CEMENTED CARBIDES AND CERMETSThe history of cemented carbides is relatively short. After appearing...
Transcript of CEMENTED CARBIDES AND CERMETSThe history of cemented carbides is relatively short. After appearing...
Prepared by:A. E. ShapiroTitanium Brazing, IncorporatedD. W. BucholzConforma Clad, Incorporated
ContentsIntroduction 410Base Materials 410Brazing Filler Metals 418Joint Design 423Fluxes and Atmospheres 426Precleaning andSurface Preparation 427Brazing Techniquesand Equipment 428Postbrazing Operations 434Strength of Brazed Joints 435Examination andTesting 437Brazing of SuperhardMaterials toCemented Carbides 439Applications 440Wear-ResistantHardfacing Produced byBrazing Carbide Particles 441Troubleshooting 444Bibliography 447
CHAPTER 22
CEMENTED CARBIDES AND CERMETS
Courtesy of Conforma Clad, Incorporated
AWS BRAZING HANDBOOK 409
INTRODUCTION
410 CHAPTER 22—CEMENTED CARBIDES AND CERMETS AWS BRAZING HANDBOOK
The materials commonly known as cemented car-bides or hard alloys are actually a wide variety ofmetal matrix composites in which one or more typesof hard carbide (and sometimes carbonitride) parti-cles are bound together by a ductile metallic binder.The history of cemented carbides is relatively short.After appearing in the 1920s, they were implementedin industry in the 1930s as carbide-to-steel brazedcutting tools, resulting in a jump in productivity andthe quality of machining steels.
Although the cemented carbides are best knownfor their use in metal cutting tool bits, they are foundin many applications that require one or more of theoutstanding physical and mechanical properties ofthese materials—extremely high hardness, high com-pressive strength, rigidity and impact resistance,excellent wear and corrosion resistance. Typicalapplications include brazed metal cutting tools,wood cutting tools, abrasive wheels, metal-formingtools such as punches and dies, slitters and rolls, sealrings and valve sets in combustion engines, wear-and heat-resistant brazed parts in jet engines.
Several techniques for joining the cemented car-bides to metals or ceramics have been developed.The major techniques are brazing and mechanicalfastening. Brazing is a successful and reliable methodof mounting carbides to steel shanks (see Figure22.1) or other base materials. The specifics of braz-ing design and technology are generally influencedby (1) a large difference between cemented carbidesand most faying structural alloys with respect to thecoefficient of thermal expansion (CTE) and (2) ahigh content of the carbide phase in the structure ofthese materials. Special attention should be paid to(1) providing sufficient wetting of carbides by themolten brazing filler metal and (2) minimizing ther-mal strains in brazements. However, the strength of
cemented carbide brazed joints is significantly betterthan that of ceramic joints due to presence of themetallic phase in the former’s structure.
BASE MATERIALS
Cemented carbides vary widely in compositions,but with respect to brazing, the following generalclassifications can be made:
CEMENTED CARBIDES AND CERMETS
CHAPTER 22
Photograph courtesy of Titanium Brazing, Incorporated
Figure 22.1—WC-Co Carbide Insert Brazed toSteel Drill Bits by High-Frequency Induction
Brazing Using Brazing Filler Metal AWS BAg-6