MR 0176 00

&NACE' NACE Standard MRO176-2000 Item No. 21303

THE C O R R O S I O N S O C I E T Y

Standard Material Requirements

Metallic Materials for Sucker-Rod Pumps for Corrosive Oilfield Environments

This NACE International standard represents a consensus of those individual members who have reviewed this document, its scope, and provisions. Its acceptance does not in any respect preclude anyone, whether he has adopted the standard or not, from manufacturing, marketing, purchasing, or using products, processes, or procedures not in conformance with this standard. Nothing contained in this NACE International standard is to be construed as granting any right, by implication or otherwise, to manufacture, sell, or use in connection with any method, apparatus, or product covered by Letters Patent, or as indemnifying or protecting anyone against liability for infringement of Letters Patent. This standard represents minimum requirements and should in no way be interpreted as a restriction on the use of better procedures or materials. Neither is this standard intended to apply in all cases relating to the subject. Unpredictable circumstances may negate the usefulness of this standard in specific instances. NACE International assumes no responsibility for the interpretation or use of this standard by other parties and accepts responsibility for only those official NACE International interpretations issued by NACE International in accordance with its governing procedures and policies which preclude the issuance of interpretations by individual volunteers

Users of this NACE International standard are responsible for reviewing appropriate health, safety, environmental, and regulatory documents and for determining their applicability in relation to this standard prior to its use. This NACE International standard may not necessarily address all potential health and safety problems or environmental hazards associated with the use of materials, equipment, and/or operations detailed or referred to within this standard. Users of this NACE International standard are also responsible for establishing appropriate health, safety, and environmental protection practices, in consultation with appropriate regulatory authorities if necessary, to achieve compliance with any existing applicable regulatory requirements prior to the use of this standard.

CAUTIONARY NOTICE: NACE International standards are subject to periodic review, and may be revised or withdrawn at any time without prior notice. NACE International requires that action be taken to reaffirm, revise, or withdraw this standard no later than five years from the date of initial publication. The user is cautioned to obtain the latest edition. Purchasers of NACE International standards may receive current information on all standards and other NACE International publications by contacting the NACE International Membership Services Department, P.O. Box 21 8340, Houston, Texas 7721 8-8340 (telephone +1 281i228-6200).

Reaffirmed 03-28-2000 Approved January 1976 Revised October 1994

NACE International P.O. Box 218340

Houston, TX 77218-8340 +1 21 81228-6200

ISBN 1-57590-099-8 O 2000. NACE International

COPYRIGHT NACE InternationalLicensed by Information Handling ServicesCOPYRIGHT NACE InternationalLicensed by Information Handling Services

STD.NACE MRU17b-ENGL 2000 I b1152981 0502837 m

MRO176-2000

Foreword

This standard specifies metallic material requirements for the construction of sucker-rod pumps for service in corrosive oilfield environments. API”’ Spec 1 IAX’ provides dimension requirements that ensure the interchangeability of component parts. However, that document does not provide material specifications or guidelines for the proper application of various API pumps. API RP 11 AR2 does list the general advantages and disadvantages of the various pump types and lists the acceptable materials for barrels and plungers; and API RP 11 BR3 supplements API Spec 11AX by providing corrosion control methods using chemical treatment. This NACE standard should supplement the use of the aforementioned API publications.

This standard was originally published in 1976 and was revised in 1994 by NACE Task Group T-1 F- 15 on Sucker-Rod Pumps for Corrosive Environments, a component of Unit Committee T-1 F on Metallurgy of Oilfield Equipment. It was reviewed by Task Group T-1 F-28 and reaffirmed by T-1 F in 2000. This standard is issued by NACE International under the auspices of Group Committee T-1 on Corrosion Control in Petroleum Production.

In NACE standards, the terms shall, must, should, and m y are used in accordance with the definitions of these terms in the NACE Publications Style Manual, 3 ed., Paragraph 8.4.1.8. Shall and must are used to state mandatory requirements. Should is used to state that which is considered good and is recommended but is not absolutely mandatory. May is used to state that which is considered optional.

‘’I American Petroleum Institute (API), 1220 L St. NW, Washington, DC 20005.

NACE International i


STD-NACE MROL7b-ENGL 2000 m b45278L 0502838 522 9

MRO176-2000

NACE International Standard

Material Requirements

Metallic Materials for Sucker-Rod Pumps for Corrosive Oilfield Environments

Contents

1 . General ...................................................................................................................... 1 2 . Description of Tables .................................................................................................. 1 3 . Barrel Selection .......................................................................................................... 2 4 . Pump Selection .......................................................................................................... 2 5 . Maintenance Record System ...................................................................................... 3 Table 1 ........................................................................................................................... 3 Table 2 ........................................................................................................................... 4 Table 3 ........................................................................................................................... 5 Table 4 ........................................................................................................................... 6 Table 5 ........................................................................................................................... 7 Table 6 ......................................................................................................................... 10 Table 7 ......................................................................................................................... 12 Table 8 ......................................................................................................................... 12 Table 9 ......................................................................................................................... 12 Table 1 O ....................................................................................................................... 13 References ................................................................................................................... 13 Appendix A ................................................................................................................... 13 Appendix B ................................................................................................................... 14 Appendix C ................................................................................................................... 15

ii NACE International


M R01 76-2000

Section 1 : General

1.1 An adequate chemical treatment program utilizing selection of proper corrosion inhibitors and application techniques is necessary for optimum performance of sucker- rod pumping equipment in a corrosive environment. However, control of direct attack on pump materials may be accomplished by materials selection alone or by materials selection in combination with chemical treatment.

1.2 The recommended materials in this standard are presented in tables and listed in order of preferred usage in six different environments with varying degrees of corrosiveness and with and without possible abrasion. The listed materials have performed satisfactorily when used in

the specified environments. These material recommendations are based on field experience.

1.3 This standard is not intended to preclude the development and testing of new materials that might improve sucker-rod pump performance. It is the responsibility of the user to fully evaluate the performance of any new material prior to its use.

1.4 The designations and mechanical properties of the materials covered by this standard are listed in selected tables.

Section 2: Description of Tables

2.1 The specific quantities of water, hydrogen sulfide (H$), and carbon dioxide (CO,) that are used to classify the corrosiveness of a fluid as mild, moderate, or severe are detailed in Table 1.

2.1 .I Explanations of the mild, moderate, and severe metal-loss corrosion classifications given in Table 1 are intended to be a guide for the user. Currently, there is no clear consensus on which combination of produced fluids constitutes mild, moderate, or severe corrosive environments for subsurface pumps. There can be amounts of H,S, CO,, and water that do not clearly fall into one of the three combinations. The user's operation experiences coupled with analysis of failures should be used to develop the appropriate classification.

2.1.2 The three corrosion classifications are identified by amounts of water, H,S, and CO, in the produced fluids. There are other constituents in the fluid that can influence corrosion. General comments on these constituents follow:

2.1.2.1 Oxygen-Oxygen can be very destructive to the system. If oxygen is discovered, every attempt should be made to free the system of oxygen, or at least bring it to below 50 ppb dissolved oxygen. Severe corrosion can be expected above 50 ppb dissolved oxygen.

2.1.2.2 Chlorides-High chlorides can lead to pitting corrosion. High-chloride service conditions should be assumed to exist when the total dissolved solids exceed 10,000 mg/L and/or total chlorides exceed 6,000 mg/L.

2.1.2.3 H,S (Sour Service)Sour service conditions should be assumed to exist when H,S is present in the system at partial pressures equal to or greater than 0.35 kPa (0.050 psi). When operating in sour service, the material for subsurface pump fittings (connectors, bushings, etc.) should conform to the requirements of NACE Standard MROl 75.4

2.1.2.4 Water Content-Generally, if the water content is greater than 20%, the fluid exists as a water phase with oil droplets. If the water content is less than 20%, an oil phase with water droplets can exist. Inhibitors should be used if the water content is greater than 20%.

2.1.2.5 TemperatureThe higher the temperature the greater the rate of corrosion. Temperature below the crystallization point of paraffin results in deposition of a film of paraffin that may act as a corrosion barrier.

2.1.2.6 p h T h e pH at bottomhole conditions is frequently lower (more acidic) than that measured at the surface. After acidizing, the pH should be monitored to ensure that the fluid does not attack chrome plate if chrome plate is used in the pump.

2.1.2.7 Pressure-Pressure does not have a direct influence on the general corrosion rate. However, the system pressure influences the partial pressures of H,S and CO,, which have an effect on the corrosive nature of the fluids.

2.1.2.8 Velocity-Generally, the higher the velocity of produced fluids through the pump the greater the metal loss because of erosion-corrosion. .

NACE International 1


MROI 76-2000

2.1.2.9 Abrasio-Abrasion results not only from produced fluids but also from corrosion by-products, e.g., iron sulfide. If the fluids contain greater than 1 O0 ppm solids, conditions are considered abrasive.

2.2 General definitions of mild, moderate, or severe corrosive environments follow:

2.2.1 Mild metal-loss corrosive environment: Corrosion attack on downhole equipment, rods, and tubing is evident but equipment may last several years (more than three years) either with or without inhibitor treatment before corrosion-related failures occur.

2.2.2 Moderate metal-loss corrosive environment: Corrosion rates and timeto-failure are between mild and severe.

2.2.3 Severe metal-loss corrosive environment: Corrosion rates are high and corrosion failures occur in less than one year unless effective inhibitor treatment is applied.

2.3 Recommended materials for sucker-rod pumps to be used in mild, moderate, and severe metal-loss corrosive environments are listed in Tables 2, 3, and 4, respectively.

The tables are each divided into two degrees of abrasion (¡.e., “no abrasion” and “abrasion”) for each of the three corrosive environments.

2.4 A determination of the correct environmental classification for the selection of the materials to be used in a particular well should be made by an experienced corrosion or materials specialist.

2.5 The recommended pump barrels and compatible plungers are the first items shown under each environment. A plunger can be used with more than one barrel but this could alter the preferred order of usage.

2.6 The tables showing barreVplunger combinations also show the recommended material selections for valves, cages, pull tubes, valve rods, and fittings.

2.7 Materials for all parts are listed in preferred order based on optimum operating costs as determined by field experience rather than expected pump life or initial cost. In some instances, performance of these recommended materials can be similar. The total costs of pump repairs and proper material selection are discussed in Appendix A, Economic Benefits.

Section 3: Barrel Selection

3.1 Mechanical properties of the various pump barrel base 3.3 Generally, the corrosion performance of the four different materials and available surface-conditioning requirements of case-hardened barrels is comparable. Case-hardening barrels are given in Table 5. processes recommended for steel pump barrels to be used in

3.2 There is no significant difference in corrosion performance between the D l and D4 nonhardened steel barrels.

H,S environments are discussed in Appendix B.

Section 4: Pump Selection

4.1 Interrelated factors, other than the corrosive and 4.3 Standards concerning the most practical pump assembly abrasive natures of the produced fluids, that shall be for various operating conditions are unavailable; however, considered when selecting materials for a sucker-rod pump guidelines for selecting the most suitable pump for a include: particular application are given in Appendix C.

4.1.1 Type of pump.

4.1.2 Barrel length and diameter.

4.4 Materials should be selected from Tables 2 through 10 to meet the strength and hardness requirements dictated by the type of pump and anticipated operating conditions.

4.1.3 Seating depth and required material strength. 4.5 Information shown in Tables 5 through 8 lists many of the materials by specific alloy number.

4.2 For a given pump size and seating depth, the strength requirement for a barrel in a top holddown pump is greater 4.5.1 When selecting pumps, the purchaser should be than that for a barrel of a bottom holddown pump. This is the aware that common names, e.g., brass, are often used result of a top holddown pump having a greater pressure to describe alloys of significantly different compositions differential across the barrel. and properties.

2 NACE International


STD-NACE MRU27b-ENGL 2000 m h452781 0502843 037 m

MROl76-2000

4.5.2 Specific alloys should be designated as shown in with different composition, which has resulted in the tables to prevent substitution of trade name materials repetitive failures in the past.

Section 5: Maintenance Record System

5.1 A maintenance record system should be initiated to assist in reducing expenses related to sucker-rod pump failures. API 11BR details a sucker-rod pump repairhew pump log that can initiate a database for pump performance and aid in establishing a maintenance record system that should include the following factors:

5.1.1 A cross-reference file that lists the well number and pump number.

5.1.2 All of the pertinent information on the pump, including pump type and description and the complete metallurgy of the individual parts.

5.1.3 Pumping conditions.

5.1.4 Length of run.

5.1.5 Volume of fluid lifted during the run.

5.1.6 Cost, description, frequency, and type of repairs, including the type of material used in the manufacture of the replaced part or parts.

5.1.7 A method of determining the point at which replacement of the pump becomes more economically desirable than continued repair.

5.2 Effectiveness of the maintenance record system is dependent on cooperation from the pump repair facility. A study of repair records should identify the principal causes of repeated failures and also indicate the corrective measures required to solve these problems.

5.3 Record keeping should be used for tracking pump part materials and comparing the cost of repetitive failures and the cost of upgrading with more expensive materials and parts. However, because many factors other than corrosion and abrasion can cause pump failures, upgrading the metallurgy of the entire pump assembly is seldom required.

TABLE 1 CLASSIFICATION OF METAL-LOSS CORROSION FOR SUCKER-ROD PUMPS'*'

Water HzS c02

Water andlor HzS andior COZ

Water andior H2S andior COZ

Mild Metal-Loss COrrosiodB) Water cuts are less than 25"h is less than 1 O ppm is less than 250 ppm.

Moderate Metal-Loss Corrosion(B) Water cuts are between 25% and 75% is between 1 O and 1 O0 ppm is between 250 and 1,500 ppm."'

Severe Metal-Loss Corrosion'B' Water cuts are more than 75% is greater than 1 O0 pprn is greater than 1,500 ppm."'

'A'Theclassification of metal-loss corrosion is intended only as a guide for the user of subsurface pumps (see Paragraph 2.1.1). 'W For all three classifications, the higher number of the three constituents should be the guide. 'c) High concentrations of CO2 at low pressures are not corrosive, ¡.e., in shallow-depth wells less than 300 m (1,000 ft).



STD*NACE MRO17b-ENLL 2UOU E b4.52981 0502842 T 5 3 6

MR0176-2000

TABLE 2 RECOMMENDED MATERIALS FOR MILD METAL-LOSS CORROSION ENVIRONMENTS

"""""""""_""

....................... BARREL

l . Nonhardened steel

VALVES

......................

..

".

.......................................................

NO ABRASION ABRASION .............................................................................................................

PLUNGER BARREL PLUNGER .............................................................................................................

l . Chrome plate on steel l . Case hardened steel l . Chrome plate on steel

2. Spray metal on steel 2. Chrome plate on steel

1. Ball: UNS'*' S44002'" Seat: UNS S44004

VALVES"' ..............................................................................................................

2. Cobalt alloy

l . Cobalt alloy l . Spray metal on steel

2. Cobalt alloy ball, sintered carbide seat

2. Cobalt alloy ball, sintered carbide seat

CAGES CAGES ......................................................................................................................................

1. Steel 1. Steel

PULL TUBE, VALVE ROD, AND FITTINGS

PULL TUBE, VALVE ROD, AND FlITlNGS

............................................................................................................................ 1. Steel l . Steel

'*' Metals and Alloys in the Unified Numbering System (latest revision), a joint publication of the American Society for Testing and Materials LASTM) and the American Society of Automotive Engineers Inc. (SAE), Warrendale, PA. ' ) Pits In the presence of chlorides. IC) The type of valve and cage is also dependent on how hard the well is being pumped, the amount of free gas, and the pressure differential acrms the valve.



MR0176-2000

TABLE 3 RECOMMENDED MATERIALS FOR MODERATE METAL-LOSS CORROSION ENVIRONMENTS

....................................................................................

NO ABRASION ABRASION .....................................................................................

BARREL PLUNGER BARREL PLUNGER ...................................................................................

l . Brass, nonhardened l . Spray metal with nickel- copper alloy pin ends

2. Spray metal with electroless nickel pin ends

3. Heavy chrome plate on steel

2. UNS N04400'*' Same plungers as above

VALVES(*) ""..."".."".."""""""..""""""".."""""

l . Cobalt alloy

CAGES'~) ""..""".""""""""""""...""""""..""".

l . Nickel-copper alloy

2. Brass

3. Stainless steel

PULL TUBE, VALVE ROD, AND FITTINGS'B'

.."""""..""..""..."."""""..."""..""..""

l . Steel

2. Stainless steel

..

..

"

l . Chrome plate on brass l . Spray metal with nickel- copper alloy pin ends


2. Heavy chrome plate on Same plungers as above steel

3. Chrome plate on steel Same plungers as above

VALVES(*) --""..""".""_~"....."".""..."""""...."".."""""~

l . Sintered carbides

2. Cobalt alloy

CAGES'~) "".""""""."~".""....""""".""""""..""""...".

l . Nickel-copper alloy, insert or lined

2. Stainless steel, insert or lined 3. Brass, insert

PULL TUBE, VALVE ROD, AND FITTINGS@)

....................................................

l . Steel

2. Stainless steel

3. Brass 3. Brass

(*) The type of valve and cage is also dependent on how hard the well is being pumped, the amount of free gas, and the pressure differential across the valve.

See Table 8 for materials within each component.



MRO176-2000

TABLE 4 RECOMMENDED MATERIALS FOR SEVERE METAL-LOSS CORROSION ENVIRONMENTS

...................................................................................................................................... NO ABRASION ABRASION

BARREL PLUNGER BARREL PLUNGER ......................................................................................................................................

l . Nickel-copper alloy 1. Spray metal with nickel- 1. Chrome plate on nickel- 1. Spray metal with nickel- copper alloy pin ends copper alloy copper alloy pin ends



2. Brass, nonhardened Same plungers as above 2. Chrome plated on brass Same plungers as above

3. Electroless nickel coating Same plungers as above 3. Electroless nickel coating Same plungers as above on steel on brass

VALVES'") VALVES'") .......................................................................................................................................

l . Cobalt alloy l . Sintered carbides

CAGES'") CAGES'") ......................................................................................................................................

l . Nickel-copper alloy

2. Brass

1. Nickel-copper alloy, insert or lined

2. Stainless steel, insert or lined

3. Stainless steel 3. Brass, insert

PULL TUBE, VALVE ROD, PULL TUBE, VALVE ROD, AND FIlTlNGS'"' AND FllTINGS'B'

..........................................................................................................

l . Nickel-copper alloy l . Nickel-copper alloy

2. Stainless steel 2. Stainless steel

IA'The type of valve and cage is also dependent on how hard the well is being pumped, the amount of free gas, and the pressure differential across the valve. @'See Table 8 for materials within each component.



STD.NACE MR017b-ENGL SDOO II L45278L U502845 7b2

MROI 76-2000

TABLE 5

TYPICAL MECHANICAL PROPERTIES OF PUMP BARREL MATERIALS

."".""..~"""""..""..."""""""""..""""""""""~~~,""-""""""""""".""."""."""""".."""". Identification Product Description Surface Condition Base Core Base Material Typical

Symbol

PLATING "

A I

A2

A3

A4

A5

A6

A7

A8

A9

"_......."__"".

Chrome plate on steel

Chrome plate on brass

Chrome plate on r e d brass

Chrome plate on 5% chromium steel

Chrome plate on nickel-copper alloy

Chrome plate on low-alloy steel

Heavy chrome on steel

Electroless nickel coating on steel

Electroless nickel coating on low- alloy steel

"".".."""""".."

0.08 mm (0.003 in.) min. plate thickness. Chrome plate hardness 67 to 71 HRC






O. 15 mm (0.0060 in.) min. plate thickness. Chrome plate hardness 67 to 71 HRC

0.033 mm (0.001 3 in.) min. plate thickness. Plate hardness 45 to 70 HRC

0.033 mm (0.001 3 in.) min. plate thickness. Plate hardness 45 to 70 HRC

"""

"""

Hardness

"...."_""."_

Base material hardness 95 HRB to 23 HRC









"""""""".."_

".."""._"""".

Low-carbon steel. Ex.: UNS GI 0200

Inhibited admiralty brass UNS C44300

Red brass UNS C23000

5% chromium steel UNS S501 O0

Nickel- copper UNS N04400

Low-alloy steel. Ex.: UNS G41300

Low-carbon steel. Ex.: UNS G I 0200

Low-carbon steel. Ex.: UNS G 1 0200

Low-alloy steel. Ex.: UNS G41 300

Yield

" .

..

Strength, MPa (1,000 .----PS!). -.

"""".""..

410 (60)

380 (55)

240 (35)

480 (70)

380 (55)

550 (80)

41 O (60)

410 (60)

550 (80)



MR0176-2000

............................................. Identification Product Description

Symbol

... ....... ........................................................................ Surface Condition Base Core Base Material Typical

Hardness Yield Strength,

MPa (1,000 ......................................................................... ------PSI)__ ...

0.033 mm (0.001 3 in.) min. Base material Inhibited 280 (40) plate thickness. Plate hardness 83 HRB to admiralty brass hardness 45 to 70 HRC 23 HRC UNS C44300

"_"""""""""""""""""""" "

A l O Electroless nickel coating on brass

............................................... CASE HARDENING

....................................................................................

" .........................................................................................

0.25 mm (0.01 O in.) min. carburized case with 45 HRC min. hardness 0.25 mm (0.01 O in.) from the surface. Surface hardness to be 58 HRC min., 63 HRC max.

95 HRB to 23 HRC Low-carbon steel. Ex.: UNS G1 0200

450 (65)

450 (65)

480 (70)

550 (80)

B1 Carbonitrided

B2 Carburized 0.25 mm (0.01 O in.) min. carburized case with 45 HRC min. hardness 0.25 mm (0.01 O in.) from the surface. Surface hardness to be 58 HRC min., 63 HRC max.

95 HRB to 23 HRC Low-carbon steel. Ex.: UNS GI 0200

98 HRB to 27 HRC"' 5% chromium steel. UNS S501 O0

B3 Carbonitrided 5% chromium steel

0.25 mm (0.01 O in.) min. carburized case with 45 HRC min. hardness 0.25 mm (0.01 O in.) from the surface. Surface hardness to be 58 HRC min., 63 HRC max.

B4 Nitrided 41 30 0.13 mm (0.0050 in.) min. nitrided case with 45 HRC min. hardness 0.13 mm (0.0050 in.). Surface hardness to be 58 HRC min., 63 HRC max.

82 HRB to 23 HRC UNS G41300

............................................... NONHARDENED

.. ..............................

...........................................................................................................................

D l Nonhardened steel Surface is treated with a Base material Low-carbon nonmetallic-type phosphate hardness 95 HRB to steel. Ex.: UNS coating or other equally 23 HRC G1 0200 effective antigalling treatment.

D2 Nonhardened brass Surface is oiled.

41 O (60)

Base material Inhibited ad- 280 (40) hardness 83 HRB to miralty brass 23 HRC UNS C44300

D3 Nickel-copper alloy Surface is oiled. Base material Nickel-copper 380 (55) hardness 85 HRB to alloy UNS 20 HRC N04400



"...."".."_"_

Identification Symbol

MRO176-2000

Product Description ___.....".....".".."

Surface Condition(""- "..."_..."_....""

Base Core Hardness

D4 Nonhardened steel Surface is treated with a nonmetallic-type phosphate coating or other equally effective antigalling treatment


"..."__..."_....._____________

Base Material Typical Yield

Strength, MPa (1,000

_ _ "

Low-alloy steel. 550 (80) Ex.: UNS G41 300

(*I Hardness readings are converted from Rockwell superficial hardness readings. (') Regarding the thread base material condition, the hardness is the same as the core hardness.

98 HRB to 29 HRC thread base material condition.



MR0176-2000

TABLE 6

TYPICAL MECHANICAL PROPERTIES OF PLUNGER MATERIALS

.....................................................................................................

Identification Product Surface Condition Thread Base Base Material Typical Yield Symbol Description Material Strength, MPa

Hardnesdc' (1,000 psi) """"""""".."""""""""""""""""""""""""""""""""""".."."""""""""......""""."...""

A I

A2

Chrome plate 0.15 mm (0.0060 in.) min. Hardness 95 Carbon steel. Ex. 410 (60) plate thickness. Chrome HRB to 23 HRC UNS GI 0200 plate hardness 67 to 71

Chrome plate 0.30 mm (0.012 in.) min. Hardness 95 HRB Carbon steel. Ex.: 410 (60) plate thickness. Chrome to 23 HRC UNS G1 0250/ plate hardness 67 to 71 HRC(*)

G 1 0350/G 1 0450

....""__"""""""""-""""""""..."""""""".....""""""""""""""""""""....."."""""""""""

SPRAY METAL ....................................................................................

BI

B2

B3

B4

B5

B6

Spray metal (B) 0.25 mm (0.01 O in.) min. Hardness 85 HRB Carbon steel. Ex.: 410 (60)

coating thickness. to 23 HRC UNS G1 0260 Hardness 78.5 HRA (55 HRC) min.

Spray metal 0.25 mm (0.01 O in.) min. Hardness 93 HRB Carbon steel. Ex.: 410 (60) coating thickness. to 23 HRC UNS GI 0260 Hardness 78.5 HRA (55 HRC min.

(B)

spray metal (B) with 0.25 mm (0.01 O in.) min. Nickel-copper alloy Carbon steel. Ex.: 410 (60)

pin ends Hardness 78.5 HRA (55 84 HRB to 23 HRC GI 0450 HRC) min.

nickel-copper alloy coating thickness. pin ends. Hardness UNS G1 0260/

Spray (6) with 0.25 mm (0.01 O in.) min. electroless nickel coating thickness. pin ends Hardness 78.5 HRA (55

HRC) min.

spray with 0.25 mm (0.01 O in.) min. electroless nickel coating thickness.

pin ends Hardness 78.5 HRA (55

(6)

HRC) min.

Spray metal 0.25 mm (0.01 O in.) min. coating thickness. Hardness 78.5 HRA (55 HRC) min.

(B)

Electroless nickel Carbon steel. Ex.: 41 O (60) coating 0.033 mm UNS GI 0260 (0.0013 in.) on the pin ends. Base material hardness 85 HRB to 23 HRC

Electroless nickel Carbon steel. Ex.: 480 (70) coating 0.033 mm UNS GI 0450 (0.0013 in.) on the pin ends. Base material hardness 85 HRB to 23 HRC

Hardness 82 to 23 Low-alloy steel. Ex.: 550 (80) H RC UNS G41300

NACE International


Identification Symbol

B7

""

~~

STD NACE

"...."......""

Product Description

.""""""" 1BJ - Spray metal

~~ -

MROL7b-ENGL 2000

""...""."_.......""""~

Surface Condition

."__"""".""""..""". 0.25 mm (0.01 O in.) min. coating thickness. Hardness 78.5 HRA (55 HRC) min.

NONHARDENED

m L452781 0502849 308

MROI 76-2000

.."".."...""_

Thread Base Material Hardnes@'

"

Base Material " """.""."""."""

Typical Yield Strength, MPa (1,000 psi)

..

Electroless nickel Low-alloy steel. Ex.: 550 (80) coating 0.033 mm UNS G41300 (0.0013 in.) on the pin ends. Base material hardness 82 HRB to 23 HRC

...............................................

c 1 Nonhardened Surface is not hardened Hardness 95 HRB Carbon steel. 23 410 (60) or plated. to 23 HRC HRC. Ex.: UNS

G1 0260/G10350/ G 1 0450

IA) Converted from Knoop or Vickers microhardness. @'See Table 6.1 for typical chemical composition of spray metal IC) Critical strength component or plunger.

TABLE 6.1 TYPICAL CHEMICAL COMPOSITION OF SPRAY METAL

Carbon Silicon

Phosphorus Sulfur

Chromium Boron Iron

Cobalt Titanium Aluminum Zirconium

Nickel

Minimum 0.50 3.50

- - - - - - - 12.00 2.50 3.00

" ""_ """ -

Remainder

Maximum 1 .o0 5.50 o. 02 0.02 18.00 4.50 5.50 0.1 o 0.05 0.05 0.05



S T D - N A C E MROL7b-ENGL 2000 P 6452783 0502850 U Z T II

MRO176-2000

TABLE 7 TYPICAL MATERIALS FOR CAGES

...................................................................................................................................

Steel Carbon Steels UNS G1 0200 through G1 0450 Low-Alloy Steels UNS G41300 through G41450 UNS G86200 through G86450

Nickel-Copper Alloy UNS N04400

Brass UNS C46400 Stainless Steel UNS S30400, UNS S31 600

TABLE 8 ' TYPICAL MATERIALS FOR PULL TUBE, VALVE ROD, AND FllTlNGS

......................................................................................................................................

Pull Tube Steels UNS GI0200 through G10450 Stainless Steels-UNS S30400, UNS S31 600 Brass UNS C46400 Nickel-Copper Alloy UNS N04400

Valve Rod

Fittings

Steels G1 0200 through GI 0450 Stainless Steels-UNS S30400, UNS S31 600 Nickel-Copper Alloy UNS N04400

Steel Carbon Steels UNS G1 0200 through G1 0450 Low-Alloy Steels UNS G41300 through G41450 Stainless Steel-UNS S30400, UNS S31600 Nickel-Copper Alloy UNS N04400

TABLE 9 TYPICAL COMPOSITION AND HARDNESS OF CAST COBALT ALLOYS USED FOR VALVE PARTS

...........................................................................................................................

Cobalt Chromium Tungsten Carbon Other

Wt% - Ball

45.2 32.0 18.0 2.3 2.5

M0/0 - Seat

57.9 24.5 12.0 2.1 3.5

H RC 5%-63 51 -55



MR0176-2000

TABLE 10 TYPICAL COMPOSITION AND HARDNESS OF SINTERED CARBIDES USED FOR VALVE PARTS

.................................................................................

Wt% Wt% Balls and Seats Balls

Tungsten Carbide Cobalt

87 13

Titanium Carbide(*) Nickel/Cobalt

Trace Elements

60 14 1

HRA 88 HRA 90

'A) The lighter-weight titanium carbide ball reduces the impact of the ball in the valve. Titanium carbide is used in heavy pumping wells or gassy wells to reduce the effects of impact.

References

1. API Spec 11AX (latest revision), 'Specification for Subsurface Sucker Rod Pumps and Fittings" (Washington, DC: API).

2. API RP 11AR (latest revision), "Recommended Practice for Care and Use of Subsurface Pumps" (Washington, DC: API).

3. API RP 11 BR (latest revision), "Recommended Practice for Care and Handling of Sucker Rods" (Washington, DC: API).

4. NACE Standard MR0175 (latest revision), "Sulfide Stress Cracking Resistant Metallic Materials for Oilfield Equipment" (Houston, TX: NACE International).

5. "A Data-Gathering System to Optimize Production Operations: A 14-Year Overview," Journal of Petroleum Technology 39,4 (1 987): pp. 457-462.

6. D.S. Clark, W.R. Varney, Physical Metallurgy for Engineers, 2nd ed. (Princeton, NJ: Van Nostrand, 1962).

7. "Heat Treatment of Steels," Republic Alloy Steels Handbook, Republic Steel Corporation, Cleveland, OH, 1961.

8. T. Baumeister, Marks Standard Handbook for Mechanical Engineers (latest edition) (New York, NY: McGraw-Hill).

9. J. Zaba, Modern Oil-Well Pumping (Tulsa, OK: Petroleum Publishing Co., 1962).

10. T.C. Frick, ed., Petroleum Production Handbook (New York, NY: McGraw-Hill, 1962).

11. B.R. Bruton, "Selection of Metallic Materials for Subsurface Pumps for Various Corrosive Environments," presented at University of Oklahoma Short Course, September 14-16, 1970.

12. "Subsuriace Pumps-Selection and Application," United States Steel Corporation (Oilwell Supply Division), Pittsburgh, PA, 1967.

Appendix A Economic Benefits

The selection of the proper materials for use in subsurface Pump Pulling Cost pumps is paramount in establishing low costs per barrel of - Rig Travel Cost fluid lifted. The differential cost of selecting a premium - Rig Operating Cost material over a common material can be relatively - Rig Waiting Cost insignificant when the total costs for a single pump failure are evaluated. The total costs for repairing a subsurface pump Pump Repair Cost include: Administrative Cost (Direct Overhead Cost)

Electrical Cost Resulting from Decreased Volumetric Efficiency Rod and Tubular Replacement Cost Lost Production Cost



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The pump pulling, pump repair, electrical, and lost production costs are self-explanatory, Administrative costs are direct overhead costs that can be attributed directly to the failure. For example, for each failure there is generally a verification, data bank entry, establishment of failure cause, and development of a solution to prevent further failure.

Rod and tubular replacement costs are those costs associated with rods and tubing that are damaged because of the failure. The more frequently rods and tubing are handled or the connections broken and remade, the more opportunity there is for error and subsequent failures.

y e company reported an average pump repair cost of $720. The average well-pulling cost, to pull the pump and

run it or another pump back in the well, was $1,620. The average pump repair was 31% of the total of the pump repair cost and the well-pulling cost. It is difficult, however, to assign a dollar value to the other costs because these vary from well to well. From a conservative standpoint, the percentage of total costs contributed by pump pulling and repair can easily drop to 20% of the total repair cost.

The key to low cost per barrel of fluid lifted is generally associated with long pump life and keeping the pump in the well. Proper material selection, along with pump design, is a key factor in achieving this goal.

Appendix B CaseHardening Processes for Steel Pump Barrels for a Corrosive Environment

GENERAL Pump barrels intended for service in an abrasive,

corrosive environment must have a wear-resistant surface and body strength capable of resisting sulfide stress cracking (SSC). This combination can be achieved in steel barrels by either plating or case hardening the wear surface.

The inner diameter (ID) surfaces of steel pump barrels are commonly hardened by five case-hardening processes used individually or in combination: flame hardening, induction hardening, carburizing, carbonitriding, and nitriding. Although low-carbon steels can be properly cased by induction hardening, the carburizing, carbonitriding, and nitriding processes are preferred for service in an HzS environment. Barrels through-hardened by flame hardening or induction hardening are not recommended for HzS environments because of their susceptibility to SSC. Steel barrels that have been cold worked are not recommended because of residual stresses.

The surface hardness, obtained by carburizing and carbonitriding, depends on heat treatment after the composition of the case has been altered. Nitriding alters the composition of the case in such a way that hard compounds are formed without further heat treating.

A brief description of each of the three preferred casehardening processes follows. 6,7s8,12

CARBURIZING In this process, the carbon content of the surface of a

low-carbon steel (0.15 to 0.25% carbon) is increased. There are two carburizing processes used to case harden pump barrels. The characteristics of the case produced by both methods are somewhat similar. Hardness values as high as HRC 62 can be obtained with both methods.

1. In gas carburizing, carbon is absorbed into the barrel surface by heating in an atmosphere of methane. Carbon is dissolved and subsequently precipitated as iron carbide.

2. Liquid carburizing utilizes a fused bath of sodium cyanide and alkaline earth salt. The salt reacts with the

cyanide to form a cyanide of the alkaline earth metal that then reacts with iron to form iron carbide. A small amount of nitrogen is liberated and absorbed. Nitrogen increases the hardenability of steel and increases the solubility of carbon. Barrels treated by this process are hardened on both the outer diameter (OD) and ID.

The final characteristics of a carburized barrel depend on the heat treatments in general use. One method is a direct quench from the carburizing temperature into a suitable quenching medium. A second treatment is to cool slowly from the carburizing temperature, reheat to above the critical temperature of the case, and quench.

CARBONITRIDING This is a modification of the gas carburizing process. A

low-carbon steel is normally used. Anhydrous ammonia is added to the furnace atmosphere so that both carbon and nitrogen are absorbed by the steel surface. Carbonitriding is conducted at lower temperatures than gas carburizing to increase the absorption of nitrogen. Nitrogen increases the hardenability of steel and the solubility of carbon. At higher temperatures, the process approaches gas carburizing with a minimum transfer of nitrogen. The final properties are dependent primarily on the rate of cooling following the carbonitriding process. The increased hardenability made possible by the alloying effect of nitrogen permits the oil quenching of carbonitrided low-carbon steels. Otherwise, this process requires drastic water quenching to develop effective hardening. Hardness values as high as HRC 62 can be obtained by carbonitriding.

NITRIDING When using this process, the surface hardness of certain

alloy steels may be increased by heating, in contact with ammonia, without the necessity of quenching. The process involves the formation of hard, wear-resistant nitrogen compounds on the surface of the steel by absorption of nascent nitrogen.

Most of the steels that are commonly used for nitriding contain combinations of aluminum, chromium, molybdenum,



MR0176-2000

vanadium, and in some instances, nickel. Steels in the UNS also be nitrided but their corrosion resistance is greatly S40000 series also respond well to nitriding but do not reduced by nitriding. develop as hard a surface. Hardenable stainless steels may

Appendix C Selection of Optimum-Type Pump

In selecting materials for a sucker-rod pump, the pump type, size, seating depth, and required material strength must be considered. There are several methods for determining the size of pump Differing opinions concerning the proper application of various API pumps exist. However, there are some generally ac;-s3?$ recommendations that are outlined below as a guide.

TUBING PUMP This pump is suitable for severe service. It is adaptable

for producing viscous fluids because of the large flow areas. A tubing pump has fewer working parts and is often lower in cost than a rod pump of corresponding size. However, these savings can be offset by repair costs because the tubing must be pulled to repair the barrel of a tubing pump. Tubing pumps are generally used when it is necessary to lift large volumes of fluid and a pump of high displacement is required. The greater volume can result in a heavier fluid load on the sucker-rod string. A portion of the capacity advantage may be lost in excessive rod and tubing stretch.

INSERT PUMPS Stationary Barrel with Top Holddown. A top

holddown pump is designed for low-fluid-level wells because the standing valve can be submerged in the well fluids. This pump is also capable of handling low-gravity crudes and is ideally suited for fluids carrying sand. The top holddown provides a seal just below the point where fluid is discharged to the tubing; sand cannot settle around the barrel and cause the pump to stick in the tubing. Intermittent pumping may allow sedimentation between the plunger and barrel; this can be prevented by sealing off the pump body at the top with a sand-check guide and drop. The barrel in this type of pump is subject to tensile stresses that can lead to premature failure in a sulfide environment. This pump is not suitable for deep pumping because of the pressure differential across the wall of the barrel. The inside of the barrel is exposed to pressure of the full column of fluid and the outside only to the pressure of submergence. The resulting breathing of the barrel during the pumping cycle tends to increase the clearance between the plunger and the barrel, thereby increasing the slippage of fluid past the plunger. In extreme cases, the barrel can burst.

Stationary Barrel with Bottom Holddown. This is better suited for deep-well pumping because both sides of the barrel are exposed to the pressure of the column of fluid. However, a long pump should not be used because it is not anchored at the top, and the action of the sucker-rod string tends to weave it back and forth, which may cause premature

failure. This pump is not suited for handling fluid containing sand, because sand tends to settle between the barrel and the tubing, causing the pump to stick. The outside of the barrel tube of this type of pump is susceptible to corrosion because it is surrounded by stagnant fluid. To prevent this, a partial bottom discharge can be utilized to force approximately 25% of the pumped fluid through the pump- tubing annulus. Methods that permit sealing the top of the pump are available. This prevents settlement of sand in the pump-tubing annulus and corrosion of the barrel. This represents the ideal technique for deep wells producing sand with the well fluids and it is also acceptable when a long pump is needed for a deep well.

Traveling Barrel Pump. The bottom-seated traveling barrel pump is well suited for handling fluid with sand because the turbulence caused by the action of the barrel prevents the sand from settling. Also, the construction of this type of pump is such that sand cannot settle into the pump barrel when the pump is shut down, because the large traveling valve acts as a built-in sand check valve. However, in intermittent pumping, it is possible for sand to settle below the barrel, between the barrel and the holddown, and prevent full travel of the barrel on the downstroke. This type of pump can be used to pump deep wells because both sides of the barrel are exposed to the full fluid column pressure. However, long traveling barrel pumps are seldom used to pump deep wells because the compressive load on the standing valve tends to buckle the pull tube. This pump is not suited for pumping large volumes of heavy, viscous oil. Because of the long fluid passage, the smaller standing valve, and the comparatively smaller compression ratio, this pump is not suited for pumping wells that tend to gas lock.

Special Pumps. In addition to the standard API pumps, specialty sucker-rod pumps have been designed to handle unusual downhole conditions. These include such pumps as casing pumps, double-displacement pumps, three-tube pumps, and pumps having two compression chambers. Detailed discussion of these pumps is beyond the scope of this standard.



ISBN 1-57590-099-8 NACE International


MR 0176 00

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