Hydrogenation of Oils
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Transcript of Hydrogenation of Oils
PowerPoint Presentation
ContentsIntroduction
Problem
Prior Art
Our Approach
References
HydrogenationAddition of hydrogen molecule on double bonds or triple bonds in an organic moleculeLeads to reduction or saturationMostly a catalytic process
Eg.
3 atm, H2PdVegetable Oil HydrogenationProcess to turn unsaturated oils into saturated fats
Saturated fats have a longer shelf-life
Involves three major components- heat, metal catalyst and pressurized H2 gas.Why Monounsaturated Fats(MUFA)?Reduce risks of strokes, heart diseases and cancer
Help the body absorb nutrients
Reduces total cholesterol, triglycerides and LDL cholesterolProblemConvert polyunsaturated fatty acids (two or three double bonds) into monounsaturated fatty acids
No generation of completely saturated fatty acids and hence no increase in stearic percentage
Type of chemical transformation expected Linolenic C18:3 Linoleic C18:2 Oleic C18:1
Higher selectivity towards cis isomer of oleic acid
Heat and mass balance and cost per MT of feed
Basic ReactionPolyunsaturated fatty acids7-10% alpha linolenic acid, 51% linoleic acid, 23% oleic acidMonounsaturated fatty acidsCis-oleic acid (major)Trans-oleic acid (minor)Cu/SiO2453K, 2MPa, 1000rpmWhy Copper/Silica Catalyst?Extremely cheap
Mild and hence shows good selectivity
Comparatively non toxic
Better results as compared to its copper/chromite counterpart