'IUPAC ICGC ; 1 (Dresden) : 2006.09.10-15' A.. Pavia/I. Fagnoni, M ... Allahabad/IND,Tiwari, S.,...

18
gesellschaft Deutscher Chehiker Consorzio Interuniversitario „Chimlca per I'Amblente" nm^^nmsm ifps lltlillili sins miii Chemistry sponsored by t,^'n^slt> efeM\,MtU£ee>**ei. 0 Bimdesministeruim far Umwett, Nalurschutz und Raaktorsicharrieit Deutsche Eundesstiftung Umwelt Wm TIB/UB Hannover 130 243 507 89

Transcript of 'IUPAC ICGC ; 1 (Dresden) : 2006.09.10-15' A.. Pavia/I. Fagnoni, M ... Allahabad/IND,Tiwari, S.,...

gesellschaft

Deutscher ChehikerConsorzio Interuniversitario

„Chimlca per I'Amblente"

nm^^nmsm

ifps

lltlillilisinsmiii

Chemistry

sponsored by

t,^'n^slt> efeM\,MtU£ee>**ei. 0Bimdesministeruimfar Umwett, Nalurschutzund Raaktorsicharrieit

Deutsche Eundesstiftung Umwelt

Wm

TIB/UB Hannover

130 243 507

89

SCIENTIFIC PROGRAM

Lecture Program

List of Posters

CONTENTS &&BM

6

22

SOCIAL PROGRAM 46

ABSTRACTS OF THE LECTURES

Opening Lecture and Plenary Lectures

Keynote Lectures

Oral Contributions

49

55

75

ABSTRACTS OF THE POSTERS 179

AUTHORS INDEX 457

LIST OF PARTICIPANTS 471

MAP 499

5

Page

TU Dresden, Lecture Hall 3

18.00 Opening Ceremony

19.00 OPENING LECTURE

Future Outlook - Social Change and Innovation in the 21th Century 51

Ruff. R. Berlin/D

20.00Get-together

22.00

TU Dresden, Lecture Hall 3

08.30 PLENARY LECTURE

Will fusion ever be a safe, clean and sustainable energy source? 52

Ane. J.-M.. St Paul les Durache/F

BENIGN SYNTHESES ROUTES- HETEROGENEOUS CATALYSIS

TU Dresden, Lecture Hall 3

09.30 KEYNOTE LECTURE

Towards an industrially viable synthesis of 7-acetyi-1,1,3,4,4,6-hexa- 57

methyltetralin - a musk in shades of green

Newman. C. P., Canterburv/GB

10.10 New applications of indium catalysts: A novel and green concept 77

in fine chemical industryBonrath. W.. Basel/CH, Wildermann, A., Basel/CH, Netscher, T,

Basel/CH, Foricher, Y, Basel/CH

10.30 Coffee Break

10.50 Inorganic Crystalline-Supported Metal Complex Catalysts for 78

Environmentally Benign Organic SynthesisKaneda. K, Osaka/J

11.10 High surface area metal fluorides supported palladium and platinum: 79

Novel heterogeneous catalystsPatil. P.T.. Berlin/D. GroB, U., Berlin/D, ROdiger, S„ Berlin/D,

Kemnitz, E., Berlin/D

11.30 Environmentally friendly heterogeneous acid and base catalysis for 80

the methyiation of 1,2-diphenol: chances for the control of regio-

and chemo-selectivityCavani. R. Boloana/I. Ardizzi, M., Bologna/I, Ballarini, N., Bologna/I,

Chiappino, E., Bologna/I, Dal Pozzo, L, Bologna/I, Maselli, L, Bologna/I,Rovinetti, S., Bologna/I

Page

TU Dresden Lecture Hall 3

08 30 PLENARY LECTURE

Will fusion ever be a safe, clean and sustainable energy source? 52

Ane. J -M.St Paul les Durache/F

EDUCATION IN GREEN CHEMISTRY

TU Dresden Lecture Hall 4

09 30 KEYNOTE LECTURE

Title to be announced 64

1010 How will REACH contribute to sustainable chemistry? 133

Stemhauser. K G . Dessau/D. Richter, S, Dessau/D

10 30 Coffee Break

10 50 The work of Chemistry Department of Moscow M V Lomonosov 134

State University on the education and enlightment in the field of

green chemistryLokteva, E S

.Moscow/RUS. Lunin, V V, Moscow/RUS

1110 Developing a Green Chemistry Module for Undergraduate Students 135

Sevhan. H G.Ankara/TR. Morgil, I, Ankara/TR, Secken, N ,

Ankara/TR,

Yucel, A S,Ankara/TR, Yavuz, S , Ankara/TR, Oskay, O O

,Ankara/TR

1130 Green Chemistry Education within Chemical Education 136

Mammino, L. Thohovandou/ZA

7

Page

11 50 Alkylation-acylation of p-xylene with (5-butyrolactone and vinylacetic 81

acid catalyzed by heteropolycaid supported on silica

Kamiya. Y. Sapporo/J. Ooka, Y, Saporro/J, Ohmshi, R,Saporro/J,

Fujita, T, Saporro/J, Kurata, Y, Saporro/J, Tsuji, K, Saporro/J, Nakajyo, T,

Saporro/J, Okuhara, T, Saporro/J

1210 Acetylation of aromatics over H-BEA and H-FAU zeolites: seeking 82

for a viable alternative to Fnedel-Crafts catalysts

Guidotti. M .Milano/I. Canaff, C ,

Poitlers/F, Coustard, J -M , Poitiers/F,

Magnoux, P, Poitiers/F, Guisnet, M ,Poitiers/F

12 30 Lunch Break

14 00 Acid zeolites for the synthesis of acetals from carbohydrates 83

Rauter. A P. Lissabon/P. Xavier, N M, Lisboa/P, AlmeidaT, Lisboa/R

Lucas S,Lisboa/P, Marques, J P, Ram6a-Ribeiro, F, Lisboa/P,

Guisnet, M, Poitiers/F

14 20 Catalytic green routes to functionalized quinones 84

Sorokm. A. B.Villeurbanne/F. Zalomaeva, O V, Villeurbanne/F,

Kholdeeva, O A,Novosibirsk/RUS

14 40 An Efficient CeO^y-alumina Catalyst for the Oxidative 85

Dehydrogenation of Ethylbenzene Using N20Ramaswamy. V. Pune/IND. Murugan, B

,Pune/IND, Ramaswamy, A V,

Pune/IND

15 00 Supported gold nanoparticles are more selective than palladium 86

for the aerobic solvent-less oxidation of allylic alcohols

Garcia. H.Valencia/E. Abad, A, Valencia/E

15 20 A novel route for fine chemicals: cinnamaldehyde hydrogenation 87

over Supported Ionic Liquid Catalysts (SILCA)

Mikkola. J -P. Abo-Turku/FIN, Virtanen, P, Abo -Turku/FIN

15 40 Coffee Break

16 00 Sustainable, Gas-phase Methanol Carbonylation with Supported Ionic 88

Liquid Phase (SILP) CatalysisJoraensen, B

.Kas Lvnqbv/DK. Rnsager, A ,

Kgs Lyngby/DK,

Fehrmann, R, Kgs Lyngby/DK, Wassersheid, P, Erlangen/D

16 20 Nitration of Aromatics Over Solid Acid Catalysts Using Dilute Nitric Acid 89

Dongare. M K. Pune/IND. Umbarkar, S B,Pune/IND

16 40 Heterogeneous catalysts and process for reductive dechlorination 90

of polychlonnated hydrocarbonsLokteva. E S

.Moscow/RUS. Kachevsky, S A, Moscow/RUS,

Golubina, E V, Moscow/RUS, Lunin, V V, Moscow/RUS,

Turakulova, A O,Moscow/RUS, Tundo, P, Moscow/RUS

17 00 Green-Sustainable Chemistry in the Production of Nicotinates 91

Chuck. R. Bng-Glis/CH

18 30 Reception of the Mayor

8

LECTURE PROGRAM ,

Page

11.50 Green Chemistry, The Need to Develop, A Developing Countrys 137

PerspectiveTawfic Ahmed. M„ Cairo/ET

12.10 Sustainability in the Organic Chemistry Lab Courses 138

On behalf ofthe NOP-Team: Bahadir. M„ Braunschweia/D

12.30 Lunch Break

BENIGN PROCESS TECHNOLOGY - PHOTO CHEMISTRY

TU Dresden, Lecture Hall 4

14.00 KEYNOTE LECTURE

Photocatalysis and Solar Hydrogen Production 65

Kudo. A.. Tokvo/J

14.40 Photochemistry in synthesis: where, when, why 139

Albini, A.. Pavia/I. Fagnoni, M„ Pavia/1, Dondi, D„ Pavia/1

15.00 "Green Photochemistry" - The Production of Fine Chemicals 140

with Sunlight

Oelgemoeller, M.. Dublin/IRL Jung, O, Koln/D, Mattay, J., Bielefeld/D

15.20 Radical Addition of Tertiary Amines with Alkenes - Application to 141

the Synthesis of Nitrogen Containing HeterocyclesHoffmann. N.. Reims/F

15.40 Coffee Break

16.00 Investigation into continuous synthetic organic photochemistry 142

Lobedan. L, Leeds/GB. Rayner, C. M, Leeds/GB

16.20 Photocatalytic activity of heterogenized FeCI4' and CuCI4z" in the 143

chloride-assisted chlorination of alkanes

Maldotti, A.. Ferrara/I. Varani, G., Ferrara/I, Molinari, A., Ferrara/I

BENIGN PROCESS TECHNOLOGY - NEW REGULATION DEVICES

TU Dresden, Lecture Hall 4

16.40 KEYNOTE LECTURE

Novel Devices and Monitoring Strategies for Green and Sustainable 66

Chemistry Processes

Brett. C. M. A.. Coimbra/P

18.30 Reception of the Mayor

9

Page

BENIGN SYNTHESES ROUTES - HOMOGENEOUS CATALYSIS

TU Dresden, Lecture Hall 3

08.30 KEYNOTE LECTURE

Catalysisand Green Chemistry: the Key to Sustainability 58

Sheldon. R. A.. Delft/NL

09.10 Green Chemistry in Practice: Examples from Degussa 92

Almena, J.Hanau/D

09.30 New Iridium and Rhodium Complex Catalysts derived from Indolyl 93

Imines

Black. D.Svdnev/AUS, Ho Hui Hui, J., Sydney/AUS, Messerle, B. A.,

Sydney/AUS

09.50 Rhodium Catalyzed Decarbonylation of Aldehydes 94

Taarnina, E.. Lvngbv/DK. Kreis, M , Lyngby/DK, Monrad, R., Lyngby/DK,

Madsen, R., Lyngby/DK

10 10 Environmentally Benign Synthesis of Substituted Quinolines by Iridium 95

CatalysisShimizu. I.. Tokvo/J, Nakajima, T, Tokyo/J, Inada, T, Tokyo/J,

Igarashi, T, Tokyo/J, Sekioka, T, Tokyo/J

10.30 Coffee Break

10.50 Metal poor and domino cross-coupling reactions as benign 96

synthetic routes

Kotschv, A.. Budapest/H. Novak, Z., Budapest/H, Csekei, M.,

Budapest/H, Biro, A. B., Budapest/H, Nagy, A., Budapest/H

11.10 Towards Green Plastics via Stereoselective Ring-Opening 97

Polymerization of Racemic Lactide and p-Butyrolactone with

Discrete Lanthanide Catalysts

Carpentier, J.-F. Rennes/F. Amgoune, A, Rennes/F, Thomas, C. M.,

Rennes/F

11.30 An Effective Metal-Catalysed Hydroarylation of Styrenes 98

Nachtsheim. B. J.. Frankfurt (MainVD. Rueping, M., Frankfurt (Main)/D

11.50 Hydrosilylation reactions catalyzed by Mo02CI2: a DFT interpretation 99

Calhorda. M. J.. Lisboa/P. Costa, P. J„ Lisboa/P, Romao, C. O, Oeiras/P,

Fernandes, A. C, Oeiras/P, Royo, B., Oeiras/P

12.10 Sustainable Oxidation Processes in the Laboratory and 100

in Technical Scale

Lenoir. D . Neuherberg/D, Chahbane, N., Neuherberg/D, Collins, T. S ,

Pittsburgh/USA, Schramm, K.-W., Neuherberg/D

12.30 Lunch Break

10

LECTURE PROGRAM

Page

BENIGN PROCESS TECHNOLOGY - MICRO WAVE TECHNOLOGY

TU Dresden, Lecture Hall 4

08.30 KEYNOTE LECTURE

Microwave - Dream or Nightmare? 67

Ondruschka. B„ Jena/D

09.10 Microwave-Assisted Organic Synthesis in Near-Critical Water at 300 C. 144

A Proof-of-Concept StudyKremsner. J. M., Graz/A. Kappe, C. O., Graz/A

09.30 Contribution to the Enhancement of Carvone Extraction from 145

Carum carvi L Seeds by Means of Ultrasound and Micowave

Heating Processes

Chemat. S„ Ataiers/DZ. Lagha, A., Algiers/DZ, Ait-Amar, H., Algiers/DZ,

Esveld, D. O, Wageningen/NL

09.50 Greener routes to pharmaceutical^ and indusrially important 146

compoundsParmar. V. S„ Delhi/IND. Watterson, A. C, Lowell/USA

10.10 Microwave-assisted Transformation of Glucose into Anhydroglucose 147

Kaaa. H.. Sapporo/J. Sasaki, A., Sapporo/J, Sasaki, M., Sapporo/J,

Narumi, A., Sapporo/J, Takahashi, K., Kanazawa/J, Satoh, T, Sapporo/J,

Kakuchi, T„ Sapporo/J

10.30 Coffee Break

10.50 Microwave promoted hydrolysis of plant seed gums on Alumina 148

supportSinah. V.. Allahabad/IND, Tiwari, A., Allahabad/IND, Kumari, P.,

Allahabad/IND, Tiwari, S., Allahabad/IND

BENIGN PROCESS TECHNOLOGY - MICRO REACTOR TECHNIQUE

TU Dresden, Lecture Hall 4

11.10 KEYNOTE LECTURE

Microreaction Technology: Benign by Design 68

Lerou. J. J.. Plain City/USA

11.50 Sustainable Production in the Chemical Industry 149

Brahner. B.. Dessau/D, Krause, B., Dessau/D, Dubbert, W., Dessau/D,

Drotleff, J., Dessau/D, Angrick, M., Dessau/D

12.10 Research on Photoreactions in Microreactors150

Ichimura. T„ Tokvo/J. Sakeda, K„ Tokyo/J, Matsushita, Y, Tokyo/J,

Suzuki, T, Tokyo/J, Tanibata, K., Tokyo/J, Murata, T„ Tokyo/J

12.30 Lunch Break

11

BENIGN SYNTHESES ROUTES - ENZYMATIC CATALYSIS

14.00

14.40

15.00

15.20

15.40

16.00-

17.00

TU Dresden, Lecture Hall 3

KEYNOTE LECTURE

Contributions of Biocatalytic Processes to Industrial Green Chemistry 59

Witholt. B.. Zurich/CH

myo-lnositol Oxygenase: a Novel Biocatalyst for a New Industrial 101

Process

McFarlan. S„ Excelsior/USA, Schroeder, W„ Excelsior/USA,Sanchez-Riera, F, Excelsior/USA, deTroostembergh, J.-C, Vilvoorde/B

Xenobiotic Cell-Stress in Whole-Cell Biocatalysis - Causes, Effects 102and Control

Bertau. M., Dresden/D, Smolinskl, J., Dresden/D, Leppchen, K.,

Dresden/D, Katzberg, M., Dresden/D, Joerg, G., Dresden/D

Dynamic kinetic resolution of amines with heterogeneous Pd 103

catalysts and lipasesParvulescu. A.N.. Leuven/B. DeVos, D., Leuven/B, Jacobs, P., Leuven/B

Biocatalytic oxidoreductions for enantioselective and environmentally 104

benign syntheses: catalyst discovery and cofactor recyclingLi. Z. Sinaapore/SGP

Poster Session (even numbers) - Coffee Break

17.30 Visit of the Frauenkirche

12

Page

FUTURE GREEN ENERGY SOURCES - FUEL CELL TECHNOLOGY

TU Dresden, Lecture Hall 4

14.00 KEYNOTE LECTURE

Alternative Powertrains - Innovative Solutions for Reduction 69

of Consumption and Emissions

Lamm. A. Stuttaart/D

14.40 New fuels as methanol substututes in DMFC 151

Dubois. J.-L. Paris/F. Vigier, F., Poitiers/F, Coutanceau, O, Poitiers/F,

Leger, J.-M., Poitiers/F

15.00 Modification of proton - conducting membranes based on 152

poly(benzimidazoles)Smolvaninova. N A.. Ulan-Ude/RUS. Lenskaya, E. V, Ulan-Ude/RUS

15.20 Sulfonated Poly(ether sulfone)s for Fuel Cells by Solvent-Free 153

PolymerizationMeier-Haack. J

.Dresden/D. Vogel, C„ Dresden/D, Butwilowski, W.,

Dresden/D, Lehmann, D„ Dresden/D

FUTURE GREEN ENERGY SOURCES - ENERGY SAVING

TU Dresden, Lecture Hall 4

15.40 Recycling of polyolefins in steam-cracking 154

Tunaler. A. P. Budapest/H. Pinter, A., Budapest/H, Nagy, L,

Budapest/H, Vida, L., Budapest/H, Kerezsi, J., Budapest/H

17 00

~

Poster Session (even numbers) - Coffee Break

17.30 Visit ofthe Frauenkirche

13

Page

TU Dresden Lecture Hall 3

08 30 PLENARY LECTURE

Pursuing Practical Elegance in Chemical Synthesis 53

Novori. R . Saitama/J

BENIGN SYNTHESES ROUTES - NEW REAGENTS

TU Dresden, Lecture Hall 3

09 30 KEYNOTE LECTURE

Green Approaches to Highly Selective Processes: Reactions of 60

Dimethyl Carbonate Over Zeolites and Bases

Selva. M . Venezia/I

10 10 Water soluble polymers for environmentally benign applications 105

Chitanu. G C.lasi/RO

10 30 Coffee Break

10 50 Electrolysis for the benign conversion of renewables 106

Schafer. H.Munster/D. Weiper, A., Munster/D, Schamann, M ,

Munster/D, Plate, M, Munster/D, Harenbrock, M , Munster/D

1110 Ionic Liquids and Clays, Greener Solvents and Catalysts 107

Scott. J L. Melbourne/AUS, Strauss, C R., Melbourne/AUS,Rosamilia, A E, Melbourne/AUS, Higham, L T, Melbourne/AUS,

Giarrusso, M,Melbourne/AUS, Mohan, R

, Bloommgton/USA, Path, A F,

Melbourne/AUS, Wallis, P J,Melbourne/AUS, Gates, W, Melbourne/AUS

BENIGN SYNTHESES ROUTES - END OF PIPE-TECHNOLOGY

TU Dresden, Lecture Hall 3

1130 KEYNOTE LECTURE

End of the pipe off-gas treatment in Nitric Acid plants 61

TiBler. A . Bruckmuhl/D. Fischer, R W, Bruckmuhl/D, Schwefer, M ,

Dortmund/D

12 10 Heteropolyacids as effective catalysts to obtain zero sulphur diesel 108

de Angelis. A. San Donato/I. Molinan, D,San Donato/I, Pollesel, P,

San Donato/I, Frattmi, A , Bologna/I, Berti, D,San Donato/I, Parker, W O

,

San Donato/I, Martins, S C,Des Plames/USA, Perego, C

,San Donato/I

1 30 Evaluation of an electrochemical process to treat industrial 109

wastewaters

Baune. M.Bremen/D. Lmke-Wienemann, V, Bremen/D, Thommg, J

,

Bremen/D, Arevalo, E , Hamburg/D

Boat trip with dinner

LECTURE PROGRAM

Page

TU Dresden Lecture Hall 3

08 30 PLENARY LECTURE

Pursuing Practical Elegance in Chemical Synthesis 53

Novon. R, Saitama/J

FUTURE GREEN ENERGY SOURCES - HYDROGEN TECHNOLOGY

TU Dresden Lecture Hall 4

09 30 KEYNOTE LECTURE

The C02 Dilemma in the March to a H2 Economy 70

Armor. J N.Orefield/USA

10 10 A multi-stage bioprocess for hydrogen and methane production 155

from biomass

Schumacher. M.Aachen/D. Modigell, M ,

Aachen/D, Teplyakov, V V,

Moscow/RUS

10 30 Coffee Break

10 50 PVC hydrocracking with recovenng of a large amount of H2. Characten- 156

zation of the catalysts and the products after each step of the process

Giomelli. T.Tokvo/J. Qian, E W, Tokyo/J, Dumeignil, F, Lille/F,

Ishihara, A, Tokyo/J

1110 Direct synthesis of hydrogen peroxide from H2 and 02 using 157

supported Au-Pd catalystsEdwards. J

.Cardiff/GB. Solsona, B

,Valencia/E, Hutchings, G

,

Cardiff/GB, Carley, A, Cardiff/GB

11 30 Solvent-free oxidation of benzyl alcohol and hydrogen peroxide 158

synthesis using titania-supported gold-palladium catalystsEnache. D I. Cardiff/GB. Barker, D

,Cardiff/GB, Edwards, J K

Cardiff/GB, Taylor, S H , Cardiff/GB, Carley, A F, Cardiff/GB,

Knight, D W, Cardiff/GB, Hutchings, G J,Cardiff/GB

11 50 Synthesis of H202 from H2 and 02 and selective oxidation of phenol 159

on nano-sized Pd metal catalyst deposited on Ti-containing zeolite

by a photo-assisted deposition (PAD) method

Yamashita, H.Suita-Osaka/J, Miura, Y, Siuta-Osaka/J, Mori, K,

Siuta-Osaka/J, Masui, Y, Siuta-Osaka/J, Tomonan, M ,Sluta-Osaka/J,

Mimura, N, Siuta-Osaka/J

12 10 Hydrogen yield from water catalyzed radiolysis 160

Cecal. A. iasv/RO. Macovei, A, lasi/RO, Tamba, G, lasi/RO, Haota, O ,

lasi/RO, Ganju, D , lasi/RO, Rusu, I, lasi/RO

12 30 Bio-hydrogen production by catalytic ethanol steam reforming 161

Rass-Hansen. J .Kas Lvnabv/DK Falsig, H , Kgs Lyngby/DK, Dahl, S ,

Kgs Lyngby/DK, Sehested, J,Kgs Lyngby/DK, Helveg, S

,

Kgs Lyngby/DK, Chnstensen, C H,Kgs Lyngby/DK

?n no

~"

Boat tn[D Wl* dinner

15

Page

BENIGN SYNTHESES ROUTES - ALTERNATIVE SOLVENTS

TU Dresden, Lecture Hall 3

08 30 KEYNOTE LECTURE

Chemical Reactions in Supercritical Fluids 62

Poliakoff. M, Nottingham/GB

09.10 Intensification of Ionic Liquid Production Processes 110

Stark. A.. Jena/D. Ondruschka, B., Jena/D

09 30 Highly Effective Dehydration of Alcohols in Ionic Liquids 111

Ignatiev. N.. Darmstadt/D, Koppe, K., Duisburg/D, Barthen, P.,

Duisburg/D, Frohn, H.-J., Duisburg/D

09.50 Co(l)-Catalyzed Cyclotrimerisation of Alkynes in Nitrile Functionalised 112

Ionic LiquidsLombardo. M.. Bologna/I. Pasi, R, Bologna/I, Trombini, C, Bologna/I,

Seddon, K. R„ Belfast/UK

1010 Carbon Dioxide: Synthon and Solvent - A Case Study: Synthesis 113

of Dialkyi Carbonates

Plasseraud. L, Dijon/F, Ballivet-Tkatchenko, D, Dijon/F

10.30 Coffee Break

10.50 Green Processes for Asymmetric Dyhdroxylation of Olefins 114

Branco. L. O, Lisbon/P. Afonso, C. A. M., Lisbon/P

11.10 Synthesis of nickel nanoparticles dispersed in porous polystyrene 115

microspheres by compressed C02 antisolvent process

Han. B. H. Beijing/PRC. Zhang, J., Beijing/PRC, Zhang, O, Beijing/PRC,Miao, Z., Beijing/PRC, Sun, Z., Beijing/PRC

11 30 Heteropolyacids as Nano and Micro Catalyst for the Development 116

of Organic Green Procedures

Vazquez. P. La Plata/RA. Tundo, P., Venezia/I, Romanelii, G., La Plata/RA

11 50 Development of Protocols for Green Halogenation Utilizing 117

Fluorous (Br2), Aqueous Phase (NBS, HBr/H202) and Aerobic

Bromination (Air/HBr)Iskra. J.. Liubliana/SLO. Podgorsek, A., Ljubljana/SLO, Stavber, S.,

Ljubljana/SLO, Zupan, M., Ljubljana/SLO

1210 Quantitative large-scale syntheses without solvents for sustainable 118

production giving pure product while avoiding purifying workupKaupp. G

. Oldenburg/D

12.30 Lunch Break

16

Page

FUTURE GREEN ENERGY SOURCES - BIO DIESEL

TU Dresden Lecture Hall 4

08 30 KEYNOTE LECTURE

Biodiesel 71

Freund. E. Rueil-Malmaison/F

09 10 Bioglycerol Transformation into Glycols via Heterogeneous Catalysis 162

Jacobs. P. Heverlee/B. DHondt, E, Heverlee/B, Sels, B,Heverlee/B,

Jacobs, P, Heverlee/B

09 30 Solid catalysts for conversion of vegetable oils to biodiesel and 163

biolubricants

Snnivas. P.. Pune/IND. Ratnasamy, P, Pune/IND

09 50 SunDiesel - a new promising biofuel for sustainable mobility 164

Krmke. S„ Wolfsburg/D. Nannen, H, Wolfsburg/D, Degen, W, Stuttgart/D,

Hoffmann, R, Sindelfingen/D, Rudloff, M

, Freiberg/D, Bartz, M , Stuttgart/D

1010 Process Intensification in Biodiesel Production by a Robust Hybrid 165

Reactor

Thomma. J.Bremen/D. Ambrosini-Broxtermann, T, Bremen/D,

Broxtermann, O, Cloppenburg/D

10 30 Coffee Break

USE OF RENEWABLES - BIOMASS TECHNOLOGY

TU Dresden, Lecture Hall 4

10 50 KEYNOTE LECTURE

The Chemistry Transforming Bio-Mass into Liquid Fuel 72

Zhu. Q. Hefei/PRC

11 30 Renewable Feedstocks: New Syntheses with Oils and Fats 166

Biermann. U.Oldenbura/D, Metzger, J O

, Oldenburg/D

11 50 Glycerol - Waste of Biomass Technology? On its Selective Aerobic 167

Oxidation over Gold CatalystsDemirel-Gulen. S . Darmstadt/D. Lehnert, K, Darmstadt/D, Kern, P,

Darmstadt/D, Lucas, M , Darmstadt/D, Claus, P, Darmstadt/D

12 10 Organic Carbonates from C02 using a Novel Inorganic-Organic 168

Hybrid based Heterogeneous CatalystSankar. M

.Pune/IND. Kala Raj, N K

, Pune/IND, Ajithkumar, T G,

Pune/IND, Manikandan, P, Pune/IND

12 30 Lunch Break

17

Page

USE OF RENEWABLES - STARCH, CELLULOSE, SUGAR

TU Dresden Lecture Hall 3

14 00 KEYNOTE LECTURE

Biodegardable Plastic materials from Renewable Resources 63

Bastioh. C.Novara/I. Degli Innocent, F Novara/I

14 40 Green Chemistry for Sustainable Development: L'OREAL's 119

Commitment

Philippe. M D.Aulnav sous Bois/F

15 00 Dehydration of glucose in superheated steam 120

Sasaki. M. Sapporo/J, Takahashi, K, Kanazawa/J, Satoh, H, Kanazawa/J,

Sasaki, A Sapporo/J, Kaga, H, Sapporo/j

15 20 Transformation of Sugars to C-Glycosides in Water 121

Cavezza. A. Aulnav-sous-Bois/F. Dalko-Csiba M,Aulnay-sous-Bois/R

Pichaud, P, Aulnay-sous-Bois/F, Ricard, L,Palaiseau/F

15 40 Production of biodegradable polymers from organic wastes by 122

mixed microbial cultures enriched in sequencing batch reactors

Dionisi. D.Rome/I. Beccan, N

, Rome/I, Di Gregono, S ,Verona/I,

Majone, M ,Rome/I, Petrangeli Papmi, M ,

Rome/I

17 00P°ster Session (odd numbers) - Coffee Break

19 00 Semper Opera

18

<t- ->*?,?,>*'<< ?»:. s ;tam>it:nJw

..*«...,*£„..,/".k\..^..J*i,....,au,,.,'. LECTURE PROGRAM

it, 4

14 00 Green Synthesis of Ureas and Carbamates Using C02 as a C, Building 169

Block

Ion. A . Leuven/B. Parvulescu, V I Bucharest/RO, Jacobs, P

Leuven/B De Vos D,Leuven/B

14 20 Environmentally Acceptable Synthesis of Oxazolidinones from Pro- 170

pargylamines and Carbon Dioxide in the Presence of Basic Alumina

Maqgi, R„ Parma/I. Orlandini, E, Parma/I, Oro, C,Parma/I Sarton G

,

Parma/I

14 40 Catalytic transformation upon NiHZSM-5 zeolite of the vegetable 171

biomass pyrolysis bio-oil dissolved in methanol

Valle, B„ Bilbao/E. Atutxa, A Bilbao/E, Alonso, A, Bilbao/E,

Gayubo, A G Bilbao/E, Bilbao, J,Bilbao/E

15 00 Formation of Carbonated Methyl Soyate from Epoxidized Soybean Oil 172

Holser. R. Peoria/USA

15 20 Novel non- phosgene polycarbonate production process using 173

by-products C02 as a starting matenal

Fukuoka. S.Tokvo/J Fukawa, I, Tokyo/J

15 40 Future Challenges in Sourcing Biomass as Base Material for 174

Chemical Industnes

Schwarze. S .Bonn/D. Lahl, U ,

Bonn/D

17 00

~~

Poster Session (odd numbers) - Coffee Break

19 00 Semper Opera

19

Page

«miiMi

USE OF RENEWABLES - STARCH, CELLULOSE, SUGAR

TU Dresden Lecture Hall 3

08 30 Sustainable and Green Aqueous-phase Oxidation of Bioethanol 123

to Acetic Acid Using Gold CatalystsChnstensen, C H

. Kgs Lvngbv/DK. Jorgensen, B Kgs Lyngby/DK,Rass Hansen J Kgs Lyngby/DK, Riisager, A, Kgs Lyngby/DK

Egeblad, K Kgs Lyngby/DK

08 50 Ionic liquids and their application in cellulose chemistry 124

Erdmenger. T. Emdhoven/NL. Hansch, C,Eindhoven/NL

Schubert U S,Emdhoven/NL

09 10 Aerocellulose - New Ultra-light Porous Cellulose from 125

Cellulose-NaOH-Water Solutions

Gavillon. R. Sophia-Antipolis/F. Budtova T, Sophia-Antipolis/F

09 30 Cellulose fibers with switchable slow-release of medically active 126

substances

Rosenau. T. Vienna/A, Potthast A, Vienna/A Kosma P, Vienna/A

09 50 Use of Renewable Cyclodextrins in Textile Finishing 127

Grechin. A G . Krefeld/D. Buschmann, H -J,Krefeld/D, Schollmeyer E

Krefeld/D

1010 Polymerization of Biodegradable Phenolic Phytomonomers Creates 128

Environmentally-Degradable LC Ecoplastics with Extremely-HighPerformance

Kaneko. T. Nomi/J Kaneko M,Nomi/J

10 30 Catalytic approach for clean tailor made modification of 129

polysaccharides by oxidation for different applicationsSorokm. A B

.Villeurbanne/F. Kachkarova-Sorokma, S L

Villeurbanne/R Gallezot, P, Villeurbanne/F

10 50 Coffee Break

12 30

~

poster Award and Closing remarks

20

Page

USE OF RENEWABLES - BIOMASS TECHNOLOGY

TU Dresden, Lecture Hall4

08.30 Catalytic Dehydration of Biomass-derived Polyols in High Pressure 175

Water

Sarlea. M- Darmstadt/D. Vogel, H., Darmstadt/D

08.50 Glycerol transformation to valuable intermediates for the chemical 397

industry I

Duquenne. C Aachen/D. Ulgen, A., Aachen/D, Sabater, S., Aachen/D,

Holderich, W., Aachen/D, Dubois, J.-L, Pierre Benite/F

09.10 International Biorefinery-Systems 176

Kamm. B„ Teltow/D. Kamm, M., Potsdam/D

USE OF RENEWABLES - NEW DETERGENTS

TU Dresden, Lecture Hall 4

09.30 KEYNOTE LECTURE

Surfactants based on Renewable Resources for Personal Care 73

and Home Care

Hill. K. Monheim/D

10.10 Synthesis of O- and N-Acylated surfactants of fatty acids on 177

UL-MFI type materials

Parvulesco. I. V.. Bucharest/RO. Kaliaguine, S., Quebec/CDN

10.30 Arjunolic acid: A Promising New Chiral Building Block for 178

Supramolecular Chemistry and Nano-science

Bag. B. G„ Midnapore/IND

10.50 Coffee Break

TU Dresden, Lecture Hall 3

Poster Award and Closing remarks

21