Chemical Hazards: A Swine Worker’s Guide

Outline

•Precautionary & Hazard Symbols

•Point of Entry

•Protective Gear

•Solvents

•Veterinary Drugs

•Cleaners & Sanitizers

•Insecticides

•Rodenticides

•Disposal

•Emergency Numbers

•References

•Acknowledgements

PRECAUTIONARY SYMBOLS

CORROSIVE

POISON

FLAMMABLE

EXPLOSIVE

HAZARDSYMBOLS

WARNING

CAUTION

DANGER

Point of Entry

Dermal

Ocular

Ingestion

Inhalation

Areas that Absorb Chemicals Quickly

Head

Underarms

Groin

Thin skin areas have a lot of surface blood vessels that pick up chemicals from the skin & transport them

all over the body. Sweat & oil produced in these areas dissolve chemicals & speed up their

absorption.

Back of Hand

After use, wash with detergent, rinse & dry.

After use, wash with detergent, rinse & dry.

Choose respiratory protection for the hazards you will encounter (half mask or full facepiece):

Protective Gear

DO NOT WEAR CLOTH HATS!

DO NOT WEAR PERMEABLE OR SOFT CONTACT LENSES WHEN

HANDLING CHEMICALS! Look for National Institute for Occupational Safety and Health (NIOSH) approval on mask and cartridges.

RE-USABLE:

•Change cartridges when breathing becomes restricted or according to manufacturers directions.

•After use, remove & store cartridges in a sealed plastic bag.

•Wash respirator with detergent, rinse & dry & store in a sealed plastic bag.

DISPOSABLE:

•If damaged, soiled or breathing becomes difficult leave the contaminated area & dispose of respirator.

RESPIRATORS

CHEMICAL GOGGLES

WATER PROOF HAT

• Inspect for leaks.

• After use wash in detergent & water, rinse & dry.

• Inspect for leaks.

• After use wash in detergent & water, rinse & dry.

• Wear unlined rubber boots.

• Choose gloves appropriate to the hazard you will encounter.

• Inspect unlined, chemical resistant gloves for leaks.

• After use wash in detergent & water, rinse & dry.

• Wash long sleeved cotton coveralls daily.

• Wash separately from all other laundry.

Protective GearCOVERALLS

RUBBER GLOVES

DO NOT USE LEATHER OR CANVAS GLOVES!

RUBBER APRON:

RUBBER BOOTS:

DO NOT USE LEATHER BOOTS!

Protective Gear

Fuel, Degreaser, Paint, Paint thinner

Health Hazard First ResponseSkin Skin irritant- redness,

dryness & rash.Wash with soap & water.

Eyes Strong irritant. Rinse with water for 15 minutes.

Inhalation Headaches, lightheadedness, dizziness.

Move victim to fresh air, if problem persists seek medical attention.

Ingestion: POISON! Contact Poison Control Centre!

Solvents

Veterinary Drugs

Vaccines, AntibioticsAccidental injections!

Health Hazard First ResponseSkin Inflammation around

injection site & potential allergic reaction.

Seek medical attention immediately!

Protective Gear

Hormones (Prostaglandins)

Health Hazard First ResponseSkin Menstrual irregularities,

miscarriage, respiratory distress.

Seek medical attention immediately!

Protective Gear

Skin contact & accidental injection!

Veterinary Drugs

Protective Gear

Dewormer

Veterinary Drugs

Health Hazard First ResponseAtgard® (Organophosphates): At all points of entry potential for: skin allergy, headaches, muscle twitching, cramps, nausea, diarrhea, respiratory irritant, respiratory depression, weakness, sweating, blurred vision, tearing, salivation, seizures, mental confusion, loss of consciousness. *Can lead to serious additive toxicity.*

Ivermectin®, Piperzine®: Dizziness, vomiting, shortness of breath, numbing & tingling of extremities.

Skin: Wash with soap & water.

Eyes: Rinse with water for 15 minute

Inhalation: Move victim to fresh air, if problem persists seek medical attention.

Ingestion: Contact Poison Control Centre!

Protective Gear

Hypochlorite (Bleach, Javex®)

Point of Entry Health Hazard First ResponseSkin Chemical burn. Wash with soap & water.

Eyes: Strong irritant, potential for burns & blindness.

Rinse with water for 15 minutes.

Inhalation Strong irritant. Move victim to fresh air, if problem persists seek medical attention.

Ingestion: POISON! Contact Poison Control Centre!

*Irritating gas release increases in hot water, releases chlorine gas, especially with acids. Dangerous gas released when mixed with formaldehyde!*

Cleaners & Sanitizers

Phenols (Tek-Trol®, Prosovet®)

Point of Entry Health Hazard First ResponseSkin Irritation, prolonged exposure may

cause pain, redness, swelling & tissue damage.

Wash with soap & water.

Eyes Stinging, tearing, pain, redness & swelling.

Rinse with water for 15 minutes.

Inhalation Respiratory tract irritation. Move victim to fresh air, if problem persists seek medical attention.

Ingestion Nausea, vomiting & diarrhea. Contact Poison Control Centre!

Protective Gear* Irritating gas release increased in hot water.*

Cleaners & Sanitizers

Quaternary Ammonia Compounds (Proquat®)

Point of Entry Health Hazard First ResponseSkin Irritation, risk of burns. Wash with soap & water.

Eyes Severe irritation, eye lid inflammation, crying eyes & high risk of permanent damage.

Rinse with water for 15 minutes.

Inhalation Nose & throat irritation, coughing, long term exposure = nose bleeding & chronic bronchitis.

Move victim to fresh air, if problem persists seek medical attention.

Ingestion Severe irritation, affects muscles, bloating, vomiting & gas. Risk of convulsions, shock & respiratory arrest.

Contact Poison Control Centre!

Protective Gear

Cleaners & Sanitizers

Protective Gear

Persulphates (Virkon®)

Point of Entry Health Hazard First ResponseSkin Skin allergy. Wash with soap & water.

Eyes Potential chemical burn. Rinse with water for 15 minutes.

Inhalation Respiratory irritant-coughing, choking, wheezing.

Move victim to fresh air, if problem persists seek medical attention.

Ingestion POISON! Contact Poison Control Centre!

Cleaners & Sanitizers

Formaldehyde (Fumalyse®)

Point of Entry Health Hazard First ResponseSkin Irritation, risk of burns. Wash with soap & water.

Eyes Severe irritation, may cause chemical burns.

Rinse with water for 15 minutes.

Inhalation Nose & throat irritation, coughing, long tern exposure equals nose bleeding & chronic bronchitis.

Move victim to fresh air, if problem persists seek medical attention.

Ingestion Nausea, vomiting & diarrhea. Contact Poison Control Centre.

Protective Gear

*Increased irritating gas release with hot water.*

Possible CANCER hazard.

Cleaners & Sanitizers

*Can lead to serious additive toxicity*

Protective Gear

Organophosphates Fly bait (SNIP®), Fly spray (Vapona®)

Insecticides

Health Hazard First ResponseAt all points of entry potential for:

weakness, headache, tightness in chest, respiratory depression, decreased heart rate, blurred vision, non-reactive pinpoint pupils, salivation, sweating, muscle twitching, nausea, vomiting, diarrhea & cramps, seizure, loss of consciousness.

Skin: Wash with soap & water.

Eyes: Rinse with water for 15 minute

Inhalation: Move victim to fresh air, if problem persists seek medical attention.

Ingestion: Contact Poison Control Centre!

CarbamatesFly bait (STARBAR®, STIMUKIL®, BLUE STREAK®, APACHE®)

Point of Entry Health Hazard First ResponseSkin Skin irritant-redness,

dryness & rash.Wash with soap & water.

Inhalation Respiratory irritant. Move victim to fresh air, if problem persists seek medical attention.

*Can lead to serious additive toxicity.Signs & symptoms: muscle weakness, dizziness, sweating, headache,

salivation, nausea, vomiting, diarrhea, stomach cramps, pin-point pupils with blurred vision, lack of coordination, muscle twitching, slurred speech.*

Protective Gear

Insecticides

Coumarins & Inandiones Rat & Mouse bait (CONTRAC®, TOMCAT®)

Protective Gear

Point of Entry Health Hazard First ResponseSkin Irritated skin. Wash with soap & water.

Eyes Potential irritant. Rinse with water for 15 minutes.

Ingestion Nausea, vomiting, loss of appetite, extreme thirst, diarrhea, nose bleeds, bleeding gums & failure of blood to clot after skin is wounded.

Contact Poison Control Centre!

Beware of HANTIVIRUS exposure. Wear respirator in high risk areas!

Rodenticides

DISPOSAL

Health Hazard First ResponseVeterinary Drug Containers

Expired, unopened Opened

Point of purchaseMedical waste company

Dewormer Containers Hazardous waste

Cleaner and Solvent Containers Triple Rinse, puncture and dispose in appropriate waste area.

Fly Spray Containers Return to dealer for collection.

Used Fly Bait and containers Hazardous waste

Rodent Bait Hazardous waste

Before eating, drinking, smoking or using the

washroom

WASH YOUR HANDSwith soap and water.

REMEMBER…..

Chemical Manufacturers Emergency Number: See container label or Material Safety Data Sheet

Take chemical container & label with you when seeking medical attention

EMERGENCY NUMBERS

POISON CONTROL CENTRE1-866-454-1212

SPILL REPORT CENTRESaskatchewan Environmental Safety

1-800-667-7525

1. Hagel. L. 1992. A Farmer’s Guide to Pesticide Label Interpretation Poster. The Centre of Agricultural Medicine.

2. Bidwell, J. and H. Bilinski. 1999. Clothing and protective equipment for agricultural chemical application. Selection, use and laundering. The Centre of Agricultural Medicine.

3. Saskatchewan Labour Occupational Health and Safety. Health and Safety Practices in Pork Production: Technical Modules. July 2004. http://www.labour.gov.sk.ca/safety/porkproduction/porktechnicalmodules.pdf Accessed June 2005.

4. Reigart, J. R. and J.R. Roberts. 1999. Recognition and Management of Pesticide Poisonings, 5th Edition. U.S. Environmental Protection Agency. Washington, DC.

5. Phoenix Scientific, Inc. MSDS Ivermectin® http://www.starbarproducts.com/MSDS/GoldenMalrin_splbl.pdf Accessed June 2005.

6. Chem-Tech Ltd. MSDS Piperazine® http://www.durvet.com/MSDS/234_MSDS.pdf Accessed June 2005. Boehringer Ingelheim Vetmedica inc. MSDS ATGARD®

7. http://www.bimsds.us/BIMSDS/msds/AtgardC_SwineWrmer_msds.pdf Accessed June 2005.

8. The Pigsite.com. 2005. http://www.thepigsite.com/BusinessDirectory/Focus.asp?Display=2846 Accessed July 2005.

References

9. University of Illinois at Urbana=-Champaign. 2005. Swine Reproduction Swine Reproduction Information on the Internet. Induced Farrowing.

10. VIDO Swine Technical Group –Linking knowledge to practical solutions. Vaccination Guidelines for Swine - June 2004. http://www.vido.org/producers/techgroups/swine/publications.php Accessed July 2005.

11. http://www.traill.uiuc.edu/swinerepronet/paperDisplay.cfm?Type=Both&ContentID=6264. Accessed July 2005.

12. ABC Compounding. MSDS TEk-Trol®.http://www.abccompounding.com/MSDS/LA-700%20MSDS.pdfAccessed June 2005.

13. Ptrotecnica Ingenieria S.A. MSDS Proquat® BC 50.http://www.prochemusa.net/MSDS/PROQUAT%20BC50(MSDS).pdf Accessed June 2005.

14. Syndel International Inc. MSDS Virkon®.http://www.syndel.com/msds/virkon_msds.html Accessed June 2005.

15. Bio Agri Mix Ltd. MSDS Fumalyse II®. http://www.bioagrimix.com/msds/36/36280/3628049.pdf. Accessed June 2005.

References

References

16. Bell Laboratories, Inc. MSDS CONTRAC®.http://www.belllabs.com/images/MSDS/contrac_rodenticide_us.pdf Accessed June 2005.

17. Bell Laboratories, Inc. MSDS TOMCAT®. http://www.motomco.com/pdf/TOMCAT_RatMouseBait.pdf Accessed June 2005.

18. Bayer Environmental Science. MSDS Racumin 8® Rat and Mouse Rodenticide.http://www.bayercropscience.com.au/products/resources/msds/Racumin%208.pdf Accessed June 2005.

19. Mock, D.E. 1997. Lice, Mange and Other Swine Insect Problems. Entomology 230. Kansas State University.

20. Myer, R.O. and W.R. Walker. Controlling Internal Parasites in Swine. University of Florida, IFAS Extension. AS50. Farnam Companies, Inc. MSDS Blue Streak® Fly Bait. http://www.plunketts.net/bluestreak-m.htm Accessed June 2005.

21. Novelties Animal Health Canada Inc. MSDS SNIP® Fly Bait. http://www.eddenet.pmra-arla.gc.ca/4.0/4.1.2.asp?regn=25808.00&page=1&uniqueid=7%2F30%2F2004+11%3A17%3A31+AM Accessed June 2005.

References

22. MSDS.COM.AU. MSDS SNIP® Fly Bait. 1999. http://www.msds.com.au/Search_detail.asp?s_keyword=&s_AlphaSearch=S&ProductPage=6&IDNo=13635&s_Type=keyword Accessed July 2005.

23. Boehringer Ingelheim Vetmedica, Inc. Vapona® Concentrate Insecticide. http://www.bi-vetmedica.com/products/products_insectcide_list.html Accessed July 2005.

24. Troy Biosciences Inc. MSDS STIMUKIL® Fly Bait. http://www.indfumco.com/new/data/Stimukil%20Fly%20Bait%20MSDS%202.26.03.pdfAccessed June 2005.

25. Wellmark International GOLDEN MALRIN® Fly Bait. http://www.starbarproducts.com/MSDS/GoldenMalrin_splbl.pdfAccessed June 2005.

ACKNOWLEDGEMENTSPrepared by:

Sueli B. de Freitas, BSc

Niels Koehncke, MD, MSc, FRCPC

Leanne LaBrash, MSc

Helen McDuffie, PhDInstitute of Agricultural Rural & Environmental Health

Royal University HospitalUniversity of Saskatchewan

103 Hospital Drive Saskatoon, SK S7N 0W8 Canada

I.ARE.H phone: (306) 966-8286/fax: (306) 966-8799 http://iareh.usask.ca/