IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes...

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IV. Adiabatic Processes

Transcript of IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes...

Page 1: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

IV. Adiabatic Processes

Page 2: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

IV. Adiabatic ProcessesIf a material undergoes a change in its physical state (e.g.,its pressure, volume, or temperature) without any heat be-ing added to it or withdrawn from it, the change is said tobe adiabatic.

Page 3: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

IV. Adiabatic ProcessesIf a material undergoes a change in its physical state (e.g.,its pressure, volume, or temperature) without any heat be-ing added to it or withdrawn from it, the change is said tobe adiabatic.

Suppose that the initial state of a material is represented bythe point A on the thermodynamic diagram below, and thatwhen the material undergoes an isothermal transformationit moves along the line AB.

Page 4: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

IV. Adiabatic ProcessesIf a material undergoes a change in its physical state (e.g.,its pressure, volume, or temperature) without any heat be-ing added to it or withdrawn from it, the change is said tobe adiabatic.

Suppose that the initial state of a material is represented bythe point A on the thermodynamic diagram below, and thatwhen the material undergoes an isothermal transformationit moves along the line AB.

If the same material undergoes a similar change in volumebut under adiabatic conditions, the transformation wouldbe represented by a curve such as AC, which is called anadiabat.

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An isotherm and an adiabat on a p–V -diagram.

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The adiabat AC is steeper than the isotherm AB.The reason for this is easily seen.

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The adiabat AC is steeper than the isotherm AB.The reason for this is easily seen.

During the adiabatic compression (dα < 0) the internal en-ergy increases:

dq = du + p dα and dq = 0 =⇒ du = −p dα > 0

and therefore the temperature of the system rises:

du = cv dT > 0 =⇒ TC > TA

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The adiabat AC is steeper than the isotherm AB.The reason for this is easily seen.

During the adiabatic compression (dα < 0) the internal en-ergy increases:

dq = du + p dα and dq = 0 =⇒ du = −p dα > 0

and therefore the temperature of the system rises:

du = cv dT > 0 =⇒ TC > TA

However, for the isothermal compression from A to B, thetemperature remains constant: TB = TA. Hence, TB < TC.But αB = αC (the final volumes are equal); so

pB =RTB

αB<

RTC

αC= pC

that is, pB < pC.

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The adiabat AC is steeper than the isotherm AB.The reason for this is easily seen.

During the adiabatic compression (dα < 0) the internal en-ergy increases:

dq = du + p dα and dq = 0 =⇒ du = −p dα > 0

and therefore the temperature of the system rises:

du = cv dT > 0 =⇒ TC > TA

However, for the isothermal compression from A to B, thetemperature remains constant: TB = TA. Hence, TB < TC.But αB = αC (the final volumes are equal); so

pB =RTB

αB<

RTC

αC= pC

that is, pB < pC.

Thus, the adiabat is steeper than the isotherm.

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The Idea of an Air Parcel

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The Idea of an Air ParcelIn the atmosphere, molecular mixing is important only withina centimeter of the Earth’s surface and at levels above theturbopause (∼105 km).

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The Idea of an Air ParcelIn the atmosphere, molecular mixing is important only withina centimeter of the Earth’s surface and at levels above theturbopause (∼105 km).

At intermediate levels, virtually all mixing in the verticalis accomplished by the exchange of macroscale air parcelswith horizontal dimensions ranging from a few centimetersto the scale of the Earth itself.

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Page 13: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

The Idea of an Air ParcelIn the atmosphere, molecular mixing is important only withina centimeter of the Earth’s surface and at levels above theturbopause (∼105 km).

At intermediate levels, virtually all mixing in the verticalis accomplished by the exchange of macroscale air parcelswith horizontal dimensions ranging from a few centimetersto the scale of the Earth itself.

That is, mixing is due not to molecular motions, but toeddies of various sizes.

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Page 14: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

The Idea of an Air ParcelIn the atmosphere, molecular mixing is important only withina centimeter of the Earth’s surface and at levels above theturbopause (∼105 km).

At intermediate levels, virtually all mixing in the verticalis accomplished by the exchange of macroscale air parcelswith horizontal dimensions ranging from a few centimetersto the scale of the Earth itself.

That is, mixing is due not to molecular motions, but toeddies of various sizes.

Recall Richardson’s rhyme:

Big whirls have little whirls that feed on their velocity,

And little whirls have lesser whirls and so on to viscosity.

--- in the molecular sense.

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To gain some insights into the nature of vertical mixing inthe atmosphere it is useful to consider the behavior of anair parcel of infinitesimal dimensions that is assumed to be:

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To gain some insights into the nature of vertical mixing inthe atmosphere it is useful to consider the behavior of anair parcel of infinitesimal dimensions that is assumed to be:

• thermally insulated from its environment, so that its tem-perature changes adiabatically as it rises or sinks

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To gain some insights into the nature of vertical mixing inthe atmosphere it is useful to consider the behavior of anair parcel of infinitesimal dimensions that is assumed to be:

• thermally insulated from its environment, so that its tem-perature changes adiabatically as it rises or sinks

• always at exactly the same pressure as the environmentalair at the same level, which is assumed to be in hydro-static equilibrium

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Page 18: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

To gain some insights into the nature of vertical mixing inthe atmosphere it is useful to consider the behavior of anair parcel of infinitesimal dimensions that is assumed to be:

• thermally insulated from its environment, so that its tem-perature changes adiabatically as it rises or sinks

• always at exactly the same pressure as the environmentalair at the same level, which is assumed to be in hydro-static equilibrium

• moving slowly enough that the macroscopic kinetic en-ergy of the air parcel is a negligible fraction of its totalenergy.

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Page 19: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

To gain some insights into the nature of vertical mixing inthe atmosphere it is useful to consider the behavior of anair parcel of infinitesimal dimensions that is assumed to be:

• thermally insulated from its environment, so that its tem-perature changes adiabatically as it rises or sinks

• always at exactly the same pressure as the environmentalair at the same level, which is assumed to be in hydro-static equilibrium

• moving slowly enough that the macroscopic kinetic en-ergy of the air parcel is a negligible fraction of its totalenergy.

This simple, idealized model is helpful in understandingsome of the physical processes that influence the distribu-tion of vertical motions and vertical mixing in the atmo-sphere.

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The Dry Adiabatic Lapse Rate

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The Dry Adiabatic Lapse RateWe will now derive an expression for the rate of change oftemperature with height of a parcel of dry air as it movesabout in the Earth’s atmosphere.

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The Dry Adiabatic Lapse RateWe will now derive an expression for the rate of change oftemperature with height of a parcel of dry air as it movesabout in the Earth’s atmosphere.

Since the air parcel undergoes only adiabatic transforma-tions (dq = 0), and the atmosphere is in hydrostatic equilib-rium, for a unit mass of air in the parcel we have:

cv dT + p dα = 0

cv dT + d(p α)− α dp = 0

cv dT + d(R T )− α dp = 0

(cv + R)dT + g dz = 0

cp dT + g dz = 0

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Page 23: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

The Dry Adiabatic Lapse RateWe will now derive an expression for the rate of change oftemperature with height of a parcel of dry air as it movesabout in the Earth’s atmosphere.

Since the air parcel undergoes only adiabatic transforma-tions (dq = 0), and the atmosphere is in hydrostatic equilib-rium, for a unit mass of air in the parcel we have:

cv dT + p dα = 0

cv dT + d(p α)− α dp = 0

cv dT + d(R T )− α dp = 0

(cv + R)dT + g dz = 0

cp dT + g dz = 0

Dividing through by dz, we obtain

−(

dT

dz

)=

g

cp≡ Γd

where Γd is called the dry adiabatic lapse rate.6

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Since an air parcel expands as it rises in the atmosphere,its temperature will decrease with height so that Γd is apositive quantity.

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Since an air parcel expands as it rises in the atmosphere,its temperature will decrease with height so that Γd is apositive quantity.

Substituting g = 9.81ms−2 and cp = 1004JK−1kg−1 gives

Γd =g

cp= 0.0098 K m−1 = 9.8 K km−1 ≈ 10 K km−1

which is the dry adiabatic lapse rate.

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Page 26: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Since an air parcel expands as it rises in the atmosphere,its temperature will decrease with height so that Γd is apositive quantity.

Substituting g = 9.81ms−2 and cp = 1004JK−1kg−1 gives

Γd =g

cp= 0.0098 K m−1 = 9.8 K km−1 ≈ 10 K km−1

which is the dry adiabatic lapse rate.

It should be emphasized again that Γd is the rate of changeof temperature following a parcel of dry air that is beingraised or lowered adiabatically in the atmosphere.

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Page 27: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Since an air parcel expands as it rises in the atmosphere,its temperature will decrease with height so that Γd is apositive quantity.

Substituting g = 9.81ms−2 and cp = 1004JK−1kg−1 gives

Γd =g

cp= 0.0098 K m−1 = 9.8 K km−1 ≈ 10 K km−1

which is the dry adiabatic lapse rate.

It should be emphasized again that Γd is the rate of changeof temperature following a parcel of dry air that is beingraised or lowered adiabatically in the atmosphere.

The actual lapse rate of temperature in a column of air,which we will indicate by

Γ = −dT

dz,

as measured for example by a radiosonde, averages 6 or7Kkm−1 in the troposphere, but it takes on a wide rangeof values at individual locations.

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Potential Temperature

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Potential TemperatureDefinition: The potential temperature θ of an air parcelis the temperature that the parcel of air would have if itwere expanded or compressed adiabatically from its existingpressure to a standard pressure of p0 = 1000hPa.

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Potential TemperatureDefinition: The potential temperature θ of an air parcelis the temperature that the parcel of air would have if itwere expanded or compressed adiabatically from its existingpressure to a standard pressure of p0 = 1000hPa.

We will derive an expression for the potential temperatureof an air parcel in terms of its pressure p, temperature T ,and the standard pressure p0.

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Page 31: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Potential TemperatureDefinition: The potential temperature θ of an air parcelis the temperature that the parcel of air would have if itwere expanded or compressed adiabatically from its existingpressure to a standard pressure of p0 = 1000hPa.

We will derive an expression for the potential temperatureof an air parcel in terms of its pressure p, temperature T ,and the standard pressure p0.

For an adiabatic transformation (dq = 0) the thermodynamicequation is

cp dT − α dp = 0

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Page 32: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Potential TemperatureDefinition: The potential temperature θ of an air parcelis the temperature that the parcel of air would have if itwere expanded or compressed adiabatically from its existingpressure to a standard pressure of p0 = 1000hPa.

We will derive an expression for the potential temperatureof an air parcel in terms of its pressure p, temperature T ,and the standard pressure p0.

For an adiabatic transformation (dq = 0) the thermodynamicequation is

cp dT − α dp = 0

Using the gas equation pα = RT yields

cp dT − RT

pdp = 0 or

dT

T=

R

cp

dp

p

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Integrating from standard ressure p0 (where, by definition,T = θ) to p (with temperature T ), we write:∫ T

θ

dT

T=

R

cp

∫ p

p0

dp

p

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Integrating from standard ressure p0 (where, by definition,T = θ) to p (with temperature T ), we write:∫ T

θ

dT

T=

R

cp

∫ p

p0

dp

p

Evaluating the integrals, we get:

log

(T

θ

)=

R

cplog

(p

p0

)= log

(p

p0

)R/cp

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Integrating from standard ressure p0 (where, by definition,T = θ) to p (with temperature T ), we write:∫ T

θ

dT

T=

R

cp

∫ p

p0

dp

p

Evaluating the integrals, we get:

log

(T

θ

)=

R

cplog

(p

p0

)= log

(p

p0

)R/cp

Taking the exponential (antilog) of both sides

T

θ=

(p

p0

)R/cp

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Integrating from standard ressure p0 (where, by definition,T = θ) to p (with temperature T ), we write:∫ T

θ

dT

T=

R

cp

∫ p

p0

dp

p

Evaluating the integrals, we get:

log

(T

θ

)=

R

cplog

(p

p0

)= log

(p

p0

)R/cp

Taking the exponential (antilog) of both sides

T

θ=

(p

p0

)R/cp

Solving for θ,

θ = T

(p

p0

)−R/cp

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Defining the thermodynamic constant κ = R/cp, we get

θ = T

(p

p0

)−κ

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Defining the thermodynamic constant κ = R/cp, we get

θ = T

(p

p0

)−κ

This equation is called Poisson’s equation.

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Defining the thermodynamic constant κ = R/cp, we get

θ = T

(p

p0

)−κ

This equation is called Poisson’s equation.

For dry air, R = Rd = 287JK−1kg−1 and cp = 1004JK−1kg−1.

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Page 40: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Defining the thermodynamic constant κ = R/cp, we get

θ = T

(p

p0

)−κ

This equation is called Poisson’s equation.

For dry air, R = Rd = 287JK−1kg−1 and cp = 1004JK−1kg−1.

Recall that, for a diatomic gas, R : cp = 2 : 7, so

κ =2

7≈ 0.286

? ? ?

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Conservation of θ

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Page 42: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Conservation of θRecall the thermodynamic equation in the form

ds ≡ dq

T= cp

dT

T−R

dp

p= cp

θ(∗)

The quantity ds is the change in entropy (per unit mass).

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Page 43: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Conservation of θRecall the thermodynamic equation in the form

ds ≡ dq

T= cp

dT

T−R

dp

p= cp

θ(∗)

The quantity ds is the change in entropy (per unit mass).

By definition, diabatic changes have dq = 0.Therefore, we also have ds = 0 and dθ = 0.

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Page 44: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Conservation of θRecall the thermodynamic equation in the form

ds ≡ dq

T= cp

dT

T−R

dp

p= cp

θ(∗)

The quantity ds is the change in entropy (per unit mass).

By definition, diabatic changes have dq = 0.Therefore, we also have ds = 0 and dθ = 0.

Thus, [Adiabatic

Changes

]correspond to

[Isentropic

Changes

]

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Page 45: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Conservation of θRecall the thermodynamic equation in the form

ds ≡ dq

T= cp

dT

T−R

dp

p= cp

θ(∗)

The quantity ds is the change in entropy (per unit mass).

By definition, diabatic changes have dq = 0.Therefore, we also have ds = 0 and dθ = 0.

Thus, [Adiabatic

Changes

]correspond to

[Isentropic

Changes

]We can write the thermodynamic equation (*) as:

dq

dt=

cpT

θ

dt

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Page 46: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Conservation of θRecall the thermodynamic equation in the form

ds ≡ dq

T= cp

dT

T−R

dp

p= cp

θ(∗)

The quantity ds is the change in entropy (per unit mass).

By definition, diabatic changes have dq = 0.Therefore, we also have ds = 0 and dθ = 0.

Thus, [Adiabatic

Changes

]correspond to

[Isentropic

Changes

]We can write the thermodynamic equation (*) as:

dq

dt=

cpT

θ

dt

The potential temperature is constant for adiabatic flow.The entropy is constant for adiabatic flow.

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Parameters that remain constant during certain transfor-mations are said to be conserved. Potential temperature isa conserved quantity for an air parcel that moves around inthe atmosphere under adiabatic conditions.

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Page 48: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Parameters that remain constant during certain transfor-mations are said to be conserved. Potential temperature isa conserved quantity for an air parcel that moves around inthe atmosphere under adiabatic conditions.

Potential temperature is an extremely useful parameter inatmospheric thermodynamics, since atmospheric processesare often close to adiabatic, in which case θ remains essen-tially constant.

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Page 49: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Parameters that remain constant during certain transfor-mations are said to be conserved. Potential temperature isa conserved quantity for an air parcel that moves around inthe atmosphere under adiabatic conditions.

Potential temperature is an extremely useful parameter inatmospheric thermodynamics, since atmospheric processesare often close to adiabatic, in which case θ remains essen-tially constant.

Later, we will consider a more complicated quantity, theisentropic potential vorticity, which is approximately con-served for a broad range of atmospheric conditions.

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Thermodynamic Diagrams

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Thermodynamic DiagramsTo examine the variation of temperature in the vertical di-rection, the most obvious approach would be to plot T as afunction of z.

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Page 52: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Thermodynamic DiagramsTo examine the variation of temperature in the vertical di-rection, the most obvious approach would be to plot T as afunction of z.

It is customary to use T as the abscissa and z as the ordinate,to facilitate interpretation of the graph.

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Page 53: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Thermodynamic DiagramsTo examine the variation of temperature in the vertical di-rection, the most obvious approach would be to plot T as afunction of z.

It is customary to use T as the abscissa and z as the ordinate,to facilitate interpretation of the graph.

For the mean conditions, we obtain the familiar picture,with the troposphere, stratosphere, mesosphere and ther-mosphere.

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Atmospheric stratification.

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The Tephigram

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Page 56: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

The TephigramThere are several specially designed diagrams for depictionof the vertical structure. The one in common use in Irelandis the tephigram.

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Page 57: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

The TephigramThere are several specially designed diagrams for depictionof the vertical structure. The one in common use in Irelandis the tephigram.

The name derives from T -φ-gram, where φ was an old nota-tion for entropy. It is a temperature-entropy diagram.

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Page 58: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

The TephigramThere are several specially designed diagrams for depictionof the vertical structure. The one in common use in Irelandis the tephigram.

The name derives from T -φ-gram, where φ was an old nota-tion for entropy. It is a temperature-entropy diagram.

The tephigram was introduced by Napier Shaw (1854–1945),a British meteorologist, Director of the Met Office.

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Page 59: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

The TephigramThere are several specially designed diagrams for depictionof the vertical structure. The one in common use in Irelandis the tephigram.

The name derives from T -φ-gram, where φ was an old nota-tion for entropy. It is a temperature-entropy diagram.

The tephigram was introduced by Napier Shaw (1854–1945),a British meteorologist, Director of the Met Office.

Shaw founded the Department of Meteorology at ImperialCollege London, and was Professor there from 1920 to 1924.He did much to establish the scientific foundations of mete-orology.

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Page 60: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

The TephigramThere are several specially designed diagrams for depictionof the vertical structure. The one in common use in Irelandis the tephigram.

The name derives from T -φ-gram, where φ was an old nota-tion for entropy. It is a temperature-entropy diagram.

The tephigram was introduced by Napier Shaw (1854–1945),a British meteorologist, Director of the Met Office.

Shaw founded the Department of Meteorology at ImperialCollege London, and was Professor there from 1920 to 1924.He did much to establish the scientific foundations of mete-orology.

We owe to Shaw the introduction of the millibar (now re-placed by the hectoPascal).

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Page 61: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

We define the change in specific entropy due to the additionof heat to a unit mass of material:

ds =dq

T

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Page 62: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

We define the change in specific entropy due to the additionof heat to a unit mass of material:

ds =dq

T

By the first law of thermodynamics, this can be written

ds =cpdT − αdp

T= cp

dT

T−R

dp

p(∗)

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Page 63: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

We define the change in specific entropy due to the additionof heat to a unit mass of material:

ds =dq

T

By the first law of thermodynamics, this can be written

ds =cpdT − αdp

T= cp

dT

T−R

dp

p(∗)

But recall the definition of potential temperature:

θ = T

(p

p0

)−κ

or log θ = log T − κ(log p− log p0)

16

Page 64: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

We define the change in specific entropy due to the additionof heat to a unit mass of material:

ds =dq

T

By the first law of thermodynamics, this can be written

ds =cpdT − αdp

T= cp

dT

T−R

dp

p(∗)

But recall the definition of potential temperature:

θ = T

(p

p0

)−κ

or log θ = log T − κ(log p− log p0)

Differentiating and multiplying by cp, we have

cpdθ

θ= cp

dT

T−R

dp

p(∗∗)

16

Page 65: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

We define the change in specific entropy due to the additionof heat to a unit mass of material:

ds =dq

T

By the first law of thermodynamics, this can be written

ds =cpdT − αdp

T= cp

dT

T−R

dp

p(∗)

But recall the definition of potential temperature:

θ = T

(p

p0

)−κ

or log θ = log T − κ(log p− log p0)

Differentiating and multiplying by cp, we have

cpdθ

θ= cp

dT

T−R

dp

p(∗∗)

From (*) and (**) it follows that

ds = cpdθ

θ= cpd log θ

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Page 66: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Again,ds = cpd log θ

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Page 67: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Again,ds = cpd log θ

Integrating from a reference value θ0 where s = s0, we get

s = cp log(θ/θ0) + s0

? ? ?

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Page 68: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Again,ds = cpd log θ

Integrating from a reference value θ0 where s = s0, we get

s = cp log(θ/θ0) + s0

? ? ?

We will now consider a straightforward plot of T against s(figure to follow).

17

Page 69: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Again,ds = cpd log θ

Integrating from a reference value θ0 where s = s0, we get

s = cp log(θ/θ0) + s0

? ? ?

We will now consider a straightforward plot of T against s(figure to follow).

The entropy is linearly related to the logarithm of potentialtemperature θ. Thus

s = cp log θ + const.

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Page 70: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Again,ds = cpd log θ

Integrating from a reference value θ0 where s = s0, we get

s = cp log(θ/θ0) + s0

? ? ?

We will now consider a straightforward plot of T against s(figure to follow).

The entropy is linearly related to the logarithm of potentialtemperature θ. Thus

s = cp log θ + const.

We can thus plot θ instead of s on the vertical axis, on alogarithmic scale.

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Page 71: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

The temperature-entropy diagram or tephigram. Theregion of primary interest is indicated by the small box.

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Page 72: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Next, recall the definition of potential temperature:

θ = T

(p

p0

)−κ

.

19

Page 73: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Next, recall the definition of potential temperature:

θ = T

(p

p0

)−κ

.

Taking logarithms of both sides,

log θ = log T − κ log p + const.

ors = cp log T −R log p + const.

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Page 74: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Next, recall the definition of potential temperature:

θ = T

(p

p0

)−κ

.

Taking logarithms of both sides,

log θ = log T − κ log p + const.

ors = cp log T −R log p + const.

So, for a constant value of pressure, s is given by the loga-rithm of temperature. We can plot a series of such curvesof s against T for a range of values of pressure, and get thepicture shown above.

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Page 75: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Next, recall the definition of potential temperature:

θ = T

(p

p0

)−κ

.

Taking logarithms of both sides,

log θ = log T − κ log p + const.

ors = cp log T −R log p + const.

So, for a constant value of pressure, s is given by the loga-rithm of temperature. We can plot a series of such curvesof s against T for a range of values of pressure, and get thepicture shown above.

The region of interest for the lower atmopshere is indicatedby a small square. This region is extracted and used in thedesign of the tephigram. Since surfaces of constant pressureare approximately horizontal, it is convenient to rotate thediagram through 45◦.

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Page 76: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

The temperature-entropy diagram or tephigram. Zoomand rotation of area of interest (Wallace & Hobbs,

1st Edn, p. 96).

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Page 77: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Notes on Tephigram:

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Page 78: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Notes on Tephigram:

• The spacing on the temperature axis is uniform.

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Page 79: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Notes on Tephigram:

• The spacing on the temperature axis is uniform.

• log θ is uniformly spaced, so that θ is not. However, on therestricted range, the spacing of θ appears nearly uniform.

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Page 80: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Notes on Tephigram:

• The spacing on the temperature axis is uniform.

• log θ is uniformly spaced, so that θ is not. However, on therestricted range, the spacing of θ appears nearly uniform.

• The isobars are fairly close to horizontal.

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Page 81: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Notes on Tephigram:

• The spacing on the temperature axis is uniform.

• log θ is uniformly spaced, so that θ is not. However, on therestricted range, the spacing of θ appears nearly uniform.

• The isobars are fairly close to horizontal.

• We can think of the chart as a plot of temperature as afunction of pressure. However, its special design enablesus to deduce stability properties by inspection.

21

Page 82: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Notes on Tephigram:

• The spacing on the temperature axis is uniform.

• log θ is uniformly spaced, so that θ is not. However, on therestricted range, the spacing of θ appears nearly uniform.

• The isobars are fairly close to horizontal.

• We can think of the chart as a plot of temperature as afunction of pressure. However, its special design enablesus to deduce stability properties by inspection.

• Lines of constrant temperature are called isotherms.

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Page 83: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Notes on Tephigram:

• The spacing on the temperature axis is uniform.

• log θ is uniformly spaced, so that θ is not. However, on therestricted range, the spacing of θ appears nearly uniform.

• The isobars are fairly close to horizontal.

• We can think of the chart as a plot of temperature as afunction of pressure. However, its special design enablesus to deduce stability properties by inspection.

• Lines of constrant temperature are called isotherms.

• Lines of constant potential temperature are called adia-bats or isentropes.

21

Page 84: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Notes on Tephigram:

• The spacing on the temperature axis is uniform.

• log θ is uniformly spaced, so that θ is not. However, on therestricted range, the spacing of θ appears nearly uniform.

• The isobars are fairly close to horizontal.

• We can think of the chart as a plot of temperature as afunction of pressure. However, its special design enablesus to deduce stability properties by inspection.

• Lines of constrant temperature are called isotherms.

• Lines of constant potential temperature are called adia-bats or isentropes.

• Lines of constant pressure are called isobars.

21

Page 85: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Extract from the Met Eireann web-site

(9 August, 2004)

A tephigram is a graphical representation of observations of pres-sure, temperature and humidity made in a vertical sounding of theatmosphere. Vertical soundings are made using an instrument calleda radiosonde, which contains pressure, temperature and humiditysensors and which is launched into the atmosphere attached to aballoon.The tephigram contains a set of fundamental lines which are usedto describe various processes in the atmosphere. These lines in-clude:

• Isobars — lines of constant pressure

• Isotherms — lines of constant temperature

• Dry adiabats — related to dry adiabatic processes (potentialtemperature constant)

• Saturated adiabats — related to saturated adiabatic processes(wet bulb potential temperature constant)

On the tephigram there are two kinds of information represented22

Page 86: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

• The environment curves (red) which describes the structure ofthe atmosphere

• The process curves (green) which describes what happens to aparcel of air undergoing a particular type of process (e.g. adi-abatic process)

In addition, the right hand panel displays height, wind directionand speed at a selection of pressure levels.Tephigrams can be used by the forecaster for the following pur-poses

• to determine moisture levels in the atmosphere

• to determine cloud heights

• to predict levels of convective activity in the atmosphere

• forecast maximum and minimum temperatures

• forecast fog formation and fog clearance

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Page 87: IV. Adiabatic Processes - UCD School of Mathematics …. Adiabatic Processes If a material undergoes a change in its physical state (e.g., its pressure, volume, or temperature) without

Sample Tephigram based on radiosode ascent from Valential

Observatory for 1200 UTC, 9 August, 2004.

24