PROJECT PRE-FEASIBILITY REPORTenvironmentclearance.nic.in/writereaddata/Online/... · PROJECT...

PROJECT PRE-FEASIBILITY REPORT

FOR

PROPOSED PROJECT FOR THE MANUFACTURING OF PESTICIDE

INTERMEDIATES, FUNGICIDES, HERBICIDES, INSECTICIDES

[Schedule 5 (b) Category “A” as per EIA notification 2006 and its amendment thereof]

At

Plot No. 2817/1, Chemical Zone Near Sandhya Chemical, GIDC Sarigam, Ta: Umbergaon, District- Valsad 396155

Gujarat.

Land/Plot Area: 55000 m

2

Production Capacity: 24000 TPA

APPLICANT CONSULTANT

M/S HERANBA INDUSTRIES LTD. ECO CHEM SALES & SERVICES

Plot No. 2817/1, Chemical Zone Near Sandhya Chemical, GIDC

Sarigam, Ta: Umbergaon, District- Valsad 396155,Gujarat.

E-Mail:[email protected] Tel No.: +919712993470

Office Floor, Ashoka Pavilion - A New Civil Road, Surat, 395001

NABET/EIA/1720/SA 085 E-mail: [email protected] Tel No. +91 261 2231630

Prefeasibility Report Heranba Industries Limited

Manufacturing of Pesticide Intermediate and Pesticide Technical Page 1

1.0 EXECUTIVE SUMMARY

1.0.1 Name & Location

Name of the Project: M/s Heranba Industries Limited

Location: Plot No. – 2817/1, Chemical Zone, Near Sandhya Chemical GIDC Sarigam, Ta:

Umbergaon, District- Valsad 396155, Gujarat.

1.0.2 Project

M/s Heranba Industries Limited is located in notified industrial area, GIDC Sarigam falling

under medium Scale category.

The company proposes to manufacture Pesticide Intermediates, Fungicides, Herbicides,

Insecticides.

The proposed cost of the project will be Rs. 107 Crore.

1.0.3 Applicability of EIA notification – 2006

Category as per the amended EIA notification-2006: as proposed products (i.e. Pesticide

Intermediates, Fungicides, Herbicides, Insecticides) are covered under the Category-5 (b) A.

Hence, Environmental clearance is required.

1.0.4 Project Proponent

The company in India comprises of 4 directors

Medium scale unit

1.1 LIST OF FINISHED PRODUCTS

Sr. No.

Product Capacity, TPA

CAS Number End use of the product

Insecticides

1. Diafenthiuron 2500 80060-09-9 Control of insects and mites resistant to major chemical classes such as ops or Pyrotheroids

2. Profenofos 41198-08-7 Can be used on a variety of crops including cotton and vegetables such as maize, potato, soybean, and sugar beet

.3. Lambda-cyhalothrin

91465-08-6 Used to control a wide range of pests

4. Bifenthrin 82657-04-3 Used against malaria and filarial vector mosquitoes

5. Cyphenothrin 39515-40-7 Is a synthetic pyrotheroids insecticide and is effective against cockroaches

6. Fenpropathrin 64257-84-7 Is a widely used pyrotheroids insecticide in agriculture and household.

7. Zeta-cypermethrin

1315501-18-8 Used to control a broad spectrum of chewing, sucking and flying insects

8. Tranfluthrin 118712-89-3 It is a repellent insecticide, generally used for the control of mosquitoes in the household. It is also the primary

https://en.wikipedia.org/wiki/Pyrethroid

https://en.wikipedia.org/wiki/Insecticide

https://en.wikipedia.org/wiki/Agriculture

https://en.wikipedia.org/wiki/Agriculture



insecticide in certain products for killing wasps and hornets, including their nests.

9. Pymetrozine 123312-89-0

Control of aphids and whiteflies in vegetables, ornamentals, cotton, field crops, deciduous and citrus fruit; control of plant hoppers in rice.

10. Nitenpyram 150824-47-8 Used to treat flea infestations in cats and dogs

11. Acetamiprid 135410-20-7 Used to protect plants against sucking insects

Fungicides

12. Difenoconazole 1000 119446-68-3 Controls a broad spectrum of foliar, seed and soil-borne diseases caused by Ascomycetes, Basidiomycetes and Deuteromycetes in cereals, soya, rice, grapes, pome fruit, stone fruit, potatoes, sugar beet and several vegetable and ornamental crops.

13. Hexaconazole 79983-71-4 Can be used on fruit trees

14. Propiconazole 60207-90-1 Used agriculturally as a systemic fungicide on turf grasses

15. Tebuconazole 107534-96-3 Used agriculturally to treat plant pathogenic fungi.

16. Cyproconazole 94361-06-5 Use on greenhouse- and field-grown roses and as a wood preservative.

17. Epoxiconazole 133855-98-8 Control of Black Sigatoka (Mycosphaerella fijiensis) and Yellow Sigatoka (Mycosphaerella musicola) in bananas and Coffee Rus

18. Metalaxyl 57837-19-1 Is applied by foliar spray, as a soil drench, soil spread with incorporation, or by dipping plants before planting

19. Thiophanate-methyl

23564-05-8 Is a systemic fungicide used on a variety of tree, vine, and root crops, as well as on canola and wheat.

20. Azoxystrobin 131860-33-8 Is widely used in farming, particularly in wheat farming and provides protection against many types of diseases, including: Wheat septoria

21. Pyraclostrobin 175013-18-0 Use on the Residential and recreational turfgrass sites and golf course turf.

22. Picoxystrobin 117428-22-5 Use for control of various fungal diseases including leaf rust, stripe rust, powdery mildew, net blotch, scald and speckled leaf blotch.

23. Trifluoxystrobin 141517-21-7 Used as agricultural fungicide

24. Kresoxim-methyl 143390-89-0 To control powdery mildew on the greenhouse-grown ornamental crops

25. Thiabendazole 148-79-8 Used primarily to control mold, blight, and other fungal diseases in fruits and vegetables

https://en.wikipedia.org/wiki/Mold

https://en.wikipedia.org/wiki/Blight



Herbicides

26. Bispyribac-sodium

500 125401-92-5 For the control of wide range of weeds

27. Imazethapyr 81335-77-5 For control of wide variety of broad leaf weed species

28. Quizalofop-ethyl 76578-14-8 Used to control annual and perennial grass weeds in potatoes, soybeans, sugar beets, peanuts vegetables, cotton and flax

29. Fenoxaprop-ethyl

66441-23-4 Is a herbicide which is selective against perennial and annual grass weeds in many crops.

30. Carfentrazone 128639-02-1 Is a broad spectrum herbicide

31. Sulfentrazone 122836-35-5 Herbicide to control broadleaf and grass weed species in soybeans, sugarcane, tobacco, and several species of turfgrass.

Pesticides Intermediates

32. Cypermethric acid chloride

(CMAC)

3000 52314-67-7 Used in the manufacture of Parathyroid class of Pesticides like Cypermethrin, Alphamethrin, Permethrin and Deltamethrin.

33. Diethyl thiophosphoryl chloride (DETC)

15000 1470-61-7 Used in the preparation of various organophosporus insecticide

34. Bifenthrin alcohol

1000 76350-90-8 pyrethroid insecticide

35. Lambda-acid 1000 72748-35-7 Used to control a wide range of pests

Total 24000

By-products

1 Sodium bi sulphite powder

(80%)

291 7631-90-5 water treatment, in prevention of corrosion, wine making

2 Sodium sulfide (80%)

859 1313-82-2 pulp and paper industry

3 Ammonium chloride Powder

(85%)

1794 12125-02-9 fertilizer

4 Sodium sulphate powder(80%)

5166 7757-82-6 detergents and in the Kraft process of paper pulping,

5 Sodium sulphite powder (80%)

6718 7757-83-7 food and beverage industry as a reducing agent

Total 14828

Manufacturing process with chemical reaction and mass balance is attached as Annexure-3.

1.2 RESOURCE REQUIREMENT

S. No. Components Proposed Resources availability

1. Power, kVA 3000 Dakshin Gujarat Vij Co. Ltd.

2. Fresh Water, KLD 865 GIDC water supply dept.

https://en.wikipedia.org/wiki/Pyrethroid

https://en.wikipedia.org/wiki/Insecticide



3. Imported Coal for boiler (25 TPH), MT/h

3.5 Will be sourced Local Dealer

4. Natural gas for Incinerator, SCM/h 140 Will be sourced from Local Dealer

5. Fuel (HSD) for D.G. Set (1000 KVA) , Kg/h

150 Will be sourced from Local Dealer

6. Chilling plant, TR 300 In-house

7. Cooling tower, TR 500 In-house

1.3 RAW MATERIAL CONSUMPTION:

Product CapacityTPA

Name of RM CAS Number

RM consumption in MT

MT/MT of product

MT Per annum

Diafenthiuron 2500 Xylene 1330-20-7 2.5 6250

2,6 DIPPTU 135252-10-7 0.9 2250

Isopropanol 67-63-0 2 5000

Tert-butylamine 75-64-9 0.2 500

Profenofos 2500 Monochlorobenzene 108-90-7 3 7500

2 – chlorophenol 95-57-8 0.36 900

Bromine 7726-95-6 0.45 1125

DEPCT 2524-04-1 0.51 1275

Trimethylamine 75-50-3 0.16 400

n- propyl bromide 106-94-5 0.335 837.5

Lambda- Cyhalothrin

2500 Lambda-Cyhalothric acid 72748-35-7 0.58 1450

N,N –dimethylformamide 68-12-2 0.005 12.5

Thionyl chloride 7719-09-7 0.29 725

n-hexane 110-54-3 2 5000

Sodium cyanide 143-33-9 0.115 287.5

3-phenoxy benzaldehyde 39515-51-0 0.45 1125

Isopropyl alcohol 67-63-0 2 5000

Di isopropylamine 108-18-9 0.05 125

Bifenthrin 2500 Lambda-Cyhalothric acid 72748-35-7 0.6 1500

N,N –dimethylformamide 68-12-2 0.005 12.5

Thionyl chloride 7719-09-7 0.3 750

n-hexane 110-54-3 2 5000

Bifenthrin alcohol 76350-90-8 0.475 1187.5

Cyphenothrin 2500 Toluene 108-88-3 4 10000

2,2- DMMPCPCA 111-80-8 0.5 1250

N,N –dimethyl formamide 68-12-2 0.005 12.5

Thionyl Chloride 7719-09-7 0.36 900

Sodium cyanide 143-33-9 0.14 350

3-phenoxy benzaldehyde 39515-51-0 0.565 1412.5

Isopropyl alcohol 67-63-0 2 5000

Di isopropylamine 108-18-9 0.05 125

Fenopropathrin

2500 2,2,3,3- TMCPCA 585-25-1 0.44 1100

N,N- dimethylformamide 68-12-2 0.005 12.5


n-hexane 110-54-3 2 5000

Sodium cyanide 143-33-9 0.145 362.5



3-phenoxy benzaldehyde 39515-51-0 0.59 1475

Isopropyl alcohol 67-63-0

2 5000

Di ispropylamine 108-18-9 0.05 125

Zeta-Cypermethrin

2500 Toluene 108-88-3 4 10000

CMA 59042-49-8 0.545 1362.5

N,N –dimethyl formamide 68-12-2 0.005 12.5


Sodium cyanide 143-33-9 0.12 300

3-phenoxy benzaldehyde 39515-51-0 0.495 1237.5

Isopropyl alcohol 67-63-0

2 5000

Di ispropylamine 108-18-9 0.05 125

Transfluthrin 2500 Toluene 108-88-3 5 12500

CMA 59042-49-8 0.6 1500

N,N- dimethyl formamide 68-12-2 0.005 12.5


TFPM 4084-38-2 0.475 1187.5

Pymetrozine 2500 Dichloroethane 107-06-2 4 10000

Methyl acetate 79-20-9 0.375 937.5

Hydrazine hydrate 7803-57-8 0.495 1237.5

Trisphosgene 32315-10-9 0.5 1250

Potassium carbonate 584-08-7 0.325 812.5

Chloroacetone 78-95-5 0.45 1125

Methanol 67-56-1 2.5 6250

Hydrochloric acid 7647-01-0 0.1 250

Nicotinaldehyde 555-90-8 0.4 1000

Nitenpyram 2500 Toluene 108-88-3 2.5 6250

CCMP 70258-18-3 0.635 1587.5

Ethylamine 70% 75-04-7 0.5 1250

MMTNEA 61832-41-5 0.565 1412.5

Acetamiprid 2500 Toluene 108-88-3 2.5 6250

CCMP 70258-18-3 0.8 2000

Methylamine 74-89-5 0.325 812.5

Methanol 67-56-1 0.5 1250

Ethyl N-cyanoacetimidate 1558-82-3 0.525 1312.5

Difenaconazole

1000 Dichloroethane 107-06-2 2.5 2500

CCPPE 119851-28-4 0.75 750

1,2-propanediol 57-55-6 0.205 205

Bromine 7726-95-6 0.21 210

Chlorine 7782-50-5 0.185 185

1,2,4- triazole 288-88-0 0.175 175

Sodium hydroxide 1310-73-2 0.105 105

Hexaconazole 1000 Toluene 108-88-3 2.5 2500

2,4 – DCPP 61023-66-3 0.78 780

Dimethyl Sulphide 75-18-3 0.21 210


1,2,4 triazole 288-88-0 0.225 225

Propiconazole 1000 Dichloroethane 107-06-2 2.5 2500

2,4 –DICAP 2040-05-3 0.6 600

1,2- pentanediol 5343-92-0 0.33 330

Bromine 7726-95-6 0.25 250

Chlorine 7782-50-5 0.11 110

https://www.chemicalbook.com/CASEN_7803-57-8.htm

http://www.merckmillipore.com/IN/en/search/-?search=&SingleResultDisplay=SFProductSearch&TrackingSearchType=pdp_related_product&SearchTerm=*&SearchParameter=%26%40QueryTerm%3D*%26feature_cas_no_value%3D57-55-6



1,2,4 triazole 288-88-0 0.21 210


Tebuconazole 1000 Dichloroethane 107-06-2 2.5 2500

CPDMP 66346-01-8 0.775 775

Dimethyl Sulfide 75-18-3 0.215 215


1,2,4- triazole 288-88-0 0.23 230

Cyproconazole 1000 Dichloroethane 107-06-2 2.5 2500

CPCPP 6740-85-8 0.76 760

Dimethyl sulphide 75-18-3 0.225 225


1,2,4 – triazole 288-88-0 0.245 245

Epoxiconazole 1000 Toluene 108-88-3 2.5 2500

BFPPCB - 1.04 1040

3-CBPA 937-14-4 0.55 550

1,2,4- triazole 288-88-0 0.215 215


Metalaxyl 1000 n-hexane 110-54-3 2.5 2500

2,6 dimethylaniline 87-62-7 0.45 450

Sodium carbonate 497-19-8 (anhydrous)

0.4 400

Methyl 2-chloropropionate 17639-93-9 0.46 460

2-methoxy acetyl chloride 38870-89-2 0.4 400

Thiophanate methyl

1000 Dichloroethane 107-06-2 2.5 2500

Sodium thiocyanate 540-72-7 0.5 500

Methyl chloroformate 79-22-1 0.6 600

1,2 – diammonia benzene 106-50-3 0.325 325

Azoxystrobin 1000 Toluene 108-88-3 2.5 2500

MHPMA 125808-20-0 0.55 550

Potassium Hydroxide, 85%

1310-58-3 0.175 175

4,6 DCP 1193-21-1 0.4 400

2- hydroxy benzonitrile 611-20-1 0.31 310

Sodium Hydroxide 1310-73-2 0.1 100

Pyraclostrobin 1000 Methanol 67-56-1 3 3000

(4-chlorophenyl) hydrazine

1073-69-4 0.425 425

Methyl acrylate 96-33-3 0.26 260

Sulphuric acid 7664-93-9 0.013 13

oxygen 7782-44-7 0.05 50

Sodium Hydroxide 1310-73-2 0.1 100

1- BMNB 3958-60-9 0.565 565

Ammonium chloride 12125-02-9 0.1 100

Toluene 108-88-3 4 4000

Methylchloroformate 79-22-1 0.265 265

Potassium carbonate 584-08-7 0.04 40

Dimethyl sulphate 77-78-1 0.15 150

Picoxystrobin 1000 Toluene 108-88-3 2.5 2500

6-TFMP 94239-04-0 0.49 490

Potassium hydroxide, 85%

1310-58-3 0.2 200

Isochroman-3-one 4385-35-7 0.445 445

Methanol 67-56-1 0.095 95





p- TSA, MH 104-15-4 0.005 5

Methyl formate 107-31-3 0.17 170

Potassium hydroxide 1310-58-3 0.025 25

Trifloxystrobin 1000 Potassium hydroxide, 85%

1310-58-3 0.175 175

Toluene 108-88-3 2 2000

2- TFMPEO 99705-50-7 0.52 520

TBAB 1643-19-2 0.005 5

MBMPMIA 115199-26-3 0.73 730

Kresoxim Methyl

1000 Toluene 108-88-3 3 3000

2-MPMBA 108475-90-7 0.835 835


Sodium cyanide 143-33-9 0.167 167

HAOMHC 593-56-6 0.28 280

Methanol 67-56-1 0.11 110

Thiabendazole 1000 Toluene 108-88-3 2.5 2500

4- cyano thiazole 1452-15-9 0.575 575

Hydrochloric acid 30% 7647-01-0 0.65 650

OPDA 95-54-5 0.55 550

Bisyribac Sodium

500 Ethyl Acetate 141-78-6 1.25 625

2,6 DHBA 303-07-1 0.375 187.5

Dimethylsulfate 77-78-1 0.325 162.5

Sodium bicarbonate 144-55-8 0.225 112.5

4,6 DMMSP 113583-35-0 1.05 525

Potassium carbonate 584-08-7 0.7 350

Toluene 108-88-3 2 1000

Isopropanol 67-63-0

2 1000


Imazethapyr 500 Methanol 67-56-1 1.5 750


ADMBA 40963-14-2 0.465 232.5

DEEPDC 105151-48-2 0.9 450

Toluene 108-88-3 1 500

Hydchloric acid 30% 7647-01-0 0.435 217.5

Quizalofop – Ethyl

500 Toluene 108-88-3 3 1500

Hydroquinone 123-31-9 0.325 162.5

Potassium hydroxide 85% 1310-58-3 0.57 285

2,6 DCQ 112230-20-3 0.585 292.5


Ethyl 2-chloropropionate 535-13-7 0.39 195

Fenoxaprop Ethyl

500 Toluene 108-88-3 3 1500

Hydroquinone 123-31-9 0.33 165

Potassium hydroxide 85% 1310-58-3 0.59 295

2,6 DCB 3621-82-7 0.565 282.5


Ethyl 2-chloropropionate 535-13-7 0.39 195

Carfetrazone 500 Dichloroethane 107-06-2 2 1000

CFNPDFMMT - 0.855 427.5

Tin powder 7440-31-5 0.01 5

Hydrochloric acid 7647-01-0 0.35 175

Sodium nitrite 7632-00-0 0.185 92.5

Ethyl acrylate 140-88-5 0.25 125

https://www.chemsrc.com/en/baike/344480.html




Sulfentrazone 500 Toluene 108-88-3 2 1000

CFNPDFMMT - 0.95 475

Tin powder 7440-31-5 0.01 5

Hydrochloric acid 7647-01-0 0.375 187.5

Methane sulfonyl chloride 124-63-0 0.31 155

CMAC 3000 Forcut 520-45-6 0.38 1140

Acrylonitrile 107-13-1 0.5 1500

CTC 56-23-5 1.55 4650

Acetonitrile 75-05-8 0.022 66

Catalyst 0.02 60

DEA-HCl 14426-21-2 0.011 33

HCl 30% 7647-01-0 1.8 5400

DMF 68-12-2 0.03 90

TC (Thionyl Chloride) 7719-09-7 1.673 5019

Caustic lye 48% 1310-73-2 2.344 7032

n- hexane 110-54-3 9.14 27420

IB 115-11-7 0.594 1782

TEA 121-44-8 0.834 2502

Soda Ash 497-19-8 (anhydrous)

0.005 15

Caustic 100% 1310-73-2 0.971 2913

Sulphuric acid 7664-93-9 1.199 3597

Diethyl thiophosphoryl

chloride (DETC)

15000 Xylene 1330-20-7

2.5 37500

Phosphorous pentasulfide 1314-80-3 0.65 9750

Ethanol 64-17-5 0.55 8250

Chlorine 7782-50-5 0.4 6000

Sodium bicarbonate 10% 144-55-8 0.2 3000

Bifenthrin Alcohol

1000 Tetrahydrofuran 109-99-9 6 6000

Magnesium powder 7439-95-4 0.265 265

2,6 dichlorotoluene 118-69-4 0.9 900

Bromobenzene 108-86-1 0.875 875


N, N dimethylformamide 68-12-2 0.4 400

Toluene 108-88-3 3 3000

Lambda acid (3-(2-chloro-

3,3,3-trifluoroprop-1-

enyl)-2,2- dimethylcyclopropanecarboxy

lic acid

1000 t- butanol 75-65-0 3 3000

Potassium t-butoxide 865-47-4 0.1 100

MTCTFDMH 1.4 1400

Potassium hydroxide 1310-58-3 0.14 140

Sulphuric acid 7664-93-9 0.1 100

1.4 WATER AND WASTE WATER MANAGEMENT

Total raw water requirement will be 953 m3/day (88 m3/day recycled + 865 m3/day fresh) supply

will be met from GIDC water supply department. Copy of GIDC water supply is enclosed

herewith.

Total Industrial Waste water generation will be 213.8 m3/day generated from process, scrubber,

cooling tower blow down, boiler blow down, D M rejection n and container washing etc. Out of

128.8 m3/day of process effluent, 82 m3/day of concentrated effluent will be segregated and will

be treated in solvent stripper followed by MEE and ATFD. 69.8 m3/day of Condensate from



MEE will be taken to ETP for treatment. Balance 47 m3/day of normal effluent will be taken to

ETP. 40 m3/day from cooling tower, 15 m3/day from D M rejection, 10 m3/day from boiler blow

down, 15 m3/day from floor/container washing and 5 m3/day from secondary scrubber will be

collected, treated in RO plant. RO rejection will be taken to ETP and RO permeate will be

recycled in process. Thus total net discharge will be 133.8 m3/day, will be treated in our own

primary, secondary and tertiary ETP and send to common ETP of M/S Sarigam Clean Initiative,

GIDC Sarigam through closed under ground pipe line for further treatment and disposal; into

Arabian Sea.

Domestic waste water (20 m3/day) will be treated in STP and STP treated waste water will be

recycled for plantation, coal/ash wetting and toilet flushing as per requirement.

1.5 AIR EMISSION AND ITS CONTROL MEASURES

1.5.1 Flue Gas Emission

There will be flue gas emission from 25 TPH capacity of imported coal fired steam boiler in the

form of PM, SOx & NOx. Adequate capacity of electro static precipitator and wet scrubber

along with 55 meters height of chimney will be provided. 3.5 TPH of imported coal will be used

as a fuel in 25 TPH of boiler.

A standard Coal handling system with screening, coal crushing and conveying system will be

installed for the proposed plant. There will be a coal crusher plant with impact blade crusher,

screen, conveyor & elevator and reject of the screen will be recycled with two roll crusher and

elevator.

A standard fly ash handling system will be installed for the proposed plant. The fly ash collected

in Economizer and APH shall be designed to collect fly ash in dry form in the silo. From the silo,

fly ash shall be dispatched to trucks. After burning, less than 6 mm coal in AFBC type boiler

furnace will convert in to ash (fly ash particle size which is 100% less than 300 microns) and

this will carry over with flue gas through super heater, economizer, air – heater (APH) and

finally /will be precipitated in ESP zone. The ash collected in the hoppers of ESP will be

discharged in the silo by gravity. Level in the silo will be controlled by level controllers provided

on silo. Whenever the level exceeds, the pneumatic valve opens and ash shall be conveyed to

ash hopper through pipes with the help of compressed dry air at a pressure of 5 kg/cm2.Unit

will provide the Dense Phase pneumatic ash conveying system under the ash discharge points

of economizer, APH, and all ESP fields. At the discharge point of ash silo, ash conditioner shall

be put where water spay shall be done for duct free loading of trucks/lorry under the ash silo.

Finally ash shall be taken by contractor for brick making/filling of low lying area

Also the unit will install 1000 KVA capacity of D G set, as standby. It will be used only during

power failure. 150 kg/h of HSD will be used as a fuel & 11 meters height of chimney will be

provided.

1.5.2 Process Gas Emission

Three numbers of two stage water followed by alkali scrubbers will be provided to scrub Hydro

chloric acid gas and three numbers of two stage alkali scrubbers will be provided to scrub

Sulphur dioxide and one number of two stage alkali scrubbers will be provided to scrub,

hydrogen sulphide gas generated from the various product process. Separate 11 meters height

of vent will be provided.

The unit proposes to install natural gas fired incinerator having capacity of (250 kg/h of solid

and 100 kg/h liquid) and 140 SCM/h of natural gas will be used. Adequate ventury & wet

scrubber along with 30 meters height of chimney will be provided.



Details of Air pollution control measures are attached as Annexure-9.

1.6 HAZARDOUS WASTES AND ITS MANAGEMENT

No Type of waste

Schedule and

Category

Source Qty. MT/ Anum

Treatment Disposal

1 ETP waste Sch:I/35.3 Neutralization of effluent

3888 Dried, packed in bags

Dispose off into TSDF of M/S Detox,

Ankleshwar

2 Salt from MEE

Sch:I/37.3 Evaporation of effluent



Ankleshwar

3 Mixed spent solvent

Sch:I/29.4 From solvent stripper

65 Pack in Drums

Sell to authorized distillator

4. Distillation residue

Sch:I/29.1 Distillation process

1407 Pack in Drums

Sent for co-processing to

cement industries

5. Used Oil Sch:I/5.1 Gear box and D G set

0.05 Packed in carboys

Incinerated into own Incineration system

6. Discarded containers

Sch:I/33.1 Empty containers of raw materials

20 De-contaminated,

stored

Sell to authorized recycler

7. Incineration ash

Sch:I/37.2 incinerator 140 Packed in bags

Sell to brick manufacturer

9. Used rubber hand

gloves/pipes etc

Sch:I/X-08

Production plant

2 Packed in drums/bags


10. Inorganic Acid (Hydro Chloric acid (30-32%)

Sch:I/29.6 process 18727 Tanker Sell to actual users having Rule 9

permission

11. Spent solvent Sch:I/29.4 process 3834 Storage tank Recycled in process after in-house

distillation

12. Date expired and off

specification pesticide

Sch:I/29.3 process 5.0 Packed in drums/bags


13. Contaminated cotton rags

and other cleaning materials

Sch:I/33.2 plant 1.0 Packed in drums/bags


14. Fly ash - boiler 2722 Store in silo Sell to brick manufacturer



1.7 INTRODUCTION OF THE PROJECT AND THE PROPONENT.

Name of the project: M/s Heranba Industries Limited

M/s Heranba Industries Limited is a medium scale unit is located in notified industrial estate,

GIDC, Sarigam, Ta: Umbergaon, District: Valsad having total plot area 55000 m2 & total investment

will be Rs. 110 Crore. The proponent wishes to set up a plant for the manufacture of Pesticide

Intermediate, Insecticides, Fungicides and Herbicides with total capacity of 2000 MT per month.

These Pesticides Intermediate are especially used in manufacture of parathyroid insecticides and

other pesticide technical such as insecticides are used to protect plant against sucking insect,

fungicides used on various fruits and herbicides used to control wide range of weed species in

crops as per requirement.

The proposed project site lies on 20018‟36.73” N Latitude & 72051‟20.63”E Longitude. M/s

Heranba Industries Limited is proposing to be located at Plot No. 2817/1, Chemical Zone, GIDC

Sarigam, Near Sandhya Chemical, Valsad district in Gujarat state and same western part comes

under Daman union Territory. GIDC is located nearby National Highway No. 8 connecting Mumbai

and Ahmedabad and is surrounding by Union territories of Daman in western side. The western

Railway Main Line is passing through the area (Double & Electrified). Nearest town & industrial

estate Vapi is the biggest railway station in the study area; where, almost all the important mail &

express trains stop. Entire study area is well connected with the other major cities of the state and

the country.

Beside the rail connectivity, and also well connected by road transport. There is a good network of

roads in the area and contributes for the development and economic growth of the area. The

National Highway No. 8 (Surat – Mumbai) is now six lanes, double tracked, more elevated and

Jam free highway, which is developed by M/s L&T Company. This highway has given a further

boost to the economic growth of this area.

The unit is operated by technocrats having more than 30 years of experience in manufacturing and

marketing of various organic intermediates and organic pigments.

This is a new medium scale unit and wishes to set up a plant in Sarigam, Gujarat for the

manufacture of organic intermediates.

The proponent proposes to start production of Pesticide intermediates and Pesticide Technical

(Insecticides, Herbicides, Fungicides) with total capacity of 2000 MT per month and process

capabilities to manufacture various organic intermediates.

M/s Heranba Industries Limited is a new medium scale unit and managed by professional

Partners and proposes to manufacture Pesticide intermediates and Pesticide Technical

(Insecticides, Herbicides, Fungicides). Senior personnel are available for providing support to the

manufacturing unit in the areas of technology, R&D, manufacturing, quality control and quality

assurance.

1.7.1 Identification of the Project Proponent:

The unit shall be managed by technocrat Mr. Sadashiv K Shetty having 30 years of experience in manufacturing and marketing of various Agro Chemicals worldwide. Team members having 20 years of experience of Agro Chemicals industries. The details of directors and technical team are as under;

S. No. Name Qualification Designation Experience

1 Mr.Sadashiv K.Shetty

M Sc. ( Organic Chemistry )

Chairman 35 years



2 Mr.Raghuram K.Shetty

Graduate in Economics ,

Diploma in Import & Export

Management.

Managing Director 35 years

3 Mrs.Sujata Sadashiv Shetty

B. com Director 19 years

4 Mrs.Vanita Raghuram Shetty

B Sc ( Botany ) Director 19 years

5 Mr.Madhav K.Raikar

BE Chemical Engineering

GM-Works 30 years

6 Mr.Karan R.Shetty MBA GM-HR & ADM. 30 years

7 Dr.Venketaswara Rao

Phd (Chemistry) GM-QC & R&D. 28 years

8 Mr.M.R.Wilson BE Mechanical Engineering

AGM-Mechanical 25 years

9 Mr.Sumit R.Agrawal M.Sc (Chemistry) AGM-Production 27 years

10 Mr.Vijay Warrier B.Sc (Chem), M.Sc.(Physics)

Production Manager

25 years

11 Mr.Ajijt Patel M.Sc (Organic) Manager-QC 20 years

12 Mr.Vipul G.Makwana

B.Sc (Chem), PDIS, PDI.ENV & Tech. IOSH, NEBOSH

(IGC)

Manager-EHS 20 years

13 Mr.Ramakant S.Pathak

Diploma Electrical Engineering

Asst.Manager-Elect.

29 years

1.7.2 Brief description of nature of the Project:

M/s Heranba Industries Limited Proposes to set up a plant for the manufacture of Pesticide

intermediates and Pesticide Technical (Insecticides, Herbicides, Fungicides) at proposed Plot No.

2817/1, Chemical Zone, GIDC Sarigam, Near Sandhya Chemical,, Ta: Umbergaon, 396155,

District- Valsad (Gujarat).

The proposed project involves the production of “Pesticide intermediates and Pesticide

Technical (Insecticides, Herbicides, Fungicides)”. These Pesticides Intermediate are especially

used in manufacture of parathyroid insecticides and other pesticide technical such as insecticides

are used to protect plant against sucking insect, fungicides used on various fruits and herbicides

used to control wide range of weed species in crops as per requirement.

As per the EIA notification - 2006 as amended products are covered under any category 5(b)

required Prior Environmental Clearance.

For the proposed new project, the company intends to procure the available latest technology for

manufacturing the products.

This project will manufacture Pesticide intermediates and Pesticide Technical (Insecticides,

Herbicides, and Fungicides). A typical plant consists of following major equipments;

S.No. Name of equipments MOC

1 Reactor Mild Steel

2 Reactor Stainless Steel

3 Reactor Glasslined

4 Heat Exchanger Mild Steel



5 Heat Exchanger Stainless Steel

6 Heat Exchanger Graphite

7 Storage Tank Mild Steel

8 Storage Tank Stainless Steel

9 Storage Tank HDPE

10 Reciever Mild Steel

11 Reciever Stainless Steel

12 Reciever Glasslined

13 Reciever HDPE

14 Centrifugal Pump Cast Iron

15 Centrifugal Pump Stainless Steel

16 Centrifugal Pump PP

17 Steamjet Ejector Graphite

18 Waterjet Ejector PP

19 Cooling tower PP FRP

20 Chilling Plant

21 Brine Plant

22 ETP Equipment

23 Incinerator

24 Spray Dryer

25 Transformer

26 Electric Pannel

27 Boiler

The industrial sector in the past 7 to 10 years has seen a drastic boom and also the keeping in

mind the globalization trend, we have identified the demand for the product and with continuous R

& D found that it can be developed in-house and produce commercially for domestic market as well

as an eye more on export markets.

1.7.3 Need for the project and its importance to the country and region:

The proposed project provides a potential growth opportunity for the already running business of

the company. The company is already engaged in the business of manufacturing of “Pesticide

technical, intermediates & its formulation”. The project would increase the overall export and

also increase the foreign revenue.

India produces about 80,000-90,000 MT of pesticides a year. India‟s Agro chemicals & pesticide

industries are the largest in Asia and the twelfth largest in the world. With over 400 million acres

under cultivation and over 60% of the country‟s population dependent on agriculture, the country‟s

economy depends on the agricultural sector to a substantial extent.

India loses nearly 30% of its potential crop to insects, weeds and rodent attacks. The

Pesticides/Crop Protection/Agrochemicals industry plays a crucial role in protecting crops from

damage by weeds, pests, insects and fungus, both before and after harvest. This helps to increase

crop yields, which is important given the rate at which cultivable land is shrinking.

1.7.4 Demand –Supply Gap:

The production of pesticides started in India in 1952 with the establishment of a plant for the production of BHC near Calcutta, and India is now the second largest manufacturer of pesticides in Asia after China. There has been a steady growth in the production of technical grade pesticides in India, from 5,000 metric tons in 1958 to 102,240 metric tons in 1998. In 1996–97 the demand for



pesticides in terms of value was estimated to be around Rs. 22 billion (USD 0.5 billion), which is about 2% of the total world market. The products have very high specific demand as they are especially used as herbicide etc. as per requirement.

1.7.5 Imports vs. Indigenous production:

Manufacturing these proposed products in the country will be very much economical as compared to Import of the same. The export of these Agrochemicals will earn revenue for the country.

1.7.6 Export Possibility:

The proposed products have high export potential. Also these products have very good potential in

local market.

1.7.7 Domestic / export Markets:

The company‟s product is used as raw material to manufacture various herbicides as per the required applications and having very good market in domestic and also having very good international markets.

1.7.9 Employment Generation (Direct and Indirect) due to the project:

During the construction phase around 100 workers and during the operational phase around 170 workers including contractors will be required. Local skilled and semi-skilled workers will be engaged during construction phase. The positive impacts include enhanced direct employment for technical/administrative works and indirect employment opportunities for transporters of raw materials and finished goods.

1.8 PROJECT DESCRIPTION:

1.8.1 Type of Project including interlinked and interdependent projects, if any:

The proposed project is an interdependent project of the company.

1.8.2 Location (map showing general location, Specific location, and project boundary & project site layout) with coordinates:

The map showing general location, specific location and project boundary and project site lay out

is enclosed as Annexure-1. Plant layout is attached as Annexure-2.

1.8.3 Details of alternate sites considered and the basis of selecting the proposed site, particularly the environmental considerations gone into should be highlighted:

The proposed activity will be accommodated in the notified industrial area having proper industrial

infrastructure so; there is no alternate site consideration. Proposed expansion will be carried out in

exiting premises only. (Land allotment letter is attached as Annexure-8)

1.8.4 Size or magnitude of operation:

As per the proposed project cost, the project is covered under medium Scale category of

manufacturing industries.

1.8.5 Project description with process details (a schematic diagram/ flow chart showing the project layout components of the project etc. should be given):

Detailed project description with process details is enclosed as Annexure-3.

1.8.6 Raw material required along with estimated quantity, likely source, marketing area of final products/s, mode of transport of raw Material and finished



product:

Detailed raw material requirement along with estimated quantity, likely source, marketing of final

products, mode of transport of raw materials and finished products & characteristics of hazardous

chemicals are as below:

DETAILS ON PRODUCT TRANSPORTATION

S. No.

Product Physical State Dispatch Means of Transportation

1 Diafenthiuron Solid 25 kg packing By Road

2 Profenofos Liquid 200 kg packing By Road

3 Lambda-cyhalothrin Liquid or Solid

200 kg packing / 25 kg packing

By Road

4 Bifenthrin Liquid or Solid

200 kg packing / 25 kg packing

By Road

5 Cyphenothrin Liquid 200 kg packing By Road

6 Fenpropathrin Solid 25 kg packing By Road

7 Zeta-cypermethrin Liquid 200 kg packing By Road

8 Tranfluthrin Liquid 200 kg packing By Road

9 Pymetrozine Solid 25 kg packing By Road

10 Nitenpyram Solid 25 kg packing By Road

11 Acetamiprid Solid 25 kg packing By Road

12 Difenoconazole Solid 25 kg packing By Road

13 Hexaconazole Solid 25 kg packing By Road

14 Propiconazole Liquid 200 kg packing By Road

15 Tebuconazole Solid 25 kg packing By Road

16 Cyproconazole Solid 25 kg packing By Road

17 Epoxiconazole Solid 25 kg packing By Road

18 Metalaxyl Solid 25 kg packing By Road

19 Thiophanate-methyl Solid 25 kg packing By Road

20 Azoxystrobin Solid 25 kg packing By Road

21 Pyraclostrobin Solid 25 kg packing By Road

22 Picoxystrobin Solid 25 kg packing By Road

23 Trifluoxystrobin Solid 25 kg packing By Road

24 Kresoxim-methyl Solid 25 kg packing By Road

25 Thiabendazole Solid 25 kg packing By Road

26 Bispyribac-sodium Solid 25 kg packing By Road

27 Imazethapyr Solid 25 kg packing By Road

28 Quizalofop-ethyl Solid 25 kg packing By Road

29 Fenoxaprop-ethyl Solid 25 kg packing By Road



30 Carfentrazone Liquid 200 kg packing By Road

31 Sulfentrazone Solid 25 kg packing By Road

32 Cypermethric acid chloride

(CMAC)

Liquid 200 kg packing By Road

33 Diethyl thiophosphoryl

chloride (DETC)

Liquid 200 kg packing By Road

34 Bifenthrin alcohol Solid 25 kg packing By Road

35 Lambda-acid Solid 25 kg packing By Road

36 Sodium bi sulphite powder

(80%)

Solid 25 kg packing By Road

37 Sodium sulfide (80%) Solid 25 kg packing By Road

38 Ammonium chloride Powder

(85%)


39 Sodium sulphate powder

(80%)


40 Sodium sulphite powder

(80%)


DETAILS OF RAW MATERIAL – TRANSPORTATION

No. Substance

Physical State Source of Supply and Packaging

Means of Transportation

Distance of supplier from project site (km)

1 (4-chlorophenyl) hydrazine

Solid DL Intrachem, Ahmedabad & 25 kgs bags

Road 375

2 1- BMNB Solid Henan Daken Chemical Co., Ltd., China & 25 kgs bags

Sea & Road 5000

3 1,2 – diammonia benzene

Solid Nikanth Organics,

Mumbai& 25 kgs bags

Road 150

4 1,2- pentanediol Liquid Henan Daken Chemical Co., Ltd., China &

200 kgs drums

Sea & Road 5000

5 1,2,4 – triazole Solid Capot Chemical Co., Ltd., China & 25 kgs bags

Sea & Road 5000

6 1,2-propanediol Liquid Mainchem Co., Ltd.,

China & 200

Sea & Road 5000



kgs drums

7 2 – chlorophenol Liquid Capot Chemical Co., Ltd., China &

200 kgs drums

Sea & Road 5000

8 2- hydroxy benzonitrile Solid Henan Daken Chemical Co., Ltd., China & 25 kgs bags

Sea & Road 5000

9 2- TFMPEO Solid Capot Chemical Co., Ltd., China & 25 kgs bags

Sea & Road 5000

10 2,2- DMMPCPCA Liquid Hubei Jusheng

Technology Co., Ltd.,

China & 200 kgs drums

Sea & Road 5000

11 2,2,3,3- TMCPCA Solid Henan Daken Chemical Co., Ltd., China & 25 kgs bags

Sea & Road 5000

12 2,4 – DCPP Liquid Capot Chemical Co., Ltd., China &

200 kgs drums

Sea & Road 5000

13 2,4 –DICAP Liquid Capot Chemical Co.,

Ltd., China

Sea & Road 5000

14 2,6 DCB Solid Mainchem Co., Ltd.,

China & 25 kgs bags

Sea & Road 5000

15 2,6 DCQ Solid Henan Daken Chemical Co., Ltd., China & 25 kgs bags

Sea & Road 5000

16 2,6 DHBA solid Capot Chemical Co., Ltd., China & 25 kgs bags

Sea & Road 5000

17 2,6 dichlorotoluene liquid Mainchem Co., Ltd.,


Sea & Road 5000

18 2,6 dimethylaniline liquid Capot Chemical Co., Ltd., China &

200 kgs drums

Sea & Road 5000

19 2,6 DIPPTU solid Capot Chemical Co., Ltd., China & 25 kgs bags

Sea & Road 5000

20 2-methoxy acetyl chloride

liquid Manav Biochem

Impex Pvt. Ltd., Mumbai

& 200 kgs drums

Road 150



21 2-MPMBA Solid Hangzhou J&H Chemical

Co., Ltd., China & 25 kgs bags

Sea & Road 5000

22 3-CBPA Solid Capot Chemical Co., Ltd., China & 25 kgs bags

Sea & Road 5000

23 3-phenoxy benzaldehyde

liquid Heranba Industries

Limited, Vapi

Road 150

24 4- cyano thiazole Solid Dayang Chemicals Co., Ltd.,

China & 25 kgs bags

Sea & Road 5000

25 4,6 DCP Solid Mainchem Co., Ltd.,

China & 25 kgs bags

Sea & Road 5000

26 4,6 DMMSP Solid Capot Chemical Co., Ltd., China & 25 kgs bags

Sea & Road 5000

27 6-TFMP Solid Capot Chemical Co., Ltd., China & 25 kgs bags

Sea & Road 5000

28 Acetonitrile Liquid Anteres Chem Pvt. Ltd.,

Mumbai & 200 kgs drums

Road 150

29 ADMBA Solid Capot Chemical Co., Ltd., China & 25 kgs bags

Sea & Road 5000

30 Ammonium chloride solid Shalibhadra Dyechem

Private Limited,

Ahmedabad & 25 kgs bags

Road 375

31 BFPPCB Solid Mainchem Co., Ltd.,

China & 25 kgs bags

Sea & Road 5000

32 Bifenthrin alcohol solid Capot Chemicals Co., Ltd.,

China & 25 kgs bags

Sea & Road 5000

33 Bromine liquid Mody Chemi-Pharma Limited,


Road 150

34 Bromobenzene Liquid Heranba Industries

Limited, Vapi

Road 25



& 200 kgs drums

35 Catalyst Solid Anteres Chem Private Limited,

Mumbai & 25 kgs bags

Road 150

36 Caustic 100% solid Gujarat Alkalies &

Chemcicals Limited, Dahej & 25 kgs bags

Road 230

37 CCMP Solid Capot Chemicals Co., Ltd.,

China & 25 kgs bags

Sea & Road 5000

38 CCPPE Solid Mainchem Co., Ltd.,

China & 25 kgs bags

Sea & Road 5000

39 CFNPDFMMT Solid Mainchem Co., Ltd.,

China & 25 kgs bags

Sea & Road 5000

40 Chlorine gas Gujarat Alkalies &

Chemcicals Limited, Dahej

& 500 kgs cylinders

Road 230

41 Chloroacetone liquid Mainchem Co., Ltd.,


Sea & Road 5000

42 CMA solid Heranba Industries

Limited, Vapi & 25 kgs bags

Road 25

43 CPCPP Liquid Hubei Jusheng

Technology Co., Ltd.,


Sea & Road 5000

44 CPDMP Liquid Mainchem Co., Ltd.,


Sea & Road 5000

45 CTC liquid Reliable Traders,


Road 150

46 DEA-HCl Solid Balaji Amines Chemicals

Limited, Solapur & 25

kgs bags

Road 575

47 DEEPDC Liquid Henan Daken Chemical Co.,

Sea & Road 5000



Ltd., China & 200 kgs drums

48 DEPCT Liquid Excel Crop Care Limited, Bhavnagar &

200 kgs drums

Road 500

49 Di isopropylamine Liquid Balaji Amines Chemicals


kgs drums

Road 575

50 Dichloroethane Liquid Vitrag Chem, Mumbai & 200

kgs drums

Road 150

51 Dimethyl Sulfide Liquid FDC Limited, Mumbai & 200

kgs drums

Road 150

52 DMF Liquid Salvi Chemical Industries Limited,


Road 150

53 Ethanol Liquid Triveni Chemicals, Vapi & 200 kgs drums

Road 25

54 Ethyl 2-chloropropionate

Liquid Vardhman Esters, Halol

& 200 kgs drums

Road 300

55 Ethyl acrylate Liquid Paari Chem Resources,


Road 150

56 Ethyl N-cyanoacetimidate

Liquid Mainchem Co., Ltd.,


Sea & Road 5000

57 Ethylamine 70% Liquid Balaji Amines Chemicals


kgs drums

Road 575

58 HAOMHC Solid Henan Daken Chemical Co., Ltd., China & 25 kgs bags

Sea & Road 5000

59 Hydrazine hydrate Liquid Jinan Runqiang

Chemical Co., Ltd., China &

200 kgs drums

Sea & Riad 5000

60 Hydrochloric acid Liquid AB Enterprises,


Road 150

61 Hydroquinone Solid Anteres Chem Private Limited,

Road 150




62 IB Gas Vinati Organics

Limited, Lote & 10 MT tankers

Road 500

63 Isochroman-3-one Solid Capot Chemicals Co., Ltd.,

China & 25 kgs bags

Sea & Road 5000

64 Isopropanol Liquid Siddhi Vinayak

Industries, Ahmedabad & 200 kgs drums

Road 375

65 Lambda-Cyhalothric acid

Solid Jebagro, China & 25 kgs bags

Sea & Road 5000

66 Magnesium powder Solid Neeraj Industries,

Rohtak & 25 kgs bags

Road 1325

67 MBMPMIA Solid Aikon International

Limited, China & 25 kgs bags

Sea & Road 5000

68 Methane sulfonyl chloride

Liquid Anteres Chem Private Limited,


Road 150

69 Methanol Liquid Anteres Chem Private Limited,


Road 150

70 Methyl 2-chloropropionate

Liquid Ava Chemicals Pvt. Ltd.,


Road 150

71 Methyl acetate liquid Agro Chem Corporation,


Road 150

72 Methyl chloro formate liquid Meru Chem Private Limited,


Road 150

73 Methyl formate liquid Ashchemie India, Mumbai

& 200 kgs drums

Road 150

74 Methylamine Gas Balaji Amines Chemicals


Road 575



kgs cylinders

75 MHPMA Solid Dayang Chemicals Co., Ltd.,

China & 25 kgs bags

Sea & Road 5000

76 MMTNEA Solid Capot Chemicals Co., Ltd.,

China & 25 kgs bags

Sea & Road 5000

77 Monochlorobenzene liquid Panoli Intermediates India Private

Limited, Vadodara &

200 kgs drums

Road 300

78 MTCTFDMH Solid Dayang Chemicals Co., Ltd.,

China

Sea & Road 5000

79 n- hexane Liquid Anteres Chem Private Limited,


Road 150

80 n- propyl bromide liquid Mody Chemi-Pharma Limited,


Road 150

81 N, N dimethylformamide

Liquid Salvi Chemical Industries Limited,


Road 150

82 n-hexane Liquid Anteres Chem Private Limited,


Road 150

83 Nicotinaldehyde LIquid Career Henan Co., Ltd.,


Sea & Road 5000

84 OPDA Solid Nikanth Organics,


Road 150

85 p- TSA, MH Solid Anteres Chem Private Limited,


Road 150

86 Phosphorous pentasulfide

liquid Prasol Chemicals

Private

Road 150



Limited, Mumbai & 200

kgs drums

87 Potassium carbonate solid Finox Pellets Industries,

Ahmedabad & 25 kgs bags

Road 375

88 Potassium hydroxide Solid Gujarat Alkalies &


Road 230

89 Potassium t-butoxide Solid Chemit Laboratories, Hyderabad & 25 kgs bags

Road 850

90 Soda Ash Solid Gujarat Alkalies &


Road 230

91 Sodium bicarbonate Solid Gujarat Alkalies &


Road 230

92 Sodium carbonate solid Gujarat Alkalies &


Road 230

93 Sodium cyanide solid Jebagro, China & 25 kgs bags

Sea & Road 5000

94 Sodium hydroxide solid Gujarat Alkalies &


Road 230

95 Sodium thiocyanate solid Anteres Chem Private Limited,


Road 150

96 Sulphuric acid Liquid Gujarat Alkalies &


& 200 kgs drums

Road 230

97 t- butanol liquid Crystal Chemicals,

Mumbai

Road 150

98 TBAB solid Mihir Chemicals,


Road 150

99 Tert-butylamine Liquid Balaji Amines Chemicals

Road 575




kgs drums

100 Tetrahydrofuran Liquid Goyal Fine Fab Pvt. Ltd., Ahmedabad & 200 kgs drums

Road 375

101 TFPM Liquid Capot Chemicals Co., Ltd.,


Sea & Road 5000

102 Thionyl chloride Liquid Dev Enterprises, Vadodara &

200 kgs drums

Road 300

103 Tin powder Solid Sarda Industrial

Enterprises, Jaipur & 25 kgs bags

Road 1000

104 Toluene Liquid Hitech Chemicals,


Road 150

105 Trimethylamine Liquid Balaji Amines Chemicals


kgs drums

Road 575

106 Trisphosgene Solid Capot Chemical Co., Ltd., China & 25 kgs bags

Sea & Road 5000

107 Xylene Liquid Credence Chem Private

Limited, Ahmedabad & 200 kgs drums

Road 375

DETAILS ON STORAGE & HANDLING OF HAZARDOUS CHEMICALS

Name of Raw Materials

Quantity Stored , MT/Month

Place of Storage

Boiling Point

Melting Point

Flash Point

State operating pressure &

Temp.

LEL, UEL%

TLV IDLH

Maximum, MT

Actual, MT

(4-chlorophenyl) hydrazine 35 10 Bags - 203 - Stable under

Recommended Conditions

- - -

1- BMNB 50 10 - - - - - - -

1,2 – diammonia benzene 30 10 Bags 267 °C 138 -

143 °C 110 °C Normal at STP LEL -1.5

1,2- pentanediol 20 5 Storage Tank 206 - 105 Normal at STP - - -

1,2,4 – triazole 15 5 Bags 260 119-122

140 Normal at STP - - -

1,2-propanediol 15 5 Storage Tank 187 °C - 60 °C 103 °C Normal at STP 2.6/12.5 - -

2 – chlorophenol 75 10 Storage Tank 62 °C - 63

°C 8 °C 64 °C Normal at STP - - -

2- hydroxy benzonitrile 12 10 Bags 149 °C 95 °C - 98 °C

Not applicable.

Stable under recommended

storage conditions

Not Available

- -

2- TFMPEO 44 10 Bags - 83 °C - 86 °C

- - - - -

2,2- DMMPCPCA 100 20 Bags 149 °C 95 °C - 98 °C

Not applicable.


storage conditions

Not Available

- -

2,2,3,3- TMCPCA 100 20 Storage Tank 173°C at

760 mmHg 56.5°C - - - -

2,4 – DCPP 65 10 Bags 149 °C 95 °C - 98 °C

Not applicable.


storage conditions

Not Available

- -

2,4 –DICAP 50 10 Bags 176-180°C

83mm 37-

41 °C >230 °F - - - -

2,6 DCB 25 5 Bags 110 50 - - - -



2,6 DCQ 25 5 Bags - - - - - - -

2,6 DHBA 25 5 Bags - 165 - - - - -

2,6 dichlorotoluene 75 10 Storage Tank 203 2 82 Normal at STP - - -

2,6 dimethylaniline 40 10 Storage Tank - 10.0 - 11.0

- Normal at STP - - -

2,6 DIPPTU 190 20 Bags - 165 - - - - -

2-methoxy acetyl chloride 30 10 Storage Tank 112 - 113 °C - 28 °C Normal at STP - - -

2-MPMBA 70 10 Bags - - - - - - -

3-CBPA 45 10 Bags 264 °C 92 - 94

°C - - - - -

3-phenoxy benzaldehyde 120 20 Storage Tank 140 deg C

@ .10mmHg 13 deg

C > 112 deg

C Normal at STP - - -

4- cyano thiazole 50 10 bags 100-120℃ 60-61℃ 96.1 °C - - - -

4,6 DCP 35 2 Bags 176 64 - 66

°C - - - - -

4,6 DMMSP 35 2 Bags - - - - - - -

6-TFMP 30 2 Storage Tank - - - - - - -

Acetonitrile 125 20 Storage Tank 81.6 -

Closed cup: 2

open cup: 5.6

Normal at STP 4.4/1.6 TWA:

40 ppm

500

ADMBA 20 2 bags - - - - - - -

Ammonium chloride 10 5 Bags 520°C 328°C - Hygroscopic - TWA:

10 mg/m³

-

BFPPCB 85 10 Bags - 64 - - - - -

Bifenthrin alcohol

Storage Tank 72-72.5 177

Polymerization may occur

above 150 deg C Temperature

- -

Bromine 100 10 Storage Tank - - Not

Applicable Normal at STP

TWA: 0.1 ppm

3 ppm

Bromobenzene 75 10 Storage Tank 156 °C -31 °C 51 °C Normal at STP 0.5/2.5 - -



Catalyst 1 0.5 Bags - - - - - - -

Caustic 100% 100 10 Storage Tank 142 - 144°C 12°C Not

Applicable


storage conditions.

Rapidly absorbs carbon dioxide

from the air, forming sodium

carbonate.

- - -

CCMP 50 10 Bags - 37-42 deg C

> 110.00 deg C

- - - -

CCPPE 50 10 Bags - - - - - - -

CFNPDFMMT 50 10 bags - - - - - - -

Chlorine 20 10 Cylinder minus 34 °C minus

101 °C - Normal at STP - - -

Chloroacetone 30 5 Storage Tank 120 °C -44.5

°C 35 °C -

closed cup


storage conditions.

- - -

CMA 20 5 Bags 290.6 °C at 760 mmHg

83 - 85ºC

129.6 °C - - - -

CPCPP 30 10 Storage Tank 130°C >100°C - - - - -

CPDMP 30 10 Storage Tank 297.4° C at 760 mmHg

69.96° C

- - - - -

CTC 30 10 Storage Tank 76 - 77 °C -23 °C - - - - -

DEA-HCl 25 10 Storage Tank 63 °C at 1013 hPa

- 14 °C - - - -

DEEPDC 35 5 bags - - - - - - -

DEPCT 15 5 Storage Tank 45 deg C @ 3.00mm Hg

- 97 deg C - - - -

Di isopropylamine 10 5 Storage Tank -61 °C Normal at STP 0.8/7.1 - -

Dichloroethane 10 5 Storage Tank 81 - 85 °C -35 °C 13 °C Normal at STP 6.2/15.9 TWA:

10 ppm

50 ppm

Dimethyl Sulfide 10 5 Storage Tank 37.3 °C -98 °C -49 °C Normal at STP 2.2/19.7 10 -



ppm (TWA)

DMF 50 10 Storage Tank 153

Closed cup:

57.778 open cup:

67

Normal at STP 2.2/15.2 TWA:

10 ppm

500 ppm

Ethanol 50 10 Storage Tank 78.5 -114.1 12.78

Stable under the prescribed

storage conditions.

3.3/19 - 3000

Ethyl 2-chloropropionate 50 10 Storage Tank 146.0 -

149.0 deg C @ 760.00m

38 deg C


storage conditions.

- - -

Ethyl acrylate 50 10 Storage Tank 100 °C -72 °C 8 °C Light sensitive 1.8/12

Ethyl N-cyanoacetimidate 15 5 bags - - - - - - - -

Ethylamine 70% 20 5 Storage Tank 39 -70 -26 Normal at STP 3/12.8 - -

Hydrazine hydrate 25 5 Storage Tank 117.2 °C -57 °C 91 °C Air Sensitive 4.7/100

Hydrochloric acid 100 10 Storage Tank 50.5 -62.25 Not

applica ble Highly Reactive

Not applica

ble 50 ppm

Hydroquinone 50 10 Bags 285 - 287 deg C @

760 mmHg

170 - 174

deg C Normal at STP

2 mg/m3 TWA

50 mg/m3

IB 50 10 Storage Tank 106 -108 °C 28 °C minus 108 °C

Normal at STP - - -

Isopropanol 50 10 Storage Tank 82.5 -88.5 11.667 Normal at STP 2/12.7 - 2000 ppm

Magnesium powder 5 2 bags 1107.2 °C 651.1

°C

Pyrophoric: Spontaneously flammable in air

- - -

Methane sulfonyl chloride 20 5 Storage Tank 161 °C -33 °C 110 °C Normal at STP - - -

Methanol 50 10 Storage Tank 64.5 -97.8 12 Normal at STP 6/36.5 - 6000 ppm

Methyl 2-chloropropionate 50 10 Storage Tank 132 - 133 °C -10 °C 38 °C Normal at STP 2.8/13.9 -



Methyl acetate 50 10 Storage Tank 57 -98.05 -5.56 Normal at STP 3.1/16 - 3100 ppm

Methyl chloroformate 30 2 Storage Tank 71.4 -81 22.78 Normal at STP 6.7 -

Methyl formate 30 2 Storage Tank 31 - 33 °C -100 °C -32 °C Normal at STP 4.5/23 TWA:

50 ppm

4500 ppm

Methylamine 30 2 Storage Tank Minus 6.3 °C Minus

93.5 °C Normal at STP 4.9/20.7 - -

Monochlorobenzene 50 10 Storage Tank 131.6 28 Normal at STP 1.3/7.1 TWA 10

ppm

1000 ppm

n- hexane 50 10 Storage Tank 62-69°C at 760 mm Hg

-95°C Normal at STP - - -

n- propyl bromide 50 5 Storage Tank 71°C -110°C 21°C Normal at STP - - -

N, N dimethylformamide 50 10 Storage Tank 58 °C Normal at STP - - -

Nicotinaldehyde 50 10 Storage Tank 95-97 °C at 15 mmHg

7 °C 60 °C Normal at STP 2.0/10.0 - -

Phosphorous pentasulfide 20 10 Bags 514 - 525 °C 280 -

288 °C

Contact with water liberates

toxic gas - - -

Potassium carbonate 20 5 Bags Decomposes 891 Not

Applica ble

Normal at STP Not

Applicable - -

Potassium hydroxide 20 5 Bags 1320 °C 360 °C

Readily absorbs carbon dioxide and moisture

from the air and deliquesces (to

absorb atmospheric

water vapor and become liquid)

- - -

Potassium t-butoxide 20 2 Storage Tank 66 °C -21 °C

Water reactive. Air sensitive.

May form explosive peroxides. Moisture

1.5/12 TWA:

50 ppm

2000 ppm



sensitive.

Soda Ash 60 10 Bags Not Available 851 Not

Applicable


storage conditions.

Not Applicable

- -

Sodium bicarbonate 60 10 Bags 270

deg C

May decompose on

exposure to moist air or

water

- -

Sodium carbonate 60 10 Bags Not Available 851 Not

Applicable

Hygroscopic: absorbs

moisture or water from the

air.

Not Applicable

- -

Sodium cyanide 25 5 Bags 1496 563 Not

Available Normal at STP

Not Available

- -

Sodium hydroxide 25 5 Bags 1390 °C 318 °C



air.

- -

Sodium thiocyanate 25 5 Bags Decomposes 287 Not

Available



air.

Not Available

- -

Sulphuric acid 300 20 Storage Tank 270 -35 Not

applicable

Reacts vigorously, violently or

explosively with many organic and inorganic chemicals and

with water.

Not applicable

3.74 ppm

t- butanol 60 10 Storage Tank 83 °C 25 to 25.5 °C

11 °C Normal at STP 2.4/8.0 TWA: 100 ppm

1600 ppm



Tert-butylamine 20 5 Storage Tank 46 °C -67 °C -38 °C Normal at STP 1.7/8.9 -

Tetrahydrofuran 35 10 Bags 65 -108.3 -14.5 Normal at STP 2.0/11.8 - NA

Thionyl chloride 35 10 Storage Tank 76 -104.5 Not

Applicable Reacts violently

with water. -

Tin powder 25 10 Bags 2507 deg C 231.9 deg C

Normal at STP -

Toluene 60 10 Storage Tank -95 110.61 4.44 Normal at STP 1.27/7.1 - 500 ppm

Trimethylamine 50 10 Storage Tank < 30 - 100

°C -2 °C -45 °C Normal at STP 2.0/16.6 -

Trisphosgene 15 5 Bags 203 - 206 °C 77 - 81

°C

heat sensitive. Moisture sensitive.

Contact with water liberates

toxic gas.

-

Xylene 50 5 Storage Tank 138.5 -47.4 24 Normal at STP 1.0/7.0 -



Name of Raw Materials LD50,LC 50 Specific gravity

Vapour density

odour threshold

health hazard

fire hazardous

Reactivity Antidotes

(4-chlorophenyl) hydrazine - - - - - - - -

1- BMNB - - - - - - - -

1,2 – diammonia benzene

LD50 Oral - Rat - 80 mg/kg LC50 Inhalation - Rat - male - 4 h - 0.92

mg/l

- - Toxic

1,2- pentanediol 12700 mg/kg 0.971 - - 3 1 - -

1,2,4 – triazole 3129 mg/kg - - - 2 1 - -

1,2-propanediol LD 50 Oral - rat - 20

mg/kg - 2.63 - - - - -

2 – chlorophenol

LC50 - Lepomis macrochirus (Bluegill) - 5,7 - 12 mg/l - 96,0 h LC50 - Pimephales promelas (fathead

minnow) - 6 - 16 mg/l - 96,0 h LC50 -

Carassius auratus (goldfish) - 10,7 - 15,2

mg/l - 96,0 h

- - - - - - -

2- hydroxy benzonitrile - - - - - - - -

2- TFMPEO - - - - - - - -

2,2- DMMPCPCA - - - - - - - -

2,2,3,3- TMCPCA - - - - Flammable

Liquids, Category 3

- - -

2,4 – DCPP - - - - - - - -

2,4 –DICAP - - - - Irritant - - -

2,6 DCB - - - - - - - -

2,6 DCQ - - - - - - - -

2,6 DHBA - - - - - - - -



2,6 dichlorotoluene - - - - - - - -

2,6 dimethylaniline Oral, mouse: LD50 = 707 mg/kg; Oral, rat: LD50 = 840 mg/kg;

0.978-0.980 - - - - - -

2,6 DIPPTU - - - - - - - -

2-methoxy acetyl chloride - 1.187 - - 3 1 - -

2-MPMBA - - - - - - - -

3-CBPA LD 50 Oral 1807

mg/kg (Rat) - - - - - - -

3-phenoxy benzaldehyde

Draize test, rabbit, eye: 100 mg Moderate; Inhalation, mouse:

LC50 = 31000 ppm/30M; Oral, mouse: LD50 = 1760

mg/kg; Oral, rat: LD50 = 1215

mg/kg; Skin, rabbit: LD50 =

>20 mL/kg;

1.1130 g/cm3

7.77 - 2 4 - -

4- cyano thiazole - - - - - - - -

4,6 DCP - - - - - - - -

4,6 DMMSP - - - - 2 1 - -

6-TFMP - - - - 2 2 - -

Acetonitrile - - - - 2 3 - -

ADMBA - - - - - -

Ammonium chloride

Draize test, rabbit, eye: 500 mg/24H Mild;

Draize test, rabbit, eye: 100 mg Severe; Oral, mouse: LD50 = 1300

mg/Kg; Oral, rat: LD50 = 1650 mg/Kg

1530 kg/m³ - - 2 0

BFPPCB - - - - - - -

Bifenthrin alcohol - - - Irritant - - -



Bromine - - - - Corrosive - - -

Bromobenzene LD 50 Oral 2383 mg/kg LC 50 Inhalation 20411

mg/l 1.49 - - 2 2 - -

Catalyst - - - - - - - -

Caustic 100%

FISH TOXICITY: 240 ug/L 96 hour(s) LC50

(Mortality) Bluegill (Lepomismacrochirus)

INVERTEBRATE TOXICITY: 330000-

1000000 ug/L 48 hour(s) LC50 (Mortality) Cockle (Cerastoderma

edule)

- - - - - - -

CCMP - - - - - - - -

CCPPE - - - - - - - -

CFNPDFMMT - - - - - - - -

Chlorine - 1.406

g/cm3 at 20 °C

2.45 - - - - -

Chloroacetone

LD50 Oral - Rat - 100 mg/kg(Chloroacetone)

Remarks: Behavioral:Somnolence (general depressed

activity). Behavioral:Ataxia. Skin

and Appendages: Other: Hair. LD50

Dermal - Rabbit - 141 mg/kg(Chloroacetone)

Remarks: Behavioral:Somnolence (general depressed

activity). Behavioral:Ataxia. Skin

- - - - - - -



and Appendages: Other: Hair.

CMA - - - - - - - -

CPCPP - - - - - - - -

CPDMP - - - - - - - -

CTC

LD50 Oral - Rat - 2.350 mg/kg LC50 Inhalation - Rat - 4 h - 8000 ppm LD50 Dermal - Rabbit -

> 20.000 mg/kg

- - - - - - -

DEA-HCl

Acute oral toxicity : LD50: > 2,000 mg/kg Species: Rat Method: OECD Test Guideline 401 Acute

inhalation toxicity Methanol : LC50:

64000 ppm Exposure time: 4 h Species: Rat Acute dermal toxicity

Methanol : LD50: 15,800 mg/kg Species:

Rabbit

- - - - - - -

DEEPDC - - - - - - - -

DEPCT

Inhalation, mouse: LC50 = 725 mg/m3/2H; Inhalation, rat: LC50 =

20 ppm/4H; Oral, mouse: LD50 = 800 mg/kg; Oral, rabbit: LD50 = 900 mg/kg;

Oral, rat: LD50 = 1340 mg/kg.

- - - - - - -

Di isopropylamine

LD50 Oral LD50 = 770 mg/kg ( Rat ) LD50

Dermal LD50 = 2000 mg/kg ( Rabbit ) LC50

Inhalation LC50 = 4800

0.72 3.5 3 3



mg/m3 ( Rat ) 2 h

Dichloroethane

LD50 Oral 625 mg/kg ( Rat )

413 mg/kg ( Mouse ) LD50 Dermal 2800

mg/kg ( Rabbit ) LC50 Inhalation 28.79 mg/L (

Rat ) 1h 7.8 mg/l ( Rat ) 4h

1.25 3.4 3 3

Dimethyl Sulfide

LD50 oral 3300 mg/kg (rat) LD50 dermal > 5000 mg/kg (rabbit) LC50 40250 mg/m³

(rat); 4H

- 2.1 2.5 ppm - - - -

DMF - - - - - - - -

Ethanol

ORAL (LD50): Acute: 7060 mg/kg [Rat].

(LC50): Acute: 20000 ppm 8

hours [Rat].

- - - Flammable - - -

Ethyl 2-chloropropionate - 1.0720g/cm

3 - - - - - -

Ethyl acrylate

Oral: LD50/rat: 550 mg/kg (BASF-Test)

Inhalation: LC50/rat: 5.9 mg/l / 4 h

Dermal: LD50/rat: 470 mg/kg

- - - 3 3 2 -

Ethyl N-cyanoacetimidate - - - - - - - -

Ethylamine 70% LC 50: 240 mg/l 96 hrs - - Not

Applicable - 3, 8 - -

HAOMHC - - - - - - - -

Hydrazine hydrate

Oral LD50 50 - 300 mg/kg Dermal LD50 200 - 1000 mg/kg.

Vapor LC50 0.5 - 2 mg/l

1.028 1.1 @ 15 °C

- 4 2

Hydrochloric acid (LD50): 900 mg/kg - Corrosive



[Rabbit] (LC50): Acute: 4701 ppm 0.5

hours [Rat]

Hydroquinone

Oral, mouse: LD50 = 350 mg/kg; Oral, rabbit:

LD50 = 200 mg/kg; Oral, rat: LD50 = 302 mg/kg; Oral, rat: LD50

= 320 mg/kg;

1.320 g/cm3 3.8 - 2 1

IB

LD 50 oral Rat > 2830 mg/kg LC 50 Inhalation

> 24 mg/l 4 h LC 50 Dermal rat > 2000

mg/kg

0.802 - - - - -

Isochroman-3-one - - - - - - -

Isopropanol

Oral (LD50): Acute: 5045 mg/kg [Rat]

(LC50):16000 8 hours [Rat].


Lambda-Cyhalothric acid - - - - - - -

Magnesium powder LD50 Oral >2000

mg/kg ( Rat ) 1.74 - - 0 4 - -

MBMPMIA - - - - - - - -

Methane sulfonyl chloride

LD50 Oral 250 mg/kg ( Rat ) LD50 Dermal LD50 = 200 mg/kg (

Rat ) LC50 Inhalation LC50 22.3 - 27.7 ppm (

Rat ) 4 h

1.48 4 - 4 - - -

Methanol

ORAL (LD50): Acute: 5628 mg/kg [Rat]

(LC50): Acute: 64000 ppm 4 hours [Rat]


Methyl 2-chloropropionate 1.075 - 2 2

Methyl acetate ORAL (LD50): Acute:

5001 mg/kg [. Rat] - - - 2 3 - -

Methyl chloroformate LD50: 60 mg/kg [Rat]

44 ppm 4 hour(s) [Rat]. - - - 4 3 - -



Methyl formate

LD50 Oral LD50 = 475 mg/kg ( Rat ) LD50

Dermal LD50 > 5000 mg/kg ( Rabbit )

LD50 > 5 g/kg ( Rabbit )

LC50 Inhalation LC50 > 21 mg/L ( Rat ) 4 h

0.968 2.07 - 2 4 - -

Methylamine

LC 50 (Rat, 4 h): 3555 ppm LC 50 (Rat, 1 h): 7110 ppm LC 50 (Rat, 1,0 h): 7000 ppm LC 50 (Leuciscus idus, 48

h): 16 mg/l (Static) Remarks: Experimental

result, Key Study LC 50 (Fish, 96 h): 970

mg/l

- 1 - - - - -

Monochlorobenzene - - - - Flammable - - -

MTCTFDMH - - - - - - - -

n- hexane

Draize test, rabbit, eye: 10 mg mild Inhalation,

mouse: LC50 = 150000 mg/m3/2H Inhalation,

rat: LC50 = 48000 ppm/4H Inhalation, rat:

LC50 = 627000 mg/m3/3M Oral, rat:

LD50 = 25 g/kg

0.678 2.97 - - - - -

n- propyl bromide LC50/4H 253mg/m3/4H

(Rat) - - - - - - -

N, N dimethylformamide - 1.03 - - 2 2 - -

Nicotinaldehyde Oral Rat LD50: 2207

mg/kg 1.135 - - - - - -

OPDA - - - - - - - -

p- TSA, MH - - - - - - - -

Phosphorous pentasulfide (oral) 500.00mg/kg 2.03@20°C - 1 ppm - - - -



body weight (dust, mist) 1.50mg/l/4h

Potassium carbonate (LD50): Acute: 1870

mg/kg [Rat]. - - Irritant - - -

Potassium hydroxide LD50 Oral LD50 = 284

mg/kg ( Rat ) 2.04 - - 3 0 - -

Potassium t-butoxide

LD50 Oral 1650 mg/kg ( Rat ) LD50 Dermal > 2000 mg/kg (Rabbit) LC50 Inhalation 180

mg/L ( Rat ) 1 h 53.9 mg/L ( Rat ) 4 h

0.929 2.5 - 3 3 - -

Soda Ash

(LD50): Acute: 4090 mg/kg [Rat]

(LC50): Acute: 2300 mg/m 2

hours [Rat]

- Irritant - -

Sodium bicarbonate

Draize test, rabbit, eye: 100 mg/30S Mild; Oral, mouse: LD50 = 3360

mg/kg; Oral, rat: LD50 = 4220 mg/kg;

- 2 0 - -

Sodium carbonate

(LD50): Acute: 4090 mg/kg [Rat]

(LC50): Acute: 2300 mg/m 2

hours [Rat]

- Irritant - -

Sodium cyanide (LD50): Acute: 6.44

mg/kg [Rat]. - 4 0 - -

Sodium hydroxide LD50 Dermal LD50 = 1350 mg/kg ( Rabbit )

2.13 - 3 0 - -

Sodium thiocyanate ORAL (LD50): Acute:

764 mg/kg [Rat] - 2 1 - -

Sulphuric acid

ORAL (LD50): Acute: 2140 mg/kg [Rat.] (LC50): Acute: 510 mg/m 2 hours [Rat].

Acute: 510 mg/m 2 hours [Rat].

- 3 0 - -



t- butanol

LD 50 Oral > 310 mg/kg (Rat) LD 50

Dermal > 2000 mg/kg (Rat) LC 50 Inhalation

>31 mg/L 4h (Rat)

0.78 2.6 - 2 3 - -

Tert-butylamine

LD50 Oral 464 mg/kg ( Rat ) LC50 Inhalation LC50 = 3800 mg/m3

( Rat ) 4 h

0.69 2.5 - 3 3 - -

Tetrahydrofuran 0.8892 50 ppm - - - -

TFPM - - - - -

Thionyl chloride LC50): Acute: 500 ppm

1 hours [Rat] - Corrosive - - -

Tin powder 7.31 - 1 1

Toluene


(LC50): Acute: 49000 mg/m 4 hours [Rat].

- 3 3

Trimethylamine

LD50 Oral LD50 = 1200 mg/kg ( Rat )

LD50 Dermal LD50 > 5000 mg/kg ( Rat )

LC50 Inhalation LC50 > 5.9 mg/L ( Rat ) 4 h

0.86 - 3 4

Trisphosgene

LD50 Oral >2000 mg/kg ( Rat ) LD50

Dermal > 2000 mg/kg ( Rat ) LC50 Inhalation LC50 = 41.5 mg/m3

( Rat ) 4 h

- 4 1

Xylene


(LC50): 5000 4 hours [Rat]

861 - 880 kg/m³

3.7 - 3 3 0

1.8.7 Resource optimization/ recycling and reuse envisaged in the project, if any, should briefly outline:

Resource optimization/recycling and reuse envisaged in the project (Solvent recovery system) in

detail are as mentioned below:

The raw materials will be stored in closed containers and will be handled through closed

system to avoid the handling losses.

The Reactor shall be connected to an efficient double condenser system with

cooling/chilling water/brine circulation.

Reactor and solvent handling pumps shall have mechanical seals to prevent leakages. Also

provide with breather valve to prevent losses.

Solvent will be taken from storage tank to reactors through closed pipe line. Storage tank

shall be vented through trap receiver & condenser operated on cooling water.

The condensers shall be provided with sufficient HTA and residence time so as to prevent

any loss of solvent.

Proper earthing shall be provided where ever solvent handling is done.

Entire plant is flameproof.

Solvent will be stored as per statutory requirement. Solvent will be kept at a separate

specified area with all the safety measures.

LDAR Programme will be implemented regularly

RO Permeate will be recycled in the process to minimize the fresh water consumption.

Domestic waste water will be treated and recycled.

Valuable by-products will be recovered and sold as products.

Details of solvent used, recovered & recycled as under;

Productwise Solvent consumption and recovery at per ton, per month and per Anum of product

Product Capacity,

TPA Name of Solvent

Solvent consumption in MT

% Recovery

Ton Per Ton of

product Per day Per Annum

Per month

Insecticides

Diafenthiuron 2500

Xylene (Fresh) 0.04 0.308 100 8.3 98.4

Xylene (Recovered) 2.46 18.92 18.92 1.6

Isopropyl alcohol (Fresh)

0.045 0.346 112.5 9.4

97.95 Isopropyl alcohol

(Recovered) 1.955 15.04 15.04 1.3

246.46 20.5

Profenofos 2500

Monochlorobenzene (fresh)

0.05 0.385 125 10.4

98.33 Monochlorobenzene

(recovered) 2.95 22.69 22.69 1.9

147.69 12.3



Lambda Cyhalothrin

2500

Isopropyl alcohol (fresh)

0.04 0.308 100 8.3


(recovered) 1.96 15.08 15.08 1.3

115.08 9.6

Bifenthrin 2500 n-hexane (fresh) 0.05 0.385 125 10.4

97.5 n-hexane (recovered) 1.95 15 15 1.3

140 11.7

Cyphenothrin 2500

Toluene (fresh) 0.05 0.385 125 10.4 98.75

Toluene (recovered) 3.95 30.38 30.38 2.5


0.04 0.308 100 8.3


(recovered) 1.96 15.08 15.08 1.3

270.46 22.5

Fenpropathin 2500

n-hexane (fresh) 0.05 0.385 125 10.4 97.5

n-hexane (recovered) 1.95 15 15 1.3


0.04 0.308 100 8.3


(recovered) 1.96 15.08 15.08 1.3

255.08 21.3

Zeta- Cypermethrin

2500

Toluene (fresh) 0.05 0.385 125 10.4 98.75



0.04 0.308 100 8.3


(recovered) 1.96 15.08 15.08 1.3

270.46 22.5

Transfluthrin 2500 Toluene (fresh) 0.05 0.385 125 10.4

99.0 Toluene (recovered) 4.95 38.08 38.08 3.2

163.08 13.6

Pymetrozine 2500

Dichloroethane (fresh)

0.02 0.154 50 4.2

99.5 Dichloroethane

(recovered) 3.98 30.62 30.62 2.6

Methanol (fresh) 0.04 0.308 100 8.3 98.4

Methanol (recovered) 2.46 18.92 18.92 1.6

199.54 16.6

Nitenpyram 2500 Toluene (fresh) 0.05 0.385 125 10.4


143.85 12.0



Acetamiprid 2500 Toluene (fresh) 0.05 0.385 125 10.4


Methanol (Fresh) 0.025 0.19 62.5 5.2

95.0 Methanol (Recovered)

0.475 3.65 3.65 0.3

210 17.5

Maximum 270.46 22.5

Fungicides

Difenaconazole 1000


0.05 0.154 50 4.2

98.0 Dichloroethane

(recovered) 2.45 7.538 7.538 0.6

57.538 4.8

Hexaconazole 1000 Toluene (fresh) 0.05 0.154 50 4.2


57.538 4.8

Propiconazole 1000


0.05 0.154 50 4.2

98.0 Dichloroethane

(recovered) 2.45 7.538 7.538 0.6

57.538 4.8

Tebuconazole 1000


0.05 0.154 50 4.2

98.0 Dichloroethane

(recovered) 2.45 7.538 7.538 0.6

57.538 4.8

Cyproconazole 1000


0.05 0.154 50 4.2

98.0 Dichloroethane

(recovered) 2.45 7.538 7.538 0.6

57.538 4.8

Epoxiconazole 1000 Toluene (fresh) 0.05 0.154 50 4.2


Metalaxyl 1000 n-hexane (fresh) 0.05 0.154 50 4.2

98.0 n-hexane (recovered) 2.45 7.538 7.538 0.6

57.538 4.8

Thiophanate Methyl

1000


0.05 0.154 50 4.2

98.0 Dichloroethane

(recovered) 2.45 7.538 7.538 0.6

57.538 4.8

Azoxystrobin 1000 Toluene (fresh) 0.05 0.154 50 4.2 98.0




57.538 4.8

Pyraclostrobin 1000

Methanol (fresh) 0 0 0 0.0

100 Methanol (Recovered)

3.1 9.538 9.538 0.8

Toluene (fresh) 0.025 0.077 25 2.1 99.3


46.768 3.9

Picoxystrobin 1000 Toluene (fresh) 0.05 0.154 50 4.2


57.538 4.8

Trifloxystrobin 1000 Toluene (fresh) 0.06 0.185 60 5.0


65.969 5.5

Kresoxim Methyl 1000 Toluene (fresh) 0.05 0.154 50 4.2


59.077 4.9

Thiabendazole 1000 Toluene (fresh) 0.05 0.154 50 4.2


57.538 4.8

Maximum - - 65.9 5.5

Herbicides

Bispyribac Sodium

500

Ethyl Acetate (fresh) 0.05 0.077 25 2.1

96.0 Ethyl Acetate (recovered)

1.2 1.846 1.846 0.2

Toluene (fresh) 0.04 0.062 20 1.7 98.0


Isopropyl alcohol (Fresh)

0.04 0.062 20 1.7


(Recovered) 1.96 3.015 3.015 0.3

72.876 6.1

Imazethapyr 500

Methanol (fresh) 0.05 0.077 25 2.1

96.6 Methanol (Recovered)

1.45 2.231 2.231 0.2

Toluene (fresh) 0.05 0.077 25 2.1 95.0


53.693 4.5

Quizalofop Ethyl 500 Toluene (fresh) 0.05 0.077 25 2.1


29.538 2.5



Fenoxaprop Ethyl

500 Toluene (fresh) 0.05 0.077 25 2.1


29.538 2.5

Carfentrazone Ethyl

500


0.05 0.077 25 2.1

97.5 Dichloroethane

(recovered) 1.95 3 3 0.3

28 2.3

Sulfentrazone Ethyl

500 Toluene (fresh) 0.05 0.077 25 2.1

97.5 Toluene (recovered) 1.95 3 3 0.3

28 2.3

Maximum - - 72.8 6.1

Pesticide Intermediates

CMAC 3000

n-hexane (fresh) 0.228 2.105 684 57.0 97.5

n-hexane (recovered) 8.912 82.26 82.26 6.9

TEA (fresh) 0.01 0.092 30 2.5 98.8

TEA (recovered) 0.824 7.606 7.606 0.6

IB (fresh) 0.457 4.218 1371 114.3

23.0 IB (recovered) 0.137 1.265 1.265 0.1

2176.131 181.3

Diethyl thiphosphoryl

Chloride (DETC) 15000

Xylene (fresh) 0.05 2.307 750 62.5 98.0

Xylene (recovered) 2.45 113.08 113.08 9.4

863.08 71.9

Bifenthrin alcohol

1000

Tetrahydrofuran (fresh)

0.1 0.308 100 8.3

98.3 Tetrahydrofuran

(recovered) 5.9 18.15 18.15 1.5

Toluene (fresh) 0.05 0.154 50 4.2 98.3


177.227 14.8

Lambda Acid 1000 t-butanol (fresh) 0.2 0.615 200 16.7

93.3 t-butanol (recovered) 2.8 8.615 8.615 0.7

208.615 17.4

Overall total 3834.182 319.5



Solvent Management plan

Selection of proper material of construction to get optimum heat-transfer co-efficient and minimize the loss of product as well solvent.

Provision of either Chilled water or Brine water in secondary heat exchanger to eliminate the possibility of any solvent loss.

The Reactors involved are provided with mechanical seal to ensure the elimination of any leakage.

Heat exchangers for these operations are specially designed, procured from over seas countries, like China, Germany, USA etc.

Vent of the heat exchangers is provided with the solvent trap, which have the jacket to prevent and minimize the vapor loss to atmosphere.

SolventMain

StorageTank

AdditionTank

ReactionMassWith

Solvent

ReceiverDistilledSolvent

Solvent DistillationSystem

Recycle

Organic Layer/spent solvent to recovery

system

FLOW DIAGRAM OF PROPOSED SPENT SOLVENT MANAGEMENT SYSTEM

CHW in

CHB. in

CHW out

CHB.out

CHB. Chilled Brine

CHW Chilled Water

Distillationcolumn



1.8.8 Availability of water source, Energy/Power requirement and source should be given:

Availability of water its source, Energy/power required and its source is below. Water withdrawal

permission is attached as Annexure-4.

PRODUCTWISE WATER CONSUMPTION & EFFLUET GENERATION M3 PER TONE

AND PER DAY OF PRODUCT

Sr.

No. Product

Water

Consump

tion,

m3

/tone

Effluent Generation, m

3/tone Water

Consumption,

m3

/day

Effluent Generation, m

3/day

High

COD/High

TDS stream

to MEE

Normal

stream

to ETP

High

COD/High

TDS stream

to MEE

Normal

stream

to ETP

Insecticides

1. Diafenthiuron 0 0 0 0 0 0

2. Profenofos 2 1.325 1.54 15.38 10.19 11.8

3. Lambda-

cyhalothrin 2 1.775 0.562 15.38 13.65 4.32

4. Bifenthrin 0.75 0 0.8 5.76 0 6.15

5. Cyphenothrin 2 1.845 0.565 15.38 14.19 4.35

6. Fenpropathrin 2 1.814 0.565 15.38 13.95 4.35

7. Zeta-cypermethrin 2 1.78 0.575 15.38 13.69 4.42

8. Transfluthrin 0.64 0 0.685 4.923 0 5.27

9. Pymetrozine 1 0.255 1.525 7.692 1.962 11.7

10. Nitenpyram 1.25 0.64 1.22 9.615 4.923 9.38

11. Acetamiprid 0.75 1.15 0 5.769 8.846 0

Maximum - - - 15.38 14.19 11.8

Fungicides

12. Difenoconazole 1.25 1.16 0.625 3.846 3.56 1.92

13. Hexaconazole 1.5 1.03 0.88 4.615 3.169 2.71

14. Propiconazole 1.25 1.245 0.625 3.846 3.8 1.92

15. Tebuconazole 1.5 1.025 0.89 4.615 3.154 2.74

16. Cyproconazole 1.5 1.05 0.9 4.615 3.231 2.77

17. Epoxiconazole 1.5 1.275 1 4.615 3.923 3.08

18. Metalaxyl 1.75 1.25 0.915 5.385 3.846 2.82

19. Thiophanate-

methyl 1 1.3

0

3.077 4 0

20. Azoxystrobin 1.25 0.69 0.925 3.846 2.123 2.85

21. Pyraclostrobin 4 2.13 2.46 12.31 6.554 7.57

22. Picoxystrobin 1 0.61 0.64 3.077 1.877 1.97

23. Trifluoxystrobin 1 1.32 0 3.077 4.062 0



24. Kresoxim-methyl 1 1.332 0 3.077 4.098 0

25. Thiabendazole 1 0

1.68 3.077 0 5.169

Maximum - - - 12.31 6.554 7.57

Herbicides

26. Bispyribac-sodium 2 3.74 0

3.077 5.754 0

27. Imazethapyr 1 0

1.815 1.538 0 2.79

28. Quizalofop-ethyl 2 2.3 1.485 3.077 3.53 2.28

29. Fenoxaprop-ethyl 2 2.308 1.485 3.077 3.55 2.28

30. Carfentrazone 2 0

2.57 3.077 0 3.95

31. Sulfentrazone 0.75 1.2 0

1.154 1.846 0

Maximum - - - 3.077 5.754 3.95

Pesticide

Intermediates

32, CMAC 13.997 3.192 1.165 129.2 29.46 10.8

33. DETC 0 0.25 0 11.54 0

34. Bifenthrin alcohol 2 0

4.11 6.154 0 12.6

35. Lambda-acid 4 4.765 0

12.31 14.66 0

Total 178.43 82.158 46.72

OVERALL WATER CONSUMPTION & WASTE WATER GENERATION

S.No. Particulars Water

consumption, m3/day

Waste water generation, m3/day

Normal Concentrated

1 Domestic 20 20 0

2 Processing and product washing 178 47 82

3 Cooling 400 40 0

4 Boiler (blow down & DM rejection) 270 25 0

5 Floor/container/equipment washing

15 15 0

6 Scrubber 45 5 0

7 Coal and fly ash wetting 10 0 0

8 Gardening 15 0 0

Total 953 152 82

Recycle from R O 68

Mode of treatment and disposal

To STP 20

A To solvent stripper followed by MEE & ATFD

82

B Cooling/boiler/scrubber/washing to RO

85

C Condensate from MEE to ETP 69.8



D RO rejection to ETP 17

E Normal effluent from process to ETP

47

Net discharge to primary secondary & tertiary ETP to CETP

(C + D + E)

133.8



herewith.


cooling tower blow down, boiler blow down, D M rejection and container washing etc. Out of








primary, secondary and tertiary ETP and send to common ETP of M/s Sarigam Clean Initiative,

GIDC Sarigam through closed underground pipe line for further treatment and disposal; into

Arabian Sea.



WATER BALANCE DIAGRAM


Total Water Consumption: 953 M3/day (Fresh: 865 M3/Day + Recycle : 88 M3/Day)

Domestic: 20 Processing: 178 Cooling: 400 Washing: 15 Scrubber: 45 Gardening: 15

128.8 40 15HCl (30%): 40

Collection tank: 133.8 M3/Day

RO Rejection: 17Collection tank: 82

Neutralization tankCa(OH)3 slurry : 9.0 MT/Day

Filtration 9.0 MT/Day ETPsludge to TSDF

Holding tank: 82

MEE/ATFD Condensate from MEE: 69.8

12 MT/Day of Salt to TSDF

Concentrated: 82

Treated effluent under ground effluent drainage pipe line

Arabian Sea through closed pipe line

Treated effluent holding tank

Primary/Secondary/Tertiary ETP

Solvent Stripper0.2 MT Solvent Recovered

Tail scrubber: 5

Boiler: 270

D M Plant: 270

D M Rejection: 15

255 + 255 Boiler: 510

Condensate: 255 Steam: 245 Blow down: 10

Normal: : 47R O Plant: 85 RO Permeate: : 68

CETP Sarigam

STP

For Gardening/Toilet flushing/Coal/ash wetting

Coal/ash wetting: 10



ENERGY REQUIREMENTS AND ITS SOURCE

S. No. Particulars Proposed Source

1. Steam requirement 20000 kg/h Proposed 25 TPH capacity of coal

fired steam boiler

POWER REQUIREMENTS AND ITS SOURCE

S. No.

Particulars Proposed Source

1. Power – Electricity

requirement 3000 kVA Will be sourced from Dakshin Gujarat Vij Co. Ltd.

1.8.9 Quantity of waste to be generated (liquid and solid) and scheme for their Management/disposal

Quantity of waste to be generated (liquid and solid) and scheme for their Management/ disposal

is enclosed as Annexure-5.

1.8.10 Schematic representations of the feasibility drawing which give information of EIA purpose

A schematic representation of the feasibility drawing is enclosed as Annexure-8.

1.9 SITE ANALYSIS

1.9.1 Connectivity

The project is to be located in notified Industrial Estate of Sarigam which is very well connected to

National Highway no.8, Western Railways. And the nearest airport (Mumbai) and port are 150 KM

away from the project site by road.

1.9.2 Land Form, Land use and Land ownership

The land is in the form of industrial shed owned by Gujarat Industrial Development Corporation.

1.9.3 Topography (along with map)

Topography map showing the elevation of study area is below;

The catchment area of the proposed project site altitude is 35 m (MSL) consists of the near site is

flat topped, highly dissected plateaus and dyke ridges running in a west to east direction. The Main

River (Daman Ganga) in the catchment area flows in incised meanders forming steep

geomorphologically „V‟ shaped valleys with steep sides. The entire catchment has a rectangular

and trellis pattern of drainage depicting the influence of the structures on the drainage

development. The piedmonts at the base of the steep plateaus and dyke ridges are covered with

thin soils, which support agriculture in very few areas. The river valley, wherever flat, has good

quality soil and is mostly cultivated based on the availability of water. The river valley fills with thick

alluvium provides the only area for cultivation.

The command area of the proposed expansion project is surrounded by moderately dissected

plateaus and piedmont slopes. The slope of the land along the piedmont and the nature of flow of

the streams (e.g. in the upper part of the command area near the village, Vapi) provide sample



proof of scarp retreat. The Daman Ganga River with tributaries in the piedmont slope area show

parallel pattern, which are partly controlled by the lineaments. Along the river valley the flood plain

consists of good quality soil, suitable for cultivation. The largest portion of the command area is the

alluvial plain, which has been formed by the river Man. The alluvial plain is studded with number of

residual hills with degraded forests. The river man in the command area also flows in straight

channels, which shows that the river is structurally controlled. Topography map showing the

elevation of the study area below. The topographical map is enclosed as Annexure-6.

1.9.4 Existing land use pattern (agriculture, non-agriculture, forest, water bodied ( including area under CRZ)), shortest distances from the periphery of the project to periphery of the forest, national park, wild life sanctuary, eco sensitive areas, water bodies (distance from the HFL of the river), CRZ. In case of notified industrial area, a copy of Gazette notification should be given

The land is located in the notified industrial area and possession letter and gazette notification is

enclosed as Annexure-7

1.9.5 Existing Infrastructure

GIDC notified industrial area of Sarigam has the entire available infrastructure like water,

electricity, roads, rail, transportation, CETP availability of raw material and drainage system.

1.9.6 Soil classification

General soil classification of the area is as under:

The area, being of basaltic formation, falls under the broad soil group of red loams and black clay

soils. The transmission of water through similar parent material seems to have influenced the

development of different physiographic characteristics of the soils in the area.

The area in between the hills with sloping lands contains dark yellowish brown to very dark greyish

brown gravelly clay loam to clayey soils of shallow to moderate thickness. The dissected hill and

steep slopes suffer from severe erosion hazards. The steep hill slopes are almost devoid of soil.

1.9.7 Climate data from secondary sources

Rainfall Data:

The project site location receives annual rainfall of 2010 – 1200 to 1300 mm in 35 rainy days with

coefficient of variation of 65 %. There is large spatial and temporal variation in rainfall of the study

area. The low rainfall areas receiving less than 500 mm rainfall are comprised of Kutch district and

western parts of Banaskantha and Patan district and parts of Jamnagar, Rajkot and Surendranagar

districts. These are also characterized by arid climate. The high rainfall (> 1400 mm) receiving

areas (Project site, Dang, Valsad, Navsari and Surat, Dadra & nagar haveli and Daman & Diu) are

characterized as sub humid climate. The rest part of the state receives rainfall between 500-1000

mm and generally fall under semi-arid climate. Considering the abnormality of weather particularly

rainfall during the monsoon period. The observed and predicted rainfall was then analysed for its

validity.

S. No.

Region Rainfall Projection (in mm) June – Oct

Normal Rainfall (In mm)

Rainfall Projection (% Departure from

normal)

1. Middle Gujarat 905.3 796 13.7

2. South Gujarat 696.3 575 21.0

3. Project site 2071.7 1433.7 44.5

4. Saurashtra 767.1 580.4 32.2



5. Gujarat State 1110.1 846.5 31.1

Source: AAU, Anand, Gujarat

Temperature Data

The site location M/s. Hemani Chemi Organic Pvt. Limited is located in the southern part of

Gujarat. The secondary data was collected from free data of Worldclim.org year of 2013. The

project site temperature regime for medium to high level temperature (30-32 °C) during the

seasonal months (June to Sep). The climate map for site location shows that temperature

recorded over a month of (4 month).Coastal area from the inland site for 10 km distance,

temperature recorded for this area low to medium level. Figure showing project site for seasonal

temperature in (June to September-2013).

1.9.8 Social Infrastructure available

Social Infrastructure in Valsad district is as under:

Education : There are 990 primary and 161 secondary and higher secondary Table 5: List of

Educational Institutes schools in the district Educational Total With over 1,250 seats, there are 6

ITIs offering several industrial training Institutes programs which includes, fitting, armature & motor

rewinding, Primary School 990 electrician, information technology and electronic system

maintenance Secondary School etc 166 Higher Secondary School, One Government polytechnic

College is present in the district offering courses in civil, chemical, electrical, mechanical and

plastic engineering, ITI‟s 6 with an intake capacity of 360 Polytechnic 1 College§ With 120 seats,

there is one Degree Engineering College present in Pharmacy College 2 Valsad offering

engineering courses in mechanical and chemical Engineering 1 branches College§ Located in

Vapi, G. M. Bilakhia Pharmacy College has an intake Management 1 College capacity of 60

students per year Other Colleges Rofel Institute of Management studies in Valsad offers full time

MBA Other Colleges: Arts, Commerce, Science, B.Ed and Law College course and takes 120

students per annum Source: Department of Education, 2007

Health: There are 43 primary healthcare centres, 10 community healthcare centres, 10

Government and 1 Municipal hospital present in the district. Valsad has several private

11specialized hospitals to provide a comprehensive range of tertiary and secondary care services

backed by state-of- the- art technology and trained medicos. A multi-specialty 21st Century

Hospital, (branch of Nadkarni Group of Hospitals) is present in Vapi, giving services in general and

laparoscopic surgery, trauma, orthopaedic and urology etc. the hospital is one of the few centres in

India offering Uterine Thermochoice thermal Balloon Therapy for Dysfunctional Uterine Bleeding

(DUB) patients. Beside this, several private hospitals such as, Kasturba Hospital, Bhatia General

Hospital, and Adarsh Hospital are also present in Valsad

Tourism: Tourism Built in 1742, the Fire Temple at Udawada, which is also known Fire Temple as

Mecca for the Parsi community in India, makes the city a famous pilgrimage centre throughout the

world§ Dharampur is surrounded on three sides by the Sahyadri Mountains which grace the town

with pleasant climate throughout the years The collection at the Lady Wilson Museum in

Dharampur includes tribal art and art crafts that highlights the local culture. Besides this, District

Science Centre is also present in Valsad Proximity of Valsad with Daman & Diu, has increased the

graph of tourist flow in the district.



1.10 PLANNING BRIEF

1.10.1 Planning Concept (Type of industries, facilities, transportation, etc.) Town and Country Planning /Development authority Classification

There is a cluster of numerous large-scale, medium-scale and small-scale industries, engaged in

manufacture of variety of products, for example pharmaceuticals, dyes and chemicals, paper mills,

paints, plastics, packaging, textiles, speciality chemicals, pesticides and others in the Gujarat

Industrial Development Corporation (GIDC) notified area of Sarigam.

1.10.2 Land use Planning (breakup along with green belt etc)

The proposed project is located within the Notified Industrial Area by Government of Gujarat and

due to the proposed project there will not be any change in the land use pattern of the region.

Proposed Green belt planning in the project area is as below.

For Green Belt Development as per the layout plan, the company proposes approx. 33% green

belt of the total land, i.e. 18150 m2 the company shall develop green belt along the periphery of

the proposed site and in common premises available outside the company premises.

While selecting the plants species to be grown in the green belt zone, following points will be taken

into account:

1. Climatic condition and soil characteristics of the region.

2. The air pollution emitted by the industry – gaseous and particulate matter. Plant interaction

with both gaseous and particulate pollutants and to a great extent absorbs them and thus,

removes them from the atmosphere.

3. Characteristics of plants including shapes of crowns considered necessary for effective

absorption of pollutant gases and removal of dust particles.

4. Height of the plants should not be too high to be lethal.

5. For absorbance of gases, the duration of the foliage should be longer.

6. Vegetation controls soil erosion rates significantly. The decrease of water erosion rates with

increasing vegetation cover is exponential. This review reveals that the decrease in water

erosion rates with increasing root mass is also exponential. Plant species having good root

system are selected, so that soil erosion can be checked.

SITE PLAN WITH AREA TABLE FOR PROPOSED PLANT

S. No Particulars Area in m2

1. Production area 4212

2. Boiler 450

3. Other utilities 250

4. Solid raw material storage 5000

5. Finished product storage 2000

6. Solvent tank farm 500

7. Liquid raw material storage 816

8. ETP, MEE, incinerator & Solid waste storage 1500

9. Plantation 18150

10. Weigh bridge, parking, & Security Area 200

11. Office &Admin 500

12. Laboratory 250

13. Internal road 2000

14. Open Space 18172

15. Scrap Yard 1000

16. Total 55000

1.10.3 Site map with Green Belt Development Planning

1.10.4 Assessment of Infrastructure demand (Physical & Social)

There is no need for any infrastructure demand in terms of physical or social needs for proposed

plant.

1.10.5 Amenities/ Facilities:

GIDC notified industrial area of Sarigam has the entire available infrastructure like CETP, water,

electricity, roads, rail, transportation, availability of raw material and drainage system.

1.11 PROPOSED INFRASTRUCTURE

1.11.1 Industrial Area (Processing Area):

The proposed infrastructure to manufacture products will be built with standard engineering design

considering all the relevant parameters related to environment, health and safety.

1.11.2 Residential Area (Non Processing Area):

No residential area is involved in the proposed expansion project.

1.11.3 Green Belt

Green belt will be provided and maintained at the tune of 33% of the total land area.

1.11.4 Social Infrastructure

Not applicable

1.11.5 Connectivity (Traffic and Transportation Road/Rail/ Metro/ Water ways etc.)

The project site is very well connected by road through National Highway no. 8, western railways.

1.11.6 Drinking Water management (Source & Supply of water)

Source of water is from GIDC water supply services.

1.11.7 Sewerage System

GIDC has provided sewerage system to dispose the sewage effluent.

1.11.8 Industrial Waste Management



herewith.












Arabian Sea.





1.11.9 Solid/Hazardous Waste Management

No Type of

waste Schedule

and Category

Source Qty. MT/ Anum

Treatment Disposal

1 ETP waste Sch:I/35.3 Neutralization of effluent



Ankleshwar

2 Salt from MEE

Sch:I/37.3 Evaporation of effluent



Ankleshwar

3 Mixed spent solvent

Sch:I/29.4 From solvent stripper

65 Pack in Drums

Sell to authorized distillator

4. Distillation residue

Sch:I/29.1 Distillation process

1407 Pack in Drums

Sent for co-processing to

cement industries

5. Used Oil Sch:I/5.1 Gear box and D G set

0.05 Packed in carboys


6. Discarded containers

Sch:I/33.1 Empty containers of raw materials

20 De-contaminated,

stored

Sell to authorized recycler

7. Incineration ash

Sch:I/37.2 incinerator 140 Packed in bags

Sell to brick manufacturer

9. Used rubber hand

gloves/pipes etc

Sch:I/X-08

Production plant

2 Packed in drums/bags


10. Inorganic Acid (Hydro Chloric acid (30-32%)

Sch:I/29.6 process 18727 Tanker Sell to actual users having Rule 9

permission

11. Spent solvent Sch:I/29.4 process 3834 Storage tank Recycled in process after in-house

distillation

12. Date expired and off

specification pesticide

Sch:I/29.3 process 5.0 Packed in drums/bags


13. Contaminated cotton rags

and other cleaning materials

Sch:I/33.2 plant 1.0 Packed in drums/bags


14. Fly ash - boiler 2722 Store in silo Sell to brick manufacturer



TSDF Membership Certificate



1.11.10 Power Requirement & Supply / Source

Power requirement for proposed project will be taken from DGVCL.

1.12 REHABILITATION AND RESETTLEMENT (R&R) PLAN

1.12.1 Policy to be adopted (Central/ State) in respect of the project affected persons including home oustees, land oustees and landless labourers (a brief outline to be given)

There is no habitation on the proposed project activity area and it is barren land, so R & R policy is not applicable to this project.

There shall not be displacement of any population in project area. Any major activity that may lead

to resettlement of the people is considered as permanent impact. Hence, there is no permanent

impact on this account. The increasing industrial activity will boost the commercial and economical

status of the locality up to some extent.

1.13 PROJECT SCHEDULE & COST ESTIMATES:

1.13.1 Likely date of start of construction and likely date of completion (Time schedule for the project to be given)

After obtaining Environmental clearance and Consent to operate from GPCB, the company shall

start the proposed construction and commissioning of the project.

1.13.2 Estimated project cost along with analysis in terms of economic viability of the project

Estimated project cost along with the analysis in terms of economic viability of the project is given

as below;

Plant & Machinery, Pipeline & Fittings, Electrical Installation, Safety systems, etc. are the major

heads considered in the Capital Cost Projection for the proposed project. Environment Protection

has also been considered in planning the Cost Projection, which will include Green belt

development, safety systems, etc.

CAPITAL COST PROJECTION

S. No. Particulars Cost in Lakhs

1. Land 1800.00

2. Building 4000.00

3. Plant & Machinery 4000.00

4. Green belt Devlopment , rain water harvesting and safety/fire hydrant system

300.00

5. Environmental Management System 600.00

Total Project Cost 10700.00

UTILITIES AND FUEL REQUIREMENT

S. No.

Particulars Total

Utilities

1. Steam Boiler, TPH 25.0

2. D.G. Set (Standby), kVA 1000

3. Power from DGVCL, kVA 3000

4. Cooling tower, TR 500

5. Chilling plant, TR 300



PROJECT VIABILITY

S. No. Particulars Amount (Lakhs/Annum)

1. Proposed Sale 178000.00

2. Raw Material Cost 115700.00

3. Power & Fuel 12069.00

4. Labor Cost 5340.00

5. Environmental Management System 9027.00

6. Maintenance Cost 3560.00

7. Selling, packing & Office Expenses 12104.00

8. Proposed Profit 20200.00

The company will provide budgetary provision for the recurring expenses for environmental issues

while planning the allocation of funds during the annual budgetary planning.

RECURRING/OPERATING COST PER ANNUM

S. No. Component Proposed

(Lakhs/annum)

1. Water Environment 8499.0

2. Air Environment 60.0

3. Hazardous waste 412.0

4. Safety and Health 50.0

5. Greenbelt Maintenance 6.0

Total 9027.0

1.14 ANALYSIS OF PROPOSAL (FINAL RECOMMENDATIONS):

1.14.1 Financial and social benefits with special emphasis on the befit to the local people including tribal population, if any, in the area

Proposed project activity will provide benefits to the local people in terms of financial and social

welfare.

Local people will get direct financial benefit by way of employment.

Local people will get some contracts of supply and services to get indirect income.

Company will contribute in improving education and health facilities in nearby area.

Incinerator, kg/h 350

MEE, kg/h 5000

Fuel

1. Coal for Steam Boiler ,kg/h 3500

2. Fuel (HSD) for D. G. Set (1000 kVA), kg/h 150

3. Natural gas for incinerator, SCM/h 140



ANNEXURES



ANNEXURE: 1 LOCATION MAP SHOWING THE PROJECT SITE AND INTER-STATE BOUNDARY WITHIN 5 KMS RADIUS

The map showing general location, specific location and project boundary and project site layout of

M/s Heranba Industries Limited, located at Plot No. 2817/1, GIDC Sarigam-396155, District-

Valsad (Gujarat). The location of the project site and topography map is shown below:



ANNEXURE: 2 PLANT LAYOUT



ANNEXURE: 3 MANUFACTURING PROCESS

The company is using the latest available process technology for the production. This chapter

includes the manufacturing process of the product, chemical reactions, and material mass

balance & mole balance for the product.

(1) DIAFENTHIURON

Manufacturing Process

Charge xylene and 2,6-diisopropyl-4-phenoxy phenylthiourea. Rise to reflux and maintain

for 6 hours. Distil out xylene under reduced pressure to obtain 2,6-isopropyl-4-phenoxy

phenylthioisocyanate.

Charge isopropanol and 2,6-isopropyl-4-phenoxy phenylthioisocyanate. Rise to 50oC and

add tert-butylamine for 2 hours. Rise to 65oC and maintain for 4 hours. Cool the mass to

10oC and filter the slurry. Dry the wet cake to obtain Diafenthiuron Technical. Distil out the

filtrate to recover isopropanol for recycling the solvent.

Chemical Reactions

NH

S

H2N

O

2,6-diisopropyl-4-phenoxyphenyl thiourea

C19H24N2OS

328.47

N

S

Oxylene

1,3-diisopropyl-2-isothiocyanato-5-phenoxybenzene

C19H21NOS311.44

N

S

O

1,3-diisopropyl-2-isothiocyanato-5-phenoxybenzene

C19H21NOS

311.44

NH2

tert-butylamine

C4H11N73.14

+

NH

S

O

HN

DIAFENTHIURON

C23H32N2OS384.58

isopropanol



Material Balance

(2) PROFENOFOS


Charge monochlorobenzene and 2-chlorophenol. Cool to 0oC and add bromine slowly for

6 hours. Rise to 30oC and maintain for 2 hours. Add water and separate the aqueous

phase. Add O,O-diethyl phosphoro chloridothioate (DEPCT) slowly for 2 hours. Rise to

75oC and maintain at 75oC for 3 hours. Add water and separate the aqueous phase.

Charge organic phase and trimethylamine. Cool to 10oC. Add n-propyl bromide for 3

hours and maintain for 2 hours. Rise to 50oC and maintain for 5 hours. Cool water and

separate the aqueous phase. Distil out the organic phase to recover solvent

monochlorobenzene under reduced pressure to obtain Profenofos Technial.



Chemical Reactions

PROFENOFOS

OH

Cl

PO

OO

SCl

Br

PO

OO

SCl

Br

PCl

OO

2-chlorophenol

OH

Cl

Br

4-bromo-2-chlorophenol

Br2+

Bromine

S

O,O-diethyl phosphorochloridothioate

O-4-bromo-2-chlorophenylO,O-diethyl phosphorothioate

PO

OO

SCl

Br

O-4-bromo-2-chlorophenylO,O-diethyl phosphorothioate

+ Br

n-propyl bromide

Material Balance



(3) LAMBDA-CYHALOTHRIN


Charge lambda-cyhalothric acid and catalyst N,N-dimethyl formamide. Cool to 20oC and

add thionyl chloride for 4 hours. Scrub liberated hydrogen chloride and sulfur dioxide

gases. Rise to 50oC in 3 hours and maintain for 2 hours. This is lambda-cyhaloric acid

chloride.

Charge n-hexane, water and sodium cyanide. Add lambda-cyhalothric acid chloride and

then 3-phenoxy benzaldehyde at 20oC. Rise to 40oC and maintain for 6 hours. Cool to

10oC and separate the phases. Wash with water and recover n-hexane under reduced

pressure. Cool the mass to 5oC. Charge isopropyl alcohol and di isopropylamine.

Maintain at 5oC for 16 hours, and then -5oC for 12 hours. Charge water and separate the

phases. Charge acetic acid aqueous solution and separate the phases. Rise the

temperature to recover isopropanol under reduced pressure and to obtain Lambda-

cyhalothrin technical.

Chemical Reactions

O

OH

F3C

Cl

O

Cl

F3C

Cl

Lambda cyhalothrin acidLambda cyhalothin acid chloride

+ S

O

Cl

C l

thionyl chloride

Cl2OS118.97

C9H10ClF3O2

242.62 C9H9Cl2F3O261.07

O

Cl

F3C

Cl

Lambda cyhalothin acid chloride

C9H9Cl2F3O261.07

O

O


C13H10O2

198.22

+O

O

F3C

Cl

O

CN

Lambda-cyhalothrinC23H19ClF3NO3

449.85

NaCN



Material Balance

(4) BIFENTHRIN


Charge lambda-cyhalothrin acid and catalyst N,N-dimethyl formamide. Cool to 20oC and

add thionyl chloride for 4 hours. Scrub liberated hydrogen chloride and sulfur dioxide

gases. Rise to 50oC in 3 hours and maintain for 2 hours. This is lambda-cyhalothrin acid

chloride.

Charge n-hexanee and bifenthrin alcohol. Rise to 40oC and add lambda-cyhalothin acid

chloride for 5 hours. Add water and separate the phases. Rise the temperature to recover

toluene under reduced pressure and to obtain Bifenthrin Technical.



Chemical Reactions

O

OH

F3C

Cl

O

Cl

F3C

Cl

Lambda cyhalothrin acidLambda cyhalothin acid chloride

+ S

O

Cl

C l

thionyl chloride

Cl2OS118.97

C9H10ClF3O2

242.62 C9H9Cl2F3O261.07

O

Cl

F3C

Cl

Lambda cyhalothin acid chloride

C9H9Cl2F3O261.07

+

O

O

F3C

ClHO

(2-methylbiphenyl-3-yl)methanolBifenthrin alcohol

C14H14O198.26

BifenthrinC23H22ClF3O2

422.87

Material Balance



(5) CYPHENOTHRIN


Charge toluene, 2,2-dimethyl-3-(3-methylprop-1-enyl)cyclopropanecarboxylic acid (2,2-

DMMPCPCA) and catalyst N,N-dimethyl formamide. Cool to 20oC and add thionyl

chloride for 4 hours. Scrub liberated hydrogen chloride and sulfur dioxide gases. Rise to

50oC in 3 hours and maintain for 2 hours. This is 2,2-DMMPCPCA chloride.

Charge toluene, water and sodium cyanide. Add 2,2-DMMPCPCA chloride and then 3-

phenoxy benzaldehyde at 20oC. Rise to 40oC and maintain for 6 hours. Cool to 10oC and

separate the phases. Wash with water and recover toluene under reduced pressure. Cool

the mass to 5oC. Charge isopropyl alcohol and di isopropylamine. Maintain at 5oC for 16

hours, and then -5oC for 12 hours. Charge water and separate the phases. Rise the

temperature to recover isopropanol under reduced pressure and to obtain Cyphenothrin

technical.

Chemical Reactions

O

O

N

CYPHENOTHRIN

C24H25NO3

375.46

O

O

OH

2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylic acid

C10H16O2

168.23

O

Cl

2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarbonyl chloride

C10H15ClO186.68

O

Cl

2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane

carbonyl chlorideC10H15ClO

186.68

OO


C13H10O2

198.22

+ NaCN

S

O

Cl

Cl

thionyl chloride

Cl2OS

118.97

+

toluene



Material Balance



(6) FENPROPATHRIN


Charge 2,2,3,3-tetramethylcyclopropyl carboxylic acid (2,2,3,3-TMCPCA) and catalyst

N,N-dimethyl formamide. Cool to 20oC and add thionyl chloride for 4 hours. Scrub

liberated hydrogen chloride and sulfur dioxide gases. Rise to 50oC in 3 hours and

maintain for 2 hours. This is 2,2,3,3,-tetramethylcyclopropyl carboxylic acid chloride.

Charge n-hexane, water and sodium cyanide. Add 2,2,3,3-tetramethyl cyclopropyl

carboxylic acid chloride and then 3-phenoxy benzaldehyde at 20oC. Rise to 40oC and

maintain for 6 hours. Cool to 10oC and separate the phases. Wash with water and

recover n-hexane under reduced pressure. Cool the mass to 5oC. Charge isopropyl

alcohol and di isopropylamine. Maintain at 5oC for 16 hours, and then -5oC for 12 hours.

Charge water and separate the phases. Rise the temperature to recover isopropanol

under reduced pressure and to obtain Fenpropathrin technical.

Chemical Reactions

O O

O

N

FENPROPATHRINC22H23NO3

349.42

O OH

2,2,3,3-tetramethylcyclopropanecarboxylic acid

C8H14O2

142.20

S

O

Cl

Cl

thionyl chloride

Cl2OS118.97

+

O Cl

2,2,3,3-tetramethylcyclopropane

carbonyl chloride

C8H13ClO

160.64

O Cl

2,2,3,3-tetramethylcyclopropane

carbonyl chloride

C8H13ClO160.64

O


C13H10O2

198.22

+ NaCN

O

toluene



Material Balance

(7) ZETA-CYPERMETHRIN


Charge toluene, 3-(2,2-dichlorovinyl-2,2-dimethylcyclopropanecarboxylic acid (CMA) and

catalyst N,N-dimethyl formamide. Cool to 20-25oC and add thionyl chloride for 2 hours.

Scrub liberated hydrogen chloride and sulfur dioxide gases. Rise to 50oC in 3 hours and

maintain for 2 hours. This is CMA chloride.

Charge toluene, water and sodium cyanide. Add CMA chloride and then 3-phenoxy

benzaldehyde at 20oC. Rise to 40oC and maintain for 6 hours. Cool to 10oC and separate

the phases. Wash with water and recover toluene under reduced pressure. Cool the

mass to 5oC. Charge isopropyl alcohol and di isopropylamine. Maintain at 0oC for 12

hours, and then -15oC for 12 hours. Charge water and separate the phases. Rise the

temperature to recover isopropanol under reduced pressure and to obtain Zeta-

cypermethrin technical.



Chemical Reactions

O

O

Cl

Cl

O

N

ZETA-CYPERMETHRIN

C22H19Cl2NO3

416.30

O

OH

Cl

Cl

3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid

C8H10Cl2O2

209.07

O

Cl

Cl

Cl

3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarbonyl chloride

C8H9Cl3O

227.52

S

O

Cl

Cl

thionyl chloride

Cl2OS

118.97

+

toluene

O

Cl

Cl

Cl


C8H9Cl3O

227.52

O

O

3-phenoxybenzaldehyde

C13H10O2

198.22

+

toluene

Material Balance



(8) TRANSFLUTHRIN


Charge toluene, 3-(2,2,-dichlorovinyl)-2,2,-dimethyl cyclopropyl carboxylic acid (CMA) and

catalyst N,N-dimethyl formamide. Cool to 20oC and add thionyl chloride for 4 hours.

Scrub liberated hydrogen chloride and sulfur dioxide gases. Rise to 40oC in 3 hours and

maintain for 2 hours. This is CMA chloride.

Charge toluene and (2,3,5,6-tetrafluoro phenyl)methanol (TFPM). Rise to 40oC and add

CMA chloride for 5 hours. Add water and separate the phases. Rise the temperature to

recover toluene under reduced pressure and to obtain Transfluthrin Technical.

Chemical Reactions

O

O

Cl

ClF

F

F

F

TRANSFLUTHRIN

C15H12Cl2F4O2

371.15

O

OH

Cl

Cl

HO F

F

F

F

3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid

C8H10Cl2O2

209.07

O

Cl

Cl

Cl


C8H9Cl3O227.52

S

O

Cl

Cl

thionyl chloride

Cl2OS118.97

+

toluene

O

Cl

Cl

Cl


C8H9Cl3O227.52

+

(2,3,5,6-tetrafluorophenyl)methanol

C7H4F4O

180.10

toluene



Material Balance

(9) PYMETROZINE


Charge ethyl acetate and hydrazine hydrate in dichloroethane. Reflux for 6 hours and cool

to 30oC. Separate the aqueous phase and organic phase at 30oC. The organic phase

contains acetohydrazide in dichloroethane.

Charge triphosgene to the organic phase and reflux for 6 hours. Cool to 30oC.

Charge potassium carbonate to the mass. Rise to 50oC and add chloroacetone at 50oC

and maintain for 3 hours. Cool to 30oC and charge water. Separate the organic phase

and distil out to recover solvent dichloroethane and to obtain 5-methyl-3-(2-oxopropyl)-

1,3,4-oxadiazol-2-(3H)-one.

Charge 5-methyl-3-(2-oxopropyl)-1,3,4-oxadiazol-2-(3H)-one and methanol. Add

hydrazine hydrate and maintain for 6 hours at 65oC. Cool and add hydrochloric acid and

nicotinaldehyde. Maintain at 60oC for 3 hours and cool to 0oC. Filter the slurry and dry to

obtain Pymetrozine Technical.



Chemical Reactions

O

O

methyl acetate

H2N

NH2H

O

H

hydrazine hydrate

+

O

NH

H2N

acetohydrazide

N NH

OO

O

Cl

N NH

OO

5-methyl-1,3,4-oxadiazol-2(3H )-one

N N

OO

O

5-methyl-3-(2-oxopropyl)-1,3,4-oxadiazol-2(3H )-one

H2N

NH2

H

O

H

N

NH

N

NH2

O

4-amino-6-methyl-4,5-dihydro-1,2,4-triazin-3(2H )-one

N

NH

N

NH2

O

4-amino-6-methyl-4,5-dihydro-1,2,4-triazin-3(2H )-one

N

NH

N

O

N

N

PYMETROZINE

N

O

nicotinaldehyde

+HCl

5-methyl-1,3,4-oxadiazol-2(3H )-one

chloroacetone

Material Balance



(10) NITENPYRAM


Charge toluene and 2-chloro-5-(chloromethyl) pyridine (CCMP). Cool to 0oC and add

ethylamine solution slowly for 4 hours. Maintain for 4 hours at 0oC. Rise to 25oC and

maintain for 4 hours at 25oC. Add water, settle and separate the organic phase.

Charge organic phase and cool to 10oC. Add N-methyl-1-(methylthio)-2-nitroethenamine

(MMTNEA) for 2 hours at 10oC and maintain for 2 hours. Rise to 40oC and maintain for 3

hours. Add water and stir for 1 hour. Settle and separate the organic phase. Cool the

organic phase to 0oC and filter the slurry and dry the wet cake to obtain Nitenpyram

technical.

Chemical Reactions

NCl

NH

N-((6-chloropyridin-3-yl)methyl)ethanamine

C8H11ClN2

170.64

NCl

Cl

2-chloro-5-(chloromethyl)pyridine

C6H5Cl2N

162.02

NH2

ethylamine

C2H7N

45.08

+

toluene

NCl

NH

N-((6-chloropyridin-3-yl)methyl)ethanamine

C8H11ClN2

170.64

NCl

N

HN

NO2

NITENPYRAM

C11H15ClN4O2

270.72

+ HN

NO2

Stoluene

N-methyl-1-(methylthio)-2-nitroethenamine

C4H8N2O2S148.18

Chemical Formula: C4H8N2O2S

Molecular Weight: 148.18



Material Balance

(11) ACETAMIPRID


Charge toluene and 2-chloro-5-(chloromethyl)pyridine. Cool the mass to 0oC and pass

methylamine slowly for 6 hours. Maintain the mass at 0oC for 2 hours and rise to 20oC.

Maintain at 20oC for 3 hours and add water. Stir for 1 hour and separate the organic

phase.

Charge organic phase and apply vacuum to distil off toluene. After completion of the

distillation cool the mass to 60oC and charge ethyl N-cyanoacetimidate for 1 hour.

Maintain at 60oC for 4 hours. Cool the mass to 0oC and filter the slurry. Dry the wet cake

to obtain Acetamiprid Technical.



Chemical Reactions

O

N N

Ethyl N-cyanoacetimidate

C5H8N2O

Mol. Wt. 112.13

HN

N

Cl

N-[(6-Chloropyridin-3-yl)methyl]methylamine

C7H9ClN2

Mol. Wt. 156.61

N

Cl

Cl

2-chloro-5-(chloromethyl)pyridine

C6H5Cl2N

Mol. Wt. 162.02

N

N

N

N

Cl

C10H11ClN4

Mol. Wt. 222.67

ACETAMIPRID

H2N

Methylamine

CH5N

Mol. Wt. 31.06

+

HN

N

Cl

N-[(6-Chloropyridin-3-yl)methyl]methylamine

C7H9ClN2

Mol. Wt. 156.61

+

Toluene

0oC

Methanol

60oC

Material Balance



(12) DIFENACONAZOLE


Charge dichloroethane, 1-(2-chloro-4-(4-chlorophenoxy)phenyl)ethanone (CCPPE) and

1,2-propanediol. Rise to reflux and remove water azeotropically. After completion removal

of water, cool the mass to 50oC and add bromine slowly for 3 hours. Maintain for 2 hours

and pass chlorine at 50oC for 3 hours. Maintain for 2 hours at 50oC and add water. Stir for

1 hour and settle the mass. Separate the organic phase (A).

Charge dichloroethane, 1,2,4-triazole and sodium hydroxide flakes. Rise to reflux and

remove water azeotropically. After completion of the water removal cool to 50oC and add

the organic phase (A) at 50oC for 2 hours. Rise to 75oC and maintain for 3 hours. Cool to

40oC and add water. Stir for 1 hour and settle. Separate the organic phase and cool to

0oC. Stir for 1 hour at 0oC and filter the slurry. Dry the wet cake to obtain Difenaconazole

technical.

Chemical Reactions

NN

N

OO

O

Cl

Cl

DIFENOCONAZOLE

C19H17Cl2N3O3

406.26

O

Cl

Cl OO

O

Cl

ClO

1-(2-chloro-4-(4-chlorophenoxy)phenyl)ethanone

C14H10Cl2O2

281.13

2-(2-chloro-4-(4-chlorophenoxy)phenyl)-2,4-dimethyl-1,3-dioxolane

C17H16Cl2O3

339.21

OHHO

1,2-propanediol

C3H8O2

76.09

DCE

OO

O

Cl

Cl

2-(2-chloro-4-(4-chlorophenoxy)phenyl)-2,4-dimethyl-1,3-dioxolane

C17H16Cl2O3

339.21

OO

O

Cl

Cl

Br Br

bromine

Br2

159.81

+

DCE

Br

2-(bromomethyl)-2-(2-chloro-4-(4-chlorophenoxy)phenyl)-4-methyl-1,3-dioxolane

C17H15BrCl2O3

418.11

OO

O

Cl

Cl

Br

2-(bromomethyl)-2-(2-chloro-4-(4-chlorophenoxy)phenyl)-4-methyl-1,3-dioxolane

C17H15BrCl2O3

418.11

NH

NN

1,2,4-triazole

C2H3N3

69.07

+

NaOH

Chlorine



Material Balance

(13) HEXACONAZOLE


Charge toluene, 1-(2,4-dichlorophenyl)pentan-1-one (2,4-DCPP) and dimethyl sulphide.

Cool to 15oC and add sodium hydroxide portion-wise for 4 hours. Maintain for 2 hours at

15oC and rise to 40oC. Maintain at 40oC for 3 hours and cool to 5oC. Add water and stir

for 1 hour. Settle the mass and separate the organic phase (A).

Charge toluene, 1,2,4-triazole and sodium hydroxide flakes. Rise to reflux and reflux for 1

hour. Cool to 50oC and add the organic phase (A) at 50oC for 2 hours. Rise to 75oC and

maintain for 3 hours. Cool to 40oC and add water. Stir for 1 hour and settle. Separate the

organic phase and cool to 0oC. Stir for 1 hour at 0oC and filter the slurry. Dry the wet cake

to obtain Hexaconazole technical.



Chemical Reactions

+

+

HO

N

NN

Cl

Cl

HEXACONAZOLE2-(2,4-dichlorophenyl)-1-

(1H-1,2,4-triazol-1-yl)hexan-2-ol

C14H17Cl2N3O

314.21

O

Cl

Cl

1-(2,4-dichlorophenyl)pentan-1-one

C11H12Cl2O

231.12

Cl

Cl O

2-butyl-2-(2,4-dichlorophenyl)oxirane

C12H14Cl2O245.14

S

dimethyl sulfide

C2H6S

62.13

Cl

Cl O

2-butyl-2-(2,4-dichlorophenyl)oxirane

C12H14Cl2O245.14

NH

N N

1,2,4-triazole

Toluene

NaOH

Toluene

NaOH

C2H3N3

69.07

Material Balance



(14) PROPICONAZOLE


Charge dichloroethane, 1-(2,4-dichlorophenyl)ethanone, (2,4-DICAP) and 1,2-pentanediol.

Rise to reflux and remove water azeotropically. After completion removal of water, cool the

mass to 50oC and add bromine slowly for 3 hours. Maintain for 2 hours and pass chlorine

at 50oC for 3 hours. Maintain for 2 hours at 50oC and add water. Stir for 1 hour and settle

the mass. Separate the organic phase (A).

Charge dichloroethane, 1,2,4-triazole and sodium hydroxide flakes. Rise to reflux and

remove water azeotropically. After completion of the water removal cool to 50oC and add

the organic phase (A) at 50oC for 2 hours. Rise to 75oC and maintain for 3 hours. Cool to

40oC and add water. Stir for 1 hour and settle. Separate the organic phase and distil out

to recover solvent under reduced pressure and to obtain Propiconazole technical.

Chemical Reactions

+

DCECl

Cl

Cl

Cl

O

1-(2,4-dichlorophenyl)ethanoneC8H6Cl2O

189.04

HO

OH

1,2-pentanediolC5H12O2

104.15

OO

2-(2,4-dichlorophenyl)-2-methyl-4-propyl-1,3-dioxolane

C13H16Cl2O2

275.17

Cl

Cl

OO

2-(2,4-dichlorophenyl)-2-methyl-

4-propyl-1,3-dioxolaneC13H16Cl2O2

275.17

Cl

Cl

OOBr

2-bromomethyl-2-(2,4-dichlorophenyl)-

4-propyl-1,3-dioxolane

C13H15BrCl2O2

354.07

Br Br

bromine

Br2159.81

+DCE

Cl

Cl

OO

Cl

Cl

OO

NH

NN

1,2,4-triazole

C2H3N3

69.07

+

NaOH NBr

2-bromomethyl-2-(2,4-dichloro

phenyl)-4-propyl-1,3-dioxolaneC13H15BrCl2O2

354.07

N

N

PROPICONAZOLEC15H17Cl2N3O2

342.22

Chlorine

DCE



Material Balance

(15) TEBUCONAZOLE


Charge dichloroethane, 1-(4-chlorophenyl)-4,4-dimethyl-3-pentanone (CPDMP) and

dimethyl sulphide. Cool to 15oC and add sodium hydroxide portion-wise for 4 hours.

Maintain for 2 hours at 15oC and rise to 40oC. Maintain at 40oC for 3 hours and cool to

5oC. Add water and stir for 1 hour Settle the mass and separate the organic phase (A).

Charge dichloroethane, 1,2,4-triazole and sodium hydroxide flakes. Rise to reflux and and

reflux for 1 hour. Cool to 50oC and add the organic phase (A) at 50oC for 2 hours. Rise to

75oC and maintain for 3 hours. Cool to 40oC and add water. Stir for 1 hour and settle.

Separate the organic phase and cool to 0oC. Stir for 1 hour at 0oC and filter the slurry. Dry

the wet cake to obtain Tebuconazole technical.



Chemical Reactions

OHN

NN

Cl

TEBUCONAZOLE

C16H22ClN3O

307.82

S

dimethyl sulfide

C2H6S

62.13

+

DCE

O Cl

2-(4-chlorophenethyl)-2-tert-butyloxirane

C14H19ClO

238.75

ClO

O Cl

2-(4-chlorophenethyl)-2-tert-butyloxirane

C14H19ClO238.75

NH

NN

1,2,4-triazole

C2H3N3

69.07

NaOH+

NaOH

DCE

1-(4-chlorophenyl)-4,4-dimethylpentan-3-one

C13H17ClO224.73

Material Balance



(16) CYPROCONAZOLE


Charge dichloroethane, 1-(4-chlorophenyl)-2-cyclopropyl-propan-1-one (CPCPP) and

dimethyl sulphide. Cool to 15oC and add sodium hydroxide portion-wise for 4 hours.

Maintain for 2 hours at 15oC and rise to 40oC. Maintain at 40oC for 3 hours and cool to

5oC. Add water and stir for 1 hour Settle the mass and separate the organic phase (A).

Charge dichloroethane, 1,2,4-triazole and sodium hydroxide flakes. Rise to reflux and and

reflux for 1 hour. Cool to 50oC and add the organic phase (A) at 50oC for 2 hours. Rise to

75oC and maintain for 3 hours. Cool to 40oC and add water. Stir for 1 hour and settle.

Separate the organic phase and cool to 0oC. Stir for 1 hour at 0oC and filter the slurry. Dry

the wet cake to obtain Cyproconazole technical.

Chemical Reactions

S

dimethyl sulfide

C2H6S

62.13

DCE

NH

NN

1,2,4-triazoleC2H3N3

69.07

NaOH

NN

NHO

Cl

CYPROCONAZOLE

C15H18ClN3O

291.78

O

Cl

1-(4-chlorophenyl)-2-cyclopropyl-propan-1-one

C12H13ClO

208.68

O

Cl

2-(4-chlorophenyl)-2-(1-cyclopropylethyl)oxirane

C13H15ClO

222.71

+

O

Cl

2-(4-chlorophenyl)-2-(1-cyclopropylethyl)oxirane

C13H15ClO

222.71

+

NaOH

DCE



Material Balance

(17) EPOXICONAZOLE


Charge toluene and 1-(3-bromo-2-(4-fluorophenyl)prop-1-enyl)-2-chlorobenzene

(BFPPCB). Rise to 40oC and add 3-chlorobenzoperoxoic acid (3-CBPA) in 2 hours. Rise

to 60oC and maintain for 4 hours. Add water and stir for 1 hour at 60oC. Settle and

separate the organic phase.

Charge toluene, 1,2,4-triazole and sodium hydroxide flakes. Rise to reflux and remove

water azeotropically. After complete removal of water add the organic phase at 75oC for 3

hours. Rise to 90oC and maintain for 2 hours. Cool to 50oC and add water. Stir for 1 hour

and settle. Separate the organic phase and cool to 10oC. Stir for 1 hour at 10oC and filter

the slurry. Dry the wet cake to obtain Epoxiconazole technical.



Chemical Reactions

F

Br

Cl

(Z)-1-(3-bromo-2-(4-fluorophenyl)prop-1-enyl)-2-

chlorobenzene

C15H11BrClF325.60

ClO

O

HO

3-chlorobenzoperoxoic acid

C7H5ClO3

172.57

+

F

Br

ClO

2-(bromomethyl)-3-(2-chlorophenyl)-2-(4-fluorophenyl)oxirane

C15H11BrClFO341.60

F

Br

ClO

2-(bromomethyl)-3-(2-chlorophenyl)-2-(4-fluorophenyl)oxirane

C15H11BrClFO341.60

NH

NN

1,2,4-triazole

C2H3N3

69.07

+

F

N

ClO

NNNaOH

toluene

toluene

EPOXICONAZOLE

C17H13ClFN3O329.76

Material Balance



(18) METALAXYL


Charge n-hexane, 2,6-dimethylaniline and sodium carbonate. Rise to 55oC and add

methyl 2-chloropropionate for 2 hours. Rise to 100oC and maintain for 6 hours. Cool the

mass to 20oC and add water. Stir for 1 hour and separate the phases.

Charge organic phase and cool to 0oC. Add methoxy acetyl chloride for 6 hours. Rise to

30oC and maintain for 3 hours. Charge water and stir for 1 hour at 30oC. Cool to 10oC

and filter the slurry mass. Dry the wet product to obtain Metalaxyl technical.

Chemical Reactions

NH2

2,6-dimethylaniline

C8H11N

Mol. Wt: 121.18

O

O

Cl

methyl 2-chloropropionate

C4H7ClO2

Mol. Wt: 122.55

N

OO

O

O

METALAXYL

C15H21NO4

Mol. Wt: 279.33

NH

OO

methyl 2-(2,6-dimethylphenylamino)propanoate

C12H17NO2

Mol. Wt: 207.27

O

Cl

O

2-methoxyacetyl chloride

C3H5ClO2

Mol. Wt: 108.52

Na2CO3

n-hexane



Material Balance

(19) THIOPHANATE METHYL


Charge dichloroethane and sodium thiocyanate. Rise to 40oC and add methyl

chloroformate slowly for 2 hours. Maintain the reaction at 40oC for 4 hours. Add 1,2-

diamino benzene for 4 hours and maintain for 2 hours. Cool to 10oC and filter the mass.

Wash with water and dry the wet product to obtain Thiophanate methyl technical.

NH2H2N

1,2-diaminobenzene

C6H8N2

M. Wt. 108.14

NaSCN

DCE / DMA

O

OCl

methylchloroformate

C2H3ClO2

M. Wt: 94.50

O

OSN

cyanic (methyl carbonic) thioanhydride

C3H3NO2S

M. Wt: 117.13

NH

S

NH

O

O

HN

S

HN

O

O

THIOPHANATE METHYL

C12H14N4O4S2

M. Wt. 342.39



Material Balance

(20) AZOXYSTROBIN


Charge toluene and methyl 2-(2-hydroxyphenyl)-3-methoxyacrylate (MHPMA). Charge

potassium hydroxide portion-wise at 30oC for 2 hours. Rise to reflux and remove water

azeotropically. Cool to 50oC and add 4,6-dichloropyrimidine (4,6-DCP) for 2 hours and

maintain for 4 hours. Cool to 30oC and add water. Stir for 1 hour and separate the organic

phase, say Mass-A.

Charge toluene, 2-hydroxy benzonitrile and sodium hydroxide. Rise to 60oC and reflux for

2 hours. Cool to 60oC and add Mass-1 slowly at 60oC for 2 hours. Maintain for 6 hours at

60oC and cool to 40oC. Add water and separate the organic phase. Cool the organic

phase to 0oC. Filter the slurry at 0oC and dry to obtain Azoxystrobin technical.



Chemical Reactions

O

O

O

O

NN

Cl

methyl-2-[2-(6-chloropyrimidin-4-yl)oxyphenyl]-3-methoxy prop-2-enoate

(MCPOMP)C15H13ClN2O4

320.73

O

OO

HO

methyl 2-(2-hydroxyphenyl)-3-methoxyacrylate (MHPMA)

C11H12O4

208.21

NN

Cl Cl

4,6-dichloropyrimidine

C4H2Cl2N2

148.98

OH

CN

2-hydroxybenzonitrile

C7H5NO

119.12

+

O

O

O

O

NN

Cl

methyl-2-[2-(6-chloropyrimidin-4-yl)oxyphenyl]-3-methoxy prop-2-enoate (MCPOMP)

C15H13ClN2O4

320.73

O

O

O

O

NN

O

CN

(Z)-methyl 2-(2-(6-(2-cyanophenoxy)pyrimidin-4-yloxy)phenyl)-3-methoxyacrylate

AZOXYSTROBIN

C22H17N3O5

403.39

+

KOH

Toluene

NaOH

Toluene

Material Balance



(21) PYRACLOSTROBIN


Charge methanol, (4-chlorophenyl)hydrazine and methyl acrylate. Maintain at 80oC for 3

hours. Cool to 30oC to obtain 1-(4-chlorophenyl)pyrazolidin-3-one. Charge sulfuric acid

and pass air at 60oC for 6 hours. Cool to 30oC to obtain 1-(4-chlorophenyl)-1H-pyrazol-3-

ol.Charge sodium hydroxide and 1-(bromomethyl)-2-nitrobenzene. Maintain at 65oC for 3

hours to obtain 1-(4-chlorophenyl)-3-(2-nitrobenzyloxy)-1H-pyrazole. Charge ammonium

chloride and maintain at 35oC for 4 hours. Distil out to recover methanol under reduced

pressure. Add toluene and water. Separate the organic phase of toluene and N-(2-((1-(4-

chlorophenyl)-1H-pyrazol-3-yloxy)methyl)phenyl)hydroxylamine.Charge organic phase and

add methyl chloroformate. Maintain at 30oC for 3 hours to obtain methyl 2-((1-(4-

chlorophenyl)-1H-pyrazol-3-yloxy)methyl) phenyl(hydroxy) carbamate.

Charged potassium carbonate and add dimethyl sulfate. Maintain at 50oC for 5 hours.

Add water and separate the organic phase. Cool the organic phase to obtain slurry. Filter

the slurry and dry to obtain Pyraclostrobin Technical.

Chemical Reactions

OO N

NH

Cl

ON

N

Cl

OH

NN

Cl

O

O2N

HN

Cl

NH2O2

Br

O2N

H2SO4

NN

Cl

O

NHHO

MeOH

NH4Cl

NN

Cl

O

NHO

OO

Toluene

OO

Cl

NN

Cl

O

NO

OO

SO

O

O

O

K2CO3

MeOH(4-chlorophenyl)hydrazine

C6H7ClN2

142.59

1-(4-chlorophenyl)pyrazolidin-3-one

C9H9ClN2O

196.63

1-(4-chlorophenyl)-1H-pyrazol-3-ol

C9H7ClN2O

194.62

1-(bromomethyl)-2-nitrobenzene

C7H6BrNO2

216.03

MeOH/NaOH

1-(4-chlorophenyl)-3-(2-nitrobenzyloxy)-1H-pyrazole

C16H12ClN3O3

329.74

N -(2-((1-(4-chlorophenyl)-1H-pyrazol-3-yloxy)methyl)phenyl)hydroxylamine

C16H14ClN3O2

315.75

PYRACLOSTROBIN

C19H18ClN3O4

387.82

methyl 2-((1-(4-chlorophenyl)-1H-pyrazol-3-yloxy)methyl)phenyl(hydroxy)carbamate

C18H16ClN3O4

373.79



Mass Balance

(22) PICOXYSTROBIN


Charge toluene and 6-(trifluoromethyl)pyridine-2-ol (6-TFMP). Charge potassium

hydroxide portion-wise at 30oC for 2 hours. Rise to reflux and remove water

azeotropically. Cool to 50oC and add isochroman-3-one for 2 hours and maintain for 6

hours. Cool to 40oC and add water. Stir for 1 hour and separate the organic phase.

Charge organic phase, methanol and p-toluene sulfonic acid, monohydrate as catalyst (p-

TSA, MH). Rise to 65oC and maintain for 4 hours. Cool to 40oC and add methyl formate



and potassium hydroxide as catalyst. Rise to 75oC and maintain for 6 hours at 75oC. Cool

to 40oC and add water and separate the organic phase. Cool the organic phase to 0oC.

Filter the slurry at 0oC and dry to obtain Picoxystrobin technical.

Chemical Reactions

+

O

O

O

+

KOH

Toluene

Toluene

O

N

CF3

PICOXYSTROBINmethyl 3-methoxy-2-(2-((6-(trif luoromethyl)pyridin-2-

yloxy)methyl)phenyl)acrylate

C18H16F3NO4

367.32

O

O

O

N

CF3

methyl 2-(2-((6-(trifluoromethyl)pyridin-2-yloxy)methyl)

phenyl)acetate(MTFMPMPA)C16H14F3NO3

325.28

OO

methyl formate

C2H4O2

60.05

O

O

O

N

CF3

methyl 2-(2-((6-(trifluoromethyl)pyridin-2-yloxy)methyl)

phenyl)acetate(MTFMPMPA)

C16H14F3NO3

325.28

OH

methanol

CH4O32.04

O

OH

O

N

CF3

2-(2-((6-(trif luoromethyl)pyridin-2-loxy)methyl)

phenyl)acetic acid(TFMPMPAA)

C15H12F3NO3

311.26

PTSA

O

OH

O

N

CF3

2-(2-((6-(trifluoromethyl)pyridin-2-loxy)methyl)

phenyl)acetic acid(TFMPMPAA)

C15H12F3NO3

311.26

+

Toluene

OH

N

CF3

O

O

isochroman-3-one

C9H8O2

148.16

6-(trifluoromethyl)pyridin-2-ol

C6H4F3NO163.10

KOH

Material Balance

(23) TRIFLOXYSTROBIN


Charge water, potassium hydroxide and toluene. Add (E)-1-(3-

(trifluoromethyl)phenyl)ethanone oxime (3-TFMPEO)and stir for 2 hours at 30oC. Add



tetra-n-butyl ammonium bromide (TBAB). Add (E)-methyl 2-(2-(bromomethyl)phenyl)-2-

(methoxyimino)acetate (MBMPMIA) lot-wise for 2 hours. Rise to 65oC and maintain for 3

hours. Settle and separate the aqueous phase. Cool the organic phase to 0oC and filter

the slurry. Dry the wet cake to obtain Trifloxystrobin technical.

Chemical Reactions

O

O

ON

CF3

NO

TRIFLOXYSTROBIN

O

O

Br

NO

HON

CF3

(E)-methyl 2-(2-(bromomethyl)phenyl)-2-(methoxyimino)acetate

(E)-1-(3-(trifluoromethyl)phenyl)ethanone oxime

+KOH

C11H12BrNO3

286.12C9H8F3NO

203.16C20H19F3N2O4

408.37

toluene

Material Balance

(24) KRESOXIM-METHYL


Charge toluene, 2-[(2-methylphenoxy)methyl]-benzoic acid (2-MPMBA). Rise to 50oC and

add thionyl chloride for 3 hours. Rise to reflux and reflux for 4 hours. Cool to 10oC add

sodium cyanide lot-wise slowly for 3 hours. Rise to 20oC and maintain for 2 hours. Add

hydroxylamine O-methyl, hydrochloride (HAOMHC) lot-wise for 2 hours at 20oC. Rise to

30oC and add water. Maintain for 4 hours at 50oC. Separate the aqueous phase. Charge



methanol and rise to reflux slowly. Reflux and remove water azeotropically. Cool 0oC and

filter the slurry. Dry the wet cake to obtain Kresoxim-methyl technical.

Chemical Reactions

O

O

O

N

O

KRESOXIM-METHYL

O

O

2-[(2-methylphenoxy)methyl]-benzoic acid

OH

O

OCl

2-[(2-methylphenoxy)methyl]-benzoyl chloride

O

OCN

2-(o-tolyloxymethyl)benzoyl cyanide

O

HO

O

N

O

NH2

O HCl

Hydroxylamine,O-methyl-,

hydrochloride

(E )-2-(methoxyimino)-2-(2-(o-tolyloxymethyl)phenyl)acetic acid

SOCl2 NaCN

MeOH

C15H14O3

242.27C15H13ClO2

260.72C16H13NO2

251.28

CH6ClNO83.52

C17H17NO4

299.32

C18H19NO4

313.35

toluene



Material Balance

(25) THIABENDAZOLE


Charge toluene and 4-cyano thiazole. Rise to 60oC and add hydrochloric acid for 2 hours

at 60oC. Maintain at 60oC for 4 hours and cool to 40oC. Settle and separate the organic

phase. Add water to the organic phase, stir for 1 hour and separate the organic phase.

Charge organic phase and benzene-1,2-diamine (OPDA). Rise to reflux and remove

water azeotropically. After completion of water removal cool to 30oC and add water. Stir

for 1 hour and separate the organic phase. Cool the organic phase to 0oC and filter the

slurry. Dry the wet cake to obtain Thiabendazole technical.



Chemical Reactions

+Toluene N

H

N

S

N

THIABENDAZOLE4-(1H-benzo[d]imidazol-2-yl)thiazole

C10H7N3S201.25

4-cyano thiazole

C4H2N2S110.14

NCS

N

S

N

HO

O

thiazole-4-carboxylic acid

C4H3NO2S129.14

NH2

NH2

benzene-1,2-diamine

C6H8N2

108.14

S

N

HO

O

thiazole-4-carboxylic acid

C4H3NO2S129.14

+

Toluene

HCl

hydrogen chloride

ClH36.46

Material Balance

(26) BISPYRIBAC SODIUM


Charge ethylacetate, 2,6-dihydroxy benzoic acid (DHBA) and sodium bicarbonate. Add

dimethyl sulfate and maintain the reaction at 50oC for 5 hours. Cool and add water and



separate the organic phase. Distil out the organic phase to recover ethylacetate. After

recovery of ethyl acetate, cool the mass and add water to crystallize the intermediate.

Filter the mass to obtain Intermediate 1.

Charge Intermediate 1, 4,6-dimethoxy-2-(methylsulphonyl)pyrimidine (4,6-DMMSP),

potassium carbonate and toluene. Rise the temperature to reflux and remove reaction

water. Cool and add water and separate the organic phase. Distil out the organic phase

to recover toluene and cool the mass. Add water to crystallize and filter the mass to obtain

Intermediate 2.

Charge Intermediate 2, isopropanol and sodium hydroxide. Rise to reflux and reflux for 6

hours. Cool to 0oC and filter the mass. Dry the wet cake to obtain Bispyribac Sodium

Technical.

Chemical Reactions

OHO

OHHO

2,6-dihydroxy benzoic acid

C7H6O4

154.12

SO

O

O

O

dimethyl sulfate

C2H6O4S126.13

O O

OHHO

methyl 2,6-dihydroxy benzoate

C8H8O4

168.15

+EtOAc

NaHCO3

O O

OHHO

methyl 2,6-dihydroxybenzoate

C8H8O4

168.15

N

N

O

O

S

O

O

4,6-dimethoxy methylsulfonyl pyrimidine

C7H10N2O4S218.23

+

O O

OO N

NN

N O

OO

O

methyl 2,6-bis(4,6-dimethoxypyrimidin-2-yloxy)benzoate

C20H20N4O8

444.39

toluene

K2CO3

O O

OO N

NN

N O

OO

O

methyl 2,6-bis(4,6-dimethoxypyrimidin-2-yloxy)benzoate

C20H20N4O8

444.39

O ONa

OO N

NN

N O

OO

O

BISPYRIBAC SODIUMC19H17N4NaO8

452.35

NaOH

isopropanol



Mass Balance



(27) IMAZETHAPYR


Charge methanol and sodium hydroxide. Charge 2-amino-2,3-dimethyl butyramide

(ADMBA) and rise to 40oC. Charge diethyl 5-ethyl pyridine-2,3-dicarboxylate (DEEPDC)

for 2 hours and maintain at 40oC for 4 hours. Rise to reflux and reflux for 4 hours. Distil

out methanol and add water and toluene. Settle and separate the organic phase. Distil

out the organic phase to recover toluene. Take the aqueous phase and adjust pH to 2.0

with hydrochloric acid. Stir for 1 hour and filter the mass. Dry the wet product to obtain

Imazethapyr technical.

Chemical Reactions

N

O O

N

HO ONH

N

O

IMAZETHAPYR

C15H19N3O3

289.33

Methanol

NaOH

+O

O

diethyl 5-ethylpyridine-2,3-dicarboxylate

C13H17NO4

251.28

ONH2

NH2

2-amino-2,3-dimethylbutyramide

C6H14N2O130.19

Material Balance

(28) QUIZALOFOP-ETHYL




Charge toluene, hydroquinone and potassium hydroxide. Rise to reflux and remove water

azeotropically. After complete removal of water cool the mass to 60oC and add 2,6-

dichloroquinoxaline (2,6-DCQ) for 2 hours. Rise to 100oC and maintain for 4 hours.

Check the reaction completion and cool to 30oC. Charge water and adjust pH to 3 with

HCl. Stir for 1 hour, settle and separate the organic phase.

Charge organic phase and potassium hydroxide. Rise to reflux and remove water

azeotropically. After complete removal of water cool the mass to 60oC and add ethyl 2-

chloropropionate for 4 hours at 60oC. Maintain the reaction for 4 hours at 60oC and check

the conversion. After completion of the reaction cool the mass to 30oC and add water. Stir

for 1 hour, settle and separate the organic phase. Cool the organic phase to 5oC and

maintain for 1 hour at 5oC. Filter the slurry and dry the wet cake to obtain Quizalofop-ethyl

technical.

Chemical Reactions

OO

O

ON

NCl

QUIZALOFOP-ETHYL

C19H17ClN2O4

372.80

ClN

NCl

2,6-dichloroquinoxaline

C8H4Cl2N2

199.04

OH

HO

hydroquinone

C6H6O2

110.11

ON

NCl OH

C14H9ClN2O2

272.69

N

N

O

OHCl

6-chloro-2-(4'-hydroxyphenoxy)quinoxaline

C14H9ClN2O2

272.69

6-chloro-2-(4'-hydroxyphenoxy)quinoxaline

Cl

OO

ethyl 2-chloropropionate

C5H9ClO2

136.58

+

+

toluene

toluene

KOH

KOH



Material Balance

(29) FENOXAPROP ETHYL


Charge toluene, hydroquinone and potassium hydroxide. Rise to reflux and remove water

azeotropically. After complete removal of water cool the mass to 60oC and add 2,6-

dichlorobenzoxazole (2,6-DCB) for 1 hours. Rise to 80oC and maintain for 2 hours. Check

the reaction completion and cool to 30oC. Charge water and adjust pH to 3 with HCl. Stir

for 1 hour, settle and separate the organic phase.

Charge organic phase and potassium hydroxide. Rise to reflux and remove water

azeotropically. After complete removal of water cool the mass to 60oC and add ethyl 2-

chloropropionate for 4 hours at 60oC. Maintain the reaction for 4 hours at 60oC and check



the conversion. After completion of the reaction cool the mass to 30oC and add water. Stir

for 1 hour, settle and separate the organic phase. Cool the organic phase to 5oC and

maintain for 1 hour at 5oC. Filter the slurry and dry the wet cake to obtain Fenoxaprop-

ethyl technical.

Chemical Reactions

OH

HO

hydroquinone

C6H6O2

110.11

ethyl 2-chloropropionate

C5H9ClO2

136.58

+

+

toluene

toluene

KOH

2,6-dichlorobenzoxazole

C7H3Cl2NO

188.01

O

N

Cl

Cl

O

N

O

Cl

O

O

N

O

Cl

OH

4-(6-chlorobenzoxazol-2-yloxy)phenolC13H8ClNO3

261.66

O

NO

Cl

OH

4-(6-chlorobenzoxazol-2-yloxy)phenolC13H8ClNO3

261.66

O

O

FENOXAPROP-ETHYL

C18H16ClNO5

361.78

Cl

O

O

KOH



Material Balance

(30) CARFENTRAZONE-ETHYL


Charge dichloroethane and 1-(4-chloro-2-fluoro-5-nitrophenyl)-4-(difluoromethyl)-3-methyl-

1H-1,2,4-triazol-5(4H)-one (CFNPDFMMT). Add tin powder and hydrochloric acid. Rise to

65oC and maintain for 6 hours. After completion of the reaction cool the mass to 0oC. Add

sodium nitrite solution slowly at 0oC and maintain for 4 hours at 0oC. Add ethyl acrylate

slowly at 0oC for 2 hours and maintain for 3 hours. Rise to 30oC and maintain for 2 hours.

Settle the mass and separate the organic phase. Cool the organic phase to 0oC and filter

the slurry. Dry the wet cake to obtain Carfentrazone-ethyl.



Chemical Reactions

N

NN

O

F

F

F

Cl

Cl

OO

CARFENTRAZONE-ETHYL

C15H14Cl2F3N3O3

412.19

NO2

N

NN

O

F

F

F

Cl

NH2

N

NN

O

F

F

F

Cl

1-(4-chloro-2-fluoro-5-nitrophenyl)-4-(difluoromethyl)-3-methyl-1H-1,2,4-triazol-5(4H)-one

C10H6ClF3N4O3

322.63

1-(5-amino-4-chloro-2-f luorophenyl)-4-(dif luoromethyl)-3-methyl-1H-

1,2,4-triazol-5(4H)-one

C10H8ClF3N4O

292.64

Sn

HCl

NH2

N

NN

O

F

F

F

Cl

1-(5-amino-4-chloro-2-f luorophenyl)-4-(difluoromethyl)-3-methyl-1H-

1,2,4-triazol-5(4H)-one

C10H8ClF3N4O

292.64

O

O

ethyl acrylate

C5H8O2

100.12

+

Material Balance



(31) SULFENTRAZONE


Charge toluene and 1-(2,4-dichloro-5-nitrophenyl)-4-(difluoromethyl)-3-methyl-1H-1,2,4-

triazol-5(4H)-one (CFNPDFMMT). Add tin powder and hydrochloric acid. Rise to 60oC

and maintain for 4 hours. After completion of the reaction cool the mass to 30oC. Add

water, settle the mass and separate the organic phase. Add methane sulfonyl chloride

slowly at 30oC for 3 hours. Rise to 45oC and maintain for 5 hours. Cool the mass to 0oC

and filter the slurry. Dry the wet cake to obtain Sulfentrazone-ethyl.

Chemical Reactions

S

O

OHN

N

NN

O

F

F

Cl

Cl

SULFENTRAZONE

C11H10Cl2F2N4O3S

387.19

N

NN

O

F

F

Cl

Cl

NO2

1-(2,4-dichloro-5-nitrophenyl)-4-(difluoromethyl)-3-methyl-1H-1,2,4-triazol-5(4H)-one

C10H6Cl2F2N4O3

339.08

N

NN

O

F

F

Cl

Cl

NH2

1-(5-amino-2,4-dichlorophenyl)-4-(difluoromethyl)-3-methyl-1H-1,2,4-triazol-5(4H )-one

C10H8Cl2F2N4O309.10

Sn

HCl

N

NN

O

F

F

Cl

Cl

NH2

1-(5-amino-2,4-dichlorophenyl)-4-(difluoromethyl)-3-methyl-1H-1,2,4-triazol-5(4H)-one

C10H8Cl2F2N4O309.10

S

O

O

Cl

methanesulfonyl chloride

CH3ClO2S

114.55

+

toluene



Material Balance

(32) CMAC

Manufacturing Process Stage -1:- Preparation of tetra Chloro Butyro Nitrite (TBN)

Reaction of Carbon Tetra Chloride with Acrylonitrile at 100°Cto 125°C in present of cupric chloride catalyst, DEA HCI as a buffer and Acetonitrile as solvent gives Tetra Chloro Butyro Nitrile ( TBN (.Excess CTC and Acetonitrile is removed by distillation. In water wash cupric chloride DEA HCI is removed.

Stage - 2:- Preparation of tetra Chloro Butyic Acid. (TBA)

Acid hydrolysis of crude TBN using 30 % HCI solution gives tetra Chloro Butyic Acid (TBA). After reaction TBA is separated from bottom and dehydrated up to moisture contain level of 0.1 %.

Stage - 3:- Preparation of tetra Chloro Butyric Acid Chloride (TBAC)

Reaction of TBA with Thionyl Chloride in presence of Dimethyl Formamide at 60°C gives tetra Chloro Butyric Acid Chloride (TBAC), during reaction SO2 and HCI gas is evolved which is scrubbed in scrubber. Crude TBAC is further distilled under high vacuum. The purity of Distilled TBAC is 98 %.



Stage-4:- Preparation of 2 - Chloro CycIo Butanone Derivative (2 CB)

TBAC is reacted with isobutylene in presence of Tri Ethyl Amine (TEA) at 70°C under 5.0 Kg/cm2 pressure, n-Hexane is used as solvent. After reaction excess Isobutylene is recovered. The whole mass is washed with water to remove TEA. The organic mass is neutralized with Sodium bi carbonate and organic mass is transferred for further process.

Stage - 5:- Preparation of Sodium Salt of Cypermerhric Acid (Na-CMA)

2 CB is isomerised to 4 CB in presence of catalyst and then directly reacted with caustic lye solution which gives Na-CMA.

Stage - 6:- Preparation of Cypermerhric Acid (CMA)

Na- CMA is acidified with dilute Sulphuric Acid at room temperature. CMA is extracted in n-Hexane. Aqueous layer (sodium sulphate + sodium chloride + organic impurities) is drain to ETP

Stage - 7:- Preparation of Cypenmerhric Acid Chloride (CMAC)

Reaction of CMA with Thionyl Chloride in presence of Dimethyl Formamide at 60X gives Cypermethric Acid Chloride (CMAC). During reaction SO2, and HCI gas is evolved which is scrubbed in scrubber. Crude CMAC is further distilled under high vacuum. The purity of Distilled CMAC is 98 %.

Chemical Reactions

Stage - 1

Cl

CCl4 CH2 CH CN CCl3 CH2 CH CN154 53 207

CTC Acrylonitrile Tetra Chloro Butyronitrile

Stage - 2

Cl Cl

CCl3 CH2 CH CN 2H2O + HCl CCl3 CH2 CH COOH NH4Cl207 18 36.5 226

53.5

Tetra Chloro Butyronitrile Water Hydrochloric

AcidTetra Chloro Butyric Acid

Ammonium Chloride

Stage - 3

Cl Cl

CCl3 CH2 CH COOH SOCl2 CCl3 CH2 CH COCl SO2 + HCl226 119 244.5 64 36.5

Tetra Chloro Butyric Acid Thyonil Chloride Tetra Chloro Butyric Acid Chloride Sulphur Di

oxide

Hydrochlor

ic Acid

Stage - 4

Cl Cl

H3C

CCl3 CH2 CH COCl C CH2 CCl3 CH2 C C O + HCl

H3C

H3C C CH2

H3C244.5 56

26436.5

Tetra Chloro Butyric Acid Chloride Isobutylene 2 - Chloro Cyclobutanone Derivat ive Hydrochloric

Acid

Preperation of Tetra Chloro Butyronitrile TBN

Preperation of Tetra Chloro Butyric Acid

Preperation of Tetra Chloro Butyric Acid Chloride

Preperation of 2 - Chloro Cyclobutanone Derivative



Stage - 5

Cl

CCl3 CH2 C C O CCl3 CH2 CH C O

H3C C CH2 H3C C CH Cl

H3C H3C

264 264

2 - Chloro Cyclobutanone Derivat ive 4 - Chloro Cyclobutanone Derivat ive

Stage -6

CCl3 CH2 CH C O + 2 NaO H CCl3 CH2 CH CH C OONa + NaCl

C

H3C C CH Cl H3C CH3

H3C

264 80 267.5 58.5

4 - Chloro Cyclobutanone Derivat ive Sodium Hydroxide Sodium Salt of Saturated Cypermethric Acid Sodium Chloride

Stage -7

CCl3 CH2 CH CH C OONa + NaOH CCl2 CH CH CH C OONa + NaCl

C C

H3C CH3 H3C CH3

267.5 40 23158.5

Sodium Salt of Saturated Cypermethric Acid Sodium Hydroxide Sodium Salt of Cypermethric Acid Sodium Chloride

Preperation of Sodium Salt of Saturated Cypermethric Acid

Preperation of Sodium Salt of Cypermethric Acid

Preperation of 4 - Chloro Cyclobutanone Derivative

Stage - 8

CCl2 CH CH CH C OONa + 1/2 H2SO4 CCl2 CH CH CH C OOH 1/2 Na2SO4

C C

H3C CH3 H3C CH371

231 49 209Sodium Sulphate

Sodium Salt of Cypermethric AcidSulphuric Acid

Sodium Salt of Cypermethric Acid

Stage - 9

CCl2 CH CH CH C OOH + SOCl2 CCl2 CH CH CH C OCl + SO2 + HCl

C C

H3C CH3 H3C CH3

209 119 227.5 64 36.5

Sodium Salt of Cypermethric Acid Thyonil Chloride Cypermethric Acid chloride Sulphur Di oxideHydrochloric

Acid

Preperation of Cypermethric Acid

Preperation of Cypermethric Acid Chloride



Material Balance

(1) CYPERMETHRIC ACID CHLORIDE

Stage : 1TBN

Forcut : 380 Kgs, Acrylonitrile : 500 KgsCTC : 1550 KgsAcetonytrile : 22 KgsCatalyst : 10 Kgs, DEA-HCl : 11 KgsWater : 230 Kgs

Evaporation Loss : 22 KgsForcut Recovery : 380 KgsWaste Water to ETP : 328 Kgs

Stage : 2TBA

29% Ammonium chloride solution: 1753 KgsHCl 30% : 1800 Kgs

Water : 333 Kgs

Stage : 2ATBA Washing Waste water to ETP : 837 Kgs

Water : 281KgsWater from 2 CB : 610 Kgs

Stage : 3TBAC

DMF : 20 Kgs, TC: 1067 KgsWater for HCl : 763 kgsCaustic Lye 48% : 1495

Water for scrubber: 2989 Kgs

Distillation water recycle stage 2A : 286 KgsEvaporation Loss: 174 Kgs, 22.3% Na2SO3 : 5058 Kgs, 30% HCl recycle in stage 2 : 1090 KgsOrganic Residue : 68 Kgs

Stage : 42 CB

IB Recivered : 137 KgsEvaporation Loss: 300 KgsTEA + HCl + 764 C.S Lye : 1622 Kgsn-Hexane Recovery : 4840 KgsSoda wash Aq. : 610 Kgs

n-Hexane : 5140 KgsIB : 594 Kgs, TEA : 824 KgsWater for TEA HCl : 500 KgsSoda Ash : 5.0 KgsWater for Soda Ash : 505 Kgs

TEA Recovered : 824 Kgs

Aq. Mass to MEE : 1562 Kgs

Catalyst : 10 Kgs, TEA : 10 Kgsn-Hexane : 1000 Kgs

Caustic 100% : 971 KgsWater : 5141 Kgs

Stage : 5Na-CMA n-Hexane : 1405 Kgs

Sulphuric Acid : 1199 KgsWater : 514 Kgs

n-Hexane : 3000 Kgs

Stage : 6CMA

6889 (20%) Sodium Sulphate Soln. : 8519 KgsSent To MEE : 1630 Kgs

DMF : 10 Kgs, TC : 606 KgsCaustic Lye 48% : 849, Water for

Scrubber: 1697 Kgs, Water for HCl : 434 Kgs

Stage : 7CMAC

CMAC Distillation

n-Hexane Recovery : 2667 Kgs22.3% Na2SO3 Soln. : 2976 Kgs30% HCl recycle in stage 2 : 620 KgsEvaporation Loss : 333 Kgs

Organic residue : 45 Kgs

CMAC : 1000 Kgs

(33) DIETHYL THIOPHOSPHORYL CHLORIDE (DETC)


Charge xylene and phosphorous pentasulfide. Add ethanol at 50oC for 3 hours and scrub

the liberated hydrogen sulphide in caustic solution. Maintain the reaction at 90oC for 3

hours and cool to 50oC. Apply vacuum and distil out xylene till 90oC. Cool the mass to 15-

20oC and pass chlorine gas for 6 hours. Scrubb the liberated hydrogen chloride in water

to get 25-30% hydrochloric acid. Cool the mass to 10oC and add sodium carbonate

solution to neutralise. Filter the mass to obtain wet sulfur powder, aqueous phase and

organic phase. Distil out the organic phase at 90oC under reduced pressure to get DETC.



Chemical Reactions

PS

S

SP

S

S

phosphorus(V) sulf ide

P2S5

222.27

+ HOxylene

90oC

ethanol

C2H6O4 x 46.07

4 P

OO

HSS

O,O-diethylphosphorodithionic acid

2 + H2S

hydrogensulfide

H2S

34.08

C4H11O2PS2

2 x 186.23

P

OO

HSS

O,O-diethylphosphorodithionic acid

+ Cl2

chlorine

Cl22 x 70.91

15-20oCP

OO

ClS

O,O-diethylphosphorochloridothioate

C4H10ClO2PS

2 x 188.61

22 2 + 2 HCl + 2 S

2 x 36.46 2 x 32.06

C4H11O2PS2

2 x 186.23

Material Balance



(34) BIFENTHRIN ALCOHOL


Charge tetrahydrofuran, magnesium powder and 2,6-dichlorotoluene. Rise to 50oC and

add bromobenzene for 4 hours. Rise to reflux and reflux for 6 hours. Cool to 40oC and

add water and hydrochloric acid to pH 2. Distil out under reduced pressure to recover

tetrahydrofuron. Cool and separate the aqueous phase.

Charge tetrahydrofuran and magnesium powder to the organic phase. Rise to 50oC and

add N,N-dimethylformamide for 4 hours. Rise to reflux and reflux for 6 hours. Distil to

recover tetrahydrofuran under reduced pressure and add diluted sulfuric acid and toluene.

Separate the aqueous phase and cool the organic phase to 0oC. Filter the slurry and dry

to obtain Bifenthrin alcohol.

Chemical Reactions

Cl Cl

2,6-dichloro toluene

Br

bromobenzene

Cl

3-chloro-2-methylbiphenyl

+

Cl

3-chloro-2-methylbiphenyl

HO

BIFENTHRIN ALCOHOL

+ O N

N,N-dimethylformamide

Mg

Mg

C7H6Cl2161.03

C6H5Br

157.01C13H11Cl202.68

C13H11Cl202.68

C3H7NO

73.09

C14H14O

198.26

THF

THF



Material Balance

(35) LAMBDA ACID (3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-

dimethylcyclopropanecarboxylic acid)


Charge t-butanol, potassium t-butoxide and cool to -15oC. Add methyl 4,6,6-trichloro-

7,7,7-trifluoro-3,3-dimethylheptanoate (MTCTFDMH) and maintain for 8 hours. Charge

potassium hydroxide and reflux for 6 hours. Cool to 20oC and add water. Add 50%

sulfuric acid to pH 2 and separate the aqueous phase. Cool the organic phase to 0oC and

filter the slurry. Dry the wet cake to obtain Lambda acid.

Chemical Reactions



F

F

F

ClCl

Cl

O

O

methyl 4,6,6-trichloro-7,7,7-trifluoro-3,3-dimethylheptanoate

F

F

F

ClCl

O

O

methyl 3-(2,2-dichloro-3,3,3-trif luoropropyl)-2,2-

dimethylcyclopropanecarboxylate

F

F

F

ClCl

O

O

methyl 3-(2,2-dichloro-3,3,3-trif luoropropyl)-2,2-

dimethylcyclopropanecarboxylate

F

F

F

Cl

O

OH

K+O-

potassiumt-butoxide

LAMBDA ACID

Material Balance



(36) DIAFENTHIURON

Material Balance

(37) PROFENOFOS

Material Balance



38. LAMBDA-CYHALOTHRIN

(38) BIFENTHRIN



(39) CYPHENOTHRIN

(40) FENPROPATHRIN



(41) ZETA-CYPERMETHRIN

(42) TRANSFLUTHRIN



(43) PYMETROZINE

Material Balance

(44) NITENPYRAM



(45) ACETAMIPRID

(46) DIFENACONAZOLE



(47) HEXACONAZOLE

(48) PROPICONAZOLE



(49) TEBUCONAZOLE

(50) CYPROCONAZOLE



(51) EPOXICONAZOLE

(52) METALAXYL



(53) THIOPHANATE METHYL

(54) AZOXYSTROBIN



(55) PYRACLOSTROBIN

(56) PICOXYSTROBIN



(57) TRIFLOXYSTROBIN

Material Balance

(58) KRESOXIM-METHYL

Material Balance



(59) THIABENDAZOLE

(60) BISPYRIBAC SODIUM

Mass Balance



(61) IMAZETHAPYR

(62) QUIZALOFOP-ETHYL



(63) FENOXAPROP ETHYL

(64) CARFENTRAZONE-ETHYL



(65) SULFENTRAZONE

(66) CMAC

Material Balance

(1) CYPERMETHRIC ACID CHLORIDE

Stage : 1TBN

Forcut : 380 Kgs, Acrylonitrile : 500 KgsCTC : 1550 KgsAcetonytrile : 22 KgsCatalyst : 10 Kgs, DEA-HCl : 11 KgsWater : 230 Kgs

Evaporation Loss : 22 KgsForcut Recovery : 380 KgsWaste Water to ETP : 328 Kgs

Stage : 2TBA

29% Ammonium chloride solution: 1753 KgsHCl 30% : 1800 Kgs

Water : 333 Kgs

Stage : 2ATBA Washing Waste water to ETP : 837 Kgs

Water : 281KgsWater from 2 CB : 610 Kgs

Stage : 3TBAC

DMF : 20 Kgs, TC: 1067 KgsWater for HCl : 763 kgsCaustic Lye 48% : 1495

Water for scrubber: 2989 Kgs

Distillation water recycle stage 2A : 286 KgsEvaporation Loss: 174 Kgs, 22.3% Na2SO3 : 5058 Kgs, 30% HCl recycle in stage 2 : 1090 KgsOrganic Residue : 68 Kgs

Stage : 42 CB

IB Recivered : 137 KgsEvaporation Loss: 300 KgsTEA + HCl + 764 C.S Lye : 1622 Kgsn-Hexane Recovery : 4840 KgsSoda wash Aq. : 610 Kgs

n-Hexane : 5140 KgsIB : 594 Kgs, TEA : 824 KgsWater for TEA HCl : 500 KgsSoda Ash : 5.0 KgsWater for Soda Ash : 505 Kgs

TEA Recovered : 824 Kgs

Aq. Mass to MEE : 1562 Kgs

Catalyst : 10 Kgs, TEA : 10 Kgsn-Hexane : 1000 Kgs

Caustic 100% : 971 KgsWater : 5141 Kgs

Stage : 5Na-CMA n-Hexane : 1405 Kgs

Sulphuric Acid : 1199 KgsWater : 514 Kgs

n-Hexane : 3000 Kgs

Stage : 6CMA

6889 (20%) Sodium Sulphate Soln. : 8519 KgsSent To MEE : 1630 Kgs

DMF : 10 Kgs, TC : 606 KgsCaustic Lye 48% : 849, Water for

Scrubber: 1697 Kgs, Water for HCl : 434 Kgs

Stage : 7CMAC

CMAC Distillation

n-Hexane Recovery : 2667 Kgs22.3% Na2SO3 Soln. : 2976 Kgs30% HCl recycle in stage 2 : 620 KgsEvaporation Loss : 333 Kgs

Organic residue : 45 Kgs

CMAC : 1000 Kgs



(67) DIETHYL THIOPHOSPHORYL CHLORIDE (DETC)

(68) BIFENTHRIN ALCOHOL



(69) LAMBDA ACID (3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-

dimethylcyclopropanecarboxylic acid)

Material Balance



ANNEXURE: 4 WATER REQUIREMENT LETTER FROM NOTIFIED INDUSTRIAL ESTATE



ANNEXURE: 5 QUANTITY OF WASTE TO BE GENERATED (LIQUID AND SOLID) AND

SCHEME FOR THEIR MANAGEMENT/DISPOSAL

S.No. Particulars Water

consumption, m3/day

Waste water generation, m3/day

Normal Concentrated

1 Domestic 20 20 0

2 Processing and product washing 178 47 82

3 Cooling 400 40 0

4 Boiler (blow down & DM rejection) 270 25 0

5 Floor/container/equipment washing

15 15 0

6 Scrubber 45 5 0

7 Coal and fly ash wetting 10 0 0

8 Gardening 15 0 0

Total 953 152 82

Recycle from R O 68

Mode of treatment and disposal

To STP 20

A To solvent stripper followed by MEE & ATFD

82

B Cooling/boiler/scrubber/washing to RO

85

C Condensate from MEE to ETP 69.8

D RO rejection to ETP 17

E Normal effluent from process to ETP

47

Net discharge to primary secondary & tertiary ETP to CETP

(C + D + E)

133.8



herewith.












Arabian Sea.







Total Water Consumption: 953 M3/day (Fresh: 865 M3/Day + Recycle : 88 M3/Day)

Domestic: 20 Processing: 178 Cooling: 400 Washing: 15 Scrubber: 45 Gardening: 15

128.8 40 15HCl (30%): 40


RO Rejection: 17Collection tank: 82



Holding tank: 82



Concentrated: 82

Treated effluent under ground effluent drainage pipe line


Treated effluent holding tank

Primary/Secondary/Tertiary ETP


Tail scrubber: 5

Boiler: 270

D M Plant: 270

D M Rejection: 15

255 + 255 Boiler: 510

Condensate: 255 Steam: 245 Blow down: 10

Normal: : 47R O Plant: 85 RO Permeate: : 68

CETP Sarigam

STP

For Gardening/Toilet flushing/Coal/ash wetting

Coal/ash wetting: 10

Details of proposed effluent treatment plant followed by solvent stripper, multi effect evaporator and agitated thin film dryer for concentrated effluent stream. 1. Design Criteria :

Product : Pesticides

Source of Effluent : process

Flow of effluent : 82 KLD Maximum

Design Flow of Effluent : 100 KLD

Design Parameters : As under

Effluent Characteristics:

S. No

Effluent Parameter

Untreated concentrated effluent

Condensate from MEE/ATFD

1. pH 4.0-5.0 7.0-8.0

2. Color pt. Co 500-600 100-150

3. Suspended solids , mg/L

300-400 80-100

4. Total dissolved solids, mg/L

120000-150000 500-600

5. Oil and grease, mg/L

1-2 0.1-0.2

6. NH3-N, mg/L 35-40 10-15

7. BOD , mg/L 17000-20000 600-700

8. COD , mg/L 60000-65000 2000-2500

9. Heavy metal, mg/L ND ND



10. Phenolic Compounds, mg/L

0.1 ND

11. Pesticides, mg/L 0.1-1.0 ND

It can be seen that; concentrated effluent generated from process having very high COD, BOD and

TDS. Also pH of effluent is acidic. It is found that; organics in the effluent due to solvent traces and

TDS due to chlorides and sulphates in the effluent.

It is decided to treat the effluent in solvent stripper followed by MEE and ATFD. Condensate will be

taken to ETP for further treatment and disposal.

The details of proposed effluent treatment plant followed by solvent stripper, multi effect evaporator

and agitated thin film dryer for concentrated effluent stream as under;

Sr. No. Particulars Size in meters Capacity in M3

MOC

1 Oil/Grease trap 1 x 1 X 0.2 0.2 M3 MS/Epoxy

2 Collection cum pH correction tank with air

diffuser

5 x 5 x 4.0 100 M3 RCC

3 Hydrated lime dosing tank

- 1.0 M3 HDPE

4 Neutralization tank with stirrer

- 10 KL RCC/TL

5 Filter press - 48 x 48 PP

6 Solvent stripper 0.6 Ø x 4.0 ht. 100 M3/d SS 316

7 Mix solvent collection tank

- 0.5 M3 HDPE

8 MEE Calndria:I 0.6 Ø x 4.0 Ht. 100 M3/d SS 316

9 MEE Calndria:II 0.6 Ø x 4.0 Ht

10 MEE Calndria:III 0.6 Ø x 4.0 Ht

11 Agitated Thin Film Dryer (ATFD)

0.3 Ø x 2.7 ht. 15 TPD SS 316

12 Final holding tank for water from MEE

condensate & ATFD

5 x 5 x 4.0 100 M3 RCC



FLOW DIAGRAM OF EFFLUENT TREATMENT PLANT FOR CONCENTRATED EFFLUENT STREAM


Collection tank: 82



Holding tank: 82



Concentrated Effluent from process: 82


Details of proposed effluent treatment plant for normal effluent stream. 2. Design Criteria :


Source of Effluent : process, cooling, DM Plant, Boiler blow down, Floor/container washing, tail scrubber and condensate from MEE/ATFD etc.

Flow of effluent : 133.8 KLD Maximum


Design Parameters : As under Effluent Characteristics:

S. No

Effluent Parameter

normal effluent from

process

Effluent from Boiler blow down, cooling tower, tail

scrubber and floor washing

Condensate from MEE/ATFD

1. pH 4.5-5.5 6.0-7.0 7.0-8.0

2. Color pt. Co 600-800 150-200 100-150


300-400 100-150 80-100


4000-4500 2500-3000 500-600


2-3 0.1-0.5 0.1-0.2

6. NH3-N, mg/L 30-40 10-20 10-15

7. BOD , mg/L 800-900 80-100 600-700

8. COD , mg/L 3000-3500 500-600 2000-2500



9. Heavy metal, mg/L ND ND ND

10. Phenolic Compounds, mg/L

0.1 ND ND

It can be seen that; effluent generated from process having slightly high COD, BOD, TDS and

other impurities, which can be easily treated in conventional ETP. Also Effluent generated from

Boiler blow down, DM plant, cooling tower, tail scrubber and floor washing having low pollution

potential and can be recycled after RO treatment. MEE condensate having low pollution potential

and can be treated in conventional ETP.

It is decided to install following treatment scheme for normal effluent stream;

Quantity of effluent from Cooling tower, DM plant, Boiler blow down, tail scrubber and floor

washing: 85 KLD

Sr. No. Particulars Size in meters Capacity in M3

MOC

1 Oil/Grease trap 1 x 1 X 0.2 0.2 M3 MS/Epoxy

2 Collection cum pH correction tank with air

diffuser

5 x 5 x 4.0 100 M3 RCC

3 Di. Caustic dosing tank

- 0.2 M3 HDPE

4 RO plant - 4.5 KL/Hr PP/FRP/SS

5 R O permeate collection tank

- 50 M3 RCC

Washing: 15Cooling tower Blow down: 40

Collection tank of ETP

RO Rejection: 17

Tail scrubber: 5D M Rejection: 15 Boiler Blow down: 10

R O Plant: 85 RO Permeate recycle : : 68

FLOW DIAGRAM OF RIVERSE OSMOSIS PLANT FOR NORMAL EFFLUENT STREAM

Characteristics of RO Permeate

S. No Effluent Parameter RO Permeate

1. pH 7.0-7.5

2. Color pt. Co 50-60

3. Suspended solids , mg/L 10-20

4. Total dissolved solids, mg/L 150-200

5. COD, mg/L 20-30



Details of proposed effluent treatment plant for normal effluent stream. 3. Design Criteria :


Source of Effluent : process, cooling, DM Plant, Boiler blow down, Floor/container washing, tail scrubber and condensate from MEE/ATFD etc.

Flow of effluent : 133.8 KLD Maximum


Design Parameters : As under Effluent Characteristics:

S. No

Effluent Parameter

normal effluent

from process

RO Rejection Condensate from MEE/ATFD

Combined effluent from process, RO rejection and

MEE condensate

1. pH 4.5-5.5 6.0-7.0 7.0-8.0 5.0-6.0

2. Color pt. Co 600-800 200-300 100-150 600-800


300-400 300-400 80-100 300-400


4000-4500 5000-6000 500-600 4500-5000


2-3 0.1-0.5 0.1-0.2 2-3

6. NH3-N, mg/L 30-40 10-20 10-15 30-40

7. BOD , mg/L 800-900 300-500 600-700 800-900

8. COD , mg/L 3000-3500 1000-1500 2000-2500 3000-3500

9. Heavy metal, mg/L

ND ND ND ND

10. Phenolic Compounds,

mg/L

0.1 ND ND 0.1

It can be seen that; combined normal effluent having slightly high COD, BOD and other impurities. It is decided to treat entire combined effluent in proposed primary, secondary and tertiary ETP.



S.No. Name of the unit Capacity in m3 MOC

1. Oil and grease trap 1 RCC/TL

2. Collection cum equalization tank 50 RCC/TL

3. Effluent transfer pump 5 HP CI/PP

4. Neutralization tank 10 RCC/TL

5. H.lime/FeSO4 dosing tank 1.0 HDPE

6. Floculator 3 MSRL

7. P E dosing tank 0.2 HDPE

8. Primary Clarifier. 35 RCC

9. Filter press 48 plates PP

10. Bio-reactor with air diffuser 300 RCC

11. Secondary Clarifier. 35 RCC

12. Holding tank 35 RCC

13. Pressure sand bed filter 5 MSRL

14. Activated carbon filter 5 MSRL

16. Final holding tank. 150 RCC

17. Flow meter, TOC meter - -




RO Rejection: 17Condensate from MEE: 69.8

Primary Clarifier


Bio Reactor

Neutralization tank

Normal effluent from process: : 47

Secondary Clarifier

H. Lime/FeSO4 soln.

FloculatorPoly Electrolyte

Filter press

Activated carbon filter/sand bed filter

Final treated waste water holding tank

CETP Sarigam through under ground effluent drainage line

FLOW DIAGRAM OF EFFLUENT TREATMENT PLANT FOR NORMAL EFFLUENT STREAM

Characteristics of final treated effluent:

S. No

Effluent Parameter

Combined untreated

effluent from process, RO rejection and

MEE condensate

Final Treated effluent

CETP Sarigam inlet norms

CETP Sarigam outlet norms prescribed by

GPCB

1. pH 5.0-6.0 7.0-8.0 6.5-8.5 6.5-8.5

2. Color pt. Co 600-800 60-80 <100 <100


300-400 80-90 <300 <300


4500-5000 1900-2100 <2100 <2100


2-3 0.1-0.4 <10 <10



6. NH3-N, mg/L 30-40 15-20 <50 <50

7. BOD , mg/L 800-900 80-90 <400 <30

8. COD , mg/L 3000-3500 200-250 <1000 <250

9. Heavy metal, mg/L

ND ND <0.2 <0.2

10. Phenolic Compounds,

mg/L

0.1 0.01-0.1 <1 <1

11. Pesticide , mg/L ND ND Absent Absent

12. Cyanide, mg/L ND ND 0.2 0.2

Details of Compact Sewage treatment plant

Quantity of domestic effluent: 20 m3/day

Bar Screen Chamber

Qty 1 No.

Dimension 0.3‟ X 0.3‟

Capacity 0.2 m3

MOC RCC-Civil (By Client)

Screen Qty 1 No

Opening Size 20 mm

MOC of Screen SS304

Septic Tank

Qty 01

Capacity 25000 Ltr

Dimension As per drawing

MOC RCC/Client Scope

Scope By Client

Equalization Cum Collection Tank

Qty 01

Capacity 25000 Ltr

Dimension As per drawing

MOC RCC/Client Scope

Aeration Grid 1 Lot

Type Coarse Bubble

MOC PP Header

Raw Sewage Transfer Pump

Qty 1 Nos. (1W)

Flow-rate 1000 LPH

Power 1 HP

MOC Sewage sum. Pump

Head @25m

Type Horizontal/Submersible

Make Jee/Indoforce/Kirloskar/Equiv

Bio – Reactor Tank

Qty 1 Nos.



Capacity 10 KL APROX

Retention As per Design

Dimension As per Design

MOC MSEP 6MM THIKNEES

MBBR Media Lot

MOC of Media PP Virgin

Air Blower

Qty 1 Nos(1w)

Type Twin Lobe Rotary Blower

Pressure 0.3 , 0.4 kg/Cm2

Air – Flow 100 M3/H

Make of Blower AGS/Pooja/Eqv./evrest/astra

Motor Rating 3HP

Air Diffuser

Qty 2 Lot

Type Tubular Fine Bubble

Dimension 300 mm

MOC Silicon Disk type

Make German Make

Tube Setting Tank

Qty 1 Nos.

Capacity As per Design

Dimension As per Design

MOC MSEP – 6 MM THIKNESS

Tube Setting Media

Qty 1 Lot

Type Vertical Hexagonal

Dimension 750 L x 100 W

MOC PP

Make Cool Deck/Eqv.

RAS Pump ( Raw Activated Sludge Pump)

Qty N – A

Flow - Rate 1 M3 / H

MOC Cl

Head @ 25m

Type Centrifugal/Non Clog

Make Lee / Indoforce /Eqv.

Motor - Rating

Chlorine Contact Tank

Qty 01

Capacity 100 Ltr

Dimension Round

MOC PP

Chlorine Dosing System

Qty 01

Dose 30 PPM/Ltr

Make E-dose/1-Dose/Eqv.

Filter Feed Pump

Qty 1 Nos.



Flow-rate 2 m3/h

MOC CI

Head @25m

Type Centrifuge

Make Crompton/Kirloskar/Eqv.

Multi Grade Sand Filter

Qty 01

Flow Rate 2000-3000 LPH

MOC MS/FRP (16” x 65”)

Pressure 2 KG/C m2

Make MS/FRP

Media Sand, Pabbles,Gravels

Activated Carbon Filter

Qty 01

Flow Rate 2000-3000 LPH

MOC MS/FRP –MAGNUM-PANTER

Pressure 2 KG/C m2

Make MS

Media Activate Carbon (900 ID)

Inter Collection Type/Valve 1 Lot

Electrical Panel (Automatic)

1 Lot



Details of Incineration system General:

Equipment Incinerator

Process Thermal destruction of organic matter by heat and mass transfer.

Design temperature 1200 deg. C

Fuel Consumpotion NG : 140 SCM/Hr

Power supply 440 V, 30, 50 Hz AC

Operations Continuous

Capacity for solid waste 250 Kg/Hr

Capacity for liquid waste 100 Kg/Hr

Waste Agro chemical plant solid waste [CV-4392 Kcal/Kg]

Moisture content – 27.15% Ash content – 22.91%

Ash generation 55-60 kg/hr

Thermal capacity 150 X 104 kcal/hr

SOLID WASTE DOUBLE DRUM PYROLISER – 8 nos:

Type Solid hearth under /over fire -furnace Pyroliser Suitable for solid waste pyrolisis as

well as De-contamination of empty drums

Capacity Two Half waste filled drums/batch

Principle Thermal destruction/Vaporization of organic matter/de contamination of drum by pyrolisis.

Calorific value 4392 kcal/kg

Operation Batch wise/ 6-8 Hrs. cycle

Pyroliser size 4786 (L) X 1706 (B) X 3000 (Ht)

Construction MS lined with 115 mm insulation bricks and 230 mm Fire brikcs.

Refractory lining 115mm Insulation Bricks 230mm Fire bricks

Access doors hinged door suitable for drum loading

Fuel burner 3 Nos. (Two burners are of 10-12X10^4 Kcal/hr and one burner is of 15-17X10^4 Kcal/hr)

Fuel Used NG

Operating temperature 300-800 C

Air-port 1 no.

Operating Pressure -5 to –10mmwc

Emergency vent 2 no [1 no mechanical + 1 no actuated]

Drum Pyrolisers feeding works in 2 Hr interval cyclic methods.

MAIN COMBUSTION CHAMBER (MCC):

Operating temperature 750-900⁰C



Fuel PNG

Installed heating load 45 X 104 Kcal/Hr

Fuel Oil Burner Fuel Burner automatic

Operating Pressure -5 to -10 mm WC (g)

Emergency Vent Valve 2 Nos. 450 mm dia. Automatically vent - 01 no.

Dead Weight type mechanical - 01 Nos.

Access door 1 No. 550 mm (W) X 550 mm (H) refractory lined.

View ports/peep hole One

MOC MS fabricated with internally refractory lined.

Refractory 115 mm thk, insulation brick, 230 mm thk. Fire brick.

POST COMBUSTION CHAMBER (PCC):

Installation Stationary, Horizontally fired

Operating temperature 1000-1200 deg C

Installed heating load 30 X 104 Kcal/ Hr

Fuel Oil Burner Fuel Burner automatic

Operating Pressure @ – 15 mm WC (g)

Emergency Vent Valve 2 Nos. 450 mm dia. Automatically vent - 01 no.

Dead Weight type mechanical - 01 Nos.

Hearth High temp refractory bed

View ports/peep hole One

Ash/Access door 550 mm square door, refractory lined Hinged door.

MOC MS with internal refractory lining

Refractory 50 mm thk, ceramic wool 115 mm thk insulation brick,

230 mm thk, fire brick

FUEL BURNER:

Type Fully automatic

Fuel Natural Gas

Capacity 40X104Kcal/Hr - 2 nos. MCC 40X104Kcal/Hr - 2 nos. PCC

15X104Kcal/Hr - 8 no‟s. /Drum Pyroliser 10X104Kcal/Hr - 16 no‟s. /Drum Pyroliser

Accessories Burner body/combustion head/ burner block Flame sensor /Ignition transformer /

Sequence controller/ Flame tube/air fan

COMBUSTION AIR FAN:

Type Centrifugal, Backward Curved

Service Air for combustion waste



Fluid Air

Discharge 6500 M3/Hr & 3000 M3/Hr

Fluid temperature 30°C

Static pressure 450 mm WC

Connected load 15 HP & 10 HP

MOC Casing - MS Impeller - MS

Base Plate - MS

HIGH TDS EFFLUENT DRYER CUM DRY SCRUBBER:

Feed material Scrubber effluent

Type Stationary / Circular / Disc Atomizer

Service Drying of effluent/ Neutralization of flue gas

M.O.C Acid proof refractory lined / M.S - IS2062. – MS + acid proof brick lined

Cone –SS-403 Internal Duct – SS

Distributor –SS

Flue gas inlet temp @ 1100 C

Flue gas outlet temp @ 230-250 C

Effluent injection facility Disc atomizer/disc RPM – 8-9000

Solid discharge Rotary discharge system. RAV motor - @ 1 HP

Overall Size 4000 mm dia. X 8000 mm ht with conical bottom.

Quenching Media Alkaline effluent with max. 10% TD

Material to be dried/Out Inorganic Salts

Atomizer Centrifugal Disc atomizer,

Effluent drying @1000-1200Ltr/Hr

Manhole 500 mm X 500mm

Hand hole size 400mm X 400mm

Oil recirculation for atomizer

Bearing cooling

by gravity

Disc Atomizer 1no

DISC ATOMIZER COOLING BLOWER:

Capacity 1000 M3/Hr


Motor 2 HP

SPRAY DRYER-DRY SCRUBBER PUMP - (1 W + 1 S):

Type Screw Pump

Capacity 2000 Lit/hr

Pressure 3 Kg/Cm2



Temperature Ambient

MOC SS

Motor 1 HP

CYCLONE - 2 nos.:

Type Circular

Principle Kinetic Energy

Inlet temp 230 – 2500C

Length of cyclone 2100 mm

Dia. of cyclone 700 mm

Material of Construction SS

Bottom discharge Through rotary air valve RAV motor – 0.5 HP

VENTURI SCRUBBER:

Type Pressure jet venture

Throat Dia. 225 mm

Length 4000 mm

Nozzle SS

Allowable Pressure Drop Across Ventury: 300 mm WC, Max gas side

Inlet/Outlet gas temp. 100/ 70 deg. C

Scrubbing liquor Alkaline Scrubber Liquid (Free alkali more than 8-10%) Caustic solution

Liquid Circulation Ventury Scrubber- Operating : 5 M3/

Spray Nozzles Axial Spiral cone at top – SS


PACKED BED SCRUBBER:

Type Counter Current Packed Bed scrubber/ Separation tower

Inlet / Outlet gas temp. 70/65 deg C

Mist Eliminator 500 mm Dry packing

Packing ht. 2000

Packing : Type Pall Ring

Size First two layers: 75 mm Random : 50 mm

Dry packing : 50 mm

Scrubbing Liquor Alkali Solution

Liquid Circulation, Operating : 15 M3/hr,

Backwash Spray nozzles One set

Liquid Distributor Type :-Header and lateral type pipe distributor provided with

spiral cone SS316 nozzles

MOC SS



Packing PP

SCRUBBER CIRCULATION TANK:

Type Re-circulation Tank

Duty To Re-circulate liquid

Tank Volume 3 M3

MOC S.S internally special coated

SCRUBBER RECIRCULATION PUMP:

Type Centrifugal

Capacity 20 M3/Hr

Operating pressure 3 Kg/Cm2

Motor rating 10 HP

MOC CI

Quantity 2 nos.

CAUSTIC SOLUTION CUM DOSING TANK:

Type Cylindrical, Tank

Duty Hold caustic solution for dosing in Alkali Scrubber

Tank Volume Operating: 2 M3

Material of Construction MS with epoxy painted

CAUSTIC SOLUTION DOSING PUMPS (02 NOS):

Type Plunger/metering Pump

Qty 2 Nos.

Capacity 100 LPH at 2 Kg/cm2 g head

Fluid solution 10 % Caustic

Motor 0.5 HP

MOC All contact part in SS316

INDUCED DRAFT FAN (1 OP+ 1 SB):

Type & arrangement Centrifugal Fan

Duty To overcome pressure drop in liquid incineration plant and to maintain required negative pressure in upstream equipment.


Inlet Gas Pressure -600 mm wcg

Outlet Gas Pressure +25 mm wcg

Differential Head 625 mm wc

Operating temperature 73 Deg. C

Capacity 13000m3/hr

Impeller Type Backward inclined



Coupling Directly coupled

Base Frame Common for Blower and Motor

Internal Efficiency 72 %

Blower Speed 1818 rpm

Motor Speed 1400 rpm

Motor Rating 60 HP

Motor Type Safe Zone, VFD driven

Casing SS 316

Impeller SS 316

Base Frame MS with Epoxy Painted

Noise Level < 85 db at 1.0 M distance

Performance test As per IS 4894

Balancing Certificate As per ISO 1940 Grade 6.3

CHIMNEY:

Type Self supported

Height 30 mtr

Top dia 650 mm

Bottom dia 1000 mm

Accessories Ladder/platform, Sampling nozzle, lightning arrestor, drain

plug, bottom cleaning door.

MOC MS with internally special coating

INSTRUMENTS:

Temperature Transmitter 21 Nos.

Pressure switch 11 Nos.

Level indicator 03 Nos.

Pressure Gauges 03 Nos.

Control Valves 02 Nos

Level Switch 02 No.

Pressure transmitter 02 No.

VFD 01 No.

PH analyzer 01 No.



Acknowledgment letter for CETP membership



ANNEXURE-6 PLOT ALLOTMENT LETTER ISSUED BY THE GIDC



NOTIFICATION FOR SARIGAM NOTIFIED INDUSTRIAL ESTATE



ANNEXURE 8 A SCHEMATIC REPRESENTATION OF THE FEASIBILITY DRAWING



ANNEXURE: 9 DETAILS OF PROPOSED AIR POLLUTION & ITS CONTROL MEASURES

Flue Gas Emission

There will be flue gas emission from 25 TPH capacity of imported coal fired steam boiler in the

form of PM, SOx & NOx. Adequate capacity of electro static precipitator and wet scrubber

along with 55 meters height of chimney will be provided. 3.5 TPH of imported coal will be used

as a fuel in 25 TPH of boiler.

A standard Coal handling system with screening, coal crushing and conveying system will be

installed for the proposed plant. There will be a coal crusher plant with impact blade crusher,

screen, conveyor & elevator and reject of the screen will be recycled with two roll crusher and

elevator.

A standard fly ash handling system will be installed for the proposed plant. The fly ash collected

in Economizer and APH shall be designed to collect fly ash in dry form in the silo. From the silo,

fly ash shall be dispatched to trucks. After burning, less than 6 mm coal in AFBC type boiler

furnace will convert in to ash (fly ash particle size which is 100% less than 300 microns) and

this will carry over with flue gas through super heater, economizer, air – heater (APH) and

finally /will be precipitated in ESP zone. The ash collected in the hoppers of ESP will be

discharged in the silo by gravity. Level in the silo will be controlled by level controllers provided

on silo. Whenever the level exceeds, the pneumatic valve opens and ash shall be conveyed to

ash hopper through pipes with the help of compressed dry air at a pressure of 5 kg/cm2.Unit

will provide the Dense Phase pneumatic ash conveying system under the ash discharge points

of economizer, APH, and all ESP fields. At the discharge point of ash silo, ash conditioner shall

be put where water spay shall be done for duct free loading of trucks/lorry under the ash silo.

Finally ash shall be taken by contractor for brick making/filling of low lying area

Also the unit will install 1000 KVA capacity of D G set, as standby. It will be used only during

power failure. 150 kgs/hr of HSD will be used as a fuel & 11 meters height of chimney will be

provided.

S. No. Particulars Details

Flue gas emission

1.0 Capacity of steam boiler, TPH 25

1.1 Fuel to be used Imported coal

1.2 Consumption of fuel in kgs/hr 3500

1.3 APC to be provided ESP followed Wet scrubber

1.4 Dia/Height of Chimney 900 mm/30 meter

2.0 Capacity of D G set, KVA 100

2.1 Fuel to be used HSD

2.2 Consumption of fuel in kgs/hr 150

2.3 APC to be provided Exhaust

2.4 Dia/Height of Chimney 200 mm/11 meter

3.0 Expected Emission PM: <150 mg/Nm3 SOx: <100 ppm NOx: < 50 ppm



Details of Electro static Precipitator attached to proposed coal/Briquettes fired steam boiler ( 25 TPH):

ESP (ELECTROSTATIC PRECIPITATOR)

Application - To Collect Fly Ash Particle from Boiler Flue Gas

Type - Horizontal Flow, Dry Type, Single Pass

Fuel - Imported coal

No. of ESP No One

No. of Gas Path per Precipitator No One

No. of Gas Fields in series in direction of Gas flow

Nos Four

No. of Electrical Fields per Boiler Nos Four

Flue Gas Flow Rate M³/Sec 8.45

Flue Gas Temperature at ESP °C 150

Inlet Dust Concentration gm/NM³ 38.5

Outlet Dust Concentration mgm/ NM³ 100

Gas Velocity at Electrode Zone on M/Sec 0.48 / 0.51

Details of wet scrubber attached to steam boiler

Gas volume 5000 cfm

Gas temperature 160 to 230 oC

Wet scrubber mmwg 4 to 6 inches

Scrubber type Cyclomex with buffel wet scrubber

Total stage single

Total shell height 14 feet

Total Diameter 6 feet

MOC SS 304, 4 mm thickness

Inner pipe SS 304



Total Area

Plate Area M² 2061.1

Specific Collection Area M²/M³/Sec 120.88

Velocity through ESP M/Sec 0.53

Treatment Time Sec 24.6

Migration Velocity Cm/Sec 5.50

Aspect Ratio - 1.29

Overall Dust Collection Efficiency with all fields in service

% 98.5

Design Static Pressure mmWC -250

Type of Rapping - EMIGI Type

Pressure Drop across ESP (Flange to Flange)

mmWC 25 – 30

Ash Hopper Outlet Flange Elevation M 2.5

No. of Hoppers in ESP Nos Four

COLLECTING ELECTRODE SPECIFICATIONS

Material - CRCA Sheet (IS 513 Grade – “D”)

Thickness SWG 18

EMITTING ELECTRODE SPECIFICTIONS

Type - Spike Type

Material - ERW Tubes & Carbon Steel Studs

GAS DISTRIBUTION SYSTEM

No. of Screen Nos Three at Inlet / One at Outlet

Type - Perforated Formed Sheet

Location - ESP Inlet & Outlet



COAL HANDLING SYSTEM A standard Coal handling system with screening, coal crushing and conveying system will be installed. There is a coal crusher plant will be provided with impact blade crusher, screen, conveyor & elevator and reject of the screen will be recycled with two roll crusher and elevator. Total area of the covered coal yard is 250 m2 and about 500 tons of coal can be stored in this yard.



Coal Handling System

Following measures has been taken during coal transportation, handling and storage and shall be continued for the proposed plant.

Water sprinkler system shall be used to control the fugitive dusts.

Greenbelt shall be provided in and around the premises area, around the coal stack yard and

along the roads to minimize the generation of fugitive coal dust.

For transportation, loading & unloading of goods, closed conveyor belt system shall be

provided.

To control the fugitive dusts from coal handling, adequate moisture content shall be provided.

Enclosures for transport vehicles/storage vessel, spraying of water on road & ground is/shall be

effectively implemented to control the coal dust problem. During the operation phase proper

EMP shall be in place for handling of Coal.

The trucks used for transporting the goods will be covered by the tarpaulin and overloading in

trucks shall not be allowed, to prevent the dusting and spillage of goods from the truck.

Regular Air monitoring and inspection of the environmental management practices shall be

carried out and the necessary documents & records shall be maintained.

A fire hydrant system line is/shall be provided for immediate response to the unlikely

spontaneous combustion in the stored fuel.

Lime Charging for SO2 Control

In the proposed plant, proponent shall use imported coal with low sulfur content. However

as a safety measure, it is proposed to have boiler designed for feeding/charging lime stone



for SO2 control. Feeding arrangement of lime stone shall be provided along with separate

bunker in line with boiler fuel feeding so that suitable quantity of lime stone can be added if

and when required.

Fly Ash Handling System

A standard fly ash handling system shall be installed. The fly ash collected in Economizer

and APH shall be designed to collect fly ash in dry form in the silo. From the silo, fly ash

shall be dispatched to trucks.

APC for Boiler Flue gases and scheme of Ash Handling



Process Gas Emission

Three numbers of two stage water followed by alkali scrubbers will be provided to scrub Hydro

chloric acid gas and three numbers of two stage alkali scrubbers will be provided to scrub

Sulphur dioxide and one number of two stage alkali scrubbers will be provided to scrub,

hydrogen sulphide gas generated from the various product process. Separate 11 meters height

of vent will be provided.

The unit proposes to install natural gas fired incinerator having capacity of (250 kg/h of solid

and 100 kg/h liquid) and 140 SCM/h of natural gas will be used. Adequate ventury & wet

scrubber along with 30 meters height of chimney will be provided.

Product-wise Process gas emission

S. No. Product Pollutant Quantity, tone/tone

3 Lambda Cyhalothrin Hydrogen chloride 0.088

Sulfur dioxide 0.155

4 Bifenthrin Hydrogen chloride 0.175


5 Cyphenothrin Hydrogen chloride 0.11

Sulfur dioxide 0.19

6 Fenpropathin Hydrogen chloride 0.113


7 Zeta- Cypermethrin Hydrogen chloride 0.095


8 Transfluthrin Hydrogen chloride 0.205


9 Pymetrozine HCl gas 0.365

CO2 Gas 0.105

18 Metalaxyl CO2 0.180

24 25

Kresoxim Methyl Hydrogen chloride 0.125


32 Sulfentrazone Ethyl Hydrogen chloride 0.095

34 35

Diethyl thiphosphoryl Chloride (DETC)

Hydrogen Sulfide 0.1

Hydrogen Chloride 0.2

Details of Air pollution and its control measures

Process gas emission

1.0 Type of pollutant HCl

1.1 Source of pollutant Reaction

1.2 APC to be provided Two stage water followed by alkali scrubber

1.3 Height of vent 11 meter

1.4 Expected emission HCl: < 20 mg/Nm3

2.0 Type of pollutant SO2




2.2 APC to be provided Two stage alkali scrubber


2.4 Expected emission SO2: < 40 mg/Nm3

3.0 Type of pollutant H2S




3.4 Expected emission H2S: < 25 mg/Nm3

4.0 Type of pollutant Acid mist

4.1 Source of pollutant Acid storage tanks



4.4 Expected emission Acid mist: <5 mg/Nm3

5.0 Type of pollutant PM,SOx,NOx

5.1 Source of pollutant Incinerator

5.2 APC to be provided Dryer, cyclone and ventury scrubber


5.4 Expected emission PM: <50 mg/Nm3 SOx: < 200 Mg/Nm3 NOx: < 25 mg/Nm3 TOC: < 20 mg/Nm3

HCl: <50 mg/Nm3 Specification of HCl Gas scrubbing system:

1. Specifications of Falling Film Graphite HCl Scrubber: Type : Parallel flow falling film type Tube side : HCl gas, Shell side : cooling water HCl/Cl2 gas /hour : 100 kg/h Scrubbing media : water Heat of solution kcal/h : 10000 kcal/h Cooling water required at 40 approach : 2.5 m3/h No of tubes required : 65 tubes, 20 dia x 2.5 m length HTA required : 10 m2 Diameter of scrubber : 350 mm Overall length : 3000 mm MOC tubes : Glass MOC shell : HDPE/Graphite Specifications of tails tower Inlet HCl : 50 kg/h Scrubbing media : Water, 58 kg /h, to be fed to main scrubber Tower dia : 350 mm



Packed length : 1500 mm Overall length : 2000 mm MOC : FRP Packing dia : 40 mm PP Outlet HCl : 0.0025 KG/h Specifications of Alkali Ventury Inlet HCl : 0.0025 kg/h Scrubbing media : 10 % dilute alkali Size of Ventury : 150 dia x 1250 mm ht. MOC : FRP Alkali circulation tank : 2000 liter HDPE Circulation pump : 2.5 m3/h S/S Vent diameter : 150 mm Height of vent : 11 meters

Primary Circulation Tank

PrimaryHClSCRUBBER

SecondaryCirculation Tank

Gas From Plant

TailSCRUBBERFor HCl

Un Condensed HCl gas

Caustic LyeCirculation Tank

Header

To Atmosphere

HCl SCRUBBER SYSTEM

VENTURY

2. Specification of SO2 Gas scrubbing system

Sr. No.

Name of the Equipment Capacity



1 Scrubber size 420 mm dia x 5000 mm

2 MOC of scrubber HDPE

3 Type of packing PP Racing ring

4 Height of packing 3500 mm

5 Alkali Circulation tank 5 m3, HDPE

6 Alkali circulation pump 3 HP

7 ventury scrubber 300 dia x 3000

8 Alkali circulation tank 1 m3

9 Alkali circulation pump 10 m3/h

10 Height of vent 11 meter

11 Dia of vent 150 mm

NRV

PG

DILUTE NaOH

10 %NaOH

PACKEDCOLUMNSOx

SCRUBBER

NaOH LYE

VENTURY SCRUBBER

BLOWER

STACK

REACTOR

SOx FUMES

REACTORS

TWO STAGE SOx SCRUBBING SYSTEM

3. Specification of Scrubber attached to Acid Storage tank:

No Details of Scrubber Size

1 Packed height in meters 2 mt.

2. Dia in meters 0.3

3. Circulating liquid Dilute caustic

4. Size of tank 100 liters, HDPE

5. Capacity of the pump ,m3/h 3 HP

6. Capacity of the blower, Nm3/h 1500

7. Vent diameter in mm 200

8. Height of the vent from ground 11 mt

9. Sampling arrangement provided



NRV

PG

DILUTE NaOH

10 %NaOH

PACKEDCOLUMN

NaOH LYE

VENTURY SCRUBBER

BLOWER

STACK

Acid vapour

Storage tanks

TWO STAGE SCRUBBING SYSTEM FOR ACID STORAGE TANKS

4. Specification of H2S Gas scrubbing system

Sr. No.

Name of the Equipment Capacity

1 Height of scrubber (Packed column) 2 meter

2 Size of scrubber 600 mm

MOC of scrubber HDPE

3 Type of packing PP Racing ring

4 Height of packing 1500 mm

5 Alkali Circulation tank 2 m3, HDPE

6 Alkali circulation pump 3 HP

7 ventury scrubber 300 dia x 3000

8 Alkali circulation tank 1 m3

9 Alkali circulation pump 10 m3/h

10 Height of vent 11 meter

11 Dia of vent 150 mm



PG

Alkali

VENT

REACTOR

H2SSCRUBBERPACKEDTOWER

VENTURYSCRUBBER

CHW

Alkali

H2S Gas

TWO STAGE H2S SCRUBBING SYSTEM

5. Specification of scrubbing system attached to incinerator HIGH TDS EFFLUENT DRYER CUM DRY SCRUBBER:

Feed material Scrubber effluent

Type Stationary / Circular / Disc Atomizer

Service Drying of effluent/ Neutralization of flue gas

M.O.C Acid proof refractory lined / M.S - IS2062. – MS + acid proof brick lined

Cone –SS-403 Internal Duct – SS

Distributor –SS

Flue gas inlet temp @ 1100 C

Flue gas outlet temp @ 230-250 C

Effluent injection facility Disc atomizer/disc RPM – 8-9000

Solid discharge Rotary discharge system. RAV motor - @ 1 HP

Overall Size 4000 mm dia. X 8000 mm ht



with conical bottom.

Quenching Media Alkaline effluent with max. 10% TD

Material to be dried/Out Inorganic Salts

Atomizer Centrifugal Disc atomizer,

Effluent drying @1000-1200Ltr/Hr

Manhole 500 mm X 500mm

Hand hole size 400mm X 400mm

Oil recirculation for atomizer

Bearing cooling

by gravity

Disc Atomizer 1no

DISC ATOMIZER COOLING BLOWER:

Capacity 1000 M3/Hr


Motor 2 HP

SPRAY DRYER-DRY SCRUBBER PUMP - (1 W + 1 S):

Type Screw Pump

Capacity 2000 Lit/hr

Pressure 3 Kg/Cm2

Temperature Ambient

MOC SS

Motor 1 HP

CYCLONE - 2 nos.:

Type Circular

Principle Kinetic Energy

Inlet temp 230 – 2500C

Length of cyclone 2100 mm

Dia. of cyclone 700 mm


Bottom discharge Through rotary air valve RAV motor – 0.5 HP

VENTURI SCRUBBER:

Type Pressure jet venture

Throat Dia. 225 mm

Length 4000 mm

Nozzle SS

Allowable Pressure Drop Across Ventury: 300 mm WC, Max gas side

Inlet/Outlet gas temp. 100/ 70 deg. C

Scrubbing liquor Alkaline Scrubber Liquid (Free alkali more than 8-10%) Caustic solution

Liquid Circulation Ventury Scrubber- Operating : 5 M3/

Spray Nozzles Axial Spiral cone at top – SS


PACKED BED SCRUBBER:

Type Counter Current Packed Bed scrubber/ Separation tower

Inlet / Outlet gas temp. 70/65 deg C



Mist Eliminator 500 mm Dry packing

Packing ht. 2000

Packing : Type Pall Ring

Size First two layers: 75 mm Random : 50 mm

Dry packing : 50 mm

Scrubbing Liquor Alkali Solution

Liquid Circulation, Operating : 15 M3/hr,

Backwash Spray nozzles One set

Liquid Distributor Type :-Header and lateral type pipe distributor provided with

spiral cone SS316 nozzles

MOC SS

Packing PP

SCRUBBER CIRCULATION TANK:

Type Re-circulation Tank

Duty To Re-circulate liquid

Tank Volume 3 M3

MOC S.S internally special coated

SCRUBBER RECIRCULATION PUMP:

Type Centrifugal

Capacity 20 M3/Hr

Operating pressure 3 Kg/Cm2

Motor rating 10 HP

MOC CI

Quantity 2 nos.

CAUSTIC SOLUTION CUM DOSING TANK:

Type Cylindrical, Tank

Duty Hold caustic solution for dosing in Alkali Scrubber

Tank Volume Operating: 2 M3

Material of Construction MS with epoxy painted

CAUSTIC SOLUTION DOSING PUMPS (02 NOS):

Type Plunger/metering Pump

Qty 2 Nos.

Capacity 100 LPH at 2 Kg/cm2 g head

Fluid solution 10 % Caustic

Motor 0.5 HP

MOC All contact part in SS316

INDUCED DRAFT FAN (1 OP+ 1 SB):

Type & arrangement Centrifugal Fan

Duty To overcome pressure drop in liquid incineration plant and to maintain required negative pressure in upstream equipment.


Inlet Gas Pressure -600 mm wcg

Outlet Gas Pressure +25 mm wcg

Differential Head 625 mm wc

Operating temperature 73 Deg. C



Capacity 13000m3/hr

Impeller Type Backward inclined

Coupling Directly coupled

Base Frame Common for Blower and Motor

Internal Efficiency 72 %

Blower Speed 1818 rpm

Motor Speed 1400 rpm

Motor Rating 60 HP

Motor Type Safe Zone, VFD driven

Casing SS 316

Impeller SS 316

Base Frame MS with Epoxy Painted

Noise Level < 85 db at 1.0 M distance

Performance test As per IS 4894

Balancing Certificate As per ISO 1940 Grade 6.3

CHIMNEY:

Type Self supported

Height 30 mtr

Top dia 650 mm

Bottom dia 1000 mm

Accessories Ladder/platform, Sampling nozzle, lightning arrestor, drain

plug, bottom cleaning door.

MOC MS with internally special coating

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