ATTACHMENT A REVISED QUALITY ASSURANCE MANUAL …ENVIROTECH RESEARCH, INC. 777 New Durham Road...

ATTACHMENT A

REVISED QUALITY ASSURANCE MANUALENVIROTECH RESEARCH, INC.

A.R305I29

ENVIROTECH RESEARCH, INC.

777 New Durham RoadEdison, New Jersey 08817Tel: (908) 549-3900Fax: (908) 549-3679

QUALITY ASSURANCE MANUAL


February 1995

AR305I30


Table of Contents

Page

1. Introduction 1

2. Sample Container Preparation and Shipment 2

3. Sample Bottle Control and Cleaning " 51

4. Chain of Custody Procedures . 54

5. Procedures for Sample Receipt. Log In and Mitigation ofLaboratory Contamination 66

6. Preparation, Purity and Storage of Reagents and Standards 76

7. Preventive Maintenance and Calibration Procedures for allAnalytical Instruments and Ancillary Equipment 79

8. Analytical Methodology 83

9. Procedures for Experimentally Determined Method DetectionLimits and Precision and Accuracy Data 92

10. Statistical Quality Control 96

11. Procedure for Internal QA Inspection and Corrective Action 100

12. Procedure for Data Management and Handling 132

13. Document Control Procedures 138

14. Laboratory Certification 141

15. Floor Plan, Major Instrumentation and Computing Capabilities 160

AE305I3I


Introduction

The purpose of this manual is to establish quality assurance program criteria andprocedures for Envirotech Research, Inc. This quality assurance program is designed to meet orexceed all routine regulatory quality assurance requirements for environmental analyses and toprovide analytical results of the highest accuracy and precision.

Envirotech Research, Inc. provides analytical testing of environmental water, soil andwaste samples for a variety of clients ranging from small businesses to Fortune 100 companiesand government agencies. Our goal, from the company's inception, has been to be thelaboratory of choice in New Jersey and the surrounding region known first and foremost for thequality of the data we produce and the service we provide. The commitment of EnvirotechResearch, Inc. to production of the highest quality data is reflected by our investment in the bestavailable analytical instrumentation. Envirotech Research performs testing of a full array ofsample matrices for a wide variety of organic chemicals, trace metals and conventional indicatorsof environmental quality.

The central concern in all aspects of sample analysis by Envirotech Research is strictadherence to quality assurance and quality control procedures, insuring data that will meet theneeds of our clients.—The-quality-nof -analytical -results are msured through a variety ofmechanisms Jncluding--use--ofJEPA_published-protocols-and other accepted authoritativemethodologies. _ __ _ _ ______„__„..____,„.„ „ . ,_...

Environmental testing requires strict adherence to method requirements. At Envirotech-Research, Inc; we have -successfully- applied fundamental quality assurance principles toenvironmental Jesting. ..Our.chemists are instructed to-understand analytical requirements andtake corrective action the instant any method non-conforrnance occurs. This principle of "doingit right the first time" not only ensures a work product free of non-conformance but actuallyhelps boost productivity/The apparent "cost" of stopping analyses periodically is faroutweighed by the "benefit" of providing conforming data.

Envirotech Research's Quality Assurance Manual spells out specific requirements forprocedures that are applied throughout our laboratory. In addition, our analytical StandardOperating Procedures (SOPs) document in great detail our procedures for each of the analyticalmethods performed at our laboratory. These analytical SOPs, consisting of thousands of pages,supplement our Quality Assurance Manual and will be provided as required on a project specificbasis.

A more detailed discussion of the quality assurance and quality control proceduresutilized by Envirotech Research, Inc. is provided in the following pages.

AR305I32


ENVIROTECH RESEARCH SOP No. S101.1STANDARD OPERATING PROCEDURE

FOR SAMPLE CONTAINER PREPARATION AND SHIPMENT

doc: S101Revision:

AR305I33


1. SCOPE and APPLICATION

1.1. The procedures outlined below are to be followed for preparing sample shipmentcontainers.

1.2. Included in this procedure are the requirements for producing Field Blanks andTrip Blanks.

1.3. The procedure is applicable for commercial clients and government contracts forcontainers being picked up or shipped via an overnight courier.

2. APPARATUS

2.1. Level II precleaned Sample bottles

2.2. Sample coolers

2.3. Ice bags

2.4. Preservation Reagents

2.5. Chain of Custody Documents, Custody Seals, Sample container labels, Hazardous.contents labels

3. PROCEDURES

3.1. A request for bottle order form, Attachment 1 is initiated by marketing. Itspecifies the client, anticipated date of sampling, number of samples to be takenby matrix, the required methodology and any required QA/QC including Fieldand Trip Blanks or other project specific requirements.

3.2. The Sample Custody Officer or his assistant will prepare the bottle order eitherthe day before or the day of anticipated sampling. Attachment 2, taken from theNJDEPE "Field Sampling Procedures Manual, May 1992" is referenced todetermine the proper bottle type and preseverative for the methodology requested.A chart that describes containers for Task Trip and Field blanks is given inAttachment 3. Footnotes from Attachment 2 also apply to Attachment 3.

NOTE: CLP Statement of Work references: The USEPA Contract LaboratoryProgram (CLP) Statement of Work (SOW) references have been removed fromthe Attachment I referenced above. Envirotech Research will specify the SOW tobe used as required by ag.,Qverseeing Government Agency or that which has beenproposed in a site specific QA Project Plan.

AR3Q5I31*

*>'<5>,ENVIROTECH RESEARCH, INC. *$"

3.3. The Sample Custody Officer or his assistant retrieves the appropriate glasswarefrom the stock room. The bottles with the oldest date of receipt tag on them arealways used first. The number of bottles required, taking into account the projectQA/QC requirements are taken and staged on the bottle preparation bench and theappropriate preservative is added in accordance with Attachment 2.

3.4. A Hazardous contents label is affixed to each bottle spiked with a preservative thatidentifies the preservative and its CAS number. Additionally, the top of the bottleis marked with the preservative and the analytical parameter the bottle is toreceive.

3.5. A bottle is filled with water and marked "Temperature Monitor Bottle". Itaccompanies the sample bottles and is used to record the temperature of theincoming samples in accordance with Envirotech Research SOP No. SI03.

3.6. PREPARATION OF FIELD and TRIP BLANKS

3.6.1. For projects which require a field blank, the Sample Custody Officer or hisassistant determines the required parameters from the request for bottleorder form and prepares the bottles as if the field blank were an aqueousenvironmental sample as outlined above.

3.6.2. Additionally, another identical set of bottles are retrieved and notpreserved. These bottles are filled with the analyte free laboratory waterused for method blanks. They are not preserved. The bottles are labeledwith the preprinted label that identifies the bottle's use as water for creationof the field blank. The analytical parameter is filled in on the label and thedate the lab water added is written on the label.

3.6.3. For projects which require a Trip Blank, the Sample Custody Officer or hisassistant will preserve two 40 ml VOA vials with four drops ofconcentrated HC1 and fill with analyte free water. A Hazardous contentslabel is affixed to each vial. Care must be taken to eliminate any air bubbleswhen filling and sealing the vials. An Envirotech Research sample label isfilled out, noting the date and time prepared and the preparers signature.

AR305 I 35


3.6.4. The Field and Trip Blanks accompany the environmental sampling bottlesto the site and back to the laboratory.

3.7, All the required bottleware, including the blanks and the Temperature MonitorBottle are placed hi a sufficient number of coolers. Do not stack bottles on top ofeach other.

3.8. For each cooler packed, two or more bags of ice are placed on top of the samplecontainers. After sampling, the ice is removed from the bags and poured over thesamples.

3.9. Use one custody seal for each cooler. Record the number on the Chain of Custodydocument

3.10. SAMPLE CONTAINER DELIVERY

3.10.1. For containers being picked up by the samplers, sign the custody over tothem upon their arrival to the laboratory after going over the contents withthem in accordance with ETR SOP No. S100. Proceed to step 3.11.

3.10.2. For containers being shipped by overnight courier, proceed with steps 3.11and 3.12. Then fill out an air bill for each cooler and have it picked up bythe overnight carrier. Retain the shipping receipt to document its delivery.This information will be included with the sampling documents when thesamples are returned to the laboratory.

3.11. Place sample Chain of Custody documents, extra cooler custody seals and samplelabels in a zip lock bag and tape it to the inside cover of the cooler.

3.12. Seal each cooler with a Custody Seal.

AR305136


777 New Durham RoadEdison, New Jersey 08817Tel: (908) 549-3900Fax: (908) 549-3679

ATTACHMENT 1Laboratory Service Request Form

Client: ___________________ Date Of Request: ________Project Name: ______________Project Manager: ______________ Deliverables Required: D ReducedAddress:_________________ 2 Fu»

D Other:Phone/Fax:Turnaround Request: Type of Testjng Program:

D Standard (34 weeks) D NjpDES(600Series/40CFR136)U 2 Week Rush (Surcharge Approved) p SW-846D 1 Week Rush (Surcharge Approved) Q CLPD 24 Hour (PHC's only) (Surcharge Approved) D RCRA Waste ClassificationD Wm:——————————————————— D Drinking Water (500 Series)

D Other: ___________

Sampling Containers Required# of Samples Matrix

-

Parameters Requested

D Field Blanks: D Trio Blanks:Special Instructions:

d Container Pick-up at Laboratory; or d Delivery d Sample Delivery to Laboratory: or d PickupDate/Time: Date/Time:Location: Location:

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AR305I71*43

FOOTNOTES

P = Plastic, hard or soft G «• Glass, hard or soft

Discard bottles which have chips, cracks and etched surfaces.Bottle closures must be water tight. Microbiological samplecontainers must resist sterilization and solvent action of water.Sterilization must not produce toxic materials or .bacteriostaticor nutritive compounds. Presterilized plastic bags can be used fordrinking water total coliform samples.

•= Sodium thiosulfate

HC1 * Hydrochloric acidCl2 = Chlorine

EDTA = Ethylenediaminetetraacetic acid tetrasodium salt

NaOH = Sodium hydroxide

neutralized formalin = 100% neutralized formalin with sodiumtetraborate to pH 7.0-7.3

USEPA Statement of Work for Sample Container Repository, 4/85,Attachment A

4. Detergent wash. Tap water rinse. Distilled water rinse. Air dry.Heat in oven at 105 degrees Celsius for one hour. Cool in areafree of organics.

5. SW-846, 3rd edition, Volume 1-B, Section 4.1.4

6. Sample container cleaning procedure not specified

7. Washed. Rinse with extraction solvent (Chlorofluorocarbon 113).

8. Detergent, hot water wash. Hot tap water rinse. Rinse three timeswith distilled and deionized (ASTM Type II) water (non-toxictubing material). Cover tops and necks of glass closure bottleswith aluminum foil or heavy craft paper. Sterilize in autoclave at121 degrees Celsius for 15 minutes or in hot air oven at 170degrees Celsius for two hours.

9. Detergent and tap water wash. 1:1 HNOs rinse. Tap water rinse.Distilled and deionized (ASTM Type II) water rinse. (Additionaloption: Chromic acid or NOCHROMIX rinse, thorough Distilled anddeionized (ASTM Type II) water rinse to remove all traces ofchromium. Do not use on plastic bottles.)

Chromium cleaning solution. Detergent wash, hot. Tap water rinse.Distilled water rinse. Drain dry. Muffle furnace, 400 degreesCelsius C 15-30 minutes. Seal and store free from dust.

A&305I7544

11. Detergent wash, hot. Hot tap water rinse. Drain dry. Mufflefurnace at 400 degrees Celsius for 15-30 minutes. Acetone rinsefollowed by hexane rinse may be substituted for muffle furnace.Store inverted or capped with foil.

12. Sample container volume is not specified in methodology. Volume isrecommended by KJDEPE-Bureau of Environmental Measurements andQuality Assurance. •

13. Washed, rinsed with acetone or methylene chloride and dried beforeuse.

14. Detergent wash, hot. Tap water rinse. Distilled and deionized(ASTM Type II) water rinse. Drain dry. Oven or muffle furnace at400 degrees Celsius for 1 hour. Acetone rinse may be substitutedfor heating. Store inverted or capped with foil in cleanenvironment.

15. Detergent wash, hot tap water rinse. Drain dry. Oven or mufflefurnace at 400 degrees Celsius for one hour. Acetone rinse. Storeinverted or capped with foil in a clean environment.

16. Detergent wash, tap water, distilled water or solvent rinse, aiirdry (where appropriate) in an oven.

17. Rinse with last solvent used. Detergent wash, hot. Tap waterrinse. Reagent water rinse. Drain dry. Oven or muffle furnace at450 degrees Celsius for 1 hour. Acetone rinse may be substitutedfor heating. Store inverted or aluminum foil capped in cleanenvironment.

18. Detergent wash, rinse with tap and distilled water, dry at 105degrees Celsius for 1 hour before use.

19. Detergent wash, distilled water rinse. Optional treatment withhydrochloric acid (1+9).

20. Warm detergent solution wash, thorough r,inse in tap and distilledwater.

21. Optionally, all samples may be tested with lead acetate paperbefore pH adjustment in order to determine if sulfide is present.If sulfide is present, it can be removed by the addition ofcadmium nitrate powder until a negative spot test is obtained. Thesample is filtered and the NaOH is added to pH>12.

22. Samples should be filtered immediately on site before addingpreservative for dissolved metals.

23. Thoroughly rinse with last solvent used. Hot water and detergeijBwash, thorough rinsing with dilute acid, tap and reagent water.Drain dry. Heat in oven or muffle furnace at 400 degrees Celsiusfor 1 hour. Thorough rinsing with acetone may be substituted for

Ar a AR30517645

heating. Seal and store in clean environment. Store inverted orcapped with aluminum foil.

24. Rinse with water or last solvent used. Detergent wash, tap rinse,redistilled acetone rinse, pesticide quality hexane rinse. Heat inmuffle furnace at 400-500 degrees Celsius for ^30 minutes toovernight. Store inverted or cover with aluminum foil.

25. Detergent wash, rinse in dilute HC1 and then distilled water.Rinse with redistilled acetone rinse, pesticide quality hexanerinse. Heat in muffle furnace at 400-500 degrees Celsius for 30minutes to overnight. Store inverted or cover with aluminum foil.

26. If HNOs cannot be used because of shipping restrictions, samplesmay be inititally preserved by icing and immediately shipping tothe laboratory. Upon receipt in the laboratory, the sample must beacidified with cone. HNOs to pH<2. At time of analysis, samplecontainer should be thoroughly rinsed with 1:1 HNOs; washingsshould be added to sample.

27. Cleaning of all chambers and equipment shall be in accordance withthe following procedures:As soon after breaking down a test as is practical, rinse withacetone to remove organic compounds and then rinse twice withlaboratory grade freshwater; and secondly, soak and wash with awarm synthetic detergent/laboratory grade freshwater solution, andthen rinse with 50 degrees Celsius or warmer laboratory gradewater; and

Finally, rinse with a fresh 5% hydrochloric or nitric acidsolution, for the removal of metals and bases, and then rinseagain with 50 degrees Celsius or warmer laboratory gradefreshwater.

28. NJDEPE recommended holding time for sample extraction andanalysis.

29. No test; calculated as total Kjeldahl Nitrogen minus AmmoniaNitrogen

30. Proposed under Safe Drinking Water Act - size of communitydependent.

31. CFR 141 is under final rule to change from CFR 143.

t32. Evidence indicates that some aromatic compounds, notably benzene,

toluene and ethylbenzene are succeptble to rapid biodegradationunder certain environmental conditions. Refrigeration alone maynot be adequate to preserve these compounds in wastewaters formore than seven days. For this reason, a separate sample should becollected, acidified, and analyzed when these aromatics are to bedetermined.

« AR30517746

Attachment 3

SW-846 Methods Trio and Field Blank Requirement's

Sample SampleContainer Maximum Analytical Container

Parameter Volume___Preservation Hold Time* Methodology____Cleaning

Volatile Gvial 4 drops cone, 14 days SW-846,3d 5Organics Teflon lined HC1, coo!4°C edition,

septum Vol 1-B,40ml GC 8010,8015

GC/MS 8240

Semi- Amber G, Cool, 4°C Extraction- SW-846,3d 5Volatile Teflon Lined Dark 7 days edition,Organics Cap Analysis- Vol 1-B,*

1000ml 40 days GC/MS 8270fromextraction

Organo- As Above As Above As Above SW-846,3d 5chlorine edition,Pesticides Vol 1-B,and PCBs GC 8080

Organo- As Above As Above As Above As Above As AbovechlorinePesticides

PCBs As Above As Above As Above As Above As Above

Metals P Bottle, HNOs to 180 days SW-846,3d 9except Hg PCap, pH<2 edition,and Cr+6 P Liner Vol 1-A,

1000ml 7000 series

Hg As Above As Above 28 days As Above 9

• AE30517847

Attachment 3

SW- 846 Methods Trio and Field Blank Requirements


Parameter Volume Preservation Hold Time* Methodology____ Cleaning

Total G, 1000ml Cool,4<>C 7days SW-846,3dPetroleum edition,Hydrocarbons Vol 1-C,

Method 418.1

Holding time begins at time of sample collection

HR305I7948


CLP Methods Trio and Field Blank Requirements

Sample ' SampleContainer Maximum Analytical Container

Parameter Volume___Preservation Hold Time* Methodology____Cleaning

Volatile G, Black Cool,4°C 10 days USEPA-CLP 3Organics phenolic ' Dark Statement of

plastic screw Work forcap teflon- Organiclined septum Analysis40 ml Multi-media

Multi-Concentration(Doc.#OLM03.1)8/94

Semi- Amber G. Cool, 4°C Extraction- As AboveVolatile Teflon Lined Dark ContinuousOrganics Cap liquid-liquid

1000ml extractionmust bestartedwithin 5daysAnalysis-days fromVTSR*

Organo- As Above As Above As Above As AbovechlorinePesticidesand PCBs

Organo- As Above As Above As Above As AbovechlorinePesticides

PCBs As Above As Above As Above As Above

AR30518040

CLP MethodTrip and Field Blank Requirements


Parameter Volume____Preservation Hold Time* Methodology_____Cleaning

Inorganics P Bottle, HNO3 to 180 days USEPA-CLP As Aboveexcept Hg P Cap, pH<2 Statement ofand Cyanide P Liner Work for

1000ml InorganicAnalysisMulti-media

IP Multi-Concentration(DOC#ILM03.O)

Hg As Above As Above 26 days As Above

Validated time of sample receipt (at the laboratory)

Cyanide As Above NaOH to 12 days As Above As AbovepH<2,4°Cuntilanalyzed

AR305I8I

\ENVIROTECH RESEARCH, INC.

ENVIROTECH RESEARCH SOP No. S102STANDARD OPERATING PROCEDURE

TOR SAMPLE BOTTLE CONTROL AND CLEANING

doc: SI02Revision:

AR305I8251



1.1. The following procedure is used to receive precleaned sampling bottles, label thecases and store the bottles in a manner that facilitates using the oldest bottles first(stock rotation).

2. APPARATUS

2.1. Material Receiving Labels

3. PROCEDURE

3.1. All sampling bottles are purchased from a vendor, presently Eagle Picher, whocleans the containers as outlined below.

3.2. The Sample Receipt Login Technician is responsible for ordering bottles andmaintaining the inventory of bottles

3.3. The sampling bottles are cleaned by either Procedure A, B or C. These, procedures are as follows:

3.3.1. Wash Procedure A - used for all glass wide mouth jars and Boston Roundbottles.

3.3.1.LBottles, liners and caps are washed in laboratory grade, non-phosphate detergent.

3.3.1.2.Rinsed three times with distilled water.3.3.1.3.Rinsed with 1:1 nitric acid3.3.1.4.Rinsed three times with ASTM Type 1 organic free water.3.3.1.5.Oven dried for one hour.3.3.1.6.Rinsed with hexane.3.3.1.7.Oven dried for one hour.

3.3.2. Wash Procedure B - used for any bottles to contain samples for volatileorganic analysis.

3.3.2.LBottles, septa and caps are washed in laboratory grade, non-phosphate detergent.

3.3.2.2.Rinsed three times with distilled water.3.3.2.3.Rinsed three times with ASTM Type 1 organic free water.

AH30518352


3.3.2.4.Oven dried for one hour.

3.3.3. Wash Procedure C - used for all high density polyehtylene bottles

3.3.3.LBottles, liners and caps are washed in laboratory grade, non-phosphate detergent.

3.3.3.2.Rinsed three times with distilled water.3.3.3.3 .Rinsed with 1:1 nitric acid3.3.3 ARinsed three times with ASTM Type 1 organic free water.3.3.3.5.Air dried.

3.4. Sample bottles are received in the loading dock area. Every case of bottles islabeled with a tag that bears the date the bottles are received and the individualwho received them.

3.5. The sample bottles'are transported to the sample bottle room which is in anorganic ree-section of-the laboratory.-The-newly received cases of bottles areplaced in the rear of the racks which hold the bottles. The bottles with the oldest

—date of receipt arelnoved to the front of the rack so that they are consumed first.

3.6. With every new shipment of bottles, a bottle is randomly selected for each bottletype received. If a bottle type has potential use for more than one analysis,additional bottles are selected. These bottles are filled with analyte free water

. and are used to create the following days method blank for the analysis for whichthey will be used. If subsequent analysis produces any positive result, the entireshipment of bottle type is removed from inventory and subjected to anothercheck. If this subsequent check confirms the first check, the entire shipment ofbottle type is rejected and returned to the vendor. At no time are bottles to beissued to a client without undergoing this checking procedure.

AR305I81453


ENVIROTECH RESEARCH SOP No. SI00.2STANDARD OPERATING PROCEDURE

FOR MAINTAINING SAMPLE CHAIN OF CUSTODY

doc: SI00.2Revision:

AJR305I8554


1.3. This Chain-.of Custody-procedure is designed to create a written record ofeveryone hrcustody ofthe sample'from jh tijmejbf collection tojts disposal

jample isin:an individual's'"custody" if irfe injuslictual physical possessionor-sight or if it is secured in a restricted area-of limited access.

2. APPARATUS,

Attachment 1,_CustqdySTeaTAttachment 2, Chain of Custody"Attachment 3", Instructions foVChain of Custody ~~~

— -Attachment 4, Common Abbreviations for Laboratory Tests_ _Attachment, 5, Lab-Chronicle__ __ -_ Attachment 6, Internal Custody Record

3. PROCEDURE

3.1. Upon receiving a Request for Bottle Order, the Sample Custody Officer or hisassistant prepares a sample shipment container in accordance with EnvirotechResearch SOP No. SI01 and initiates an Envirotech Research Chain ofCustody document for the contents of the cooler. A Custody Seal is used toseal each cooler. See Attachment 1 for an example Custody Seal.

3.2. The appropriate information is entered on the Envirotech Research Chain ofCustody, including but not limited to container type, number of containers andpreservation reagents. One Chain of Custody form may be used for the entireshipment of containers.

cc AR305I86oo


1.1. The following procedure details all required aspects of maintaining and-executing Chain of Custody control documents for environmental samplesexcept for samples submitted under government contract.

1.2. Analysis requests from NJDEPE for analytical services in accordance with theX-26174 contract requires the use of NJDEPE forms 095 or 096 and NJDEPEform" 077 foFIhtemal Chain of Custody described in Envirotech Research SOP

—NO. sioor


3.3. The Sample Custody Officer or his assistant relinquishes the custody of thesampling container(s) to the sampling team by signing the first "Relinquishedby" box on the bottom of the Chain of Custody document. A member of thesampling team signs the adjacent "Received by" box on the bottom of the formand assumes custody of the container(s).

3.4. Upon return to the laboratory, a member of the sampling team who assumedcustody of the containers relinquishes custody of them back to the SampleCustody Officer or his assistant.

3.5. At this point, either a client Chain of Custody form or another EnvirotechResearch Chain of Custody form is initiated. Each sampling point is enteredon one line. If the Envirotech Research Chain of Custody document is usedand the total number of samples taken exceeds ten, then additional forms areadded as required. A example of the Envirotech Research Chain of Custodyform is given in Attachment 2. Instructions for the Chain of Custody are givenin Attachment 3. Common abbreviations used to request laboratory analysisare given in Attachment 4.

3.6. The Sample Custody Officer or his assistant then checks the actual samplesagainst the information on the Chain of Custody form. If there are any errors ordiscrepancies, they are corrected at this point. in time and initialed. Thecustody of the samples is then signed from the sampling crew to the SampleCustody Officer or his representative and logged into the laboratory and placedin a locked refrigerator in accordance with Envirotech Research SOP No.SI 03.

3.7. For sampling containers received by common carrier, the shipping documentsare to be retained to document their possession with the shipper and theSample Custody Officer will accept custody as of the time the container isopened in the laboratory.

3.8. The completed Chain of Custody is placed in the Job Folder in the DocumentControl Area.

3.9. INTERNAL CHAIN OF CUSTODY

3.9.1. After the samples have been logged in per Envirotech Research SOPSI03, a Laboratory Chronicle is initiated for each sample received bythe laboratory. An example is given in Attachment 5. An InternalChain of Custody is initiated for each group of samples from the Job ofsimiliar matrix and method. An example is given in Attachment 6.

&8.30518756


The Laboratory Chronicle contains the client name, site name, sample number,matrix, date sampled and date received in the header. Along the left column, eachanalysis requested is listed. The Internal Custody Record tracks the samplesthrough the laboratory and identifies who has custody of the sample or samplealiquot at any given time. The Lab Chronicle also records by whom and whenpreparation and analysis of each parameter is performed in addition to the QualityAssurance batch number for each parameter analyzed for the sample.

3.9.2. The Laboratory Chronicles are maintained in the Job Folder inaccordance with Envirotech Research SOP No. D100.

3.9.3. The Internal Chain of Custody Records remain in the sample storagearea and follow the samples as they are handled.

AB305I88

ATTACHMENT 1

CUSTODY SEAL(ugniturt)

Date Collected ______________________ Time Collected.Person Collecting Sample ______________________ Sample No,

(ugniturt)

11304

58 AR305I89

ATTACHMENT 2

AR305190

ATTACHMENT 3.(Page 1 of 2)

Instructions: Chain of Custody / Analysis Request Form

ENVIROTECH RESEARCH INC.T7TiM.cwn.mi<Mo ' Chain of Custody / Analysis Request

1. Provide the name, address and phone and fax number of the person who is to receive theanalytical report and invoice.

2. Print the name of the sampler, the site/project name, the state the site is located in and thetype of regulatory program under which the analysis falls. Please provide the EnvirotechQuote/Project number with the Project Identification Information. If your companyrequires a purchase order number (P.O.#) for payment of laboratory services, pleaseprovide it in the noted box.

3. Note the required analysis turnaround time. Standard analysis turnaround time for complexprojects is approximately 15 to 20 work days. Standard turnaround time for other projects (i.e.VOAs, PHC, and most general chemistry) is approximately 10 to 15 work days. Rushanalytical services will be provided upon request with the following surcharges applied tostandard unit prices:

2 Week Rush (10 work days) for a 25% surcharge;1 Week Rush (5 work days) for a 50% surcharge;Less Than 5 Work Day service for a 100% surcharge.

Rush Total Petroleum Hydrocarbon testing is not subject to this surcharge policy and isoffered faster and at lower rush price surcharges. Please see our price list for details.

60

(Over)

AH305I9I

ATTACHMENT 3(Page 2 of 2)

4. List the analyses you would like performed under "Analysis Requested". Place one analysisper column starting at the left column. You may use common abbreviations. Please see ourlist of common abbreviations for laboratory tests.

5. Place the sample descriptions (as you wish them to appear in your laboratory report) in theSample Identification column. Note the date of sampling, time of sampling, the sample matrix(soil/water) and the number of containers for each sample. Place an "X" under theappropriate type of analysis for each sample to indicate your request foreach requiredanalysis.

6. Note the preservation used for soil and water samples by placing the correct number code ineach box. Most soil samples must be preserved by cooling to ice temperature (#1). Waterpreservatives are generally noted on the containers provided by the laboratory. Two separatelines are provided for soil and water preservation information so that both soil and watersample preservation information can be provided.

7. Place special instructions on the space provided. Also, note whether the any water samplesbeing tested for metals have been field filtered.

8. The signature of the person who's name is printed in the "Samplers Name" box must appearin the first "Relinquished by" box. His/her company name must follow as well as the date andtime of change in sample custody. The person receiving the samples must then sign andprovide their company affiliation. This procedure must be followed each time samples changecustody.

9. Please do not use the section noted "Lab use only". This section is required by the laboratoryfor identification of laboratory samples.

AH30519261

ATTACHMENT 4' - (Page 1 of 2)

Common Abbreviations for Laboratory Tests

Priority Pollutants (PP)PP • VOA«Priority Pollutant Volatile Organic Analysis with xylenesPP - VOA +10- Priority Pollutant Volatile Organic Analysis with xylenes plus a GC/MS library

search for up to 10 non-target compoundsPP • BN - Priority Pollutant Base/Neutral Extractable OrganicsPP - BN + 16 - Priority Pollutants Base/Neutral Extractable Organics plus a GC/MS library

search for up to 15 non-target compoundsPP - BNA - Priority Pollutant Base/Neutral and Acid Extractable OrganicsPP - BNA + 25 > Priority Pollutant Base/Neutral and Acid Extractable Organics plus a GC/MS

library search for up to 25 non-target compoundsPP • Metals • Priority Pollutant Metals (13 elements • As, Sb, Be, Cd, Cr, Cu, Ni, Pb, Hg, Se, Ag,

•71, Zn)PP - PCB/Pest - Priority Pollutant Polychlorinated Biphenyls (PCBs) and Organochlorine

PesticidesPP + 40 • Priority Pollutants + 40 (PP-VOA+15, PP-BNA+25. PP-PCB/Pest, and PP-Metals)PP - PAH - Priority Pollutant Polynuclear Aromatic Hydrocarbons

Target Compound List (TCL) and Target Analyte List (TAL):TCL - VOA +10 - Target Compound List Volatile Organic Analysis plus a GC/MS library search

for up to 10 non-target compoundsTCL • BN +10 - Target Compound List Base/Neutral Extractable Organics plus a GC/MS library

search for up to 10 non-target compoundsTCL • BNA + 20 - Target Compound List Base/Neutral and Acid Extractable Organics plus a

GC/MS library search for up to 20 non-target compoundsTAL • Metals - Target Analyte List Metals (23 elements • Al, Sb, As, Ba, Be, Cd, Ca, Cr, Co, Cu,

Fe, Pb. Mg, Mn, Hg. Ni. K. Se. Ag. Na, Tl. V, Zn)TCL - PCB/Pest - Target Compound List Polychlorinated Biphenyls (PCBs) and Organochlorine

PesticidesTAL/TCL + 30 - Target Analyte List and Target Compound List +30 (TCL-VOA+10,

- -TCL-BNA+20, TCL-PCB/Pest, TAL-Metals)CN - Cyanide

EPA Contract Laboratory Program (CLP):TCL/TAL Analysis is provided by the EPA's CLP statement of work. When CLP analysis isrequired, please clearly specify "CLP* analysis in the Special Instructions section. Thelaboratory will follow SW-846 methods for TCL and TAL analysis unless "CLP" analysis isspecified.

Waste Characteristic Testing:TCLP - Toxicity Characteristic Leaching Procedure (Full TCLP), Including:

1. TCLP Zero Headspace Extraction2. TCLP Inorganic and Semivolatile Organic Extraction3. TCLP-VOA - TCLP Volatile Organics Analysis4. TCLP-BNA - TCLP Base/Neutral and Acid Extractable Organics Analysis5. TCLP Metalse.TCLP-Pest- Pesticides7. TCLP-Herb - TCLP Herbicides

For individual TCLP fractions note the specific test required, i.e. TCLP-VOA orTCLP-Metals

I,C,R - Ignitability, Corrosivity, and Reactivity (for Cyanide and Sulfide)PCB - Polychlorinated BiphenylsPHC - Total Petroleum Hydrocarbons

(Over)AR305I93

-. o 2.

ATTACHMENT 4(Page 2 of 2)

Volatile Organic Profiles:Ac & Ac - Acrolein and Acrylonitrile by methods 603/8030BTEX - Benzene, Toluene, Ethylbenzene and Xylenes by methods 602/8020BTEX by MS • Benzene, Toluene, Ethylbenzene and Xylenes by methods 624/8240MTBE - Methyl tertiary butyl ether7BA - Tertiary butyl alcoholDIPE • Diisopropylether

Petroleum Discharge Evaluation Analyses:Fingerprint • GC-FID Hydrocarbon Product IdentificationGRO - Gasoline Range Organics (PHC by GC)DRO • Diesel Range Organics (PHC by GC)3650 Cleanup • Acid-Base Partition Cleanup3611 Cleanup - Alumina Column Cleanup

individual Metals:Al Aluminum Co Cobalt P-ICP Phosphorus by ICPB Boron Cu Copper Se SeleniumSb Antimony Fe Iron Ag SilverAs Arsenic Au Gold Na SodiumBa Barium Pb Lead Sr StrontiumBe Beryllium Mg Magnesium 71 ThalliumCd Cadmium Mn Manganese Sn TinCa Calcium Hg Mercury Ti TitaniumCr Chromium, Total Mo Molybdenum V VanadiumCr*4 Chromium, Ni Nickel Zn Zinc

Hexavalent K Potassium

General Chemistry:Alk • Alkalinity, as CaCO3 ORP - Oxidation Reduction PotentialBr - Bromide PO4 - OrthophosphateCOj - Carbon Dioxide, Free P • Phosphorus, TotalCEC - Cation Exchange Capacity 70S - Total Dissolved SolidsCOD - Chemical Oxygen Demand 7SS - Total Suspended SolidsCl - Chloride TS - Total SolidsCN • Cyanide TVS - Total Volatile SolidsF - Fluoride SS • Settleable SolidsHrd • Hardness Sp. Cond. - Specific ConductanceHerb - Herbicides (2,4-D and 2,4, 5-TP) SO4 - SulfateNH) - Ammonia Nitrogen S*1 • SulfideNO} - Nitrate Nitrogen TOC - Total Organic CarbonNO2 - Nitrite Nitrogen PHC • Total Petroleum HydrocarbonO & G - Oil and Grease. GravimetricO & G, IR - Oil and Grease by IR

6.3 AR305I9I*

ATTACHMENT 5

LABORATORY CHRONICLE

ENVIROTECH RESEARCH, INC.777 NEW DURHAM ROAD, EDISON, NJ 08817

(908) $49-3900

Client: ENVIROTECH RESEARCH, INC. Date Sampled: 6/9/94

Site: XYZ Chemical Co. Date Received: 6/9/94

Matrix: SOLID Job No.: G780

Sample No.: 98318

Analytic Extraction Extractor's Analysis Analyst's QAParameter Date Name Date Name Batch

PPVOA+IS _ _ __ _

C7••P PEST/PCB " '

-!"1™ _ "/"M J«~ TL c. Jnh* *~*. £><*- 7yioARSENIC

BERYLLH'M

CADMU'M

CHROMIUM

COPPER

LEAD

MERCURY

MCKEL

SELENIUM

SILVER

ZINC

54 ttR30SI95

ATTACHMENT 6

INTERNAL CHAIN of CUSTODY RECORD

Job No.: Fraction:_______

Sample Nos.:_

Client: Matrix:

Site: Date Rec'd:

In Custody Of Date Time

SSA ____

SSA=Secured Storage Area

&R305I9665


ENVIROTECH RESEARCH SOP No. SI03STANDARD OPERATING PROCEDURE FOR SAMPLE RECEIPT.

LOGIN. IDENTIFICATION. STORAGE andMITIGATION of SAMPLE and LABORATORY CONTAMINATION

doc: SI03Revision: Number 3-July 11,1995

flR305!9766


1. SCOPE and APPLICATION '

1.1. The following procedure details the steps required to receive and uniquelyidentify samples received at he laboratory. This procedure is used inconjunction with Envirotech Research SOP No. SI00 which specifies internaland external Chain of Custody procedures.

1.2. This SOP addresses sample storage and security procedures performed by theSample Custody Officer or his Assistant.

1.3. This SOP further addresses procedures and precautions which eliminate or atworst minimize contamination of samples from other samples or from thelaboratory.

2. APPARATUS

2.1. Sample Log Book

2.2. Preprinted Sample Identification Labels

2.3. 0-14 pH Paper

2.4. Calibrated Thermometer

2.5. . Cooler Temperature Logbook

2.6. Gloves, Labcoat, Safety Glasses

3. PROCEDURE

3.1. Sample Login and Storage

3.1.1. A checklist with all steps for sample receipt and login is given asAttachment 1. The initial acceptance of samples at EnvirotechResearchjnc. is performed by the Sample Custody Officer or hisassistant. Samples may enter the laboratory only at the designatedsample receiving area. Samples which have an odor or are suspected tobe high in concentration are logged in under a fume hood.

3.1.2. The containers are checked for damage and appropriate volume,container type, and preservation for the proposed analysis by theSample Custody Officer or his assistant. Broken or damagedcontainers and samples which are not in the proper container are notaccepted.

AR305I9867


3.1.3. To mitigate sample cross contamination, the lid on every sample bottleis tightened down if it is not already so and any sample bottle withsample residue on its exterior surface is rinsed off in the adjacent sink.If the sample bottle has residue which is not removable, the samplebottle is placed in a ziplock bag to eliminate any potential contact withother samples.

3.1.4. If the containers do not have appropriate label information, the SampleCustody Officer or his assistant will complete an Envirotech samplelabel for each container.

3.1.5. When the Sample Custody Officer or his assistant determines that thesamples are in satisfactory condition and are properly preserved thechain-of-custody form(s) which accompanied the samples is checkedagainst the samples for accuracy and executed in accordance withEnvirotech Research SOP No. SI00.

3.1.6. The Sample Custody Officer or his assistant assigns an EnvirotechResearch, Inc. sample number to each sample and a job number foreach sample submission. The job number is assigned to a group ofsamples received at one time which are to be analyzed and reported inone report to one client. The sample number is a five digit numberwhich applies to every fraction of an individual sample. One sample isdefined as the sum of all material taken from a specific point at aparticular time. For example, multiple containers filled at the samesurface location, depth and time for volatile organics and metalsanalysis constitutes one sample. One sample may therefore consist ofone or more containers. As another example, material removed fromthe same surface location but at different depths constitutes more thanone sample and must have a separate sample identification. Two wellwater samples taken at the same location but at different times are alsoseparate samples.

3.1.7. A preprinted sticker with the sample number is affixed to each samplecontainer and its lid. The sample and job numbers are also printed onthe chain-of-custody form.

3.1.8. The Sample Custody Officer or his assistant makes an entry in thebound Sample Log Book for each sample received. Each entrycontains the sample number, job number, date received, date sampled,the number of containers for the sample, the matrix, the client'sidentification for the sample, the parameters to be analyzed, clientname, the refrigerator identification where the samples are secured andany additional comments. An example page from the Sample LogBook is included as Attachment 2.

AH305199~ 68

"'t


3.1.9. Sample preservation is recorded for each job documenting thecondition of the samples upon receipt and the pH of any samples whichrequired preservation noting any adjustments made at the lab. Thetemperature of the incoming samples is taken from the TemperatureMonitor Bottle and is recorded in the Cooler Temperature Log. If thetemperature of the incoming samples is too high, the client isimmediately notified and the laboratory must receive guidance from theclient if analysis is to proceed. Samples requiring preservation arechecked with pH paper (0-14 range, 0.5 sensitivity). This informationis recorded hi the Sample Login Book on the back of the page that thejob is being logged in on. Any samples that are improperly preservedare adjusted and documented on the outside of the Job Folder.Deficiencies will be noted hi a non-conformance statementaccompanying each sample report.

3.1.10. The Sample Custody. Officer or his assistant secures the sample-containers for analyses other than VOAs in the secured limited accesssample storage refrigerators. Refrigerator A is used for any sampleswhich are pure product or are suspected to be high concentrationsamples. The temperature of the sample storage refrigerators ismaintained at 4°C and is monitored and recorded daily.

3.1.11. All sample bottles which contain samples that will be analyzed forvolatile organics are brought to the organic free area in the VOAlaboratory. Sample containers for VOA analysis are secured in lockedlimited access sample storage refrigerators. Sample bottles whichcontain solid samples that will be analyzed for volatile organics arescreened by an Hnu. If a response is detected, the sample containersare placed in the separate high concentration volatile organicsrefrigerator located in the VOA lab. Water samples and solid sampleswhich do not screen are placed in one of the low level volatile organicsrefrigerators located in the VOA lab.

3.1.12. After the samples are logged in, internal sample tracking forms areinitiated in accordance with ETR SOP SI00. Samples to be analyzedfor NJDEPE Contract X-26174 require NJDEPE form 077 as specifiedby SOP SI00.

3.1.13. The Sample Custody Officer or his assistant enters sample specificinformation for each job into the laboratory sample tracking systemdatabase. This information consists of the client, job number, datereceived and sampled and number of analyses for each parameter.

3.1.14. Completed chain-of-custody forms and the internal sample trackingforms are delivered to the Laboratory Data Management Office and are

&K3Q5200

ENVIROTECH RESEARCH, INC.• - .

handled in accordance with Envirotech Research .SOP No. D100 forData Management and Handling Procedures.

3.2. Procedures and Measures to Mitigate Sample Contamination

3.2.1. Section 3.1 of this SOP outlines the measures taken to ensure thatsamples do not cross contaminate one another. These steps are takenduring the login procedure'and are repeated as the samples are handled.Samples for volatile organics analysis are segregated immediately afterlogin to an isolated area of the laboratory that is free of volatileorganics. They are further segregated after they are screened to isolatehigher concentration samples from low level samples. Sample bottleswhich have material on the exterior of the bottle are decontaminated inthe sink located in sample receiving. If this is not adequate, the samplebottle is placed in a ziplock bag so it cannot come in contact with othersamples. Sample bottles which contain pure product or are suspected tobe high in concentration are isolated in Refrigerator A.

3.3. Procedures and Measures to Mitigate Laboratory Contamination

3.3.1. Envirotech Research's laboratory has been designed to isolate samplestorage, sample bottle storage and volatile organics analysis areas frompotential sources of contamination by physically isolating the areaswhere solvents are permitted and organic free areas using full height

_ solvent containment walls, by specially designed air handling systemswhich prevent ambient lab air from being transported to areas wherevolatile organics samples are stored and analyzed and by constantlymaintaining air pressure control to ensure that areas which aredesignated as organic free are always under positive pressure.

3.3.2. Laboratory contamination is prevented by screening samples to insurethat unacceptably high concentration samples do not contaminateanalytical instruments and result in cross contamination betweenanalyses. VOA samples are screened prior to analysis on a GC-FIDwith a Tekmar heated headspace sample introduction system.Semivolatile organic samples are also screened by GC-FID.

3.3.3. The presence of laboratory contamination is evaluated with the use oflaboratory "blanks" as required by applicable methods. If unacceptableblank contamination is present (i.e. three times the CRQL formethylene chloride, acetone, benzene, toluene or phthalates; or abovethe CRQL for other parameters) then analysis is halted until the sourceof contamination is located and the system brought under control.

AR3Q520I


3.4. Procedure for Documenting and Assessing Sample and Laboratory 'Contamination and Cleanup

3.4.1. Sections 3.1 and 3.2 describe cleanup procedures used to prevent crosscontamination from samples. A record of sample bottles which containpure product or are suspected to be high in concentration that areisolated hi Refrigerator A is made in the Sample Receiving Log Book.

3.4.2. Documentation of the results of all VOA and Semivolatile OrganicScreening analyses are retained hi the appropriate Job Folder alongwith the results of blank analyses.

3.4.3. Each Department Supervisor evaluates the results of blank analyses forcontamination and screening analyses for consistency with finalanalytical results JLaboratpries are maintained in clean and orderly wayto prevent contamination of samples. If unacceptable blankcontamination is noted the applicable Department Supervisor will takethe necessary cleanup action.

3.4.4. Documentation is provided in the Case Narrative if unacceptable blankcontamination is noted describing factors related to any analysis thatwas halted until the source of unacceptable blank contamination waslocated and the system brought back under control.

- 3.4,5. If an accident causes a spill or leak in the laboratory action will betaken as specified in the Envirotech Research, Inc. Contingency Planand Emergency Procedures which is provided in Health and SafetySOP No. Ml06.

3.5. Procedures for After Hours Receipt of Samples

3.5.1. The Sample Control Officer or his Assistant is generally available toreceive samples on work days until 7:00 p.m. When there is a need forafter hours sample receipt and storage the Sample Control Officer or hisAssistant will either:

a) Remain at the laboratory to receive samples if notified in advance ofthe expected time of sample delivery, or;

b) Return to the laboratory to receive samples from the NJDEPE uponrequest when telephoned at the number given below for Mr. RobMcGrady924-3630

3.6. Procedures to Flag Rush or Short Holding Time Samples

AR3Q5202


3.6.1. Rush samples and samples with short holding times are flagged at four3points in the login procedure:

a) With the sample's entry in the Sample Log Book;b) In the sample tracking system database;c) On the sample scheduling sheets in the Laboratory Data Management

Office;d) In red ink on the top of the Job Folder that contains all documents that

relate to the samples.

3.6.2. For short holding time samples the Sample Control Officer or hisAssistant will also verbally notify the person assigned to start theanalysis or their Department Supervisor so that they are aware thatsamples have been received that require special handling.

AR30520372

r-.


Attachment 1

Sample Receipt and Login Checklist

Yes No

1. Was custody seal on cooler intact?2. Was cooler temperature recorded?3. Were all samples in good condition?4. Were samples labeled?5. Were sample container lids tightened and any sample

residue rinsed off the outside of the container?6. Was chain of custody record form completed?7. Did number of samples and information on sample

labels correspond to number of samples andInformation on the chain of custody record form?

8. Did client relinquish samples to the Sample CustodyOfficer by signing the chain of custody record formin the space provided with the date and time?

9. Did Sample Custody Officer receive the samples bysigning the chain of custody record form in thespace provided with the correct date and time?

10. Did client receive a copy of the properly executedchain of custody record?

11. Were the sample containers labeled with theirlaboratory sample number on the side and top?

12. Were the job number and sample numbers printed onthe chain of custody record form?

13. Was an entry made in the Sample Log Book with allnecessary information (i.e. sample number, job numberdate received, date sampled, number of containersmatrix, client I.D., parameters, client name, preservationrefrigerator location and any comments)?

14. Were solid samples requiring volatile organicsanalysis screened with the HNU in the VOA laboratory?

15. Were samples requiring volatile organics analysisstored in either the high concentration or lowconcentration refrigerator in the VOA laboratory?

16. Were all other samples secured in a refrigerator?17. Were sample tracking forms initiated?

AR305201*73


Attachment 1

Sample Receipt and Login Checklist

Yes No18. Was the job entered into the laboratory sample

tracking data base with all necessary information(client, job number date received, date sampled andnumber of analyses for each parameter)?

19. Were completed chain of custody record forms andInternal sample tracking forms delivered to theLaboratory Data Management Office?

Job No.___ Signed________ Date

' AR30520574

75 A.R305206


ENVIROTECH RESEARCH SOP No. Ml 00STANDARD OPERATING PROCEDURE

FOR PREPARATION. PURITY and STORAGE ofREAGENTS and STANDARDS

doc: Ml00Revision:

AR30520776


1. INTRODUCTION:

1.1. The following procedure is written to address laboratory procedures fordocumenting the preparation, purity/traceability and storage of reagents andstandard reference materials. In all areas of the laboratory, it is each department'ssupervisors responsibility to maintain records (bound notebooks) of all reagentsand standard reference materials used in his/her area of responsibility.

2. STORAGE:

2.1. All reagents, solvents, bulk chemicals, neat materials and primary referencestandards are "logged in" by writing the date received into the laboratory directlyon the container. In addition, when a reagent, solvent, bulk chemical, neat materialor primary reference is opened for use, it is dated and initialed by the analyst. Bulkdry reagents are stored in the balance room located adjacent to the glasswarewashroom in the rear of the laboratory. Bulk solvents are stored in the solventstorage room adjacent to the shipping/receiving dock located in the rear of thebuilding. In the event of an accidental spill or container failure the floor of thisstorage areas is sealed to 6 inches above floor level with a Sentry PolymerSemstone 245 coating. Bulk acids are stored in a "corrosives" storage cabinetlocated in the solvent storage room. An exhaust fan operates 24 hours in this areato eliminate any build up of solvent or acid fumes. Detailed procedures for the

- storage of working reagents and standard reference materials used in routinesample analysis are addressed in each relevant analytical SOP.

3. PURITY OF STANDARDS AND REAGENTS:

3.1. The purity or grade of reagents used for testing purposes in the laboratory aremethod specific. Each analytical method has unique requirements andspecifications for reagents and standards used (i.e. pesticide residue analysisrequires the use of pesticide grade solvents while volatile organic analysis requirespurge and trap grade methanol). These requirements are detailed in Section 3(Reagents) of each analytical SOP.

3.2. In all instances, existing stocks of chemicals and reagents must be consumed ordisposed of upon expiration prior to introducing a new lot or source of materialsinto the laboratory. Once a new materials is introduced into a testing procedurestandard QA/QC procedures such as analysis of reagent blanks, matrix spike,matrix spike duplicate and blank spikes will make

77 AR305208

ENVIROTECH RESEARCH, INC. t&

obvious any substandard performance of new materials. Gross changes inperformance can be seen and corrected at the bench level upon review of the abovelisted QC checks. Subtle changes are best viewed by tracking these QC checkparameter with Shuhart Charts. These charts are updated monthly and distributedto the appropriate lab supervisors.

4.1. The actual mechanics of preparing laboratory reagents and standard referencematerials are detailed in each analytical SOP.

4.2. At a minimum all reagents and solutions must be labeled to indicate identity, whenapplicable titer, strength or concentration, diluent, preparation and expirationdates. The dates are used to cross reference working standards to the boundlogbook entry. Upon preparation or opening of a pre-prepared standard solution,the following information is entered into a bound laboratory notebook (Identityand source of neat material or purchased stock solution, lot number if applicable,concentration, diluant, date prepared or placed in service, expiration date, analystresponsible for preparation and a record of all weights and dilutions used). Eachpage of the notebook must be signed by both the analyst preparing the reagent orstandard and authenticated with the signature of his/her immediate supervisor.

AR305209


ENVIROTECH RESEARCH SOP No. Ml02STANDARD OPERATING PROCEDURE

FOR PREVENTIVE MAINTENANCE and CALIBRATION PROCEDURESFOR ALL ANALYTICAL INSTRUMENTS and ANCILLARY EQUIPMENT

doc: M102Revision:

AR3052IO


1'. SCOPE and APPLICATION

I.I. The following procedure outlines the steps taken to ensure that instruments andancillary equipment are in condition to perform their respective functions.

2. PROCEDURE

2.1. Analytical Instruments - The maintenance procedures, calibration procedures andtuning procedures which are carried out by analysts are covered in detail in theanalytical SOPs. Every analytical instrument is covered by a service contractwhich calls for immediate service from the vendor should a failure occur. Inaddition to covering the instrument hardware, the software which controls theinstruments is also covered by a maintenance contract. The department supervisoris responsible for the maintenance of the instruments within his laboratory.

2.2. Ancillary Equipment - The inorganic laboratory supervisor is responsible for all theancillary equipment listed below except for the GC items which are theresponsibility of the GC Supervisor. In addition to routine instrument maintenanceprovided by manufacturer's maintenance contracts and software services,Envirotech will perform the following checks to insure that ancillary equipment

- and instrumentation are capable of functioning properly:

2.2.1. Analytical Balances

2.2.1.1. The balance is to be certified and checked once a year by a balanceservicing company.

2.2.1.2. The analytical balance is to be checked once per month with classS weights, over the range of 10 milligrams to 30 grams.

2.2.1.3. All pertinent information will be recorded in a bound log book.

2.2.2. pH Meters

2.2.2.1. Meters are to be standardized against two buffers that bracket thepH of the sample.

80 AR3052M


2.2.2.2.The electrodes will be immersed in an appropriate buffer or waterwhen not in use, and filled with an appropriate filling solutionspecified by the manufacturer.

2,2.2.3.A daily check of the pH meter will be made after calibration by_ setting the meter jo pH 7.00 with a bufjer standard and then with

no further adjustment, reading pH buffer standards of pH 4.00 and10.00 and recording the actual readings in a bound log book.

2.2.3. Spectrophotometers

2.2.3.1.A quarterly calibration of the Sequoia Turner Model 340Spectrophotometer will be performed for determinations includingcyanide and phenols.

2.2.3.2.The wavelength observed, date of check and analyst's name will berecorded in a bound log book.

2.2.4. Drying Ovens

2.2.4.1.The temperature of each drying oven will be recorded in a boundlog book daily or for each day the oven is in use.

2.2.5. Refrigerators

2.2.5.1. The temperature of each refrigerator shall be recorded daily in abound notebook by reading an in-place thermometer immersed in

—-— liquid on a shelf of the refrigerator.

2.2.6. Thermometers

2.2.6.1.All glass thermometers will be verified yearly by comparing thereadings of these thermometers with a NBS traceable certifiedthermometer. Each thermometer will be identified and a record willbe maintained including thermometer identification, the temperatureof the certified thermometer, the temperature of the

AR3052I281

--• :- - ' - . . . rtfr'


thermometer being verified, date of verification and analyst whoperformed verification.

2.2.7. Gas Chromatograph Detectors

2.2.7.1.A record will be maintained for each detector with the serialnumber, date of installation, and background current profilesobtained at the time of installation.

2.2.8. Gas Chromatograph Columns

2.2.8.1. A record containing column ID number, date of packing orpurchase, liquid phase identity and lot number of precoated columnpacking, conditioning temperature, flow rate and number of hours,length and shape of column, background current profiles and dateof silation of column will be maintained for each column.

AR3052I3


Analytical Methods

Envirotech Research. Inc. performs analyses using EPA methodology and otherpublished authoritative methods. A detailed description of our procedures .foreach method arefound in our analytical standard operating procedures manual

The following analytical methods summary provides a listing of analytical methodsroutinely offered by Envirotech Research. Inc. as of November 1995. In addition, this summaryprovides a listing of major groups of analyses and analytical packages routinely offered.Additional methods are offered for special projects upon request.

The table provided below gives a summary of the pages that follow.

Methods and Parameters Contents Summary'

1. Priority Pollutants. Major Groups and Packages

2. TCL and TAL. Major Groups and Packages

3. EPA Contract Laboratory Program MethodsHazardous Waste Classification Analyses

-4.-Volatile Organic Analysis Profiles -------- --— —

5. Metals Analyses. Individual Metals and Packages

6. General Chemistry

7. Petroleum Discharge Evaluation Analyses

RR3052li»O O


Priority Pollutant Major Groups and Packages

600 Series Methods for Water and WastewaterSW-846 Methods for Soil and Solid Waste

MethodParameter Water/Soil

Priority Pollutant Volatile Organicswith Xylenes (VOA) 624/8240

Priority Pollutant Volatile Organics +15with Xylenes (VOA+15) 624/8240

Priority Pollutant Volatile Organics +15with Xylenes, MTBE and TBA 624/8240

Priority Pollutant Base/neutralExtractable Organics (BN) 625/8270

Priority Pollutant PolynuclearAromatic Hydrocarbons (PAHs) 625/8270

Priority Pollutant Base/neutralExtractable Organics +15 (BN+15) 625/8270

Priority Pollutant Base/neutral andAcid Extractable Organics (BNA) 625/8270

Priority Pollutant Base/neutral andAcid Extractable Organics +25 (BNA+25) 625/8270

Polychlorinated Biphenyls (PCBs) 608/8080

Priority Pollutant Pesticides & PCBs (Pest/PCB) 608/8080

Priority Pollutant Metals (PP Metals) 200 Series/6010&700013 elements: As, Sb, Be, Cd, Cr,Cu, Ni.Pb, Hg, Se, Ag, Tl, Zn

Full Priority Pollutants (VOA, BNA, PestPCB, and Metals)

Full Priority Pollutants +40 (VOA+15, BNA+25, Pest/PCB, Metals)

84 AR3052I-5-


Target Compound List (TCL) Organics andTarget Analyte List (TAL) Metals Major Groups and Packages

600 Series Methods for Water and WastewaterSW-846 Methods for Soil and Solid Waste

Parameter

TCL Volatile Organics with Xylenes

TCL Volatile Organics +10 with Xylenes

TCL Volatile Organics +10 with Xylenes,MTBE and TEA

TCL Base/neutral Extractable Organics

TCL Base/neutral Extractable Organics +10

TCL Base/neutral and Acid ExtractableOrganics

Base/neutral and Acid ExtractableOrganics +20

TCL Pesticides & PCBs

TAL Metals 20023 elements: Al, Sb, As, Ba, Be,Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn,Hg, Ni, K, Se, Ag, Na, Tl, V, Zn

Cyanide

Full TCL Analysis Package (VOA, BNA, PestPCB)

Full TCL+30 Analysis Package (VOA+10, BNA+20,

MethodWater/Soil

624/8240

624/8240

624/8240

625/8270

625/8270 • H

625/8270

625/8270

608/8080

Series/60 10&7000

335.2

PestPCB)

Full TAL & TCL Analysis Package (VOA, BNA, Pest/PCB, Metals CN)*.

Full TAL & TCL+30 Analysis Package(VOA+10, BNA+20, Pest/PCB, Metals, CN)

V

85 AR3052I6


USEPA Contract Laboratory Program (CLP)

Analysis and reporting is provided as specified in the 3/90 CLP Statement OfWork (SOW) Methodology for Organics Analysis Multi-Media, Multi-Concentration,document number OLM03.1 , -

Metals and Cyanide analysis and reporting is provided as specified in the CLPSOW Methodology for Inorganic Analysis Multi-Media, Multi-Concentration, documentILM03.0

Parameter

CLP Target Compound List (TCL):

CLP-TCL Volatile Organics +10

CLP-TCL Semivolatile Organics +20

CLP-TCL Pesticides & PCBs

Target Analyte List (TAL):

Target Analyte List Metals.23 elements: Al, Sb, As, Ba, Be,Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn,Hg, Ni, K, Se, Ag, Na, Tl, V, Zn

Cyanide

CLP-TCL +30 Organics Package

Full CLP-TAL & TCL +30 Package

Matrix

Water or Soil

Water or Soil

Water or Soil

Water or Soil

Water or Soil

Water or Soil

Water or Soil

When CLP analysts is required, please specify "CLP" analysis on the Chain-of-Custodyrecord provided with your samples.

Prices include CLP full format laboratory deliverable reports.

CLP methods require site specific quality assurance samples. With20 environmental samples provided over a period of 14 days or lessmatrix spike duplicate are required, resulting in two billable samples.

each group of up to, a matrix spike and

AR3052I7o 6

ENVIROTECH RESEARCH, INC.>

Waste Characteristic Testing

Parameter

Toxicity Characteristic Leaching Procedure (TCLP):

1 . TCLP Zero Headspace Extraction

2. TCLP Inorganic and SemivolatileOrganic Extraction

3. TCLP Volatile Organics Analysis

4. TCLP Base/neutral and AcidExtractable Organics Analysis

5. TCLP Metals Analysis

6. TCLP Pesticides and Herbicides

Other RCRA Characteristic Tests:

7. Ignitability

8, Corrosivity

Method

•

1311

1311

8240

8270

6010/7471

8080/8150 V

1020 '*.

9045

9. Reactivity (Cyanide and Sulfide) SW-846 Chapter 7.3

Other Waste Classification Tests:

10. Total Petroleum Hydrocarbons (PHC)

11. Polychlorinated Biphenyls (PCBs)

418.1

8080

Waste Classification Packages

Full TCLP

Full TCLP, RCRA Tests, PHC & PCBs

Items 3-6,Items 1-6,

Items 3-1 1Items 1-11

WaterSolid

WaterSolid

S7 . AR3052I80 /


Volatile Organic Profiles

Gas ChromatographyMethod

Parameter Water/Soil•Acrolein & Acrylonitrile (GC-FID) 603/8030•Alcohols or Glycols (GC-FID) 8015•Benzene, Toluene, Ethylbenzeneand Xylenes (BTEX) (GC-PID) 602/8020•To add MTBE, TBA or DIPE to a BTEX analysisadd $10 per compound•To add Naphthalene to a BTEX analysis add $20•Purgeable Aromatics (GC-PID) 602/8020•Purgeable Halocarbons (GC-ELCD) 601/8010•Purgeable Halocarbons and Aromatics(GC-PID/ELCD) 601&602/8021•Volatile Organics in (Drinking) Water(Capillary GC-PID/ELCD) 502.2

Gas Chromatography/Mass

Parameter•Purgeable Organics in (Drinking) Water(Capillary GC/MS)•Priority Pollutant Volatile Organicswith Xylenes•Priority Pollutant Volatile Organics +15with Xylenes•Priority Pollutant Volatile Organics +15with Xylenes, MTBE and TBA•TCL Volatile Organics with Xylenes•TCL Volatile Organics +10 with Xylenes•TCL Volatile Organics +10 with Xylenes,MTBE and TBA•TCL Volatile Organics +10

SpectrometryMethod

Water/Soil

524.2

624/8240

624/8240

624/8240624/8240624/8240

. 624/8240CLP-SOW

AR3052I9-

Vt,ENVIROTECH RESEARCH, INC.

Metals Analyses

Individual MetalsMethod Method

Parameter_____Water/Soil___________Parameter Water/Soil

Al Aluminum 200.7/6010 Mg Magnesium "200.7/6010Sb Antimony 204.2/6010 Hg Mercury 245.1/7471As Arsenic 206.2/7060 Mo Molybdenum 200.7/6010Ba Barium 200.7/6010 N Nickel 200.7/6010Be Beryllium 200.7/6010 K Potassium 200.7/6010Cd Cadmium 200.7/6010 Se Selenium 270.2/7740Ca Calcium 200.7/6010 Ag Silver . 200.7/6010

. Cr Chromium, Total 200.7/6010 Na Sodium 200.7/6010Co Cobalt 200.7/6010 Tl Thallium 279.2/7841Cu Copper 200.7/6010 Sn Tin 200.7/6010Fe iron 200.7/6010 Ti Titanium 200.7/6010Pb Lead 239.2/6010 V Vanadium 200.7/6010

Zn Zinc 200.7/6010

A digestion fee is charged once per sample in addition to the analysis fee listedabove for each individual metal.No digestion fee is charged for Mercury or Metals Packages.See General Chemistry Section, Page 8, for Hexavalent Chromium AnalysisPrices.

Metals Analysis Packages

____Parameter______________________Matrix

RCRA or Drinking Water Metals8 elements: As, Ba, Cd, Cr, Pb, Hg, Se, Ag Water or Soil

Priority Pollutant Metals (PP Metals)13 elements: As, Sb, Be, Cd, Cr,Cu, Ni.Pb, Hg, Se, Ag, Tl, Zn Water or Soil

Target Analyte List Metals (TAL Metals)23 elements: Al, Sb, As, Ba, Be, Cd, Ca, Cr, Co, Cu,Fe, Pb, Mg, Mn, Hg, Ni, K, Se, Ag, Na, Tl, V, Zn Water or Soil

RR305220


General Chemistry

ParameterAcidityAlkalinityCarbon Dioxide, FreeCation Exchange CapacityChemical Oxygen DemandChlorideChlorine Residual

MethodWater/Soil305.1310.1406B9081410.4325.3330.5

Chromium, Hexavaient (Cr+6) 1-1 230-84/3060-7 196ACyanideFluorideHardnessHerbicidesNitrogen, AmmoniaNitrogen, NitrateNitrogen, NitriteOil Grease, GravimetricOil Grease, IROxidation Reduction Potential (Water)Oxygen, Dissolved (Winkler)Petroleum Hydrocarbons, Total (PHC):

• Standard turnaround analysis• Three to Five work day rush analysis• Next day rush analysis

pH - water samplespH - soil samplesPhosphate, OrthoPhosphorous, TotalPhenols, TotalResidue:

• Total Dissolved Solids• Total Suspended Solids• Total Solids• Total Volatile Solids• Settleable Solids• Percent Solids (Moisture) in Soil

Specific ConductanceSulfateTotal Organic Carbon - waterTotal Organic Carbon - soilTurbidity

335.2340.2314A

515.1/8150350.3353.3353.3413.1413.2

ASTM D1498360.2

418.1418.1418.1150.19045365.3365.3420.1

160.1160.2160.3160.4160.5

3550 Sec. 7.2120.1375.4415.19060180.1

90 - &R30522I •—-


.- .' t

Petroleum Discharge Evaluation Analyses

Parameter

Total Petroleum Hydrocarbons (PHC):• Standard turnaround analysis• Three to Five work day rush analysis• Next day rush analysis

Priority Pollutant Volatile Organics +15with Xylenes (VOA+15)

Priority Pollutant Volatile Organics +15with Xylenes, MTBE and TBA

Priority Pollutant Volatile Organics +15with Xylenes and Naphthalenes

Priority Pollutant Base/neutralExtractable Organics +15 (BN+15)

Priority Pollutant Polynuclear•Aromatic Hydrocarbons (PAH)

Benzene, Toluene, Ethylbenzeneand Xylenes (BTEX)

MethodWater/Soil

418.1418.1418.1

624/8240

624/8240. w

624/8240

625/8270

625/8270 '

602/8020

To add MTBE, TBA or DIPE to a BTEX analysis add $ percompound. To add Naphthalene to a BTEX analysis add $ )

Lead in Water (Including Digestion Fee)Lead In Soil (Including Digestion Fee)

Polychlorinated Biphenyls (PCBs)

Hydrocarbon Product Identification (GC-FID):1 ) Qualitative - "GC-Fingerprint"2) Quantitative -

•Specify Gasoline Range Organics (GRO)•or Diesel Range Organics (DRO)

Extractable Organic Cleanup Procedures:• Acid-Base Partition Cleanup• Alumina Column Cleanup

239.26010

608/8080

8015

8015

36503611

AR30522291


ENVmOTECH RESEARCH SOP No. Ml01.1STANDARD OPERATING PROCEDURE

FOR EXPERIMENTALLY DETERMINED MDLs andPRECISION and ACCURACY

doc:M101Revision:

A.R305223


1. INTRODUCTION:

The following procedure is designed to demonstrate and document the laboratory'sability to produce data of acceptable quality and to establish long term procedures forgenerating data that meets or exceeds method precision, accuracy and detection limitrequirements.

2. PRECISION AND ACCURACY:

2.1. Prior to analyzing samples or after modifying the analytical procedure the analystmust make a one-time demonstration to generate acceptable accuracy andprecision with each analytical method. This is accomplished by spiking fouraliquots if reagent water with a Q.C. check sample concentrate (this concentratemust be prepared independently from the standard solution used to produce thecalibration curve for quantitation). The concentration and makeup of the Q.C.check sample is dictated by the method and defined in each analytical SOP. Thefour Q.C. check samples are processed through the entire analytical scheme andresultant concentrations calculated. The mean concentration (X), percentrecovery (P) and standard deviation (S) (in concentration units) are calculatedand compared to the method Q.C. acceptance criteria. If X, P S are within Q.C.limits, sample analysis can begin.

2.2. On an ongoing basis 1 in 20 environmental samples are spiked in duplicate withthe Q.C. sample concentrate together with a spiked reagent blank and the percentrecovery compared to method percent recovery limits. If any sample parameterpercent matrix spike, recovery is outside Q.C. limits the value of the blank spikefor that parameter, is checked against the method limits. If the blank spikerecovery is within Q.C. limits, the sample spike recovery is considered to be dueto sample matrix interference and all data points within that QA batch of samplescan be reported. If the blank spike results are outside Q.C. limits, the analyticalsystem is considered "out of control". Sample analysis can not continue until theproblem is resolved and an additional blank spike analysis is within Q.C. limits.All samples extracted and analyzed while the analytical system was "out ofcontrol" must be reextracted and reanalyzed.

93 AR30522U


3. METHOD DETECTION LIMIT:

3.1. Prior to sample analysis, method detection limits (MDLs) are determined for eachanalytical procedure used. These MDLs must be confirmed yearly (in the first quarterof each year/preferably in January but no later than March). It is the responsibility ofthe Supervisor to schedule this work in an identical fashion td scheduledenvironmental samples. The procedure published in the Code of Federal Regulations,40 CFR 136, Appendix B, "Definitions and Procedures for the Determination of theMethod Detection Limit", July 1, 1990 is to be used to determine each MDL. Thefollowing concentrations must be used in determining laboratory generated MDLs.

Analvte Concentration

Metals (All Techniques) 3xest. IDL

Purgeable Halocarbons(Method 601) lug/1

Purgeable Halocarbons(Method 8010) lug/kg

Purgeable Aromatics(Method 602) 2 ug/1

Purgeable Aromatics(Method 602) 10.5 ug/

, _ _Purgeable Aromatics(Method 8020) 2 ug/kg

Purgeable Aromatics(Method 8020) 0.5 ug/kg

Purgeables(Method 624) 2 ug/1

Purgeables(Method 8240) 5 ug/kg

Pesticides/PCBs(Method 608) 1/5 ug/1

Pesticides/PCBs(Method 8080) 30/150 ug/kg

Base/Neutral Acid Extractables(Method 625) 10 ug/1 B/N, 20 ug/1 AE

Base/Neutral Acid Extractables(Method 8270) 300 ug/kg B/N, 600 ug/kg AE

Acrolein and Acrylonitrile(Method 603/624) 10/25 ug/1

94 1R305225

ENVIROTECH RESEARCH, INC._______________________________________%• v

Analyte Concentration

Cyanide (Method 335.3) 5 ug/1

Total Phenolics (Method 420.1) 50 ug/1

' Total Petroleum Hydrocarbons(Method 418.1) " l.Omg/1

At the above listed concentrations seven replicates of spiked reagent water or Na SO , asappropriate, are processed through the entire analytical scheme. The standard solution usedto prepare the seven replicate spike samples must be prepared or purchased from anindependent source than that of the quantitation standards as detailed in each analytical SOP.Analyte concentrations and standard deviations- S (in concentration units) are calculated andMDLs are determined using the following equation.

(S) x (3.143) = MDL

When following CLP methodologies for organic analyses (OLM03.1), the ContractRequired Quantitation Limit (CRQL) is set at the concentration in the sample equivalent tothe concentration of the lowest calibration standard analyzed for each analyte. The analysisof this low standard confirms the laboratory's ability to meet the CRQL.

-j

AR305226


Statistical Quality Control

Internal quality control (QC) samples analyzed in accordance with methods other thanCLP are entered into a QA data base. Data maintained in this system includes analytical resultsfrom laboratory blanks, spiked blanks, matrix spikes and matrix spike duplicate analyses. Thisdata is used to establish known control limits of accuracy and precision for specific analyticalparameters.

The primary function of the QC data base is to produce Shewhart Control Charts whichprovide accuracy and precision information. Shewhart Charts use QC data from the twenty mostrecent quality assurance batches for each individual analysis. Separate charts are plotted for eachmatrix type. Shewhart Charts are produced using parameter and matrix specific data of thefollowing types:

- Blank Spike Percent Recovery

- Matrix Spike Percent Recovery

- Relative Percent Difference of MatrixSpike and Matrix Spike Duplicates

Information presented on these charts include average values, upper control limits, lowercontrol limits, upper warning limits and lower warning limits. The upper and lower control limitsare determined and plotted at three standard deviations from the mean. If results fall outside thecontrol limits action is taken to determine the cause of the outlying result. Upper and lowerwarning limits are determined and plotted at two standard deviations from the mean. Results thatfall outside the warning limits are evaluated for any developing trends that may affect data quality.

Several representative Shewhart Charts are presented on the following pages.

95 AR305227

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97 AR305228

1

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98 AR305229

IOf101mg3uIQaQ:o


ENVIROTECH RESEARCH SOP No. D 102.1STANDARD OPERATING PROCEDURE FOR

INTERNAL OA INSPECTION AND CORRECTIVE ACTION PROCEDURES

doc: D102Revision:

100 A~R3Q523i


1.0 SCOPE and APPLICATION

1.1 This procedure explains the process of review of Quality Control indicators whichare performed in accordance with the methodology being employed. .

1.2 The specific criteria which are evaluated are method specific and are enumerated inthe respective analytical SOPs. Detailed audit procedures including NJDEPE QArequirements for each method are given in the following QA Checklists:

Attachment QA Checklist Title

1 Volatile Organics, SW846 Method 8240

2 Semivolatile Organics, SW846 Method 8270

3 Organochlorine Pesticides and PCBs,SW846 Method 8080

4 Metals by ICP, SW846 Method 6010

5 Metals by Graphite Furnace AA,SW846 7000 Series Methods

- 6 - Mercury by Cold Vapor AA, SW846 Method 7471

7 General Chemistry

8 Volatile Organics, USEPA 3/90 SOW

9 Semivolatile Organics, USEPA 3/90 SOW

10 Metals by ICP, USEPA SOW

11 Metals by Graphite Furnace AA, USEPA SOW

12 Mercury by Cold Vapor AA, USEPA SOW

1.3 Corrective action procedures are presented in Section 3 of this SOP as guidancewhen criteria described in Attachments 1 through 12 are out of acceptance limits.

101 AR305232


2.0 PROCEDURE

2.1 The ultimate responsibility for quality inspection rests with the Quality AssuranceOfficer. The review of Quality Control criteria is performed in a tiered approach. Thefirst level of review is performed by the analyst conducting the test,, the next tier ofreview rests with the department supervisor and the final tier of review is performed bythe Quality Assurance Officer.

2.2 Environmental samples are analyzed by different methodologies within a department.The analyst determines which methodology is to be followed before initiating theanalysis. Instrument tunes and calibrations are conducted in accordance with themethod. If any criteria do not completely satisfy the method requirements for tune andcalibration, the analyst stops and rectifies the problem in accordance with the specificanalytical SOP. The analyst may seek the assistance of the supervisor.

2.3 The root cause for a nonconformance to method criteria may either be local orsystematic. A local nonconformance requires a solution which is isolated to a particularinstrument and is readily rectified. A systematic nonconformance is normally presentacross all instruments in a department. Local nonconformance may be rectified by theanalyst alone or by the analyst and the department supervisor. If at any time a systematicnonconformance is suspected, the Quality Assurance Officer is notified and the QAO,department supervisor and one or more analysts initiate a corrective action investigationto isolate and eliminate the root cause of the nonconformance.

2.4 Analysis of samples may occur only after the cause of the nonconformance has beeneliminated. The analyst proceeds to acquire data in accordance with the method beingfollowed. After an analytical sequence is complete, each sample is reviewed todetermine if it meets the method criteria set forth in the analytical SOP. Specific criteria-may vary from method to method and include but are not limited^o analytical acquisitionoccurring within a specified clock, areas of internal standards, surrogate recoverieswithin acceptable limits, post digestate spike recoveries within limits and absence ofcontamination in the laboratory blank.

2.5 Particular attention is paid to the Quality Control samples which were run. Thesesamples are subject to the same criteria as typical samples but also give indications oflocal or systematic nonconformance. An analyst need not notify the departmentsupervisor if the laboratory blank, Matrix Spike, Matrix Spike Duplicate and Blank Spikesamples are within method specifications or within the laboratory's control limits asestablished by the Shewhart Charts. The method being employed determines whetherlaboratory established or method established criteria are to be used. If any of thesesamples are outside acceptable limits the department supervisor is notified and reportingof all samples associated with the QC samples is writhed pending a determination as tothe cause of the nonconformance.

102 BR305233


2.6 Whenever a nonconformance is reported, the supervisor collects all relevantinformation relating to the analysis in order to follow a logical path to sound judgment.The supervisor first determines if the nonconformance is local or systematic. If asystematic nonconformance is suspected, the Quality Assurance Officer is notified and acorrective action investigation is initiated. Typically, samples will be re-extracted andrerun if sufficient sample exists to confirm local nonconformance. The QualityAssurance Officer has the final authority and say if there is a disagreement.

2.7 The correction of a local nonconformance is documented in the analytical runlogbook.

2.8 All instances of nonconformance are explained on the jobs Non-ConformanceSummary which is kept in the job specific folder in the Data Management Office.

2.9 Periodically, random, unannounced comprehensive QA audits are conducted by theQuality Assurance Officer.

3.0 CORRECTIVE ACTIONS

3.1 Corrective Actions are taken based upon QA Checklists presented in Attachments 1through 12. The type of action that may be taken is based upon an overall assessment offactors relating to a particular testing program and when a problem is discovered i.e. isthe sample still within its holding time).

3.2 The corrective action most frequently required when a question in Attachments 1through 12 is answered "no" is to reject the results and re-analvzed the samples. Thisassumes that the specific problems noted in the QA Checklist is discovered when thesample is within holding time. Accordingly the first round of QA review is performed bythe analyst conducting the test and resolved with their supervisor.

3.3 Corrective action taken if it is discovered that a sample exceeds holding timeincludes contacting the client to determine if new samples that are within holding time areavailable. If new samples are available perform analysis within holding time, if not noteholding time nonconformance in the case narrative or nonconformance summary.

AH30523U103

ENVIROTECH RESEARCH, INC. '%/|.

Attachment 1

QA Checklist - Volatile Organics, SW846 Method 8240

Yes No

I. For soil or water samples preserved with Hcl upon sample collection, wasanalysis conducted within 14 days of sample collection and was the pH of the•water samples recorded in the sun log?For un-preserved water samples, was analysis conducted within 7 days ofsample collection?

2. Did every analytical sequence commence run at standard injection of 50 ngof BFB that met the method specified criteria?

3. Was a 5 point initial calibration run at standard concentrations of 10,20,50, 100 and 200 ppb and did this calibration range meet the method specifiedcriteria for Minimum RF and Maximum %RSD and were SurrogateCompounds added to the standards at these concentrations?

4.1f a continuing calibration check standard was run, was it run at the midpointof the initial calibration range, did it meet the method specified criteria forMinimum RF and Maximum %D and were all subsequent samples quantitated.using the RFs generated by the continuing calibration check?

5.Did the method blank contain less than the MDL for all target compounds,except for the Methylene Chloride, 2-Butanone and Acetone, which must beless than or equal to 3 times the MDL?

6.Were the standard or standards run immediately after the BFB?

7.Was the method blank run immediately after the standard or standards?

8. Were all subsequent samples injected within 12 hours of the BFB injectiontime?

9.Were the following Internal Standards used at the following concentrationsin all standards, samples, blanks and QA samples?

1. Bromochloromethane - 50 ppb2. 1,4-Difluorobenzene - 50 ppb3. Chlorobenzene - d5 - 50 ppb

104 AR305235


Yes No

Attachment 1


10. Were the compounds quantitated against the method specified internalstandard?

11. Were the Internal Standard areas within -50% to +100% of the InternalStandard area of the calibration standard?

12. Were the following Surrogate Compounds added to all samples, blanksand Q A samples at the following concentrations?

1. l,2-Dichloroethane-d4 -50 ppb2. Toluene-d8 - 50 ppb3. Bromofluorobenzene - 50 ppb

13. Were the surrogate recoveries within laboratory control limits?

14. If either the Internal Standard areas or Surrogate Compound recoverieswere outside acceptable limits, was the sample re-analyzed to confirm thematrix interferences?

15. Was at least one Matrix Spike/Matrix Spike Duplicate pair run per 20environmental samples per matrix and were the following compound spikedat the following concentrations?

1.1,1-Dichloroethene - 50 ppb.2. Trichloroethene - 50 ppb3. Benzene - 50 ppb4. Toluene - 50 ppb5. Chlorobenzene - 50 ppb

16. Were all environmental samples analyzed within 28 days of their relatedMS/MSD?

17. Are the chromatograms adequately resolved, not overloaded and free ofcarryover?

105 AR305236

^ENVIROTECH RESEARCH, INC. ^

Attachment 1


Yes No '

_ _ 18. Were RT and/or mass spectral identification criteria met?

_ _ 19. Were all detected analytes within the linear range of the instrument?

_ _ 20. Have all calculations involving dilutions been spot checked?

_ _ 21. Was the purge heated to 40°C for low level soil analyses?

106 AJR3Q5237


Attachment 2

QA Checklist - Semivolatile Organics, SW846 Method 8270

1. Were soil samples extracted within 14 days of sample collection and wasanalysis performed within 40 days of sample extraction?Were water samples extracted within 7 days of sample collection and wasanalysis performed within 40 days of sample extraction?

2. Did every analytical sequence commence with an injection of 50 ng ofDFTPP that met the method specified criteria?

3. Was a 5 point initial calibration run at standard concentrations of 10,20, 50,80 and 120 ppm and did this calibration range meet the method specifiedcriteria for Minimum RF and Maximum %RSD and were SurrogateCompounds added to the standards at these concentrations?

4. If a continuing calibration check standard was run, was it run at themidpoint of the initial calibration range and did it meet the method specifiedcriteria for Minimum RF and Maximum %D?

" 5. Did the method blank contain less than the MDL for all target compounds,except for the phthalate esters, which must be less than or equal to 3 times theMDL?

6. Were the standard or standards run immediately after the DFTPP?

7. Were all subsequent samples injected within 12 hours of the DFTPPinjection time?

8. Were the following Internal Standards used at the following concentrationsin all standards, samples, blanks and QA samples?

1. l,4-Dichlorobenzene-d4 -40 ppm2. Naphthalene-d8 -40 ppm3. Chysene-dl2 -40 ppm4. Acenapthene-dlO -40 ppm5. Phenanthrene-d 10 -40 ppm6. Perylene-dl2 -40 ppm

AR305238107


Yes Ho

Attachment 2



10. Were the Internal Standard areas within - 50% to +100% of the InternalStandard area of the calibration standard?

11. Were the following Surrogate Compounds added to all low level samples,blanks and QA samples at the following concentrations?

1. 2-Fluorophenol - 800 ppm x 0.25 ml2. Phenol-d5 -800 ppm x 0.25 ml3. 2,4,6-Tribromophenol -800 ppm x 0.25 ml4. Nitrobenzene-d5 -400 ppm x 0.25 ml5. 2-Fluorobephenyl -400 ppm x 0.25 ml6. Terphenyl-dl4 -400 ppm x 0.25 ml

12 Were the following Surrogate Compounds added to all high level samples,-blanks and QA samples at the following concentrations?

1. 2-Fluorophenol - 800 ppm x 0.50 ml2. Phenol-d5 -800 ppm x 0.50 ml3. 2,4,6-Tribromophenol -800 ppm x 0.50 ml4. Nitrobenzene-d5 -400 ppm x 0.50 ml5. 2-Fluorobephenyl -400 ppm x 0.50 ml6. Terphenyl-dl4 -400 ppm x 0.50 ml

13. If either the Internal Standard areas or Surrogate Compound recoveriesoutside acceptable limits, was the sample re-analyzed to confirm the matrixinterference?

14. Was at least one Matrix Spike/Matrix Spike Duplicate pair run per 20 lowlevel environmental samples per matrix and were the following compoundspiked at the following concentrations?

1. Phenol - 800 ppm x 0.25 ml2.2-Chlorophenol - 800 ppm x 0.25 ml3.1,4-Dichlorobenzene - 400 ppm x 0.25 ml

AR305239108


Attachment 2


Yes No

4. N-Nitoso-di-n-propylamine - 400 ppm x 0.25 ml5.1,2,4-Trichlorobenzene - 400 ppm x 0.25 ml6.4-Chloro-3-methylphenol - 800 ppm x 0.25 ml7. Acenaphthene - 400 ppm x 0.25 ml8. 4-Nitrophenol - 800 ppm x 0.25 ml9.2,4-Dinitrotoluene - 400 ppm x 0.25 ml10. Pentachlorophenol - 800 ppm x 0.25 ml11. Pyrene - 400 ppm x 0.25 ml

14. Was at least one Matrix Spike/Matrix Spike Duplicate pair run per 20 highlevel environmental samples per matrix and were the following compound

spiked at the following concentrations?

1. Phenol - 800 ppm x 0.5 ml2. 2-Chlorophenol - 800 ppm x 0.5 ml3. 1,4-Dichlorobenzene - 400 ppm x 0.5 ml

- 4, N-Nitoso-di-n-propylamine - 400 ppm x 0.5 ml5.1,2,4-Trichlorobenzene - 400 ppm x 0.5 ml6. 4-Chloro-3-methylphenol - 800 ppm x 0.5 ml7. Acenaphthene - 400 ppm x 0.5 ml8.4-Nitrophenol - 800 ppm x 0.5 ml9. 2,4-Dinitrotoluene - 400 ppm x 0.5 ml10. Pentachlorophenol - 800 ppm x 0.5 ml11. Pyrene - 400 ppm x 0.5 ml

15 Were all environmental samples prepared within 28 days of their relatedMS/MSD?

16. Are the chromatograms adequately resolved, not overload and free ofcarryover?

17. Were RT and /or mass spectral identification criteria met?

18. Were all detected analytes within the linear range of the instrument?

19. Have all calculations involving dilutions been spot checked?

109 AB3052UO


Yes No

Attachment 3

QA Checklist - Organochlorine Pesticides and PCBsSW846 Method 8080

1. Were soil samples extracted within 14 days of sample collection and wasanalysis performed within 40 days of sample extraction?Were water samples extracted within 7 days of sample collection and wasanalysis performed within 40 days of sample extraction?

2. Were standards, QA samples and samples run on two dissimilar columns?

3. For Pesticide Analysis, was a 5 point initial calibration run on both columnsfor single components and did this calibration range meet the method specifiedcriteria for Maximum %RSD and were Surrogate Compounds added to thestandards?

4. For PCS Analysis, was a 5 point initial calibration run on both columns forArochlor-1016 and Arochlor-1260 and did this calibration range meet themethod specified criteria for Maximum % RSD?

5. If a 5 point calibration was not run within the analytical clock for the singlecomponents or 1016 and 1260, was a successful check standard run against a 5point range for these analytes? -

6. Was a single point run for all other target analytes within the analyticalclock for the purpose of identification?

7. If an analyte other than a single component Pesticide, Arochlor-1016 orArochlor 1260 was identified in a sample, was a successful 5 point initialcalibration run for the analyte or was a successful check standard run against a5 point calibration for that analyte within the analytical clock?

8. For Pesticide Analysis, was an Endrin/DDT standard run on both columnsprior to analysis and did was the breakdown within method specified limits?

9. If an interference was present in the analysis, was the appropriate extractcleanup procedure used?

A.R3052M


Yes No

Attachment 3

QA Checklist - ORGANOCHLORINE Pesticides and PCBsSW846 Method 8080

10. Did the method blank contain less than the MDL for all targetcompounds?

11. Were the following Surrogate Compounds added to all samples, blanksand QA samples at the following concentrations for Pesticide Analysis?

1. Tetrachloro-m-xylene - 10 ppm x 0.05 ml2. Dibutylchlorendate ' -10 ppm x 0.05 ml3. Decachlorobiphenyl -10 ppm x 0.05 ml

12. Were the following Surrogate Compounds added to all samples, blanksand QA samples at the following concentrations for PCB Analysis?

1. Tetrachloro-m-xylene - 10 ppm x 0.05 ml2. Dibutylchlorendate - 10 ppm x 0.05 ml3. Decachlorobiphenyl - 10 ppm x 0.05 ml

13. Were the surrogate recoveries within laboratory control limits?

14. Was at least one Matrix Spike/Matrix Spike Duplicate pair run forPesticide Analysis per 20 environmental samples per matrix and were thefollowing compound spiked at the following concentrations?

1. Lindane - 20 ppm x 0.1 ml2. Heptachlor - 20 ppm x 0.1 ml3. Aldrin - 20 ppm x 0.1 ml4. Dieldrin • 20 ppm x 0.1 ml5. Endrin - 20 ppm x 0.1 ml6. 4,4'-DDT - 20 ppm x 01.2 ml

15. Was at least one Matrix Spike/Matrix Spike Duplicate pair run for PCBAnalysis per 20 environmental samples per matrix and were the followingcompound spiked at the following concentrations?

1. Arochlor-1016 - 100 ppm x 0.05 ml2. Arochlor-1260 - 100 ppm x 0.05 ml

AR3Q52i*2


Yes No

Attachment 3

QA Checklist - Organochlorine Pesticides and PCBsSW846 Method 8080

16. Were all environmental samples prepared within 28 days of their relatedMS/MSD?


18. WereRT identification criteria met on both the primary and confirmationcolumns?



AR3G52U


Yes No

Attachment 4

QA CHECKLIST - Metals by ICP, SW846 Method 6010

1. Were all samples digested and analyzed within 180 days of samplecollection?

2. Were QC samples (e.g. Laboratory Control Sample, Prep Blank, SpikeSample, Spike Sample Duplicate and Sample Duplicate) digested with eachbatch of 20 environmental samples?

3. Was the instrument calibrated with a minimum of 3 standards?

4. Was an Initial Calibration Verification run prior to sample analysis run?

5. Was an Initial Calibration Blank run after each Initial CalibrationVerification?

6. Was the high standard analyzed at the beginning of the sample analysis runand were the results±5% of the true value?

-7. Were Interference Check Samples (ICSA and ICSAB) run at the beginningand end of sample analysis run?

8. Was a Continuing Calibration Verification run after a maximum of 10samples?

9. Was a Continuing Calibration Blank run after each Continuing CalibrationVerification?

10. Did the Initial Calibration Verification/Continuing CalibrationVerification meet the 10% control limit?

11. absolute value of the Initial Calibration Blank/Continuing CalibrationBlank less than the MDL?

12. Were the results of the ICSAB within 20% of the true value?

13. Was each sample within the calibration range?

rtENVIROTECH RESEARCH, INC.

Yes No

Attachment 4

QA CHECKLIST - Metals by ICP, SW846 Method 6010

14. Did the Prep Blank meet criteria i.e. were the results less than the absolutevalue the MDL?

15. If the Prep Blank did not meet criteria, was the entire prep batch re-digested and reanalyzed?

16. Were MS/MSD recoveries within 75-125% limit?

17. Was MS/MSD RPD less than 20%?

18. Was a Post Analysis Spike run to demonstrate the absence of interference?

19. Was the Laboratory Control Sample within QC Limits?

20. Was Sample/Duplicate RPD less than 20%?

21. Was a Serial Dilution run for each batch of samples to show the absence ofinterferences?

22. Were the results of the Serial Dilution within 10% of the originaldetermination?

114 AR3052U5

.V*ENVIROTECH RESEARCH, INC.

Attachment 5

QA CHECKLIST - Metals by Graphite Furnace AA,SW846 7000 Series Methods

*

GRAPHITE FURNACE:

Yes Ho

_ _ 1. Were all samples digested and analyzed within 180 days of samplecollection?

_ _ 2. Were QC Samples (e.g. Laboratory Control Sample, Prep Blank, SpikeSample, Spike Sample Duplicate and Sample Duplicate) digested with eachbatch of 20 environmental samples?

_ 3. Were calibration standards and calibration check standards prepared daily?

_ _ 4. Was the instrument calibrated with a minimum of 5 standards?

_ _ 5. Was each calibration standard injected in triplicate?

_ _ 6. Was an Initial Calibration Verification run prior to sample analysis run?

_ 7. Was an Initial Calibration Blank run after each Initial CalibrationVerification?

_ _ 8. Was a Continuing Calibration Verification run after each 20 sampleinjections?

_ _ 9. Was a Continuing Calibration Blank run after each Continuing CalibrationVerification?

_ _ 10. Did the Initial Calibration Verification/Continuing Calibration Verificationmeet the 10% control limit?

_ _ 11. Was the absolute value of the Initial Calibration Blank/ContinuingCalibration Blank less than the MDL?

_ _ 12. Was each sample digestate injected in duplicate?

-•_ _ 13. Was the duplicate injection less than 20% RPD?

_ __ 14. Was each sample within the calibration range?

AR.3G52l*6- 115

Attachment 5

QA CHECKLIST - Metals by Graphite Furnace AA,SW846 7000 Series Methods

GRAPHITE FURNACE:

Yes No

15. Was each sample post spiked?

16. Was the post spike recovery within 85-115?

17. If the post spike recovery was not within acceptable limits, was the samplerun by Method of Standard Addition?

18. Were Method of Standard Addition requirements met?

19. Did the Prep Blank meet criteria i.e. were results less than the absolutevalue of the MDL?

20. If the Prep Blank did not meet criteria, was the entire prep batch re-"digested and re-analyzed?

21 Were MS/MSD recoveries within 75-125% limit?



24 Was the Laboratory Control Sample within QC limits?

flR3052i<7


Attachment 6

QA CHECKLIST - Mercury by Cold Vapor AA, SW846 Method 7471

COLD VAPOR:

Yes No


2. Were QC Samples (e.g. Laboratory Control Sample, Prep Blank, SpikeSample, Spike Sample Duplicate and Sample Duplicate) digested with eachbatch of 20 environmental samples?





7.Was a Continuing Calibration Blank run after each Continuing CalibrationVerification?

8. Did the Initial Calibration Verification/Continuing Calibration Verificationmeet the 20% control limit?

9. Was the absolute value of the Initial Calibration/Continuing CalibrationBlank less than the MDL?


11. Did the Prep Blank meet criteria i.e. were the results less than the absolutevalue of the MDL?

ftR3052l»8

ENVIROTECH RESEARCH, INC. I

Attachment 6

QA CHECKLIST - Mercury by Cold Vapor AA, SW846 Method 7471

COLD VAPOR:

12. If the Prep Blank did not meet criteria, was the entire prep batch re-digested and re-analyzed?

13. Were MS/MSD recoveries within 75-125% limit?



16. Was the Laboratory Control Sample within QC litmus?


Yes No

Attachment 7

QA CHECKLIST - GENERAL CHEMISTRY

1. Were all samples extracted and analyzed within the appropriate holdingtimes?

2. Were acceptable calibration standards run?

3. Did the method blank contain less than the MDL of the target analyte?

4. If applicable, was an MS/MSD or MS/DUP analyzed and was the recoverywithin laboratory limits?

5. If applicable, were all environmental samples prepared within 28 days oftheir related MS/MSD or MS/DUP?

6. Were all analyte concentrations within the linear range of the instrumentbeing used?


119 AR305250

y * ,-esENVIROTECH RESEARCH, INC.

Attachment 8

QA CHECKLIST - Volatile Organics, USEPA SOW

1. For soil or water samples preserved with Hcl upon sample collection, wasanalysis conducted within 10 days of verified sample receipt and was the pHof the water samples recorded in the run log?

2. Did every analytical sequence commence with an injection of 50 ng of BFBthat met the method specified criteria?

3. Was a 5 point initial calibration run at standard concentrations of 10, 20, 50,100 and 200 ppb and did this calibration range meet the method specifiedcriteria for Minimum RF and Maximum %RSD and were System MonitoringCompounds added to the standards at these concentrations?

4. If a continuing calibration check standard was run, was it run at themidpoint of the initial calibration range, did it meet the method specifiedcriteria for Minimum RF and Maximum %D and were all subsequent samplesquantitated using the RFs generated by the continuing calibration check?

5. Did the method blank contain less than th eCRQL for all target compounds,except for the Methylene Chloride, 2-Butanone and Acetone, which must beless than or equal to 5 times the CRQL. If the analysis is being done for theNJ Laboratory Services contract, Methylene Chloride, 2-Butanone andAcetone must be less than or equal to 3 times the CRQL.?

6. Were the standard or standards run immediately after the BFB?

7. Was the method blank run immediately after the standard or standards and ifthe analysis was being conducted for the NJ Lab Services contract, was anaqueous blank used?

8. Were all subsequent samples injected within 12 hours of the BFB injectiontime?

9. Were the following Internal Standards used at the following concentrationsall standards, samples, blanks and QA samples?

l.Bromochloromethane 50 ppb2. 1,4-Difluorobenzene 50 ppb3. Chlorobenzene - d5 50 ppb

120 AR30625I


Attachment 8

QA CHECKLIST - CLP 3/90 - VOAs

YjsHo .

_ _ 10. Were compounds quantitated against the method specified internalstandard?

_ _ 11. Were the Internal Standard areas within-50% to+100% of the InternalStandard area of the calibration standard?

_ _ 12. Were the following System Monitoring Compounds added to all samples,blanks and QA samples at the following concentrations?

1. l,2-Dichloroethane-d4 - 50 ppb2. Toluene-d8 - 50 ppb3. Bromofluorobenzene - 50 ppb

_ _ 13. Were the System Monitoring Compound within contract required limits?

_ _ 14. If either the Internal Standard areas or System Monitoring Compoundrecoveries outside acceptable limits, was the sample re-analyzed to confirm thematrix interference?

_ _ 15. Was at least one Matrix Spike/Matrix Spike Duplicate pair run per 20environmental samples per matrix and were the following compound spiked atthe following concentrations?

1.1,1-Dichloroethene - 50 ppb2. Trichloroethene - 50 ppb3. Benzene - 50 ppb4. Toluene - 50 ppb

- 5. Chlorobenzene -50 ppb

_ _ 16. Were all environmental samples analyzed within 14 days of their relatedMS/MSD?

_ _ 17. Are the chromatograms adequately resolved, not overloaded and free ofcarryover?

_ 18. Were RT and/or mass spectral identification criteria met?

121 RR305252


Attachment 8

QA CHECKLIST - CLP 3/90 - VOAs



21. Was the purge heated to 40°C for low level soil analyses?

122 AR3Q5253

iif%ENVIROTECH RESEARCH, INC.

Attachment 9

QA CHECKLIST - Semivolatile Organics, USEPA SOW

YjiNo

_ _ 1 . Were soil samples extracted within 10 days of verified sample receipt andwas analysis performed within 40 days of sample extraction?Were water samples extracted within 10 days of verified sample receipt andwas analysis performed within 40 days of sample extraction?

_ _ 2. Did every analytical sequence commence with an injection of 50 ng ofDFTPP that met the method specified criteria?

_ _ 3. Was a 5 point initial calibration run at standard concentrations of 10, 25, 40,60 and 80 ppm and did this calibration range meet the method specifiedcriteria for Minimum RF and Maximum %RSD and were SurrogateCompounds added to the standards at these concentrations?

_ _ 4. If a continuing calibration check standard was run, was it run at the 25 ppmconcentration and did it meet the method specified criteria for Minimum RFand Maximum %D?

_ _ 5. Did the method blank contain less than of equal to the CRQL of every target.compound except the phthalate esters, which must be less than of equal to 5times the CRQL? If the analysis is being done for the NJ Laboratory Servicescontract, the phthalate esters must be less than or equal to 3 times the CRQL.

_ _ 6. Were 2 ul injected for all the standards, QA samples and environmentalsamples?

_ _ 7. Were the standard or standards run immediately after the DFTPP?

_ _ 8. Were all subsequent samples injected within 12 hours of the DFTPPinjection time?

_ _ 9. Were the following Internal Standards used at the following concentrationsin all standards, samples, blanks and QA samples?

1. l,4-Dichlorobenzene-d4 - 20 ppm.2. Naphthalene-d8 - 20 ppm3 . Chysene-d 12 - 20 ppm4. Acenapthene-dlO - 20 ppm5. Phenanthrene-dlO - 20 ppm6. Perylene-dl2 -20 ppm

AJR305251*


Attachment 9



11. Were the Internal Standard areas within -50% to +100% of the InternalStandard area of the calibration standard?

12. Were the following Surrogate Compounds added to all samples, blanksand QA samples at the following concentrations?

1) 2-Fluorophenol -150 ppm x 0.5 ml2) Phenol-d5 -150 ppm x 0.5 ml3) 2-Chlorophenol-d4 -150ppmx0.5.ml4) Nitrobenzene-d5 -100 ppm x 0.5 ml5) 2-Fluorobiphenyl -100 ppm x 0.5 ml

- 6) l,2-Dichlorobenzene-d4 -100 ppm x 0.5 ml7) Terphenyl-d 14 -100 ppm x 0.5 ml8) 2,4,6-Tribromophenol -150 ppm x 0.5 ml

13. Were the surrogate recoveries within contract required control litmus?

14. If either the Internal Standard areas or Surrogate Compound recoveriesoutside acceptable limits, was the sample re-analyzed to confirm the matrixinterference?

124 AJR305255

ENVIROTECH RESEARCHING.

Attachment 9


15. Was at least one Matrix Spike/Matrix Spike Duplicate pair run per 20environmental samples per matrix and were the following compound spiked atthe following concentrations?

Phenol - 150 ppm x 0.5 ml2-Chlorophenol - 150 ppm x 0.5 ml1,4-Dichlorobenzene - 100 ppm x 0.5 mlN-Nitoso-di-n-propylamine - 100 ppm x 0.5 ml1,2,4-Trichlorobenzene - 100 ppm x 0.5 ml4-Chloro-3-methylphenol - 150 ppm x 0.5 mlAcenaphthene - 100 ppm x 0.5 ml4-Nitrophenol - 150 ppm x 0.5 ml2,4-Dinitrotoluene - 100 ppm x 0.5 mlPentachlorophenol - 150 ppm x 0.5 mlPyrene - 100 ppm x 0.5 ml

16. Were all environmental samples prepared within 14 days of their relatedMS/MSD?


18. Were RT and/or mass spectral identification criteria met?]



12g &R305256


ICP:

Yes No

Attachment 10

QA CHECKLIST - Metals by ICP, USEPA SOW


2. Were QC samples (e.g. Laboratory Control Sample, Prep Blank, SpikeSample and Sample Duplicate) digested with each batch of 20 environmentalsamples?




6. Was a CRT run at the beginning and end of sample analysis run?

7. Were Interference Check Samples (ICSA and ICSAB) run at the beginningand end of sample analysis run?




11. Was the absolute value of the Initial Calibration Blank/ContinuingCalibration Blank less than the CRDL?

12. Were the results of the ICSAB within 20% of the true value?

126 AR305257


Attachment 10

QA CHECKLIST - Metals by ICP, USEPA SOW

ICP:

Me ._ 13. Was each sample within the calibration range?

_ 14. Did the Prep Blank meet criteria i.e. were results less than the absolutevalue of the CRDL?

_ 15. If the Prep Blank did not meet criteria, was the entire prep batch re-digested and re-analyzed?

_ 16. Was MS recovery within 75-125% limit?

_ • 17. If MS Recovery was outside the QC limit was a Post Spike run?

_ 18. Was the Laboratory Control Sample within QC Limits?

_ 19. Was Sample/Duplicate RPD less than 20%?

_ 20. Was a Serial Dilution run for each batch of samples?

_ 21. Were the results of the Serial Dilution within 10% of the originaldetermination?

127 AE305258

1ENVIROTECH RESEARCH, INC.

Attachment 11

QA CHECKLIST - Metals by Graphite Furnace AA, USEPA SOW

GRAPHITE FURNACE:

1 . Were all samples digested and analyzed within 1 80 days of samplecollection?

2. Were QC Samples (e.g. Laboratory Control Sample, Prep Blank, SpikeSample and Sample Duplicate) digested with each batch of 20 environmentalsamples?

3. Were calibration standards and calibration check standards prepared daily?


5. Was each calibration standard injected in duplicate?

6. Was the duplicate injection less than 20% RPD?

7. Were the results of the standard analysis within 5% of the true value?



10. Was a Contract Required Detection Limit Analysis run prior to sampleanalysis run?

11. Was a Continuing Calibration Verification run after a maximum of 20injections?


13. Did the Initial Calibration Verification/Continuing CalibrationVerification meet the 10% control limit?

128 AB305259

s


Attachment 11

QA CHECKLIST - Metals by Graphite Furnace AA, USEPA SOW

GRAPHITE FURNACE:

Yes No

14. Was the absolute value of the Initial Calibration Blank/ContinuingCalibration Blank less the CRDL?

15. Was each sample digestate injected in duplicate?

16. Was the duplicate injection less than 20% RPD?


18. Was each sample post spiked?

19. Was the post spike recovery within 85-115?

20. If the post spike recovery was not within acceptable limits, was the samplerun by Method of Standard Addition?

21. Were Method of Standard Addition requirements met?

22. Did the Prep Blank meet criteria i.e. are results less than the absolute valueof the CRDL?

23. If the Prep Bland did not meet criteria, was the entire prep batchre-digested and re-analyzed?

24. Was MS recovery within 75-125% limit?


26. Was the Laboratory Control Sample within QC Limits?

129 AH305260


Attachment 12QA CHECKLIST - Mercury by Cold Vapor AA, USEPA SOW

COLD VAPOR:

Yes Ho


2. Were QC Samples (e.g. Laboratory Control Sample, Prep Blank, SpikeSample and Sample Duplicate digested with each batch of 20 environmentalsamples?-




6. Was a Contract Required Detection Limit Analysis run prior to sampleanalysis run?


8. Was a Continuing Calibration Blank run after each Continuing CalibrationVerification? . ...


10. Was the absolute value of the Initial Calibration Blank/ContinuingCalibration Blank less than the CRDL?


12. Did the Prep Blank meet criteria i.e. were the results less than the absolutevalue of the CRDL?

130 AR30526I


Attachment 12QA CHECKLIST - Mercury by Cold Vapor AA, USEPA SOW

COLD VAPOR:

Yes No

13. If the Prep Blank did not meet criteria, was the entire prep batchre-digested and re-analyzed?

14. Was MS recovery within 75-125% limit?

15. Was Sample/Duplicate RDP less than 20%?

16. Was the Laboratory Control Sample within QC limits?

131 AH305262


ENVIROTECH RESEARCH SOP No. Dl'OOSTANDARD OPERATING PROCEDURE FOR

DATA MANAGEMENT AND HANDLING PROCEDURES

doc: D100Revision: B

132 AR305263



1.1. This SOP outlines the steps taken to eliminate data entry errors and to maintainthe security of the databases and data systems.

1.2. The mechanism for tracking sections of data packages is also discussed.

2. PROCEDURE

2.1. CONTROLLING AND ESTIMATING DATA ENTRY ERRORS

2.1.1. The data reporting system is designed to input analytical results directlyfrom analytical instruments via a network. This minimizes the number oftranscriptions which in turn minimizes the potential for a reporting error.

2.1.2. Reviewed, processed data is uploaded from instruments to the appropriatereporting database.

2.1.3. Data that must be manually entered is checked by an individual other thanthe person who entered the data. Any errors found are highlighted with ared marker and the corner of the page is turned down so. that it cannot beused again. The corrected page is checked against the original after thecorrection is made.

.2.2. REVIEWING CHANGES TO DATA AND DELIVERABLES AND. ENSURING TRACEABILITY OF UPDATES

2.2.1. All data in the Document Management Office including data which is tobe used in the production of the data report is the responsibility of theDocument Control Officer.

2.2.2. Data repositories such as instrument run logs, extraction logbooks andmaintenance logs are kept in bound, paginated books. The signature of theresponsible analyst is subjected to verification by the respectivesupervisor. Logbooks which become filled are stored in a secured cabinetin the laboratory.

2.2.3. As data is produced, it may be tracked through an individual departmentby means of the information contained in the job folder and the run logs orextraction logs maintained in the individual department.

133 AR30526ii


2.2.4. The reporting databases are secured by means of a password protectionsystem that accounts for any changes that are made to the database. Anaudit trail is created to reconstruct what changes were made and who madethem.

2.2.5. The job folder acts as the repository for all data pertaining to the specificgroup of samples. After the report is sent out, the Document .ControlOfficer archives the job folder in increasing job number order. The jobfolders are kept on site for a period of not less than five years and areeasily accessible if information is requested at a later date.

2.3. TESTING, MODIFYING, AND IMPLEMENTING CHANGES TO EXISTINGCOMPUTER SYSTEMS INCLUDING HARDWARE, SOFTWARE, ANDDOCUMENTATION OR INSTALLING NEW SYSTEMS.

2.3.1. All modifications to computer systems or new system installations arecoordinated by the System Manager.

2.3.2. Initially, a meeting is held with but not limited to the System Manager,Lab Manager, Quality Control Officer, and pertinent departmentsupervisors. System enhancements and development are discussed andorganized at this meeting. Upon satisfactory agreement of all parties, thescope of the development is defined.

.2.3.3. Testing is performed throughout the development cycle by thedevelopment staff. Depending on the scope of the System DevelopmentProject, lab personnel will be involved with testing either throughout thedevelopment cycle or at the end for final testing and approval.

2.3.4. Where possible, any new or modified systems are tested side-by-side withexisting systems to ensure accuracy and to limit the introduction of newand unforeseen 'bugs.'

2.3.5. Documentation is maintained during the development cycle for systemadministration and maintenance purposes. End-user documentation iscreated at the end of the cycle to be included with any end-user trainingneeded. In addition, any SOPs which are affected by these changes aremodified.

2.3.6. Finally, upon approval of the Lab Manager and the Quality ControlOfficer, the new development or modifications are implemented andbecome standard operating procedure.

134 AR305265


2.4. DATABASE SECURITY, BACKUP AND ARCHIVAL

2.4.1. All electronic data is archived from analytical instruments and datareporting databases using a variety of media ranging from cassette tapesfor GC and GC/MS data to cassette tapes and floppy disks for metals data.Archived data is indexed and cross referenced to instrument run logs tofacilitate retrieval if necessary.

2.4.2. All data is archived in duplicate. One copy is maintained at the mainfacility for quick retrieval and the other copy is maintained at a remotelocation for disaster recovery.

2.4.3. Database security is maintained by limiting access rights throughpassword protection. In general, users are granted the minimum amountof privilege needed to perform their respective job functions.

2.4.4. Audit Trails are maintained on all databases to monitor data manipulationand modifications.

2.5. SYSTEM MAINTENANCE

2.5.1. All routine maintenance procedures are documented in a manual which ismaintained by the System Manager. This manual contains step-by-stepprocedures for administering critical system activities including; backups,retrievals, user maintenance, and security procedures.

Hardware

2.5.2. Data systems are continually monitored by the System Manager to ensureproper operation and full functionality.

2.5.3. Where critical, redundancies are built-in to the system to maintain fullsystem operation in the event of a critical hardware failure. Theseredundancies usually involve maintaining a backup system, which canreplace a main system until that main system is repaired or replaced.

2.5.4. Where possible and cost-effective, replacement hardware is stock-piled foremergency.

2.5.5. Backup systems are routinely tested, specifically when normal systemmaintenance requires the shutdown of the main systems.

135 AR305266


2.5.6. Maintenance contracts are maintained with vendors for all criticalhardware.

2.5.7. Response times for in-house maintenance are not more than six hours.Response times for maintenance contracts are not more than 24 hours.

2.5.8. All systems are protected against electronic surges or spikes and criticalsystems are protected by Uninterruptible Power Supplies in the event ofpower failures.

Software

2.5.9. Telephone support contracts are maintained with vendors for all criticalsystems software. Response time for critical problems is not more than 4hours

2.5.10. A close working relationship is maintained with all critical softwarevendors to ensure software compliance with all methods and certifications.

2.5.11. Custom software is developed and maintained by the in-house staff, wherea suitable third-party package can not be found.

,2.5.12. All electronic media which enters or leaves the lab, is checked against thelatest anti-virus software packages.

2.6. SYSTEM MANAGEMENT RESPONSIBILITY

2.6.1. SYSTEM MANAGER

Responsibilities include:

2.6.1.1. The maintenance of all system hardware including but notlimited to; computers, network hardware, printers, and otherperipherals

2.6.1.2. Ensuring the proper operation, installation, and availability ofall software such as; database management systems, datareporting, data acquisition, general office packages, operatingsystems, and network operations.

2.6.1.3. The operation and availability of the computer network

2.6.1.4. Data backup, archival, and retrieval.

136 AR305267


2.6.1.5. System and Database Security.

2.6.1.6. Evaluation, acquisition, and implementation of new systems andsoftware.

2.6.1.7. All in-house software development

2.6.1.8. Technical and Software Support

2.6.1.9. General end-user training.

2.6.2. DATA SYSTEMS ADMINISTRATOR

Responsibilities include:

2.6.2.1. Software compliance with existing Certifications and Contracts

2.6.2.2. Data Integrity

2.6.2.3. Data Systems Operations

2.6.2.4. Data System Support and Training.

2.7. : STAFF TRAINING PROCEDURES

2.7.1. Staff training in data systems is the responsibility of the respectivedepartment supervisor. Where such media exists, training videos ormultimedia presentations are used to introduce the trainee to the datasystem or software application. The user is then given any SOP orsoftware documentation available as additional introduction to the system.

2.7.2. After initial exposure, a system expert will provide one-on-one support tothe trainee detailing the specific operation of the package and how thesystem is to be used to perform the job at hand.

2.7.3. Upon satisfactory completion of the training, the trainee's supervisor willdetermine if the user is ready to work or if more training is needed.

2.7.4. When the new user's training is approved, a password and securityprivileges are assigned and the new user is allowed to work with thesystem.

137 AR305268


ENVIROTECH RESEARCH SOP No. D101STANDARD OPERATING PROCEDURE FORDOCUMENT CONTROL PROCEDURES

doc: D101Revision:

138 flR3°5269



1.1. This procedure addresses the mechanism for centralizing the documents supportinga sample submission and for retrieval of these documents.

1.2. This procedure also addresses the maintenance of all notebooks used in thelaboratory.

2. PROCEDURE

2.1. Accounting for supporting documents for a sample submission

2.1.1. A group of samples submitted for analysis are assigned an EnvirotechResearch Job No. in accordance with SOP No. SI03. The Job No. is theprimary key which is used to retrieve information pertinent to the samplesubmission.

2.1.2. A job folder is created when a group of samples are received. It is kept inthe Document Management Office while the analysis is in progress.Internal and external sample control documents are kept in this folderincluding Chain of Custody documents. Raw instrument data specific tothe samples in the group are also deposited in the job folder. Thesedocuments specify the dates and times the samples were prepared oranalyzed which provides a cross reference to the appropriate laboratorylogbooks.

2.1.3. An individual wishing to retrieve job specific information need only to lookat the job folder. If further information is required, the laboratorynotebooks may be examined by the cross reference provided in the jobfolder. The instrument run logs also give an indexed key to achievedanalytical data stored on reel to reel tape, cassette tape or diskette. Otherdocuments include the following:

Extraction LogsPreventive Maintenance LogsBalance LogsStandards Prep LogsLaboratory Notebooks

139 AR305270


2.1 A. After a job is completed and the final data report is sent to the client, theentire job folder is sequentially archived for not less than five years and iseasily accessible if information is required at a later date.

2.2. Laboratory Logbooks •

2.2.1. The laboratory logbooks provide the most basic and fundamentalinformation about sample preparation and analysis, the various maintenancemeasures taken and standard preparation information. All laboratorynotebooks are bound, paginated filled out in black pen only and subject tosignature authentication procedures.

2.2.2. Separate logbooks are dedicated to separate procedures, functions andinstruments.

2.2.3. The information contained in the logbooks are unique to the operation towhich they are dedicated. Logbooks maintained for sample preparation orinstruments logs will contain the information pertinent to the function theyare used for in accordance with the analytical SOP. These logbooks will allcontain at a minimum, however, the date, sample number and job numberand signature for the responsible party. The logbooks will be maintained ina sequential manner.

2.2.4. Logbooks which become filled are archived in a secured cabinet in thelaboratory.

140 AR3Q527!


Laboratory Certification

Information is enclosed on laboratory certifications and approvals for EnvirotechResearch, Inc. Documentation of these governmental approvals is enclosed, as follows:

Attachment Certification

1 U.S. Army Corps of Engineers Validation

2 State of New Jersey Certification

3 State of New York Certification

4 State of Delaware DNREC Superfund Approval

5 State of Rhode Island License

Laboratory certification insures that standards relating to personnel, facilities, datareporting, testing methodology and quality control procedures meet criteria adopted by the Statesof New Jersey, New York, Delaware and the U.S. Army Corps of Engineers. To maintain thesecertifications Envirotech Research, Inc. has continually analyzed performance evaluationsamples acceptably and has passed intensive laboratory audit programs.

141 AH305272

DEPARTMENT OF THE ARMY• U.S. ARMY CORPS OF ENGINEERS — MRDHTRW MANDATORY CENTER OF EXPERTISE

12565 WEST CENTER ROADOMAHA. NEBRASKA 68144-3869

February 28, 1995

Environmental, Hazardous, Toxicand Radioactive Waste Division

Envirotech Research, Inc.777 New Durham RoadEdison, New Jersey 08817

Gentlemen:

This correspondence addresses the recent evaluation of yourlaboratory by the U.S. Army Corps of Engineers (USAGE) forchemical analysis in support of the USAGE Hazardous and ToxicWaste Program.

Envirotech Research, Inc., has successfully analyzed theproject required performance evaluation (PE) samples as listedbelow:

METHOD_________PARAMETERS______________________MATRIX

8240A Volatile Organics Water

8270A Semi-Volatile Organics Water827OA Semi-Volatile Organics Soil

8080 Pesticides Water8080 PCBs . Water8080 PCBs Soil8150 Herbicides Water

SW-846 Metals - 13 PP + Ba1 WaterSW-846 Metals - 13 PP + Ba1 Soil

418.1 TRPH Water9071/418.1 TRPH Soil

9010 " Cyanide Water

Remirks: 1 Metals-Thirteen Priority Pollutant Metals pluc Baffin: antimony, arsenic, barium, beryllium,cactaiu*, chromtm, copper, lead, mercury, nickel, selenium, silver, thallium, and zinc.

Enclosed for your information is a copy of the LaboratoryInspection and Evaluation Report. Your laboratory has respondedto the deficiencies as noted in the report.

142 A.R305273

-2-

Based on the successful analysis of the project specific PEsamples indicated in the table in paragraph two above and theresults of the laboratory inspection, Envirotech-Research, Inc.,is validated for multimedia sample analysis by the methods listedabove. The period of validation is eighteen (18) months andexpires on July 13, 1996.

USAGE reserves the right to conduct additional laboratoryauditing or to suspend validation status for any or all of thelisted parameters if deemed necessary. It should be noted thatyour laboratory may not subcontract USAGE analytical work to anyother laboratory location without approval of this office. Thislaboratory validation does.not guarantee the delivery of anyanalytical samples from a USAGE Contracting Officer.

If you have any questions or comments regarding thisspecific validation activity, please contact Dr. Anand Mudambi at(402) 697-2571. General questions or comments with regard toyour lab's validation status should be directed to Ms. ElenaWebster at (402) 697-2574.

Sincerely,

\_ y U>te«jlarcia c. Davies, Ph.D.Director, USAGE Hazardous,Toxic and Radioactive WasteMandatory Center of Expertise

Enclosure

AR305271*

DEPARTMENT OF ENVIRONMENTALPROTECTION AND ENERGY

CHRISTINE TODD WHITMAN ROBERT C. SMNN, JR.Governor ' Commissioner

November 17, 1994

Envirotech Research, Inc.Envirotech Research/Div. AFF-EN777 New Durham RoadEdison, N.J. 08817

Manager: Michael J. Urban

Lab ID# 12543

Dear Mr. Urban:Enclosed is your 1994-95 Annual Certified Parameter List.This list replaces the 1993-94 form and must beconspicuously displayed at the laboratory, along with yourpermanent Laboratory Certificate.

Your cooperation in this matter is appreciated.

Sincerely,

Dottie CorrentiAdministrative Analyst IBureau of Revenue

DCP:ch-208Enclosurecc: Jerry Bundy

New Jersey Is An Equal Opportunity Employer • Printed on Recycled and Recyclable Paper

144 flR.305275

STATE OF MEM JERSEY <?;>..DEPARTMENT OF ENVIRONMENTAL PROTECTION .;;,'%

OFFICE OF QUALITY ASSURANCE ^ 'ANNUAL CERTIFIED PARAMETER LIST FOR 1994-1995

£,. AROTECH RESEARCHt INC. (12543) IS CERTIFIED TO PERFORM THE ANALYSESENVIROTECH RESEARCH/DIV.AFF.EN BELOW UNTIL JUNE 30 1995.

DRINKING WATER LABORATORY CERTIFICATION

LIMITED CHEMISTRY

951 PH, GLASS ELECTRODE

952 TOT DISS SOLIDSe TOT RES

METALS

901 BA, ATOMIC ABSORPTION

902 AGV ATOMIC ABSORPTION

903 CUV ATOMIC ABSORPTION

904 FE, ATOMIC ABSORPTION

906 ZN, ATOMIC ABSORPTION

912 HG,MANUAL COLD VAPOR

Slit AS, GRAPHITE FURNACE

915 BAf GRAPHITE FURNACE

916 CD, GRAPHITE FURNACE

917 CR, GRAPHITE FURNACE

913 PB, GRAPHITE FURNACE

920 SE, GRAPHITE FURNACE

921 AG, GRAPHITE FURNACE

PAGE 1 LAB 1254311/15/f3&

RR305276145

•DRINKING WATER LABORATORY CERTIFICATION

METALS

922 CUf GRAPHITE FURNACE••

923 FE, GRAPHITE FURNACE

924 MN, GRAPHITE FURNACE

925 ZN, GRAPHITE FURNACE

954 NA, ATOMIC ABSORPTION

961 BARIUM, ICAP

962 CADMIUM f ICAP

963 CHROMIUM, ICAP

965 SILVER, ICAP

966 COPPER, ICAP

967 IRON, ICAP

966 MANGANESE, ICAP

969 ZINC, ICAP

ORGANICS

, 942 CHLOROPHENOXY ACID HERB

2,4,5-TPCSILVEX)943 TRIHALOMETHANES

CHLOROFORMBROMOFORMBROMODICHLOROMETHANEDIBROMOCHLOROMETHANE

502.2 VOC (PT/GC)

515.1 CHLORINATED HERB. (GC)

524.2 VOC (PT/GC-MS)

PAGE 2 LAB 1254311/15/94

AR305277146

I-WATER POLLUTION LABORATORY CERTIFICATION

LIMITED CHEMISTRY

00010 TEMPERATURE

00076 TURBIDITY

00095 SPECIFIC CONDUCTANCE

00300 DISS OXYGEN-WINKLER

00340 COD

00400 HYDROGEN IQN-PH

00410 ALKALINITY

00436 ACIDITY

00500 TOT SOLIDS

00505 TOT VOLATILE SOLIDS

00530 SUSP SOLIDS

00556 OIL AND GREASE

00610 AF.MCNIA NITROGEN

00615 NITRITE

00630 NITRATE

00650 PHOSPHORUS, TOT AS P04

00660 ORTHOPHQSPHATE AS PQ4-

00665 PHOSPHORUS, TOT AS P

00671 ORTHOPHOSPHATE AS P

00680 ORGANIC CARBON, TOTAL

00681 ORGANIC CARBON, DISSOLVED

00720 CYANIDE, TOTAL

PAGE 3 LAB 1254311/15/94

AR305278147

-HATER POLLUTION LABORATORY CERTIFICATION -V<vi ,'

LIMITED CHEMISTRY ""

00722 CYANIDE, AMEN TO CHLOR

00745 SULFIDE

00900 HARDNESS

00940 CHLORIDE

00945 SULFATE

00951 FLUORIDE, TOTAL

01032 CR HEX

32730 PHENOLS

50060 CHLORINE RESIDUAL

70300 TOT DISS SOLIDS

METALS

00915 CALCIUM (ICAP)

00916 CALCIUM (AA)

00925 MAGNESIUM (ICAP)

00927 MAGNESIUM (AA)

00929 SODIUM (ICAP)

00930 SODIUM (AA)

00935 POTASSIUM (ICAP)

00937 POTASSIUM (AA)

01000 ARSENIC (ICAP)

01002 ARSENIC (AA/GF)

PAGE 4 LAB 1254311/15/94

148 AR3Q5279

•WATER POLLUTION LABORATORY CERTIFICATION

METALS

01005 BARIUM (ICAP)

01007 BARIUM (AA/GF)

01010 BERYLLIUM (ICAP)

01012 BERYLLIUM (AA/GF)

01025 CADMIUM (ICAP)

01027 CADMIUM (AA/GF)

01030 CHROMIUM (ICAP)

01032 CHROMIUM VI (AA)

01034 CHROMIUM (AA/GF)

01035 COBALT (ICAP)

01037 COBALT (AA/GF)

01040 COPPER (ICAP)

01042 COPPER (AA/GF)

01045 IRON (ICAP)

01046 IRON (AA/GF)

01049 LEAD (ICAP)

01051 LEAD (AA/GF)

01055 MANGANESE (ICAP)

• 01056 MANGANESE (AA/GF)

01059 THALLIUM (AA/GF)

01060 MOLYBDENUM (ICAP)

• 01062 MOLYBDENUM (AA/GF)

PAGE 5 LAB 1254311/15/94i/94

AR305280


METALS

01065 NICKEL (ICAP)

01067 NICKEL (AA/GF)

01075 SILVER (ICAP)

01077 SILVER (AA/GF)

01085 VANADIUM (ICAP)

01087 VANADIUM (AA/GF)

01090 ZINC (ICAP)

01092 ZINC (AA/GF)

01097 ANTIMONY (AA/GF)

01102 TIN (AA/GF)

01105 ALUMINUM (ICAP)

01106 ALUMINUM (AA/GF)

01145 SELENIUM (ICAP)

01147 SELENIUM (AA/GF)

01152 TITANIUM (AA/GF)

71900 MERCURY (COLD VAPOR)

ORGANICS

601 PURGEABLE HALOCARBONS(GC)

602 PURGEABLE AROMATICS (GC)

608 PESTICIDES C PCBS (GC)

624 PURGEABLES (GC/MS)

PAGE 6 LAB 1254311/15/94

AJL3-Q528I150


ORGANICS

625 B/N, ACIDS £ PEST (GC/MS)

99007 PESTICIDES39330 ALDRIN39380 DIELDRIN39360 ODD39365 DDE39370DDT39410 HEPTACHLOR39350 CHLQRDANE

THIS LIST MUST BE CONSPICUOUSLY DISPLAYED WITH THE PERMANENTCERTIFICATE AT THE LABORATORY

PAGE 7 LAB 12543

AR305282151

NEW YORK STATE DEPARTMENT OF HEALTH

BARBARA A. DEBUONSA M.&L if.P.H. Commissioner

Expires 12*01 AH April 1, 1996ISSUED April 1, 1995REVISED June 30, 1995

INTERIM CERTIFICATE OF APPROVAL FOR LABORATORY SERVICE

Issued in accordance with and pursuant to section 502 Public Health Low of New York .State

Lab ID No. t 11452 Director* MR. MICHAEL URBANLab Name i ENVIROTECH RESEARCH ISCAddress i 777 NEW DURHAM ROAD

EDISON NJ 08817

is hereby APPROVED as an Environmental Laboratory for the category

ENVIRONMENTAL ANALYSES NON POTABLE HATER

All approved subcategories and/or analytes are listed belowi

Jsi. lydrocarboa Pesticides .• Vastevater KisceJlaneons: Easterner Ketals III? lotrient >4,('-m Broiide . Cold, Total Aiionia (u I)4,t'-M tent. Total Cobalt, Total litrite (as II4JMDT Cyanide, Total JfolfMenoi. Total Xitrate (as I)i nC Color fin, Total Ortbopbospbate (as f)». i Corrosirity Titaaioi, Total Ibospborns, Totalieta-JSC Pbenols TiaJliui. Total Oeiand >Xfllcrfaae Total Oil k Grtitt Total Keeorerable Acrol«j& and Aerylonitrile (ALL) Cbeiieal Oireeg Deiaodilelta-BHC Frdrooen Icn (cEI P/enzidines (ALL! Cbloroobenorr Acid Pesticides (ALL)JjeJdhn 5beci!ic Conductance Chlorinated Hydrocarbons /ALL) laloetbers (ALL)Jndrin aldebyde Sulfide (as 5) rasterater Ketals I (ALL) ' Fastevater Ketals II (ALL)fndrin - Teiperatore Kineral (ALL) Xitroaroiatics and Isopborone (ALL)Jndosolfaa I Oroacic Carbon. Total Vitrosoaiines (ALL) Polynttclear Aroiatics (ALL)Indosulfan II Polrcclorinated fiipbenvls (ALL) Pbtbalate Ksters (ALL) Priority Pollutant Pbenoli (ALL)indosulfas sulfate . hretiblt Arozatics (ALII Puroeable lalocarbcas (ALL) Residue (ALL)flestacblor rcif Additional Coipounds (ALL)ieptacblor epoiidelicdane*ett?ivctlorJcwpceae

Serial No.: 027319 Wadsworth Center for Laboratories and Research

property of the New York State Department of Health. Valid only at the address shown.Must be conspicuously posted. Valid certificate has a red serial number.

DOH-3317 (12/92)RR305283


BARBARA A. DEBUONQ,* JtMR M.P.H. Commissioner

Expires 12.01 AM April 1, 1996ISSUED April lf 1995REVISED June 30, 1995


Issued in accordance with and pursuant to tection 502 Public Health Lav of New York State

Lab ID No. t 11452 Director! MR. MICHAEL URBANLab Name i ENVIROTECH RESEARCH INCAddress t 777 NEW DURHAM ROAD

EDISON NJ 08817

is hereby APPROVED as an Environmental Laboratory for the category•tC 4

ENVIRONMENTAL ANALYSES/ POTABLE WATER

All approved subcategories and/or analytes are listed below trater Joe-totals : Drinking rater Tribaloietbane (ALL) Printline rater Ketals I (ALL) Drinking rater Ketals II (ALL)

JUtahnity Volatile Aroiatics (ALL) Volatile Balocarions (ALL)lalcioi Hardness

Cwroiritr/Jaoride. Totalfitrite lit I)Kitrate (as IIJfrdrooec Ion /nHiSolids. Total PissolredJalttit (as 504)

Serial No.: 027320 Wadsworth Center for Laboratories and Research

Property of the New York State Department of Health. Valid only at the address shown.Must be conspicuously posted. Valid certificate has a red serial number.

DOH-3317 (UK) A.R30528U

153


BARBARA A. DEBUONQ^ >?*S M.P.H. Commissioner

Expires 12t01 AM April 1, 3.996ISSUED April 1, 1995REVISED June 30, 1995


Issued in accordance with and purtuant to section 502 Public Health Law of New York -State

Lab ID No. i 11452 Director: MR. MICHAEL URBANLab Name t ENVIROTECH RESEARCH INC

• Address t 777 NEW DURHAM ROADEDISON NJ 08817

is hereby APPROVED as an Environmental Laboratory for the categoryma

ENVIRONMENTAL ANALYSES/SOLID AND HAZARDOUS WASTE

All approved subcategories and/or analytes are listed belowtararteristic Testing : Kiscellaneous j Acrolein and Acrylonitrile (EL) Cbloropbeaoiy Acid Pesticides (ALL)Corrosirity Cyanide. Total Cblor. Sydrocarioa Pesticides (ALL) Cblorinated eydroearions (ALL)Joiitability Lead in Paint ialoetben (ALL) Ketals I (ALL)frjjjteity Jydrogen Ion (pfi) Ketals II (ALL) ffitroaroiatics Isopborone (ALL)

V Sulfide /as SI Polysaclear Aroi. Hrdrocarbon (ALL) Polychlorinated lipbenyls (ALL)t. ozicitr Pbtbalate Isters (ALL) Priority Pollutant Phenols (ALL) Portable Aroiatics (ALL)

jreeabJe JaJocarbons 'ALL I

.erial No.: 027321 Wadsworth Center for Laboratories and Research

Property of the New York State Department of Health. Valid only at the address shown.

Must be conspicuously posted. Valid certificate has a red serial number.

DOH-3317 (12/92) A.R305285

NEW YORK STATE DEPARTMENT OF HEALTH.1

BARBARA A. DEBUONOf M.D., M.P.H. Commissioner

Expires 12t01 AM April 1, 1996ISSUED October 5, 1995REVISED October 6f 1995


Issued in accordance with and pursuant to section 502 Public Health Law of New York State

Lab ID No. i 11452 Director/ MR. MICHAEL URBANLab Name: ENVIROTECH RESEARCH INCAddress i 777 NEW DURHAM ROAD

EDISON NJ 08817

is hereby APPROVED as an Environmental Laboratory for the category

- - ..CONTRACT LABORATORY PROTOCOL (CLP)

All approved subcategories and/or analytes are listed belowif Inoraanics CLP PCB/festicides CLP Seii-Folatile Organics CLP Folatile Orjaaics

Serial No.: 031511 Wadsworth Center

Property of the New York State Department of Health. Valid only at the address shown.Must be conspicuously posted. Valid certificate has a red serial number.

BOH0317 (3/93) A.R 3 Q 5 2 8 6lob

STATE OF DELAWAREDEPARTMENT OF NATURAL RESOURCES

AND ENVIRONMENTAL CONTROLDIVISION OF AIR AND WASTE MANAGEMENT

715GRANTHAM LANEWASTE MANAGEMENT SECTION NEW CASTLE. DELAWARE 1972O-A601 TELEPHONE: (3O2) 323 - *54O

SUFERFUND BRANCH , FAX: 002)323-4561

March 3,1993 .

Mark Haulenbeck, Vice PresidentEnvirotech Research Inc.777 New Durham RoadEdison, New Jersey 08817

Subject: HSCA Laboratory Selection

Dear Mr. Haulenbeck:

Thank you for your letter and attachments of January 25, 1993 regarding EnvirotechResearch Inc.'s response to my on-site evaluation report dated January 6,1993. EnvirotechResearch Inc. successfully completed and fulfilled all necessary requirements to be approvedfor analytical services under the Hazardous Substance Cleanup Act for the SuperfundBranch, of the State of Delaware.

Envirotech Research Inc. will be placed on a list of laboratories to provide analyticalsupport to potentially responsible parties or their consultants on Delaware Superfund sites.

Please find enclosed, a copy of the State of Delaware's Standard Operating Procedures forChemical Analytical Programs. I would appreciate any comments that you may havepertaining to this document. I look forward to developing a positive working relationship.If you have any further questions, please call me at (302) 323-4540.

/Robert M. Schulte'Environmental Scientist/Laboratory SpecialistSuperfund Branch

RMS/mlbRMS93022

Enclosure

pc: Stephen N. Williams

APPENDIX TO ANALYTICAL LABORATORY LICENSE # 132________ ./.'"-f' tf>,-. '';ty '

ENVIROTECH RESEARCH, INC

Address: 777 New Durham Road, Edison, NJ 08817

Date Issued: July 1, 1995

Date Expires: June 30, 1997

|. Potable Water;B. Trace Metals: Aluminum; Antimony; Arsenic; Barium; Beryllium; Boron; Cadmium;Chromium; Copper; Lead; Manganese; Mercury; Molybdeum; Nickel; Selenium; Silver;Thallium; Zinc

C. Inorganics: Nitrate as N; Nitrite as N; Fluoride; Residual Chlorine; Turbidity;Total Filterable Solids; Calcium; pH; Alkalinity; Sodium; Corrosivity; SulfateCyanide;

D. Trihalomethanes

H. Herbicides

I. Volatile Organic Compounds:

Nnn-potnhle and Waste Waters;

B. Trace Metals: Aluminum; Arsenic; Beryllium; Cadmium; Cobalt; Chromium; Copper;Iron; Mercury; Manganese; Nickel; Lead; Selenium; Vanadium; Zinc; Antimony; Silver;Thallium; Molybdenum; Strontium; Titanium

C. Minerals: pH; specific Conductance; Total Dissolved Solids; Hardness; Calcium;Magnesium; Sodium; Potassium; Alkalinity; Chloride; Fluoride; Sulfate

D. Nutrients: Ammonia N.; Nitrate N.; Ortho Phosphate; Kjeldahl N.; Total Phosphorus

E. Demands: Chemical Oxygen Demand; Total Organic Carbon; 5-Day BOD; CarbonaceousBOD

AR305289158

F. Miscellaneous: Total Cyanide; NonrFilterable solids; Oil and grease; TotalPhenolics; Total Residual Chlorine

G. PcB's in water Matrix

H. PCB's in oil MatrixI. Chlorinated Hydrocarbon Pesticides

J. Volatile Halocarbons

K. Volatile Aromatics

L. Acid Extractables

M. Base Neutral Extractables

159 AR305290

A £&R30529!

160

..vX


Major Instrumentation and Equipment

7 - Hewlett Packard 5970B mass spectrometers interfaced with 5890A gas chromatographs

4 - Hewlett Packard 1000 computer systems for GC/MS operations and data management

6 - Tekmar ALS VOA purge and trap autosamplers

3 - Hewlett Packard 5 890A gas chromatographs with dual column/dual auto injector capabilityand dual electron capture detectors, each with dedicated computerized Chemstation forinstrument control and data management

2 - Hewlett Packard 5890 Series n gas chromatographs with flame ionization detectors

1 - Hewlett Packard 5890A gas Chromatograph with flame ionization detector and photoionization detector

1 - Hewlett Packard 5 890A gas Chromatograph with flame ionization detector

1 - Hewlett Packard 5890A gas Chromatograph with flame ionization detector and tandemphotoionization detector and electrolytic conductivity detector

1 - Zymark Gel Permeation Cleanup System

1 - Perkin Elmer 5100 atomic absorption spectrophotometer with flame and graphite furnacecapability

1 - Perkin Elmer 4100 graphite furnace atomic absorption spectrophotometer

1 - ARL 3400 inductively coupled argon plasma (ICAP) emission spectrophotometer

1 - Thermo Jarrell Ash ICAP 6 IE "Trace" emission spectrophotometer

1 - Spectro Products cold vapor mercury analyzer

1 - Perkin Elmer 1600 Series Fourier transform infrared spectrophotometer

1 - Dohrman DC-80 Total Organic Carbon analyzer with optional sludge/sediment andpurgeable organic carbon capability

1 - Sequoia-Turner Model 340 spectrophotometer

Full RCRA characteristic testing capability, including: TCLP/ZHE extractors, Setaflashflashpoint tester, Reactivity and Corrosivity test equipment

BR305292


Computing Capabilities

Hardware

Our Local Area Network is comprised of 9 Unix Workstations, a Novell Netware 3.12 Server, 4HP-RTE Minicomputers, and over 35 IBM-type PCs (486 or better).

Software Capabilities

Operating EnvironmentsUnix (HP-UX and SCO)DOS/Windows 3.1

HP-RTE

Network EnvironmentsNovell Netware 3.12

TCPIPlOBaseT-Ethernet

Office SoftwareMicrosoft Word 6.0 for WindowsMicrosoft Excel 5.0 for Windows

Microsoft Powerpoint 4.0 for WindowsAldus PageMaker

Scientific SoftwareHP GC ChemstationHP MS ChemstationHP RTE-Aquarius

Target 3.1Envision 3.2Ward Scientific

Development SoftwarePowerBuilder 4.0

Turbo C-H-

Database Management SoftwareInformixIngres

AH305293162

Computer Location: BNA 1 LabNetwork Wire: L7 Hub Location: T10Motherboard: 80484DX2-66 Ram (MB): 16

Floppy Drivel: Teac1.2MB Floppy Drive 2: Teac 1.44 MbHard Drivel: WD540MB Hard Drive2:

Tape: I/O Card: Generic S/N:WD37CNetwork Card: Novell S/N:086166 Network Address:Video Card: Trident 2Mb SVGA Monitor: Optiquest17"

Mouse: Microsoft Mouse Keyboard: Keytronic101Case: Desktop

Computer Location: BNA 2 LabNetwork Wire: L13 Hub Location: C16Motherboard: 80486DX2-66 Ram (MB): 16

Floppy Drive 1: Teac 1.44 Mb Floppy Drive 2: Teac 1.2 MbHard Drivel: WD 540 MB Hard Drive 2:

Tape: I/O Card: GenericNetwork Card: Novell Network Address:

Video Card: Trident 2Mb SVGA Monitor: Optiquest 17"Mouse: Microsoft Keyboard: KeytronidOlCase: Desktop

&R3Q529U163

Computer Location: BNA 3 LabNetwork Wire: L9 Hub Location:• T13Motherboard: 80486DX4-100 Ram (MB): 16

Floppy Drivel: TEAC 1.44 3.5-W595848 Floppy Drive 2: .Hard Drive 1: WD 425 MB VT681010071 Hard Drive 2:

Tape: I/O Card: VLB IDE 9316600Network Card: Multi-Tech EN301T16-100330 Network Address:Video Card: Trident 2Mb VLP VGA GUIZ432K14702 Monitor: OptiQuest 4000DS 0241201419

Mouse: Kensington Expert Mouse Keyboard: Keytronic J943700767Case: Desktop

Computer Location: BNA GC InstrumentNetwork Wire: L20 Hub Location: T3Motherboard: 80486DX-33 Ram (MB): 8

Floppy Drive 1: TEAC 1.2 Mb 5.25 Floppy Drive 2: TEAC 1.44 Mb 3.5Hard Drive 1: Maxtor 170 Mb Hard Drive 2:

Tape: I/O Card:Network Card: Multitech Network Address:

Video Card: Trident Local Bus SVGA Monitor: ADI Microscan 3gMouse: Kensington Mouse Keyboard: Key-Tronic 101 KeyboardCase: Desktop

164 RR305295

Computer Location: Bookkeeper's OfficeNetwork Wire: 010 Hub Location: B10Motherboard: 80486DX-33 S/N:9214253 Ram (MB): 8

Floppy Drivel: Teac 1.2MB S/N:7388816 Floppy Drive 2: Teac 1.44MB S/N:M746806Hard Drivel: Conner 170MB S/N:AMD7CPG Hard Drive2:

Tape: I/O Card: IDE-GoldStar S/N:9314495Network Card: SMC 10BNC S/N:D2D062667 Network Address:

Video Card: Cirrus Logic 1 MB S/N:045495 Monitor: ADl ProVista SVGA S/N:N3284Mouse: Microsoft Mouse Keyboard: Focus 2001 S/N:940104887Case: Desktop

Computer Location: Client ServicesNetwork Wire: O12 Hub Location: M9Motherboard: 80486DX2-66 Ram (MB): 8

Floppy Drivel: TEAC 1.2 MB B290866 Floppy Drive 2: TEAC 1.44 MB W595847Hard Drivel: WD 200 MB WT2692016573 Hard Drive 2:

Tape: I/O Card: VLE IDE 9316598Network Card: MultiTech EN301T16 Network Address:

Video Card: Trident 1 MB VLB VGA GR6Z435Q00740 Monitor: ADl 3G D46555550148780Mouse: Microsoft Mouse 2049860 Keyboard: KeytronicCase: Desktop

A.R305296165

Computer Location: Data Room - Black and White X-TerminalNetwork Wire: D4 Hub Location: M8Motherboard: B/W RISC X-Terminal S/N:0692L101491 Ram (MB): 4

Floppy Drive 1: Floppy Drive 2:Hard Drivel: Hard Drive2:

Tape: I/O Card: NCDNetwork Card: NCD Network Address:

Video Card: NCD Monitor: NCD19RP3TW S/N:30-221520Mouse: Logitech M-CE-15-9F-NCD S/N:LT202CO Keyboard: NCD N-97 0600023 S/N:SC212Case: Desktop

Computer Location: Data Room - General PCNetwork Wire: D6 Hub Location: T8Motherboard: 80486DX-33 S/N:0906034 Ram (MB): 8

Floppy Drivel: Teac 5.25 S/N:L857317 Floppy Drive 2: Teac 3.5 S/N:5580607Hard Drivel: Conner 120MB S/N:NBRT81 Hard Drive2: Conner 120MB S/N:NB87KP

Tape: I/O Card: Generic S/N:9203595Network Card: SMC 8013WC S/N:02A298751 Network Address: OOOOCOCFA95

Video Card: Trident 1MB SVGA S/N:8127074 Monitor: ViewSonic 4E S/N:3314835464Mouse: Kensington Expert S/N:296323 Keyboard: Fujitsu FKB4700 S/N:H2395496Case: Mid-Tower

NR305297166

Computer Location: Data Room - HP730Network Wire: UNX Hub Location: M9Motherboard: HP PA-RISC 730 Ram (MB): 32

Floppy Drive 1: Floppy Drive 2:Hard Drivel: HP 420 MB Hard Drive 2: HP 13 GB External Tower

Tape: I/O Card:Network Card: HP Ethernet Network Address:Video Card: HP Mono Graphics Monitor: HP

Mouse: HP Keyboard: HPCase: Desktop

Computer Location: Data Room - Novell ServerNetwork Wire: SRV Hub Location: T11Motherboard: 80386DX-33 Ram (MB): 8

Floppy Drivel: 5.25 HD Floppy Drive 2: 3.5 HDHard Drivel: 312MB Hard Drive 2: 312MB

Tape: I/O Card:Network Card: MultiTech S/N:100317 Network Address:

Video Card: Monitor: GoldStar MonochromeMouse: Keyboard:Case:

HR305298167

Computer Location: Data Room - Programmer/AnalystNetwork Wire: D3 Hub Location: M4Motherboard: 80486DX-33 Ram (MB): 20

Floppy Drivel: Teac 5.25 S/N:N676255 Floppy Drive 2: Teac 3.5 S/N:8455806Hard Drive 1: WD Caviar 2200 212 MB S/N:WT254178 Hard Drive 2:

Tape: Colorado 120MB S/N:AAA0049395 I/O Card: Colorado Floppy Tape AdapterNetwork Card: SMC8013WC S/N:02A307942 Network Address: OOOOC042CE5

Video Card: Trident 1MB SVGA S/N:81B7070 Monitor: Sceptre CMGD S/N:228DWOOOMouse: Microsoft Mouse S/N:0011243 Keyboard: Fujitsu FKB4700 S/N:H835988Case: Mid-Tower

Computer Location: Decomissiioned - BNA 3 LabNetwork Wire: Hub Location:Motherboard: 80286 S/N:8805049082 Ram (MB): 1

Floppy Drivel: 5.25 S/N:FD0113324 Floppy Drive 2:Hard Drivel: Generic S/N:251-M1C2 Hard Drive 2:

Tape: I/O Card: Generic S/N:NDC5425Network Card: Western Digital S/N:085172 Network Address:

Video Card: Generic Monitor: Sceptre S/N:GKR66206BMouse: Keyboard: Arche Technologies S/N:73544Case:

JtR305299168

.-, •• .'i.v.'- ''-if -

Computer Location: Lab ManagerNetwork Wire: O1 Hub Location: M2Motherboard: 80486-DX66 S/N:F93043391 Ram (MB): 16

Floppy Drive 1: Teac 5.25 S/N:X654790 Floppy Drive 2: Teac 3.5 S/N:E482391Hard Drivel: Caviar2200 220MB S/N:99-00411-002 Hard Drive2:

Tape: I/O Card: PT-604A S/N:9314638Network Card: SMC8013WC Network Address: OOOOC041CE5Video Card: Trident 1MB SVGA S/N:9317405 Monitor: ADl MicroScan 3e+ S/N:560500

Mouse: 'Microsoft Mouse S/N:0028367 Keyboard: Fujitsu FKB4700 S/N:H274588Case: Mid-Tower (

Computer Location: Mail RoomNetwork Wire: O14 Hub Location: B12Motherboard: 80486DX-33 Ram (MB): 8

Floppy Drivel: Teac 5.25 S/N:G991119 Floppy Drive 2: Teac 3.5 S/N:G991116Hard Drive 1: 170 MB Connor Hard Drive 2:

Tape: I/O Card: Generic S/N:9103776Network Card: SMC Ethernet Network Address: 000800100344Video Card: Cirrus Logic 1 Mb Monitor: ViewSonic 2 S/N:1410512990P

Mouse: Microsoft Mouse Keyboard: Chicony S/N:003013152Case: Desktop

169 AR305300

Computer Location: Metals AA #1Network Wire: L4 Hub Location: T7Motherboard: 80486DX-33 Ram (MB): 1

Floppy Drivel: Teac 5.25 S/N:N626235 Floppy Drive 2: Teac 3.5 S/N:5993703Hard Drivel: Conner S/N:AB73MBW Hard Drive 2:

Tape: tfO Card: Generic S/N: 190458Network Card: MultiTech S/N: 100809 Network Address:Video Card: Paradise VGA S/N:20229802 Monitor: ViewPerfect S/N:1104214572

Mouse: Kensington Expert S/N:294886 Keyboard: Keytronic FT11 S/N:0188276Case: Tower

Computer Location: Metals AA #2Network Wire: L5 Hub Location: T15Motherboard: 80486DX-33 S/N:0906023 Ram (MB): 1

Floppy Drivel: Teac5.25 S/N:W797349 Floppy Drive2: Teac3.5 S/N:2106120Hard Drivel: Conner WD2120 S/N:WT231370924 Hard Drive2:

Tape: I/O Card:Network Card: MultiTech S/N:100318 Network Address:

Video Card: Paradise VGA S/N:20207218 Monitor: ViewSonic! S/N:1620789681PMouse: Kensington Expert Mouse S/N:293017 Keyboard: Fujitsu FKB4700 S/N:GY34991Case: Mid-Tower

AR305301

,.1?;.

Computer Location: Metals ARL-ICPNetwork Wire: L3 Hub Location:Motherboard: 80386SX-16 S/N:78492 Ram (MB): 2

Floppy Drivel: Teac 3.5 Floppy Drive 2: Teac 5.25Hard Drivel: 120MB Hard Drive2:

Tape: I/O Card: Generic S/N:KW182672Network Card: MultiTech S/N: 100316 Network Address:

Video Card: Generic Monitor: Taxan770 S/N:K1A592045Mouse: Keyboard: Keytronics S/N:0274044Case: Desktop

Computer Location: Metals OfficeNetwork Wire: L6 Hub Location: B11Motherboard: 80486-DX33 S/N:0906039 Ram (MB): 8

Floppy Drivel: Teac 5.25 S/N:L857316 Floppy Drive 2: Teac 3.5 S/N:5580606Hard Drivel: Conner 120MB S/N:NDC7DC Hard Drive2:

Tape: Colorado Jumbo 120 I/O Card: Generic S/N: 188197Network Card: SMC 8013WC S/N:61-600406-005 Network Address: OOOOC076A24

Video Card: Trident 1MB SVGA S/N:8127068 Monitor: ViewSonic 4E S/N:3314835462Mouse: Kensington Expert Mouse S/N:289464 Keyboard: Fujitsu FKB4700 S/N:H239594Case:

AR305302171

Computer Location: Metals Prep LabNetwork Wire: L1 Hub Location:Motherboard: 80386SX-16 Ram (MB): 2

Floppy Drivel: 5.25 Floppy Drive 2: 3.5Hard Drivel: 120MB Hard Drive 2:

*

Tape: I/O Card:Network Card: MultiTech Network Address:Video Card: Generic Monitor: Samsung SyncMaster 3

Mouse: City Mouse Keyboard:Case:

Computer Location: Metals TJA-ICPNetwork Wire: Hub Location:Motherboard: 80386DX-33 Ram (MB): 4

Floppy Drivel: TEAC 5 1/4 G991119 Floppy Drive 2: TEAC 5 1/4 G991116Hard Drivel: LODJ7780Mb Hard Drive2:

Tape: I/O Card:Network Card: SMC Ethernet Network Address:

Video Card: Generic S/N:AT10-10C Monitor: ViewSonicMouse: Microsoft Mouse Keyboard: Fujitsu FKB4700 S/N:GY34997Case:

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Computer Location: MIS Manager's Office ( SCOSYSV)Network Wire: 08 Hub Location: M6Motherboard: Pentium 90 - Dual Processor Ram (MB): 32

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Floppy Drivel: Teac 3.5 S/N:F795986 Floppy Drive 2:Hard Drive 1: Micropolis 2112 1.2GB S/N;3045212091 Hard Drive 2:

Tape: Archive Python 2GB 4mm DAT I/O Card: Generic S/N:9309118Network Card: Racor-Datacom ES3210 S/N:243M3733 Network Address:Video Card: Trident 1MB SVGA S/N:9215648 Monitor: ADl Microscan 3E+ S/N:560500

Mouse: Microsoft Bus Mouse 0016199 Keyboard: Fujitsu FKB4700 S/N:H274693Case: Full Tower

Computer Location: MIS Manager's Office PCNetwork Wire: O9 Hub Location: M7Motherboard: Gateway 200 P5-66 Pentium Ram (MB): 16

Floppy Drive 1: 3 1/2 - Gateway Floppy Drive 2:Hard Drive 1: 520 MB - Connor Hard Drive 2: 440 MB - Connor

Tape: Double Speed CD-ROM I/O Card:Network Card: SMC Ethernet Network Address:Video Card: PCI Diamond Stealth 2 MB Monitor: Gateway 2000-1572

Mouse: Microsoft Keyboard Mouse ' Keyboard: Gateway 2000 AnyKeyCase: Gateway Desktop

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Computer Location: Pest/PCB Office - HP710Network Wire: L17 Hub Location: M1Motherboard: HP PA-RISC 9000/710 S/N:6216A00472 Ram (MB): 32

Floppy Drivel: 3.5 High Density Floppy Drive 2:Hard Drivel: 330 MB SCSI Hard Drive 2: 1.3GB SCSI S/N:3212E00593

Tape: 1.3GB 4mm DAT S/N:3141A01704 I/O Card:Network Card: HP Ethernet w/ Transceiver Network Address:Video Card: HP Monitor: HP 98774B S/N:320T1308

Mouse: HP 46060B S/N:314750035 Keyboard: HP C1429A#ABA S/N:3147501Case: Desktop

Computer Location: Pest/PCB Office PCNetwork Wire: 02 Hub Location: T2Motherboard: 80386DX-25 S/N:MB0102793 Ram (MB): 5

Floppy Drivel: Teac 5.25 S/N:48001364 Floppy Drive 2: Teac 3.5 S/N:633740Hard Drive 1: Micropolis 86MB S/N:084745 Hard Drive 2:

Tape: I/O Card:Network Card: SMC S/N:61-600406-015 Network Address: OOOOC07BA24

Video Card: Paradise OEM VGA S/N:1134865 Monitor: ViewSonic 2V S/N:110421458Mouse: Kensington Expert S/N:30Q470 Keyboard: Keytronic FT11 s/N:0273031Case: Desktop

AR305305174

Computer Location: Pesticide Lab GC #1Network Wire: L11 Hub Location: M5Motherboard: 80486DX-33 S/N:A1025 Ram (MB): 8

Floppy Drivel: 5.25 S/N:L458691 Floppy Drive 2: 3.5 S/N:5380052Hard Drivel: Conner S/N: N88E1W Hard Drive 2:

Tape: I/O Card:Network Card: SMC S/N:D28062214 Network Address:

Video Card: Monitor: ViewSonic 4EMouse: Kensington Keyboard: Fujitsu FKB4700Case: Mid-Tower

Computer Location: Pesticide Lab GC #2Network Wire: L12 Hub Location: T12Motherboard: 80486DX-33 S/N:A1025190 Ram (MB): 8

Floppy Drivel: 5.25 HD S/N:19307351-49 Floppy Drive 2: 3.5 HD S/N: 19307332-40Hard Drive 1: Western Digital 125MB S/N:99-004085-0 Hard Drive 2: 19307332-40

Tape: I/O Card:Network Card: SMC Plus S/N:6i-600406-004 Network Address:

Video Card: Trident TVGA S/N:143149 Monitor: ViewSonic 4E S/N:3314835479Mouse: Keyboard:Case:

AR3Q-5306175

Computer Location: Pesticide Lab GC #3Network Wire: L16 Hub Location: M5Motherboard: 80486DX33 S/N:91410957 Ram (MB): 8

Floppy Drivel: Teac 5.25 HD S/N:W052072 Floppy Drive 2: Teac 3.5 HD S/N:7474655Hard Drivel: Conner CP301044 S/N:AB7396J Hard Drive 2:

Tape: I/O Card:Network Card: SMC Ethernet S/N:K1A10749 Network Address:

Video Card: Generic S/N:81A1343 Monitor: ViewSonic 4E S/N:3821235564Mouse: Kensington S/N:342372 Keyboard: Fujitsu FKB4700 S/N:46427977Case: Mid-Tower

Computer Location: President's OfficeNetwork Wire: 03 Hub Location: B6Motherboard: 80486DX2-66 S/N:T90004 Ram (MB): 16

Hard Drive 1: LODJ77 S/N:9105918 120 MB Hard Drive 2:

Tape: I/O Card:Network Card: SMC Network Address: OOOOCOFC637

Video Card: Expert SVGA S/N:20113064 Monitor: Viewsonic 1 S/N: 1621772971PMouse: Microsoft Mouse Keyboard: Fujitsu FKB4700 S/N:H2395391Case: Mid-Tower

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Computer Location: Reception Area - Print ServerNetwork Wire: D2 Hub Location: M10Motherboard: 80386SX-25 Ram (MB): 0

Floppy Drivel: Teac5.25 S/N:L778172 Floppy Drive2:Hard Drivel: Hard Drive2:

Tape: I/O Card: Generic S/N:KT0193789Network Card: MultiTech S/N: 100330 Network Address: 000800100856Video Card: Generic S/N:9101039 Monitor: Samsung MA2565 S/N:HSRAC

Mouse: Keyboard: ASTASTKB101 S/N:200910Case: Desktop

Computer Location: ReceptionistNetwork Wire: 04 Hub Location: T5Motherboard: 80486DX-33 Ram (MB): 8

Floppy Drivel: Teac 5.25 S/N:6991117 Floppy Drive 2: Chinon 5.25 S/N:20252154Hard Drive 1: Seagate ST351A40MB S/N:913001 -305 Hard Drive 2:

Tape: I/O Card: Generic S/N:9103709Network Card: MultiTech S/N:100395 Network Address: 000800100395

Video Card: Western Digital VGA S/N:541762 Monitor: ViewSonic 2 S/N:1410512985PMouse: • Keyboard: Chicony S/N:910311547Case: Desktop

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Computer Location: Sample ReceivingNetwork Wire: L2 Hub Location: M3Motherboard: 80486DX-33 S/N:9310685 Ram (MB): 8

Floppy Drivel: Teac5.25 S/N:W194480 Floppy Drive2: Teac3.5 S/N:E308975Hard Drivel: Conner 170MB S/N: AMBBE13 Hard Drive 2:

Tape: I/O Card: PT-604A S/N:9310662Network Card: SMC8013WC S/N:K1A592042 Network Address:

Video Card: Trident 1MB SVGA S/N:9345953 Monitor: ADl MicroScan 3E+ S/N:01256Mouse: Microsoft Mouse S/N:0255723 Keyboard: Keytronic KT2000 S/N:C932035Case: Mid-Tower

Computer Location: Technical Director's OfficeNetwork Wire: 06 Hub Location: B5Motherboard: Zeos Laptop 80486SLC25 MHz Ram (MB): 8

Floppy Drivel: 3.5 internal Floppy Drive2:Hard Drivel: internal Hard Drive2:

Tape: I/O Card:Network Card: GVC Pocket Adapter Network Address:

Video Card: Zeos Monitor: ADl ProVistaMouse: Logitech Portable Trackman Keyboard: ZeosCase: Laptop-Zeos

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Computer Location: Vice President's OfficeNetwork Wire: 05 Hub Location: B9Motherboard: 80386DX-40 S/N:9207730 Ram (MB): 8

Floppy Drivel: Teac 5.25 S/N:Q742732 Floppy Drive 2: Teac 3.5 S/N:9107930Hard Drive 1: WD Caviar 2120 120MB S/N:WT256121 Hard Drive 2:

Tape: I/O Card:Network Card: SMC Network Address:

Video Card: Cirrus SVGA S/N:Q212256 Monitor: ViewSonic 1 S/N:1623083775PMouse: Kensington Expert Mouse S/N:323728 Keyboard: Fujitsu FKB4700 S/N:4955659Case: Low Tower

Computer Location: VOA 12 LabNetwork Wire: L8 Hub Location: T11Motherboard: MultiTech S/N:A0326487-E Ram (MB): 1

Floppy Drivel: 5.25 S/N:FD-556FR-633-0 Floppy Drive 2:Hard Drivel: Seagate S/N:00481520 Hard Drive2:

Tape: I/O Card: Generic S/N:61-000107-00Network Card: Novell S/N:738-000220-001 Network Address:

Video Card: Generic S/N:59-6672-OOA1 Monitor: NEC APC-H530 S/N:A3D5YRMouse: Keyboard: Generic S/N:0274042Case: MultiTech S/N:A052008159

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Computer Location: VOA GC #2Network Wire: L13 Hub Location: B12Motherboard: 80486DX-33 S/N:A1039908 Ram (MB): 8

Floppy Drivel: Teac5.25 S/N:M905314 Floppy Drive2: Teac3.5 S/N: 7489733Hard Drivel: Conner S/N:BP06327 Hard Drive2:

Tape: I/O Card: IEEE Card S/N:3009Network Card: 8013WC Network Address: OOOOCOFF637

Video Card: Generic S/N:81A1320 Monitor: ViewSonic 4EMouse: Kensington Expert Mouse S/N:305545 Keyboard: Fujitsu FKB4700 S/N:H5417081Case: Mid-Tower

Computer Location: VOA GC - Grayscale X-TerminalNetwork Wire: L19 Hub Location: T5Motherboard: RISC X-Terminal S/N:0592K100746 Ram (MB): 4

Floppy Drivel: Floppy Drive2: ^PHard Drive 1: Hard Drive 2:

Tape: I/O Card: NCDNetwork Card: NCD Network Address:

Video Card: NCD Monitor: NCD BDC1107 S/N:21300038Mouse: Logitech M-CE-15-9F-NCD S/N:LT112RO Keyboard: NCD 9100044 S/N:C0121743Case: Desktop

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Computer Location: VOA 34 LabNetwork Wire: L10 Hub Location: T14Motherboard: IBM PS/2 Model 50 S/N:72-8247390 Ram (MB):

Floppy Drive 1: IBM 40 MB Floppy Drive 2:Hard Drivel: IBM 3.5 Hard Drive 2:

Tape: I/O Card:Network Card: Western Digital S/N:800f240E26 Network Address:

Video Card: Monitor: ViewSonic 2V S/N:1104214596Mouse: Keyboard: IBM S/N:2584867Case: Desktop

Computer Location: VOA GC #1Network Wire: L15 Hub Location: B8Motherboard: 80486DX-33 Ram (MB): 8

Floppy Drivel: 5.25 FD Floppy Drive 2: 3.5 FDHard Drivel: 120MB Hard Drive 2:

Tape: I/O Card:Network Card: SMC Ethernet Network Address:

Video Card: SVGA Monitor: ViewSonic 4EMouse: Kensington Expert Mouse Keyboard:Case: Mid-Tower

AB3053I2180

Computer Location: VOA/BNA OfficeNetwork Wire: 013 Hub Location: B3Motherboard: 80486DX-33 S/N:9310686 Ram (MB): 4

Floppy Drivel: Teac 5.25 S/N:R167003 Floppy Drive 2: Teac 3.5 S/N:E308974Hard Drivel: Conner 170MB S/N:AMBT3K1 Hard Drive2:

Tape: I/O Card: DT-604A S/N:9310663Network Card: SMC8013WC S/N:K1A592044 Network Address: OOOOC079A24Video Card: Trident 1MB SVGA S/N:9346139 Monitor: ADl Microscan 3E+ S/N:027560

Mouse: Microsoft Mouse S/N:0500112 Keyboard: Keytronics KT2000 S/N:C93203Case: Mid-Tower

Computer Location: Wet Chem LabNetwork Wire: L14 Hub Location: B7Motherboard: 80486-DX33 Ram (MB): 8

Floppy Drivel: Teac 5.25 S/N:E132878 Floppy Drive 2:Hard Drive 1: WD Caviar 2120 120MB S/N:WR316078 Hard Drive 2: .

Tape: I/O Card:Network Card: SMC8013WC Network Address: OOOOC072A24Video Card: Trident 1MB S/N:WBD334608705 Monitor: ViewSonic 1 S/N:1621067218D

Mouse: Kensington Expert Mouse Keyboard: KeytronicFT15 S/N:D27Y042Case: Desktop

AR3053I3182

ATTACHMENT A REVISED QUALITY ASSURANCE MANUAL …ENVIROTECH RESEARCH, INC. 777 New Durham Road...

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Transcript of ATTACHMENT A REVISED QUALITY ASSURANCE MANUAL …ENVIROTECH RESEARCH, INC. 777 New Durham Road...