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Transcript of Preparation and Characterization of Inorganic Catalysts and Their Use in the Oxidation of Organic...
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7/31/2019 Preparation and Characterization of Inorganic Catalysts and Their Use in the Oxidation of Organic Substrates
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Vtevbtbxgao boh Knbtbkxetgpbxgao ai Goatcbogk Kbxblw{x{ boh Xnegt U{e go
xne A~ghbxgao ai Atcbogk [ud{xtbxe{
Bd{xtbkx0
Aut e~vetgjeox sb{ xsaialh0 2'Xsa hgiieteox {bleo lgcboh hetgybxgye{ sete {woxne{gpeh boh
kajvle~eh sgxn Ka.GG' boh Og.GG'/ Daxn lgcboh{ boh lgcboh*jexbl kajvle~e{ sete knbtbkxetgpeh u{gocybtgau{ {vekxta{kavgk xeknogrue{, b{ sell b{ bd gogxga kajvuxbxgaobl xeknogrue{/ Xne vtevbteh
kbxblw{x{ sete xneo u{eh xa a~ghgpe {elekxeh vneoal{ xa katte{vaohgoc rugoaoe{ go b jalekulbt
a~wceo tgkn eoygtaojeox/ Hbxb iat {bleo kbxblw{x{ sgxn hgiietgoc iuokxgaobl ctauv{ sete kajvgleh bohu{eh xa hexetjgoe va{{gdle tebkxgao jeknbog{j{ iat xne kbxblwxgk kaoyet{gao ai ybtgau{ vneoal{ xarugoaoe{/ Kbxblwxgk eiigkgeokw sb{ xtbkmeh u{goc ruboxgxbxgye boh {vekxta{kavgk xeknogrue{/ 4'
Vtava{eh jeknbog{j{ sete xe{xeh u{goc {eyetbl bvvtabkne{, gokluhgoc xne u{e ai dbte kadblx jexbl
go a~ghbxgao xe{x{, xne {woxne{g{ ai b Ku.GG'*db{eh kbxblw{x, xe{xgoc ai kbxblw{e{ go aveo bgt tbxnet xnbogo a~wceo tgkn bxja{vnete, boh xgje*kaoxtalleh a~ghbxgao{/
Dbkmctauoh0
Atcboajexbllgk {bleo{ bte ai goxete{x dekbu{e ai xnegt bdglgxw xa kaathgobxe sgxn jexbl{ {ukn xnbx xnewiatj eiiekxgye boh ngcnlw {elekxgye kbxblwxgk kajvle~e{ 2, 4, ;, 8/ Atcboajexbllgk {bleo lgcboh{ bte yetw
yet{bxgle go xnbx xnegt {vekgigk kbxblwxgk iuokxgao boh jeknbog{j
kbo de xuoeh dw jbmgoc knboce{ xa xne {xtukxute ai xne lgcboh 5,
9, 3/ Go bhhgxgao, xne{e {xtukxute{ kbo kajvle~ sgxn b sghe
ybtgexw ai xtbo{gxgao jexbl{, biiathgoc xnej eyeo ctebxet
yet{bxglgxw/ [aje vtbkxgkbl u{e{ ai xne{e kajvle~e{ gokluhe
eva~ghe tgocaveogoc kbxblw{g{ >, nexeta Hgel{Blhet tebkxgao{ 7,
boh nwhtakwbobxgao{ 26/ Xnew nbye bl{a deeo e~vlateh go xnegt
bdglgxw xa nelv dgoh a~wceo teyet{gdlw boh go {a hagoc, kbxblwpe
xne a~ghbxgao ai lgcogo 22/
Go aut te{ebtkn ctauv, se sete goxete{xeh go xnekbxblwxgk bdglgxw ai atcboajexbllgk {bleo{ {gjglbt xa 8d boh 5b,
vgkxuteh go igcute{ 2 boh 4, b{ ibkglgxbxeh xntaucn xne dgohgoc ai
a~wceo/ Bll xne lgcboh{ {woxne{gpeh boh xe{xeh sete [kngii
db{e lgcboh{/ Xne jbgo {xtukxutbl ybtgbxgao{ ejvlaweh sete xne
{woxne{g{ ai daxn bo exnwleoedb{eh lgcboh dbkmdaoe 5b, boh
bo btajbxgkdb{eh dbkmdaoe 8d, boh ybtgbxgao ai xne iuokxgaobl
ctauv{vbtb xa xne nwhta~w ctauv{ ao xne gjghe btajbxgk{/
Kajvauoh{ sete {woxne{gpeh b{ najaceoau{lw b{ va{{gdle/ Ogkmel.GG' boh kadblx.GG' sete kna{eo xa
de aut jexbl keoxet{, b{ xnew saulh kajvle~ sgxn {gjglbt ceajextge{, wex hgiiet go te{vekx xa xnegt h
elekxtao kauox/ Gx sb{ delgeyeh xnbx aolw xne kadblx[kngii db{e lgcboh{ saulh hg{vlbw kbxblwxgkbkxgygxw, b{ xnew sete bdle xa kbxblwpe a~wceo bkxgybxgao dekbu{e ai xnegt uovbgteh helekxtao/ Xng{
saulh bllas iat goxetbkxgao sgxn vbtbjbcoexgk jalekulbt a~wceo, sneteb{ ogkmel.GG', sgxn b iglleh h
{nell, saulh de uobdle xa kbxblwpe xne a~ghbxgao{ ai vneoal{ dw bkxgybxgoc a~wceo go xng{ jbooet/ Go
bhhgxgao se e~vlateh xne jeknbog{j dw sngkn aut kadblx[kngii db{e lgcboh{ bkxgybxe a~wceo0
{xtukxutbllw b{ he{ktgdeh bdaye, b{ sell b{ dw xe{xgoc b{ jbow eoygtaojeoxbl ybtgbdle{ b{ va{{gdle/
Xne{e hbxb bte vte{eoxeh delas, go xne e~vetgjeoxbl {ekxgao/
Igc 2/ Lgcboh 8d0 Nwhta~w {ud{xgxuxeh
{bleo sgxn deopwllgk dbkmdaoe/
Igc 2/ Lgcboh 5b0 Jexnwl {ud{xgxuxeh
{bleo sgxn exnwleoe dbkmdaoe/
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E~vetgjeoxbl
[woxne{g{0
L5b .4,4#*..2E,2#E'*.exnboe*2,4*hgwldg{.bpbowlwlgheoe''dg{.jexnbowlwlgheoe''dg{.8*jexnwlvneoal''0 Xa b 266jL tauohdaxxaj ilb{m kaoxbgogoc 6/5889c .29jjal' 5jexnwl{blgkwlblhenwhe go 25 jl JeAN, 6/22;9 jL .> jjal' exnwleoehgbjgoe sb{ bhheh hgtekxlw ygbjgktavgvex/ Xne te{ulxgoc {aluxgao sb{ teilu~eh sgxn {xgttgoc go b nax jgoetbl agl dbxn iat 76 jgouxe{/
Xne jg~xute sb{ bllaseh xa kaal xa taaj xejvetbxute boh xneo gjjet{eh go bo gke sbxet dbxn/ Xne
vtekgvgxbxe sb{ iglxeteh dw ybkuuj, boh xne iglxtbxe hg{kbtheh, wgelhgoc 6/583>c .>5%' ai iluiiw, dtgcnxwellascteeo, vebtle{keox, ilbmw ktw{xbl{/ OJT KHKL; .vvj'0 24/7 .4N, AN', >/; .4N, gjghe', 9/73/2 .9N, btajbxgk', ;/47 .8N, KN4', 4/; .9N, KN;'/
L8d .4,4#*..2E,2#E'*.2,4*vneowleoedg{.bpbowlwlgheoe''dg{.jexnbowlwlgheoe''dg{.deopeoe*
2,8*hgal''0 Xa b 266jL tauohdaxxaj ilb{m kaoxbgogoc 6/5545c .29jjal' 5nwhta~w{blgkwlblhenwhe go
;6jL JeAN, 6/4294c .>jjal' aexnwleoehgbjgoe hg{{alyeh go 25jL JeAN sb{ bhheh/ Xne
te{ulxgoc {aluxgao sb{ teilu~eh sgxn {xgttgoc go b nax jgoetbl agl dbxn iat 256 jgouxe{/ Xne {aluxgao sb{
bllaseh xa kaal xa taaj xejvetbxute boh xneo gjjet{eh go bo gke sbxet dbxn/ He{gteh lgcboh
vtekgvgxbxeh aux ai {aluxgao, boh ybkuuj iglxtbxgao wgelheh 6/;897c .85%' yetw igoe, {ngow, dtgcnxteh
vashet/ OJT KHKl;.vvj'0 24/2 .8N, AN'= 7/2 .4N, gjghe'= >/>= 3/59/> .btajbxgk'= 8/2 rubtxex=
;/4= ;/2, haudlex/
L5b Kadblxa{bleo0 Go b 256jL Etleojewet ilb{m, 6/8566c .2/545 jjal' ai lgcboh 5Bsb{ hg{{alyehgo 35jL ai JeAN/ Xne te{ulxgoc {aluxgao sb{ {xgtteh sgxn ceoxle nebxgoc, uoxgl xne bhheh lgcboh sb{
kajvlexelw hg{{alyeh/ Go b {evbtbxe 256jL Etleojewet ilb{m, 6/;37>c .2/545 jjal' ai Ka.GG' bkexbxe
sb{ kajvlexelw hg{{alyeh go b jgogjbl bjauox ai JeAN/ Xne xsa {aluxgao{ sete kajdgoeh, boh
bllaseh xa {xgt sgxnaux iutxnet nebxgoc iat 2625 jgouxe{/ Xne {aluxgao sb{ tejayeh boh vlbkeh go bo
gke sbxet dbxn, boh xne te{ulxgoc vtekgvgxbxe sb{ iglxeteh dw ybkuuj u{goc igoe itgxxeh clb{{/ Xne
te{ulxgoc {algh sb{ bllaseh xa htw, wgelhgoc 6/9392c .>2%' ai yetw igoe, dlbkm, iluiiw, nbgt lgme jbxetgbl/
E[GJ[0 [gocle, vtajgoeox vebm ;5;/4 j!p/ Eybo{ jexnah OJT gokaoklu{gye/
AN
A
N
NA
AN
AN
N
N4O ON4
AN
AN
N
NO
N
ON4
AN
AN4
N
NO
ON4
NA
NON4O
N
A
AN
O
ON4
N
N4A
Igc 4/Vtava{eh jeknbog{j iat iatjbxgao ai exnwleoedb{eh [ngii db{e lgcboh 5b/
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Gogxgbl Kbxblw{g{0
Gogxgbl kbxblwxgk a~ghbxgao{ ai {elekxeh vneoal{ sete vetiatjeh u{goc b 2602 {ud{xtbxe0kbxblw{x jalbt
tbxga go ;6jL JeAN, uohet kao{xbox jalekulbt a~wceotgkn bxja{vnete/
L5b Ogkmel{bleo - Vneoal0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal, 6/67;5c
.6/499 jjal' ai exnwleoedb{eh ogkmel kbxblw{x 5b sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc {aluxgao,
6/4259c .4/99 jjal' vneoal sb{ bhheh/ OJT KHKl;.vvj'0 3/48 .N jexb xa AN'= 9/7; .N vbtb
xa AN'= 9/>8 .N atxna xa AN'= 5/;5 .AN'/
L5b Ogkmel{bleo - Nwhtarugoaoe0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal,
6/6377c .6/443 jjal' ai exnwleoedb{eh ogkmel kbxblw{x 5b sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc
{aluxgao, 6/4529c .4/43 jjal' nwhtarugoaoe sb{ bhheh/ OJT HJ[A .vvj'0 >/57 .4N vbtb AN'=
9/53 .4N atxna xa AN'/
L5b Ogkmel{bleo - 4,9*hgjexnwlvneoal0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal,
6/6342c .6/465 jjal' ai exnwleoedb{eh ogkmel kbxblw{x 5b sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc
{aluxgao, 6/4525c .4/65 jjal' 4,9hgjexnwlvneoal sb{ bhheh/ OJT KHKl;.vvj'0 9/7; .4N jexb xa
KN;'= 9/38 .N vbtb xa AN'= 8/99 .AN'= 4/46 .9N ao KN;{'/
L5b Kadblxa{bleo - Vneoal0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal, 6/266;c
.6/499 jjal' ai exnwleoedb{eh kadblx kbxblw{x 5b sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc {aluxgao,
6/4556c .4/99 jjal' vneoal sb{ bhheh/ CKJ[0 ;/;> jgo .9>%', j!p0 26>, >4 .K4N4', 58 .KA',
;/58jgo .;4%', j!p0 78, 55 .K8N3'/ OJT KHKl;.vvj'0 9/7; .4N jexb xa KN;'= 9/>6 .8N, atxna xa
AN'= 9/38 .N vbtb xa AN'= 8/99 .AN'= 4/46 .9N ao KN;{'/
L5b Kadblxa{bleo - Nwhtarugoaoe0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal,
6/6>64c .6/443 jjal' ai exnwleoedb{eh kadblx kbxblw{x 5b sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc
{aluxgao, 6/452>c .4/43 jjal' nwhtarugoaoe sb{ bhheh/ CKJ[0 ;/84 jgo .266%', j!p0 26>, >4 .
K4N4', 58 .KA'/ OJT KHKl;.vvj'0 9/>6 .8N, atxna xa AN'/
L5b Kadblxa{bleo - 4,9*hgjexnwlvneoal0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal,
6/63;8c .6/465 jjal' ai exnwleoedb{eh kadblx kbxblw{x 5b sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc
{aluxgao, 6/4529c .4/65 jjal' 4,9hgjexnwlvneoal sb{ bhheh/ CKJ[0 5/;9 jgo .89%', j!p0 244,
263 .KN;', 72 .A', 33 .KN4'= 5/52 jgo .58%', j!p0 244, 263 .KN;', 72 .A', 33 .KN8'/
L8d Ogkmel{bleo - Vneoal0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal, 6/228;c
.6/499 jjal' ai deopeoe db{eh ogkmel kbxblw{x 8d sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc {aluxgao,
6/4584c .4/99 jjal' vneoal sb{ bhheh/ OJT KHKl;0 3/48 .N jexb xa AN'= 9/7; .N vbtb xa
AN'= 9/>8 .N atxna xa AN'= 5/;5 .AN'/
L8d Ogkmel{bleo - Nwhtarugoaoe0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal,
6/6>64c .6/443 jjal' ai deopeoe db{eh ogkmel kbxblw{x 8d sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc
{aluxgao, 6/4586c .4/43 jjal' nwhtarugoaoe sb{ bhheh/ OJT HJ[A .vvj'0 >/57 .4N vbtb AN'=
9/53 .4N atxna xa AN'/
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L8d Ogkmel{bleo - 4,9*hgjexnwlvneoal0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal,
6/6>43c .6/465 jjal' ai deopeoedb{eh ogkmel kbxblw{x 8d sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc
{aluxgao, 6/4527c .4/65 jjal' 4,9hgjexnwlvneoal sb{ bhheh/ OJT KHKl;.vvj'0 9/7; .4N jexb xa
KN;'= 9/38 .N vbtb xa AN'= 8/99 .AN'= 4/46 .9N ao KN;{'/
L8d Kadblxa{bleo - Vneoal0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal, 6/2264c
.6/499 jjal' ai deopeoedb{eh kadblx kbxblw{x 8d sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc {aluxgao,
6/45;3c .4/99 jjal' vneoal sb{ bhheh/ CKJ[0 ;/73 jgo .>3%', j!p0 78, 99 .K4N8, KA', 56 .A'=
5/9> jgo .22%', j!p0 22;, 32 .K4N4A', 53 .KN4'= 9/27 jgo .4%', uomoaso {ud{xboke/
L8d Kadblxa{bleo - nwhtarugoaoe0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal,
6/6768c .6/443 jjal' ai deopeoedb{eh kadblx kbxblw{x 8d sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc
{aluxgao, 6/487>c .4/43 jjal' nwhtarugoaoe sb{ bhheh/ CKJ[0 ;/4> jgo .78%', j!p0 26>, >4 .
K4N4', 58 .KA'= 9/75 jgo .9%', j!p0 2;>, 24; .KN;', 26> .KN;', >4 .K4N4', 58.KA'/
L8d Kadblxa{bleo - 4,9*hgjexnwlvneoal0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal,
6/6>53c .6/465 jjal' ai deopeoedb{eh kadblx kbxblw{x 8d sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc
{aluxgao, 6/4962c .4/65 jjal' 4,9hgjexnwlvneoal sb{ bhheh/ CKJ[0 5/58 jgo .266%', j!p0 2;9,
242 .KN;', 26> .KA', 37 .KNA'/
Go ebkn ai xne bdaye kb{e{, xne ilb{m{ sete {ebleh u{goc b {xbohbth tuddet {evxuj boh kavvet sgte,
eybkubxeh ygb te{vgtbxat uoxgl xne {aluxgao dagleh, xneo ilu{neh sgxn vute, jalekulbt a~wceo/ Xne
{aluxgao sb{ eybkubxeh!ilu{neh ;5 xgje{/ Bixet xng{, b kao{xbox a~wceotgkn eoygtaojeox sb{
adxbgoeh u{goc b vte{{utgpeh dbllaao/ Xne {aluxgao sb{ bllaseh xa {xgt uohet kao{xbox a~wceo
vte{{ute iat 482 n/ Bixet xne a~ghbxgao sb{ kajvlexe, xne {aluxgao sb{ jbhe goxa b {luttw u{goc
kelgxe jehgb, boh iglxeteh dw ctbygxw xntaucn e~xtb igoe iglxet vbvet bvvta~gjbxelw aoexngth iglleh sgxn
{glgkb cel, xa ibkglgxbxe tejaybl ai jexbl/
Xbdle 4 vte{eox{ xne e~vetgjeoxbl hbxb iat xne igt{x {ex ai kbxblw{e{, boh g{ hg{ku{{eh go iutxnet hexbgl
go xne te{ulx{ boh hg{ku{{gao {ekxgao/
Aveo*Bgt Kbxblw{e{0
Aoke gogxgbl kbxblwxgk a~ghbxgao hbxb nbh deeo cbxneteh, xne vte{eoke ai vute, jalekulbt a~wceo sb{
tejayeh, boh xne a~ghbxgao{ sete tuo go aveo bgt iat kajvbtbdle bjauox{ ai xgje .482 n', u{goc
aolw Kadb{eh kbxblw{x{, b{ Og nbh deeo {naso xa de goeiiekxgye/
L5b Kadblxa{bleo - Vneoal0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc 86jL jexnboal, 6/2676c
.6/499 jjal' ai exnwleoedb{eh kadblx kbxblw{x 5b sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc {aluxgao,
6/435>c .4/99 jjal' vneoal sb{ bhheh/ CKJ[0 ;/32 jgo .266%' j!p0 78, 55 .K8N3'/ OJT KHKl;
.vvj'0 9/7; .4N jexb xa KN;'= 9/38 .N vbtb xa AN'= 8/99 .AN'= 4/46 .9N ao KN;{'/
L5b Kadblxa{bleo - Nwhtarugoaoe0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc 86jL jexnboal,
6/67>9c .6/443 jjal' ai exnwleoedb{eh kadblx kbxblw{x 5b sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc
{aluxgao, 6/45;>c .4/43 jjal' nwhtarugoaoe sb{ bhheh/ CKJ[0 ;/4; jgo .92%', j!p0 78, 55 .
K8N3'= 9/;2 jgo .;5%', j!p0 2;>, 24; .KN;', 26> .KN;', 75, >4 .K4N4', 97, 58 .KA'= >/>2 jgo
.5%', j!p0 2;>, 244, 226, 75, >4, 97/
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Kadblx .GG' Bkexbxe - 4,9*hgjexnwlvneoal0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc 86jL
jexnboal, 6/6726c .6/465 jjal' ai kadblx .GG' bkexbxe sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc
{aluxgao, 6/4592c .4/65 jjal' 4,9hgjexnwlvneoal sb{ bhheh/ CKJ[0 5/6; jgo .266%', j!p0 244,
263 .KN;', 72 .A', 33 .KN4'/ OJT KHKl;.vvj'0 9/7; .4N jexb xa KN;'= 9/38 .N vbtb xa AN'=
8/99 .AN'= 4/46 .9N ao KN;{'/
Go ebkn ai xne bdaye kb{e{, xne {aluxgao sb{ bllaseh xa {xgt go bo aveo Etleojewet ilb{m uohet
oatjbl bxja{vnetgk kaohgxgao{ .2 bxj, 46K, nujghgxw uomoaso, 275 ix/ eleybxgao' iat 482 n/
Bixet xne a~ghbxgao sb{ kajvlexe, xne {aluxgao sb{ jbhe goxa b {luttw u{goc kelgxe jehgb, boh iglxeteh
dw ctbygxw xntaucn e~xtb igoe iglxet vbvet bvvta~gjbxelw aoexngth iglleh sgxn {glgkb cel, xa ibkglgxbxe
tejaybl ai jexbl/
A~wceo0Kadblx .GG' Bkexbxe - Vneoal0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc 86jL jexnboal, 6/6329c
.6/499 jjal' ai kadblx .GG' bkexbxe sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc {aluxgao, 6/4524c .4/99
jjal' vneoal sb{ bhheh/ CKJ[0 ;/97 jgo .266%', j!p0 26>, >4 .K4N4', 58 .KA'/ OJT KHKl;0
3/48 .N jexb xa AN'= 9/7; .N vbtb xa AN'= 9/>8 .N atxna xa AN'= 5/;5 .AN'/
Kadblx .GG' Bkexbxe - Nwhtarugoaoe0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc 86jL jexnboal,
6/6372c .6/443 jjal' ai kadblx .GG' bkexbxe sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc {aluxgao,
6/453;c .4/43 jjal' nwhtarugoaoe sb{ bhheh/ CKJ[0 ;/42 jgo .5%', j!p0 26>, >4 .K4N4', 58 .
KA'= 9/54 jgo .75%', j!p0 2;>, 24; .KN;', 26> .KN;', >4 .K4N4', 58.KA'/ OJT KHKl;.vvj'0
9/7; .4N jexb xa KN;'= 9/38 .N vbtb xa AN'= 8/99 .AN'= 4/46 .9N ao KN;{'/
Kadblx .GG' Bkexbxe - 4,9*hgjexnwlvneoal0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc 86jL
jexnboal, 6/63>6c .6/465 jjal' ai kadblx .GG' bkexbxe sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc
{aluxgao, 6/4539c .4/65 jjal' 4,9hgjexnwlvneoal sb{ bhheh/ CKJ[0 5/6; jgo .266%', j!p0 244,
263 .KN;', 72 .A', 33 .KN4'/ OJT KHKl;.vvj'0 9/7; .4N jexb xa KN;'= 9/38 .N vbtb xa AN'=8/99 .AN'= 4/46 .9N ao KN;{'/
Go ebkn ai xne bdaye kb{e{, xne ilb{m{ sete {ebleh u{goc b {xbohbth tuddet {evxuj boh kavvet sgte,
eybkubxeh ygb te{vgtbxat uoxgl xne {aluxgao dagleh, xneo ilu{neh sgxn vute, jalekulbt a~wceo/ Xne
{aluxgao sb{ eybkubxeh!ilu{neh ;5 xgje{/ Bixet xng{, b kao{xbox a~wceotgkn eoygtaojeox sb{
adxbgoeh u{goc b vte{{utgpeh dbllaao/ Xne {aluxgao sb{ bllaseh xa {xgt uohet kao{xbox a~wceo
vte{{ute iat 482 n/ Bixet xne a~ghbxgao sb{ kajvlexe, xne {aluxgao sb{ jbhe goxa b {luttw u{goc
kelgxe jehgb, boh iglxeteh dw ctbygxw xntaucn e~xtb igoe iglxet vbvet bvvta~gjbxelw aoexngth iglleh sgxn
{glgkb cel, xa ibkglgxbxe tejaybl ai jexbl/
Te{ulx{ bte vte{eoxeh go Xbdle 8/
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Kaavetbxgye Hbxb0
Xbdle 5 cgye{ bll hbxb bybglbdle iat xne eoxgte te{ebtkn ctauv, iat a~ghbxgao{ vetiatjeh sgxn ybtgau{lw
{ud{xgxuxeh Og boh Kadb{eh kbxblw{x{, vetiatjeh go a~wceo tgkn eoygtaojeox{/ Eiiatx{ sete jbhe
xa u{e najaceoau{ e~vetgjeoxbl xeknogrue boh jbgoxbgo b kbxblw{g{ xgje ai 482 n/
Kavvet .GG' Db{eh Kbxblw{e{0
Kavvet .GG' db{eh lgcboh{ sete {woxne{gpeh boh xe{xeh iat a~ghbxgye bdglgxw ao {elekxeh vneoal{, xa
xe{x xne gjvatxboke ai bo uovbgteh elekxtao go kbxblwxgk lgcboh kbvbkgxw/
L5b Kavvet{bleo - Vneoal0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal, 6/6993c
.6/2>9 jjal' ai exnwleoedb{eh kavvet kbxblw{x 5b sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc {aluxgao,
6/2/>95c .2/>9 jjal' vneoal sb{ bhheh/ CKJ[0 ;/97 jgo .266%', j!p0 26>, >4 .K4N4', 58 .KA'/
OJT KHKl;0 3/48 .N jexb xa AN'= 9/7; .N vbtb xa AN'= 9/>8 .N atxna xa AN'= 5/;5 .AN'/
L5b Kavvet{bleo - Nwhtarugoaoe0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal,
6/6377c .6/2>9 jjal' ai exnwleoedb{eh kavvet kbxblw{x 5b sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc
{aluxgao, 6/4697c .2/>9 jjal' nwhtarugoaoe sb{ bhheh/ CKJ[0 9/58 jgo .266%', j!p0 2;>, 24; .
KN;', 26> .KN;', >4 .K4N4', 58.KA'/ OJT HJ[A .vvj'0 >/57 .4N vbtb AN'= 9/53 .4N atxna xa AN'/
L5b Kavvet{bleo - 4,9*hgjexnwlvneoal0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal,
6/69>8c .6/2>9 jjal' ai exnwleoedb{eh kavvet kbxblw{x 5b sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc
{aluxgao, 6/4438c .4/65 jjal' 4,9hgjexnwlvneoal sb{ bhheh/ CKJ[0 5/82 jgo .266%', j!p0 244,
263 .KN;', 72 .A', 33 .KN4'/ OJT KHKl;.vvj'0 9/7; .4N jexb xa KN;'= 9/38 .N vbtb xa AN'=
8/99 .AN'= 4/46 .9N ao KN;{'/
L5b Kavvet{bleo - Vneoal0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal, 6/2663c
.6/48; jjal' ai exnwleoedb{eh kavvet kbxblw{x 5b sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc {aluxgao,
6/4435c .4/8; jjal' vneoal sb{ bhheh/ CKJ[0 ;/97 jgo .266%', j!p0 26>, >4 .K4N4', 58 .KA'/
OJT KHKl;0 3/48 .N jexb xa AN'= 9/7; .N vbtb xa AN'= 9/>8 .N atxna xa AN'= 5/;5 .AN'/
L5b Kavvet{bleo - Nwhtarugoaoe0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal,
6/2668c .6/48; jjal' ai exnwleoedb{eh kavvet kbxblw{x 5b sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc
{aluxgao, 6/49>5c .4/8; jjal' nwhtarugoaoe sb{ bhheh/ CKJ[0 9/95 jgo .266%', j!p0 2;>, 24; .
KN;', 26> .KN;', >4 .K4N4', 58.KA'/ OJT HJ[A .vvj'0 >/57 .4N vbtb AN'= 9/53 .4N atxna xa
AN'/
L5b Kavvet{bleo - 4,9*hgjexnwlvneoal0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc ;6jL jexnboal,
6/2647c .6/48; jjal' ai exnwleoedb{eh kavvet kbxblw{x 5b sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc{aluxgao, 6/;62;c .4/8; jjal' 4,9hgjexnwlvneoal sb{ bhheh/ CKJ[0 5/65 jgo .266%', j!p0 244,
263 .KN;', 72 .A', 33 .KN4'/ OJT KHKl;.vvj'0 9/7; .4N jexb xa KN;'= 9/38 .N vbtb xa AN'=
8/99 .AN'= 4/46 .9N ao KN;{'/
Go ebkn ai xne bdaye kb{e{, xne ilb{m{ sete {ebleh u{goc b {xbohbth tuddet {evxuj boh kavvet sgte,
eybkubxeh ygb te{vgtbxat uoxgl xne {aluxgao dagleh, xneo ilu{neh sgxn vute, jalekulbt a~wceo/ Xne
{aluxgao sb{ eybkubxeh!ilu{neh ;5 xgje{/ Bixet xng{, b kao{xbox a~wceotgkn eoygtaojeox sb{
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adxbgoeh u{goc b vte{{utgpeh dbllaao/ Xne {aluxgao sb{ bllaseh xa {xgt uohet kao{xbox a~wceo
vte{{ute iat 482 n/ Bixet xne a~ghbxgao sb{ kajvlexe, xne {aluxgao sb{ jbhe goxa b {luttw u{goc
kelgxe jehgb, boh iglxeteh dw ctbygxw xntaucn e~xtb igoe iglxet vbvet bvvta~gjbxelw aoexngth iglleh sgxn
{glgkb cel, xa ibkglgxbxe tejaybl ai jexbl/
Te{ulx{ bte vte{eoxeh go Xbdle 9/
Kaoxtallgoc iat Xgje0Nwhtarugoaoe boh exnwleoe{bleo 5b sete kna{eo xa xe{x iat tebkxgao xgje ai a~ghbxgao{0
L8d Kadblxa{bleo - Nwhtarugoaoe0 Xa b 245jL Etleojewet ilb{m kaoxbgogoc 56jL jexnboal,
6/786c .6/;2> jjal' ai exnwleoedb{eh kadblx kbxblw{x 5b sb{ bhheh sgxn {xgttgoc/ Xa xne te{ulxgoc
{aluxgao, ;/56>c .;/2> jjal' nwhtarugoaoe sb{ bhheh/ Blgruax{ sete kallekxeh bx ;6jgouxe
goxetybl{/ Xne {aluxgao sb{ bllaseh xa {xgt go bo aveo Etleojewet ilb{m uohet oatjbl bxja{vnetgk
kaohgxgao{ .2 bxj, 46K, nujghgxw uomoaso, 275 ix/ eleybxgao'/ Bixet ;6 jgouxe{0 CKJ[0 ;/4; jgo
.>7%', j!p0 78, 55 .K8N3'= 9/5; jgo .22%', j!p0 26>, >4 .K4N4', 58 .KA'/ OJT KHKl;.vvj'0
9/7; .4N jexb xa KN;'= 9/38 .N vbtb xa AN'= 8/99 .AN'= 4/46 .9N ao KN;{'/
Xng{ {ucce{x{ xnbx a~ghbxgao akkut{ yetw tbvghlw iat xng{ vbtxgkulbt lgcboh!{ud{xtbxe kajdgobxgao/
@ad(Ouj @ad(Obje [xagkngajextw Db{g{ D;LWV(E(.Nbtxtee' D;LWV(E.mkbl!jal' E
28223 Elxnwleoehgbjgoe K4N>O4 9;22-C.h,v' 276/5>9>>97 227578/7>9>
2824; 5jexnwl{blgkwlblhenwhe K>N>A4 9;22-C.h,v' 896/484;>24 4>>>69/4;98
282>2 4,5hgnwhta~wdeopblhenwhe K3N9A; 9;22-C.h,v' 879/25>956> ;22;88/62>>282>4 Avneowleoehgbjgoe K9N>O4 9;22-C.h,v' ;8;/69;989; 425435/5459
28234 L5B(-(Og K2>N2>O4OgA4 9;22-C.h,v' 4895/;3;;88 258368;/794
28472 L5B(-(Ka K2>N2>KaO4A4.4' 9;22-C.h,v' 4;;7/>;6>> 289>498/7;9
28;35 L8D(-(Ka K46N28KaO4A8.4' 9;22-C.h,v' 4598/2;2264 2967625/;88
28;74 L8D(-(Og K46N28O4OgA8 9;22-C.h,v' 49>7/935>99 29>3375/>2;
2887; L8D(-(Og((JeAN K46N28O4OgA8 9;22-C.h,v' 49>7/34;447 29>3>45/5;8
28875 L8D(-(Og((JeAN K46N28O4OgA8 9;22-C.h,v' 49>7/34;444 29>3>45/547
28569 L8D(-(Og((JeAN((Ly(;(CEAJ K46N28O4OgA8 9;22-C.h,v' ;274/9>57; 466;8;7/259
2852; L8D(-(Ka((JeAN K46N28KaO4A8.4' 9;22-C.h,v' 4598/23>865 2967685/643
28465 L8D K46N29O4A; 9;22-C.h,v' 2263/4;>593 978>64/2953
28256 L5B K2>N46O4A4 9;22-C.h,v' 75>/2>2237; 962493/;2;3
L5B(JeAN 75>/4668797 962437/8;59 24/2427934;
L8D(JeAN 22>4/8>23 384623/7672 83425/38;8;
47/342258; mkbl!jal
24/2427934; mkbl!jal
E(iat(exnwleoe!KN;!Ka(te{ulxgoc(itaj(JeAN(kblkulbxgao{(y{(cb{(vnb{e0
E(iat(dbte(exnwleoe!KN;(te{ulxgoc(itaj(JeAN(kblkulbxgao{(y{(cb{(vnb{e0
7;5;8/>5277
;78;78/24>>
3>337/64578
3>3>6/89729
Xbdle 2/ [elekxeh kajvuxbxgaobl knejg{xtw te{ulx{/
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Xbdle 5/ Kao{alghbxeh kbxblwxgk a~ghbxgao hbxb iat eoxgte te{ebtkn ctauv/
Ogkmel# #Vneoal# Nwhtarugoaoe# 4,95HJV#
[ud{xtbxe# A~ghgpeh# [ud{xtbxe# A~ghgpeh# [ud{xtbxe# A~ghgpeh#
nwhta!exnwleoe-- 266- 6- 266- 6- 266- 6-
- 266- 6- 266- 6- 266- 6-
knlata!exnwleoe-- 266- 6- 266- 6- 266- 6-
- 266- 6- 266- 6- 266- 6-
jexnwl!exnwleoe-- 266- 6- 266- 6- 266- 6-
- 266- 6- 266- 6- 266- 6-
nwhta~w!exnwleoe-- 266- 6- 266- 6- 266- 6-
- 266- 6- 266- 6- 266- 6-
nwhta!hgbjgoadeopeoe-- 266- 6- 266- 6- 266- 6-
- 266- 6- 266- 6- 266- 6-
knlata!hgbjgoadeopeoe-- 266- 6- 77/9- 6/2- 266- 6-
- 266- 6- 266- 6- 266- 6-
jexnwl!hgbjgoadeopeoe-- 266- 6- 266- 6- 266- 6-
- 266- 6- 266- 6- 266- 6-
nwhta~w!hgbjgoadeopeoe-- 266- 6- 266- 6- 266- 6-
- ***- ***- ***- ***- ***- ***-
Kadblx# #Vneoal# Nwhtarugoaoe# 4,95HJV#
[ud{xtbxe# A~ghgpeh# [ud{xtbxe# A~ghgpeh# [ud{xtbxe# A~ghgpeh#
nwhta!exnwleoe-- 266- 6- 8>- 84- ;5- 95-
- 266- 6- 78- 9- 2>- >4-
knlata!exnwleoe-- 266- 6- 5- 75- 266- 6-
- 266- 6- ***- ***- 2>- >4-
jexnwl!exnwleoe-- 266- 6- 6- 266- 52- 87-
- ;4- 9>- 6- 266- 83- 5;-
nwhta~w!exnwleoe-- 266- 6- 266- 6- 9- 78-
- 266- 6- ***- ***- 34- 4>-
nwhta!hgbjgoadeopeoe-- 266- 6- ***- ***- 5- 75-
- 266- 6- 266- 6- 2- 77-
knlata!hgbjgoadeopeoe-- 266- 6- >>- 24- 39- 48-
- 266- 6- 76- 26- 39- 48-
jexnwl!hgbjgoadeopeoe-- 266- 6- 36- ;6- 46- >6-
- 266- 6- 6- 266- 6- 266-
nwhta~w!hgbjgoadeopeoe-- 24- >>- 6- 266- 6- 266-
- ***- ***- ***- ***- 6- >6-
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Xbdle 9/ E~vetgjeoxbl hbxb iat Kudb{eh kbxblw{e{ vetiatjeh uohet kao{xbox vte{{ute a~wceo/
Ku.GG'#
Kbxblw{e{# lgcboh# jexbl# {ud{xtbxe#.c'# kbxblw{x#.c'# a~ghbxgao#.%'b#
vneoal#exnwleoe#
Ku#
6/2>95# 6/6958# 6#
deopa# 6/4835# 6/2663# 6#
nwhtarugoaoe# exnwleoe# 6/4697# 6/6993# 6#deopa# 6/49>5# 6/2668# 6#
4,9NHJV#exnwleoe# 6/4438# 6/69>8# 6#
deopa# 6/;62;# 6/2647# 6#
#
Kajvuxbxgaobl Satm0
Heo{gxw iuokxgaobl xneatw boh {ejgejvgtgkbl {elikao{g{xeox igelh jexnah{ sete u{eh xa jahel xne
ybtgau{ tebkxbox{, lgcboh vtahukx{, boh jexbllbxeh kajvle~e{/ Xne xwvgkbl bvvtabkn sb{ xa duglh b
{xtukxute boh bvvlw gokteb{goclw tadu{x xneatw boh
db{g{ {ex avxgjgpbxgao{/ Ceajextw avxgjgpbxgao{
sete kbttgeh aux decgoogoc sgxn TNI![XAC bohkuljgobxgoc sgxn D;LWV!9;22C*.h,i',
goktejeoxgoc xne xneatw!db{g{ {ex{ xa ngcnet leyel{
{laslw, {a b{ xa avxgjgpe kajvuxbxgaobl ka{x/
Iallasgoc xng{, ygdtbxgaobl iterueokge{ boh OJT
{vekxtb sete vtehgkxeh u{goc D;LWV!9;22C*.h,i'/
Xne avxgjgpeh lgcboh {xtukxute{ sete xneo
jexbllbxeh, u{goc ogkmel boh kadblx, boh
Igc 5/ [xtukxute ai jexnwl{ud{xgxuxeh L5B, kblkulbxeh bx
Igc 8/ Ctbvn{ ai kbxblwxgk hbxb cbxneteh dw eoxgte te{ebtkn ctauv/
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avxgjgpeh sgxn gokteb{goclw tadu{x xneatw!db{g{ {ex{, b{ he{ktgdeh bdaye/
Ctauoh {xbxe eoetcge{ iat xne hgiieteox lgcboh{ go cb{
vnb{e sete kajvbteh xa xne ctauoh {xbxe eoetcge{
iat xne jexbllbxeh lgcboh{ go cb{ vnb{e/ Bx xng{ vagox,
xne kblkulbxgao{ sete xneo tevebxeh go jexnboal
{alyeox, b{ xng{ sb{ aut vtgjbtw e~vetgjeoxbl
{alyeox/ Cgyeo bherubxe xgje, aoe kaulh u{e dajd
kblatgjextw boh GT {vekxta{kavw xa kajvbte xne
xneatexgkbllw kblkulbxeh yblue{ iat {aje ai xne{e
kajvauoh{ xa xna{e adxbgoeh e~vetgjeoxbllw/
Xne te{ulxgoc {xtukxute iat jexnwl{ud{xgxuxeh L5b
sb{ {lgcnxlw oaovlbobt, hue xa xne itee taxbxgao ai xne
KO daoh{ bxxbkneh xa xne exnwleoe dbkmdaoe/ Goxete{xgoclw, xne {xtukxute iat dbte deopa{bleo 5d
sb{ hg{xgokxlw oaovlbobt, sgxn xne itee taxbxgao ai xne gjghe iuokxgaobl ctauv{ te{ulxgoc go xsa
hgiieteox laseoetcw ceajextw avxgjgpbxgao{, b{ vgkxuteh go igcute{ 8 boh 5/ Xne eoetcw hgiieteoke
dexseeo xne xsa {bleo{ go cb{ boh {alyeox vnb{e g{ {naso go xbdle 2/
Xne avxgjgpeh {xtukxute{b
sete xneo jexbllbxehsgxn ogkmel at kadblx, xneo iutxnet avxgjgpeh b{ he{ktgdeh
bdaye, uoxgl ceajextge{ boh eoetcge{ sete adxbgoeh bx
xne D;LWV!9;22C*.h,v' leyel/ Xne vtake{{ sb{ bcbgo
tevebxeh daxn sgxn boh sgxnaux jexnboal {alybxgao, go
athet xa nelv eyblubxe xne gjvatxboke ai jexnboal go
{xbdglgpgoc xne ctauoh {xbxe {xtukxute{/ Iallasgoc xne
bhhgxgao ai xne jexbl keoxet{, xne eoetcge{ iat xne xsa
{xtukxute{ hgiieteh dw b jbtcgo ai bdaux 47 mkbl!jal, b{
{naso go xbdle 2/ Xng{ oax go{gcogigkbox oujdet
{ucce{x{ xnbx xne knagke ai {alyeox va{{gdlw vlbw{ bo
gjvatxbox tale go xne {xtukxute boh dw e~xeo{gao, xne
iuokxgao ai xne{e kbxblw{x{/
Bhhgxgaobl kajvuxbxgaobl satm sb{ haoe sgxn te{vekx xa xne kadblxa{bleo lgcboh{, b{ xne{e
hg{vlbweh kbxblwxgk bkxgygxw, sneteb{
xne ogkmel.GG' db{eh {bleo{ hgh oax/
[vekgigkbllw, dekbu{e xne kadblx
kajvauoh{ nbh b {gocle uovbgteh
elekxtao, TANI boh UNI ceajextw
boh eoetcw avxgjgpbxgao{ sete
vetiatjeh ao xne exnwleoedb{eh
lgcboh 5b, kajvle~eh sgxn kadblx.GG'/Xne te{ulx{ ai xne{e kblkulbxgao{ bte
hg{vlbweh go igcute 7, sgxn eoetcw
kajvbtg{ao{ {naso go xbdle 2/ B{
{naso go igcute 7, xne {xtukxute
te{ulxgoc itaj uote{xtgkxeh Nbtxtee
b
Cbu{{gbo 6;0 D;LWV!9;22C*.h,v'
Igc 9/ [xtukxute ai nwhta~w{ud{xgxuxeh L8d,
kblkulbxeh bx D;LWV!9;22C*.h,i'
Igc 3/Blxetobxe {xtukxute ai nwhta~w{ud{xgxuxeh L8d,
kblkulbxeh bx DV>9!9;22C*.h,v'
Igc >/ [xtukxute iat kadblxa{bleo L5b, te{ulxgoc itaj D;LWV!9;22C*.h,v'
ceajextw avxgjgpbxgao go Cbu{{gbo 6;/
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Iakmd kblkulbxgao{ hg{vlbweh b {lgcnxlw hgiieteox ceajextw jgogjuj, go sngkn xne jexbl bvvebt{ xa
nbye kaathgobxeh go b yetw {rubte vlbobt kaoigcutbxgao/ Xng{ g{ {lgcnxlw hgiieteox itaj xne te{ulx{
adxbgoeh u{goc te{xtgkxeh heceoetbxeatdgxbl kblkulbxgao{ bx b jukn ngcnet leyel ai xneatw boh db{g{
{ex vgkxuteh go igcute >, go sngkn xne jexbl
keoxet g{ {lgcnxlw hg{xatxeh itaj degoc vlbobt/
B{ {eeo go igcute 26, xne ile~gdglgxw ai
xne lgcboh dbkmdaoe g{ la{x sgxn xne bhhgxgao
ai xne jexbl keoxet/ Xne kadblx[kngii db{e
{bleo bhavx{ bo e~xtejelw vlbobt eoetcw
jgogjuj, bllasgoc jukn dexxet {xetgk bkke{{
iat xtbo{ lgcboh{ xa kaathgobxe xa xne jexbl
keoxet/ Xng{ g{ b va{{gdle g{{ue, b{ {eeo go
igcute 22, snete b va{{gdle {uveta~ghe
xtbo{gxgao {xbxe nb{ deeo jaheleh/ Xne
exnwleoe dbkmdaoe leoh{ b ketxbgo ile~gdglgxw
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