GORDES ZEOLITE PRESENTATION(GORDES)

26
The address where Turkish zeolite is sought for in the World!

Transcript of GORDES ZEOLITE PRESENTATION(GORDES)

Page 1: GORDES ZEOLITE PRESENTATION(GORDES)

The address where Turkish zeolite is

sought for in the World!

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The Founder of the Öztürk Group, Fikret Öztürk, who started his private business at the beginning of the 80’s, has since made some unique achievements in the business world. By

investing in the future he attained a position of respect in business circles. He made the Öztürk

Group a multi-faceted company with his entrepreneurial spirit. The steady success accomplished

in the field of petrol trade and distribution directed the company towards business sectors with a

huge growth potential such as real estate development and food. Today, the Öztürk Group is

noted for its professional management, high performance companies, sound financial

infrastructure and ongoing innovative project launches.

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Established in 1992, OPET Petrolcülük A.ù. is engaged in distribution and International trading of oil

products. In 2002, the Koç Holding Energy Group became a 50% shareholder in Opet. Since its inception, OPET has been heavily investing in infrastructure. Its storage capacity (terminals) gives

Opet a significant competitive edge, of which capacity has reached 845,930 cubic meters. Having been increasing its market share continuously the company’s goal is to become the first choice of

Turkish consumers. Opet’s efforts are based on ensuring customer satisfaction through improved

quality while protecting the environment and strictly complying with all applicable laws and

regulations.With its robust infrastructure and realistic vision, and its faith in Turkey, Opet has become

the fastest and most steadily growing oil company of the last decade in Turkey.Currently, there are

1600 petrol stations across Turkey under Opet and SUNPET.

www.opet.com.tr

Türk Hava Yolları A.O. and OPET Petrolcülük A.ù. have each 50% interest in the company THY OPET Havacılık Yakıtları A.ù. established on September 18, 2009 with a 75-million-dollar investment

budget to operate in the field of fuel storage and refueling of aircrafts. Combining the aviation expertise of Turkish Airlines that proceeds on its path to become one of the

leading airlines of Europe with Opet’s long-established presence in the fuel sector, THY OPET aims

to become a landmark company in each category in which it operates at home and abroad with a

focus on “Unconditional Customer Satisfaction and High Quality” with its experienced and qualified workforce.

Having commenced jet fuel supply and into plane operations on July 1, 2010 with its strong technical

infrastructure and the specially equipped state-of-the-art refuellers and dispensers, THY OPET was

capable of providing supply and into plane services in all airports Turkey-wide as of the end of 2010.

THY OPET is a company that aims to meet the fuel requirements of national and global airlines,

including THY. THY OPET operates at all airports in Turkey today.

www.thyopet.com

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Opet Petrolcülük A.ù. carries out its Mineral Oil production operations at its facility located at İzmir Atatürk Organized Industrial Zone. Opet Fuchs A.ù

facility which is capable of producing 30,000 tons of mineral oil and 6 million units of car care products on an annual basis via a single shift has the

following certificates: TS EN ISO 9001: 2000 Quality Management System and TS EN ISO 14001:2004 Environmental Management System, TS

18001:1999 OHSAS - Occupational Health and Safety Administration System and TS 16949 Quality Management System for Automotive and Relevant Spare Part Producers. It has also obtained Ford Q1 and TSE EN ISO/IEC 17025 Laboratory Accreditation Certificates. Opet Fuchs A.ù a broad product

range in the Mineral Oil and Car Care Market with our FMY branded products approved by Opet, Fuchs, Rom, Wynn's, Türk Traktör and Ford Otosan.

Approved by the internationally respected engine producers such as MAN, Volvo, Mercedes Benz, and Ford, our products are preferred by the consumer.Opet MineralOilsand Rom Car Care Products are also exported to more than20countries.

Opet Fuchs A.ù., a company established in partnership with FUCHS PETROLUB AG, the biggest independent mineral oil producer of the world, in 2005 to engage in the

production and distribution of industrial oils, is every day

progressing on its way to become the leader of the

industrial oil market in Turkey.

www.opetfuchs.com

Regnum is a leading property developer with projects in Turkey, Bulgaria and the UK. Regnum offers a diverse range of projects suitable for different levels of investment and requirements. City projects in Istanbul and London

offer potentially significant capital appreciation and healthy rental yields for its investors. Regnum’s lifestyle

projects are currently located in the beach resort of Bodrum-Turkey and the ski resort of Bansko-Bulgaria offering

secure well managed complexes of the highest quality.

Completed projects include: Sky Residence, Elitkent and Astrum Towers in Istanbul, Bargylia in Bodrum,

Carya Golf Club in Belek-Antalya, the office & logistics project, Gimat, in Ankara, Crystal Luxury Ski &

Spa Apartments in Bansko and Helion Place in London. Current projects include: Solarkent in Istanbul,

Escana in Bodrum, and a project in the vicinity of Tower Bridge in London. Regnum is also working on major gated community projects in Turkey around the İstanbul and Antalya areas.

Future plans include: projects in Kosuyolu and Cobancesme, in Istanbul, Belek in Antalya, Plovdiv in

Bulgaria and Royal Mint Street in London-UK.

www.regnum.com.tr

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Güvenok Logistics has been conducting transportation operations of OPET warehouses and renders transportation service to all OPET dealers who demand it, and carries out the transportation operations of

OPET Commercial Industrial Fuels department. Furthermore, it has been executing all the transportation

operations of TÜPRAù since June2006. Operating in accordance with EMRA and State Highways transportation standards, which are requirements to be observed by the fuel transportation sector, Güvenok

A.ù. has adopted the principle of safe and high quality service. The company conducts outgoing supply

operations in HSE-S standard via ADR Certified tankers and trailers, meeting ADR standards.

www.guvenok.com.tr

www.caryagolf.com

Carya Golf Club invites you to experience Turkey’s first heathland inspired

golf course and share our traditional style golf club, which we hope you will

make a home away from home during your stay in Antalya’s Belek region.

Our outstanding golf course has been designed by Thomson Perrett &Lobb Golf Course Architects, the international golf course design practice founded by

five time British Open Champion Peter Thomson. As you would expect, a very

special

and memorable round of golf awaits you.

Carya Golf Course is a naturally beautiful golf course set on undulating sand hills. Inspired by the classic heathland courses found in the UK where Peter

Thomson enjoyed much success as a player in the 1950’s and 1960’s, the

spectacular Par 72 layout measures 6,563metres (7,177 yards) from the championship tees, with free flowing golf holes running through the pine forest.

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Based upon 30 years of experience in business, Öztürk Group is now the owner of Gordes Zeolite that takes part in the area of

the most productive zeolite deposits thus the group has started to provide services in the mining sector during the last quarter of 2011, as well.

Our company which had been known as “Enli Mining” in the world natural zeolite literature with its qualified and comprehensive sectorial

backgroud since 1998, is now named as “Gordes Zeolite” which is the name of this distinguished region we produce clinoptilolite raw material.

Gordes Mining is one of the well-known manufacturers of natural zeolite in the world in terms of the purity of the product and innovation. The area

we produce this industrial raw material, which has the ability of solving many problems naturally, such as air-water-soil pollution and global

warming, has become a preferred mineral deposit and a requested name worldwide in recent years.

Production land of Gordes Mining has features of high quality clinoptilolite structure. It is the only private field in the country that contents high

grade of clinoptilolite type of Zeolite, as the mostly sought and the most widely used type of zeolite among the other 7 types of zeolite which have

commercial importance. In addition, our mine is the only one in the world, including two different recipes of clinoptilolite (potassium and calcium

clinoptilolite) in the same quarry. The mine has a rich source containing potassium, sodium and calcium clinoptilolite -type Clinoptilolite.

Furthermore, our clinoptilolite products differ from the others in the market in terms of purity and functionality. Quality of our products is also

revealed by the academic studies and industrial trials in universities and industrial foundations.

Gordes has undertaken an important mission in the representation of Turkey's

high quality zeolite -based products in the world's natural zeolite platform even it

is the leading Turkish company that has provided to EU market with the local

commercial coded products, enabling the sector to survive. For more than 17

years, our company has been dealing with the marketing and sales business of

clinoptilolite based products all over the world. Technical Team of the Company

is experienced in using and applications with zeolite based products in scope of

agricultural and animal feed industry, especially in Turkey. Gordes Zeolite is a

leading company that has offered the natural zeolite with the specifications in

mass quantities.

www.gordeszeolite.com

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The commercial brands are now indispensable in this market. The product i.e. Agro-Clino,

Clino-San, Nat-Min 9000 code are preferred to almost all zeolite based products in the

global market. The R&D works in our company is of the utmost importance and the

production is carried out complying with the quality requirements of ISO 22000-2005 and

ISO 9001-2008. Considering the benefits of our products, it is obviously seen that our

products are more functional and cost effective compared to other raw materials and

products in the market.

Our mission is to process this industrial raw material using the most advanced technologies

and provide it with the most useful forms and recipes for the service of humanity.

The need of humanity for nature and natural, is increasing every day. We believe, this

stone has life in it and we desire to make this wonder of nature a part of our lives by the special products we developed, and provide humanity a clean, lively World.

www.gordeszeolite.com

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Mine Deposit Information

City Town Village Location Licence number

Starting time to mine

Licence group, acording to Law for Mining in Turkey

Mine type

Production land

Manisa Gördes Kıranköy Hekim Damları

32242

1998 IV-a

Mineral, Zeolite

3231,41 hectar (32 km2)

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Mine Deposit Information 144 million tons (proven), 1,5 billion tons geological reserve. Deposit determined by a

professional team from Istanbul Technical University. It was also accepted by Republic

of Turkey, Ministry of Energy & Natural Resources. Land is also declared by General Directorate of Mineral Resource & Exploration. In this publication, lower tuff unit has

more than 85% of zeolite (clinoptilolite), 1,1 billion tons, proven, but covered reserve is

estimated about more than 10 billion tons according to this production

The map for location: Production land is about 150 km far from Izmir Port.

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About Zeolite

Zeolites are described as hydrated aluminum silicates. According to the lexical meaning of the term “Zeolite” means

"boiling stone” . It was discovered by

Freiherr Axel Fredrick Cronstedt, a famous

Swedish mineralogist, in 1756.

Millions of years ago, the zeolites have been formed due to the chemical reaction of ash and lavas as a result of volcano

explosion with the lakes and sea water.

The varieties such as the temperature

geological location-water/ash ratio provide

the zeolites with unique specifications. 50

natural zeolite types have been defined

with different compositions in last200

years. Clinoptilolite is the one that has

been widely used with industrial purpose

featuring

the

commercial

value.

The cage-shaped structure of zeolites makes a wide internal and outer surface area for ion

exchange and chemical reactions. The pores cover the volume by 50%. These pores function

as the molecular sieve. Zeolites are naturally loaded negative and capable of high ion

exchange. Due to the porous structure and high ion exchange capacity, the zeolites are

capable to keep and absorb many kinds of gas and odor, water and moisture, petrochemical substances, low level radioactive elements, ammonium, toxins, heavy metals and many

solutions. Thanks to environmentally friendly and low costs, zeolite is used in many industrial

areas and a variety of environmental projects.

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CLINOPTILOLITE

Millions tons of zeolites are used globally every year. The most widespread zeolite group is

clinoptilolite. Main usage areas are; agricultural products (fertilizer additive and soil amendment), construction sector, radioactive and other pollution refinement. Clinoptilolite have hundreds of usage

areas thanks to their high cation exchange, heavy metal removal, water retention capacity and large

surface area.

Some of them are as follows;

Mineral fertilizer additive and soil conditioner for

animal and farming applications

Mineral fertilizer additive and soil conditioner for

gardening applications

Building and construction material

Cement additive

Removal of oil spills

Desiccants

Water filtration

Domestic purposes

Carrier of pesticide and herbicide

Animal feed additive

* Anti-caking agent / flow agent

- Toxin-binder - Feed pellet-binder

Cleaning of marine oil and surface damp

Processing of animal waste

Odor control

Cleaning of chemical spills, hazardous waste

Waste treatment

Natural filtrating material for drinking water and

waste water treatment

Cleaning of waste

Carrier of colloidal materials

Products with vitamin

Nuclear improvement

Carrier of enzymes, antibiotics, glucose, sugar

Food additive

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GORDES ZEOLITE (CLINOPTILOLITE) Gordes zeolite is in clinoptilolite structure. It is highly pure as can be seen on the photograph

demonstrating its crystal structure. Our products are in potassium-calcium alumina silicate

structure.

Chemical structure of our Gordes zeolite products are as follows:

Element: % by weight Si =

29.4

- 30.1 Al =

5.6

-6.1 Fe =

0.05

- 0.25 Mg =

0.1

- 0.6 Ca =

0.9

- 1.3 Na =

0.2

- 0.5 K=

1.9

- 2.7

SEM Photograph of Gordes Clinoptilolite (Crystalline structure )

Unit cellular chemistry of Gordes clinoptilolite (chemical

formulation) is as follows;

(Na 0.5 K 2.5) (Ca 1.0 Mg 0.5)(Al 6 ,Si 30) O 72 . 24 H2O

Description: Natural potassium, calcium, magnesium, sodium, hydrate

alumina- silicate mineral.

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GORDES ZEOLITE (CLINOPTILOLITE )

In its chemical composition, main oxide components

except trace elements are;

Oxide Component

% (By Weight)

SiO2

67.11

Al2O3 11.84 Fe2O3 1.47

Some of the physical characteristics are;

Natural rock, white, beige,

MgO 1.15 CaO 2.18

Color

Hardness (according to Mohs hardness scale)

almond green

3

Na2O

0.38

Specific Weight

2,1 g/cm³

K2O 3.44 Ignition loss 12.5

Visible porosity 35% Water absorption capacity 135% Water retention capacity 20-50% Thermal stability:

840 °C

Surface area (BET)

40͘79 m²/g

NH4 ion exchange

capacity:

1,7-2,1 meq/g

Thermal stability Up to 840 °C Clinoptilolite crystal size 5-15 μ m

pH stability: 1,5-11,5

Average pore radius 0,041 μ m

Capacity of water

absorption by weight:

20-40%

Quiet homogenous, containing 85- Mineralogical feature: 99% clinoptilolite. Gangues are

Feldspar, mica and clay.

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Current Product Line of Gordes Zeolite Mining Corporation

CLINO-SAN

Clinoptilolite for many of miscellaneous purposes

Animal feed additive,

NAT-MIN 9000

Covers EU feed lows

(Contents minimum 90 % Clinoptilolite, up to 99 %) Fertilizer additive and soil amendment , for all uses in agriculture

AGRO-CLINO

High C.E.C., water adsorption capacity, covers Organic Farm Input Material, EC 2092/91,

Annex II Fertilizer additive and soil amendment, especially for grasses, golf courses and horticultural applications.

CLINO-ÇİM

High C.E.C., water adsorption capacity, covers organic farm input material, EC 2092/91,

Annex II

Animal litter ZETA

High C.E.C., ammonium adsorbent, odour and moisture removing, Drinking and waste water treatment, FILTER-CLINO

High C.E.C., ammonium adsorbent, and heavy metal adsorbent, particle size is optional

CLINOPTILOLITE For current and other applications, prepared according to demands, special material

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FEED ADDITIVE PRODUCTS

Nat-Min 9000 is a product that is safely used by factories that produce feed for dairy and beef cattle, broiler and laying hens, sheep and turkey raising. Using high CEC feature, it retains water, oil and many molten minerals (Na, CA, Ammonium) in its channels, releases them effectively during digestion and provides an

effective, well balanced and healthy diet.

Nat-Min 9000 is mixed with the feed (2%, approximately 1-2 tablespoons to 1 liter of feed) of the pets,

poultries, bovine and ovine animals. Product may also be added to the drinking water of aminals, at the same

rate. It supports digestion, removes hazardous substances(such as ammonia, ammonium, heavy metals,

mycotoxins) quickly from their metabolisms and enhances growth of animals. You can safely use Nat-Min

9000 which is produced from totally natural minerals.

Nat-Min 9000 provides improvement of the appetite of the animals, regulation of digestion system and

strengthening of the immune system.

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AGRICULTURAL PRODUCTS

Using AGRO-CLINO in Plant Nutrition

Clinoptilolite releases its natural nutritional elements into soil by ion exchange. Thus, nutritional elements enrich the soil. It also maintains cation exchange and

water retention feature for a long time since it is not dissolved in water.

AGRO-CLINO as Soil Conditioner AGRO-CLINO is an excellent soil conditioner with its high cation exchange capacity, water retention and adsorption

features. In a research conducted in China, yield of the products like potato, corn and wheat has increased between 5,8 - 14,14% by its addition to soil in certain quantities. It was stated that clinoptilolite improved water regime of the soil and

prevented washing of the nutritional elements in soil.

Effects of AGRO-CLINO on Benefiting from Fertilizer • AGRO-CLINO can function in plant nutrition as ionic fertilizer additive by translocation with ammonium and

potassium. Besides, the most important macro-nutritional elements, potassium and nitrogen and the most important

micro elements, iron, copper, manganese and zinc can be provided by means of AGRO-CLINO.

• AGRO-CLINO prevents nitrogen fertilizer from being washed with high selectivity of clinoptilolite against ammonia and

high ammonium exchange capacity. • As the particle size of clinoptilolite decreases, its surface area and water retention capacity increases. Moisture rate

detained in the soil increased as well, based on the implemented clinoptilolite dosage.

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USAGE

Turf can be mixed with chemical fertilizer and farm fertilizer and used in cultivation of all plants under field

and greenhouse conditions. In fruit trees such as apple, cherry, peach, nut, apricot, quince, plum and banana, it is mixed with soil to

branch knot at root level.

Amount to be used depends on the plant and soil structure.

For fruit trees:

2-6 kg/tree

For industrial plants:

50 kg/da For vegetables:

50 kg/da Greenhouses:

150-200 kg/da Cereal production:

50 kg/da Nut production:

2,5 - 5 kg/da Strawberry production:

100-150 kg/da

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ANIMAL LITTER PRODUCTS

ZETA is a 100% natural product that can be used directly or mixed with other base plate materials with its high water retention capacity, and ability to adsorb ammonia

gas due to its ion exchange feature. Both of the positive features of the product can

be clearly seen in animal base plate applications.

Unpleasant odor caused by ammonia is one of the most serious health problems

encountered in stables of cattle, poultry coops and living environment of pets.

UREA + WATER = = > AMMONIA GAS + CARBON DIOXIDE GAS ZETA’s function can be summarized as removing the moisture on the base plate and

ammonia gas that occurs. Therefore, a base plate material with higher water

retention capacity is required.

USAGE ZETA is used by mixing with wood shavings or other adsorbent materials such as bentonite.

ZETA also keeps the living environment of animals sterile. It is already known that gelling feature of sepiolite and bentonite is fine. However, ZETA has to be coupled with these products when natural and permanent solution is sought for odor control.

We serve you ZETA in 25 kg. packages.

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FILTER PRODUCTS Products Features

Product Name

FILTER CLINO

FILTER CLINO is produced from clinoptilolite, which

is one of the calcium alumina-silicate group minerals and used globally for filtration and refinement applications. FILTER-CLINO is used for

gas separation in drinking water, domestic and

industrial waste water refinement and filter and

refinement material in odor control applications.

Usage Purpose Produced from watery potassium, calcium alumina- silicate Clinoptilolite mineral. Natural mineral fertilizer

additive and soil amendment

Color Whitish beige, white, almond green Specific weight 2.1 g/cm3

Bulk density 0,6 - 1,0 g/cm3

Water retention capacity 20-40% Visible porosity, mean

35 -40%

FILTER CLINO’s Function

Chemical composition

SiO2 = 66-69

Na2O = 0.5 Al2O3 =11-12

K2O = 3-3.5 Water Filtration Applications

Fe2O3 = 1.0-1.7

BaO < 0.1 Urban drinking water

TiO2 < 0.1

SrO < 0.1 Pool water

MgO = 1

LOI = 12-14 Industrial waste water

CaO = 2

FILTER CLINO can absorb pollution in water with

its cation exchange, molecular sieve and

NH4 exchange capacity 1,6 - 2,0 meq/g (Mean) = 1,8 meq/g

adsorbent features, Helps to increase clarity of water,

Filtrates grains below 0,1 micron, Filtrates ammonium, heavy metal ions and

bacteria, Adsorbs ammonium ions, reduces chloramines,

odor and eye burns.

CO2 adsorption capacity Clinoptilolite unit-cellular chemistry

Clinoptilolite Crystal Size

Mean pore diameter size

Surface Area

94 mg CO2/g (Na 0.5 K 2.5) (Ca 1.0 Mg 0.5)(Al 6 ,Si 30) O 72 . 24 H2O

(5-15 mμ)

0,041 μ m

40,79 (m2/g)

Clinoptilolite thermal resistance

(High, up to 840o C')

Particle size 1 -3 m ; 1 - 4 mm, 3 - 7 mm, 4 - 9 mm or in other preferential sizes

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Regeneration: FILTER CLINO is rechargeable and can be used again and again. It can be recharged generally

through a sodium chloride salted water process. 20 g NaCl solution is prepared with 1 liter of water. FILTER CLINO is

well washed before using in filtration system. After recharging, salted water solution will contain ammonium. FILTER

CLINO is replaced by time due to saturation and saturated FILTER CLINO can be used as soil amendment as well.

Using FILTER CLINO in Urban Drinking Water Filtration: FILTER CLINO’s function has three aspects;

Physical filtration; micro sized grains (< 4 micron) are adsorbed on the blanks of mineral grains Chemical filtration; FILTER CLINO is a fine cation exchanger used in removing heavy metals ( Pb, Cu, Cd, Zn, Co,

Cr, Mn, As, Hg, etc) and ammonium, Adsorbs bacteria, algae and various coloring substances). Thanks to its wide surface area, molecular sieve, high cation exchange feature, FILTER CLINO can be used instead

of quartz sand in filtration environments where quartz sand is used. FILTER-CLINO in Aqua Culture Applications: Fish population significantly declined due to reasons such as pollution

of the seas with industrial and domestic waste and demolition of fish beds due to excessive hunting. This event, led

people to different areas to meet the needs of fish. Fish farms and salmon production plants were established in the

seas and fresh waters. In such systems, where closed or circulatory water tanks are used, ammonium occurs as a result of separation of

excrement and feed remnant, which has a toxic effect for fish.

FILTER-CLINO is used in cleaning these waters much more effectively and safely compared to standard biological

systems thanks to its selectivity against Ammonium and Ammonium exchange capacity. FILTER CLINO in Industrial Waste Water Filtration: Heavy metal ions contained by waste water have been

restricted according o EU environmental laws. FILTER CLINO adsorbs easily many monovalent and divalent heavy

metals and also used as an adsorbent or cation exchanger in industrial applications.

Usage FILTER CLINO can bu used directly in filter media. For drinking water treatments; it is mixed with quartz sand in equal

proportions. It can be also mixed with active carbon, resin or other filter materials. It can be regenerated by NaCl

solution easily.

Packaging In 25 or 50 kg pp bags.

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AQUARIUM PRODUCT

Filter Clino-Bio, can be used safely in aquariums as a large ornamental stone and filtrating material.

Product reduces the amount and adverse effects of ammonia, and the fish live in a healthy

environment where they can also use as feed.

Because its appearance is like a natural tuff, Filter Clino-Bio will match easily with other ornamental

stones and materials in the aquarium.

Filter Clino-Bio is provided in 10-25 kg packages.

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CERTIFICATES OF MINE LİCENCES from MINISTRY OF ENERGY & NATURAL SOURCES

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CERTIFICATES

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CERTIFICATES ...

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www.gordeszeolite.com

Headquarters Ankara Cad. No:81 Kat:18 D:123, 35580 Bayraklı/İzmir - TURKEY

Phone : +90-232-3485656, +90-232-3484311 Fax : +90-232-3484310

[email protected]

Production Plant Bodamaz Mevkii, Gördes/Manisa – Turkey

Phone & Fax : +90 236-547-30-17