100 Wood Acetic Acid

7/23/2019 100 Wood Acetic Acid

1/12

SAFETY DATA SHEET acc. to 453/2010/EC

ACETIC ACID 100%

SDB_ES_100_07_EN.doc Rev. 07 vom Juli 2011 Seite 1 von 12

1 IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY

1.1 Product identifier

Trade Name: Lenzing Acetic acid 100%

1.2 Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses of the substance or mixture

Manufacture of food productsThis sector of use is not covered by REACh, if necessary, exposition scenario 1 can be used.)

sector of use category SU 4exposition scenario 1 - Manufacturing of acetic acid

Manufacture of acetic acid or use as an intermediate or process chemical or extraction agent. Includingrecycling/recorvery, material transfers, storage, sampling, associated laboratory activities, maintenance andloading (including marine vessel/barge, road/rail car and bulk container).sector of use category SU 3, 8, 9process category PROC 1, 2, 3, 4, 8a, 8b, 15environmental release category ERC 1exposition scenario 1 - Manufacturing of acetic acid

loading (including marine vessel/barge, rail/road car and IBC loading) and repacking (including drums andsmall packs) of substance including its distribution and associated laboratory activities

sector of use category SU 3, 8, 9process category PROC 1, 2, 3, 4, 8a, 8b, 15environmental release category ERC 1 (loading)

2 (repacking)exposition scenario 2 - Distribution of acetic acid

Use as an intermediate of acetic acidThis scenario is covered by ES1 Manufacturing of acetic acidExpositionsszenarium / exposition scenario 3 - Use as an intermediate of acetic acid

Formulation, packing and re-packing of the substance and its mixtures in batch or continuous operations,including storage, materials transfers, mixing, large and small scale packing, maintenance and associatedlaboratoy activities

sector of use category SU 3, 10process category PROC 1, 2, 3, 4, 5, 8a, 8b, 9, 14, 15environmental release category ERC 2exposition scenario 4 - Formulation of acetic acid

Covers the use as a component of cleaning products including transfer from storage, pouring/unloadingfrom drums or containers. Exposures during mixing/diluting in the preparatory phase and cleaning activities(including spraying, brushing, dipping, wiping, automated and by hand), related equipment cleaning andmainenance.sector of use category SU 3, 5, 6process category PROC 2, 3, 4, 7, 8a, 8b, 10, 13environmental release category ERC 4exposition scenario 5 - Use of acetic acid in cleaning agents

industrial


2/12


ACETIC ACID 100%


Covers the use as a component of cleaning products including pouring/unloading from drums or containers;and exposures during mixing/diluting in the preparatory phase and cleaning activities (including spraying,brushing, dipping, wiping automated and by hand).sector of use category SU 22process category PROC 1, 2, 3, 4, 8a, 8b, 10, 11, 13environmental release category ERC 8A, 8Dexposition scenario 6 - Use of acetic acid in cleaning agents

professional

Use of acetic acid in cleaning agents consumerno detailled description availablesector of use category SU no informationprocess category PROC no information

environmental release category ERC no informationexposition scenario 7 - Use of acetic acid in cleaning agents consumer

Manufacture of substance A or use as an intermediate or process chemical or extraction agent. Includingrecycling/recovery, material transfer, storage, sampling, associated laboratory activities, maintenance andloading (including marine vessel/barge, road/rail car and bulk container)sector of use category SU 3, 10process category PROC 1, 2, 3, 4, 8a, 8b, 15environmental release category ERC 1exposition scenario 8 - Use of acetic acid in oil field drilling

industrial

Use as an agrochemical excipient for application by manual or machine spraying, smokes and fogging,including storage, equipment clean-downs and disposalsector of use category SU 3, 10process category PROC 1, 2, 3, 4, 8a, 8b, 15environmental release category ERC 1exposition scenario 9 - Use of acetic acid in agrochemicals

professional

no detailled description availablesector of use category SU no informationprocess category PROC no informationenvironmental release category ERC no informationexposition scenario 10 - Use of acetic acid in agrochemicals

consumer

Use of the substance within laboratory settings, including material transfer and equipment cleaning.sector of use category SU 3, 10process category PROC 10, 15environmental release category ERC 4exposition scenario 11 - Use of acetic acid in laboratory reagents

industrial

Use of small quantities wiithin laboratory settings, including material transfer and equipment cleaning.sector of use category SU 22process category PROC 10, 15environmental release category ERC 8A

exposition scenario 12 - Use of acetic acid in laboratory reagents profesional


3/12


ACETIC ACID 100%


Covers the use of the substance for the treatment of water at industrial facilities in open and closedsystems.sector of use category SU 3, 8, 9process category PROC 1, 2, 3, 4, 8a, 8b, 15environmental release category ERC 1exposition scenario 13 - Use of acetic acid in water treatment

industrial

Covers the use of the substance for the treatment of water in open and closed systems.sector of use category SU 3, 8, 9process category PROC 1, 2, 3, 4, 8a, 8b, 15environmental release category ERC 1exposition scenario 14 - Use of acetic acid in water treatment

professionell

1.2 uses advised againstnone

1.3 Details of the supplier of the safety data sheet

Lenzing Aktiengesellschaft,Werkstrasse 2A 4860 Lenzing, AustriaPhone: +43 7672 701 3262 Mark eting and Sales

supplier

Facsimile: +43 7672 701 3111 Marketing and Sales

safety data sheet: [email protected]

1.4 emergency telephone numberLenzing fire brigade +43 7672 701 2500

(only in german)24 hours

United KingdomUK: National Poison Information Service(not for the public)

+44 (0) 844 892 0111 24 hours

England: NHS direct (public) +44 (0) 845 4647 24 hoursWales: NHS direct (public) +44 (0) 845 4647 24 hoursScotland: NHS direct (public) +44 (0) 8454 242424 24 hours

IrelandPoisons information centerof Ireland (for professionals) Dublin

+353 (0) 1 8379964+353 (0) 1 8092566 24 hours

2 HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixtureInformation acc. GHS (1272/2008/EC)flam. liq. 3skin corr 1B

Information acc. 67/548/EC and 1999/45/ECC Corrosive


4/12


ACETIC ACID 100%


Food additive. Ingestion of diluted acetic acid is quite harmless.

2.2 Label elementsInformation acc. GHS (1272/2008/EC)

DANGER

H226 Flammable liquid and vapour.H314 Causes severe skin burns and eye damage.

Information acc. 67/548/EC and 1999/45/EC

R 10 Flammable.R 34 Causes burns.

2.3 Other hazardsnot a PBT substancenot a vPvB substanceno other hazards

3 COMPOSITION/INFORMATION ON INGREDIENTS

Name Acetic acid

Formula: CH3CO2HCAS number 64-19-7Index number 607-002-00-6EINECS number: 200-580-7

REACh registration number: 01-2119475328-30-0036

4 FIRST AID MEASURES

4.1 Description of first aid measures

Inhalation: Fresh air, rest, half-upright position. Refer for medical attention.Skin contact: Remove contaminated clothes. Rinse with plenty of water. Wash with

water (or 2% Na2CO3-solution) for several times. Refer for medialattention.

Ingestion: Rinse m outh. Do NOT induce vom iting. Give plenty of water to drink.Refer for medical attention.

Eye contact: Open eye lid and r inse for at least 15 m inutes with running water.Remove contact lenses if easily possible. Refer for medical attention.

4.2 Most important symptoms and effects, both acute and delayedLethal oral dose 20 70 g for grown-up people.The symptoms of lung oedema often becomes manifest after some hours time, they are intensified byphysical effort. Rest and medical observation is essential.

4.3 Indication of any immediate medical attention and special treatment neededno special advise


5/12


ACETIC ACID 100%


5 FIRE FIGHTING MEASURES

5.1 Extinguishing media:Water, foam or carbonic acid extinguisher.

5.2 special hazards arising from the substance or mixtureAbove 39 C explosive vapour-air mixtures may be formed. Vapours are heavier than air.

5.3 advice for firefightersAbove 39 C explosive vapour-air mixtures may be formed. Vapours are heavier than air.

6 ACCIDENTAL RELEASE MEASURES

6.1 Protective equipment and measures:Remove people form dangerous area.Protective clothing: Goggles, gloves, special proctection suit.

6.2 Environmental protection:Inform consumer of drinking, industrial and cooling water.Measures to dam spoiled material. Use ex-proof pump

6.3 methods and material for containment and cleaning up

Cover remaining material with non-combustible material (ground limestone, dry earth or sand etc.) andtransfer to a safe disposal site.

6.4 reference to other sectionsrefer to section 8 and 13

7 HANDLING AND STORAGE

7.1 Precautions for safe handlingGasmask filter A or compresssed air breathing apparatus, protective goggles, special protection suit.

7.2 Conditions for safe storage, including any incompatibilitiesSuitable materials: Acid resistant steel, polyethylen, polypropylen, PTFE, glass.Avoid higher temperatures.Do not store together with strong oxidising agents.Keep apart from open flame and ignition sources.Store in closed vessels.Corrosive: Do not store higher than waist-high.

7.3 specific end use(s)none


6/12


ACETIC ACID 100%


8 EXPOSURE CONTROL / PERSONAL PROTECTION

8.1 Control parameters

Occupational exposure limits:

EU (91/322/EWG; 98/24/EWG; 2000/39/EG;2006/15/EG; 2009/161/EU)

10mL/m = 25mg/m

United Kingdom (Workplace exposure LimitsEH40/2005)

no limit

Ireland (2007 Code of Practice for the Safety,Health and Welfare at W ork (ChemicalAgents) Regulations 2001)

25mg/m

recommended monitoring proceduresrefer to: GESTIS Analytical Methods (http://www.dguv.de/ifa/en/gestis/analytical_methods/index.jsp)

DNEL values

DNEL values

Worker short term local inhalation 25mg/m

Worker long term local inhalation 25mg/m

general population short term local inhalation 25mg/m

general population long term local inhalation 25mg/m

PNEC Werte / PNEC values

PNEC value method

fresh water 3,058mg/L assessment factor /

marine water 0,3058mg/L assessment factor /

water (intermittent release) 30,58mg/L assessment factor /

sediment fresh water 11,36mg/kg dw statistical extrapolation

sediment marine water 1,136mg/kg dw statistical extrapolation

soil 0,478mg/kg dw statistical extrapolation

sewage treatment plants 85mg/L assessment factor /

8.2. Exposure controls

8.2.1 Appropriate engineering controlsNo open container and equipment wherever possible. Local exhaust ventilation (control of air flow).Precautionary measures against spoiling and fire. Remove ignition sources.

8.2.2 Individual protection measures, such as personal protective equipmentRespiratory protection: gas mask filter A or compressed air breathing apparatus

chemical applications

glove material Butyl natural latex

glove thickness 0,3mm 1mm

break through time >480min 110min

Hand protection:

type KCL Butoject Art.Nr. 897 Combi Latex Art.Nr. 395


7/12


ACETIC ACID 100%


food applications

glove material natural latex Nitrile

glove thickness 0,6mm 0,4mm

break through time 32min 59min

Hand protection:

type KCL Lapren Art.Nr. 706 Camatril Latex Art.Nr. 729

The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and theresultant standard EN374, for example KCL 897 Butoject, KCL 295 Combi Latex, KCL 706 Lapren or KCL729 Camatril. The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types. This recommendation applies only to the product statedin the safety data sheet and supplied by us as well to the purpose specified by us. When dissolving in ormixing with other substances and under conditions deviating from those stated in EN374 please contact thesupplier of CE- approved gloves (e.g. KCL GmbH, D- 36124 Eichenzell, Internet:www.kcl.de)

Eye protection: Tightly sealing protection goggles

body protection: acid resistant work wear, special protection suit when necessary

General protective and hygiene measures: Remove contaminated clothing immediately.Avoid eye and skin contact !

8.2.3 Environmental exposure controlsIn the chemcial safety assessment no hazard was identified. Therefore an exposure estimation and riskcharacterization is not necessary.

9 PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

data according chemical safety report for 100% acetic acidshape LiquidColour Colourless

Appearance

odour: Pungent, vinegar-like.

Melting point: 16,64C (289,64K at 1013hPa)Boiling point: 117,9C (390,9K at 1013hPa)Density: 1,0446 g/cm (at 25C)Vapour pressure: 20,79 hPa (at 25C)Solubility: 602,9g/L (at 25C)

Mixable with water in any proportion.partition coefficient n-octanol/water: log POW= -0,17Flash point: 39 CFlammability limits: 4 19,9 Vol%Ignition temp.: ca. 463Cdissociation constant pKa = 4,756 at 25Cviscosity 1,056mPa*s at 25C

9.2 Other informationpH-value 30%pH-value 40%pH-value 50 %

1,71,51,3


8/12


ACETIC ACID 100%


10 STABILITY AND REACTIVITY

10.1 Reactivitynon reactive

10.2 chemical stabilityThe product is chemically stable under standard ambient conditions.

10.3 Possibility of hazardous reactionsViolent reaction in case of contact with strong basic substances (NaOH, KOH), oxidising agents and otherreactive m aterials. Development of hydrogen in contact with carbon-steel and several m etals.

10.4 conditions to avoidAbove 39 C explosive vapour/air mixtures may be formed.No decomposition if used in agreed manner.

10.5 Incompatible materialsViolent reaction in case of contact with strong basic substances (NaOH, KOH), oxidising agents and otherreactive m aterials. Development of hydrogen in contact with carbon-steel and several m etals.

10.6 Hazardous decomposition productsno information

11 TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

a) Acute toxicity:

Klimisch ratingLD50LD50LD50

LC50LC50RD50

3310 mg/kg4960 mg/kg3530 mg/kg

>16000ppm (4h)5620ppm (1h)227 ppm (1h)

rat, oralmouse, oralrat, oral

rat, inhalationmouse, inhalationmouse, inhalation

2 (reliable with restrictions)2 (reliable with restrictions)4 (not assignable)

4 (not assignable)4 (not assignable)2 (reliable with restrictions)

no such properties

b) skin corrosion/irritation

Acetic acid (25%) is corrossive

c) serious eye damage/irritation

Acetic acid (25%) is corrosive

d) respiratory or skin sensitisation

no such properties

e) germ cell mutagenicity

no such properties


9/12


ACETIC ACID 100%


f) carcinogenicityno such properties

g) reproductive toxicityno such properties

h) STOT-single exposureno such properties

i) STOT-repeated exposureno such properties

j) aspiration hazard

no such properties

12 ECOLOGICAL INFORMATION

12.1 Toxicity

Fish toxicity (short term)

species method test material result ranking

Oncorhynchusmykiss

fresh waterOECD203

acetate ion LC50 (96h): >300,82mg/L 2 (reliable with restrictions)key study

Values used for chemical safety assessment

LC50 freshwater 300,82mg/L acetate ion

LC50 marine water 300,82mg/L acetate ion

aquatic invertebrates (short term)


Daphnia magna fresh waterOECD202

acetate ion EC50 (48h):>300,82mg/L

2 (reliable with restrictions)key study


EC/LC50 freshwater 300,82mg/L acetate ion

Algae and aquatic plants


Sceletonemacostatum

salt waterISO10253

acetate ion EC50 (72h):>300,82mg/L



EC/LC50 saltwater 300,82mg/L acetate ion

12.2 Persistence and degradability

compartment method test material result ranking

soil laboratory;loamy sand

Acetic acid DT50: 2 days 2 (reliable with restrictions)key study

water BOD procedure Acetic acid 96% after 20days



10/12


ACETIC ACID 100%


air calculation Acetic acid DT50: days 2 (reliable with restrictions)key study

Acetic acid is readily degradable

12.3 Bioaccumulative potential

Non bioaccumulable (log KOW: -0,23; BCF 3,16)

Acetic acid is not bioaccumulable

12.4 Mobility in soil

method test material result ranking

QSAR Acetic acid KOC: 1,153 key study

Acetic acid has a low potential for adsorption

12.5 Results of PBT and vPvB assessmentno PBT or vPvB properties

12.6 Other adverse effectskeine / none

13 DISPOSAL CONSIDERATIONS

EUcategory (acc. 91/689/EEC): 06 01 06

14 TRANSPORT INFORMATION

ACETIC ACID, SOLUTION, more than 80% acid by mass

RID /ADR IMDG ICAO IATA

14.1 UN number 2789 2789 2789 2789

14.2 UN proper shipping nam e ACETIC ACID, SOLUTION, more than 80% acid by m ass

14.3 Transport hazard class(es) 8 (3) 8 (3) 8 (3) 8 (3)

14.4 Packing group II II II II

14.5 Environmental hazards no marine pollutant

14.6 Special precautions for user none14.7 Transport in bulk according to Annex II ofMARPOL 73/78 and the IBC Code

not appropriate

15 REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulation (EC) No 2037/2000 of the European Parliament and of the Council of 29 June 2000 onsubstances that deplete the ozone layer.not appropriate


11/12


ACETIC ACID 100%


Regulation (EC) No 850/2004 of the European Parliament and of the Council of 29 April 2004 on persistentorganic pollutants and amending Directive 79/117/EEC.not appropriate

Regulation (EC) No 689/2008 of the European Parliament and of the Council of 17 June 2008 concerning theexport and import of dangerous chemicalsnot appropriate

COUNCIL DIRECTIVE 96/82/EC of 9 December 1996 on the control of major-accident hazards involvingdangerous substancesnot appropriate

Council Directive 1999/13/EC of 11 March 1999 on the limitation of emissions of volatile organic compounds

due to the use of organic solvents in certain activities and installationsappropriate (mind intended use)

Regulation (EC) No 273/2004 of the European Parliament and of the Council of 11 February 2004 on drugprecursorsnot appropriate

WGK 1(VwVwS Anhang 2)

15.2 Chemical safety assessmentFor this product a chemical safety assessment was carried out.The extended safety data sheet containing the exposition scenarios will be provided upon request.

16 OTHER INFORMATION

Information acc. GHS (1272/2008/EC)H226 Flammable liquid and vapour.H314 Causes severe skin burns and eye damage.P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.P241 Use explosion-proof electrical/ventilating/lighting//equipment.P260 Do not breathe dust/fume/gas/mist/vapours/spray.P280 Wear protective gloves/protective clothing/eye protection/face protection.P303+P361+P353

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin withwater/shower.

P305+P351+P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if presentand easy to do. Continue rinsing.

Information acc. 67/548/EC and 1999/45/ECR10 Flammable.R34 Causes burns.S01/02 Keep locked up and out of the reach of children.S23 Do not breathe vapour/aerosol.S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice.S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where

possible).

Used abbreviations and acronyms can be looked up atwww.wikipedia.org.


12/12


ACETIC ACID 100%


Provide adequate information, instruction and training for operators.

Change

The information contained herein is accurate to the best of our knowledge and belief. It is intended todescribe the product from a point of view of health and safety requirements. It is not therefore constructed asguaranteeing specific properties. For specific product information consult product specification

100 Wood Acetic Acid

Documents

Transcript of 100 Wood Acetic Acid