Table A.2 Values of t

R = 8.314 8.314

83.14 8,314

82.06 62,356

1.987 1.986

0.7302 10.73

1,545

Perubahan Suhu300 C 572 F

Perubahan tekanan30 bar 3000000 Pa 3000 kPa

435.114 psia

J mol-1 K-1 m3 Pa mol-1 K-1

cm3 bar mol-1 K-1 cm3 kPa mol-1 K-1

cm3 (atm) mol-1 K-1 cm3 (torr) mol-1 K-1

cal mol-1 K-1 (Btu) (lbmol)-1 (R)-1

(ft)3 (atm) (lbmol)-1 (R)-1 (ft)3 (psia) (lbmol)-1 (R)-1

(ft) (lbf) (lbmol)-1 (R)-1

MW ω Tc (K) Pc (bar) Zcmethane 16.043 0.012 190.6 45.99 0.289ethane 30.07 0.1 305.3 48.72 0.279propane 44.097 0.152 369.8 42.48 0.276n-butane 58.123 0.2 425.1 37.96 0.274n-Pentane 72.15 0.252 469.7 33.7 0.27n-Hexane 86.177 0.301 507.6 30.25 0.266n-Heptane 100.204 0.35 540.2 27.4 0.261n-Octane 114.231 0.4 568.7 24.9 0.256n-Nonane 128.258 0.444 594.6 22.9 0.252n-Decane 142.285 0.492 617.7 21.1 0.247Isobutane 58.123 0.181 408.1 36.48 0.282Isooctane 114.231 0.302 544 25.68 0.266Cyclopentane 70.134 0.196 511.8 45.02 0.273Cyclohexane 84.161 0.21 553.6 40.73 0.273Methylcyclopentane 84.161 0.23 532.8 37.85 0.272Methylcyclohexane 98.188 0.235 572.2 34.71 0.269Ethylene 28.054 0.087 282.3 50.4 0.281Propylene 42.081 0.14 365.6 46.65 0.2891-Butene 56.108 0.191 420 40.43 0.277cis-2-Butene 56.108 0.205 435.6 42.43 0.273trans-2-Butene 56.108 0.218 428.6 41 0.2751 -Hexene 84.161 0.28 504 31.4 0.265Isobutylene 56.108 0.194 417.9 40 0.2751,3-Butadiene 54.092 0.19 425.2 42.77 0.267Cyclohexene 82.145 0.212 560.4 43.5 0.272Acetylene 26.038 0.187 308.3 61.39 0.271Benzene 78.114 0.21 562.2 48.98 0.271Toluene 92.141 0.262 591.8 41.06 0.264Ethylbenzene 106.167 0.303 617.2 36.06 0.263Cumene 120.194 0.326 631.1 32.09 0.261o-Xylene 106.167 0.31 630.3 37.34 0.263m-Xylene 106.167 0.326 617.1 35.36 0.259p-Xylene 106.167 0.322 616.2 35.11 0.26Styrene 104.152 0.297 636 38.4 0.256Naphthalene 128.174 0.302 748.4 40.51 0.269Biphenyl 154.211 0.365 789.3 38.5 0.295Formaldehyde 30.026 0.282 408 65.9 0.223Acetaldehyde 44.053 0.291 466 55.5 0.221Methyl acetate 74.079 0.331 506.6 47.5 0.257Ethyl acetate 88.106 0.366 523.3 38.8 0.255Acetone 58.08 0.307 508.2 47.01 0.233Methyl ethyl ketone 72.107 0.323 535.5 41.5 0.249Diethyl ether 74.123 0.281 466.7 36.4 0.263Methyl t-butyl ether 88.15 0.266 497.1 34.3 0.273Methanol 32.042 0.564 512.6 80.97 0.224Ethanol 46.069 0.645 513.9 61.48 0.241 -Propanol 60.096 0.622 536.8 51.75 0.254

1-Butanol 74.123 0.594 563.1 44.23 0.261 -Hexanol 102.177 0.579 611.4 35.1 0.2632-Propanol 60.096 0.668 508.3 47.62 0.248Phenol 94.113 0.444 694.3 61.3 0.243Ethylene glycol 62.068 0.487 719.7 77 0.246Acetic acid 60.053 0.467 592 57.86 0.211n-Butyric acid 88.106 0.681 615.7 40.64 0.232Benzoic acid 122.123 0.603 751 44.7 0.246Acetonitrile 41.053 0.338 545.5 48.3 0.184Methylamine 31.057 0.281 430.1 74.6 0.321Ethylamine 45.084 0.285 456.2 56.2 0.307Nitromethane 61.04 0.348 588.2 63.1 0.223Carbon tetrachloride 153.822 0.193 556.4 45.6 0.272Chloroform 119.377 0.222 536.4 54.72 0.293Dichloromethane 84.932 0.199 510 60.8 0.265Methyl chloride 50.488 0.153 416.3 66.8 0.276Ethyl chloride 64.514 0.19 460.4 52.7 0.275Chlorobenzene 112.558 0.25 632.4 45.2 0.265Tetrafluoroethane 102.03 0.327 374.2 40.6 0.258Argon 39.948 0 150.9 48.98 0.291Krypton 83.8 0 209.4 55.02 0.288Xenon 131.3 0 289.7 58.4 0.286Helium 4 4.003 -0.39 5.2 2.28 0.302Hydrogen 2.016 -0.216 33.19 13.13 0.305Oxygen 31.999 0.022 154.6 50.43 0.288Nitrogen 28.014 0.038 126.2 34 0.289Air+ 28.851 0.035 132.2 37.45 0.289Chlorine 70.905 0.069 417.2 77.1 0.265Carbon monoxide 28.01 0.048 132.9 34.99 0.299Carbon dioxide 44.01 0.224 304.2 73.83 0.274Carbon disulfide 76.143 0.111 552 79 0.275Hydrogen sulfide 34.082 0.094 373.5 89.63 0.284Sulfur dioxide 64.065 0.245 430.8 78.84 0.269Sulfur trioxide 80.064 0.424 490.9 82.1 0.255Nitric oxide (NO) 30.006 0.583 180.2 64.8 0.251Nitrous oxide (NzO) 44.013 0.141 309.6 72.45 0.274Hydrogen chloride 36.461 0.132 324.7 83.1 0.249Hydrogen cyanide 27.026 0.41 456.7 53.9 0.197Water 18.015 0.345 647.1 220.55 0.229Ammonia 17.031 0.253 405.7 112.8 0.242Nitric acid 63.013 0.714 520 68.9 0.231Sulfuric acid 98.08 924 64 0.147

Vc (cm3/mol) Tn (K)98.6 111.4

145.5 184.6200 231.1255 272.7313 309.2371 341.9428 371.6486 398.8544 424600 447.3

262.7 261.4468 372.4258 322.4308 353.9319 345368 374.1131 169.4

188.4 225.5239.3 266.9233.8 276.9237.7 274

354 336.3238.9 266.3220.4 268.7

291 356.1113 189.4259 353.2316 383.8374 409.4427 425.6369 417.6376 412.3379 411.5352 418.3413 491.2502 528.2115 254.1154 294228 330.1286 350.2209 329.4267 352.8280 307.6329 328.4118 337.9167 351.4219 370.4

275 390.8381 430.6220 355.4229 455191 470.5

179.7 391.1291.7 436.4

344 522.4173 354.8154 266.8207 289.7173 374.4276 349.8239 334.3185 312.9143 249.1200 285.4308 404.9198 247.1

74.6 87.391.2 119.8118 165

57.3 4.264.1 20.473.4 90.289.2 77.384.8124 239.1

93.4 81.794

160 319.498.5 212.8122 263.1127 317.9

58 121.497.4 184.7

81 188.2139 298.9

55.9 373.272.5 239.7145 356.2177 610

Name Formula A B CAcetone C3H6O 14.3145 2756.22 228.060Acetic acid C2H402 15.0717 3580.80 224.650Acetonitrile* C2H3N 14.8950 3413.10 250.523Benzene C6H6 13.7819 2726.81 217.572iso-Butane C4HIO 13.8254 2181.79 248.870n-Butane C4HI0 13.6608 2154.70 238.789I-Butanol C4H100 15.3144 3212.43 182.7392-Butanol* C4HI0O 15.1989 3026.03 186.500iso-Butanol C4HIOO 14.6047 2740.95 166.670tert-Butanol C4HIOO 14.8445 2658.29 177.650Carbon tetrachloride CC14 14.0572 2914.23 232.148Chlorobenzene C6H5C1 13.8635 3174.78 211.7001 -Chlorobutane C4H9CI- 13.7965 2723.73 218.265Chloroform CHC13 13.7324 2548.74 218.552Cyclohexane C6H12 13.6568 2723.44 220.618Cyclopentane C5HIO 13.9727 2653.90 234.510n-Decane ClOH22 13.9748 3442.76 193.858Dichloromethane CH202 13.9891 2463.93 223.240Diethyl ether C41-1100 14.0735 2511.29 231.2001,4-Dioxane C4Hg02 15.0967 3579.78 240.337n-Eicosane C20H42 14.4575 4680.46 132.100Ethanol C2HrO 16.8958 3795.17 230.918Ethylbenzene CSHIO 13.9726 3259.93 212.300Ethylene glycol* C211602 15.7567 4187.46 178.650n-Heptane C7HI6 13.8622 2910.26 216.432n-Hexane C6H14 13.8193 2696.04 224.317Methanol CH40 16.5785 3638.27 239.500Methyl acetate C3H602 14.2456 2662.78 219.690Methyl ethyl ketone C4HgO 14.1334 2838.24 218.690Nitromethane* CH3NO2 14.7513 3331.70 227.600n-Nonane CgH20 13.9854 3311.19 202.694iso-Octane C8HI8 13.6703 2896.31 220.767n-Octane C81118 13.9346 3123.13 209.635n-Pentane C5H12 13.7667 2451.88 232.014Phenol C6H60 14.4387 3507.80 175.400I-Propanol C3HgO 16.1154 3483.67 205.8072-Propanol C3H8O 16.6796 3640.20 219.610Toluene C7H8 13.9320 3056.96 217.625Water H20 16.3872 3885.70 230.170o-Xylene C8H10 14.0415 3358.79 212.041m-Xylene C8HIO 14.1387 3381.81 216.120p-Xylene C8HIO 14.0579 3331.45 214.627

A B Cpropan C3H8 13.7097 1872.82 -25.1011

Hn (KJ/mol) Tn (C)-26-77 29.10 56.224-142 23.70 117.9-27-81 30.19 81.66-104 30.72 80.0-83-7 21.30 -11.9-73-19 22.44 -0.537-138 43.29 117.625-120 40.75 99.530-128 41.82 107.810-101 39.07 82.3-14-101 29.82 76.629--159 35.19 131.7-17-79 30.39 78.5-23-84 29.24 61.19-105 29.97 80.7-35-71 27.30 49.265-203 38.75 174.1-38-60 28.06 39.7-43-55 26.52 34.420-105 34.16 101.3208-379 57.49 343.63-96 38.56 78.233-163 35.57 136.2100-222 50.73 197.34-123 31.77 98.4-19-92 28.85 68.7-11-83 35.21 64.7-23-78 30.32 56.9-8 - 103 31.30 79.656-146 33.99 101.246-178 36.91 150.82-125 30.79 99.226-152 34.41 125.6-45-58 25.79 36.080-208 46.18 181.820 -116 41.44 97.28-100 39.85 82.213-136 33.18 110.60-200 40.66 100.040-172 36.24 144.435-166 35.66 139.135-166 35.67 138.3

0C

panas penguapan Tn(K) Tc(K) ω Pc(bar) Cp/R18773.1 231.1 369.8 0.152 42.48 9.011

kPa

K

NO komponen ω Tc,K Pc,Bar Zcpropane 44.097 0.152 369.8 42.48 0.276 200

R 8.314 J/mol K

Data SenyawaKondisi 1 Kondisi 2

60 C 333.15 K T2

18 bar 1800 kPa P2

0.900892374256 Tr2

0.423728813559 Pr2

-0.415695895414 -0.12762583

0.885429943344 1.242333114

-0.594445672375

-1827.633444181

-4495.04724

-3418.528863 J/mol-77.52293495 kJ/kg

BM (gr/mol) Vc,(cm3/mol)

T1

P1

Tr1

Pr1

Bo B1 Bo

dBo/dTr dB1/dTr dBo/dTr

HR/RTc HR/RTc

HR HR

Hig

Htotal

komponen BM ω Tc,K Pc,Bar Zc Tn (K)methane 16.043 0.012 190.6 45.99 0.289 98.6 111.4ethane 30.07 0.1 305.3 48.72 0.279 145.5 184.6propane 44.097 0.152 369.8 42.48 0.276 200 231.1n-butane 58.123 0.2 425.1 37.96 0.274 255 272.7n-Pentane 72.15 0.252 469.7 33.7 0.27 313 309.2n-Hexane 86.177 0.301 507.6 30.25 0.266 371 341.9n-Heptane 100.204 0.35 540.2 27.4 0.261 428 371.6n-Octane 114.231 0.4 568.7 24.9 0.256 486 398.8n-Nonane 128.258 0.444 594.6 22.9 0.252 544 424n-Decane 142.285 0.492 617.7 21.1 0.247 600 447.3Isobutane 58.123 0.181 408.1 36.48 0.282 262.7 261.4Isooctane 114.231 0.302 544 25.68 0.266 468 372.4Cyclopent 70.134 0.196 511.8 45.02 0.273 258 322.4Cyclohexa 84.161 0.21 553.6 40.73 0.273 308 353.9Methylcyc 84.161 0.23 532.8 37.85 0.272 319 345Methylcyc 98.188 0.235 572.2 34.71 0.269 368 374.1Ethylene 28.054 0.087 282.3 50.4 0.281 131 169.4Propylene 42.081 0.14 365.6 46.65 0.289 188.4 225.51-Butene 56.108 0.191 420 40.43 0.277 239.3 266.9cis-2-Bute 56.108 0.205 435.6 42.43 0.273 233.8 276.9trans-2-Bu 56.108 0.218 428.6 41 0.275 237.7 2741 -Hexene 84.161 0.28 504 31.4 0.265 354 336.3Isobutylen 56.108 0.194 417.9 40 0.275 238.9 266.31,3-Butadi 54.092 0.19 425.2 42.77 0.267 220.4 268.7Cyclohexe 82.145 0.212 560.4 43.5 0.272 291 356.1Acetylene 26.038 0.187 308.3 61.39 0.271 113 189.4Benzene 78.114 0.21 562.2 48.98 0.271 259 353.2Toluene 92.141 0.262 591.8 41.06 0.264 316 383.8Ethylbenz 106.167 0.303 617.2 36.06 0.263 374 409.4Cumene 120.194 0.326 631.1 32.09 0.261 427 425.6o-Xylene 106.167 0.31 630.3 37.34 0.263 369 417.6

Vc,(cm3/mol)

m-Xylene 106.167 0.326 617.1 35.36 0.259 376 412.3p-Xylene 106.167 0.322 616.2 35.11 0.26 379 411.5Styrene 104.152 0.297 636 38.4 0.256 352 418.3Naphthale 128.174 0.302 748.4 40.51 0.269 413 491.2Biphenyl 154.211 0.365 789.3 38.5 0.295 502 528.2Formaldeh 30.026 0.282 408 65.9 0.223 115 254.1Acetaldeh 44.053 0.291 466 55.5 0.221 154 294Methyl ace 74.079 0.331 506.6 47.5 0.257 228 330.1Ethyl acet 88.106 0.366 523.3 38.8 0.255 286 350.2Acetone 58.08 0.307 508.2 47.01 0.233 209 329.4Methyl eth 72.107 0.323 535.5 41.5 0.249 267 352.8Diethyl et 74.123 0.281 466.7 36.4 0.263 280 307.6Methyl t-b 88.15 0.266 497.1 34.3 0.273 329 328.4Methanol 32.042 0.564 512.6 80.97 0.224 118 337.9Ethanol 46.069 0.645 513.9 61.48 0.24 167 351.41 -Propano 60.096 0.622 536.8 51.75 0.254 219 370.41-Butanol 74.123 0.594 563.1 44.23 0.26 275 390.81 -Hexanol 102.177 0.579 611.4 35.1 0.263 381 430.62-Propanol 60.096 0.668 508.3 47.62 0.248 220 355.4Phenol 94.113 0.444 694.3 61.3 0.243 229 455Ethylene g 62.068 0.487 719.7 77 0.246 191 470.5Acetic acid 60.053 0.467 592 57.86 0.211 179.7 391.1n-Butyric a 88.106 0.681 615.7 40.64 0.232 291.7 436.4Benzoic ac 122.123 0.603 751 44.7 0.246 344 522.4Acetonitril 41.053 0.338 545.5 48.3 0.184 173 354.8Methylami 31.057 0.281 430.1 74.6 0.321 154 266.8Ethylamin 45.084 0.285 456.2 56.2 0.307 207 289.7Nitrometh 61.04 0.348 588.2 63.1 0.223 173 374.4Carbon tet 153.822 0.193 556.4 45.6 0.272 276 349.8Chlorofor 119.377 0.222 536.4 54.72 0.293 239 334.3Dichlorom 84.932 0.199 510 60.8 0.265 185 312.9Methyl chl 50.488 0.153 416.3 66.8 0.276 143 249.1Ethyl chlor 64.514 0.19 460.4 52.7 0.275 200 285.4Chloroben 112.558 0.25 632.4 45.2 0.265 308 404.9Tetrafluor 102.03 0.327 374.2 40.6 0.258 198 247.1Argon 39.948 0 150.9 48.98 0.291 74.6 87.3Krypton 83.8 0 209.4 55.02 0.288 91.2 119.8Xenon 131.3 0 289.7 58.4 0.286 118 165Helium 4 4.003 -0.39 5.2 2.28 0.302 57.3 4.2Hydrogen 2.016 -0.216 33.19 13.13 0.305 64.1 20.4Oxygen 31.999 0.022 154.6 50.43 0.288 73.4 90.2Nitrogen 28.014 0.038 126.2 34 0.289 89.2 77.3Air+ 28.851 0.035 132.2 37.45 0.289 84.8Chlorine 70.905 0.069 417.2 77.1 0.265 124 239.1Carbon mo 28.01 0.048 132.9 34.99 0.299 93.4 81.7Carbon dio 44.01 0.224 304.2 73.83 0.274 94Carbon dis 76.143 0.111 552 79 0.275 160 319.4Hydrogen s 34.082 0.094 373.5 89.63 0.284 98.5 212.8

Sulfur diox 64.065 0.245 430.8 78.84 0.269 122 263.1Sulfur trio 80.064 0.424 490.9 82.1 0.255 127 317.9Nitric oxid 30.006 0.583 180.2 64.8 0.251 58 121.4Nitrous ox 44.013 0.141 309.6 72.45 0.274 97.4 184.7Hydrogen c 36.461 0.132 324.7 83.1 0.249 81 188.2Hydrogen 27.026 0.41 456.7 53.9 0.197 139 298.9Water 18.015 0.345 647.1 220.55 0.229 55.9 373.2Ammonia 17.031 0.253 405.7 112.8 0.242 72.5 239.7Nitric acid 63.013 0.714 520 68.9 0.231 145 356.2Sulfuric ac 98.08 924 64 0.147 177 610

Tn (K)231.1 9.011

0 C 273.15 K

4.8 bar 480 kPa

0.738642509465

0.112994350282

-0.602200346824 -0.47491

1.483797373389 3.488822

-0.244303420024

-751.1150668838

Cpig298/R

(Ideal gas)

B1

dB1/dTr

4.2176.3699.011

11.92814.731

17.5520.36123.174

11.901

10.52

16.24

10.25912.92215.993

Cpig298/R (Ideal gas)

4.1916.506

5.5478.948

3.4683.5353.5023.5094.0823.5074.4675.5324.114

4.7966.094

3.594.6463.512

4.3266

4.269

NO komponen ω Tc,K Pc,Bar Zcpropane 44.097 0.152 369.8 42.48 0.276

R 8.314 J/mol K

Data SenyawaKondisi 1

60 C 333.15 K

18 bar 1800 kPa

0.900892374256

0.423728813559

Parameter Van der waals RKα(Tr) 1 1.05357

σ 0 1ε 0 0Ω 0.125 0.08664ψ 0.421875 0.4278Zc 0.375 0.333333β 0.058792929331 0.040751

q 3.746285457001 5.774481

Z 0.805235340665 0.763914

0 -0.5I 0.073013349467 0.053344

BM (gr/mol)

T1

P1

Tr1

Pr1

d lnα(Tr)/d ln Tr

-0.468293508611 -0.698141

-1297.083621622 -1933.717

-4495.04724

Van der Waals

-3578.3046 J/mol-81.146215 kJ/kg

komponen BM ω Tc,K Pc,Bar Zcmethane 16.043 0.012 190.6 45.99 0.289 98.6ethane 30.07 0.1 305.3 48.72 0.279 145.5propane 44.097 0.152 369.8 42.48 0.276 200n-butane 58.123 0.2 425.1 37.96 0.274 255n-Pentane 72.15 0.252 469.7 33.7 0.27 313n-Hexane 86.177 0.301 507.6 30.25 0.266 371n-Heptane 100.204 0.35 540.2 27.4 0.261 428n-Octane 114.231 0.4 568.7 24.9 0.256 486n-Nonane 128.258 0.444 594.6 22.9 0.252 544n-Decane 142.285 0.492 617.7 21.1 0.247 600Isobutane 58.123 0.181 408.1 36.48 0.282 262.7Isooctane 114.231 0.302 544 25.68 0.266 468Cyclopentan 70.134 0.196 511.8 45.02 0.273 258Cyclohexane 84.161 0.21 553.6 40.73 0.273 308Methylcyclo 84.161 0.23 532.8 37.85 0.272 319Methylcyclo 98.188 0.235 572.2 34.71 0.269 368Ethylene 28.054 0.087 282.3 50.4 0.281 131Propylene 42.081 0.14 365.6 46.65 0.289 188.41-Butene 56.108 0.191 420 40.43 0.277 239.3cis-2-Butene 56.108 0.205 435.6 42.43 0.273 233.8trans-2-Bute 56.108 0.218 428.6 41 0.275 237.71 -Hexene 84.161 0.28 504 31.4 0.265 354Isobutylene 56.108 0.194 417.9 40 0.275 238.91,3-Butadien 54.092 0.19 425.2 42.77 0.267 220.4Cyclohexene 82.145 0.212 560.4 43.5 0.272 291Acetylene 26.038 0.187 308.3 61.39 0.271 113Benzene 78.114 0.21 562.2 48.98 0.271 259Toluene 92.141 0.262 591.8 41.06 0.264 316Ethylbenzene 106.167 0.303 617.2 36.06 0.263 374Cumene 120.194 0.326 631.1 32.09 0.261 427o-Xylene 106.167 0.31 630.3 37.34 0.263 369

HR/RT

HR

Hig

Htotal

Vc,(cm3/mol)

m-Xylene 106.167 0.326 617.1 35.36 0.259 376p-Xylene 106.167 0.322 616.2 35.11 0.26 379Styrene 104.152 0.297 636 38.4 0.256 352Naphthalene 128.174 0.302 748.4 40.51 0.269 413Biphenyl 154.211 0.365 789.3 38.5 0.295 502Formaldehyd 30.026 0.282 408 65.9 0.223 115Acetaldehyd 44.053 0.291 466 55.5 0.221 154Methyl aceta 74.079 0.331 506.6 47.5 0.257 228Ethyl acetate 88.106 0.366 523.3 38.8 0.255 286Acetone 58.08 0.307 508.2 47.01 0.233 209Methyl ethyl 72.107 0.323 535.5 41.5 0.249 267Diethyl ether 74.123 0.281 466.7 36.4 0.263 280Methyl t-buty 88.15 0.266 497.1 34.3 0.273 329Methanol 32.042 0.564 512.6 80.97 0.224 118Ethanol 46.069 0.645 513.9 61.48 0.24 1671 -Propanol 60.096 0.622 536.8 51.75 0.254 2191-Butanol 74.123 0.594 563.1 44.23 0.26 2751 -Hexanol 102.177 0.579 611.4 35.1 0.263 3812-Propanol 60.096 0.668 508.3 47.62 0.248 220Phenol 94.113 0.444 694.3 61.3 0.243 229Ethylene glyc 62.068 0.487 719.7 77 0.246 191Acetic acid 60.053 0.467 592 57.86 0.211 179.7n-Butyric aci 88.106 0.681 615.7 40.64 0.232 291.7Benzoic acid 122.123 0.603 751 44.7 0.246 344Acetonitrile 41.053 0.338 545.5 48.3 0.184 173Methylamine 31.057 0.281 430.1 74.6 0.321 154Ethylamine 45.084 0.285 456.2 56.2 0.307 207Nitromethan 61.04 0.348 588.2 63.1 0.223 173Carbon tetra 153.822 0.193 556.4 45.6 0.272 276Chloroform 119.377 0.222 536.4 54.72 0.293 239Dichloromet 84.932 0.199 510 60.8 0.265 185Methyl chlor 50.488 0.153 416.3 66.8 0.276 143Ethyl chlorid 64.514 0.19 460.4 52.7 0.275 200Chlorobenze 112.558 0.25 632.4 45.2 0.265 308Tetrafluoroe 102.03 0.327 374.2 40.6 0.258 198Argon 39.948 0 150.9 48.98 0.291 74.6Krypton 83.8 0 209.4 55.02 0.288 91.2Xenon 131.3 0 289.7 58.4 0.286 118Helium 4 4.003 -0.39 5.2 2.28 0.302 57.3Hydrogen 2.016 -0.216 33.19 13.13 0.305 64.1Oxygen 31.999 0.022 154.6 50.43 0.288 73.4Nitrogen 28.014 0.038 126.2 34 0.289 89.2Air+ 28.851 0.035 132.2 37.45 0.289 84.8Chlorine 70.905 0.069 417.2 77.1 0.265 124Carbon mono 28.01 0.048 132.9 34.99 0.299 93.4Carbon dioxi 44.01 0.224 304.2 73.83 0.274 94Carbon disulf 76.143 0.111 552 79 0.275 160Hydrogen sul 34.082 0.094 373.5 89.63 0.284 98.5

Sulfur dioxid 64.065 0.245 430.8 78.84 0.269 122Sulfur trioxid 80.064 0.424 490.9 82.1 0.255 127Nitric oxide 30.006 0.583 180.2 64.8 0.251 58Nitrous oxide 44.013 0.141 309.6 72.45 0.274 97.4Hydrogen chl 36.461 0.132 324.7 83.1 0.249 81Hydrogen cya 27.026 0.41 456.7 53.9 0.197 139Water 18.015 0.345 647.1 220.55 0.229 55.9Ammonia 17.031 0.253 405.7 112.8 0.242 72.5Nitric acid 63.013 0.714 520 68.9 0.231 145Sulfuric acid 98.08 924 64 0.147 177

Tn (K)200 231.1 9.011

Kondisi 1Van der WaalsZ (tebak)

10.85148727550.81798243920.80888029990.80628832480.80554042710.80532380770.80526099790.80524278010.80523749560.80523596260.8052355179

Kondisi 2 0.8052353889

T2 0 C 273.15 K 0.8052353515

P2 4.8 bar 480 kPa

Tr2 0.7386425095

Pr2 0.1129943503 Kondisi 2Van der Waals

Parameter Van der waals RK Z (tebak)α(Tr) 1 1.1635441 1

σ 0 1 0.9334207555ε 0 0 0.9274355106Ω 0.125 0.08664 0.9268562631ψ 0.421875 0.4278 0.9267998154Zc 0.375 0.3333333 0.9267943109β 0.0191219617 0.0132538 0.9267937741

q 4.5691927512 7.7780528 0.92679372170.92679371660.92679371610.92679371610.92679371610.92679371610.9267937161

Z 0.9267937161 0.9023119

0 -0.5I 0.0206323817 0.0146887

Vc,(cm3/mol)Cpig

298/R (Ideal gas)

d lnα(Tr)/d ln Tr

-0.1674796128 -0.269063

-380.34102564 -611.033

RK

-3172.3633979 J/mol-71.940571874 kJ/kg

Tn (K)111.4 4.217184.6 6.369231.1 9.011272.7 11.928309.2 14.731341.9 17.55371.6 20.361398.8 23.174

424447.3261.4 11.901372.4322.4353.9

345374.1169.4225.5266.9 10.52276.9

274336.3 16.24266.3268.7356.1189.4353.2 10.259383.8 12.922409.4 15.993425.6417.6

HR/RT

HR

Htotal

Cpig298/R (Ideal

gas)

412.3411.5418.3491.2528.2254.1 4.191

294 6.506330.1350.2329.4352.8307.6328.4337.9 5.547351.4 8.948370.4390.8430.6355.4

455470.5391.1436.4522.4354.8266.8289.7374.4349.8334.3312.9249.1285.4404.9247.1

87.3119.8

1654.2

20.4 3.46890.2 3.53577.3 3.502

3.509239.1 4.082

81.7 3.5074.467

319.4 5.532212.8 4.114

263.1 4.796317.9 6.094121.4 3.59184.7 4.646188.2 3.512298.9 4.3266373.2239.7 4.269356.2

610

RKZ (hitung) Galat Z (tebak) Z (hitung) Galat0.8514873 0.1485127 1 0.8238646 0.17613540.8179824 0.0393486 0.8238646 0.7820527 0.05075090.8088803 0.0111275 0.7820527 0.7696629 0.01584270.8062883 0.0032044 0.7696629 0.765762 0.00506830.8055404 0.0009276 0.765762 0.7645107 0.00163410.8053238 0.0002689 0.7645107 0.7641068 0.0005282

0.805261 7.799E-05 0.7641068 0.7639763 0.00017090.8052428 2.262E-05 0.7639763 0.763934 5.529E-050.8052375 6.563E-06 0.763934 0.7639204 1.789E-05

0.805236 1.904E-06 0.7639204 0.7639159 5.79E-060.8052355 5.522E-07 0.7639159 0.7639145 1.874E-060.8052354 1.602E-07 0.7639145 0.763914 6.064E-070.8052354 4.647E-08 0.763914 0.7639139 1.962E-07

0.8052353 1.348E-08 0.7639139 0.7639138 6.351E-08

RKZ (hitung) Galat Z (tebak) Z (hitung) Galat0.9334208 0.0665792 1 0.9128618 0.08713820.9274355 0.0064122 0.9128618 0.9035568 0.01019330.9268563 0.0006246 0.9035568 0.9024603 0.00121360.9267998 6.09E-05 0.9024603 0.9023296 0.00014480.9267943 5.939E-06 0.9023296 0.902314 1.728E-050.9267938 5.792E-07 0.902314 0.9023121 2.062E-060.9267937 5.649E-08 0.9023121 0.9023119 2.461E-07

0.9267937 5.509E-09 0.9023119 0.9023119 2.937E-080.9267937 5.372E-10 0.9023119 0.9023119 3.505E-090.9267937 5.239E-11 0.9023119 0.9023119 4.183E-100.9267937 5.109E-12 0.9023119 0.9023119 4.991E-110.9267937 4.982E-13 0.9023119 0.9023119 5.957E-120.9267937 4.864E-14 0.9023119 0.9023119 7.109E-130.9267937 4.672E-15 0.9023119 0.9023119 8.478E-14

NO Name Formula A B C Hn (KJ/mol)Ethanol C2HrO 16.8958 3795.17 230.918 3-96 38.56

Data Senyawa kondisiR 8.314 J/mol K

Mencari P Mencari T

T 11 284.15 K P 2 bar

1.207963625691 T 96.322843548

3.34666265099 kPa 369.47284355 K

0C

oC

ln Psat/kPa oC

Psat

T=(B/(A-LnP))-C

Tn (C)78.2

200 kPa

Name Formula A B C Hn (KJ/mol) Tn (C)Acetone C3H6O 14.3145 2756.22 228.060 -26-77 29.10 56.2Acetic acid C2H402 15.0717 3580.80 224.650 24-142 23.70 117.9Acetonitrile* C2H3N 14.8950 3413.10 250.523 -27-81 30.19 81.6Benzene C6H6 13.7819 2726.81 217.572 6-104 30.72 80.0iso-Butane C4HIO 13.8254 2181.79 248.870 -83-7 21.30 -11.9n-Butane C4HI0 13.6608 2154.70 238.789 -73-19 22.44 -0.5I-Butanol C4H100 15.3144 3212.43 182.739 37-138 43.29 117.6

2-Butanol* C4HI0O 15.1989 3026.03 186.500 25-120 40.75 99.5iso-Butanol C4HIOO 14.6047 2740.95 166.670 30-128 41.82 107.8tert-Butanol C4HIOO 14.8445 2658.29 177.650 10-101 39.07 82.3Carbon tetrachlorideCC14 14.0572 2914.23 232.148 -14-101 29.82 76.6Chlorobenzene C6H5C1 13.8635 3174.78 211.700 29--159 35.19 131.7

1 -Chlorobutane C4H9CI- 13.7965 2723.73 218.265 -17-79 30.39 78.5

Chloroform CHC13 13.7324 2548.74 218.552 -23-84 29.24 61.1Cyclohexane C6H12 13.6568 2723.44 220.618 9-105 29.97 80.7Cyclopentane C5HIO 13.9727 2653.90 234.510 -35-71 27.30 49.2n-Decane ClOH22 13.9748 3442.76 193.858 65-203 38.75 174.1Dichloromethane CH202 13.9891 2463.93 223.240 -38-60 28.06 39.7Diethyl ether C41-1100 14.0735 2511.29 231.200 -43-55 26.52 34.41,4-Dioxane C4Hg02 15.0967 3579.78 240.337 20-105 34.16 101.3

n-Eicosane C20H42 14.4575 4680.46 132.100 208-379 57.49 343.6Ethanol C2HrO 16.8958 3795.17 230.918 3-96 38.56 78.2Ethylbenzene CSHIO 13.9726 3259.93 212.300 33-163 35.57 136.2Ethylene glycol* C211602 15.7567 4187.46 178.650 100-222 50.73 197.3n-Heptane C7HI6 13.8622 2910.26 216.432 4-123 31.77 98.4n-Hexane C6H14 13.8193 2696.04 224.317 -19-92 28.85 68.7Methanol CH40 16.5785 3638.27 239.500 -11-83 35.21 64.7Methyl acetate C3H602 14.2456 2662.78 219.690 -23-78 30.32 56.9Methyl ethyl ketone C4HgO 14.1334 2838.24 218.690 -8 - 103 31.30 79.6Nitromethane* CH3NO2 14.7513 3331.70 227.600 56-146 33.99 101.2n-Nonane CgH20 13.9854 3311.19 202.694 46-178 36.91 150.8iso-Octane C8HI8 13.6703 2896.31 220.767 2-125 30.79 99.2n-Octane C81118 13.9346 3123.13 209.635 26-152 34.41 125.6n-Pentane C5H12 13.7667 2451.88 232.014 -45-58 25.79 36.0Phenol C6H60 14.4387 3507.80 175.400 80-208 46.18 181.8I-Propanol C3HgO 16.1154 3483.67 205.807 20 -116 41.44 97.22-Propanol C3H8O 16.6796 3640.20 219.610 8-100 39.85 82.2Toluene C7H8 13.9320 3056.96 217.625 13-136 33.18 110.6Water H20 16.3872 3885.70 230.170 0-200 40.66 100.0o-Xylene C8H10 14.0415 3358.79 212.041 40-172 36.24 144.4m-Xylene C8HIO 14.1387 3381.81 216.120 35-166 35.66 139.1p-Xylene C8HIO 14.0579 3331.45 214.627 35-166 35.67 138.3

0C

Antoine Ln(Psat)=A-(B/(T+C)) dataT=(B/(A-LnP))-C Tc 647.1 K 22080.6 J/mol

Tn 373.2 KAir Pc 220.55 barA 16.532B 3985.44C -38.994P 20 bar LnP 7.600902

2000 kPaT 485.237λ2 0.818825

Tsuper 350 C 623.15 KQ

λtn

Tr1 0.576727Tr2 0.749864

λ2 0.818825

Jerry 12Diky 341 Eka 14Sofi 14 cara di atas pake Data, data validation,Eka 14Aji 15

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