Flexible organic transistors on standard printing paper...

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Flexible organic transistors on standard printing paper and memory properties induced by floated gate electrode By: Peng, BY (Peng, Boyu) [ 1 ] ; Chan, PKL (Chan, Paddy K. L.) [ 1 ] ORGANIC ELECTRONICS Volume: 15 Issue: 1 Pages: 203-210 DOI: 10.1016/j.orgel.2013.11.006 Published: JAN 2014 View Journal Information Abstract Integrating electronic devices with unconventional substrate has been a popular research direction. Among these substrates, cellulose fiber paper has advantages in low-cost, recyclable and bio-degradable. We demonstrated directing printing of all contact electrodes on standard untreated Fuji Xerox printer paper without using planarization layer. The screen-printed gate electrodes based on silver nanoparticles can smooth out the paper substrate surface by two orders of magnitude and allow us to use parylene and DNTT as the dielectric and active layer directly. The transistors show average mobility of 0.297 cm(2) V-1 s(-1) and on/off ratio larger than 10(5). The low leakage current allows us to demonstrate memory properties by employing the floated gate method. The devices show excellent memory retention time for more than 10,000 s. The unique flexibility and combustibility of the organic transistors on paper substrate manifest their applications as next generation of green electronics. (C) 2013 Elsevier B.V. All rights reserved. Keywords Author Keywords: Screen-printing; Cellulose fiber paper; Memory; Floated gate KeyWords Plus: SELF-ASSEMBLED MONOLAYERS; PERFORMANCE; PENTACENE; HYDROPHILICITY; SEMICONDUCTORS; DIELECTRICS; HYDROLYSIS; ROUGHNESS; CIRCUITS; LAYER Author Information Reprint Address: Chan, PKL (reprint author) Univ Hong Kong, Dept Mech Engn, Pokfulam Rd, Hong Kong, Hong Kong, Peoples R China. Addresses: [ 1 ] Univ Hong Kong, Dept Mech Engn, Hong Kong, Hong Kong, Peoples R China E-mail Addresses: [email protected] Funding Funding Agency Grant Number University of Hong Kong 201209160033 201210159031 View funding text Publisher ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS Categories / Classification Research Areas: Materials Science; Physics Web of Science Categories: Materials Science, Multidisciplinary; Physics, Applied Document Information Document Type: Article Citation Network 3 Times Cited 40 Cited References View Related Records View Citation Map Create Citation Alert (data from Web of Science TM Core Collection) All Times Cited Counts 3 in All Databases 3 in Web of Science Core Collection 1 in BIOSIS Citation Index 0 in Chinese Science Citation Database 0 in Data Citation Index 0 in SciELO Citation Index Most Recent Citation Peng, Boyu. High performance organic transistor active-matrix driver developed on paper substrate. SCIENTIFIC REPORTS, SEP 19 2014. View All This record is from: Web of Science TM Core Collection View Record in Other Databases: View most recent data (in Current Contents Connect ® ) Suggest a correction If you would like to improve the quality of the data in this record, please suggest a correction. Web of Science TM InCites TM Journal Citation Reports ® Essential Science Indicators SM EndNote ® Sign In Help English My Tools Search History Marked List Add to Marked List Full Text from Publisher Save to Other File Formats 1 of 4 Search Return to Search Results Web of Science [v.5.15] - All Databases Full Record http://apps.webofknowledge.com/full_record.do?product=UA&searc... 1 z 2 7. 11. 2014 11:01

Transcript of Flexible organic transistors on standard printing paper...

Flexible organic transistors on standard printing paper and

memory properties induced by floated gate electrode

By: Peng, BY (Peng, Boyu)[ 1 ] ; Chan, PKL (Chan, Paddy K. L.)[ 1 ]

ORGANIC ELECTRONICS

Volume: 15 Issue: 1 Pages: 203-210

DOI: 10.1016/j.orgel.2013.11.006

Published: JAN 2014

View Journal Information

Abstract

Integrating electronic devices with unconventional substrate has been a popular research direction.

Among these substrates, cellulose fiber paper has advantages in low-cost, recyclable and

bio-degradable. We demonstrated directing printing of all contact electrodes on standard untreated Fuji

Xerox printer paper without using planarization layer. The screen-printed gate electrodes based on silver

nanoparticles can smooth out the paper substrate surface by two orders of magnitude and allow us to

use parylene and DNTT as the dielectric and active layer directly. The transistors show average mobility

of 0.297 cm(2) V-1 s(-1) and on/off ratio larger than 10(5). The low leakage current allows us to

demonstrate memory properties by employing the floated gate method. The devices show excellent

memory retention time for more than 10,000 s. The unique flexibility and combustibility of the organic

transistors on paper substrate manifest their applications as next generation of green electronics. (C)

2013 Elsevier B.V. All rights reserved.

Keywords

Author Keywords: Screen-printing; Cellulose fiber paper; Memory; Floated gate

KeyWords Plus: SELF-ASSEMBLED MONOLAYERS; PERFORMANCE; PENTACENE;

HYDROPHILICITY; SEMICONDUCTORS; DIELECTRICS; HYDROLYSIS; ROUGHNESS; CIRCUITS;

LAYER

Author Information

Reprint Address: Chan, PKL (reprint author)

Univ Hong Kong, Dept Mech Engn, Pokfulam Rd, Hong Kong, Hong Kong, Peoples R China.

Addresses:

[ 1 ] Univ Hong Kong, Dept Mech Engn, Hong Kong, Hong Kong, Peoples R China

E-mail Addresses: [email protected]

Funding

Funding Agency Grant Number

University of Hong Kong 201209160033

201210159031

View funding text

Publisher

ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS

Categories / Classification

Research Areas: Materials Science; Physics

Web of Science Categories: Materials Science, Multidisciplinary; Physics, Applied

Document Information

Document Type: Article

Citation Network

3 Times Cited

40 Cited References

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3 in All Databases

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Most Recent Citation

Peng, Boyu. High performance organictransistor active-matrix driverdeveloped on paper substrate.SCIENTIFIC REPORTS, SEP 19 2014.

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Language: English

Accession Number: WOS:000328855800030

ISSN: 1566-1199

eISSN: 1878-5530

Journal Information

Table of Contents: Current Contents Connect ®

Impact Factor: Journal Citation Reports ®

Other Information

IDS Number: 277YS

Cited References in Web of Science Core Collection: 40

Times Cited in Web of Science Core Collection: 3

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Relationship of Surface Hydrophilicity, Charge, and Roughness

of PET Foils Stimulated by Incipient Alkaline Hydrolysis

By: Skvarla, J (Skvarla, Jiri)[ 1 ] ; Luxbacher, T (Luxbacher, Thomas); Nagy, M (Nagy, Martin)[ 1 ] ; Sisol,

M (Sisol, Martin)[ 1 ]

ACS APPLIED MATERIALS & INTERFACES

Volume: 2 Issue: 7 Pages: 2116-2127

DOI: 10.1021/am100368v

Published: JUL 2010

View Journal Information

Abstract

An enhancement of wettability of PET foils pretreated hydrolytically by immersing in mild alkaline (NaOH)

solutions has been documented by a descending sigmoidal dependence between the interfacial free

energy gamma(SL) of the PET/water interface and the concentration of NaOH solution c(NaOH). An

increase in temperature of the NaOH solution below the glass-transition temperature of PET further

promotes the hydrophilicity, resulting in a proportional shift of the gamma(SL) VS c(NaOH) dependence.

The limiting hydrophilicity of PET is thermodynamically predicted to occur at gamma(SL) -> 0,

corresponding to the advancing water contact angle theta(a) approximate to 50 degrees (for 6% NaOH

and 60 degrees C). The surface roughness due to the partial hydrolytic degradation as well as the weight

loss (dissolution) of PET are found to reach a maximum value just when the latter dependence goes

through its inflection. Assuming a general parallelism between the interfacial free energy and the

dissolution kinetics, we propose the hydrolytically stimulated formation and growth of pits on the PET

surface to cause the initial acceleration as well as subsequent retardation of dissolution as c(NaOH),

increases, leading to the S-shaped gamma(SL) VS c(NaOH) dependence with the inflection for a specific

c(NaOH). Moreover, the zeta potential measured by the streaming current method also attains a

maximum at the same specific concentration of NaOH. It would indicate that the largest amount of

electric charges is populated via polar carboxyl and hydroxyl groups created by chemical scissions of

PET polymer chains when a change in the dissolution rate increases to the utmost. In such a way, partial

hydrolysis restricted to the uppermost part of moderately hydrophobic surface of solid PET allowed us to

better understand the intermingled role of thermodynamic and physical aspects in surface wettability

itself:

Keywords

Author Keywords: PET; hydrolysis; wettability; surface roughness; interfacial free energy; contact

angle; alkaline degradation; dissolution

KeyWords Plus: SPUN POLY(ETHYLENE-TEREPHTHALATE) FIBERS; MOISTURE-RELATED

PROPERTIES; FROTH FLOTATION; POLYVINYL-CHLORIDE; POLYMER SURFACES; CONTACT

ANGLES; FREE-ENERGY; ELECTROKINETIC MEASUREMENTS; PVC/PET MIXTURES; FTIR-ATR

Author Information

Reprint Address: Skvarla, J (reprint author)

Tech Univ Kosice, Inst Montaneous Sci & Environm Protect, Ctr Primary & Secondary Raw Mat

Proc, Pk Komenskeho 19, Kosice 04384, Slovakia.

Addresses:

[ 1 ] Tech Univ Kosice, Inst Montaneous Sci & Environm Protect, Ctr Primary & Secondary Raw

Mat Proc, Kosice 04384, Slovakia

E-mail Addresses: [email protected]

Funding

Funding Agency Grant Number

Scientific Grant Agency of the Slovak Republic (VEGA) 2/0159/08

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Most Recent Citation

Peng, Boyu. Flexible organictransistors on standard printing paperand memory properties induced byfloated gate electrode. ORGANICELECTRONICS, JAN 2014.

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Slovak Research and Development Agency APVV-0598-07

View funding text

Publisher

AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA

Categories / Classification

Research Areas: Science & Technology - Other Topics; Materials Science

Web of Science Categories: Nanoscience & Nanotechnology; Materials Science, Multidisciplinary

Document Information

Document Type: Article

Language: English

Accession Number: WOS:000280367000048

ISSN: 1944-8244

Journal Information

Table of Contents: Current Contents Connect ®

Impact Factor: Journal Citation Reports ®

Other Information

IDS Number: 631SB

Cited References in Web of Science Core Collection: 74

Times Cited in Web of Science Core Collection: 4

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Electrokinetic Potential for Characterization of

Nanosctructured Solid Fiat Surfaces

By: Kolska, Z (Kolska, Zdenka)[ 1 ] ; Kasalkova, NS (Kasalkova, Nikola Slepickova)[ 2 ] ; Siegel, J (Siegel,

Jakub)[ 2 ] ; Svorcik, V (Svorcik, Vaclav)[ 2 ]

JOURNAL OF NANO RESEARCH

Volume: 25 Pages: 31-39

DOI: 10.4028/www.scientific.net/JNanoR.25.31

Published: 2013

View Journal Information

Abstract

Electrokinetic potential (zeta potential) is a characteristic parameter for description of the surface

chemistry of solid flat materials and it can be used for a fast analysis of materials modified by different

chemical or physical methods. Due to its sensitivity, zeta potential is able to distinguish surface modified

by coating with monolayers of various materials or nanostructures created after plasma treatment. Also

metal nanostructures deposited on surfaces can be characterized by zeta potential. It can also be used

for isoelectric point determination of materials. We present data on zeta potential in 0.001 mol/dm(3) KCl

at constant pH approximate to 7.0 and also in pH range (2.5-7.0) for isoelectric point determination for

pristine polymers PET, PTFE, PS, LDPE, HDPE, PLLA, PVF, PVDF, PMP and polyimides (Upilex R,

Upilex S, Kapton). The zeta potential of selected polymers, modified by plasma and by chemical coatings

(e.g. by biphenyldithiol or polyethyleneglycol) or by gold deposition was measured too. Zeta potentials of

these modified materials were also studied to confirmation that electrokinetic analysis is acceptable

method for their fast description.

Keywords

Author Keywords: electrokinetic potential; polymers; surface modification; plasma treatment; gold

deposition; cell adhesion and proliferation

KeyWords Plus: CELL-ADHESION; POLYETHYLENE; POLYTETRAFLUOROETHYLENE;

PROLIFERATION; POLYMERS; CHARGE

Author Information

Reprint Address: Kolska, Z (reprint author)

Univ JE Purkyne, Fac Sci, Ceske Mladeze 8, Usti Nad Labem 40096, Czech Republic.

Addresses:

[ 1 ] Univ JE Purkyne, Fac Sci, Usti Nad Labem 40096, Czech Republic

[ 2 ] Inst Chem Technol, Dept Solid State Engn, CR-16628 Prague, Czech Republic

E-mail Addresses: [email protected]; [email protected]; [email protected];

[email protected]

Funding

Funding Agency Grant Number

Grant Agency of Czech Republic 13-06609S

P108/10/1106

View funding text

Publisher

TRANS TECH PUBLICATIONS LTD, LAUBISRUTISTR 24, STAFA-ZUERICH, CH-8712,

SWITZERLAND

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1 Times Cited

20 Cited References

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Most Recent Citation

Reznickova, Alena. Characterization ofSurface Nanostructures on "Thin"Polyolephine Foils. JOURNAL OFNANO RESEARCH, 2014.

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Research Areas: Science & Technology - Other Topics; Materials Science; Physics

Web of Science Categories: Nanoscience & Nanotechnology; Materials Science, Multidisciplinary;

Physics, Applied

Document Information

Document Type: Article

Language: English

Accession Number: WOS:000327907800004

ISSN: 1662-5250

eISSN: 1661-9897

Journal Information

Impact Factor: Journal Citation Reports ®

Other Information

IDS Number: 264UZ

Cited References in Web of Science Core Collection: 20

Times Cited in Web of Science Core Collection: 1

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Modulation of cell adhesion, proliferation and differentiation on materials designed for body implantsBy: Bacakova, Lucie; Filova, Elena; Parizek, Martin; et al.

BIOTECHNOLOGY ADVANCES Volume: 29 Issue: 6 Pages: 739-767 Published: NOV-DEC 2011

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The intrinsic charge on hydrophobic microfluidic substratesBy: Beattie, James K.

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Cell Adhesion on polytetrafluoroethylene modified by UV-irradiation in an ammonia atmosphereBy: Heitz, J; Svorcik, V; Bacakova, L; et al.

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OCT 1 2003

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Cell Adhesion and Proliferation on Plasma-Treated and Poly(ethylene glycol)-Grafted PolyethyleneBy: Kasalkova, N.; Makajova, Z.; Parizek, M.; et al.

JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY Volume: 24 Issue: 4 Pages: 743-754 Published: 2010

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Cell adhesion and proliferation on polyethylene grafted with Au nanoparticlesBy: Kasalkova, N. Slepickova; Slepicka, P.; Kolska, Z.; et al.

Conference: 17th International Conference on Ion Beam Modification of Materials (IBMM) Location: Montreal, CANADA

Date: AUG 22-27, 2010

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MATERIALS AND ATOMS Volume: 272 Pages: 391-395 Published: FEB 1 2012

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Zeta potential of microfluidic substrates: 1. Theory, experimental techniques, and effects on

separationsBy: Kirby, BJ; Hasselbrink, EF

ELECTROPHORESIS Volume: 25 Issue: 2 Pages: 187-202 Published: JAN 2004

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E-Polymers Volume: 83 Pages: 1-13 Published: 2012

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Nano-structuring of PTFE surface by plasma treatment, etching, and sputtering with goldBy: Reznickova, Alena; Kolska, Zdenka; Hnatowicz, Vladimir; et al.

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Comparison of glow argon plasma-induced surface changes of thermoplastic polymersBy: Reznickova, A.; Kolska, Z.; Hnatowicz, V.; et al.

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Properties of gold nanostructures sputtered on glassBy: Siegel, Jakub; Lyutakov, Olexiy; Rybka, Vladimir; et al.

NANOSCALE RESEARCH LETTERS Volume: 6 Article Number: 96 Published: 2011

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Relationship of Surface Hydrophilicity, Charge, and Roughness of PET Foils Stimulated by Incipient

Alkaline HydrolysisBy: Skvarla, Jiri; Luxbacher, Thomas; Nagy, Martin; et al.

ACS APPLIED MATERIALS & INTERFACES Volume: 2 Issue: 7 Pages: 2116-2127 Published: JUL 2010

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Properties of Au nanolayers on polyethyleneterephthalate and polytetrafluoroethyleneBy: Slepicka, P.; Kolska, Z.; Nahlik, J.; et al.

SURFACE AND INTERFACE ANALYSIS Volume: 41 Issue: 9 Pages: 741-745 Published: AUG 2009

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e-Polymers Volume: 133 Pages: 1-6 Published: 2010

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Plasma-Modified and Polyethylene Glycol-Grafted Polymers for Potential Tissue Engineering

ApplicationsBy: Svorcik, V.; Makajova, Z.; Kasalkova-Slepickova, N.; et al.

Conference: 3rd International Conference on Advanced Nano Materials (ANM) Location: Agadir, MOROCCO Date: SEP

12-15, 2010

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Properties of Au nanolayer sputtered on polyethyleneterephthalateBy: Svorcik, V.; Kolska, Z.; Luxbacher, T.; et al.

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Modification of surface properties of high and low density polyethylene by Ar plasma dischargeBy: Svorcik, V; Kolarova, K; Slepicka, P; et al.

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Relationship of Surface Hydrophilicity, Charge, and Roughness

of PET Foils Stimulated by Incipient Alkaline Hydrolysis

By: Skvarla, J (Skvarla, Jiri)[ 1 ] ; Luxbacher, T (Luxbacher, Thomas); Nagy, M (Nagy, Martin)[ 1 ] ; Sisol,

M (Sisol, Martin)[ 1 ]

ACS APPLIED MATERIALS & INTERFACES

Volume: 2 Issue: 7 Pages: 2116-2127

DOI: 10.1021/am100368v

Published: JUL 2010

View Journal Information

Abstract

An enhancement of wettability of PET foils pretreated hydrolytically by immersing in mild alkaline (NaOH)

solutions has been documented by a descending sigmoidal dependence between the interfacial free

energy gamma(SL) of the PET/water interface and the concentration of NaOH solution c(NaOH). An

increase in temperature of the NaOH solution below the glass-transition temperature of PET further

promotes the hydrophilicity, resulting in a proportional shift of the gamma(SL) VS c(NaOH) dependence.

The limiting hydrophilicity of PET is thermodynamically predicted to occur at gamma(SL) -> 0,

corresponding to the advancing water contact angle theta(a) approximate to 50 degrees (for 6% NaOH

and 60 degrees C). The surface roughness due to the partial hydrolytic degradation as well as the weight

loss (dissolution) of PET are found to reach a maximum value just when the latter dependence goes

through its inflection. Assuming a general parallelism between the interfacial free energy and the

dissolution kinetics, we propose the hydrolytically stimulated formation and growth of pits on the PET

surface to cause the initial acceleration as well as subsequent retardation of dissolution as c(NaOH),

increases, leading to the S-shaped gamma(SL) VS c(NaOH) dependence with the inflection for a specific

c(NaOH). Moreover, the zeta potential measured by the streaming current method also attains a

maximum at the same specific concentration of NaOH. It would indicate that the largest amount of

electric charges is populated via polar carboxyl and hydroxyl groups created by chemical scissions of

PET polymer chains when a change in the dissolution rate increases to the utmost. In such a way, partial

hydrolysis restricted to the uppermost part of moderately hydrophobic surface of solid PET allowed us to

better understand the intermingled role of thermodynamic and physical aspects in surface wettability

itself:

Keywords

Author Keywords: PET; hydrolysis; wettability; surface roughness; interfacial free energy; contact

angle; alkaline degradation; dissolution

KeyWords Plus: SPUN POLY(ETHYLENE-TEREPHTHALATE) FIBERS; MOISTURE-RELATED

PROPERTIES; FROTH FLOTATION; POLYVINYL-CHLORIDE; POLYMER SURFACES; CONTACT

ANGLES; FREE-ENERGY; ELECTROKINETIC MEASUREMENTS; PVC/PET MIXTURES; FTIR-ATR

Author Information

Reprint Address: Skvarla, J (reprint author)

Tech Univ Kosice, Inst Montaneous Sci & Environm Protect, Ctr Primary & Secondary Raw Mat

Proc, Pk Komenskeho 19, Kosice 04384, Slovakia.

Addresses:

[ 1 ] Tech Univ Kosice, Inst Montaneous Sci & Environm Protect, Ctr Primary & Secondary Raw

Mat Proc, Kosice 04384, Slovakia

E-mail Addresses: [email protected]

Funding

Funding Agency Grant Number

Scientific Grant Agency of the Slovak Republic (VEGA) 2/0159/08

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Peng, Boyu. Flexible organictransistors on standard printing paperand memory properties induced byfloated gate electrode. ORGANICELECTRONICS, JAN 2014.

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Slovak Research and Development Agency APVV-0598-07

View funding text

Publisher

AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA

Categories / Classification

Research Areas: Science & Technology - Other Topics; Materials Science

Web of Science Categories: Nanoscience & Nanotechnology; Materials Science, Multidisciplinary

Document Information

Document Type: Article

Language: English

Accession Number: WOS:000280367000048

ISSN: 1944-8244

Journal Information

Table of Contents: Current Contents Connect ®

Impact Factor: Journal Citation Reports ®

Other Information

IDS Number: 631SB

Cited References in Web of Science Core Collection: 74

Times Cited in Web of Science Core Collection: 4

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Impinging jet study of the deposition of colloidal particles on

modified polycarbonate and poly(ethylene terephthalate)

surfaces

By: Lapcik, L (Lapcik, Lubomir, Jr.)[ 1 ] ; Frastik, M (Frastik, Michal)[ 1 ] ; Lapcikova, B (Lapcikova,

Barbora)[ 1 ]

INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER

Volume: 55 Issue: 5-6 Pages: 1513-1518

DOI: 10.1016/j.ijheatmasstransfer.2011.11.002

Published: FEB 2012

View Journal Information

Abstract

Main focus of this study was on characterization of surface properties of virgin and 1,2-dipalmitoyl-

sn-glycero-3-phosphocholine (DPPC) phospholipid layer coated poly(ethylene terephthalate) (PET) and

polycarbonate (PC) planar articles. Surface properties were followed measuring static contact angles of

wetting by means of sessile drop method and deposition of negative polystyrene (PS) colloidal particles

followed by impinging jet method at defined flow regimes. It was found that phospholipid coating of both

studied samples (PET, PC) let to the vigorous increase of the surface free energy. For coated samples

major part of the surface free energy was dominated by polar component in contrast to the non-treated

materials. Here the dispersive component was dominating. Results of the deposition experiments of

polystyrene particles of 3 mu m diameter correspond with trends obtained by contact angle

measurements, i.e. the surface treated materials exhibited higher surface activity reflected in increased

particle deposition rates. Simultaneously there was confirmed the fact, that with increasing magnitude of

the Reynolds number of the dispersion flux the higher deposition rates were observed. (C) 2011 Elsevier

Ltd. All rights reserved.

Keywords

Author Keywords: Contact angles of wetting; Impinging jet; Poly(ethylene terephthalate);

Polycarbonate; Phospholipid layer; Polystyrene particles; Deposition kinetics

KeyWords Plus: HYALURONIC-ACID; SOLID-SURFACES; KINETICS; ADSORPTION; WALL

Author Information

Reprint Address: Lapcik, L (reprint author)

Tomas Bata Univ Zlin, Fac Technol, Ctr Polymer Syst, Nam TG Masaryka 5555, Zlin 76005, Czech

Republic.

Addresses:

[ 1 ] Tomas Bata Univ Zlin, Fac Technol, Ctr Polymer Syst, Zlin 76005, Czech Republic

E-mail Addresses: [email protected]

Author Identifiers:

Funding

Funding Agency Grant Number

Operational Program Research and Development for Innovations

European Regional Development Fund (ERDF)

national budget of Czech Republic CZ.1.05/2.1.00/03.0111

View funding text

Publisher

PERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON,

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1 Times Cited

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Most Recent Citation

Vlcek, Jakub. Impinging jet study of thedeposition of colloidal particles onsynthetic polymer (Zeonor).INTERNATIONAL JOURNAL OFHEAT AND MASS TRANSFER, NOV2014.

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OXFORD OX5 1GB, ENGLAND

Categories / Classification

Research Areas: Thermodynamics; Engineering; Mechanics

Web of Science Categories: Thermodynamics; Engineering, Mechanical; Mechanics

Document Information

Document Type: Article

Language: English

Accession Number: WOS:000300333700009

ISSN: 0017-9310

Journal Information

Table of Contents: Current Contents Connect ®

Impact Factor: Journal Citation Reports ®

Other Information

IDS Number: 893CR

Cited References in Web of Science Core Collection: 26

Times Cited in Web of Science Core Collection: 1

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Cited References: 26(from Web of Science Core Collection)

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COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS Volume: 165 Issue: 1-3 Pages:

157-187 Published: MAY 30 2000

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Times Cited: 25

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Kinetics of particle deposition in the radial impinging-jet cellBy: Adamczyk, Z; Siwek, B; Warszynski, P; et al.

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Wettability and topography of phospholipid DPPC multilayers deposited by spin-coating on glass,

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CARBONATE PARTICLESBy: KAMITI, M; VANDEVEN, TGM

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Relationship of Surface Hydrophilicity, Charge, and Roughness of PET Foils Stimulated by Incipient

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Relationship of Surface Hydrophilicity, Charge, and Roughness

of PET Foils Stimulated by Incipient Alkaline Hydrolysis

By: Skvarla, J (Skvarla, Jiri)[ 1 ] ; Luxbacher, T (Luxbacher, Thomas); Nagy, M (Nagy, Martin)[ 1 ] ; Sisol,

M (Sisol, Martin)[ 1 ]

ACS APPLIED MATERIALS & INTERFACES

Volume: 2 Issue: 7 Pages: 2116-2127

DOI: 10.1021/am100368v

Published: JUL 2010

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Abstract

An enhancement of wettability of PET foils pretreated hydrolytically by immersing in mild alkaline (NaOH)

solutions has been documented by a descending sigmoidal dependence between the interfacial free

energy gamma(SL) of the PET/water interface and the concentration of NaOH solution c(NaOH). An

increase in temperature of the NaOH solution below the glass-transition temperature of PET further

promotes the hydrophilicity, resulting in a proportional shift of the gamma(SL) VS c(NaOH) dependence.

The limiting hydrophilicity of PET is thermodynamically predicted to occur at gamma(SL) -> 0,

corresponding to the advancing water contact angle theta(a) approximate to 50 degrees (for 6% NaOH

and 60 degrees C). The surface roughness due to the partial hydrolytic degradation as well as the weight

loss (dissolution) of PET are found to reach a maximum value just when the latter dependence goes

through its inflection. Assuming a general parallelism between the interfacial free energy and the

dissolution kinetics, we propose the hydrolytically stimulated formation and growth of pits on the PET

surface to cause the initial acceleration as well as subsequent retardation of dissolution as c(NaOH),

increases, leading to the S-shaped gamma(SL) VS c(NaOH) dependence with the inflection for a specific

c(NaOH). Moreover, the zeta potential measured by the streaming current method also attains a

maximum at the same specific concentration of NaOH. It would indicate that the largest amount of

electric charges is populated via polar carboxyl and hydroxyl groups created by chemical scissions of

PET polymer chains when a change in the dissolution rate increases to the utmost. In such a way, partial

hydrolysis restricted to the uppermost part of moderately hydrophobic surface of solid PET allowed us to

better understand the intermingled role of thermodynamic and physical aspects in surface wettability

itself:

Keywords

Author Keywords: PET; hydrolysis; wettability; surface roughness; interfacial free energy; contact

angle; alkaline degradation; dissolution

KeyWords Plus: SPUN POLY(ETHYLENE-TEREPHTHALATE) FIBERS; MOISTURE-RELATED

PROPERTIES; FROTH FLOTATION; POLYVINYL-CHLORIDE; POLYMER SURFACES; CONTACT

ANGLES; FREE-ENERGY; ELECTROKINETIC MEASUREMENTS; PVC/PET MIXTURES; FTIR-ATR

Author Information

Reprint Address: Skvarla, J (reprint author)

Tech Univ Kosice, Inst Montaneous Sci & Environm Protect, Ctr Primary & Secondary Raw Mat

Proc, Pk Komenskeho 19, Kosice 04384, Slovakia.

Addresses:

[ 1 ] Tech Univ Kosice, Inst Montaneous Sci & Environm Protect, Ctr Primary & Secondary Raw

Mat Proc, Kosice 04384, Slovakia

E-mail Addresses: [email protected]

Funding

Funding Agency Grant Number

Scientific Grant Agency of the Slovak Republic (VEGA) 2/0159/08

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4 Times Cited

74 Cited References

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4 in All Databases

4 in Web of Science Core Collection

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Slovak Research and Development Agency APVV-0598-07

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Publisher

AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA

Categories / Classification

Research Areas: Science & Technology - Other Topics; Materials Science

Web of Science Categories: Nanoscience & Nanotechnology; Materials Science, Multidisciplinary

Document Information

Document Type: Article

Language: English

Accession Number: WOS:000280367000048

ISSN: 1944-8244

Journal Information

Table of Contents: Current Contents Connect ®

Impact Factor: Journal Citation Reports ®

Other Information

IDS Number: 631SB

Cited References in Web of Science Core Collection: 74

Times Cited in Web of Science Core Collection: 4

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