Calcium hypochlorite_Unicorn Chemicals Co.

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Calcium hypochlorite Uses Calcium hypochlorite is an inorganic compound with formula Ca(ClO)2. As a mixture with lime and calcium chloride, it is marketed as chlorine powder or bleach powder for water treatment and as a bleaching agent.[1] This compound is relatively stable and has greater available chlorine than sodium hypochlorite (liquid bleach).[2] It is a white solid, although commercial samples appear yellow. It strongly smells of chlorine, owing to its slow decomposition in moist air. It is not highly soluble in water and is more preferably used in soft to medium-hard water. It has two forms: dry and hydrated. Sanitation Calcium hypochlorite is commonly used to sanitize public swimming pools and disinfect drinking water. Generally the commercial substance is sold with a purity of a 68% (with other additives and contaminants varying based upon the product's intended purpose). For instance as a swimming pool chemical it is often mixed with cyanuric acid stabilizers and anti-scaling agents (in order to reduce the loss of chlorine from ultraviolet radiation and to prevent calcium hardening). Calcium hypochlorite is also used in kitchens to disinfect surfaces and equipment.[3] Other common uses include bathroom cleansers, household disinfectant sprays, algaecides, herbicides, and laundry detergents. Organic chemistry Calcium hypochlorite is a general oxidizing agent and therefore finds some use in organic chemistry.[4] For instance the compound is used to cleave glycols, α-hydroxy carboxylic acids and keto acids to yield fragmented aldehydes or carboxylic acids.[5] Calcium hypochlorite can also be used in the haloform reaction to manufacture chloroform.

Transcript of Calcium hypochlorite_Unicorn Chemicals Co.

Page 1: Calcium hypochlorite_Unicorn Chemicals Co.

Calcium hypochlorite

Uses

Calcium hypochlorite is an inorganic compound with formula Ca(ClO)2. As a mixture with lime and calcium chloride, it is marketed as chlorine powder or bleach powder for water treatment and as a bleaching agent.[1] This compound is relatively stable and has greater available chlorine than sodium hypochlorite (liquid bleach).[2] It is a white solid, although commercial samples appear yellow. It strongly smells of chlorine, owing to its slow decomposition in moist air. It is not highly soluble in water and is more preferably used in soft to medium-hard water. It has two forms: dry and hydrated.

SanitationCalcium hypochlorite is commonly used to sanitize public swimming pools and disinfect drinking water. Generally the commercial substance is sold with a purity of a 68% (with other additives and contaminants varying based upon the product's intended purpose). For instance as a swimming pool chemical it is often mixed with cyanuric acid stabilizers and anti-scaling agents (in order to reduce the loss of chlorine from ultraviolet radiation and to prevent calcium hardening). Calcium hypochlorite is also used in kitchens to disinfect surfaces and equipment.[3] Other common uses include bathroom cleansers, household disinfectant sprays, algaecides, herbicides, and laundry detergents.Organic chemistryCalcium hypochlorite is a general oxidizing agent and therefore finds some use in organic chemistry.[4] For instance the compound is used to cleave glycols, α-hydroxy carboxylic acids and keto acids to yield fragmented aldehydes or carboxylic acids.[5] Calcium hypochlorite can also be used in the haloform reaction to manufacture chloroform.

Page 2: Calcium hypochlorite_Unicorn Chemicals Co.

ProductionCalcium oxychloride is produced industrially by treating lime

(Ca(OH)2) with chlorine gas. The reaction can be conducted in stages to

give various compositions, each with different concentration of calcium

hypochlorite, together with unconverted lime and calcium chloride. The

full conversion is shown[1]

2 Cl2 + 2 Ca(OH)2 → Ca(OCl)2 + CaCl2 + 2 H 2OBleaching powder is not a simple mixture of calcium hypochlorite,

calcium chloride, and calcium hydroxide. Instead, it is a mixture

consisting principally of calcium hypochlorite Ca(OCl)2, dibasic

calcium hypochlorite, Ca3(OCl)2(OH)4, and dibasic calcium chloride,

Ca3Cl2(OH)4.[7] It is made from slightly moist slaked lime.

SafetyCalcium hypochlorite is stored dry and cold, away from any organic

material and metals. The hydrated form is safer to handle.