16 고무 업종 품질기술세미나 160629

2. 1. 2.

3. . 2 (1493~1496) , . , , ' , = coa () + ochu ( )

4. (rub) , Rubber() . '' () , gomme() gom() Vulcanization (1839) : Charles Goodyear (1906) : Oenslager () (1910) : (1924)

5. 5 ? 250 Kg ? 6 22 ? 50 Kg

6. Compound? Specific Physical Property Rubber Filler NR, SBR, BR, Butyl . . . Carbon Black, Silica, Clay . . . , Ozone . . . Process Oil, Activator . . . , . . . , . . . B/M, ,Roll ( 9~15 ) ( 200) 1. Component - Target ( , , . . . ) - ( Crack , . . . ) 2. ( , Tack . . . ) 3. Cost 4. . . . Compd

7. ; PHR (Per Hundred Rubber) - (Polymer) 100 Recipe * SBR1712 : 100 + A#2 Oil 37.5 100 Carbon Black 65 Oil 10 4 2.0 1.0 Total 183.0 phr SBR1712 * 137.5 Carbon Black 75 Oil 9 4 2.2 1.5 Total 229.2 phr 2 : Step Banbury Mixer ( A : B : Final )

8. ROLL MIXING MIXING SHEETING

9. 1. 1. 2. 3. 4.

10. Filler , , ,, , , , , , , M.V, , , Chemical ,

11. Filler , Chemical ,

12. , Rubber, Elastomer, Polymer (), (), Polymer() 10, , ( , ,) . (, Crosslinking, Curing) , . (C) (H)

13. , . (Backbone) (Vibrating) (Brown Motion) . Backbone , , . ?

14. polymer Tg () NR Isoprene Rubber -72 BR Butadiene Rubber -79 SBR Styrene-Butadiene Rubber -52 NBR( (20%) Acrylonitrile-Butadiene Rubber (Nitrile Rubber) -56 CR Chloroprene Rubber -40 IIR Isobutene-Isoprene Rubber (Butyl Rubber) -80 Vinyl-Methyl Silicone Rubber -118~-128 Chlorosulphonated Polyethylene Rubber -34

15. Dien : NR, SBR, BR -> . (Main Chain, , Backbone) , , ,

16. ASTM NR -40~60 ,,,,, ,, - SBR , -35~90 ,,, , BR NR -45~90 , ,, ,, CR ,,, -30~100 ,,, , NBR ,, -25~100 ,,,, top roll IIR ,, -40~120 , Curing bag ,,,, - EPDM ,, , -40~140 , CSM ,, -25~130 ,,, , ACM ANM , -10~160 FPM , -25~220 ,, , Q ,, ,, -90~200 ,, sealant,

17. 1) (kgf/) 2) (%) 3) 4) 5) (pphm) 6) 7) () : NR > NBR > CR > CPE > CSP > EVA > SR > SBR > EPDM. : NR > EPDM > SR > CSP > CPE > EVA > SBR > CR > NBR : SR > EPDM > CSP > CPE > EVA > CR > NBR > SBR > NR : SR > EPDM > CR > EVA > CSP > CPE > NBR > SBR > NR : EPDM > EVA > SR > CSP > CPE > CR > SBR > NBR > NR : NBR > CR > EVA > CSP > CPE > SR > SBR > EPDM > NR : EPDM > EVA > SR > CSP > SBR > NR > CPE > CR > NBR .

18. 88.23% 5.04% 4.10% 0.84% 1.74% , , . , , . Natrual Rubber CHCH2 CH CH2 n Natural Rubber (Poly-isoprene) CH3

19. , Sheet Block

20. RSS#3 (Ribbed Smoked Sheet #3) TSR (Technically Specified Rubber, ) Special Rubber [ Light Grade & CV (Constant MV) ] TSR-10 (Dirt 0.10 % ) TSR-20 (Dirt 0.16 % ) STR [ Standard Thai R. ] SMR [ Standard Malaysian R. ] SIR [ Standard Indonesia R. ] SCR [ Standard China R. ] SVR [ Standard Vietnam R. ]

21. Styrene Butadiene Rubber ( 80%), , Styrene 23.5% High Styrene Hot, Cold Rubber , Cold(5 ~ 10 ) 80% Grade IISRP( ) . . , , , . , Scorch NR, BR Blend SBR . Polymer . , Calender , , . Rubber , NR

22. SBR (Emulsion SBR ; E-SBR) . Solvent : Water (Radical ) . (MWD : 4 6), . . Microstructure Control (Random Copolymer) . E-SBR Grade . SBR (Solution SBR ; S-SBR) . Solvent : Hydrocarbon (Anionic ) . Vinyl Styrene Microstructure . . E-SBR Sharp(MWD:1.052.2) , 1000 1500 1600 1700 1800 Hot E-SBR Non-Oil (Dry) Extended Cold E-SBR Carbon Black Master Batch Non-Oil Extended Cold E-SBR Oil Extended Cold E-SBR Carbon Black Master Batch Oil Extended Cold E-SB

23. (number-average molecular weight): Mn Mn = / , (weight-average molecular weight): Mw ( x ) / .) MWD : : Mw/Mn :

24. High Cis Polybutadiene (Tg) -100 . High Cis Polybutadiene . Roll , NR SBR Blend Low Cis Polybutadiene High Cis BR Low Cis BR (BR) .

25. NR SBR , , . , Blending, , , Cold flow, Chipping Cutting Roll BR NR SBR Blending

26. Ethylene - Propylene - Diene Rubber Ethylene Propylene EPM Diene , , . , , , , , . . . bloom , .

27. , / / (Fillers) . 90~99% . Rubber Polymer . Polymer . Silane Coupling Agent

28. / ( Particle Size ) : , ( Structure ) : (H-bonding,Van der Waals bonding ) Structure Structure SAF Die Swell ISAF HAF FEF GPF SRF MT

29. . , . CB Grade ASTM No (nm) SAF (Super Abrasion Furnance) N110 N134 11~19 ISAF (Intermediate Super Abrasion Furnance) N220 N234 20~25 SAF HAF HAF (High Abrasion Furnance N326 N330 N339 N351 26~30 , Fast Extruding Furnance) N550 N582 40~48 SRF FEF , Modulus . SRF (Semi Reinforce Furnance N762 N774 61~100 ,

30. Compound Carbon Black Carbon black Particle size Smaller Higher Structure Loading Level-up Rubber properties Surface area Larger Incorporation time - Dispersion Uncured Mill-bagging - Rubber Mooney viscosity Scorch time Die-swell Hardness 300% Modulus Tensile strength Cured Elongation - Rubber Tear resistance Wear resistance Rebound Heat-build-up Hysteresis Increase Decrease Compromising Slightly increase

31. (Vulcanization) 3 . , . Effective Crosslink S 1 S 2 S 3 S X S yAcc. -- S z Mono- Di- Poly- Cyclic Sulfide Pendant Sulfide Rubber(diene polymer) Sulfur+ (Cross-link ) + ZnO+

32. Chain . 1839 C. Goodyear Polymer . , .

33. Polymer , Main Chain . . . Static Anti Oxidant Chemical AntiOzonant Wax Film . Dynamic Anti Oxidant AntiOzonant , Ozone Composition Heat Resistance Ozone Resistance Bloom Rate Volatility Persistance 77PD N,N'-bis(1,4-dimethylphenthyl-PPD IPPD N-phenyl-N-isopropyl-PPD 6PPD N-(1,3-dimethylbutyl-N'-phenyl-PPD W-100 Mixed Diaryl-PPD TMQ Poly(2,2,4-trimethyl-1,2-dihydroqunoline BLE Hihg temperature reaction product of acetone and diphenylamine

34. Rubber Rubber Rubber , Non-Vulcanizer Rubber , , , roller Processing Oil Plasticizers

35. NR SBR CR BR NBR EPT

36. () NO 6-1 F/P. ? ( ) , , (CMB,FMB ->//: 0.3%,:1.0%) - (F/P) - : 205, : 70% ( ) () (1/LOT) - : , - :

37. 1. 2. POP : / 1. LOT 2. 3. 4. 1. - : , , , (EVA, LDPE, ) - , , , SPC Bar Code . 2. Tag

38. 3. 1. Bar Code : SIGNAL

39. Polymer C/BLACK Filler C/B M/B OIL M/B ZnO M.V 40, 100 C/B Rust [] Item . [] Item .

40. / (2/1) NO Lot No (EX) 1 MGO 1 110405 20110405 Lot No 2 S 1 1104181 20110418 Lot No 3 P V I 1 80961B - Lot No 4 FAB 1 BPLA0318 - Lot No 5 ZNO () 1 - 6 D O P 1 U10307D3 20110307 Lot No 7 P # 6 1 2011.2.11 20110211 8 TP 95 1 0006527386 - Batch No 9 BIB 40P 1 - 10 3 C 1 2011,03,17 20110317 Production Date 11 K13(6C) 1 110228109 20110228 12 BLE N(65) 1 11011401 20110114 Lot No 13 M B 1 02508 - 14 MBPC 2246 1 20100427 20100427 Production Date 15 R D 1 11042109 20110421 Lot No 16 SP N 1 2011,04,24 20110424 Production Date 17 PAN 1 011402 - Lot No 18 TL PT 1 102102 - Lot No 19 AW-P 1 371041 - Lot No 20 TC 1 - 21 UL 160 1 5/4/2011 20110504 Date Produced 22 UL 200 1 8/9/2010 20100809 Date Produced 23 P WAX 1 - 24 FinaWax OK 1 205/11/10 - Batch No 25 P-Wax EP 1400 1 000B11 - Lot No 26 P # 1 1 2011.03.11 20110311 27 P 90 1 AD-5217 - Lot No 28 S1503 1 AD-0046 - Lot No 29 STR 5L 1 15/1796 - Lot No 30 B Z 1 110213 - 31 D M 1 11022001 20110220 Lot No 32 E Z 1 11022361 20110223 Batch No 33 M 1 11011601 20110116 Lot No

41. R R1 (SBR) R3 (EPDM) R6 C/B C C FILLER C SILICA C5 (caco3) C6 P P S POWDER S M MASTER BATCH M X X Y Y A A1 WAX A5 TACK T T CODE

42. () NO 6-2 F/P. ? , () ( ) - , , - : 6 - : 1

44. . () / . -. () , -. 2015 () ()

45. , ,,

46. MAIN SILO DAILY BIN MIXER WEIGHING SYSTEM ROLLER-DIE FEEDING SYSTEM BATCH OFF M/C

47. C/B Tank A Tank Mixer Roller Die Ext. TakeAway C/V TakeAway C/V Batch off M/C Wig-wag & C/V C/V Non-pro Mixer Line

48. Final Mixer Line

49. Mixer Construction Ram Hopper door Rotor Drop Door Latch Bed Hopper Chamber End Frame

50. Rotor ( ) Chamber Rotor Blade Clearance Rotor () Chamber Rotor Mixing Banbury Mixer Mixing

51. , , Band Bank Bank Band( ) Bank Roll ( ) () Bank Band Bank Band , Bank , Roll Roll , Open Roll Mixing

52. Mixer Mixer , Roll Mill Roll Band Mixing mixing Open : cooling Mixing Cycle . Tangential Type Rotor Chamber [80%] Rotor Rotor , , , . B/t Kneader Mixer . , . Intermeshing Type Rotor Rotor . Rotor . . .

53. ROLL 50~60 120

54. Banbury Mixer Open Roll - - Thermochemical Breakdown - Rotor Wall Mixing - Chamber Mixing (Internal Mixier) - Cycle Time (50~90sec) - (180kg ) - - Mixing - - Mechanical Breakdown - Cylindrical Roll - ( Cutting, Overlaping ) - Open System ( ) - Cycle Time ( ) - - . . Radical Filler network(Rubber Gel) .

55. Type 2W 4W(S) 4W 4WH 4WH-II 6WI Geometry G/Details L : 40~ 45 S : 40 ~ 45 L : 30 S : 30 L : 35 S : 30 Low Power Low Price .Thermal Advatage . Rapid and compact discharge . High Fill Factor . High Intake . High Energy Input .Large scale .High productivity .Flexibility High Productivity High Quality Higher productivity High quality Good dispersion Final + Remill Master Batch Master Batch Final + Master Final + Master Master batch L S M Mixer Rotor Type Tangential Type

56. (4Wing) (Full 4Wing) [ Tangential Type ] [ Intermeshing Type ] [ ] Rotor Geometry

57. Tandem-Principle Top Machine: Ram Type Mixer Tandem Mixer Dump: Twin Screw Extruder with Roller Die

58. Tandem Mixing Principle Conventional Multi-Step Process Tandem Principle

59. () NO 7-2 F/P. ? , ( -> 0.5%) (F/P) - : 205, : 70% ( ) (F/P) F/PROOF - - / () Lay Out : ( ) LOT ( )

60. 4. 4. 1. 2. / 3. (,) 4. () ; 5. Main Server DB 0.2kg 0.1kg 0.1kg 0.05kg 1. Main Server DB 0.001kg 0.001kg

61. / 1 2 3 4 5 6 7 8 9 10 11 NR50(07)-C-1 SVR-3L ZNO SUNNOC PVI FAB FEF(N550) MT-C 3C RD K13(6C) P-WAX(EP-1400) 1201510010024 (g) 40,000.00 3,200.00 400.00 120.00 300.00 6,400.00 9,200.00 800.00 400.00 400.00 400.00 R0115J010069 40,000.00 3,200.00 400.00 120.00 300.00 6,380.00 9,200.00 800.00 400.00 400.00 400.00 R0115J010070 40,000.00 3,199.00 400.00 120.00 300.00 6,360.00 9,200.00 800.00 400.00 400.00 400.00 R0115J010071 40,000.00 3,202.00 400.00 120.00 300.00 6,380.00 9,200.00 800.00 400.00 400.00 400.00 NR50(07)-C-1 SVR-3L ZNO SUNNOC PVI FAB FEF(N550) MT-C 3C RD K13(6C) P-WAX(EP-1400) 1201510020026 (g) 40,000.00 3,200.00 400.00 120.00 300.00 6,400.00 9,200.00 800.00 400.00 400.00 400.00 R0115J020063 40,000.00 3,200.00 400.00 120.00 300.00 6,400.00 9,200.00 800.00 400.00 400.00 400.00 R0115J020064 40,000.00 3,203.00 400.00 120.00 300.00 6,380.00 9,200.00 800.00 400.00 400.00 400.00 NR50(07)-C-1 SVR-3L ZNO SUNNOC PVI FAB FEF(N550) MT-C 3C RD K13(6C) P-WAX(EP-1400) 1201510030027 (g) 40,000.00 3,200.00 400.00 120.00 300.00 6,400.00 9,200.00 800.00 400.00 400.00 400.00 R0115J030060 40,000.00 3,201.00 400.00 120.00 300.00 6,420.00 9,200.00 800.00 400.00 400.00 400.00 R0115J030061 40,000.00 3,198.00 400.00 120.00 300.00 6,420.00 9,200.00 800.00 400.00 400.00 400.00 NR50(07)-C-1 SVR-3L ZNO SUNNOC PVI FAB FEF(N550) MT-C 3C RD K13(6C) P-WAX(EP-1400) 1201510050010 (g) 40,000.00 3,200.00 400.00 120.00 300.00 6,400.00 9,200.00 800.00 400.00 400.00 400.00 R0115J050024 40,000.00 3,199.00 400.00 120.00 300.00 6,420.00 9,200.00 800.00 400.00 400.00 400.00 R0115J050025 40,000.00 3,202.00 400.00 120.00 300.00 6,420.00 9,200.00 800.00 400.00 400.00 400.00 R0115J050026 40,000.00 3,201.00 400.00 120.00 300.00 6,420.00 9,200.00 800.00 400.00 400.00 400.00 / 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 EP40(04E)-2 KEP 960 EPDM(KEP210) ()MISTRON VAPOR FEF(N550) P#1 (P-1) P-WAX ZNO FAB BZ CZ(CBS(G)) TT NA-22 MIRAD-RG S CIR#90 CaCO3 PEG4000 , MB 1201510010001 (g) 15,525.00 12,650.00 13,800.00 345.00 11,500.00 1,150.00 1,150.00 230.00 368.00 115.00 138.00 115.00 345.00 92.00 460.00 2,300.00 230.00 115.00 R0115J010001 15,650.00 12,770.00 13,720.00 345.00 11,420.00 1,151.00 1,149.00 230.00 368.00 115.00 138.00 115.00 345.00 92.00 460.00 2,300.00 230.00 115.00 R0115J010002 15,640.00 12,720.00 13,740.00 345.00 11,420.00 1,151.00 1,151.00 230.00 368.00 115.00 138.00 115.00 345.00 92.00 460.00 2,300.00 230.00 115.00 EP40(04E)-2 KEP 960 EPDM(KEP210) ()MISTRON VAPOR FEF(N550) P#1 (P-1) P-WAX ZNO FAB BZ CZ(CBS(G)) TT NA-22 MIRAD-RG S CIR#90 CaCO3 PEG4000 , MB 1201510030017 (g) 15,525.00 12,650.00 13,800.00 345.00 11,500.00 1,150.00 1,150.00 230.00 368.00 115.00 138.00 115.00 345.00 92.00 460.00 2,300.00 230.00 115.00 R0115J030040 15,460.00 12,670.00 13,780.00 345.00 11,410.00 1,150.00 1,149.00 230.00 368.00 115.00 138.00 115.00 345.00 92.00 460.00 2,300.00 230.00 115.00 R0115J030041 15,410.00 12,720.00 13,780.00 345.00 11,410.00 1,151.00 1,150.00 230.00 368.00 115.00 138.00 115.00 345.00 92.00 460.00 2,300.00 230.00 115.00 EP40(04E)-2 KEP 960 EPDM(KEP210) ()MISTRON VAPOR FEF(N550) P#1 (P-1) P-WAX ZNO FAB BZ CZ(CBS(G)) TT NA-22 MIRAD-RG S CIR#90 CaCO3 PEG4000 , MB 1201510040002 (g) 15,525.00 12,650.00 13,800.00 345.00 11,500.00 1,150.00 1,150.00 230.00 368.00 115.00 138.00 115.00 345.00 92.00 460.00 2,300.00 230.00 115.00 R0115J040003 15,540.00 12,650.00 13,840.00 345.00 11,410.00 1,151.00 1,151.00 230.00 368.00 115.00 138.00 115.00 345.00 92.00 460.00 2,300.00 230.00 115.00 R0115J040004 15,550.00 12,660.00 13,860.00 345.00 11,410.00 1,151.00 1,150.00 230.00 368.00 115.00 138.00 115.00 345.00 92.00 460.00 2,300.00 230.00 115.00 EP40(04E)-2 KEP 960 EPDM(KEP210) ()MISTRON VAPOR FEF(N550) P#1 (P-1) P-WAX ZNO FAB BZ CZ(CBS(G)) TT NA-22 MIRAD-RG S CIR#90 CaCO3 PEG4000 , MB 1201510070020 (g) 15,525.00 12,650.00 13,800.00 345.00 11,500.00 1,150.00 1,150.00 230.00 368.00 115.00 138.00 115.00 345.00 92.00 460.00 2,300.00 230.00 115.00 R0115J070045 15,600.00 12,640.00 13,800.00 345.00 11,420.00 1,151.00 1,149.00 230.00 368.00 115.00 138.00 115.00 345.00 92.00 460.00 2,300.00 230.00 115.00 R0115J070046 15,600.00 12,640.00 13,780.00 345.00 11,410.00 1,150.00 1,149.00 230.00 368.00 115.00 138.00 115.00 345.00 92.00 460.00 2,300.00 230.00 115.00 EP40(04E)-2 KEP 960 EPDM(KEP210) ()MISTRON VAPOR FEF(N550) P#1 (P-1) P-WAX ZNO FAB BZ CZ(CBS(G)) TT NA-22 MIRAD-RG S CIR#90 CaCO3 PEG4000 , MB 1201510100018 (g) 15,525.00 12,650.00 13,800.00 345.00 11,500.00 1,150.00 1,150.00 230.00 368.00 115.00 138.00 115.00 345.00 92.00 460.00 2,300.00 230.00 115.00 R0115J100035 15,520.00 12,700.00 13,820.00 345.00 11,410.00 1,150.00 1,151.00 230.00 368.00 115.00 138.00 115.00 345.00 92.00 460.00 2,300.00 230.00 115.00 R0115J100036 15,520.00 12,710.00 13,820.00 345.00 11,420.00 1,149.00 1,149.00 230.00 368.00 115.00 138.00 115.00 345.00 92.00 460.00 2,300.00 230.00 115.00 NR50 POP DATA EP40 POP DATA : SPEC POP LOT

62. - - pop - check -

63. P.O.P DATA, FOOL PROOF SYSTEM

64. () Oil . , . , . : 1/( Batch ) . : Oil OIL CHECK SHEET 2015 8 8/1 8/2 8/3 8/4 8/5 8/6 8/7 8/8 8/9 8/10 8/11 8/12 8/13 8/14 8/15 8/16 8/17 8/18 8/19 8/20 8/21 8/22 8/23 8/24 8/25 8/26 8/27 8/28 8/29 8/30 8/31 DOP P-1 A2 TP95 : 0.2% : 0.2% : 0.2% : 0.2% OIL CHECK SHEET 2015 8 8/1 8/2 8/3 8/4 8/5 8/6 8/7 8/8 8/9 8/10 8/11 8/12 8/13 8/14 8/15 8/16 8/17 8/18 8/19 8/20 8/21 8/22 8/23 8/24 DOP P-1 A2 TP95 : 0.2% : 0.2% : 0.2% : 0.2%

66. , 1. -> . : : -> Breakdown[mastication], [Incorporation], [Distribution] [Dispersion], [Simple Mixing]

67. Mixing Procedure Subdivision 1000 m Incorporation , Rubber , 10 m Dispersion [Shear Stress] [Agglomerate] size , 0.1 m Distribution [Entropy] Simple Mixing Mastication ,

68. Power Profile 0: 1: Ram Down 2 : Mixing(Rubber) 3 : Filler + Chemicals 4 : Ram Down 5 : 4~5 BT(Black Incorporation) BIT 6 : Oil Injection Or Clean 7 : : , [Power level down] 1 : , / [Power level up] 2 : , /, [Power down] 3 : , [Power Plateau] Subdivision Incorporation Dispersion & Distribution Simple Mixing(Mastication)

69. Optimum Fill Factor Energy Input(ESP) Mixing Chart(BIT, Flow, Tq Amplitude) Heat Generation Rate(/sec) Mixing Sound Amplitude of Ram Movement(2~3cm) Step Viscosity Reduction Rate(From Non-Pro to FMB Mixing)

70. 1. Slip 2. Torque Amplitude 3. Ram Indicator (Optimum Movement 2~3cm ) Fill factor 1. Mixing Energy Input ( + + ) 2. Mixing Sequence E . Filler Energy Loss BIT(Carbon Incorporation Time)

71. Volume 69.35% B/M VOL: 255 Liter 1.1667 (W) PHR (d) V (w/d) SBR 35Kg NR SBR ZnO 70.0 30.0 60.0 5.0 3.0 1.0 3.0 0.93 0.92 1.82 5.60 0.92 1.21 1.00 75,27 32.61 32.97 0.89 3.26 0.83 3.00 81.67 35.00 70.00 5.83 3.50 1.67 3.50 172.0 1.1557 148.82 204.4 VOLUNE 2. Component = x PHR ) NR : 1.1667 X 70 = 81.67 Kg 3. VOL CMB 4. Mixing Volume = Total Wt(Kg) / Mixer Vol. / Density ) 204.4 / 255 /1.1557 =69.35% 1. ( Fill Factor ) Volume ) SBR BALE : 35Kg : 35/30 = 1.1667 PHR (Kg) ( 4 ) (Kg) phr [ Volume : ] 50 - 90% 75~100% 75~110% 60 - 80% 80~95% 80~100% Scorch 60~70% 75~85% 75~90 %

73. 1. Cheesy, Crumble Polymer 80% 2nd Peak . Slip . Oil Injection 1. Clean Stagnation Zone Mixing Surface 2. 2nd Peak ~ 2nd Peak 85% 2 Clean Slope Ram Sweep

74. System Lot , Over Mixing, Over Heating . Step . Next Step . Drop Door Open . Rotor, Chamber, Drop Door . Mixing .

75. Mixing Parameter Control Method Classical : High Viscosity Polymer(NR Block), :High Grade Fillers,High Loading(70part ) Fill factor : Slip,Torque, interaction(Rheology), Dispersion, , Ram Press(Hydrodynamic Stress) : , , TCU Set Value : , Mixing Effect, -(Classical,U/S/D) - Main Factor - Fill factor, Ram ,Pressure - Rotor Speed, TCU Set Mixing Sequence - - Mixing - Oil or Clean - Dump Out - Emergency

76. 1) Conventional Mixing Upside down Mixing 2) Mixing Method Muti Step Process 1 Stage Mixing Process Mixing Process Method Mixing Conventional , ,CB, CHMICAL , . BATCH . Upside-Down CB Oil High Loading Fill factor . OR Mixing Method

77. Principle (sec) (Kwh) Wu = k P[t]dt/Vb High Oil Loading Compd (Mixer Slip ) ( Hardening Compd Slope ) (Kw) Torque Viscosity () , , ,

78. () NO 7-1 ? - (), / - , ( )

79. ROLL , 80 , , ,

80. 15G07-115G07-2 15G07-3 15J05-115J05-215J05-3 15J01-1 15J01-2 15J01-3 B/T (POP : POWER CHART )

81. () NO 8-1 F/P. (,,Chamber,) , - , Chamber, ROLL (F/P) , , - - 8-2 (,) , - , , ,

82. 6. 7. / 1. / 2. MIXING Main Server DB , , , . 3. 4. 5. (,,,...) 6. 1. 2. 3. 4. / :BLEND , , 5. C/VC/V 2O/R 6. 7. 8.

83. 6. BOM 7. 1, 2. BOM / 3. 4. B.O.M 5. () 6. FMB SLITTING 7. SLITTING / 1. ( 205) Bar Code Location

84. - - 5 chiller - 15 - 40 - 5

85. 10. / 1. 2. 3. ( vs ) 3. 3-1. ( , ) 3-23. / / / / Bar Code

86. RF-ID BAR-PRT MCS Server RS-422 RS-422 RS-232 RS-422 TCP/IP SOCKET TCP/IP Oracle SQL-Net TCP/IP Oracle SQL-Net TCP/IP SOCKET TCP/IP INTOUC H Ethernet TCP/IP RS-232 PLC Ethernet TCP/IP SOCKET PCC Relay SignalRelay Signal OFF-LINE BAG TCP/IP Oracle SQL-Net TCP/IP Oracle SQL-Net TCP/IP Oracle SQL-Net RF-ID Bar-Code Scanner BATCH SHEET NMP PLC SCC MCS Client UACS TCP/IP Oracle SQL-Net Interface

88. [ ] A Monitoring

89. [ ] , , Bin No. 1 3 5 6 8 9 1 AAC332A AAC332A AAC332A AAC141A AAC131A AAC241A 2 AAC331A AAC331A AAC331A AAC231A AAC241A AAC141A 3 AAC341A AAC341A AAC341A AAC421A AAC141A AAD241A 4 AAC421A AAC421A AAC241A AAC241A AAD342A AAC332A 5 AAC231A AAC141A AAC231A AAC331A AAD241A AAC331A 6 AAC141A AAC241A AAC141A AAC332A AAC331A AAC231A 7 DUST C/B DUST C/B DUST C/B DUST C/B AAC332A AAC131A 8 AAD241A AAD342A AAD241A AAD241A DUST C/B DUST C/B 1 AAY101A Spare AAK302A AAD342A AAD111A AAD111A 2 AAD623A AAD623A AAD342A AAT501A AAY106A AAY106A 3 AAY106A AAY106A AAD111A AAD111A AAY307A AAY307A 1 AAY307A AAY307A Spare Spare 2 AAY215A AAD645A AAY106A AAY106A 3 AAD111A AAD111A AAY307A AAY307A 1 AAA101A AAA101A AAA101A AAA101A AAK121A AAA241A 2 AAA121A AAA121A AAA121A AAA121A AAA101A AAA101A 3 AAT108A AAT108A AAA201A AAA201A AAT501A AAT108A 4 AAT311A AAT311A AAA241A AAA241A AAA121A AAA121A 5 AAT303A AAF321A 6 AAA201A AAA201A 7 AAT421A AAT421A 8 AAX901A AAT303A 9 AAT311A AAT311A 10 AAA241A AAK121A 11 AAT302A AAT302A 12 AAK401A AAF306A 13 AAT108A AAT501A 14 AAK301A AAT415A 1 AAP104A AAP104A AAP104A AAP104A AAP104A AAP104A 2 AAP206A AAP206A AAP206A AAP206A AAP206A AAP206A 3 AAP105A AAP105A AAP105A AAP105A AAP105A AAP105A 1 2 3 Bin No. 1 2 1 AAK121A AAK121A 2 AAF321A AAA103A 3 AAK301A AAT210A 4 AAA121A AAA121A 5 AAT108A AAT108A 6 AAT303A AAT303A 7 AAT311A AAT311A 8 AAA201A AAA201A 9 AAA102A AAA102A 10 AAT421A AAT421A 11 AAF306A AAT415A 12 AAK401A AAT302A 13 AAA241A AAA241A 14 AAA101A AAA101A [ Off-Line Line ]

90. List No. 1 2 1 2 3 H/Door Ram D/Door 1 Yes Open High Close 2 , Yes Yes Open High Close 3 , Yes Yes Open High Close 4 ,Q Yes Open High Close 11 , Yes Yes Yes Open High Close 12 ,,1 Yes Yes Yes Open High Close 13 ,,2 Yes Yes Yes Open High Close 14 ,,1,2 Yes Yes Yes Yes Open High Close 15 ,1 Yes Yes Open High Close 16 ,1,1 Yes Yes Yes Open High Close 17 ,1,2 Yes Yes Yes Open High Close 18 ,1,1,2 Yes Yes Yes Yes Open High Close 19 ,,1 Yes Yes Yes Open High Close 20 ,,2 Yes Yes Yes Open High Close 21 ,,1,2 Yes Yes Yes Yes Open High Close 22 ,, Yes Yes Yes Open High Close 23 ,,,1 Yes Yes Yes Yes Open High Close 24 ,,,2 Yes Yes Yes Yes Open High Close 25 ,,,1,2 Yes Yes Yes Yes Yes Open High Close 26 ,,1 Yes Yes Yes Open High Close 27 ,,1,1 Yes Yes Yes Yes Open High Close 28 ,,1,2 Yes Yes Yes Yes Open High Close 29 ,1 Yes Yes Open High Close 30 ,2 Yes Yes Open High Close 31 ,1,2 Yes Yes Yes Open High Close 35 ,,3 Yes Yes Yes Open High Close 36 ,,1,3 Yes Yes Yes Yes Open High Close 37 ,,2,3 Yes Yes Yes Yes Open High Close 38 ,1,3 Yes Yes Yes Open High Close 39 ,1,2,3 Yes Yes Yes Yes Open High Close 40 ,1,1,3 Yes Yes Yes Yes Open High Close 41 ,,3 Yes Yes Yes Open High Close 42 ,,2,3 Yes Yes Yes Yes Open High Close 43 ,,1,3 Yes Yes Yes Yes Open High Close 44 ,,,3 Yes Yes Yes Yes Open High Close 45 ,,,1,3 Yes Yes Yes Yes Yes Open High Close 46 ,,,2,3 Yes Yes Yes Yes Yes Open High Close 47 ,,1,3 Yes Yes Yes Yes Yes Open High Close 48 ,3 Yes Yes Open High Close 49 ,2,3 Yes Yes Yes Open High Close No. 1 2 1 2 3 H/Door Ram D/Door 50 ,,,1,2,3 Yes Yes Yes Yes Yes Yes Open High Close 51 Yes Open High Close 52 ,1 Yes Yes Open High Close 53 ,2 Yes Yes Open High Close 54 ,1,2 Yes Yes Yes Open High Close 55 1 Yes Open High Close 56 1,1 Yes Yes Open High Close 57 1,2 Yes Yes Open High Close 58 1,1,2 Yes Yes Yes Open High Close 59 2 Yes Open High Close 60 2,1 Yes Yes Open High Close 61 2,2 Yes Yes Open High Close 62 2,1,2 Yes Yes Yes Open High Close 65 ,1,3 Yes Yes Yes Open High Close 66 ,3 Yes Yes Open High Close 67 ,2,3 Yes Yes Yes Open High Close 68 ,1,3 Yes Yes Yes Open High Close 69 1,3 Yes Yes Open High Close 70 1,2,3 Yes Yes Yes Open High Close 71 1,1,3 Yes Yes Yes Open High Close 72 2,2,3 Yes Yes Yes Open High Close 73 2,3 Yes Yes Open High Close 74 2,1,3 Yes Yes Yes Open High Close 75 2,3 Yes Yes Open High Close 76 1,3 Yes Yes Open High Close 77 3 Yes Open High Close 81 Close Middle Close 82 1 Close Middle Close 83 2 Close Middle Close 84 1 Yes Close High Close 85 2 Yes Close High Close 86 1,2 Yes Yes Close High Close 91 RAM SWEEP Close Middle Close 92 Close Low Close 93 Open High Open 94 START Open High Close 95 TOP Yes Open High Close 96 , Yes Yes Open High Close 97 ,,1,2,3 Yes Yes Yes Yes Yes No Open High Close 98 ,,2,3 Yes Yes Yes Yes No Open High Close

92. [ ] Trend Log (Linear)

93. [ ] Trend Log (Overlap)

94. 1) ( ) 1) POP -> LOTNO LO T (A) () () (F) RPM STEP (mm: ss) INPUT OUTP UT STE P1 STE P2 STE P3 STE P4 STE P5 STE P6 16 111024 A70230 2 1 A702 3 2011- 10-24 15:47 :46 16:10 :21 22:35 0.0~1 76.0 33.0~ 121.0 19.0~ 22.0 22.0~ 25.0 0.0~7. 6 0.0~3 0.0 240 210210 60 0 0 17 111024 A70230 3 1 A702 3 2011- 10-24 16:35 :24 17:07 :24 32:00 0.0~1 72.0 29.0~ 115.0 19.0~ 22.0 22.0~ 25.0 0.0~7. 3 0.0~3 0.0 240 210210 60 0 0 18 111024 A70230 4 1 A702 3 2011- 10-25 10:56 :26 11:18 :23 21:57 0.0~1 77.0 36.0~ 121.0 19.0~ 22.0 22.0~ 25.0 0.0~7. 4 0.0~2 9.0 240 210210 60 0 0 19 111024 A70230 5 1 A702 3 2011- 10-25 13:30 :16 13:51 :19 21:03 0.0~1 61.0 20.0~ 123.0 19.0~ 22.0 20.0~ 25.0 0.0~7. 6 0.0~2 9.0 240 210210 60 0 0 20 111024 A70230 6 1 A702 3 2011- 10-25 13:55 :51 14:18 :58 23:07 0.0~1 65.0 63.0~ 123.0 20.0~ 25.0 24.0~ 30.0 0.0~7. 6 0.0~2 9.0 240 210210 60 0 0 21 111024 A70230 7 1 A702 3 2011- 10-25 14:36 :03 15:02 :24 26:21 0.0~1 63.0 43.0~ 123.0 27.0~ 30.0 28.0~ 33.0 0.0~7. 6 0.0~2 9.0 240 210210 60 0 0 22 111024 E70020 1 1 E700 2 2011- 10-24 11:49 :18 11:58 :42 09:24 0.0~1 78.0 26.0~ 85.0 20.0~ 22.0 22.0~ 24.0 0.0~6. 0 0.0~2 9.0 180 119 0 0 0 0 23 111024 E70020 2 1 E700 2 2011- 10-25 10:25 :20 10:44 :35 19:15 0.0~1 89.0 43.0~ 74.0 19.0~ 22.0 22.0~ 24.0 0.0~6. 3 0.0~2 8.0 180 120 0 0 0 0

95. , , , , M.V, , ,

96. () NO 8-3 F/P.CMB/FMB ? - ,,,, ( -> tc90 10% : ) - () SPC - , , , , - ( : O O O)

97. 8. 9. 1. () 2. / 3. Compound 3-1. ,Scorch,, 3-2. 4. 5. 1. 2. 3. / 4. / 5.

98. ODR MDR RHEO METER

99. Tmax 45 5 15 2.2 Tmin 11.5 2 2.4 0.6 t50 6.5 1 4.2 0.7 t90 9 1.5 7.4 0.9

100. 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 49 51 53 55 57 59 61 63 65 67 69 71 73 CEP4082F SPEC 10% SPEC 3 10% 3 CEP4082F 3:5060 4:0024 (4.000.40) 4:0045 2.74% 0.00% CEP5082H 3:4060 3:4422 (3.720.31) 3:4455 19.8% 0.76% EP80 4:1425 (4.220.41) 4:149 0% 0%

101. A GEP1365F D : D 3 : 3 5 : 5 LINE E :

102. () NO 9-1 F/P.(CMB, FMB) ? , / (F/P) - : 205, : 70% ( )

103. () NO 9- 2 F/P. ? ( ) , Tag () , , - - , , , ( ) FMB (FMB ) FMB ( -> 0.5% ) / FMB

104. : ML, TC10, TC90 TORQUE

105. , , ,

106. 2. 1. 2. 3. 4. 5. 6. 7. MAN

108. Rheometer ts2 Rheometer ts1 -> ts2 Rheometer

109. . -,,

110. - POP

111. (,,) (,,) ) (,,)

112. BAR CODE , F/PROOF PROGRAM

114. - - () - - () ()

118. : Cpk : 0.25 : Cpk : 1.82

120. /

122. 1200(1PPM) 1400 (1PPM)

125. ( )

126. - () BOX

127. 60 80 60 80

129. - , BOX - BOX ,

130. Lay-out Lay-out Lay-out Lay-out GNR2970 Lay-out

131. .

132. CMB/FMB Tag FMB () , CMB () CMB

133. , () ,

136. .(:0~100 ,:145~150) (0 ~ 300)

139. (, ) OVER 95% ERP CODE () Cavity (EA) () RUBBER BUSH R1SR046-00 RUBBER BUSH (NF) (NF+GH+SM) - 475 64 30,400 - 30,400 500 RUBBER BUSH R1SR051-00 RUBBER BUSH (TD RR) 130,081 475 64 30,400 65,041 500 RUBBER BUSH R1SR065-00 RUBBER BUSH (TD RR) - 475 64 30,400 - 30,400 500 RUBBER BUSH R1SR041-00 RUBBER BUSH CV9(R,UPR) - 475 32 15,200 - 15,200 500 RUBBER BUSH R1SR068-00 RUBBER BUSH (YD) 14,509 475 64 30,400 14,509 15,891 500 RUBBER BUSH R1MR094-00 M/T BUSH GMT966 49,516 475 32 15,200 49,516 500 RUBBER BUSH R1MR167-A1 M/T BUSH ZETA - 475 36 17,100 - 17,100 500 RUBBER BUSH R1MR081-00 MOUNTING BUSH SRM - 475 32 15,200 - 15,200 500 RUBBER BUSH R1MR142-00 M/T BUSH C200 - 475 36 17,100 - 17,100 500 INSULATOR R1SR063-00 INSULATOR B/R ASS'Y(LM+EL) 40,713 475 24 11,400 40,713 500 INSULATOR R1SR064-00 INSULATOR B/R ASS'Y(SL+SLS) - 475 24 11,400 - 11,400 500 INSULATOR R1SR075-00 INSULATOR B/R ASS'Y(VG F/L) - 475 24 11,400 - 11,400 500 INSULATOR CKD[] R00005-A0 BUSH ASSY (LM) - 475 24 11,400 - 11,400 500 INSULATOR R00005-A0 BUSH ASSY (LM) - 475 24 11,400 - 11,400 500 INSULATOR R1SR048-00 MOUNTING BKT ASS'Y W200 - 475 24 11,400 - 11,400 500 INSULATOR R1SR057-00 MOUNTING ASS'Y C200 - 475 24 11,400 - 11,400 500 RUBBER R1MR159-00 DAMPING COUPLER (D1XX) 6,461 950 72 68,400 6,461 61,939 1,000

140. ( / ) (,) ( )

141. NAME PLATE NAME PLATE NAME PLATE

142. , , : 170 10 : 170 10 ) : 170 10 : 160 10 : 170 10 : 160 10

143. - -

144. MAN

147. , or OJT , . OJT

16 고무 업종 품질기술세미나 160629

Technology

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