Arctic Marine Biogeochemistry · 2012. 3. 7. · Extreme Thermochemistry . Millero et al., several...
Transcript of Arctic Marine Biogeochemistry · 2012. 3. 7. · Extreme Thermochemistry . Millero et al., several...
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Arctic Marine Biogeochemistry
Los Alamos National Laboratory COSIM:
Climate Ocean Sea Ice Modeling
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LANL: Elliott, Maltrud, Hunke, Jeffery, Rowland LBL: Reagan, Moridis, Collins IARC: Deal, Jin LLNL: Cameron-Smith, Bhattacharyya, Bergmann PNNL: Liu, Ghan, Easter, Rasch ORNL: Hoffman, Erickson, Branstetter OTHER: NPS, universities and international…
DOE: SciDAC, Fossil Energy, EPSCOR (IARC), Cloud-Cryosphere, SFA core, SciDAC redux Other: New Mexico IAS, IARC/JAMSTEC Cooperative, SOLAS, the Chevron Alliance
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OUTLINE STRUCTURE –From 50o northward via Pacific Arctic OKHOTSK –A methane hub MARGINS –CICE and coupling POP EAST SIBERIA –More CH4, brine bgc/transport CENTRAL –Resource limitations, biogenics to clouds
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CH4 flare rise: Determined by surfactants
Arctic Plumes
Obzhirov 04 Methane Flares 100-300 meters
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Integration: Sea of Okhotsk
Depth contours, coloring suggesting areas of potential destabilization (reds) vs. low-flux areas (blues)
GRL 2010 ICGH 2011 JGR 2011
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IARC ice geocycling: JGR, DSR, AGU monograph
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Chl in, DMS from bottom: JGR 2009, GBC 2010, Oceanography 2011, JGR 2012
log10Chl (l), mg/m2 log10DMS (r), nM May 1992 (upper) |June 1992 (lower)
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Through sea ice and CICE…
JGR 2011, SOLAS 2011
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Marion, 2002
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∆Ice
Unknown?
N ?
Cu ?
O2, Fe ?
GRL 2010 (Schematic)
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Leck, 2002
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SUMMARY STRUCTURE –From 50o northward via Pacific Arctic OKHOTSK –A methane hub MARGINS –CICE and coupling POP EAST SIBERIA –More CH4, brine bgc/transport CENTRAL –Resource limitations, biogenics to clouds
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IARC Coupled Sulfur Cycle: Subdued effects in POP/CICE Points to algal loss vs. retention?
In Prep
S-ice OFF S-ice ON
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EXTRAS
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JGR 2011
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Ocean-Ice in NSF/DOE CESM
* *
*LANL
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Systems Modeling means BGC
BIOGENICS JGR, GBC, GRL, other
ICE GEOCYCLING JGR, DSR, SOLAS, other
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JGR 2011
CH4 sources: Upward seabed flow Sinking particles CH4 sinks: Empirical log linear a) Surface (nM), b) Saturation ratio, c) 150 meters (nM)
Global Cycle
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320 meter fluxes 8 one-cell sites Log linear τ 30 years, coarse POP
300 100 10 0
CH4 (millimole/m2 and /m3)
LBL, mole/m2y
JGR 2010
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O2, CO2 and Plume Expansion 300 200 100 0
0 -0.02 -0.04 -0.1 -0.2
millimole/m3
O2
∆pH
5000 1000 100 0
CH4, millimole/m2
5000 1000 100 0
300 meters, 30 years JGR 2011
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CD sends these today, DMS left ice algal source off, right on (bluer images on left side of page are concentration, right yellow are column) This is coupled open water and ice biogeochemistry, pretty rare Real DMS increases in surface waters as early as April Nanomolar large areas, Bering extreme at close to ten nanomolar But nanomolar scale activity many locations Less pronounced than in my stand alone CICE simulations and we are now sorting out the potential reasons One is that POP is not capturing the then freshened bottom layer below and left over from the pack as it melts The other is that we are using different release parameterizations for the algae from the ice, quicker in the coupled version In stand alone I took a hard look at bottom layer chl data beyond the Pacific Arctic and decided I had to include some extension See Lavoie et al. 2005 for a closely related approach and some references… if growth and melting are slow the algae can maintain position L05 section 3.2.3 is good on this and I encourage Clara to ask MBJ to test in the coupled model
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MBJ (caption)
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Leck, 2002
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Once and future DMS in CC&ESM: GRL 2011
y2000, nM
y2100, nM
∆nM
∆%
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Gases in Ice
Los Alamos National Laboratory The Climate Ocean and Sea Ice Model (COSIM) project
Computational and Theoretical Science Divisions
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LANL: S. Elliott, E. Hunke, N. Jeffery, M. Maltrud IARC: C. Deal, M. Jin LBL: M. Reagan, G. Moridis LLNL: P. Cameron Smith, D. Bergmann Others: B. Loose, J. Stefels, M. Levasseur
U.S. DOE SciDAC for Earth System Modeling, Plus Gas Hydrates and IMPACTS methane cycling
and around
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OUTLINE: Gases of the Ice Domain OPENING MONTAGE –volatiles on parade ECOLOGY first but MINERALOGY close behind Extreme THERMO and C BUDGETS coming fast ORGANOSULFUR in ice and surroundings METHANE BUBBLES below and to the pack OTHER compounds, issues
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Loose et al. 2011 Deboer et al. 2011 Light et al. 2002 Obzhirov et al. 2004 Shakhova et al. 2009
CO2, DMS, O2, CH4
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N, Si, Fe drive: nCO2 + nH2O = (CH2O)n + nO2 + ∆alkalinity Ca2
+ + CO32- = ikaite + ∆alkalinity
H2O.CO2 = H+ + HCO3-
HCO3- = H+ + CO3
2-
Vertical and ice-air transfer All hypersaline: Pitzer eqs.
All roads lead to ecodynamics, but… IARC/LANL, JGR & DSR
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Extreme Thermochemistry
Millero et al., several ? No, CRREL as usual Pitzer equations -just Debye-Huckel on steroids
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2HCO3- + Ca2+
CaCO3 + CO2
CaCO3 + CO2
2HCO3- + Ca2+
CO2
CO2
In spring, CaCO3 trapped within sea ice dissolves. This process consumes CO2.
Budget of winter and
spring processes is a net sink of CO2. It depends on: ratio of CaCO3 trapped
vs CO2 expelled (?) quantity of CO2 which
pass below the pycnocline during the autumn-winter (?)
fall/winter spring
GAS COMPOSITION IN SEA ICE A potential abiotic CaCO3 Carbon pump
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Rysgaard et al., 2007, Delille et al., in prep.
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DMS via CICE: beneath, residual
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O2, photo-radical chemistry -Biological stress Nitrogen redox: -Nitrification, N2O (Which incidentally… (Points to rest of N system… (Reduced gases too, NH3/NH4+)
Major Elements
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Bubble rise for DOE Impacts and Gas Hydrates
{Swap in latest runs, methane trapped below ice…}
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Bubbles and Futures
JF
AJ
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…and (ever) more Organic surface chemistry Transfer from leads Halogenates, I2
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By these criteria, rank order for high latitude cycles: -Ice chlorophyll (surface darkening) -DMS -Organics tweak sea-air transfer -CH4 -Organics tweak aerosol -Seeding tweaks sea-air transfer -Open, brine, skeletal C cycles -Aerosol/ice iron cycle -Ice nitrogen (NH3/4
+, N2O) -O2 and radical photochemistry
The envelope please…
Note: Order 102 characters –IPCC does same job in 106
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By these criteria, rank order for high latitude cycles: -Ice chlorophyll (surface darkening) -DMS -Organics tweak sea-air transfer -CH4 -Organics tweak aerosol -Seeding tweaks sea-air transfer -Open, brine, skeletal C cycles -Aerosol/ice iron cycle -Ice nitrogen (NH3/4
+, N2O) -O2 and radical photochemistry
The envelope please…
Note: Order 102 characters –IPCC does same job in 106
CO2, O2
All
CO2
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Loose et al. 2011 Deboer et al. 2011 Light et al. 2002 Obzhirov et al. 2004 Shakhova et al. 2009
CO2, DMS, O2, CH4