Brent Crude Oil - Shetland Islands Council€¦ · EnQuest Annan House Palmerston Road Aberdeen -...

Brent Crude Oil Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 2015/830 Date of issue: 07.11.2019 Revision date: 07.11.2019 Version: 1.0

07.11.2019 (Version: 1.0)

EN (English) 1/32

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance (UVCB)

Trade name : Brent Crude Oil

Chemical name : Petroleum; Crude oil

EC Index-No. : 649-049-00-5

EC-No. : 232-298-5

CAS-No. : 8002-05-9

REACH registration No : exempt

Other means of identification : Petroleum Crude oil [A complex combination of hydrocarbons, It consists predominantly of aliphatic, alicyclic and aromatic hydrocarbons. It may also contain small amounts of nitrogen, oxygen and sulfur compounds. This category encompasses light, medium, and heavy petroleums, as well as the oils extended from tar sands. Hydrocarbonaceous materials requiring major chemical changes for their recovery or conversion to petroleum refinery feedstocks such as crude shale oils; upgraded shale oils and liquid coal fuels are not included in this definition.]

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.2.1. Relevant identified uses

Use of the substance/mixture : Refinery Feedstock for Distillation

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number Emergency number : +44 (0)1224 975000

SECTION 2: Hazards identification 2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Mixtures/Substances: SDS EU 2015: According to Regulation (EU)

2015/830 (REACH Annex II)

Flammable liquids, Category 1 H224

Germ cell mutagenicity, Category 1B H340

Carcinogenicity, Category 1A H350

Aspiration hazard, Category 1 H304

Hazardous to the aquatic environment — Chronic Hazard, Category 3 H412

Full text of H statements : see section 16

Adverse physicochemical, human health and environmental effects

No additional information available

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]Extra labelling to displayExtra classification(s) to display

Hazard pictograms (CLP) :

GHS02 GHS08

Signal word (CLP) : Danger

Supplier

EnQuest Annan House Palmerston Road Aberdeen - United Kindgdom T : 01224 975000 - F : 01224 287105 e-mail: [email protected]

mailto:[email protected]

Brent Crude Oil Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 2015/830

07.11.2019 (Version: 1.0)

EN (English) 2/32

Hazard statements (CLP) : H224 - Extremely flammable liquid and vapour. H304 - May be fatal if swallowed and enters airways. H340 - May cause genetic defects. H350 - May cause cancer. H412 - Harmful to aquatic life with long lasting effects.

Precautionary statements (CLP) : P201 - Obtain special instructions before use. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P235 - Keep cool. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301+P310+P331 - IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting.

2.3. Other hazards No additional information available

SECTION 3: Composition/information on ingredients 3.1. Substances Substance type : UVCB

Name : Petroleum; Crude oil

Trade name : Brent Crude oil

CAS-No. : 8002-05-9

EC-No. : 232-298-5

EC Index-No. : 649-049-00-5

Name Product identifier %

Petroleum; Crude oil (CAS-No.) 8002-05-9 (EC-No.) 232-298-5 (EC Index-No.) 649-049-00-5 (REACH-no) exempt

94,88

butane (CAS-No.) 106-97-8 (EC-No.) 203-448-7 (EC Index-No.) 601-004-00-0 (REACH-no) not available

1,58

pentane (CAS-No.) 109-66-0 (EC-No.) 203-692-4 (EC Index-No.) 601-006-00-1 (REACH-no) not available

1,53

isopentane; 2-methylbutane (CAS-No.) 78-78-4 (EC-No.) 201-142-8 (EC Index-No.) 601-085-00-2 (REACH-no) not available

0,96

propane (CAS-No.) 74-98-6 (EC-No.) 200-827-9 (EC Index-No.) 601-003-00-5 (REACH-no) Not available

0,68

benzene (CAS-No.) 71-43-2 (EC-No.) 200-753-7 (EC Index-No.) 601-020-00-8 (REACH-no) Not available

0,57

isobutane (CAS-No.) 75-28-5 (EC-No.) 200-857-2 (EC Index-No.) 601-004-00-0 (REACH-no) Not available

0,34

Full text of H-statements: see section 16

3.2. Mixtures Not applicable

SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. If breathing is irregular or

stopped, administer artificial respiration.

First-aid measures after skin contact : Wash with plenty of water. Take off immediately all contaminated clothing. If skin irritation occurs: Get medical advice/attention.


07.11.2019 (Version: 1.0)

EN (English) 3/32

First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice and attention.

First-aid measures after ingestion : Never give anything by mouth to an unconscious person. Drink directly plenty of water or milk. Do NOT induce vomiting. Get immediate medical advice/attention. Caution if victim vomits: Risk of aspiration!.

4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation : May cause respiratory irritation. Cough.

Symptoms/effects after skin contact : Repeated exposure may cause skin dryness or cracking.

Symptoms/effects after eye contact : May cause slight temporary irritation.

Symptoms/effects after ingestion : May be fatal if swallowed and enters airways. May result in aspiration into the lungs, causing chemical pneumonia.

4.3. Indication of any immediate medical attention and special treatment needed No additional information available

SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : carbon dioxide (CO2), dry chemical powder, foam.

Unsuitable extinguishing media : Do not use a water jet since it may cause the fire to spread.

5.2. Special hazards arising from the substance or mixture Fire hazard : Extremely flammable liquid and vapour. Flammable vapours can accumulate in head space

of closed systems.

Explosion hazard : Vapours can travel considerable distances to a source of ignition where they can ignite, flash back, or explode. May form flammable vapour-air mixture.

Hazardous decomposition products in case of fire : Toxic gases and fumes may be released in a fire.

5.3. Advice for firefighters Firefighting instructions : Eliminate all ignition sources if safe to do so. Do not use a water jet since it may cause the

fire to spread. Cool closed containers exposed to fire with water spray.

Protective equipment for firefighters : In case of fire: Wear self-contained breathing apparatus.

SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Protective equipment : Wear suitable protective clothing.

Emergency procedures : Stop leak if safe to do so. Evacuate area. Immediately contact emergency personnel.

6.1.2. For emergency responders

Protective equipment : Wear suitable protective clothing. In case of fire: Wear self-contained breathing apparatus.

Emergency procedures : Evacuate and limit access. Ventilate affected area. Contain large spills to maximize product recovery or disposal. Special danger of slipping by leaking/spilling product. Notify environmental authorities.

6.2. Environmental precautions Do not allow to enter into surface water or drains.

6.3. Methods and material for containment and cleaning up For containment : Contain any spills with dikes or absorbents to prevent migration and entry into sewers or

streams. This material will float on water. In case of small spillages in closed waters, contain product with floating barriers or other equipment.

Methods for cleaning up : Remove from the water surface (e.g. skimming, sucking). Recover large spills by pumping (use an explosion proof or hand pump). The use of dispersants should be advised by an expert, and, if required, approved by local authorities.

6.4. Reference to other sections No additional information available

SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : A specific assessment on inhalation risk due to the presence of H2S in tank headspaces,

confined spaces, product residue, tank waste and waste water should be carried out in order to determine appropriate control parameters.

Precautions for safe handling : Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid contact with skin, eyes and clothes. Open and handle container with care. Handle empty containers with care because residual vapours are flammable. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose containers to flames, sparks, heat, or other potential ignition sources.

Hygiene measures : Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Handle in accordance with good industrial hygiene and safety practice. Take care for general good hygiene and housekeeping. Wash contaminated clothing before reuse.


07.11.2019 (Version: 1.0)

EN (English) 4/32

7.2. Conditions for safe storage, including any incompatibilities Technical measures : Provide for an automatic sprinkler system.

Storage conditions : Keep container tightly closed. Store in a well-ventilated place. Keep container closed (and grounded).

Heat and ignition sources : Keep away from open flames, hot surfaces and sources of ignition.

Special rules on packaging : To avoid the risks of fires, all contaminated materials should be stored in purpose-built containers or in metal containers with tight-fitting self-closing lids with pressure relief valve.

7.3. Specific end use(s) No additional information available

SECTION 8: Exposure controls/personal protection 8.1. Control parameters

Brent Crude Oil (8002-05-9)

Bulgaria - Occupational Exposure Limits

Local name Газьол (нафта)-петролеев дестилат

OEL TWA (mg/m³) 1600 mg/m³

Regulatory reference Наредба № 13 от 30.12.2003 г. за защита на работещите от рискове, свързани с експозиция на химични агенти при работа (изм. и доп. ДВ. бр.73 от 4 септември 2018 г.)

Croatia - Occupational Exposure Limits

GVI (granična vrijednost izloženosti) (mg/m³) 400 mg/m³

GVI (granična vrijednost izloženosti) (ppm) 100 ppm

Latvia - Occupational Exposure Limits


pentane (109-66-0)

EU - Occupational Exposure Limits

Local name Pentane

IOELV TWA (mg/m³) 3000 mg/m³

IOELV TWA (ppm) 1000 ppm

Regulatory reference COMMISSION DIRECTIVE 2006/15/EC

Austria - Occupational Exposure Limits

Local name n-Pentan

MAK (mg/m³) 1800 mg/m³

MAK (ppm) 600 ppm

MAK Short time value (mg/m³) 3600 mg/m³

MAK Short time value (ppm) 1200 ppm

Regulatory reference BGBl. II Nr. 186/2015

Belgium - Occupational Exposure Limits

Local name Pentane, tous isomères # Pentaan, alle isomeren

Limit value (mg/m³) 1800 mg/m³

Limit value (ppm) 600 ppm

Short time value (mg/m³) 2250 mg/m³

Short time value (ppm) 750 ppm

Regulatory reference Koninklijk besluit/Arrêté royal 02/09/2018


Local name n-Пентан


OEL TWA (ppm) 1000 ppm

Notes • (Химични агенти, за които са определени гранични стойности във въздуха на работната среда за Европейската общност)


07.11.2019 (Version: 1.0)

EN (English) 5/32

pentane (109-66-0)



Local name Pentan



Naznake (HR) Direktiva: 2006/15/EZ

Regulatory reference Pravilnik o izmjenama i dopunama Pravilnika o graničnim vrijednostima izloženosti opasnim tvarima pri radu i o biološkim graničnim vrijednostima (NN 91/2018)

Czech Republic - Occupational Exposure Limits

Local name Pentan

Expoziční limity (PEL) (mg/m³) 3000 mg/m³

Expoziční limity (PEL) (ppm) 1017 ppm

Expoziční limity (NPK-P) (mg/m³) 4500 mg/m³

Expoziční limity (NPK-P) (ppm) 1525,5 ppm

Remark (CZ) *

Regulatory reference Nařízení vlády č. 361/2007 Sb. (zapracovány změny č. 246/2018 Sb.)

Denmark - Occupational Exposure Limits

Local name Pentan

Grænseværdie (langvarig) (mg/m³) 1500 mg/m³

Grænseværdie (langvarig) (ppm) 500 ppm

Grænseværdie (kortvarig) (mg/m³) 3000 mg/m³

Grænseværdie (kortvarig) (ppm) 1000 ppm

Anmærkninger (DK) E (betyder, at stoffet har en EF-grænseværdi)

Regulatory reference BEK nr 655 af 31/05/2018

Estonia - Occupational Exposure Limits

Local name Pentaan



Regulatory reference Vabariigi Valitsuse 18. septembri 2001. a määruse nr 293 (RT I, 30.11.2011, 5)

Finland - Occupational Exposure Limits

Local name n-Pentaani

HTP-arvo (8h) (mg/m³) 1500 mg/m³

HTP-arvo (8h) (ppm) 500 ppm

HTP-arvo (15 min) 1900 mg/m³

HTP-arvo (15 min) (ppm) 630 ppm

Regulatory reference HTP-ARVOT 2018 (Sosiaali- ja terveysministeriö)

France - Occupational Exposure Limits

Local name n-Pentane

VME (mg/m³) 3000 mg/m³

VME (ppm) 1000 ppm

Note (FR) Valeurs règlementaires contraignantes

Regulatory reference Article R4412-149 du Code du travail (réf.: INRS ED 984, 2016)


07.11.2019 (Version: 1.0)

EN (English) 6/32

pentane (109-66-0)

Germany - Occupational Exposure Limits (TRGS 900)

TRGS 900 Local name Pentan

TRGS 900 Occupational exposure limit value (mg/m³) 3000 mg/m³

TRGS 900 Occupational exposure limit value (ppm) 1000 ppm

TRGS 900 Limitation of exposure peaks 2(II)

TRGS 900 Remark DFG;EU;Y

TRGS 900 Regulatory reference TRGS900

Gibraltar - Occupational Exposure Limits

Name of agent Pentane

Eight hours mg/m3 3000 mg/m³

Eight hours ppm 1000 ppm

Regulatory reference Factories (Control of Chemical Agents at Work) Regulations 2003 (LN. 2018/181)

Greece - Occupational Exposure Limits

Local name Πεντάνιο (όλα τα ισομερή)



OEL STEL (mg/m³) 2950 mg/m³

OEL STEL (ppm) 1000 ppm

Regulatory reference Π.Δ. 90/1999

Hungary - Occupational Exposure Limits

Local name n-PENTÁN

AK-érték 2950 mg/m³

CK-érték 9400 mg/m³

Megjegyzések (HU) EU2 (2006/15/EK irányelvben közölt érték)

Regulatory reference 25/2000. (IX. 30.) EüM–SZCSM együttes rendelet a munkahelyek kémiai biztonságáról

Ireland - Occupational Exposure Limits

Local name n-Pentane

OEL (8 hours ref) (mg/m³) 1800 mg/m³

OEL (8 hours ref) (ppm) 600 ppm

OEL (15 min ref) (mg/m3) 2250 mg/m³

OEL (15 min ref) (ppm) 750 ppm

Notes (IE) IOELV

Regulatory reference Code of Practice for the Chemical Agents Regulations 2018

Italy - Occupational Exposure Limits

Local name Pentano



Regulatory reference Allegato XXXVIII del D.Lgs. 9 aprile 2008, n. 81 e s.m.i.


Local name Pentāns



Regulatory reference Ministru kabineta 2007.gada 15.maija noteikumiem Nr.325


07.11.2019 (Version: 1.0)

EN (English) 7/32

pentane (109-66-0)

Lithuania - Occupational Exposure Limits

Local name Pentanas

IPRV (mg/m³) 3000 mg/m³

IPRV (ppm) 1000 ppm

Regulatory reference LIETUVOS HIGIENOS NORMA HN 23:2011 (Nr. V-695/A1-272, 2018-06-12)

Luxembourg - Occupational Exposure Limits

Local name Pentane



Regulatory reference Mémorial A Nº 684 de 2018

Malta - Occupational Exposure Limits

Local name Pentane



Regulatory reference S.L.424.24 (L.N.57 of 2018)

Netherlands - Occupational Exposure Limits

Local name n-Pentaan

Grenswaarde TGG 8H (mg/m³) 1800 mg/m³

Regulatory reference Arbeidsomstandighedenregeling 2018

Poland - Occupational Exposure Limits

Local name Pentan

NDS (mg/m³) 3000 mg/m³

Regulatory reference Dz. U. 2018 poz. 1286

Portugal - Occupational Exposure Limits

Local name Pentano , todos os isómeros


Regulatory reference Norma Portuguesa NP 1796:2014

Romania - Occupational Exposure Limits

Local name Pentan



Regulatory reference Hotărârea nr. 584/2018

Slovakia - Occupational Exposure Limits

Local name Pentán

NPHV (priemerná) (mg/m³) 3000 mg/m³

NPHV (priemerná) (ppm) 1000 ppm

Regulatory reference Nariadenie vlády č. 33/2018 Z.z.

Slovenia - Occupational Exposure Limits

Local name pentan





Remark (SI) Y (Snovi, pri katerih ni nevarnosti za zarodek ob upoštevanju mejnih vrednosti in bat vrednosti), EU


07.11.2019 (Version: 1.0)

EN (English) 8/32

pentane (109-66-0)

Regulatory reference Uradni list RS, št. 78/2018 z dne 4.12.2018

Spain - Occupational Exposure Limits

Local name n-Pentano

VLA-ED (mg/m³) 3000 mg/m³

VLA-ED (ppm) 1000 ppm

Notes VLI (Agente químico para el que la U.E. estableció en su día un valor límite indicativo).

Regulatory reference Límites de Exposición Profesional para Agentes Químicos en España 2019. INSHT

Sweden - Occupational Exposure Limits

Local name n-Pentan

nivågränsvärde (NVG) (mg/m³) 1800 mg/m³

nivågränsvärde (NVG) (ppm) 600 ppm

kortidsvärde (KTV) (mg/m³) 2000 mg/m³

kortidsvärde (KTV) (ppm) 750 ppm

Anmärkning (SE) V (Vägledande korttidsgränsvärde ska användas som ett rekommenderat högsta värde som inte bör överskridas)

Regulatory reference Hygieniska gränsvärden (AFS 2018:1)

United Kingdom - Occupational Exposure Limits

Local name Pentane

WEL TWA (mg/m³) 1800 mg/m³

WEL TWA (ppm) 600 ppm

Regulatory reference EH40/2005 (Third edition, 2018). HSE

Iceland - Occupational Exposure Limits

Local name Pentan, allir ísómerar



Regulatory reference Reglugerð um mengunarmörk og aðgerðir til að draga úr mengun á vinnustöðum (Nr. 390/2009)

Norway - Occupational Exposure Limits

Local name Pentan

Grenseverdier (AN) (mg/m³) 750 mg/m³

Grenseverdier (AN) (ppm) 250 ppm

Merknader (NO) E (EU har en veiledende grenseverdi for stoffet)

Regulatory reference FOR-2018-08-21-1255

Switzerland - Occupational Exposure Limits

Local name Pentane (tous les isomères) / Pentan (alle Isomere)


MAK (ppm) 600 ppm

KZGW (mg/m³) 3600 mg/m³

KZGW (ppm) 1200 ppm

Critical toxicity SNP / PNS

Notation SSC / SSC

Remark NIOSH

Regulatory reference www.suva.ch, 01.07.2019

Turkey - Occupational Exposure Limits

Local name Pentan


07.11.2019 (Version: 1.0)

EN (English) 9/32

pentane (109-66-0)



Regulatory reference 12 Ağustos 2013 Tarihli ve 28733 Sayılı Resmî Gazete

propane (74-98-6)


Local name Propan (R 290)


MAK (ppm) 1000 ppm





Local name Hydrocarbures aliphatiques sous forme gazeuse: (Alcanes C1-C3) # Alifatische koolwaterstoffen in gas-vorm: Alkanen (C1-C3)




Local name Пропан




Local name Propan (Flaskegas)



Grænseværdie (kortvarig) (mg/m³) 3600 mg/m³

Grænseværdie (kortvarig) (ppm) 2000 ppm



Local name Propaan





Local name Propaani






07.11.2019 (Version: 1.0)

EN (English) 10/32

propane (74-98-6)

Huomautus (FI) Happea syrjäyttämällä tukahduttavat kaasut: Eräät kaasut voivat suurina pitoisuuksina vaikuttaa tukahduttavasti ilman muita merkittäviä fysiologisia vaikutuksia. Hapen puutetta voi ilmaantua työilman normaalin happipitoisuuden (noin 21 %) laskiessa alle 18 %:n. Erityisesti typetettyihin tiloihin kulkuun liittyy merkittävä tukehtumisriski ja hengenvaara. Liian alhaiselta happipitoisuudelta suojaudutaan valvomalla työilman happipitoisuutta ja tarkoituksenmukaisin teknisin järjestelyin sekä suojaimin, johon hengityskelpoista ilmaa saadaan letkuilla tai säiliöstä riippumatta ympäröivästä ilmasta. Erityisen herkkiä alhaiselle happipitoisuudelle voivat olla eräitä sydän- ja keuhkosairauksia sairastavat työntekijät. Jotkut tukahduttavista kaasuista, kuten vety ja asetyleeni, ovat erittäin helposti syttyviä jo pienemmissä pitoisuuksissa, ja myös tämän vuoksi niiden työilmapitoisuus on pidettävä alhaisena. Muita happea syrjäyttämällä tukahduttavia kaasuja ovat mm. helium, neon, argon ja jo edellä mainittu typpi.



TRGS 900 Local name Propan




TRGS 900 Remark DFG



Local name Προπάνιο





Local name Propane

OEL (15 min ref) (ppm) 3000 ppm (calculated (Aliphatic hydrocarbon gases - Alkanes (C1-C4))

Notes (IE) Asphx. (Gaseous chemical substances which may not produce significant physiological effects in the exposed employee, but when present in high concentrations will act as simple asphyxiants).

OEL chemical category (IE) Simple asphyxiant



Local name Propāns



Regulatory reference Ministru kabineta 2007.gada 15.maija noteikumiem Nr.325 (Grozījumi Ministru kabineta 2015.gada 7.aprīlī noteikumiem Nr.163)


Local name Propan






Local name Propan





07.11.2019 (Version: 1.0)

EN (English) 11/32

propane (74-98-6)




Local name propan







Local name Propano

VLA-ED (ppm) 1000 ppm Hidrocarburos alifáticos alcanos (C1 – C4) y sus mezclas, gases (Butano; Etano; Metano; Propano)



Local name Própan (flöskugas)





Local name Propan



Grenseverdier (Korttidsverdi) (mg/m3) 1125 mg/m³ (value calculated)

Grenseverdier (Korttidsverdi) (ppm) 625 ppm (value calculated)



Local name Propane / Propan


MAK (ppm) 1000 ppm


KZGW (ppm) 4000 ppm

Critical toxicity Formel / Formal

Remark NIOSH


butane (106-97-8)


Local name Butan (beide Isomeren): n-Butan (R 600)


MAK (ppm) 800 ppm





07.11.2019 (Version: 1.0)

EN (English) 12/32

butane (106-97-8)


Local name Butane, tous isomères: n-butane # Butaan, alle isomeren: n-butaan





Local name n-Бутан




Local name Butan



KGVI (kratkotrajna granična vrijednost izloženosti) (mg/m³)

1810 mg/m³

KGVI (kratkotrajna granična vrijednost izloženosti) (ppm)

750 ppm

OEL chemical category (HR) Carcinogen Category 1A containing >=0.1% 1,3-Butadiene, Mutagen Category 1B containing >=0.1% 1,3-Butadiene



Local name n-Butan





Local name n-butaan





Local name n-Butaani







07.11.2019 (Version: 1.0)

EN (English) 13/32

butane (106-97-8)



Local name n-Butane


VME (ppm) 800 ppm

Note (FR) Valeurs recommandées/admises

Regulatory reference Circulaire du Ministère du travail (réf.: INRS ED 984, 2016)


TRGS 900 Local name Butan




TRGS 900 Remark DFG



Local name Βουτάνιο





Local name n-BUTÁN


CK-érték 9400 mg/m³

Megjegyzések (HU) IV. (NAGYON GYENGE KÁROSÍTÓ HATÁSÚ ANYAGOK (ÁK > 500 ml/m3))



Local name Butane


OEL (15 min ref) (ppm) 3000 ppm (calculated)



Local name Butāns




Local name Butan (n-butan)


NDSCh (mg/m³) 3000 mg/m³



Local name Butano, todos os isómeros




07.11.2019 (Version: 1.0)

EN (English) 14/32

butane (106-97-8)


Local name bután s obsahom ≥ 0,1% butadiénu (n-bután) (izo-bután)



Upozornenie (SK) Kategória karcinogénov 1A – Dokázaný karcinogén pre ľudí

Regulatory reference Nariadenie vlády č. 83/2015 Z. z.


Local name butan





OEL chemical category (SL) Category 1A containing >=0.1% Butadiene, Category 1B containing >=0.1% Butadiene



Local name Butano


VLA-ED (ppm) 1000 ppm Hidrocarburos alifáticos alcanos (C1 – C4) y sus mezclas, gases (Butano; Etano; Metano; Propano)



Local name Butane



WEL STEL (mg/m³) 1810 mg/m³

WEL STEL (ppm) 750 ppm

Remark (WEL) Carc (Capable of causing cancer and/or heritable genetic damage, only applies if Butane contains more than 0.1% of buta-1,3-diene)

WEL chemical category Capable of causing cancer and/or heritable genetic damage containing >0.1% Buta-1,3-diene



Local name n- Bútan





Local name Butan




Grenseverdier (Korttidsverdi) (ppm) 312,5 ppm (value calculated)



Local name n-Butane / n-Butan


07.11.2019 (Version: 1.0)

EN (English) 15/32

butane (106-97-8)


MAK (ppm) 800 ppm


KZGW (ppm) 3200 ppm

Critical toxicity SNC / ZNS


isopentane; 2-methylbutane (78-78-4)


Local name Isopentane

IOELV TWA (mg/m³) 3000 mg/m³


Regulatory reference COMMISSION DIRECTIVE 2006/15/EC


Local name Isopentan (2-Methylbutan)


MAK (ppm) 600 ppm





Local name Pentane, tous isomères # Pentaan, alle isomeren

Limit value (mg/m³) 1800 mg/m³






Local name Изопентан



Notes • (Химични агенти, за които са определени гранични стойности във въздуха на работната среда за Европейската общност)



Local name Izopentan; 2-metilbutan



Naznake (HR) Direktiva: 2006/15/EZ



Local name isoPentan (iso-Pentan)


Expoziční limity (PEL) (ppm) 1020 ppm


07.11.2019 (Version: 1.0)

EN (English) 16/32


Expoziční limity (NPK-P) (mg/m³) 4500 mg/m³ (3)

Expoziční limity (NPK-P) (ppm) 1526 ppm (3)

Remark (CZ) (3) Je brán zřetel na fyzikálně-chemické vlastnosti (například výbušnost).



Local name Isopentan



Anmærkninger (DK) E (betyder, at stoffet har en EF-grænseværdi)



Local name Isopentaan (2-metüülbutaan)





Local name 2-Metyylibutaani









VME (ppm) 1000 ppm

Note (FR) Valeurs règlementaires indicatives

Regulatory reference Arrêté du 30 juin 2004 modifié (réf.: INRS ED 984, 2016)


TRGS 900 Local name Methylbutan




TRGS 900 Remark DFG;EU


Gibraltar - Occupational Exposure Limits

Name of agent Isopentane

Eight hours mg/m3 3000 mg/m³

Eight hours ppm 1000 ppm

Regulatory reference Factories (Control of Chemical Agents at Work) Regulations 2003 (LN. 2018/181)


Local name Ισοπεντάνιο




07.11.2019 (Version: 1.0)

EN (English) 17/32




Local name IZOPENTÁN


Megjegyzések (HU) EU2 (2006/15/EK irányelvben közölt érték)



Local name iso-Pentane


Notes (IE) IOELV (Indicative Occupational Exposure Limit Values)


Italy - Occupational Exposure Limits

Local name Isopentano



Regulatory reference Allegato XXXVIII del D.Lgs. 9 aprile 2008, n. 81 e s.m.i.


Local name Izopentāns





Local name Izopentanas

IPRV (mg/m³) 3000 mg/m³

IPRV (ppm) 1000 ppm


Luxembourg - Occupational Exposure Limits




Regulatory reference Mémorial A Nº 684 de 2018

Malta - Occupational Exposure Limits




Regulatory reference S.L.424.24 (L.N.57 of 2018)


Local name Isopentaan

Grenswaarde TGG 8H (mg/m³) 1800 mg/m³



Local name Izopentan (metylobutan)




07.11.2019 (Version: 1.0)

EN (English) 18/32



Local name Pentano , todos os isómeros




Local name 2- metil butan/Izopentan





Local name Metylbután (izopentán)



Regulatory reference Nariadenie vlády č. 33/2018 Z.z.


Local name izopentan (metilbutan)





Remark (SI) EU



Local name Isopentano (Metilbutano)


VLA-ED (ppm) 1000 ppm

Notes VLI (Agente químico para el que la U.E. estableció en su día un valor límite indicativo).



Local name iso-Pentan

nivågränsvärde (NVG) (mg/m³) 1800 mg/m³

nivågränsvärde (NVG) (ppm) 600 ppm



Anmärkning (SE) V (Vägledande korttidsgränsvärde ska användas som ett rekommenderat högsta värde som inte bör överskridas)








Local name Ísópentan



07.11.2019 (Version: 1.0)

EN (English) 19/32





Local name Isopentan



Merknader (NO) E (EU har en veiledende grenseverdi for stoffet)



Local name Pentane (tous les isomères) / Pentan (alle Isomere)


MAK (ppm) 600 ppm


KZGW (ppm) 1200 ppm

Critical toxicity SNP / PNS

Notation SSC / SSC

Remark NIOSH



Local name İzopentan




benzene (71-43-2)


Local name Benzene

IOELV TWA (mg/m³) 3,25 mg/m³


Notes Skin (Substantial contribution to the total body burden via dermal exposure possible)

Regulatory reference DIRECTIVE (EU) 2019/130 (amending Directive 2004/37/EC)


Local name Benzol

MAK (mg/m³) 3,2 mg/m³

MAK (ppm) 1 ppm

MAK Short time value (mg/m³) 12,8 mg/m³


Remark (AT) H



Local name Benzène # Benzeen

Limit value (mg/m³) 3,25 mg/m³



07.11.2019 (Version: 1.0)

EN (English) 20/32

benzene (71-43-2)

Remark (BE) C: la mention “C” signifie que l’agent en question relève du champ d’application du titre 2 relatif aux agents cancérigènes, mutagènes et reprotoiques du livre VI du code de bien-être au travail, D: la mention “D” signifie que la résorption de l’agent, via la peau, les muqueuses ou les yeux, constitue une partie importante de l’exposition totale. Cette résorption peut se faire tant par contact direct que par présence de l’agent dans l’air. # C: de vermelding “C” betekent dat het betrokken agens valt onder het toepassingsgebied van titel 2 betreffende kankerverwekkende, mutagene en reprotoxische agentia van boek VI van de codex over het welzijn op het werk, D: de vermelding “D” betekent dat de opname van het agens via de huid, de slijmvliezen of de ogen een belangrijk deel van de totale blootstelling vormt. Deze opname kan het gevolg zijn van zowel direct contact als zijn aanwezigheid in de lucht.



Local name Бензен

OEL TWA (mg/m³) 3,25 mg/m³

Notes Кожа (възможна е значителна резорбция чрез кожата); • (Химични агенти, за които са определени гранични стойности във въздуха на работната среда за Европейската общност)


Bulgaria - Biological limit values

Local name Бензен

Bulgaria - BLV 2 mg/l Parameter: Trans, trans-Muconic acid - Medium: urine - Sampling time: at the end of exposure or end of work shift (possible significant absorption through the skin) 0,045 mg/g creatinine Parameter: S-Phenyl Mercapturic acid - Medium: urine - Sampling time: at the end of exposure or end of work shift (possible significant absorption through the skin)



Local name Benzen

GVI (granična vrijednost izloženosti) (mg/m³) 3,25 mg/m³


Naznake (HR) Direktiva: 2017/2398. Napomena: Koža (razvrstana kao tvar koja nadražuje kožu (H315)), Karc 1A, Muta 1B

OEL chemical category (HR) Carcinogen Category 1A, Skin notation, Mutagen Category 1B


Croatia - Biological limit values

Croatia - BLV 28 μg/l Parameter: Benzene - Medium: blood - Sampling time: right at the end of the work shift 46 µg/g creatinine Parameter: S-Phenylmercapturic acid - Medium: urine - Sampling time: at the end of the work shift (calculated on the average Creatinine value of 1.2 g/L urine)


Local name Benzen


Expoziční limity (PEL) (ppm) 0,94 ppm

Expoziční limity (NPK-P) (mg/m³) 10 mg/m³

Expoziční limity (NPK-P) (ppm) 3,1 ppm

Remark (CZ) D (při expozici se významně uplatňuje pronikání látky kůží), I (dráždí sliznice (oči, dýchací cesty) resp. kůži), P (u látky nelze vyloučit závažné pozdní účinky)



07.11.2019 (Version: 1.0)

EN (English) 21/32

benzene (71-43-2)

Czech Republic - Biological limit values

Czech Republic - BLV 0,024 µmol/mmol Creatinine Parameter: S-Phenylmercapturic acid - Medium: urine - Sampling time: end of shift 0,05 mg/g creatinine Parameter: S-Phenylmercapturic acid - Medium: urine - Sampling time: end of shift 1,2 µmol/mmol Creatinine Parameter: trans,trans-Muconic acid - Medium: urine - Sampling time: end of shift 1,5 mg/g creatinine Parameter: trans,trans-Muconic acid - Medium: urine - Sampling time: end of shift


Local name Benzen

Grænseværdie (langvarig) (mg/m³) 1,6 mg/m³

Grænseværdie (langvarig) (ppm) 0,5 ppm

Anmærkninger (DK) E (betyder, at stoffet har en EF-grænseværdi); H (betyder, at stoffet kan optages gennem huden); K (betyder, at stoffet anses for at kunne være kræftfremkaldende)

OEL chemical category (DK) Potential for cutaneous absorption



Local name Benseen


OEL TWA (ppm) 0,5 ppm



Remark (ET) A (Naha kaudu kergesti absorbeeruvad ained), C (Kantserogeensed ained)



Local name Bentseeni

HTP-arvo (8h) (mg/m³) 3,25 mg/m³


Huomautus (FI) iho, Valtioneuvosto on työturvallisuuslain nojalla antamissaan päätöksissä ja asetuksissa määrännyt työpaikan ilman epäpuhtauksille joukon sitovia raja-arvoja. Soveltamisala: Kaikki työt. Viite: Valtioneuvoston asetus työhön liittyvän syöpävaaran torjunnasta (716/2000), Bentseeni voi imeytyä elimistöön hengitysteitse, ihon kautta tai nieltynä. Se saattaa aiheuttaa syöpää. Bentseeni saattaa aiheuttaa myös perimävaurioita, joten siihen tulee suhtautua siten kuin se aiheuttaisi periytyviä mutaatioita ihmisen sukusoluissa. Se vahingoittaa elimiä a voi tappaa nieltynä ja joutuessaan iholle. Lisäksi se ärsyttää silmiä ja ihoa. Haju ei varoita terveysvaarasta.



Local name Benzène

VME (mg/m³) 3,25 mg/m³

VME (ppm) 1 ppm

Note (FR) Valeurs règlementaires contraignantes; substance classée cancérogène de catégorie 1A et mutagène de catégorie 1B; risque de pénétration percutanée

Regulatory reference Article R4412-149 du Code du travail (réf.: INRS ED 984, 2016)

France - Biological limit values

France - BLV 5 mg/l Parameter: Muconic acid - Medium: urine - Sampling time: end of shift


TRGS 910 Local name Benzol

TRGS 910 Acceptable concentration (Volume conc.) 0,06 ppm

TRGS 910 Acceptable concentration (Weight conc.) 0,2 mg/m³


07.11.2019 (Version: 1.0)

EN (English) 22/32

benzene (71-43-2)

TRGS 910 Acceptable concentration notes b) Akzeptanzkonzentration assoziiert mit Risiko 4:10000

TRGS 910 Tolerance concentration (Volume conc.) 0,6 ppm

TRGS 910 Tolerance concentration (Weight conc.) 1,9 mg/m³

TRGS 910 Tolerance concentration excess factor 8

TRGS 910 Remarks H - Hautresorptiv

TRGS 910 Equivalence value for tolerance concentration

5 μg/l 25 µg/g creatinine 500 µg/g creatinine

TRGS 910 Equivalence value for acceptable concentration

0,8 μg/l 3 µg/g creatinine

TRGS 910 Parameter Benzol S-Phenylmerkaptursäure Trans, trans-Muconsäure

TRGS 910 Testing material U - Urin

TRGS 910 Testing time b - Expositionsende bzw. Schichtende

TRGS 910 Regulatory reference TRGS 910


Local name Βενζόλιο


OEL TWA (ppm) 1 ppm



Local name BENZOL

MK-érték 3 mg/m³

Megjegyzések (HU) k (rákkeltő), b (Bőrön át is felszívódik), i (ingerlő anyag, amely izgatja a bőrt, nyálkahártyát, szemet vagy mindhármat); EU99 (99/38/EK irányelvben közölt érték), BEM (biológiai expozíciós mutató)



Local name Benzene



OEL (15 min ref) (mg/m3) 9 mg/m³ (calculated)

OEL (15 min ref) (ppm) 3 ppm (calculated)

Notes (IE) BOELV (Binding Occupational Exposure Limit Values), Sk (Substances which have the capacity to penetrate intact skin when they come in contact with it, and be absorbed into the body), Carc.1A (Substances known to have carcinogenic potential for humans), Muta.1B (Substances which should be regarded as if they induce heritable mutations in the germ cells of humans)



Local name Benzols


OEL TWA (ppm) 1 ppm


Latvia - Biological limit values

Latvia - BLV 25 µg/g creatinine Parameter: Phenol - Medium: urine - Sampling time: end of shift


Local name Benzenas (benzolas)


07.11.2019 (Version: 1.0)

EN (English) 23/32

benzene (71-43-2)

IPRV (mg/m³) 3,25 mg/m³

IPRV (ppm) 1 ppm

TPRV (mg/m³) 19 mg/m³

TPRV (ppm) 6 ppm

Remark (LT) K (kancerogeninis poveikis); M (mutageninis poveikis); O (medžiaga į organizmą gali prasiskverbti pro nepažeistą odą)



Local name Benzeen

Grenswaarde TGG 8H (mg/m³) 3,25 mg/m³

Remark (MAC) H (Huidopname) Stoffen die relatief gemakkelijk door de huid kunnen worden opgenomen, hetgeen een substantiële bijdrage kan betekenen aan de totale inwendige blootstelling, hebben in de lijst een H-aanduiding. Bij deze stoffen moeten naast maatregelen tegen inademing ook adequate maatregelen ter voorkoming van huidcontact worden genomen.

MAC chemical category Skin notation



Local name Benzen

NDS (mg/m³) 1,6 mg/m³

Remark (PL) Skóra (Oznakowanie substancji notacją „skóra” oznacza, że wchłanianie substancji przez skórę może być tak samo istotne jak przy narażeniu drogą oddechową)



Local name Benzeno

OEL TWA (ppm) 0,5 ppm

OEL STEL (ppm) 2,5 ppm



Local name Benzen


OEL TWA (ppm) 1 ppm


Romania - Biological limit values

Romania - BLV 25 µg/g creatinine Parameter: S-Phenylmercapturic acid - Medium: urine - Sampling time: end of shift 500 µg/g creatinine Parameter: Trans, trans-muconic acid - Medium: urine - Sampling time: end of shift 50 mg/l Parameter: total Phenols - Medium: urine - Sampling time: end of shift


Local name benzén


NPHV (priemerná) (ppm) 3,25 ppm

Upozornenie (SK) Kategória karcinogénov 1A – Dokázaný karcinogén pre ľudí; Kategória karcinogénov 1B – Mutagén cicavčích zárodočných buniek; Prienik cez pokožku (Niektoré látky môžu prenikať ľahko cez pokožku a spôsobovať smrteľné otravy často bez varovných príznakov)



Local name Benceno


07.11.2019 (Version: 1.0)

EN (English) 24/32

benzene (71-43-2)

VLA-ED (mg/m³) 3,25 mg/m³

VLA-ED (ppm) 1 ppm

Notes C1A (Carcinógeno para el hombre), M1B (Sustancias de las que se considera que inducen mutaciones hereditarias en las células germinales humanas), vía dérmica (Indica que, en las exposiciones a esta sustancia, la aportación por la vía cutánea puede resultar significativa para el contenido corporal total si no se adoptan medidas para prevenir la absorción. En estas situaciones, es aconsejable la utilización del control biológico para poder cuantificar la cantidad global absorbida del contaminante), VLB® (Agente químico que tiene Valor Límite Biológico), v (Real Decreto 1124/2000, de 16 de junio (BOE nº 145 de 17 de junio de 2000), por el que se modifica el Real Decreto 665/1997, de 12 de mayo, sobre la protección de los trabajadores contra los riesgos relacionados con la exposición a agentes cancerígenos durante el trabajo), r (Esta sustancia tiene establecidas restricciones a la fabricación, la comercialización o el uso en los términos especificados en el “Reglamento (CE) nº 1907/2006 sobre Registro, Evaluación, Autorización y Restricción de sustancias y preparados químicos” (REACH) de 18 de diciembre de 2006 (DOUE L 369 de 30 de diciembre de 2006). Las restricciones de una sustancia pueden aplicarse a todos los usos o sólo a usos concretos. El anexo XVII del Reglamento REACH contiene la lista de todas las sustancias restringidas y especifica los usos que se han restringido).


Spain - Biological limit values

Local name Benceno

Spain - BLV 0,045 mg/g creatinine Parameter: S-Phenyl mercapturic acid - Medium: urine - Sampling time: end of exposure or end of shift 2 mg/l Parameter: trans, trans-Muconic acid - Medium: urine - Sampling time: end of exposure or end of shift



Local name Bensen

nivågränsvärde (NVG) (mg/m³) 1,5 mg/m³

nivågränsvärde (NVG) (ppm) 0,5 ppm



Anmärkning (SE) C (Ämnet är cancerframkallande. Risk för cancer finns även vid annan exponering än via inandning. För vissa cancerframkallande ämnen som inte har gränsvärden gäller förbud eller tillståndskrav enligt föreskrifterna om kemiska arbetsmiljörisker); H (Ämnet kan lätt upptas genom huden. Det föreskrivna gränsvärdet bedöms ge tillräckligt skydd endast under förutsättning att huden är skyddad mot exponering för ämnet ifråga)



Local name Benzene

WEL TWA (mg/m³) 3,25 mg/m³

WEL TWA (ppm) 1 ppm

Remark (WEL) Carc (Capable of causing cancer and/or heritable genetic damage), Sk (Can be absorbed through the skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity)



Local name Bensen

OEL (8 hours ref) (mg/m³) 1,6 mg/m³

OEL (8 hours ref) (ppm) 0,5 ppm

Notes (IS) H (efnið getur auðveldlega borist inn í líkamann gegnum húð), K (efnið er krabbameinsvaldandi)



07.11.2019 (Version: 1.0)

EN (English) 25/32

benzene (71-43-2)


Local name Benzen




Grenseverdier (Korttidsverdi) (ppm) 2 ppm (value calculated)

Merknader (NO) G (EU har fastsatt en bindende grenseverdi for stoffet); H (Kjemikalier som kan tas opp gjennom huden); K (Kjemikalier som skal betraktes som kreftfremkallende)

OEL chemical category (NO) Carcinogen, Skin notation



Local name Benzène / Benzol

MAK (mg/m³) 1,6 mg/m³

MAK (ppm) 0,5 ppm

Critical toxicity Leucémie / Leukämie

Notation R, C1A, M1B, B / H, C1A, M1B, B

Remark HSE, NIOSH, DFG, BG

OEL chemical category (CH) Category C1A carcinogen, Category 1B mutagen, Skin notation


Switzerland - Biological limit values

Switzerland - BLV 25 µg/g creatinine Parameter: S-Phenyl-mercapturic acid - Medium: urine - Sampling time: end of shift 500 µg/g creatinine Parameter: t,t-Muconic acid - Medium: urine - Sampling time: end of shift


Local name Benzen


OEL TWA (ppm) 1 ppm

Comments Deri

OEL chemical category (TR) Skin notation regulation on health and safety measures involving carcinogenic and mutagenic substances at workplaces


isobutane (75-28-5)


Local name Butan (beide Isomeren): Isobutan (R 600a)


MAK (ppm) 800 ppm





Local name Butane, tous isomères: iso-butane # Butaan, alle isomeren: iso-butaan





07.11.2019 (Version: 1.0)

EN (English) 26/32

isobutane (75-28-5)


Local name Isobutaan (2-metüülpropaan)





Local name i-Butaani (2-Metyylipropaani)









VME (ppm) 800 ppm


TRGS 900 Local name Isobutan




TRGS 900 Remark DFG



Local name Butane, all isomers

OEL (15 min ref) (mg/m3) 1000 mg/m³



Local name Butano, todos os isómeros




Local name bután s obsahom ≥ 0,1% butadiénu (n-bután) (izo-bután)



Upozornenie (SK) Kategória karcinogénov 1A – Dokázaný karcinogén pre ľudí



07.11.2019 (Version: 1.0)

EN (English) 27/32

isobutane (75-28-5)


Local name izobutan







Local name iso-Butane / iso-Butan


MAK (ppm) 800 ppm


KZGW (ppm) 3200 ppm

Critical toxicity SNC / ZNS


8.2. Exposure controls

Appropriate engineering controls:

Either local exhaust or general room ventilation is usually required. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Use explosion-proof electrical equipment.

Personal protective equipment:

Gloves. In case of splash hazard: safety glasses. Protective clothing. Insufficient ventilation: wear respiratory protection.

Materials for protective clothing:

Wear chemical resistant protective clothing (EN 14605) and protective shoes (S1P or S3)

Hand protection:

Wear suitable gloves tested to EN 374. NBR (Nitrile rubber). Thickness of the glove material > 0.4 mm. Breakthrough times and swelling properties of the material must be taken into consideration. The breakthrough time of the selected gloves must be greater than the intended use period.

Eye protection:

Chemical goggles or face shield with safety glasses. DIN EN 166

Respiratory protection:

This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used. If excessive exposure exists, use only approved air-purifying or supplied air respirator operated in a positive pressure mode. An approved organic vapour respirator/supplied air or self-contained breathing apparatus must be used when vapour concentration exceeds applicable exposure limits

Personal protective equipment symbol(s):

Environmental exposure controls:

Do not allow uncontrolled discharge of product into the environment;The final disposal of this material should be supervised by a specialist, following applicable environmental legislation.

Other information:

Handle in accordance with good industrial hygiene and safety procedures.


07.11.2019 (Version: 1.0)

EN (English) 28/32

SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid

Colour : Black. brown.

Odour : Hydrocarbon-like.

Odour threshold : No data available

pH : No data available

Relative evaporation rate (butylacetate=1) : No data available

Melting point : < -3 °C (Pour point) ; ASTMD5853

Freezing point : No data available

Boiling point : > -42 °C IP601

Flash point : < 30 °C IP34

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapour pressure : No data available

Relative vapour density at 20 °C : No data available

Relative density : No data available

Density : 0,829 @ 15°C - IP365

Solubility : No data available

Log Pow : No data available

Viscosity, kinematic : 3,064 mm²/s @40°C (IP71)

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidising properties : Not oxidizing.

Explosive limits : No data available

9.2. Other information No additional information available

SECTION 10: Stability and reactivity 10.1. Reactivity Stable under normal conditions.

10.2. Chemical stability Stable at room temperature.

10.3. Possibility of hazardous reactions Hazardous polymerization will not occur.

10.4. Conditions to avoid Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

10.5. Incompatible materials Strong oxidizing agents.

10.6. Hazardous decomposition products On burning: release of (highly) toxic gases/vapours.

SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity (oral) : Not classified

Acute toxicity (dermal) : Not classified

Acute toxicity (inhalation) : Not classified

Skin corrosion/irritation : Not classified

Serious eye damage/irritation : Not classified

Respiratory or skin sensitisation : Not classified

Germ cell mutagenicity : May cause genetic defects.

Carcinogenicity : May cause cancer.

Reproductive toxicity : Not classified

STOT-single exposure : Not classified

STOT-repeated exposure : Not classified

Aspiration hazard : May be fatal if swallowed and enters airways.


07.11.2019 (Version: 1.0)

EN (English) 29/32

Brent Crude Oil (8002-05-9)

Viscosity, kinematic 3,064 mm²/s @40°C (IP71)

SECTION 12: Ecological information 12.1. Toxicity Hazardous to the aquatic environment, short-term (acute)

: Not classified

Hazardous to the aquatic environment, long-term (chronic)

: Not classified

12.2. Persistence and degradability No additional information available

12.3. Bioaccumulative potential No additional information available

12.4. Mobility in soil No additional information available

12.5. Results of PBT and vPvB assessment No additional information available

12.6. Other adverse effects No additional information available

12.6. Other adverse effects No additional information available

SECTION 13: Disposal considerations 13.1. Waste treatment methods Regional legislation (waste) : Dispose of this material and its container to hazardous or special waste collection point.

Dispose of contents/container to comply with applicable local, national and international regulations.

Waste treatment methods : Dispose of contents/container to industrial incineration plant.

Product/Packaging disposal recommendations : Burn in an approved incinerator or dispose of in approved chemical landfill in accordance with all applicable local, state and federal laws and regulations.

European List of Waste (LoW) code : 05 01 00 - wastes from petroleum refining

SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN

ADR IMDG IATA ADN RID

14.1. UN number

UN 1267 UN 1267 UN 1267 UN 1267 UN 1267

14.2. UN proper shipping name

PETROLEUM; CRUDE OIL PETROLEUM; CRUDE OIL Petroleum; Crude oil PETROLEUM; CRUDE OIL PETROLEUM; CRUDE OIL

Transport document description

UN 1267 PETROLEUM; CRUDE OIL, 3, I, (D/E)

UN 1267 PETROLEUM; CRUDE OIL, 3, I

UN 1267 Petroleum; Crude oil, 3, I



14.3. Transport hazard class(es)

3 3 3 3 3

14.4. Packing group

I I I I I

14.5. Environmental hazards

Dangerous for the environment : No


Marine pollutant : No




No supplementary information available


07.11.2019 (Version: 1.0)

EN (English) 30/32

14.6. Special precautions for user

Overland transport

Classification code (ADR) : F1

Special provisions (ADR) : 357

Limited quantities (ADR) : 500ml

Excepted quantities (ADR) : E3

Packing instructions (ADR) : P001

Mixed packing provisions (ADR) : MP7, MP17

Portable tank and bulk container instructions (ADR)

: T11

Portable tank and bulk container special provisions (ADR)

: TP1, TP8

Tank code (ADR) : L4BN

Vehicle for tank carriage : FL

Transport category (ADR) : 1

Special provisions for carriage - Operation (ADR) : S2, S20

Hazard identification number (Kemler No.) : 33

Orange plates :

Tunnel restriction code (ADR) : D/E

EAC code : 3WE

APP code : A(fl)

Transport by sea

Special provisions (IMDG) : 357

Limited quantities (IMDG) : 500 ml

Excepted quantities (IMDG) : E3

Packing instructions (IMDG) : P001

Tank instructions (IMDG) : T11

Tank special provisions (IMDG) : TP1, TP8

EmS-No. (Fire) : F-E

EmS-No. (Spillage) : S-E

Stowage category (IMDG) : E

Properties and observations (IMDG) : Immiscible with water.

MFAG-No : 128

Air transport

PCA Excepted quantities (IATA) : E3

PCA Limited quantities (IATA) : Forbidden

PCA limited quantity max net quantity (IATA) : Forbidden

PCA packing instructions (IATA) : 351

PCA max net quantity (IATA) : 1L

CAO packing instructions (IATA) : 361

CAO max net quantity (IATA) : 30L

Special provisions (IATA) : A3, A177

ERG code (IATA) : 3L

Inland waterway transport

Classification code (ADN) : F1

Special provisions (ADN) : 357

Limited quantities (ADN) : 500 ml

Excepted quantities (ADN) : E3

Carriage permitted (ADN) : T

Equipment required (ADN) : PP, EX, A

Ventilation (ADN) : VE01

Number of blue cones/lights (ADN) : 1

Rail transport

Classification code (RID) : F1


07.11.2019 (Version: 1.0)

EN (English) 31/32

Special provisions (RID) : 357

Limited quantities (RID) : 500ml

Excepted quantities (RID) : E3

Packing instructions (RID) : P001

Mixed packing provisions (RID) : MP7, MP17

Portable tank and bulk container instructions (RID) : T11

Portable tank and bulk container special provisions (RID)

: TP1, TP8

Tank codes for RID tanks (RID) : L4BN

Transport category (RID) : 1

Hazard identification number (RID) : 33

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable

SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1. EU-Regulations

No REACH Annex XVII restrictions

Petroleum; Crude oil is not on the REACH Candidate List Petroleum; Crude oil is not on the REACH Annex XIV List Petroleum; Crude oil is not subject to REGULATION (EU) No 649/2012 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 4 July

2012 concerning the export and import of hazardous chemicals.

Petroleum; Crude oil is not subject to Regulation (EU) No 2019/1021 of the European Parliament and of the Council of 20 June 2019 on persistent

organic pollutants

Directive 2012/18/EU (SEVESO III)

Seveso Additional information : No

15.1.2. National regulations

Germany

Reference to AwSV : Water hazard class (WGK) 3, Highly hazardous to water (Classification according to AwSV; ID No. 1937)

12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV

: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)

Netherlands

SZW-lijst van kankerverwekkende stoffen : Petroleum; Crude oil is listed

SZW-lijst van mutagene stoffen : Petroleum; Crude oil is listed

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Borstvoeding

: The substance is not listed

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Vruchtbaarheid


NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Ontwikkeling


Denmark

Class for fire hazard : Class II-1

Store unit : 5 liter

Classification remarks : R10 <H224;H304;H340;H350>; Emergency management guidelines for the storage of flammable liquids must be followed

Danish National Regulations : Pregnant/breastfeeding women working with the product must not be in direct contact with the product

The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal

15.2. Chemical safety assessment For this substance a chemical safety assessment has not been carried out

Reason: Exempted from REACH

SECTION 16: Other information

Abbreviations and acronyms:

SDS Safety Data Sheet

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006


07.11.2019 (Version: 1.0)

EN (English) 32/32

OECD Organisation for Economic Co-operation and Development

IMDG International Maritime Dangerous Goods

IATA International Air Transport Association

BCF Bioconcentration factor

PBT Persistent Bioaccumulative Toxic

vPvB Very Persistent and Very Bioaccumulative

CAS CAS (Chemical Abstracts Service) number

EC EC - European Community

EEC EEC - European Economic Community

Sources of Key data : Regulation (EC) No 1272/2008 Annex VI.

Other information : It is the user's responsibility to take mentioned precaution measures and ensure that this information is complete and sufficient for the use of this product. Such information is actually to be best of our knowledge and beliefs accurate as reliable.

Full text of H- and EUH-statements:

Aquatic Chronic 2 Hazardous to the aquatic environment — Chronic Hazard, Category 2

Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3

Asp. Tox. 1 Aspiration hazard, Category 1

Carc. 1A Carcinogenicity, Category 1A

Eye Irrit. 2 Serious eye damage/eye irritation, Category 2

Flam. Gas 1 Flammable gases, Category 1

Flam. Liq. 1 Flammable liquids, Category 1

Flam. Liq. 2 Flammable liquids, Category 2

Muta. 1B Germ cell mutagenicity, Category 1B

Press. Gas Gases under pressure

Press. Gas (Liq.) Gases under pressure : Liquefied gas

Skin Irrit. 2 Skin corrosion/irritation, Category 2

STOT RE 1 Specific target organ toxicity — Repeated exposure, Category 1

STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Narcosis

H220 Extremely flammable gas.

H224 Extremely flammable liquid and vapour.

H225 Highly flammable liquid and vapour.

H280 Contains gas under pressure; may explode if heated.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H319 Causes serious eye irritation.

H336 May cause drowsiness or dizziness.

H340 May cause genetic defects.

H350 May cause cancer.

H372 Causes damage to organs through prolonged or repeated exposure.

H411 Toxic to aquatic life with long lasting effects.

H412 Harmful to aquatic life with long lasting effects.

SDS EU (REACH Annex II)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental

requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

Brent Crude Oil - Shetland Islands Council€¦ · EnQuest Annan House Palmerston Road Aberdeen -...

Documents

Transcript of Brent Crude Oil - Shetland Islands Council€¦ · EnQuest Annan House Palmerston Road Aberdeen -...