At Village & P.O. Jhiwana, Tehsil Tijara, District...

Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation

Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a

At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)

Pre-Feasibility Report

M/s. SRF Limited 1

(Unit: Bhiwadi)

PRE-FEASIBILITY REPORT

1.0 EXECUTIVE SUMMARY

(I) INTRODUCTION

SRF is a multi-business entity engaged in the manufacture of chemical based industrial

intermediates. It has Fluorochemical Business and Speciality Chemical Business (Organic) Plant at

Village & P.O. Jhiwana, Tehsil Tijara, Distt. Alwar (Raj.); which was established in Year 1989. SRF

limited is proposing expansion of Multi-Purpose Plant / Fluorospeciality Plant (3000 TPA to

6000 TPA); Installation of New Generation Refrigerants & Refrigerant Blends Plant (90,000

TPA) and Change in Product Mix of Chloromethanes and HFC 134a.

As per the EIA Notification dated 14th Sept, 2006, and as amended from time to time, the project falls

under category ‘A’, Project or Activity 5(f).

Table - 1

Salient Features of the Project

S. No. PARTICULARS DETAILS

A. Nature & Size of the Project

Unit Existing Capacity

(TPA)

Proposed

Expansion

Capacity (TPA)

Total Capacity after

Expansion

(TPA)

Multi-Purpose

Plant/ Fluoro

speciality Plant

3000 3000 6000

New Generation

Refrigerants &

Refrigerant

Blends*

Nil 90,000 90,000

Chloromethane

Plant

50,000

(Product range

Methylene Chloride,

Chloroform, Carbon

tetra chloride)

Nil

(Extraction of

intermediate

Methyl chloride as

a product)

50,000

(Product range Methyl

chloride, Methylene

chloride, Chloroform,

Carbon tetra chloride)

HFC134a Plant

12000

(Product range

HFC134a)

Nil

(Swing over plant

for HFC32)

12000

(Product range

HFC134a & HFC32)

(*List of products is attached as Annexure - 1)

B. Category of the Project As per EIA Notification dated 14th Sept., 2006 & as amended from time to time;

this project falls under Category A, Project or Activity ‘5 (f)’

C. Location Details

Village Jhiwana

Tehsil Tijara





M/s. SRF Limited 2

(Unit: Bhiwadi)

District Alwar

State Rajasthan

Latitude & Longitude

28° 9’ 18.41” N - 76° 50’ 27.58” E

28° 9’ 25.07” N - 76° 50’ 12.92” E

28° 9’ 45.73” N - 76° 50’ 20.41” E

28° 9’ 37.63” N - 76° 50’ 35.01” E

Toposheet No. 53 D/16

Location Map has been shown in Figure-1

D. Area Details

Total Plant Area 34 ha

Greenbelt / Plantation Area

(ha)

Out of the total plant area, 12.24 ha (~36 %) has already been developed under

green belt/ plantation and same will be maintained.

E. Environmental Setting Details (with approximate aerial distance & direction from plant site)

1. Nearest Town Bhiwadi (~ 4.0 km in NNE direction from the plant site)

2. Nearest City Rewari (~22 km in WNW direction from the plant site)

3. Nearest National Highway /

State Highway

NH-71B ( ~5.5 km in N direction from the plant site)

SH-25 ( ~1.3 km in W direction from the plant site)

4. Nearest Railway station Rewari Railway Station (~22 km in WNW direction from the plant site)

5. Nearest Airport Indira Gandhi International Airport, New Delhi (~50 km in NNE direction from

the plant site )

6. Archaeological important

site

None within the 10 km radius

7. National Parks, Wild Life

Sanctuaries, Biosphere

Reserves, Tiger/ Elephant

Reserves, Wildlife Corridors

etc. within 10 km radius

No National Park, Wildlife Sanctuary, Biosphere Reserve, Tiger / Elephant

Reserve, Wildlife Corridors etc. falls within 10 km radius of the plant site.

8. Reserved Forests (RF) /

Protected Forests (PF) etc.

within 10 Km. radius

Protected Forests

� Chaupanki (~5.5 km in ESE direction)

� Banvan (~2.5 km in E direction)

� Khori Kalan (~4.5.0 km in SE direction)

� Sarekalan (~7.0 km in SE direction)

� Protect Forest (adjacent in East direction)

� Gondhan (~1.2 km in NNE direction)

Reserve Forests

� Rangala (~7.5 km in NE direction)

� Indaur (~8.5 km in SE direction)

9. River / Water Body (within

10 km radius)

� Sahibi River (Seasonal) (~9.0 km in WNW direction)

� Indori lake (~9 km in SE direction)

� Indori Nala (~8.5 km in ENE direction)





M/s. SRF Limited 3

(Unit: Bhiwadi)

10. Critically Polluted Area as

per CEPI - CPCB

Bhiwadi, a critically polluted area declared under CEPI as per MoEF Circular

dated 15.03.2010 exist within 15 km radius study area.

F. Cost Details

Total Cost of the Expansion

Project

Rs. 20 Crores (as per the information provided by M/s. SRF Ltd.)

Cost for Environment

Management Plan

� Capital Cost – Rs. 2.0 Crores

� Recurring Cost – Rs. 0.5 Crores/Annum

G. Basic Requirements for the project

Water requirement (KLD)

The allowable quota for water requirement is 2921 KLD; existing water

requirement is 2300 KLD and for proposed expansion, it will be 300 KLD. Thus,

after proposed expansion, the total water requirement will remain within the

allowable quota (i.e. 2921 KLD).

Source: Ground water & Recycled water

Power Requirement (MW) After expansion power requirement will be 11.1MW

Source: Captive power plant (12MW) and RSEB (4MW)

Man Power Requirement Existing man power requirement is 940

After proposed expansion total man power requirement will be 955

1.1 ENVIRONMENTAL MANAGEMENT PLAN

Particulars Details

Air Quality Management

Emissions

� Proper pollution control equipment e.g. Venturi Scrubbers / Graphite Scrubbers,

Central Absorption System (CAS), HCl Absorption System to remove the pollutants

such as Cl2, HF and HCl are in place and same will be maintained.

� Stacks of suitable height as per norms are being/will be provided.

� MPP (FSP) and New Refrigerant Plants - Central absorption (CAS) & Hypo system

having adequate size scrubber, running and stand by pump for water circulation,

running and stand by blower for vapour suction is being/ will be provided to ensure

Zero emission.

� Storage, filling and transfer of material will be in closed pipelines so that there is

Zero/ negligible fugitive emission.

� Green belt around the periphery and within premises is already in place and same

will be maintained.

Monitoring � Ambient air quality and stack emissions are being/will be regularly monitored and

effective controls exercised, so as to keep the emission within the statutory limits.

Water Management

Management � A full fledged ETP is already in place. Most of the treated water from ETP is

being/will be recycled back to the processes and remaining is/will be used for

greenbelt development.





M/s. SRF Limited 4

(Unit: Bhiwadi)

� Domestic waste water generated from the plant is being/ will be treated in Sewage

Treatment Plant. And treated water will be used in greenbelt development.

� Ultra filtration system rejects will be used as make up water for cooling system.

� Water conservation practices like construction of rain water harvesting and check-

dams is being/ will be practiced under CSR programme in nearby areas

Noise Management

Management � Green belt around the periphery and within premises has already been developed

and same will be maintained that helps in reducing noise.

� All rotating equipments are well lubricated and provided with acoustic enclosures to

reduce noise transmission.

� Noise generating units like, Air & Refrigeration compressors D.G set, and turbine and

boiler are installed in closed buildings and D.G. Sets are being/will be provided with

acoustic enclosure so that effect of noise is reduced.

� Acoustic Enclosures are being/will be provided to operators working in High Noise

area.

Solid & Hazardous Waste Management

� The sludge from ETP arising out of water treatment contains CaF2. This would be mixed with the raw material of

HF plant & hence 100% recycling is being/will be done.

� The sludge from STP is being dried on sludge drying beds and is being/will be used for greenbelt development.

� Spent oil generated from existing/proposed facilities is being/will be sent to authorized recyclers.

� Plastic cut drums generated from existing/proposed facilities is being/will be sent to secured landfill.

Green Belt Development / Plantation

� Out of the total plant area, 12.24 ha (~36%) has already been developed under green belt/ plantation. The same

will be maintained properly.

� Green belt developed and there maintenance along with the road & plant boundary will attenuate noise level

arrest dust and improve the environment in surrounding.

� Native plant species has been planted in consultation with DFO.

2.0 INTRODUCTION OF THE PROJECT/ BACKGROUND INFORMATION

i. Identification of Project and Project Proponent

SRF is a multi-business entity engaged in the manufacture of chemical based industrial

intermediates. It was established in year 1973; its business portfolio covers Technical Textiles,

Fluorochemicals, Specialty Chemicals, Packaging Films and Engineering Plastics. Fluorochemical

Business and Speciality Chemical Business (Organic) Plant at Village & P.O. Jhiwana, Tehsil

Tijara, Distt. Alwar (Raj.) was established in Year 1989. Today, it has grown into a global

enterprise with operations in 4 countries and having a turnover of $450 million. SRF started its

journey in the space of fluorochemicals by manufacturing CFCs and HCFCs at Bhiwadi in

Rajasthan, faced with the challenge of phasing out of CFCs as per Montreal Protocol, SRF, to its

credit, made investments in R&D and successfully developed in-house technology to

manufacture ozone friendly and new generation of refrigerants of that time, HFC 134a in 2006.





M/s. SRF Limited 5

(Unit: Bhiwadi)

M/s. SRF Ltd. is the only Company in India which has developed indigenous capability for

manufacturing HFC-134A which is a new generation Refrigerant & and has zero ODP. Till date,

SRF remains the only manufacturer of HFC 134a in India. SRF's Specialty Chemicals Business

enjoys an enviable reputation for its capabilities in developing and manufacturing advanced

intermediates those are used in various agrochemical and pharmaceutical industries.

ii. Brief description of nature of the project

M/s. SRF Ltd. is proposing expansion in Multi-Purpose Plant / Fluorospeciality Plant (3000 TPA

to 6000 TPA); Installation of New Generation Refrigerants & Refrigerant Blends Plant (90,000

TPA) and Change in Product Mix of Chloromethanes and HFC 134a at Village & P.O. Jhiwana,

Tehsil Tijara, District Alwar (Rajasthan).

As per the EIA Notification dated 14.09.2006, and as amended time to time, the project falls

under category ‘A’, Project or Activity 5(f).

iii. Need for the project and its importance to the country and or region

M/s. SRF Ltd. are engaged presently in production of Fluorochemicals (Refrigerant gases),

Chloromethane and speciality chemicals products, which are used for a variety of Industrial,

commercial and household applications and intermediates for pharmaceutical & agrochemical

industry.

Hydro-Chlorofluoro carbons like R-22 are phasing out and new refrigerants/refrigerant blends

are coming in market. Also fluoro specialty product range has been growing in India, the project

proponent intends to put up new set ups for producing new refrigerant/refrigerant blends,

Expansion of MPP/Fluoro specialty products facility and change in product mix of

chloromethane to produce C1 (Methyl chloride) and change in product mix of HFC134a plant to

produce HFC32 at their existing facility in Rajasthan.

iv. Demand- Supply Gap

Demand - Supply projection for Fluorochemicals on National and State basis reveals that there

exists an imbalance between availability and demand of Fluorochemicals India. The long term

prospects for Fluorochemicals are great in India due to under penetration of most of the end use

products like AC’s, Automobiles, Cold Storages, Refrigerated transport, Pharma etc. Secondly the

weather is India is hot for most part of the year thereby demanding air conditioning &

refrigeration products over a longer stretch of time. Nearly 55% of the market demand in India is

for HCFC, while 45% is for HFC’s.

Most of the HFC’s like R134a, R410a, R407c, R404a etc. are imported into India. Except for one

domestic player making R134a (SRF), all HFC’s are imported.

The Specialty Chemicals Industry is a mature sector. For decades, many industries have utilized

specialty chemicals in manufacturing and finishing. Some specific areas where these products

are used include: agriculture, requiring fertilizers, construction materials, sealants, coatings,

paints and plastics; and consumer goods, such as perfumes, detergents, paper items and





M/s. SRF Limited 6

(Unit: Bhiwadi)

pharmaceuticals out of which agriculture and pharmacy sector are need driven. Hence big

industries are dependent upon the indigenous availability of such chemicals for accelerated

growth and development of the nation. As such the Indian market is driven by global suppliers

to a great extent and is subject to global demand supply challenges.

Under these circumstances to bridge the gap, SRF has proposed for installation of new

generation refrigerants/blends & expansion of MPP/Fluorospeciality plant. Product mix change

in CMS & HFC134a plant.

Imports vs. Indigenous Production

The proposed expansion will utilize both locally and imported raw materials. Most of the raw

material for the the Refrigerant & Refrigerant blends plant is imported via sea route, most of

them from china. Raw materials for the speciality plant is being /will be sourced from both

national and international markets, via, sea, rail and road routes.

Basic raw material for the fuel including coal is being/will be sourced from Indian markets, in

trucks and tankers, via road.

v. Export Possibility-

Due to lacking competitive scale of production in the various countries of the world for the

production of both fluoro chemicals and specialty chemicals, and increase in demand scale of the

products, there is huge scope for export possibility of the products from both existing and new

plant units. Various Products from the existing units are exported to the various global markets

that hold customers from various developed and developing nations.

vi. Domestic / Export Markets

Most of the products from the existing plant units are sent to the national costumers, which

include various big and small manufacturing industries. Products are being exported to various

parts of the globe, mostly covering west Asian, European and North American markets. New

products after expansion in addition to the product from existing plant will be exported to

different parts of the world, most equally to both developing and developed nations, via sea and

air routes. Major section of the revenue is generated from the export sections, however due to

increased development and raised level of living standards, the demand of such chemicals have

been increased as part of various finished products in the domestic markets.

vii. Employment Generation (Direct and Indirect) due to the project

Table -2

Manpower requirement

Particulars Existing Proposed Total after expansion

Skilled 535 10 545

Semi – Skilled 87 5 92

Unskilled 318 - 318

Total 940 15 955





M/s. SRF Limited 7

(Unit: Bhiwadi)

3.0 PROJECT DESCRIPTION

(i) Type of Project including interlinked and independent projects if any

M/s. SRF Ltd. is proposing expansion in Multi-Purpose Plant / Fluorospeciality Plant (3000 TPA

to 6000 TPA); Installation of New Generation Refrigerants & Refrigerant Blends Plant (90,000

TPA) and Change in Product Mix of Chloromethanes and HFC 134a.

There is no interlinked project.

(ii) Location (map showing general location, specific location, and project boundary & project

site layout) with coordinates

Figure -1: Location Map

Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation Refrigerants & Refrigerant Blends Plant (90,000 TPA)

Product Mix of Chloromethanes and HFC134a


M/s. SRF Limited

(Unit: Bhiwadi)

speciality Plant (3000 TPA to 6000 TPA); Installation of New Generation Refrigerants & Refrigerant Blends Plant (90,000 TPA)

8

Figure - 2: Plant Layout

speciality Plant (3000 TPA to 6000 TPA); Installation of New Generation Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in


Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in

Product Mix of Chloromethanes and HFC134a



M/s. SRF Limited 9

(Unit: Bhiwadi)

Figure - 3: Key Plan





M/s. SRF Limited 10

(Unit: Bhiwadi)

(iii) Details of alternative sites consideration and basis of selecting the proposed site, particularly

the environmental considerations gone into should be highlighted.

Since, the proposed expansion and new installation will be done within the existing plant and no

additional land will be required; therefore, no alternative site has been considered.

(iv) Size or magnitude of operation

SRF Ltd. is proposing expansion in Multi-Purpose Plant / Fluorospeciality Plant (3000 TPA to 6000

TPA); Installation of New Generation Refrigerants & Refrigerant Blends Plant (90,000 TPA) and

Change in Product Mix of Chloromethanes and HFC134a at Village & P.O. Jhiwana, Tehsil Tijara,

District Alwar (Rajasthan).

Table - 3

Size or Magnitude of operation

S.

No.

Name Abbreviation Existing

capacity

(MTA)

Proposed

capacity

(MTA)

Total capacity

after

expansion

(MTA)

A. Multipurpose plant/Fluorospecialty plant

1 Trifluoroacetic acid TFA 1600.0 - 1600.0

2 Trifluoroacetic anhydride TFAA

3 Methyl chlorodifluoroacetate MCDFA

4 Chlorodifluoroacetic acid CDFA

5 Chlorodifluoroacetic anhydride CDFAA

6 Ethyl trifluoroacetate ETFA

7 Ethyl trifluoroacetoacetate ETFAA

8 2,3,4,5,6 Pentafluorobenzoic acid PFBA 100.0 125 225

9 Pentafluorobenzene PFB

10 Bromopentafluoro benzene BPFB

11 Pentafluorophenol PFP

12 Difluoroacetic acid DFA 600.0 600.0

13 Ethyl difluoroacetate EDFA

14 Ethyl difluoroacetoacetate EDFAA

15 Ethyl 3 – amino - 4, 4, 4 - trifluoro crotonate

P9 400.0 100 500

16 Tetrafluoro benzyl alcohol TFBAL 100.0 - 100.0

17 4-bromofluoro benzene PBFB 200.0 - 200.0

18 Difluoromethyl pyrazole acid - 225 225

19 Pyrazole acid amides

20 Alkyl & Phenyl Pyrazole derivatives

21 Other Pyrazolic acid/amides & derivatives

22 2,4,5 trifluorophenyl acetic acid TPA

23 Other fluorinated aliphatics

24 Other fluorinated acids





M/s. SRF Limited 11

(Unit: Bhiwadi)

25 Methyl trifluoroacetate MTFA - 325 325

26 Methyl bromodifluoroacetate MBDFA

27 Ethyl bromodifluoroacetoacetate EBDFAA

28 Ethyl bromodifluoroacetate EBDFA

29 Ethyl chlorodifluoroacetate ECDFA

30 Isopropyl trifluoroacetate IPTFA

31 Methyl difluoroacetate MDFA

32 Sodium trifluoroacetate

33 Potassium trifluoroacetate

34 Sodium chlorodifluoroacetate

35 Other fluorinated esters

36 Other chlorofluoro esters

37 2,3,5,6 Tetrafluoro-4-methylbenzyl alcohol

- 125 125

38 Trifluorethanol

39 Hexafluoropropanol

40 Fluorinated alcohols

41 1,4-difluorobenzene - 325 325

42 1,3-difluorobenzene

43 1,2,4-trifluorobenzene

44 Hexafluorobenzene HFB

45 Trifluoroethoxy benzene

46 Cynopentafluoro benzene

47 Fluorobenzene FB

48 Difluoronitro benzene

49 Difluoro dinitro benzene

50 Fluorobenzenes

51 Fluoronitro benzenes

52 Fluoroiodo benzenes

53 Trifluoroacetamide - 275 275

54 Trifluoroacetone TFAc

55 Trifluoroacetonitrile

56 Trifluoroethyl amine

57 Trifluoroethyl amine hydrochloride

58 Fluoro anhydrides

59 Fluoro amides

60 Fluoro aldehydes

61 Fluoro ethers

62 Fluoro ketones

63 Other fluorinated acid derivatives

64 Sulphur tetrafluoride SF4 - 125 125

65 Nitrogen trifluoride NF3

66 Diethyl amino sulphur trifluoride

67 Other fluorine/fluorinated reagents

68 Difluoromethane sulphonyl chloride DFMSC - 175 175

69 Difluorobenzene sulphonyl chloride

70 Perfluorobutane sulphonyl fluoride





M/s. SRF Limited 12

(Unit: Bhiwadi)

71 Perfluorobutane sulphonic acid

72 Fluoro aryl sulphonic acids & derivatives

73 Fluoro alkyl sulphonic acids & derivatives

74 Boron trifluoride - 750 750

75 Potassium fluoride

76 HF-Pyridine

77 BF3 Etherate

78 Other inorganic fluorides

79 3-trifluoromethyl aniline ABTF - 225 225

80 4-trifluoromethyl aniline

81 2,6-Dichloro-4-trifluoromethyl aniline Synthon1

82 Heptafluoroisopropyl-2-methyl aniline HFPOT

83 Difluoromethoxy aniline

84 Trifluoromethoxy aniline

85 Difluoro anilines & other fluorinated anilines

86 Other fluorinated anilines

87 Difluorobenzo dioxole - 225 225

88 5-Bromo-2,2-difluoro-1,3-benzodioxole DFBD

89 Difluorobenzodioxole methyl ester DFBD Me

90 Fluoroesters

Total 3000 3000 6000

B. Cloromethanes (TPA ) (Product range methylene chloride, chloroform, carbontetrachloride)

50000

Nil (Extraction of intermediate

Methyl chloride as a

product)

50000

C. New Generation Refrigerants & Refrigerant Blends (TPA) (details of the products is provided in Annexure-1) 0 90,000 90,000

D. HFC134a (Product range HFC134a) 12000

TPA

Nil (Addition of

HFC32) 12000 TPA

(v) Project description with process details (a schematic diagram/ flow chart showing the

project layout, components of the project etc. should be given)

The procedure for production of Multi-Purpose Plant / Fluorospeciality Plant, HFC 134a Plant,

Chloromethane plant and New Generation Refrigerants & Refrigerant Blends process details are

enclosed as Annexure -2.

Process flow chart for New Generation Refrigerants & Refrigerant Blends Plant, MPP /

Fluorospeciality Plant, CMS Plant & HFC134a Plant has been enclosed as Annexure - 3.





M/s. SRF Limited 13

(Unit: Bhiwadi)

(vi) Raw material required along with estimated quantity, likely source, marketing area

of final products, mode of transport of raw material and finished product.

a) Raw Material Requirements:

Details of Raw material requirement for Multi-Purpose Plant /Fluorospeciality Plant),

Chloromethane plant, New Generation Refrigerants & Refrigerant Blends & Chloromethane

plant has been enclosed as Annexure - 4.

Details reg. Fuel is given in Table 4.

Table - 4

Fuel Requirement

S.

No.

Name of

Raw

Material

Quantity Required (TPA) Calorific

value

(Kcal./kg)

% Ash

%

Sulphur

Source Distance & Mode of

Transportation Existing Proposed

Expansion

Total after

proposed

expansion

1. Coal 125070 Nil 125070 3500-4000 35-40 0.5 CCL Through trucks via road

2. Husk 67980 NIL 67980 3000-3300 5-7 <0.5 Open Market Through Trucks via road,

from different Locations

3. Lignite 128370 NIL 128370 3500-4000 15-20 2-3 Open Market Through trucks via road

3. HSD 1800 NIL 1800 11840 - <0.05 IOCL Rewari 30 kms through Tankers.

4. FO 3200 NIL 3200 9800 to

10200

.034 to

0.15

1.18 to

4.0

Reliance

industries by Tankers

b) Marketing Area and Mode of transportation of Final Product

SRF has explored National and international markets for their products from both existing and

proposed expansion units, Most of the product will be exported to the West Asian and North

American countries in sealed tankers, barrels and other sophisticated carrying containers via sea

and air route. Increasing markets has also been explored for both refrigerants products and

fluorospeciality products. Refrigerants products have markets available all over the nation with

increasing demand from small vehicle AC manufacturing unit to the large and big industries

requiring refrigeration.

Whereas Speciality products holds markets in a rapid booming and revolutionary sector like

pharmacy and agricultural products, with this demand from the other industries as a raw

material for production of various other products has also came in.

Products are being and will be provided to various sectoral markets of nation with the increasing

demand. Transportation within the country will be done in the various sealed containers,

isotanks, cylinders and barrels, via road, rail, waterways and airways.





M/s. SRF Limited 14

(Unit: Bhiwadi)

(vii) Resources optimization/ recycling and reuse envisaged in the project, if any, should be

briefly outlined.

Water as a resource is recycled at each possible step of the process and more latest technology

and methodology will be adopted to conserve and reuse the resource.

Waste water being/ will be generated from the process goes to ETP and treated water after pH

corrections is used again back into the various processes and remaining is used for the

horticulture purposes.

(viii) Availability of water its source, energy /power requirement and source should be given.

a) Water Requirement and Source

With their strong focus on conservation recycling & reuse of water, industry has significantly

reduced their water consumption & their existing consumption to 2300 KLD. Proposed

expansion further needs about 300 KLPD water. Therefore, total water requirement after

expansion will be 2600 KLPD.

Source: Ground water & Recycled water (Allowable quota 2921 KLPD).

b) Power Requirement and Source

Total power requirement after proposed expansion will be 11.1 MW.

Source: Captive Power Plant (12MW) and RSEB (4MW).

(vii) Quantity of waste to be generated (liquid and solid) and scheme for their

management/disposal

� A full fledged ETP is already in place. Most of the treated water from ETP is being/will be

recycled back to the processes and remaining is/will be used for greenbelt development.



� Ultra filtration system rejects is being / will be used as make up water for cooling system.

� Spent oil will be generated from the proposed expansion and new installation project. The

same will be sent to authorized recycler as per current practices followed.

� The sludge from ETP arising out of water treatment contains CaF2. This would be mixed

with the raw material of HF plant & hence 100% recycling is being/will be done.

� The sludge from STP is being dried on sludge drying beds and is being/will be used for


� Plastic cut drums generated from existing/proposed facilities is/will be sent to secured

landfill.





M/s. SRF Limited 15

(Unit: Bhiwadi)

4.0 SITE ANALYSIS

(i) Connectivity

The plant site is well connected to National Highway i.e NH-71B (~5.5 km in N direction).

The nearest railway station is Rewari Railway Station (~20 km in WNW direction from the plant

site) and nearest Airport is Indira Gandhi International Airport, New Delhi (~50 km in NNE

direction from the plant site).

The site is suitably located with respect to availability of raw material, water, road network,

skilled / semi-skilled / unskilled and professional manpower etc. All communication facilities

such as telephone, telefax & internet are available in the vicinity of the plant site.

(ii) Land form Land use and land ownership

Total plant area is 34.0 ha. Since, the proposed expansion and new installation will be done

within the existing plant premises, thus, no additional land is required. Hence, land ownership

will be considered as industrial type.

The plant area break- up is given in Table - 5.

Table – 5

Plant Area Break- Up

Unit

Area (ha)

Existing Additional for

proposed expansion

Total after proposed

expansion

Total Constructed Plant area 7.99 1.0 8.99

Total road area 3.03 - 3.03

Greenbelt area 12.24 - 12.24

Open area 10.74 (-) 1.0 9.74

Total Plant Area 34.0 Nil 34.0

(iii) Topography

Rajasthan has varying topographic features though a major part of the state is dominated by

parched and dry region. The extensive topography includes rocky terrain, rolling sand dunes,

wetlands, barren tracts or land filled with thorny scrubs, river-drained plains, plateaus, ravines

and wooded regions. In a more broad way the topography of Rajasthan can be divided in the

following regions- The Aravalli or The Hilly regions, The Thar and other arid regions, the

Plateaus including Vindhaya and The Malwa, the Fertile plains including The Mewar, the Forest

Regions and the Water bodies including Rivers and Salt Lakes.





M/s. SRF Limited 16

(Unit: Bhiwadi)

(iv) Existing land use pattern (agriculture, non-agriculture, forest, water bodies (including

area under CRZ), shortest distances from the periphery of the project to periphery of the

forests, national park, wild life sanctuary, eco sensitive areas, water bodies (distance

from the HFL of the river), CRZ. In case of notified industrial area, a copy of the gazette

notification should be given

Table – 6

Environmental Settings of the Area

S. No. Particulars Details

(with approx. distance & direction from the plant site)

1. Nearest Town /City � Nearest Town: Bhiwadi (~4.0 km in NNW direction)

� Nearest City : Rewari(~22 km in NNE direction)

2. Nearest National Highway / State Highway NH-71B ( ~5.5 km in N direction)

SH-25 ( ~1.3 km in W direction)

3. Nearest Railway station Rewari Railway Station (~20 km in W direction)

4. Nearest Airport Indira Gandhi International Airport, New Delhi (at a distance of ~50

km in NNE direction)

5. Archaeological important site None within 10 km radius

6. National Parks, Wild Life Sanctuaries,

Biosphere Reserves, Tiger/ Elephant

Reserves, Wildlife Corridors etc. within 10

km radius

None within 10 km radius

7. Reserved Forests (RF) / Protected Forests

(PF) etc. within 10 Km. radius

Protected Forests


� Banvan (~2.5 km in E direction)

� Khori Kalan (~4.5.0 km in SE direction)

� Sarekalan (~7.0 km in SE direction)


� Khidarpur (~4.0 km in NE direction)

� Gondhan (~1.2 km in NNE direction)

Reserve Forests

� Rangala (~7.5 km in NE direction)

� Indaur (~8.5 km in SE direction)

8. River / Water Body (within 10 km radius) � Sahibi River (Seasonal) (~9.0 km in WNW direction)

� Indori lake (~9 km in SE direction)

� Indori Nala (~8.5 km in ENE direction)

9. Soil Type Sandy loam

10. Seismic Zone Zone – II [as per IS 1893 (Part-I): 2002]





M/s. SRF Limited 17

(Unit: Bhiwadi)

(v) Existing Infrastructure

Total plant area is 34 ha and the proposed expansion and new installation will be done within

the existing plant premises.

(vi) Soil Classification

The soil is of silty loam type with yellowish brown colour.

(vii) Climatic Data from Secondary Sources

The Alwar district has a hot dry summer and a moderate cold season. The temperature

continuously rises in the hot season from March to June and goes down after mid-November till it

declines up to the month of January. The average minimum temperature in the district goes down

to 5oC while maximum temperature rises upto 440C throughout the year. The region is medium

rainfall area. On an average, 500 - 600 mm of rainfall annually occurs in the area, mainly from

southwest monsoon. Nearly 80 % of annual rainfall is received during the September. Only about

5 % of the normal rainfall is received during the other season. On an average there are 30 - 35

rainy days, that is, days with rainfall of 2.5 mm or more in a day.

(vii) Social Infrastructure available

Telephone and medical facilities are available in the nearby towns. Adequate infrastructure has

been developed by SRF around their existing chemical plant premises. Various infrastructure

development activities like construction of classrooms, toilets, drinking water facility, and

development of playground have been brought into existence. Other facilities like small shops

and markets are existing in the area that supports the basic lifestyle of the people.

5.0 PLANNING BRIEF

(i) Planning Concept (type of industries, facilities, transportation etc.) / Town and country

Planning/ Development authority classification.

The existing industry is chemical industry and proposed expansion and new installation will be

done within the existing plant premises. Facilities required for the proposed expansion and new

installation project will be provided as per requirement.

Transportation of raw material and final product will be done via existing road.

(ii) Population Projection

Temporary influx of people will be there as the managerial and supervisory staff will generally

be outsider. A projection may be made by a governmental organization, or by those unaffiliated

with a government.





M/s. SRF Limited 18

(Unit: Bhiwadi)

(iii) Land use planning

Total existing area is 34.0 ha. Proposed expansion and new installation will be done within the

existing plant premises; thus, no additional land will be required. Out of the total plant area,

12.24 ha (~36 %) has already been developed under green belt/ plantation and same will be

properly maintained.

(iv) Assessment of infrastructure demand (Physical & Social)

M/s. SRF Limited has assess the demand of infrastructure (Physical & Social) in the nearby area

of the plant site and development activities are being undertaken under corporate social

responsibilities program for rural development initiatives for the upliftment of the nearby

communities.

(v) Amenities/Facilities

M/s. SRF Limited has taken various infrastructure development activities around the plant

premises, facilities like construction of classrooms, toilets, drinking water facility, development

of playground have been brought into existence. In nearby schools other facilities like small

establishment of IBM kid smart centres, capacity building training, community health

programmes are being /will be organised. Development of area by providing vocational training

and promoting women self help groups is also being done which will be promoted further. SRF is

being developing/will develop the amenities/facilities in nearby area of the plant site as per

requirement of local people of the nearby area under corporate social responsibilities

programme.

6.0 PROPOSED INFRASTRUCTURE

(i) Industrial Area (Processing Area)

No additional area will be required for the proposed expansion and new installation as

expansion will be within the existing plant premises.

(ii) Green Belt

Out of the total plant area i.e. 34 ha about, 12.24 ha (~36 %) has already been developed under

green belt/ plantation and same will be properly maintained.

(iii) Social Infrastructure

Proposed expansion and new installation project will result in growth of the surrounding areas

by increased direct and indirect employment opportunities in the region including development

and supporting infrastructure.

(iv) Connectivity

The plant site is well connected to National Highway i.e NH-71B (~5.5 km in N direction).





M/s. SRF Limited 19

(Unit: Bhiwadi)

The nearest railway station is Rewari Railway Station ( ~22 km in WNW direction) and nearest

Airport is Indira Gandhi International Airport, New Delhi (~50 km in NNE direction).

The site is suitably located with respect to availability of raw material, water, road network,

skilled / semi-skilled / unskilled and professional manpower etc. All communication facilities

such as telephone, telefax & internet are available in the vicinity of the plant site.

(v) Drinking Water

As the proposal is of expansion of the facility at the existing site therefore increase in drinking

water requirement will be of insignificant amount. Approximate increase will be in the range of

100 to 200 Liter per day.

(vi) Sewerage system



� The sludge from STP is being dried on sludge drying beds and is being/will be used for


(vii) Industrial waste management

� A full fledged ETP is already in place. Most of the treated water from ETP is being/will be

recycled back to the processes and remaining is/will be used for greenbelt development.

� Ultra filtration system rejects will be used as make up water for cooling system.



(viii) Solid waste management

� The sludge from ETP arising out of water treatment contains CaF2. This would be mixed

with the raw material of HF plant & hence 100% recycling is being/will be done.

� The sludge from STP is being dried on sludge drying beds and used for horticulture purpose,

which is a common practice in the existing plant. .

� Plastic cut drums generated from existing/proposed facilities is/will be sent to secured

landfill.

(ix) Power requirement and source

After expansion power requirement will be 11.1MW which will be sourced from Captive power

plant (12MW) and RSEB (4MW).





M/s. SRF Limited 20

(Unit: Bhiwadi)

7.0 REHABILITATION AND RESETTLEMENT (R & R) PLAN

(i) Policy to be adopted (Central/State) in respect of the project affected persons including

home oustees, land oustees and landless labourers

R & R Plan is not applicable to the proposed expansion and new installation project as the

proposed expansion will be done within the existing premises & no additional land is required

for the same.

8.0 PROJECT SCHEDULE AND COST ESTIMATES

(i) Likely date of start of construction and likely date of completion

The project will start only after obtaining Environmental Clearance and all other required

clearance. An implementation period of 60 months from the date of signing/ effectiveness of the

main equipment supply contract is foreseen for this project.

The likely date of start of construction is after obtaining EC from MoEFCC / CTE from SPCB &

likely date of start of operation within 3 years of obtaining EC/ CTO.

(ii) Estimated project cost:

� Capital Cost of the project is Rs. 20.0 Crores.

� Environment Management Protection Cost:

o Capital Cost: Rs. 2.0 Crores

o Recurring Cost: Rs. 0.5 Crores/annum.

9.0 ANALYSIS OF PROPOSAL

(i) Financial and social benefits with special emphasis on the benefit to the local people

including tribal, population, if any in the area

Proposed expansion and new installation project will result in growth of the surrounding areas

by increased direct and indirect employment opportunities in the region including development

and supporting infrastructure.

Special emphasis on financial and social benefits will be given to the local people including tribal

population, if any, in the area. Development of social amenities will be in the form of medical

facilities, education to underprivileged and creation of self-help groups.

Also, the state will get revenues in terms of taxes and local people will get opportunities in terms

of indirect employment. Business opportunities for the local people will be enhanced like

transport of product in the market, maintenance & housekeeping contract work etc.

No adverse effect on environment is envisaged as proper mitigation measure will be taken up for

the same.

ANNEXURE-1

List of Refrigerant & Refrigerant blends:

S. No Product Total Plant Capacity (TPA)

1 R-32 (Difluoro Methane) 120002 R-600A (Isobutane) 33003 R-600 (n-Butane) 10004 R-290 (Propane) 10005 R133A (Chlorotrifluoro Ethane) 7006 R21 (Dichlorofluoro Methane) 12507 TCE (Trichloro Ethylene) 18508 R-23 (Trifluoro Methane) 12509 R-227 (HeptaFluoro Ethane) Pharma Grade 2000

10 C1 (Methyl Chloride) 200011 R-125 (Pentafluoro Ethane) 1850012 R143A (Trifluoro Ethane) 300013 R-152A (Difluoro Ethane) 300014 R-142B (Chlorodifluoro Ethane) 140015 R404A (R-125+143A+R-134a) 200016 R407C (R-32+R-134A+R-125) 250017 R410A(R-32+R-125) 800018 Blend of R-152A+R-134A 200019 Blend of R-142B+R-22 75020 Blend of R-134A+ DME (Di Methyl Ether) 250021 R-407 A(R-32+R-134a+R-125) 125022 R-407 F(R-32+R-134a+R-125) 125023 R-417 A (R-125+R-134a+R-600) 125024 R-417 B(R-125+R-134a+R-600) 125025 R-421 A(R-125+R-134A) 125026 R-421 B (R-125+R-134A) 125027 R-422 A(R-125+R-134a+R-600A) 125028 R-422 B(R-125+R-134a+R-600A) 125029 R-422 C(R-125+R-134a+R-600A) 125030 R-422 D(R-125+R-134a+R-600A) 125031 R-424 A(R-125+R-134a+R-600+R-600a+R-601a) 125032 R-427 A(R-134+R-125+R-32+R-143a) 125033 R-428 A(R-125+143a+R-600a+propane) 125034 R-434 A(R-125+R-134a+R-143a+R-600a) 125035 R-438 A(R-134a+R-32+R-125+butane) 125036 R-507 A(R-134a+R-125) 1250

TOTAL 90,000

ANNEXURE - 2

1

MANUFACTURING PROCESS

MULTIPURPOSE PLANT (FLUOROSPECIALITY PLANT)

1. Trifluoroacetic acid (TFA)Trichloroacetyl chloride (TCAC) & hydrogen fluoride (HF) are passed through a reactor togenerate TFA & Hydrogen Chloride (HCl gas). Reaction outlet is absorbed in water togenerate Trifluoroacetic Acid (TFA). HCl is absorbed in water to make saleable 33% HCl.2. Trifluoroacetic Anhydride (TFAA)TFA is reacted with SO3 present in oleum to form TFAA & water. Unreacted TFA with spentsulfuric acid is recycled to TFA plant for TFA recovery. Crude TFA from reactor is taken fordistillation.3. Methyl chloro difluoro acetate (MCDFA)Methanol reacts with chlorodifluoroacetyl fluoride to form ester of methyl chlorodifluoroacetate. Product is distilled from top is sent to storage.4. Chlorodifluoro Acetic Acid (CDFA)Chlorodifluoro Acetic Acid is produced in the following two steps: Reaction of Trichloroacetylchloride with Hydrogen fluoride to form Chlorodifluoro acetyl fluoride. Hydrolysis ofChlorodifluoro acetyl fluoride with water to form Chlorodifluoro acetic acid & hydrogenfluoride.5. Chloro difluoro Acetic anhydride (CDFAA)Chloro difluoro Acetic Acid is reacted with SO3 present in oleum to form Chloro difluoroAcetic Anhydride & water. Crude Chloro difluoro acetic acid from reactor is taken fordistillation.6. Ethyl Trifluoroacetate (ETFA)Reaction:Ethanol reacts with Trifluoroacetyl fluoride to form ester of Ethyl Trifluoroacetate.Distillation:After reaction is complete product is removed from the reactor by reactive distillation.Product distilled from top is sent to storage.7. Ethyl trifluoroacetoacetate (ETFAA)Ethyltrifluoroacetate (ETFA) is reacted to form ETFAA. ETFAA is recovered by distillation.

ANNEXURE - 2

2

8. Pentafluorobenzoic Acid (PBFA)Benzonitrile and chlorine are passed through a reactor. HCL is absorbed in water to makesaleable 33% Hydrochloric Acid. PCBN is then hydrolyzed in H2SO4 acid to generatePentafluorobenzoic Acid (PFBA, solid)9. Pentafluorobenzene (PFB)Reaction:Pentafluorbenzoic acid is mixed with water and then heated to high temperature andpressure.Extraction & Distillation:After reaction is complete organic layer is extracted and then sent to distillation. Productobtained from column top is then sent to storage.10.Bromopentafluorobenzene (BPFB)Pentafluorobenzoic acid is heated to high temperature and pressure to form intermediatecompound. Product is extracted and aqueous layer is treated. Organic layer is then decantedand distilled to give product which is then sent to storage.

11. Pentafluorophenol (PFP)Pentafluorobromobenzene reacts with BF3 Etherate to form an intermediate product.This intermediate product is then extracted with ether and is heated at elevated pressure toform product pentafluorophenol.Product formed is then sent to distillation to remove ether from column top and pureproduct is obtained from column bottom. Product obtained is then sent to storage.12. Parabromofluorobenzene (PBFB)Fluorobenzene and bromine are reacted in a reactor to generate p-Bromofluorbenzene(PBFB, liquid) and Hydrobromic Acid (HBr, gas).Hbr is absorbed in water to generatesaleable 48 % Hydrobromic Acid.p-Bromofluorobenzene is distilled out and packed fordispatched.13. Tetrafluorobenzyl Alcohol (TFBAL)The process for the manufacture of Tetrafluorobenzyl Alcohol uses C6F5CN (as Rawmaterial), an intermediate, Produced in the manufacturing process of the existing productPentafluoro benzoic acid. All the reactions involved are in the solid/Liquid phase; hence noair emission is envisaged.

ANNEXURE - 2

3

14. Difluoroacetic Acid (DFA)Methyl Chloro Difluoroacetate is reacted with Methanol at high pressure & temperatureconditions to give an intermediate compound. This compound is then reacted withhydrochloric acid to give Difluoroacetic acid.The product is then neutralized with sodium hydroxide to kill acidity & then extracted toremove methanol & other organics.Final product is then bone dried by extraction with sulfuric acid. After removal of moistureproduct is sent to storage.15. Ethyldifluoroacetate (EDFA)R22 is passed through Ethanol solution to give product Ethyl Difluoroacetate.After reaction mixture is sent for layer separation where heavy organic layer is decantedfrom bottom and is then treated to remove any ethanol present in the product as impurity.Final product is then again layer separated to remove aqueous layer and organic layer is thensent to storage.16. Ethyldifluoroacetoacetate (EDFAA)EDFA is reacted to form salt of EDFAA in presence of suitable solvent. Salt is acidified withDry HCl to form EDFAA and Sodium salt at RT. Solvent is recovered from Rm and taken forfiltration. Crude product is further distilled and purified to get desired quantity product.17. Ethyl 3-amono-4,4,4-trifluorocrotonateETFAA is reacted with ammonia to form ammonium salt of ETFAA. Amino crotanate isformed by thermal decomposition of salt.18. 2,4,5 Trifluorophenyl Acetic Acid.2,4-Dichloroacetophenone is reacted with Chlorosulfonic acid to form 5-Acetyl-2,4-dichlorobenzene-1-sulfonylchloride, is fluorinated using KF .5-Acetyl-2,4-dichlorobenzene-1-sulfonyl fluoride is fluorinated using KF to form 1-(2,4,5-trifluorophenyl) ethanone.Reaction mass is reacted with morpholine and sulfur to form 2,4,5 Tri fluorophenylaceticacid.19. TrifluoroacetoneETFAA, reacts with water to form Trifluoroacetone, Ethanol and carbon dioxide. Which aresubsequently separated.

ANNEXURE - 2

4

20. Sulfur Tetra fluoride (SF4)Chlorine gas is purged into the molten for the formation of Sulfur Monochloride Vapor whichare condensed and collected. Fluorine gas is purged into the Sulfur Monochloride for theformation of Sulfur Tetra fluoride and Sulfur Dichloride. The Sulfur Tetra fluoride gas comingout of the reactor is condensed, collected and filled into the cylinders.21. Difluoromethane Sulphonyl Chloride (DFMSC)1. Benzyl chloride, thio-urea & caustic lye is reacted to form benzyl mercaptan thiouron HCl..2. Benzyl mercaptan on reaction with R22 (Chlorodifluoromethane) & caustic to form BDFMS(Benzyl Difluoromethyl Sulphide).3. Layer separation is done to remove aqueous layer. Organic layer is taken to distillation torecover pure DFMSC.22. 3-trifluoromethyl aniline (ABTF)Benzotrifluoride reacts with AHF to form benzotrifluoride which again reacts with sulphuricacid and nitric acid to form 3 nitro benzotrifluoride. 3-nitrobenzotrifluoride reacts to form 3amino benzotrifluoride.23. 2,6-dichloro-4-trifluoromethyl aniline (Synthon1)1. p-Chlorotoluene is photochlorinated to form 4-ClBTC (1-chloro-4-(trichloromethyl)benzene).2. 4-ClBTC is reacted with AHF to form 4-ClBTF (1-chloro-4-(trifluoromethyl) benzene).3. 4-ClBTF is treated with ammonia to form 4-ABTF (4-Amino benzotrifluoride).4. 4 -ABTF is treated with chlorine to form Synthon1.24. Heptafluoroisopropyl-2-methyl aniline (HFPOT)1. Hexafluoropropylene (HFP) is reacted with bromine to form DBHFP at atmospherictemperature.2. DBHFP is reacted with KF for the formation of HFiPBr.3. HFiPBr is reacted with o-toluidine & triethylamine to form HFPOT & HFPOT Isomer.4. HFPOT salt is dissolved in MTBE & then neutralized with ammonia to form ammonium saltwhich is filtered .MTBE & HFPOT is then taken to distillation to recover pure HFPOT.25. 5-Bromo-2,2-difluoro-1,3-benzodioxole (DFBD)1. 1,3-benzodioxide is reacted with Phosphorus pentachloride to give 2,2-Dichloro-1,3-benzodioxide.2. 2,2-Dichloro-1,3benzodioxide is fluorinated with HF to give 2,2-Difluoro-1,3-benzodioxide.3. 2,2-Difluoro-1,3-benzodioxide formed in then further brominated with HBr to give 5-Bromo-2,2-Difluoro-1,3-benzodioxole.

ANNEXURE - 2

5

26. Difluorobenzodioxole methyl ester (DFBDMe)1. 1,3-benzodioxole reacts with phosphorus pentachloride to form DCBD Me and phosphorustrichloride.2. 2,2 Difluoro benzodioxole reacts with bromine to form 5-Bromo-2,2-Difluoro-1,3-Benzodioxole and HBr.CHLOROMETHANES (CMS) PLANT

(a) Hydrochlorination & C1 Wash Section :In Hydro section, main raw materials are: Methanol and 100% HCL (FromPhotochlorination section). The reaction takes place. At the outlet of hydro-reactor, C1(Methyl Chloride) is formed which after purification (removal of acidity, free chlorine &moisture, etc.) and compression is sent to storage.CH3OH + HCL CH3CL + H2O

CH3Cl + Cl2 CH2Cl2 + HCl

CH3Cl + 2 Cl2 CHCl3 + 2 HCl

CH3Cl + 3 Cl2 CCl4 + 3 HCl

New Generation Refrigerants and Refrigerant Blends Plant

1. R-32 PLANTR-32 can be purchased directly from market and store in MTF (Main Tank Farm) or ProductR-32 is manufactured by the following stepwise process:FEEDSECTION

REACTORSECTION

CRUDEDISTILLATION

WASHSECTION

MTF(MAINTANKFARM)

ITF(INTERMEDIATETANK FARM)

PRODUCTDISTILLATION

ANNEXURE - 2

6

Feed Section:Dichloromethylene & Anhydrous Hydrofluoric acid pumped from the respective storagevessels to plant reactors.Reactor Section:Dichloromethylene & Anhydrous Hydrofluoric acid reacts in a gas phase to produce R-31A.Then R-31A reacts with AHF & produce Hydrochloric acid & R-32A.Crude Distillation:In this section Hydrochloric acid is removed from reactor outlet crude mixture & R-32A isremoved in a crude form. From this section AHF & R-31A is recycled back to reactors bydifferent columns.Wash Section:Crude R-32A gas is scrubbed in water as a result dilute hydrofluoric acid get seperated asbyproduct, then by sulfuric wash it leads to dry acidity free crude gas which is thencompresses to liquid form.Product Distillation:Pure R-32A is recovered in this operation and distilled R-31A is recycled back to crudedistillation.ITF &MTF:Product R-32A is then stored in ITF (Intermediate Tank Farm) for quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.

2. R-600A PLANTR-600A can be purchased directly from market and fill in MTF (Main Tank Farm) or ProductR-600A is manufactured by the following stepwise process:FEED SECTION DE-ETHANIZER DE-PROPANIZER

MTF (MAINTANK FARM)


DE-ISOBUTANIZER

Feed Section:LPG pumped from the respective storage vessels to De-ethanizer column.De-ethanizer column:Ethane will separate out from mixture of Ethane, Propane, n-Butane and Iso-butane.De-propanizer Column:Propane will separate out from mixture of Propane,n-Butane and Isobutane.

ANNEXURE - 2

7

De-Isobutanizer :Isobutane will separate out from mixture of n-Butane and Isobutane.ITF & MTF:Product Isobutane is then stored in ITF (Intermediate Tank Farm) for quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.

3. N-Butane PLANTn-Butane can be purchased directly from market and fill in MTF (Main Tank Farm) orProduct n-butane is manufactured by the following stepwise process :FEED SECTION DE-ETHANIZER DE-PROPANIZER

MTF (MAINTANK FARM)


DE-ISOBUTANIZER

Feed Section:LPG pumped from the respective storage vessels to De-ethanizer column.De-ethanizer column:Ethane will separate out from mixture of Ethane,Propane,n-Butane and Isobutane.De-propanizer Column:Propane will separate out from mixture of Propane,n-Butane and Isobutane.De-Isobutanizer:Isobutane will separate out from mixture of n-Butane and Isobutane.ITF &MTF:Product n-butane is then stored in ITF (Intermediate Tank Farm) for quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.

4. Propane PLANTPropane can be purchased directly from market and fill in MTF (Main Tank Farm) or ProductPropane is manufactured by the following stepwise process:FEED SECTION DE-ETHANIZER DE-PROPANIZER

MTF(MAIN TANKFARM)

ITF (INTERMEDIATETANK FARM)

ANNEXURE - 2

8

Feed Section:LPG pumped from the respective storage vessels to De-ethanizer column.De-ethanizer column:Ethane will separate out from mixture of Ethane,Propane,n-Butane and Isobutane.De-propanizer Column:Propane will separate out from mixture of Propane,n-Butane and Isobutane.ITF &MTF:Product Propane is then stored in ITF (Intermediate Tank Farm) for quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.

5. R-133A PLANTR-133A can be purchased directly from market and fill in MTF (Main Tank Farm) or ProductR-133A is manufactured by the following stepwise process:FEEDSECTION

REACTORSECTION

CRUDEDISTILLATION

WASHSECTION

MTF(MAINTANKFARM)


PRODUCTDISTILLATION

Feed Section:Trichloroethylene & Anhydrous Hydrofluoric acid pumped from the respective storagevessels to plant reactors.Reactor Section:Trichloroethylene & Anhydrous Hydrofluoric acid reacts in a gas phase to produce R-133Aand Hydrochloric acid.Crude Distillation:In this section Hydrochloric acid is removed from reactor outlet crude mixture & R-133A isremoved in a crude form. From this section AHF & TCE is recycled back to reactors.Wash Section:Crude R-133A gas is scrubbed in water as a result dilute hydrofluoric acid get separated asbyproduct, then by sulfuric wash it leads to dry acidity free crude gas which is thencompresses to liquid form.Product Distillation:Pure R-133A is recovered in this operation.

ANNEXURE - 2

9

ITF &MTF:Product R-133A is then stored in ITF (Intermediate Tank Farm) for quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.6. R-21 PLANTR-21 can be purchased directly from market and fill in MTF (Main Tank Farm) or Product R-21 is manufactured by the following stepwise process:

FEED SECTION REACTOR SECTION WASH SECTION

MTF (MAINTANK FARM)


PRODUCTDISTILLATION

Feed Section:Trichloromethane & Anhydrous Hydrofluoric acid pumped from the respective storagevessels to plant reactors.Reactor Section:Trichloromethane & Anhydrous Hydrofluoric acid reacts in a gas phase to produce R-21.Wash Section:Crude R-21 gas is scrubbed in water as a result dilute hydrofluoric acid get separated asbyproduct, then by sulfuric wash it leads to dry acidity free crude gas which is thencompresses to liquid form.Product Distillation:Pure R-21 is recovered in this operation.ITF &MTF:Product R-21 is then stored in ITF (Intermediate Tank Farm) for quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.

7. TCE (Trichloroethylene) PLANTTCE can be purchased directly from market and fill in MTF (Main Tank Farm) or Product TCEis manufactured by the following stepwise process:FEEDSECTION

REACTORSECTION

WASH SECTION DECANTATION

MTF (MAINTANKFARM)


PRODUCTDISTILLATION

ANNEXURE - 2

10

Feed Section:Di Chloroethylene& chlorine gas pumped from the respective storage vessels to plantreactors.Reactor Section:Di Chloroethylene& chlorine gas reacts in a gas phase to produce TCE and Tetrachloroethylene.Wash Section:Crude TCE is scrubbed in water as a result dilute hydrochloric acid get separated asbyproduct, then by caustic wash and decantation it leads to dry acidity free crude.Product Distillation:Pure TCE is recovered in this operation and distilled Tetra chloroethylene is used asbyproduct.ITF &MTF:Product TCE is then stored in ITF (Intermediate Tank Farm) for quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.

8. R-23 PLANTR-23 can be purchased directly from market and fill in MTF (Main Tank Farm) or Product R-23 is manufactured by the following stepwise process:FEED SECTION REACTOR SECTION WASH SECTION

MTF (MAINTANK FARM)


PRODUCTDISTILLATION

Feed Section:Trichloromethane& Anhydrous Hydrofluoric acid pumped from the respective storagevessels to plant reactors.Reactor Section:Trichloromethane& Anhydrous Hydrofluoric acid reacts in a gas phase to produce R-22 & R-23.Wash Section:Crude R-22 & R-23 gas is scrubbed in water as a result dilute hydrofluoric acid get separatedas byproduct, then by sulfuric wash it leads to dry acidity free crude gas which is thencompresses to liquid form.Product Distillation:Pure R-23 is recovered in this operation.

ANNEXURE - 2

11

ITF & MTF:Product R-23 is then stored in ITF (Intermediate Tank Farm) for quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.9. R-125 PLANTR-125 will be purchased directly from market and fill in MTF (Main Tank Farm). Afterapproval from quality it will be sent for filling.10. R-143 PLANTR-143 will be purchased directly from market and fill in MTF (Main Tank Farm). Afterapproval from quality it will be sent for filling.11. R-152A PLANTR-152A will be purchased directly from market and fill in MTF (Main Tank Farm). Afterapproval from quality it will be sent for filling.12. R-142B PLANTR-142B will be purchased directly from market and store in MTF (Main Tank Farm). Afterapproval from quality it will be sent for filling.13. R-404A PLANT (R-125: R-134A: R-143A = 44 : 4 :52)R-125 and R-143A will be purchased directly from market and fill in MTF (Main Tank Farm).R-134A will be manufactured within SRF and will store in MTF. Then we will make a blend ofR-125, R-134A and R-143A in specific ratio. After approval from quality it will be sent forfilling.14. R-407C PLANT (R-125: R-134A: R-32 = 25 : 52 :23)R-125 and R-32 will be purchased directly from market and fill in MTF (Main Tank Farm). R-134A will be manufactured within SRF and will store in MTF. Then we will make a blend ofR-125, R-134A and R-32 in specific ratio. After approval from quality it will be sent for filling.15. R-410A PLANT (R-125: R-32 = 50:50)R-125 and R-32 will be purchased directly from market and fill in MTF (Main Tank Farm).Then we will make a blend of R-125 and R-32 in specific ratio. After approval from quality itwill be sent for filling.16. Blend of R-152A and R-134AR-152A will be purchased directly from market and fill in MTF (Main Tank Farm). R-134Awill be manufactured within SRF and will store in MTF. Then we will make a blend of R-152Aand R-134A in specific ratio. After approval from quality it will be sent for filling.

ANNEXURE - 2

12

Blend of R-142B and R-22R-142B will be purchased directly from market and fill in MTF (Main TankFarm).R- 22 will be manufactured within SRF and will be stored in MTF.Then we will make a blend of R-142B and R-22 in specific ratio.After approval from quality it will be sent for filling.17. Blend of R-134A and DME (Dimethyl Ether)Dimethyl ether will be purchased directly from market and store in MTF (Main Tank Farm).R-134A will be manufactured within SRF and will store in MTF. Then we will make a blend ofR-134A and DME in specific ratio. After approval from quality it will be sent for filling.18. R-407A PLANT (R-125: R-134A: R-32 = 40:40:20)R-125 and R-32 will be purchased directly from market and store in MTF (Main Tank Farm).R-134A will be manufactured within SRF and will store in MTF. Then we will make a blend ofR-125, R-134A and R-32 in specific ratio. After approval from quality it will be sent for filling.19. R-407F PLANT (R-125: R-134A: R-32 = 30:40:30)R-125 and R-32 will be purchased directly from market and store in MTF (Main Tank Farm).R-134A will be manufactured within SRF and will store in MTF. Then we will make a blend ofR-125, R-134A and R-32 in specific ratio. After approval from quality it will be sent for filling.20. R-417A PLANT (R-125: R-134A: R-600 = 46.6 : 50 : 3.4)R-125 and R-600A will be purchased directly from market and store in MTF (Main TankFarm). R-134A will be manufactured within SRF and will store in MTF. Then we will make ablend of R-125, R-600A and R-134A in specific ratio. After approval from quality it will besent for filling.21. R-417B PLANT (R-125: R-134A: R-600 = 79 : 18.25 : 2.75)R-125 and R-600A will be purchased directly from market and store in MTF (Main TankFarm). R-134A will be manufactured within SRF and will store in MTF. Then we will make ablend of R-125, R-600A and R-134A in specific ratio. After approval from quality it will besent for filling.22. R-421A PLANT (R-125: R-134A =58: 42)R-125 will be purchased directly from market and store in MTF (Main Tank Farm). R-134Awill be manufactured within SRF and will store in MTF. Then we will make a blend of R-125and R-134A in specific ratio. After approval from quality it will be sent for filling.

ANNEXURE - 2

13

23. R-421B PLANT (R-125: R-134A =85: 15)R-125 will be purchased directly from market and store in MTF (Main Tank Farm). R-134Awill be manufactured within SRF and will store in MTF. Then we will make a blend of R-125and R-134A in specific ratio. After approval from quality it will be sent for filling.24. R-422A PLANT (R-125: R-134A: R-600A = 85.1:11.5: 3.4R-125 and R-600A will be purchased directly from market and store in MTF (Main TankFarm). R-134A will be manufactured within SRF and will store in MTF. Then we will make ablend of R-125, R-600A and R-134A in specific ratio. After approval from quality it will besent for filling.25. R-422B PLANT (R-125: R-134A: R-600A = 55:42: 3)R-125 and R-600A will be purchased directly from market and store in MTF (Main TankFarm). R-134A will be manufactured within SRF and will store in MTF. Then we will make ablend of R-125, R-600A and R-134A in specific ratio. After approval from quality it will besent for filling.26. R-422C PLANT (R-125: R-134A: R-600A = 82:15: 3)R-125 and R-600A will be purchased directly from market and store in MTF (Main TankFarm). R-134A will be manufactured within SRF and will store in MTF. Then we will make ablend of R-125, R-600A and R-134A in specific ratio. After approval from quality it will besent for filling.27. R-422D PLANT (R-125: R-134A: R-600A = 65.1:31.5: 3.4)R-125 and R-600A will be purchased directly from market and store in MTF (Main TankFarm). R-134A will be manufactured within SRF and will store in MTF. Then we will make ablend of R-125, R-600A and R-134A in specific ratio.After approval from quality it will besent for filling.28. R-424A PLANT (R-125: R-134A: R-600A: R-600: R-601A = 50 : 47 : 0.9: 1 : 0.6)R-125, R-600, R-601A and R-600A will be purchased directly from market and store in MTF(Main Tank Farm). R-134A will be manufactured within SRF and will store in MTF. Then wewill make a blend of R-125, R-600A, R-601A, R-600 and R-134A in specific ratio. Afterapproval from quality it will be sent for filling.29. R-427A PLANT (R-125: R-134A: R-32: R-143A = 25 : 50 :15 :10)R-125, R-32 and R-143A will be purchased directly from market and store in MTF (MainTank Farm). Then we will make a blend of R-125, R-32 and R-143A in specific ratio. Afterapproval from quality it will be sent for filling.

ANNEXURE - 2

14

30. R-428A PLANT (R-125: R-143A: R-600A: R-290 = 77.5:20:1.9:0.6)R-125, R-290, R-143A and R-600A will be purchased directly from market and store in MTF(Main Tank farm). Then we will make a blend of R-125, R-600A, R-290 and R-143A in specificratio. After approval from quality it will be sent for filling.31. R-434A PLANT (R-125: R-143A: R-134A: R-600A = 63.2:18:16:2.8)R-125, R-143A and R-600A will be purchased directly from market and store in MTF (MainTank Farm). R-134A will be manufactured within SRF and will store in MTF. Then we willmake a blend of R-125, R-600A, R-134A and R-143A in specific ratio. After approval fromquality it will be sent for filling.32. R-438A PLANT (R-125: R-32: R-134A: R-600 = 45:8.5:44.2:2.3)R-125, R-32 and R-600 will be purchased directly from market and store in MTF (Main TankFarm). R-134A will be manufactured within SRF and will store in MTF. Then we will make ablend of R-125, R-600, R-32 and R-134A in specific ratio. After approval from quality it willbe sent for filling.33. R-507A PLANT (R-125: R-134A = 50:50)R-125 will be purchased directly from market and store in MTF (Main Tank Farm). R-134Awill be manufactured within SRF and will store in MTF. Then we will make a blend of R-125,R-134A in specific ratio. After approval from quality it will be sent for filling.

HFC 134A PLANTHFC-134APLANTProduct R134a is manufactured by the following stepwise process:Feed Section Reactor section Crude Distillation WashSection Product Distillation ITF (Intermediate tank farm)MTF (Main tank Farm)1. Feed Section:Trichloroethylene & Anhydrous Hydrofluoric acid Pumped from the respective storagevessels to plant reactors.2. Reactor Section:Trichloroethylene & Anhydrous Hydrofluoric acid reacts in a gas phase to produce R133a.Then R133a reacts with AHF & produce Hydrochloric acid & R134a.3. Crude Distillation:In this section Hydrochloric acid is removed from reactor outlet crude mixture & R134a isremoved in a crude form. From this Section AHF & R133a is recycled back to reactors by

ANNEXURE - 2

15

different columns.4. Wash Section:Crude R134a gas is scrubbed in water as a result dilute hydrofluoric acid get separated asbyproduct, then by sulfuric wash it leads to dry acidity free crude gas which is thencompressed to liquid form.5. Product Distillation:Pure R134a is recovered in this operation and distilled R133a is recycled back to crudedistillation.6. ITF & MTF:Product R134a is then stored in ITF (Intermediate tank farm) for Quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.

Water

1. TFA

HCl

Water 33% HCl

2. TFAA

3. MCDFA

Reactor

Crude TFAADistillation

ReactorDistillation

TFAAStorage

MCDFAStorage

ReactorDistillation

CDFAStorage

RM2storage

RM1storage

Reactor CrudeCDFAA

Distillation

Reactor

DistillationETFA

Storage

ReactorNeutralization

Distillation

Filtration

ChlorinationReactor

FluorinationReactor Hydrolysis

Reactor Extraction

CDFAAStorage

RM1storage

RM2storage

RM1storage

RM1storage

RM2storage

RM2storage

RM3storage

RM1storage

PFBAStorage

RM2Storage

RM1Storage

ChlorineStorage H2SO4

Storage

RM1Storage

DistillationPFB

Storage

RM2Storage

RM1storage

RM2storage

ETFAAStorage

Reactor

CrudeDistillation

Hydrolysis

RM2storage

RM1storage

Absorbtion

TFAStorage

TFADistillation

ReactionRM1

RM 2

Extraction Distillation

Sulfolane

Sodium

Sodium MetaBisulfite

BPFB Storage

ReactionRM1

RM2


Ether

PFP Storage

ReactionRM1

RM2

Distillation PBFB Storage

ReductionRM1

Water

Hydrolysis Esterification Reduction Distillation TFBAl Storage

RM2

Sulfuric Acid Alcohol

ReactionRM1

RM2

Neutralization Drying DFA Storage

Sodium hydroxide

ReactionRM 1

RM 2

Separation EDFA Storage

Potassiumhydroxide

ReactionRM 1

RM 2

Filtration Distillation EDFAA Storage

ReactionRM 1

RM 2

DistillationAmino Crotonate

Storage

1. Reaction-I2. Filteration-I3. Distillation-I

RM1

RM2

1. Reaction-II2. Filteration-II3. Distillation-II

1. Reaction-III2. Filteration-III3. Distillation-III

ReactionRM1

RM 2

SeparationTrifluoroacetone

Storage

1. Reaction-IV2. Filteration-IV3. Distillation-IV

Trifluorophenyl Aceticacid Storage

RM 4

RM 3RM 5

RM 6

1.Morpholine2. Sulphur3. p-Toluene sulphnicacid4. NaOH5. HCl

ReactionRM 1

RM 3

RM 2

Reaction SF4 StorageDistillation

ReactionRM 1

RM 4

RM 2

Filteration DistillationReaction

RM 3

DFMSc Storage

Water Chlorine

Step IReactionRM 1

RM 2

Distillation Step IIIReaction

Step IIReaction Filteration

Conc.H2SO4 Conc. HNO3 MeOHH2

Distillation Storage

Step IReaction

RM 1

RM

Step IIReaction

Step IIIReaction DFBD Storage

HBr H2O2HF DCM

Distillation Distillation

Step IReaction

RM 1

RM

Step IIReaction

Step IIIReaction Distillation

Br2 FeHF


Step IVReaction

N-Butylithuim Dry Ice

Step VReaction

Methanol H2SO4

Distillation Distillation DFBDMeStorage

Step IReaction

RM 1

RM 2

Step IIIReaction Distillation Step IV

Reaction

HF

Step IIReaction Filteration Filteration Washing

Hexane Water

Distillation Distillation Synthon1Storage

Copper

Cao

NH3Chlorine HF

ReactionRM 1

RM 2

Filteration Washing FilterationDistillation Distillation Purification Filteration Distillation HFPOTStorage

MTBE Ammonia

Multipurpose plant

4. CDFA

Water

5. CDFAA

Reactor


ReactorDistillation

TFAAStorage

MCDFAStorage

ReactorDistillation

CDFAStorage

RM2storage

RM1storage

Reactor CrudeCDFAA

Distillation

Reactor

DistillationETFA

Storage


Distillation

Filtration

ChlorinationReactor


Reactor Extraction

CDFAAStorage

RM1storage

RM2storage

RM1storage

RM1storage

RM2storage

RM2storage

RM3storage

RM1storage

PFBAStorage

RM2Storage

RM1Storage


Storage

RM1Storage

DistillationPFB

Storage

RM2Storage

RM1storage

RM2storage

ETFAAStorage

Reactor

CrudeDistillation

Hydrolysis

RM2storage

RM1storage

Absorbtion

TFAStorage

TFADistillation

ReactionRM1

RM 2


Sulfolane

Sodium


BPFB Storage

ReactionRM1

RM2


Ether

PFP Storage

ReactionRM1

RM2


ReductionRM1

Water


RM2


ReactionRM1

RM2


Sodium hydroxide

ReactionRM 1

RM 2


Potassiumhydroxide

ReactionRM 1

RM 2


ReactionRM 1

RM 2


Storage


RM1

RM2



ReactionRM1

RM 2


Storage



RM 4

RM 3RM 5

RM 6


ReactionRM 1

RM 3

RM 2


ReactionRM 1

RM 4

RM 2


RM 3

DFMSc Storage

Water Chlorine

Step IReactionRM 1

RM 2





Step IReaction

RM 1

RM

Step IIReaction


HBr H2O2HF DCM


Step IReaction

RM 1

RM

Step IIReaction


Br2 FeHF


Step IVReaction


Step VReaction

Methanol H2SO4


Step IReaction

RM 1

RM 2


Reaction

HF


Hexane Water


Copper

Cao

NH3Chlorine HF

ReactionRM 1

RM 2


MTBE Ammonia

Multipurpose plant

6. ETFA

7. ETFAAHCl

Crude ETFAA

Reactor


ReactorDistillation

TFAAStorage

MCDFAStorage

ReactorDistillation

CDFAStorage

RM2storage

RM1storage

Reactor CrudeCDFAA

Distillation

Reactor

DistillationETFA

Storage


Distillation

Filtration

ChlorinationReactor


Reactor Extraction

CDFAAStorage

RM1storage

RM2storage

RM1storage

RM1storage

RM2storage

RM2storage

RM3storage

RM1storage

PFBAStorage

RM2Storage

RM1Storage


Storage

RM1Storage

DistillationPFB

Storage

RM2Storage

RM1storage

RM2storage

ETFAAStorage

Reactor

CrudeDistillation

Hydrolysis

RM2storage

RM1storage

Absorbtion

TFAStorage

TFADistillation

ReactionRM1

RM 2


Sulfolane

Sodium


BPFB Storage

ReactionRM1

RM2


Ether

PFP Storage

ReactionRM1

RM2


ReductionRM1

Water


RM2


ReactionRM1

RM2


Sodium hydroxide

ReactionRM 1

RM 2


Potassiumhydroxide

ReactionRM 1

RM 2


ReactionRM 1

RM 2


Storage


RM1

RM2



ReactionRM1

RM 2


Storage



RM 4

RM 3RM 5

RM 6


ReactionRM 1

RM 3

RM 2


ReactionRM 1

RM 4

RM 2


RM 3

DFMSc Storage

Water Chlorine

Step IReactionRM 1

RM 2





Step IReaction

RM 1

RM

Step IIReaction


HBr H2O2HF DCM


Step IReaction

RM 1

RM

Step IIReaction


Br2 FeHF


Step IVReaction


Step VReaction

Methanol H2SO4


Step IReaction

RM 1

RM 2


Reaction

HF


Hexane Water


Copper

Cao

NH3Chlorine HF

ReactionRM 1

RM 2


MTBE Ammonia

Multipurpose plant

8. PFBA

9. PFB

H2O

Reactor


ReactorDistillation

TFAAStorage

MCDFAStorage

ReactorDistillation

CDFAStorage

RM2storage

RM1storage

Reactor CrudeCDFAA

Distillation

Reactor

DistillationETFA

Storage

Reactor Neutralization

Filtration

ChlorinationReactor


Reactor Extraction

CDFAAStorage

RM1storage

RM2storage

RM1storage

RM1storage

RM2storage

RM2storage

RM3storage

RM1storage

PFBAStorage

RM2Storage

RM1Storage


Storage

RM1Storage

Distillation

PFB Storage

RM2Storage

RM1storage

Reactor

CrudeDistillation

Hydrolysis

RM2storage

RM1storage

Absorbtion

TFAStorage

TFADistillation

ReactionRM1

RM 2


Sulfolane

BPFB Storage

ReactionRM1

RM2


Ether

PFP Storage

ReactionRM1

RM2


ReductionRM1

Water


RM2


ReactionRM1

RM2


Sodium hydroxide

ReactionRM 1

RM 2


Potassiumhydroxide

ReactionRM 1

RM 2


ReactionRM 1

RM 2


Storage


RM1

RM2



ReactionRM1

RM 2


Storage



RM 4

RM 3RM 5

RM 6


ReactionRM 1

RM 3

RM 2


ReactionRM 1

RM 4

RM 2


RM 3

DFMSc Storage

Water Chlorine

Step IReactionRM 1

RM 2





Step IReaction

RM 1

RM 2

Step IIReaction


HBr H2O2HF DCM


Step IReaction

RM 1

RM

Step IIReaction


Br2 FeHF


Step IVReaction


Step VReaction

Methanol H2SO4


Step IReaction

RM 1

RM 2


Reaction

HF


Hexane Water


Copper

Cao

NH3Chlorine HF

ReactionRM 1

RM 2


MTBE Ammonia

Multipurpose plant

10.BPFB

11.PFP

12.PBFB

Reactor


ReactorDistillation

TFAAStorage

MCDFAStorage

ReactorDistillation

CDFAStorage

RM2storage

RM1storage

Reactor CrudeCDFAA

Distillation

Reactor

DistillationETFA

Storage


Distillation

Filtration

ChlorinationReactor


Reactor Extraction

CDFAAStorage

RM1storage

RM2storage

RM1storage

RM1storage

RM2storage

RM2storage

RM3storage

RM1storage

PFBAStorage

RM2Storage

RM1Storage


Storage

RM1Storage

Distillation

PFB Storage

RM2Storage

RM1storage

RM2storage

ETFAAStorage

Reactor

CrudeDistillation

Hydrolysis

RM2storage

RM1storage

Absorbtion

TFAStorageTFA

ReactionRM1

RM 2


Sulfolane

Sodium

Sodium Meta

BPFB Storage

ReactionRM1

RM2


Ether

PFP Storage

ReactionRM1

RM2


ReductionRM1

Water


RM2


ReactionRM1

RM2


Sodium hydroxide

ReactionRM 1

RM 2


Potassium

ReactionRM 1

RM 2


ReactionRM 1

RM 2


Storage


RM1

RM2



ReactionRM1

RM 2


Storage



RM 4

RM 3RM 5

RM 6


ReactionRM 1

RM 3

RM 2


ReactionRM 1

RM 4

RM 2


RM 3

DFMSc Storage

Water Chlorine

Step IReactionRM 1

RM 2





Step IReaction

RM 1

RM 2

Step IIReaction


HBr H2O2HF DCM


Step IReaction

RM 1

RM 2

Step IIReaction


Br2 FeHF

Distillation DistillationStep IV

Reaction


Step VReaction

Methanol H2SO4


Step IReaction

RM 1

RM 2


Reaction

HF


Hexane Water


Copper

Cao

NH3Chlorine HF

ReactionRM 1

RM 2


MTBE Ammonia

Multipurpose plant

15.EDFA

13.TFBAl

14.DFA

Reactor


ReactorDistillation

TFAAStorage

MCDFAStorage

ReactorDistillation

CDFAStorage

RM2storage

RM1storage

Reactor CrudeCDFAA

Distillation

Reactor

DistillationETFA

Storage


Distillation

Filtration

ChlorinationReactor


Reactor Extraction

CDFAAStorage

RM1storage

RM2storage

RM1storage

RM1storage

RM2storage

RM2storage

RM3storage

RM1storage

PFBAStorage

RM2Storage

RM1Storage


Storage

RM1Storage

DistillationPFB

Storage

RM2Storage

RM1storage

RM2storage

ETFAAStorage

Reactor

CrudeDistillation

Hydrolysis

RM2storage

RM1storage

Absorbtion

TFAStorage

TFADistillation

ReactionRM1

RM 2


Sulfolane

Sodium

Sodium Meta

BPFB Storage

ReactionRM1

RM2


Ether

PFP Storage

ReactionRM1

RM2


ReductionRM1

Water

Hydrolysis Esterification Reduction

DistillationTFBAl StorageRM2


ReactionRM1

RM2


Sodium hydroxide

ReactionRM 1

RM 2


Potassiumhydroxide

ReactionRM 1

RM 2


ReactionRM 1

RM 2


Storage


RM1

RM2



ReactionRM1

RM 2


Storage



RM 4

RM 3RM 5

RM 6


ReactionRM 1

RM 3

RM 2


ReactionRM 1

RM 4

RM 2


RM 3

DFMSc Storage

Water Chlorine

Step IReactionRM 1

RM 2





Step IReaction

RM 1

RM 2

Step IIReaction


HBr H2O2HF DCM


Step IReaction

RM 1

RM

Step IIReaction


Br2 FeHF


Step IVReaction


Step VReaction

Methanol H2SO4


Step IReaction

RM 1

RM 2

Step IIIReaction

Distillation Step IVReaction

HF


Hexane Water


Copper

Cao

NH3Chlorine HF

ReactionRM 1

RM 2


MTBE Ammonia

Multipurpose plant

17. Amino Crotonate

16.EDFAA

18. Trifluorophenyl Acetic Acid

Reactor


ReactorDistillation

TFAAStorage

MCDFAStorage

ReactorDistillation

CDFAStorage

RM2storage

RM1storage

Reactor CrudeCDFAA

Distillation

Reactor

DistillationETFA

Storage


Distillation

Filtration

ChlorinationReactor


Reactor Extraction

CDFAAStorage

RM1storage

RM2storage

RM1storage

RM1storage

RM2storage

RM2storage

RM3storage

RM1storage

PFBAStorage

RM2Storage

RM1Storage


Storage

RM1Storage

DistillationPFB

Storage

RM2Storage

RM1storage

RM2storage

ETFAAStorage

Reactor

CrudeDistillation

Hydrolysis

RM2storage

RM1storage

Absorbtion

TFAStorage

TFADistillation

ReactionRM1

RM 2


Sulfolane

Sodium

Sodium Meta

BPFB Storage

ReactionRM1

RM2


Ether

PFP Storage

ReactionRM1

RM2


ReductionRM1

Water




ReactionRM1

RM2


Sodium hydroxide

ReactionRM 1

RM 2


Potassiumhydroxide

ReactionRM 1

RM 2


ReactionRM 1

RM 2


Storage


RM1

RM2



ReactionRM1

RM 2


Storage



RM 4

RM 3RM 5

RM 6


ReactionRM 1

RM 3

RM 2


ReactionRM 1

RM 4

RM 2


RM 3

DFMSc Storage

Water Chlorine

Step IReactionRM 1

RM 2





Step IReaction

RM 1

RM 2

Step IIReaction


HBr H2O2HF DCM


Step IReaction

RM 1

RM

Step IIReaction


Br2 FeHF


Step IVReaction


Step VReaction

Methanol H2SO4


Step IReaction

RM 1

RM 2

Step IIIReaction


HF


Hexane Water


Copper

Cao

NH3Chlorine HF

ReactionRM 1

RM 2


MTBE Ammonia

Multipurpose plant

20. SF4

19.Trifluoroacetone

Reactor


ReactorDistillation

TFAAStorage

MCDFAStorage

ReactorDistillation

CDFAStorage

RM2storage

RM1storage

Reactor CrudeCDFAA

Distillation

Reactor

DistillationETFA

Storage


Distillation

Filtration

ChlorinationReactor


Reactor Extraction

CDFAAStorage

RM1storage

RM2storage

RM1storage

RM1storage

RM2storage

RM2storage

RM3storage

RM1storage

PFBAStorage

RM2Storage

RM1Storage


Storage

RM1Storage

DistillationPFB

Storage

RM2Storage

RM1storage

RM2storage

ETFAAStorage

Reactor

CrudeDistillation

Hydrolysis

RM2storage

RM1storage

Absorbtion

TFAStorage

TFADistillation

ReactionRM1

RM 2


Sulfolane

Sodium

Sodium Meta

BPFB Storage

ReactionRM1

RM2


Ether

PFP Storage

ReactionRM1

RM2


ReductionRM1

Water




ReactionRM1

RM2


Sodium hydroxide

ReactionRM 1

RM 2


Potassiumhydroxide

ReactionRM 1

RM 2


ReactionRM 1

RM 2


Storage


RM1

RM2



ReactionRM1

RM 2


Storage



RM 4

RM 3RM 5

RM 6


ReactionRM 1

RM 3

RM 2


ReactionRM 1

RM 4

RM 2


RM 3

DFMSc Storage

Water Chlorine

Step IReactionRM 1

RM 2





Step IReaction

RM 1

RM 2

Step IIReaction


HBr H2O2HF DCM


Step IReaction

RM 1

RM

Step IIReaction


Br2 FeHF


Step IVReaction


Step VReaction

Methanol H2SO4


Step IReaction

RM 1

RM 2

Step IIIReaction


HF


Hexane Water


Copper

Cao

NH3Chlorine HF

ReactionRM 1

RM 2


MTBE Ammonia

Multipurpose plant

21. DFMSC

22. ABTF

Reactor


ReactorDistillation

TFAAStorage

MCDFAStorage

ReactorDistillation

CDFAStorage

RM2storage

RM1storage

Reactor CrudeCDFAA

Distillation

Reactor

DistillationETFA

Storage


Distillation

Filtration

ChlorinationReactor


Reactor Extraction

CDFAAStorage

RM1storage

RM2storage

RM1storage

RM1storage

RM2storage

RM2storage

RM3storage

RM1storage

PFBAStorage

RM2Storage

RM1Storage


Storage

RM1Storage

DistillationPFB

Storage

RM2Storage

RM1storage

RM2storage

ETFAAStorage

Reactor

CrudeDistillation

Hydrolysis

RM2storage

RM1storage

Absorbtion

TFAStorage

TFADistillation

ReactionRM1

RM 2


Sulfolane

Sodium

Sodium Meta

BPFB Storage

ReactionRM1

RM2


Ether

PFP Storage

ReactionRM1

RM2


ReductionRM1

Water




ReactionRM1

RM2


Sodium hydroxide

ReactionRM 1

RM 2


Potassiumhydroxide

ReactionRM 1

RM 2


ReactionRM 1

RM 2


Storage


RM1

RM2



ReactionRM1

RM 2


Storage



RM 4

RM 3RM 5

RM 6


ReactionRM 1

RM 3

RM 2


ReactionRM 1

RM 4

RM 2


RM 3DFMSc Storage

Water Chlorine

Step IReactionRM 1

RM 2


Step IIReaction


DistillationStorage

Step IReaction

RM 1

RM 2

Step IIReaction


HBr H2O2HF DCM


Step IReaction

RM 1

RM

Step IIReaction


Br2 FeHF


Step IVReaction


Step VReaction

Methanol H2SO4


Step IReaction

RM 1

RM 2

Step IIIReaction


HF


Hexane Water


Copper

Cao

NH3Chlorine HF

ReactionRM 1

RM 2


MTBE Ammonia

Filteration

Multipurpose plant

23.

SYNTHON1

24. HFPOT

Step IReaction

RM 1

RM 2

Step IIIReaction

DistillationStep IV

Reaction

HF


Hexane Water


Copper

Cao

NH3Chlorine HF

MTBE Ammonia

25. DFBD

26. DFBD-Me

Step IReaction

RM 1

RM 2

Step IIReaction

Step IIIReaction

DFBD Storage

HBr H2O2HF DCM


Step IReaction

RM 1

RM

Step IIReaction

Step IIIReaction

Distillation

Br2 FeHF


Step IVReaction

N-

Butylithuim Dry Ice

Step VReaction

Methanol H2SO4

Distillation Distillation DFBDMe Storage

ReactionRM 1

RM 2

Filteration Washing FilterationDistillation Distillation Purification Filteration Distillation HFPOT Storage

Multipurpose plant

1 R-600A (IsoButane)

2 R-600 (N-Butane)

LPG Storage

Tank

De-

Ethanizer

Column

De-

Propanizer

Column

De-

Isobutanizer

Column

Intermediate

Storage Tank

Main Storage

Tank

LPG Storage

Tank

De-

Ethanizer

Column

De-

Propanizer

Column

De-

Isobutanizer

Column

Intermediate

Storage Tank

Main Storage

Tank

Filling Station

Filling Station

LPG Storage

Tank

De-

Ethanizer

Column

De-

Propanizer

Column

De-

Isobutanizer

Column

Intermediate

Storage Tank

Main Storage

Tank

LPG Storage

Tank

De-

Ethanizer

Column

De-

Propanizer

Column

De-

Isobutanizer

Column

Intermediate

Storage Tank

Main Storage

Tank

Filling Station

Filling Station

3 R-290 (N-Propane)

4 R-133A (Chloro Tri Fluoro Ethane)

LPG Storage

Tank

De-

Ethanizer

Column

De-

Propanizer

Column

Intermediate

Storage Tank

Main Storage

Tank

Tri Chloro

Ethylene

Storage Tank

Anhydrous

Hydrofluoric

Acid Storage

Tank

Reaction

Section

Crude

Distillation

Wash

Section

Product

Distillation

Intermediate

Storage Tank

Main Storage

Tank

Filling Station

Filling Station

LPG Storage

Tank

De-

Ethanizer

Column

De-

Propanizer

Column

Intermediate

Storage Tank

Main Storage

Tank

Tri Chloro

Ethylene

Storage Tank

Anhydrous

Hydrofluoric

Acid Storage

Tank

Reaction

Section

Crude

Distillation

Wash

Section

Product

Distillation

Intermediate

Storage Tank

Main Storage

Tank

Filling Station

Filling Station

Refrigerant blends plant1

5 R-21 (Di Chloro Fluoro Methane)

6 TCE (Tri Chloro Ethylene)

Tri Chloro

Methane

Storage Tank

Anhydrous

Hydrofluoric

Acid Storage

Tank

Reaction

Section

Wash

Section

Product

Distillation

Intermediate

Storage Tank

Main Storage

Tank

Tri Chloro

Ethylene

Filling Station

Tri Chloro

Methane

Storage Tank

Anhydrous

Hydrofluoric

Acid Storage

Tank

Reaction

Section

Wash

Section

Product

Distillation

Intermediate

Storage Tank

Main Storage

Tank

Tri Chloro

Ethylene

Filling Station

7 R-23 (Tri Fluoro Methane)

Ethylene

Storage Tank

Anhydrous

Hydrofluoric

Acid Storage

Tank

Reaction

Section

Wash

Section

Decantat

ion

Product

Distillation

Intermediate

Storage Tank

Main Storage

Tank

Tri Chloro

Methane

Storage Tank

Anhydrous

Hydrofluoric

Acid Storage

Tank

Reaction

Section

Wash

Section

Product

Distillation

Intermediate

Storage Tank

Main Storage

Tank

Filling Station

Filling Station

Ethylene

Storage Tank

Anhydrous

Hydrofluoric

Acid Storage

Tank

Reaction

Section

Wash

Section

Decantat

ion

Product

Distillation

Intermediate

Storage Tank

Main Storage

Tank

Tri Chloro

Methane

Storage Tank

Anhydrous

Hydrofluoric

Acid Storage

Tank

Reaction

Section

Wash

Section

Product

Distillation

Intermediate

Storage Tank

Main Storage

Tank

Filling Station

Filling Station


8 R-227 (HeptaFluoro Ethane)

9 R-125 (Tri Fluoro Methane)

Main Storage

Tank

Filling Station

Crude Hepta

Fluoro Ethane

Storage Tank

Product

Distillation

Intermediate

Storage Tank

Main Storage

Tank Filling Station

Main Storage

Tank

Filling Station

Crude Hepta

Fluoro Ethane

Storage Tank

Product

Distillation

Intermediate

Storage Tank

Main Storage


10 R-143 (Tri Fluoro Ethane)

11 R-152 (Di Fluoro Ethane)

Main Storage

Tank

Filling Station

Main Storage

Tank

Filling Station

Main Storage

Tank

Filling Station

Main Storage

Tank

Filling Station


12 R-142B (Chloro Di Fluoro Ethane)

13 R-404A

Main Storage

Tank

Filling Station

R-125 Storage

Tank

R-134A

Storage Tank

Blender Intermediate

Stotage tank

Dryer Main Storage


Main Storage

Tank

Filling Station

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage


14 R-407C

R-143A

Storage Tank

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage


R-32 Storage

Tank

R-143A

Storage Tank

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage


R-32 Storage

Tank


15 R-410A

16 Blend of R-152A and R-134A

R-125 Storage

Tank

R-32 Storage

Tank


Stotage tank

Dryer Main Storage


R-152A

Storage Tank

R-125 Storage

Tank

R-32 Storage

Tank


Stotage tank

Dryer Main Storage


R-152A

Storage Tank

17 Blend of R-142B and R-22

R-134A

Storage Tank


Stotage tank

Dryer Main Storage


R-142B

Storage Tank

R-22 Storage

Tank


Stotage tank

Dryer Main Storage


R-134A

Storage Tank


Stotage tank

Dryer Main Storage


R-142B

Storage Tank

R-22 Storage

Tank


Stotage tank

Dryer Main Storage



18 Blend of R-134A and DME (DiMethyl Ether)

19 R-407A

R-142B

Storage Tank

R-22 Storage

Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-142B

Storage Tank

R-22 Storage

Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

20 R-407F

R-32 Storage

Tank

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-32 Storage

Tank

R-32 Storage

Tank

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-32 Storage

Tank


21 R-417A

22 R-417B

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-600 Storage

Tank

R-125 Storage

Tank

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-600 Storage

Tank

R-125 Storage

Tank

23 R-421A

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-600 Storage

Tank

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-600 Storage

Tank

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station


24 R-421B

25 R-422A

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

26 R-422B

Storage Tank

R-600A

Storage Tank

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-600A

Storage Tank

Storage Tank

R-600A

Storage Tank

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-600A

Storage Tank


27 R-422C

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage


R-600A

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage


R-600A

Storage Tank

28 R-422D

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage


R-600A

Storage Tank

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage


R-600A

Storage Tank


29 R-424A

R-125

Storage Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-600 Storage

Tank

R-600A

Storage Tank

R-125

Storage Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-600 Storage

Tank

R-600A

Storage Tank

30 R-427A

R-601A

Storage Tank

R-125

Storage Tank

R-134 A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-32 Storage

Tank

R-143A

Storage Tank

R-601A

Storage Tank

R-125

Storage Tank

R-134 A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-32 Storage

Tank

R-143A

Storage Tank


31 R-428A

R-125 Storage

Tank

R-600A

Storage Tank


Stotage tankDryer Main Storage


Propane

Storage Tank

R-143A

Storage Tank

R-125 Storage

Tank

R-600A

Storage Tank




Propane

Storage Tank

R-143A

Storage Tank

32 R-434A

R-125 Storage

Tank

R-600A

Storage Tank




R-134A

Storage Tank

R-143A

Storage Tank

R-125 Storage

Tank

R-600A

Storage Tank




R-134A

Storage Tank

R-143A

Storage Tank


33 R-438A

R-125 Storage

Tank

R-600 Storage

Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-134A

Storage Tank

R-125 Storage

Tank

R-600 Storage

Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-134A

Storage Tank

34 R-507A

R-32 Storage

Tank

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station

R-32 Storage

Tank

R-125 Storage

Tank

R-134A

Storage Tank


Stotage tank

Dryer Main Storage

Tank

Filling Station


R-134A (1,1,1,2-Tetrafluoro Ethane)

RM 1

RM2 StorageTank

ReactionSection

CrudeDistillation

WashSection

ProductDistillation

IntermediateStorage Tank

Main StorageTank

Filling Station

R-32 (Di Fluoro Methane)

RM2 StorageTank

ReactionSection

CrudeDistillation

WashSection

ProductDistillation


Main StorageTank

Filling Station

RM 1

RM 2 Storage

ReactionSection

CrudeDistillation

WashSection

ProductDistillation


Main StorageTank

Filling Station

HFC 134a1

Methyl Chloride (C1)

CMS Plant C1IntermediateStorage Tank

C1 MainStorage Tank

Filling StationCMS Plant C1IntermediateStorage Tank

C1 MainStorage Tank

Filling Station

Chloromethane plant1

Annexure - 4

1

Raw Material Requirement, Source & Transportation

1. Multipurpose plant (Fluorospeciality plant)

S. No Name Existing

Storage (MT)

Proposed

(MT)

Total after

expansion

(MT)

Source of Raw Material Mode of

Transportation Mode of Storage

1. Trichloro acetyl

Chloride 60 30 90

Tml Industries Ltd & Hari Orgochem Pvt. Ltd.

Baroda, Gujarat By Road Tank/Drums

2. Anhydrous Hydrofluoric

Acid 3 1.5 4.5 In House

By Pipeline within

plant premises Tank

3. Methanol 12 6 18 B.K. Sales Corporation By Road Common Storage With

CMS Plant

4. Ethanol 16 8 24 DCM Shriram Industries Ltd. Unit - Daurala

Sugar Works, Daurala, UP By Road Tank/Barrels

5. Sulfuric Acid 8 4 12

Oriental Carbo & Chemicals Ltd. Dharuhera,

Gurgaon; Sunny Trading Co. Chittorgarh,

Udaipur, Rajasthan; The Jayshree Chemicals &

Fertilizers, Pataudi, Gurgaon

By Road Tank

6 Benzonitrile 3 1.5 4.5

Hebei Fulong Import & Export Co. Ltd, China;

Zhejiang Tongxiang Foreign Trade (Group)C

Ltd. China

By Ship & By Road Drums

7 Chlorine 1 0.5 2

Aditya Birla Chemicals India Ltd. Palamu,

Jharkhand; Grasim Industries Ltd. Nagda;

Kanoria Chemicals & Industries Ltd.

Renukoot; Lords Chloro Alkali Ltd. Alwar;

Shriram Vinyl & Chemicals Industries, Kota;

Shriram Alkali & Chemicals Ltd. Jhagadia;

Punjab Alkalies & CHemcials Ltd., Nangal Siel

Chemicals Complex, Rajpura

Nirma Limited, Vill. Kalatalav, Distt. Bhav

Nagar, Gujarat

By Road Tonners

8 Potassium Fluoride 100 50 150 Tanfac Ltd, Cuddulore,Tamil Nadu By Road Stored in Plastic

Annexure - 4

2

Packaging

9 Sodium Hydroxide(48

%) 27 13.5 40.5 Rajendra Trading Co./ SVCI Kota

By Pipeline within

plant premises

Common Storage With

CMS Plant

10 Potassium Hydroxide 35 17.5 52.5 Hukum Chand,Delhi By Road Stored in plastic

Packaging

11 Ferric Chloride 0.1 0.05 0.15 Tital Biotec Bhiwadi By Road Stored in Plastic

Packaging

12 Toulene 1.5 0.75 2.25 Hemco Organics,new Delhi & R.P.G

Enterprises, Delhi By Road Stored In Barrels

13 Bromine 5 2.5 7.5

Solaris Chemtech Industries Ltd, Tata

Chemicals Ltd & Agrocel Industries Ltd.

Kutch, Gujarat

By Road Stored In Bottles

14 Sodium Sulphate 0.1 0.05 0.15 Hukum Chand,Delhi By Road Stored In Bags

15 Zinc Dust/Powder 10 5 15 Transpek-Silox Limited, Gujarat By Road Drums

16 Sodium Borohydride 3 1.5 4.5 Hasmukhray & Co., Mumbai By Road Stored in Plastic

Packaging

17 Monoglyme 5 2.5 7.5 Hasmukhray & Co., Mumbai By Road Stored In Barrels

18 Methylene Chloride 1 0.5 1.5 In House By Road Stored In Barrels

19 Sodium Carbonate 3 1.5 4.5 J Brothers & Hukum Chand, Delhi By Road Stored in Plastic

Packaging

20 Sodium Bi Sulphite 0.5 0.25 0.75 Sheel Scientific, Rajasthan By Road Stored in Plastic

Packaging

21 Acetic Acid 0.5 0.25 0.75 Hukum Chand, Delhi By Road Stored In Carboys

22 Potassium Dihydrogen

Phosphate 3 1.5 4.5

Hukum Chand, Delhi

Oscar Chemicals, Ahmedabad By Road

Stored in Plastic

Packaging

23 Diethyl Ether

0 0 Sheel Scientific, Rajasthan By Road Stored in Plastic

Packaging

24 Sodium meta bi Sulphite 3 1.5 4.5 Hukum Chand,Delhi By Road Stored in Plastic

Packaging

25 Tetra Fluoro Ethyl

Methyl Ether 13 6.5 19.5 HFL Hyderabad By Road Tank

Annexure - 4

3

26 Ethyl Acetate 20 10 30 Sheel Scientific, Rajasthan By Road Tank

27 Anhydrous Hydrochloric

Acid - - - In House

By Pipeline within

plant premises

Tapping From the CMS

Plant Distillation

Column

28 Cyclo hexane 10 5 15

Sachin Chemical Mumbai

Hasmukhray & Co Mumbai

International Solvents & Chemicals Company,

Mumbai

By Road Stored In Barrels

29 Anhydrous Ammonia 1 0.5 1.5 Aggarwal Gas Agency, Bhiwadi, Rajasthan By Road Stored In Cylinders

30 Liquid Nitrogen 35 17.5 52.5 INOX AP, Dharuheda, Haryana By Pipeline within

plant premises

Common Storage With

CMS Plant/HFC-134a

plant

31 Fluorine 5 2.5 7.5 Solvay, South Korea By Road Drum/Cylinder/Tanks

32 Sulphur 0 15 15 - By Road Drum/Cylinder/Tanks

33 Benzyl Chloride 0 15 15 - By Road Drum/Cylinder/Tanks

34 Thiourea 0 20 20 - By Road Drum/Cylinder/Tanks

35 Benzotrichloride 0 30 30 - By Road Drum/Cylinder/Tanks

36 Nitric Acid 0 12 12 GNFC / Oswal Chemicals By Road Drum/Cylinder/Tanks

37 Raney Nickel 0 0.5 0.5 - By Road Drum/Cylinder/Tanks

38 Copper 0 2 2 - By Road Drum/Cylinder/Tanks

39 Copper Acetate 0 10 10 Vipul Life Sciences By Road Drum/Cylinder/Tanks

40 Hexane 0 15 15 - By Road Drum/Cylinder/Tanks

41 p-Chlorotoluene 0 30 30 - By Road Drum/Cylinder/Tanks

42 Dimethylformamide 0 20 20 - By Road Drum/Cylinder/Tanks

43 Hexafluoropropylene

(HFP) 0 25 25 Hangzhou Ruilipu Trade CO. Ltd. China By Road Drum/Cylinder/Tanks

44 Potassium Carbonate 0 1 1 Universal Chemicals /Manish Chemicals /

Oswal Chemicals/ R R Innovative By Road Drum/Cylinder/Tanks

45 Methyl tert-butyl ether

(MTBE) 0 12 12 SAVLA CHEMICALS / VINATI ORGANICS By Road Drum/Cylinder/Tanks

Annexure - 4

4

46 O-Toluidine 0 15 15 Oscar Chemicals (Deepak Nitrite) By Road Drum/Cylinder/Tanks

47 Sodium dithionite

(Na2S2O4) 0 6 6 Tranpsek - Silox By Road Drum/Cylinder/Tanks

48 Tetrabutyl ammonium

hydrogen sulfate 0 5 5 - By Road Drum/Cylinder/Tanks

49 1,3 Benzodioxide 0 25 25 MDB Chemicals By Road Drum/Cylinder/Tanks

50 Phosphorus

pentachloride 0 10 10 Sandhya Industries By Road Drum/Cylinder/Tanks

51 Hydrogen Bromide 0 20 20 - By Road Drum/Cylinder/Tanks

52 Hydrogen Peroxide

(50%) 0 5 5

Guljag Industries / Manish Chemicals and

others By Road Drum/Cylinder/Tanks

53 Acetonitrile 0 10 10 Krishna Solvchem (Alkyl Amines) and others By Road Drum/Cylinder/Tanks

54 Chloro sulfuric acid 0 50 50 - By Road Drum/Cylinder/Tanks

55 Dichloro acetophenone 0 20 20 - By Road Drum/Cylinder/Tanks

56 Morpholine 0 12 12 - By Road Drum/Cylinder/Tanks

57 p-Toluenesulfonic acid 0 1 1 - By Road Drum/Cylinder/Tanks

58 Sulfolane 0 10 10 Cadila Pharma (Casil Industries) By Road Drum/Cylinder/Tanks

59 Dimethyl Amine 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

60

Boron

tribromide/chloride/flu

oride

0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

61 Boron trifluoride

etherate 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

62 sec/n-butyl nitrite 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

63

Ortho/meta/para-

fluoro/chloro/bromo/io

do-aniline


64 Boric acid (H3BO3) 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

65 Sodium nitrite 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

66 ortho/meta/para-

difluoro/dichloro/dibro0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

Annexure - 4

5

mo/diiodo-benzene

67

Tetraalkyl ammonium

bromide/chloride/fluori

de/iodide


68 Sodium sulphite 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

69

Aluminium

chloride/fluoride/bromi

de/iodide


70 butanol/popanol 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

71 Ethylene dichloride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

72 benzenediol 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

73 N-Methyl pyrrolidone 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

74 Lithium aluminium

hydride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

75 n-/sec-butyl lithium 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

76 Tetrahydrofuran 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

77 N-Bromo/chloro-

succinimide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

78 Formaldehyde 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

79 Sodium/potassium -

iodide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

80 Iodine 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

81 Alkyl iodide/chloride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

82 Methyl-2-chloroacetate 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

83 Sodium/Potassiummetho

xide/ ethoxide/butoxide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

84 Dioxane 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

85 Dimethyl oxalate 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

86 Mono/Diethylene glycol 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

87 Acetone 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

Annexure - 4

6

88 Acrylonitrile 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

89 Acetaldehyde 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

90 Acetophenone 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

91 Sodium hydride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

92 Propionotrile 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

93

Ethyl

Chloride/bromide/iodid

e


94 Methyl pyridine 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

95 Xylene 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

96 Tri alkyl chloro silane 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

97 Ammonium chloride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

98 Ammonium hydroxide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

99 Acetaldoxime 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

100 Monomethyl hydrazine 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

101 Hydrazine hydrate 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

102 Hydroxyl amine 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

103 Copper sulphate 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

104 Magnesium

chloride/bromide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

105 Ethyl vinyl ether 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

106 Dimethyl sulphoxide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

107 Thionyl chloride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

108 Methane sulphonyl

chloride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

109 Pyridine 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

110 Anisole 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

111 Sodium Thiosulphate 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

112 Isopyopyl bromide/

chloride/iodide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

Annexure - 4

7

113 Hydroxyl toluene 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

114 Benzene 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

115 Triethyl/methyl amine 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

116 Carbon disulphide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

117 Chloro/bromo/fluoro/

iodo toluene 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

118 Trimethyl acetyl

chloride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

119 Acetic anhydride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

120 Dimethyl acetamide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

121 Potassium

Permanganate 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

122 Phosphorus

oxy/tri/penta-chloride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

123 Ethyl acetoacetate 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

124 Aniline 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

125 Methyl trioctyl

ammonium chloride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

126 Butylated hydroxyl

toluene 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

127 Sodium bisulphite 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

128 Benzotrifluoride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

129

Amino benzo-

trifluoride/chloride/bro

mide/iodide


130 Chloro/bromo/iodo/flu

oro-benzene 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks

Annexure - 4

8

2. Chloromethane plant

S. No. Raw Material Requirement (TPD) Source of Raw Material Transportation

1. Chlorine 170 Aditya Birla Chemicals India Ltd., Palamu, Jharkhand; Grasim

Industries Ltd., Nagda; Kanoria Chemicals & Industries Ltd., Renukoot;

Lords Chloro Alkali Ltd., Alwar; Shriram Vinyl & Chemicals Industries,

Kota

Shriram Alkali & Chemicals Ltd., Jhagadia; Punjab Alkalies & Chemicals

Ltd., Nangal; Siel Chemical Complex, Rajpura; Nirma Limited, Vill.

Kalatalav, Distt. Bhav Nagar

By Road

2. Sodium Hydroxide 7.5 Rajendra Trading Co. / Svci Kota By Road

3. Sulphuric Acid 10.0 Oriental Carbon & Chemicals Ltd., Dharuhera, Gurgaon; Sunny Trading

Co., Chittorgarh, Udaipur, Rajasthan; The Jayshree Chemicals &

Fertilizers, Pataudi, Gurgaon

By Road

4. Methanol 51.0 B.K. Sales Corporation By Road

5. Liq. Nitrogen 0.5 Air Liquide North India Ltd., Panipat & Roorkee By Road

3. New Generation Refrigerants & Refrigerant Blends Plant

S. No. Raw Material Requirement (TPA) Source Mode of transportation

1 MDC 21275.1 In House

2 HF 503.1 In House

3 LPG 13586.1 IOCL/BPCL/HPCL refineries By road

4 Chloroform (C3) 3870.9 In House

5 EDC 900.9 China By Sea

6 Cl2 600.6 Aditya Birla/Shriram Alkali/As Existing By Road

7 R-22 376.2 In House

8 DME 1250.7 China By Sea

9 R-134A 9520.5 In House

10 R-601A 9.9 China By Sea

Annexure - 4

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11 R-32 (Difluoromethane) 5260.2 China/In house By Sea

12 R-600A (Isobutane) 234.3 China By Sea

13 R-600 (n-Butane) 85.8 China By Sea

14 R-290 (Propane) 9.9 China By Sea

15 TCE (Trichloroethylene) 600.6 In House

16 R-125 (Pentafluoroethane) 17087.4 China By Sea

17 R143A (Trifluoroethane) 1643.4 China By Sea

18 R-152A (Difluoroethane) 999.9 China By Sea

19 R-142B (Chlorodifluoro Ethane) 376.2 China By Sea

20 R-227 Technical grade 1999.8 China By Sea

4. HFC134a Plant

S. No. Raw Material Requirement

Source TPD TPA

1 TCE 52 17160 In House

2 AHF 36 12000 In House

3 C2 62 20460 In House

At Village & P.O. Jhiwana, Tehsil Tijara, District...

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