12929.68 124 107 167 191 179 702 286 246 792 130 119 109 123 117 120

29.7 130 93 193 158 142 613 301 205 658 126 136 148 98 121 12029.72 113 100 182 160 126 585 273 212 569 114 143 114 101 119 11529.74 123 126 216 144 112 524 225 191 583 109 127 136 115 109 10429.76 135 117 196 142 134 432 218 182 479 109 133 108 112 116 10629.78 115 130 224 117 133 392 233 195 435 94 127 84 95 128 89

29.8 129 124 232 120 124 346 231 176 446 113 123 108 113 115 10829.82 107 128 217 131 125 378 221 158 368 102 141 104 88 118 11229.84 126 95 195 132 113 286 203 163 353 132 143 113 99 113 9829.86 109 108 215 117 141 288 205 172 328 122 109 99 92 130 13329.88 112 100 238 130 122 247 205 156 285 109 122 83 88 111 100

29.9 112 100 225 124 141 197 183 174 263 111 132 101 102 115 11029.92 100 111 200 131 119 205 212 161 244 114 168 84 100 124 11729.94 119 103 221 120 119 183 206 149 264 120 141 105 102 120 12329.96 115 111 190 118 122 202 188 154 223 124 153 115 114 114 12329.98 91 104 191 138 127 179 160 134 224 135 139 100 107 134 120

30 110 82 174 135 138 177 187 144 222 140 173 102 103 137 11630.02 113 87 208 122 135 149 200 169 188 129 157 93 116 149 11530.04 94 98 216 124 130 153 209 184 219 137 165 98 122 147 12530.06 110 107 219 116 149 160 220 183 179 144 191 125 115 133 11830.08 123 95 210 123 133 160 197 155 183 137 186 115 103 113 125

30.1 125 100 232 133 130 167 213 209 172 129 183 132 112 132 117

294

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

30.12 89 85 210 127 145 156 205 179 151 147 189 123 105 143 15330.14 112 96 222 129 147 171 251 191 178 141 210 126 113 158 14430.16 128 96 219 135 164 149 242 229 207 162 212 113 133 145 15630.18 125 101 234 137 177 178 257 259 194 153 197 127 131 145 168

30.2 147 99 207 136 165 165 262 249 217 173 230 141 145 169 18130.22 153 114 199 168 167 196 287 263 190 200 254 141 147 165 18130.24 128 115 207 135 161 189 303 316 200 201 265 165 150 186 16830.26 153 117 233 163 183 209 319 323 226 209 282 180 149 155 20430.28 128 96 238 186 194 225 300 367 232 214 262 181 185 216 233

30.3 200 132 234 170 225 252 336 366 260 231 293 214 179 213 22630.32 183 163 194 211 226 239 372 424 247 232 340 169 187 224 26730.34 181 163 191 235 222 230 384 419 294 241 384 195 216 205 26030.36 189 143 191 238 239 273 425 594 275 280 379 220 231 252 28730.38 206 150 209 248 250 274 394 568 335 356 447 202 222 242 317

30.4 209 193 201 263 266 308 421 611 336 344 451 250 255 298 32830.42 235 204 207 289 294 282 500 731 363 364 531 307 286 294 36630.44 278 200 231 283 324 319 531 782 374 396 558 343 295 298 44130.46 302 187 258 320 330 340 595 887 432 491 613 387 326 368 47230.48 303 231 208 362 443 408 689 987 430 565 686 408 350 389 501

30.5 340 280 296 407 493 419 681 1102 502 622 783 451 392 483 56830.52 377 274 269 463 528 473 803 1187 542 689 851 409 470 457 63630.54 438 310 267 500 595 574 877 1356 567 771 947 536 520 518 73330.56 510 338 298 576 616 614 984 1569 704 875 1051 632 524 610 87230.58 595 399 293 684 718 658 1094 1808 784 989 1319 696 618 718 1012

30.6 654 467 371 747 810 750 1253 2053 861 1056 1403 787 719 751 111230.62 724 521 411 837 913 929 1390 2446 985 1259 1627 917 845 871 125230.64 851 606 428 895 1074 962 1627 2787 1226 1396 1943 1016 894 1054 149530.66 991 692 464 1098 1294 1238 1906 3411 1292 1607 2356 1264 1112 1148 167530.68 1176 870 568 1286 1471 1430 2143 3962 1570 1871 2923 1513 1186 1301 1910

30.7 1329 989 660 1428 1784 1591 2534 4689 1734 2357 3778 1791 1421 1526 239730.72 1581 1189 801 1668 2205 1908 3028 5743 2088 2825 4512 2082 1663 1770 288930.74 1733 1473 894 2035 2543 2259 3635 6701 2461 3353 5615 2692 2052 2043 353030.76 2089 1899 1161 2442 3260 2692 4323 7832 3002 4321 6694 3391 2424 2592 451330.78 2580 2421 1461 2866 3731 3163 5279 9202 3429 5430 8136 4331 2961 3164 5568

30.8 3225 2997 1862 3534 4675 3921 6105 10264 4234 6857 9307 5322 3572 3896 691230.82 3719 3971 2438 4368 5501 4889 7398 11093 5013 8734 #### 6821 4574 4886 909230.84 4872 5184 3062 5257 6329 5847 8495 11724 5966 #### #### 8091 5822 6343 ####30.86 6251 6841 3905 6366 7314 7148 9634 11944 7473 #### #### 9943 7493 7916 ####30.88 8052 8384 4991 7806 8382 8536 #### 11535 8492 #### #### #### 9690 #### ####

30.9 10560 10334 5914 9423 9525 9994 #### 10801 #### #### #### #### #### #### ####30.92 13508 11392 6809 #### #### #### #### 9823 #### #### #### #### #### #### ####30.94 16849 11557 7520 #### #### #### #### 8527 #### #### #### #### #### #### ####

295

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

30.96 19962 10329 7529 #### #### #### #### 7295 #### #### #### 9440 #### #### ####30.98 21127 8447 6996 #### #### #### 9824 6004 #### #### #### 6197 #### #### ####

31 19975 7006 5998 #### #### #### 8503 4925 #### #### 8499 3693 #### #### ####31.02 17038 5505 4986 #### #### #### 7373 3858 #### 8251 6508 2403 #### #### 762731.04 13895 4001 4028 #### 9224 #### 6240 3094 #### 5863 5034 1362 #### #### 523531.06 11026 2898 3070 #### 7479 8794 5116 2470 9079 4147 3634 1340 9782 8022 354631.08 8598 1902 2168 8683 5566 7200 4102 1904 7845 2810 2835 1281 7496 5806 2652

31.1 5691 1448 1514 7137 4279 5604 3506 1532 6317 2137 2280 996 5298 4123 197331.12 4068 1110 1119 5607 3135 4380 2770 1330 4975 1693 1883 1123 3613 2895 157631.14 2597 890 809 4161 2188 3335 2287 1037 3908 1428 1454 760 2503 2086 120231.16 1924 664 683 3212 1638 2613 1947 887 3252 1147 1294 575 1842 1595 105531.18 1570 594 578 2374 1274 2022 1681 696 2571 995 1060 530 1516 1323 848

31.2 1274 507 495 1867 1022 1543 1402 595 2059 830 951 307 1234 1047 75131.22 981 399 401 1544 838 1309 1151 523 1640 658 844 348 1012 893 65731.24 790 307 391 1235 716 985 1066 441 1331 598 659 320 813 797 56031.26 701 277 341 989 612 826 816 349 1138 512 577 280 713 695 46831.28 558 230 277 892 498 705 800 342 937 454 511 307 560 639 375

31.3 488 190 238 725 426 579 664 291 773 392 461 241 456 610 31831.32 376 182 206 558 365 491 543 251 642 341 409 220 435 582 32331.34 322 162 184 498 331 405 524 261 553 319 363 180 380 542 27631.36 279 159 199 437 292 350 442 230 469 266 324 145 313 539 26031.38 247 137 162 359 267 276 439 217 418 299 326 154 270 519 251

31.4 262 130 158 349 224 276 401 221 343 243 316 164 247 512 23331.42 222 128 162 276 215 248 362 162 341 221 303 174 221 428 22431.44 213 124 178 269 224 225 327 163 301 197 249 168 211 394 22331.46 175 104 165 242 214 194 322 155 279 206 250 142 218 333 20531.48 170 115 153 222 216 196 308 159 273 209 242 127 176 287 186

31.5 177 116 150 237 176 184 269 140 222 195 217 126 199 287 17531.52 136 97 142 195 165 178 260 133 232 174 208 114 171 220 17431.54 147 82 135 183 172 183 226 132 228 167 192 104 152 191 17731.56 126 99 146 175 175 151 220 147 185 145 183 97 142 178 16631.58 123 97 135 151 151 161 202 125 195 157 159 126 163 174 162

31.6 107 114 138 152 147 160 202 112 193 124 165 122 123 183 14931.62 123 81 149 166 131 157 219 121 178 143 160 111 128 150 17331.64 128 99 143 162 140 158 183 100 163 147 141 111 161 162 16831.66 127 96 146 143 128 135 181 116 163 160 124 87 109 146 19931.68 124 94 149 122 140 108 173 109 155 131 140 84 127 155 204

31.7 126 89 131 132 139 126 164 93 172 127 145 86 128 123 18631.72 108 95 148 121 114 119 173 82 141 141 109 80 116 129 16431.74 118 81 148 122 107 119 139 98 145 104 130 88 123 146 15031.76 95 71 138 124 112 103 147 97 145 112 127 94 123 130 15331.78 123 80 126 102 104 115 134 98 132 109 118 74 105 138 173

296

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

31.8 92 79 132 137 136 113 122 102 106 118 128 85 122 121 12131.82 114 85 151 105 88 106 126 100 118 107 111 84 94 137 10831.84 120 74 144 118 91 101 120 95 128 119 92 61 98 124 12231.86 110 66 123 103 104 98 133 98 127 99 110 72 93 133 11631.88 103 92 127 107 102 93 112 83 132 83 108 70 95 133 124

31.9 84 82 125 82 112 98 116 73 113 85 92 54 112 134 10031.92 103 86 113 95 80 92 130 77 120 88 86 88 83 137 11431.94 95 69 112 115 97 95 116 83 109 103 126 78 92 130 11531.96 98 79 120 109 95 102 94 107 108 79 82 74 95 154 12831.98 85 79 116 111 88 88 103 81 124 86 88 74 93 132 119

32 87 78 119 99 104 91 121 71 92 94 85 51 107 103 14732.02 93 66 129 85 79 93 92 82 128 71 77 56 112 142 16232.04 87 70 119 90 92 96 101 80 100 88 79 68 75 154 15532.06 101 73 118 75 105 84 103 84 109 85 88 53 83 148 16632.08 81 83 116 84 87 92 95 80 96 96 82 68 83 135 198

32.1 97 58 128 95 95 71 104 77 97 89 77 71 99 130 18532.12 85 62 123 73 93 108 102 79 102 77 79 66 82 147 18532.14 91 83 137 87 79 73 92 73 91 87 84 73 95 145 19432.16 93 81 112 100 93 81 83 62 81 86 94 76 93 133 15632.18 89 72 116 79 105 81 97 88 98 93 97 56 79 128 164

32.2 78 78 115 100 81 80 94 92 93 70 71 66 91 116 12332.22 79 60 97 83 89 107 93 75 103 68 70 57 68 114 12532.24 93 68 107 74 80 87 101 72 91 61 79 43 76 114 10432.26 96 75 110 83 72 89 89 69 70 86 75 52 79 120 8432.28 84 79 107 95 79 103 89 69 97 63 70 54 66 106 92

32.3 85 91 109 86 78 88 94 78 95 69 86 73 61 101 8432.32 82 71 106 69 73 80 103 85 83 92 72 76 87 90 7232.34 72 67 117 94 74 75 87 84 84 73 74 75 70 91 9232.36 69 70 112 96 77 81 83 65 95 76 74 56 81 87 7332.38 76 70 102 85 71 69 87 78 84 74 98 58 74 90 93

32.4 95 67 89 90 76 66 94 63 98 79 67 68 72 91 6832.42 88 65 99 81 76 77 94 66 98 73 69 48 75 84 7932.44 93 70 86 75 71 60 92 75 79 71 79 62 71 81 8232.46 57 67 77 82 70 77 95 72 87 82 59 90 66 86 7932.48 60 58 94 72 76 74 90 65 81 74 69 52 86 93 72

32.5 74 63 89 86 80 71 100 80 107 65 57 63 87 83 7432.52 86 74 93 70 82 74 100 75 65 69 57 64 78 99 7432.54 78 63 84 97 68 57 82 61 84 83 68 48 75 84 5832.56 98 73 82 85 82 62 85 68 77 77 87 73 76 90 6832.58 90 57 84 61 77 76 102 82 73 73 72 58 81 87 81

32.6 73 72 91 79 81 69 96 76 64 72 64 50 67 83 7232.62 91 63 71 85 88 67 87 69 65 84 74 66 83 103 65

297

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

32.64 79 61 81 68 82 82 81 87 78 77 61 55 65 96 8932.66 86 61 108 89 85 86 82 65 74 77 64 70 78 88 8232.68 74 72 87 77 91 66 90 82 72 79 65 69 72 86 92

32.7 79 50 87 84 84 82 106 76 91 68 85 48 83 94 9232.72 77 59 91 75 75 82 97 70 68 69 72 46 78 84 6032.74 74 49 93 79 86 75 102 77 71 74 65 44 84 129 8432.76 86 67 96 78 78 79 86 74 72 81 84 79 76 93 7132.78 80 61 114 89 89 87 84 87 67 71 70 54 101 91 72

32.8 77 56 93 74 91 67 103 72 84 74 77 56 74 90 6832.82 74 79 106 79 90 72 104 97 88 65 69 73 86 83 7832.84 89 53 106 81 87 60 88 95 83 82 74 47 82 101 7732.86 83 71 117 93 79 83 83 87 81 76 73 51 70 76 7832.88 88 92 127 87 83 70 106 84 81 75 59 57 90 99 77

32.9 86 60 150 79 69 77 99 80 82 80 74 50 90 92 6432.92 71 73 135 69 82 73 98 83 72 80 69 70 77 103 8432.94 93 96 173 94 90 84 106 83 101 92 83 69 82 82 5632.96 73 79 207 74 85 97 90 101 80 94 73 49 105 135 8532.98 80 113 247 91 90 95 110 100 78 86 96 66 94 77 81

33 71 74 222 101 99 84 111 97 103 88 88 66 88 117 8033.02 78 88 201 87 90 81 100 106 91 106 69 64 73 90 8633.04 93 99 220 74 78 93 111 97 99 92 92 88 110 100 8433.06 72 81 175 105 89 101 123 106 105 98 89 82 88 95 7833.08 83 74 137 85 103 89 130 94 92 99 89 69 72 122 101

33.1 83 87 167 98 107 111 124 105 92 96 94 78 95 134 7533.12 101 77 112 108 96 111 108 125 102 91 96 65 105 125 11833.14 88 77 114 129 131 128 141 172 115 109 105 73 109 118 11333.16 85 70 101 110 135 135 149 150 124 102 119 102 103 132 10133.18 111 60 127 96 130 126 150 157 133 127 139 80 108 115 101

33.2 108 92 121 131 142 115 187 173 124 134 140 84 106 124 12033.22 107 89 98 120 145 153 175 222 154 136 176 121 115 124 12133.24 98 95 113 130 173 139 224 250 147 142 177 110 108 137 13233.26 110 94 109 143 183 164 195 257 165 138 189 110 140 147 15633.28 132 103 104 165 212 163 218 306 184 180 210 134 123 151 173

33.3 151 122 116 160 226 159 248 321 183 205 239 158 151 178 19133.32 181 137 122 189 231 187 289 399 222 181 288 146 167 180 27433.34 191 146 126 202 266 214 287 398 248 252 260 207 207 231 25733.36 192 177 176 223 298 220 316 472 266 237 306 271 191 228 31133.38 187 195 169 262 295 256 370 507 271 344 362 303 269 258 395

33.4 240 231 180 262 345 272 417 574 330 395 355 359 302 323 46533.42 294 270 237 314 368 328 477 627 389 522 417 410 338 375 52933.44 363 322 268 421 409 418 512 624 444 573 521 478 421 461 64733.46 407 395 311 440 425 485 538 701 482 744 560 477 520 539 802

298

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

33.48 581 495 353 557 500 484 553 623 582 876 570 595 626 625 94133.5 678 523 389 598 534 619 540 579 628 855 583 620 723 764 940

33.52 867 589 412 681 567 674 506 496 661 824 528 544 774 814 90333.54 1101 554 469 790 638 695 519 476 726 721 513 502 958 851 82633.56 1266 479 454 810 694 724 542 404 713 649 433 381 965 797 68733.58 1281 448 411 753 721 718 471 325 719 566 389 231 966 853 616

33.6 1203 383 385 756 668 677 402 268 689 474 340 167 793 746 47833.62 1012 280 328 705 598 615 369 248 570 369 293 116 707 682 36733.64 851 257 275 608 518 534 366 217 540 317 214 118 593 526 28333.66 696 215 241 546 423 482 297 164 523 251 214 130 452 451 23833.68 544 121 187 449 349 360 272 167 408 205 194 99 387 380 192

33.7 423 121 199 366 326 325 257 167 371 185 152 108 290 283 16033.72 292 110 168 319 236 268 196 145 322 166 174 118 254 228 16633.74 243 100 157 253 185 255 206 138 273 158 156 93 181 171 16033.76 206 115 150 201 159 206 171 124 238 118 113 97 152 179 15333.78 154 99 120 189 142 165 193 92 197 99 114 81 141 166 148

33.8 161 82 132 160 105 151 156 90 182 129 106 77 112 139 14533.82 120 80 123 141 120 126 152 91 147 91 84 44 118 132 13433.84 119 72 140 142 114 123 123 80 152 100 79 59 106 142 12633.86 99 57 157 126 98 116 131 78 111 80 78 50 115 116 14433.88 107 66 141 106 102 91 111 61 133 79 98 54 89 111 119

33.9 89 82 150 131 89 104 115 64 128 78 87 87 83 107 11333.92 87 85 140 107 87 80 125 68 115 76 70 69 79 105 9133.94 96 65 157 102 86 81 129 91 102 75 82 78 84 90 8633.96 72 66 171 97 74 82 109 60 105 69 71 79 63 86 8833.98 75 77 159 95 85 84 112 73 82 94 79 60 75 105 90

34 83 60 195 79 62 81 93 67 88 67 75 39 75 94 7234.02 84 62 164 89 89 75 98 80 87 81 70 52 73 93 8434.04 78 61 176 66 73 89 79 75 68 83 78 51 76 86 8034.06 76 73 198 83 77 66 99 69 88 67 74 43 82 68 6934.08 73 78 187 89 80 78 88 86 75 74 63 51 80 92 74

34.1 72 70 205 77 82 80 94 64 77 61 66 72 69 96 8434.12 74 85 190 81 73 78 92 73 107 67 61 58 69 77 7234.14 88 72 191 71 79 68 86 57 75 79 68 53 71 94 7434.16 66 85 194 74 82 83 88 71 82 84 74 77 75 81 5134.18 62 74 206 91 79 79 78 75 85 65 66 60 66 98 80

34.2 69 85 189 91 82 90 84 75 85 73 71 46 67 81 7634.22 66 69 213 84 68 73 75 75 73 77 55 52 54 90 8534.24 72 81 224 79 66 68 86 74 78 60 61 46 60 83 9634.26 69 76 221 80 75 55 85 65 77 76 46 47 61 93 7634.28 86 69 213 96 81 73 106 63 75 75 58 54 67 95 59

34.3 80 85 239 87 64 87 74 58 79 85 64 53 78 89 74

299

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

34.32 79 91 203 66 86 68 93 62 92 65 77 72 68 85 7234.34 84 114 239 87 65 78 104 59 75 65 59 62 70 85 6534.36 87 79 237 72 72 69 69 61 101 70 62 67 67 71 8134.38 75 109 255 72 93 84 95 74 102 69 51 61 84 89 75

34.4 77 85 277 74 77 65 75 79 85 69 58 41 77 81 5834.42 70 98 248 85 83 81 94 57 77 52 60 48 63 86 6534.44 79 114 272 79 85 81 101 74 69 69 65 44 71 86 9034.46 72 126 281 90 94 88 99 64 91 61 56 42 87 88 6734.48 83 115 283 88 99 87 94 80 93 80 67 55 66 108 58

34.5 73 102 295 102 82 92 101 76 92 69 63 72 59 82 7734.52 68 105 310 88 72 86 94 67 88 63 52 67 83 65 6634.54 81 125 311 90 77 84 109 77 94 78 71 53 77 94 7934.56 82 122 310 93 83 79 94 73 71 71 53 56 73 98 5734.58 89 115 309 66 76 87 105 100 97 63 55 56 61 82 68

34.6 69 129 320 69 79 79 106 82 102 67 66 56 66 85 6434.62 75 128 270 92 92 70 104 97 86 75 77 48 75 79 6834.64 93 138 310 69 94 73 127 93 89 64 65 60 71 86 7434.66 76 149 289 90 96 97 114 99 99 62 65 57 75 74 7334.68 93 121 299 95 109 89 117 92 106 86 62 58 72 92 66

34.7 82 118 301 117 87 100 119 89 98 74 62 71 78 81 7034.72 85 132 301 97 101 91 113 101 110 64 68 64 83 110 8034.74 73 122 328 97 98 100 120 93 96 73 71 47 64 81 6834.76 87 137 347 85 106 96 117 121 110 67 61 52 75 95 6534.78 94 125 332 94 109 91 132 97 110 77 81 64 70 97 69

34.8 78 135 306 92 112 93 128 124 127 84 90 42 74 104 7934.82 91 122 334 89 98 95 137 127 113 76 91 90 90 90 8234.84 83 144 330 101 107 105 126 137 97 95 71 70 95 100 9734.86 81 123 333 95 113 82 124 139 121 77 66 58 101 90 9334.88 97 139 383 100 115 92 139 146 113 84 74 89 109 99 91

34.9 94 164 381 110 120 97 130 144 107 95 88 85 108 99 10434.92 89 153 341 116 137 97 133 170 125 108 99 66 92 113 9634.94 101 140 372 99 122 132 169 179 135 114 106 91 95 121 10134.96 119 154 387 97 125 119 150 204 155 129 98 75 103 120 11034.98 114 150 365 110 140 100 174 186 132 103 122 86 112 100 129

35 103 159 413 124 141 133 191 233 154 121 130 121 119 140 10935.02 116 161 337 131 151 136 194 237 148 142 131 96 155 132 12035.04 137 156 337 164 166 155 221 266 184 161 137 131 128 157 16735.06 160 160 318 162 190 176 243 309 195 168 187 152 167 165 14135.08 147 161 349 178 187 195 258 369 206 166 207 159 139 195 208

35.1 189 168 350 182 209 155 254 395 220 211 228 173 176 178 19935.12 182 187 327 187 243 203 283 451 233 223 267 213 209 197 23535.14 206 188 373 221 269 213 307 449 279 273 320 258 188 213 254

300

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

35.16 228 193 324 242 293 266 363 506 261 340 319 261 229 258 35235.18 282 290 359 289 323 293 418 548 356 409 396 292 307 311 420

35.2 301 304 369 318 357 348 446 533 380 486 456 386 329 362 46935.22 413 376 426 377 383 359 477 532 418 610 484 449 434 449 59635.24 488 459 449 462 443 444 477 559 444 765 571 537 492 520 70635.26 595 513 468 512 484 489 517 508 481 845 597 560 608 644 80935.28 748 617 495 551 534 557 591 526 556 885 585 609 696 696 803

35.3 931 630 550 668 650 590 543 480 575 886 580 566 858 796 82835.32 1089 602 538 691 685 615 516 411 599 763 546 464 1024 866 74035.34 1182 533 564 663 680 599 489 366 629 652 491 363 981 879 64435.36 1188 449 537 714 692 625 459 355 607 613 456 253 958 792 55435.38 1071 399 519 724 654 596 435 314 625 545 429 224 896 773 457

35.4 919 327 434 681 592 524 409 295 579 440 317 141 823 613 39135.42 795 300 412 593 528 506 361 290 506 318 293 149 622 536 32635.44 676 221 297 488 469 458 337 246 438 251 231 134 535 444 24035.46 569 197 318 475 397 378 286 205 440 232 208 101 462 352 21135.48 407 167 310 417 302 338 257 194 350 190 188 104 357 304 157

35.5 326 137 272 345 254 291 271 165 331 187 172 113 286 238 15635.52 233 97 275 294 226 244 223 140 268 150 153 85 202 228 13535.54 186 120 259 256 205 232 198 113 241 131 137 93 184 156 14335.56 184 83 231 213 156 197 160 113 216 146 130 102 150 189 10935.58 138 97 194 208 136 176 174 121 191 113 116 93 133 121 104

35.6 131 85 231 157 143 160 180 100 170 103 118 76 123 134 11135.62 127 94 219 162 124 136 163 119 178 119 101 91 110 117 10635.64 119 59 208 147 115 130 150 93 161 104 112 72 111 109 9235.66 102 71 194 135 106 106 159 98 180 104 102 69 120 130 9035.68 107 73 195 114 94 108 128 100 124 104 84 71 101 122 89

35.7 95 88 169 117 84 104 133 106 144 99 81 57 98 85 8535.72 91 86 169 116 112 114 119 111 124 96 84 62 94 108 7735.74 83 76 202 96 111 100 113 101 124 80 88 85 101 110 9235.76 89 94 174 87 116 105 101 120 124 92 68 62 89 99 7335.78 80 74 211 95 102 78 128 129 117 85 79 74 86 108 88

35.8 90 70 164 115 98 100 112 137 90 92 74 89 88 89 8235.82 95 64 166 107 96 76 130 132 107 98 82 78 73 95 7235.84 90 76 179 97 99 86 123 135 113 100 77 62 79 100 7235.86 88 64 154 115 108 98 125 156 105 99 91 77 91 92 7935.88 87 68 177 101 100 90 121 171 127 115 84 70 85 96 82

35.9 102 65 184 101 101 106 103 162 115 114 92 75 89 100 7935.92 95 67 176 111 108 113 105 148 116 133 86 94 85 112 7135.94 95 83 180 95 122 101 128 158 126 147 84 108 78 101 11435.96 94 66 198 92 149 119 117 151 130 153 86 104 76 111 10035.98 118 70 186 106 120 128 142 146 148 166 99 104 89 104 90

301

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

36 88 74 168 102 159 126 127 134 147 143 83 112 80 96 12836.02 89 93 162 108 166 140 172 139 170 169 101 99 83 111 13736.04 99 73 169 100 177 133 156 116 184 109 74 88 79 91 12836.06 98 57 150 109 149 143 187 109 193 114 69 89 88 111 10336.08 82 65 177 120 151 150 190 118 179 110 97 83 73 109 101

36.1 97 73 186 106 156 161 175 120 166 101 80 67 82 106 11736.12 81 67 188 110 130 161 175 103 201 72 71 57 94 94 8636.14 78 80 164 101 119 183 183 86 204 90 65 58 78 109 8136.16 86 63 181 94 127 164 145 96 210 83 80 76 81 120 9836.18 95 57 198 108 116 173 151 98 204 93 77 55 66 130 69

36.2 90 88 193 95 113 146 148 87 205 81 69 73 82 103 8136.22 88 64 173 81 107 172 151 94 204 83 73 81 64 134 7236.24 89 72 190 102 108 172 140 91 194 71 73 68 82 143 8036.26 86 80 197 90 104 180 136 88 170 78 56 66 79 123 8036.28 80 51 174 97 90 144 108 85 173 60 64 59 67 145 77

36.3 79 69 188 89 107 135 132 83 148 82 69 63 73 138 8236.32 74 72 162 86 93 154 117 84 174 84 57 68 81 156 7036.34 84 67 206 104 97 138 132 84 132 75 65 59 74 147 7736.36 61 82 222 80 112 145 124 78 136 79 60 44 74 121 6636.38 93 68 202 99 93 125 138 88 126 96 66 68 70 139 76

36.4 75 75 219 87 116 105 113 85 130 68 73 53 63 128 7736.42 77 79 205 88 108 116 141 79 114 90 72 48 54 117 7336.44 87 113 248 74 92 101 115 98 124 75 72 69 76 98 9336.46 84 114 268 95 131 124 153 82 108 100 73 78 76 100 7436.48 67 139 271 83 129 132 163 83 138 88 73 54 86 101 74

36.5 71 126 309 94 136 113 179 96 108 80 77 59 82 121 10936.52 92 109 313 102 164 163 189 85 119 93 83 73 68 154 11536.54 96 109 355 72 155 172 174 98 117 95 69 71 71 206 13136.56 83 102 360 98 172 191 220 81 106 90 81 73 74 155 8136.58 113 102 302 85 183 187 203 88 134 99 77 59 78 151 98

36.6 93 83 246 100 184 162 185 86 104 81 80 46 75 123 8536.62 79 100 301 82 159 130 176 87 93 69 68 64 89 140 9036.64 88 75 267 97 152 150 141 74 118 80 68 66 73 123 8336.66 85 101 247 100 166 146 129 120 111 71 68 64 79 126 7536.68 84 83 227 90 151 125 144 83 87 84 79 81 79 114 76

36.7 90 82 240 95 150 98 132 92 98 79 85 74 69 95 6936.72 86 89 224 106 109 111 124 77 117 80 74 65 70 109 7636.74 88 72 209 110 101 86 116 128 106 80 91 62 78 83 7036.76 97 60 212 116 136 87 126 107 84 82 58 66 81 82 7536.78 75 80 224 108 118 104 103 105 105 87 74 75 83 77 65

36.8 98 77 235 106 122 100 121 98 102 76 67 55 90 95 8336.82 115 87 204 104 135 82 112 113 107 86 75 70 81 106 68

302

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

36.84 90 100 212 92 120 85 130 123 124 81 82 81 71 95 8236.86 86 108 210 105 112 104 116 155 111 102 77 72 84 99 7136.88 103 93 202 111 108 100 120 146 113 101 79 54 91 108 108

36.9 103 93 219 127 138 101 127 152 98 79 96 77 92 101 8136.92 90 95 198 112 129 93 130 158 113 98 92 107 82 107 9036.94 85 98 227 116 136 97 130 151 135 98 102 83 103 120 10136.96 95 81 237 119 126 100 129 185 123 108 121 88 98 113 9536.98 104 117 257 120 127 106 151 200 129 126 111 107 125 135 104

37 131 116 308 119 135 127 150 234 116 128 138 99 133 128 9437.02 124 130 282 126 148 132 170 255 123 131 144 99 142 124 11837.04 129 140 272 153 167 132 191 257 141 140 110 128 115 166 13737.06 129 130 283 151 160 147 187 315 166 171 129 133 158 142 14837.08 154 151 257 159 167 147 201 354 174 165 164 136 162 162 159

37.1 166 146 251 176 175 150 246 437 186 164 191 146 152 174 17137.12 171 158 264 181 184 174 261 499 222 195 226 161 136 171 18137.14 178 181 247 224 232 228 306 548 235 191 250 176 206 229 21837.16 230 161 247 222 249 248 337 684 272 262 295 196 223 220 23737.18 229 195 251 266 271 295 404 795 303 294 355 233 234 226 286

37.2 255 262 288 315 331 328 421 827 368 331 463 313 273 287 38937.22 298 344 303 388 415 403 508 984 434 437 581 412 363 359 47337.24 405 371 368 428 512 445 642 1025 486 519 718 517 424 458 60737.26 471 475 474 521 592 563 798 1078 598 720 856 699 523 506 74137.28 553 654 504 610 703 636 861 1084 688 874 1058 846 659 691 1008

37.3 815 867 642 780 831 819 976 1030 831 1156 1254 1052 855 922 121637.32 1037 1005 712 892 1033 857 1137 944 959 1432 1547 1167 1105 1145 158237.34 1322 1066 814 1060 1158 1050 1143 884 1097 1633 1553 1196 1428 1334 170637.36 1487 1057 915 1219 1159 1186 1154 844 1174 1579 1528 1072 1620 1513 155237.38 1843 922 856 1317 1264 1168 1154 710 1209 1352 1324 859 1792 1580 1268

37.4 1752 796 817 1367 1251 1252 1134 628 1256 1135 1080 607 1758 1607 106937.42 1560 693 737 1271 1104 1193 1007 450 1178 943 949 356 1622 1380 94937.44 1325 602 606 1282 1058 1067 828 459 1111 825 814 272 1385 1092 79837.46 1210 451 518 1214 849 920 739 403 998 634 592 164 1226 934 62737.48 1034 369 464 1072 747 849 669 268 915 483 455 156 974 882 415

37.5 820 322 410 934 636 749 545 266 809 371 355 124 823 698 34337.52 629 245 354 786 495 645 435 201 665 247 263 135 684 562 26037.54 508 182 327 670 394 538 355 203 559 173 211 118 498 358 20537.56 354 160 299 547 285 442 286 174 464 170 178 114 356 306 16337.58 253 165 262 405 261 318 270 131 382 140 128 123 270 215 135

37.6 234 139 251 322 224 274 229 120 362 142 121 79 213 184 14537.62 199 130 260 269 160 257 206 98 275 97 125 76 180 167 12037.64 174 124 235 245 149 195 156 114 273 105 111 79 158 143 13637.66 129 116 199 199 142 185 173 110 215 103 107 77 142 150 106

303

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

37.68 112 102 223 179 129 160 160 91 178 102 86 58 119 126 9237.7 132 103 236 167 129 150 147 90 130 93 71 58 114 121 83

37.72 116 86 193 170 123 120 126 81 166 85 86 65 96 120 7937.74 106 98 200 117 138 115 125 88 141 86 78 69 98 99 7337.76 110 100 169 116 106 98 128 78 134 80 81 64 99 102 7437.78 89 99 191 116 118 100 114 85 126 79 68 74 112 105 72

37.8 89 64 160 103 91 93 120 82 91 80 61 67 71 115 6737.82 87 70 157 106 84 76 105 63 110 72 73 72 85 100 6837.84 78 92 146 89 91 81 87 67 100 73 75 48 98 100 7637.86 89 70 172 103 83 82 92 77 102 57 61 59 68 71 6137.88 87 76 173 90 77 80 112 62 93 92 59 40 74 101 67

37.9 90 79 147 87 83 91 112 65 101 73 66 49 74 91 6937.92 89 69 141 89 83 65 98 64 90 66 58 51 68 104 7537.94 67 61 128 95 84 80 94 57 94 79 68 56 64 90 5037.96 89 67 144 85 81 74 81 73 83 68 70 38 72 74 5937.98 85 65 142 78 85 80 95 65 95 61 57 69 64 88 73

38 84 67 122 93 84 69 94 77 99 60 64 57 81 80 5238.02 81 69 130 65 73 86 84 63 63 68 56 44 76 83 7038.04 65 63 118 91 77 73 89 55 72 58 36 39 71 93 6238.06 84 68 110 73 73 64 86 56 82 68 50 47 83 84 4638.08 83 61 136 71 87 84 80 54 73 41 62 54 54 84 63

38.1 74 62 117 79 89 60 78 62 65 69 55 63 62 68 5338.12 79 64 118 86 81 58 75 75 63 62 56 80 77 93 6638.14 63 67 124 82 64 79 106 49 76 55 40 63 69 69 6238.16 57 73 109 101 71 51 91 63 66 79 48 46 62 71 6438.18 64 53 114 76 80 71 83 76 77 74 55 53 76 96 64

38.2 70 58 129 78 65 67 80 54 76 75 66 41 72 84 5438.22 76 59 111 61 71 79 76 70 79 58 47 48 74 88 6738.24 70 56 137 72 85 61 73 74 83 57 41 41 56 88 6238.26 76 66 111 64 86 70 79 52 83 71 56 71 54 75 4438.28 88 56 120 70 92 53 84 75 76 79 57 46 80 82 68

38.3 72 45 124 84 101 64 91 70 79 75 51 74 51 100 6238.32 58 46 113 71 89 57 78 66 70 61 57 48 63 90 7038.34 69 60 95 67 91 66 70 67 79 56 59 48 77 90 6338.36 80 59 127 74 99 83 83 51 84 58 62 33 79 98 7538.38 81 67 108 52 79 74 88 54 77 62 52 53 74 104 58

38.4 79 47 119 69 114 66 81 51 69 60 52 42 82 95 7638.42 71 56 106 59 82 87 94 65 75 74 55 47 77 95 6538.44 73 52 122 66 91 83 82 62 80 58 44 61 72 107 6338.46 62 52 116 74 86 76 79 59 84 49 63 54 87 84 6338.48 68 66 130 69 84 75 91 59 72 55 54 45 69 94 76

38.5 66 58 135 60 100 79 77 59 97 66 64 62 59 119 72

304

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

38.52 78 54 108 75 78 55 94 62 84 67 58 38 61 114 5138.54 63 68 115 72 92 64 92 65 76 64 48 54 80 136 6438.56 80 59 118 66 85 82 84 69 78 74 62 53 69 136 8438.58 61 59 104 76 92 75 90 74 69 64 62 46 59 184 80

38.6 72 66 110 75 101 68 72 66 62 57 67 48 64 185 9438.62 69 67 109 66 83 55 84 64 75 69 51 74 55 187 9238.64 78 62 124 58 101 57 83 78 84 48 63 49 58 238 6438.66 83 67 122 71 88 82 79 54 77 60 58 52 73 238 8238.68 78 47 124 76 88 75 88 76 70 65 58 57 83 197 78

38.7 67 59 103 63 98 80 75 60 79 66 61 60 74 180 7638.72 71 71 107 72 69 95 80 67 79 51 61 35 61 160 7238.74 75 66 124 60 75 66 85 67 70 58 57 56 79 168 8138.76 84 69 106 62 60 68 83 66 59 54 68 59 60 147 6638.78 70 68 128 72 59 57 77 61 77 58 57 44 70 150 79

38.8 69 69 115 59 84 55 84 68 70 56 61 52 58 129 7138.82 87 77 129 77 73 68 85 68 65 71 57 67 62 122 5638.84 64 65 121 57 57 61 80 74 80 58 46 61 73 103 7138.86 58 64 114 56 74 53 71 63 69 56 61 60 63 110 5238.88 57 68 110 71 73 77 64 72 78 59 72 66 75 91 83

38.9 76 53 112 69 92 63 93 70 68 54 58 36 73 79 6638.92 77 57 115 71 68 79 78 72 67 45 47 49 67 92 7438.94 82 74 125 70 70 63 89 70 79 68 46 48 79 94 5638.96 65 63 98 75 80 62 72 53 85 69 57 53 82 78 7138.98 66 56 111 72 65 69 89 83 79 72 64 41 62 89 64

39 84 66 107 64 60 77 87 62 90 66 57 71 71 72 7239.02 79 66 107 89 59 61 82 62 78 71 56 54 73 69 6139.04 65 61 111 77 77 76 80 72 91 55 70 54 75 90 6839.06 87 49 115 63 67 69 84 60 77 76 70 53 65 92 6039.08 86 62 107 75 72 55 94 70 95 75 76 63 67 83 55

39.1 85 64 103 73 81 70 75 75 81 68 68 47 74 81 6139.12 87 71 119 66 87 74 94 74 75 51 53 66 70 73 5839.14 75 60 110 57 82 79 83 89 63 58 66 65 69 94 6339.16 77 59 102 68 89 76 86 98 81 73 65 60 64 88 6439.18 86 54 105 90 102 75 96 104 98 80 68 60 68 76 54

39.2 96 37 125 68 83 74 87 112 79 61 53 64 73 94 7439.22 88 61 124 66 96 79 84 129 84 68 66 58 67 93 8239.24 80 54 130 75 102 95 88 127 95 78 65 62 58 88 7739.26 81 48 95 69 111 104 88 146 76 78 61 66 72 79 6639.28 79 55 133 76 106 77 119 162 91 82 63 72 84 90 59

39.3 79 58 119 81 96 68 94 190 112 72 62 71 63 101 7539.32 83 60 116 72 114 82 106 205 96 90 61 76 82 83 8039.34 96 72 136 78 117 90 108 172 107 96 72 89 83 97 78

305

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

39.36 82 77 152 68 122 113 118 235 106 120 85 89 85 103 10639.38 97 79 149 99 125 116 132 206 117 118 109 90 72 107 102

39.4 90 102 192 68 154 114 132 230 137 148 109 129 60 118 18239.42 110 100 246 99 175 114 197 199 136 188 127 135 69 98 17639.44 105 119 276 100 199 124 214 169 161 195 121 104 101 99 17439.46 162 105 331 99 209 156 252 155 174 198 116 95 85 115 15539.48 171 84 236 112 252 159 263 153 198 178 104 86 68 109 186

39.5 157 68 189 112 316 169 262 154 199 138 82 63 77 112 15439.52 134 79 178 133 223 177 245 135 210 129 100 77 71 120 15239.54 103 73 212 127 258 196 224 152 206 125 94 69 89 125 13039.56 107 82 202 132 192 173 213 135 242 123 77 82 78 105 11339.58 117 69 159 112 176 191 220 122 234 102 70 53 88 122 120

39.6 124 65 122 105 184 202 186 89 260 81 78 73 80 85 8339.62 97 73 135 104 161 232 186 112 247 76 74 63 82 97 8039.64 97 49 115 90 139 223 190 99 249 66 57 63 73 82 5939.66 82 59 115 94 113 214 138 97 226 89 74 49 69 84 7239.68 90 58 141 109 102 178 147 101 198 56 70 55 72 87 60

39.7 89 68 128 84 97 204 139 93 235 88 67 70 82 91 5939.72 93 59 138 99 76 191 126 79 228 55 64 67 79 83 6239.74 91 75 130 89 88 193 126 96 213 76 65 58 81 89 6139.76 77 76 120 102 96 152 113 97 180 63 67 80 71 102 7739.78 85 72 122 82 76 157 89 88 170 63 75 52 60 84 58

39.8 93 57 136 82 85 148 93 96 182 84 52 45 84 103 7839.82 98 52 145 80 81 134 98 83 160 62 59 49 85 80 5239.84 84 55 132 83 88 119 84 83 152 80 64 61 77 85 6239.86 69 82 115 83 88 116 103 70 126 59 72 41 78 111 6139.88 76 59 117 79 89 113 106 83 137 57 54 57 74 95 65

39.9 72 58 124 83 86 113 109 78 121 75 52 65 81 82 5339.92 85 58 107 89 92 116 112 92 123 61 44 62 77 83 7139.94 81 69 107 89 88 119 91 80 110 60 57 61 67 87 5739.96 94 64 137 75 94 91 97 88 139 76 76 63 75 96 5939.98 77 80 117 100 75 91 100 90 111 70 77 79 59 75 66

40 87 61 101 94 98 110 97 88 113 91 73 78 76 79 7040.02 78 61 121 81 86 99 94 83 98 59 72 54 67 103 6140.04 71 71 124 76 97 95 86 73 92 72 67 67 66 112 6340.06 77 69 100 81 93 91 90 79 111 77 60 70 71 78 6740.08 83 68 129 75 101 102 91 81 101 73 63 41 67 81 79

40.1 74 73 120 67 85 99 110 86 95 75 85 54 67 84 7940.12 87 67 107 80 94 100 118 68 99 86 60 64 82 109 7240.14 86 73 123 84 83 87 109 75 117 65 81 53 82 121 7540.16 91 75 117 89 85 89 118 108 96 85 93 63 68 87 7840.18 76 73 135 74 102 103 120 92 98 86 60 78 87 99 84

306

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

40.2 78 83 152 92 100 98 128 77 84 87 93 83 73 111 8540.22 75 78 155 95 102 85 146 75 96 94 82 83 83 109 8940.24 100 88 155 79 131 96 140 84 97 94 82 69 74 103 9440.26 87 93 163 102 115 112 135 98 122 95 86 60 98 110 10140.28 107 93 113 97 128 117 149 112 101 94 106 76 86 118 118

40.3 124 85 120 114 113 115 151 103 110 82 91 61 94 101 11740.32 95 77 134 115 124 115 164 119 109 103 84 57 90 113 9840.34 108 63 117 100 111 98 137 119 103 116 83 79 109 131 9340.36 94 70 124 127 101 118 149 106 112 89 87 61 94 101 9840.38 97 92 141 95 102 113 117 133 125 100 106 63 84 117 95

40.4 120 94 143 121 114 112 145 125 113 94 86 67 109 110 10040.42 126 70 138 102 105 98 151 113 126 92 87 85 97 112 8940.44 84 81 120 96 116 109 140 105 119 94 116 84 106 133 9740.46 97 69 136 104 95 117 137 121 127 82 94 82 86 128 10140.48 100 71 137 121 126 104 134 135 107 89 105 98 117 104 92

40.5 118 59 115 122 119 92 144 152 125 116 112 109 116 134 9440.52 115 91 123 110 109 118 139 183 139 99 90 89 117 145 10740.54 107 86 126 131 108 110 146 171 153 113 106 87 112 143 10040.56 114 65 118 119 125 122 143 193 128 114 122 81 101 139 10540.58 140 82 137 117 108 120 154 195 133 105 128 84 107 119 108

40.6 114 94 149 137 132 153 165 218 162 139 119 79 120 138 13340.62 125 89 167 144 153 127 181 258 160 141 123 132 144 145 13340.64 126 107 145 141 160 130 182 267 181 146 134 111 128 166 14340.66 119 96 175 161 161 158 204 308 157 163 164 128 162 169 13740.68 167 101 183 159 162 169 205 348 211 161 148 117 163 208 158

40.7 152 124 201 160 190 170 250 375 232 182 180 166 196 217 16640.72 173 123 198 185 167 188 272 459 213 195 210 150 192 248 19240.74 160 166 205 208 184 206 306 492 265 215 247 161 156 263 19440.76 216 135 203 230 220 228 312 542 242 242 251 181 213 310 26440.78 230 167 198 234 248 221 377 598 324 268 262 224 212 341 242

40.8 268 146 206 294 262 272 403 651 336 300 310 270 239 367 29040.82 252 230 220 274 317 317 418 767 356 299 367 259 274 441 31040.84 278 207 246 350 348 369 463 881 385 339 395 289 330 429 36040.86 335 223 237 382 394 406 547 1080 454 427 499 338 347 421 40840.88 392 254 231 397 462 455 634 1277 518 471 593 436 401 431 458

40.9 395 304 249 473 534 519 740 1435 649 494 659 436 432 498 53340.92 451 373 291 576 641 595 835 1683 650 624 794 548 484 540 61340.94 571 418 313 647 739 694 1000 1945 803 743 1029 677 529 607 68940.96 624 503 390 747 889 767 1193 2140 901 886 1279 850 701 728 91040.98 775 682 482 859 1090 1019 1370 2367 1067 1083 1603 983 885 888 1186

41 887 800 565 1092 1284 1184 1633 2605 1291 1511 1778 1304 1017 994 146541.02 1121 1085 806 1299 1508 1355 1919 2738 1559 1982 2069 1739 1342 1263 2028

307

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

41.04 1433 1454 963 1632 1667 1600 2164 2896 1753 2455 2325 2076 1665 1664 264541.06 1803 1866 1234 1913 1901 1994 2474 2751 2213 3202 2911 2532 2141 2116 334141.08 2415 2269 1441 2229 2175 2337 2734 2710 2438 4001 3279 2925 2821 2732 3956

41.1 3262 2614 1671 2560 2552 2674 2798 2613 2795 4383 3360 3033 3506 3387 434141.12 4046 2724 1896 2958 2955 2967 2845 2406 3019 4472 3356 3062 4283 3890 413441.14 4886 2565 2032 3324 3185 3182 2806 2112 3128 3952 2905 2571 4842 4005 357441.16 5133 2173 1827 3560 3189 3215 2682 1889 3260 3394 2579 1890 5097 4013 311341.18 5097 1813 1709 3428 3155 3124 2514 1630 3142 2833 2217 1349 4943 3629 2510

41.2 4547 1725 1440 3425 2958 2987 2232 1452 3004 2642 2070 833 4445 3408 243541.22 3831 1517 1262 3223 2635 2743 2019 1237 2954 2350 1734 607 3783 2978 206141.24 3323 1254 1065 2912 2235 2498 1780 1047 2603 1893 1402 325 3179 2504 158041.26 2936 1001 962 2693 1900 2215 1529 892 2446 1414 1141 298 2774 2133 122241.28 2633 722 795 2366 1651 2004 1333 713 2199 976 890 255 2440 1821 868

41.3 2072 528 566 1948 1404 1754 1065 618 1827 710 629 281 1904 1417 63041.32 1547 357 422 1582 1132 1458 952 521 1496 609 493 250 1411 1089 50341.34 1097 302 358 1427 836 1113 789 465 1220 454 432 329 1001 832 43341.36 789 278 309 1160 644 925 701 328 1076 405 341 277 769 669 35841.38 615 224 243 936 523 723 559 328 926 331 320 246 577 519 294

41.4 508 180 212 759 422 655 522 315 762 295 286 190 456 453 25041.42 428 179 177 619 374 515 415 249 638 234 218 153 365 359 22841.44 344 153 165 509 283 407 423 222 496 220 203 109 321 327 20341.46 281 115 141 455 259 337 360 217 494 202 196 61 315 268 16641.48 227 123 129 359 261 297 318 175 372 166 157 72 245 240 189

41.5 216 110 135 285 181 255 272 155 388 142 134 75 222 207 13041.52 174 84 144 287 187 225 261 135 274 157 163 71 207 171 13641.54 171 109 125 274 173 206 188 124 285 129 143 108 159 160 11941.56 167 86 115 204 167 176 197 132 259 107 120 120 135 171 10741.58 156 94 111 208 162 187 189 137 241 102 136 109 155 151 89

41.6 140 76 127 165 130 148 194 109 186 113 123 74 130 158 10641.62 130 81 132 147 133 171 168 112 194 133 109 101 131 136 10441.64 116 97 119 142 132 117 168 94 182 98 116 60 101 134 8641.66 106 90 107 154 110 122 169 99 180 113 109 41 114 124 8141.68 119 70 120 123 111 122 128 84 143 99 124 56 105 130 94

41.7 109 80 114 139 96 123 138 88 161 109 77 72 111 107 8141.72 106 91 130 120 111 119 120 79 138 89 84 77 100 117 9541.74 92 66 132 113 114 99 112 88 116 95 90 73 98 118 8141.76 96 88 105 113 101 90 115 82 126 85 72 66 103 98 7741.78 91 86 117 113 113 100 106 96 116 82 87 84 88 111 75

41.8 87 72 105 91 93 99 108 72 120 84 70 67 79 114 9041.82 88 71 122 105 85 86 108 77 110 78 75 51 103 109 5941.84 91 64 99 89 80 79 98 64 97 111 95 70 84 105 8541.86 92 76 98 91 91 72 114 72 91 81 97 75 84 119 70

308

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

41.88 92 70 97 100 83 71 95 70 96 82 82 55 83 93 8141.9 72 79 104 96 78 89 98 62 80 84 68 60 84 103 73

41.92 100 66 122 95 93 84 107 79 81 80 79 63 86 101 8241.94 93 77 123 82 79 66 116 95 106 80 61 47 100 93 6041.96 99 72 99 76 77 100 92 68 82 87 67 43 69 91 7641.98 89 71 130 87 85 87 104 72 94 78 85 42 67 102 68

42 83 64 115 73 73 62 83 68 86 78 78 70 86 85 5742.02 99 72 90 84 85 76 93 68 76 71 53 55 63 97 7142.04 83 61 129 57 84 68 90 82 96 72 83 62 95 84 8142.06 84 73 107 77 79 78 91 65 97 76 75 53 69 90 6642.08 73 66 105 88 57 92 94 68 87 61 64 61 71 80 75

42.1 61 55 109 77 81 68 88 59 79 71 62 44 89 83 7942.12 88 69 122 92 92 77 99 64 111 61 63 45 69 90 6342.14 82 63 103 74 78 70 103 63 81 86 63 47 68 92 6042.16 89 78 112 78 70 74 89 63 73 58 76 49 74 84 6842.18 82 72 97 76 86 73 99 72 71 75 72 58 73 86 61

42.2 79 63 111 78 74 73 101 72 59 66 55 48 73 96 5142.22 91 63 127 91 88 71 81 64 92 78 69 69 61 94 6642.24 75 68 105 67 79 61 83 41 84 72 77 47 65 82 7442.26 67 67 138 70 77 62 81 60 81 79 68 52 76 66 8242.28 84 60 109 84 89 73 106 82 97 68 50 51 66 93 78

42.3 74 65 111 74 90 70 87 69 80 81 64 35 86 98 6842.32 67 81 128 82 86 81 86 48 91 77 64 45 63 82 7242.34 69 82 164 89 93 96 107 76 94 84 68 55 73 104 8042.36 80 85 163 80 82 67 101 91 89 85 68 53 85 92 9042.38 83 113 148 89 88 84 124 69 84 69 69 58 81 85 99

42.4 76 86 168 93 101 94 131 68 66 80 59 48 84 115 11942.42 66 92 180 71 110 98 132 80 98 79 59 52 72 148 16142.44 69 91 181 84 115 112 144 54 76 88 63 46 90 131 16642.46 75 95 170 90 91 98 165 62 86 80 68 45 80 82 17342.48 94 90 168 75 94 100 176 66 84 73 61 52 76 92 154

42.5 69 102 162 94 82 97 148 67 99 88 48 57 89 95 9042.52 65 76 157 88 94 86 110 72 92 73 66 57 73 102 8342.54 58 73 135 84 91 85 119 72 86 58 59 55 75 97 10842.56 76 60 139 87 78 83 89 83 111 69 73 61 89 92 11242.58 78 71 112 82 85 81 106 61 73 62 72 56 80 95 93

42.6 65 63 111 75 78 68 100 75 81 56 63 70 100 85 8242.62 72 63 112 76 77 88 99 52 100 68 65 59 84 73 8142.64 71 63 108 79 84 67 101 58 79 64 58 58 83 94 6442.66 73 70 128 76 57 88 88 65 81 62 61 49 86 86 9042.68 62 71 109 77 80 60 91 68 77 64 54 52 81 87 54

42.7 64 62 80 77 67 67 105 76 88 67 59 52 93 91 64

309

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

42.72 72 79 97 74 77 61 66 84 73 72 51 55 75 94 7842.74 57 67 104 70 72 63 73 67 79 76 65 42 82 82 7642.76 98 66 100 71 80 74 90 77 76 73 62 49 82 93 7042.78 90 67 113 82 76 74 86 82 77 59 57 66 76 81 61

42.8 64 49 88 64 66 75 82 97 73 66 67 69 88 82 5942.82 82 54 84 60 69 69 94 91 92 64 65 49 84 78 6042.84 62 47 82 73 62 79 86 79 79 62 69 62 103 84 6442.86 73 62 95 76 85 76 90 77 76 80 65 65 80 70 7442.88 77 56 103 78 83 70 82 79 93 72 64 58 71 78 61

42.9 68 45 79 85 76 67 81 97 76 64 63 44 81 79 7342.92 68 59 100 83 74 76 80 99 97 90 75 55 97 88 7442.94 69 43 95 71 86 77 102 98 74 82 73 60 104 88 5442.96 78 51 75 77 92 79 82 113 87 65 65 69 99 93 6742.98 86 57 83 94 78 86 97 102 90 72 61 56 91 85 67

43 87 66 98 77 78 76 80 120 84 85 63 61 91 90 9243.02 94 55 97 66 61 91 107 156 99 74 74 74 102 95 6043.04 83 40 77 79 88 79 92 167 79 85 67 78 70 76 6543.06 84 53 84 58 92 101 100 164 106 112 71 59 85 82 7343.08 93 72 94 104 84 89 104 197 76 103 84 104 87 102 79

43.1 84 40 91 76 85 86 109 213 101 117 87 148 81 112 7243.12 83 44 77 74 93 79 102 202 111 145 84 120 89 107 8643.14 92 63 110 78 103 110 86 177 117 185 89 113 78 92 8543.16 102 59 93 71 103 112 120 170 99 241 98 104 73 84 8543.18 94 62 91 107 121 101 143 153 131 271 119 100 80 100 112

43.2 103 34 106 77 153 94 131 170 139 214 149 88 78 104 10343.22 99 62 99 111 148 107 138 164 133 165 136 78 76 110 11043.24 95 56 78 107 162 128 142 180 161 169 125 79 93 111 10843.26 97 66 81 95 148 119 168 144 168 150 103 72 61 93 11643.28 122 50 92 101 130 140 186 133 181 168 116 58 90 121 131

43.3 123 73 94 112 135 123 174 158 200 161 104 63 71 131 14243.32 98 69 87 115 144 150 169 113 208 125 107 68 81 130 14443.34 90 54 99 109 119 156 183 121 246 87 107 77 82 145 10943.36 106 57 113 122 110 160 154 125 210 115 96 56 89 182 10843.38 98 63 98 98 110 179 158 140 242 108 83 71 81 156 116

43.4 106 58 93 88 103 189 140 138 207 114 77 65 85 171 10943.42 96 67 93 114 111 170 148 154 238 98 83 78 92 120 9143.44 107 58 97 93 94 191 170 184 239 89 91 102 101 124 8943.46 106 72 114 82 108 222 157 174 244 100 81 95 87 142 10143.48 105 90 98 87 102 195 161 191 241 87 87 80 93 139 86

43.5 83 90 105 115 133 199 140 201 205 99 95 107 93 157 8043.52 113 87 108 118 124 209 154 223 201 116 102 100 114 128 7843.54 127 85 108 131 112 182 155 253 196 105 131 79 108 140 109

310

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

43.56 128 85 115 108 112 189 151 237 227 121 122 109 129 113 12143.58 136 91 120 138 153 201 185 295 200 124 145 99 120 130 150

43.6 150 95 120 161 160 195 185 341 248 144 164 151 151 140 12643.62 131 126 128 164 177 204 210 337 213 168 185 160 156 161 16243.64 165 136 150 195 210 245 238 434 250 204 224 188 166 177 19143.66 195 145 151 228 216 228 241 400 250 255 268 231 197 210 21643.68 215 160 160 248 257 292 290 422 312 308 291 261 231 281 307

43.7 273 259 228 266 270 300 367 474 355 372 376 333 281 318 36643.72 349 306 218 305 316 323 374 449 350 500 387 368 326 363 47543.74 403 397 285 360 327 386 423 469 376 582 504 430 425 466 57243.76 528 391 316 428 407 393 432 454 438 683 511 492 573 511 60943.78 612 409 331 503 504 434 411 402 457 665 573 530 709 590 613

43.8 762 417 332 529 491 472 465 387 505 643 522 464 706 692 61743.82 794 358 315 542 544 509 410 352 508 543 469 382 742 703 50843.84 758 298 340 547 533 505 434 334 467 466 446 272 769 664 43943.86 717 305 280 557 457 466 359 320 466 430 353 160 683 597 38443.88 598 292 286 491 419 473 367 247 468 443 339 194 624 504 360

43.9 545 233 262 488 431 403 365 218 458 364 299 96 586 430 31343.92 526 212 215 448 363 356 315 194 434 298 274 123 476 399 27143.94 412 180 215 393 322 375 264 194 371 249 207 99 466 377 22743.96 394 155 182 377 317 315 253 145 365 194 184 103 407 354 17343.98 325 122 153 336 215 289 256 148 314 160 148 111 297 242 160

44 287 97 126 288 216 248 193 164 289 145 143 111 253 205 13644.02 215 92 115 255 186 235 178 128 245 135 100 101 206 183 11944.04 158 100 129 243 163 173 177 126 236 103 123 74 171 124 10644.06 172 70 126 199 130 197 181 120 194 128 103 95 134 133 10744.08 164 85 104 172 110 143 146 110 189 105 100 72 126 124 74

44.1 133 67 96 142 133 153 153 103 154 85 96 41 129 137 9244.12 114 76 113 155 100 131 154 113 152 118 89 74 123 118 8844.14 121 77 91 147 118 135 116 96 173 93 110 63 100 120 10144.16 95 80 101 125 101 114 151 118 135 94 101 57 94 101 8144.18 112 65 102 117 102 107 133 102 118 87 108 81 111 101 80

44.2 85 65 110 95 91 117 104 118 132 87 80 78 98 110 8644.22 99 65 79 107 93 106 145 96 138 97 99 85 109 96 7444.24 98 73 99 101 103 85 119 92 121 91 93 72 84 113 7444.26 98 69 89 106 98 97 133 86 127 69 84 81 87 101 9244.28 89 66 87 95 108 100 119 128 107 82 90 79 86 99 87

44.3 88 77 95 96 103 96 126 103 105 95 95 65 95 101 7644.32 89 60 92 102 95 83 132 115 109 101 88 59 111 97 6844.34 99 68 102 101 103 84 140 125 122 99 107 80 97 116 7644.36 102 57 106 92 98 90 131 131 102 88 92 74 76 100 9644.38 83 49 91 108 91 67 110 123 122 94 121 69 98 91 88

311

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

44.4 94 70 82 89 100 101 131 129 126 98 99 67 107 124 9544.42 105 69 108 88 95 97 119 130 113 94 99 92 102 115 8144.44 99 66 92 115 102 96 130 149 102 107 122 104 112 102 9444.46 100 67 87 127 90 110 153 213 114 107 120 85 105 122 9444.48 92 53 94 109 97 117 165 185 126 115 126 80 82 117 95

44.5 107 88 97 145 119 127 165 204 151 121 106 107 109 116 11044.52 115 74 84 148 124 116 153 205 138 138 129 97 121 132 12344.54 107 52 140 126 145 127 185 223 158 156 153 107 130 135 12244.56 139 77 96 139 127 140 200 235 163 132 172 144 137 129 13844.58 128 97 109 149 168 139 220 305 181 155 195 133 124 134 161

44.6 155 92 103 168 172 173 263 332 173 177 209 158 174 166 16144.62 170 121 98 191 185 186 268 433 213 191 209 149 192 178 17444.64 152 122 114 195 179 179 308 407 219 192 238 159 207 203 21244.66 197 146 152 226 235 180 251 539 253 225 262 184 200 203 22944.68 194 147 157 256 221 224 323 593 288 247 288 170 234 222 237

44.7 234 204 132 276 289 261 410 679 317 276 378 193 250 248 25644.72 268 209 171 286 367 294 471 830 340 294 427 259 287 271 32644.74 295 225 196 348 420 323 517 934 406 339 524 337 291 304 34644.76 298 248 217 387 484 400 632 1081 476 435 703 447 342 348 44344.78 365 348 253 463 561 443 738 1259 549 594 774 531 358 431 597

44.8 446 397 324 534 697 533 879 1407 625 668 966 655 507 456 74744.82 528 557 385 642 774 646 974 1429 658 940 1096 863 628 614 92044.84 666 687 498 836 909 804 1130 1560 901 1202 1306 1031 797 846 123944.86 885 927 649 917 936 1021 1337 1508 1129 1544 1557 1217 1059 1036 169444.88 1109 1148 778 1140 1145 1193 1449 1519 1213 2017 1831 1459 1435 1407 2043

44.9 1487 1375 861 1425 1326 1307 1494 1300 1425 2217 1913 1765 1877 1681 220044.92 2116 1350 1038 1632 1497 1409 1540 1289 1607 2161 1931 1597 2251 1967 220144.94 2456 1292 968 1697 1574 1682 1561 1150 1787 2008 1649 1374 2617 2089 179044.96 2730 1035 958 1873 1748 1668 1424 1124 1707 1642 1461 1085 2732 2146 148944.98 2819 937 862 1918 1641 1680 1305 991 1716 1432 1262 705 2402 2081 1281

45 2469 794 741 1806 1477 1527 1242 831 1562 1280 1105 427 2110 1771 120945.02 2038 752 691 1814 1276 1410 1100 716 1606 1190 946 261 1879 1527 114445.04 1680 731 642 1611 1170 1293 980 565 1426 1129 824 227 1610 1403 101345.06 1613 645 579 1447 1003 1154 933 480 1311 887 744 250 1502 1221 74045.08 1468 518 522 1299 938 1061 759 442 1241 730 548 166 1333 1044 569

45.1 1279 357 384 1177 763 899 641 363 998 512 435 154 1068 893 42845.12 1040 283 321 987 670 760 574 298 901 391 366 227 816 749 35345.14 771 221 269 879 485 615 505 254 758 336 292 231 607 582 28645.16 559 218 232 735 393 570 380 248 676 269 273 165 472 424 23645.18 430 159 203 597 308 430 335 207 520 254 193 147 418 366 217

45.2 350 159 192 497 284 402 323 173 464 224 197 159 328 300 17745.22 290 148 163 403 218 335 265 163 402 193 169 114 255 266 183

312

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

45.24 266 117 151 337 210 268 223 158 339 167 131 75 249 223 16745.26 218 95 169 268 186 240 229 139 289 171 111 46 230 193 15845.28 189 81 153 275 172 200 197 108 275 139 111 83 178 176 139

45.3 212 83 146 225 139 191 178 94 248 131 116 54 148 160 10645.32 183 78 157 200 146 152 149 122 228 96 105 61 135 159 10945.34 153 80 141 189 137 134 152 113 178 98 88 57 143 140 10845.36 143 92 138 170 117 137 118 81 142 99 99 72 125 118 11745.38 135 86 138 145 127 110 146 96 154 86 89 92 117 124 104

45.4 99 87 129 109 116 118 121 92 150 90 79 72 94 149 9645.42 110 74 139 123 110 118 112 87 128 80 84 78 84 108 11645.44 97 67 125 114 85 94 113 75 131 80 80 81 103 128 12345.46 82 66 121 111 71 86 100 80 119 75 76 60 99 121 10645.48 90 90 134 107 95 106 111 94 89 86 66 57 92 126 98

45.5 115 63 124 86 95 97 112 63 104 71 70 50 91 146 10545.52 90 83 153 95 89 76 95 67 96 82 71 53 79 129 8345.54 80 62 106 84 86 79 83 63 99 72 74 66 95 137 8945.56 91 64 113 101 96 73 82 76 98 80 75 56 91 100 7945.58 78 55 106 77 67 80 93 71 101 86 88 79 86 117 92

45.6 85 63 93 95 79 79 94 73 90 68 66 64 82 90 7245.62 79 59 102 90 64 85 107 69 99 69 68 61 86 91 8045.64 62 62 102 101 80 66 94 69 103 65 59 59 68 89 7745.66 85 58 95 85 91 74 107 90 89 87 60 60 93 106 6545.68 66 54 97 80 82 77 105 61 84 58 61 57 69 75 66

45.7 74 65 113 81 68 74 78 60 67 85 63 46 75 73 6745.72 72 83 120 74 92 63 108 76 92 82 56 56 75 90 7445.74 65 64 128 83 89 84 105 57 73 75 63 63 64 89 9445.76 66 67 136 69 90 76 97 59 75 61 76 67 66 86 8645.78 65 64 144 80 108 72 139 63 86 73 62 57 80 88 73

45.8 71 76 132 73 111 88 162 62 87 66 64 59 78 99 6845.82 72 57 117 77 107 75 99 66 78 83 59 69 61 93 7545.84 71 76 106 86 113 80 117 66 93 74 47 66 62 76 7145.86 63 60 97 65 86 75 105 65 83 72 55 58 59 88 7345.88 68 52 116 81 89 77 106 55 66 60 75 53 62 68 69

45.9 76 61 125 68 83 75 109 51 75 59 51 60 73 93 7945.92 81 64 119 73 73 68 115 53 85 52 56 66 83 90 6545.94 68 67 100 65 91 72 88 64 78 69 75 46 63 79 6945.96 72 69 97 65 57 60 70 59 59 68 58 45 59 85 5945.98 71 56 125 72 81 64 75 68 85 68 61 62 60 71 48

46 70 60 80 64 81 59 94 63 71 55 47 64 70 77 4846.02 64 58 99 70 78 64 76 52 66 62 53 55 55 71 5246.04 65 56 89 69 75 65 74 57 78 56 61 61 64 74 6846.06 48 60 110 60 70 67 70 66 79 58 55 58 54 69 54

313

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

46.08 74 53 95 62 72 60 65 42 62 48 53 61 74 72 7246.1 66 48 91 73 50 70 72 51 87 64 61 41 59 79 67

46.12 65 46 82 59 83 69 93 57 79 63 47 45 60 83 6146.14 68 46 86 66 74 59 76 74 62 67 62 53 57 73 5046.16 61 51 92 76 70 72 68 56 53 60 74 49 57 68 4846.18 65 48 88 68 57 75 83 45 74 56 65 45 87 74 65

46.2 72 51 71 61 73 62 75 61 59 66 63 64 86 68 4646.22 69 47 68 60 51 75 57 63 62 57 57 50 65 85 6946.24 68 45 88 74 68 60 72 63 71 53 55 52 49 69 5846.26 69 57 82 58 66 52 74 74 55 50 57 50 75 74 5246.28 61 54 80 67 69 66 79 62 62 69 59 61 55 56 51

46.3 62 56 71 59 61 55 67 53 73 64 56 71 59 89 6446.32 66 65 71 57 47 56 73 51 51 59 49 52 64 62 4646.34 62 59 75 55 73 57 57 53 80 63 56 51 57 62 6246.36 68 60 74 68 53 61 66 69 70 63 63 58 67 64 4446.38 57 50 79 61 75 54 94 67 77 59 50 65 67 56 48

46.4 64 44 57 71 66 62 58 58 76 69 65 56 69 71 5046.42 75 57 72 69 68 61 81 65 75 50 54 58 52 77 5546.44 52 54 71 65 73 69 63 69 61 55 55 57 57 75 5646.46 57 39 77 69 67 69 72 55 79 58 62 58 57 64 5546.48 68 44 69 49 73 54 76 58 78 51 53 44 59 66 52

46.5 59 44 75 55 62 69 77 53 76 67 52 51 52 82 6046.52 63 64 73 62 65 63 84 54 69 67 58 46 77 73 4546.54 50 52 63 59 62 73 78 49 86 64 62 64 55 85 4246.56 67 50 53 39 62 60 65 82 71 46 67 49 68 73 4746.58 53 40 74 57 66 51 66 64 55 57 58 45 52 61 46

46.6 66 52 80 72 64 58 77 79 72 44 61 60 61 82 6046.62 63 39 63 65 58 65 75 58 79 66 73 59 56 77 4046.64 57 50 62 70 69 60 84 57 68 68 59 62 66 78 4446.66 73 47 70 61 67 70 73 56 78 63 60 51 50 74 5846.68 53 46 80 70 59 65 95 57 80 68 66 49 71 81 57

46.7 70 55 73 76 74 72 69 68 61 58 60 51 56 60 5546.72 72 54 62 58 70 59 76 63 70 61 45 51 76 72 6346.74 65 48 59 74 60 64 86 65 89 80 66 52 75 77 5646.76 58 54 62 66 61 65 84 76 82 56 50 59 74 84 5446.78 76 39 64 67 66 58 88 60 76 54 54 53 62 76 62

46.8 67 47 69 65 66 62 86 60 68 56 54 58 61 95 6746.82 86 57 59 68 53 65 80 62 79 53 57 57 62 86 4746.84 72 61 59 57 68 69 102 75 62 78 63 46 64 83 5746.86 85 55 57 58 62 68 81 65 64 84 45 60 73 89 6246.88 85 64 61 58 80 63 74 73 77 79 44 61 52 83 52

46.9 67 61 72 64 65 58 79 76 75 78 60 58 65 80 53

314

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

46.92 77 59 63 77 104 74 78 63 70 78 72 57 67 79 5746.94 67 49 75 59 67 59 67 100 72 80 68 74 66 86 7346.96 65 47 70 63 71 69 79 89 77 81 76 61 62 80 6546.98 76 55 77 73 63 56 84 93 87 70 74 42 65 79 64

47 79 59 77 70 56 53 103 99 94 82 66 58 64 98 6847.02 63 56 82 65 56 66 73 77 53 92 54 75 76 69 5247.04 70 52 72 56 69 71 89 107 81 82 71 53 62 74 6647.06 92 47 59 75 69 87 76 92 67 94 66 71 78 90 5347.08 67 37 87 74 84 65 85 92 70 83 62 90 57 71 66

47.1 62 50 101 77 72 89 99 118 71 80 88 71 69 86 8547.12 55 53 84 68 75 80 96 108 89 96 64 76 61 73 6647.14 69 58 76 64 97 74 95 106 92 114 88 65 66 68 5747.16 81 53 79 59 70 85 88 105 87 90 72 79 69 92 8047.18 52 51 67 68 91 79 89 96 99 87 79 88 63 86 61

47.2 78 50 70 63 66 71 111 108 93 81 62 63 54 74 7547.22 91 52 65 63 82 86 106 112 105 76 69 67 55 85 7847.24 80 53 82 63 83 74 108 104 97 92 69 64 75 80 8847.26 74 54 96 72 88 88 104 127 115 67 65 63 60 78 7047.28 92 49 92 72 83 73 117 133 112 87 76 61 71 84 74

47.3 63 61 112 86 89 79 95 132 122 66 98 66 78 78 6647.32 62 61 79 79 99 105 113 147 127 72 71 74 66 90 7247.34 74 42 115 84 77 117 107 165 97 74 76 75 79 85 7947.36 72 59 96 68 92 97 116 177 102 75 73 82 62 85 7047.38 83 53 109 74 60 92 90 198 103 69 65 85 79 79 78

47.4 81 46 105 68 94 104 78 197 118 73 65 73 72 88 8547.42 86 50 93 64 79 131 108 226 133 96 68 80 54 75 5947.44 80 51 89 68 96 109 87 223 99 106 73 93 65 65 6347.46 55 45 103 63 73 115 81 204 118 122 95 126 64 79 5847.48 81 54 76 69 104 101 97 209 143 103 87 123 58 77 83

47.5 84 49 90 72 92 105 108 191 108 119 116 101 72 77 7347.52 79 64 73 72 108 101 112 185 122 129 88 87 70 73 6447.54 91 51 83 88 114 128 121 202 137 111 86 104 76 83 8847.56 84 51 71 79 120 118 123 176 133 128 80 101 69 79 7147.58 95 50 74 81 110 111 123 151 116 139 77 101 55 87 83

47.6 62 45 58 96 125 99 136 141 145 97 83 78 68 69 10647.62 72 50 70 108 114 113 141 161 150 122 95 85 66 76 8647.64 70 59 63 81 110 136 157 131 172 95 80 69 71 73 9847.66 84 54 65 95 105 120 140 113 180 94 82 55 77 65 8747.68 92 45 65 89 101 132 150 103 169 93 77 60 64 84 75

47.7 72 41 65 90 103 145 170 109 184 94 67 65 60 65 7947.72 78 40 62 73 107 136 143 96 198 61 61 46 65 78 6847.74 65 60 71 83 86 125 147 103 203 75 63 60 64 74 57

315

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

47.76 72 44 65 98 92 158 138 110 200 76 60 53 69 82 6747.78 77 62 73 90 64 171 147 94 201 68 67 69 79 71 57

47.8 79 44 71 75 105 167 133 110 195 57 59 63 65 75 5647.82 82 42 56 89 81 172 140 73 181 67 67 49 58 77 6247.84 79 43 68 81 83 173 123 113 181 60 50 73 88 60 5547.86 82 50 68 79 93 155 127 77 176 63 71 66 64 64 6247.88 67 42 86 66 63 164 112 97 160 59 61 68 51 72 66

47.9 86 49 71 83 69 154 111 77 162 73 53 60 55 77 5947.92 64 55 73 76 78 144 110 76 152 60 60 52 55 78 6247.94 69 44 94 83 82 140 115 87 162 51 60 65 51 73 6147.96 57 53 80 61 54 137 103 70 125 62 59 59 49 68 6147.98 68 56 80 79 90 143 94 87 141 78 67 59 54 79 58

48 64 52 103 75 73 139 108 84 126 82 69 68 63 84 5948.02 72 50 84 65 73 125 91 90 167 60 57 59 72 67 6048.04 62 45 96 70 68 142 97 87 133 66 72 62 51 64 5748.06 85 45 84 66 72 110 89 88 134 51 76 47 69 74 6948.08 79 55 83 75 86 110 94 84 140 51 59 73 67 76 67

48.1 66 53 86 79 62 121 72 78 111 67 64 55 52 86 5948.12 69 63 93 79 82 107 82 85 106 57 72 57 64 64 6148.14 68 51 85 56 66 86 71 95 91 64 78 58 69 85 5648.16 78 42 94 59 66 88 74 85 88 81 72 68 81 85 7248.18 70 50 83 56 84 104 96 92 123 65 71 74 76 88 71

48.2 80 54 81 69 72 99 88 90 109 58 69 70 67 72 6148.22 67 51 82 76 71 88 84 98 116 55 89 56 59 81 6148.24 63 49 91 59 76 78 105 116 97 60 72 69 66 73 6348.26 66 43 70 66 87 99 97 121 104 89 66 81 66 75 6448.28 82 59 76 66 79 84 89 105 131 72 94 82 65 81 61

48.3 61 32 75 92 73 93 77 121 124 91 68 74 60 74 7748.32 89 46 58 71 71 67 85 129 87 72 66 73 84 75 6348.34 83 61 55 72 87 81 95 169 100 80 87 64 81 88 6948.36 68 51 74 72 66 94 82 157 109 83 97 71 58 87 7948.38 72 45 71 76 76 84 106 169 83 92 84 68 68 88 78

48.4 78 45 66 78 79 91 124 196 124 109 71 71 74 85 7348.42 68 59 68 74 72 93 93 238 109 102 91 98 84 96 8448.44 80 52 55 87 98 107 105 236 111 110 88 78 62 92 7148.46 97 43 63 66 104 93 108 209 111 120 97 89 67 96 8348.48 78 46 61 90 97 79 123 216 105 146 116 101 84 105 83

48.5 81 39 48 80 115 102 123 208 132 165 106 108 72 96 9748.52 95 32 75 74 116 103 111 211 134 180 113 111 73 105 8848.54 89 45 57 96 106 84 123 176 139 179 138 88 73 100 10148.56 79 42 69 79 123 107 131 187 149 155 135 115 76 98 10348.58 77 51 66 100 120 119 125 164 154 154 124 110 52 114 111

316

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

48.6 92 51 66 91 135 117 138 159 162 138 101 102 85 117 12248.62 79 35 66 107 120 119 161 152 176 136 105 91 86 139 10948.64 90 54 64 91 116 151 166 130 189 127 98 78 88 142 13448.66 86 49 65 121 124 140 165 154 177 132 116 82 74 143 10048.68 72 54 56 110 125 140 169 151 204 112 91 80 88 187 118

48.7 89 53 65 107 119 159 177 133 202 123 111 88 92 154 13148.72 90 57 66 80 115 185 181 139 252 95 108 69 79 161 11348.74 83 47 52 102 101 163 182 142 258 109 94 70 83 175 9948.76 97 58 55 96 86 193 171 155 223 90 88 84 66 176 15248.78 98 57 63 105 107 188 173 124 196 92 87 79 88 142 119

48.8 95 43 83 111 97 185 181 107 235 99 98 72 85 137 11448.82 91 63 75 113 113 158 167 123 240 93 100 95 84 131 10648.84 92 70 72 106 100 175 145 146 237 91 114 95 82 131 10648.86 88 52 79 120 95 191 140 166 226 107 75 80 88 150 8548.88 88 61 63 116 123 181 159 166 215 102 102 90 82 142 102

48.9 90 58 69 107 111 182 169 148 209 94 97 94 100 124 9548.92 103 51 73 99 112 178 165 201 229 117 102 86 103 137 10848.94 95 59 84 131 118 173 151 194 220 119 125 101 115 129 9748.96 106 52 72 112 133 180 189 192 245 115 122 87 124 124 13448.98 104 65 74 100 113 200 165 203 217 108 148 117 111 130 127

49 105 89 86 122 123 171 192 219 207 139 158 100 107 123 11349.02 128 86 99 120 146 197 213 199 224 129 158 106 119 148 13449.04 114 87 87 142 176 207 198 242 231 128 174 121 140 153 14049.06 148 94 103 180 162 179 232 268 237 145 209 158 130 181 14549.08 164 110 114 164 204 214 260 316 241 193 206 160 132 178 179

49.1 162 117 122 204 203 215 257 351 255 221 249 154 181 207 18249.12 165 136 135 207 232 199 251 342 289 223 275 225 186 208 23949.14 160 131 147 236 211 235 286 353 278 259 312 242 219 213 26749.16 218 183 183 260 251 323 316 340 318 344 343 282 225 267 31249.18 253 220 184 284 305 320 322 386 357 403 353 313 263 337 355

49.2 305 253 201 335 328 286 341 352 373 507 420 346 338 372 42249.22 337 311 257 354 330 357 383 355 371 597 462 440 448 430 53449.24 413 304 248 378 354 363 372 358 384 624 492 493 487 478 55349.26 527 350 253 419 396 383 351 321 389 572 471 390 575 576 61149.28 630 343 299 435 420 424 395 320 434 578 471 439 653 578 515

49.3 667 324 280 466 452 411 371 345 483 513 414 336 714 587 46449.32 663 323 287 456 450 414 382 304 433 445 369 306 659 539 42849.34 636 269 257 504 419 399 367 287 385 431 352 228 620 472 36049.36 616 258 224 455 413 430 322 264 385 364 357 142 557 474 32949.38 524 215 195 443 387 365 354 224 451 337 296 130 499 427 333

49.4 493 217 180 426 362 339 320 233 361 312 260 133 410 426 31649.42 422 192 186 404 304 356 276 220 420 290 277 116 403 340 244

317

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

49.44 434 169 157 406 326 304 251 213 374 243 190 120 402 326 20249.46 359 126 145 343 255 276 232 196 340 197 196 121 324 274 17349.48 345 132 124 330 249 294 249 166 284 153 159 107 286 244 145

49.5 307 91 128 296 226 250 204 144 244 153 161 102 207 190 17149.52 209 87 89 243 185 211 227 162 267 140 142 95 201 192 13649.54 191 76 78 233 136 193 214 155 250 136 134 98 167 164 13849.56 163 84 83 205 154 169 198 134 251 136 122 85 149 144 11449.58 161 70 91 192 144 192 175 156 196 130 113 93 139 131 119

49.6 134 75 81 182 146 151 176 146 209 119 133 79 134 130 11249.62 144 70 104 165 123 158 165 137 182 116 120 102 122 136 10549.64 121 64 86 153 116 143 171 123 194 97 130 97 128 116 11049.66 107 63 91 138 115 147 170 118 177 94 113 120 114 104 10949.68 110 59 88 156 129 149 175 114 142 94 118 102 109 100 94

49.7 91 53 73 125 124 139 174 135 155 138 123 80 112 113 7949.72 94 59 80 138 116 126 168 120 138 107 128 102 109 118 10749.74 101 71 89 104 119 122 163 131 143 106 137 81 93 97 9449.76 96 64 92 111 98 106 172 112 142 117 113 96 98 94 8749.78 102 69 87 129 94 106 155 125 130 94 124 93 94 108 82

49.8 104 51 101 121 108 130 145 116 147 98 142 89 129 111 9849.82 83 65 74 104 110 110 159 138 158 105 124 110 110 105 11849.84 99 70 95 124 112 109 180 146 123 113 131 111 118 114 8149.86 99 59 82 122 133 121 158 117 161 115 157 127 105 107 8649.88 93 70 123 107 119 104 177 155 118 114 122 91 102 116 101

49.9 102 73 103 114 126 133 164 168 153 128 146 135 139 103 10749.92 117 66 107 132 140 110 177 162 165 127 148 115 111 121 13249.94 95 67 92 122 132 103 187 191 138 142 163 120 106 118 11049.96 111 76 115 116 113 137 200 174 176 135 135 115 122 134 13849.98 99 80 112 138 141 149 204 206 177 150 174 111 127 139 130

50 109 74 112 139 149 117 224 244 197 140 197 108 121 120 14750.02 117 80 154 133 139 163 226 256 159 164 175 138 134 167 15650.04 116 106 151 179 200 161 279 233 174 174 202 148 129 170 14950.06 123 115 170 162 222 204 333 251 228 181 225 156 134 162 18950.08 126 139 153 175 250 182 331 291 218 203 239 171 162 186 206

50.1 162 139 207 211 288 226 409 358 236 240 272 169 162 197 20750.12 179 125 210 193 304 235 424 351 238 234 334 204 168 220 28750.14 169 126 204 245 371 268 521 407 278 224 363 221 187 206 31150.16 163 107 190 250 436 325 478 404 313 242 389 253 197 253 37750.18 159 133 189 252 427 286 504 443 348 285 402 226 231 260 269

50.2 175 128 184 256 451 289 535 505 333 305 436 263 240 248 32450.22 226 173 188 321 433 337 482 566 348 298 462 301 247 298 30250.24 228 153 196 303 478 381 562 589 427 378 488 328 280 290 34550.26 243 190 170 361 502 363 633 645 452 374 501 333 298 308 433

318

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

50.28 303 209 235 367 525 383 649 721 496 431 545 414 334 328 48750.3 318 199 242 415 527 455 697 790 549 524 608 455 370 379 531

50.32 336 204 203 479 564 460 775 895 567 576 656 541 388 435 64150.34 378 289 255 523 589 526 796 985 595 659 686 548 443 462 65050.36 438 305 245 570 602 575 892 1045 672 793 746 614 562 567 81350.38 468 369 289 663 634 702 910 1098 771 983 859 798 633 665 976

50.4 559 442 355 683 669 745 997 1232 850 1226 953 921 838 809 113750.42 654 574 419 839 731 806 1010 1300 963 1408 1041 953 922 922 136350.44 831 659 476 937 751 908 1135 1329 1064 1637 1164 1182 1157 1179 152850.46 1022 748 602 1101 829 1019 1125 1319 1101 1832 1142 1302 1427 1259 170450.48 1240 919 636 1193 992 1134 1140 1333 1153 1836 1212 1343 1674 1467 1770

50.5 1597 1081 772 1280 1055 1169 1197 1333 1282 1877 1223 1336 1946 1753 186750.52 1960 1125 794 1371 1180 1365 1198 1268 1354 1779 1264 1254 2193 1876 175350.54 2352 1111 868 1431 1350 1329 1146 1320 1346 1668 1202 1070 2324 1969 170050.56 2650 1029 872 1539 1456 1321 1166 1248 1396 1618 1197 905 2317 1889 148550.58 2682 894 828 1545 1507 1389 1148 1199 1358 1523 1075 762 2252 1807 1395

50.6 2583 840 778 1619 1421 1406 1114 1161 1413 1420 1045 584 2150 1743 128350.62 2404 786 710 1575 1398 1361 1034 1131 1443 1267 1018 529 1944 1596 122450.64 2124 683 619 1480 1327 1278 1061 1061 1398 1133 900 365 1728 1406 110750.66 1854 662 600 1465 1221 1246 952 1044 1375 1045 889 355 1596 1362 94550.68 1835 686 531 1435 1037 1129 933 1041 1230 937 847 395 1448 1198 821

50.7 1638 536 492 1311 1059 1079 900 949 1245 833 801 403 1302 1140 73650.72 1530 453 459 1188 975 1000 945 977 1124 745 769 400 1214 1011 67550.74 1370 430 346 1107 961 970 909 936 1088 689 742 364 1031 896 63250.76 1125 331 319 1012 874 928 960 962 1132 667 727 433 863 772 58450.78 953 330 315 996 800 812 952 1017 1043 613 758 499 806 741 554

50.8 827 306 287 936 821 831 894 1027 1017 593 761 539 709 670 58650.82 668 284 264 846 802 817 969 1071 962 657 823 493 666 622 59350.84 673 300 272 805 766 812 916 1109 987 702 827 540 645 581 61350.86 669 383 273 832 797 873 1037 1202 973 704 879 569 632 589 66650.88 584 374 283 841 820 869 1047 1247 1068 785 955 721 673 640 729

50.9 627 413 313 900 848 907 1186 1355 1093 968 1037 809 706 633 90050.92 709 453 382 925 882 902 1291 1391 1141 1110 1066 823 828 795 105050.94 769 572 391 977 934 1009 1343 1526 1232 1303 1314 978 972 856 129750.96 913 684 486 1094 1045 1076 1425 1558 1362 1660 1466 1153 1034 1143 149350.98 1044 800 588 1188 1136 1134 1487 1538 1365 1953 1630 1439 1403 1306 1755

51 1229 1005 735 1388 1183 1269 1510 1533 1431 2349 1801 1603 1684 1507 209551.02 1622 1197 833 1536 1284 1401 1501 1543 1535 2450 1885 1740 1967 1866 227951.04 1893 1415 996 1651 1502 1504 1508 1617 1653 2474 1892 1801 2344 2044 232951.06 2312 1433 1073 1759 1648 1479 1537 1498 1679 2395 1839 1850 2622 2325 221651.08 2822 1462 1125 1819 1700 1605 1516 1417 1814 2190 1658 1696 3008 2431 2092

51.1 3054 1366 1044 1970 1771 1672 1466 1380 1702 1997 1633 1308 2892 2413 1833

319

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

51.12 3132 1149 1002 1942 1897 1584 1474 1291 1806 1862 1485 981 2776 2298 167351.14 2932 1065 945 1983 1770 1554 1320 1178 1740 1815 1402 852 2594 2136 156751.16 2645 1024 799 1870 1665 1653 1281 1093 1670 1685 1273 631 2351 1971 159551.18 2354 908 737 1856 1527 1486 1183 1058 1623 1471 1119 470 2109 1722 1374

51.2 2082 795 734 1685 1345 1491 1153 952 1575 1235 1068 367 1947 1642 124151.22 2064 764 600 1562 1311 1344 1026 890 1486 1158 952 335 1775 1495 105651.24 1963 663 598 1528 1175 1270 971 770 1373 956 779 379 1625 1333 88451.26 1737 562 485 1334 1042 1160 859 710 1226 768 684 320 1434 1224 78751.28 1529 458 441 1305 919 1089 716 608 1200 658 573 309 1261 1101 616

51.3 1288 356 376 1125 812 994 711 571 1087 553 512 242 1044 871 51551.32 1059 317 320 1066 690 821 655 489 968 463 475 295 891 744 48951.34 932 243 298 915 613 731 571 441 899 390 414 276 700 632 41851.36 757 223 187 790 520 698 568 399 808 341 371 235 566 524 37851.38 635 174 182 657 411 594 486 344 760 352 301 205 476 432 297

51.4 511 175 187 593 381 533 405 358 607 313 304 178 417 418 27251.42 483 159 126 521 337 433 407 250 501 244 284 130 376 350 24251.44 426 118 129 458 287 420 351 233 478 237 248 135 344 319 21151.46 403 122 113 409 263 347 370 261 468 199 199 95 310 283 19951.48 318 116 118 386 233 304 325 216 443 218 184 83 264 222 193

51.5 304 96 122 309 230 304 270 205 367 189 159 77 261 234 16551.52 237 85 110 289 218 258 258 174 332 175 159 80 191 195 12851.54 193 94 89 269 189 215 242 151 298 158 144 89 158 162 12151.56 175 67 91 239 131 208 214 142 296 138 126 96 172 160 12851.58 160 87 89 201 150 188 207 146 216 116 111 89 159 111 101

51.6 128 69 63 201 129 154 193 136 229 139 131 101 139 142 10651.62 152 67 67 160 123 155 154 129 221 128 131 114 151 117 8951.64 99 62 65 146 133 135 148 123 161 101 108 112 102 101 9051.66 120 55 77 137 117 152 142 105 193 118 120 102 117 98 8851.68 88 53 56 136 94 112 143 104 173 82 103 102 94 113 104

51.7 107 53 84 122 96 125 141 92 160 106 94 82 88 113 9251.72 93 51 69 150 90 96 137 111 151 88 95 99 100 107 8851.74 98 50 70 111 106 89 117 82 135 93 89 79 91 77 7351.76 81 57 62 100 89 80 115 86 127 91 93 68 102 107 8651.78 83 62 59 112 83 112 115 91 115 75 79 62 89 110 93

51.8 89 55 65 100 100 90 95 65 113 78 48 78 84 115 8551.82 89 54 74 115 84 92 96 95 113 67 85 73 89 88 6251.84 73 52 65 96 83 73 98 78 105 80 68 64 84 90 6951.86 85 47 64 93 81 75 103 67 118 67 67 62 72 75 7651.88 75 61 67 81 72 68 87 73 104 86 73 64 85 76 67

51.9 76 41 58 79 80 102 94 64 101 66 64 63 71 91 7251.92 74 40 67 86 93 76 89 78 88 74 75 60 71 78 5751.94 67 48 51 78 75 83 89 68 94 61 57 59 75 54 54

320

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

51.96 70 56 68 82 63 72 100 69 87 67 73 65 75 77 7051.98 86 56 55 76 63 65 93 56 70 59 73 52 83 84 53

52 55 61 62 92 77 76 89 63 82 73 70 54 87 85 7352.02 62 39 62 96 72 53 70 61 72 49 64 57 64 82 6352.04 61 47 69 64 70 58 90 59 79 55 63 61 62 76 6252.06 66 56 62 74 60 51 79 71 66 71 80 51 74 84 7252.08 74 53 54 64 81 60 73 62 74 56 66 64 71 87 56

52.1 73 46 73 70 65 77 97 50 74 64 67 66 60 78 7852.12 67 49 71 86 77 75 76 49 62 63 59 63 52 84 6452.14 72 52 75 69 87 65 84 88 83 60 52 80 74 83 6452.16 61 60 72 69 65 69 79 69 71 55 61 63 52 89 6452.18 68 54 62 82 81 79 76 67 75 76 66 61 62 95 65

52.2 67 49 85 68 81 59 53 69 82 56 69 45 47 111 7152.22 50 50 63 77 68 70 82 64 82 73 65 64 73 135 6352.24 76 48 76 77 59 53 82 57 85 74 76 63 60 118 7352.26 64 53 87 54 57 73 76 62 87 79 63 63 67 124 6352.28 70 49 80 91 66 76 78 57 74 70 60 54 63 134 75

52.3 69 65 79 67 74 81 77 60 82 92 61 66 67 121 6952.32 73 59 69 71 49 74 69 63 79 78 68 76 75 120 6652.34 95 52 83 76 77 89 95 62 70 79 66 67 72 115 8752.36 95 56 86 75 80 77 76 65 83 68 69 67 92 108 6852.38 83 57 87 76 79 82 66 68 83 76 72 69 92 116 57

52.4 85 55 65 89 71 74 87 55 77 67 59 62 93 116 7052.42 96 58 92 70 69 73 86 61 81 70 49 72 91 101 6552.44 90 53 80 69 65 72 83 61 92 74 61 52 75 72 6852.46 82 45 69 72 57 66 82 65 76 59 59 52 71 95 6552.48 54 55 74 64 67 72 68 49 92 84 76 50 68 89 52

52.5 74 64 75 66 71 55 71 52 61 57 52 50 66 87 5552.52 72 54 85 65 61 60 74 56 74 50 66 43 78 90 6852.54 65 52 70 67 57 61 70 50 63 52 50 46 69 72 4652.56 61 43 75 68 67 62 71 51 74 48 50 44 67 84 5452.58 68 41 75 55 62 65 61 54 73 63 49 41 70 79 59

52.6 65 43 69 73 57 63 74 52 60 53 51 47 55 75 4552.62 78 50 84 70 58 64 58 52 61 55 41 53 63 57 5252.64 50 40 75 60 49 64 49 54 80 60 42 49 56 64 4852.66 65 41 80 49 53 55 55 42 53 36 36 59 45 67 7052.68 43 52 91 67 63 56 65 53 65 58 35 44 64 62 49

52.7 69 40 99 68 57 64 76 43 65 57 53 43 51 58 3552.72 63 40 76 64 67 55 66 50 51 53 44 46 65 54 5552.74 56 40 89 70 62 53 55 50 63 59 53 45 43 75 4352.76 37 48 76 61 56 46 66 43 54 47 56 52 52 62 6252.78 47 44 77 38 67 49 57 54 54 43 46 43 52 65 48

321

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

52.8 57 37 112 69 59 52 57 44 53 42 44 35 43 68 6052.82 47 54 78 53 51 49 53 39 70 43 60 50 54 55 5052.84 55 53 93 49 49 66 48 49 57 53 53 42 54 56 5252.86 62 44 85 67 59 65 60 42 64 47 35 44 62 58 4752.88 62 42 66 55 54 65 41 48 58 60 42 35 55 62 53

52.9 46 35 84 50 57 70 56 43 61 38 46 39 61 57 5152.92 54 40 61 57 36 55 51 49 64 47 42 33 65 65 5552.94 47 45 75 56 47 52 59 39 62 65 43 36 46 55 5752.96 57 50 71 64 67 42 47 36 46 52 46 36 54 52 4952.98 32 39 85 42 68 43 60 53 58 42 53 49 46 60 56

53 67 53 85 46 47 53 58 43 49 50 38 37 44 49 4053.02 49 52 91 58 51 49 57 41 68 48 34 52 51 52 4753.04 48 38 69 58 52 54 64 39 61 47 41 56 52 45 3853.06 53 41 72 56 66 46 45 45 50 55 38 44 47 47 5453.08 53 42 82 65 56 57 71 41 47 44 46 49 44 60 39

53.1 46 37 83 60 63 69 57 48 55 54 39 48 42 73 4053.12 44 43 73 53 69 57 70 40 60 56 49 39 44 41 3653.14 53 57 80 49 60 59 51 41 59 50 47 29 47 55 4453.16 43 35 77 64 70 43 60 49 46 56 35 35 52 55 4153.18 49 46 75 56 77 50 58 43 53 59 48 37 50 47 39

53.2 55 43 83 50 61 44 54 55 65 43 41 28 49 57 2953.22 40 52 97 63 73 50 59 51 45 50 53 29 46 47 4253.24 54 40 90 52 65 45 63 49 61 54 39 31 46 46 4153.26 46 39 95 53 61 46 64 49 56 48 37 32 46 54 4053.28 50 45 90 59 63 63 57 54 44 45 42 47 46 59 42

53.3 46 55 96 45 62 41 54 45 53 41 43 37 53 50 4253.32 43 38 69 61 76 53 54 56 65 38 38 43 54 64 5253.34 55 35 84 57 58 41 54 43 66 49 36 33 51 51 4153.36 53 37 68 47 62 48 62 47 60 51 44 32 52 58 5053.38 53 38 79 49 45 48 49 46 53 49 53 31 48 64 50

53.4 58 53 82 40 69 55 55 45 68 47 43 45 37 49 4053.42 59 36 84 49 53 66 52 49 53 54 48 49 49 41 4053.44 59 40 78 54 59 62 45 42 42 58 35 18 48 56 3953.46 53 31 59 47 58 49 54 47 50 55 49 23 48 39 4053.48 51 37 75 53 54 54 60 36 48 48 46 40 49 57 46

53.5 52 44 80 61 65 51 51 36 64 47 48 47 40 52 5653.52 67 48 98 54 47 47 63 52 53 43 42 41 61 59 4953.54 37 46 73 55 58 46 67 41 55 55 44 26 45 49 6253.56 57 47 70 52 65 48 44 40 67 54 32 37 41 50 5653.58 52 37 93 46 52 54 53 34 48 48 38 35 50 59 46

53.6 51 52 75 52 53 60 48 55 54 41 40 45 51 45 4053.62 56 48 77 52 61 57 48 50 45 52 51 35 44 48 40

322

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

53.64 35 35 57 35 58 56 47 50 45 46 44 26 53 59 4553.66 62 53 80 56 57 36 53 38 61 50 47 19 58 51 4853.68 40 52 60 57 56 49 53 47 47 39 40 34 44 45 22

53.7 60 43 74 44 59 51 70 45 51 43 48 36 54 41 4453.72 44 37 77 50 59 53 48 32 53 45 33 34 56 65 5553.74 40 51 69 55 47 34 54 51 45 41 54 23 40 56 5553.76 68 48 82 53 59 35 56 38 45 48 40 36 36 63 6053.78 50 41 77 54 63 57 71 46 43 47 37 47 47 58 47

53.8 63 47 72 53 48 53 51 58 41 47 51 33 42 46 4453.82 42 40 78 45 44 50 53 38 57 39 52 46 45 41 4253.84 56 50 79 54 54 51 59 29 50 63 38 28 62 58 4653.86 45 34 94 45 58 47 49 43 56 47 37 21 44 57 2553.88 50 39 91 46 52 61 50 45 48 49 44 43 49 61 52

53.9 55 47 84 54 51 38 59 40 49 47 35 30 52 48 3453.92 48 39 86 39 48 55 53 51 62 42 41 24 50 45 5053.94 54 45 78 48 53 45 59 42 50 39 40 22 45 64 5153.96 52 35 87 42 70 44 65 41 42 61 48 19 42 44 5553.98 40 38 100 61 53 36 46 42 38 34 31 27 52 57 36

54 47 42 105 44 55 63 72 34 50 40 39 25 47 47 4254.02 44 34 80 58 59 49 63 50 47 34 44 16 39 68 4154.04 45 40 90 44 53 37 52 47 49 43 54 31 44 47 4454.06 56 33 87 55 49 49 52 42 39 40 38 35 47 59 3154.08 53 43 62 47 51 43 53 30 53 41 43 51 45 48 45

54.1 59 33 70 50 45 48 59 40 56 36 45 40 56 60 4654.12 56 39 79 46 43 58 52 41 48 45 33 32 42 65 4154.14 52 41 64 70 51 48 60 39 46 42 36 46 45 60 3954.16 51 50 80 46 50 45 46 58 51 49 43 40 38 54 4754.18 56 45 115 48 48 56 49 32 47 44 50 37 44 44 46

54.2 47 44 64 59 46 50 57 36 64 40 33 22 61 54 3654.22 54 44 77 43 50 45 57 45 46 45 45 21 42 55 3154.24 43 47 78 52 41 47 53 43 56 48 34 19 52 44 4054.26 61 35 90 50 59 55 52 34 38 48 42 24 49 53 5154.28 50 44 98 32 42 49 51 46 59 49 49 22 36 54 46

54.3 48 40 109 53 56 54 48 49 53 55 54 24 61 60 4354.32 37 38 89 49 47 57 65 37 45 38 41 18 44 63 3354.34 42 40 101 49 53 56 40 44 47 44 34 38 56 50 3054.36 61 54 84 46 47 53 61 42 36 47 42 25 42 51 3854.38 50 35 102 45 44 61 60 50 54 38 32 23 50 55 42

54.4 45 40 77 43 53 49 66 45 52 44 49 35 44 48 4254.42 43 38 79 54 40 52 45 29 44 44 35 29 37 45 3654.44 50 45 93 46 49 52 58 41 58 44 44 31 48 45 3054.46 41 38 81 46 56 54 56 37 49 34 53 31 45 44 46

323

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

54.48 24 37 88 58 59 36 68 53 42 41 30 31 40 44 4854.5 57 43 85 57 56 49 54 44 44 47 36 39 47 56 53

54.52 51 28 78 44 56 38 51 44 47 52 45 38 42 59 5854.54 56 42 77 37 54 42 47 34 59 46 45 36 35 65 5154.56 56 45 85 42 59 55 53 38 54 63 40 38 52 63 5854.58 53 36 78 56 47 53 57 39 56 42 38 27 47 68 62

54.6 49 64 80 43 46 45 55 43 49 33 31 29 46 57 4654.62 53 48 85 39 59 53 52 46 48 51 51 22 39 51 5954.64 45 35 80 60 57 55 66 41 60 35 48 15 42 54 5554.66 49 36 95 44 54 42 48 53 64 45 35 21 47 42 4654.68 48 39 70 45 62 53 45 32 41 54 41 22 40 63 69

54.7 51 49 84 53 55 51 56 52 59 49 35 24 47 48 5154.72 61 40 79 58 52 41 56 63 62 38 42 28 37 43 6354.74 50 46 79 53 69 44 57 48 47 41 28 26 42 62 3654.76 53 37 99 57 60 38 72 47 57 48 32 32 47 49 5254.78 43 52 84 42 60 50 84 33 47 47 42 31 46 63 46

54.8 49 46 120 47 73 56 69 39 57 38 51 28 36 50 4754.82 61 48 124 45 70 68 72 44 51 51 35 34 39 62 5054.84 46 50 111 60 81 66 75 34 45 64 45 38 48 56 6754.86 60 62 110 61 83 64 72 38 58 49 35 23 50 49 6554.88 53 45 134 54 79 69 93 43 64 50 44 34 61 66 58

54.9 58 44 118 55 79 51 82 41 45 50 40 31 45 58 6154.92 46 43 134 68 82 60 82 48 60 53 37 39 47 52 5254.94 42 55 119 55 67 60 66 47 54 39 29 20 43 73 3354.96 40 59 97 46 65 74 58 46 55 48 44 28 53 53 5554.98 42 57 112 53 58 49 74 48 38 55 38 27 36 57 53

55 50 52 126 55 77 59 88 42 54 48 29 22 47 53 4655.02 48 44 101 44 66 53 59 42 44 50 47 23 49 49 5855.04 47 26 105 47 55 44 85 26 54 37 36 17 46 64 4155.06 46 44 121 67 59 55 90 53 53 52 38 23 40 54 5855.08 52 52 113 53 62 46 67 46 59 38 34 24 55 55 45

55.1 56 51 108 46 55 48 62 38 52 36 43 35 44 62 4755.12 46 41 92 52 60 63 60 51 48 42 43 30 43 54 4955.14 53 47 92 43 53 46 54 37 53 35 35 36 44 50 4455.16 53 48 96 40 60 51 68 41 58 50 45 42 35 52 4455.18 53 36 100 49 57 46 54 40 44 44 34 28 28 50 58

55.2 42 44 105 54 45 47 59 51 64 45 39 45 48 50 4755.22 59 41 100 50 60 40 43 51 37 39 37 29 44 62 3755.24 47 50 98 43 58 50 49 45 37 40 35 26 48 59 4955.26 36 53 100 44 62 55 53 45 57 41 49 33 50 58 4455.28 54 38 107 57 57 53 63 41 60 57 52 24 47 40 44

55.3 46 40 89 55 67 56 64 41 57 42 45 32 67 63 46

324

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

55.32 40 39 102 65 90 54 73 48 52 36 43 29 36 55 5555.34 49 41 90 50 85 48 75 42 50 48 59 31 46 59 6055.36 56 37 91 41 69 46 64 40 42 39 43 26 44 61 6755.38 50 34 88 45 72 53 65 45 44 49 38 34 55 59 57

55.4 51 40 86 47 56 57 51 37 63 32 52 27 50 49 5555.42 43 42 102 46 48 32 53 37 60 50 29 38 53 55 4955.44 52 52 104 58 49 44 61 37 42 47 40 37 39 42 4155.46 54 51 96 35 62 54 59 33 50 54 52 22 41 60 5155.48 53 34 85 48 60 51 60 56 55 34 52 32 38 67 44

55.5 51 41 84 54 63 52 49 50 41 44 50 30 37 48 5055.52 62 47 89 35 58 52 51 51 51 58 32 29 47 58 5855.54 49 33 83 48 70 54 69 48 53 57 38 31 37 64 3255.56 48 29 87 48 43 39 59 39 50 34 36 34 46 65 4755.58 53 44 95 66 42 56 59 43 38 42 40 20 36 87 40

55.6 43 49 86 50 54 42 52 42 65 41 38 27 56 68 4555.62 41 48 72 43 57 30 67 39 41 69 37 26 50 75 3455.64 59 42 83 43 56 39 41 35 49 51 40 28 48 89 4155.66 33 41 83 38 45 59 56 36 52 33 40 24 42 99 4155.68 48 54 121 48 51 34 54 37 51 52 34 41 40 98 47

55.7 57 37 80 45 38 50 63 33 53 49 34 35 49 114 4755.72 41 43 82 52 50 43 54 41 39 37 35 32 36 106 5255.74 60 53 86 45 51 43 50 45 48 40 42 39 52 108 5155.76 51 43 87 48 62 41 53 45 37 38 45 29 33 106 4855.78 43 43 93 53 47 46 59 43 44 47 47 31 43 110 39

55.8 40 40 96 52 48 43 61 49 48 52 30 31 52 116 3955.82 41 34 87 46 38 45 58 45 48 42 46 33 61 106 5955.84 49 43 87 45 45 39 60 50 50 47 48 30 58 89 4355.86 54 43 83 54 47 43 42 57 47 43 50 27 46 77 4355.88 63 43 88 42 46 43 54 33 52 51 46 26 38 82 42

55.9 46 35 84 46 37 41 54 35 44 41 35 29 48 88 3455.92 54 52 91 41 39 41 47 41 57 42 35 27 43 84 4555.94 57 38 84 51 35 41 56 43 43 43 28 29 30 70 4555.96 53 44 92 46 45 49 52 34 56 40 40 33 51 78 3955.98 39 41 83 39 49 36 61 42 44 34 44 41 51 74 40

56 52 45 104 42 52 38 53 38 39 42 38 34 45 49 4556.02 52 51 90 34 48 37 35 39 48 48 47 31 43 49 4356.04 42 42 92 39 59 59 42 35 48 40 39 28 30 69 4456.06 30 39 89 49 45 41 40 31 50 43 37 36 47 57 4156.08 42 54 87 54 47 54 50 34 47 50 32 29 34 64 42

56.1 50 33 107 42 45 43 54 31 42 42 47 34 51 59 4956.12 46 45 119 53 57 46 41 41 57 49 41 35 44 58 3256.14 32 39 122 48 44 46 49 44 45 31 29 28 53 63 38

325

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

56.16 51 55 136 45 49 50 51 37 69 54 41 35 57 57 4756.18 51 48 155 46 37 41 44 39 53 44 34 30 47 55 36

56.2 45 48 183 45 51 54 54 48 39 41 44 21 53 59 4056.22 59 51 175 42 52 41 46 37 55 58 52 23 52 41 4956.24 48 53 137 37 63 54 41 41 53 43 48 28 49 54 4656.26 46 44 136 49 43 48 51 46 58 44 39 29 54 53 3456.28 52 61 138 52 44 49 46 38 54 42 44 28 47 50 46

56.3 47 47 112 39 54 47 54 46 49 40 38 32 54 59 4256.32 40 46 130 47 50 48 60 54 45 48 39 26 56 52 4656.34 45 54 124 47 55 54 42 44 49 48 43 25 45 47 3856.36 47 49 127 59 53 55 58 45 44 42 37 38 39 47 3856.38 54 60 115 57 46 43 54 41 52 48 34 39 48 53 48

56.4 48 45 85 35 56 46 56 45 55 35 46 41 45 48 4756.42 49 52 112 41 49 48 46 63 52 39 31 32 52 43 4256.44 44 51 97 47 43 41 45 62 56 52 40 47 59 53 5056.46 51 41 71 36 49 50 48 61 45 38 42 47 44 54 4156.48 56 49 80 47 40 36 58 61 56 52 49 40 53 61 51

56.5 51 37 83 44 51 44 49 65 47 44 45 46 40 55 6356.52 50 36 89 40 54 41 39 67 54 49 51 27 51 56 5856.54 65 65 67 51 60 43 51 51 45 69 38 31 51 40 4256.56 52 48 84 41 60 50 55 59 51 76 44 27 58 56 4556.58 56 38 81 48 64 44 66 50 53 91 53 30 44 49 44

56.6 59 44 84 43 56 46 61 45 45 82 50 31 45 56 5156.62 67 39 67 43 45 59 54 55 61 71 54 34 56 47 6056.64 45 31 76 46 64 47 63 48 54 56 53 39 44 55 5156.66 44 44 70 45 71 53 68 57 54 46 48 37 58 36 4556.68 41 34 91 49 52 50 55 44 48 61 46 34 43 63 46

56.7 47 45 67 54 52 48 83 40 70 58 46 51 49 57 5356.72 50 31 78 49 60 49 58 56 48 60 45 32 45 54 4756.74 47 48 58 63 65 71 56 54 64 53 35 38 50 58 4256.76 50 48 74 60 49 53 64 50 57 47 41 32 56 51 5656.78 49 39 68 52 62 58 67 50 75 47 37 35 50 50 44

56.8 54 51 69 59 47 49 72 40 56 39 46 43 48 57 4556.82 43 44 70 50 64 56 68 51 83 56 41 19 46 55 5956.84 40 41 64 45 59 58 69 52 67 47 33 35 51 56 4256.86 49 46 65 49 54 58 62 47 64 55 48 37 37 65 3856.88 53 41 60 52 58 50 62 46 65 50 42 24 58 66 56

56.9 64 35 64 57 66 46 55 64 61 41 39 20 42 45 4556.92 34 45 57 40 55 63 65 47 66 45 48 30 35 52 4556.94 46 40 71 50 45 44 57 59 56 30 36 34 44 53 4056.96 58 42 65 42 44 65 52 41 73 41 35 35 39 39 4656.98 46 31 59 35 56 53 56 37 67 37 41 34 36 46 33

326

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

57 52 39 55 37 49 48 55 46 64 46 36 35 47 48 4357.02 51 36 63 58 45 68 53 44 47 40 46 32 49 41 3657.04 36 27 71 42 58 53 64 54 66 50 42 46 50 57 4257.06 55 28 67 39 38 62 60 41 63 41 42 39 52 49 4357.08 43 36 56 41 41 56 50 44 64 51 42 34 38 45 56

57.1 38 38 68 56 56 55 60 52 57 58 37 40 44 59 4657.12 46 36 65 48 54 64 60 41 56 50 49 40 47 50 3857.14 47 37 77 43 55 42 52 58 55 37 34 34 28 55 4357.16 55 32 65 40 61 47 49 50 63 37 42 33 39 61 4757.18 51 40 81 48 41 62 56 52 50 48 39 54 44 53 34

57.2 43 36 58 48 54 68 63 46 54 42 48 29 51 48 5057.22 51 41 77 56 47 58 56 55 59 48 39 27 36 40 5057.24 47 39 70 51 46 47 77 54 47 43 62 31 41 57 5357.26 50 43 62 48 59 57 61 70 58 41 42 35 48 54 4057.28 40 41 72 35 43 53 57 67 59 39 34 38 43 57 53

57.3 41 39 64 49 61 54 53 88 63 44 47 40 43 40 4157.32 49 39 80 34 49 63 42 83 53 63 44 54 48 49 3957.34 66 39 54 51 60 48 63 73 62 65 54 46 55 46 5057.36 41 35 52 45 57 68 47 65 62 70 52 50 41 47 4857.38 45 39 79 51 64 55 57 63 45 60 50 52 36 48 63

57.4 54 37 81 52 66 56 67 61 63 86 69 55 50 48 6057.42 41 30 57 50 56 54 72 80 65 89 50 46 39 47 7757.44 49 41 63 54 68 57 74 79 65 77 75 51 56 55 6557.46 59 36 60 48 53 69 79 92 71 67 47 36 52 61 6657.48 58 46 63 50 64 63 65 67 70 80 54 38 59 58 71

57.5 61 53 54 57 73 51 64 78 68 61 38 67 48 60 6157.52 55 39 73 45 67 58 75 75 80 67 58 30 45 49 5657.54 60 50 89 52 75 65 85 61 108 63 64 37 45 64 7657.56 62 46 55 57 71 65 75 68 88 72 53 26 40 42 5257.58 57 31 73 67 62 89 73 82 84 62 52 43 38 54 69

57.6 49 49 67 56 55 69 119 49 111 57 51 44 45 51 5557.62 50 44 62 53 58 82 83 56 90 49 41 50 43 54 4557.64 60 35 75 49 57 92 88 56 96 63 43 44 55 55 4957.66 59 44 70 60 58 81 85 61 106 51 42 32 44 58 5157.68 49 41 63 46 45 77 61 41 91 44 45 41 53 56 53

57.7 51 28 70 49 57 96 69 61 86 53 43 39 48 56 5557.72 36 45 69 55 53 92 78 44 102 47 42 49 53 44 5957.74 46 44 76 51 58 80 65 69 110 46 41 51 51 65 4257.76 49 32 83 59 52 82 68 44 94 52 34 40 55 47 4057.78 66 52 78 46 59 85 56 61 103 43 56 34 51 58 54

57.8 53 32 70 52 55 79 75 48 95 52 39 45 43 54 5357.82 54 47 70 61 59 77 75 69 83 51 46 43 47 72 46

327

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

57.84 54 41 74 54 44 97 63 48 92 45 34 35 48 62 3657.86 45 45 66 41 42 89 55 42 84 40 41 38 48 61 4357.88 51 36 74 68 49 76 61 54 82 44 46 42 37 62 43

57.9 40 29 72 50 63 74 55 61 81 46 37 32 50 59 4357.92 50 38 71 74 71 76 59 64 69 39 45 37 47 57 4957.94 52 45 60 39 56 59 71 65 73 62 44 50 42 56 5357.96 53 41 66 50 44 81 64 75 70 48 46 36 51 58 3957.98 44 42 74 58 59 65 70 48 69 46 52 41 59 85 35

58 44 41 58 54 41 60 52 62 94 46 42 45 73 58 4158.02 59 43 60 79 47 69 63 52 79 45 50 33 49 54 4558.04 52 37 62 54 60 70 56 58 58 56 38 31 52 50 3758.06 61 37 57 45 62 65 70 48 70 42 44 35 48 46 5558.08 53 35 66 53 53 68 50 61 74 47 37 48 41 41 57

58.1 49 36 68 44 56 53 67 63 78 61 44 47 49 49 4858.12 60 45 81 55 52 55 68 50 63 45 49 33 49 46 5658.14 44 32 67 52 55 64 72 52 72 60 34 34 49 53 5558.16 53 49 70 39 56 70 61 51 83 53 38 39 54 49 5358.18 47 37 61 58 49 65 65 41 68 32 59 45 57 55 42

58.2 39 27 67 41 50 58 66 49 53 40 53 50 54 54 4358.22 44 41 52 46 63 52 62 48 83 56 38 46 36 55 4158.24 52 45 52 50 56 53 66 72 67 51 40 49 53 44 4858.26 49 44 57 49 46 52 64 57 58 58 54 52 50 62 5258.28 51 40 51 60 55 56 72 63 68 48 55 45 45 72 50

58.3 46 36 66 39 47 60 65 64 82 55 69 36 49 55 5958.32 49 49 72 59 73 67 77 68 61 50 44 40 47 61 5058.34 56 38 54 54 51 66 61 67 76 52 39 43 56 42 6058.36 65 36 52 56 66 57 75 61 71 53 64 43 50 61 6058.38 49 41 74 53 59 61 66 60 74 47 51 47 43 54 39

58.4 54 54 62 59 74 53 57 83 60 58 52 38 57 57 4658.42 61 30 67 54 65 67 89 60 81 60 63 59 50 58 6658.44 58 43 67 54 57 66 86 89 80 44 54 53 58 60 5258.46 63 39 63 64 62 78 75 104 90 43 59 62 56 61 6658.48 51 37 66 68 68 62 78 90 74 59 46 49 68 67 52

58.5 69 43 67 66 65 79 108 102 89 57 69 59 64 56 6058.52 61 53 82 80 57 69 88 101 62 62 66 48 62 60 6158.54 59 53 66 74 83 71 95 99 94 73 79 63 53 64 7658.56 67 57 82 81 73 76 88 111 68 76 84 52 77 65 6558.58 70 55 70 83 80 77 109 126 110 78 91 54 70 87 81

58.6 83 50 89 92 86 84 116 135 106 86 96 60 64 86 7858.62 89 76 70 85 88 89 114 181 125 93 88 58 91 97 7058.64 72 74 89 89 108 86 117 165 116 105 115 74 82 80 9558.66 73 80 86 91 118 117 140 208 135 81 132 75 91 84 91

328

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

58.68 91 74 97 122 112 131 159 220 153 106 147 88 97 103 9058.7 114 82 101 118 127 131 152 211 157 126 145 107 121 97 135

58.72 99 84 99 134 150 126 175 265 144 120 162 121 109 109 13958.74 111 84 113 158 175 153 183 274 178 146 175 140 135 140 17158.76 133 117 119 162 168 174 212 275 192 191 220 164 159 164 18858.78 146 137 128 172 188 168 273 317 240 255 261 202 178 177 237

58.8 181 149 151 220 197 205 253 309 266 290 290 216 207 230 29558.82 221 185 166 220 257 236 334 342 263 356 335 276 255 257 32658.84 303 219 183 258 269 274 326 327 298 437 386 302 325 319 41458.86 332 270 242 320 295 297 330 328 343 451 395 350 423 364 48158.88 414 282 226 302 312 318 312 287 335 461 402 345 454 413 460

58.9 504 303 267 345 328 329 311 272 343 438 373 293 548 495 43658.92 550 292 268 373 385 337 259 298 343 391 314 262 515 459 37458.94 563 231 224 391 385 305 350 246 357 353 289 211 527 492 28658.96 523 197 217 405 342 310 285 224 368 306 271 174 482 417 28458.98 504 195 201 378 358 328 253 224 338 308 257 121 410 357 280

59 390 180 201 367 265 274 266 227 335 280 255 105 348 319 28759.02 348 187 213 335 277 281 263 227 340 291 237 55 342 313 29759.04 355 151 181 320 267 252 257 182 304 288 226 60 350 303 25259.06 341 169 162 295 253 264 215 174 264 211 200 75 310 321 20559.08 347 137 184 298 236 222 205 174 290 224 164 45 307 273 181

59.1 321 110 178 291 209 221 208 164 252 180 133 60 294 254 16359.12 281 122 151 239 220 205 168 161 219 130 121 70 242 203 11059.14 261 77 138 226 186 202 158 139 245 104 107 62 196 182 10859.16 186 78 104 211 147 193 151 138 206 123 99 54 187 160 9259.18 174 54 133 193 119 180 133 135 199 103 76 68 150 149 90

59.2 154 54 96 160 98 152 133 105 186 85 60 105 124 110 8659.22 117 63 91 171 110 127 116 108 166 86 95 70 97 111 6759.24 103 53 74 143 106 135 119 116 171 86 77 76 101 104 8259.26 104 72 88 118 102 128 124 139 152 70 86 62 117 91 8059.28 83 46 74 122 104 106 108 125 152 76 83 58 106 83 91

59.3 95 41 91 114 90 120 118 127 125 79 65 56 90 84 7459.32 75 69 68 109 88 110 114 125 131 65 87 59 91 81 7959.34 82 58 102 122 80 113 128 135 117 72 92 67 84 98 7759.36 80 49 90 104 99 94 134 130 164 87 84 46 82 78 8159.38 79 50 90 107 100 107 135 160 144 72 60 73 89 90 69

59.4 86 59 75 127 97 112 122 155 131 85 79 71 83 96 9359.42 111 48 88 100 90 96 154 179 143 86 105 73 90 115 12259.44 82 51 87 100 93 106 132 185 143 81 111 67 103 91 9159.46 95 64 81 118 119 126 161 195 155 91 110 89 86 104 12159.48 81 65 89 130 125 138 150 186 147 114 127 94 114 102 114

59.5 121 73 100 123 119 126 189 253 169 114 142 102 111 118 134

329

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

59.52 116 83 97 136 126 131 190 274 178 108 168 110 109 128 12859.54 132 86 102 148 153 146 230 283 191 129 188 120 135 135 14859.56 132 88 117 163 168 167 220 333 233 164 199 120 138 156 14459.58 158 83 94 179 183 180 236 352 214 164 229 158 157 179 131

59.6 163 117 114 191 191 214 302 406 247 192 241 151 155 163 19459.62 168 114 142 247 241 219 300 400 252 182 311 172 179 182 22759.64 193 145 155 223 247 248 351 472 286 216 307 209 196 235 27959.66 210 168 156 276 295 280 405 484 319 274 334 235 221 232 30259.68 259 182 156 329 345 283 396 514 393 321 401 308 271 276 319

59.7 265 257 198 337 359 337 470 526 410 454 457 364 335 324 48259.72 345 265 251 354 376 401 476 551 460 540 557 455 436 441 53259.74 393 347 293 441 430 423 500 517 505 688 715 475 513 539 66559.76 509 443 344 482 470 458 559 546 532 826 773 618 664 653 77159.78 615 535 402 528 572 506 605 534 573 936 849 661 806 767 761

59.8 870 529 451 626 611 538 591 554 604 936 772 708 974 833 80159.82 981 579 515 650 718 558 553 518 613 837 773 676 1061 926 72659.84 1071 475 439 636 675 592 566 492 588 727 678 592 1121 917 64659.86 1128 494 474 693 774 589 544 486 632 652 630 448 1106 901 62659.88 1164 393 463 669 702 629 554 461 648 574 560 344 1001 839 572

59.9 1007 389 398 687 689 586 552 442 623 572 522 295 839 753 55659.92 915 364 406 647 590 544 533 412 620 567 487 207 735 705 56659.94 765 352 360 583 547 566 521 387 572 561 474 166 705 633 54359.96 711 367 408 572 515 556 496 350 550 531 431 101 682 643 50059.98 677 305 382 529 476 503 468 331 524 491 417 115 635 581 403

60 635 286 328 519 450 468 449 274 485 415 332 130 599 537 37360.02 648 228 286 496 432 457 372 313 486 330 261 93 600 480 31160.04 601 206 281 435 359 395 330 243 441 230 214 87 531 429 22160.06 523 187 256 401 345 386 288 204 424 191 196 74 409 351 22160.08 424 146 194 362 302 329 266 208 344 190 152 86 358 282 178

60.1 324 144 184 356 242 285 261 172 330 137 131 94 263 242 14260.12 302 110 205 283 235 280 226 159 312 138 114 72 215 199 15860.14 193 95 183 228 208 225 223 153 280 117 118 73 182 194 11860.16 189 77 153 211 163 216 218 125 215 111 90 59 151 148 10760.18 165 79 152 222 130 180 153 123 200 88 94 60 135 138 99

60.2 129 90 134 210 106 189 163 103 210 97 85 75 133 134 7160.22 146 78 166 148 110 154 133 110 194 84 76 68 111 95 7060.24 128 64 148 164 87 132 107 92 171 73 74 52 100 95 9260.26 92 70 136 130 107 138 90 94 152 69 77 41 96 77 8160.28 111 53 145 116 85 104 113 76 144 84 68 62 90 91 83

60.3 88 56 160 118 79 114 93 80 133 83 51 49 91 74 7860.32 90 68 152 96 67 92 121 85 98 70 58 50 72 81 5760.34 67 65 150 106 94 94 88 60 113 70 64 51 90 82 52

330

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

60.36 67 61 140 91 66 94 76 78 105 59 55 37 81 69 4960.38 68 57 139 81 73 72 81 64 90 57 54 44 76 54 53

60.4 68 46 159 79 59 68 75 65 95 53 57 45 62 56 6560.42 66 39 156 86 56 89 98 73 101 57 54 43 65 67 5760.44 52 51 155 69 66 60 68 63 84 52 49 44 68 55 6260.46 53 51 178 78 64 79 67 75 100 69 41 49 51 71 4860.48 56 49 134 62 51 74 64 75 96 52 55 37 62 56 45

60.5 61 52 153 55 70 73 78 81 77 38 42 51 52 66 3460.52 48 53 177 65 62 50 65 97 91 56 52 59 63 55 6360.54 61 51 160 62 62 58 67 72 82 50 40 54 62 55 6560.56 54 47 161 73 61 65 72 82 67 54 67 38 41 58 5460.58 60 55 168 64 55 61 66 77 73 72 44 49 51 54 39

60.6 54 52 156 52 63 67 59 76 64 47 52 42 65 53 5760.62 55 52 160 53 53 67 65 60 73 65 57 49 41 64 5160.64 57 39 157 45 47 52 68 91 72 61 52 48 41 66 5060.66 58 40 151 43 67 49 65 81 67 63 61 53 53 59 4760.68 63 39 165 50 52 43 72 61 73 63 68 58 53 67 49

60.7 52 50 157 60 62 50 71 61 74 85 58 52 49 58 5160.72 52 51 136 65 53 69 45 69 70 88 58 46 52 66 5660.74 63 50 159 60 72 60 59 71 72 68 42 49 53 58 5760.76 60 45 137 56 48 47 79 67 80 55 48 62 51 56 5360.78 47 53 134 57 74 49 67 51 69 58 50 46 46 46 56

60.8 58 51 124 59 72 47 74 64 72 50 53 46 53 65 4160.82 47 52 136 42 56 57 85 65 69 52 51 29 39 56 4660.84 61 44 116 61 58 75 65 86 73 49 59 39 44 67 5660.86 48 47 128 51 52 78 76 67 68 61 41 48 52 67 4760.88 51 42 139 60 59 67 72 51 86 48 48 33 37 62 61

60.9 55 52 134 44 67 71 65 73 103 52 32 63 48 49 4260.92 55 48 109 55 51 77 56 74 89 65 63 50 55 63 4160.94 46 39 113 49 58 66 65 68 75 71 67 41 37 64 4460.96 41 39 101 65 72 78 79 70 86 58 61 45 39 59 3760.98 60 53 122 53 42 76 66 58 77 56 83 56 40 56 47

61 49 39 119 52 49 62 62 67 78 72 89 47 49 53 4361.02 54 45 112 46 66 82 75 66 96 65 137 48 46 58 5161.04 57 32 122 66 63 63 83 64 82 54 148 43 38 45 4661.06 55 34 102 49 68 59 65 59 80 45 118 53 33 43 4661.08 48 41 106 56 55 82 65 67 74 46 95 26 43 48 47

61.1 47 48 106 43 63 66 62 58 79 57 76 32 45 58 4961.12 44 43 95 54 68 61 67 63 89 43 70 42 51 55 4361.14 42 44 106 51 63 61 48 62 82 57 65 47 40 56 4961.16 46 35 102 54 56 81 68 67 87 51 55 25 54 56 4561.18 46 37 108 40 49 64 76 51 89 55 66 28 42 65 51

331

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

61.2 41 33 97 48 53 70 59 58 95 61 73 38 49 48 4461.22 51 37 94 45 58 83 78 61 90 55 72 38 44 49 5661.24 42 53 95 44 60 66 53 58 100 42 69 39 40 50 5261.26 50 51 133 67 50 71 49 65 90 50 58 45 53 36 4561.28 55 38 92 51 56 70 55 85 73 48 56 52 36 42 55

61.3 57 40 108 48 78 70 70 67 79 56 51 30 52 60 4861.32 56 51 106 55 58 79 74 67 58 46 55 36 38 55 4561.34 57 39 103 50 51 63 68 57 80 57 49 69 49 49 4661.36 54 46 102 55 55 62 62 64 83 56 50 45 40 57 4861.38 42 51 108 63 54 63 53 60 76 58 64 38 44 54 47

61.4 51 44 110 48 58 60 61 80 71 64 86 32 50 39 4561.42 45 45 94 53 49 77 56 57 73 69 91 45 49 55 5261.44 46 48 109 67 64 83 67 67 63 82 62 34 37 47 5361.46 50 46 121 68 53 56 73 65 69 69 51 48 47 40 4061.48 40 54 96 47 66 70 70 56 85 56 44 58 47 42 41

61.5 47 47 117 55 62 48 78 67 69 71 54 40 49 44 4561.52 59 56 124 52 61 68 77 58 93 35 47 36 43 44 5261.54 38 65 136 49 55 73 70 71 76 57 45 30 42 57 5061.56 48 59 122 55 50 73 69 54 66 56 60 43 59 56 4061.58 51 61 117 61 66 69 74 55 93 55 75 36 55 58 44

61.6 42 57 133 45 64 58 75 65 75 63 62 43 43 54 5361.62 46 76 121 54 54 80 79 61 68 42 56 46 48 58 4561.64 58 74 109 53 67 79 85 77 83 58 68 39 48 49 5761.66 61 62 122 38 68 85 89 66 87 54 56 34 40 69 6761.68 50 63 132 42 60 63 72 49 95 64 40 44 51 60 56

61.7 56 56 105 63 71 67 63 63 90 62 58 42 48 62 4761.72 53 70 124 62 90 63 70 47 106 57 54 50 57 64 4961.74 58 49 109 58 71 68 70 71 93 49 54 43 58 50 4161.76 50 59 111 62 75 70 74 57 81 65 65 40 60 58 5461.78 50 68 128 53 62 78 79 64 98 46 52 41 44 52 64

61.8 39 63 116 67 56 76 100 83 101 53 57 45 47 66 6661.82 66 63 137 64 65 78 105 57 96 67 72 56 51 61 6261.84 46 66 114 67 77 81 89 59 80 80 65 61 66 75 7261.86 70 57 117 62 56 89 70 64 69 81 65 69 70 68 7461.88 66 69 89 77 73 73 79 88 80 85 55 58 72 78 72

61.9 56 55 112 54 83 77 80 68 90 86 77 63 89 87 9761.92 84 56 102 85 72 95 107 97 74 88 84 77 75 81 8261.94 80 73 117 81 89 84 93 81 104 91 76 89 76 98 10761.96 81 66 116 68 78 83 76 92 110 81 73 61 89 107 9161.98 90 66 97 73 73 68 83 90 105 108 88 89 92 114 89

62 114 74 131 79 76 104 92 81 98 65 79 77 119 107 8862.02 133 98 101 86 82 76 106 95 111 85 91 53 110 93 72

332

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

62.04 134 74 111 115 79 88 97 78 85 103 87 65 125 102 8362.06 144 65 121 86 87 89 82 84 83 78 74 77 112 92 9862.08 157 62 105 77 100 77 74 58 77 97 79 48 109 99 91

62.1 116 66 100 86 94 82 77 79 91 88 78 47 115 89 9662.12 128 54 103 96 76 106 82 85 80 88 69 46 110 94 8262.14 114 52 96 101 93 95 75 68 91 65 60 47 96 105 8062.16 84 56 90 88 83 81 67 84 99 65 59 28 90 93 5662.18 99 57 87 91 83 81 77 76 101 74 63 45 95 86 62

62.2 110 61 78 75 88 83 67 68 91 68 72 44 80 102 6962.22 92 55 90 60 77 87 84 68 104 85 63 30 82 82 7462.24 94 67 72 85 58 72 74 55 92 69 64 25 89 103 6362.26 84 53 66 79 71 79 92 63 77 68 57 32 70 79 5962.28 78 42 63 63 72 79 86 71 72 58 52 47 66 77 69

62.3 75 48 87 76 73 66 56 58 66 56 35 35 61 80 5262.32 78 37 75 68 72 66 79 59 77 45 56 50 68 81 6062.34 63 51 65 60 78 68 55 69 74 44 48 44 64 77 5062.36 71 51 72 69 66 59 70 62 68 54 56 38 51 62 4262.38 65 42 92 67 81 61 68 58 70 43 63 44 54 72 40

62.4 56 38 61 51 68 64 58 51 53 64 51 47 51 79 5262.42 58 36 60 66 63 63 81 53 58 54 51 53 48 58 4662.44 49 40 86 75 72 40 56 56 68 51 50 43 60 59 4562.46 52 47 58 61 55 55 47 63 72 48 46 33 64 61 4662.48 45 40 67 53 57 57 74 59 61 57 52 38 41 58 47

62.5 65 36 56 62 64 48 55 46 76 59 57 37 64 45 5862.52 41 43 69 53 54 60 63 52 59 52 44 26 52 59 3162.54 52 49 61 48 57 50 66 52 58 53 55 36 54 44 4462.56 51 36 65 60 58 76 71 50 58 57 51 34 54 51 5262.58 56 45 65 52 65 47 64 44 63 44 52 32 42 51 42

62.6 40 52 58 60 56 60 67 49 52 37 44 34 51 54 5262.62 58 33 78 59 49 53 61 52 70 52 39 44 45 42 3762.64 61 34 71 52 57 61 67 59 60 66 69 38 41 46 4562.66 53 45 69 51 56 52 64 48 59 50 54 49 49 54 4862.68 35 51 63 48 50 58 68 46 54 50 48 41 67 63 37

62.7 51 31 75 44 39 38 65 60 65 45 57 39 54 58 5962.72 52 33 68 51 57 54 62 50 70 50 72 39 49 54 5062.74 52 45 71 61 46 61 52 48 70 37 55 64 37 52 4462.76 41 44 55 56 59 48 70 55 65 58 48 48 42 60 4562.78 42 34 61 62 52 69 74 69 64 50 69 49 57 61 55

62.8 56 40 60 60 56 56 67 66 62 52 44 41 63 54 5262.82 55 39 55 51 48 57 64 69 56 64 41 48 54 55 5062.84 74 42 65 77 65 63 74 76 61 66 49 37 52 52 5162.86 52 43 64 61 65 58 67 88 78 55 64 49 64 43 51

333

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

62.88 58 32 62 55 69 54 70 73 86 63 65 50 51 69 6862.9 58 34 67 69 70 69 75 89 87 54 45 33 52 72 54

62.92 40 33 50 69 77 65 79 90 69 55 74 40 62 63 6162.94 60 36 63 70 71 56 90 107 69 66 89 56 58 55 5662.96 50 31 59 66 63 58 80 98 72 60 60 42 60 72 6362.98 76 47 64 54 68 68 86 96 79 70 80 55 66 69 60

63 59 40 63 71 69 83 95 116 89 72 70 58 59 65 7163.02 73 50 69 77 72 85 124 123 96 82 90 62 83 59 5863.04 66 50 58 89 78 80 117 119 91 89 96 70 66 70 8363.06 60 42 56 89 88 94 111 134 96 98 98 74 84 76 8563.08 84 44 68 105 93 84 113 146 126 111 102 68 89 86 90

63.1 73 42 71 107 84 91 116 172 104 106 130 111 86 72 10363.12 73 70 77 89 118 104 162 186 124 100 142 116 97 90 11463.14 97 49 77 84 127 113 155 197 129 113 154 101 83 87 11563.16 104 56 82 141 131 105 190 208 136 112 177 111 99 99 10563.18 96 72 83 120 140 127 194 239 163 113 197 147 117 112 145

63.2 107 70 79 125 148 126 189 218 169 149 188 129 127 118 13463.22 142 89 76 160 186 148 190 286 209 156 222 142 132 119 15963.24 157 90 93 164 178 166 259 321 194 187 226 154 148 142 18763.26 135 112 85 203 199 176 251 342 226 174 272 204 170 139 20163.28 171 126 106 209 203 212 298 348 235 264 302 215 196 178 259

63.3 182 144 107 228 244 228 289 395 280 306 346 224 211 229 31263.32 205 160 130 248 244 266 334 390 298 355 393 318 264 246 34963.34 231 212 199 303 284 275 376 434 345 467 474 350 344 306 41363.36 285 254 184 300 297 341 406 436 342 541 529 425 426 376 48663.38 382 357 273 391 359 353 420 463 426 588 581 443 495 466 576

63.4 453 411 265 417 393 385 404 458 394 657 565 567 632 503 63863.42 573 406 295 453 405 415 402 422 427 627 549 520 728 675 58963.44 631 400 298 457 444 402 406 429 474 522 486 474 791 632 58563.46 775 358 291 503 510 434 390 392 460 466 485 398 815 686 46363.48 771 332 294 510 481 448 360 386 466 431 432 328 774 600 439

63.5 732 269 237 523 493 420 365 346 467 402 408 232 672 559 38763.52 645 269 262 503 399 464 352 357 449 374 348 165 613 503 39263.54 587 230 222 479 405 442 349 317 431 388 350 184 509 431 39563.56 485 215 214 453 332 405 298 312 458 375 326 164 500 418 38263.58 380 206 192 410 304 374 310 264 395 364 321 107 443 386 349

63.6 393 218 184 408 327 347 272 306 413 309 314 63 450 362 33963.62 437 227 185 410 291 378 247 232 391 297 228 90 455 383 27763.64 448 186 207 388 277 327 252 231 314 229 217 80 393 336 24163.66 401 162 149 320 287 333 203 205 312 197 184 64 370 314 19563.68 381 152 134 312 246 263 200 155 286 163 171 66 342 260 178

63.7 311 78 147 317 211 261 182 160 292 137 143 71 257 227 137

334

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

63.72 251 92 80 271 206 203 185 137 249 130 106 61 227 194 12663.74 171 102 106 250 167 213 168 132 255 103 116 58 187 173 11063.76 159 83 105 215 149 203 172 134 212 93 103 72 153 129 10263.78 143 64 97 177 129 167 158 105 211 91 107 60 125 123 117

63.8 119 62 92 183 102 145 118 116 162 105 103 68 112 114 8263.82 128 52 79 163 91 138 121 96 153 80 89 47 110 108 8063.84 84 46 85 146 102 130 128 100 155 83 85 73 108 95 5063.86 100 50 82 128 82 101 129 86 163 82 93 67 93 109 8363.88 99 57 71 133 98 114 113 112 101 88 83 53 87 83 91

63.9 87 52 87 105 86 108 101 100 124 78 90 61 79 81 7163.92 77 48 70 83 78 111 108 78 107 79 89 52 79 77 5463.94 63 47 99 114 84 117 90 72 120 65 90 53 73 76 6963.96 78 62 79 109 78 102 107 84 112 59 75 55 78 82 7163.98 78 54 83 94 87 93 108 85 111 75 66 51 71 54 86

64 72 57 97 98 84 69 126 95 92 80 93 55 69 77 6764.02 91 51 82 99 86 65 120 86 85 71 96 55 83 71 7864.04 83 44 74 91 91 101 124 80 114 68 95 50 72 73 7164.06 57 52 75 85 73 73 119 88 106 84 87 57 63 62 7864.08 56 58 71 75 77 82 128 91 94 82 112 62 65 66 71

64.1 69 50 78 81 84 75 121 93 102 89 111 55 86 90 7864.12 73 50 86 90 104 74 107 107 91 83 80 55 84 78 7264.14 45 41 86 84 64 68 118 95 107 77 112 63 75 82 8764.16 64 59 93 85 84 86 117 102 86 85 100 67 76 84 8564.18 66 58 88 93 92 81 109 118 85 111 103 75 76 84 82

64.2 68 60 72 84 88 104 134 130 113 99 95 87 68 75 8364.22 88 61 80 91 107 89 138 114 105 100 120 95 95 62 10464.24 74 52 95 90 122 78 126 124 124 111 100 72 81 90 10464.26 76 75 68 94 91 88 125 150 112 92 126 96 86 86 10064.28 87 58 87 105 107 95 146 163 116 121 147 99 85 96 116

64.3 94 67 94 99 97 102 144 145 142 111 149 91 94 106 12864.32 93 68 111 118 118 115 171 172 128 147 172 107 107 107 13864.34 108 55 91 131 100 121 174 197 154 166 146 134 134 104 18364.36 99 90 98 125 126 131 167 202 151 183 222 125 127 124 18964.38 129 101 96 133 128 154 179 207 139 208 186 148 163 145 241

64.4 135 107 94 162 126 160 175 211 174 243 229 165 172 177 24864.42 151 117 114 158 151 167 195 207 179 289 232 200 193 206 27764.44 174 143 115 160 158 196 185 219 215 295 279 156 184 244 30864.46 200 145 126 201 162 179 165 218 188 291 230 211 237 267 30864.48 214 186 143 220 182 207 196 220 190 259 233 214 286 268 292

64.5 308 182 145 256 203 196 198 223 219 248 241 195 279 277 31464.52 336 186 143 218 182 202 200 202 227 246 220 197 294 268 27564.54 367 155 152 260 200 223 203 252 214 219 211 145 321 276 245

335

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

64.56 355 135 126 249 224 218 190 218 231 248 251 152 280 244 22864.58 371 123 152 223 214 197 182 213 218 229 205 151 257 247 240

64.6 287 128 125 207 223 217 165 184 224 221 217 103 235 231 22464.62 250 127 119 226 194 208 175 214 222 215 217 119 234 217 23364.64 281 118 115 215 219 194 175 199 216 192 200 85 226 221 20264.66 236 102 102 241 170 191 162 176 198 198 217 88 212 182 19664.68 236 105 127 194 156 187 161 224 205 200 190 76 179 185 156

64.7 213 115 115 221 182 185 149 167 181 168 210 78 192 183 13464.72 207 99 102 212 177 169 168 200 185 156 169 99 182 164 15964.74 240 99 94 160 179 179 166 185 187 152 194 84 140 165 14764.76 205 83 103 178 156 186 165 188 182 127 161 63 173 136 12864.78 186 70 104 185 167 179 145 174 154 117 168 86 155 153 133

64.8 150 79 83 159 144 168 163 160 185 123 150 93 130 136 11764.82 141 84 84 172 142 170 178 161 194 117 164 88 117 116 13364.84 116 75 77 139 126 130 180 171 206 131 160 94 113 113 11464.86 114 75 91 163 143 164 190 177 188 123 151 88 131 108 10664.88 119 56 83 151 138 143 175 183 209 112 127 117 121 121 123

64.9 122 71 86 150 124 153 175 172 164 116 144 106 129 119 13464.92 117 75 92 129 150 176 188 206 183 108 127 113 96 86 13164.94 103 67 78 157 153 167 173 176 187 127 163 121 110 109 14064.96 105 82 72 139 114 155 201 187 171 157 173 131 118 130 14564.98 116 87 94 145 156 173 184 212 201 177 167 114 133 146 162

65 119 97 100 188 144 171 186 200 199 197 174 142 180 153 17765.02 165 119 93 170 153 166 199 182 225 225 200 182 178 159 23165.04 168 109 110 179 154 171 198 228 247 274 209 168 206 193 20565.06 160 136 140 200 162 177 204 224 257 277 212 160 203 200 23765.08 199 136 147 217 180 208 172 230 205 295 217 208 240 216 293

65.1 235 152 139 227 177 196 216 194 252 291 228 210 257 286 26165.12 269 164 151 245 187 236 183 215 227 295 209 202 319 298 25365.14 327 190 164 240 198 221 193 204 250 295 218 189 323 272 26765.16 347 193 168 245 215 247 213 205 259 263 217 209 346 291 26765.18 387 181 152 282 242 240 183 198 273 242 209 178 349 282 223

65.2 413 184 171 256 229 235 223 233 274 248 215 143 372 296 22065.22 418 152 159 269 235 192 195 209 237 230 190 152 320 298 18565.24 394 124 153 267 208 243 169 181 219 236 200 128 307 267 24165.26 333 155 110 264 209 210 175 201 276 215 168 104 303 241 17165.28 324 137 123 267 190 233 185 181 234 194 138 92 256 220 172

65.3 263 115 125 245 194 197 164 177 216 201 182 96 257 217 17265.32 275 136 127 209 165 209 155 157 206 162 153 70 233 205 17965.34 264 132 117 206 167 209 153 142 241 160 141 74 251 186 15365.36 268 120 125 200 187 174 157 139 187 135 128 75 236 210 15165.38 265 90 110 210 166 179 156 164 199 155 105 54 201 198 129

336

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

65.4 232 90 111 194 163 185 137 145 177 118 108 63 186 163 12565.42 219 78 86 180 157 153 130 117 175 117 105 61 181 152 10865.44 179 70 96 158 144 149 129 145 172 102 99 65 161 138 9565.46 151 70 78 165 118 166 124 132 202 87 83 53 134 122 8265.48 147 65 77 132 117 118 122 136 142 80 106 51 107 110 94

65.5 120 69 67 132 98 127 114 148 146 83 85 71 87 118 9365.52 110 41 61 114 90 115 90 155 161 101 87 42 80 91 8765.54 81 64 76 121 85 136 102 162 135 87 65 57 86 90 6065.56 95 38 68 105 92 96 102 113 133 106 74 68 99 84 8365.58 97 60 56 100 97 103 113 116 114 117 65 59 82 80 71

65.6 72 35 67 103 86 106 110 113 113 164 70 73 89 65 5465.62 73 51 80 98 83 101 105 119 101 236 76 62 74 87 6665.64 80 58 64 89 72 115 102 120 131 264 85 77 60 93 7665.66 67 57 65 95 79 110 93 134 121 227 67 85 85 91 8065.68 91 37 58 90 70 87 91 123 119 209 69 68 53 68 90

65.7 68 55 65 84 106 96 105 136 119 175 83 84 75 88 7665.72 80 61 78 82 77 92 102 126 111 156 89 59 82 88 7765.74 77 44 67 98 84 90 94 127 110 111 102 77 73 87 6765.76 73 46 60 88 107 82 115 122 114 140 80 75 90 69 9165.78 84 61 67 81 116 99 129 143 115 140 99 72 67 83 89

65.8 82 70 65 108 101 102 117 129 120 138 89 65 83 95 9265.82 65 59 71 81 98 100 119 124 112 178 104 88 98 104 9565.84 92 53 82 94 86 106 138 142 147 172 113 89 100 76 8865.86 97 62 90 99 127 114 129 136 144 159 128 89 99 96 10065.88 98 69 82 108 123 92 148 135 137 143 127 94 112 107 102

65.9 117 102 76 118 122 102 140 137 134 162 138 115 122 120 12665.92 122 66 72 112 104 131 133 151 156 162 113 102 117 115 12365.94 112 100 83 120 126 128 140 149 146 188 138 155 125 121 14665.96 137 110 100 126 124 167 172 152 192 202 179 122 125 125 16865.98 162 108 98 159 141 155 174 175 175 222 189 161 162 177 174

66 157 116 121 165 159 147 174 176 175 236 179 194 180 184 22266.02 187 135 133 152 172 150 148 172 177 274 195 183 243 213 21366.04 231 145 149 198 178 171 165 155 172 267 204 214 255 215 22766.06 265 149 141 209 170 169 179 144 198 303 216 198 274 219 21566.08 285 158 135 203 171 194 159 153 183 231 186 178 296 246 196

66.1 307 154 146 185 205 157 167 151 196 233 167 153 277 229 16866.12 327 142 154 197 193 194 159 164 197 210 141 159 270 268 21166.14 291 119 122 206 206 185 153 156 209 159 158 118 304 220 18466.16 274 127 103 210 184 179 152 139 218 192 150 97 233 224 17566.18 261 108 107 227 163 189 148 110 189 167 168 78 234 158 144

66.2 233 111 121 207 158 135 135 145 225 179 142 67 194 211 16466.22 217 83 110 163 145 170 150 128 153 179 157 60 185 180 156

337

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

66.24 249 122 103 175 136 167 133 132 178 173 133 66 217 172 13466.26 194 103 112 184 139 156 133 115 213 155 110 54 188 180 14766.28 217 103 97 161 109 129 132 124 180 125 124 61 199 162 117

66.3 204 74 85 173 134 168 127 90 162 114 98 54 172 128 7566.32 205 82 79 171 130 148 125 105 163 99 86 48 155 128 11166.34 165 65 74 133 119 103 99 90 138 79 84 70 124 93 8166.36 147 58 83 144 86 102 108 90 141 85 82 37 130 104 7766.38 136 55 86 141 110 104 98 76 142 87 78 65 98 122 61

66.4 133 61 60 101 94 109 94 87 138 80 73 61 103 91 6866.42 124 36 73 107 85 96 86 80 136 71 60 47 94 84 8066.44 93 52 56 112 66 82 80 72 95 71 72 56 79 75 5666.46 75 39 70 102 79 87 90 77 104 65 43 59 77 68 6066.48 66 51 69 101 78 95 88 69 96 72 49 62 63 72 55

66.5 93 58 61 100 67 112 94 91 89 58 71 36 62 74 6266.52 89 45 58 63 77 90 89 77 101 64 59 45 51 80 6066.54 57 50 49 91 69 82 100 87 91 56 59 60 71 72 5966.56 75 34 43 73 83 78 78 58 94 65 56 58 55 62 4166.58 60 33 60 69 56 75 69 68 91 36 56 36 56 61 57

66.6 65 55 57 68 55 75 73 69 69 54 54 43 71 68 4966.62 53 43 58 73 64 59 65 78 89 62 60 48 66 63 4066.64 60 42 65 61 56 95 66 74 83 63 55 39 64 67 5166.66 69 34 61 63 59 54 71 67 78 52 48 55 73 54 7566.68 60 21 62 62 62 82 70 65 75 57 42 46 50 63 53

66.7 57 31 60 59 60 79 87 72 85 72 53 51 53 66 5466.72 62 45 36 65 60 77 90 84 84 49 53 40 52 65 5766.74 53 36 53 64 78 57 64 81 86 41 56 37 70 65 6366.76 63 46 57 68 66 63 65 70 88 52 49 50 69 58 6066.78 50 35 63 52 57 71 76 75 66 51 51 53 48 66 52

66.8 60 39 64 63 52 42 94 83 74 44 54 51 53 74 6066.82 58 48 39 80 66 69 89 97 88 49 58 51 54 83 5966.84 55 50 48 90 71 66 82 85 70 62 57 55 57 50 4666.86 68 38 46 81 55 81 74 85 106 48 67 41 48 75 7666.88 55 34 60 77 66 59 85 84 75 61 63 38 62 68 59

66.9 61 52 68 70 65 74 115 117 76 72 58 55 69 73 7066.92 56 49 64 66 64 61 84 103 81 57 58 73 79 76 6566.94 64 38 60 77 79 67 109 103 102 52 67 68 63 73 7566.96 74 49 68 65 57 99 101 114 94 64 71 50 92 86 7366.98 63 49 60 98 98 76 89 135 91 74 68 71 52 98 68

67 70 54 64 79 66 93 113 142 105 77 85 59 74 95 7567.02 74 50 65 93 86 71 129 130 113 76 95 81 68 80 9067.04 77 56 72 87 106 89 138 156 126 100 98 78 81 128 8367.06 93 68 74 99 109 97 131 183 127 100 114 87 87 113 72

338

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

67.08 79 70 75 112 113 98 145 222 147 104 108 91 113 101 9067.1 87 73 74 103 117 132 150 211 150 113 116 73 86 110 114

67.12 95 72 61 126 121 125 180 245 166 123 145 114 119 109 11567.14 126 65 79 147 162 109 205 272 183 126 160 115 122 124 13567.16 124 84 87 143 155 133 231 271 187 141 171 147 152 136 12867.18 148 105 94 174 173 152 235 332 219 154 180 166 116 144 154

67.2 149 94 106 182 182 158 232 357 215 197 215 181 148 146 16167.22 161 105 103 212 237 202 262 380 242 209 226 216 194 173 21867.24 181 131 127 234 235 227 291 370 289 244 253 254 207 191 26867.26 190 145 156 235 255 267 346 436 294 303 284 291 235 219 32467.28 261 151 170 275 299 313 330 427 314 415 380 356 294 265 427

67.3 294 262 171 329 279 306 409 457 379 490 380 449 342 338 54867.32 343 312 233 361 325 350 410 477 435 588 507 548 412 436 59767.34 465 344 276 406 363 372 416 458 438 659 570 597 510 472 70467.36 531 375 347 442 398 430 479 434 460 776 478 569 645 636 74767.38 726 428 315 519 492 481 412 480 484 760 520 581 783 664 685

67.4 782 431 368 561 509 460 443 470 533 653 517 568 881 656 66667.42 888 404 348 583 534 470 430 428 494 541 411 434 893 642 53967.44 945 359 346 601 569 478 392 437 556 490 359 333 851 646 48767.46 899 281 316 536 553 447 426 383 568 443 362 259 720 536 39567.48 761 250 249 600 520 468 400 389 480 352 302 252 547 508 373

67.5 693 228 220 544 438 405 385 362 509 383 279 185 478 435 41467.52 532 218 226 546 391 441 370 302 512 380 324 108 490 433 38567.54 508 199 214 518 357 386 315 313 436 421 323 96 463 409 41567.56 502 247 210 458 306 370 326 303 444 386 281 58 459 415 33667.58 508 252 208 464 312 348 302 275 420 348 264 81 471 408 328

67.6 538 201 197 388 299 398 251 251 426 314 225 41 486 384 30467.62 558 217 184 395 351 306 270 228 360 256 205 64 435 323 20667.64 484 181 188 368 301 299 230 204 336 240 195 46 406 290 20367.66 431 174 164 336 290 259 276 184 331 178 150 63 300 267 16767.68 371 146 166 337 234 271 206 138 312 130 113 57 246 198 166

67.7 338 147 169 276 224 229 205 150 267 142 111 65 199 164 15167.72 252 122 153 285 201 222 217 131 242 105 95 76 188 149 15167.74 216 105 127 234 174 193 193 137 230 93 100 71 134 155 13867.76 152 86 132 232 148 189 190 112 188 103 72 70 136 131 12567.78 146 64 102 177 165 152 164 112 194 68 56 73 108 114 101

67.8 124 62 103 152 114 152 144 91 190 72 66 61 102 105 9167.82 94 75 99 125 108 131 129 103 176 70 64 49 105 89 8567.84 100 65 86 124 80 127 106 91 164 84 55 56 85 90 8067.86 106 69 94 111 126 112 109 86 126 74 69 42 90 87 7367.88 81 69 97 122 99 93 97 67 121 60 46 45 84 72 70

67.9 93 67 88 96 91 88 105 81 107 57 50 25 63 65 86

339

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

67.92 63 63 106 91 88 100 129 60 110 61 57 29 66 77 6567.94 72 54 78 72 96 96 117 73 104 58 64 27 65 103 7067.96 64 43 86 82 72 89 110 59 98 76 50 44 57 68 6467.98 65 38 80 90 78 101 88 70 91 67 42 41 55 66 57

68 62 59 56 75 59 64 92 80 82 49 44 36 67 56 5568.02 64 57 84 60 69 73 85 56 88 54 44 29 60 60 6368.04 62 63 71 62 75 67 74 64 83 69 60 46 55 73 4868.06 63 50 98 72 78 75 79 71 71 70 45 40 54 55 4868.08 60 80 101 74 96 73 65 57 75 55 49 40 51 54 75

68.1 63 92 122 85 98 67 112 57 76 61 43 44 69 67 6568.12 73 68 112 66 92 68 127 70 74 61 53 45 41 46 7968.14 62 60 116 78 93 80 148 64 84 53 60 50 66 52 8368.16 63 59 93 62 87 75 151 48 71 59 51 29 47 56 9468.18 50 39 99 79 80 82 96 58 81 44 51 38 63 60 71

68.2 52 40 114 50 64 64 97 40 75 55 53 37 51 58 5668.22 64 51 105 58 86 56 87 50 69 55 35 39 55 52 6068.24 55 53 106 61 69 84 87 58 83 66 35 33 48 63 5468.26 59 64 113 58 84 81 110 76 76 50 50 50 50 67 4268.28 50 70 131 58 66 82 101 48 63 68 46 41 60 64 66

68.3 52 64 116 60 78 75 115 53 59 57 57 37 47 65 6368.32 62 78 97 71 63 80 140 30 44 60 60 47 36 70 6568.34 46 51 123 63 81 78 118 54 64 49 46 40 56 74 6168.36 58 44 124 54 79 65 90 46 57 36 54 47 49 68 5968.38 50 43 82 57 52 71 89 52 55 44 39 46 50 53 59

68.4 57 46 71 54 65 60 84 41 57 51 45 37 46 54 4668.42 52 48 59 68 67 50 78 36 45 61 38 38 42 56 4168.44 37 58 60 35 69 54 79 28 54 44 42 42 58 42 3568.46 48 45 72 36 50 50 68 49 56 40 34 34 35 58 4568.48 44 41 74 52 56 43 69 34 55 47 39 42 44 59 37

68.5 46 57 75 49 59 43 59 28 43 42 41 34 43 45 4368.52 45 39 70 48 61 49 70 40 51 33 39 27 38 59 4468.54 48 32 68 42 43 47 71 46 57 45 33 25 43 53 5368.56 50 32 64 44 53 45 64 44 38 44 47 26 41 62 4568.58 53 42 54 36 52 44 48 53 40 41 31 22 43 44 36

68.6 49 35 51 36 49 42 53 32 49 52 37 21 37 55 4168.62 41 22 63 43 44 39 51 27 46 34 45 26 48 44 3068.64 33 39 58 38 52 46 50 35 42 41 49 24 40 50 5768.66 44 30 58 54 40 33 52 36 40 36 50 28 46 55 4168.68 49 42 58 49 31 44 58 28 36 53 37 35 45 35 33

68.7 46 42 70 57 46 47 59 44 53 36 36 18 36 59 3668.72 38 40 55 42 53 37 47 39 40 44 44 40 49 59 3968.74 32 37 62 41 33 43 46 35 40 42 38 41 43 54 50

340

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

68.76 42 29 56 35 41 39 44 54 44 31 40 30 48 54 4168.78 52 21 68 36 51 41 38 51 51 35 37 43 34 37 40

68.8 45 37 45 45 55 45 47 39 40 47 36 29 51 41 4268.82 42 32 50 49 43 52 62 40 48 44 40 35 38 45 4968.84 40 37 62 47 45 40 44 41 60 38 42 35 54 35 3768.86 47 33 56 40 31 46 49 37 43 44 37 31 44 42 4068.88 32 39 59 46 46 37 44 38 41 39 29 26 44 43 41

68.9 46 25 73 34 47 27 66 37 39 51 31 40 38 43 5068.92 39 30 62 43 49 30 47 34 45 32 30 34 34 40 2768.94 55 38 55 47 55 35 57 34 41 45 24 20 38 44 4968.96 48 34 73 50 32 47 44 39 47 53 36 23 24 27 3468.98 40 44 68 44 50 37 57 39 52 39 36 27 42 29 36

69 44 35 53 41 44 43 48 23 48 42 36 19 40 52 3269.02 50 34 51 52 51 34 46 36 64 47 39 25 50 43 3069.04 41 29 58 45 60 35 43 43 55 36 45 33 54 44 2969.06 30 39 58 34 45 46 45 44 39 37 52 30 50 47 4469.08 43 38 59 35 53 39 43 55 43 36 38 26 57 45 52

69.1 47 43 59 40 29 42 59 48 44 41 38 26 45 44 2969.12 29 39 59 47 44 56 40 35 49 47 45 44 40 44 4269.14 35 41 55 47 46 38 51 46 56 46 41 32 42 51 3869.16 51 32 65 36 37 48 51 41 49 42 40 46 37 50 4869.18 32 33 66 45 43 45 42 42 46 38 39 35 41 40 43

69.2 35 39 64 40 44 45 53 38 41 60 44 38 48 50 4469.22 51 41 54 38 50 41 50 40 50 43 38 32 50 39 3569.24 44 29 53 45 44 52 60 29 66 56 32 31 39 41 3769.26 36 43 54 45 48 41 55 47 58 63 43 22 37 42 4969.28 45 36 57 48 39 46 53 43 56 31 39 42 59 30 38

69.3 35 33 44 43 64 49 51 47 44 40 55 30 51 45 4069.32 58 42 68 43 37 36 44 45 65 34 34 27 31 48 4269.34 45 32 69 38 54 41 59 44 52 55 44 34 51 43 4469.36 36 33 73 49 66 55 49 48 44 53 29 32 41 48 4469.38 40 32 49 37 49 42 43 37 54 46 36 26 43 35 42

69.4 43 31 51 54 40 49 47 40 49 42 50 20 50 54 3569.42 42 37 67 38 50 39 55 52 44 44 47 28 50 47 4569.44 36 38 53 40 41 41 54 44 50 37 42 30 49 49 5569.46 49 43 60 46 50 55 51 50 51 46 50 40 40 42 3769.48 48 36 72 62 53 39 57 26 60 48 51 29 40 38 41

69.5 43 30 67 48 48 40 49 39 61 53 35 39 40 39 3469.52 49 38 67 50 45 49 54 45 49 48 40 20 49 34 4869.54 42 29 71 35 44 57 65 49 50 47 55 31 53 55 4269.56 52 30 61 52 46 42 48 39 59 44 35 35 44 50 5369.58 47 48 75 50 44 64 69 42 52 47 37 29 41 54 39

341

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

69.6 59 28 70 47 59 51 55 52 56 46 37 47 45 42 5169.62 48 42 62 48 44 38 56 42 39 41 41 45 48 56 3969.64 35 41 61 56 38 44 58 41 51 48 40 32 37 47 3869.66 50 26 45 52 52 53 44 53 53 34 53 41 51 50 4669.68 54 38 57 54 47 51 48 61 47 39 51 29 43 34 36

69.7 52 36 65 56 42 40 57 51 53 58 48 36 54 41 5369.72 52 45 68 55 46 49 59 57 50 48 46 32 37 52 4269.74 45 30 46 46 60 47 52 67 49 44 51 24 47 59 4869.76 47 41 69 65 55 54 68 53 63 61 61 40 46 54 4469.78 38 38 53 63 50 50 57 49 65 46 61 40 61 42 55

69.8 55 38 64 59 52 53 71 65 53 49 45 51 52 42 4469.82 62 41 59 49 63 60 61 48 58 60 61 33 50 56 4369.84 47 41 58 67 61 49 63 54 69 67 57 52 44 55 5269.86 60 55 60 55 67 55 81 71 62 65 61 49 46 51 5769.88 47 45 56 46 73 54 74 73 80 54 52 31 44 71 65

69.9 62 43 59 48 53 49 88 66 80 60 74 56 71 59 6569.92 50 46 61 47 73 60 73 73 59 61 63 63 69 77 5969.94 65 56 67 55 74 65 79 57 81 58 68 66 70 74 5069.96 70 59 68 69 73 61 77 77 75 59 68 68 61 57 5969.98 84 49 70 50 70 51 84 84 81 87 92 30 65 82 58

70 70 46 79 73 86 66 88 90 76 72 74 62 64 75 7370.02 88 48 65 69 71 68 92 73 71 77 58 56 70 84 6970.04 78 52 60 66 80 83 80 66 79 75 58 37 70 72 7570.06 80 42 62 72 79 86 93 94 91 99 76 41 75 62 5470.08 74 43 63 69 77 88 88 97 97 74 67 66 61 75 66

70.1 74 50 86 72 85 60 105 105 96 75 100 47 66 84 5970.12 89 51 62 80 89 63 86 121 112 75 83 69 73 90 5870.14 72 34 81 73 86 92 103 93 95 69 82 69 91 90 7870.16 63 55 82 84 91 97 116 95 104 98 95 61 94 91 8370.18 72 58 67 72 93 70 125 116 110 92 75 76 83 75 88

70.2 80 51 71 78 97 92 108 121 122 98 82 48 101 79 9570.22 87 56 78 85 105 94 103 131 114 99 89 76 78 113 10870.24 87 65 76 87 105 93 154 127 123 119 102 81 107 113 9670.26 80 64 74 102 93 103 138 131 129 121 99 103 89 114 11770.28 84 79 83 95 102 91 143 138 136 143 114 86 102 111 141

70.3 100 64 75 141 102 124 155 169 151 128 110 110 117 127 16170.32 110 66 74 125 128 131 147 158 155 214 124 113 126 131 17770.34 117 82 75 154 117 133 157 178 174 177 132 144 119 149 17870.36 120 86 96 151 142 119 175 203 160 225 139 165 164 199 22870.38 140 104 82 161 106 166 169 188 183 225 124 159 179 230 231

70.4 167 118 108 165 130 133 179 204 180 215 143 198 190 244 23570.42 174 123 129 185 123 180 195 206 192 251 142 165 257 269 242

342

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

70.44 203 129 121 187 142 178 146 211 210 239 148 171 287 264 27670.46 280 159 148 229 143 176 178 179 203 268 165 170 313 277 25170.48 300 173 138 225 166 197 164 205 224 269 161 171 308 300 275

70.5 344 159 175 231 185 202 157 189 212 228 167 170 319 348 22670.52 425 163 168 219 172 175 193 204 227 226 132 149 343 335 23270.54 434 163 158 227 200 208 176 188 243 214 170 125 303 348 23770.56 429 155 133 244 195 201 178 171 253 192 174 70 320 271 21270.58 377 132 142 214 217 200 160 184 243 200 124 99 279 248 214

70.6 368 109 130 235 225 212 174 196 221 173 131 80 274 301 18270.62 317 111 110 224 179 181 154 176 209 175 140 69 280 236 17870.64 287 104 142 215 183 194 172 149 217 182 135 64 230 244 18770.66 267 108 94 181 181 185 117 133 218 130 132 74 220 214 17070.68 265 97 102 212 145 195 143 141 188 163 119 61 178 198 156

70.7 244 113 115 169 141 164 139 163 183 122 91 43 197 172 13670.72 250 101 110 163 133 164 128 115 191 136 100 46 186 186 13370.74 230 82 111 192 123 162 108 111 185 131 92 49 181 142 11070.76 232 73 116 162 149 136 108 107 165 92 85 74 144 133 9570.78 238 76 91 153 139 122 117 106 144 100 77 28 160 134 75

70.8 174 66 84 142 120 111 112 103 151 89 73 49 127 143 11070.82 149 58 95 122 106 129 101 93 118 92 78 56 116 113 7570.84 119 53 84 110 88 101 92 85 124 91 60 31 96 109 6470.86 119 47 84 94 67 104 90 86 113 83 79 28 96 82 7270.88 102 55 78 100 96 95 91 59 105 63 54 28 75 79 64

70.9 92 58 67 87 65 101 88 67 105 69 77 45 69 86 5770.92 79 45 65 103 70 105 79 83 93 49 62 33 69 71 5270.94 88 38 66 73 56 89 67 50 77 57 55 35 70 74 6170.96 74 43 47 65 47 87 77 58 91 71 58 21 62 58 5870.98 73 44 71 84 59 77 57 58 97 49 50 47 53 69 48

71 57 38 72 74 68 72 75 53 71 56 49 29 53 67 4571.02 42 40 50 61 41 62 64 57 90 43 49 22 58 57 4371.04 55 40 66 52 54 76 69 66 70 48 39 27 49 61 5071.06 54 54 59 54 44 64 66 68 72 41 55 25 66 56 5871.08 56 41 72 67 46 60 59 63 57 51 49 23 49 41 39

71.1 43 44 61 61 44 59 60 55 71 49 48 34 55 57 3871.12 42 36 51 59 42 63 54 55 65 53 28 21 63 51 3671.14 47 26 56 57 41 56 69 57 52 48 39 39 52 56 5371.16 45 33 55 56 43 70 54 47 51 34 43 41 40 45 4471.18 54 45 69 36 50 47 54 48 71 41 51 21 46 53 53

71.2 48 33 49 38 42 41 55 48 51 39 40 34 33 42 5571.22 48 38 53 44 43 45 57 53 53 43 43 30 46 49 3871.24 43 27 61 45 45 41 59 44 53 39 37 25 44 46 5471.26 54 36 59 51 40 53 57 39 54 36 43 33 51 60 45

343

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

71.28 43 34 69 41 50 46 42 44 39 35 46 22 45 52 5871.3 53 31 65 34 38 34 45 44 58 47 40 35 50 47 42

71.32 47 35 53 50 39 48 47 32 57 42 33 27 47 59 4271.34 51 38 64 48 41 46 57 38 50 44 41 23 51 52 4471.36 35 32 65 47 34 33 43 45 47 39 37 21 40 60 4171.38 46 34 75 51 37 38 60 37 48 39 37 29 40 52 30

71.4 48 43 75 43 43 45 51 47 46 34 34 34 63 62 3771.42 33 40 66 36 40 38 56 38 49 39 47 25 42 60 4071.44 43 35 65 50 31 36 37 39 54 38 43 27 38 60 3871.46 42 29 65 41 38 36 57 42 51 45 43 21 35 59 3971.48 38 53 88 53 39 37 51 53 46 32 30 27 49 73 33

71.5 41 28 62 41 54 49 58 35 57 49 36 28 49 50 3871.52 38 41 62 40 38 46 51 29 49 47 44 27 45 75 4171.54 49 22 84 37 44 36 47 41 51 37 37 28 24 62 5271.56 44 38 90 27 45 35 46 46 53 40 45 27 33 43 4471.58 41 30 62 33 35 42 48 36 53 36 41 33 33 55 44

71.6 41 37 65 36 34 36 53 33 52 34 28 24 37 64 3771.62 36 22 77 40 30 41 54 32 46 43 35 21 43 50 3371.64 45 28 68 46 36 39 36 35 46 45 26 32 38 39 4471.66 35 42 73 37 38 29 44 48 47 29 38 33 41 42 3371.68 30 37 71 34 30 40 40 40 29 36 52 20 44 59 42

71.7 41 30 70 39 37 50 42 40 44 38 37 21 44 52 3871.72 33 31 80 47 51 33 51 33 47 52 33 25 41 53 2871.74 45 34 73 49 49 48 45 40 38 35 41 24 37 49 3671.76 29 36 59 31 46 42 52 40 41 40 42 23 35 46 3671.78 45 26 66 47 41 45 41 43 36 42 32 20 33 35 55

71.8 36 41 82 45 43 39 56 39 33 34 36 16 39 47 3771.82 47 36 71 37 56 45 50 37 38 41 44 29 37 50 4271.84 40 43 61 47 36 48 39 33 55 34 46 25 44 43 4571.86 34 25 63 39 45 52 51 46 48 38 47 27 46 32 2771.88 32 26 83 37 30 47 49 36 43 34 27 26 47 48 46

71.9 40 38 62 45 36 41 61 32 43 36 28 30 53 38 4571.92 51 39 79 42 49 47 40 32 60 42 34 28 29 36 3271.94 46 40 69 35 52 45 50 46 41 35 36 25 38 46 3171.96 29 30 71 39 35 40 50 41 43 30 42 19 40 32 3471.98 46 36 64 44 44 48 42 36 47 42 45 23 37 53 24

72 35 28 50 49 52 44 40 44 47 39 29 20 29 58 5172.02 40 31 89 41 42 41 52 37 39 36 39 20 38 57 4272.04 50 35 60 46 31 26 48 46 54 38 32 28 39 47 4572.06 32 37 68 35 38 53 51 47 37 51 27 23 39 54 5372.08 42 40 74 41 48 40 43 40 38 46 32 23 29 30 42

72.1 51 33 75 54 40 37 49 33 45 35 37 26 45 40 47

344

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

72.12 42 38 69 35 38 40 54 46 51 34 38 29 46 51 3372.14 35 30 81 45 43 48 50 32 45 40 44 30 34 45 4372.16 39 45 71 54 38 30 45 39 55 33 39 42 33 43 4372.18 28 41 71 51 31 30 47 39 48 38 40 25 44 47 38

72.2 49 36 73 42 42 33 59 42 61 42 27 30 37 30 5572.22 48 42 76 44 32 56 61 34 37 41 34 34 30 59 3972.24 48 25 79 44 44 42 37 49 46 50 39 35 33 40 3572.26 32 47 71 47 45 43 50 53 36 39 45 38 42 40 4072.28 48 30 74 50 45 52 38 55 39 37 38 34 39 57 47

72.3 41 43 68 40 42 34 44 44 52 40 43 29 38 47 4172.32 31 43 74 40 51 48 59 44 52 44 43 29 43 47 3572.34 48 46 79 58 48 41 46 49 48 43 53 33 42 32 4472.36 44 41 84 46 39 44 46 54 47 48 44 26 47 56 4772.38 49 37 83 42 58 36 55 50 50 52 36 27 41 37 53

72.4 51 31 81 41 59 49 53 60 44 48 51 32 49 51 4472.42 53 33 82 49 58 54 63 56 58 44 50 23 52 56 4472.44 58 33 74 47 57 53 52 61 52 37 44 38 41 55 4072.46 34 38 76 47 56 54 69 49 64 53 52 27 56 40 5772.48 40 51 79 52 62 61 77 58 60 55 50 36 48 66 46

72.5 43 34 63 70 56 54 63 52 64 43 70 42 59 49 4772.52 50 43 75 44 69 40 70 68 63 51 61 31 50 45 4472.54 47 43 71 56 52 63 61 76 72 61 61 40 50 44 6072.56 40 47 78 58 57 71 79 80 71 67 60 48 48 55 6072.58 47 50 94 57 79 66 75 85 62 53 68 62 59 63 58

72.6 54 40 83 71 80 75 63 69 84 51 60 49 52 72 6572.62 60 44 80 72 78 76 86 94 66 87 65 52 63 62 8372.64 62 66 77 63 71 66 86 116 65 62 77 55 69 64 7572.66 69 44 77 61 74 68 101 112 88 79 80 56 91 65 8772.68 55 60 104 80 82 75 104 95 92 80 79 63 66 66 75

72.7 70 63 94 86 76 91 105 111 107 88 79 62 72 72 9172.72 67 72 97 89 90 102 105 126 114 116 97 76 91 93 9872.74 76 62 79 104 76 102 114 124 116 130 113 98 102 89 10172.76 91 69 102 99 70 91 132 128 128 145 117 89 115 101 11872.78 103 93 119 103 109 115 115 120 101 150 138 115 130 146 178

72.8 119 94 109 100 97 114 115 125 130 196 162 126 171 133 16472.82 123 102 117 133 124 111 129 139 138 177 156 127 140 179 16972.84 172 87 104 129 118 123 122 131 157 181 156 136 218 173 15772.86 198 127 150 140 139 147 112 113 177 156 121 147 230 194 16172.88 203 132 116 149 142 134 132 133 143 154 133 156 222 218 175

72.9 233 111 156 159 156 109 125 128 162 147 108 117 201 217 14072.92 231 111 141 157 161 125 106 116 156 152 118 116 223 186 11372.94 262 104 135 151 164 139 124 113 137 137 130 83 184 126 105

345

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

72.96 209 87 129 152 165 151 116 108 159 136 104 81 190 161 10772.98 181 83 110 151 131 142 122 129 171 135 86 58 183 152 125

73 169 103 131 129 115 144 124 124 135 117 102 46 126 144 11273.02 145 84 117 139 119 125 100 116 123 133 104 42 134 133 10873.04 159 90 117 129 128 129 104 126 127 134 100 38 133 150 9873.06 145 79 118 152 111 111 122 103 124 114 99 44 153 146 9673.08 126 85 100 131 108 114 94 95 150 114 91 33 140 117 84

73.1 139 77 82 116 100 119 103 102 129 82 97 32 136 121 9773.12 135 72 107 114 119 103 92 85 117 92 90 23 101 111 8973.14 138 64 104 94 99 108 76 84 135 89 86 33 132 98 7773.16 133 59 78 113 100 93 94 86 134 92 89 28 112 94 6073.18 116 64 86 102 86 98 82 70 110 75 64 29 89 97 61

73.2 97 56 97 96 98 99 92 71 110 66 72 46 83 93 5173.22 93 51 86 85 86 77 91 63 89 66 58 29 72 79 5673.24 76 37 70 87 77 75 94 69 103 58 51 32 64 63 5273.26 65 43 63 61 65 93 81 83 98 76 50 50 60 61 5273.28 65 54 77 84 81 57 74 64 92 57 50 25 67 63 53

73.3 71 47 62 67 66 71 81 44 76 51 40 40 59 71 5573.32 63 46 50 61 59 62 69 54 88 69 44 41 57 49 5473.34 55 55 81 69 45 58 56 67 89 55 51 44 47 44 4373.36 47 46 76 56 46 77 84 39 83 38 41 27 44 59 4673.38 70 57 82 69 63 64 52 52 87 50 57 56 39 55 50

73.4 58 39 77 69 76 69 73 59 68 45 39 40 45 51 4173.42 48 42 91 59 60 56 73 61 67 54 58 26 50 50 6173.44 51 40 81 61 62 62 64 50 70 43 37 42 39 60 5073.46 43 34 81 50 65 58 75 54 84 66 57 27 47 55 6173.48 39 57 81 67 55 55 71 44 76 49 53 29 47 50 50

73.5 51 31 70 55 67 47 72 36 70 46 46 38 49 44 3373.52 43 39 78 54 62 59 71 45 71 50 38 30 53 72 3773.54 46 39 67 52 50 36 83 50 58 41 44 19 38 65 3873.56 48 36 61 50 47 58 75 48 57 45 39 31 45 46 4073.58 54 38 78 55 43 48 55 50 65 41 50 29 47 50 46

73.6 42 37 68 46 36 61 57 46 66 50 36 23 38 51 4173.62 46 62 58 62 59 56 62 50 58 46 47 21 47 51 3973.64 44 43 69 41 45 52 67 42 73 50 41 38 40 51 4273.66 53 42 83 58 56 57 64 54 70 54 40 16 55 55 4273.68 42 44 57 66 61 54 61 43 64 50 44 35 41 53 48

73.7 48 47 65 38 51 54 59 43 57 53 48 34 50 64 5173.72 57 29 71 47 41 58 59 49 68 48 40 39 45 50 4873.74 41 41 63 45 43 60 70 35 58 43 43 29 41 63 4073.76 46 31 71 46 52 51 54 41 60 42 48 31 50 42 5073.78 50 38 66 44 63 48 60 44 63 45 37 36 49 36 44

346

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

73.8 39 33 71 39 49 56 52 49 53 51 53 45 39 62 3173.82 64 42 73 41 59 60 59 57 43 50 45 43 59 49 4473.84 37 46 63 52 60 32 47 38 61 49 51 40 42 45 3473.86 42 27 57 47 63 60 61 36 52 62 40 24 56 55 4173.88 52 46 63 51 72 64 57 50 64 45 40 32 61 64 39

73.9 45 35 56 62 59 57 43 43 66 47 43 37 37 62 3873.92 56 43 71 58 42 44 61 54 63 40 40 45 46 64 4473.94 40 42 59 58 45 51 50 59 55 48 42 34 42 59 4073.96 40 48 69 57 53 61 59 56 63 50 46 37 53 56 4773.98 42 63 81 52 53 42 71 50 48 57 36 45 45 55 54

74 57 34 59 50 45 52 64 53 64 47 39 34 26 51 4174.02 46 41 68 60 49 47 68 52 62 50 45 29 44 50 4474.04 49 31 79 45 37 48 72 51 55 52 59 26 53 54 6274.06 61 45 61 51 58 57 77 44 55 50 51 30 55 65 5174.08 49 35 62 52 50 58 55 55 60 31 45 44 39 58 45

74.1 48 52 59 47 51 62 69 64 64 54 47 40 51 73 4174.12 49 59 54 60 63 54 71 60 65 40 48 46 43 54 4474.14 45 38 61 53 57 59 78 53 73 54 54 23 52 76 5674.16 59 51 57 60 62 58 76 63 56 43 61 39 56 58 6574.18 60 59 70 58 63 46 78 56 64 46 58 37 53 67 57

74.2 59 59 53 58 72 61 74 65 57 41 54 29 48 99 4474.22 55 42 69 64 62 56 72 58 76 40 58 62 55 78 5774.24 62 48 67 61 64 66 77 63 88 46 70 48 45 74 6574.26 48 49 61 61 59 78 82 71 71 72 68 57 72 83 5374.28 63 47 66 50 62 56 83 69 76 65 69 51 42 62 61

74.3 53 52 58 77 66 72 73 82 79 67 62 41 54 73 5074.32 64 45 60 68 69 69 92 84 79 64 59 38 47 76 6474.34 75 46 72 59 54 70 71 63 88 57 73 32 71 69 7574.36 51 60 62 71 81 84 82 83 105 57 67 54 59 74 6974.38 53 50 71 61 70 73 89 91 96 69 74 50 63 75 65

74.4 70 49 63 65 80 75 94 95 96 80 72 72 72 90 7374.42 61 68 72 68 74 85 80 107 87 76 72 80 75 80 8774.44 56 54 72 80 76 85 108 99 110 74 75 49 72 101 8374.46 72 55 71 92 79 102 94 117 82 110 94 72 90 87 8074.48 87 65 84 100 75 87 76 123 111 99 88 57 85 84 86

74.5 85 60 88 95 81 90 111 113 127 118 81 80 102 111 9774.52 108 69 97 113 92 111 121 124 93 129 98 105 89 97 11274.54 103 78 79 118 105 103 114 147 115 135 108 109 108 111 10774.56 123 88 90 113 80 100 117 131 125 151 107 103 124 132 15374.58 104 94 85 134 121 122 119 112 118 166 132 140 124 130 136

74.6 132 82 92 157 97 113 140 125 133 155 124 125 160 153 15274.62 144 79 94 140 120 120 135 135 152 188 110 143 170 156 134

347

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

74.64 174 119 123 142 120 121 139 130 126 192 141 141 188 194 15174.66 167 128 103 146 127 112 160 131 131 210 132 135 225 184 15874.68 201 117 111 165 135 109 131 122 155 178 142 137 220 197 165

74.7 224 152 100 150 133 140 151 135 135 189 127 127 254 203 15374.72 260 132 111 155 152 125 144 138 135 158 122 103 233 195 15874.74 268 137 118 183 145 140 125 121 142 174 134 125 220 212 13474.76 280 118 132 179 133 133 133 130 140 173 117 91 199 191 15674.78 287 122 122 169 142 147 126 141 137 156 126 82 202 181 143

74.8 278 100 116 171 186 126 131 122 150 171 112 50 181 172 12574.82 221 106 115 177 149 129 126 124 132 143 104 67 166 171 12974.84 222 79 122 163 148 138 114 128 140 157 101 48 180 171 12174.86 208 105 91 157 94 128 124 117 125 134 112 63 159 158 12274.88 189 89 104 162 125 111 119 118 147 125 102 61 167 127 107

74.9 194 79 88 149 99 110 114 93 118 130 95 41 166 148 10874.92 176 96 82 156 116 105 123 98 134 117 103 67 157 133 11274.94 172 79 82 158 117 129 94 81 111 90 93 56 150 142 9274.96 158 80 98 126 114 119 97 96 102 92 66 22 157 137 8074.98 176 53 98 127 96 126 82 94 109 85 76 46 119 136 88

75 152 68 78 153 121 104 88 92 96 108 70 59 112 113 6075.02 144 63 89 114 101 92 75 90 117 58 72 50 100 111 6475.04 135 67 75 112 82 113 89 73 96 85 74 50 96 76 8775.06 131 61 64 98 78 88 95 80 119 57 62 42 88 102 5975.08 116 55 71 89 82 96 75 57 88 78 60 33 79 81 62

75.1 105 56 74 109 86 82 83 68 96 64 63 50 72 74 5175.12 102 39 65 85 76 92 69 77 77 64 74 40 64 69 5975.14 80 48 76 83 58 70 68 57 98 64 47 25 94 53 5675.16 85 34 41 85 69 91 75 55 88 49 53 28 60 87 5075.18 74 44 59 81 70 78 73 53 84 58 65 50 52 61 53

75.2 77 35 61 75 59 65 72 49 93 50 51 31 56 67 6675.22 66 49 76 71 72 63 71 58 75 56 54 33 65 55 5075.24 62 31 62 68 62 82 66 59 83 41 42 26 56 49 5375.26 53 42 57 51 48 64 61 72 66 50 40 39 53 57 6175.28 59 50 53 64 64 54 59 42 48 46 34 39 46 56 55

75.3 49 34 53 67 45 61 74 49 64 44 35 48 57 62 5375.32 39 39 53 57 48 44 51 63 65 57 42 34 51 47 3775.34 65 43 61 60 42 70 62 37 55 58 59 35 52 47 4475.36 47 41 48 64 46 48 49 45 63 45 49 31 39 46 4675.38 45 50 39 64 64 57 61 48 61 38 52 44 53 43 50

75.4 48 29 61 44 72 47 49 34 65 47 56 21 45 51 4875.42 67 49 72 53 42 44 50 39 49 47 46 41 47 46 5675.44 41 34 51 54 46 58 52 50 64 38 41 27 29 64 4575.46 48 37 41 60 43 49 67 44 70 46 32 35 49 42 46

348

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

75.48 56 36 42 55 51 40 66 46 68 49 56 39 37 46 3675.5 37 31 58 45 42 58 57 41 40 34 45 38 50 55 45

75.52 59 49 54 46 41 56 70 48 44 46 39 34 44 56 4375.54 52 44 62 44 44 57 60 42 54 46 35 31 39 40 3775.56 44 52 53 59 62 42 65 29 68 54 38 20 35 46 4675.58 40 39 56 47 48 63 62 38 63 47 28 32 44 52 51

75.6 55 47 64 52 65 57 59 60 54 45 31 28 38 38 5575.62 55 44 62 55 69 63 74 45 62 39 37 37 41 52 5575.64 52 52 78 40 65 50 95 36 64 49 41 28 54 61 6575.66 49 54 68 42 59 55 108 37 60 48 44 42 30 49 8675.68 50 48 58 48 53 53 77 32 52 49 48 33 44 62 85

75.7 58 46 61 42 54 47 79 47 48 45 40 30 56 64 5275.72 44 34 48 52 48 48 68 38 42 37 43 26 49 47 4875.74 34 35 63 50 36 46 67 52 59 42 35 23 38 54 4875.76 48 48 48 57 60 50 54 45 61 41 35 33 49 36 4575.78 49 36 49 41 49 48 48 47 61 53 36 33 50 34 38

75.8 42 43 57 53 49 59 63 31 50 29 34 27 45 33 4775.82 35 42 68 43 39 45 64 40 60 30 33 21 46 47 4475.84 38 51 66 46 60 41 61 35 49 44 45 25 45 50 4875.86 40 37 63 46 50 47 65 51 36 50 37 38 41 49 5475.88 46 31 67 56 46 44 70 44 71 48 43 25 45 45 55

75.9 57 29 56 59 55 44 54 34 54 57 44 35 34 51 4575.92 41 42 59 40 60 43 59 45 46 38 46 37 56 43 4375.94 56 35 57 60 47 40 62 42 61 47 41 44 42 52 3675.96 46 39 48 52 44 44 49 50 53 35 38 33 48 49 4575.98 52 39 58 60 43 42 53 51 40 38 45 24 59 57 33

76 47 25 45 48 50 46 70 25 47 33 51 32 37 48 3776.02 62 32 68 47 40 42 46 44 44 46 43 45 41 59 3676.04 45 29 42 49 52 55 51 45 50 52 39 31 51 46 4576.06 42 37 52 56 37 37 59 37 61 45 35 31 39 43 4476.08 49 43 73 45 41 40 49 38 47 50 48 28 35 52 37

76.1 48 32 43 42 53 50 58 41 57 48 51 30 41 49 3576.12 35 36 50 42 45 40 59 44 59 37 49 21 57 48 4476.14 44 35 66 46 47 52 49 44 54 33 49 29 33 45 4676.16 37 34 41 34 38 51 70 51 58 48 43 25 50 51 4576.18 45 32 46 46 51 47 57 56 50 44 34 28 34 56 38

76.2 26 36 52 58 41 55 62 47 58 49 44 37 40 45 4476.22 45 39 52 52 55 39 65 63 58 44 36 38 36 39 4676.24 48 41 57 45 54 43 55 48 57 41 39 26 40 35 3876.26 40 29 46 54 37 45 56 56 47 43 44 42 50 46 3876.28 40 38 48 52 57 44 59 52 59 44 53 35 33 46 42

76.3 44 32 60 49 41 54 60 52 50 57 51 40 48 43 37

349

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

76.32 48 36 58 43 57 45 66 70 66 42 56 49 59 46 4376.34 51 27 56 60 63 46 70 51 49 57 44 32 34 55 5076.36 43 38 38 49 61 41 48 49 68 41 42 22 46 58 4576.38 54 33 58 47 50 58 74 64 61 55 40 29 55 47 48

76.4 51 35 50 54 42 48 88 59 72 63 52 33 54 52 4276.42 55 35 46 54 50 69 73 53 50 48 54 38 36 45 4376.44 50 31 66 61 49 60 74 60 59 53 55 37 41 46 4676.46 52 33 42 68 62 49 91 56 72 55 60 51 51 48 4876.48 41 43 63 66 61 54 91 74 81 52 57 36 44 51 52

76.5 58 37 67 57 65 63 86 78 78 64 77 36 54 60 5176.52 55 33 62 55 65 60 102 74 70 54 69 47 51 47 5676.54 43 43 58 56 65 66 87 70 67 49 82 36 59 55 5376.56 56 52 59 61 83 70 75 98 87 72 78 37 60 59 5276.58 55 39 43 72 71 76 84 80 71 66 78 50 66 61 66

76.6 53 52 44 64 70 68 68 95 114 52 66 52 47 61 6976.62 63 46 49 70 74 66 75 88 89 70 78 61 63 55 6076.64 68 54 56 78 79 74 80 118 80 80 88 62 68 78 6976.66 49 41 62 71 91 93 102 116 106 55 88 58 68 64 7176.68 60 63 59 73 92 79 115 114 93 89 82 55 76 79 75

76.7 80 40 69 81 82 76 79 113 114 81 93 69 64 71 7576.72 68 59 75 107 104 97 120 119 127 90 108 58 78 100 7676.74 71 57 55 109 107 110 155 119 122 98 114 92 86 86 8176.76 68 64 73 98 97 109 135 139 114 109 112 64 96 102 9176.78 80 73 58 118 91 111 128 134 111 117 121 92 90 94 106

76.8 101 83 78 107 99 107 143 126 141 130 142 120 101 106 10576.82 101 60 90 133 117 145 150 144 153 171 124 109 104 106 12276.84 108 90 81 132 109 100 146 151 139 168 139 126 127 122 14476.86 115 90 81 139 133 126 134 178 135 202 161 139 143 139 16476.88 133 95 77 153 132 147 155 168 139 211 184 134 161 147 158

76.9 158 111 98 148 149 146 156 164 162 242 179 172 200 195 17376.92 200 109 93 167 159 141 163 143 169 240 189 180 235 215 22676.94 203 110 117 178 156 162 160 158 150 257 190 174 218 210 21176.96 234 146 134 172 172 163 154 177 179 239 187 179 286 245 21676.98 279 137 138 193 178 168 145 161 185 227 201 186 246 271 191

77 274 148 143 200 171 163 154 144 178 188 200 167 265 280 20177.02 377 141 154 222 186 176 149 207 170 174 197 142 307 272 16477.04 352 144 111 214 221 163 157 158 204 174 170 144 278 224 16977.06 325 119 122 218 206 192 157 169 182 168 167 119 241 193 17477.08 318 121 117 199 200 184 143 173 176 208 132 108 243 200 167

77.1 305 125 121 189 183 148 138 158 185 180 149 92 215 198 15577.12 257 112 103 183 183 169 155 173 196 173 146 64 228 191 13277.14 240 109 110 185 169 188 142 170 154 151 138 81 190 192 144

350

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

77.16 243 92 92 172 126 153 134 157 188 177 157 53 199 179 13177.18 208 96 91 174 133 161 152 163 171 165 142 65 195 189 148

77.2 208 101 71 177 133 152 129 147 168 176 144 53 182 198 14677.22 211 77 96 161 152 155 129 118 181 141 142 30 173 205 12877.24 192 88 83 181 129 143 116 129 171 126 124 34 153 165 12877.26 201 92 99 164 129 162 114 111 143 138 116 68 151 161 10777.28 212 70 83 137 152 144 111 125 147 132 87 62 136 122 98

77.3 189 82 68 141 138 115 126 129 147 127 88 53 136 133 11077.32 176 80 70 129 120 116 111 121 136 83 94 53 129 116 8977.34 157 55 72 148 130 105 103 124 119 97 100 41 120 118 9177.36 129 59 66 136 132 121 108 108 144 99 85 53 112 104 7577.38 127 59 69 117 98 120 81 112 115 95 70 64 115 94 72

77.4 135 47 67 128 109 117 90 100 136 95 85 58 86 110 7777.42 100 60 54 105 90 85 106 87 114 89 60 50 117 93 7577.44 114 64 57 81 67 94 107 85 122 86 75 56 78 90 9077.46 95 53 52 97 81 97 90 84 117 68 92 58 81 86 7577.48 104 37 62 85 95 98 85 78 106 74 81 26 77 94 60

77.5 107 47 58 97 79 101 85 99 102 63 57 43 93 68 6677.52 97 40 55 91 68 80 81 87 104 66 50 40 91 74 5177.54 79 40 71 95 73 89 100 72 97 77 55 34 60 77 5077.56 64 49 82 93 80 67 73 77 99 63 77 44 84 73 6577.58 64 35 65 67 68 85 77 56 88 63 50 35 55 64 55

77.6 81 57 84 62 67 83 90 59 95 60 66 34 60 57 5077.62 71 39 77 68 58 81 69 74 84 64 67 32 66 64 4477.64 75 50 73 73 69 70 82 53 83 54 62 28 72 60 4777.66 75 42 70 76 54 72 75 60 90 49 55 19 57 65 3777.68 67 45 66 72 63 61 56 66 91 40 54 14 57 68 55

77.7 67 36 68 61 52 60 84 59 69 58 59 24 51 51 5877.72 53 46 61 63 55 66 61 56 67 40 42 27 62 64 5177.74 53 43 47 62 49 58 65 47 69 44 48 31 49 58 4377.76 57 27 46 49 46 60 74 59 77 47 53 25 60 67 4677.78 47 48 48 61 50 50 49 40 85 52 45 23 41 52 45

77.8 67 39 53 57 54 54 69 41 47 32 45 12 54 63 4777.82 50 36 58 46 60 70 50 52 65 34 42 30 48 53 3277.84 60 24 67 42 51 74 76 54 54 35 32 27 50 38 4277.86 49 44 57 50 62 61 50 53 69 40 39 36 45 40 2977.88 49 31 54 55 48 63 59 48 69 50 37 41 43 50 43

77.9 47 38 47 51 72 49 60 58 62 36 47 35 41 57 3877.92 52 43 49 46 46 48 52 56 54 41 33 34 52 46 3177.94 36 37 53 43 45 44 48 48 61 36 42 37 45 48 3477.96 44 28 63 48 37 51 45 37 49 40 38 16 41 56 3777.98 27 33 51 45 45 52 42 37 50 42 36 25 34 41 45

351

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

78 35 39 46 49 51 53 59 51 59 38 35 28 28 53 2778.02 47 31 39 48 57 50 43 36 52 37 32 36 37 41 3778.04 48 30 56 37 37 50 46 53 61 30 37 29 43 36 4778.06 41 29 48 54 39 60 43 44 40 50 47 21 36 38 2978.08 54 33 48 42 39 39 46 59 45 42 35 33 38 47 29

78.1 40 29 46 33 57 37 52 44 45 41 29 24 39 47 3378.12 44 35 42 37 46 38 44 49 49 49 35 23 52 33 2978.14 36 34 39 38 40 44 45 45 57 40 40 11 41 41 2678.16 47 27 31 38 46 52 46 34 49 31 32 24 32 42 3478.18 46 28 45 35 55 30 41 46 50 42 36 13 46 43 37

78.2 50 26 46 40 37 45 33 35 45 52 43 21 43 49 4278.22 31 49 38 43 45 36 63 40 41 40 30 27 33 62 2878.24 52 40 55 43 56 40 47 48 47 34 34 24 41 52 3278.26 44 37 39 36 37 39 48 45 31 33 41 21 38 42 3278.28 53 22 46 40 54 43 51 40 49 32 46 20 34 48 31

78.3 34 35 30 35 37 46 40 36 41 41 32 29 40 49 4678.32 51 29 48 38 35 34 61 44 48 46 28 31 31 45 4078.34 41 36 42 50 39 33 39 29 47 32 38 16 38 48 3678.36 47 26 41 46 35 43 29 28 35 34 34 29 50 53 3578.38 47 41 43 36 51 56 53 33 46 46 36 33 38 34 33

78.4 41 24 43 62 41 42 31 31 55 46 37 29 33 51 4378.42 31 31 42 48 45 39 45 47 31 27 31 29 42 59 4978.44 47 48 46 43 53 42 41 39 39 56 42 15 45 57 3078.46 49 30 46 48 34 40 43 33 39 34 39 24 31 48 4378.48 49 43 39 37 40 42 51 38 42 41 34 6 44 52 35

78.5 45 36 35 43 38 46 47 45 33 42 47 25 32 43 3078.52 32 25 32 43 43 42 37 33 51 37 41 19 46 49 4178.54 40 36 56 51 43 47 45 28 55 33 30 28 34 53 4078.56 33 38 43 36 46 39 41 48 46 38 33 28 39 57 3678.58 38 29 45 40 36 43 33 32 47 34 34 21 44 60 49

78.6 41 37 30 42 41 33 35 34 42 38 34 31 41 62 4078.62 37 40 45 49 35 34 32 39 35 41 30 30 45 59 3778.64 51 35 49 49 38 33 49 42 46 34 35 21 35 62 4278.66 44 31 45 38 46 46 31 36 38 45 43 26 46 57 3378.68 47 36 49 39 39 54 42 41 35 41 33 22 39 48 34

78.7 43 42 42 41 40 42 40 40 38 50 23 26 47 46 2678.72 54 43 42 39 36 41 34 46 38 51 40 25 49 50 4778.74 31 26 48 33 45 44 33 49 39 35 44 21 34 51 3278.76 35 33 55 52 43 60 36 39 43 27 37 22 43 49 3878.78 40 22 49 45 38 39 42 46 52 41 40 21 43 49 32

78.8 40 34 46 39 48 37 43 45 43 37 33 16 44 41 3478.82 29 24 56 34 45 38 39 29 44 31 33 31 31 52 35

352

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

78.84 46 29 58 37 37 53 47 45 43 55 31 16 41 57 3378.86 37 31 37 26 47 44 39 53 45 37 39 28 38 49 2578.88 42 29 51 38 43 37 37 36 38 29 38 42 53 38 37

78.9 46 36 49 36 45 43 50 35 40 35 43 22 45 40 3478.92 43 37 58 31 45 38 42 36 39 40 40 34 37 61 3978.94 46 39 39 38 43 41 38 45 53 31 41 25 53 43 4778.96 43 37 40 40 37 47 48 30 39 38 36 24 44 42 3178.98 46 26 44 55 39 37 34 40 31 34 29 37 52 40 45

79 36 32 51 44 36 48 43 44 25 37 55 31 42 48 3579.02 53 33 51 49 52 44 47 50 35 42 35 29 47 54 3679.04 43 33 47 49 35 35 50 47 41 34 42 36 34 41 4079.06 39 27 48 35 46 32 51 40 33 41 39 22 46 52 3079.08 49 40 59 50 41 53 43 45 51 36 38 46 37 46 29

79.1 47 38 44 53 33 43 48 36 45 35 31 27 47 46 3179.12 45 27 44 45 48 43 49 40 49 43 31 28 42 53 4479.14 45 29 38 53 52 45 59 38 46 36 38 30 44 53 4779.16 42 42 56 40 34 41 34 50 52 38 43 34 40 50 4579.18 53 26 43 40 52 48 44 42 42 44 35 31 54 46 30

79.2 48 34 42 54 40 38 57 41 54 47 30 29 48 48 4179.22 32 34 41 38 50 43 61 39 56 44 46 25 40 57 3779.24 36 27 44 45 34 50 57 49 43 49 35 19 39 53 3579.26 54 26 40 55 57 47 67 49 69 49 41 26 59 52 4779.28 49 30 46 47 49 33 55 66 67 43 44 26 40 63 43

79.3 53 37 51 38 62 48 51 46 59 55 31 23 38 43 5279.32 50 36 38 57 46 58 52 61 43 50 56 25 44 53 6279.34 57 34 50 41 55 54 62 60 56 48 45 28 49 38 5779.36 44 26 42 45 57 39 68 71 59 50 51 38 31 54 5279.38 61 37 51 61 38 74 65 75 59 47 44 47 62 35 44

79.4 49 57 55 58 67 56 68 77 66 56 40 32 59 65 4379.42 51 33 47 57 65 59 72 62 71 54 71 58 54 55 5579.44 73 43 53 62 73 60 79 63 67 45 67 51 58 60 6079.46 48 42 59 63 60 70 87 80 86 64 74 54 55 62 5679.48 60 33 67 65 57 87 80 85 88 62 72 75 60 71 48

79.5 57 39 46 81 65 63 94 105 124 72 67 79 57 68 7979.52 61 49 74 72 69 58 94 88 103 75 82 69 67 54 8679.54 70 53 73 87 80 72 97 88 108 90 67 85 79 102 8679.56 67 64 63 93 73 70 116 105 90 99 80 95 86 97 9079.58 78 65 62 86 97 88 104 103 104 122 102 101 88 92 123

79.6 77 68 70 100 77 86 113 110 101 127 102 86 92 100 13179.62 94 89 63 101 103 86 100 105 108 151 115 103 130 134 13679.64 105 91 76 115 103 102 92 106 93 160 123 112 140 130 15079.66 116 77 96 107 106 89 97 105 122 150 112 109 134 163 125

353

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

79.68 105 70 94 116 110 84 113 106 119 141 110 112 143 145 10479.7 168 89 97 126 127 116 99 117 142 126 103 88 167 150 122

79.72 148 99 91 112 129 103 107 92 129 132 117 66 169 146 11079.74 152 86 93 97 121 131 109 70 127 85 79 79 146 164 9879.76 145 76 71 102 122 104 110 106 125 97 98 59 140 151 8979.78 123 86 92 102 126 125 91 116 107 93 78 62 114 115 98

79.8 120 68 86 92 117 102 106 94 118 105 108 51 117 115 10479.82 109 70 79 116 108 99 105 88 116 97 70 36 79 102 8879.84 111 51 91 107 111 116 108 84 91 96 82 55 114 98 11579.86 106 69 82 119 107 92 93 73 116 100 86 33 113 108 12079.88 101 57 104 102 94 98 121 93 100 104 82 38 90 111 105

79.9 86 76 105 83 97 104 113 83 101 98 75 40 133 104 7779.92 104 82 79 103 98 103 96 86 104 85 75 24 120 114 8579.94 114 78 85 86 84 88 96 55 82 71 57 35 104 110 8879.96 95 59 65 86 86 85 92 85 90 86 72 34 105 101 7879.98 115 54 74 105 92 103 83 71 97 81 58 38 75 100 69

80 121 47 80 95 113 69 59 77 88 71 59 40 77 73 6280.02 84 44 63 75 85 77 84 66 75 49 47 33 76 83 7080.04 94 48 70 77 57 80 74 52 76 58 51 32 65 72 5980.06 81 44 58 83 71 83 77 68 82 50 52 43 58 69 6580.08 74 52 55 73 59 69 76 67 77 61 56 25 49 66 58

80.1 73 38 55 57 59 70 79 72 74 64 55 56 53 53 5380.12 65 38 65 64 52 44 80 58 64 60 44 51 61 69 5880.14 65 36 67 74 56 71 69 57 70 49 55 33 58 65 4680.16 53 41 49 67 52 60 63 47 67 47 39 49 49 58 6480.18 70 38 57 63 53 56 76 58 66 65 38 49 53 55 51

80.2 50 40 46 48 58 61 69 58 69 58 40 44 49 60 5880.22 50 48 56 66 46 63 59 65 69 57 43 31 58 61 5180.24 59 38 57 65 47 57 57 45 56 43 53 31 37 79 5780.26 53 41 52 60 56 55 65 60 60 68 51 46 67 61 4580.28 55 47 58 60 52 68 55 61 61 50 53 53 56 48 54

80.3 59 38 42 65 50 63 63 56 71 71 48 43 50 70 4980.32 54 37 39 72 47 57 65 53 73 52 41 59 67 75 6680.34 74 56 54 67 62 57 56 53 57 69 44 34 63 63 5780.36 67 41 44 67 54 52 63 50 54 59 63 38 71 50 5880.38 62 34 55 56 49 44 52 61 74 62 44 57 71 68 51

80.4 69 41 44 60 63 53 66 43 74 57 64 35 55 55 5280.42 67 35 59 56 68 68 49 45 88 43 51 45 75 76 6380.44 73 33 62 66 56 63 57 58 51 64 43 34 55 76 4580.46 70 41 59 63 47 60 70 41 77 63 60 58 63 75 6380.48 68 39 55 56 63 40 60 66 49 55 53 51 54 69 47

80.5 83 34 63 53 64 56 56 53 50 49 58 38 63 63 38

354

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

80.52 76 25 62 55 62 53 61 47 54 53 46 30 56 53 4480.54 80 33 41 61 67 60 57 50 54 57 52 24 66 49 6680.56 71 43 44 68 51 46 46 39 59 44 55 34 52 69 5280.58 59 42 55 67 58 47 58 47 58 63 50 54 50 64 50

80.6 73 37 46 50 47 54 59 43 49 45 35 39 48 56 4780.62 56 47 53 62 53 56 55 46 52 58 50 27 58 65 5380.64 55 46 43 60 44 56 59 35 48 56 44 45 71 63 5280.66 63 36 45 74 71 46 54 46 48 59 51 24 53 51 4680.68 47 62 43 46 48 42 68 51 57 44 43 38 45 62 43

80.7 51 29 50 60 58 49 41 34 46 56 45 36 51 53 4180.72 47 38 42 62 57 41 50 42 44 35 52 30 48 57 5480.74 72 38 39 54 48 43 48 53 44 48 47 29 40 64 4280.76 50 23 48 44 49 57 62 47 50 37 42 32 48 48 4480.78 44 35 43 51 50 43 42 42 42 34 50 45 48 45 39

80.8 61 31 42 32 51 42 47 41 42 52 41 50 43 46 5180.82 43 43 56 44 49 47 59 44 55 27 40 30 56 48 3980.84 52 27 49 56 53 41 50 43 42 40 41 26 41 39 3480.86 33 31 38 45 45 51 44 51 46 42 36 37 46 55 3780.88 49 23 45 50 43 48 42 45 57 41 43 39 50 42 30

80.9 40 40 34 43 44 50 45 49 37 40 40 39 40 52 3180.92 47 32 48 46 36 59 33 42 43 46 36 40 40 50 3780.94 46 33 36 49 48 35 51 38 49 58 40 52 38 48 4180.96 31 21 51 46 50 39 39 35 34 42 38 41 41 48 4380.98 52 39 42 49 38 28 45 58 45 45 36 36 39 53 42

81 57 32 48 41 38 45 54 37 43 41 28 33 36 47 3681.02 47 30 45 49 48 52 48 45 44 57 41 25 31 58 4081.04 50 31 39 49 52 36 55 44 38 56 44 30 36 56 4381.06 39 37 46 43 49 48 52 48 59 53 40 47 49 44 6081.08 32 42 46 48 48 37 72 49 42 34 51 41 38 45 41

81.1 39 34 56 54 49 52 57 51 46 49 40 34 51 36 4981.12 42 34 60 49 49 46 57 54 51 50 52 44 35 47 4681.14 38 34 57 35 67 59 70 51 51 40 56 35 44 50 5081.16 51 42 56 57 52 36 58 52 44 74 45 37 39 58 4181.18 42 31 62 47 57 53 80 41 60 55 41 34 44 54 41

81.2 46 45 58 53 54 50 65 54 46 55 28 38 46 41 4681.22 34 41 56 47 52 45 49 45 58 50 38 33 47 59 3681.24 44 34 43 53 40 52 58 44 48 62 43 43 49 53 3981.26 37 50 59 42 55 54 47 44 45 53 41 46 43 65 3881.28 56 32 53 52 50 52 46 54 43 59 40 47 43 52 47

81.3 41 42 58 50 43 48 52 52 48 47 38 28 48 47 5081.32 61 33 60 47 53 53 36 44 50 62 51 46 40 57 4881.34 49 40 68 51 49 46 55 41 55 57 44 47 59 41 58

355

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

81.36 52 29 50 56 64 51 58 46 58 67 39 55 64 60 5581.38 65 36 47 50 51 63 70 46 54 52 44 52 46 76 51

81.4 66 47 61 43 61 64 69 61 56 60 50 39 66 60 6181.42 56 46 55 45 74 66 82 66 54 69 47 47 69 68 4881.44 52 47 81 50 60 68 66 68 55 53 36 40 59 84 6081.46 65 52 48 54 61 73 67 49 59 68 38 57 51 105 6181.48 51 43 66 52 60 57 84 42 70 81 36 34 49 118 51

81.5 62 39 58 51 73 48 66 56 61 51 41 42 58 117 5981.52 54 25 63 58 65 62 77 49 51 55 49 37 58 94 5181.54 55 53 56 55 49 60 65 53 62 59 55 39 52 80 4081.56 54 35 52 43 72 66 55 49 50 50 51 37 37 72 6181.58 60 41 52 59 48 48 54 45 56 44 40 39 47 58 52

81.6 47 37 51 48 51 58 58 75 65 53 47 41 52 55 5281.62 55 40 56 51 52 46 63 47 53 67 47 40 50 39 4981.64 62 40 50 51 60 69 58 57 57 56 45 35 56 51 4681.66 60 41 49 51 58 56 72 54 59 50 57 30 59 61 5781.68 46 42 52 43 55 39 74 61 66 59 38 47 49 65 43

81.7 47 38 54 55 53 51 68 61 59 61 38 34 41 57 5781.72 57 36 49 53 65 62 76 76 66 57 50 34 38 74 5281.74 49 40 44 44 55 54 77 63 64 50 54 51 44 93 3881.76 48 35 48 46 44 61 52 50 67 59 44 34 44 71 6381.78 49 32 47 49 45 48 60 63 56 49 36 38 53 55 51

81.8 45 23 50 64 63 59 59 51 67 54 57 40 56 51 5081.82 47 37 38 48 45 55 65 55 58 48 58 39 51 53 3781.84 40 24 41 58 52 61 59 53 76 60 40 34 40 48 5281.86 47 49 38 46 53 63 64 59 66 52 51 35 48 64 4781.88 38 32 49 33 45 47 65 58 57 52 49 35 46 49 40

81.9 40 39 56 43 62 54 64 54 62 53 57 41 64 53 5581.92 59 33 40 49 64 54 63 56 63 51 62 33 44 57 4581.94 54 39 50 51 68 61 64 58 73 55 64 44 40 46 5281.96 43 34 56 44 38 49 64 57 62 60 46 50 50 53 5581.98 58 30 37 50 55 72 71 55 63 68 62 54 62 51 57

82 45 40 49 59 47 55 52 53 65 62 46 52 47 55 4682.02 58 38 45 60 41 57 63 62 63 68 55 50 62 63 4182.04 55 47 47 48 55 65 63 57 69 61 58 61 71 62 6082.06 49 36 59 64 63 55 58 65 85 54 53 41 66 57 5782.08 64 39 48 64 58 74 64 58 73 72 66 39 61 56 78

82.1 57 44 49 60 65 66 64 73 78 64 65 50 60 58 5982.12 64 39 54 66 83 64 67 78 66 67 82 51 62 69 5982.14 72 44 60 65 72 67 71 64 85 74 52 57 51 50 7582.16 79 48 56 81 87 64 69 76 90 83 66 51 80 73 5982.18 58 48 45 58 59 65 74 78 76 80 64 61 66 75 52

356

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

82.2 59 41 42 59 78 78 77 79 100 66 74 50 76 70 5382.22 69 44 60 65 62 88 72 72 84 65 63 54 60 72 6282.24 72 59 43 75 70 77 69 79 72 63 68 54 65 58 7282.26 72 43 44 69 64 76 91 80 88 70 68 59 72 67 6882.28 62 45 52 84 83 94 83 79 87 76 73 47 60 72 76

82.3 73 42 49 82 66 82 87 108 90 71 87 54 72 79 6582.32 89 53 60 76 79 83 91 93 114 69 82 58 70 88 7882.34 79 39 47 69 81 73 99 101 91 73 82 61 78 86 8282.36 90 56 56 82 64 83 97 92 85 76 81 65 78 80 6982.38 74 49 45 91 82 74 84 85 100 91 89 62 89 85 83

82.4 79 61 51 82 98 90 97 115 98 98 79 78 94 86 9382.42 89 60 54 93 90 88 89 86 79 108 90 62 96 97 11282.44 101 58 53 96 84 91 119 132 106 110 99 89 97 89 9582.46 89 77 71 117 84 102 109 110 88 117 107 99 118 117 12582.48 98 75 61 98 88 91 116 103 144 137 110 90 111 109 145

82.5 113 81 64 115 104 107 96 123 108 130 102 103 105 141 13982.52 125 78 77 128 81 101 107 119 99 132 102 103 138 135 13782.54 147 88 81 119 87 126 81 122 120 145 111 103 148 146 15182.56 132 98 74 107 90 109 118 118 111 146 107 129 144 147 14182.58 176 98 73 126 96 110 79 96 114 120 124 99 171 155 142

82.6 177 97 78 108 124 92 104 107 123 145 131 98 155 158 13482.62 184 106 84 127 118 129 109 112 125 134 103 95 157 164 12882.64 228 108 106 113 108 112 84 103 114 126 110 105 183 158 11782.66 184 99 85 118 120 102 104 125 123 131 97 71 175 138 12582.68 218 95 98 128 108 128 103 121 108 115 101 86 165 163 122

82.7 203 105 87 148 143 124 86 95 121 124 96 69 166 139 12882.72 207 84 89 127 132 125 91 112 125 117 104 64 144 144 10682.74 196 76 88 120 110 120 97 98 109 112 95 45 118 127 11082.76 153 76 81 113 96 111 92 95 113 120 87 35 131 135 10782.78 122 62 76 124 97 122 91 79 104 120 92 62 124 119 110

82.8 142 66 83 111 85 102 94 90 118 89 97 47 122 125 10482.82 139 63 66 109 85 95 77 92 93 89 86 33 110 137 10082.84 158 85 61 107 74 126 72 94 98 89 91 37 129 121 10582.86 104 67 77 108 99 85 75 91 100 88 86 35 134 117 8882.88 131 73 63 111 82 95 73 90 74 96 71 54 111 112 67

82.9 134 62 58 102 88 94 75 63 108 69 68 28 122 113 7882.92 140 49 80 84 79 89 87 81 104 86 63 40 99 104 7182.94 129 51 55 111 87 100 72 77 106 65 56 40 75 78 7682.96 117 59 49 94 81 90 73 80 89 78 56 39 101 76 5582.98 97 52 51 86 70 90 77 54 85 65 52 50 71 73 72

83 93 47 49 73 74 67 67 82 77 63 58 32 84 80 5883.02 94 47 52 71 84 71 69 78 84 60 58 44 72 72 54

357

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

83.04 81 37 51 78 65 68 81 64 79 52 66 30 59 69 4883.06 67 35 43 75 50 59 59 61 74 56 49 38 53 54 4483.08 79 36 50 74 65 66 70 56 87 49 49 47 63 72 65

83.1 58 36 49 60 56 66 67 60 79 51 49 36 61 68 5183.12 58 47 47 53 49 59 63 49 66 38 47 43 51 46 6183.14 60 40 27 57 51 66 58 66 78 54 40 48 50 57 4683.16 56 26 40 57 45 62 71 52 62 59 52 36 40 44 4883.18 66 33 43 55 48 52 61 47 60 40 39 40 48 37 43

83.2 52 33 34 63 50 59 51 59 74 41 36 45 42 65 3583.22 69 30 53 44 46 60 47 51 48 41 31 29 55 52 3883.24 61 37 41 45 46 53 71 48 71 33 34 36 50 44 4983.26 58 40 38 47 40 45 44 35 47 29 47 31 40 49 4683.28 39 44 44 58 36 41 52 59 64 49 41 30 39 53 49

83.3 41 34 34 60 35 60 57 41 61 33 37 36 41 58 5783.32 46 27 51 52 41 40 38 48 48 50 41 34 37 49 3883.34 49 32 36 54 51 48 53 47 50 48 54 20 39 48 4083.36 54 38 56 43 59 52 45 41 45 40 42 36 43 35 4383.38 54 36 44 39 31 34 59 43 46 44 49 27 37 49 45

83.4 43 36 43 50 42 42 44 46 63 53 40 19 50 54 3183.42 42 25 46 59 33 46 42 49 43 41 46 33 34 32 5483.44 40 33 35 50 41 43 58 40 56 45 36 35 40 61 5283.46 36 30 52 45 44 36 41 41 42 45 32 25 43 42 4383.48 36 40 41 36 49 44 40 47 50 44 41 31 30 53 31

83.5 54 35 44 48 41 45 49 34 54 55 42 33 39 47 3983.52 52 32 42 56 57 63 41 44 40 36 30 26 56 48 3683.54 37 35 40 36 47 46 49 52 46 39 38 52 50 45 4683.56 46 29 57 44 34 31 49 50 53 37 43 26 35 41 3683.58 45 29 37 40 35 59 48 46 45 40 36 47 36 39 54

83.6 32 34 43 46 45 45 48 50 54 47 49 33 42 34 3883.62 46 35 48 41 47 40 55 50 48 37 37 27 59 54 3283.64 29 40 48 31 47 38 41 43 53 53 38 42 46 54 4983.66 44 35 33 45 48 33 40 55 47 46 52 42 44 31 4483.68 36 26 43 44 54 36 48 49 53 44 52 32 40 49 41

83.7 40 29 50 44 46 67 49 52 54 53 40 39 50 50 4283.72 56 40 49 40 45 39 68 60 47 39 43 37 37 47 3883.74 46 29 61 53 52 53 47 55 44 45 42 35 32 39 3983.76 59 36 43 36 40 57 63 55 37 58 42 53 45 34 4483.78 40 28 50 49 59 58 49 52 75 62 39 32 50 50 43

83.8 49 39 51 44 53 47 61 53 52 61 66 44 60 47 5383.82 47 33 56 47 57 44 74 34 54 60 82 36 46 54 4483.84 48 38 54 50 53 27 51 44 51 44 89 40 59 41 5683.86 57 28 59 46 49 61 56 44 57 48 89 39 46 42 51

358

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

83.88 53 44 35 52 62 58 64 54 53 56 64 39 49 46 5583.9 55 30 46 54 52 35 62 68 60 48 54 28 50 54 53

83.92 45 41 48 50 50 46 49 53 53 33 67 30 47 51 5283.94 45 34 43 54 52 42 57 61 47 47 57 35 47 47 5183.96 50 30 47 50 50 62 53 71 53 53 39 42 52 65 5783.98 56 43 48 52 52 54 51 56 54 46 45 31 43 56 62

84 48 38 43 42 52 52 49 37 64 43 57 30 48 51 4184.02 44 32 38 55 44 66 61 52 61 46 48 24 42 48 4884.04 64 45 46 51 60 68 66 57 51 53 42 46 63 42 4984.06 42 37 54 35 46 58 48 63 55 55 47 28 50 62 6084.08 52 27 40 62 42 53 64 40 58 36 67 33 44 46 53

84.1 38 33 44 52 46 64 53 47 48 54 62 36 40 40 3784.12 59 32 35 54 58 57 54 45 67 56 47 28 39 56 4884.14 50 38 53 57 44 57 60 53 56 58 55 32 49 54 4784.16 43 31 42 51 27 38 50 53 56 54 56 32 53 66 5284.18 55 29 46 48 51 56 49 38 55 41 41 37 47 54 49

84.2 45 17 50 55 46 55 52 54 60 51 38 44 48 41 3784.22 49 40 33 50 47 69 58 56 65 39 45 31 43 55 5784.24 55 34 43 55 55 47 50 46 57 30 43 35 45 50 3284.26 44 29 41 40 44 62 73 59 58 43 42 30 48 58 4484.28 57 42 59 47 36 46 58 63 74 51 55 38 50 57 55

84.3 45 35 41 50 58 55 56 48 68 38 41 27 55 53 4684.32 47 29 44 47 46 52 59 41 74 49 33 38 55 43 4784.34 37 44 34 42 57 68 47 56 76 37 49 43 45 53 5084.36 38 27 41 50 44 63 52 51 69 37 54 23 54 41 3784.38 44 35 49 49 48 55 55 69 53 66 53 50 41 39 53

84.4 55 35 46 44 54 56 65 46 70 42 48 41 44 53 4684.42 50 44 45 53 65 50 49 63 70 40 51 36 34 53 4384.44 45 26 46 41 63 57 53 45 71 50 47 38 50 46 4884.46 63 31 52 45 54 78 64 60 62 46 59 36 54 52 5184.48 51 45 42 49 50 68 59 60 68 53 51 50 53 50 47

84.5 55 42 47 77 56 53 62 67 75 59 54 40 59 66 4184.52 53 39 45 53 54 56 68 70 81 61 61 43 36 68 6084.54 41 34 39 56 59 66 74 70 60 60 57 51 62 58 5484.56 46 43 40 61 52 53 74 73 64 56 74 65 53 67 6584.58 64 46 51 58 59 76 66 85 89 54 61 45 70 69 70

84.6 63 42 37 58 73 76 72 77 69 76 74 72 78 82 7684.62 64 41 62 69 62 66 72 83 69 74 72 66 75 68 8484.64 82 52 66 75 61 55 74 95 82 92 71 46 86 78 8184.66 83 53 64 76 70 71 61 75 78 105 83 71 87 74 8484.68 100 66 69 78 63 75 68 72 80 101 79 75 96 105 85

84.7 100 57 62 78 81 72 86 83 71 81 70 71 94 100 85

359

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

84.72 111 55 65 91 76 79 72 73 84 91 87 67 90 97 8584.74 92 58 67 93 96 90 83 69 90 81 85 63 96 95 7684.76 105 57 66 91 80 70 82 84 79 74 64 63 110 95 5284.78 103 50 67 79 64 82 65 79 100 55 71 47 82 88 72

84.8 100 50 49 77 75 67 77 80 82 58 60 47 59 81 7384.82 84 59 55 92 66 83 64 60 94 54 68 41 76 70 7584.84 93 46 50 84 71 70 74 71 73 69 78 48 78 60 7284.86 69 39 48 65 61 77 73 64 80 72 62 23 71 74 6384.88 79 36 58 65 67 61 76 80 71 65 63 33 80 77 59

84.9 70 42 51 76 55 69 61 77 74 70 73 49 78 63 5884.92 74 55 51 73 52 72 59 50 67 65 68 26 70 76 6184.94 80 50 54 75 63 63 54 75 79 61 49 27 74 74 5384.96 72 41 59 69 64 58 63 74 67 66 53 25 79 78 5784.98 82 45 47 67 81 65 65 60 63 55 56 28 74 74 49

85 73 41 61 83 68 63 59 71 72 77 46 27 62 71 4885.02 78 50 46 86 72 69 74 63 76 66 60 24 71 83 5585.04 67 40 51 57 51 62 59 52 77 58 43 45 64 53 3485.06 67 39 40 59 65 49 60 65 66 47 44 30 58 66 5385.08 68 31 46 62 52 46 47 48 66 50 40 29 56 53 49

85.1 53 30 35 69 50 36 58 61 67 43 38 38 65 67 5085.12 56 39 43 61 51 52 66 43 67 52 37 40 49 38 4685.14 62 33 40 59 43 48 47 53 65 50 45 38 53 54 4285.16 53 28 34 55 49 44 70 41 55 41 34 38 37 54 5385.18 49 36 42 57 55 56 51 50 59 41 41 37 43 57 35

85.2 37 30 42 49 57 48 41 48 50 37 42 38 38 46 3785.22 34 28 52 53 46 39 45 48 51 47 47 45 44 36 2985.24 39 37 51 50 56 47 37 43 54 38 43 30 38 43 5285.26 42 35 38 51 40 52 59 42 57 42 35 31 30 55 4685.28 60 33 47 47 53 54 42 63 59 30 34 25 47 43 43

85.3 38 34 42 50 47 52 66 30 50 48 47 23 34 46 4485.32 38 24 37 41 37 54 56 35 46 46 39 37 35 42 4285.34 49 39 38 48 43 44 52 44 47 50 33 41 38 42 3685.36 47 33 52 44 39 49 47 56 37 56 46 31 43 40 4185.38 48 38 51 53 43 42 52 50 46 37 48 24 40 38 39

85.4 34 27 30 36 43 47 54 39 66 46 41 38 42 45 3685.42 44 37 42 57 41 50 49 52 64 36 42 25 37 57 3385.44 40 28 35 41 54 49 49 44 53 45 43 26 35 50 3985.46 47 28 38 50 38 48 58 46 43 50 37 25 36 42 5885.48 57 32 48 32 60 46 51 46 57 49 43 28 42 53 43

85.5 39 22 41 41 39 42 54 36 47 35 34 25 35 46 4585.52 38 32 33 55 34 45 61 36 42 37 57 47 28 47 5085.54 38 35 39 35 40 40 34 40 45 34 54 33 34 29 37

360

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

85.56 33 32 28 39 34 49 46 41 41 38 51 26 42 37 3585.58 31 20 43 42 35 46 55 41 44 43 37 32 26 46 44

85.6 41 28 33 43 34 51 52 41 49 47 44 25 40 36 4485.62 46 26 36 37 46 50 49 43 48 45 37 23 34 44 3885.64 35 22 35 45 53 46 37 28 38 48 38 39 33 52 2985.66 47 37 46 47 49 45 44 49 41 24 37 24 49 42 2585.68 50 28 38 55 38 46 49 48 51 36 42 36 41 43 56

85.7 38 36 47 37 50 55 42 43 54 42 44 37 44 53 4285.72 45 23 41 45 46 41 62 34 48 44 31 36 59 52 3185.74 38 40 42 47 46 45 61 51 55 43 38 33 46 38 5385.76 45 26 34 38 32 65 54 31 56 47 39 26 29 54 4285.78 36 38 33 49 40 57 50 48 55 41 42 18 44 49 48

85.8 27 28 41 39 41 50 48 45 49 49 58 28 40 49 4285.82 44 23 42 47 45 41 48 40 57 45 45 30 42 39 3685.84 38 37 47 41 45 51 37 47 47 47 52 37 40 35 4785.86 47 29 35 52 38 36 40 49 52 54 48 22 55 55 4485.88 41 42 51 48 39 52 48 53 58 40 37 42 44 44 39

85.9 50 34 43 48 46 38 69 45 59 55 50 31 46 40 4585.92 46 36 40 49 44 42 49 45 38 55 54 42 34 47 4485.94 38 27 35 46 54 45 53 58 50 54 50 35 50 53 4485.96 23 24 37 52 60 45 42 58 40 41 48 39 48 39 4185.98 43 31 44 56 33 37 49 62 65 54 56 19 39 43 41

86 48 34 39 46 47 44 67 37 41 40 45 36 44 50 4386.02 48 26 34 44 59 50 49 60 63 48 43 43 44 44 5386.04 52 35 32 55 44 46 48 49 57 52 50 50 43 47 4486.06 44 32 41 45 59 45 49 62 61 46 51 29 44 55 5086.08 49 26 40 50 52 55 64 54 50 54 54 42 39 52 50

86.1 51 30 51 42 51 58 56 55 54 33 52 33 46 51 4286.12 63 34 42 55 55 48 59 63 63 41 52 38 62 50 5386.14 51 39 39 51 62 41 60 51 58 48 68 49 37 56 5586.16 51 27 45 47 52 70 50 53 76 45 50 48 51 53 4386.18 58 32 47 46 57 38 72 66 65 59 57 31 47 46 54

86.2 48 42 37 48 56 72 55 51 67 50 61 29 57 56 6786.22 44 28 40 51 47 53 65 71 60 61 55 47 48 54 5586.24 46 35 45 50 54 56 72 82 78 66 70 60 50 59 5886.26 49 38 46 57 64 62 64 65 76 42 54 64 46 51 4586.28 50 43 44 56 49 60 73 51 66 57 63 48 64 60 62

86.3 66 35 46 66 61 52 70 90 82 67 66 44 65 59 4586.32 60 35 60 63 68 64 69 83 79 72 56 54 61 53 6586.34 56 39 44 64 54 67 77 75 92 46 61 63 60 81 8386.36 68 44 50 68 69 76 105 95 67 65 56 55 64 66 5786.38 65 37 59 68 59 74 88 103 83 77 79 56 56 75 65

361

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

86.4 66 44 33 74 62 76 89 81 92 97 87 59 79 71 6786.42 79 43 39 73 83 84 93 113 89 78 86 58 75 69 7686.44 85 56 47 74 93 83 92 77 102 116 97 72 88 97 10986.46 69 69 59 96 80 67 87 117 94 117 90 72 106 94 11686.48 82 30 57 70 85 90 87 94 88 104 99 84 85 95 105

86.5 89 62 53 101 86 93 80 110 112 154 92 92 94 107 12286.52 91 61 61 103 76 77 98 105 103 146 102 99 126 95 11386.54 100 71 58 116 89 109 107 87 110 135 95 105 119 120 12386.56 110 64 81 122 98 113 99 99 98 161 99 100 160 135 14986.58 120 59 72 84 90 84 108 108 104 149 134 118 145 126 138

86.6 150 82 77 104 92 88 106 102 112 143 117 86 144 116 12286.62 161 84 79 122 83 109 89 120 122 158 118 95 171 158 13386.64 179 73 89 114 108 96 101 128 126 132 127 111 188 158 12286.66 217 97 99 121 107 120 120 104 116 132 115 99 151 157 11386.68 211 106 93 118 110 100 89 125 103 127 103 90 158 127 115

86.7 208 83 100 133 112 108 121 104 108 137 120 65 159 143 9786.72 190 86 89 130 111 100 94 103 140 144 125 102 154 147 10586.74 212 82 85 117 141 88 101 118 107 107 120 70 163 122 9986.76 165 71 59 128 137 101 102 112 98 130 102 62 146 130 12286.78 177 89 59 154 98 121 105 115 122 120 113 63 133 123 104

86.8 134 61 70 130 92 85 108 103 113 112 108 54 122 111 10786.82 142 64 60 130 88 90 97 106 115 100 96 45 140 105 11486.84 135 66 76 86 76 95 96 101 126 135 92 49 122 122 8886.86 134 71 66 113 88 96 96 115 113 102 75 37 116 111 11386.88 139 65 53 97 96 102 88 105 113 105 97 46 138 97 89

86.9 142 71 55 110 87 109 100 90 109 113 83 32 100 92 10986.92 120 51 55 96 90 95 80 94 125 97 83 30 126 82 8786.94 133 66 64 97 75 79 80 100 115 85 55 35 114 89 7086.96 122 50 66 96 99 98 102 92 90 82 86 42 89 97 7986.98 156 56 70 83 96 89 86 87 113 101 76 50 108 93 82

87 112 45 49 87 79 87 89 79 88 83 59 26 114 105 7387.02 110 48 47 86 79 86 76 92 84 79 58 26 94 89 7587.04 107 60 52 74 76 64 73 89 92 67 62 41 86 83 7487.06 86 39 39 82 70 90 84 75 95 57 64 51 89 77 5687.08 91 38 32 73 68 77 82 85 81 69 63 54 59 66 66

87.1 95 56 46 85 72 56 90 83 86 69 68 29 69 67 5887.12 74 40 63 96 69 76 84 84 93 57 60 36 61 77 6087.14 66 40 49 68 61 72 74 70 97 62 54 38 71 58 6787.16 69 36 30 72 68 81 88 85 83 61 55 53 64 74 5687.18 70 45 39 91 69 85 82 83 81 54 64 41 70 57 67

87.2 62 34 49 82 50 70 70 91 95 50 61 47 70 59 5887.22 59 38 42 67 70 67 78 84 90 62 67 46 81 62 51

362

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

87.24 74 28 50 80 71 74 84 71 95 65 54 43 54 58 4687.26 65 38 46 83 61 68 85 99 68 61 67 44 66 50 5087.28 70 46 46 71 60 69 72 96 90 69 57 61 51 61 58

87.3 62 36 51 75 76 67 82 75 86 63 62 42 73 76 5487.32 51 44 57 70 69 70 74 82 87 61 77 33 65 66 5487.34 54 39 52 84 54 74 93 99 100 83 58 41 57 60 5687.36 65 35 55 75 63 74 104 97 94 61 77 35 71 61 6387.38 61 41 44 81 72 96 96 89 90 64 75 56 62 57 63

87.4 60 46 43 79 55 70 91 105 101 71 74 65 57 74 6387.42 65 38 47 82 99 83 90 93 102 67 74 57 92 87 5887.44 62 41 42 85 68 98 97 110 114 73 74 55 51 66 6887.46 77 46 50 98 77 84 116 93 109 69 86 48 76 67 7987.48 77 42 47 89 88 87 113 120 85 60 102 73 61 74 79

87.5 56 49 59 87 95 108 117 128 108 84 90 63 68 79 6487.52 65 45 46 104 100 80 108 136 118 83 99 60 69 87 10287.54 89 62 63 97 86 89 117 146 149 87 110 53 82 72 7487.56 88 61 50 111 91 124 117 148 124 88 121 67 80 89 9987.58 89 55 61 107 97 131 168 151 113 98 107 95 85 90 104

87.6 75 60 53 120 110 112 130 161 129 94 113 88 93 115 8887.62 90 65 56 127 115 112 134 167 149 98 120 90 89 109 11687.64 101 60 72 103 125 132 166 195 151 128 124 102 104 108 12787.66 104 80 73 148 114 122 158 184 152 154 145 96 135 106 14487.68 122 79 71 141 136 133 164 194 175 145 144 125 135 133 175

87.7 157 100 80 165 130 139 180 205 169 138 166 107 147 146 16687.72 133 90 72 146 147 126 184 205 189 181 194 165 164 175 19687.74 175 111 104 171 154 142 194 204 182 202 217 184 186 169 18787.76 162 117 98 180 169 198 208 231 197 226 215 149 183 199 24187.78 170 141 117 212 167 193 195 244 227 254 259 217 231 227 269

87.8 220 137 113 241 199 188 212 244 237 314 262 213 238 236 32287.82 231 171 119 243 214 194 209 230 242 347 311 240 309 276 31087.84 292 198 147 245 203 219 227 225 222 330 289 230 318 296 33387.86 348 202 175 275 260 226 221 235 226 313 334 213 391 345 32187.88 349 213 174 279 249 196 217 266 246 305 295 251 408 351 306

87.9 390 205 173 292 263 209 212 239 241 308 283 228 419 354 32287.92 454 220 179 266 268 200 207 230 270 282 258 207 418 361 28087.94 471 191 165 266 282 224 226 228 217 258 233 171 410 359 24887.96 467 189 180 266 276 194 217 248 300 219 208 164 409 344 26887.98 406 165 146 292 271 231 212 240 232 219 216 150 363 335 242

88 354 160 127 298 250 221 180 214 260 199 217 145 337 303 22388.02 346 143 131 283 245 200 195 237 249 214 225 98 358 260 19488.04 334 136 136 281 224 212 184 193 260 182 222 110 243 261 20188.06 305 112 128 269 200 202 229 210 220 206 214 90 263 260 187

363

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

88.08 270 107 131 271 197 207 170 230 243 203 192 90 235 234 20388.1 264 133 98 262 210 184 196 218 259 188 193 76 251 208 213

88.12 254 126 123 257 178 199 171 190 217 185 181 78 230 220 21588.14 247 128 110 244 170 201 192 196 222 187 185 76 244 212 19888.16 248 115 95 222 170 178 154 184 179 150 162 53 266 234 17488.18 274 142 89 245 179 204 173 186 217 169 177 32 250 222 170

88.2 251 131 96 224 174 171 161 164 214 185 151 54 249 217 16788.22 266 110 110 216 157 163 137 136 212 125 119 53 254 216 14788.24 223 105 99 183 167 165 133 167 174 119 122 53 209 173 13688.26 222 95 81 202 150 184 132 162 189 108 134 34 193 163 12188.28 210 85 104 176 160 145 132 138 173 111 117 46 162 166 101

88.3 194 74 87 151 134 134 121 143 167 98 119 72 148 156 10488.32 163 77 81 156 116 147 114 123 176 99 97 46 124 138 9788.34 155 71 65 164 104 128 121 134 150 93 87 50 132 138 9988.36 152 63 60 150 114 121 108 127 139 75 71 34 113 137 7388.38 128 44 67 129 106 128 94 118 151 86 73 56 87 117 106

88.4 112 48 64 140 89 109 120 121 129 69 72 42 108 111 8288.42 123 40 64 107 89 126 95 109 133 92 80 48 82 123 8088.44 101 38 54 101 90 122 81 88 123 80 81 39 105 109 7688.46 79 58 64 121 62 96 107 98 124 68 82 76 90 113 8488.48 99 44 51 114 71 81 94 81 113 70 76 51 93 117 65

88.5 96 47 63 106 73 98 79 84 125 71 69 64 91 103 5388.52 79 50 51 114 79 92 97 105 110 71 58 65 87 104 7188.54 97 45 53 84 70 103 84 89 108 74 65 58 80 94 7788.56 96 37 68 89 79 103 81 106 108 72 50 63 97 89 7388.58 74 47 56 78 74 104 81 82 112 82 73 66 69 86 63

88.6 81 48 53 88 68 76 73 87 119 55 70 39 78 93 5688.62 83 36 55 84 70 78 76 75 86 56 68 34 79 84 6188.64 91 42 43 82 69 101 76 100 93 61 71 67 66 84 8888.66 75 43 50 69 70 67 66 90 94 47 52 34 63 71 6388.68 78 58 52 82 55 67 81 75 94 74 73 41 62 79 64

88.7 87 40 51 84 76 76 59 88 82 73 72 45 72 73 5588.72 74 46 46 73 82 55 80 76 86 66 59 44 71 78 6188.74 70 36 51 72 65 70 71 85 91 68 65 32 75 66 4588.76 85 39 33 86 64 83 80 81 102 63 56 43 76 74 6388.78 57 44 33 67 74 92 81 81 92 64 60 50 71 98 39

88.8 53 70 36 72 74 68 80 85 95 68 75 34 72 83 4588.82 70 39 40 62 66 65 88 92 82 62 67 59 81 68 6288.84 73 35 52 78 76 76 57 78 76 65 70 44 61 71 6888.86 70 37 40 71 70 77 101 73 95 72 59 40 73 76 6688.88 79 42 55 70 65 51 78 67 93 62 73 54 71 70 68

88.9 81 46 56 70 80 86 84 81 83 58 80 54 61 81 68

364

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

88.92 77 44 48 81 79 73 80 72 78 59 64 48 65 83 6388.94 68 48 40 79 79 77 77 90 95 76 54 72 65 74 6388.96 73 52 43 79 71 65 84 73 90 63 77 51 63 72 6188.98 67 37 48 65 71 85 83 100 65 69 66 62 82 76 64

89 78 52 41 93 72 85 82 89 79 55 59 72 76 68 7289.02 51 48 55 78 86 68 97 96 91 72 83 66 75 75 6689.04 83 51 53 85 79 80 104 74 84 82 73 64 67 74 8289.06 81 52 43 87 81 82 96 97 122 79 78 60 66 67 7689.08 69 51 50 77 78 87 88 107 98 73 74 75 86 93 84

89.1 70 66 55 86 78 94 102 125 110 86 99 54 82 81 9289.12 74 48 50 78 68 86 101 117 103 106 120 87 82 81 8989.14 85 61 64 103 104 93 108 111 98 132 110 82 93 98 13689.16 87 61 53 76 86 88 95 90 123 120 103 82 105 105 10489.18 108 70 64 98 90 92 115 117 115 122 117 106 116 119 113

89.2 121 65 81 122 94 97 104 132 123 160 113 105 133 113 12389.22 114 93 66 97 102 100 105 99 113 131 127 88 134 138 13889.24 127 84 66 127 105 99 120 134 116 161 93 121 159 150 14689.26 132 87 76 112 99 96 106 112 140 133 100 107 176 162 12589.28 167 96 74 117 112 103 103 115 115 155 121 102 191 139 145

89.3 182 100 80 127 107 107 108 112 137 148 108 96 196 172 11889.32 179 88 78 138 137 116 91 116 123 147 124 89 156 149 10689.34 180 94 90 119 106 105 130 104 110 145 116 93 186 166 10489.36 161 96 80 118 120 101 99 121 126 123 99 87 154 134 11289.38 176 87 70 134 119 102 93 115 114 132 93 91 139 133 90

89.4 159 76 88 135 108 100 97 106 119 127 96 89 152 137 13689.42 149 63 71 134 100 102 93 115 127 100 92 51 141 123 9189.44 142 73 64 124 103 113 85 99 121 105 119 63 138 135 11789.46 134 60 72 116 111 102 104 111 112 96 85 82 132 132 12789.48 124 80 74 125 104 113 103 100 101 126 105 60 148 110 99

89.5 135 86 66 125 120 114 112 99 92 115 100 53 137 110 9589.52 105 76 70 124 93 111 86 116 122 125 83 37 147 120 9889.54 118 68 68 108 116 80 83 83 104 125 85 73 134 111 10189.56 146 72 65 111 89 105 63 118 135 107 81 49 121 136 9889.58 124 74 62 97 100 111 73 80 99 88 84 41 147 117 84

89.6 138 63 63 99 97 92 76 79 94 84 73 39 133 115 6789.62 111 66 70 88 82 82 89 87 108 93 74 39 115 106 7989.64 107 46 54 105 91 83 73 101 93 91 71 44 97 88 6689.66 110 55 52 102 82 79 83 75 111 60 51 29 73 94 6489.68 107 47 38 91 70 91 72 85 100 61 73 24 91 103 80

89.7 89 38 62 81 58 83 59 69 92 78 68 41 85 84 6689.72 98 41 47 85 63 93 74 87 97 56 62 51 84 69 6089.74 87 45 52 77 58 88 70 62 93 58 58 24 71 76 56

365

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

89.76 73 54 56 67 53 97 61 55 71 53 59 35 85 67 6589.78 74 28 47 98 69 70 78 46 70 44 49 38 79 63 54

89.8 73 46 54 93 55 79 57 79 74 67 42 51 75 63 5089.82 65 42 41 71 52 73 65 58 67 47 52 30 62 69 5089.84 73 24 49 67 63 63 72 61 77 44 49 39 62 54 4889.86 62 35 33 71 45 55 60 59 77 62 37 27 68 55 6689.88 63 26 39 78 61 65 51 66 67 45 49 23 74 64 62

89.9 62 33 47 64 60 52 71 56 78 55 57 40 43 52 5289.92 58 47 46 61 67 65 57 67 66 41 48 23 64 56 5489.94 60 40 33 52 50 58 57 67 51 51 54 33 45 37 3789.96 62 35 55 51 57 57 55 58 63 39 46 40 71 57 5289.98 56 43 31 57 51 54 61 62 81 57 58 46 52 58 40

90 71 35 40 56 67 71 65 55 63 51 50 36 56 45 4190.02 61 33 33 50 42 40 55 67 62 52 47 48 50 55 5390.04 48 35 37 61 44 55 56 51 59 47 48 49 41 49 5190.06 49 34 43 50 48 67 54 64 49 44 42 44 59 53 5090.08 50 34 48 57 38 67 51 60 62 48 48 50 43 47 56

90.1 54 35 42 46 50 28 59 62 68 44 56 43 49 58 5390.12 58 37 46 54 62 57 65 49 54 53 55 37 54 55 4490.14 43 30 30 53 47 56 59 56 63 57 58 48 53 65 6090.16 54 30 38 67 56 54 55 60 63 58 51 52 42 44 5090.18 59 36 52 69 49 56 58 57 67 57 46 56 57 51 56

90.2 57 56 35 55 54 59 68 57 66 64 63 49 70 63 7190.22 58 41 52 73 44 58 64 64 65 71 62 48 66 57 5490.24 57 53 51 49 65 61 51 74 59 58 44 45 83 65 6790.26 80 37 43 51 45 69 67 54 62 60 63 57 61 64 6390.28 74 51 34 65 60 71 52 50 68 63 56 50 87 72 59

90.3 77 48 38 66 61 63 55 64 62 58 52 39 66 64 6290.32 84 50 39 59 56 65 54 46 64 62 62 45 65 77 4690.34 88 37 53 52 57 57 73 59 65 57 46 29 72 63 4890.36 89 42 50 50 59 51 46 57 57 46 62 39 65 47 6090.38 73 39 36 47 70 66 61 55 59 52 42 42 63 70 55

90.4 75 34 36 54 68 65 60 54 64 51 47 38 64 56 4390.42 69 36 37 72 74 51 51 41 57 49 59 44 56 71 5190.44 67 25 34 60 54 63 64 45 58 65 51 26 43 61 4990.46 55 44 39 57 58 52 63 48 72 52 50 36 46 56 5490.48 63 42 46 66 59 46 46 68 66 57 48 35 61 43 47

90.5 66 36 36 62 67 59 51 41 68 43 47 50 63 60 4790.52 59 37 40 58 42 53 56 49 53 60 57 37 47 60 5990.54 55 43 42 55 49 54 44 47 60 50 54 39 50 43 5690.56 57 39 44 54 50 51 59 36 49 51 47 28 54 55 4790.58 65 46 43 51 63 55 44 59 52 47 41 29 56 54 56

366

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

90.6 58 31 38 45 49 45 58 54 68 57 43 33 64 75 2890.62 63 28 38 53 47 52 41 40 60 52 36 40 73 60 5090.64 63 41 37 53 45 50 49 39 56 44 50 35 53 59 4690.66 70 44 36 54 47 50 47 38 61 47 42 34 37 61 4890.68 54 39 39 59 49 47 46 44 55 36 39 33 44 48 49

90.7 59 37 52 48 48 42 56 47 52 59 49 35 41 61 5690.72 58 46 53 47 64 53 44 37 54 43 29 40 39 47 4190.74 29 50 42 44 65 51 65 35 47 59 33 31 38 44 5190.76 53 49 51 40 50 44 58 51 53 38 42 42 55 36 5390.78 44 41 57 46 47 59 60 47 58 49 32 23 45 45 65

90.8 52 42 48 53 50 42 58 34 51 47 44 30 31 49 7190.82 64 42 49 50 37 50 56 32 48 42 30 31 34 49 6790.84 43 38 39 43 64 46 63 49 35 52 36 32 47 53 5890.86 41 46 47 52 42 41 57 44 49 41 44 39 29 55 5190.88 36 35 43 56 39 69 39 28 64 41 35 24 51 46 46

90.9 43 38 42 31 41 46 45 36 53 34 40 27 48 45 5090.92 43 36 46 38 46 48 55 33 45 40 39 29 43 37 2290.94 56 30 48 27 36 31 43 39 32 48 49 32 40 41 5490.96 51 33 34 48 38 37 53 43 41 37 40 30 46 30 4890.98 39 40 36 42 44 53 51 37 36 49 37 28 36 45 32

91 42 29 35 38 39 45 47 37 35 42 38 18 35 42 4291.02 55 35 29 40 52 36 45 42 33 38 29 34 39 46 3691.04 41 58 48 43 51 40 52 27 42 39 41 21 35 52 3591.06 37 43 42 39 38 43 49 35 37 42 37 27 37 49 4791.08 42 43 39 32 40 51 41 36 48 42 39 35 40 45 46

91.1 45 38 54 38 44 44 53 43 40 47 40 32 46 51 4891.12 52 30 41 41 38 56 43 39 49 53 45 23 36 41 5591.14 37 25 42 42 52 56 46 34 36 39 29 25 29 47 5191.16 36 37 48 32 52 32 38 20 42 37 33 31 31 57 3691.18 38 19 41 51 41 35 46 36 42 38 35 39 34 45 47

91.2 39 25 42 28 42 41 36 47 36 35 36 35 35 53 3891.22 42 40 28 37 41 33 53 33 47 32 42 27 27 59 3591.24 42 26 36 36 38 39 57 33 38 49 33 33 34 43 5191.26 51 31 44 41 31 39 39 33 40 44 29 29 38 50 3391.28 39 36 19 41 38 38 42 36 43 47 35 40 38 37 39

91.3 32 36 45 45 45 36 50 32 42 36 37 38 46 55 4691.32 48 27 42 29 38 47 39 35 49 34 45 37 37 40 4491.34 35 26 30 50 39 33 58 40 40 41 46 32 34 57 4591.36 39 29 30 45 39 37 46 36 40 38 38 22 39 49 3991.38 40 28 23 29 37 36 42 34 34 32 37 33 32 29 41

91.4 31 24 39 43 44 38 49 37 37 43 44 36 40 46 3391.42 34 32 38 56 37 29 42 39 35 39 25 34 42 48 47

367

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

91.44 35 28 29 35 35 35 55 46 34 42 36 33 44 48 3091.46 41 35 33 47 50 41 47 44 35 42 34 33 36 42 3191.48 41 30 44 29 43 46 43 26 44 27 42 30 38 45 40

91.5 39 37 45 37 33 40 29 43 35 38 33 49 46 42 3591.52 29 29 42 38 40 28 50 42 44 42 41 32 38 48 3691.54 39 35 35 40 31 42 39 39 32 46 31 30 50 49 3991.56 33 22 31 36 40 42 38 30 35 31 37 31 42 45 3191.58 48 27 32 36 28 34 48 33 42 43 39 27 36 53 33

91.6 39 25 41 38 31 45 47 35 53 38 43 20 38 50 3091.62 32 35 38 40 43 46 49 39 35 48 42 36 37 41 4091.64 43 20 41 41 39 44 45 43 39 36 48 22 40 47 4591.66 42 30 34 38 40 41 37 47 39 35 42 36 39 35 4491.68 50 37 34 35 51 34 46 32 41 41 36 28 41 42 34

91.7 42 28 44 38 44 39 48 43 45 31 49 44 40 52 3791.72 37 21 36 42 28 30 48 33 42 49 60 33 36 43 4191.74 38 36 29 46 55 39 44 32 38 40 33 23 41 29 4491.76 36 40 39 35 41 46 48 32 47 50 39 36 32 40 4391.78 28 27 39 56 35 48 59 47 42 35 41 32 38 51 37

91.8 51 36 38 39 46 43 46 45 34 51 49 38 36 58 3391.82 30 36 44 44 44 48 40 33 43 46 24 33 34 41 3891.84 50 33 34 47 48 46 40 28 42 37 45 39 40 39 4291.86 36 35 43 38 49 46 52 29 38 46 30 30 42 42 3691.88 48 28 37 55 42 43 53 40 51 54 51 41 30 53 52

91.9 37 27 45 35 49 47 43 43 52 37 48 27 53 46 4291.92 34 30 35 42 41 33 46 41 42 49 52 28 37 41 3891.94 41 40 36 38 40 50 46 43 48 35 43 33 40 50 3491.96 48 38 46 47 36 47 40 46 49 44 50 18 41 37 4791.98 39 26 41 38 34 55 40 33 34 49 50 39 36 47 52

92 38 46 37 48 39 60 53 38 52 43 52 34 51 50 6092.02 38 31 32 46 38 55 49 47 48 53 40 22 49 44 4592.04 60 27 32 49 49 44 52 50 58 51 46 48 53 60 3892.06 44 41 37 53 41 52 52 66 50 50 50 45 56 44 4892.08 51 30 48 49 37 59 52 42 51 43 49 39 43 48 41

92.1 48 26 40 50 31 45 50 35 51 57 52 39 49 60 4992.12 35 30 47 54 45 44 49 35 51 53 56 43 54 41 4692.14 50 37 55 49 47 61 54 42 46 51 54 39 55 58 5192.16 68 41 43 67 61 52 59 38 44 66 50 49 55 50 5692.18 56 40 43 47 51 55 45 54 49 51 46 47 74 56 55

92.2 66 37 39 47 45 45 46 51 56 44 48 54 74 70 5292.22 58 40 38 53 58 53 54 51 43 59 51 46 58 49 5192.24 55 32 52 46 48 62 53 55 55 65 52 44 60 66 4792.26 56 35 50 59 49 44 52 46 50 57 44 53 56 58 32

368

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

92.28 79 28 46 51 55 50 48 46 56 42 45 36 62 63 6492.3 71 46 38 59 44 53 39 44 58 35 42 38 60 67 60

92.32 58 37 37 51 47 51 51 31 42 50 49 33 61 52 3792.34 76 44 37 53 57 46 65 62 44 44 38 33 60 62 5392.36 63 39 42 63 52 64 48 43 50 44 45 34 92 57 5092.38 76 37 44 63 49 56 53 64 48 41 36 33 53 52 55

92.4 55 41 41 66 47 41 50 43 44 54 37 26 44 49 4292.42 56 36 38 50 50 50 43 39 57 45 39 28 52 55 4992.44 58 34 32 41 48 44 54 40 39 54 53 31 59 61 5592.46 65 35 42 60 50 39 52 38 54 51 43 27 35 55 6392.48 44 41 59 50 48 53 57 41 52 49 43 35 47 61 50

92.5 55 56 39 52 40 50 44 47 42 56 40 35 62 47 5192.52 50 40 41 46 35 50 45 49 51 30 43 26 53 47 5192.54 54 43 47 58 38 48 54 46 40 44 36 38 39 43 5892.56 63 29 51 51 56 52 51 46 59 47 53 25 50 59 7092.58 48 40 36 51 37 45 47 59 52 46 45 30 35 47 53

92.6 59 39 31 47 45 54 55 45 53 37 46 30 42 41 4092.62 50 33 36 51 38 44 56 59 50 44 45 34 42 53 3792.64 44 32 36 52 45 54 54 45 50 38 41 27 57 40 4892.66 46 41 39 35 55 56 47 35 46 31 40 29 42 43 4092.68 48 31 26 47 48 49 40 48 68 37 46 38 43 47 45

92.7 72 27 49 36 43 44 67 33 42 41 41 29 27 48 3692.72 48 29 34 48 55 34 48 40 53 49 53 27 42 46 4292.74 41 46 31 42 32 43 52 36 41 51 48 44 41 44 4292.76 49 38 36 47 42 43 44 45 46 48 27 31 58 47 4692.78 47 38 35 53 44 43 36 29 39 36 40 35 48 37 46

92.8 56 37 33 52 49 53 40 48 45 42 33 42 45 53 5892.82 49 25 27 47 52 49 55 41 36 39 52 24 38 46 4192.84 43 33 43 40 50 61 38 39 45 47 48 23 48 40 4292.86 43 38 42 54 34 40 47 41 38 41 31 27 39 47 3492.88 42 39 48 54 44 30 56 45 47 38 42 34 35 41 35

92.9 44 28 34 53 49 56 50 47 40 45 52 40 36 49 3492.92 40 31 41 42 37 41 63 39 45 37 40 30 31 44 4592.94 42 38 42 48 44 53 38 32 49 43 45 28 39 42 3392.96 36 29 38 50 44 50 36 49 35 37 44 32 37 63 4492.98 45 32 36 43 38 42 51 38 42 38 52 32 29 37 46

93 42 29 37 42 54 39 44 43 26 52 42 27 32 42 4893.02 57 29 34 59 40 48 53 52 52 43 40 29 41 39 4693.04 39 34 51 45 52 54 46 40 38 30 53 28 37 45 4893.06 35 29 43 55 51 59 39 37 49 47 34 36 41 45 3593.08 51 33 40 37 46 45 42 53 47 46 48 40 44 56 51

93.1 41 26 50 37 31 45 45 43 47 48 34 24 48 53 51

369

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

93.12 52 26 41 48 62 34 38 56 50 43 53 44 39 48 4993.14 44 33 41 46 47 41 49 46 46 46 33 43 33 45 5693.16 45 38 60 50 59 40 45 41 47 60 36 29 36 49 4093.18 40 33 47 36 52 36 43 35 42 53 32 28 55 38 44

93.2 53 30 39 38 58 42 49 48 56 47 38 21 31 43 4793.22 60 45 39 43 46 40 53 40 45 45 32 31 51 46 3993.24 54 35 43 46 44 57 52 37 47 44 47 34 46 47 4893.26 55 36 35 48 36 47 43 57 60 46 40 35 44 52 5093.28 59 40 43 56 52 44 38 42 50 42 43 25 45 43 46

93.3 56 29 29 49 39 38 43 43 41 40 45 43 50 57 3993.32 53 28 50 39 43 41 38 47 37 42 40 32 40 53 4793.34 66 34 47 38 43 30 46 44 50 43 35 24 44 44 3993.36 56 37 50 46 41 56 53 44 39 45 34 23 44 41 4593.38 33 30 48 46 40 38 32 36 50 39 39 29 44 46 32

93.4 50 26 35 41 39 41 47 35 50 45 42 29 36 50 4593.42 45 47 49 56 39 36 49 43 51 48 55 20 35 45 4593.44 55 39 39 35 41 49 34 48 46 43 38 23 43 43 4793.46 59 29 37 50 46 29 43 35 45 47 34 31 46 45 4393.48 38 30 50 36 39 39 55 34 59 57 53 43 40 63 43

93.5 50 32 33 42 39 34 43 42 58 49 35 42 35 54 4193.52 40 30 37 38 40 41 66 45 39 45 39 29 42 54 3893.54 45 27 44 29 39 37 31 38 60 37 34 32 38 52 4493.56 51 37 41 38 39 34 51 38 52 50 41 26 51 44 4493.58 40 30 44 35 49 47 29 54 53 30 33 25 25 46 35

93.6 40 40 35 68 35 37 53 41 40 35 30 27 42 34 3193.62 43 36 35 44 56 45 51 40 54 39 37 34 36 38 3793.64 35 28 48 35 37 36 36 37 33 32 29 43 39 51 3993.66 55 37 47 44 41 38 48 43 27 30 30 34 34 44 4693.68 45 36 33 36 43 35 40 45 31 40 30 21 47 38 40

93.7 43 26 43 31 45 47 31 47 42 33 38 39 38 43 3493.72 46 30 35 47 39 50 34 34 49 41 36 33 38 43 3793.74 35 27 32 47 33 48 44 37 49 30 39 37 26 53 2893.76 43 37 47 48 35 47 41 35 50 35 43 26 34 42 3093.78 54 20 43 30 30 34 38 44 40 34 48 30 42 40 48

93.8 29 38 40 34 42 39 36 35 38 35 36 30 46 43 4993.82 43 32 32 44 36 35 44 26 45 34 28 37 34 39 3993.84 42 38 34 45 41 40 44 44 34 25 41 30 40 45 3993.86 33 33 40 34 29 42 33 46 46 37 32 32 43 39 3493.88 53 26 47 33 53 45 29 34 40 38 31 36 39 35 42

93.9 30 35 48 42 35 40 36 30 47 32 27 29 37 35 2993.92 38 35 33 43 37 44 47 37 38 32 41 29 42 38 3593.94 27 29 48 32 41 34 40 35 30 35 39 27 39 39 40

370

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

93.96 35 30 37 30 33 39 37 44 32 33 43 24 45 32 3493.98 46 28 43 42 46 41 43 33 37 42 39 16 50 34 51

94 36 32 46 32 39 38 37 24 50 43 36 24 50 34 4294.02 40 33 47 41 27 41 43 35 39 48 37 31 29 43 4594.04 35 23 33 43 44 25 38 54 46 40 42 29 46 42 2794.06 45 40 42 33 49 38 51 36 37 35 35 24 33 42 3194.08 34 25 44 47 59 39 38 33 43 35 44 43 44 39 37

94.1 40 35 35 37 37 34 58 46 42 28 32 23 36 46 4194.12 27 26 41 39 31 36 35 42 46 30 34 38 32 29 4494.14 40 42 36 47 34 39 37 35 43 39 38 29 37 36 3294.16 48 27 31 34 45 41 40 39 37 39 33 36 33 35 4294.18 37 31 47 30 55 43 39 44 46 48 46 43 33 34 30

94.2 44 31 42 38 36 43 39 38 28 31 40 22 34 34 3394.22 28 24 36 37 47 32 33 28 41 31 40 38 35 48 4494.24 48 33 52 40 39 28 38 41 52 44 38 26 30 36 3994.26 27 30 37 37 39 36 40 49 46 32 35 18 33 51 3994.28 47 32 34 36 47 49 33 44 39 48 41 39 34 32 41

94.3 40 42 43 41 43 41 43 27 32 40 34 37 33 42 3994.32 49 23 31 34 47 45 34 42 51 28 34 29 33 38 4094.34 36 25 37 51 38 42 37 25 33 36 43 53 33 35 4594.36 40 31 39 31 41 41 41 34 31 41 31 30 37 30 4294.38 31 28 44 47 38 28 39 31 43 38 36 16 43 29 44

94.4 23 34 43 28 40 40 33 44 45 45 48 36 39 38 3494.42 51 26 40 40 36 29 41 37 45 37 34 27 31 36 3194.44 44 23 41 48 50 31 47 36 52 39 44 32 32 45 3994.46 46 27 41 45 37 46 42 42 46 38 34 27 29 42 3394.48 52 26 43 29 46 36 44 39 52 42 46 28 36 38 30

94.5 33 27 45 44 40 46 46 37 45 41 34 19 42 33 3794.52 37 27 49 39 35 27 50 30 35 29 34 27 47 49 4194.54 26 31 29 29 55 41 40 34 34 45 40 40 36 43 3594.56 37 21 32 36 42 46 56 47 58 49 38 31 41 36 4094.58 30 18 50 42 42 34 57 31 41 42 36 34 36 53 35

94.6 40 39 46 46 49 35 60 43 40 45 36 28 32 43 4994.62 41 34 45 36 44 51 47 42 40 41 40 32 31 34 4994.64 42 35 31 41 45 43 46 43 45 50 44 17 37 38 4494.66 38 38 59 39 67 41 51 47 41 46 38 30 34 37 4094.68 36 23 42 36 49 49 60 44 41 49 35 24 43 46 49

94.7 38 27 43 43 38 49 48 37 41 49 37 33 30 30 4894.72 48 45 37 38 43 41 46 55 44 47 35 38 40 44 3594.74 35 33 42 38 45 53 48 45 45 58 50 19 41 35 3394.76 39 27 48 36 57 46 39 33 39 60 37 38 39 51 3494.78 36 31 39 39 60 41 39 47 33 40 36 35 25 44 35

371

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

94.8 33 36 28 41 40 44 46 48 44 38 29 32 42 41 5694.82 41 28 38 36 47 37 45 55 30 45 44 31 24 42 4594.84 41 36 46 41 50 38 41 59 31 43 33 31 19 41 4994.86 45 45 43 39 38 49 50 46 48 44 34 30 31 40 5094.88 45 30 39 45 49 45 46 50 35 44 43 39 43 48 46

94.9 40 26 41 34 45 44 38 48 34 46 37 37 44 35 4994.92 37 34 54 27 36 43 53 55 37 42 43 34 41 35 3794.94 43 29 46 48 50 52 43 54 42 46 41 30 35 47 4694.96 47 27 47 38 42 50 50 42 55 45 37 35 36 48 4994.98 44 38 55 43 43 45 57 52 46 46 30 25 44 33 62

95 44 40 50 51 43 58 46 48 48 55 45 25 48 44 5595.02 45 33 43 48 36 49 54 52 42 46 42 30 46 50 5495.04 33 41 61 38 58 40 59 47 36 55 38 25 43 45 4995.06 43 43 54 44 67 45 45 50 51 51 45 39 39 39 4695.08 41 33 53 47 52 38 53 52 36 45 57 30 60 38 48

95.1 49 37 57 40 54 45 57 46 51 49 27 46 40 44 5795.12 51 31 60 48 69 40 60 52 53 49 38 33 34 46 5295.14 32 44 52 36 63 45 51 41 63 42 40 29 45 50 5095.16 48 28 49 37 51 52 49 44 47 37 44 40 52 54 4795.18 43 21 60 41 66 37 40 48 51 57 42 26 29 42 54

95.2 39 30 55 32 47 49 52 48 52 42 51 38 34 46 6295.22 38 34 54 37 49 48 49 43 58 40 49 20 35 56 5295.24 41 36 42 40 37 42 60 44 46 45 32 25 30 54 4195.26 36 31 52 44 50 45 47 46 65 48 40 23 41 42 4295.28 44 27 53 32 31 44 59 41 56 35 20 32 31 44 46

95.3 38 29 54 44 36 38 50 49 52 51 35 52 35 49 5295.32 42 40 44 37 44 50 53 62 67 50 49 40 31 44 4495.34 48 34 47 40 52 48 62 55 53 40 35 22 35 35 5195.36 49 42 54 43 44 43 56 47 55 45 44 42 39 55 4695.38 52 24 54 36 53 47 66 37 41 36 36 31 44 52 40

95.4 33 43 48 45 56 49 62 65 56 44 33 29 45 46 5695.42 44 32 50 39 47 45 47 41 57 47 42 28 42 49 4095.44 40 27 53 37 52 46 57 49 47 51 39 29 43 42 5395.46 33 34 50 36 40 56 53 50 62 34 40 32 38 44 5295.48 47 38 49 39 49 52 53 46 45 42 41 31 36 43 40

95.5 43 40 46 50 44 45 50 39 64 41 37 36 45 46 3795.52 43 37 53 43 33 62 49 40 42 45 43 29 34 54 4895.54 53 25 56 43 42 58 43 43 51 38 36 24 42 53 4495.56 37 38 41 36 34 33 33 54 54 45 46 38 37 41 4795.58 48 30 41 35 33 62 45 47 61 39 45 33 40 48 45

95.6 35 33 37 37 44 47 58 35 49 38 44 27 41 46 5595.62 43 33 45 39 47 45 50 41 54 43 43 11 45 43 53

372

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

95.64 37 30 35 52 38 58 64 43 56 32 34 27 40 43 3795.66 40 42 37 48 40 48 44 45 43 59 37 27 41 61 5695.68 48 26 48 38 45 56 53 43 56 44 30 27 45 59 48

95.7 42 30 34 38 41 45 49 47 55 40 41 26 45 54 4395.72 29 29 43 42 44 49 48 44 59 48 30 30 42 58 3695.74 45 27 36 40 40 41 44 51 57 35 35 33 39 47 5095.76 49 28 47 38 40 43 67 45 38 39 39 31 45 51 4695.78 41 43 35 45 41 42 59 42 40 28 29 30 49 42 37

95.8 60 24 38 40 53 67 45 54 62 43 43 32 39 43 2495.82 39 41 48 42 45 44 51 29 56 43 49 28 46 45 3495.84 49 40 41 42 45 45 44 36 52 36 35 25 54 46 3695.86 64 31 45 33 37 48 60 54 64 37 33 39 39 50 4595.88 42 25 37 50 50 61 61 40 48 40 46 43 38 44 29

95.9 35 40 49 35 39 51 52 39 44 33 27 36 42 32 4795.92 43 30 45 42 41 48 50 32 53 37 40 43 39 50 3295.94 43 34 49 56 27 47 40 41 48 32 34 44 50 48 4795.96 27 30 39 42 43 51 39 46 51 32 40 44 45 36 3495.98 30 40 34 46 49 40 54 36 64 34 36 33 34 43 45

96 61 36 36 45 41 42 45 36 44 47 43 40 46 47 3396.02 58 41 38 43 48 44 49 52 40 37 41 38 35 48 4496.04 40 23 43 53 33 47 32 41 39 44 37 25 40 45 4896.06 41 42 39 47 44 48 42 45 58 44 38 30 41 35 4296.08 37 33 39 35 51 53 41 55 55 47 41 38 34 48 33

96.1 49 28 39 48 49 50 46 49 51 57 43 33 40 33 4296.12 37 48 37 60 55 44 60 53 49 40 35 41 43 37 3796.14 32 35 56 42 59 60 43 54 33 49 37 50 46 53 4196.16 47 38 32 50 48 58 53 54 57 45 37 42 35 51 4996.18 43 36 50 49 35 58 45 40 59 45 51 27 50 59 49

96.2 56 41 48 46 52 59 52 43 60 44 41 26 47 43 2596.22 35 35 54 43 44 30 63 43 63 35 49 34 44 50 5296.24 42 36 45 40 52 47 44 44 54 53 42 24 37 44 5496.26 36 38 49 38 43 41 52 36 53 46 42 26 41 49 4396.28 38 38 47 40 70 54 60 31 54 41 39 37 47 48 52

96.3 38 40 43 45 40 54 55 40 45 41 37 26 37 54 4996.32 46 43 51 49 43 41 51 42 59 38 44 27 54 43 3896.34 49 39 41 41 56 52 57 44 45 49 44 33 47 33 5096.36 36 47 41 40 51 47 54 49 46 44 36 29 39 56 3696.38 35 30 40 38 47 47 51 42 62 48 41 49 43 57 39

96.4 41 39 45 32 44 52 49 57 46 44 32 36 36 34 3796.42 47 35 37 44 55 41 41 43 36 51 31 40 53 58 4396.44 35 34 49 50 34 52 52 37 45 34 36 27 40 53 4896.46 38 31 45 50 48 60 58 34 59 58 40 33 41 61 40

373

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

96.48 54 31 36 54 54 48 42 43 53 47 47 41 48 60 4596.5 47 30 49 48 54 46 43 38 50 40 34 38 43 44 54

96.52 40 34 49 47 45 39 47 44 43 38 32 47 38 48 5596.54 49 38 51 54 49 45 53 44 46 38 40 38 48 53 4596.56 47 41 51 35 44 56 53 38 59 32 51 36 39 57 4696.58 43 43 60 50 52 51 48 49 57 48 34 31 40 58 55

96.6 42 32 40 46 48 40 56 49 46 42 47 41 45 51 5796.62 43 42 46 54 49 42 42 41 46 50 46 34 50 54 5396.64 39 42 44 36 48 46 46 60 54 52 43 39 41 46 4496.66 57 31 46 50 59 50 43 42 40 49 43 36 45 57 6996.68 45 37 40 39 51 33 45 48 56 53 48 38 43 46 44

96.7 51 30 57 56 37 48 58 38 39 38 48 23 50 51 5096.72 48 36 39 51 43 43 58 32 51 45 38 28 49 49 4596.74 42 25 43 31 46 45 48 49 55 49 43 29 52 55 3696.76 37 40 55 48 53 45 46 43 47 44 52 30 53 48 4496.78 35 35 43 44 55 42 46 42 34 40 36 33 52 54 45

96.8 52 34 35 40 46 56 57 43 48 41 47 17 55 32 3596.82 45 33 43 52 42 46 51 42 51 34 37 33 56 53 4696.84 48 38 36 41 40 39 43 35 46 40 41 24 43 42 4296.86 39 32 38 38 54 43 56 40 50 33 42 35 50 45 4796.88 48 36 29 53 52 45 48 43 43 36 43 34 36 61 41

96.9 30 38 35 42 35 51 55 46 39 47 38 30 52 50 3196.92 43 33 39 45 40 47 51 48 51 42 32 29 42 43 4396.94 54 32 38 39 44 50 47 55 48 43 47 35 32 63 4996.96 47 28 38 39 43 50 59 49 64 41 37 31 51 55 3596.98 47 43 56 43 40 43 46 39 55 39 40 32 45 46 45

97 50 32 26 51 47 55 51 37 45 39 47 34 47 37 4297.02 48 35 51 38 44 44 52 41 50 39 39 33 34 53 5697.04 29 28 52 46 40 43 53 37 48 36 43 45 45 54 5097.06 44 34 29 40 40 56 57 49 44 61 34 25 35 45 3197.08 47 30 43 51 42 33 44 43 56 31 40 31 37 41 35

97.1 51 31 41 47 52 51 46 43 33 45 38 37 35 44 4397.12 49 32 51 47 44 51 55 47 48 44 46 31 37 37 4497.14 42 33 33 27 43 44 45 44 52 49 35 24 48 39 4797.16 36 29 37 42 44 54 38 39 44 32 46 29 35 42 4997.18 57 30 38 43 46 45 48 41 46 34 41 34 55 50 35

97.2 48 34 37 35 53 47 41 32 39 40 34 27 39 53 3397.22 43 38 35 40 30 49 38 34 54 41 40 32 40 46 4097.24 41 42 52 35 48 41 43 44 47 43 56 29 36 59 3897.26 41 38 43 38 53 52 51 38 48 49 46 38 38 46 3897.28 50 42 34 43 37 46 60 43 52 32 41 37 45 40 37

97.3 35 29 51 46 38 49 54 39 54 39 34 27 48 48 42

374

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

97.32 40 38 36 52 43 52 35 39 38 45 34 36 43 51 3897.34 51 32 50 39 36 46 41 38 44 31 53 27 37 38 4597.36 29 38 26 48 38 50 32 45 40 48 43 29 48 50 2597.38 45 32 37 45 37 34 41 38 35 40 43 28 34 47 31

97.4 38 35 45 38 45 46 46 41 35 41 40 39 40 37 2697.42 35 23 39 41 34 37 49 45 40 42 35 30 39 45 3197.44 47 36 42 48 43 45 40 37 53 35 42 38 36 41 3297.46 47 28 39 29 52 44 31 43 46 40 35 32 40 39 4097.48 49 39 40 43 45 46 38 30 41 39 37 29 41 43 33

97.5 28 39 31 30 51 45 42 47 39 42 45 31 40 42 3497.52 29 34 39 47 61 42 60 37 55 47 40 37 36 48 4297.54 45 30 51 47 43 43 47 48 31 59 52 27 42 38 5197.56 37 28 37 40 49 42 52 33 48 46 37 28 46 42 3797.58 41 24 42 43 52 48 48 47 51 42 38 26 31 41 37

97.6 44 35 27 54 48 41 59 35 40 55 46 23 30 38 4297.62 43 37 47 52 39 29 38 41 46 52 44 28 43 55 3397.64 40 30 52 43 42 47 42 41 56 45 42 43 35 49 4497.66 47 36 43 47 42 45 52 40 44 48 47 34 43 37 4697.68 45 30 32 34 37 47 53 41 51 42 37 27 47 48 48

97.7 38 34 47 50 32 42 44 40 39 46 46 35 43 49 4697.72 41 32 36 34 37 45 45 52 49 38 39 28 49 38 3297.74 28 36 42 35 43 46 42 46 45 39 34 28 46 36 3997.76 49 32 44 44 45 51 37 30 48 36 50 45 39 44 5297.78 35 32 35 36 38 34 53 41 41 40 44 22 42 43 50

97.8 46 27 39 47 39 46 33 40 43 45 49 32 41 51 3297.82 38 31 31 54 38 41 44 33 33 34 44 31 44 44 3997.84 40 24 38 55 51 48 40 44 44 47 44 27 51 50 3997.86 48 40 48 49 47 60 38 47 43 33 46 37 41 39 4897.88 39 28 34 42 36 48 40 36 43 54 42 30 52 43 44

97.9 42 38 35 39 37 47 46 47 50 46 40 44 42 47 4497.92 51 37 45 38 37 53 35 50 52 49 48 37 42 38 5297.94 40 32 46 38 45 44 40 38 34 39 37 49 45 36 4197.96 32 39 38 43 40 43 52 31 38 46 37 35 33 45 4697.98 38 29 42 50 50 45 49 51 39 48 51 25 33 37 42

98 40 33 36 33 46 50 47 36 41 51 43 26 43 38 4298.02 39 29 42 33 40 41 49 44 44 36 46 36 44 45 4698.04 44 42 43 45 44 38 48 49 40 37 51 40 57 48 5698.06 34 42 35 35 34 40 47 48 49 45 41 34 43 50 3498.08 40 38 51 41 43 43 44 53 42 35 36 27 42 40 57

98.1 43 41 39 40 36 43 50 51 42 44 38 30 55 39 4798.12 46 32 49 38 50 43 48 57 42 37 37 41 52 45 3498.14 44 41 47 46 34 47 52 34 40 43 49 34 50 45 32

375

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

98.16 42 42 39 39 44 49 49 43 42 42 52 40 35 52 5798.18 34 47 41 34 46 60 37 40 53 40 40 36 47 34 50

98.2 48 32 38 36 58 51 49 45 40 42 42 33 44 37 5198.22 43 25 52 45 42 43 40 43 42 43 51 34 42 52 4198.24 45 31 47 34 42 43 57 44 54 35 48 31 37 52 4098.26 50 36 47 55 65 47 54 42 50 33 37 29 35 50 4498.28 47 44 39 48 45 46 47 32 46 50 43 20 47 42 42

98.3 49 36 30 49 41 44 46 41 52 42 44 36 40 44 3798.32 40 32 38 54 49 40 65 43 54 47 35 41 36 39 4198.34 52 42 41 49 49 57 48 42 46 42 46 39 51 49 4798.36 42 33 46 39 45 50 42 42 48 43 52 40 46 48 5498.38 38 34 37 41 34 53 48 44 62 35 45 40 34 47 40

98.4 44 41 29 45 54 46 56 51 46 41 51 37 40 55 4398.42 60 35 39 49 66 41 60 39 43 43 28 50 38 40 3298.44 51 42 35 36 51 52 52 34 48 39 50 50 48 50 4298.46 42 42 45 39 61 46 46 32 44 54 52 32 41 57 6598.48 59 34 43 59 51 51 50 49 44 44 52 30 53 48 38

98.5 61 28 53 48 46 44 51 43 51 51 48 38 42 45 4898.52 43 37 39 43 51 52 61 52 49 54 40 38 43 46 4898.54 42 33 45 50 41 53 48 55 57 48 58 35 42 50 4398.56 45 28 36 49 49 45 50 51 48 29 48 56 40 40 4198.58 39 35 47 46 52 51 58 53 36 47 50 34 51 46 37

98.6 54 32 62 59 60 49 65 47 53 43 45 52 50 48 4998.62 54 31 58 41 38 50 56 54 64 43 43 36 52 67 5998.64 35 46 35 46 39 53 48 50 38 50 47 28 46 44 4798.66 45 56 57 53 48 50 54 38 47 57 50 53 50 52 5498.68 51 41 47 52 48 38 59 49 47 43 50 27 43 35 43

98.7 59 40 48 51 55 47 50 40 63 38 51 31 56 56 5598.72 52 44 53 63 54 43 63 50 63 54 39 36 51 64 5698.74 52 40 61 67 59 65 72 52 49 55 50 36 48 62 4898.76 50 40 54 52 57 34 62 50 47 52 59 23 37 54 4298.78 46 36 51 55 57 53 62 50 53 51 42 43 37 52 51

98.8 39 37 48 64 47 47 53 53 51 58 52 41 41 47 4398.82 44 52 47 56 52 47 53 55 52 60 59 38 53 59 5698.84 44 35 58 44 60 54 65 44 49 43 45 45 40 44 4998.86 39 43 59 55 44 57 50 77 69 47 47 41 44 52 5098.88 42 34 31 49 63 45 54 54 60 47 48 35 53 58 40

98.9 67 30 51 54 65 52 72 59 55 54 49 38 49 61 5198.92 59 45 52 49 55 33 64 69 52 47 42 36 54 47 5098.94 56 41 41 63 47 59 57 51 61 58 41 29 52 56 5998.96 43 38 46 57 55 50 64 60 61 36 50 41 58 60 4798.98 51 31 48 56 49 62 67 55 55 50 49 39 51 45 37

376

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

99 39 51 33 54 56 55 53 68 62 46 64 37 54 67 4799.02 58 41 51 50 61 66 73 62 47 58 55 60 45 55 5199.04 37 42 46 50 65 55 72 73 54 46 60 45 41 54 5499.06 52 51 46 60 59 49 64 71 55 49 84 39 50 51 5899.08 57 35 35 57 56 59 70 64 68 68 62 50 49 52 56

99.1 51 36 51 65 63 51 83 59 55 71 70 45 53 51 5799.12 62 48 59 67 63 71 68 81 59 68 67 50 50 50 6599.14 49 49 53 61 66 49 64 74 64 72 99 58 63 71 5799.16 57 36 34 62 47 67 76 81 62 61 88 40 53 62 4599.18 60 37 57 63 62 52 67 81 58 62 85 50 63 52 63

99.2 46 45 64 53 69 61 75 76 75 74 93 44 74 44 6299.22 68 32 39 64 56 72 97 80 92 48 87 48 60 69 6199.24 51 47 44 58 67 62 71 89 74 67 89 65 52 64 5299.26 55 49 59 72 70 66 88 77 76 76 92 73 71 60 6299.28 62 46 52 62 61 76 101 65 99 82 93 82 62 56 78

99.3 69 34 49 70 68 88 69 84 74 88 108 57 57 66 6599.32 50 45 50 75 66 65 90 94 96 77 93 56 61 61 7399.34 87 46 52 81 65 69 85 105 84 84 97 60 80 73 5499.36 57 59 44 72 91 72 104 109 83 84 123 73 72 73 7299.38 64 46 50 99 90 84 94 105 104 96 100 74 73 72 84

99.4 77 58 57 85 89 70 108 104 84 102 89 77 57 72 7099.42 76 50 35 81 90 72 118 108 115 104 95 59 86 75 9099.44 72 56 58 89 105 78 114 107 113 93 124 90 95 87 9199.46 73 53 48 82 83 101 142 121 137 111 104 97 89 92 10299.48 89 50 52 129 85 112 123 129 155 123 125 80 106 96 112

99.5 98 67 79 98 104 95 138 129 129 124 146 85 110 118 11099.52 95 71 76 104 108 106 140 164 114 140 133 101 120 107 11299.54 104 52 75 102 101 113 144 125 145 161 149 102 115 113 13299.56 102 65 83 136 114 99 139 149 134 152 181 116 151 128 13499.58 122 80 74 132 115 107 131 153 123 186 181 129 151 152 150

99.6 133 82 107 117 125 133 145 144 155 221 195 132 168 152 18699.62 161 95 110 138 127 130 173 131 163 236 202 141 200 191 17099.64 172 123 96 154 159 152 152 160 177 230 202 122 202 206 15999.66 181 100 103 150 126 150 153 166 162 219 216 152 235 190 20499.68 197 121 113 164 169 164 172 174 168 198 197 149 241 212 189

99.7 246 132 120 143 156 142 157 172 181 190 186 145 245 199 17299.72 268 110 117 179 166 155 159 165 166 176 167 102 258 219 16899.74 252 113 113 166 173 152 138 168 159 159 171 125 215 233 14899.76 298 129 135 204 211 150 156 164 176 171 150 126 225 185 14399.78 264 108 92 166 164 151 157 164 182 151 153 102 190 238 125

99.8 242 105 98 164 156 142 145 175 168 160 139 91 200 159 13399.82 239 77 89 176 164 147 161 139 164 133 122 108 183 154 138

377

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

99.84 181 108 104 164 156 138 147 176 168 151 145 101 197 156 12499.86 197 75 76 155 137 138 139 159 167 114 144 68 153 180 12599.88 182 84 89 159 115 145 143 149 167 144 149 86 147 132 120

99.9 158 99 93 157 123 149 163 170 174 138 113 78 143 135 12899.92 151 94 88 159 132 122 116 154 161 163 159 88 172 157 10999.94 161 74 97 143 135 141 136 148 170 166 138 75 164 110 10799.96 123 92 82 149 114 127 149 144 185 144 136 47 146 158 12299.98 118 68 87 136 123 139 163 140 171 140 141 84 169 144 116

100 172 81 75 156 113 145 125 144 150 161 134 35 175 159 164100.02 158 100 78 142 114 137 120 159 146 144 154 63 172 135 125100.04 152 106 101 150 125 110 121 140 151 142 143 56 148 158 125100.06 153 87 84 154 134 143 139 129 167 130 145 66 159 149 143100.08 180 82 76 131 121 154 121 104 152 140 120 55 170 164 131

100.1 153 82 86 144 127 134 137 130 138 102 129 56 137 141 106100.12 145 77 83 128 125 127 116 152 147 98 141 80 125 118 127100.14 155 76 75 120 123 134 121 148 152 120 124 72 127 131 98100.16 169 81 68 135 125 130 127 139 151 94 115 79 135 122 100100.18 141 56 68 155 116 132 135 138 145 124 123 70 113 109 107

100.2 137 71 82 124 122 134 137 120 152 106 122 94 110 93 94100.22 119 75 70 121 106 133 122 138 160 107 132 56 108 114 106100.24 108 70 55 140 123 110 131 131 142 111 119 76 110 123 144100.26 115 66 67 127 103 134 130 163 148 124 131 72 133 107 116100.28 100 57 73 117 106 125 135 160 148 131 123 73 129 120 103

100.3 113 74 79 132 115 138 139 161 157 129 155 109 128 121 109100.32 108 70 64 154 100 114 148 139 140 127 142 81 131 144 104100.34 105 80 70 140 119 135 134 151 154 148 134 106 128 125 123100.36 115 65 76 128 117 127 129 147 157 122 142 111 124 118 118100.38 122 78 70 132 136 120 115 156 162 149 136 106 121 107 129

100.4 141 87 82 137 113 131 164 150 172 134 132 107 146 136 121100.42 141 83 94 128 125 138 177 161 167 137 153 125 148 125 162100.44 147 86 92 147 120 163 153 185 174 120 163 100 178 134 150100.46 133 87 89 160 134 138 174 157 171 159 170 106 146 128 170100.48 152 91 88 160 132 153 135 186 177 184 167 157 156 140 155

100.5 154 98 85 117 146 141 151 177 175 192 179 119 165 154 166100.52 149 96 107 145 131 147 150 184 157 203 191 164 152 150 192100.54 186 132 86 145 146 143 159 188 177 211 175 150 179 159 180100.56 162 108 82 174 143 184 189 163 168 229 209 172 209 181 194100.58 186 110 95 161 128 177 148 191 173 242 204 168 228 192 220

100.6 191 115 120 191 151 161 150 179 182 239 217 146 254 225 208100.62 231 143 105 188 145 172 159 189 174 229 217 193 279 226 203100.64 241 118 119 193 178 170 167 175 180 260 188 146 282 201 209100.66 254 134 129 201 183 177 164 180 171 198 200 175 293 207 179

378

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

100.68 285 137 143 179 155 163 145 196 198 205 166 129 274 228 191100.7 294 145 141 199 163 171 163 177 185 220 175 159 294 226 206

100.72 313 131 119 181 202 150 140 176 185 198 191 121 279 207 181100.74 300 163 142 200 191 188 138 163 187 186 167 109 252 210 152100.76 291 131 136 186 194 191 144 161 201 201 160 120 248 172 156100.78 284 127 118 203 196 139 133 186 207 188 143 128 256 199 172

100.8 262 125 112 185 162 185 151 173 145 191 142 94 234 149 163100.82 246 104 111 186 182 175 130 181 199 164 162 60 213 155 172100.84 251 103 95 217 175 173 168 164 171 155 144 91 215 165 146100.86 210 99 128 199 163 134 140 147 173 147 141 72 178 146 132100.88 211 93 100 169 162 163 136 165 171 167 148 79 197 155 133

100.9 184 92 84 167 130 171 129 178 160 163 134 71 150 161 134100.92 181 73 84 158 147 156 134 165 181 147 136 53 164 154 120100.94 180 103 90 174 139 150 123 137 170 149 140 31 153 135 137100.96 173 87 101 175 145 167 125 164 158 148 121 57 198 146 143100.98 157 87 80 130 137 158 127 131 147 148 128 80 202 138 150

101 178 80 86 147 126 158 109 149 146 146 131 58 187 136 136101.02 164 79 104 159 116 140 103 136 144 152 118 65 152 117 125101.04 161 97 73 128 107 152 104 128 169 122 124 51 183 127 124101.06 178 83 99 148 97 134 92 145 122 130 100 60 154 123 116101.08 172 83 68 138 132 144 110 132 158 118 113 41 167 129 106

101.1 176 86 87 122 126 116 109 129 144 117 98 55 128 116 117101.12 153 73 89 141 110 107 102 111 129 109 104 35 146 127 92101.14 143 81 74 120 116 121 105 110 131 94 94 48 114 113 100101.16 170 68 93 119 89 135 114 106 109 84 97 61 118 119 64101.18 134 68 61 111 83 100 96 97 119 93 101 68 103 108 73

101.2 144 69 61 106 102 103 95 111 106 91 93 43 106 97 96101.22 111 58 62 106 109 116 76 98 122 92 88 37 108 106 110101.24 98 67 66 107 88 96 93 85 120 70 71 50 106 72 90101.26 98 75 84 106 90 104 75 117 119 81 83 51 102 85 81101.28 102 54 57 101 78 92 84 94 105 67 75 74 86 91 75

101.3 103 56 59 106 91 96 102 102 98 65 72 49 96 71 69101.32 78 46 71 101 91 85 93 93 88 69 69 34 83 78 74101.34 98 57 57 103 72 85 82 93 96 69 62 31 67 65 72101.36 68 46 62 104 72 80 71 100 133 62 62 43 88 66 65101.38 90 34 56 90 67 84 95 79 93 64 54 40 75 69 55

101.4 80 44 46 83 72 85 84 79 107 57 75 37 88 54 58101.42 71 35 59 81 55 79 57 81 102 64 63 50 76 69 62101.44 81 50 67 71 62 100 74 87 78 49 56 58 73 68 58101.46 79 57 34 72 71 78 68 60 92 68 54 60 76 62 57101.48 46 49 51 69 63 79 67 56 80 60 72 61 56 53 58

101.5 61 51 61 74 60 66 60 68 75 62 72 47 71 54 52

379

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

101.52 69 50 58 56 69 63 62 64 83 51 49 38 59 62 60101.54 65 42 69 65 74 72 59 83 76 52 51 37 65 54 58101.56 47 40 62 67 52 63 71 62 78 71 57 44 49 54 65101.58 63 54 55 59 80 73 60 66 74 51 53 38 68 57 57

101.6 67 40 47 65 57 66 59 57 73 57 61 27 51 49 57101.62 57 36 53 60 57 50 73 67 69 59 56 37 64 62 57101.64 64 41 54 56 55 56 67 70 69 47 58 26 55 64 40101.66 65 52 49 42 63 62 70 55 66 63 75 56 54 66 55101.68 55 49 60 57 63 69 71 56 61 58 63 44 51 62 45

101.7 54 47 65 51 53 59 59 62 67 55 68 36 51 67 57101.72 63 37 57 56 53 58 66 61 61 46 49 32 57 67 51101.74 67 44 58 79 57 55 64 56 71 57 57 32 59 54 58101.76 49 55 52 62 58 74 67 58 61 43 52 28 63 60 65101.78 53 39 49 58 66 51 65 57 68 58 68 30 46 60 52

101.8 60 36 60 59 55 48 74 59 64 47 65 40 54 59 67101.82 61 42 61 60 64 54 72 49 56 59 56 23 59 63 67101.84 54 43 63 55 53 50 54 54 50 52 43 40 47 59 61101.86 51 37 58 55 53 65 68 55 74 46 57 34 52 69 55101.88 65 37 45 72 54 68 50 47 58 53 46 43 55 53 51

101.9 61 50 52 55 61 66 52 51 49 44 54 39 54 62 51101.92 64 51 50 48 57 47 43 70 59 63 53 42 58 65 54101.94 57 34 58 54 46 55 70 63 62 45 49 58 41 46 46101.96 52 41 53 40 59 77 54 55 63 64 48 49 57 62 44101.98 59 40 57 46 69 53 53 55 53 58 50 56 55 61 55

102 55 45 50 69 70 57 51 51 54 42 47 53 47 49 51102.02 46 47 63 78 50 54 50 53 52 52 65 29 58 59 52102.04 37 40 60 68 53 77 61 56 65 45 72 40 49 54 69102.06 52 44 47 58 61 60 56 54 59 45 42 34 47 60 49102.08 51 59 39 49 57 46 67 52 58 43 67 40 52 54 48

102.1 45 36 60 63 57 60 57 65 57 46 47 44 46 50 56102.12 56 49 77 57 53 69 62 49 58 59 57 44 60 40 52102.14 65 52 58 46 53 58 70 72 58 49 52 51 59 51 42102.16 59 44 73 58 61 45 57 50 60 61 52 41 56 58 60102.18 57 44 62 69 67 51 65 61 66 53 41 37 50 59 47

102.2 51 45 59 55 57 43 62 43 55 65 59 62 69 58 49102.22 58 44 59 64 59 52 68 53 54 59 43 37 50 44 36102.24 45 40 68 63 89 58 61 50 62 58 42 46 53 60 57102.26 53 50 64 48 52 66 61 59 50 56 46 36 51 58 47102.28 50 49 61 55 53 58 61 45 60 81 76 29 52 59 49

102.3 53 46 66 64 64 51 55 43 69 54 57 35 55 50 49102.32 38 52 55 56 50 58 58 31 52 44 42 28 52 64 41102.34 60 44 55 66 47 48 65 45 44 66 53 35 40 61 59

380

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

102.36 53 51 66 69 48 69 53 51 72 66 49 35 50 60 66102.38 52 43 52 59 60 42 61 59 53 51 55 33 47 68 48

102.4 33 44 53 54 66 70 59 42 58 60 51 46 46 51 64102.42 54 44 54 57 42 56 42 36 54 62 49 38 54 55 52102.44 55 40 50 50 57 60 58 48 66 54 56 39 67 62 41102.46 55 38 61 66 59 60 51 51 65 47 56 40 57 58 54102.48 58 39 59 56 54 59 68 44 71 57 45 47 65 42 51

102.5 46 42 56 51 72 59 62 48 51 64 49 25 45 46 49102.52 65 45 66 51 64 48 77 45 79 51 39 39 38 51 68102.54 51 45 66 58 62 65 74 38 55 49 50 39 47 69 46102.56 57 42 55 47 62 57 63 43 70 51 44 37 41 54 52102.58 36 39 66 41 58 59 74 67 48 44 45 43 53 56 62

102.6 64 41 58 57 59 51 65 43 52 58 51 39 50 47 53102.62 42 35 48 42 65 47 57 41 52 65 49 38 37 64 43102.64 49 40 50 45 51 61 58 45 42 40 47 42 49 61 54102.66 51 43 40 61 61 56 47 46 61 45 50 36 38 61 66102.68 54 39 53 53 56 62 50 51 54 44 57 33 53 58 38

102.7 54 39 60 49 45 67 67 53 58 53 41 29 41 52 51102.72 54 43 55 59 48 49 58 48 58 54 52 48 46 42 58102.74 49 42 68 49 53 52 43 47 45 61 51 44 56 63 57102.76 40 43 58 63 44 58 56 46 45 59 47 52 55 63 51102.78 43 36 59 54 52 48 65 56 57 43 60 37 56 57 53

102.8 49 33 61 52 55 52 55 33 46 33 41 36 59 48 51102.82 54 41 44 54 68 39 59 47 43 59 60 32 49 47 48102.84 59 33 64 45 55 43 70 40 55 48 48 29 40 51 58102.86 56 43 55 53 57 41 50 59 71 46 40 54 55 50 43102.88 49 35 65 58 55 41 56 50 55 54 54 33 47 50 42

102.9 43 39 64 45 52 51 55 53 45 45 51 35 62 46 42102.92 49 48 43 63 60 58 58 45 30 49 53 56 44 59 70102.94 64 42 54 48 42 55 46 49 53 59 55 28 55 52 61102.96 44 54 54 43 45 52 44 55 47 38 50 29 49 49 53102.98 53 39 55 54 46 58 61 53 55 42 52 34 50 66 47

103 40 39 51 51 61 45 54 52 64 41 54 34 46 43 51103.02 59 44 48 51 59 62 57 43 58 44 53 32 47 59 57103.04 32 31 46 61 50 59 58 37 46 60 67 42 57 55 71103.06 51 43 53 52 48 53 51 46 46 42 43 44 52 61 61103.08 50 28 26 50 45 52 53 51 59 43 62 32 43 55 41

103.1 48 38 48 35 48 40 47 44 56 48 57 28 47 52 65103.12 44 45 44 51 54 54 70 49 62 43 51 40 51 41 46103.14 52 44 47 46 53 57 52 55 38 47 56 37 49 51 55103.16 53 38 63 54 52 66 51 46 60 45 38 42 39 53 42103.18 37 44 43 65 46 54 65 45 51 58 61 46 54 44 58

381

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

103.2 44 31 35 56 53 60 61 48 48 54 45 37 50 41 51103.22 57 36 54 55 50 47 59 54 47 55 50 36 48 47 52103.24 57 39 48 54 39 48 64 38 57 50 61 47 46 65 49103.26 45 36 63 52 53 52 64 51 48 50 53 45 46 45 52103.28 47 45 45 52 50 51 66 41 48 38 51 38 58 49 69

103.3 52 49 42 62 63 51 68 53 61 53 46 64 48 43 50103.32 51 40 49 64 51 54 64 48 69 55 58 33 55 55 49103.34 50 37 62 51 55 49 52 37 57 60 40 43 44 54 74103.36 53 35 57 66 56 60 53 38 76 45 60 40 49 51 50103.38 59 48 37 44 47 65 58 63 54 50 53 49 39 44 57

103.4 51 50 46 61 64 66 50 49 56 58 49 32 48 55 51103.42 47 40 40 55 58 52 54 50 46 53 58 47 47 51 50103.44 46 34 40 54 56 44 51 57 50 62 41 42 47 43 48103.46 60 48 54 58 51 41 61 41 55 51 55 54 47 48 57103.48 46 37 50 80 60 52 55 61 58 50 50 57 50 57 52

103.5 51 32 56 68 49 58 53 49 67 69 54 57 41 42 52103.52 47 43 52 55 58 48 65 57 70 47 42 38 53 44 58103.54 65 40 50 48 52 53 69 34 49 44 55 43 60 53 42103.56 61 45 50 61 54 50 57 56 72 34 64 43 68 53 55103.58 59 39 68 47 46 69 62 46 63 55 54 43 45 53 53

103.6 47 37 54 62 57 50 54 56 67 58 58 48 50 37 39103.62 46 33 60 54 58 52 72 54 56 56 52 44 36 43 59103.64 48 38 47 43 62 44 54 52 64 56 63 38 56 48 58103.66 55 43 52 60 62 56 75 62 62 43 58 37 58 61 69103.68 53 48 56 63 51 61 72 51 65 54 49 45 53 59 57

103.7 53 32 38 57 55 61 69 50 54 53 48 48 39 60 62103.72 52 40 51 56 61 55 72 49 73 58 68 56 43 57 55103.74 51 52 48 57 63 47 68 58 77 58 54 42 54 50 74103.76 52 39 61 49 57 59 77 67 53 63 54 65 57 63 54103.78 53 35 45 49 63 61 69 67 66 68 73 40 45 74 57

103.8 52 42 43 49 58 51 64 65 67 43 57 64 52 59 66103.82 56 47 66 60 75 64 85 57 61 61 62 46 53 45 61103.84 52 52 47 61 63 52 67 52 71 50 67 42 56 57 57103.86 52 47 46 62 47 55 70 53 77 50 64 34 57 53 68103.88 60 40 46 65 59 64 72 43 52 67 62 49 54 70 68

103.9 56 31 53 72 57 66 72 73 68 54 76 47 63 64 67103.92 60 50 55 59 60 59 75 65 56 48 87 52 74 69 64103.94 56 51 64 65 67 52 72 64 70 66 57 56 49 74 46103.96 68 53 46 52 60 52 77 86 61 74 63 63 61 77 72103.98 61 50 58 63 61 67 58 66 64 79 84 60 64 58 64

104 63 53 61 74 74 59 83 62 72 59 72 44 77 63 51104.02 42 45 55 53 68 58 65 83 49 84 80 54 63 66 57

382

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

104.04 54 44 45 74 74 61 70 70 69 65 76 54 57 72 68104.06 59 43 49 61 65 60 71 56 68 80 78 59 69 72 63104.08 69 43 47 81 65 70 78 80 72 66 92 48 65 67 69

104.1 68 41 55 79 65 76 72 63 71 63 78 70 80 56 85104.12 64 55 51 80 61 65 61 80 88 74 88 47 92 74 72104.14 73 46 48 65 89 69 82 64 77 77 62 65 74 78 80104.16 70 55 50 72 77 70 78 71 84 94 77 72 72 73 74104.18 69 54 58 72 81 92 84 77 91 72 91 61 71 93 87

104.2 57 55 55 85 89 91 87 81 86 90 77 69 83 70 88104.22 73 51 54 78 66 77 86 71 64 73 74 80 87 96 84104.24 86 58 56 83 88 87 74 79 74 83 99 65 90 83 92104.26 94 54 82 70 75 65 90 91 101 76 96 58 81 93 76104.28 77 56 56 75 66 79 82 70 97 80 95 63 95 87 89

104.3 76 57 61 85 86 89 88 95 100 85 85 70 75 96 89104.32 85 57 47 81 66 85 97 79 81 99 102 58 100 78 89104.34 100 61 53 97 88 87 96 85 99 87 91 62 84 89 112104.36 100 62 65 78 91 78 92 79 90 115 91 67 104 100 85104.38 88 61 55 101 81 94 73 82 105 105 91 74 104 89 92

104.4 89 57 59 88 86 107 72 97 96 100 99 84 94 88 79104.42 100 51 59 93 95 78 88 114 106 118 92 72 88 90 90104.44 91 56 60 77 94 109 99 85 105 113 107 74 109 94 112104.46 101 56 59 93 85 96 96 90 86 104 86 69 95 95 100104.48 94 68 62 113 91 87 102 77 95 107 105 63 112 110 107

104.5 100 58 59 86 86 95 87 88 109 111 109 73 122 94 109104.52 87 53 76 97 88 101 94 97 98 100 115 83 97 106 105104.54 116 64 64 90 76 98 98 89 113 108 85 68 104 103 106104.56 107 80 60 106 90 107 96 99 106 121 97 70 115 100 119104.58 137 70 68 104 87 77 93 97 89 129 95 76 110 113 125

104.6 126 76 61 95 97 90 101 93 107 112 99 75 125 100 108104.62 132 66 72 97 98 82 99 103 104 109 94 77 117 91 122104.64 141 67 86 99 99 115 85 124 113 103 95 77 147 126 114104.66 157 71 62 86 88 118 106 100 110 96 90 80 131 111 88104.68 164 85 70 114 91 101 92 94 109 113 113 65 117 114 85

104.7 138 81 71 125 105 89 84 83 91 104 99 81 122 116 91104.72 177 79 72 95 102 103 90 88 104 99 101 79 117 102 95104.74 139 95 62 95 109 95 88 96 97 101 111 49 128 105 87104.76 147 59 76 101 114 92 97 96 98 82 98 66 111 106 118104.78 146 92 69 88 85 87 76 106 105 116 108 61 109 103 82

104.8 136 51 64 99 105 105 71 75 104 97 99 54 100 108 81104.82 147 76 55 111 92 94 86 103 100 86 100 61 119 105 81104.84 135 66 64 97 91 94 93 87 89 116 99 43 103 91 87104.86 113 67 71 93 96 102 86 99 82 80 110 60 95 95 101

383

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

104.88 106 52 62 106 82 104 99 95 80 94 89 55 91 110 89104.9 105 66 51 102 91 103 88 85 78 98 95 54 107 98 90

104.92 99 70 57 90 82 80 93 100 96 100 94 64 89 92 82104.94 126 65 57 99 102 91 90 93 88 106 80 55 92 90 94104.96 100 60 62 100 94 101 95 83 110 102 68 56 99 78 82104.98 119 65 59 104 84 96 71 95 111 94 72 65 102 90 95

105 94 58 69 92 82 92 87 83 94 85 104 50 96 87 77105.02 135 52 64 97 88 90 81 85 103 79 71 58 87 106 80105.04 104 73 67 82 92 84 81 80 97 74 80 53 95 96 77105.06 114 61 74 81 80 106 99 90 96 88 77 69 101 88 80105.08 128 67 52 88 72 88 101 86 87 76 72 51 117 99 80

105.1 102 48 55 88 89 84 69 88 94 77 86 42 86 84 83105.12 116 56 54 94 86 92 86 89 84 92 85 55 102 79 88105.14 113 71 67 77 87 91 74 101 71 83 78 56 101 97 84105.16 97 57 48 74 92 93 84 93 94 74 96 67 102 85 80105.18 87 56 65 110 96 85 84 69 73 67 83 52 84 83 76

105.2 108 53 57 91 89 78 76 94 75 69 82 61 71 85 76105.22 80 58 54 104 78 79 92 84 99 72 82 75 77 97 70105.24 98 45 50 76 72 74 91 79 89 85 83 64 74 78 77105.26 96 52 54 89 83 85 66 81 85 76 68 42 78 70 70105.28 90 58 52 72 67 80 76 69 101 75 75 38 62 93 67

105.3 84 48 66 65 71 96 81 71 89 74 82 42 68 84 65105.32 89 49 59 74 81 85 85 76 90 65 65 59 79 65 58105.34 83 45 59 73 70 79 88 73 86 75 65 49 59 75 72105.36 73 49 68 70 79 99 77 68 76 69 81 43 68 74 68105.38 76 60 57 68 67 68 81 70 83 62 53 51 77 81 85

105.4 72 43 52 75 60 89 72 75 89 63 78 56 53 66 55105.42 74 45 47 64 67 64 78 73 84 59 72 67 68 77 63105.44 80 50 55 71 75 76 73 78 83 65 88 38 74 72 74105.46 66 47 62 82 74 65 86 59 87 68 67 48 69 79 57105.48 92 40 57 67 74 90 74 77 71 68 68 74 84 75 59

105.5 76 32 58 76 76 72 75 74 70 62 70 60 66 60 62105.52 63 49 52 64 66 82 91 68 82 66 68 74 69 86 60105.54 69 51 51 63 62 72 86 82 77 63 68 62 73 47 70105.56 64 44 49 81 65 76 82 71 87 59 76 65 58 69 56105.58 70 48 44 74 67 63 78 78 84 71 69 47 61 65 66

105.6 67 46 53 78 82 75 69 81 75 43 70 50 72 79 69105.62 60 51 55 63 86 63 76 59 73 55 78 51 63 71 67105.64 74 45 39 61 68 74 93 77 72 58 71 66 73 73 76105.66 62 48 62 82 66 80 94 73 73 56 78 68 61 72 61105.68 69 41 51 63 67 80 84 65 85 80 76 62 53 61 58

105.7 60 39 42 64 68 70 85 79 87 67 75 52 61 68 70

384

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

105.72 67 48 45 76 79 68 85 72 100 73 80 58 58 62 75105.74 59 42 39 83 85 62 73 70 79 63 73 68 50 62 65105.76 74 35 48 69 53 85 79 90 79 60 64 53 73 62 79105.78 72 34 45 73 84 89 91 86 82 63 68 56 75 75 68

105.8 58 51 53 80 74 77 87 82 77 60 85 61 65 71 89105.82 60 41 38 75 72 74 114 91 88 68 67 74 73 55 80105.84 51 48 45 77 75 84 80 92 92 71 82 63 69 59 73105.86 65 45 67 98 66 75 85 82 103 77 80 69 66 56 81105.88 79 42 55 67 61 82 96 94 87 77 86 71 54 70 85

105.9 71 55 38 92 73 55 77 104 85 80 85 77 60 77 76105.92 69 54 47 96 65 84 107 95 75 91 87 58 83 85 76105.94 61 56 43 83 73 87 112 78 95 80 70 73 68 78 103105.96 84 40 41 88 61 66 94 98 99 93 98 97 88 77 87105.98 64 41 64 81 62 85 114 94 99 100 100 73 85 82 102

106 90 36 68 104 76 89 112 115 85 94 95 86 75 90 93106.02 67 42 63 91 97 85 110 83 107 107 96 87 71 68 89106.04 79 48 44 109 87 97 104 110 97 109 112 80 86 96 104106.06 74 49 72 91 103 97 123 104 116 112 95 84 110 85 94106.08 85 51 59 87 80 89 108 99 131 103 114 80 88 92 129

106.1 112 56 59 93 93 87 102 102 101 135 119 87 108 98 128106.12 101 70 66 102 82 86 126 123 88 118 120 70 103 102 138106.14 94 60 62 104 98 103 104 118 110 157 134 94 121 109 129106.16 97 77 85 107 95 108 101 127 136 147 131 99 117 91 149106.18 87 70 65 102 88 117 127 122 112 156 146 110 145 129 141

106.2 112 70 64 125 97 114 128 120 114 197 120 98 127 127 162106.22 127 95 66 114 94 120 131 128 130 178 128 107 137 129 175106.24 127 84 84 116 113 122 123 116 125 168 136 127 156 169 131106.26 144 97 74 128 110 124 110 114 142 161 152 104 171 175 189106.28 161 87 95 142 121 131 125 133 125 174 143 126 183 161 187

106.3 156 75 77 127 111 132 128 119 125 190 131 149 166 147 185106.32 195 93 79 140 122 132 126 117 122 187 172 124 174 193 159106.34 214 109 89 142 141 142 110 105 146 167 157 116 220 179 173106.36 204 87 112 112 128 113 118 139 153 140 132 117 220 193 156106.38 220 111 106 141 120 111 123 142 148 156 148 94 194 174 175

106.4 223 105 98 145 131 143 138 135 124 144 141 104 179 190 160106.42 235 104 98 152 133 142 104 137 132 154 147 119 182 175 173106.44 211 128 96 154 151 120 124 107 140 136 133 125 181 168 164106.46 225 109 89 149 147 124 118 116 129 148 147 96 209 150 147106.48 241 113 89 129 157 117 132 144 130 161 133 92 183 146 120

106.5 226 100 88 126 132 159 124 111 113 134 123 92 178 154 121106.52 211 83 99 151 132 99 123 130 144 132 119 86 153 147 150106.54 194 96 82 160 134 106 118 108 117 117 133 71 174 167 119

385

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

106.56 183 81 96 130 126 108 110 125 142 131 126 64 166 130 154106.58 167 85 68 142 112 139 136 121 126 127 122 85 147 135 125

106.6 177 94 72 142 122 145 124 131 180 111 139 87 145 143 125106.62 165 71 87 116 124 145 107 142 132 128 104 41 146 138 134106.64 151 78 93 122 134 129 107 143 134 125 108 82 126 145 124106.66 146 72 72 136 115 128 108 125 115 146 116 75 159 118 116106.68 146 71 71 138 98 132 115 101 107 118 114 54 138 130 130

106.7 132 67 65 126 105 114 116 113 132 120 108 42 121 110 114106.72 155 67 66 131 115 120 92 116 132 106 97 61 132 110 121106.74 151 72 78 113 106 122 102 108 143 118 106 52 153 113 106106.76 121 70 79 125 113 126 100 92 105 90 94 58 164 121 113106.78 147 66 79 107 109 100 105 99 117 101 79 76 118 116 102

106.8 150 85 76 114 96 94 104 82 134 109 91 42 139 97 90106.82 159 71 56 123 101 123 102 98 105 104 90 29 117 126 106106.84 139 53 75 97 97 116 103 104 102 98 69 49 121 122 96106.86 154 51 59 89 110 100 86 95 111 80 81 39 107 90 84106.88 128 59 70 117 79 118 93 88 107 72 79 38 95 96 85

106.9 117 61 77 100 93 101 77 93 101 67 76 50 90 98 80106.92 110 49 63 101 91 86 93 106 104 65 77 41 95 84 83106.94 107 65 58 96 76 94 85 90 122 82 77 47 90 83 78106.96 112 50 50 85 85 111 99 103 106 77 62 43 74 73 75106.98 99 53 62 101 73 93 86 88 84 66 86 35 95 88 95

107 93 51 64 84 69 84 91 80 83 66 74 51 86 82 61107.02 86 53 47 107 92 88 77 94 108 64 82 46 77 74 75107.04 85 50 57 102 79 77 81 85 80 67 64 34 63 68 71107.06 79 40 61 65 76 78 79 73 100 57 58 60 74 57 63107.08 66 43 48 77 56 88 91 63 92 58 75 42 64 68 57

107.1 62 45 55 89 62 73 83 62 95 66 54 51 54 64 61107.12 71 39 43 72 68 93 74 94 88 62 65 56 70 66 66107.14 49 47 55 81 66 80 72 85 88 74 55 40 65 46 51107.16 67 43 49 68 59 98 81 75 87 55 56 40 73 72 67107.18 75 44 50 61 57 71 83 75 84 42 62 34 47 56 60

107.2 51 40 44 66 67 70 71 65 69 52 53 50 70 61 61107.22 72 40 55 77 64 65 85 64 68 51 49 39 59 53 56107.24 61 45 51 52 63 74 59 57 78 46 58 58 57 64 49107.26 49 40 37 59 71 66 79 83 70 49 67 55 77 55 51107.28 62 42 57 74 48 76 62 70 78 57 75 45 39 45 61

107.3 60 42 54 64 36 67 76 57 79 37 47 59 65 60 52107.32 51 49 41 73 61 62 73 74 79 53 66 41 41 60 54107.34 50 44 44 58 54 64 65 59 84 63 63 40 59 59 68107.36 65 33 42 63 54 54 69 77 81 51 46 54 56 67 56107.38 56 31 45 58 50 55 61 58 70 49 54 41 62 58 54

386

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

107.4 44 34 37 72 57 67 59 68 71 59 52 29 48 49 52107.42 67 48 46 64 74 60 68 79 73 73 66 50 46 39 55107.44 51 38 35 74 45 67 55 61 78 52 68 44 48 69 59107.46 52 36 43 62 57 76 64 79 81 57 52 48 60 77 62107.48 55 43 34 62 55 59 73 64 69 64 77 46 57 57 60

107.5 63 47 46 70 70 73 64 82 75 65 52 42 55 52 49107.52 69 40 40 73 68 63 75 82 80 74 74 61 55 51 50107.54 55 37 44 68 61 83 83 73 82 75 62 65 59 64 55107.56 56 36 41 83 60 69 58 81 77 70 60 55 73 59 78107.58 54 41 59 79 53 79 61 56 63 64 59 47 73 66 80

107.6 60 50 50 75 47 71 75 59 75 73 66 44 57 63 69107.62 78 46 42 69 66 74 61 68 61 70 89 66 79 76 72107.64 83 44 56 79 57 84 77 63 67 72 80 47 75 67 60107.66 90 46 54 69 56 70 85 65 95 78 82 51 72 74 66107.68 80 58 46 68 60 79 73 73 94 71 75 74 90 86 80

107.7 81 44 52 66 52 71 77 59 63 91 92 65 74 81 75107.72 86 54 54 76 70 82 83 65 83 67 64 50 91 81 77107.74 83 57 54 88 73 64 77 71 73 77 68 66 87 87 81107.76 78 47 41 64 71 64 69 73 69 88 83 50 63 84 80107.78 98 50 49 76 74 63 68 66 65 71 80 49 74 94 70

107.8 94 52 56 94 77 65 89 69 83 65 72 52 78 85 69107.82 75 53 55 77 81 64 50 63 63 74 71 48 73 75 53107.84 96 48 51 82 79 66 68 86 78 56 77 48 78 67 68107.86 89 47 40 69 60 72 66 67 73 63 68 55 75 77 63107.88 73 51 40 64 76 82 65 68 64 54 62 46 54 65 48

107.9 73 36 47 57 75 58 67 81 69 73 67 40 86 64 72107.92 75 44 38 70 72 69 55 72 70 67 56 50 70 65 65107.94 67 50 49 78 54 75 85 88 69 71 50 39 66 62 55107.96 68 48 45 79 78 66 79 60 84 61 61 55 56 75 57107.98 57 34 49 60 65 70 76 73 63 58 62 45 64 55 50

108 70 35 51 75 55 71 75 61 74 80 55 64 77 65 61108.02 63 46 55 61 69 83 67 67 82 62 57 44 73 64 63108.04 64 53 38 78 65 63 70 90 86 57 58 61 69 70 71108.06 76 54 42 62 70 63 72 86 78 68 72 46 60 61 61108.08 69 43 45 63 65 81 76 73 80 55 64 41 65 82 71

108.1 68 46 47 67 55 64 82 75 88 49 52 54 70 83 74108.12 73 40 52 72 64 63 64 74 73 68 78 58 70 66 74108.14 73 38 42 95 61 79 82 56 75 62 64 38 75 61 64108.16 79 40 37 82 69 52 65 65 83 59 54 54 82 73 63108.18 70 46 44 56 70 73 64 64 72 67 60 52 73 64 61

108.2 71 46 54 87 56 70 64 50 82 60 74 51 69 65 50108.22 67 28 36 68 52 58 75 75 74 44 62 65 63 71 63

387

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

108.24 79 42 53 61 58 54 70 68 94 72 68 42 62 76 75108.26 73 47 53 69 61 71 60 77 76 71 65 53 64 70 68108.28 71 38 38 75 72 67 73 71 72 66 72 45 72 61 59

108.3 70 38 44 70 64 79 68 74 81 65 74 60 64 79 60108.32 72 47 54 83 67 71 82 71 80 70 64 55 78 55 68108.34 70 45 42 89 74 77 62 76 76 77 70 49 74 59 70108.36 64 54 37 78 53 60 72 63 81 96 88 57 71 78 72108.38 82 47 52 90 73 73 74 75 97 79 80 50 82 70 76

108.4 65 47 41 71 67 65 79 77 81 98 81 57 92 76 74108.42 69 42 47 88 83 63 66 71 83 93 109 61 89 78 84108.44 73 50 55 79 65 79 77 85 96 77 94 70 113 96 88108.46 71 56 62 86 64 76 67 72 84 94 73 99 111 88 90108.48 90 70 61 76 75 77 74 71 91 85 102 71 108 107 89

108.5 102 60 56 80 86 84 83 74 80 101 112 66 114 91 84108.52 118 68 69 73 86 92 84 92 103 104 94 85 104 128 84108.54 116 69 71 101 85 78 70 69 93 114 99 84 119 104 93108.56 122 67 57 83 96 91 74 76 85 103 93 57 129 109 90108.58 105 61 60 76 92 68 73 76 100 104 94 88 95 107 84

108.6 121 68 48 78 87 67 83 76 93 101 71 74 125 97 94108.62 139 63 71 76 91 76 66 84 83 90 74 44 111 112 83108.64 125 48 67 85 95 82 94 68 77 80 68 65 101 110 78108.66 97 49 47 107 89 84 80 78 70 65 74 59 87 82 67108.68 100 60 64 96 85 79 73 90 93 72 75 61 87 83 98

108.7 95 58 46 91 93 77 76 77 76 68 71 42 81 78 88108.72 96 45 54 89 69 81 84 86 75 75 75 40 80 78 68108.74 95 57 51 97 71 83 70 65 77 57 74 47 60 85 59108.76 91 52 37 76 76 64 79 68 95 65 69 40 86 72 63108.78 78 46 51 73 67 84 79 63 95 61 71 40 85 69 71

108.8 97 45 49 94 79 59 73 71 77 64 69 52 70 75 67108.82 100 53 44 72 61 80 79 88 72 78 75 60 83 66 67108.84 89 41 44 79 74 70 89 77 75 73 71 43 54 75 52108.86 61 39 51 67 64 51 73 64 86 76 81 17 85 65 66108.88 81 48 42 78 67 65 66 74 99 70 55 36 82 79 56

108.9 80 54 45 67 65 84 72 60 74 73 59 42 75 74 72108.92 74 42 48 85 57 61 59 64 77 73 59 19 76 85 69108.94 80 48 46 80 64 71 66 43 70 85 70 19 72 86 67108.96 80 45 41 77 64 76 59 52 87 67 67 31 77 63 58108.98 79 43 49 62 53 79 72 53 73 70 58 27 72 67 49

109 89 49 48 70 66 66 63 50 72 87 73 45 71 48 57109.02 67 46 49 81 56 73 55 59 68 60 71 46 69 75 66109.04 81 33 57 58 56 54 60 70 71 53 50 41 70 64 60109.06 89 44 49 55 57 66 55 68 76 51 47 21 74 53 66

388

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

109.08 73 34 32 63 66 66 67 65 61 53 66 42 55 57 66109.1 61 31 43 65 61 56 49 50 78 46 52 32 63 54 64

109.12 56 45 48 60 57 57 56 51 63 48 48 42 74 61 43109.14 64 30 36 47 59 63 56 63 66 54 42 27 60 54 44109.16 52 38 45 58 47 56 57 63 67 40 50 41 45 48 46109.18 48 33 37 54 58 58 54 56 66 42 44 35 52 64 44

109.2 63 35 41 52 61 53 48 62 55 38 54 50 43 43 47109.22 50 34 38 58 58 46 40 46 65 46 60 22 64 53 44109.24 58 33 36 54 53 50 48 62 52 53 41 26 60 56 37109.26 48 40 47 57 52 54 60 54 57 45 61 47 41 40 53109.28 48 35 39 53 44 51 59 59 59 37 41 44 43 39 35

109.3 47 31 41 52 33 59 64 50 52 46 37 32 35 57 54109.32 60 32 28 53 37 45 52 53 58 33 44 43 46 44 31109.34 50 40 39 57 50 51 51 51 71 48 46 31 36 43 34109.36 59 30 41 58 39 60 53 57 48 36 42 40 48 36 36109.38 56 36 30 57 26 58 39 42 59 42 42 36 41 39 46

109.4 43 41 34 44 39 50 51 46 55 43 46 18 59 36 36109.42 49 26 33 35 45 47 44 45 56 41 48 31 49 41 48109.44 46 32 28 34 43 42 50 42 56 40 34 30 43 38 49109.46 40 34 25 50 43 62 39 48 55 50 38 36 50 36 41109.48 50 35 34 63 45 52 57 42 50 37 44 28 41 50 44

109.5 43 19 39 50 39 45 52 54 60 52 42 27 54 56 50109.52 48 38 27 48 42 33 56 47 49 51 52 19 47 47 41109.54 40 24 26 56 58 49 60 67 52 41 46 34 40 40 48109.56 48 32 39 41 39 41 42 40 41 35 38 25 38 37 42109.58 35 22 29 47 29 50 49 45 59 50 38 31 44 33 39

109.6 42 33 23 43 35 51 59 39 53 38 37 34 50 40 49109.62 46 31 27 41 51 51 43 50 50 39 43 44 38 34 35109.64 42 23 40 33 54 36 50 39 48 38 44 45 56 52 43109.66 44 26 33 49 43 54 51 47 61 49 36 34 48 45 35109.68 40 30 25 44 47 51 38 45 41 46 44 20 47 40 45

109.7 44 34 25 46 47 46 44 51 44 45 48 28 36 53 49109.72 45 31 39 37 51 45 40 39 46 36 40 24 26 35 45109.74 42 37 34 45 40 58 57 45 57 39 46 31 47 43 45109.76 37 28 30 39 50 47 44 50 51 40 40 22 37 58 34109.78 51 35 23 41 50 50 43 49 35 38 47 22 54 48 57

109.8 42 35 38 39 39 39 39 48 48 48 44 25 43 44 44109.82 39 30 28 49 44 44 49 41 62 33 43 35 28 46 46109.84 56 24 34 53 37 45 47 37 65 50 37 41 48 54 40109.86 46 30 25 36 47 51 49 43 39 38 49 27 48 44 39109.88 43 26 31 41 37 37 54 47 61 40 41 36 41 48 36

109.9 38 25 32 49 45 36 51 41 50 52 34 38 44 37 54

389

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

109.92 37 30 27 45 42 36 45 41 55 55 46 36 46 53 39109.94 45 35 31 63 38 43 43 38 46 40 39 30 41 43 36109.96 32 32 35 42 43 57 44 50 45 38 45 28 46 38 36109.98 47 29 29 40 44 46 55 43 50 48 34 38 51 53 37

110 40 33 42 46 40 33 46 53 39 45 44 17 38 47 50110.02 41 34 37 54 41 51 48 53 38 33 54 29 49 35 42110.04 33 26 42 51 33 46 58 35 49 42 43 21 39 32 41110.06 34 33 32 40 39 41 48 54 45 42 59 19 37 50 54110.08 37 34 33 50 45 45 53 51 41 37 49 29 37 52 43

110.1 42 27 32 57 49 36 56 50 60 47 45 28 43 21 49110.12 45 18 32 39 47 53 44 45 52 47 35 38 38 46 43110.14 48 30 35 41 37 44 45 38 50 39 41 35 36 45 40110.16 40 36 30 57 49 37 52 48 48 47 46 33 66 41 55110.18 33 36 38 46 25 36 43 37 57 50 31 33 40 47 39

110.2 41 27 30 46 44 46 52 42 49 49 46 34 51 49 41110.22 42 23 38 48 30 49 47 33 47 42 48 23 45 48 37110.24 64 29 33 49 39 53 47 47 55 34 52 28 50 50 52110.26 44 28 37 52 54 43 40 44 56 41 43 35 43 43 50110.28 34 23 34 47 45 42 52 56 54 56 38 45 41 44 44

110.3 34 30 44 44 46 35 47 33 62 43 44 27 42 50 37110.32 48 33 29 48 45 50 54 33 52 55 45 34 55 39 39110.34 42 32 37 49 40 40 29 53 55 52 43 32 49 41 53110.36 37 25 28 51 39 51 44 54 47 44 49 36 44 42 47110.38 38 32 43 46 47 50 51 52 51 40 51 22 54 64 39

110.4 35 23 33 37 39 39 57 56 56 42 40 36 45 54 54110.42 58 38 37 45 53 47 48 65 42 52 55 43 52 52 30110.44 34 27 50 36 44 47 43 55 45 48 47 34 48 55 48110.46 50 43 33 44 42 46 47 51 65 42 40 43 56 55 57110.48 55 31 43 46 51 54 53 55 44 45 57 48 45 52 47

110.5 58 27 36 52 44 44 55 47 47 57 52 44 49 53 47110.52 61 30 28 41 65 43 39 47 51 71 50 39 48 68 57110.54 63 40 28 58 45 70 50 61 58 61 50 45 56 53 44110.56 44 31 33 42 50 52 40 59 52 53 56 43 58 47 47110.58 62 23 33 52 49 55 56 53 51 59 42 46 56 52 52

110.6 65 28 44 51 35 49 54 42 44 57 61 52 48 60 45110.62 62 51 31 48 40 55 47 50 61 50 54 44 61 60 47110.64 53 33 29 47 43 44 66 46 51 38 46 39 65 48 45110.66 44 36 29 51 62 56 54 47 59 52 46 46 56 58 53110.68 64 32 43 51 54 53 54 62 47 63 60 41 46 66 40

110.7 80 38 26 53 51 57 62 41 41 44 52 48 35 54 40110.72 62 28 37 59 59 57 32 38 62 51 39 40 51 54 45110.74 36 38 31 40 57 51 47 47 58 50 38 30 55 46 47

390

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

110.76 48 37 34 57 59 46 48 46 54 58 48 21 40 49 37110.78 46 27 32 51 47 43 60 56 64 57 50 30 58 45 44

110.8 61 28 30 54 40 55 49 58 60 50 59 29 48 62 43110.82 55 28 43 58 52 44 45 69 69 41 47 29 56 58 53110.84 56 36 35 52 49 53 52 54 54 46 42 17 52 51 43110.86 45 31 35 54 50 55 45 58 55 44 46 37 42 43 37110.88 71 29 37 46 55 51 53 47 48 49 49 22 55 42 49

110.9 46 30 33 51 46 53 33 60 56 44 42 43 56 44 57110.92 65 29 30 64 44 56 56 48 60 44 37 26 42 57 57110.94 45 34 37 52 43 43 39 46 56 37 42 33 55 48 48110.96 51 38 36 68 47 42 45 62 46 55 53 31 43 55 46110.98 42 31 39 54 61 48 50 47 62 36 44 32 47 45 34

111 54 31 37 51 49 52 52 45 49 45 42 34 48 55 48111.02 42 34 31 60 35 52 58 53 60 41 52 51 51 50 50111.04 53 27 35 31 43 58 59 55 50 50 41 32 36 46 40111.06 65 37 33 47 61 38 59 54 52 41 55 22 43 41 43111.08 45 38 34 54 43 53 49 50 40 47 33 26 46 40 47

111.1 57 33 40 45 50 44 49 36 67 49 61 18 39 49 44111.12 49 26 30 57 50 43 62 49 54 41 46 27 63 57 44111.14 50 35 30 64 36 41 57 53 57 37 36 42 52 44 43111.16 51 34 34 51 53 59 43 60 46 47 32 31 36 47 45111.18 61 27 28 43 45 51 59 40 54 49 47 34 52 54 47

111.2 50 26 38 48 48 52 54 47 52 35 39 37 45 52 52111.22 52 29 30 46 36 60 58 48 55 53 45 44 41 46 46111.24 52 25 36 45 38 64 62 51 63 37 33 34 52 46 40111.26 46 31 24 52 35 38 42 38 47 36 45 33 44 32 46111.28 41 30 31 49 51 58 42 57 57 37 66 34 53 46 42

111.3 54 33 28 57 46 43 55 56 57 37 29 40 49 54 47111.32 47 28 38 57 47 52 45 50 61 43 39 18 44 39 44111.34 52 32 42 44 72 52 42 53 57 42 44 32 52 45 48111.36 48 29 41 54 64 46 56 56 60 45 45 49 38 39 38111.38 54 28 37 54 42 43 59 56 66 51 52 42 49 54 52

111.4 50 29 26 46 53 47 60 56 54 37 51 33 40 36 59111.42 42 31 29 51 52 69 51 46 51 41 52 42 48 49 53111.44 65 28 36 50 41 56 66 54 59 42 59 30 51 49 45111.46 53 38 34 60 45 69 61 61 56 45 55 30 47 40 59111.48 47 26 37 49 57 54 64 54 67 48 44 38 46 66 44

111.5 54 32 29 62 57 59 63 50 63 42 48 38 51 42 33111.52 59 36 45 43 61 49 62 52 59 56 75 45 48 50 36111.54 46 36 37 49 46 47 66 62 74 32 43 43 52 59 44111.56 44 39 22 55 42 43 62 57 58 54 51 29 41 55 58111.58 57 28 28 51 54 69 52 53 73 56 61 46 47 48 58

391

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

111.6 51 41 33 55 43 53 75 62 72 59 55 42 59 49 64111.62 46 33 34 59 71 60 53 53 73 56 61 39 58 64 57111.64 49 28 43 60 43 60 74 66 72 54 51 39 65 61 64111.66 45 34 39 72 59 71 72 62 64 73 66 45 49 55 69111.68 50 24 43 75 52 57 68 66 68 58 59 34 57 47 57

111.7 50 28 39 56 57 66 72 78 56 79 64 41 61 53 63111.72 63 36 28 66 66 62 57 76 67 64 50 54 61 63 80111.74 75 32 32 66 59 58 77 67 68 75 59 67 61 58 69111.76 71 49 41 78 77 84 79 76 85 87 82 55 60 63 67111.78 63 36 40 65 61 64 79 79 82 91 52 39 61 73 89

111.8 88 50 45 80 49 73 71 93 79 95 85 44 78 63 72111.82 62 54 41 77 66 61 70 93 86 82 81 45 71 67 80111.84 61 45 33 81 69 63 81 77 86 97 73 51 87 78 71111.86 90 45 38 92 74 92 77 94 90 76 90 68 88 70 87111.88 89 50 37 58 73 79 89 85 92 105 63 66 92 84 94

111.9 80 62 58 84 80 73 74 78 84 106 79 54 82 76 80111.92 91 55 51 66 105 79 97 87 90 96 75 65 104 80 78111.94 108 52 56 91 82 74 75 80 83 97 82 68 105 99 82111.96 91 78 48 96 97 75 86 70 73 102 72 67 105 75 73111.98 124 54 57 78 74 83 81 87 80 75 68 81 89 87 82

112 92 55 44 80 95 89 73 103 79 101 77 59 100 97 77112.02 92 62 61 101 107 74 101 102 87 90 84 65 104 83 75112.04 103 59 47 81 84 71 95 95 107 87 64 57 84 86 81112.06 97 50 53 91 87 94 77 79 105 86 79 67 92 77 68112.08 104 43 56 103 84 84 81 90 75 84 79 44 82 86 78

112.1 86 50 59 76 87 91 87 83 84 73 63 59 82 62 80112.12 105 41 48 89 70 87 83 88 93 74 73 67 98 67 88112.14 103 28 47 88 75 83 72 87 98 75 78 66 79 83 70112.16 90 43 41 88 71 92 75 100 97 62 65 21 72 75 66112.18 86 33 46 89 68 78 96 92 93 83 71 49 77 76 73

112.2 80 53 45 93 75 73 91 90 89 70 83 50 76 79 72112.22 76 41 69 78 65 82 111 78 94 87 75 47 76 67 79112.24 86 54 38 78 82 87 87 96 115 95 75 61 77 64 81112.26 90 44 34 90 69 86 80 94 106 100 84 63 83 75 93112.28 97 57 43 83 73 90 88 81 98 98 90 27 85 76 77

112.3 84 43 52 93 76 85 94 97 101 89 87 61 86 102 94112.32 92 54 42 109 71 86 71 105 98 82 94 44 114 95 83112.34 88 46 42 113 88 85 80 110 104 109 81 65 103 98 83112.36 100 59 45 91 82 82 91 95 111 73 74 69 105 72 89112.38 86 49 49 91 79 79 90 123 88 83 87 73 83 77 97

112.4 106 66 65 110 77 102 97 107 100 91 91 63 97 94 76112.42 102 46 52 105 78 99 101 83 115 98 98 60 90 96 89

392

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

112.44 100 52 54 99 77 103 90 95 116 81 82 66 109 103 87112.46 111 48 56 104 101 96 112 89 110 113 93 64 99 104 94112.48 104 65 42 107 88 101 98 86 120 91 91 71 117 103 82

112.5 100 62 54 99 81 80 102 97 106 113 99 70 109 89 110112.52 104 53 45 116 94 96 97 101 108 112 96 68 97 96 105112.54 101 46 54 111 86 96 96 110 94 96 103 66 122 104 100112.56 112 63 64 116 80 116 85 114 113 103 90 70 124 92 85112.58 124 58 71 106 71 101 104 108 98 113 95 80 115 92 93

112.6 111 48 64 111 93 89 102 114 96 97 90 88 128 112 96112.62 123 68 50 118 87 114 67 105 119 119 92 90 145 94 119112.64 135 67 52 95 107 88 102 128 113 107 110 92 159 107 97112.66 132 67 45 124 75 100 89 138 131 106 106 91 135 123 104112.68 157 61 65 125 107 117 99 101 103 122 104 75 140 106 109

112.7 127 74 57 124 101 109 101 109 103 95 87 97 139 105 98112.72 140 71 54 106 113 96 94 104 100 116 109 87 139 106 123112.74 163 70 60 113 111 92 106 119 101 117 108 114 134 107 115112.76 150 56 62 113 101 104 107 102 118 133 110 83 146 118 116112.78 166 79 68 115 119 116 111 95 120 119 125 90 137 92 105

112.8 166 78 80 152 106 103 112 111 120 116 110 97 168 136 110112.82 158 84 75 130 114 117 99 100 119 135 126 84 154 118 118112.84 140 53 82 116 92 89 112 97 112 147 109 100 165 131 115112.86 144 79 73 134 123 96 102 121 118 127 123 80 168 120 141112.88 145 78 65 146 120 100 101 106 115 146 126 69 173 129 145

112.9 151 72 65 145 115 112 117 108 133 148 116 102 170 128 125112.92 183 79 67 123 116 105 100 106 120 134 118 64 165 134 114112.94 139 81 74 149 141 96 93 112 127 135 112 67 173 134 120112.96 177 71 79 145 107 122 128 137 128 146 118 85 191 123 120112.98 179 75 82 144 108 116 105 107 116 132 118 68 145 144 129

113 199 89 78 133 138 124 93 139 135 122 108 96 165 139 126113.02 186 74 80 117 112 123 95 117 120 143 111 94 173 127 114113.04 208 92 77 133 112 104 102 91 100 126 111 72 184 133 111113.06 156 86 83 119 126 119 101 115 125 107 124 75 160 125 120113.08 223 91 70 128 129 103 92 120 113 116 112 57 163 114 99

113.1 187 78 62 124 123 106 104 112 126 115 107 54 145 137 102113.12 167 84 73 125 105 118 105 120 104 95 90 62 173 114 120113.14 179 78 74 117 96 99 105 120 124 88 104 52 146 117 103113.16 182 85 87 120 125 93 87 102 122 98 99 59 124 105 110113.18 157 74 73 139 103 116 87 102 123 97 89 49 134 95 90

113.2 144 72 60 126 94 110 106 101 122 85 88 64 139 101 85113.22 148 51 67 142 106 99 93 114 123 75 99 42 131 93 81113.24 159 67 63 121 115 114 85 105 121 106 83 49 119 99 102113.26 149 54 62 119 103 110 97 110 118 96 105 47 121 88 90

393

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

113.28 134 51 45 114 110 87 86 111 98 78 69 61 114 101 87113.3 137 56 41 121 85 106 96 110 125 98 75 47 110 105 73

113.32 137 43 67 99 86 104 99 105 105 80 79 28 116 112 75113.34 132 64 63 111 102 95 79 107 109 98 62 53 116 86 70113.36 135 50 55 117 84 109 93 94 121 90 77 58 107 98 84113.38 124 55 57 118 76 91 58 85 95 95 89 66 108 85 70

113.4 116 63 51 94 93 97 73 81 124 85 74 46 95 88 76113.42 114 51 54 86 80 75 93 88 89 63 71 40 108 87 89113.44 104 58 52 101 94 82 62 77 98 83 75 40 102 96 105113.46 117 46 61 94 91 79 85 96 104 75 90 37 87 82 76113.48 133 54 51 86 82 87 65 70 81 70 67 41 100 88 67

113.5 85 52 57 105 90 86 63 76 89 69 83 39 94 93 71113.52 125 65 50 93 69 75 80 87 105 69 61 36 100 76 58113.54 101 42 50 107 80 89 69 83 73 72 50 43 76 70 63113.56 97 41 61 83 77 75 71 69 75 68 57 42 97 78 71113.58 104 29 54 81 76 74 72 81 79 63 63 42 82 66 79

113.6 89 46 47 85 66 71 69 81 94 62 57 34 72 65 73113.62 105 52 34 103 62 58 78 84 88 64 54 33 73 88 61113.64 83 43 31 78 75 68 70 82 90 67 48 36 73 78 62113.66 101 30 50 93 60 67 65 91 98 45 58 29 64 54 50113.68 66 38 34 85 47 71 59 81 71 62 51 36 50 66 76

113.7 84 44 34 61 59 67 62 60 50 68 73 34 68 56 66113.72 75 43 37 77 55 72 63 78 77 57 60 31 75 63 61113.74 62 35 40 72 43 62 66 67 87 61 45 28 84 59 55113.76 54 27 48 68 60 67 64 79 101 54 53 50 70 75 46113.78 64 33 55 62 60 64 72 81 87 55 57 30 63 51 56

113.8 69 32 33 70 56 70 47 73 93 47 46 36 56 61 54113.82 53 31 33 65 63 69 64 66 85 50 52 23 61 50 45113.84 53 28 40 67 71 69 74 75 79 47 59 35 72 55 63113.86 71 35 47 57 59 69 67 70 72 66 48 36 55 64 54113.88 66 37 47 81 46 56 75 73 46 61 51 37 66 43 41

113.9 70 41 38 59 72 64 68 71 84 50 55 47 51 69 51113.92 58 40 24 63 56 59 59 55 62 61 53 30 57 68 54113.94 72 30 37 73 44 65 66 62 65 49 38 27 44 62 56113.96 52 36 30 62 53 54 64 67 69 51 49 51 59 73 60113.98 73 41 30 63 55 51 72 60 61 40 51 33 70 55 49

114 67 25 47 65 57 71 81 52 71 53 36 36 57 57 51114.02 68 36 35 63 71 69 64 63 57 51 48 47 50 52 50114.04 56 27 40 59 57 51 50 70 73 48 50 49 51 63 49114.06 80 26 33 58 55 51 55 62 76 54 46 44 35 59 49114.08 61 32 34 52 57 54 66 61 59 42 50 46 43 56 64

114.1 58 41 54 51 51 55 69 56 63 60 51 37 60 51 51

394

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

114.12 49 30 41 57 54 52 64 44 63 60 37 46 35 62 46114.14 54 25 29 56 50 66 59 56 55 66 38 40 59 44 41114.16 57 37 30 69 50 67 65 58 67 41 60 42 62 52 39114.18 65 40 43 51 42 46 41 62 57 56 41 36 46 46 56

114.2 63 29 36 53 60 55 64 51 63 45 42 40 50 65 63114.22 53 30 48 60 55 57 69 53 73 54 47 40 45 49 46114.24 52 33 28 49 49 56 59 66 63 54 57 49 42 53 51114.26 57 36 40 51 54 58 58 64 63 41 45 39 40 55 48114.28 50 23 41 57 54 48 64 63 71 55 55 41 41 44 56

114.3 52 28 35 60 46 51 40 63 56 45 51 41 66 45 37114.32 71 52 54 58 78 67 57 51 64 56 54 41 52 61 51114.34 65 32 46 51 64 49 72 62 65 56 50 46 42 54 49114.36 64 27 51 45 59 50 61 60 62 52 62 35 62 42 64114.38 58 32 47 58 58 54 64 58 61 49 51 48 66 48 64

114.4 66 22 43 59 56 56 64 63 51 60 39 41 63 55 64114.42 73 34 49 55 54 72 67 52 67 68 52 51 63 55 68114.44 69 39 58 59 49 64 54 58 67 50 48 39 55 62 58114.46 77 42 51 52 59 51 65 56 55 46 60 44 56 42 63114.48 88 38 59 63 60 61 62 65 79 70 41 25 58 46 58

114.5 78 47 54 54 66 61 50 65 62 58 48 54 73 65 57114.52 86 46 40 69 48 70 58 67 59 76 47 33 57 38 67114.54 70 41 57 49 61 51 54 58 65 59 41 39 68 65 52114.56 62 35 57 56 51 54 63 55 55 59 48 47 59 47 56114.58 71 39 44 52 62 54 59 64 56 44 65 35 62 55 59

114.6 62 39 49 64 67 61 72 54 59 67 38 37 56 64 61114.62 64 37 57 56 58 56 74 55 65 63 49 34 49 67 55114.64 70 25 39 49 47 60 59 65 70 38 49 38 63 69 62114.66 49 26 37 46 56 56 62 57 64 71 52 31 69 63 38114.68 54 31 51 57 57 57 55 70 71 53 58 21 50 65 50

114.7 58 34 36 58 45 51 59 49 59 45 53 37 54 64 54114.72 63 36 40 52 44 58 60 60 62 51 59 46 60 56 45114.74 64 45 46 58 50 57 54 57 66 49 46 35 50 62 50114.76 57 28 39 48 43 51 58 45 61 58 38 40 47 41 49114.78 55 32 45 62 45 40 46 47 59 52 42 28 52 39 43

114.8 45 38 45 45 53 47 69 67 67 51 49 44 61 43 48114.82 60 37 34 44 53 40 54 52 53 37 52 40 39 50 30114.84 48 35 43 51 52 52 52 50 48 50 53 33 45 49 36114.86 45 35 52 45 51 55 60 47 60 46 47 29 43 47 44114.88 58 36 43 50 54 46 55 38 57 44 44 34 54 39 65

114.9 50 35 36 58 42 65 59 43 55 50 40 42 47 69 38114.92 53 33 47 59 49 64 56 59 58 53 62 41 42 42 45114.94 53 30 42 56 49 48 59 55 50 51 33 26 46 48 45

395

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

114.96 52 33 46 48 55 55 55 51 61 50 41 34 51 51 45114.98 54 36 40 47 47 40 65 48 61 51 42 30 54 46 52

115 51 27 36 49 53 48 59 53 38 45 34 37 58 51 32115.02 57 38 42 50 55 54 62 43 58 51 50 28 57 50 45115.04 40 26 38 51 46 58 59 51 52 43 35 33 54 43 30115.06 66 28 44 53 44 42 62 48 52 39 49 36 44 71 52115.08 56 34 38 54 51 54 55 56 61 44 52 42 47 45 39

115.1 51 32 38 58 49 44 69 62 56 41 37 42 45 50 43115.12 51 31 40 40 51 47 58 62 66 49 50 26 51 58 51115.14 52 34 40 55 44 47 53 65 42 41 36 32 43 48 36115.16 42 34 41 55 47 59 56 47 45 46 56 38 55 42 28115.18 52 22 39 59 60 43 50 47 59 45 48 28 41 42 38

115.2 49 34 31 38 68 67 55 61 65 38 49 28 43 47 38115.22 61 25 38 52 49 48 59 52 60 49 42 30 50 52 60115.24 55 29 49 58 36 46 55 54 58 36 58 27 39 47 56115.26 55 31 29 49 48 65 63 43 63 53 45 29 49 47 46115.28 50 20 33 56 47 58 63 53 70 44 50 25 50 60 44

115.3 43 38 37 50 54 57 69 61 67 36 47 40 57 43 47115.32 45 37 35 61 47 43 58 63 65 55 50 40 41 37 53115.34 47 36 41 69 52 48 72 62 51 56 50 50 50 51 39115.36 57 25 35 67 66 45 63 60 40 52 37 30 45 52 38115.38 54 37 34 57 47 54 60 56 53 44 45 47 60 46 37

115.4 49 24 29 43 46 43 51 55 55 48 52 36 53 51 47115.42 57 29 31 60 49 60 59 61 56 55 58 38 53 38 60115.44 52 27 39 60 56 55 54 60 58 55 59 38 56 47 47115.46 55 35 26 52 68 65 60 68 57 54 44 41 55 50 52115.48 56 39 38 68 58 70 64 72 74 63 62 52 58 50 38

115.5 58 32 39 60 50 67 74 71 77 55 74 44 49 60 50115.52 64 28 39 59 65 74 74 77 76 61 71 50 65 55 54115.54 50 43 38 67 63 60 86 75 68 63 48 43 51 54 64115.56 50 26 45 79 56 71 69 70 72 63 74 50 43 51 55115.58 55 37 34 91 53 62 80 73 84 69 66 47 66 77 69

115.6 66 46 38 64 63 67 80 73 80 67 76 53 65 64 66115.62 65 30 34 83 72 61 83 65 72 86 75 61 70 57 74115.64 76 44 31 62 53 52 86 77 72 77 97 72 71 59 75115.66 63 34 42 55 73 73 66 78 74 75 86 78 68 69 65115.68 69 45 40 84 70 79 81 96 79 88 76 65 73 75 79

115.7 68 39 54 86 64 79 80 81 105 104 91 67 87 89 83115.72 80 51 40 76 68 83 68 100 84 113 104 82 79 90 96115.74 77 58 57 97 73 87 94 90 79 120 111 91 105 112 104115.76 87 45 58 81 50 90 97 92 96 115 115 79 119 99 84115.78 81 49 57 90 85 68 80 96 85 140 117 85 132 110 97

396

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

115.8 106 62 63 90 101 82 103 77 105 120 113 87 116 127 103115.82 109 73 65 80 86 79 98 79 94 132 106 99 120 112 85115.84 114 74 56 106 93 67 104 98 101 140 98 79 115 140 100115.86 121 73 65 101 91 88 92 84 96 132 100 91 136 101 101115.88 128 67 76 101 108 85 81 94 98 104 116 80 134 129 89

115.9 157 82 82 96 107 87 71 87 94 112 94 80 146 138 114115.92 134 64 61 100 73 82 85 96 105 115 86 80 139 137 101115.94 136 79 76 99 99 79 96 105 95 99 87 60 118 119 96115.96 133 76 57 110 116 82 83 94 87 106 91 63 130 136 108115.98 175 57 63 78 109 83 82 93 102 90 79 68 124 106 101

116 127 73 57 86 91 105 80 98 99 78 81 75 131 117 74116.02 145 48 64 110 75 87 77 89 74 82 78 59 105 116 64116.04 121 47 53 94 96 87 82 85 103 101 65 53 109 95 84116.06 119 61 65 100 91 77 80 87 88 82 63 62 100 92 65116.08 113 43 49 87 82 80 89 77 98 76 81 59 89 93 78

116.1 119 32 40 93 77 62 91 106 100 83 74 56 83 95 65116.12 99 62 64 97 86 92 73 81 87 88 59 49 108 77 67116.14 100 45 56 85 80 87 73 85 91 75 69 57 75 79 83116.16 95 45 59 92 59 80 91 76 85 88 68 44 99 94 70116.18 98 38 53 93 65 88 73 101 102 85 68 45 88 73 64

116.2 101 48 56 71 77 85 85 96 85 85 69 25 84 77 86116.22 87 40 40 90 81 68 60 67 69 72 67 27 82 80 80116.24 73 53 35 76 78 95 79 77 86 94 80 39 82 84 71116.26 84 56 47 86 79 68 80 80 90 92 71 37 91 86 78116.28 104 44 47 108 68 72 71 93 92 87 73 27 94 79 82

116.3 84 48 46 93 62 82 67 86 68 88 60 40 82 82 69116.32 109 52 43 91 71 76 71 76 77 80 75 24 87 85 66116.34 92 43 54 86 60 74 63 70 72 82 61 43 82 93 68116.36 101 56 54 77 77 80 73 73 77 73 56 44 104 91 63116.38 78 51 49 79 62 69 66 85 79 67 55 32 81 79 65

116.4 87 51 46 83 82 63 76 76 87 61 56 44 93 84 56116.42 78 38 59 67 75 60 56 65 79 60 52 33 73 92 54116.44 94 40 56 77 60 74 71 72 76 63 61 32 83 84 50116.46 77 42 29 85 61 63 66 80 68 68 67 24 73 78 51116.48 83 34 41 67 75 66 57 67 78 69 49 22 77 66 64

116.5 77 43 40 64 68 61 64 81 71 56 49 42 63 58 58116.52 78 40 36 70 59 73 70 67 64 54 45 25 49 67 63116.54 65 35 34 68 55 71 69 95 61 59 52 28 66 53 51116.56 66 35 39 64 54 58 49 47 69 48 52 36 49 68 44116.58 68 54 47 76 52 51 64 60 67 46 54 21 64 54 51

116.6 55 26 40 72 40 57 49 66 64 50 43 35 56 68 45116.62 70 28 39 61 47 51 52 62 51 45 50 17 42 65 44

397

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

116.64 54 29 31 54 47 55 57 50 77 43 44 38 53 55 42116.66 71 24 43 65 49 52 67 53 77 51 50 46 49 63 58116.68 66 34 29 62 66 61 46 64 60 38 49 45 39 55 52

116.7 64 28 40 57 48 56 36 63 65 61 40 39 47 46 51116.72 59 38 41 59 53 67 49 60 71 42 53 33 39 53 48116.74 47 40 35 66 41 44 62 64 52 36 56 36 61 48 53116.76 50 26 34 61 35 54 61 58 57 39 45 24 43 43 52116.78 63 33 28 48 64 51 46 52 56 54 43 35 55 45 54

116.8 59 39 41 42 54 59 56 52 75 29 42 33 38 41 41116.82 44 35 36 40 51 45 52 52 52 61 37 22 38 48 46116.84 53 42 38 44 61 62 65 54 53 51 48 34 41 43 33116.86 52 35 31 53 38 50 43 54 70 56 43 23 53 56 50116.88 43 22 51 60 50 45 48 58 54 36 53 45 43 52 36

116.9 39 32 46 56 42 46 58 66 54 44 39 33 52 69 49116.92 47 27 29 53 46 46 55 41 64 42 49 39 37 49 36116.94 47 28 38 52 41 51 52 55 65 41 38 44 40 49 42116.96 47 27 35 45 43 65 50 57 54 49 31 31 35 55 36116.98 56 30 38 48 44 67 52 72 55 41 46 31 50 55 37

117 50 24 45 55 34 37 43 48 51 40 43 41 54 49 43117.02 53 27 34 38 32 61 42 57 47 53 52 51 52 42 38117.04 36 31 37 43 48 43 46 43 71 49 36 42 44 41 36117.06 46 25 32 35 39 41 62 36 51 60 55 33 50 53 39117.08 53 26 28 48 53 36 56 43 58 40 45 41 43 44 48

117.1 37 27 47 41 49 67 45 52 47 41 51 38 58 57 38117.12 52 32 36 45 28 34 58 47 60 49 43 24 41 42 54117.14 57 24 25 57 44 35 54 48 61 56 51 31 48 48 52117.16 58 26 44 47 38 56 42 55 63 48 46 35 64 51 53117.18 54 29 42 53 50 46 40 40 60 63 42 41 47 59 50

117.2 56 37 44 46 37 56 52 50 58 45 41 38 54 53 39117.22 61 28 39 48 53 36 49 51 50 49 56 34 68 61 48117.24 62 42 47 58 55 49 38 64 51 46 50 37 50 64 55117.26 52 34 38 41 44 43 40 57 59 46 56 43 61 58 45117.28 69 40 47 40 44 38 49 41 71 35 48 24 54 49 45

117.3 51 32 40 64 49 51 46 40 56 45 54 26 61 50 40117.32 77 16 48 45 42 32 55 50 45 42 36 28 56 65 52117.34 59 25 39 38 50 49 43 50 44 38 45 31 52 56 49117.36 35 32 44 41 47 51 48 49 52 55 45 36 44 55 44117.38 67 32 32 45 61 53 35 47 59 55 43 41 55 52 36

117.4 54 40 36 66 45 46 49 52 45 43 40 25 42 41 46117.42 55 37 37 55 44 48 49 49 49 50 39 28 52 45 37117.44 44 33 33 56 58 34 51 56 39 43 34 46 38 47 38117.46 60 33 31 60 38 41 50 38 62 52 46 25 41 54 43

398

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

117.48 71 28 36 51 44 40 48 56 51 44 57 23 45 45 43117.5 54 27 34 56 57 47 54 51 44 40 54 18 40 46 38

117.52 47 29 42 50 43 50 47 56 43 46 36 23 54 50 49117.54 51 24 46 59 29 44 50 52 51 51 47 32 44 49 38117.56 43 32 42 47 47 36 38 40 52 42 38 22 31 50 39117.58 56 29 48 48 49 30 46 51 55 59 39 33 37 45 45

117.6 56 21 38 48 38 50 45 45 45 46 33 38 51 50 47117.62 50 23 40 48 40 45 54 45 42 51 49 32 46 54 42117.64 42 19 28 46 47 39 47 44 48 48 44 32 46 59 45117.66 45 46 39 53 40 43 46 39 47 59 48 39 60 51 37117.68 45 33 43 47 46 45 58 52 60 52 46 24 40 45 42

117.7 42 33 28 47 48 57 44 53 54 32 43 26 39 49 39117.72 53 29 31 38 43 46 45 52 55 38 45 22 54 42 36117.74 40 28 33 42 39 41 42 42 41 51 47 35 34 57 46117.76 48 30 38 46 35 43 49 39 60 41 34 33 43 47 38117.78 49 27 41 50 40 44 33 52 45 34 39 45 39 43 45

117.8 57 27 45 54 41 43 37 38 48 43 34 43 36 48 45117.82 47 26 40 45 42 58 33 51 44 37 40 19 43 55 34117.84 55 25 31 50 48 36 43 50 56 45 39 25 38 47 38117.86 61 29 23 41 42 30 38 47 43 35 30 17 42 44 36117.88 51 23 34 44 40 44 41 35 53 49 39 29 62 44 34

117.9 52 31 39 37 37 35 46 46 51 34 35 42 47 36 37117.92 55 27 33 53 45 40 55 48 51 52 45 20 57 48 37117.94 49 24 33 42 46 53 39 36 49 61 52 36 47 49 40117.96 47 21 37 48 45 47 36 51 46 38 36 29 38 39 37117.98 42 30 33 60 52 27 54 36 45 40 39 28 51 42 47

118 35 30 32 41 33 58 41 54 43 39 33 23 58 37 34118.02 31 24 35 48 53 46 42 45 42 39 49 28 47 39 42118.04 55 32 41 49 41 48 48 53 45 50 47 26 32 37 41118.06 43 30 39 50 47 41 39 56 49 46 46 36 47 38 57118.08 32 30 33 44 55 44 48 55 46 48 43 28 50 52 41

118.1 48 31 34 25 48 35 51 44 51 44 53 25 59 58 43118.12 38 28 36 34 39 39 51 56 53 30 37 25 36 42 45118.14 43 33 31 50 42 25 50 47 52 37 47 24 38 42 43118.16 42 31 32 39 45 47 41 53 43 51 30 28 50 32 53118.18 54 20 43 61 48 40 58 36 40 43 42 40 44 42 53

118.2 40 31 50 41 48 38 56 52 45 30 42 32 50 47 44118.22 47 24 41 48 40 29 48 50 41 43 38 31 44 43 39118.24 39 22 45 41 37 45 61 39 61 45 46 42 48 43 43118.26 41 32 45 49 48 42 50 55 54 53 48 30 38 43 40118.28 45 31 50 33 47 41 66 47 61 55 37 24 41 52 59

118.3 40 28 41 42 46 63 73 41 52 40 50 41 42 47 60

399

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

118.32 44 35 52 46 49 47 62 44 43 51 38 25 46 58 47118.34 42 32 39 47 49 63 65 44 58 39 47 34 47 46 43118.36 47 33 47 47 47 38 52 52 48 42 58 20 45 38 33118.38 39 28 40 52 47 50 66 49 62 46 47 32 55 38 46

118.4 49 30 30 46 51 44 54 57 48 50 46 36 43 48 41118.42 57 33 49 48 48 52 67 41 49 59 51 29 38 48 52118.44 41 39 44 49 46 45 50 56 60 40 59 30 50 47 47118.46 42 24 36 37 41 45 58 45 47 43 42 40 55 51 43118.48 46 32 41 34 49 57 58 53 51 64 42 35 47 55 51

118.5 42 33 42 64 48 34 47 61 65 54 47 49 44 50 45118.52 48 29 46 50 53 51 62 43 65 52 59 33 46 59 48118.54 54 39 35 45 51 50 66 55 54 49 66 34 59 48 50118.56 39 24 38 46 55 52 81 55 57 53 51 48 54 56 47118.58 61 26 35 54 47 54 56 46 55 47 48 42 52 44 52

118.6 47 35 38 44 54 51 69 72 58 62 48 41 48 67 47118.62 48 37 51 50 55 52 61 50 66 52 47 51 59 42 50118.64 58 38 43 62 42 40 53 63 61 51 66 45 52 45 53118.66 47 32 40 66 53 62 60 52 54 58 38 39 57 51 60118.68 48 31 40 63 60 55 61 54 53 54 60 38 52 50 48

118.7 55 21 35 64 61 52 48 64 66 72 60 47 54 58 58118.72 60 32 51 71 51 54 54 53 53 60 59 51 53 53 65118.74 59 31 48 64 43 40 71 63 61 57 56 48 47 48 62118.76 60 31 48 45 61 50 66 56 69 62 67 38 73 60 49118.78 41 34 49 68 49 50 55 55 65 58 53 45 47 55 59

118.8 65 30 34 64 69 52 62 60 58 55 56 44 52 62 58118.82 59 32 53 64 42 67 66 46 51 60 52 38 48 58 49118.84 52 35 41 70 62 66 53 49 58 72 80 48 56 66 63118.86 54 34 40 56 57 62 57 61 64 76 54 49 52 64 47118.88 68 36 38 66 47 57 69 48 66 68 75 57 64 65 61

118.9 53 39 50 55 63 47 59 59 69 78 68 79 66 68 67118.92 44 29 53 74 66 59 66 66 64 83 73 68 69 65 49118.94 67 57 39 56 52 49 53 54 71 69 84 60 79 69 70118.96 57 36 43 51 56 69 63 67 71 87 56 46 65 75 64118.98 60 43 47 75 70 78 55 72 80 68 61 53 97 80 73

119 71 49 45 60 46 58 52 74 75 98 75 59 83 73 62119.02 79 31 45 69 60 61 70 62 62 77 56 60 86 68 77119.04 66 43 52 63 61 67 69 70 91 77 86 55 103 78 75119.06 91 39 52 72 69 60 53 82 69 95 76 62 83 84 67119.08 75 57 57 62 65 57 52 57 69 77 70 49 95 89 77

119.1 83 38 54 70 61 80 65 76 73 81 72 52 103 90 86119.12 81 54 44 68 67 68 56 66 68 72 72 59 81 81 71119.14 82 47 59 72 64 71 73 63 67 76 71 56 81 85 79

400

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

119.16 91 42 58 63 55 53 61 69 79 85 72 67 80 103 69119.18 101 56 45 75 58 49 58 65 78 75 68 69 103 79 74

119.2 110 43 52 72 70 55 60 60 85 76 56 56 87 73 68119.22 105 52 57 69 72 67 60 62 79 75 66 47 84 80 70119.24 97 44 55 71 71 69 66 72 69 66 68 49 88 87 55119.26 98 48 54 78 63 53 72 58 86 68 65 54 92 81 70119.28 100 56 58 71 76 62 60 80 74 77 57 54 94 72 65

119.3 113 50 46 54 65 63 61 44 84 73 63 55 81 91 76119.32 85 46 48 80 67 59 66 80 65 69 64 48 98 70 54119.34 81 43 53 69 62 65 63 80 68 61 74 47 69 63 53119.36 99 39 37 74 75 72 65 71 61 68 70 36 62 74 61119.38 70 32 46 68 60 63 58 59 65 77 46 37 79 88 63

119.4 87 38 41 68 67 56 64 67 67 74 45 35 76 63 67119.42 71 32 45 63 69 51 67 60 64 62 54 17 59 82 50119.44 73 32 49 71 62 64 46 61 88 84 65 44 69 58 49119.46 63 40 37 64 61 42 56 65 77 92 57 38 60 71 66119.48 79 37 44 76 60 55 78 55 53 58 63 47 69 79 61

119.5 76 40 41 70 58 62 60 57 81 55 57 26 82 55 63119.52 68 30 54 60 60 63 65 63 64 67 50 20 67 62 67119.54 67 23 52 64 56 57 63 62 65 67 54 45 65 56 53119.56 60 35 56 70 43 46 59 68 55 69 50 26 70 55 51119.58 65 29 49 58 62 57 58 67 55 52 58 34 64 55 48

119.6 71 31 39 47 57 50 46 64 68 45 52 28 66 69 48119.62 62 31 50 57 62 63 63 65 70 51 50 37 69 67 52119.64 80 43 41 66 44 60 44 62 74 48 52 34 57 70 55119.66 81 38 48 68 60 70 50 61 75 43 64 29 55 70119.68 75 39 48 85 49 57 47 70 57 59 51 33 58 57

119.7 89 31 44 68 40 47 58 58 53 62 56 34 59 63119.72 74 47 50 51 55 63 50 68 56 62 50 38 68 54119.74 65 31 44 61 54 56 46 49 61 73 50 27 64 56119.76 69 36 37 63 56 64 54 62 50 62 52 29 57 67119.78 67 40 42 61 52 59 54 56 72 56 56 27 64 61

119.8 76 29 33 39 42 64 41 63 61 47 43 32 47 47119.82 74 37 55 60 46 46 46 52 70 56 45 21 64 54119.84 57 34 48 46 71 54 41 56 67 57 59 27 50 60119.86 55 29 51 53 41 49 45 56 59 53 45 29 39 52119.88 58 24 47 56 47 57 35 59 55 54 42 36 52 50

119.9 57 24 36 53 45 57 52 45 70 42 56 37 59 47119.92 64 35 35 50 35 60 52 58 58 44 34 44 52 47119.94 53 28 44 59 44 62 51 58 49 43 45 37 28 63119.96 39 39 31 69 46 53 52 61 58 44 39 39 35 44119.98 52 34 32 37 47 51 48 47 60 39 42 30 41 46

401

Degrees 2 Theta

DOL- STD Queen Yates

Pg B1

Pt UU

Pwv O1

Ph C1

Pwls 22-1

Mlb 22-1

SH 202

SM 307

BM 454

UP 7718

CB 751

CB 770

120 52 40 35 59 44 58 47 47 50 38 41 36 59 36

402

APPENDIX C Single peak FWHM values for calcite-rich Sierra Madera and Mission Canyon Formation

samples.

Single Peak FWHM values for calcite standard and calcite-rich Sierra Madera samplesCALSTD Kwf AA Kwf CC Kwf CR2-Theta FWHM 2-Theta FWHM 2-Theta FWHM 2-Theta FWHM

23.057 0.152 20.871 0.133 23.088 0.15 23.087 0.14626.699 0.06 23.076 0.15 24.88 1.124 26.665 0.0929.419 0.106 26.645 0.125 26.672 0.121 29.433 0.16130.959 0.106 29.416 0.154 29.428 0.148 31.476 0.19331.442 0.136 31.453 0.174 31.465 0.143 36.005 0.15335.977 0.101 35.987 0.144 35.995 0.142 39.446 0.14839.416 0.105 36.557 0.069 39.437 0.148 43.204 0.13943.156 0.104 39.426 0.14 43.196 0.138 47.168 0.16447.122 0.089 42.432 0.094 47.144 0.182 47.55 0.17647.509 0.107 43.183 0.132 47.523 0.165 48.549 0.16848.515 0.108 47.163 0.157 48.534 0.161 56.62 0.162

56.57 0.092 47.525 0.158 56.61 0.166 57.452 0.17857.4 0.116 48.524 0.159 57.443 0.157 58.118 0.156

58.086 0.153 50.109 0.135 58.133 0.184 60.683 0.20860.626 0.261 54.863 0.126 60.684 0.17 61.452 0.36661.388 0.099 56.588 0.148 61.451 0.66 63.098 0.186

63.05 0.108 57.419 0.157 63.096 0.165 64.713 0.17564.66 0.095 58.123 0.147 64.702 0.163 65.675 0.216

65.607 0.156 59.946 0.129 65.644 0.206 69.246 0.19369.176 0.103 60.662 0.217 69.211 0.188 70.308 0.22770.251 0.1 61.435 0.285 70.294 0.199 72.936 0.23572.886 0.135 63.089 0.175 72.923 0.218 73.692 0.20573.671 0.123 64.684 0.172 73.747 0.194 76.363 0.26276.269 0.106 65.633 0.186 76.321 0.18 77.208 0.28877.176 0.112 69.239 0.179 77.207 0.229 81.639 0.29781.528 0.116 70.251 0.217 81.58 0.269 83.838 0.24183.767 0.138 72.924 0.208 83.823 0.212 84.876 0.24284.822 0.125 73.722 0.183 84.862 0.19 94.803 0.52886.452 0.08 76.328 0.203 93.106 0.269 96.24 0.38693.069 0.085 77.207 0.229 95.023 0.483 99.237 0.33795.023 0.176 81.588 0.265 96.265 0.362 106.137 0.4996.148 0.157 83.814 0.208 99.205 0.3 109.586 0.49199.157 0.165 84.832 0.229 102.897 0.662

102.928 0.142 95.025 0.461 106.075 0.53104.156 0.175 96.236 0.264 109.536 0.339

105.81 0.111 99.224 0.308106.13 0.149 106.029 0.563

109.546 0.119 109.542 0.348110.478 0.166117.927 0.106119.275 0.199

404

Single Peak FWHM values for calcite-rich Sierra Madera samplesKwf NN Kwf ZZ2-Theta FWHM 2-Theta FWHM

20.902 0.234 20.881 0.11923.106 0.17 23.085 0.15924.945 0.158 26.657 0.144

26.67 0.161 29.439 0.18129.456 0.18 31.479 0.18631.532 0.156 36.008 0.15736.021 0.157 36.566 0.08439.471 0.163 39.45 0.15843.229 0.16 42.472 0.08547.189 0.215 43.205 0.15347.572 0.194 47.177 0.17748.574 0.186 47.568 0.19850.122 0.151 48.558 0.18656.635 0.178 50.126 0.157.477 0.19 56.612 0.193

58.17 0.241 57.457 0.18860.716 0.25 58.161 0.20961.498 0.465 59.961 0.13263.183 0.259 60.712 0.20964.744 0.189 61.466 0.66465.678 0.259 63.118 0.25367.689 0.195 64.732 0.19469.282 0.236 65.682 0.28970.337 0.248 68.313 0.18372.951 0.318 69.296 0.23476.398 0.243 70.304 0.32477.286 0.326 72.938 0.31581.644 0.41 76.358 0.2683.869 0.277 77.248 0.44684.961 0.305 81.604 0.39594.796 0.513 83.843 0.273

99.3 0.495 84.885 0.314106.062 0.595 94.844 0.502

99.304 0.467109.588 0.704

405

Single Peak FWHM values for calcite-rich Mission Canyon Formation samplesCB 725 BM 579 SH 2342-Theta FWHM 2-Theta FWHM 2-Theta FWHM 2-Theta FWHM

23.085 0.158 84.875 0.229 23.086 0.149 23.085 0.15925.422 0.142 88.448 0.387 29.433 0.16 28.279 0.20529.417 0.149 93.13 0.235 31.468 0.156 29.435 0.17130.933 0.181 94.954 0.543 36 0.15 31.463 0.1831.403 0.166 96.267 0.331 39.44 0.152 35.996 0.15935.289 0.113 99.185 0.253 43.196 0.139 39.439 0.15535.981 0.138 106.263 0.497 47.16 0.161 43.196 0.14937.391 0.165 109.551 0.292 47.544 0.17 46.977 0.35838.659 0.14 48.538 0.163 47.545 0.158

39.43 0.129 56.605 0.16 48.539 0.16740.844 0.134 57.435 0.167 55.793 0.12741.141 0.365 58.141 0.178 56.616 0.162

43.18 0.129 60.666 0.218 57.447 0.17744.943 0.13 61.449 0.295 58.218 0.272

45.5 0.127 63.105 0.187 60.697 0.18947.133 0.701 64.706 0.172 61.457 0.29847.533 0.134 65.653 0.2 63.095 0.2148.532 0.169 69.23 0.161 64.717 0.17349.202 0.207 70.296 0.194 65.66 0.19750.552 0.199 72.924 0.223 69.259 0.14151.093 0.185 73.717 0.191 70.29 0.20652.259 0.182 76.318 0.192 72.934 0.198

55.74 0.169 77.223 0.232 76.373 0.21156.594 0.148 81.592 0.238 77.209 0.24457.419 0.149 83.815 0.228 81.627 0.35158.114 0.144 84.837 0.199 83.84 0.24658.996 0.154 93.123 0.252 84.913 0.244

60.66 0.205 95.029 0.47 87.391 0.14961.441 0.321 96.231 0.299 95.04 0.462

63.06 0.224 99.211 0.275 99.275 0.30164.691 0.155 102.89 0.581 106.225 0.65765.625 0.201 106.17 0.523 109.613 0.34167.436 0.195 109.555 0.26269.225 0.16870.261 0.24372.901 0.19573.658 0.396

76.32 0.18377.214 0.20881.566 0.22783.814 0.207

406

106.198 0.434

Single Peak FWHM values for calcite-rich Mission Canyon Formation samplesSM 4212-Theta FWHM 2-Theta FWHM

20.821 0.247 109.564 0.28923.098 0.136 119.385 0.32626.656 0.09129.454 0.14331.494 0.12936.019 0.10739.462 0.11342.445 0.098

43.21 0.1245.81 0.085

47.167 0.13147.567 0.14848.552 0.14650.156 0.0756.619 0.13557.456 0.12758.132 0.13459.996 0.10860.691 0.18861.454 0.25663.096 0.13564.701 0.14765.664 0.10768.163 0.09569.251 0.14670.285 0.1872.946 0.18873.747 0.16176.333 0.17577.182 0.191

79.91 0.07781.584 0.25883.831 0.18284.877 0.2193.092 0.26594.981 0.48296.233 0.2299.245 0.254

102.995 0.27104.203 0.322

407

APPENDIX D Single peak FWHM values for dolomite-rich Sierra Madera and Mission Canyon

Formation samples.

Single Peak FWHM values for dolomite standard and dolomite-rich unshocked core samplesDOLOSTD Queen Dolomite Yates Dolomite2-Theta FWHM 2-Theta FWHM 2-Theta FWHM

22.047 0.117 20.86 0.199 19.372 0.59124.075 0.136 22.005 0.142 19.693 0.52626.628 0.067 24.04 0.131 20.834 0.11429.418 0.258 26.577 0.107 22.015 0.09130.958 0.133 30.923 0.159 23.565 0.21833.556 0.137 33.529 0.175 24.038 0.17335.328 0.131 35.322 0.157 25.399 0.48337.377 0.124 37.343 0.128 26.618 0.16341.148 0.126 41.112 0.134 27.919 0.32843.82 0.126 43.768 0.142 30.946 0.156

44.941 0.12 44.904 0.137 32.988 0.11749.298 0.142 49.271 0.204 33.548 0.1750.562 0.151 50.522 0.168 34.921 0.85851.088 0.169 51.062 0.172 35.301 0.21858.926 0.146 58.904 0.169 36.515 0.24359.851 0.158 59.803 0.169 37.011 0.09862.07 0.187 63.426 0.163 37.357 0.141

63.472 0.15 64.506 0.165 39.459 0.07964.546 0.158 65.17 0.194 41.135 0.14965.197 0.174 66.082 0.213 43.793 0.17166.11 0.193 67.369 0.172 44.917 0.14467.43 0.158 70.517 0.211 49.295 0.2170.54 0.195 72.874 0.22 50.12 0.132

72.912 0.173 74.731 0.242 50.55 0.1974.737 0.228 76.992 0.288 51.086 0.16777.007 0.226 79.647 0.224 56.217 0.09979.698 0.158 82.657 0.283 58.908 0.20282.686 0.223 86.709 0.296 59.807 0.18484.789 0.244 87.899 0.246 61.668 0.75186.703 0.242 89.352 0.247 63.442 0.17187.92 0.229 99.703 0.247 65.204 0.186

89.359 0.282 100.67 0.387 66.088 0.18499.771 0.247 106.495 0.365 67.404 0.172

100.738 0.365 70.521 0.171104.653 0.531 72.933 0.256106.446 0.299 74.775 0.322108.725 0.285 77.027 0.243113.013 0.886 82.687 0.256115.985 0.306 87.926 0.262

100.721 0.381

409

Single Peak FWHM values for dolomite-rich Sierra Madera samplesMlb 22-1 Pg B1 Ph C12-Theta FWHM 2-Theta FWHM 2-Theta FWHM

22.058 0.148 22.086 0.15 20.891 0.15623.166 0.218 24.097 0.219 22.043 0.16624.077 0.241 26.672 0.157 24.043 0.22526.66 0.143 29.503 0.24 26.669 0.141

29.538 0.296 30.978 0.223 29.511 0.26930.964 0.243 33.559 0.232 30.909 0.24733.539 0.264 35.325 0.225 33.479 0.34735.327 0.263 37.396 0.195 35.242 0.28136.058 0.38 41.161 0.221 23.156 0.1937.369 0.215 43.839 0.225 37.353 0.19639.604 0.372 44.958 0.201 39.479 0.15341.142 0.239 49.325 0.268 41.101 0.23643.38 0.173 50.578 0.323 42.469 0.148

43.862 0.342 51.085 0.324 43.301 0.2244.945 0.211 58.934 0.261 43.755 0.23347.833 0.968 59.849 0.303 44.9 0.22448.743 0.529 63.469 0.285 47.749 0.44949.269 0.331 64.532 0.239 49.296 0.39550.567 0.387 65.222 0.338 50.513 0.41651.058 0.391 66.114 0.346 51.015 0.44858.89 0.297 67.435 0.293 58.84 0.235

59.826 0.346 70.537 0.411 59.797 0.36963.471 0.347 72.895 0.364 63.394 0.33265.224 1.13 74.73 0.419 64.552 1.19366.098 0.459 77.005 0.538 65.17 0.30767.416 0.358 79.614 0.33 66.015 0.41670.533 0.507 82.659 0.51 67.334 0.3472.841 0.427 86.666 0.441 70.442 0.62974.671 0.623 87.96 0.431 72.74 0.44576.995 0.702 89.367 0.432 74.659 0.41779.558 0.54 99.755 0.444 76.951 0.63682.608 1.151 100.707 0.617 79.511 0.55786.639 0.55 106.577 0.646 87.875 0.50187.887 0.559 99.635 0.53189.222 0.551 100.482 0.67999.694 0.608100.57 0.792

410

Single Peak FWHM values for dolomite-rich Sierra Madera samplesPt UU Pwls 22-1 Pwv O12-Theta FWHM 2-Theta FWHM 2-Theta FWHM

20.869 0.172 21.946 0.186 20.87 0.18922.072 0.165 23.961 0.238 22.062 0.15524.078 0.191 29.291 0.325 23.235 0.22126.674 0.148 30.852 0.256 24.075 0.20229.455 0.229 33.432 0.278 26.662 0.11430.966 0.23 35.169 0.295 29.568 0.30833.584 0.289 37.263 0.231 30.965 0.22135.337 0.222 39.343 0.27 33.55 0.21437.383 0.172 41.03 0.275 35.319 0.23839.503 0.128 43.11 0.17 36.159 0.36141.151 0.222 43.715 0.288 36.568 0.09143.252 0.116 44.829 0.233 37.378 0.20743.823 0.185 47.501 0.595 39.597 0.32144.944 0.209 48.436 0.185 41.148 0.2349.352 0.227 49.175 0.365 43.855 0.24850.575 0.279 50.464 0.398 44.944 0.20551.101 0.274 50.96 0.398 47.869 0.72258.936 0.234 58.782 0.315 48.821 0.43859.851 0.251 59.718 0.374 49.275 0.32363.469 0.254 63.372 0.363 50.555 0.32

64.6 0.24 64.422 0.275 51.083 0.3665.23 0.281 65.142 0.801 58.891 0.251

66.126 0.298 66.085 0.69 59.846 0.33367.414 0.258 67.32 0.395 63.471 0.32270.628 0.25 70.452 0.562 64.494 0.23872.913 0.217 72.772 0.481 65.265 0.6774.766 0.303 74.64 0.577 66.092 0.36477.011 0.36 76.933 0.699 67.39 0.31379.723 0.263 79.547 0.516 70.54 0.53482.711 0.319 82.542 0.575 72.887 0.45987.947 0.318 86.551 0.582 74.741 0.5599.698 0.36 87.799 0.592 76.983 0.608

100.708 0.515 89.201 0.551 79.714 0.371106.61 0.87 99.735 0.639 82.711 0.701

113.066 1.129 100.511 0.734 86.593 0.559116.038 0.383 87.902 0.553

89.294 0.51899.662 0.505

100.636 0.632

411

115.9 0.345

112.893 1.138

Single Peak FWHM values for dolomite-rich Mission Canyon Formation samplesCB 751 CB 770 BM 4542-Theta FWHM 2-Theta FWHM 2-Theta FWHM

22.07 0.233 19.024 0.149 22.029 0.15324.082 0.156 20.867 0.116 24.049 0.14225.472 0.171 22.008 0.09 26.634 0.093

26.67 0.142 24.041 0.136 29.422 0.19430.949 0.165 25.396 0.13 30.914 0.17433.546 0.199 26.647 0.116 33.493 0.19235.318 0.175 29.478 0.165 35.269 0.16937.379 0.14 30.905 0.148 37.341 0.14138.631 0.156 32.132 0.134 39.416 0.08641.144 0.151 33.485 0.147 41.104 0.16243.827 0.146 35.27 0.157 43.102 0.08944.943 0.151 37.341 0.123 43.776 0.15248.744 0.175 39.481 0.138 44.906 0.15149.293 0.175 41.1 0.132 47.483 0.20250.531 0.206 42.46 0.089 49.265 0.17351.069 0.208 43.783 0.14 50.494 0.22558.916 0.172 44.9 0.126 51.049 0.20559.837 0.188 48.642 0.235 58.877 0.17463.45 0.178 49.26 0.15 59.801 0.177

64.498 0.206 50.488 0.199 63.415 0.17565.167 0.23 51.029 0.182 64.489 0.23766.11 0.224 58.88 0.15 65.155 0.28367.41 0.18 59.79 0.177 66.071 0.215

70.505 0.273 63.409 0.175 67.365 0.19172.866 0.202 64.465 0.209 70.453 0.34174.735 0.262 65.108 0.243 72.855 0.21476.976 0.218 66.057 0.217 74.641 0.26779.674 0.202 67.354 0.165 76.929 0.32382.679 0.343 70.44 0.28 79.598 0.25986.637 0.351 72.829 0.208 82.587 0.33587.894 0.279 74.662 0.303 86.608 0.40289.321 0.263 76.938 0.258 87.862 0.28399.688 0.287 79.604 0.182 89.289 0.329

100.644 0.394 82.572 0.297 99.651 0.365106.535 0.603 86.537 0.286 100.609 0.397108.621 0.329 87.844 0.262 106.419 0.433112.957 0.974 89.246 0.257

99.651 0.287100.599 0.415106.385 0.417

412

112.849 1.137

Single Peak FWHM values for dolomite-rich Mission Canyon Formation samplesSH 202 SM 307 UP 77182-Theta FWHM 2-Theta FWHM 2-Theta FWHM

22.036 0.169 22.025 0.136 22.065 0.1323.097 0.202 23.071 0.109 24.091 0.14124.047 0.118 24.038 0.162 30.965 0.16626.636 0.107 26.646 0.181 33.554 0.18229.417 0.137 29.424 0.074 35.335 0.16130.908 0.152 30.888 0.21 37.384 0.14333.485 0.14 33.474 0.245 41.156 0.15

35.27 0.145 35.245 0.211 43.828 0.1536.006 0.141 37.34 0.145 44.951 0.13537.353 0.126 41.09 0.195 49.308 0.15839.464 0.111 43.784 0.162 50.545 0.19241.107 0.133 44.897 0.175 51.085 0.18743.182 0.083 48.568 0.116 58.921 0.16243.771 0.134 49.252 0.212 59.839 0.16644.906 0.133 50.512 0.329 62.049 0.24847.577 0.592 51.038 0.258 63.455 0.17248.531 0.155 58.875 0.196 64.528 0.21949.248 0.16 59.794 0.192 65.184 0.22350.481 0.195 61.021 0.08 66.109 0.19951.028 0.176 63.401 0.22 67.416 0.15558.875 0.16 64.438 0.383 70.529 0.2459.791 0.149 65.101 0.251 72.884 0.20963.405 0.163 66.046 0.208 74.703 0.22364.44 0.212 67.356 0.206 76.984 0.262

65.105 0.193 70.508 0.57 79.697 0.17866.07 0.32 72.805 0.215 82.67 0.284

67.365 0.162 74.68 0.491 84.737 0.20970.444 0.296 76.935 0.323 86.644 0.30572.803 0.218 79.632 0.239 87.912 0.2474.643 0.305 82.585 0.405 89.31 0.27476.904 0.246 86.691 0.414 99.697 0.28679.621 0.181 87.852 0.279 100.68 0.33582.652 0.458 89.229 0.364 106.478 0.46386.552 0.285 99.641 0.326 108.605 0.31987.846 0.244 100.571 0.503 112.972 0.97289.281 0.252 106.46 0.603 115.974 0.3599.625 0.249 115.814 0.367

100.603 0.374106.414 0.493108.597 0.195

413

APPENDIX E Rietveld parameters for all X-ray diffraction samples.

Sample Name t0 t1 t2

CALSTD 0.00323 0.00725 0.02117Kwf CC 0.03295 -0.18553 0.37146Kwf NN 0.05562 -0.32251 0.62025Kwf CR 0.03973 -0.23456 0.4669Kwf AA 0.03161 -0.18132 0.36694Kwf ZZ 0.05927 -0.33518 0.63439SM 421 0.01198 -0.05182 0.12953BM 579 0.0323 -0.18452 0.3736SH 234 0.04838 -0.26637 0.4885CB 725 0.00988 -0.04589 0.16204DOLSTD 0.02659 -0.12327 0.22367Pg B1 0.09146 -0.49805 0.96968Pwls 22-1 0.14493 -0.77154 1.43673Mlb 22-1 0.14097 -0.77681 1.43808Pwv O1 0.12771 0.75998 1.37958Pt UU 0.07792 -0.40226 0.76667Ph C1 0.1698 -1.00834 1.82076SM 307 0.06577 -0.35776 0.6556BM 454 0.06079 -0.333 0.57506SH 202 0.04215 -0.22875 0.40371UP 7718 0.03608 -0.18489 0.34195CB 770 0.05114 -0.28332 0.4816CB 751 0.05294 -0.26207 0.4483Queen 0.05093 -0.27386 0.46202Yates 0.06381 -0.31846 0.52548

415

APPENDIX F Rietveld data for Sierra Madera and Mission Canyon Fm calcite samples.

Degrees 2 Theta

CAL- STD

Kwf CC

Kwf NN

Kwf CR

Kwf AA

Kwf ZZ

SM 421

BM 579

SH 234

CB 725

15 0.0675 0.1223 0.1546 0.1302 0.1187 0.1617 0.0860 0.1203 0.1476 0.081516 0.0683 0.1192 0.1502 0.1264 0.1157 0.1571 0.0852 0.1172 0.1435 0.081417 0.0692 0.1163 0.1459 0.1229 0.1127 0.1528 0.0844 0.1143 0.1396 0.081518 0.0701 0.1135 0.1418 0.1195 0.1100 0.1486 0.0838 0.1115 0.1358 0.081719 0.0710 0.1109 0.1379 0.1164 0.1074 0.1447 0.0833 0.1090 0.1322 0.082120 0.0719 0.1086 0.1343 0.1135 0.1051 0.1410 0.0829 0.1067 0.1288 0.082621 0.0728 0.1064 0.1310 0.1109 0.1030 0.1376 0.0826 0.1045 0.1257 0.083322 0.0738 0.1045 0.1279 0.1085 0.1012 0.1345 0.0825 0.1027 0.1227 0.084223 0.0747 0.1028 0.1252 0.1065 0.0996 0.1317 0.0825 0.1011 0.1200 0.085124 0.0757 0.1015 0.1229 0.1047 0.0982 0.1292 0.0826 0.0998 0.1176 0.086325 0.0767 0.1004 0.1209 0.1033 0.0972 0.1270 0.0828 0.0987 0.1155 0.087626 0.0777 0.0996 0.1193 0.1023 0.0965 0.1253 0.0832 0.0980 0.1137 0.089027 0.0787 0.0991 0.1181 0.1016 0.0961 0.1240 0.0837 0.0976 0.1122 0.090628 0.0797 0.0989 0.1173 0.1014 0.0960 0.1230 0.0843 0.0975 0.1111 0.092329 0.0808 0.0991 0.1170 0.1015 0.0962 0.1225 0.0851 0.0978 0.1103 0.094130 0.0818 0.0995 0.1172 0.1020 0.0968 0.1225 0.0860 0.0984 0.1099 0.096031 0.0829 0.1003 0.1178 0.1029 0.0977 0.1229 0.0870 0.0993 0.1099 0.098132 0.0840 0.1014 0.1189 0.1042 0.0989 0.1238 0.0882 0.1005 0.1103 0.100233 0.0851 0.1029 0.1205 0.1059 0.1005 0.1251 0.0894 0.1021 0.1111 0.102534 0.0862 0.1046 0.1225 0.1080 0.1023 0.1268 0.0908 0.1039 0.1123 0.104935 0.0873 0.1067 0.1249 0.1104 0.1045 0.1290 0.0923 0.1061 0.1138 0.107336 0.0884 0.1090 0.1277 0.1132 0.1069 0.1317 0.0939 0.1086 0.1158 0.109937 0.0896 0.1116 0.1310 0.1163 0.1097 0.1347 0.0956 0.1113 0.1181 0.112538 0.0908 0.1145 0.1346 0.1197 0.1126 0.1381 0.0974 0.1143 0.1207 0.115339 0.0919 0.1176 0.1385 0.1234 0.1158 0.1419 0.0994 0.1175 0.1237 0.118140 0.0931 0.1210 0.1428 0.1273 0.1193 0.1460 0.1014 0.1210 0.1271 0.121041 0.0943 0.1245 0.1475 0.1315 0.1229 0.1504 0.1035 0.1246 0.1307 0.124042 0.0956 0.1283 0.1524 0.1360 0.1268 0.1552 0.1057 0.1285 0.1346 0.127043 0.0968 0.1323 0.1576 0.1406 0.1309 0.1602 0.1080 0.1326 0.1388 0.130244 0.0981 0.1365 0.1630 0.1455 0.1351 0.1655 0.1104 0.1369 0.1432 0.133445 0.0993 0.1408 0.1687 0.1506 0.1395 0.1711 0.1129 0.1413 0.1479 0.136646 0.1006 0.1453 0.1746 0.1559 0.1441 0.1769 0.1154 0.1459 0.1527 0.140047 0.1019 0.1500 0.1807 0.1613 0.1488 0.1829 0.1181 0.1507 0.1579 0.143448 0.1032 0.1549 0.1870 0.1669 0.1537 0.1892 0.1208 0.1556 0.1632 0.146949 0.1046 0.1598 0.1936 0.1726 0.1587 0.1956 0.1236 0.1606 0.1687 0.150450 0.1059 0.1649 0.2003 0.1785 0.1639 0.2023 0.1264 0.1658 0.1743 0.154051 0.1073 0.1702 0.2071 0.1846 0.1691 0.2091 0.1294 0.1711 0.1802 0.157752 0.1086 0.1756 0.2142 0.1908 0.1745 0.2161 0.1324 0.1766 0.1862 0.161453 0.1100 0.1811 0.2214 0.1971 0.1801 0.2233 0.1354 0.1821 0.1924 0.165254 0.1115 0.1867 0.2287 0.2035 0.1857 0.2306 0.1386 0.1878 0.1987 0.169055 0.1129 0.1924 0.2363 0.2101 0.1915 0.2381 0.1418 0.1936 0.2052 0.172956 0.1143 0.1983 0.2439 0.2168 0.1973 0.2458 0.1451 0.1995 0.2118 0.1769

417

Degrees 2 Theta

CAL- STD

Kwf CC

Kwf NN

Kwf CR

Kwf AA

Kwf ZZ

SM 421

BM 579

SH 234

CB 725

57 0.1158 0.2043 0.2517 0.2236 0.2033 0.2536 0.1484 0.2055 0.2186 0.180958 0.1173 0.2103 0.2597 0.2306 0.2094 0.2615 0.1518 0.2117 0.2254 0.185059 0.1188 0.2165 0.2678 0.2376 0.2156 0.2696 0.1553 0.2179 0.2325 0.189260 0.1203 0.2228 0.2760 0.2448 0.2219 0.2779 0.1589 0.2243 0.2396 0.193461 0.1218 0.2292 0.2844 0.2521 0.2283 0.2863 0.1625 0.2307 0.2469 0.197762 0.1234 0.2358 0.2929 0.2595 0.2348 0.2948 0.1662 0.2373 0.2544 0.202063 0.1250 0.2424 0.3015 0.2671 0.2414 0.3035 0.1699 0.2440 0.2619 0.206464 0.1266 0.2491 0.3103 0.2747 0.2482 0.3123 0.1737 0.2507 0.2696 0.210965 0.1282 0.2560 0.3192 0.2825 0.2550 0.3213 0.1776 0.2576 0.2774 0.215466 0.1299 0.2629 0.3283 0.2904 0.2619 0.3304 0.1815 0.2646 0.2853 0.220067 0.1315 0.2700 0.3375 0.2984 0.2690 0.3396 0.1856 0.2717 0.2934 0.224768 0.1332 0.2771 0.3468 0.3065 0.2761 0.3490 0.1896 0.2789 0.3016 0.229569 0.1350 0.2844 0.3563 0.3147 0.2834 0.3586 0.1938 0.2863 0.3099 0.234370 0.1367 0.2918 0.3659 0.3231 0.2908 0.3683 0.1980 0.2937 0.3184 0.239271 0.1385 0.2993 0.3757 0.3316 0.2983 0.3781 0.2023 0.3013 0.3270 0.244172 0.1403 0.3070 0.3856 0.3402 0.3059 0.3881 0.2067 0.3089 0.3357 0.249173 0.1421 0.3147 0.3957 0.3490 0.3136 0.3983 0.2111 0.3167 0.3446 0.254374 0.1439 0.3226 0.4060 0.3579 0.3215 0.4086 0.2156 0.3247 0.3536 0.259475 0.1458 0.3306 0.4164 0.3669 0.3294 0.4190 0.2202 0.3327 0.3628 0.264776 0.1477 0.3387 0.4269 0.3761 0.3375 0.4297 0.2249 0.3409 0.3721 0.270177 0.1496 0.3470 0.4376 0.3854 0.3458 0.4405 0.2296 0.3492 0.3816 0.275578 0.1516 0.3554 0.4485 0.3949 0.3541 0.4515 0.2344 0.3576 0.3912 0.281079 0.1536 0.3639 0.4596 0.4045 0.3626 0.4627 0.2393 0.3662 0.4009 0.286680 0.1556 0.3726 0.4709 0.4143 0.3712 0.4740 0.2443 0.3749 0.4109 0.292381 0.1577 0.3814 0.4823 0.4242 0.3800 0.4855 0.2494 0.3837 0.4210 0.298182 0.1598 0.3903 0.4939 0.4343 0.3889 0.4973 0.2546 0.3927 0.4312 0.304083 0.1619 0.3994 0.5057 0.4446 0.3980 0.5092 0.2599 0.4018 0.4417 0.310084 0.1641 0.4087 0.5178 0.4550 0.4072 0.5213 0.2652 0.4112 0.4523 0.316185 0.1663 0.4181 0.5300 0.4657 0.4166 0.5337 0.2707 0.4206 0.4631 0.322386 0.1685 0.4277 0.5424 0.4765 0.4262 0.5462 0.2762 0.4302 0.4741 0.328687 0.1708 0.4375 0.5551 0.4874 0.4359 0.5590 0.2819 0.4400 0.4853 0.335088 0.1731 0.4474 0.5680 0.4986 0.4458 0.5720 0.2876 0.4500 0.4967 0.341689 0.1755 0.4575 0.5811 0.5100 0.4558 0.5852 0.2935 0.4602 0.5083 0.348290 0.1779 0.4678 0.5944 0.5216 0.4661 0.5987 0.2995 0.4705 0.5201 0.355091 0.1804 0.4783 0.6080 0.5334 0.4765 0.6125 0.3056 0.4810 0.5321 0.361992 0.1829 0.4890 0.6219 0.5454 0.4872 0.6265 0.3118 0.4918 0.5444 0.368993 0.1854 0.4999 0.6360 0.5577 0.4980 0.6407 0.3181 0.5027 0.5569 0.376194 0.1880 0.5110 0.6504 0.5702 0.5091 0.6553 0.3246 0.5139 0.5696 0.383495 0.1907 0.5224 0.6651 0.5829 0.5203 0.6701 0.3312 0.5252 0.5826 0.390996 0.1934 0.5339 0.6801 0.5959 0.5318 0.6852 0.3379 0.5368 0.5959 0.398597 0.1961 0.5457 0.6953 0.6092 0.5436 0.7006 0.3448 0.5487 0.6094 0.406298 0.1990 0.5578 0.7109 0.6227 0.5555 0.7164 0.3518 0.5607 0.6232 0.4142

418

Degrees 2 Theta

CAL- STD

Kwf CC

Kwf NN

Kwf CR

Kwf AA

Kwf ZZ

SM 421

BM 579

SH 234

CB 725

99 0.2018 0.5700 0.7268 0.6365 0.5678 0.7325 0.3590 0.5731 0.6373 0.4222100 0.2048 0.5826 0.7431 0.6506 0.5802 0.7489 0.3663 0.5857 0.6517 0.4305101 0.2078 0.5954 0.7597 0.6650 0.5930 0.7657 0.3738 0.5985 0.6664 0.4389102 0.2109 0.6085 0.7767 0.6798 0.6060 0.7828 0.3815 0.6117 0.6815 0.4476103 0.2140 0.6219 0.7940 0.6948 0.6194 0.8003 0.3893 0.6251 0.6968 0.4564104 0.2172 0.6356 0.8118 0.7102 0.6330 0.8183 0.3973 0.6389 0.7125 0.4654105 0.2205 0.6496 0.8299 0.7260 0.6469 0.8366 0.4055 0.6530 0.7286 0.4746106 0.2239 0.6640 0.8485 0.7421 0.6612 0.8554 0.4139 0.6674 0.7451 0.4841107 0.2274 0.6787 0.8675 0.7586 0.6758 0.8746 0.4225 0.6821 0.7619 0.4938108 0.2309 0.6937 0.8870 0.7755 0.6908 0.8943 0.4313 0.6972 0.7792 0.5037109 0.2345 0.7092 0.9069 0.7928 0.7061 0.9145 0.4404 0.7127 0.7969 0.5138110 0.2383 0.7250 0.9274 0.8106 0.7219 0.9351 0.4496 0.7285 0.8151 0.5242111 0.2421 0.7412 0.9484 0.8288 0.7380 0.9564 0.4591 0.7448 0.8337 0.5349112 0.2460 0.7579 0.9699 0.8475 0.7545 0.9781 0.4689 0.7615 0.8528 0.5459113 0.2500 0.7749 0.9920 0.8667 0.7715 1.0005 0.4789 0.7787 0.8724 0.5572114 0.2542 0.7925 1.0148 0.8864 0.7890 1.0234 0.4892 0.7963 0.8925 0.5687115 0.2584 0.8105 1.0381 0.9066 0.8069 1.0470 0.4998 0.8144 0.9132 0.5806116 0.2628 0.8291 1.0621 0.9274 0.8253 1.0713 0.5107 0.8330 0.9344 0.5928117 0.2673 0.8482 1.0867 0.9488 0.8443 1.0962 0.5219 0.8521 0.9563 0.6054118 0.2719 0.8678 1.1121 0.9709 0.8638 1.1219 0.5334 0.8718 0.9788 0.6183119 0.2767 0.8880 1.1383 0.9936 0.8839 1.1483 0.5453 0.8921 1.0020 0.6316120 0.2816 0.9088 1.1652 1.0169 0.9046 1.1755 0.5575 0.9130 1.0259 0.6454

419

APPENDIX G Rietveld data for Sierra Madera and Mission Canyon Fm dolomite samples.

Degrees 2 Theta

DOL- STD Queen Yates Pg

B1Pwls 22-1

Mlb 22-1

Pwv O1

Pt UU

Ph C1

SM 307

BM 454

SH 202

UP 7718

CB 770

CB 751

15 0.119 0.151 0.176 0.207 0.261 0.252 0.227 0.196 0.262 0.173 0.164 0.138 0.133 0.150 0.16216 0.117 0.147 0.172 0.202 0.255 0.245 0.219 0.191 0.253 0.169 0.159 0.134 0.130 0.145 0.15817 0.115 0.143 0.167 0.197 0.248 0.239 0.212 0.187 0.244 0.164 0.155 0.130 0.127 0.141 0.15418 0.113 0.138 0.163 0.192 0.242 0.232 0.205 0.183 0.236 0.160 0.150 0.127 0.124 0.137 0.15119 0.111 0.134 0.159 0.188 0.237 0.226 0.198 0.179 0.228 0.156 0.146 0.123 0.121 0.132 0.14720 0.109 0.130 0.155 0.184 0.231 0.221 0.191 0.176 0.220 0.152 0.141 0.120 0.119 0.128 0.14421 0.107 0.127 0.151 0.180 0.226 0.215 0.185 0.172 0.213 0.148 0.137 0.117 0.116 0.124 0.14122 0.105 0.123 0.148 0.177 0.222 0.211 0.179 0.169 0.206 0.145 0.133 0.114 0.114 0.121 0.13823 0.104 0.120 0.144 0.174 0.218 0.206 0.174 0.167 0.200 0.142 0.130 0.111 0.112 0.117 0.13524 0.102 0.117 0.141 0.171 0.214 0.202 0.169 0.164 0.194 0.139 0.126 0.108 0.111 0.114 0.13225 0.101 0.114 0.138 0.169 0.211 0.199 0.164 0.163 0.189 0.137 0.123 0.106 0.109 0.111 0.13026 0.100 0.111 0.135 0.168 0.208 0.196 0.161 0.161 0.185 0.135 0.121 0.104 0.108 0.108 0.12827 0.099 0.109 0.133 0.167 0.206 0.193 0.157 0.160 0.181 0.133 0.118 0.102 0.107 0.106 0.12628 0.099 0.107 0.131 0.166 0.205 0.192 0.155 0.159 0.178 0.132 0.116 0.101 0.106 0.104 0.12429 0.098 0.105 0.129 0.166 0.204 0.190 0.153 0.159 0.176 0.131 0.115 0.100 0.106 0.102 0.12330 0.098 0.104 0.127 0.166 0.203 0.190 0.152 0.159 0.174 0.130 0.113 0.099 0.105 0.101 0.12231 0.098 0.103 0.126 0.167 0.204 0.190 0.152 0.159 0.174 0.130 0.113 0.099 0.105 0.100 0.12132 0.098 0.102 0.125 0.168 0.205 0.191 0.152 0.160 0.174 0.131 0.112 0.099 0.106 0.099 0.12133 0.098 0.102 0.125 0.170 0.206 0.192 0.154 0.161 0.176 0.132 0.112 0.099 0.106 0.099 0.12134 0.099 0.102 0.125 0.173 0.208 0.195 0.156 0.163 0.178 0.133 0.113 0.100 0.107 0.099 0.12135 0.100 0.103 0.125 0.176 0.211 0.198 0.159 0.165 0.181 0.135 0.114 0.101 0.109 0.100 0.12236 0.101 0.104 0.126 0.179 0.214 0.201 0.163 0.168 0.185 0.137 0.115 0.102 0.110 0.101 0.12337 0.102 0.105 0.127 0.183 0.218 0.205 0.167 0.171 0.190 0.140 0.117 0.104 0.112 0.103 0.12438 0.103 0.107 0.128 0.187 0.223 0.210 0.172 0.174 0.196 0.143 0.120 0.106 0.114 0.105 0.12639 0.105 0.109 0.130 0.192 0.228 0.215 0.178 0.178 0.203 0.146 0.122 0.108 0.116 0.107 0.12840 0.107 0.112 0.132 0.197 0.233 0.221 0.184 0.182 0.210 0.150 0.126 0.111 0.119 0.110 0.13041 0.108 0.115 0.135 0.202 0.239 0.227 0.191 0.186 0.218 0.154 0.129 0.114 0.121 0.113 0.13342 0.111 0.118 0.138 0.208 0.246 0.234 0.198 0.191 0.226 0.158 0.133 0.118 0.124 0.117 0.13643 0.113 0.121 0.141 0.214 0.253 0.241 0.206 0.196 0.235 0.163 0.137 0.121 0.128 0.121 0.13944 0.115 0.125 0.145 0.220 0.260 0.249 0.214 0.201 0.244 0.168 0.142 0.125 0.131 0.125 0.14245 0.118 0.129 0.149 0.227 0.268 0.257 0.223 0.207 0.254 0.173 0.147 0.129 0.135 0.129 0.14646 0.121 0.134 0.153 0.234 0.276 0.265 0.232 0.213 0.264 0.179 0.152 0.133 0.139 0.134 0.15047 0.124 0.139 0.157 0.241 0.285 0.274 0.241 0.219 0.275 0.185 0.157 0.138 0.143 0.139 0.15448 0.127 0.143 0.162 0.249 0.294 0.283 0.251 0.225 0.286 0.191 0.163 0.143 0.147 0.144 0.15949 0.130 0.149 0.167 0.257 0.303 0.293 0.261 0.232 0.297 0.197 0.169 0.147 0.151 0.149 0.16350 0.133 0.154 0.172 0.265 0.312 0.302 0.271 0.239 0.309 0.204 0.175 0.153 0.156 0.155 0.16851 0.137 0.159 0.177 0.273 0.322 0.312 0.281 0.246 0.321 0.210 0.181 0.158 0.160 0.161 0.17352 0.140 0.165 0.183 0.281 0.332 0.323 0.292 0.253 0.333 0.217 0.188 0.163 0.165 0.167 0.17853 0.144 0.171 0.189 0.290 0.343 0.333 0.303 0.261 0.346 0.224 0.194 0.169 0.170 0.173 0.18454 0.148 0.177 0.195 0.299 0.353 0.344 0.314 0.268 0.359 0.232 0.201 0.174 0.175 0.179 0.18955 0.152 0.183 0.201 0.308 0.364 0.355 0.325 0.276 0.372 0.239 0.208 0.180 0.180 0.186 0.19556 0.156 0.190 0.207 0.317 0.375 0.367 0.337 0.284 0.385 0.247 0.215 0.186 0.186 0.192 0.20157 0.160 0.196 0.214 0.327 0.387 0.378 0.349 0.292 0.399 0.255 0.223 0.192 0.191 0.199 0.20758 0.164 0.203 0.221 0.337 0.398 0.390 0.361 0.301 0.413 0.262 0.230 0.198 0.197 0.206 0.21359 0.169 0.209 0.228 0.346 0.410 0.402 0.373 0.309 0.427 0.271 0.238 0.205 0.202 0.213 0.21960 0.173 0.216 0.235 0.357 0.422 0.415 0.386 0.318 0.441 0.279 0.245 0.211 0.208 0.220 0.22661 0.178 0.223 0.242 0.367 0.435 0.427 0.398 0.327 0.456 0.287 0.253 0.218 0.214 0.227 0.23362 0.182 0.231 0.249 0.377 0.447 0.440 0.411 0.336 0.470 0.296 0.261 0.225 0.220 0.235 0.23963 0.187 0.238 0.257 0.388 0.460 0.453 0.424 0.345 0.485 0.305 0.270 0.231 0.226 0.242 0.246

421

Degrees 2 Theta

DOL- STD Queen Yates Pg

B1Pwls 22-1

Mlb 22-1

Pwv O1

Pt UU

Ph C1

SM 307

BM 454

SH 202

UP 7718

CB 770

CB 751

64 0.192 0.245 0.265 0.399 0.473 0.466 0.438 0.355 0.501 0.313 0.278 0.238 0.233 0.250 0.25365 0.197 0.253 0.272 0.410 0.486 0.479 0.451 0.364 0.516 0.322 0.286 0.245 0.239 0.258 0.26166 0.202 0.261 0.280 0.421 0.500 0.493 0.465 0.374 0.532 0.332 0.295 0.253 0.245 0.266 0.26867 0.207 0.268 0.289 0.432 0.513 0.507 0.479 0.384 0.548 0.341 0.304 0.260 0.252 0.274 0.27568 0.213 0.276 0.297 0.443 0.527 0.521 0.493 0.394 0.564 0.350 0.313 0.267 0.259 0.282 0.28369 0.218 0.285 0.305 0.455 0.542 0.535 0.507 0.404 0.580 0.360 0.322 0.275 0.266 0.290 0.29170 0.223 0.293 0.314 0.467 0.556 0.550 0.522 0.415 0.597 0.370 0.331 0.283 0.273 0.299 0.29971 0.229 0.301 0.323 0.479 0.571 0.564 0.536 0.426 0.614 0.380 0.340 0.290 0.280 0.307 0.30772 0.235 0.310 0.331 0.491 0.585 0.579 0.551 0.436 0.631 0.390 0.350 0.298 0.287 0.316 0.31573 0.240 0.318 0.340 0.504 0.601 0.595 0.566 0.447 0.649 0.400 0.360 0.306 0.294 0.325 0.32374 0.246 0.327 0.350 0.516 0.616 0.610 0.582 0.458 0.666 0.410 0.369 0.315 0.302 0.334 0.33275 0.252 0.336 0.359 0.529 0.632 0.626 0.597 0.470 0.684 0.421 0.379 0.323 0.309 0.343 0.34076 0.258 0.345 0.368 0.542 0.647 0.642 0.613 0.481 0.702 0.432 0.389 0.331 0.317 0.352 0.34977 0.265 0.354 0.378 0.556 0.664 0.658 0.629 0.493 0.721 0.443 0.400 0.340 0.325 0.362 0.35878 0.271 0.364 0.388 0.569 0.680 0.674 0.646 0.505 0.740 0.454 0.410 0.349 0.333 0.371 0.36779 0.277 0.373 0.398 0.583 0.697 0.691 0.662 0.517 0.759 0.465 0.421 0.358 0.341 0.381 0.37680 0.284 0.383 0.408 0.597 0.714 0.708 0.679 0.529 0.778 0.477 0.432 0.367 0.349 0.391 0.38681 0.291 0.393 0.418 0.611 0.731 0.726 0.696 0.542 0.798 0.488 0.443 0.376 0.357 0.401 0.39582 0.297 0.402 0.429 0.625 0.748 0.743 0.714 0.555 0.818 0.500 0.454 0.385 0.366 0.411 0.40583 0.304 0.413 0.440 0.640 0.766 0.761 0.732 0.568 0.838 0.512 0.465 0.395 0.374 0.422 0.41584 0.311 0.423 0.451 0.655 0.784 0.779 0.750 0.581 0.859 0.525 0.477 0.404 0.383 0.432 0.42585 0.318 0.434 0.462 0.670 0.803 0.798 0.768 0.594 0.880 0.537 0.488 0.414 0.392 0.443 0.43586 0.326 0.444 0.473 0.686 0.821 0.817 0.787 0.608 0.902 0.550 0.500 0.424 0.401 0.454 0.44587 0.333 0.455 0.485 0.701 0.841 0.836 0.806 0.622 0.923 0.563 0.512 0.434 0.411 0.465 0.45688 0.341 0.466 0.496 0.717 0.860 0.856 0.825 0.636 0.946 0.576 0.525 0.445 0.420 0.476 0.46789 0.348 0.477 0.508 0.734 0.880 0.875 0.844 0.650 0.968 0.589 0.537 0.455 0.430 0.488 0.47890 0.356 0.489 0.520 0.750 0.900 0.896 0.864 0.665 0.991 0.603 0.550 0.466 0.439 0.500 0.48991 0.364 0.501 0.533 0.767 0.921 0.916 0.885 0.680 1.014 0.617 0.563 0.477 0.449 0.512 0.50092 0.373 0.513 0.545 0.785 0.942 0.937 0.906 0.695 1.038 0.631 0.577 0.488 0.460 0.524 0.51293 0.381 0.525 0.558 0.802 0.963 0.959 0.927 0.711 1.063 0.646 0.590 0.499 0.470 0.536 0.52494 0.389 0.537 0.571 0.820 0.985 0.981 0.948 0.727 1.087 0.660 0.604 0.511 0.481 0.549 0.53695 0.398 0.550 0.585 0.838 1.007 1.003 0.970 0.743 1.113 0.675 0.618 0.523 0.491 0.562 0.54996 0.407 0.563 0.599 0.857 1.030 1.026 0.993 0.759 1.138 0.691 0.633 0.535 0.503 0.575 0.56197 0.416 0.576 0.613 0.876 1.053 1.049 1.015 0.776 1.165 0.706 0.647 0.547 0.514 0.589 0.57498 0.425 0.589 0.627 0.895 1.076 1.073 1.039 0.794 1.191 0.722 0.662 0.560 0.525 0.602 0.58799 0.435 0.603 0.641 0.915 1.101 1.097 1.063 0.811 1.219 0.739 0.678 0.572 0.537 0.616 0.601

100 0.444 0.617 0.656 0.935 1.125 1.121 1.087 0.829 1.247 0.755 0.693 0.586 0.549 0.631 0.614101 0.454 0.631 0.671 0.956 1.150 1.147 1.112 0.847 1.275 0.772 0.709 0.599 0.561 0.645 0.628102 0.464 0.646 0.687 0.977 1.176 1.172 1.137 0.866 1.304 0.790 0.726 0.613 0.574 0.660 0.643103 0.474 0.661 0.703 0.999 1.202 1.199 1.163 0.885 1.334 0.808 0.742 0.627 0.587 0.676 0.657104 0.485 0.676 0.719 1.021 1.229 1.226 1.190 0.905 1.365 0.826 0.759 0.641 0.600 0.691 0.672105 0.496 0.692 0.736 1.044 1.257 1.253 1.217 0.925 1.396 0.844 0.777 0.656 0.613 0.707 0.688106 0.507 0.708 0.753 1.067 1.285 1.282 1.244 0.946 1.428 0.863 0.795 0.670 0.627 0.724 0.703107 0.518 0.724 0.770 1.091 1.314 1.311 1.273 0.967 1.460 0.883 0.813 0.686 0.641 0.740 0.719108 0.530 0.741 0.788 1.115 1.343 1.340 1.302 0.988 1.494 0.903 0.832 0.701 0.655 0.758 0.736109 0.542 0.758 0.806 1.140 1.374 1.371 1.332 1.010 1.528 0.923 0.851 0.718 0.670 0.775 0.753110 0.554 0.776 0.825 1.165 1.405 1.402 1.362 1.033 1.563 0.944 0.871 0.734 0.685 0.793 0.770111 0.566 0.794 0.844 1.191 1.437 1.434 1.394 1.056 1.599 0.966 0.891 0.751 0.701 0.812 0.788112 0.579 0.813 0.864 1.218 1.469 1.466 1.426 1.080 1.636 0.988 0.912 0.768 0.717 0.831 0.806

422

Degrees 2 Theta

DOL- STD Queen Yates Pg

B1Pwls 22-1

Mlb 22-1

Pwv O1

Pt UU

Ph C1

SM 307

BM 454

SH 202

UP 7718

CB 770

CB 751

113 0.592 0.832 0.884 1.246 1.503 1.500 1.459 1.105 1.674 1.011 0.933 0.786 0.733 0.850 0.825114 0.606 0.851 0.905 1.274 1.537 1.535 1.493 1.130 1.713 1.034 0.955 0.804 0.750 0.870 0.844115 0.620 0.871 0.927 1.303 1.573 1.570 1.528 1.156 1.753 1.058 0.977 0.823 0.767 0.891 0.864116 0.634 0.892 0.949 1.333 1.609 1.607 1.564 1.182 1.794 1.083 1.000 0.843 0.785 0.912 0.884117 0.649 0.913 0.971 1.364 1.647 1.644 1.600 1.210 1.837 1.108 1.024 0.863 0.803 0.934 0.905118 0.664 0.935 0.995 1.396 1.685 1.683 1.638 1.238 1.880 1.134 1.049 0.883 0.822 0.956 0.927119 0.680 0.958 1.019 1.428 1.725 1.722 1.677 1.267 1.925 1.161 1.074 0.904 0.841 0.979 0.949120 0.696 0.981 1.043 1.462 1.766 1.763 1.718 1.297 1.971 1.189 1.100 0.926 0.861 1.003 0.972

423

APPENDIX H Electron microprobe data for calcite-rich and dolomite-rich X-ray diffraction samples.

Calcite StandardSample CALSTD A B C D EOxide % MgO -0.03 -0.02 -0.02 0.03 0.03

FeO 0.04 0.00 0.01 0.01 0.01CaO 57.13 56.81 56.77 56.63 57.07CO2 43.70 43.78 43.79 43.82 43.72Totals 100.84 100.58 100.55 100.48 100.84

FormulaAtoms Mg -0.001 0.000 0.000 0.001 0.001

Fe 0.001 0.000 0.000 0.000 0.000Ca 1.017 1.012 1.012 1.009 1.016C 0.991 0.994 0.994 0.995 0.992Totals 5.009 5.006 5.006 5.005 5.008

Sierra Madera Calcite-rich samplesSample Kwf NN A B C D E F G H I J KOxide % MgO 0.62 0.74 0.53 0.38 0.19 0.61 0.79 0.46 0.52 0.15 0.50

FeO 0.00 0.02 0.03 -0.02 0.05 0.04 0.01 -0.04 0.03 0.04 -0.01CaO 55.53 53.77 55.91 55.83 54.94 54.70 55.43 55.90 55.70 56.71 55.93CO2 44.02 44.41 43.93 43.97 44.18 44.20 44.02 43.96 43.97 43.78 43.94Totals 100.16 98.94 100.39 100.16 99.36 99.54 100.25 100.28 100.23 100.68 100.36

FormulaAtoms Mg 0.015 0.018 0.013 0.009 0.005 0.015 0.020 0.011 0.013 0.004 0.012

Fe 0.000 0.000 0.000 0.000 0.001 0.001 0.000 -0.001 0.000 0.001 0.000Ca 0.988 0.960 0.995 0.995 0.982 0.976 0.986 0.995 0.992 1.009 0.995C 0.998 1.011 0.996 0.998 1.006 1.004 0.997 0.997 0.998 0.993 0.996Totals 5.002 4.989 5.004 5.002 4.994 4.996 5.003 5.003 5.002 5.007 5.004

Sample Kwf CC A B C D E F G H I J KOxide % MgO 0.22 0.27 0.26 0.18 0.31 0.40 0.32 0.35 0.26 0.34 0.10

FeO -0.04 0.16 0.01 0.03 0.01 0.00 0.01 0.04 0.05 0.04 -0.05CaO 54.89 53.55 56.10 56.10 56.54 56.32 55.77 55.94 56.09 56.35 56.22CO2 44.22 44.46 43.92 43.92 43.81 43.86 43.99 43.93 43.91 43.84 43.92Totals 99.28 98.45 100.29 100.23 100.67 100.57 100.09 100.27 100.31 100.58 100.19

FormulaAtoms Mg 0.005 0.007 0.007 0.005 0.008 0.010 0.008 0.009 0.007 0.009 0.003

Fe -0.001 0.002 0.000 0.000 0.000 0.000 0.000 0.001 0.001 0.001 -0.001Ca 0.981 0.960 0.999 1.000 1.006 1.002 0.994 0.996 0.999 1.003 1.002C 1.007 1.016 0.997 0.997 0.993 0.994 0.999 0.997 0.997 0.994 0.998Totals 4.993 4.984 5.003 5.003 5.007 5.006 5.001 5.003 5.003 5.006 5.002

425

Sample Kwf AA A B C D E F G H I JOxide % MgO 0.81 0.32 0.29 0.25 0.40 0.23 0.73 0.08 0.40 0.49

FeO 0.03 0.04 0.11 0.26 -0.01 0.07 0.07 -0.01 0.04 -0.03CaO 55.97 56.38 53.15 48.35 55.43 52.41 55.46 56.73 55.66 56.41CO2 43.89 43.84 44.58 45.75 44.06 44.78 44.00 43.79 43.99 43.83Totals 100.70 100.58 98.13 94.61 99.89 97.48 100.26 100.60 100.10 100.71

FormulaAtoms Mg 0.020 0.008 0.007 0.006 0.010 0.006 0.018 0.002 0.010 0.012

Fe 0.000 0.001 0.002 0.004 0.000 0.001 0.001 0.000 0.001 0.000Ca 0.994 1.003 0.954 0.876 0.988 0.942 0.986 1.010 0.992 1.003C 0.993 0.994 1.019 1.057 1.001 1.026 0.997 0.994 0.999 0.993Totals 5.007 5.006 4.981 4.943 4.999 4.974 5.003 5.006 5.001 5.007

Sample Kwf CR A B C D E F G H I JOxide % MgO 0.40 0.18 0.39 0.59 0.18 0.44 0.17 0.35 0.63 0.60

FeO 0.02 0.03 -0.05 0.03 -0.01 0.00 0.01 -0.02 0.01 0.00CaO 55.68 56.46 56.67 56.00 56.39 56.09 56.79 54.41 55.01 55.38CO2 44.00 43.84 43.79 43.90 43.86 43.90 43.77 44.31 44.13 44.05Totals 100.10 100.50 100.80 100.52 100.43 100.43 100.74 99.05 99.78 100.04

FormulaAtoms Mg 0.010 0.004 0.010 0.015 0.004 0.011 0.004 0.009 0.016 0.015

Fe 0.000 0.000 -0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000Ca 0.992 1.006 1.007 0.996 1.004 0.998 1.011 0.973 0.980 0.986C 0.999 0.995 0.992 0.995 0.996 0.995 0.992 1.009 1.002 0.999Totals 5.001 5.005 5.008 5.005 5.004 5.005 5.008 4.991 4.998 5.001

Mission Canyon Formation Calcite-rich samplesSample CB 725 A B C D E F G H IOxide % MgO 0.24 0.22 0.13 0.20 0.29 0.23 0.24 0.19 0.04

FeO -0.01 0.05 0.06 0.00 0.01 -0.02 -0.04 0.02 0.02CaO 56.30 48.23 56.65 56.51 56.93 56.27 56.60 56.40 40.64CO2 43.88 45.86 43.79 43.83 43.72 43.89 43.82 43.85 48.10Totals 100.41 94.36 100.63 100.54 100.95 100.38 100.62 100.46 88.79

FormulaAtoms Mg 0.006 0.006 0.003 0.005 0.007 0.006 0.006 0.005 0.001

Fe 0.000 0.001 0.001 0.000 0.000 0.000 -0.001 0.000 0.000Ca 1.003 0.874 1.009 1.006 1.012 1.002 1.007 1.004 0.747C 0.996 1.060 0.994 0.994 0.990 0.996 0.994 0.995 1.126Totals 5.004 4.940 5.006 5.006 5.010 5.004 5.006 5.005 4.874

426

Sample SH 234 A B C D E F G H I J KOxide % MgO 0.50 0.35 0.43 0.41 0.04 0.27 0.50 0.41 0.48 0.27 0.52

FeO 0.02 0.11 -0.07 -0.02 0.02 -0.06 0.06 -0.02 0.03 0.01 0.02CaO 55.46 54.63 55.24 56.44 74.75 55.87 56.06 55.42 56.34 55.88 56.38CO2 44.04 44.22 44.12 43.83 40.35 43.99 43.89 44.07 43.83 43.97 43.82Totals 100.02 99.30 99.72 100.67 115.15 100.07 100.50 99.88 100.68 100.12 100.75

FormulaAtoms Mg 0.012 0.009 0.011 0.010 0.001 0.007 0.012 0.010 0.012 0.007 0.013

Fe 0.000 0.001 -0.001 0.000 0.000 -0.001 0.001 0.000 0.000 0.000 0.000Ca 0.988 0.976 0.985 1.004 1.262 0.996 0.997 0.988 1.002 0.996 1.002C 1.000 1.007 1.003 0.993 0.868 0.999 0.995 1.001 0.993 0.999 0.992Totals 5.000 4.993 4.997 5.007 5.132 5.001 5.005 4.999 5.007 5.001 5.008

Sample BM 579 A B C D E F G H I J KOxide % MgO 0.28 0.23 0.22 0.24 0.28 0.21 0.25 0.63 0.29 0.28 0.42

FeO -0.07 -0.02 -0.05 0.02 0.06 -0.01 -0.03 0.04 0.03 0.00 -0.01CaO 54.69 51.29 56.40 56.61 56.04 57.08 56.32 56.54 56.37 56.57 56.55CO2 44.27 45.09 43.87 43.80 43.91 43.70 43.88 43.77 43.85 43.81 43.80Totals 99.17 96.59 100.44 100.67 100.29 100.99 100.42 100.99 100.53 100.66 100.77

FormulaAtoms Mg 0.007 0.006 0.005 0.006 0.007 0.005 0.006 0.016 0.007 0.007 0.010

Fe -0.001 0.000 -0.001 0.000 0.001 0.000 0.000 0.001 0.000 0.000 0.000Ca 0.978 0.924 1.004 1.007 0.998 1.015 1.003 1.004 1.003 1.007 1.005C 1.008 1.035 0.995 0.993 0.997 0.990 0.996 0.990 0.995 0.993 0.992Totals 4.992 4.965 5.005 5.007 5.003 5.010 5.004 5.010 5.005 5.007 5.008

Sample SM 421 A B C D E F G H I J KOxide % MgO 0.51 0.25 0.38 0.23 0.17 0.52 0.20 0.23 0.28 0.25 0.26

FeO -0.03 0.01 0.01 -0.01 0.02 0.01 -0.01 0.02 0.03 0.01 0.04CaO 56.12 56.67 45.06 55.92 56.72 56.03 53.15 56.59 56.62 56.10 56.85CO2 43.90 43.79 46.73 43.97 43.78 43.91 44.62 43.80 43.79 43.92 43.74Totals 100.50 100.72 92.18 100.11 100.70 100.46 97.97 100.65 100.72 100.28 100.89

FormulaAtoms Mg 0.013 0.006 0.010 0.006 0.004 0.013 0.005 0.006 0.007 0.006 0.006

Fe 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001Ca 0.998 1.008 0.821 0.997 1.010 0.997 0.954 1.007 1.007 1.000 1.011C 0.995 0.993 1.085 0.999 0.993 0.995 1.021 0.993 0.993 0.997 0.991Totals 5.005 5.007 4.915 5.001 5.007 5.005 4.979 5.007 5.007 5.003 5.009

427

Oxide %

Atoms

Totals 5.003 4.995 4.999 5.004 5.000 5.002 5.004

Oxide %

Atoms

Totals 5.000 4.995 5.004 4.079 4.997 4.977

Sample Kwf ZZ A B C D E F G H I J KOxide % MgO 0.46 0.52 0.55 0.35 0.81 0.80 0.58 0.62 0.59 0.40 0.51

FeO 0.02 0.18 0.10 0.11 0.09 0.04 0.09 0.16 0.12 0.02 0.05CaO 55.32 55.20 55.96 54.34 53.25 54.04 52.96 54.76 54.58 44.24 55.55CO2 44.07 44.04 43.90 44.28 44.50 44.33 44.60 44.14 44.20 46.96 44.01Totals 99.87 99.95 100.50 99.09 98.65 99.21 98.23 99.69 99.49 91.62 100.12

FormulaAtoms Mg 0.011 0.013 0.014 0.009 0.020 0.020 0.014 0.015 0.015 0.010 0.013

Fe 0.000 0.003 0.001 0.002 0.001 0.001 0.001 0.002 0.002 0.000 0.001Ca 0.986 0.984 0.995 0.972 0.952 0.964 0.949 0.976 0.974 0.807 0.989C 1.001 1.000 0.995 1.009 1.013 1.008 1.018 1.003 1.005 1.091 0.999Totals 4.999 5.000 5.005 4.991 4.987 4.992 4.982 4.997 4.995 4.909 5.001

Dolomite StandardSample DOLSTD A B C D E F G

MgO 22.01 21.47 21.63 21.67 21.67 21.85 21.73FeO 0.07 0.04 0.09 0.09 0.09 0.08 0.13CaO 30.57 30.13 30.39 31.09 30.52 30.63 30.91CO2 47.64 47.84 47.73 47.55 47.69 47.65 47.57Totals 100.29 99.49 99.85 100.39 99.98 100.20 100.35

FormulaMg 0.503 0.493 0.496 0.496 0.496 0.500 0.497Fe 0.001 0.001 0.001 0.001 0.001 0.001 0.002Ca 0.502 0.497 0.500 0.511 0.502 0.504 0.508C 0.997 1.005 1.001 0.996 1.000 0.998 0.996

Sample Yates A B C D E FMgO 21.98 21.59 21.86 20.48 22.00 20.90FeO 0.15 0.21 0.16 0.40 0.34 0.58CaO 30.28 29.96 30.91 29.16 29.76 28.26CO2 NA NA NA NA NA NATotals 100.11 99.58 100.48 98.19 99.89 98.05

FormulaMg 0.502 0.495 0.499 0.473 0.503 0.482Fe 0.002 0.002 0.002 0.005 0.004 0.007Ca 0.497 0.494 0.508 0.484 0.489 0.468C NA NA NA NA NA NA

428

Oxide %

Atoms

Totals 5.001 4.998 4.994 4.989 4.994 4.992 4.992

Oxide %

Atoms

Totals 4.986 4.987 4.989 4.985 4.982 4.989 4.975 4.976 5.004 4.984

Oxide %

Atoms

Totals 4.992 5.000 4.999 4.996 5.001 4.999 5.004 5.001 4.994 5.002

Sample Queen A B C D E F GMgO 21.95 21.37 21.30 21.13 21.22 21.24 21.30FeO 0.40 0.41 0.23 0.31 0.47 0.51 0.29CaO 30.36 30.60 30.24 29.74 30.19 29.88 29.96CO2 NA NA NA NA NA NA NATotals 100.33 100.02 99.56 99.11 99.63 99.46 99.40

FormulaMg 0.502 0.490 0.489 0.486 0.487 0.488 0.489Fe 0.005 0.005 0.003 0.004 0.005 0.006 0.003Ca 0.499 0.504 0.499 0.491 0.498 0.493 0.494C NA NA NA NA NA NA NA

Sierra Madera Dolomite-rich samplesSample Pwls 22-1 A B C D E F G H I J

MgO 20.53 20.05 20.98 19.87 19.94 21.29 19.79 19.76 23.07 20.54FeO 0.01 0.07 0.05 0.14 0.07 -0.02 -0.02 0.02 0.09 0.02CaO 30.05 30.73 29.94 30.61 30.14 29.57 29.45 29.64 29.46 29.78CO2 48.01 47.87 47.96 47.91 48.05 48.04 48.30 48.23 47.77 48.08Totals 98.61 98.72 98.93 98.53 98.19 98.88 97.51 97.65 100.38 98.42

FormulaMg 0.474 0.463 0.483 0.460 0.461 0.489 0.459 0.458 0.525 0.474Fe 0.000 0.001 0.001 0.002 0.001 0.000 0.000 0.000 0.001 0.000Ca 0.498 0.510 0.495 0.509 0.501 0.488 0.491 0.494 0.482 0.494C 1.014 1.013 1.011 1.015 1.018 1.011 1.025 1.024 0.996 1.016

Sample Ph C1 A B C D E F G H I JMgO 20.28 20.85 20.68 20.44 20.76 20.57 20.74 20.61 20.60 20.44FeO 0.03 0.03 -0.03 0.00 0.03 0.06 0.02 0.03 -0.02 -0.02CaO 31.20 31.60 31.65 31.52 31.74 31.76 32.30 32.02 31.05 32.40CO2 47.73 47.54 47.57 47.63 47.52 47.53 47.38 47.47 47.74 47.40Totals 99.24 100.02 99.87 99.59 100.05 99.91 100.44 100.12 99.37 100.22

FormulaMg 0.468 0.479 0.475 0.471 0.477 0.473 0.476 0.473 0.474 0.470Fe 0.000 0.000 0.000 0.000 0.000 0.001 0.000 0.000 0.000 0.000Ca 0.517 0.521 0.523 0.521 0.524 0.525 0.533 0.529 0.514 0.535C 1.008 1.000 1.001 1.004 0.999 1.001 0.996 0.999 1.006 0.998

429

Oxide %

Atoms

Totals 4.973 4.949 4.990 5.004 4.989 4.988 4.994 5.003 5.002 4.993 4.991

Oxide %

Atoms

Totals 4.999 5.002 5.003 5.000 4.983 5.001 5.000 5.004 5.002 4.998 4.986

Oxide %

Atoms

Totals 4.999 4.999 5.001 4.997 5.003 4.999 4.997 4.998 4.998 5.000

Sample Pwv O1 A B C D E F G H I J KMgO 19.68 19.13 20.97 21.81 20.72 18.16 21.17 21.68 21.70 21.00 20.99FeO 0.32 0.07 0.07 0.02 0.00 -0.04 0.03 0.01 0.06 0.09 0.02CaO 29.11 26.76 30.02 30.95 30.29 33.15 30.44 30.98 30.85 30.36 30.14CO2 48.29 49.14 47.94 47.58 47.92 47.53 47.81 47.60 47.61 47.83 47.92Totals 97.39 95.11 98.99 100.37 98.93 98.79 99.44 100.27 100.22 99.28 99.07

FormulaMg 0.457 0.447 0.483 0.499 0.477 0.422 0.486 0.496 0.497 0.483 0.483Fe 0.004 0.001 0.001 0.000 0.000 -0.001 0.000 0.000 0.001 0.001 0.000Ca 0.486 0.449 0.496 0.509 0.501 0.554 0.502 0.509 0.507 0.502 0.498C 1.027 1.051 1.010 0.996 1.011 1.012 1.006 0.997 0.998 1.007 1.009

Sample Mlb 22-1 A B C D E F G H I J KMgO 21.65 21.36 21.64 21.60 8.50 21.54 21.21 21.36 21.66 21.44 20.50FeO 0.02 0.08 -0.02 0.03 0.02 0.06 0.01 0.14 0.02 -0.02 0.00CaO 30.46 31.17 31.01 30.62 43.76 30.89 31.12 31.46 30.92 30.68 30.17CO2 47.74 47.57 47.60 47.70 46.00 47.63 47.63 47.47 47.61 47.72 47.99Totals 99.87 100.17 100.24 99.95 98.28 100.11 99.96 100.44 100.21 99.82 98.65

FormulaMg 0.496 0.489 0.495 0.495 0.205 0.493 0.486 0.489 0.496 0.492 0.473Fe 0.000 0.001 0.000 0.000 0.000 0.001 0.000 0.002 0.000 0.000 0.000Ca 0.501 0.513 0.510 0.504 0.760 0.508 0.513 0.518 0.509 0.505 0.500C 1.001 0.998 0.997 1.000 1.017 0.999 1.000 0.996 0.998 1.002 1.014

Sample Pg B1 A B C D E F G H I JMgO 21.72 21.48 21.53 20.89 21.82 21.51 21.12 21.03 21.61 21.57FeO 0.24 0.21 0.34 1.08 0.22 0.14 0.22 0.82 0.21 0.40CaO 30.23 30.55 30.63 30.21 30.72 30.50 30.72 30.39 30.20 30.36CO2 47.71 47.67 47.60 47.55 47.58 47.71 47.67 47.57 47.75 47.65Totals 99.91 99.91 100.09 99.73 100.34 99.86 99.73 99.81 99.77 99.97

FormulaMg 0.498 0.492 0.493 0.481 0.499 0.493 0.485 0.484 0.495 0.494Fe 0.003 0.003 0.004 0.014 0.003 0.002 0.003 0.011 0.003 0.005Ca 0.498 0.503 0.504 0.500 0.505 0.502 0.507 0.502 0.497 0.500C 1.001 1.001 0.999 1.003 0.997 1.001 1.003 1.002 1.002 1.000

430

Oxide %

Atoms

Totals 5.002 5.001 4.997 5.004 4.986 5.008 5.003 5.002 5.006 5.005

Oxide %

Atoms

Totals 5.000 5.001 5.005 5.001 5.002 5.003 5.000 5.001 4.999 4.996

Oxide %

Atoms

Totals 5.006 4.999 4.997 5.004 4.997 5.000 5.000 4.998 5.004

Sample Pt UU A B C D E F G H I JMgO 22.10 21.25 19.27 21.87 20.09 22.17 21.62 21.70 21.51 21.93FeO 0.03 0.68 6.70 0.07 0.80 0.09 0.05 -0.01 0.17 0.10CaO 30.31 30.59 27.03 30.91 29.89 31.01 31.06 30.85 31.45 30.94CO2 47.71 47.54 46.73 47.57 47.85 47.50 47.57 47.64 47.44 47.55Totals 100.16 100.05 99.73 100.42 98.63 100.77 100.30 100.18 100.57 100.51

FormulaMg 0.505 0.488 0.452 0.500 0.465 0.506 0.495 0.497 0.492 0.501Fe 0.000 0.009 0.088 0.001 0.010 0.001 0.001 0.000 0.002 0.001Ca 0.498 0.505 0.455 0.508 0.497 0.508 0.511 0.507 0.517 0.508C 0.998 0.999 1.003 0.996 1.014 0.992 0.997 0.998 0.994 0.995

Mission Canyon Formation Dolomite-rich samplesSample BM 454 A B C D E F G H I J

MgO 21.30 21.42 21.31 21.08 21.30 21.47 21.13 21.36 21.01 21.03FeO 0.00 0.02 -0.01 -0.01 0.02 -0.03 0.02 -0.01 0.07 0.07CaO 31.04 30.98 31.70 31.48 31.31 31.31 31.30 31.10 31.15 30.80CO2 47.64 47.63 47.47 47.55 47.56 47.55 47.59 47.62 47.63 47.72Totals 99.98 100.06 100.46 100.11 100.19 100.30 100.04 100.07 99.85 99.61

FormulaMg 0.488 0.491 0.488 0.484 0.488 0.491 0.485 0.489 0.482 0.483Fe 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 0.001Ca 0.511 0.510 0.522 0.519 0.516 0.515 0.516 0.512 0.514 0.508C 1.000 0.999 0.995 0.999 0.998 0.997 1.000 0.999 1.001 1.004

Sample SM 307 A B C D E F G H IMgO 21.13 21.48 20.62 20.99 20.81 20.82 20.83 20.71 21.19FeO -0.04 0.05 -0.04 0.08 0.21 0.03 0.01 0.18 0.00CaO 32.15 30.60 31.51 31.86 31.08 31.55 31.53 31.35 31.66CO2 47.38 47.71 47.62 47.44 47.62 47.56 47.57 47.58 47.49Totals 100.63 99.85 99.70 100.37 99.73 99.97 99.94 99.81 100.34

FormulaMg 0.484 0.492 0.474 0.481 0.478 0.478 0.478 0.476 0.486Fe -0.001 0.001 -0.001 0.001 0.003 0.000 0.000 0.002 0.000Ca 0.529 0.504 0.521 0.525 0.514 0.521 0.520 0.518 0.521C 0.994 1.001 1.003 0.996 1.003 1.000 1.000 1.002 0.996

431

Oxide %

Atoms

Totals 5.003 4.998 5.003 5.000 5.000 5.004 4.999 5.002 5.001 4.999

Oxide %

Atoms

Totals 5.003 5.002 5.001 5.002 5.005 5.003 5.001 5.001 5.000 4.994

Oxide %

Atoms

Totals 5.001 4.994 4.996 5.004 4.988 5.005 5.001 5.002 4.999 5.004

Sample CB 770 A B C D E F G H I JMgO 21.24 21.19 21.47 21.04 21.29 21.54 21.10 21.07 21.28 20.96FeO 0.03 0.13 -0.01 -0.03 0.03 0.01 0.01 -0.01 0.01 0.01CaO 31.52 30.74 31.29 31.45 31.06 31.34 31.15 31.63 31.24 31.33CO2 47.51 47.69 47.55 47.58 47.62 47.52 47.63 47.52 47.58 47.61Totals 100.30 99.75 100.30 100.03 100.00 100.42 99.90 100.20 100.12 99.90

FormulaMg 0.487 0.486 0.492 0.483 0.488 0.493 0.484 0.483 0.488 0.481Fe 0.000 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000Ca 0.519 0.507 0.515 0.518 0.512 0.515 0.514 0.521 0.515 0.517C 0.997 1.002 0.997 1.000 1.000 0.996 1.001 0.998 0.999 1.001

Sample CB 751 A B C D E F G H I JMgO 21.42 21.22 21.63 21.29 21.37 21.29 21.31 21.40 21.21 20.96FeO 0.07 0.02 0.06 0.03 0.00 0.04 0.03 0.00 -0.02 0.02CaO 31.29 31.39 30.80 31.37 31.70 31.48 31.14 31.12 31.24 30.70CO2 47.53 47.55 47.64 47.54 47.46 47.51 47.60 47.60 47.60 47.77Totals 100.32 100.18 100.13 100.24 100.52 100.33 100.08 100.12 100.03 99.44

FormulaMg 0.491 0.486 0.495 0.488 0.489 0.488 0.488 0.490 0.486 0.482Fe 0.001 0.000 0.001 0.000 0.000 0.001 0.000 0.000 0.000 0.000Ca 0.515 0.517 0.507 0.517 0.521 0.518 0.513 0.512 0.515 0.507C 0.997 0.998 0.999 0.998 0.995 0.997 0.999 0.999 1.000 1.006

Sample SH 202 A B C D E F G H I JMgO 21.11 20.69 20.97 21.98 19.73 21.27 21.11 20.97 21.07 21.31FeO 0.00 0.03 0.19 -0.02 0.03 0.04 0.03 0.24 0.08 0.12CaO 31.39 30.95 30.77 30.89 31.26 31.69 31.34 31.54 31.10 31.47CO2 47.57 47.74 47.69 47.59 47.79 47.46 47.57 47.47 47.63 47.49Totals 100.08 99.41 99.62 100.44 98.81 100.45 100.06 100.22 99.88 100.38

FormulaMg 0.484 0.476 0.482 0.502 0.456 0.487 0.484 0.481 0.484 0.488Fe 0.000 0.000 0.002 0.000 0.000 0.000 0.000 0.003 0.001 0.001Ca 0.517 0.512 0.508 0.507 0.519 0.522 0.517 0.520 0.513 0.518C 0.999 1.006 1.004 0.996 1.012 0.995 0.999 0.998 1.001 0.996

432

Oxide %

Atoms

Totals 5.004 5.003 5.005 4.999 5.000 5.005 5.004 4.991 5.003 5.003

433

Sample UP 7718 A B C D E F G H I JMgO 21.78 21.91 21.44 20.96 21.36 21.70 22.02 20.55 21.89 21.48FeO 0.05 0.02 0.02 -0.03 0.03 0.04 0.05 0.00 -0.04 0.01CaO 31.00 30.68 31.49 31.39 30.93 31.29 30.75 30.73 30.86 31.18CO2 47.56 47.64 47.49 47.60 47.65 47.50 47.60 47.83 47.62 47.57Totals 100.40 100.26 100.45 99.93 99.97 100.53 100.42 99.10 100.33 100.25

FormulaMg 0.498 0.501 0.491 0.481 0.490 0.496 0.503 0.473 0.500 0.492Fe 0.001 0.000 0.000 0.000 0.000 0.001 0.001 0.000 0.000 0.000Ca 0.509 0.504 0.518 0.518 0.510 0.514 0.505 0.509 0.507 0.513C 0.996 0.997 0.995 1.001 1.000 0.995 0.996 1.009 0.997 0.997