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MATERIAL SAFETY DATA SHEET In compliance to European parliament and Committee (EC) no. 1907/2006 (REACH)

and the Committee directive (EU) no. 453/2010 Acetic acid

Publication date: 14. 7. 2015 of 12

Revision date:

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PARTICLE, s.r.o. PARTICLE, s.r.o.

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY UNDERTAKING

1.1. Product identifiers

Product name: Acetic acid

CAS Number: 64-19-7

EC Number: 200-580-7

Index Number: 607-002-00-6

Other names: Ethanoic acid, Methanecarboxylic acid, Hydrogen acetate, Vinegar (when dilute)

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses: Chemical for laboratory use. Substances production.

1.3. Details of the supplier of the safety data sheet

Distributor: PARTICLE, s.r.o.

Address: Ulica mieru 2531/4

984 01 Lučenec, SLOVAKIA

ID: IČO 47858541

Telephone: +421 917 976 258

E-mail: [email protected]

1.4. Emergency Telephone number

National Toxicological Information centre University Hospital Bratislava Department of Occupational Medicine and Toxicology Limbová 5, 833 05 Bratislava, SLOVAKIA Telephone: +421 2 5465 2307 Cellphone: +421 911 166 066 Fax: +421 2 5477 4605 E-mail: [email protected]

mailto:info@particle

mailto:[email protected]




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SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Flammable liquid (Category 3), H226 Skin corrosion (Category 1A), H314

For the full text of the H-phrases mentioned in this Section, see Section 16.

Classification according to EU Directives 67/ 548/EEC or 1999/45/EC R10 C; R35

For the full text of the R-phrases mentioned in this Section, see Section 16.

2.2. Label elements

Labelling according to Regulation (EC) No 1272/2008

Hazard pictograms

Signal word Danger

Hazard statements

H226 Flammable liquid and vapour.

H314 Causes severe skin burns and eye damage.

Precautionary statements

Prevention

P280 Water protective gloves/protective clothing/eye protection/face protection.

Response

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P307 + P310 IF EXPOSED: Immediately call a POISON CENTER or doctor/physician.

2.3. Other hazards

Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII.




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SECTION 3: COMPOSITION/INFORMATION OF INGREDIENTS

3.1. Substances

Formula: CH3COOH C2H402 Molar mass: 60.05 g/mol

Hazardous components according to Regulation (EC) No 1272/2008 Acetic acid CAS No. 64-19-7

EC No. 200-580-7

Index No. 607-002-00-6

Classification Flammable liquid, Category 3, H226

Skin corrosion, Category 1A, H314 For the full text of the H-phrases mentioned in this Section, see Section 16.

Hazardous components according to Regulation (EC) No 1999/45/EC Acetic acid CAS No. 64-19-7

Classification R10

C, Corrosive, R35 For the full text of the R-phrases mentioned in this Section, see Section 16.

SECTION 4: FIRST AID MEASURES

4.1. Description of the first aid measures

In case of an accident of the health issue get immediate medical advice/attention. If medical advice is needed, have product container or label at hand.

First aider needs to protect himself.

After inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms of not breathing, give an artificial breathing. Get immediate medical advice/attention.

After skin contact

Remove contaminated clothing and shoes. Wash off with soap and plenty of water. If available swab with polyethylene glycol 400. Evaluate immediately to hospital. Get medical advice/attention.

After swallowing Do NOT induce vomiting (risk of perforation). Never give anything by mouth to an unconscious person. Rinse mouth with water (two glasses at most). Get medical advice/attention. Do not attempt to neutralise.




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After eye contact Rinse out with plenty of water for at least for 15 minutes. Immediately call in ophthalmologist.

4.2. Most important symptoms and effects, both acute and delayed

The material is extremely destructive to tissue mucosa and upper respiratory tract, eyes and skin. spasm, inflammation and edema of the larynx, spasm, inflammation and swelling of the bronchi, pneumonitis (a special kind of pneumonia), pulmonary edema, burning sensation, coughing, wheezing, laryngitis, shortness of breath, Headache, Nausea, Vomiting, Ingestion or inhalation of concentrated acetic acid causes damage of respiratory tract and gastrointestinal tract. Symptoms include: hematemesis (vomiting blood), bloody diarrhea, edema and / or perforation of the esophagus (Back protector) and the pylorus (concierge), pancreatitis (inflammation of the pancreas), hematuria (presence of blood in urine), anuria (lack of urine output), uremia (accumulation of nitrogenous waste substances in the blood), albuminuria, hemolysis, convulsions, bronchitis, pulmonary edema, pneumonia, heart attack, shock and death.

Identification of immediate medical attention and special treatment needed. Direct contact or interaction of vapors in high concentrations on the skin or eyes can cause: erythema (redness of the skin), blisters, tissue damage effects with slow healing, skin blackening, hyperkeratosis (excessive keratinization of the skin), cracks, damage to the cornea, opacification, iritis (inflammation iris), conjunctivitis (conjunctivitis), and possible blindness., the best of our knowledge, or chemical, physical, and toxicological properties have fully understood.

4.3. Identification of any immediate medical attention and special treatment needed

No information available.

SECTION 5: FIRE-FIGHTING MEASURES

5.1. Extinguishing media

Suitable extinguishing media Water, Carbon dioxide (CO2), Foam, Dry powder.

5.2. Special hazards arising from the substance or mixture

Sodium Oxide.

5.3. Precautions for fire-fighters

In necessary case of fire wear self-respiratory protection.

5.4. Other information

Product is not flammable in itself.




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SECTION 6: ACCTIDENTIAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Use protection for the respiratory tract. Avoid breathing vapors / mist / gas liquids. Provide adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe spaces. Beware of accumulation of vapors, which can reach explosive concentrations. Vapors can accumulate on the lower-lying areas.

6.2. Environmental precautions

When safe to do so prevent further leakage or spillage. Do not let product enter drains. Do not discharge into the environment

6.3. Methods and materials for containments and cleaning up

Stop leak material and vacuum it up Pick explosive in the design or sweep Wet and place in container for disposal according to local / national regulations (see section 13)

6.4. Reference to other sections

Indications about waste treatment see section 13.

SECTION 7: HANDLING AND STORAGE

7.1. Precious for safe handling

Avoid the production of dust and aerosols. Ensure efficient exhaust if the dust arises. Keep away from sources of ignition- no smoking. Perform a precautionary measure against static electricity.

7.2. Conditions for safe storage, including any incompabilities

Store in a cool place. Keep container tightly closed in a dry and well-ventilated place. Sensitive to moisture.

7.3. Specific end uses

No data available




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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Components CAS no. Value Threshold limits

Based

Acetic acid 64-19-7 Time Weight

Average

(TWA)

10 ppm

25 mg/m3 Directive Committee 91/322/EHS

assessment of indicatory limit values

NPEL 10 ppm

25 mg/m3 Highest acceptable exposure limits of

chemical factors for workplaces

8.2. Exposure controls

Engineering measures

Care of the health protection for industrial hygiene and health and safety. Wash your hands when taking a break or the work is finished wash your hands.

Individual protection measures

Respiratory protection

If the risk judgment breathing apparatus air cleaning proves satisfactory, use the multi-purpose respirator that protects the entire face (US) or cartridge respirator type ABEK (EN 14387) as a reserve for the control system. If the respirator is the sole source of protection use respirator that uses as a source of air and protects the entire face. Use breathing apparatus and devices which tested and approved as a suitable standard state organizations such as NIOSH (US) or CEN (EU).

Skin protection

Wear protective gloves. Gloves must be inspected prior to use. Use proper technique moulting gloves without touching the outer surface of the gloves to avoid skin contact with this product. After use, dispose of contaminated gloves in accordance with applicable laws and good laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of EU Directive 89/686 / EEC and derived from it to EN 374.

Body protection

Complete suit protecting against chemicals, Flame retardant antistatic protective clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Eye/face protection

Tightly fitting goggles. Face shield (minimum 20 cm) Just about hooked tools for eye protection tested and approved by the applicable national standards such as NIOSH (US) or EN 166 (EU).




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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance

Conditions Liquid

Colour Colourless

Odour Stinging

Board value of odour N/A

pH 2.4 at 60.05 g/l

Melting/setting temperature Melting point – 16.2 °C (lit.)

Boiling temperature 117 – 118 °C (lit.)

Flash temperature 40.0 °C (closed cup)

Surface tension 28.8 mN/m at temperature 10.0 °C

Vapour pressure 73.3 hPA at 50.0 °C

15.2 hPa at 20.0 °C

Upper / lower explosive limit

Upper explosive limit: 19,9 % (V)

Lower explosive limit: 4 % (V)

Viscosity N/A

Partition coefficient: n-octanol/water log Pow: -0.17

Ignition temperature 485.0 °C

Decomposition temperature N/A

Flammability (gas, solid) N/A

Solubility in water completely miscible

9.2. Other safety information

No data available.

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity

No data available-

10.2. Chemical stability

The product is chemically stable under standard ambient conditions (room temperature).




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10.3. Possibility of hazardous reactions

No data available.

10.4. Conditions to avoid

Heating, flames and sparks.

10.5. Incompatible materials

Protect against strong oxidants, soluble carbonates and phosphates, hydroxides, metals, peroxides, permanganates (e.g. potassium permanganate), amines, alcohols.

10.6. Hazardous decomposition products

Other decomposition product - No data available.

In the case of fire – see section 5.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Acute toxicity

LD50 oral – rat – 3.310 mg/kg

LC50 inhalation – mouse - 1h – 5620 ppm

Notes: Sense organs and special sense (smell, sight, hearing and taste): Eye: Irritation of the

conjunctiva. Sense organs and special sense (smell, sight, hearing and taste): Eye:

Other. Blood: Other changes.

LD50 dermal – rabbit – 1.112 mg/kg

Skin corrosion/irritation

No data available.

Serious eyes injury/irritation

Eye – rabbit: corrosive to the eyes

Respiratory irritation or skin sensitization

May cause sensitization on contact with skin.

Mutagenic effect to germ cells

No data available

Carcinogenic effects

IARC: No component of this product has not been identified by IARC at levels higher than or equal to 0.1 % as probable, possible or confirmed human carcinogen.

Mutagenic effects

No data available.




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Reproduction toxicity

No data available.

Toxicity for specific end point organ – single exposition

No data available.

Toxicity for specific end point organ – single exposition

No data available.

Aspired Hazard

No data available.

Potential health effects

AFTER INHALATION Toxic by inhalation. Material extremely damage tissue of the mucous membranes and of upper respiratory tract.

AFTER SWALLOWING Harmful if swallowed. Causes burns.

AFTER SKIN CONTACT Harmful in contact with skin. Cause skin irritation.

AFTER EYE CONTACT Causes eye burns.

Signs and symptoms of exposure

The material is extremely destructive to tissue mucosa and upper respiratory tract, eyes and skin. Spasm, inflammation and edema of the larynx, spasm, inflammation, and swelling of the bronchi, pneumonitis (a special type of inflammation of the lungs), lung edema, burning sensation, cough, shortness of breath, laryngitis, Shortness of breath, Headache, Nausea, Vomiting.

Ingestion or inhalation of concentrated acetic acid causes damage to the airways and digestive tract.

Symptoms include: hematemesis (vomiting blood), bloody diarrhea, edema and / or perforation of the esophagus (Back protector) and the pylorus (concierge), pancreatitis (inflammation of the pancreas), hematuria (presence of blood in urine), Uraemia (lack of urine output), uremia (accumulation of waste crude protein in the blood), albuminuria, haemolysis, convulsions, bronchitis, pulmonary edema, pneumonia, heart attack, shock and death.

Direct contact or interaction of vapors in high concentrations on the skin or eyes can cause: erythema (redness of the skin), blisters, tissue damage effects with slow healing, skin blackening, hyperkeratosis (excessive keratinization of the skin), cracks, damage to the cornea, opacification, iritis (inflammation iris), conjunctivitis (inflammation of the conjunctiva), and possible blindness.

The best of our knowledge or chemical, physical and toxicological properties have fully explored.




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Additional information

RTECS: VZ4725000

SECTION 12: ECOLOGICAL INFORMATION

12.1. Toxicity

Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 79 to 88 mg / l - 96 h LC50 - Lepomis macrochirus - 75 mg / l - 96 h Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 65 mg / l - 48 h

12.2. Persistence and biodegradability

Biodegradability Aerobic - Exposure time 30 days Result: 99% - Readily biodegradable. Note: It is expected that the biodegradable

12.3. Biocumulative potential

Partition coefficient: n-octanol/water – log Pow: -0.17 (lit.) Bioaccumulation is not expected.

12.4. Mobility in soil


12.5. Results of PBT and vPvB assessment

Substance does not meet the criteria for PBT od vPvB according to Regulation (EC) No 1907/2006, Annex XIII.

12.6. Other hazards or dangerous effects

Harmful to aquatic life. Additional environment information: No information available. BOD: 880 mg/g




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SECTION 13: DISPOSAL CONSIDERATION

Danger of contamination of the environment, follow your country legislation/regulation.

13.1. Waste treatment

Product

Burn in a chemical incinerator waste, which is equipped with an afterburner and scrubber. Care in igniting as this material is highly flammable. Irrecoverable surpluses and established company Offer solutions for waste disposal.

Contaminated packaging

Dispose of as unused product.

13.2. Legislation for the waste treatment

Follow your country legislation/regulation.

SECTION 14: TRANSPORT INFORMATION

14.1. UN-number

ADR/RID: 2789 IMDG:2789 IATA: 2789

14.2. UN proper shipping name

ADR/RID: Acetic acid, glacial IMDG: Acetic acid IATA: Acetic acid

14.3. Class/es of danger for the transport

ADR/RID: 8 (3) IMDG: 8 (3) IATA: 8 (3)

14.4. Packaging group

ADR/RID: II IMDG: II IATA: II

14.5. Environmental hazards

ADR/RID: No IMDG Marine pollutant: No IATA: no

14.6. Specific safety conditions for usage





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SECTION 15: REGULATORY INFORMATION

Safety data sheet complies with the Directive (EC) No 1907/2006 and the Committee directive (EU) no. 453/2010.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture


15.2. Chemical safety assessment


SECTION 16: OTHER INFORMATION

Full text of H-statements referred to under section 2 and 3

H226 Flammable liquid and vapour. H314 Causes severe skin burns and eye damage.

Full text of R-statements referred to under section 2

R10 Flammable. R35 Causes severe burns.

Statement

Safety data sheet contents data for the health and safety protection for the workers and environment. Data are in compliance up to date knowledge and experience and do comply with valid regulations and legislation. There cannot guaranty overall for the proper use or usage for the concrete application.

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