Monoethanolamine Diethanolamine Triethanolamine

21
ETHANOLAMINES Monoethanolamine Diethanolamine Triethanolamine

Transcript of Monoethanolamine Diethanolamine Triethanolamine

Page 1: Monoethanolamine Diethanolamine Triethanolamine

ETHANOLAMINES

Monoethanolamine

Diethanolamine

Triethanolamine

DSA9781.qxd 1/31/03 10:21 AM Page 1

Page 2: Monoethanolamine Diethanolamine Triethanolamine

CONTENTSIntroduction ...............................................................................................................................2

Ethanolamine Applications.........................................................................................................3

Gas Sweetening ..................................................................................................................3

Detergents, Specialty Cleaners, Personal Care Products.......................................................4

Textiles.................................................................................................................................4

Metalworking ......................................................................................................................5

Other Applications...............................................................................................................5

Ethanolamine Physical Properties ...............................................................................................6

Typical Physical Properties ....................................................................................................6

Vapor Pressure of Ethanolamines (Figure 1) .........................................................................7

Heat of Vaporization of Ethanolamines (Figure 2)................................................................7

Specific Heats of Ethanolamines (Figure 3) ..........................................................................8

Comparative Hygroscopicities of Diethanolamine and Triethanolamine (Figure 4) ...............8

Weight Percent Ethanolamine in Aqueous Solutions vs Normality of Solution (Figure 5).....9

pH of Ethanolamine Solutions (Figure 6) .............................................................................9

Partial Pressure of Ethanolamines in Aqueous Solutions at Various Temperatures (Figure 7, 9, 11) ........................................................................................................10-12

Vapor-Liquid Equilibria of Aqueous Solutions at 760 mm Hg Absolute (Figure 8, 10, 12) ......................................................................................................10-12

Absolute Viscosities of Aqueous Solutions (Figures 13-15) ................................................13

Freezing Points of Aqueous Ethanolamine Solutions (Figure 16)........................................14

Specific Gravity of Aqueous Ethanolamine Solutions (Figure 17) .......................................14

Weight per Gallon of Aqueous Solutions at Various Temperatures (Figures 18-20) ......15-16

Specific Heats of Aqueous Solutions (Figures 21-23) .........................................................17

Storage and Handling ..............................................................................................................18

Shipping Information ...............................................................................................................19

Specifications ...........................................................................................................................19

Product Safety..........................................................................................................................19

1

DSA9781.qxd 1/31/03 10:21 AM Page 2

Page 3: Monoethanolamine Diethanolamine Triethanolamine

ETHANOLAMINESDow’s versatile family of ethanolamines — including monoethanolamine (MEA),diethanolamine (DEA), and triethanolamine (TEA) — offers a broad spectrum of applicationopportunities. Triethanolamine is available as TEA, 99% and TEA, Commercial (which containsnominally 15% diethanolamine). Because ethanolamines combine the properties of aminesand alcohols, they exhibit the unique capability of undergoing reactions common to bothgroups. As amines, they are mildly alkaline and react with acids to form salts or soaps. Asalcohols, they are hygroscopic and can be esterified. The chemical structures of theethanolamines are:

MEA H2NCH2CH2OHDEA HN(CH2CH2OH)2

TEA N(CH2CH2OH)3

Ethanolamines find uses in such diverse areas as gas sweetening, where they serve as lubri-cants and scouring agents; detergent and specialty cleaner formulations, in which they areused to form various amine salts and to control pH; and in a host of other applicationsincluding concrete admixtures, flexible urethane foam catalysts, pharmaceuticals, personalcare products, agricultural chemicals, photographic emulsions, and more.

TECHNOLOGY LEADERSHIPEthanolamines from Dow are backed by approximately 80 years of innovative scientificresearch. Since their introduction in the late 1920s, MEA, DEA, and TEA have undergoneextensive commercial development in our laboratories at South Charleston, WV.

WORLD SCALE PRODUCTION CAPACITYBacked by the world’s largest ethylene oxide capacity, Dow’s efficient ethanolamines facilities, located at Seadrift, TX, are the world’s largest. Designed for flexibility, this plant iscapable of producing ethanolamines to meet the most demanding specifications of themarketplace.

Additional worldscale ethanolamines facilities were added in 1997 at Taft, LA, and in 2002,at the Optimal joint venture between Dow and Petronas at Kertih, Malaysia. Additionalplants will be added to meet other developing worldwide markets.

Dow’s position as the leading producer of basic ethylene oxide and ethanolamines translatesinto dependability, not only as a source of supply, but in quality of product as well. The purityand consistency of Dow’s ethanolamines are unsurpassed.

BROADEST DISTRIBUTION NETWORKThe Dow network of sales personnel, technical service experts, bulk storage terminals, anddistributors has been carefully constructed to reach all of Dow’s customers worldwide. Problemsolving assistance is virtually a phone call away, and Dow’s vast distribution system assuresfast delivery of tanker, barge, tank truck, tank car, or drum quantities from strategicallylocated bulk terminals and warehouses.

Whatever your needs in ethanolamines — MEA, DEA, or TEA — Dow has the technical,production, and distribution resources to serve you best. This booklet has been designed toprovide the answers to most questions about Dow’s ethanolamine products. For furtherinformation contact your Dow representative.

2

Monoethanolamine

Diethanolamine

Triethanolamine

DSA9781.qxd 1/31/03 10:21 AM Page 3

Page 4: Monoethanolamine Diethanolamine Triethanolamine

3

Ethanolamine ApplicationsTEA,

Typical Applications MEA DEA Commercial TEA, 99%

Adhesives ✗Agricultural Chemicals ✗ ✗

Cement Grinding Aids ✗ ✗Concrete Additives ✗

Detergents, Specialty CleanersPersonal Care Products ✗ ✗ ✗ ✗

Gas Treating ✗ ✗ ✗ ✗Metalworking ✗ ✗ ✗

Oil Well Chemicals ✗ ✗ ✗Packaging & Printing Inks ✗

Photographic Chemicals ✗ ✗Rubber ✗

Textile Finishing ✗ ✗ ✗ ✗Urethane Foams ✗ ✗ ✗

ETHANOLAMINES FOR GAS SWEETENINGAqueous solutions of monoethanolamine and diethanolamine react with carbondioxide and hydrogen sulfide at ambient temperature to form compounds that,when exposed to elevated temperatures, release the acid gas and regenerate theamine for reuse.

Monoethanolamine is commonly used for treating synthesis gas streams formedin ammonia, hydrogen, carbon monoxide, and flue gas facilities. Carbon dioxideis the principal contaminant that is removed.

Diethanolamine is primarily used for treating natural and refinery gas and forliquid streams. Carbon dioxide and hydrogen sulfide are the principal contaminants removed.

Engineering companies can provide individually designed plants or standard packaged unitsthat can be installed wherever it is necessary to remove carbon dioxide and/or hydrogensulfide from gas streams.

For natural gas systems and refinery-treating systems in sulfur service, diethanolamine solutionshave performed satisfactorily for years in units where carbon steel has been the major material ofconstruction. In improperly designed or improperly operated units, however, corrosion will occurin carbon steel exchangers, condensers, and reboiler-type bundles. In special situations, therefore,alloy materials of construction may be required. In addition, improved design and operatingcriteria may be specified, including activated carbon filtration and good inlet separation.

DSA9781.qxd 1/31/03 10:21 AM Page 4

Page 5: Monoethanolamine Diethanolamine Triethanolamine

4

ETHANOLAMINES FOR DETERGENTS, SPECIALTY CLEANERS, AND PERSONAL CARE PRODUCTSEthanolamines are used in heavy-duty liquid laundry detergents because theyprovide a unique combination of beneficial property and performance qualities.These ethanolamines impart a reserve alkalinity to the laundry bath, which isessential to efficient cleaning. They neutralize the fatty acids present in the oilysoil components and, through this neutralization, convert them to amine soaps.These soaps, in turn, aid in the overall cleaning process. The effect is readilyobserved when standard industrial oily soils are used.

These same ethanolamines are also effective soil anti-redeposition agents. They help to keep soilin the laundry bath from redepositing onto the fabric during the cleaning process. The effect isevident in the performance of nonionic, anionic, and mixed nonionic/anionic surfactant-basedproducts on cotton, blended cotton/polyester, and polyester fabrics.

Diethanolamine is used to prepare fatty acid amides, which may be used in various personalcare products.

Triethanolamine may be reacted with lauryl sulfate to form the foaming base surfactant usedin hair shampoos.

Fatty acids neutralized with ethanolamines, particularly triethanolamine, are excellent emulsifiersfor oil-in-water emulsions. Gel-type industrial hand cleaners, aerosol shave creams, and hand andbody lotions are only a few of the consumer products commonly formulated with such soaps.Triethanolamine is also used as the base component in the production of certain mild bar soaps.

ETHANOLAMINES FOR TEXTILESEthanolamines are used in textile processing as reaction intermediates for thepreparation of durable press fabric finishes and softeners.

Amine soaps are used as scouring agents for wool and silk because of theirlow alkalinity.

Ethanolamines are also used as dye auxiliaries. Because of their hygroscopicity,ethanolamines find application in the preparation of vat printing pastes.Diethanolamine and triethanolamine are used in making acetate rayon dyes.

Textile lubricants often incorporate salts of ethanolamines to benefit from theiranticorrosion and antistatic properties. Ethanolamine salts of mono- or di-phosphates,sulfonates, and sulfates are typical components of staple finishes.

DSA9781.qxd 1/31/03 10:21 AM Page 5

Page 6: Monoethanolamine Diethanolamine Triethanolamine

ETHANOLAMINES FOR METALWORKINGAcidic additives and/or acidic decomposition products are the prime contributorsto corrosion of metal surfaces, particularly in the presence of moisture.Ethanolamines are often used as neutralizers of acid components in lubricantsand are a time-tested means of preventing corrosion.

In water-soluble cutting and grinding fluids, ethanolamines are used to providethe alkalinity needed to protect against rusting (ferrous metals do not oxidizeunder alkaline conditions). Ethanolamines are also used as intermediates in thepreparation of water-soluble lubricants, emulsifiers, proprietary corrosioninhibitors, and biocides.

OTHER ETHANOLAMINE APPLICATIONSIn addition to supplying ethanolamines for the four major applications alreadydiscussed, Dow provides these versatile materials for a variety of other uses(See Applications Chart, page 3).

Diethanolamine and triethanolamine are used as catalysts that promote stability during the reaction process in the manufacture of flexible and rigidurethane foams. In the photographic chemical industry, these ethanolaminesfind application in complex modern developing systems. Diethanolamine andtriethanolamine are used in the agricultural chemical field as intermediates in anumber of applications, most notably the manufacture of herbicides.

Triethanolamine finds use as an intermediate for additives that control the rate at which waterevaporates from drying concrete. In another application, triethanolamine is used as a compo-nent in the formulation of cement grinding media during the manufacture of cement. In stillanother important use, triethanolamine is utilized “down hole” in oil wells to prevent corrosionof drilling equipment.

Triethanolamine also functions as an intermediate for adhesive and rubber chemicals. Mono-ethanolamine is used as a pH control agent in the formulation of packaging and printing inks.

Triethanolamine (Trolamine 99% NF Grade) meets the requirements of the applicable NationalFormulary monograph.

5

DSA9781.qxd 1/31/03 10:21 AM Page 6

Page 7: Monoethanolamine Diethanolamine Triethanolamine

Typical Physical PropertiesThe properties of Dow’s family of ethanolamines enable these versatile materials to beutilized in a broad range of applications. Typical properties of the ethanolamines are shownin the table below and in Figures 1-23.

Table 1 • Typical Properties of DOW EthanolaminesMonoethanolamine Diethanolamine Triethanolamine

Formula H2NCH2CH2OH HN(CH2CH2OH)2 N(CH2CH2OH)3Molecular Weight 61.08 105.14 149.19

Apparent Sp. Gr. at 20/20°C 1.017 1.092(a) 1.126(f)

∆Sp. Gr./∆t at 10 to 80°C 0.00080 0.00065(b) 0.00059

Boiling Point at 760 mm Hg, °C 170.4 268(c) 335(c)

at 50mm Hg, °C 101 182 245(c)

at 10mm Hg, °C 71 150 205

Vapor Pressure at 20°C, mm Hg <1 <0.01 <0.001

Freezing Point, °C(°F) 10.5 (50.9) 28.0 (82.4) 21.6 (70.9)(e)

Absolute Viscosity at 20°C, cP 24.1 — 921(f)

at 30°C, cP 16.2 380 404

Solubility at 20°C, % by wtIn Water Complete Complete(f) Complete(f)

Water In Complete — Complete(f)

Solubility in Organic Liquids at 25°C, % by wt

Acetone Complete Complete(f) CompleteBenzene 0.6 0.03 2Carbon Tetrachloride 0.1 0.01 CompleteEthyl Ether 0.7 0.5 2Heptane 0.1 0.03 <0.03Methanol Complete Complete(f) Complete

Surface Tension, dynes/cm 48.3(d) 48.5(g) 48.9(d)

Refractive Index, nD20 1.4539 1.4747(g) 1.4852(f)

∆ND/∆t at 20 to 40°C per °C 0.00034 0.00027(b) 0.00020

Flash Point, °C (°F) 96 (205)(h) 191 (375)(h) 208 (407)(h)

(a) At 30/20°C (e) Supercools easily(b) At 35 to 65°C (f) Supercooled liquid(c) Extrapolated (decomposes) (g) At 30°C(d) At 25°C (h) Determined by ASTM Method D 93,

using the Pensky-Martens Closed Cup

NOTEThis table sets forth typical properties of Monoethanolamine, Diethanolamine, andTriethanolamine based upon analysis(ses) of commercial product or purified sample, etc.;however, Dow does not analyze each shipment of product for all of these properties. Dowwarrants only that, at the time of delivery, product will conform to Dow’s standard specifica-tions as then in effect.

6

DSA9781.qxd 1/31/03 10:21 AM Page 7

Page 8: Monoethanolamine Diethanolamine Triethanolamine

7

Figure 1Vapor Pressure of Ethanolamines

Figure 2Heat of Vaporization of Ethanolamines

1000

600400

200

100

60

40

20

10

64

2

800

500

300

80

5030

8

5

3

120 40 60 80 120 160 200 240

Temperature, °C

Vapo

r Pr

essu

re, m

m H

g

Temperature, °F

70 90 120 160 200 240 320 400 480

Note: Ethanolamines begindecomposing at temperaturesabove about 200°C and canundergo self-sustained decomposition at temperaturesabove 250°C.

*1 Btu/lb = 0.56 cal/g

MEA DEATEA

440

410

380

350

320

290

260

230

200

Hea

t of

Vap

oriz

atio

n, B

tu/lb

*

MEA

DEA

TEA

Temperature, °F

150 250 350 450 550 650

50 100 150 200 250 300 350Temperature, °C

DSA9781.qxd 1/31/03 10:21 AM Page 8

Page 9: Monoethanolamine Diethanolamine Triethanolamine

8

Figure 3Specific Heat of Ethanolamines

Figure 4Comparative Hygroscopicities of Diethanolamine and Triethanolamine from 75° to 80°F

0.84

0.82

0.80

0.78

0.76

0.74

0.72

0.70

0.68

0.66

0.64

0.62

0.60

0.58

0.56

0.540 20 40 60 80 100 120 140 160 180 200

Temperature, °C

Temperature, °F40 80 120 160 200 240 280 320 360

Spec

ific

Hea

t, C

al/g

-°C

10080

60

40

20

1086

4

2

110 20 30 40 50 60 70 80

Relative Humidity, %

Perc

ent

Gai

n in

Wei

ght

at E

quili

briu

m

DEA

TEA

MEA

DEA

TEA

DSA9781.qxd 1/31/03 10:21 AM Page 9

Page 10: Monoethanolamine Diethanolamine Triethanolamine

9

Figure 5Weight Percent Ethanolamine in Aqueous Solutions vs Normality of Solution

Figure 6pH of Ethanolamine Solutions

70

60

50

40

30

20

10

00 3 6 9 12 15

Normality of Amine Solution

Am

ine,

Per

cent

by

Wei

ght

in S

olut

ion

40

20

10

4

2

1

.4

.2

.1

.04

.02

.018 9 10 11 12 13

pH at 20°C

Am

ine,

Per

cent

by

Wei

ght

MEADEA

TEA, 99%

TEA,Commercial

TEADEA

MEA

DSA9781.qxd 1/31/03 10:21 AM Page 10

Page 11: Monoethanolamine Diethanolamine Triethanolamine

10

Figure 7Partial Pressure of Monoethanolamine in Aqueous Solutions at Various Temperatures

Figure 8Vapor-Liquid Equilibria (T-x-y) of Aqueous Monoethanolamine Solutions at 760 mm Hg Absolute

10

1

0.1

0.01

10-3

10-4

0 10 20 30 40 50Temperature, °C

Part

ial P

ress

ure

of M

onoe

than

olam

ine,

mm

Hg

Temperature, °F

40 60 80 100 120

MEA% by wt

1009590

8060

3020

10

5

40

180

170

160

150

140

130

120

110

100

90

80

340

320

300

280

260

240

220

200

180

0 10 20 30 40 50 60 70 80 90 100Monoethanolamine, Percent by Weight

Tem

pera

ture

, °C

Tem

pera

ture

, °F

Vapor Phase

Liquid Phase

DSA9781.qxd 1/31/03 10:21 AM Page 11

Page 12: Monoethanolamine Diethanolamine Triethanolamine

11

Figure 9Partial Pressure of Diethanolamine in Aqueous Solutions at Various Temperatures

Figure 10Vapor-Liquid Equilibria (T-x-y) of Aqueous Diethanolamine Solutions at 760 mm Hg Absolute

0.1

0.01

10-3

10-4

10-5

10-6

15 20 25 30 35 40 45 50 55 60 65 70Temperature, °C

Part

ial P

ress

ure

of D

ieth

anol

amin

e, m

m H

g

Temperature, °F

60 80 100 120 140

DEA% by wt

10095

80

60

40

20

10

5

275

255

235

215

195

175

155

135

115

95

75

495

455

415

375

335

295

255

215

175

0 10 20 30 40 50 60 70 80 90 100Diethanolamine, Percent by Weight

Tem

pera

ture

, °C

Tem

pera

ture

, °F

Vapor Phase

Liquid PhaseNote: Ethanolamines canundergo decomposition at temperatures aboveapproximately 200°C

DSA9781.qxd 1/31/03 10:21 AM Page 12

Page 13: Monoethanolamine Diethanolamine Triethanolamine

12

Note: Ethanolamines canundergo decomposition at temperatures aboveapproximately 200°C

Figure 11Partial Pressure of Triethanolamine in Aqueous Solutions at Various Temperatures

Figure 12Vapor-Liquid Equilibria (T-x-y) of Aqueous Triethanolamine Solutions at 760 mm Hg Absolute

0 . 1

0 . 0 1

1 0 - 3

1 0 - 4

1 0 - 5

1 0 - 6

1 0 - 7

45 50 55 60 65 70 75 80 85 90 95 100Temperature, °C

Part

ial P

ress

ure

of T

rieth

anol

amin

e, m

m H

g

Temperature, °F

120 140 160 180 200

TEA% by wt

10095

80

60

40

2010

5

380

360

340

320

300

280

260

240

220

200

180

160

140

120

100

80

680

640

600

560

520

480

440

400

360

320

280

240

200

0 10 20 30 40 50 60 70 80 90 100Triethanolamine, Percent by Weight

Tem

pera

ture

, °C

Tem

pera

ture

, °F

Vapor Phase

Liquid Phase

DSA9781.qxd 1/31/03 10:21 AM Page 13

Page 14: Monoethanolamine Diethanolamine Triethanolamine

13

Figure 13Absolute Viscosity of Aqueous Monoethanolamine Solutions

1 30°C (86°F)2 50°C (122°F)3 75°C (167°F)4 100°C (212°F)

100604020106421

0.60.40.20.1A

bsol

ute

Vis

cosi

ty, C

entip

oise

1234

0 10 20 30 40 50 60 70 80 90 100Monoethanolamine, Percent by Weight

Figure 14Absolute Viscosity of Aqueous Diethanolamine Solutions

1 30°C (86°F)2 50°C (122°F)3 75°C (167°F)4 100°C (212°F)

1000400200100402010421

0.40.20.1A

bsol

ute

Vis

cosi

ty, C

entip

oise

1

2

34

0 10 20 30 40 50 60 70 80 90 100Diethanolamine, Percent by Weight

Figure 15Absolute Viscosity of Aqueous Triethanolamine Solutions

1 30°C (86°F)2 50°C (122°F)3 75°C (167°F)4 100°C (212°F)

1000400200100402010421

0.40.20.1A

bsol

ute

Vis

cosi

ty,

Cen

tipoi

se

1

2

34

0 10 20 30 40 50 60 70 80 90 100Triethanolamine, Percent by Weight

DSA9781.qxd 1/31/03 10:21 AM Page 14

Page 15: Monoethanolamine Diethanolamine Triethanolamine

14

Figure 16Freezing Points of Aqueous Ethanolamine Solutions

Figure 17Specific Gravity of Aqueous Ethanolamine Solutions at 20/20°C

60

40

20

0

-20

-40

-60

140

120

100

80

60

40

20

0

-20

-40

-60

0 20 40 60 80 100Ethanolamine, Percent by Weight

Free

zing

Poi

nt, °

C

Free

zing

Poi

nt, °

F

1.13

1.12

1.11

1.10

1.09

1.08

1.07

1.06

1.05

1.04

1.03

1.02

1.01

1.00

0 10 20 30 40 50 60 70 80 90 100Ethanolamine, Percent by Weight

Spec

ific

Gra

vity

, 20/

20°C

FreezingPoint

Note: Freezing point datafor 70% to 90%Diethanolamine in water areextrapolated

Triethanolamine

Diethanolamine

Monoethanolamine

Triethanolamine

Diethanolamine

Monoethanolamine

DSA9781.qxd 1/31/03 10:21 AM Page 15

Page 16: Monoethanolamine Diethanolamine Triethanolamine

15

Figure 18Weight per Gallon of Aqueous Monoethanolamine Solutions at Various Temperatures

Figure 19Weight per Gallon of Aqueous Diethanolamine Solutions at Various Temperatures

9.2

9.0

8.8

8.6

8.4

8.2

8.0

7.8

0 20 40 60 80 100Monoethanolamine, Percent by Weight

Poun

ds p

er G

allo

n

9.4

9.2

9.0

8.8

8.6

8.4

8.2

8.0

0 20 40 60 80 100Diethanolamine, Percent by Weight

Poun

ds p

er G

allo

n

Freezing Point Curve

Boiling Point

-20 °F

0 °F 30°F60°F90°F

120°F150°F

180°F

210°F

240°F

Freezing Point Curve

0°F

30°F

60°F

90°F

120°F

150°F

180°F

210°F

DSA9781.qxd 1/31/03 10:21 AM Page 16

Page 17: Monoethanolamine Diethanolamine Triethanolamine

16

Figure 20Weight per Gallon of Aqueous Triethanolamine Solutions at Various Temperatures

9.6

9.4

9.2

9.0

8.8

8.6

8.4

8.2

8.0

7.80 20 40 60 80 100

Triethanolamine, Percent by Weight

Poun

ds p

er G

allo

n

Freezing Point Curve

Boiling Point

0°F30°F60°F90°F

120°F150°F180°F210°F240°F

DSA9781.qxd 1/31/03 10:21 AM Page 17

Page 18: Monoethanolamine Diethanolamine Triethanolamine

17

Figure 21Specific Heats of Aqueous Monoethanolamine Solutions

1.1

1.0

0.9

0.8

0.7

0.6

Cal

/g-°

C

25

0

MEA % by Wt

50

75

100

0 20 40 60 80 100 120Temperature, °C

Temperature, °F40 80 120 160 200 240

1.1

1.0

0.9

0.8

0.7

0.6

Cal

/g-°

C

0 20 40 60 80 100 120Temperature, °C

Temperature, °F40 80 120 160 200 240

Figure 22Specific Heats of Aqueous Diethanolamine Solutions

Figure 23Specific Heats of Aqueous Triethanolamine Solutions

25

0

DEA % by Wt

50

75100

1.1

1.0

0.9

0.8

0.7

0.6

0.5

Cal

/g-°

C

0 20 40 60 80 100 120Temperature, °C

Temperature, °F40 80 120 160 200 240

25

0

TEA % by Wt

50

75

100

DSA9781.qxd 1/31/03 10:21 AM Page 18

Page 19: Monoethanolamine Diethanolamine Triethanolamine

18

Storage and HandlingProper storage and handling will help maintain the quality of ethanolamine products. Undernormal conditions ethanolamines are considered to be thermally stable molecules and arenot corrosive to the proper containers. However, they are sufficiently reactive that uponexposure to adventitious carbon dioxide, nitrogen oxides, and oxygen, trace levels ofbyproducts can form and increased color often results.

For storage and handling information contact your Dow representative.

SAFETY NOTE — MONOETHANOLAMINEMonoethanolamine in contact with iron can form a crystalline complex calledtris(ethanolamino)-iron. This compound can ignite when heated to 130-160°F (54-71°C) inthe presence of air. A fire is known to have occurred in a storage tank equipped with acarbon steel heating coil using 150 psig steam. For internal steam applications, stainless steelheating coils should be used; low-pressure steam is preferred for safety and product quality.

STORAGE TEMPERATURESEthanolamines require heated and insulated storage and transfer facilities. Ethanolaminesdarken, however, at temperatures above 140°F (60°C).

Table 2 • Storage Temperatures for EthanolaminesApproximate

Freezing Storage Viscosity, cP,Point, °C (°F) Temperature, °F 30°C (86°F)

Monoethanolamine 10.5 (50.9) 65-95 15

Diethanolamine 28.0 (82.4) 95-120 380

Triethanolamine, Commercial 15.8 (60.4) 75-110 400

Triethanolamine, 99% 21.6 (70.9)(a) 85-110 400

(a) Supercools easily

DSA9781.qxd 1/31/03 10:21 AM Page 19

Page 20: Monoethanolamine Diethanolamine Triethanolamine

19

Shipping InformationFor your convenience in ordering, Dow markets ethanolamines both direct and through aneffective network of distributors. Less than full tank car or tank truck quantities can bedelivered most rapidly through a Dow distributor. Consult your Dow representative for thename of the distributor nearest you.

For delivery of large volume orders, ethanolamines are stocked in terminals throughout theworld.

Table 3 • Shipping Data for Ethanolamines Monoethanolamine Diethanolamine Triethanolamine, Triethanolamine,

Commercial 99%

Pounds per Gallon at 20°C 8.47 9.10 (30°C) 9.37 9.38Kilograms per liter at 20°C 1.015 1.088 (30°C) 1.123 1.124

Coefficient of Expansion 0.00081 0.00060 0.00049 0.00053at 55°C, per °C

Flash Point, °C (°F)(a) 96 (205) 191 (375) 194 (382) 208 (407)

(a) Determined by ASTM Method D 93, using the Pensky-Martens Closed Cup

SpecificationsSpecifications for DOW Ethanolamines are available on request from your Dow sales representative.

Product SafetyWhen considering the use of any Dow products in a particular application, you shouldreview Dow’s latest Material Safety Data Sheets and ensure that the use you intend can beaccomplished safely. For Material Safety Data Sheets and other product safety information,please contact us using the numbers on the back cover of this brochure. Before handlingany other products mentioned in the text, you should obtain available product safety infor-mation and take necessary steps to ensure safety of use.

No chemical should be used as or in a food, drug, medical device, or cosmetic, until theuser has determined the suitability and legality of the use. Since government regulationsand use conditions are subject to change, it is the user’s responsibility to determine that thisinformation is appropriate and suitable under current, applicable laws and regulations.

Dow requests that the customer read, understand, and comply with the informationcontained in this publication and the current Material Safety Data Sheet(s). The customershould furnish the information in this publication to its employees, contractors, andcustomers, or any other users of the product(s), and request that they do the same.

DSA9781.qxd 1/31/03 10:21 AM Page 20

Page 21: Monoethanolamine Diethanolamine Triethanolamine

NOTICE: No freedom from any patent owned by Seller or others is to be inferred. Because use conditions and applicable laws may differ from one location toanother and may change with time, Customer is responsible for determining whether products and the information in this document are appropriate forCustomer’s use and for ensuring that Customer’s workplace and disposal practices are in compliance with applicable laws and other governmental enactment.Seller assumes no obligation or liability for the information in this document. NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OFMERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE ARE EXPRESSLY EXCLUDED.

Published January 2003

The Dow Chemical CompanyMidland, Michigan 48674 U.S.A.

In the United States and Canada: call 1-800-447-4369 • fax 1-989-832-1465In Europe: call toll-free +800 3 694 6367 • +32 3 450 2240 • fax +32 3 450 2815

In the Pacific: call +852 2879 7260 • fax +852 2827 5881In Other Global Areas: call 1-989-832-1560 • fax 1-989-832-1465

Or visit us at www.dow.com

*

*Trademark of The Dow Chemical Company Form No. 111-01375-0103 AMS

DSA9781.qxd 1/31/03 10:21 AM Page 21