longhornaap.comlonghornaap.com/system/assets/AdminRecord/2018/2018...Analysis: Analyzed By:...

LONGHORN ARMY AMMUNITION PLANT

KARNACK, TEXAS

ADMINISTRATIVE RECORD

Volume 50

2018

Bate Stamp Numbers 00912961 – 00914506

Prepared for

Department of the Army Longhorn Army Ammunition Plant

1976 – 2018

LONGHORN ARMY AMMUNITION PLANT KARNACK, TEXAS

ADMINISTRATIVE RECORD – CHRONOLOGICAL INDEX

VOLUME 50 2018 A. Title: Report (cont’d) – Quarterly Evaluation Report, 3rd Quarter (July–September) 2018, Groundwater Treatment Plant, Longhorn Army Ammunition Plant, Karnack, Texas, December 2018 Author(s): Bhate Environmental Associates, Inc.

Recipient: U.S. Army Corps of Engineers, Tulsa District Date: December 18, 2018

Bate Stamp: 00912961 – 00914506

Analysis:

Analyzed By:ELMS/2120 (HBN: 218949)Thomas Bosch

Workorder: 1819285

EPA 6850, DoD QSMBatch: NA

Prepared By: NABatch:

Preparation: NAClient SOW/Contract SpecifiedDoD QSM

Limits:Basis:

Analysis Information

QC Report Authorization (/S/ is an electronic signature that complies with 21 CFR Part 11)

- Sample result is greater than 4 times the spike added- Analyte above reporting limit or outside of control limits

Symbols and DefinitionsRPD - Relative % Difference (Spike / Spike Duplicate)ND - Not Detected (U - Qualifier also flags analyte as not detected)

QC results are not adjusted for moisture correction, where applicable- Sample and Matrix Duplicate less than 5 times the reporting limit NA - Not Applicable- Result is above the calibration range

The Matrix Spike, Matrix Spike duplicate or Matrix Duplicate isreported for your information only. The sample matrix may beinappropriate for the method selected.

# -

Analyst Peer Review

/S/ Thomas Bosch /S/ Stephen Brose

07/16/2018 12:52 07/16/2018 14:08

Page 2 of 2 Monday, July 16, 2018

Quality Control SampleBatch Report

QCS V4.418 of 18

00912961

WorkOrder: HS18071383Longhorn GW Treatment Plant

Bhate Environmental Associates, Inc.

Marcia Olive445 Union Blvd Ste 129

Lakewood CO 80228

09-Aug-2018

www.alsglobal.com F: +1 281 530 5887 T: +1 281 530 5656 Houston, TX 77099 10450 Stancliff Rd. Suite 210

Page 1 of 88

00912962

August 09, 2018

Marcia OliveBhate Environmental Associates, Inc.445 Union Blvd Ste 129Lakewood, CO 80228

The analytical data provided relates directly to the samples received by ALS Environmental and for only the analyses requested. Results are expressed as "as received" unless otherwise noted.

QC sample results for this data met EPA or laboratory specifications except as noted in the Case Narrative or as noted with qualifiers in the QC batch information. Should this laboratory report need to be reproduced, it should be reproduced in full unless written approval has been obtained by ALS Environmental. Samples will be disposed in 30 days unless storage arrangements are made.

If you have any questions regarding this report, please feel free to call me.

Sincerely,

ALS Environmental received 1 sample(s) on Jul 27, 2018 for the analysis presented in the following report.

Laboratory Results for: Longhorn GW Treatment Plant

Dear Marcia,

Work Order: HS18071383

Project Manager

Generated By: JUMOKE.LAWAL

RJ Modashia

10450 Stancliff Rd. Suite 210 Houston, TX 77099 T: +1 281 530 5656 F: +1 281 530 5887

www.alsglobal.comRight Solutions • Right Partner

Page 2 of 88

00912963

Client: Bhate Environmental Associates, Inc.

Work Order: HS18071383Project: Longhorn GW Treatment Plant SAMPLE SUMMARY

Lab Samp ID Client Sample ID Collection DateMatrix TagNo Date Received Hold

HS18071383-01 26-Jul-2018 13:00 27-Jul-2018 10:15LH18/24-SP650_072618 Water

ALS Group Houston, Corp 09-Aug-18Date:

Page 3 of 88

00912964

Client: CASE NARRATIVE

Work Order:Longhorn GW Treatment PlantBhate Environmental Associates, Inc.

Project:

Work Order Comments

The analysis for Perchlorate was subcontracted to ALS Salt Lake City, UT. Final report attached.•


Page 4 of 88

00912965

Client:Project:Sample ID:

Bhate Environmental Associates, Inc.Longhorn GW Treatment PlantLH18/24-SP650_072618

WorkOrder:Lab ID:

Collection Date:

HS18071383HS18071383-01

26-Jul-2018 13:00 Matrix:Water

ANALYTICAL REPORT

ANALYSES RESULT LOQDILUTION FACTORUNITS

DATE ANALYZEDQUAL DL LOD

SUBCONTRACT ANALYSIS - PERCHLORATE (EPA 6850)

Method:NA Analyst: SUB

1NA 09-Aug-2018 11:280Subcontract Analysis See Attached 0

09-Aug-18Date: ALS Group Houston, Corp

Note: See Qualifiers Page for a list of qualifiers and their explanation.

Page 5 of 88

00912966

Client:Longhorn GW Treatment PlantBhate Environmental Associates, Inc.

WorkOrder:Project:

HS18071383DATES REPORT

Collection Date Prep Date Analysis DateClient Samp IDSample ID TCLP Date DF

Batch ID R321384 Test Name : SUBCONTRACT ANALYSIS - PERCHLORATE (EPA 6850) Matrix: Water

09 Aug 2018 11:28HS18071383-01 26 Jul 2018 13:00 1LH18/24-SP650_072618


Page 6 of 88

00912967

QUALIFIERS, ACRONYMS, UNITS

Client:Project:WorkOrder:

Bhate Environmental Associates, Inc.Longhorn GW Treatment PlantHS18071383

Qualifier Description* Value exceeds Regulatory Limit

a Not accredited

B Analyte detected in the associated Method Blank above the Reporting Limit

E Value above quantitation range

H Analyzed outside of Holding Time

J Analyte detected below quantitation limit

M Manually integrated, see raw data for justification

n Not offered for accreditation

ND Not Detected at the Reporting Limit

O Sample amount is > 4 times amount spiked

P Dual Column results percent difference > 40%

R RPD above laboratory control limit

S Spike Recovery outside laboratory control limits

U Analyzed but not detected above the MDL/SDL

Acronym DescriptionDCS Detectability Check Study

DUP Method Duplicate

LCS Laboratory Control Sample

LCSD Laboratory Control Sample Duplicate

MBLK Method Blank

MDL Method Detection Limit

MQL Method Quantitation Limit

MS Matrix Spike

MSD Matrix Spike Duplicate

PDS Post Digestion Spike

PQL Practical Quantitaion Limit

SD Serial Dilution

SDL Sample Detection Limit

TRRP Texas Risk Reduction Program

ALS Group Houston, Corp Date: 09-Aug-18

Page 7 of 88

00912968

CERTIFICATIONS,ACCREDITATIONS & LICENSES

Agency Number Expire Date

Oklahoma 2017-088 31-Aug-2018

North Carolina 624-2018 31-Dec-2018

Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019

North Dakota R193 2018-2019 30-Apr-2019

Illinois 004438 29-Jun-2019

Louisiana 03087 30-Jun-2019

Dept of Defense L2231 Rev 3-30-2018 22-Dec-2018

Kentucky 123043 - 2018 30-Apr-2019


Page 8 of 88

00912969

o

f 88

00912970

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8

00912971

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8

00912972

Case Narrative Method: 6850 Analysis: Perchlorate Analysis SOP: LC-MS-CLO4 ALS WO ID(s): 1820868; 1821923

Client: ALS Laboratories (Houston, TX) Matrix: Water ELMS Batch (HBN): 2125 (220447)

General Set Information: There were two field samples in these Work Orders. The samples were analyzed for perchlorate. Method Summary: Each sample was prepared as noted below and analyzed using an Agilent 1100 LC/MSD system in select ion monitoring (SIM) mode at m/z 83 and 85, which corresponds to the loss of one oxygen atom from the perchlorate molecule. ChemStation software was used for instrument control and data analysis. The ion ratio of m/z 83 to 85 was used to positively identify the response peak as perchlorate. Quantitation was performed using the m/z 83 peak area. An internal standard (ISTD) of 18O labeled perchlorate was added to each sample to establish the perchlorate peak retention time and used in quantitation. Sample Preparation: A 10.0mL aliquot of each sample was transferred into a 15-mL centrifuge tube. 50µL of an 18O labeled perchlorate solution was added to each sample as an internal standard. The samples were then capped, vortexed, and filtered into autosampler vial using Phenex PES membrane 0.45µm Syringe filters. Holding Times: Holding times were met for all analyses. Dilutions: NA Method QC data: The method blank (LMB 613553) was less than 1/2 the CRDL. The recovery for the LCS (613554) was within acceptable parameters.

Page 12 of 88

00912973

MS/MSD Analysis: The matrix spike and matrix spike duplicate (MS/MSD) was performed on sample 1820868001 (Client ID: LH18/24-SP650_072618). The MS/MSD percent recoveries and relative percent difference (RPD) were within the performance limits. Instrument QC: Instrument initial and continuing calibrations were performed in accordance with published procedures. NC/CAR(s): NA Sample Calculation: Samples were reported in µg/L. Results were calculated in µg/L by the equation (A)x(B),

where: A = Analyte concentration from the standard curve (µg/L) B = Dilution performed at time of analysis Miscellaneous Comments: These samples were analyzed in accordance with the requirements found in the DOD QSM Version 5.1. Due to limitations of the Chemstation Software, some of the chromatographic peaks require manual integration. A manual integration was performed for datafile 07AUGD03.

Thomas Bosch August 08, 2018 Analyst Date

Page 13 of 88

00912974

ANALYTICAL REPORT

RJ ModashiaALS Environmental (Houston)10450 Stancliff RoadSuite 210Houston, TX 77099

Phone:

E-mail:

281 530-5656

[email protected]

Report Date: August 08, 2018

34-1820868Workorder:

BHATE 072618NWO1312.0150.0.16001Purchase Order:

Project ID:

Project Manager Kevin W. Griffiths

Sampling SiteReceive DateCollect DateLab IDClient Sample ID

1820868001 07/26/18LH18/24-SP650_072618 07/27/18 BHATE

Page 1 of 3 Wed, 08/08/18 4:52 PM ENVREP-V4.8

ADDRESS 960 West LeVoy Drive, Salt Lake City, Utah, 84123 USA PHONE FAX+1 801 266 7700 +1 801 268 9992

ALS GROUP USA, CORP. An ALS Limited Company

||

Page 14 of 88

00912975

ANALYTICAL REPORT

Project Manager: Kevin W. Griffiths

Client: ALS Environmental(Houston)

Workorder: 34-1820868

Analytical Results

Sample ID: 07/26/201807/27/20181820868001Lab ID:

Collected:Received:

LH18/24-SP650_072618 BHATE

Sampling Parameter: NAMatrix:

Media:

Water

125 mL NalgeneSampling Site:

Analysis: EPA 6850, DoD QSM Water

Analyzed: 08/07/2018 10:32Batch:

Instrument ID:ELMS/2125 (HBN: 220447) Percent Solid: NA

LCMS04

Report Basis: Wet

Preparation: Not Applicable

Result (ug/L)Analyte DL (ug/L) LOD (ug/L) QualLOQ (ug/L) Dilution

Analysis Method - EPA 6850, DoD QSM

4.01.0ND 2.0 UPerchlorate 1

Report Authorization

Analyst Peer ReviewMethod

(/S/ is an electronic signature that complies with 21 CFR Part 11)

EPA 6850, DoD QSM /S/ Thomas Bosch08/07/2018 12:48 08/08/2018 16:35

/S/ Stephen Brose

Laboratory Contact Information(801) [email protected]

ALS Environmental960 W Levoy DriveSalt Lake City, Utah 84123

Phone:Email:Web:


Page 15 of 88

00912976

ANALYTICAL REPORT




The results provided in this report relate only to the items tested.Samples were received in acceptable condition unless otherwise noted.Samples have not been blank corrected unless otherwise noted.This test report shall not be reproduced, except in full, without written approval of ALS.

General Lab Comments

ALS provides professional analytical services for all samples submitted. ALS is not in a position to interpret the data andassumes no responsibility for the quality of the samples submitted.

All quality control samples processed with the samples in this report yielded acceptable results unless otherwise noted.

ALS is accredited for specific fields of testing (scopes) in the following testing sectors. The quality system implemented at ALSconforms to accreditation requirements and is applied to all analytical testing performed by ALS. The following table lists testingsector, accreditation body, accreditation number and website. Please contact these accrediting bodies or your ALS projectmanager for the current scope of accreditation that applies to your analytical testing.

Testing Sector Accreditation Body Certificate Number

Website

Environmental PJLA (DoD ELAP)

Utah (TNI)NevadaOklahomaIowa

MDL = Method Detection Limit, a statistical estimate of method/media/instrument sensitivity.RL = Reporting Limit, a verified value of method/media/instrument sensitivity.CRDL = Contract Required Detection LimitReg. Limit = Regulatory Limit.ND = Not Detected, testing result not detected above the MDL or RL.< This testing result is less than the numerical value.** No result could be reported, see sample comments for details.

U = Qualifier indicates that the analyte was not detected above the MDL.J = Qualifier Indicates that the analyte value is between the MDL and the RL. It is also used to indicate an estimated value fortentatively identified compounds in mass spectrometry where a 1:1 response is assumed.B = Qualifier indicates that the analyte was detected in the blank.E = Qualifier indicates that the analyte result exceeds calibration range.P = Qualifier indicates that the RPD between the two columns is greater than 40%.

Result Symbol Definitions

Qualifier Symbol Definitions


Page 16 of 88

00912977

Analysis:


Workorder: 1820868




Limits:Basis:


Blank

LMB:

Analyte

Units:

Result

Analyzed:61355308/07/2018 10:02

ug/L

MDL RL

Perchlorate 1 2.00ND

Laboratory Control Sample

Dilution: 1ug/L

Analyte Result % Rec QC Limits

LCS:Analyzed:

61355408/07/2018 10:16

Units:

Target

Perchlorate 5.20 5.00 78.8 123.8104

Matrix Spike - Matrix Spike Duplicate

MS:Analyzed:

Dilution:Units: ug/L

108/07/2018 10:49613555Sample:

Analyzed:Dilution:

Units: ug/L108/07/2018 10:321820868001

Result RPD QC Limits

MSD:Analyzed:

61355608/07/2018 11:03

% Rec

Units: ug/LDilution: 1

Analyte Result Result % RecTarget QC Limits

Perchlorate ND 78.8 123.85 96.94.84 20.00.05.04 3.87101

Continuing Calibration Verification

Analyte Result % Rec.

CCV:Analyzed:

61355008/07/2018 09:17

Units:

Target

ug/LCriteria: ± 15%

Result % Rec.

CCV:Analyzed:

61355708/07/2018 11:33

Units:

Target


Perchlorate 26.5 25.0 106 25.7 25.0 103

Interference Check Sample


ICSA:Analyzed:

61355208/07/2018 09:47

Units:

Target


Perchlorate 0.911 1.00 91.1

Limit of Detection Verification


LODV:Analyzed:

61355108/07/2018 09:33

Units:

Target


Result % Rec.

LODV:Analyzed:

61355808/07/2018 11:47

Units:

Target


Perchlorate 1.10 1.00 110 1.24 1.00 124

Page 1 of 2 Wednesday, August 08, 2018


QCS V4.4

Page 17 of 88

00912978

Analysis:


Workorder: 1820868




Limits:Basis:







# -

Analyst Peer Review


08/07/2018 12:48 08/08/2018 16:35



QCS V4.4

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July 31, 2018





Sincerely,



Dear Marcia,


Project Manager


RJ Modashia



1 of 13

00913050





ALS Group Houston, Corp 31-Jul-18Date:

2 of 13

00913051



Project:

Work Order Comments


WetChemistry by Method E365.3

Batch ID: R320807

The test results meet requirements of the current NELAP standards, state requirements or programs where applicable.•


Batch ID: R320787



Batch ID: R320700


ALS Group Houston, Corp 31-Jul-18Date:

3 of 13

00913052



WorkOrder:Lab ID:

Collection Date:

HS18071386HS18071386-01


ANALYTICAL REPORT



AMMONIA AS N BY E350.3(ISE) Method:E350.3 Analyst: MZD1mg/L 31-Jul-2018 10:350.20Nitrogen, Ammonia (As N) 0.2010 0.20

ORTHO PHOSPHATE (PO4) AS P BY E365.3

Method:E365.3 Analyst: MZD

10mg/L 27-Jul-2018 18:450.100Phosphorus, Total Orthophosphate (As P)

0.2502.88 0.250

TOTAL ORGANIC CARBON BY E415.1 Method:E415.1 Analyst: AJH1mg/L 29-Jul-2018 10:580.500Organic Carbon, Total 1.0026.9 0.600

31-Jul-18Date: ALS Group Houston, Corp


4 of 13

00913053


WorkOrder:Project:



Batch ID R320700 Test Name : TOTAL ORGANIC CARBON BY E415.1 Matrix: Water

29 Jul 2018 10:58HS18071386-01 26 Jul 2018 13:00 1LH18/24-SP650_072618

Batch ID R320787 Test Name : AMMONIA AS N BY E350.3(ISE) Matrix: Water

31 Jul 2018 10:35HS18071386-01 26 Jul 2018 13:00 1LH18/24-SP650_072618

Batch ID R320807 Test Name : ORTHO PHOSPHATE (PO4) AS P BY E365.3 Matrix: Water

27 Jul 2018 18:45HS18071386-01 26 Jul 2018 13:00 10LH18/24-SP650_072618


5 of 13

00913054

Client:Project:

Bhate Environmental Associates, Inc.Longhorn GW Treatment Plant

WorkOrder: HS18071386

QC BATCH REPORT

Batch ID: R320700 Instrument: TOC_02 Method: E415.1

Sample ID: WBLKW4-180728 Units: mg/L Analysis Date: 29-Jul-2018 07:43

Run ID: TOC_02_320700 SeqNo: 4670445 PrepDate: DF: 1

Analyte SPK ValPQLResultSPK Ref

Value %RECControl

LimitRPD Ref

Value %RPDRPD Limit Qual

MBLK

Client ID:

Organic Carbon, Total 0.600 U1.00

Sample ID: WLCSW4-180728 Units: mg/L Analysis Date: 29-Jul-2018 07:59



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Organic Carbon, Total 10.38 10 0 104 80 - 1201.00

Sample ID: WLCSDW4-180728 Units: mg/L Analysis Date: 29-Jul-2018 08:12



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Organic Carbon, Total 10.33 10 0 103 80 - 120 10.38 0.483 201.00

Sample ID: HS18071297-01MS Units: mg/L Analysis Date: 29-Jul-2018 10:45



Value %RECControl

LimitRPD Ref


MS

Client ID:

Organic Carbon, Total 23.36 10 12.47 109 80 - 1201.00

The following samples were analyzed in this batch: HS18071386-01

ALS Group Houston, Corp Date: 31-Jul-18


6 of 13

00913055

Client:Project:



QC BATCH REPORT

Batch ID: R320787 Instrument: WetChem_HS Method: E350.3

Sample ID: MBLK-320787 Units: mg/L Analysis Date: 31-Jul-2018 10:35

Run ID: WetChem_HS_320787 SeqNo: 4672313 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Nitrogen, Ammonia (As N) 0.20 U0.20

Sample ID: LCS-320787 Units: mg/L Analysis Date: 31-Jul-2018 10:35



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Nitrogen, Ammonia (As N) 10.09 10 0 101 80 - 1200.20




Value %RECControl

LimitRPD Ref


MS

Client ID:

Nitrogen, Ammonia (As N) 12.11 10 3.224 88.9 80 - 1200.20

Sample ID: HS18071385-01MSD Units: mg/L Analysis Date: 31-Jul-2018 10:35



Value %RECControl

LimitRPD Ref


MSD

Client ID:

Nitrogen, Ammonia (As N) 12.15 10 3.224 89.3 80 - 120 12.11 0.33 200.20




7 of 13

00913056

Client:Project:



QC BATCH REPORT

Batch ID: R320807 Instrument: UV-2450 Method: E365.3

Sample ID: MBLK-320807 Units: mg/L Analysis Date: 27-Jul-2018 18:45

Run ID: UV-2450_320807 SeqNo: 4672676 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Phosphorus, Total Orthophosphate (As P)

0.0250 U0.0250

Sample ID: LCS-320807 Units: mg/L Analysis Date: 27-Jul-2018 18:45



Value %RECControl

LimitRPD Ref


LCS

Client ID:


0.223 0.25 0 89.2 85 - 1150.0250




Value %RECControl

LimitRPD Ref


MS

Client ID: LH18/24-SP650_072618


5.17 2.5 2.88 91.6 80 - 1200.250




Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18/24-SP650_072618


5.17 2.5 2.88 91.6 80 - 120 5.17 0 200.250




8 of 13

00913057





a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution




9 of 13

00913058



Oklahoma 2017-088 31-Aug-2018


Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019


10 of 13

00913059

RPG

27-Jul-2018 08:35Date/Time Received:

HS18071386

Bhate Environmental

Work Order:

Client Name:

Sample Receipt Checklist

Received by:

Shipping container/cooler in good condition?

Custody seals intact on shipping container/cooler?

Custody seals intact on sample bottles?

Chain of custody present?

Chain of custody signed when relinquished and received?

Chain of custody agrees with sample labels?

Samples in proper container/bottle?

Sample containers intact?

Sufficient sample volume for indicated test?

All samples received within holding time?

Container/Temp Blank temperature in compliance?

Temperature(s)/Thermometer(s):

Cooler(s)/Kit(s):

Date/Time sample(s) sent to storage:

Water - VOA vials have zero headspace?

Water - pH acceptable upon receipt?

pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

2.6c/2.2c U/c IR11441297/27/18 16:50

Yes No No VOA vials submitted

Yes No N/A

Yes No N/A

Checklist completed by: Paresh M. GigaDateeSignatureDateeSignature

30-Jul-201827-Jul-2018

FedExWater Carrier name:Matrices:

Reviewed by: Erica Howard

Client Contacted: Date Contacted: Person Contacted:

Contacted By: Regarding:

Comments:

Corrective Action:

Yes

NoYesTX1005 solids received in hermetically sealed vials? N/A

31-Jul-18Date:

11 of 13

00913060

12 o

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00913061

13 o

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00913062

August 01, 2018





Sincerely,



Dear Marcia,


Project Manager


RJ Modashia



1 of 23

00913063





HS18071388-02 26-Jul-2018 00:00ALS-060618-53

27-Jul-2018 08:35Trip Blank Water


2 of 23

00913064



Project:HS18071388

GCMS Volatiles by Method SW8260

Batch ID: R320892


WetChemistry by Method SW9056

Batch ID: R320826



3 of 23

00913065



WorkOrder:Lab ID:

Collection Date:

HS18071388HS18071388-01


ANALYTICAL REPORT



VOLATILES ORGANICS BY METHOD 8260C

Method:SW8260 Analyst: AKP

1ug/L 31-Jul-2018 23:03U 0.301,1,1,2-Tetrachloroethane 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.201,1,1-Trichloroethane 1.00.50 0.50



1ug/L 31-Jul-2018 23:03U 0.201,1-Dichloroethane 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.201,1-Dichloroethene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.301,1-Dichloropropene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.401,2,3-Trichlorobenzene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.501,2,3-Trichloropropane 1.00.50 0.50


1ug/L 31-Jul-2018 23:03U 0.301,2,4-Trimethylbenzene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.201,2-Dibromo-3-chloropropane 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.201,2-Dibromoethane 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.501,2-Dichlorobenzene 1.00.50 0.50


1ug/L 31-Jul-2018 23:03U 0.501,2-Dichloropropane 1.00.50 0.50






1ug/L 31-Jul-2018 23:03U 0.502-Butanone 2.01.0 1.0

1ug/L 31-Jul-2018 23:03U 0.302-Chlorotoluene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 1.02-Hexanone 2.01.0 1.0


1ug/L 31-Jul-2018 23:03U 0.304-Isopropyltoluene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.704-Methyl-2-pentanone 2.01.0 1.0

1ug/L 31-Jul-2018 23:03U 0.40Acetone 2.02.0 2.0

1ug/L 31-Jul-2018 23:03U 0.20Benzene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.40Bromobenzene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.20Bromochloromethane 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.20Bromodichloromethane 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.40Bromoform 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.40Bromomethane 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.60Carbon disulfide 2.01.0 1.0

1ug/L 31-Jul-2018 23:03U 0.50Carbon tetrachloride 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.30Chlorobenzene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.30Chloroethane 1.00.50 0.50



4 of 23

00913066



WorkOrder:Lab ID:

Collection Date:

HS18071388HS18071388-01


ANALYTICAL REPORT





1ug/L 31-Jul-2018 23:03U 0.20Chloroform 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.20Chloromethane 1.00.50 0.50

1ug/L 31-Jul-2018 23:030.20cis-1,2-Dichloroethene 1.03.8 0.501ug/L 31-Jul-2018 23:03U 0.10cis-1,3-Dichloropropene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.30Dibromochloromethane 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.20Dibromomethane 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.30Dichlorodifluoromethane 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.30Ethylbenzene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 1.0Hexachlorobutadiene 1.01.0 1.0

1ug/L 31-Jul-2018 23:03U 0.30Isopropylbenzene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.50m,p-Xylene 2.01.0 1.0

1ug/L 31-Jul-2018 23:03U 0.40Methylene chloride 2.01.0 1.0

1ug/L 31-Jul-2018 23:03U 0.40n-Butylbenzene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.30n-Propylbenzene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.30Naphthalene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.30o-Xylene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.30sec-Butylbenzene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.30Styrene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.30tert-Butylbenzene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.30Tetrachloroethene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.20Toluene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.20trans-1,2-Dichloroethene 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.20trans-1,3-Dichloropropene 1.00.50 0.50

1ug/L 31-Jul-2018 23:030.20Trichloroethene 1.01.9 0.501ug/L 31-Jul-2018 23:03U 0.30Trichlorofluoromethane 1.00.50 0.50

1ug/L 31-Jul-2018 23:03U 0.20Vinyl chloride 1.00.50 0.50

Surr: 1,2-Dichloroethane-d4 1%REC 31-Jul-2018 23:0381.4 81-1180Surr: 4-Bromofluorobenzene 1%REC 31-Jul-2018 23:0398.2 85-1140Surr: Dibromofluoromethane 1%REC 31-Jul-2018 23:0398.8 80-1190Surr: Toluene-d8 1%REC 31-Jul-2018 23:03104 89-1120

ANIONS BY SW9056A Method:SW9056 Analyst: KMU10mg/L 31-Jul-2018 07:562.00Chloride 5.00659 5.0010mg/L 31-Jul-2018 07:562.00Sulfate 5.0025.9 5.00



5 of 23

00913067


Bhate Environmental Associates, Inc.Longhorn GW Treatment PlantTrip Blank

WorkOrder:Lab ID:

Collection Date:

HS18071388HS18071388-02


ANALYTICAL REPORT










1ug/L 31-Jul-2018 22:11U 0.201,1-Dichloroethene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.301,1-Dichloropropene 1.00.50 0.50


1ug/L 31-Jul-2018 22:11U 0.501,2,3-Trichloropropane 1.00.50 0.50



1ug/L 31-Jul-2018 22:11U 0.201,2-Dibromo-3-chloropropane 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.201,2-Dibromoethane 1.00.50 0.50









1ug/L 31-Jul-2018 22:11U 0.502-Butanone 2.01.0 1.0


1ug/L 31-Jul-2018 22:11U 1.02-Hexanone 2.01.0 1.0


1ug/L 31-Jul-2018 22:11U 0.304-Isopropyltoluene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.704-Methyl-2-pentanone 2.01.0 1.0

1ug/L 31-Jul-2018 22:11U 0.40Acetone 2.02.0 2.0

1ug/L 31-Jul-2018 22:11U 0.20Benzene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.40Bromobenzene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.20Bromochloromethane 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.20Bromodichloromethane 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.40Bromoform 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.40Bromomethane 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.60Carbon disulfide 2.01.0 1.0

1ug/L 31-Jul-2018 22:11U 0.50Carbon tetrachloride 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.30Chlorobenzene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.30Chloroethane 1.00.50 0.50



6 of 23

00913068



WorkOrder:Lab ID:

Collection Date:

HS18071388HS18071388-02


ANALYTICAL REPORT





1ug/L 31-Jul-2018 22:11U 0.20Chloroform 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.20Chloromethane 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.20cis-1,2-Dichloroethene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.10cis-1,3-Dichloropropene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.30Dibromochloromethane 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.20Dibromomethane 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.30Dichlorodifluoromethane 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.30Ethylbenzene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 1.0Hexachlorobutadiene 1.01.0 1.0

1ug/L 31-Jul-2018 22:11U 0.30Isopropylbenzene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.50m,p-Xylene 2.01.0 1.0

1ug/L 31-Jul-2018 22:11U 0.40Methylene chloride 2.01.0 1.0

1ug/L 31-Jul-2018 22:11U 0.40n-Butylbenzene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.30n-Propylbenzene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.30Naphthalene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.30o-Xylene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.30sec-Butylbenzene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.30Styrene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.30tert-Butylbenzene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.30Tetrachloroethene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.20Toluene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.20trans-1,2-Dichloroethene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.20trans-1,3-Dichloropropene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.20Trichloroethene 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.30Trichlorofluoromethane 1.00.50 0.50

1ug/L 31-Jul-2018 22:11U 0.20Vinyl chloride 1.00.50 0.50

Surr: 1,2-Dichloroethane-d4 1%REC 31-Jul-2018 22:1183.1 81-1180Surr: 4-Bromofluorobenzene 1%REC 31-Jul-2018 22:1196.4 85-1140Surr: Dibromofluoromethane 1%REC 31-Jul-2018 22:1197.8 80-1190Surr: Toluene-d8 1%REC 31-Jul-2018 22:11105 89-1120



7 of 23

00913069


WorkOrder:Project:



Batch ID R320826 Test Name : ANIONS BY SW9056A Matrix: Water

31 Jul 2018 07:56HS18071388-01 26 Jul 2018 13:00 10LH18/24-SP650_072618

Batch ID R320892 Test Name : VOLATILES ORGANICS BY METHOD 8260C Matrix: Water

31 Jul 2018 23:03HS18071388-01 26 Jul 2018 13:00 1LH18/24-SP650_072618

31 Jul 2018 22:11HS18071388-02 26 Jul 2018 00:00 1Trip Blank


8 of 23

00913070

Client:Project:



QC BATCH REPORT

Batch ID: R320892 Instrument: VOA2 Method: SW8260

Sample ID: VBLKW-180731 Units: ug/L Analysis Date: 31-Jul-2018 14:22

Run ID: VOA2_320892 SeqNo: 4674299 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

1,1,1,2-Tetrachloroethane 0.50 U1.0

1,1,1-Trichloroethane 0.50 U1.0



1,1-Dichloroethane 0.50 U1.0

1,1-Dichloroethene 0.50 U1.0

1,1-Dichloropropene 0.50 U1.0

1,2,3-Trichlorobenzene 0.50 U1.0

1,2,3-Trichloropropane 0.50 U1.0


1,2,4-Trimethylbenzene 0.50 U1.0

1,2-Dibromo-3-chloropropane 0.50 U1.0

1,2-Dibromoethane 0.50 U1.0

1,2-Dichlorobenzene 0.50 U1.0


1,2-Dichloropropane 0.50 U1.0






2-Butanone 1.0 U2.0

2-Chlorotoluene 0.50 U1.0

2-Hexanone 1.0 U2.0


4-Isopropyltoluene 0.50 U1.0

4-Methyl-2-pentanone 1.0 U2.0

Acetone 2.0 U2.0

Benzene 0.50 U1.0

Bromobenzene 0.50 U1.0

Bromochloromethane 0.50 U1.0

Bromodichloromethane 0.50 U1.0

Bromoform 0.50 U1.0

Bromomethane 0.50 U1.0



9 of 23

00913071

Client:Project:



QC BATCH REPORT


Sample ID: VBLKW-180731 Units: ug/L Analysis Date: 31-Jul-2018 14:22



Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Carbon disulfide 1.0 U2.0

Carbon tetrachloride 0.50 U1.0

Chlorobenzene 0.50 U1.0

Chloroethane 0.50 U1.0

Chloroform 0.50 U1.0

Chloromethane 0.50 U1.0

cis-1,2-Dichloroethene 0.50 U1.0

cis-1,3-Dichloropropene 0.50 U1.0

Dibromochloromethane 0.50 U1.0

Dibromomethane 0.50 U1.0

Dichlorodifluoromethane 0.50 U1.0

Ethylbenzene 0.50 U1.0

Hexachlorobutadiene 1.0 U1.0

Isopropylbenzene 0.50 U1.0

m,p-Xylene 1.0 U2.0

Methylene chloride 1.0 U2.0

Naphthalene 0.50 U1.0

n-Butylbenzene 0.50 U1.0

n-Propylbenzene 0.50 U1.0

o-Xylene 0.50 U1.0

sec-Butylbenzene 0.50 U1.0

Styrene 0.50 U1.0

tert-Butylbenzene 0.50 U1.0

Tetrachloroethene 0.50 U1.0

Toluene 0.50 U1.0

trans-1,2-Dichloroethene 0.50 U1.0

trans-1,3-Dichloropropene 0.50 U1.0

Trichloroethene 0.50 U1.0

Trichlorofluoromethane 0.50 U1.0

Vinyl chloride 0.50 U1.0

40.63 50 0 81.3 81 - 1181.0Surr: 1,2-Dichloroethane-d4

48.42 50 0 96.8 85 - 1141.0Surr: 4-Bromofluorobenzene

48.98 50 0 98.0 80 - 1191.0Surr: Dibromofluoromethane

52.4 50 0 105 89 - 1121.0Surr: Toluene-d8



10 of 23

00913072

Client:Project:



QC BATCH REPORT


Sample ID: VLCSW-180731 Units: ug/L Analysis Date: 31-Jul-2018 13:30



Value %RECControl

LimitRPD Ref


LCS

Client ID:

1,1,1,2-Tetrachloroethane 47.57 50 0 95.1 78 - 1241.0

1,1,1-Trichloroethane 45.05 50 0 90.1 74 - 1311.0



1,1-Dichloroethane 44.5 50 0 89.0 77 - 1251.0

1,1-Dichloroethene 47.1 50 0 94.2 71 - 1311.0

1,1-Dichloropropene 42.57 50 0 85.1 78 - 1251.0

1,2,3-Trichlorobenzene 46.25 50 0 92.5 69 - 1291.0

1,2,3-Trichloropropane 44.68 50 0 89.4 73 - 1221.0


1,2,4-Trimethylbenzene 42.27 50 0 84.5 76 - 1241.0

1,2-Dibromo-3-chloropropane 43.7 50 0 87.4 62 - 1281.0

1,2-Dibromoethane 49.49 50 0 99.0 77 - 1211.0

1,2-Dichlorobenzene 44.85 50 0 89.7 80 - 1191.0

1,2-Dichloroethane 48.21 50 0 96.4 73 - 1281.0

1,2-Dichloropropane 44.82 50 0 89.6 78 - 1221.0

1,3,5-Trimethylbenzene 51.71 50 0 103 75 - 1241.0





2-Butanone 92.06 100 0 92.1 56 - 1432.0

2-Chlorotoluene 50.05 50 0 100 79 - 1221.0

2-Hexanone 90.44 100 0 90.4 57 - 1392.0

4-Chlorotoluene 50.31 50 0 101 78 - 1221.0

4-Isopropyltoluene 44.73 50 0 89.5 77 - 1271.0

4-Methyl-2-pentanone 89.53 100 0 89.5 67 - 1302.0

Acetone 87.49 100 0 87.5 39 - 1602.0

Benzene 44.99 50 0 90.0 79 - 1201.0

Bromobenzene 44.43 50 0 88.9 80 - 1201.0

Bromochloromethane 49.64 50 0 99.3 78 - 1231.0

Bromodichloromethane 47.04 50 0 94.1 79 - 1251.0

Bromoform 49.17 50 0 98.3 66 - 1301.0

Bromomethane 52.57 50 0 105 53 - 1411.0



11 of 23

00913073

Client:Project:



QC BATCH REPORT


Sample ID: VLCSW-180731 Units: ug/L Analysis Date: 31-Jul-2018 13:30



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Carbon disulfide 86.82 100 0 86.8 64 - 1332.0

Carbon tetrachloride 50.97 50 0 102 72 - 1361.0

Chlorobenzene 45.86 50 0 91.7 82 - 1181.0

Chloroethane 49.85 50 0 99.7 60 - 1381.0

Chloroform 44.66 50 0 89.3 79 - 1241.0

Chloromethane 42.78 50 0 85.6 50 - 1391.0

cis-1,2-Dichloroethene 46.15 50 0 92.3 78 - 1231.0

cis-1,3-Dichloropropene 48.78 50 0 97.6 75 - 1241.0

Dibromochloromethane 47.66 50 0 95.3 74 - 1261.0

Dibromomethane 50.49 50 0 101 79 - 1231.0

Dichlorodifluoromethane 48.19 50 0 96.4 32 - 1521.0

Ethylbenzene 44.8 50 0 89.6 79 - 1211.0

Hexachlorobutadiene 47.2 50 0 94.4 66 - 1341.0

Isopropylbenzene 46.81 50 0 93.6 72 - 1311.0

m,p-Xylene 88.27 100 0 88.3 80 - 1212.0

Methylene chloride 43.99 50 0 88.0 74 - 1242.0

Naphthalene 47.13 50 0 94.3 61 - 1281.0

n-Butylbenzene 47.61 50 0 95.2 75 - 1281.0

n-Propylbenzene 51.26 50 0 103 76 - 1261.0

o-Xylene 45.18 50 0 90.4 78 - 1221.0

sec-Butylbenzene 44.76 50 0 89.5 77 - 1261.0

Styrene 47.23 50 0 94.5 78 - 1231.0

tert-Butylbenzene 51.53 50 0 103 78 - 1241.0

Tetrachloroethene 45.81 50 0 91.6 74 - 1291.0

Toluene 43.59 50 0 87.2 80 - 1211.0

trans-1,2-Dichloroethene 45.08 50 0 90.2 75 - 1241.0

trans-1,3-Dichloropropene 51.8 50 0 104 73 - 1271.0

Trichloroethene 48.08 50 0 96.2 79 - 1231.0

Trichlorofluoromethane 48.33 50 0 96.7 65 - 1411.0

Vinyl chloride 45.22 50 0 90.4 58 - 1371.0


50.96 50 0 102 85 - 1141.0Surr: 4-Bromofluorobenzene


50.22 50 0 100 89 - 1121.0Surr: Toluene-d8



12 of 23

00913074

Client:Project:



QC BATCH REPORT


Sample ID: HS18071456-01MS Units: ug/L Analysis Date: 31-Jul-2018 15:40



Value %RECControl

LimitRPD Ref


MS

Client ID:





1,1-Dichloroethane 45.01 50 0 90.0 77 - 1251.0

1,1-Dichloroethene 49.07 50 0 98.1 71 - 1311.0







1,2-Dibromoethane 45.95 50 0 91.9 77 - 1211.0


1,2-Dichloroethane 45.92 50 0 91.8 73 - 1281.0


1,3,5-Trimethylbenzene 52 50 0 104 75 - 1241.0





2-Butanone 84.38 100 0 84.4 56 - 1432.0

2-Chlorotoluene 49.9 50 0 99.8 79 - 1221.0

2-Hexanone 83.17 100 0 83.2 57 - 1392.0

4-Chlorotoluene 49.13 50 0 98.3 78 - 1221.0



Acetone 84.12 100 0 84.1 39 - 1602.0

Benzene 45.08 50 0 90.2 79 - 1201.0

Bromobenzene 43.32 50 0 86.6 80 - 1201.0



Bromoform 46.55 50 0 93.1 66 - 1301.0

Bromomethane 51.77 50 0 104 53 - 1411.0



13 of 23

00913075

Client:Project:



QC BATCH REPORT


Sample ID: HS18071456-01MS Units: ug/L Analysis Date: 31-Jul-2018 15:40



Value %RECControl

LimitRPD Ref


MS

Client ID:



Chlorobenzene 44.99 50 0 90.0 82 - 1181.0

Chloroethane 51.54 50 0 103 60 - 1381.0

Chloroform 43.64 50 0 87.3 79 - 1241.0

Chloromethane 42.56 50 0 85.1 50 - 1391.0




Dibromomethane 48.34 50 0 96.7 79 - 1231.0


Ethylbenzene 45.75 50 0 91.5 79 - 1211.0



m,p-Xylene 88.38 100 0 88.4 80 - 1212.0


Naphthalene 42.16 50 0 84.3 61 - 1281.0

n-Butylbenzene 48.09 50 0 96.2 75 - 1281.0

n-Propylbenzene 52.03 50 0 104 76 - 1261.0

o-Xylene 44.98 50 0 90.0 78 - 1221.0


Styrene 45.82 50 0 91.6 78 - 1231.0



Toluene 44.05 50 0 88.1 80 - 1211.0


trans-1,3-Dichloropropene 48.76 50 0 97.5 73 - 1271.0


Trichlorofluoromethane 51.79 50 0 104 65 - 1411.0

Vinyl chloride 45.78 50 0 91.6 58 - 1371.0




50.24 50 0 100 89 - 1121.0Surr: Toluene-d8



14 of 23

00913076

Client:Project:



QC BATCH REPORT


Sample ID: HS18071456-01MSD Units: ug/L Analysis Date: 31-Jul-2018 16:07



Value %RECControl

LimitRPD Ref


MSD

Client ID:

1,1,1,2-Tetrachloroethane 46.17 50 0 92.3 78 - 124 47.18 2.18 201.0

1,1,1-Trichloroethane 45.53 50 0 91.1 74 - 131 46.93 3.04 201.0



1,1-Dichloroethane 43.72 50 0 87.4 77 - 125 45.01 2.91 201.0

1,1-Dichloroethene 47.89 50 0 95.8 71 - 131 49.07 2.44 201.0

1,1-Dichloropropene 44.33 50 0 88.7 78 - 125 45.32 2.22 201.0

1,2,3-Trichlorobenzene 41.76 50 0 83.5 69 - 129 43.28 3.57 201.0

1,2,3-Trichloropropane 40.24 50 0 80.5 73 - 122 39.83 1.04 201.0


1,2,4-Trimethylbenzene 41.32 50 0 82.6 76 - 124 41.84 1.25 201.0

1,2-Dibromo-3-chloropropane 38.11 50 0 76.2 62 - 128 39.76 4.23 201.0

1,2-Dibromoethane 45.19 50 0 90.4 77 - 121 45.95 1.66 201.0

1,2-Dichlorobenzene 42.56 50 0 85.1 80 - 119 42.98 0.98 201.0

1,2-Dichloroethane 46.08 50 0 92.2 73 - 128 45.92 0.36 201.0

1,2-Dichloropropane 43.1 50 0 86.2 78 - 122 43.83 1.66 201.0

1,3,5-Trimethylbenzene 51.06 50 0 102 75 - 124 52 1.82 201.0





2-Butanone 82.47 100 0 82.5 56 - 143 84.38 2.29 202.0

2-Chlorotoluene 48.7 50 0 97.4 79 - 122 49.9 2.44 201.0

2-Hexanone 81.79 100 0 81.8 57 - 139 83.17 1.67 202.0

4-Chlorotoluene 47.64 50 0 95.3 78 - 122 49.13 3.09 201.0

4-Isopropyltoluene 44.32 50 0 88.6 77 - 127 45.15 1.85 201.0

4-Methyl-2-pentanone 82.41 100 0 82.4 67 - 130 82.02 0.468 202.0

Acetone 80.67 100 0 80.7 39 - 160 84.12 4.19 202.0

Benzene 43.9 50 0 87.8 79 - 120 45.08 2.65 201.0

Bromobenzene 42.58 50 0 85.2 80 - 120 43.32 1.73 201.0

Bromochloromethane 46.85 50 0 93.7 78 - 123 47.77 1.94 201.0

Bromodichloromethane 45.5 50 0 91.0 79 - 125 46.4 1.95 201.0

Bromoform 46.01 50 0 92.0 66 - 130 46.55 1.16 201.0

Bromomethane 47.93 50 0 95.9 53 - 141 51.77 7.7 201.0



15 of 23

00913077

Client:Project:



QC BATCH REPORT


Sample ID: HS18071456-01MSD Units: ug/L Analysis Date: 31-Jul-2018 16:07



Value %RECControl

LimitRPD Ref


MSD

Client ID:

Carbon disulfide 86.77 100 0 86.8 64 - 133 89.44 3.03 202.0

Carbon tetrachloride 52.33 50 0 105 72 - 136 54.35 3.79 201.0

Chlorobenzene 44.33 50 0 88.7 82 - 118 44.99 1.49 201.0

Chloroethane 48.08 50 0 96.2 60 - 138 51.54 6.94 201.0

Chloroform 43.29 50 0 86.6 79 - 124 43.64 0.82 201.0

Chloromethane 41.87 50 0 83.7 50 - 139 42.56 1.63 201.0

cis-1,2-Dichloroethene 44.88 50 0 89.8 78 - 123 44.56 0.736 201.0

cis-1,3-Dichloropropene 46.09 50 0 92.2 75 - 124 47.24 2.48 201.0

Dibromochloromethane 46.02 50 0 92.0 74 - 126 46.03 0.0114 201.0

Dibromomethane 47.93 50 0 95.9 79 - 123 48.34 0.866 201.0

Dichlorodifluoromethane 37.81 50 0 75.6 32 - 152 41.28 8.77 201.0

Ethylbenzene 44.23 50 0 88.5 79 - 121 45.75 3.38 201.0

Hexachlorobutadiene 47.46 50 0 94.9 66 - 134 48.83 2.83 201.0

Isopropylbenzene 46.6 50 0 93.2 72 - 131 47.98 2.91 201.0

m,p-Xylene 86.29 100 0 86.3 80 - 121 88.38 2.39 202.0

Methylene chloride 41.68 50 0 83.4 74 - 124 42.56 2.09 202.0

Naphthalene 43.25 50 0 86.5 61 - 128 42.16 2.56 201.0

n-Butylbenzene 46.44 50 0 92.9 75 - 128 48.09 3.49 201.0

n-Propylbenzene 50.97 50 0 102 76 - 126 52.03 2.06 201.0

o-Xylene 44.04 50 0 88.1 78 - 122 44.98 2.09 201.0

sec-Butylbenzene 44.85 50 0 89.7 77 - 126 45.47 1.37 201.0

Styrene 45.1 50 0 90.2 78 - 123 45.82 1.6 201.0

tert-Butylbenzene 51.54 50 0 103 78 - 124 52.61 2.04 201.0

Tetrachloroethene 46.69 50 0 93.4 74 - 129 47.48 1.67 201.0

Toluene 43.05 50 0 86.1 80 - 121 44.05 2.29 201.0

trans-1,2-Dichloroethene 45.05 50 0 90.1 75 - 124 46.95 4.12 201.0

trans-1,3-Dichloropropene 46.97 50 0 93.9 73 - 127 48.76 3.75 201.0

Trichloroethene 48.24 50 0 96.5 79 - 123 49.3 2.17 201.0

Trichlorofluoromethane 49.46 50 0 98.9 65 - 141 51.79 4.59 201.0

Vinyl chloride 44.44 50 0 88.9 58 - 137 45.78 2.97 201.0

41.13 50 0 82.3 81 - 118 41.35 0.534 201.0Surr: 1,2-Dichloroethane-d4

51.11 50 0 102 85 - 114 51.44 0.647 201.0Surr: 4-Bromofluorobenzene

46.74 50 0 93.5 80 - 119 47.25 1.07 201.0Surr: Dibromofluoromethane

50.82 50 0 102 89 - 112 50.24 1.16 201.0Surr: Toluene-d8



16 of 23

00913078

Client:Project:



QC BATCH REPORT


The following samples were analyzed in this batch: HS18071388-01 HS18071388-02



17 of 23

00913079

Client:Project:



QC BATCH REPORT

Batch ID: R320826 Instrument: ICS3K2 Method: SW9056

Sample ID: WBLKW1-073018 Units: mg/L Analysis Date: 31-Jul-2018 01:04

Run ID: ICS3K2_320826 SeqNo: 4673017 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Chloride 0.500 U0.500

Sulfate 0.500 U0.500

Sample ID: WLCSW1-073018 Units: mg/L Analysis Date: 31-Jul-2018 01:26



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Chloride 19.66 20 0 98.3 80 - 1200.500

Sulfate 18.79 20 0 94.0 80 - 1200.500

Sample ID: WLCSDW1-073018 Units: mg/L Analysis Date: 31-Jul-2018 01:48



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Chloride 19.68 20 0 98.4 80 - 120 19.66 0.0966 200.500

Sulfate 18.81 20 0 94.0 80 - 120 18.79 0.0798 200.500




Value %RECControl

LimitRPD Ref


MS

Client ID: LH18/24-SP650_072618

Chloride 769.5 100 659 111 80 - 120 O 5.00

Sulfate 130.8 100 25.9 105 80 - 1205.00




Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18/24-SP650_072618

Chloride 764 100 659 105 80 - 120 769.5 0.72 20 O 5.00

Sulfate 130.2 100 25.9 104 80 - 120 130.8 0.431 205.00




18 of 23

00913080





a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution



Unit Reported Descriptionmg/L Milligrams per Liter


19 of 23

00913081



Oklahoma 2017-088 31-Aug-2018


Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019


20 of 23

00913082

RPG

27-Jul-2018 08:35Date/Time Received:

HS18071388

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

2.6c/2.2c U/c IR11441297/27/18 17:35


Yes No N/A

Yes No N/A


30-Jul-201827-Jul-2018


Reviewed by: Erica Howard



Comments:

Corrective Action:

Yes


01-Aug-18Date:

21 of 23

00913083

22 o

f 23

00913084

23 o

f 23

00913085

WorkOrder: HS18080340LHAAP GWTP



Lakewood CO 80228

09-Aug-2018


Page 1 of 86

00913086

August 09, 2018





Sincerely,

ALS Environmental received 1 sample(s) on Aug 07, 2018 for the analysis presented in the following report.

Laboratory Results for: LHAAP GWTP

Dear Marcia,


Project Manager


RJ Modashia



Page 2 of 86

00913087


Work Order: HS18080340Project: LHAAP GWTP SAMPLE SUMMARY


HS18080340-01 06-Aug-2018 14:00 07-Aug-2018 10:15LH18/24_SP650_080618 Water


Page 3 of 86

00913088


Work Order:LHAAP GWTPBhate Environmental Associates, Inc.

Project:HS18080340

Work Order Comments

The analysis for Perchlorate was subcontracted to ALS Environmental in Salt Lake City Utah. Final report attached.•


Page 4 of 86

00913089


Bhate Environmental Associates, Inc.LHAAP GWTPLH18/24_SP650_080618

WorkOrder:Lab ID:

Collection Date:

HS18080340HS18080340-01

06-Aug-2018 14:00 Matrix:Water

ANALYTICAL REPORT








Page 5 of 86

00913090

Client:LHAAP GWTPBhate Environmental Associates, Inc.

WorkOrder:Project:




09 Aug 2018 11:28HS18080340-01 06 Aug 2018 14:00 1LH18/24_SP650_080618


Page 6 of 86

00913091



Bhate Environmental Associates, Inc.LHAAP GWTPHS18080340


a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution




Page 7 of 86

00913092



Oklahoma 2017-088 31-Aug-2018


Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019


Page 8 of 86

00913093

of 86

00913094



General Set Information: There were two field samples in these Work Orders. The samples were analyzed for perchlorate. Method Summary: Each sample was prepared as noted below and analyzed using an Agilent 1100 LC/MSD system in select ion monitoring (SIM) mode at m/z 83 and 85, which corresponds to the loss of one oxygen atom from the perchlorate molecule. ChemStation software was used for instrument control and data analysis. The ion ratio of m/z 83 to 85 was used to positively identify the response peak as perchlorate. Quantitation was performed using the m/z 83 peak area. An internal standard (ISTD) of 18O labeled perchlorate was added to each sample to establish the perchlorate peak retention time and used in quantitation. Sample Preparation: A 10.0mL aliquot of each sample was transferred into a 15-mL centrifuge tube. 50µL of an 18O labeled perchlorate solution was added to each sample as an internal standard. The samples were then capped, vortexed, and filtered into autosampler vial using Phenex PES membrane 0.45µm Syringe filters. Holding Times: Holding times were met for all analyses. Dilutions: NA Method QC data: The method blank (LMB 613553) was less than 1/2 the CRDL. The recovery for the LCS (613554) was within acceptable parameters.

Page 10 of 86

00913095

MS/MSD Analysis: The matrix spike and matrix spike duplicate (MS/MSD) was performed on sample 1820868001 (Client ID: LH18/24-SP650_072618). The MS/MSD percent recoveries and relative percent difference (RPD) were within the performance limits. Instrument QC: Instrument initial and continuing calibrations were performed in accordance with published procedures. NC/CAR(s): NA Sample Calculation: Samples were reported in µg/L. Results were calculated in µg/L by the equation (A)x(B),

where: A = Analyte concentration from the standard curve (µg/L) B = Dilution performed at time of analysis Miscellaneous Comments: These samples were analyzed in accordance with the requirements found in the DOD QSM Version 5.1. Due to limitations of the Chemstation Software, some of the chromatographic peaks require manual integration. A manual integration was performed for datafile 07AUGD03.


Page 11 of 86

00913096

ANALYTICAL REPORT


Phone:

E-mail:

281 530-5656

[email protected]



LHAAP/GWTP NWO1312.0150LHAAP/GWTPPurchase Order:

Project ID:



1821923001 08/06/18LH18/24-SP650.080618 08/07/18 LHAAP/GWTP




||

Page 12 of 86

00913097

ANALYTICAL REPORT




Analytical Results

Sample ID: 08/06/201808/07/20181821923001Lab ID:

Collected:Received:

LH18/24-SP650.080618 LHAAP/GWTP


Media:

Water

LiquidSampling Site:




LCMS04

Report Basis: Wet









/S/ Stephen Brose



Phone:Email:Web:


Page 13 of 86

00913098

ANALYTICAL REPORT










Website








Page 14 of 86

00913099

Analysis:


Workorder: 1821923




Limits:Basis:


Blank

LMB:

Analyte

Units:

Result

Analyzed:61355308/07/2018 10:02

ug/L

MDL RL



Dilution: 1ug/L


LCS:Analyzed:

61355408/07/2018 10:16

Units:

Target

Perchlorate 5.20 5.00 78.8 123.8104


MS:Analyzed:


108/07/2018 10:49613555Sample:

Analyzed:Dilution:

Units: ug/L108/07/2018 10:321820868001


MSD:Analyzed:

61355608/07/2018 11:03

% Rec



Perchlorate ND 78.8 123.85 96.94.84 20.00.05.04 3.87101



CCV:Analyzed:

61355008/07/2018 09:17

Units:

Target


Result % Rec.

CCV:Analyzed:

61355708/07/2018 11:33

Units:

Target


Perchlorate 26.5 25.0 106 25.7 25.0 103



ICSA:Analyzed:

61355208/07/2018 09:47

Units:

Target





LODV:Analyzed:

61355108/07/2018 09:33

Units:

Target


Result % Rec.

LODV:Analyzed:

61355808/07/2018 11:47

Units:

Target


Perchlorate 1.10 1.00 110 1.24 1.00 124



QCS V4.4

Page 15 of 86

00913100

Analysis:


Workorder: 1821923




Limits:Basis:







# -

Analyst Peer Review


08/07/2018 12:48 08/08/2018 16:35



QCS V4.4

Page 16 of 86

00913101

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00913171

August 17, 2018





Sincerely,


Laboratory Results for: LHAAP / GWTP

Dear Marcia,


Project Manager

Generated By: DAYNA.FISHER

RJ Modashia



00913172


Work Order: HS18080375Project: LHAAP / GWTP SAMPLE SUMMARY


HS18080375-01 06-Aug-2018 14:00 08-Aug-2018 09:30LH18/24-SP650_080618 Water


00913173


Work Order:LHAAP / GWTPBhate Environmental Associates, Inc.

Project:HS18080375


Batch ID: R321826



Batch ID: R321823



Batch ID: R321536Sample ID: HS18080081-01MS

MS is for an unrelated sample (Organic Carbon, Total)•


00913174


Bhate Environmental Associates, Inc.LHAAP / GWTPLH18/24-SP650_080618

WorkOrder:Lab ID:

Collection Date:

HS18080375HS18080375-01


ANALYTICAL REPORT



AMMONIA AS N BY E350.3(ISE) Method:E350.3 Analyst: MZD10mg/L 16-Aug-2018 16:172.0Nitrogen, Ammonia (As N) 2.037 2.0



10mg/L 08-Aug-2018 13:450.100Phosphorus, Total Orthophosphate (As P)

0.2507.19 0.250

TOTAL ORGANIC CARBON BY E415.1 Method:E415.1 Analyst: AJH10mg/L 10-Aug-2018 22:395.00Organic Carbon, Total 10.079.3 6.00



00913175

Client:LHAAP / GWTPBhate Environmental Associates, Inc.

WorkOrder:Project:




10 Aug 2018 22:39HS18080375-01 06 Aug 2018 14:00 10LH18/24-SP650_080618


08 Aug 2018 13:45HS18080375-01 06 Aug 2018 14:00 10LH18/24-SP650_080618


16 Aug 2018 16:17HS18080375-01 06 Aug 2018 14:00 10LH18/24-SP650_080618


00913176

Client:Project:

Bhate Environmental Associates, Inc.LHAAP / GWTP


QC BATCH REPORT


Sample ID: WBLKW1-180810 Units: mg/L Analysis Date: 10-Aug-2018 19:15



Value %RECControl

LimitRPD Ref


MBLK

Client ID:


Sample ID: WLCSW1-180810 Units: mg/L Analysis Date: 10-Aug-2018 19:29



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Organic Carbon, Total 9.746 10 0 97.5 80 - 1201.00

Sample ID: WLCSDW1-180810 Units: mg/L Analysis Date: 10-Aug-2018 19:42



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Organic Carbon, Total 9.825 10 0 98.2 80 - 120 9.746 0.807 201.00

Sample ID: HS18080081-01MS Units: mg/L Analysis Date: 10-Aug-2018 20:09



Value %RECControl

LimitRPD Ref


MS

Client ID:

Organic Carbon, Total 124 10 127.7 -37.0 80 - 120 SEO 1.00




00913177

Client:Project:



QC BATCH REPORT


Sample ID: MBLK-321823 Units: mg/L Analysis Date: 08-Aug-2018 13:45



Value %RECControl

LimitRPD Ref


MBLK

Client ID:


0.0250 U0.0250

Sample ID: LCS-321823 Units: mg/L Analysis Date: 08-Aug-2018 13:45



Value %RECControl

LimitRPD Ref


LCS

Client ID:


0.242 0.25 0 96.8 85 - 1150.0250




Value %RECControl

LimitRPD Ref


MS

Client ID:


0.241 0.25 0.007 93.6 80 - 1200.0250

Sample ID: HS18080307-01MSD Units: mg/L Analysis Date: 08-Aug-2018 13:45



Value %RECControl

LimitRPD Ref


MSD

Client ID:


0.244 0.25 0.007 94.8 80 - 120 0.241 1.24 200.0250




00913178

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:





Value %RECControl

LimitRPD Ref


LCS

Client ID:

Nitrogen, Ammonia (As N) 9.957 10 0 99.6 80 - 1200.20




Value %RECControl

LimitRPD Ref


MS

Client ID: LH18/24-SP650_080618





Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18/24-SP650_080618

Nitrogen, Ammonia (As N) 135 100 36.95 98.0 80 - 120 134.1 0.669 202.0




00913179



Bhate Environmental Associates, Inc.LHAAP / GWTPHS18080375


a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution




00913180



Oklahoma 2017-088 31-Aug-2018


Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019


00913181

JRM

08-Aug-2018 09:30Date/Time Received:

HS18080375

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

2.8c/2.5c UC/C IR254419708/08/2018 11:30


Yes No N/A

Yes No N/A

Checklist completed by: Jared R. MakanDateeSignatureDateeSignature

8-Aug-20188-Aug-2018

UPSWater Carrier name:Matrices:

Reviewed by: RJ Modashia



Comments:

Corrective Action:

Yes


17-Aug-18Date:

00913182

00913183

00913184

August 23, 2018





Sincerely,



Dear Marcia,


Project Manager


RJ Modashia



00913185






00913186



Project:HS18080783


Batch ID: R322140



Batch ID: R322114



Batch ID: R321996



00913187



WorkOrder:Lab ID:

Collection Date:

HS18080783HS18080783-01


ANALYTICAL REPORT







0.2504.57 0.250




00913188


WorkOrder:Project:




20 Aug 2018 16:54HS18080783-01 15 Aug 2018 14:00 1LH18/24-SP650_081518


16 Aug 2018 18:15HS18080783-01 15 Aug 2018 14:00 10LH18/24-SP650_081518


22 Aug 2018 11:13HS18080783-01 15 Aug 2018 14:00 1LH18/24-SP650_081518


00913189

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:





Value %RECControl

LimitRPD Ref


MS

Client ID:

Nitrogen, Ammonia (As N) 10.11 10 0.08733 100 80 - 1200.20




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Nitrogen, Ammonia (As N) 10.14 10 0.08733 101 80 - 120 10.11 0.296 200.20




00913190

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:


0.0250 U0.0250




Value %RECControl

LimitRPD Ref


LCS

Client ID:


0.229 0.25 0 91.6 85 - 1150.0250

Sample ID: LCSD-322114 Units: mg/L Analysis Date: 16-Aug-2018 18:15



Value %RECControl

LimitRPD Ref


LCSD

Client ID:


0.23 0.25 0 92.0 85 - 115 0.229 0.436 200.0250




Value %RECControl

LimitRPD Ref


MS

Client ID:


0.256 0.25 0.011 98.0 80 - 1200.0250




Value %RECControl

LimitRPD Ref


MSD

Client ID:


0.259 0.25 0.011 99.2 80 - 120 0.256 1.17 200.0250




00913191

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:





Value %RECControl

LimitRPD Ref


LCS

Client ID:

Organic Carbon, Total 9.442 10 0 94.4 80 - 1201.00




Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Organic Carbon, Total 9.521 10 0 95.2 80 - 120 9.442 0.833 201.00




Value %RECControl

LimitRPD Ref


MS

Client ID:

Organic Carbon, Total 12.08 10 3.016 90.6 80 - 1201.00




00913192





a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution




00913193



Oklahoma 2017-088 31-Aug-2018


Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


00913194


Work Order: HS18080783Project: Longhorn GW Treatment Plant SAMPLE TRACKING

Lab Samp ID Client Sample ID Action Date Person New Location

HS18080783-01 LH18/24-SP650_081518 Login 8/16/2018 1:07:09 PM JRM WET057




00913195

JRM


HS18080783

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

2.2c/1.8c UC/C IR114419608/16/2018 13:15


Yes No N/A

Yes No N/A


16-Aug-201816-Aug-2018





Comments:

Corrective Action:

Yes


23-Aug-18Date:

00913196

00913197

00913198

August 29, 2018





Sincerely,


Laboratory Results for: LHAAP 18 24

Dear Marcia,


Project Manager


RJ Modashia



1 of 25

00913199


Work Order: HS18080789Project: LHAAP 18 24 SAMPLE SUMMARY


HS18080789-01 15-Aug-2018 14:00 16-Aug-2018 09:30LH 18/24-SP650_081518 Water

HS18080789-02 15-Aug-2018 00:00ALS 051618-99

16-Aug-2018 09:30Trip Blank Water


2 of 25

00913200


Work Order:LHAAP 18 24Bhate Environmental Associates, Inc.

Project:HS18080789


Batch ID: R321901


WetChemistry by Method E300


MS and MSD are for an unrelated sample (Chloride)•


3 of 25

00913201


Bhate Environmental Associates, Inc.LHAAP 18 24LH 18/24-SP650_081518

WorkOrder:Lab ID:

Collection Date:

HS18080789HS18080789-01


ANALYTICAL REPORT





1ug/L 17-Aug-2018 19:06U 0.301,1,1,2-Tetrachloroethane 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.201,1,1-Trichloroethane 1.00.50 0.50



1ug/L 17-Aug-2018 19:06U 0.201,1-Dichloroethane 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.201,1-Dichloroethene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.301,1-Dichloropropene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.401,2,3-Trichlorobenzene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.501,2,3-Trichloropropane 1.00.50 0.50


1ug/L 17-Aug-2018 19:06U 0.301,2,4-Trimethylbenzene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.201,2-Dibromo-3-chloropropane 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.201,2-Dibromoethane 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.501,2-Dichlorobenzene 1.00.50 0.50


1ug/L 17-Aug-2018 19:06U 0.501,2-Dichloropropane 1.00.50 0.50






1ug/L 17-Aug-2018 19:06U 0.502-Butanone 2.01.0 1.0

1ug/L 17-Aug-2018 19:06U 0.302-Chlorotoluene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 1.02-Hexanone 2.01.0 1.0


1ug/L 17-Aug-2018 19:06U 0.304-Isopropyltoluene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.704-Methyl-2-pentanone 2.01.0 1.0

1ug/L 17-Aug-2018 19:060.40Acetone 2.04.1 2.01ug/L 17-Aug-2018 19:06U 0.20Benzene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.40Bromobenzene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.20Bromochloromethane 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.20Bromodichloromethane 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.40Bromoform 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.40Bromomethane 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.60Carbon disulfide 2.01.0 1.0

1ug/L 17-Aug-2018 19:06U 0.50Carbon tetrachloride 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.30Chlorobenzene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.30Chloroethane 1.00.50 0.50



4 of 25

00913202


Bhate Environmental Associates, Inc.LHAAP 18 24LH 18/24-SP650_081518

WorkOrder:Lab ID:

Collection Date:

HS18080789HS18080789-01


ANALYTICAL REPORT





1ug/L 17-Aug-2018 19:06U 0.20Chloroform 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.20Chloromethane 1.00.50 0.50

1ug/L 17-Aug-2018 19:060.20cis-1,2-Dichloroethene 1.03.0 0.501ug/L 17-Aug-2018 19:06U 0.10cis-1,3-Dichloropropene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.30Dibromochloromethane 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.20Dibromomethane 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.30Dichlorodifluoromethane 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.30Ethylbenzene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 1.0Hexachlorobutadiene 1.01.0 1.0

1ug/L 17-Aug-2018 19:06U 0.30Isopropylbenzene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.50m,p-Xylene 2.01.0 1.0

1ug/L 17-Aug-2018 19:06U 0.40Methylene chloride 2.01.0 1.0

1ug/L 17-Aug-2018 19:06U 0.40n-Butylbenzene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.30n-Propylbenzene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.30Naphthalene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.30o-Xylene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.30sec-Butylbenzene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.30Styrene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.30tert-Butylbenzene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.30Tetrachloroethene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.20Toluene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.20trans-1,2-Dichloroethene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.20trans-1,3-Dichloropropene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.20Trichloroethene 1.00.50 0.50

1ug/L 17-Aug-2018 19:06U 0.30Trichlorofluoromethane 1.00.50 0.50

1ug/L 17-Aug-2018 19:060.20Vinyl chloride 1.02.0 0.50Surr: 1,2-Dichloroethane-d4 1%REC 17-Aug-2018 19:0691.1 81-1180Surr: 4-Bromofluorobenzene 1%REC 17-Aug-2018 19:0698.7 85-1140Surr: Dibromofluoromethane 1%REC 17-Aug-2018 19:0696.0 80-1190Surr: Toluene-d8 1%REC 17-Aug-2018 19:0694.9 89-1120

ANIONS BY E300.0 Method:E300 Analyst: KMU10mg/L 24-Aug-2018 13:542.00Chloride 5.00705 5.0010mg/L 24-Aug-2018 13:542.00Sulfate 5.0023.8 5.00



5 of 25

00913203


Bhate Environmental Associates, Inc.LHAAP 18 24Trip Blank

WorkOrder:Lab ID:

Collection Date:

HS18080789HS18080789-02


ANALYTICAL REPORT










1ug/L 17-Aug-2018 14:26U 0.201,1-Dichloroethene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.301,1-Dichloropropene 1.00.50 0.50


1ug/L 17-Aug-2018 14:26U 0.501,2,3-Trichloropropane 1.00.50 0.50



1ug/L 17-Aug-2018 14:26U 0.201,2-Dibromo-3-chloropropane 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.201,2-Dibromoethane 1.00.50 0.50









1ug/L 17-Aug-2018 14:26U 0.502-Butanone 2.01.0 1.0


1ug/L 17-Aug-2018 14:26U 1.02-Hexanone 2.01.0 1.0


1ug/L 17-Aug-2018 14:26U 0.304-Isopropyltoluene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.704-Methyl-2-pentanone 2.01.0 1.0

1ug/L 17-Aug-2018 14:26U 0.40Acetone 2.02.0 2.0

1ug/L 17-Aug-2018 14:26U 0.20Benzene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.40Bromobenzene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.20Bromochloromethane 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.20Bromodichloromethane 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.40Bromoform 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.40Bromomethane 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.60Carbon disulfide 2.01.0 1.0

1ug/L 17-Aug-2018 14:26U 0.50Carbon tetrachloride 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.30Chlorobenzene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.30Chloroethane 1.00.50 0.50



6 of 25

00913204


Bhate Environmental Associates, Inc.LHAAP 18 24Trip Blank

WorkOrder:Lab ID:

Collection Date:

HS18080789HS18080789-02


ANALYTICAL REPORT





1ug/L 17-Aug-2018 14:26U 0.20Chloroform 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.20Chloromethane 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.20cis-1,2-Dichloroethene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.10cis-1,3-Dichloropropene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.30Dibromochloromethane 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.20Dibromomethane 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.30Dichlorodifluoromethane 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.30Ethylbenzene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 1.0Hexachlorobutadiene 1.01.0 1.0

1ug/L 17-Aug-2018 14:26U 0.30Isopropylbenzene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.50m,p-Xylene 2.01.0 1.0

1ug/L 17-Aug-2018 14:26U 0.40Methylene chloride 2.01.0 1.0

1ug/L 17-Aug-2018 14:26U 0.40n-Butylbenzene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.30n-Propylbenzene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.30Naphthalene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.30o-Xylene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.30sec-Butylbenzene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.30Styrene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.30tert-Butylbenzene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.30Tetrachloroethene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.20Toluene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.20trans-1,2-Dichloroethene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.20trans-1,3-Dichloropropene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.20Trichloroethene 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.30Trichlorofluoromethane 1.00.50 0.50

1ug/L 17-Aug-2018 14:26U 0.20Vinyl chloride 1.00.50 0.50

Surr: 1,2-Dichloroethane-d4 1%REC 17-Aug-2018 14:2690.5 81-1180Surr: 4-Bromofluorobenzene 1%REC 17-Aug-2018 14:2698.8 85-1140Surr: Dibromofluoromethane 1%REC 17-Aug-2018 14:2695.6 80-1190Surr: Toluene-d8 1%REC 17-Aug-2018 14:2693.0 89-1120



7 of 25

00913205

Client:LHAAP 18 24Bhate Environmental Associates, Inc.

WorkOrder:Project:




17 Aug 2018 19:06HS18080789-01 15 Aug 2018 14:00 1LH 18/24-SP650_081518

17 Aug 2018 14:26HS18080789-02 15 Aug 2018 00:00 1Trip Blank

Batch ID R322399 Test Name : ANIONS BY E300.0 Matrix: Water

24 Aug 2018 13:54HS18080789-01 15 Aug 2018 14:00 10LH 18/24-SP650_081518


8 of 25

00913206

Client:Project:

Bhate Environmental Associates, Inc.LHAAP 18 24


QC BATCH REPORT


Sample ID: VBLKW-180817 Units: ug/L Analysis Date: 17-Aug-2018 13:37



Value %RECControl

LimitRPD Ref


MBLK

Client ID:






















2-Butanone 1.0 U2.0


2-Hexanone 1.0 U2.0




Acetone 2.0 U2.0

Benzene 0.50 U1.0




Bromoform 0.50 U1.0




9 of 25

00913207

Client:Project:



QC BATCH REPORT


Sample ID: VBLKW-180817 Units: ug/L Analysis Date: 17-Aug-2018 13:37



Value %RECControl

LimitRPD Ref


MBLK

Client ID:















m,p-Xylene 1.0 U2.0





o-Xylene 0.50 U1.0


Styrene 0.50 U1.0



Toluene 0.50 U1.0









45.89 50 0 91.8 89 - 1121.0Surr: Toluene-d8



10 of 25

00913208

Client:Project:



QC BATCH REPORT


Sample ID: VLCSW-180817 Units: ug/L Analysis Date: 17-Aug-2018 12:23



Value %RECControl

LimitRPD Ref


LCS

Client ID:





1,1-Dichloroethane 46.27 50 0 92.5 77 - 1251.0

1,1-Dichloroethene 44.42 50 0 88.8 71 - 1311.0

1,1-Dichloropropene 52.48 50 0 105 78 - 1251.0



1,2,4-Trichlorobenzene 51.55 50 0 103 69 - 1301.0


1,2-Dibromo-3-chloropropane 50.98 50 0 102 62 - 1281.0

1,2-Dibromoethane 52.82 50 0 106 77 - 1211.0


1,2-Dichloroethane 50.48 50 0 101 73 - 1281.0






2,2-Dichloropropane 53.37 50 0 107 60 - 1391.0

2-Butanone 103.7 100 0 104 56 - 1432.0

2-Chlorotoluene 51.34 50 0 103 79 - 1221.0

2-Hexanone 104.7 100 0 105 57 - 1392.0

4-Chlorotoluene 52.32 50 0 105 78 - 1221.0


4-Methyl-2-pentanone 100.3 100 0 100 67 - 1302.0

Acetone 99.04 100 0 99.0 39 - 1602.0

Benzene 47.78 50 0 95.6 79 - 1201.0

Bromobenzene 47.14 50 0 94.3 80 - 1201.0

Bromochloromethane 50.07 50 0 100 78 - 1231.0

Bromodichloromethane 50.73 50 0 101 79 - 1251.0

Bromoform 53.86 50 0 108 66 - 1301.0

Bromomethane 54.33 50 0 109 53 - 1411.0



11 of 25

00913209

Client:Project:



QC BATCH REPORT


Sample ID: VLCSW-180817 Units: ug/L Analysis Date: 17-Aug-2018 12:23



Value %RECControl

LimitRPD Ref


LCS

Client ID:



Chlorobenzene 48.65 50 0 97.3 82 - 1181.0

Chloroethane 45.67 50 0 91.3 60 - 1381.0

Chloroform 45.82 50 0 91.6 79 - 1241.0

Chloromethane 45.55 50 0 91.1 50 - 1391.0


cis-1,3-Dichloropropene 55.62 50 0 111 75 - 1241.0

Dibromochloromethane 50.81 50 0 102 74 - 1261.0

Dibromomethane 53.29 50 0 107 79 - 1231.0

Dichlorodifluoromethane 55.21 50 0 110 32 - 1521.0

Ethylbenzene 53.5 50 0 107 79 - 1211.0



m,p-Xylene 111.4 100 0 111 80 - 1212.0

Methylene chloride 50.47 50 0 101 74 - 1242.0

Naphthalene 53.12 50 0 106 61 - 1281.0

n-Butylbenzene 42.96 50 0 85.9 75 - 1281.0

n-Propylbenzene 50.27 50 0 101 76 - 1261.0

o-Xylene 54.78 50 0 110 78 - 1221.0


Styrene 50.85 50 0 102 78 - 1231.0

tert-Butylbenzene 49.65 50 0 99.3 78 - 1241.0


Toluene 45.81 50 0 91.6 80 - 1211.0





Vinyl chloride 47.52 50 0 95.0 58 - 1371.0

47 50 0 94.0 81 - 1181.0Surr: 1,2-Dichloroethane-d4



45.41 50 0 90.8 89 - 1121.0Surr: Toluene-d8



12 of 25

00913210

Client:Project:



QC BATCH REPORT


Sample ID: HS18080795-04MS Units: ug/L Analysis Date: 17-Aug-2018 16:07



Value %RECControl

LimitRPD Ref


MS

Client ID:





1,1-Dichloroethane 47.43 50 0 94.9 77 - 1251.0

1,1-Dichloroethene 49.96 50 0 99.9 71 - 1311.0







1,2-Dibromoethane 52.44 50 0 105 77 - 1211.0


1,2-Dichloroethane 50.79 50 0 102 73 - 1281.0







2-Butanone 110.9 100 0 111 56 - 1432.0

2-Chlorotoluene 52.35 50 0 105 79 - 1221.0

2-Hexanone 115.3 100 0 115 57 - 1392.0

4-Chlorotoluene 53.22 50 0 106 78 - 1221.0



Acetone 110.2 100 0 110 39 - 1602.0

Benzene 49.05 50 0 98.1 79 - 1201.0

Bromobenzene 46.03 50 0 92.1 80 - 1201.0



Bromoform 54.08 50 0 108 66 - 1301.0

Bromomethane 58.15 50 0 116 53 - 1411.0



13 of 25

00913211

Client:Project:



QC BATCH REPORT


Sample ID: HS18080795-04MS Units: ug/L Analysis Date: 17-Aug-2018 16:07



Value %RECControl

LimitRPD Ref


MS

Client ID:

Carbon disulfide 103 100 0 103 64 - 1332.0


Chlorobenzene 48.81 50 0 97.6 82 - 1181.0

Chloroethane 48 50 0 96.0 60 - 1381.0

Chloroform 47.45 50 0 94.9 79 - 1241.0

Chloromethane 44.82 50 0 89.6 50 - 1391.0




Dibromomethane 54.5 50 0 109 79 - 1231.0


Ethylbenzene 55.89 50 0 112 79 - 1211.0



m,p-Xylene 116.3 100 0 116 80 - 1212.0


Naphthalene 54.34 50 0 109 61 - 1281.0

n-Butylbenzene 46.29 50 0 92.6 75 - 1281.0

n-Propylbenzene 54.61 50 0 109 76 - 1261.0

o-Xylene 56.32 50 0 113 78 - 1221.0


Styrene 49.82 50 0 99.6 78 - 1231.0


Tetrachloroethene 50.24 50 0 100 74 - 1291.0

Toluene 46.98 50 0 94.0 80 - 1211.0

trans-1,2-Dichloroethene 52.21 50 0 104 75 - 1241.0


Trichloroethene 52.74 50 0 105 79 - 1231.0


Vinyl chloride 53.91 50 0 108 58 - 1371.0




45.27 50 0 90.5 89 - 1121.0Surr: Toluene-d8



14 of 25

00913212

Client:Project:



QC BATCH REPORT


Sample ID: HS18080795-04MSD Units: ug/L Analysis Date: 17-Aug-2018 16:33



Value %RECControl

LimitRPD Ref


MSD

Client ID:





1,1-Dichloroethane 45.87 50 0 91.7 77 - 125 47.43 3.34 201.0

1,1-Dichloroethene 47.97 50 0 95.9 71 - 131 49.96 4.08 201.0

1,1-Dichloropropene 56.15 50 0 112 78 - 125 57.16 1.78 201.0

1,2,3-Trichlorobenzene 50.73 50 0 101 69 - 129 50.29 0.874 201.0



1,2,4-Trimethylbenzene 52.25 50 0 104 76 - 124 52.46 0.399 201.0

1,2-Dibromo-3-chloropropane 53.36 50 0 107 62 - 128 51.17 4.19 201.0

1,2-Dibromoethane 51.92 50 0 104 77 - 121 52.44 0.991 201.0


1,2-Dichloroethane 48.67 50 0 97.3 73 - 128 50.79 4.28 201.0






2,2-Dichloropropane 52.17 50 0 104 60 - 139 55.32 5.85 201.0

2-Butanone 111.1 100 0 111 56 - 143 110.9 0.167 202.0

2-Chlorotoluene 52.08 50 0 104 79 - 122 52.35 0.501 201.0

2-Hexanone 117.2 100 0 117 57 - 139 115.3 1.57 202.0

4-Chlorotoluene 52.51 50 0 105 78 - 122 53.22 1.33 201.0


4-Methyl-2-pentanone 111.3 100 0 111 67 - 130 110.8 0.423 202.0

Acetone 106.4 100 0 106 39 - 160 110.2 3.5 202.0

Benzene 47.73 50 0 95.5 79 - 120 49.05 2.73 201.0

Bromobenzene 46.1 50 0 92.2 80 - 120 46.03 0.165 201.0

Bromochloromethane 50.3 50 0 101 78 - 123 50.89 1.18 201.0


Bromoform 53.14 50 0 106 66 - 130 54.08 1.74 201.0

Bromomethane 51.94 50 0 104 53 - 141 58.15 11.3 201.0



15 of 25

00913213

Client:Project:



QC BATCH REPORT


Sample ID: HS18080795-04MSD Units: ug/L Analysis Date: 17-Aug-2018 16:33



Value %RECControl

LimitRPD Ref


MSD

Client ID:

Carbon disulfide 99.79 100 0 99.8 64 - 133 103 3.19 202.0


Chlorobenzene 48.4 50 0 96.8 82 - 118 48.81 0.842 201.0

Chloroethane 46.44 50 0 92.9 60 - 138 48 3.29 201.0

Chloroform 45.14 50 0 90.3 79 - 124 47.45 5 201.0

Chloromethane 43.1 50 0 86.2 50 - 139 44.82 3.91 201.0


cis-1,3-Dichloropropene 53.59 50 0 107 75 - 124 55.21 2.98 201.0

Dibromochloromethane 50.17 50 0 100 74 - 126 50.69 1.03 201.0

Dibromomethane 52.75 50 0 106 79 - 123 54.5 3.26 201.0

Dichlorodifluoromethane 56.65 50 0 113 32 - 152 61.19 7.71 201.0

Ethylbenzene 55.78 50 0 112 79 - 121 55.89 0.198 201.0



m,p-Xylene 114.5 100 0 114 80 - 121 116.3 1.57 202.0


Naphthalene 55.82 50 0 112 61 - 128 54.34 2.69 201.0

n-Butylbenzene 46.41 50 0 92.8 75 - 128 46.29 0.256 201.0

n-Propylbenzene 53.57 50 0 107 76 - 126 54.61 1.92 201.0

o-Xylene 55.59 50 0 111 78 - 122 56.32 1.3 201.0


Styrene 48.71 50 0 97.4 78 - 123 49.82 2.26 201.0



Toluene 46.48 50 0 93.0 80 - 121 46.98 1.07 201.0


trans-1,3-Dichloropropene 57.19 50 0 114 73 - 127 57.4 0.361 201.0



Vinyl chloride 49.87 50 0 99.7 58 - 137 53.91 7.78 201.0




45.67 50 0 91.3 89 - 112 45.27 0.893 201.0Surr: Toluene-d8



16 of 25

00913214

Client:Project:



QC BATCH REPORT





17 of 25

00913215

Client:Project:



QC BATCH REPORT

Batch ID: R322399 Instrument: ICS2100 Method: E300


Run ID: ICS2100_322399 SeqNo: 4705885 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:






Value %RECControl

LimitRPD Ref


LCS

Client ID:

Chloride 20.41 20 0 102 90 - 1100.500

Sulfate 20.25 20 0 101 90 - 1100.500




Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Chloride 19.5 20 0 97.5 90 - 110 20.41 4.53 200.500

Sulfate 19.33 20 0 96.6 90 - 110 20.25 4.63 200.500




Value %RECControl

LimitRPD Ref


MS

Client ID:

Chloride 84.68 10 78.56 61.2 80 - 120 SO 0.500

Sulfate 39.48 10 31.11 83.7 80 - 1200.500




Value %RECControl

LimitRPD Ref


MS

Client ID:

Chloride 28.41 10 18.87 95.4 80 - 1200.500

Sulfate 39.75 10 30.58 91.7 80 - 1200.500



18 of 25

00913216

Client:Project:



QC BATCH REPORT

Batch ID: R322399 Instrument: ICS2100 Method: E300




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Chloride 85.43 10 78.56 68.7 80 - 120 84.68 0.884 20 SO 0.500

Sulfate 39.87 10 31.11 87.6 80 - 120 39.48 0.986 200.500




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Chloride 28.11 10 18.87 92.4 80 - 120 28.41 1.05 200.500

Sulfate 39.31 10 30.58 87.3 80 - 120 39.75 1.1 200.500




19 of 25

00913217



Bhate Environmental Associates, Inc.LHAAP 18 24HS18080789


a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution





20 of 25

00913218



Oklahoma 2017-088 31-Aug-2018


Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


21 of 25

00913219


Work Order: HS18080789Project: LHAAP 18 24 SAMPLE TRACKING


HS18080789-01 LH 18/24-SP650_081518 Login 8/16/2018 1:22:58 PM JRM WET163

HS18080789-01 LH 18/24-SP650_081518 Login 8/16/2018 1:22:58 PM JRM Disposed

HS18080789-02 Trip Blank Login 8/16/2018 1:22:58 PM JRM Disposed


22 of 25

00913220

JRM


HS18080789

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

2.2c/1.8c UC/C IR114419608/16/2018 13:25


Yes No N/A

Yes No N/A


16-Aug-201816-Aug-2018





Comments:

Corrective Action:

Yes


29-Aug-18Date:

23 of 25

00913221

24 o

f 25

00913222

25 o

f 25

00913223

August 22, 2018





Sincerely,



Dear Marcia,


Project Manager


RJ Modashia



00913224






00913225



Project:

Work Order Comments

The sample was shipped directly to ALS Salt Lake City. Therefore, a sample receipt checklist is not present for ALS Houston.•

Work Order Comments



00913226



WorkOrder:Lab ID:

Collection Date:

HS18080840HS18080840-01


ANALYTICAL REPORT








00913227


WorkOrder:Project:




21 Aug 2018 09:30HS18080840-01 15 Aug 2018 14:00 1LH18/24-SP650_081518


00913228





a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution




00913229



Oklahoma 2017-088 31-Aug-2018


Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


00913230

00913231

00913232

00913233

Case Narrative Method: 6850 Analysis: Perchlorate Analysis SOP: LC-MS-CLO4 ALS WO ID(s): 1822951


General Set Information: There was one field sample in this Work Order. The sample was analyzed for perchlorate. Method Summary: Each sample was prepared as noted below and analyzed using an Agilent 1100 LC/MSD system in select ion monitoring (SIM) mode at m/z 83 and 85, which corresponds to the loss of one oxygen atom from the perchlorate molecule. ChemStation software was used for instrument control and data analysis. The ion ratio of m/z 83 to 85 was used to positively identify the response peak as perchlorate. Quantitation was performed using the m/z 83 peak area. An internal standard (ISTD) of 18O labeled perchlorate was added to each sample to establish the perchlorate peak retention time and used in quantitation. Sample Preparation: A 10.0mL aliquot of each sample was transferred into a 15-mL centrifuge tube. 50µL of an 18O labeled perchlorate solution was added to each sample as an internal standard. The samples were then capped, vortexed, and filtered into autosampler vial using Phenex PES membrane 0.45µm Syringe filters. Holding Times: Holding times were met for all analyses. Dilutions: NA Method QC data: The method blank (LMB 615254) was less than 1/2 the CRDL. The recovery for the LCS (615255) was within acceptable parameters.

00913234

MS/MSD Analysis: The matrix spike and matrix spike duplicate (MS/MSD) was performed on sample 1822951001 (Client ID: LH18/25-SP650_081518). The percent recoveries and relative percent difference (RPD) were within the performance limits. Instrument QC: Instrument initial and continuing calibrations were performed in accordance with published procedures. NC/CAR(s): NA Sample Calculation: Samples were reported in µg/L. Results were calculated in µg/L by the equation (A)x(B),

where: A = Analyte concentration from the standard curve (µg/L) B = Dilution performed at time of analysis Miscellaneous Comments: These samples were analyzed in accordance with the requirements found in the DOD QSM Version 5.1. Due to limitations of the Chemstation Software, some of the chromatographic peaks require manual integration. Manual integration were performed for datafile 21AUGD02/03/06/10.


00913235

ANALYTICAL REPORT


Phone:

E-mail:

281 530-5656

[email protected]



Treatment Plant 081518NWO1312.0150.0160001Purchase Order:

Project ID:



1822951001 08/15/18LH18/25-SP650_081518 08/16/18 LHAAP

Page 1 of 3 Wed, 08/22/18 10:34 AM ENVREP-V4.8



||

00913236

ANALYTICAL REPORT




Analytical Results

Sample ID: 08/15/201808/16/20181822951001Lab ID:

Collected:Received:

LH18/25-SP650_081518 LHAAP


Media:

Water





LCMS04

Report Basis: Wet





Comments

Workorder: 1822951

Amended 8/22/18: At client request, the sample was reanalyzed. The re-analysis showed the result to be non-detect.NC/CAR-1571 was initiated.





/S/ Stephen Brose



Phone:Email:Web:


00913237

ANALYTICAL REPORT










Website








00913238

Analysis:


Workorder: 1822951




Limits:Basis:


Blank

LMB:

Analyte

Units:

Result

Analyzed:61525408/21/2018 11:15

ug/L

MDL RL



Dilution: 1ug/L


LCS:Analyzed:

61525508/21/2018 11:29

Units:

Target

Perchlorate 5.35 5.00 78.8 123.8107


MS:Analyzed:


108/21/2018 11:59615256Sample:

Analyzed:Dilution:

Units: ug/L108/21/2018 11:451822951001


MSD:Analyzed:

61525708/21/2018 12:13

% Rec



Perchlorate ND 78.8 123.85 1236.16 20.00.06.13 0.356123



CCV:Analyzed:

61525108/21/2018 10:31

Units:

Target


Result % Rec.

CCV:Analyzed:

61525808/21/2018 12:27

Units:

Target


Perchlorate 25.7 25.0 103 25.7 25.0 103



ICSA:Analyzed:

61525308/21/2018 11:00

Units:

Target





LODV:Analyzed:

61525208/21/2018 10:46

Units:

Target


Result % Rec.

LODV:Analyzed:

61525908/21/2018 12:42

Units:

Target


Perchlorate 1.14 1.00 114 1.15 1.00 115



QCS V4.4

00913239

Analysis:


Workorder: 1822951




Limits:Basis:







# -

Analyst Peer Review


08/21/2018 13:13 08/21/2018 13:34



QCS V4.4

00913240

00913241

00913242

00913243

00913244

00913245

00913246

00913247

00913248

00913249

00913250

00913251

00913252

00913253

00913254

00913255

00913256

00913257

00913258

00913259

00913260

00913261

00913262

00913263

00913264

00913265

00913266

00913267

00913268

00913269

00913270

00913271

00913272

00913273

00913274

00913275

00913276

00913277

00913278

00913279

00913280

00913281

00913282

00913283

00913284

00913285

00913286

00913287

00913288

00913289

00913290

00913291

00913292

00913293

00913294

00913295

00913296

00913297

00913298

00913299

00913300

00913301

00913302

00913303

00913304

00913305

00913306

00913307

00913308

00913309

00913310

00913311

00913312

00913313

00913314

00913315

00913316

August 31, 2018





Sincerely,


Laboratory Results for: Longhorn GW Treatment Plant Weekly Samples

Dear Marcia,


Project Manager


RJ Modashia



00913317


Work Order: HS18081206Project: Longhorn GW Treatment Plant Weekly Samples SAMPLE SUMMARY




00913318


Work Order:Longhorn GW Treatment Plant Weekly SamplesBhate Environmental Associates, Inc.

Project:

Work Order Comments



Batch ID: R322754



Batch ID: R322633



Batch ID: R322482



00913319


Bhate Environmental Associates, Inc.Longhorn GW Treatment Plant Weekly SamplesLH18/24-SP650_082318

WorkOrder:Lab ID:

Collection Date:

HS18081206HS18081206-01


ANALYTICAL REPORT







0.2505.26 0.250







00913320

Client:Longhorn GW Treatment Plant Weekly SamplesBhate Environmental Associates, Inc.

WorkOrder:Project:




28 Aug 2018 14:09HS18081206-01 23 Aug 2018 14:00 1LH18/24-SP650_082318


24 Aug 2018 15:17HS18081206-01 23 Aug 2018 14:00 10LH18/24-SP650_082318


30 Aug 2018 17:21HS18081206-01 23 Aug 2018 14:00 1LH18/24-SP650_082318


31 Aug 2018 11:14HS18081206-01 23 Aug 2018 14:00 1LH18/24-SP650_082318


00913321

Client:Project:

Bhate Environmental Associates, Inc.Longhorn GW Treatment Plant Weekly Samples


QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:





Value %RECControl

LimitRPD Ref


LCS

Client ID:

Nitrogen, Ammonia (As N) 10.18 10 0 102 80 - 1200.20




Value %RECControl

LimitRPD Ref


MS

Client ID:





Value %RECControl

LimitRPD Ref


MSD

Client ID:





00913322

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:


0.0250 U0.0250




Value %RECControl

LimitRPD Ref


LCS

Client ID:


0.244 0.25 0 97.6 85 - 1150.0250




Value %RECControl

LimitRPD Ref


MS

Client ID: LH18/24-SP650_082318


7.49 2.5 5.26 89.2 80 - 1200.250




Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18/24-SP650_082318


7.5 2.5 5.26 89.6 80 - 120 7.49 0.133 200.250




00913323

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:





Value %RECControl

LimitRPD Ref


LCS

Client ID:

Organic Carbon, Total 10.1 10 0 101 85 - 1151.00




Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Organic Carbon, Total 10.18 10 0 102 85 - 115 10.1 0.789 201.00




Value %RECControl

LimitRPD Ref


MS

Client ID:

Organic Carbon, Total 13.3 10 3.708 95.9 80 - 1201.00




00913324



Bhate Environmental Associates, Inc.Longhorn GW Treatment Plant Weekly SamplesHS18081206


a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution




00913325




Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


00913326


Work Order: HS18081206Project: Longhorn GW Treatment Plant Weekly Samples SAMPLE TRACKING


HS18081206-01 LH18/24-SP650_082318 Login 8/24/2018 1:44:16 PM JRM Sub





00913327

JRM


HS18081206

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

2.1c/1.8c UC/C IR254389908/24/2018 13:45


Yes No N/A

Yes No N/A


24-Aug-201824-Aug-2018

FedEx Priority OvernightWater Carrier name:Matrices:




Comments:

Corrective Action:

Yes


31-Aug-18Date:

00913328

00913329

00913330



General Set Information: There two field samples in these Work Orders. The samples were analyzed for perchlorate. Method Summary: Each sample was prepared as noted below and analyzed using an Agilent 1100 LC/MSD system in select ion monitoring (SIM) mode at m/z 83 and 85, which corresponds to the loss of one oxygen atom from the perchlorate molecule. ChemStation software was used for instrument control and data analysis. The ion ratio of m/z 83 to 85 was used to positively identify the response peak as perchlorate. Quantitation was performed using the m/z 83 peak area. An internal standard (ISTD) of 18O labeled perchlorate was added to each sample to establish the perchlorate peak retention time and used in quantitation. Sample Preparation: A 10.0mL aliquot of each sample was transferred into a 15-mL centrifuge tube. 50µL of an 18O labeled perchlorate solution was added to each sample as an internal standard. The samples were then capped, vortexed, and filtered into autosampler vial using Phenex PES membrane 0.45µm Syringe filters. Holding Times: Holding times were met for all analyses. Dilutions: Samples 1824064001, 1824071001 and the MS/MSD failed the 50-150% method requirement for ISTD recovery. The samples and MS/MSD were re-analyzed and reported from 1:5 dilution. The reporting limits were adjusted accordingly. Method QC data: The method blank (LMB 616400) was less than 1/2 the CRDL. The recovery for the LCS (616401) was within acceptable parameters.

00913331

MS/MSD Analysis: MS/MSD was performed on sample 1824064001 (Client ID: LH18/24-SP650_082718). 5.0µl of Working Standard Solution Horizon ID 41828 was added to 10.0mL of sample preparation. MS/MSD failed the 50-150% method requirement for ISTD recovery so the sample was diluted 5x and reanalyzed. Spike target = 5.0µg/L. Effective spike target = 25.0µg/L Instrument QC: Instrument initial and continuing calibrations were performed in accordance with published procedures. NC/CAR(s): NA Sample Calculation: Samples were reported in µg/L. Results were calculated in µg/L by the equation (A)x(B),

where: A = Analyte concentration from the standard curve (µg/L) B = Dilution performed at time of analysis Miscellaneous Comments: These samples were analyzed in accordance with the requirements found in the DOD QSM Version 5.1. Due to limitations of the Chemstation Software, some of the chromatographic peaks require manual integration. Manual integrations were performed for datafile 29AUGPD6/7.

Stephen Brose August 30, 2018 Analyst Date

00913332

ANALYTICAL REPORT


Phone:

E-mail:

281 530-5656

[email protected]



HS18081206HS18081206Purchase Order:

Project ID:



1824071001 08/23/18LH18/24-SP650_082318 08/28/18 HS18081206

Page 1 of 3 Thu, 08/30/18 2:11 PM ENVREP-V4.8



||

00913333

ANALYTICAL REPORT




Analytical Results

Sample ID: 08/23/201808/28/20181824071001Lab ID:

Collected:Received:

LH18/24-SP650_082318 HS18081206


Media:

Water





LCMS04

Report Basis: Wet




205.0ND 10 UPerchlorate 5

Comments

Quality Control: EPA 6850, DoD QSM - (HBN: 221835)

Samples 1824064001, 1824071001 and the MS/MSD failed the 50-150% method requirement for ISTD recovery. The samplesand MS/MSD were re-analyzed and reported from 1:5 dilution.




EPA 6850, DoD QSM /S/ Stephen Brose08/30/2018 11:29 08/30/2018 13:56

/S/ Thomas T. McKay



Phone:Email:Web:


00913334

ANALYTICAL REPORT










Website








00913335

Analysis:

Analyzed By:ELMS/2136 (HBN: 221835)Stephen Brose

Workorder: 1824071




Limits:Basis:


Blank

LMB:

Analyte

Units:

Result

Analyzed:61640008/30/2018 07:19

ug/L

MDL RL



Dilution: 1ug/L


LCS:Analyzed:

61640108/30/2018 07:33

Units:

Target

Perchlorate 5.60 5.00 78.8 123.8112


MS:Analyzed:


508/30/2018 08:59616402Sample:

Analyzed:Dilution:

Units: ug/L508/30/2018 08:451824064001


MSD:Analyzed:

61640308/30/2018 09:13

% Rec



Perchlorate ND 78.8 123.825 12631.5 20.00.029.1 7.88117#



CCV:Analyzed:

61639608/30/2018 06:37

Units:

Target


Result % Rec.

CCV:Analyzed:

61640408/30/2018 09:41

Units:

Target


Perchlorate 26.2 25.0 105 26.0 25.0 104



ICSA:Analyzed:

61639908/30/2018 07:05

Units:

Target





LODV:Analyzed:

61639808/30/2018 06:51

Units:

Target


Result % Rec.

LODV:Analyzed:

61640508/30/2018 09:55

Units:

Target


Perchlorate 1.13 1.00 113 1.12 1.00 112

Page 1 of 2 Thursday, August 30, 2018


QCS V4.4

00913336

Analysis:


Workorder: 1824071




Limits:Basis:


CommentsSamples 1824064001, 1824071001 and the MS/MSD failed the 50-150% method requirement for ISTD recovery. The samples andMS/MSD were re-analyzed and reported from 1:5 dilution.






# -

Analyst Peer Review

/S/ Stephen Brose /S/ Thomas T. McKay

08/30/2018 11:29 08/30/2018 13:56



QCS V4.4

00913337

00913338

00913339

00913340

00913341

00913342

00913343

00913344

00913345

00913346

00913347

00913348

00913349

00913350

00913351

00913352

00913353

00913354

00913355

00913356

00913357

00913358

00913359




Lakewood CO 80228

31-Aug-2018


Page 1 of 98

00913360

August 31, 2018





Sincerely,



Dear Marcia,


Project Manager


RJ Modashia



Page 2 of 98

00913361






Page 3 of 98

00913362



Project:

Work Order Comments



Page 4 of 98

00913363



WorkOrder:Lab ID:

Collection Date:

HS18081379HS18081379-01


ANALYTICAL REPORT








Page 5 of 98

00913364


WorkOrder:Project:




30 Aug 2018 17:21HS18081379-01 27 Aug 2018 13:00 1LH18/24-SP650_082718


Page 6 of 98

00913365





a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution




Page 7 of 98

00913366




Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


Page 8 of 98

00913367




HS18081379-01 LH18/24-SP650_082718 Login 8/28/2018 4:50:14 PM JRM Sub


Page 9 of 98

00913368

of 9

8

00913369



General Set Information: There two field samples in these Work Orders. The samples were analyzed for perchlorate. Method Summary: Each sample was prepared as noted below and analyzed using an Agilent 1100 LC/MSD system in select ion monitoring (SIM) mode at m/z 83 and 85, which corresponds to the loss of one oxygen atom from the perchlorate molecule. ChemStation software was used for instrument control and data analysis. The ion ratio of m/z 83 to 85 was used to positively identify the response peak as perchlorate. Quantitation was performed using the m/z 83 peak area. An internal standard (ISTD) of 18O labeled perchlorate was added to each sample to establish the perchlorate peak retention time and used in quantitation. Sample Preparation: A 10.0mL aliquot of each sample was transferred into a 15-mL centrifuge tube. 50µL of an 18O labeled perchlorate solution was added to each sample as an internal standard. The samples were then capped, vortexed, and filtered into autosampler vial using Phenex PES membrane 0.45µm Syringe filters. Holding Times: Holding times were met for all analyses. Dilutions: Samples 1824064001, 1824071001 and the MS/MSD failed the 50-150% method requirement for ISTD recovery. The samples and MS/MSD were re-analyzed and reported from 1:5 dilution. The reporting limits were adjusted accordingly. Method QC data: The method blank (LMB 616400) was less than 1/2 the CRDL. The recovery for the LCS (616401) was within acceptable parameters.

Page 11 of 98

00913370

MS/MSD Analysis: MS/MSD was performed on sample 1824064001 (Client ID: LH18/24-SP650_082718). 5.0µl of Working Standard Solution Horizon ID 41828 was added to 10.0mL of sample preparation. MS/MSD failed the 50-150% method requirement for ISTD recovery so the sample was diluted 5x and reanalyzed. Spike target = 5.0µg/L. Effective spike target = 25.0µg/L Instrument QC: Instrument initial and continuing calibrations were performed in accordance with published procedures. NC/CAR(s): NA Sample Calculation: Samples were reported in µg/L. Results were calculated in µg/L by the equation (A)x(B),

where: A = Analyte concentration from the standard curve (µg/L) B = Dilution performed at time of analysis Miscellaneous Comments: These samples were analyzed in accordance with the requirements found in the DOD QSM Version 5.1. Due to limitations of the Chemstation Software, some of the chromatographic peaks require manual integration. Manual integrations were performed for datafile 29AUGPD6/7.

Stephen Brose August 30, 2018 Analyst Date

Page 12 of 98

00913371

ANALYTICAL REPORT


Phone:

E-mail:

281 530-5656

[email protected]



Groundwater TreatmentNWO1312.0150.16.0001Purchase Order:

Project ID:



1824064001 08/27/18LH18/24-SP650_082718 08/28/18




||

Page 13 of 98

00913372

ANALYTICAL REPORT




Analytical Results

Sample ID: 08/27/201808/28/20181824064001Lab ID:

Collected:Received:

LH18/24-SP650_082718 NA


Media:

Water





LCMS04

Report Basis: Wet




205.0ND 10 UPerchlorate 5

Comments

Quality Control: EPA 6850, DoD QSM - (HBN: 221835)

Samples 1824064001, 1824071001 and the MS/MSD failed the 50-150% method requirement for ISTD recovery. The samplesand MS/MSD were re-analyzed and reported from 1:5 dilution.




EPA 6850, DoD QSM /S/ Stephen Brose08/30/2018 11:29 08/30/2018 13:56

/S/ Thomas T. McKay



Phone:Email:Web:


Page 14 of 98

00913373

ANALYTICAL REPORT










Website








Page 15 of 98

00913374

Analysis:


Workorder: 1824064




Limits:Basis:


Blank

LMB:

Analyte

Units:

Result

Analyzed:61640008/30/2018 07:19

ug/L

MDL RL



Dilution: 1ug/L


LCS:Analyzed:

61640108/30/2018 07:33

Units:

Target

Perchlorate 5.60 5.00 78.8 123.8112


MS:Analyzed:


508/30/2018 08:59616402Sample:

Analyzed:Dilution:

Units: ug/L508/30/2018 08:451824064001


MSD:Analyzed:

61640308/30/2018 09:13

% Rec



Perchlorate ND 78.8 123.825 12631.5 20.00.029.1 7.88117#



CCV:Analyzed:

61639608/30/2018 06:37

Units:

Target


Result % Rec.

CCV:Analyzed:

61640408/30/2018 09:41

Units:

Target


Perchlorate 26.2 25.0 105 26.0 25.0 104



ICSA:Analyzed:

61639908/30/2018 07:05

Units:

Target





LODV:Analyzed:

61639808/30/2018 06:51

Units:

Target


Result % Rec.

LODV:Analyzed:

61640508/30/2018 09:55

Units:

Target


Perchlorate 1.13 1.00 113 1.12 1.00 112



QCS V4.4

Page 16 of 98

00913375

Analysis:


Workorder: 1824064




Limits:Basis:


CommentsSamples 1824064001, 1824071001 and the MS/MSD failed the 50-150% method requirement for ISTD recovery. The samples andMS/MSD were re-analyzed and reported from 1:5 dilution.






# -

Analyst Peer Review

/S/ Stephen Brose /S/ Thomas T. McKay

08/30/2018 11:29 08/30/2018 13:56



QCS V4.4

Page 17 of 98

00913376

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00913457

September 19, 2018





Sincerely,



Dear Marcia,


Project Manager


RJ Modashia



1 of 34

00913458





ALS Houston, US 19-Sep-18Date:

2 of 34

00913459



Project:

Work Order Comments


Work Order Comments

The analysis for Total Organic Carbon was subcontracted to ALS Kelso, WA. Final report attached.•



Batch ID: R323334



Batch ID: R322828



3 of 34

00913460



WorkOrder:Lab ID:

Collection Date:

HS18081539HS18081539-01


ANALYTICAL REPORT



AMMONIA AS N BY E350.3(ISE) Method:E350.3 Analyst: MZD1mg/L 04-Sep-2018 12:000.20Nitrogen, Ammonia (As N) 0.2036 0.20




0.2506.54 0.250


Method:NA Analyst: SUBK

1NA 17-Sep-2018 09:310Subcontract Analysis See Attached 0SUBCONTRACT ANALYSIS - TOC ANALYSIS


1NA 19-Sep-2018 08:250Subcontract Analysis See Attached 0

19-Sep-18Date: ALS Houston, US


4 of 34

00913461


WorkOrder:Project:




04 Sep 2018 12:00HS18081539-01 30 Aug 2018 14:00 1LH18/24-SP650_083018


31 Aug 2018 13:00HS18081539-01 30 Aug 2018 14:00 10LH18/24-SP650_083018


17 Sep 2018 09:31HS18081539-01 30 Aug 2018 14:00 1LH18/24-SP650_083018

Batch ID R323666 Test Name : SUBCONTRACT ANALYSIS - TOC ANALYSIS Matrix: Water

19 Sep 2018 08:25HS18081539-01 30 Aug 2018 14:00 1LH18/24-SP650_083018


5 of 34

00913462

Client:Project:



QC BATCH REPORT


Sample ID: MBLK-322828 Units: mg/L Analysis Date: 04-Sep-2018 12:00



Value %RECControl

LimitRPD Ref


MBLK

Client ID:


Sample ID: LCS-322828 Units: mg/L Analysis Date: 04-Sep-2018 12:00



Value %RECControl

LimitRPD Ref


LCS

Client ID:


Sample ID: HS18081349-01MS Units: mg/L Analysis Date: 04-Sep-2018 12:00



Value %RECControl

LimitRPD Ref


MS

Client ID:


Sample ID: HS18081349-01MSD Units: mg/L Analysis Date: 04-Sep-2018 12:00



Value %RECControl

LimitRPD Ref


MSD

Client ID:



ALS Houston, US Date: 19-Sep-18


6 of 34

00913463

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:


0.0250 U0.0250




Value %RECControl

LimitRPD Ref


LCS

Client ID:


0.234 0.25 0 93.6 85 - 1150.0250




Value %RECControl

LimitRPD Ref


MS

Client ID: LH18/24-SP650_083018


9.02 2.5 6.54 99.2 80 - 1200.250




Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18/24-SP650_083018


9.03 2.5 6.54 99.6 80 - 120 9.02 0.111 200.250




7 of 34

00913464





a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution




8 of 34

00913465




Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


9 of 34

00913466




HS18081539-01 LH18/24-SP650_083018 Login 8/31/2018 10:37:38 AM RPG WET057




10 of 34

00913467

RPG


HS18081539

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

2.4c/2.1c uc/c IR 254317708/31/2018 10:45


Yes No N/A

Yes No N/A

Checklist completed by: Raegen GigaDateeSignatureDateeSignature

31-Aug-201831-Aug-2018

FedEx Priority Overnightwater Carrier name:Matrices:




Comments:

Corrective Action:

Yes



11 of 34

00913468

12 o

f 34

00913469

13 o

f 34

00913470

ANALYTICAL REPORT


Phone:

E-mail:

281 530-5656

[email protected]

Report Date: September 18, 2018


HS18081541-01 083018HS18081541Purchase Order:

Project ID:



1824768001 08/30/18LH18/24-SP650_083018 09/01/18

Page 1 of 3 Tue, 09/18/18 9:40 AM ENVREP-V4.8



||

14 of 34

00913471

ANALYTICAL REPORT




Analytical Results

Sample ID: 08/30/201809/01/20181824768001Lab ID:

Collected:Received:

LH18/24-SP650_083018 NA


Media:

Water

125 mL Plastic WideSampling Site:




LCMS04

Report Basis: Wet





Comments

Workorder: 1824768

As directed by client, the sample from 1824779 (HS18081539) and 1824768 (HS18081541) were apparently flipped in the field.HS18081539 sample should be reported as HS18081541 and vice versa.





/S/ Stephen Brose



Phone:Email:Web:


15 of 34

00913472

ANALYTICAL REPORT










Website








16 of 34

00913473

17 of 34

00913474

18 of 34

00913475

19 of 34

00913476

September 18, 2018 Analytical Report for Service Request No: K1808656

RJ ModashiaALS Laboratory Group10450 Stancliff RoadSuite 210Houston, TX 77099-4338

Analyses were performed according to our laboratory’s NELAP-approved quality assurance program. The test results meet requirements of the current NELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP-accredited analytes, refer to the certifications section at www.alsglobal.com. All results are intended to be considered in their entirety, and ALS Group USA Corp. dba ALS Environmental (ALS) is not responsible for use of less than the complete report. Results apply only to the items submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the report.

For your reference, these analyses have been assigned our service request numberEnclosed are the results of the sample(s) submitted to our laboratory September 11, 2018

RE: ALS-Houston Environmental / HS18081539

Dear RJ,

K1808656.

Please contact me if you have any questions. My extension is 3350. You may also contact me via email at [email protected].

Respectfully submitted,

ALS Group USA, Corp. dba ALS Environmental

Kelley LovejoyProject Manager

ALS Group USA, Corp1317 South 13th AvenueKelso, WA 98626

+1 360 577 7222+1 360 636 1068

T :F :

ALS Environmental

www.alsglobal.com

RIGHT SOLUTIONS | RIGHT PARTNER20 of 34

00913477

kelley.lovejoy

Kelley Lovejoy

www.alsglobal.com

ALS Environmental

F :T :

+1 360 636 1068+1 360 577 7222

Kelso, WA 986261317 South 13th AvenueALS Group USA, Corp

Table of Contents

RIGHT SOLUTIONS | RIGHT PARTNER

Acronyms

Qualifiers

State Certifications, Accreditations, And Licenses

Case Narrative

Chain of Custody

General Chemistry

Raw Data

General Chemistry

21 of 34

00913478

ASTM American Society for Testing and Materials

A2LA American Association for Laboratory Accreditation

CARB California Air Resources Board

CAS Number Chemical Abstract Service registry Number

CFC Chlorofluorocarbon

CFU Colony-Forming Unit

DEC Department of Environmental Conservation

DEQ Department of Environmental Quality

DHS Department of Health Services

DOE Department of Ecology

DOH Department of Health

EPA U. S. Environmental Protection Agency

ELAP Environmental Laboratory Accreditation Program

GC Gas Chromatography

GC/MS Gas Chromatography/Mass Spectrometry

LOD Limit of Detection

LOQ Limit of Quantitation

LUFT Leaking Underground Fuel Tank

M ModifiedMCL Maximum Contaminant Level is the highest permissible concentration of a substance

allowed in drinking water as established by the USEPA.


MPN Most Probable Number

MRL Method Reporting Limit

NA Not Applicable

NC Not Calculated

NCASI National Council of the Paper Industry for Air and Stream Improvement

ND Not Detected

NIOSH National Institute for Occupational Safety and Health

PQL Practical Quantitation Limit

RCRA Resource Conservation and Recovery Act

SIM Selected Ion Monitoring

TPH Total Petroleum Hydrocarbonstr Trace level is the concentration of an analyte that is less than the PQL but greater than or

equal to the MDL.

Acronyms

22 of 34

00913479

Inorganic Data Qualifiers* The result is an outlier. See case narrative.

# The control limit criteria is not applicable. See case narrative.

B The analyte was found in the associated method blank at a level that is significant relative to the sample result as defined by the DOD or NELAC standards.

E The result is an estimate amount because the value exceeded the instrument calibration range.

J The result is an estimated value.

U The analyte was analyzed for, but was not detected ("Non-detect") at or above the MRL/MDL. DOD-QSM 4.2 definition : Analyte was not detected and is reported as less than the LOD or as defined by the project. The detection limit is adjusted for dilution.

i The MRL/MDL or LOQ/LOD is elevated due to a matrix interference.

X See case narrative.

Q See case narrative. One or more quality control criteria was outside the limits.

H The holding time for this test is immediately following sample collection. The samples were analyzed as soon as possible afterreceipt by the laboratory.

Metals Data Qualifiers# The control limit criteria is not applicable. See case narrative.


E The percent difference for the serial dilution was greater than 10%, indicating a possible matrix interference in the sample.

M The duplicate injection precision was not met.

N The Matrix Spike sample recovery is not within control limits. See case narrative.

S The reported value was determined by the Method of Standard Additions (MSA).


W The post-digestion spike for furnace AA analysis is out of control limits, while sample absorbance is less than 50% of spike absorbance.



+ The correlation coefficient for the MSA is less than 0.995.


Organic Data Qualifiers* The result is an outlier. See case narrative.


A A tentatively identified compound, a suspected aldol-condensation product.


C The analyte was qualitatively confirmed using GC/MS techniques, pattern recognition, or by comparing to historical data.

D The reported result is from a dilution.

E The result is an estimated value.


N The result is presumptive. The analyte was tentatively identified, but a confirmation analysis was not performed.

P The GC or HPLC confirmation criteria was exceeded. The relative percent difference is greater than 40% between the two analytical results.


i The MRL/MDL or LOQ/LOD is elevated due to a chromatographic interference.



Additional Petroleum Hydrocarbon Specific QualifiersF The chromatographic fingerprint of the sample matches the elution pattern of the calibration standard.

L The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates the presence of a greater amount of lighter molecular weight constituents than the calibration standard.

H The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates the presence of a greater amount of heavier molecular weight constituents than the calibration standard.

O The chromatographic fingerprint of the sample resembles an oil, but does not match the calibration standard.Y The chromatographic fingerprint of the sample resembles a petroleum product eluting in approximately the correct carbon range,

but the elution pattern does not match the calibration standard.

Z The chromatographic fingerprint does not resemble a petroleum product.

23 of 34

00913480

Agency Web Site Number

Alaska DEH http://dec.alaska.gov/eh/lab/cs/csapproval.htm UST-040

Arizona DHS http://www.azdhs.gov/lab/license/env.htm AZ0339

Arkansas - DEQ http://www.adeq.state.ar.us/techsvs/labcert.htm 88-0637

California DHS (ELAP) http://www.cdph.ca.gov/certlic/labs/Pages/ELAP.aspx 2795

DOD ELAP http://www.denix.osd.mil/edqw/Accreditation/AccreditedLabs.cfm L16-58-R4

Florida DOH http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm E87412

Hawaii DOH http://health.hawaii.gov/ - ISO 17025 http://www.pjlabs.com/ L16-57

Louisiana DEQ http://www.deq.louisiana.gov/page/la-lab-accreditation 03016

Maine DHS http://www.maine.gov/dhhs/ WA01276

Minnesota DOH http://www.health.state.mn.us/accreditation 053-999-457

Nevada DEP http://ndep.nv.gov/bsdw/labservice.htm WA01276

New Jersey DEP http://www.nj.gov/dep/enforcement/oqa.html WA005

New York - DOH https://www.wadsworth.org/regulatory/elap 12060

North Carolina DEQ

https://deq.nc.gov/about/divisions/water-resources/water-resources-data/water-sciences-home-page/laboratory-certification-branch/non-field-lab-certification 605

Oklahoma DEQ http://www.deq.state.ok.us/CSDnew/labcert.htm 9801

Oregon – DEQ (NELAP)http://public.health.oregon.gov/LaboratoryServices/EnvironmentalLaboratoryAccreditation/Pages/index.aspx WA100010

South Carolina DHEC http://www.scdhec.gov/environment/EnvironmentalLabCertification/ 61002

Texas CEQ http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html T104704427

Washington DOE http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html C544

Wyoming (EPA Region 8) https://www.epa.gov/region8-waterops/epa-region-8-certified-drinking-water- -

Kelso Laboratory Website www.alsglobal.com NA

ALS Group USA Corp. dba ALS Environmental (ALS) - KelsoState Certifications, Accreditations, and Licenses

Analyses were performed according to our laboratory’s NELAP-approved quality assurance program. A complete listing of specific NELAP-certified analytes, can be found in the certification section at www.ALSGlobal.com or at the accreditation bodies web site.Please refer to the certification and/or accreditation body's web site if samples are submitted for compliance purposes. The states highlighted above, require the analysis be listed on the state certification if used for compliance purposes and if the method/anlayte is offered by that state.

24 of 34

00913481

Case Narrative

ALS Environmental—Kelso Laboratory 1317 South 13th Avenue, Kelso, WA 98626 Phone (360)577-7222 Fax (360)636-1068 www.alsglobal.com

RIGHT SOLUTIONS | RIGHT PARTNER 25 of 34

00913482

CASE NARRATIVE

Client:Project:Sample Matrix:

Service Request:Date Received:

ALS Environmental - USALS-Houston EnvironmentalWater

K180865609/11/2018

All analyses were performed consistent with the quality assurance program of ALS Environmental. This report contains analytical results for samples designated for Tier IV validation deliverables including summary forms and all of the associated raw data for each of the analyses. When appropriate to the method, method blank results have been reported with each analytical test.

Sample Receipt:One water sample was received for analysis at ALS Environmental on 09/11/2018. The sample was received in good condition and consistent with the accompanying chain of custody form. The sample was stored in a refrigerator at 4ºC upon receipt at the laboratory.General Chemistry:No significant anomalies were noted with this analysis.

1317 South 13th Ave, Kelso, WA 98626 | 1-360-577-7222 | www.alsglobal.com

Approved by Date 09/18/201826 of 34

00913483

kelley.lovejoy

Kelley Lovejoy

Chain of Custody



00913484

A ~~

r1r15oi 10450 Stancliff Rd, Ste 210

Houston, TX 77099

T: + 1 281 530 5656

F: +1 281 530 5887

www.alsglobal.com

Subcontract Chain of Custody

SUBCONTRACT TO:

ALS Environmental Kelso

1317 S. 13th Avenue

Kelso, WA 98626

CUSTOMER INFORMATION:

Company:

Contact:

Address:

Phone~

Email:

Alternate Contact: Email:

ALS Houston

Rl Modashia

10450 Stancliff Rd, Ste 210

+1 281 530 5656

RJ. Modash ia@a lsg lobal. com

Jumoke M. Lawal

[email protected]

LAB SAMPLE ID CUEl'{f"SAMPLE ID ANALYSIS REQUESTED

1. HS18081539-01

DOD Level IV

LH18/24-SP650_083018

Comments: Please analyze for the analysis listed above. Send report to the emails shown above.

DOD IV

QC Level: DOD IV (DoD Data Package}

Relinquished By: .::s. ~Wl:Nv Received By: J/~·/· Cooler ID(s}:

(/ ..

COC ID: 9780

Phone: +1 360 501 3312

INVOICE INFORMATION:

Company: ALS Houston

Contact: Accounts Payable

Address: 10450 Stancliff Rd, Ste 210

Phone: +1 281 530 5656

Reference: HS18081539

TSR: Danielle Winnings

MATRIX

Water

Date/Time:

Date/Time:

Temperature(s):

COLLECT DATE DlJEDATE

30 Aug 2018 14:00

17 Sep 2018

q/to//71 1-X:OO

91r;T Ir J· ... /J910

28 of 34

00913485

t!~ rceb Cooler Receipt and Preservation Form

Client Ii!..--.) / /1f!U.Ji~°!Jl SZ:)ce Request Kl 8 6 ~ S ~(p Received: tJ /t( 11 f Opene;: !( ftR" ByQ -Unioaded:U ,{j- ;;z;t;: 1. Samples were received via? USPS <,, nu ""'_,,, -- .......

UPS

2. Samples were received in: (circle)~

3. Were custody seals on coolers?

Box

(!, N NA

If present, were custody seals intact? ~N

DHL PDX Courier Hand Delivered

Envelope Otiz er f If yes, how many and where? J I A-81,v;

If present, were they signed and dli:J?

Corrected. Corr. Thermometer ID

Cooler/COC ID Tracking Number NA

'?0

4. Packing material: Inserts ~c»;;;;;;;J;;;;p Gel Packs~)Dry Ice Sleeves

5. Were custody papers properly filled out (ink, signed, etc.)?

6. Were samples received in good condition (temperature, unbroken)? Indicate in the table below.

If applicable, tissue samples were received: Frozen Partially Thawed Tlrawed 7. Were all sample labels complete (i.e analysis, preservation, etc.)?

8. Did all sample labels and tags agree with custody papers? Indicate major discrepancies in the table on page 2.

9. Were appropriate bottles/containers and volumes received for the tests indicated?

I 0. Were the pH-preserved bottles (see SMO GEN SOP) received at the appropriate pH? Indicate in the table below

11. Were VOA vials received without headspace? Indicate in the table below.

12. Was C 12/Res negative?

I

'i Sample ID on Bottle Samele ID on COC Identified bv:

I I

i

NA

NA

NA

NA

NA

e ~ @I

Bottle Count Out of Head· Volume Reagent Lot Samele ID Bottle Type Temp space Broke pH Reaaent added Number

I I

NA

@ N

NAI Filed

€J fJ

~ tt y

y

y

Initials

N

N

N

N

N

N

N

N

Time

Notes, Discrepancies, & Resolutions: _____________________________________ _

7125116 'e __ of __ 29 of 34

00913486

General Chemistry



00913487

Client:

09/11/18

K1808656

Date Received:Date Collected:

Service Request:

WaterALS-Houston Environmental/HS18081539ALS Environmental - US

Sample Matrix:Project: 08/30/18

Carbon, Total Organic

Basis:Units: mg/L

NASM 5310 CNonePrep Method:

Analysis Method:

Lab CodeSample Name LODDate

AnalyzedDil.LOQResult Q

LH18/24-SP650_083018 09/13/18 02:2610.200.5018.0K1808656-001Method Blank 09/12/18 16:1410.200.50 UNDK1808656-MB1Method Blank 09/13/18 01:0510.200.50 UNDK1808656-MB2

Analytical Report


Printed 9/18/2018 2:51:09 PM 18-0000480734 rev 00Superset Reference:31 of 34

00913488

ALS Group USA, Corp.dba ALS Environmental

QA/QC Report

Client:ProjectSample Matrix:

Prep Method:Analysis Method:

ALS Environmental - USALS-Houston Environmental/HS18081539Water

SM 5310 CNone

Service Request:Date Collected:Date Received:

Basis:Units:

K180865608/30/1809/11/18

mg/LNA

Replicate Sample SummaryCarbon, Total Organic

Sample Name: Lab Code:Date

AnalyzedRPDLimitLOQMRL RPD

DuplicateResult Average

SampleResult

4 0.50 18.0 17.3 17.7 100.20LH18/24-SP650_083018 K1808656-001DUP 09/13/18

Results flagged with an asterisk (*) indicate values outside control criteria.

Results flagged with a pound (#) indicate the control criteria is not applicable.

Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded.


00913489

QA/QC Report

mg/LK1808656-001 Basis:Lab Code:

Units:Sample Name: LH18/24-SP650_083018

Carbon, Total OrganicMatrix Spike Summary

NA



Service Request:

Date Analyzed:Date Received:

K1808656

09/13/1809/11/18

Date Collected: 08/30/18

NoneSM 5310 C


Analyte Name ResultSample Result Spike Amount % Rec

Matrix SpikeK1808656-001MS

% Rec Limits


NADate Extracted:

Carbon, Total Organic 18.0 39.0 25.0 84 83-117





00913490

Sample Name

K1808656Date Analyzed:Service Request:


Sample Matrix:Project:Client:

Lab Control Sample SummaryCarbon, Total Organic

Analysis Method:Prep Method:

SM 5310 CNone NA

mg/LBasis:Units:

Analysis Lot: 606439

09/12/18

Spike AmountResult % Rec

% Rec Limits

NADate Extracted:

Lab Code

dba ALS EnvironmentalALS Group USA, Corp.

QA/QC Report

Lab Control Sample 83-11797 21.921.3K1808656-LCS1Lab Control Sample 83-11797 21.921.2K1808656-LCS2

18-0000480734 rev 00Superset Reference:Printed 9/18/2018 2:51:09 PM

34 of 34

00913491

WorkOrder: HS18081540Longhorn GW Treatment Plant Monthly Eff. Samples



Lakewood CO 80228

21-Sep-2018


1 of 595

00913492

September 17, 2018





Sincerely,


Laboratory Results for: Longhorn GW Treatment Plant Monthly Eff. Samples

Dear Marcia,


Project Manager


RJ Modashia



2 of 595

00913493


Work Order: HS18081540Project: Longhorn GW Treatment Plant Monthly Eff. Samples SAMPLE SUMMARY



HS18081540-02 30-Aug-2018 00:00 31-Aug-2018 09:00Trip Blank Als 050418-44 Water


3 of 595

00913494


Work Order:Longhorn GW Treatment Plant Monthly Eff. SamplesBhate Environmental Associates, Inc.

Project:

Work Order Comments


GCMS Semivolatiles by Method SW8270SIM

Batch ID: 132141Sample ID: LCSD-132141

LCSD RPD was above the control limits for surrogate 2-Fluorobiphenyl. The individual recoveries were in control. •

Sample ID: LH18/24-SP650_083018 (HS18081540-01)

The surrogate recoveries could not be determined due to dilution below the calibration range. •



MS and MSD is for an unrelated sample•

Metals by Method SW6020

Batch ID: 132160



Batch ID: R323061Sample ID: LH18/24-SP650_083018 (HS18081540-01)

Sample filtered•


4 of 595

00913495


Bhate Environmental Associates, Inc.Longhorn GW Treatment Plant Monthly Eff. SamplesLH18/24-SP650_083018

WorkOrder:Lab ID:

Collection Date:

HS18081540HS18081540-01


ANALYTICAL REPORT





1ug/L 06-Sep-2018 12:50U 0.301,1,1,2-Tetrachloroethane 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.201,1,1-Trichloroethane 1.00.50 0.50



1ug/L 06-Sep-2018 12:50U 0.201,1-Dichloroethane 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.201,1-Dichloroethene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.301,1-Dichloropropene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.401,2,3-Trichlorobenzene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.501,2,3-Trichloropropane 1.00.50 0.50


1ug/L 06-Sep-2018 12:50U 0.301,2,4-Trimethylbenzene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.201,2-Dibromo-3-chloropropane 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.201,2-Dibromoethane 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.501,2-Dichlorobenzene 1.00.50 0.50


1ug/L 06-Sep-2018 12:50U 0.501,2-Dichloropropane 1.00.50 0.50






1ug/L 06-Sep-2018 12:50U 0.502-Butanone 2.01.0 1.0

1ug/L 06-Sep-2018 12:50U 0.302-Chlorotoluene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 1.02-Hexanone 2.01.0 1.0


1ug/L 06-Sep-2018 12:50U 0.304-Isopropyltoluene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.704-Methyl-2-pentanone 2.01.0 1.0

1ug/L 06-Sep-2018 12:50U 0.40Acetone 2.02.0 2.0

1ug/L 06-Sep-2018 12:50U 0.20Benzene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.40Bromobenzene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.20Bromochloromethane 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.20Bromodichloromethane 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.40Bromoform 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.40Bromomethane 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.60Carbon disulfide 2.01.0 1.0

1ug/L 06-Sep-2018 12:50U 0.50Carbon tetrachloride 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.30Chlorobenzene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.30Chloroethane 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.20Chloroform 1.00.50 0.50



5 of 595

00913496



WorkOrder:Lab ID:

Collection Date:

HS18081540HS18081540-01


ANALYTICAL REPORT





1ug/L 06-Sep-2018 12:50U 0.20Chloromethane 1.00.50 0.50

1ug/L 06-Sep-2018 12:500.20cis-1,2-Dichloroethene 1.03.5 0.501ug/L 06-Sep-2018 12:50U 0.10cis-1,3-Dichloropropene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.30Dibromochloromethane 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.20Dibromomethane 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.30Dichlorodifluoromethane 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.30Ethylbenzene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 1.0Hexachlorobutadiene 1.01.0 1.0

1ug/L 06-Sep-2018 12:50U 0.30Isopropylbenzene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.50m,p-Xylene 2.01.0 1.0

1ug/L 06-Sep-2018 12:50U 0.40Methylene chloride 2.01.0 1.0

1ug/L 06-Sep-2018 12:50U 0.40n-Butylbenzene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.30n-Propylbenzene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.30Naphthalene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.30o-Xylene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.30sec-Butylbenzene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.30Styrene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.30tert-Butylbenzene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.30Tetrachloroethene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.20Toluene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.20trans-1,2-Dichloroethene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.20trans-1,3-Dichloropropene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.20Trichloroethene 1.00.50 0.50

1ug/L 06-Sep-2018 12:50U 0.30Trichlorofluoromethane 1.00.50 0.50

1ug/L 06-Sep-2018 12:500.20Vinyl chloride 1.01.4 0.50Surr: 1,2-Dichloroethane-d4 1%REC 06-Sep-2018 12:5088.1 81-1180Surr: 4-Bromofluorobenzene 1%REC 06-Sep-2018 12:5097.1 85-1140Surr: Dibromofluoromethane 1%REC 06-Sep-2018 12:5095.7 80-1190Surr: Toluene-d8 1%REC 06-Sep-2018 12:5090.4 89-1120

SEMIVOLATILES SIM Method:SW8270SIM Analyst: ACNPrep:SW3510 / 05-Sep-2018

100ug/L 06-Sep-2018 13:571.01,4-Dioxane 1.06.1 1.0Surr: 2-Fluorobiphenyl 100%REC 06-Sep-2018 13:57S0 40-1400

Surr: 4-Terphenyl-d14 100%REC 06-Sep-2018 13:57S0 40-1400

Surr: Nitrobenzene-d5 100%REC 06-Sep-2018 13:57S0 40-1400

ICP-MS METALS BY SW6020A Method:SW6020 Analyst: JDEPrep:SW3010A / 05-Sep-2018

1mg/L 06-Sep-2018 14:540.00190Barium 0.004000.137 0.002501mg/L 06-Sep-2018 14:54U 0.000600Lead 0.002000.00100 0.00100

1mg/L 06-Sep-2018 14:54U 0.00110Selenium 0.002000.00200 0.00200

1mg/L 06-Sep-2018 14:54U 0.000200Silver 0.002000.00100 0.00100



6 of 595

00913497



WorkOrder:Lab ID:

Collection Date:

HS18081540HS18081540-01


ANALYTICAL REPORT



HEXAVALENT CHROMIUM BY SW7196A Method:SW7196 Analyst: KVLPrep:SW7196

1mg/L 31-Aug-2018 11:57U 0.00600Chromium, Hexavalent 0.01000.0100 0.0100SUBCONTRACT ANALYSIS - PERCHLORATE (EPA 6850)





7 of 595

00913498


Bhate Environmental Associates, Inc.Longhorn GW Treatment Plant Monthly Eff. SamplesTrip Blank Als 050418-44

WorkOrder:Lab ID:

Collection Date:

HS18081540HS18081540-02


ANALYTICAL REPORT
































1ug/L 06-Sep-2018 12:25U 0.40Acetone 2.02.0 2.0

1ug/L 06-Sep-2018 12:25U 0.20Benzene 1.00.50 0.50













8 of 595

00913499


Bhate Environmental Associates, Inc.Longhorn GW Treatment Plant Monthly Eff. SamplesTrip Blank Als 050418-44

WorkOrder:Lab ID:

Collection Date:

HS18081540HS18081540-02


ANALYTICAL REPORT






1ug/L 06-Sep-2018 12:25U 0.20cis-1,2-Dichloroethene 1.00.50 0.50

1ug/L 06-Sep-2018 12:25U 0.10cis-1,3-Dichloropropene 1.00.50 0.50












1ug/L 06-Sep-2018 12:25U 0.30o-Xylene 1.00.50 0.50


1ug/L 06-Sep-2018 12:25U 0.30Styrene 1.00.50 0.50



1ug/L 06-Sep-2018 12:25U 0.20Toluene 1.00.50 0.50





1ug/L 06-Sep-2018 12:25U 0.20Vinyl chloride 1.00.50 0.50

Surr: 1,2-Dichloroethane-d4 1%REC 06-Sep-2018 12:2588.3 81-1180Surr: 4-Bromofluorobenzene 1%REC 06-Sep-2018 12:25102 85-1140Surr: Dibromofluoromethane 1%REC 06-Sep-2018 12:2595.2 80-1190Surr: Toluene-d8 1%REC 06-Sep-2018 12:2589.7 89-1120



9 of 595

00913500

WEIGHT LOG

HS18081540Longhorn GW Treatment Plant Monthly Eff. SamplesBhate Environmental Associates, Inc.

WorkOrder:Project:Client:

Batch ID: 132141 Method: SEMIVOLATILES SIM 3510_B_SIMPrep:

ContainerSampIDSample Wt/Vol

Final Volume

Prep Factor

HS18081540-01 1 980 1 (mL) 0.00102

Batch ID: 132160 Method: ICP-MS METALS BY SW6020A 3010APrep:


Final Volume

Prep Factor

HS18081540-01 1 10 10 (mL) 1


10 of 595

00913501

Client:Longhorn GW Treatment Plant Monthly Eff. SamplesBhate Environmental Associates, Inc.

WorkOrder:Project:



Batch ID 132141 Test Name : SEMIVOLATILES SIM Matrix: Water

05 Sep 2018 08:30 06 Sep 2018 13:57HS18081540-01 30 Aug 2018 14:00 100LH18/24-SP650_083018

Batch ID 132160 Test Name : ICP-MS METALS BY SW6020A Matrix: Water



06 Sep 2018 12:50HS18081540-01 30 Aug 2018 14:00 1LH18/24-SP650_083018

06 Sep 2018 12:25HS18081540-02 30 Aug 2018 00:00 1Trip Blank Als 050418-44

Batch ID R323061 Test Name : HEXAVALENT CHROMIUM BY SW7196A Matrix: Water

31 Aug 2018 11:57HS18081540-01 30 Aug 2018 14:00 1LH18/24-SP650_083018


17 Sep 2018 09:31HS18081540-01 30 Aug 2018 14:00 1LH18/24-SP650_083018


11 of 595

00913502

Client:Project:

Bhate Environmental Associates, Inc.Longhorn GW Treatment Plant Monthly Eff. Samples


QC BATCH REPORT

Batch ID: 132160 Instrument: ICPMS05 Method: SW6020


Run ID: ICPMS05_322949 SeqNo: 4718239 PrepDate: 05-Sep-2018 DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Barium 0.00250 U0.00400

Lead 0.00100 U0.00200

Selenium 0.00200 U0.00200

Silver 0.00100 U0.00200




Value %RECControl

LimitRPD Ref


LCS

Client ID:

Barium 0.04816 0.05 0 96.3 80 - 1200.00400

Lead 0.05155 0.05 0 103 80 - 1200.00200

Selenium 0.04796 0.05 0 95.9 80 - 1200.00200

Silver 0.04759 0.05 0 95.2 80 - 1200.00200




Value %RECControl

LimitRPD Ref


MS

Client ID:

Barium 0.07238 0.05 0.0235 97.8 80 - 1200.00400

Lead 0.04868 0.05 0.000141 97.1 80 - 1200.00200

Selenium 0.04576 0.05 0.000541 90.4 80 - 1200.00200

Silver 0.04675 0.05 0.000039 93.4 80 - 1200.00200




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Barium 0.07303 0.05 0.0235 99.1 80 - 120 0.07238 0.902 200.00400

Lead 0.04978 0.05 0.000141 99.3 80 - 120 0.04868 2.23 200.00200

Selenium 0.04832 0.05 0.000541 95.6 80 - 120 0.04576 5.44 200.00200

Silver 0.04661 0.05 0.000039 93.1 80 - 120 0.04675 0.3 200.00200



12 of 595

00913503

Client:Project:



QC BATCH REPORT


Sample ID: HS18081504-01PDS Units: mg/L Analysis Date: 06-Sep-2018 14:48



Value %RECControl

LimitRPD Ref


PDS

Client ID:

Barium 0.1185 0.1 0.0235 95.0 75 - 1250.00400

Lead 0.09854 0.1 0.000141 98.4 75 - 1250.00200

Selenium 0.08799 0.1 0.000541 87.5 75 - 1250.00200

Silver 0.09738 0.1 0.000039 97.3 75 - 1250.00200

Sample ID: HS18081504-01SD Units: mg/L Analysis Date: 06-Sep-2018 14:42



Value %RECControl

LimitRPD Ref

Value %D%D Limit Qual

SD

Client ID:

Barium 0.02326 0.0235 1.03 100.0200

Lead 0.00500 0.000141 0 10 U0.0100

Selenium 0.0100 0.000541 0 10 U0.0100

Silver 0.00500 0.000039 0 10 U0.0100




13 of 595

00913504

Client:Project:



QC BATCH REPORT

Batch ID: 132141 Instrument: SV-5 Method: SW8270SIM

Sample ID: MBLK-132141 Units: ug/L Analysis Date: 06-Sep-2018 11:33

Run ID: SV-5_322966 SeqNo: 4717474 PrepDate: 05-Sep-2018 DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

1,4-Dioxane 0.010 U0.010

0.08401 0.08 0 105 40 - 1400Surr: 2-Fluorobiphenyl

0.06476 0.08 0 81.0 40 - 1400Surr: 4-Terphenyl-d14

0.06457 0.08 0 80.7 40 - 1400Surr: Nitrobenzene-d5

Sample ID: LCS-132141 Units: ug/L Analysis Date: 06-Sep-2018 11:54



Value %RECControl

LimitRPD Ref


LCS

Client ID:

1,4-Dioxane 0.07025 0.08 0 87.8 40 - 1400.010


0.08524 0.08 0 107 40 - 1400Surr: 4-Terphenyl-d14

0.08248 0.08 0 103 40 - 1400Surr: Nitrobenzene-d5

Sample ID: LCSD-132141 Units: ug/L Analysis Date: 06-Sep-2018 12:14



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

1,4-Dioxane 0.06551 0.08 0 81.9 40 - 140 0.07025 6.98 200.010

0.08013 0.08 0 100 40 - 140 0.1099 31.3 20 R0Surr: 2-Fluorobiphenyl

0.07146 0.08 0 89.3 40 - 140 0.08524 17.6 200Surr: 4-Terphenyl-d14

0.07791 0.08 0 97.4 40 - 140 0.08248 5.71 200Surr: Nitrobenzene-d5




14 of 595

00913505

Client:Project:



QC BATCH REPORT


Sample ID: VBLKW-180906 Units: ug/L Analysis Date: 06-Sep-2018 12:01



Value %RECControl

LimitRPD Ref


MBLK

Client ID:






















2-Butanone 1.0 U2.0


2-Hexanone 1.0 U2.0




Acetone 2.0 U2.0

Benzene 0.50 U1.0




Bromoform 0.50 U1.0




15 of 595

00913506

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:















m,p-Xylene 1.0 U2.0





o-Xylene 0.50 U1.0


Styrene 0.50 U1.0



Toluene 0.50 U1.0









45.54 50 0 91.1 89 - 1121.0Surr: Toluene-d8



16 of 595

00913507

Client:Project:



QC BATCH REPORT


Sample ID: VLCSW-180906 Units: ug/L Analysis Date: 06-Sep-2018 11:36



Value %RECControl

LimitRPD Ref


LCS

Client ID:

1,1,1,2-Tetrachloroethane 21.54 20 0 108 78 - 1241.0



1,1,2-Trichloroethane 20.52 20 0 103 80 - 1191.0

1,1-Dichloroethane 17.2 20 0 86.0 77 - 1251.0

1,1-Dichloroethene 19.31 20 0 96.5 71 - 1311.0







1,2-Dibromoethane 21.22 20 0 106 77 - 1211.0


1,2-Dichloroethane 21.31 20 0 107 73 - 1281.0



1,3-Dichlorobenzene 20.25 20 0 101 80 - 1191.0




2-Butanone 35.47 40 0 88.7 56 - 1432.0

2-Chlorotoluene 20.94 20 0 105 79 - 1221.0

2-Hexanone 40.95 40 0 102 57 - 1392.0

4-Chlorotoluene 21.86 20 0 109 78 - 1221.0



Acetone 34.91 40 0 87.3 39 - 1602.0

Benzene 20.57 20 0 103 79 - 1201.0

Bromobenzene 20.35 20 0 102 80 - 1201.0



Bromoform 22.32 20 0 112 66 - 1301.0

Bromomethane 22.08 20 0 110 53 - 1411.0



17 of 595

00913508

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:



Chlorobenzene 21.2 20 0 106 82 - 1181.0

Chloroethane 17.91 20 0 89.5 60 - 1381.0

Chloroform 18.83 20 0 94.2 79 - 1241.0

Chloromethane 16.77 20 0 83.9 50 - 1391.0




Dibromomethane 22.11 20 0 111 79 - 1231.0


Ethylbenzene 23.26 20 0 116 79 - 1211.0

Hexachlorobutadiene 21.09 20 0 105 66 - 1341.0

Isopropylbenzene 20.97 20 0 105 72 - 1311.0

m,p-Xylene 46.68 40 0 117 80 - 1212.0


Naphthalene 20.37 20 0 102 61 - 1281.0

n-Butylbenzene 20.09 20 0 100 75 - 1281.0

n-Propylbenzene 21.78 20 0 109 76 - 1261.0

o-Xylene 22.66 20 0 113 78 - 1221.0


Styrene 21.76 20 0 109 78 - 1231.0



Toluene 19.93 20 0 99.7 80 - 1211.0





Vinyl chloride 19.03 20 0 95.2 58 - 1371.0




44.55 50 0 89.1 89 - 1121.0Surr: Toluene-d8



18 of 595

00913509

Client:Project:



QC BATCH REPORT


Sample ID: HS18090060-11MS Units: ug/L Analysis Date: 06-Sep-2018 16:30



Value %RECControl

LimitRPD Ref


MS

Client ID:





1,1-Dichloroethane 17.1 20 0 85.5 77 - 1251.0

1,1-Dichloroethene 18.08 20 0 90.4 71 - 1311.0







1,2-Dibromoethane 18.74 20 0 93.7 77 - 1211.0


1,2-Dichloroethane 18.03 20 0 90.1 73 - 1281.0







2-Butanone 32.34 40 0 80.9 56 - 1432.0

2-Chlorotoluene 19.03 20 0 95.2 79 - 1221.0

2-Hexanone 32.81 40 0 82.0 57 - 1392.0

4-Chlorotoluene 18.96 20 0 94.8 78 - 1221.0

4-Isopropyltoluene 17 20 0 85.0 77 - 1271.0


Acetone 27.41 40 0 68.5 39 - 1602.0

Benzene 18.36 20 0.2509 90.6 79 - 1201.0

Bromobenzene 17.88 20 0 89.4 80 - 1201.0



Bromoform 19 20 0 95.0 66 - 1301.0

Bromomethane 20.16 20 0 101 53 - 1411.0



19 of 595

00913510

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS

Client ID:



Chlorobenzene 19.1 20 0 95.5 82 - 1181.0

Chloroethane 16.74 20 0 83.7 60 - 1381.0

Chloroform 17.49 20 0 87.4 79 - 1241.0

Chloromethane 14.44 20 0 72.2 50 - 1391.0




Dibromomethane 19.23 20 0 96.1 79 - 1231.0


Ethylbenzene 21.46 20 0.7396 104 79 - 1211.0



m,p-Xylene 42.17 40 0 105 80 - 1212.0


Naphthalene 16.09 20 0 80.5 61 - 1281.0

n-Butylbenzene 17.97 20 0 89.8 75 - 1281.0

n-Propylbenzene 19.59 20 0 97.9 76 - 1261.0

o-Xylene 20.32 20 0 102 78 - 1221.0


Styrene 18.85 20 0 94.3 78 - 1231.0



Toluene 18.43 20 0 92.2 80 - 1211.0





Vinyl chloride 17.7 20 0 88.5 58 - 1371.0




44.45 50 0 88.9 89 - 112 S1.0Surr: Toluene-d8



20 of 595

00913511

Client:Project:



QC BATCH REPORT


Sample ID: HS18090060-11MSD Units: ug/L Analysis Date: 06-Sep-2018 16:55



Value %RECControl

LimitRPD Ref


MSD

Client ID:





1,1-Dichloroethane 15.38 20 0 76.9 77 - 125 17.1 10.6 20 S1.0

1,1-Dichloroethene 17.47 20 0 87.3 71 - 131 18.08 3.44 201.0







1,2-Dibromoethane 18.32 20 0 91.6 77 - 121 18.74 2.26 201.0


1,2-Dichloroethane 19.15 20 0 95.7 73 - 128 18.03 6.02 201.0







2-Butanone 32.16 40 0 80.4 56 - 143 32.34 0.553 202.0

2-Chlorotoluene 19.02 20 0 95.1 79 - 122 19.03 0.0459 201.0

2-Hexanone 32.93 40 0 82.3 57 - 139 32.81 0.347 202.0

4-Chlorotoluene 17.95 20 0 89.8 78 - 122 18.96 5.46 201.0

4-Isopropyltoluene 17.66 20 0 88.3 77 - 127 17 3.78 201.0

4-Methyl-2-pentanone 32.31 40 0 80.8 67 - 130 33.57 3.83 202.0

Acetone 29.93 40 0 74.8 39 - 160 27.41 8.79 202.0

Benzene 18.6 20 0.2509 91.8 79 - 120 18.36 1.31 201.0

Bromobenzene 17.78 20 0 88.9 80 - 120 17.88 0.574 201.0



Bromoform 18.77 20 0 93.8 66 - 130 19 1.25 201.0

Bromomethane 21.98 20 0 110 53 - 141 20.16 8.67 201.0



21 of 595

00913512

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD

Client ID:

Carbon disulfide 34.57 40 0 86.4 64 - 133 34.53 0.114 202.0


Chlorobenzene 19.08 20 0 95.4 82 - 118 19.1 0.116 201.0

Chloroethane 17.62 20 0 88.1 60 - 138 16.74 5.13 201.0

Chloroform 17.65 20 0 88.2 79 - 124 17.49 0.915 201.0

Chloromethane 15.93 20 0 79.6 50 - 139 14.44 9.8 201.0




Dibromomethane 19.9 20 0 99.5 79 - 123 19.23 3.42 201.0


Ethylbenzene 20.95 20 0.7396 101 79 - 121 21.46 2.36 201.0



m,p-Xylene 40.1 40 0 100 80 - 121 42.17 5.04 202.0


Naphthalene 17.48 20 0 87.4 61 - 128 16.09 8.28 201.0

n-Butylbenzene 18.49 20 0 92.5 75 - 128 17.97 2.88 201.0

n-Propylbenzene 19.95 20 0 99.8 76 - 126 19.59 1.84 201.0

o-Xylene 19.68 20 0 98.4 78 - 122 20.32 3.2 201.0


Styrene 18.9 20 0 94.5 78 - 123 18.85 0.266 201.0



Toluene 16.76 20 0 83.8 80 - 121 18.43 9.48 201.0



Trichloroethene 20.17 20 0 101 79 - 123 20.13 0.202 201.0


Vinyl chloride 18.95 20 0 94.7 58 - 137 17.7 6.83 201.0


49.97 50 0 99.9 85 - 114 50.65 1.36 201.0Surr: 4-Bromofluorobenzene


41.24 50 0 82.5 89 - 112 44.45 7.49 20 S1.0Surr: Toluene-d8



22 of 595

00913513

Client:Project:



QC BATCH REPORT





23 of 595

00913514

Client:Project:



QC BATCH REPORT

Batch ID: R323061 Instrument: UV-2450 Method: SW7196




Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Chromium, Hexavalent 0.0100 U0.0100




Value %RECControl

LimitRPD Ref


LCS

Client ID:

Chromium, Hexavalent 0.26 0.25 0 104 80 - 1200.0100




Value %RECControl

LimitRPD Ref


MS

Client ID: LH18/24-SP650_083018

Chromium, Hexavalent 0.267 0.25 -0.001 107 75 - 1250.0100




Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18/24-SP650_083018

Chromium, Hexavalent 0.264 0.25 -0.001 106 75 - 125 0.267 1.13 200.0100




24 of 595

00913515



Bhate Environmental Associates, Inc.Longhorn GW Treatment Plant Monthly Eff. SamplesHS18081540


a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution




25 of 595

00913516




Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


26 of 595

00913517

RPG


HS18081540

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

2.4c/2.1c uc/c IR 254317708/31/2018 10:45


Yes No N/A

Yes No N/A

Checklist completed by: Raegen GigaDateeSignatureDateeSignature

31-Aug-201831-Aug-2018

FedEx Priority Overnightwater Carrier name:Matrices:




Comments:

Corrective Action:

Yes



27 of 595

00913518

28 o

f 595

00913519

29 o

f 595

00913520

Volatile Organics Data Package

Bhate Environmental Associates, Inc. Project: LONGHORN GW TREATMENT PLANT

MONTHLY EFF. SAMPLES ALS WO# HS18081540

30 of 595

00913521

Form 2A - System Monitoring Compound Recovery

HS18081540

Longhorn GW Treatment Plant Monthly Eff. Samples



VOA2Instrument:Method:

SW8260

Run ID: VOA2_323037

Result Spike Recovery Low High FlagSample ID: HS18081540-02 (4718900) 06-Sep-2018 10:25%REC DF:1

118811,2-Dichloroethane-d4 88.344.16 50.00114854-Bromofluorobenzene 10251.22 50.0011980Dibromofluoromethane 95.247.59 50.0011289Toluene-d8 89.744.83 50.00

Sample ID: HS18081540-01 (4718901) 06-Sep-2018 10:50%REC DF:1

118811,2-Dichloroethane-d4 88.144.06 50.00114854-Bromofluorobenzene 97.148.56 50.0011980Dibromofluoromethane 95.747.86 50.0011289Toluene-d8 90.445.18 50.00

Sample ID: VBLKW-180906 (4718899) 06-Sep-2018 10:01%REC DF:1

118811,2-Dichloroethane-d4 88.144.06 50.00114854-Bromofluorobenzene 96.848.41 50.0011980Dibromofluoromethane 91.945.94 50.0011289Toluene-d8 91.145.54 50.00

Sample ID: VLCSW-180906 (4718898) 06-Sep-2018 09:36%REC DF:1

118811,2-Dichloroethane-d4 90.545.26 50.00114854-Bromofluorobenzene 10351.56 50.0011980Dibromofluoromethane 90.745.34 50.0011289Toluene-d8 89.144.55 50.00


31 of 595

00913522

Form 3 - Method Spike Recovery



Date Analyzed: 03-Aug-2018 00:56µg/LUnits:

GCMS VolatilesDept:

Lab Sample ID: VSTD050

QC Limits Rec.% Rec

Spike Added

Sample AmountAnalyte

Analysis Method: SW8260

Flag

Prep Date:Instrument ID: VOA2

1,1,1,2-Tetrachloroethane 45.87 91.7 80 - 12050.00

1,1,1-Trichloroethane 45.41 90.8 80 - 12050.00

1,1,2,2-Tetrachloroethane 44.71 89.4 80 - 12050.00

1,1,2-Trichloroethane 46.39 92.8 80 - 12050.00

1,1-Dichloroethane 47.27 94.5 80 - 12050.00

1,1-Dichloroethene 46.98 94.0 80 - 12050.00

1,1-Dichloropropene 50.82 102 80 - 12050.00

1,2,3-Trichlorobenzene 49.05 98.1 80 - 12050.00

1,2,3-Trichloropropane 45.48 91.0 80 - 12050.00

1,2,4-Trichlorobenzene 48.81 97.6 80 - 12050.00

1,2,4-Trimethylbenzene 52.06 104 80 - 12050.00

1,2-Dibromo-3-chloropropane 47.74 95.5 80 - 12050.00

1,2-Dibromoethane 49.13 98.3 80 - 12050.00

1,2-Dichlorobenzene 45.29 90.6 80 - 12050.00

1,2-Dichloroethane 48.45 96.9 80 - 12050.00

1,2-Dichloropropane 47.42 94.8 80 - 12050.00

1,3,5-Trimethylbenzene 46.14 92.3 80 - 12050.00





2-Butanone 104.1 104 80 - 120100.0

2-Chlorotoluene 51.49 103 80 - 12050.00

2-Hexanone 98.60 98.6 80 - 120100.0

4-Chlorotoluene 52.01 104 80 - 12050.00

4-Isopropyltoluene 42.38 84.8 80 - 12050.00

4-Methyl-2-pentanone 94.43 94.4 80 - 120100.0

Acetone 103.9 104 80 - 120100.0

Benzene 44.96 89.9 80 - 12050.00

Bromobenzene 45.96 91.9 80 - 12050.00

Bromochloromethane 51.74 103 80 - 12050.00

Bromodichloromethane 47.85 95.7 80 - 12050.00

Bromoform 49.44 98.9 80 - 12050.00

Bromomethane 57.98 116 80 - 12050.00

Carbon disulfide 95.78 95.8 80 - 120100.0

Carbon tetrachloride 50.25 100 80 - 12050.00

Chlorobenzene 45.39 90.8 80 - 12050.00

Chloroethane 45.44 90.9 80 - 12050.00

Chloroform 46.52 93.0 80 - 12050.00

Chloromethane 46.41 92.8 80 - 12050.00

20-Sep-18Date: ALS Group USA, Corp

* = Outside regulatory limit32 of 595

00913523

Form 3 - Method Spike Recovery



Date Analyzed: 03-Aug-2018 00:56µg/LUnits:

GCMS VolatilesDept:

Lab Sample ID: VSTD050

QC Limits Rec.% Rec

Spike Added

Sample AmountAnalyte

Analysis Method: SW8260

Flag

Prep Date:Instrument ID: VOA2

cis-1,2-Dichloroethene 48.79 97.6 80 - 12050.00

cis-1,3-Dichloropropene 51.06 102 80 - 12050.00

Dibromochloromethane 48.10 96.2 80 - 12050.00

Dibromomethane 51.22 102 80 - 12050.00

Dichlorodifluoromethane 46.65 93.3 80 - 12050.00

Ethylbenzene 51.06 102 80 - 12050.00

Hexachlorobutadiene 44.83 89.7 80 - 12050.00

Isopropylbenzene 42.96 85.9 80 - 12050.00

m,p-Xylene 105.3 105 80 - 120100.0

Methylene chloride 50.43 101 80 - 12050.00

n-Butylbenzene 44.30 88.6 80 - 12050.00

n-Propylbenzene 51.59 103 80 - 12050.00

Naphthalene 51.47 103 80 - 12050.00

o-Xylene 52.29 105 80 - 12050.00

sec-Butylbenzene 42.17 84.3 80 - 12050.00

Styrene 47.12 94.2 80 - 12050.00

tert-Butylbenzene 51.77 104 80 - 12050.00

Tetrachloroethene 43.09 86.2 80 - 12050.00

Toluene 43.58 87.2 80 - 12050.00

trans-1,2-Dichloroethene 49.48 99.0 80 - 12050.00

trans-1,3-Dichloropropene 52.88 106 80 - 12050.00

Trichloroethene 46.23 92.5 80 - 12050.00

Trichlorofluoromethane 45.52 91.0 80 - 12050.00

Vinyl chloride 45.84 91.7 80 - 12050.00

20-Sep-18Date: ALS Group USA, Corp

* = Outside regulatory limit33 of 595

00913524

Form 4 - Method Blank Summary

HS14080841



WorkOrder:Project:Client: VOA2Instrument:

Method: SW8260

Client Samp ID Samp ID File ID Date Analyzed

Run ID: VOA2_323037

VBLKW-180906 VBLKW-180906 D090606.D 06-Sep-2018 10:01VLCSW-180906 VLCSW-180906 D090605.D 06-Sep-2018 09:36Trip Blank Als 050418-44 HS18081540-02 D090607.D 06-Sep-2018 10:25LH18/24-SP650_083018 HS18081540-01 D090608.D 06-Sep-2018 10:50ZZZZZZ HS18090060-11 D090613.D 06-Sep-2018 12:52ZZZZZZMS HS18090060-11MS D090617.D 06-Sep-2018 14:30ZZZZZZMSD HS18090060-11MSD D090618.D 06-Sep-2018 14:55


34 of 595

00913525

Form 5 - Volatile Instrument Performance Check BROMOFLUOROBENZENE (BFB)

Lab File ID:

m/e % Relative Abundance

Injection Date: Injection Time:

E080201.DVOA2Instrument ID:02-Aug-20187:45 PM



Ion Abundance Criterion50 15.0 - 40.0% of mass 95 18.7

75 30.0 - 60.0% of mass 95 46.1 95 Base peak, 100% relative abundance 100.0 96 5.0 - 9.0% of mass 95 6.5

173 Less than 2.0% of mass 174 0.0 ( 0.0) 1174 50.0 - 120.0% of mass 95 83.8175 4.0 - 9.0% of mass 174 6.4 ( 7.6) 1176 93.0 - 101.0% of mass 174 82.8 ( 98.9) 1177 5.0 - 9.0% of mass 176 5.0 ( 6.1) 2

EPA Sample No. Date AnalyzedLab Sample ID Lab File IDThis check applies to following Samples, MS, MSD, Blanks and Standards

VSTD0005 VSTD0005 02-Aug-2018 20:37E080203.DVSTD001 VSTD001 02-Aug-2018 21:03E080204.DVSTD002 VSTD002 02-Aug-2018 21:29E080205.DVSTD005 VSTD005 02-Aug-2018 21:55E080206.DVSTD010 VSTD010 02-Aug-2018 22:21E080207.DVSTD020 VSTD020 02-Aug-2018 22:47E080208.DVSTD050 VSTD050 02-Aug-2018 23:12E080209.DVSTD100 VSTD100 02-Aug-2018 23:38E080210.DVSTD200 VSTD200 03-Aug-2018 00:04E080211.DVSTD050 VSTD050 03-Aug-2018 00:56E080213.D

1-Value is % mass 174 2-Value is % mass 176


35 of 595

00913526

Form 5 - Volatile Instrument Performance Check BROMOFLUOROBENZENE (BFB)

Lab File ID:

m/e % Relative Abundance


D090601.DVOA2Instrument ID:06-Sep-20187:58 AM



Ion Abundance Criterion50 15.0 - 40.0% of mass 95 17.5

75 30.0 - 60.0% of mass 95 46.7 95 Base peak, 100% relative abundance 100.0 96 5.0 - 9.0% of mass 95 7.8

173 Less than 2.0% of mass 174 1.0 ( 1.1) 1174 50.0 - 120.0% of mass 95 94.6175 4.0 - 9.0% of mass 174 7.2 ( 7.6) 1176 93.0 - 101.0% of mass 174 93.8 ( 99.1) 1177 5.0 - 9.0% of mass 176 5.2 ( 5.5) 2

EPA Sample No. Date AnalyzedLab Sample ID Lab File IDThis check applies to following Samples, MS, MSD, Blanks and Standards

CCV CCV 06-Sep-2018 08:47D090603.DVLCSW-180906 VLCSW-180906 06-Sep-2018 09:36D090605.DVBLKW-180906 VBLKW-180906 06-Sep-2018 10:01D090606.DHS18081540-02 HS18081540-02 06-Sep-2018 10:25D090607.DHS18081540-01 HS18081540-01 06-Sep-2018 10:50D090608.DZZZZZZZZZZ-11 ZZZZZZZZZZ-11 06-Sep-2018 12:52D090613.DZZZZZZZZZZ-11MS ZZZZZZZZZZ-11MS 06-Sep-2018 14:30D090617.DZZZZZZZZZZ-11MSD ZZZZZZZZZZ-11MSD 06-Sep-2018 14:55D090618.DCCV_END CCV_END 06-Sep-2018 19:37D090629.D

1-Value is % mass 174 2-Value is % mass 176


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Project:Client: Calibrationtion Date:

Form 6 - Volatile Initial Calibration Data

Run ID: CAL Run ID: VOA2_323037 VOA2_3213528/2/2018 10:37:00 PM

Sample ID File ID Analysis DateVSTD0005 E080203.D 02-Aug-2018 22:37VSTD001 E080204.D 02-Aug-2018 23:03VSTD002 E080205.D 02-Aug-2018 23:29VSTD005 E080206.D 02-Aug-2018 23:55VSTD010 E080207.D 03-Aug-2018 00:21VSTD020 E080208.D 03-Aug-2018 00:47VSTD050 E080209.D 03-Aug-2018 01:12VSTD100 E080210.D 03-Aug-2018 01:38VSTD200 E080211.D 03-Aug-2018 02:04

Date: 20-Sep-18ALS Houston, US

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WorkOrder:




Compound

1

1,1,1,2-Tetrachloroethane

# Amount RRF RRF# # RRF# RRF0.41035 0.420052 3 0.41648 0.42114

8 0.382090.3922276 0.406520.3948759 0.35562 010

1

1,1,1-Trichloroethane


8 0.782720.8296676 0.85130.8219459 0.74612 010

1

1,1,2,2-Tetrachloroethane


8 1.235631.2783376 1.340781.3589359 1.14599 010

1

1,1,2-Trichloroethane


8 0.311890.3186676 0.338860.3323259 0.29213 010

1

1,1-Dichloroethane


8 1.137881.1844176 1.223451.1394559 1.08615 010

1

1,1-Dichloroethene


8 0.464740.4859476 0.474230.458759 0.44714 010

1

1,1-Dichloropropene


8 0.404990.42876 0.449540.445659 0.38604 010

1

1,2,3-Trichlorobenzene

# Amount RRF RRF# # RRF# RRF156 10332 3 3463 143604

8 36480417418676 682893104659 733571 010

Date: 20-Sep-18ALS Houston, US

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Compound

1

1,2,3-Trichloropropane


8 1.237891.2481176 1.274991.2770359 1.15785 010

1

1,2,4-Trichlorobenzene


8 41949020210276 791943539459 843176 010

1

1,2,4-Trimethylbenzene


8 3.020443.2156876 3.377413.3891159 2.76187 010

1

1,2-Dibromo-3-chloropropane


8 893414404576 17461821859 177752 010

1

1,2-Dibromoethane


8 0.39480.4052176 0.41220.40759 0.37411 010

1

1,2-Dichlorobenzene


8 1.692781.7844876 1.880791.8289659 1.56076 010

1

1,2-Dichloroethane


8 0.457580.4707876 0.47740.4502259 0.42537 010

1

1,2-Dichloropropane


8 0.401910.4150976 0.44380.445759 0.37497 010

1

1,3,5-Trimethylbenzene


8 110560159856176 25193512549759 2054572 010


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WorkOrder:




Compound

1

1,3-Dichlorobenzene


8 1.790371.8674676 1.927091.8409259 1.67746 010

1

1,3-Dichloropropane


8 0.613440.6329876 0.658690.6482659 0.56752 010

1

1,4-Dichlorobenzene


8 1.737261.7735176 1.774341.7002759 1.6521 010

1

2,2-Dichloropropane


8 0.727410.7734776 0.786170.7211759 0.6979 010

1

2-Butanone


8 0.34140.3530576 0.345040.3278159 0.32379 010

1

2-Chlorotoluene


8 98589152518276 21669511051259 1862121 010

1

2-Hexanone


8 0.287660.3172376 0.321810.2967959 0.26552 010

1

4-Chlorotoluene


8 106838156175676 23602111942759 2027600 010

1

4-Isopropyltoluene


8 2.950723.136776 3.30423.176259 2.74178 010


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WorkOrder:




Compound

1

4-Methyl-2-pentanone


8 0.496310.5240576 0.552010.5438259 0.44482 010

1

Acetone


8 25214313089276 533293091759 496304 010

1

Benzene


8 1.312591.3870576 1.473791.448159 1.20003 010

1

Bromobenzene


8 1.038621.0740976 1.124241.0976359 0.9731 010

1

Bromochloromethane


8 0.29910.3049776 0.307290.2943359 0.26862 010

1

Bromodichloromethane


8 0.468960.4799476 0.497480.4867259 0.43104 010

1

Bromoform


8 0.32230.3260776 0.324120.3134259 0.30068 010

1

Bromomethane


8 21050811630376 508102850459 407619 010

1

Carbon disulfide


8 0.977271.0290976 1.041890.9962359 0.94304 010


41 of 595

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WorkOrder:




Compound

1

Carbon tetrachloride


8 39091320747476 866864367159 801906 010

1

Chlorobenzene


8 0.956261.0190376 1.046581.0198559 0.87778 010

1

Chloroethane


8 25202613149676 574302969659 461334 010

1

Chloroform


8 0.926760.962576 0.987550.9802559 0.88053 010

1

Chloromethane


8 0.96821.0424476 1.12871.0921959 0.93192 010

1

cis-1,2-Dichloroethene


8 0.611880.636976 0.669010.6371459 0.59039 010

1

cis-1,3-Dichloropropene


8 0.583970.5952776 0.604890.5893859 0.53738 010

1

Dibromochloromethane


8 0.43730.4506276 0.454360.4422259 0.40573 010

1

Dibromomethane


8 0.217240.2199976 0.221280.215359 0.20369 010


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WorkOrder:




Compound

1

Dichlorodifluoromethane


8 0.441970.4722676 0.454340.4506659 0.43157 010

1

Ethylbenzene


8 0.528670.5564776 0.581070.5787859 0.4888 010

1

Hexachlorobutadiene


8 0.451970.4600676 0.474040.4453459 0.44393 010

1

Isopropylbenzene


8 1.562081.7143976 1.802011.76659 1.39218 010

1

m,p-Xylene


8 0.624360.6743676 0.707170.7010559 0.56352 010

1

Methylene chloride


8 0.57870.5983676 0.620010.5825659 0.56122 010

1

Naphthalene


8 107911254415276 2118059231559 2110998 010

1

n-Butylbenzene


8 2.403892.5429276 2.623492.4558759 2.26163 010

1

n-Propylbenzene


8 152616781859776 34450317091459 2862527 010


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WorkOrder:




Compound

1

o-Xylene


8 0.673340.7128776 0.74760.7298559 0.6213 010

1

sec-Butylbenzene


8 3.523683.7959876 4.005593.9597459 3.24512 010

1

Styrene


8 1.093681.1516176 1.217061.2003359 0.9918 010

1

tert-Butylbenzene


8 94168751040276 21522510393159 1815463 010

1

Tetrachloroethene


8 0.303590.3190176 0.328060.326259 0.2897 010

1

Toluene


8 1.478151.5878276 1.700461.7024159 1.3411 010

1

trans-1,2-Dichloroethene


8 0.521530.5455876 0.554530.5200259 0.50644 010

1

trans-1,3-Dichloropropene


8 0.495620.4907176 0.479730.4474359 0.4681 010

1

Trichloroethene


8 0.357560.3718476 0.378640.3667359 0.33364 010


44 of 595

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WorkOrder:




Compound

1

Trichlorofluoromethane


8 0.607910.6524676 0.67480.6333459 0.59074 010

1

Vinyl chloride


8 0.672740.7407476 0.742240.7423459 0.65188 010

1

1,2-Dichloroethane-d4


8 0.583990.6064476 0.626010.6085559 0.55248 010

1

4-Bromofluorobenzene


8 41511621697276 897994508459 801860 010

1

Dibromofluoromethane


8 27770314615676 624113097259 545353 010

1

Toluene-d8


8 106377556367976 24292412833359 2025382 010


45 of 595

00913536

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WorkOrder:




Curve A0 A1 A2 %RSDOR R^2

Max RSDOR R^2

Coefficients

1,1,1,2-Tetrachloroethane AVRG 0 0.39992 150 5.337451,1,1-Trichloroethane AVRG 0 0.82541 150 5.204241,1,2,2-Tetrachloroethane AVRG 0 1.37832 150 11.073651,1,2-Trichloroethane AVRG 0 0.33334 150 7.413041,1-Dichloroethane AVRG 0 1.17307 150 3.910291,1-Dichloroethene AVRG 0 0.4738 150 4.602611,1-Dichloropropene AVRG 0 0.46639 150 14.890581,2,3-Trichlorobenzene Linear 0.01343 1.05493 0.990 0.999741,2,3-Trichloropropane AVRG 0 1.28029 150 8.404871,2,4-Trichlorobenzene Linear 0.01183 0.917826 0.990 0.999741,2,4-Trimethylbenzene AVRG 0 3.49122 150 13.761721,2-Dibromo-3-chloropropane Linear -0.00184 4.35729 0.990 0.999611,2-Dibromoethane AVRG 0 0.40004 150 5.314121,2-Dichlorobenzene AVRG 0 1.86006 150 9.212851,2-Dichloroethane AVRG 0 0.46572 150 4.049921,2-Dichloropropane AVRG 0 0.43977 150 8.240871,3,5-Trimethylbenzene Linear -0.06282 0.375097 0.990 0.995991,3-Dichlorobenzene AVRG 0 1.924 150 7.94421,3-Dichloropropane AVRG 0 0.65204 150 8.233081,4-Dichlorobenzene AVRG 0 1.81529 150 8.094032,2-Dichloropropane AVRG 0 0.76858 150 5.601982-Butanone AVRG 0 0.32846 150 5.163452-Chlorotoluene Linear -0.05284 0.415066 0.990 0.997292-Hexanone AVRG 0 0.30217 0 6.202474-Chlorotoluene Linear -0.04929 0.381545 0.990 0.997684-Isopropyltoluene AVRG 0 3.28301 150 10.369584-Methyl-2-pentanone AVRG 0 0.53071 150 7.77246Acetone Linear -0.09662 4.98429 0.990 0.99947Benzene AVRG 0 1.46828 150 11.27741Bromobenzene AVRG 0 1.12183 150 9.04015Bromochloromethane AVRG 0 0.28355 150 8.51022Bromodichloromethane AVRG 0 0.48855 150 7.18176Bromoform AVRG 0 0.31597 150 3.11427Bromomethane Linear -0.0725 3.02984 0.990 0.99787Carbon disulfide AVRG 0 1.02275 150 5.70079Carbon tetrachloride Linear -0.03003 2.59544 0.990 0.99948Chlorobenzene AVRG 0 1.06344 150 10.74148Chloroethane Linear -0.06034 2.63289 0.990 0.9957Chloroform AVRG 0 0.9845 150 7.87754Chloromethane AVRG 0 1.11433 150 11.48196cis-1,2-Dichloroethene AVRG 0 0.62873 150 3.75838cis-1,3-Dichloropropene AVRG 0 0.5786 150 4.15338Dibromochloromethane AVRG 0 0.4521 150 4.91366Dibromomethane AVRG 0 0.2083 150 5.56193Dichlorodifluoromethane AVRG 0 0.45881 150 4.48942Ethylbenzene AVRG 0 0.5848 150 9.35217Hexachlorobutadiene AVRG 0 0.45852 150 4.51058Isopropylbenzene AVRG 0 1.75774 150 10.30399


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WorkOrder:




Curve A0 A1 A2 %RSDOR R^2

Max RSDOR R^2

Coefficients

m,p-Xylene AVRG 0 0.72228 150 13.84429Methylene chloride AVRG 0 0.62851 150 10.10524Naphthalene Linear 0.00225 0.36429 0.990 0.99891n-Butylbenzene AVRG 0 2.47076 150 4.76923n-Propylbenzene Linear -0.05711 0.269651 0.990 0.99672o-Xylene AVRG 0 0.74988 150 10.15405sec-Butylbenzene AVRG 0 3.96851 150 10.07419Styrene AVRG 0 1.1731 150 7.24317tert-Butylbenzene Linear -0.04976 0.427211 0.990 0.99785Tetrachloroethene AVRG 0 0.33764 150 10.00013Toluene AVRG 0 1.71995 150 12.93045trans-1,2-Dichloroethene AVRG 0 0.53183 150 5.41605trans-1,3-Dichloropropene AVRG 0 0.45017 150 9.50099Trichloroethene AVRG 0 0.37206 150 5.55222Trichlorofluoromethane AVRG 0 0.64023 150 5.99841Vinyl chloride AVRG 0 0.74138 150 7.149361,2-Dichloroethane-d4 AVRG 0 0.62132 150 8.434754-Bromofluorobenzene Linear -0.04262 2.29922 0.990 0.998Dibromofluoromethane Linear -0.03492 2.25286 0.990 0.99891Toluene-d8 Linear -0.02685 0.835617 0.990 0.99866


47 of 595

00913538

Form 7 - Volatile Calibration Verification Summary

Lab File ID:

Compound


D090603.DVOA2Instrument ID:06-Sep-201808:47



RRF orAmount

RRF50.000or Amount

CCALRRF50.000

MINRRF

% D or% DRIFT

MAX % D or % DRIFT

CURVETYPE Q

1,1,1,2-Tetrachloroethane 48.890322 50 0.48029 -2.22 151,1,1-Trichloroethane 45.109021 50 0.89147 0.1 -9.78 151,1,2,2-Tetrachloroethane 41.338459 50 1.31875 0.3 -17.32 151,1,2-Trichloroethane 46.666602 50 0.35824 0.1 -6.67 151,1-Dichloroethane 43.450846 50 1.21452 0.2 -13.1 151,1-Dichloroethene 44.562915 50 0.52666 0.1 -10.87 151,1-Dichloropropene 53.740333 50 0.48773 7.48 151,2,3-Trichlorobenzene 49.882743 50 1.12396 -0.23 151,2,3-Trichloropropane 44.148034 50 1.32123 -11.7 151,2,4-Trichlorobenzene 51.204708 50 1.3038 2.41 151,2,4-Trimethylbenzene 52.172099 50 3.58291 4.34 151,2-Dibromo-3-chloropropane 45.18279 50 0.22305 -9.63 151,2-Dibromoethane 50.816694 50 0.46942 1.63 151,2-Dichlorobenzene 45.687008 50 2.09439 -8.63 151,2-Dichloroethane 48.111539 50 0.52533 0.1 -3.78 151,2-Dichloropropane 47.040589 50 0.46694 -5.92 151,3,5-Trimethylbenzene 47.333154 50 3.58042 -5.33 151,3-Dichlorobenzene 47.300992 50 2.19826 -5.4 151,3-Dichloropropane 47.286068 50 0.71766 -5.43 151,4-Dichlorobenzene 48.38462 50 2.09977 -3.23 152,2-Dichloropropane 55.413166 50 0.84296 10.83 152-Butanone 89.706516 100 0.30799 -10.29 152-Chlorotoluene 51.266482 50 3.09863 2.53 152-Hexanone 92.909722 100 0.34339 0 -7.09 04-Chlorotoluene 52.658467 50 3.37506 5.32 154-Isopropyltoluene 44.571778 50 3.67702 -10.86 154-Methyl-2-pentanone 88.958935 100 0.50658 -11.04 15Acetone 82.182959 100 0.18243 0 -17.82 0Benzene 46.395984 50 1.58721 0.5 -7.21 15Bromobenzene 46.473179 50 1.25586 -7.05 15Bromochloromethane 50.401273 50 0.34525 0.2 0.8 15Bromodichloromethane 49.88318 50 0.57406 -0.23 15Bromoform 52.757512 50 0.39461 0.1 5.52 15Bromomethane 56.427602 50 0.46368 0.1 12.86 15Carbon disulfide 87.797087 100 0.97887 -12.2 15Carbon tetrachloride 55.498169 50 0.52747 0.1 11 15Chlorobenzene 48.209104 50 1.20622 0.5 -3.58 15Chloroethane 42.375438 50 0.44673 -15.25 15Chloroform 44.348111 50 1.03903 0.2 -11.3 15Chloromethane 40.795077 50 1.00661 -18.41 15cis-1,2-Dichloroethene 45.734511 50 0.67243 -8.53 15

Qualifier "Q" <-- : %Drift is > Max %D

ALS Houston, USDate: 20-Sep-18

48 of 595

00913539


Lab File ID:

Compound





RRF orAmount

RRF50.000or Amount

CCALRRF50.000

MINRRF

% D or% DRIFT

MAX % D or % DRIFT

CURVETYPE Q

cis-1,3-Dichloropropene 53.493639 50 0.68924 0.2 6.99 15Dibromochloromethane 50.074288 50 0.53663 0.1 0.15 15Dibromomethane 53.166624 50 0.26115 6.33 15Dichlorodifluoromethane 47.893516 50 0.47149 -4.21 15Ethylbenzene 55.216202 50 0.65268 0.1 10.43 15Hexachlorobutadiene 48.792279 50 0.59261 -2.42 15Isopropylbenzene 47.574436 50 2.04385 -4.85 15m,p-Xylene 113.839023 100 0.78557 13.84 15Methylene chloride 48.005359 50 0.64306 -3.99 15Naphthalene 50.159137 50 3.06785 0.32 15n-Butylbenzene 47.483329 50 2.898 -5.03 15n-Propylbenzene 53.180702 50 4.81302 6.36 15o-Xylene 55.152844 50 0.83271 10.31 15sec-Butylbenzene 43.872448 50 4.37475 -12.26 15Styrene 49.687422 50 1.32636 0.3 -0.63 15tert-Butylbenzene 53.713804 50 3.14821 7.43 15Tetrachloroethene 50.436637 50 0.41027 0.2 0.87 15Toluene 45.118917 50 1.82018 0.4 -9.76 15trans-1,2-Dichloroethene 47.196044 50 0.57516 -5.61 15trans-1,3-Dichloropropene 57.558742 50 0.57483 0.1 15.12 15Trichloroethene 50.213258 50 0.45859 0.3 0.43 15Trichlorofluoromethane 50.554639 50 0.81511 1.11 15Vinyl chloride 44.183011 50 0.72911 0.1 -11.63 151,2-Dichloroethane-d4 44.666934 50 0.45562 -10.67 154-Bromofluorobenzene 52.157619 50 0.46261 0.2 4.32 15Dibromofluoromethane 44.472309 50 0.39759 -11.06 15Toluene-d8 42.910642 50 1.18622 -14.18 15



49 of 595

00913540


Lab File ID:

Compound





RRF orAmount

RRF50.000or Amount

CCALRRF50.000

MINRRF

% D or% DRIFT

MAX % D or % DRIFT

CURVETYPE Q

1,1,1,2-Tetrachloroethane 48.479935 50 0.47626 -3.04 501,1,1-Trichloroethane 46.073474 50 0.91053 0.1 -7.85 501,1,2,2-Tetrachloroethane 37.349541 50 1.1915 0.3 -25.3 501,1,2-Trichloroethane 47.126196 50 0.36177 0.1 -5.75 501,1-Dichloroethane 43.510202 50 1.21618 0.2 -12.98 501,1-Dichloroethene 45.091881 50 0.53291 0.1 -9.82 501,1-Dichloropropene 56.453952 50 0.51141 12.91 501,2,3-Trichlorobenzene 48.991494 50 1.10396 -2.02 501,2,3-Trichloropropane 38.771241 50 1.16032 -22.46 501,2,4-Trichlorobenzene 49.915847 50 1.2711 -0.17 501,2,4-Trimethylbenzene 48.525039 50 3.34766 -2.95 501,2-Dibromo-3-chloropropane 41.278143 50 0.20393 -17.44 501,2-Dibromoethane 47.932836 50 0.44278 -4.13 501,2-Dichlorobenzene 42.741057 50 1.95934 -14.52 501,2-Dichloroethane 47.376491 50 0.5173 0.1 -5.25 501,2-Dichloropropane 45.445275 50 0.45111 -9.11 501,3,5-Trimethylbenzene 43.612568 50 3.32594 -12.77 501,3-Dichlorobenzene 43.572111 50 2.02496 -12.86 501,3-Dichloropropane 44.394789 50 0.67378 -11.21 501,4-Dichlorobenzene 44.149309 50 1.91597 -11.7 502,2-Dichloropropane 49.004122 50 0.74547 -1.99 502-Butanone 84.879792 100 0.29142 -15.12 502-Chlorotoluene 47.194917 50 2.86606 -5.61 502-Hexanone 79.830957 100 0.29505 0 -20.17 504-Chlorotoluene 48.10924 50 3.10041 -3.78 504-Isopropyltoluene 41.571651 50 3.42952 -16.86 504-Methyl-2-pentanone 84.415352 100 0.48071 -15.58 50Acetone 90.538502 100 0.2002 0 -9.46 50Benzene 57.641054 50 1.9719 0.5 15.28 50Bromobenzene 43.705441 50 1.18107 -12.59 50Bromochloromethane 47.673331 50 0.32656 0.2 -4.65 50Bromodichloromethane 49.17945 50 0.56596 -1.64 50Bromoform 50.35076 50 0.37661 0.1 0.7 50Bromomethane 53.552734 50 0.44147 0.1 7.11 50Carbon disulfide 91.075606 100 1.01543 -8.92 50Carbon tetrachloride 54.598367 50 0.51919 0.1 9.2 50Chlorobenzene 47.582223 50 1.19053 0.5 -4.84 50Chloroethane 43.186466 50 0.45528 -13.63 50Chloroform 43.500402 50 1.01917 0.2 -13 50Chloromethane 37.829103 50 0.93343 -24.34 50cis-1,2-Dichloroethene 45.451265 50 0.66826 -9.1 50



50 of 595

00913541


Lab File ID:

Compound





RRF orAmount

RRF50.000or Amount

CCALRRF50.000

MINRRF

% D or% DRIFT

MAX % D or % DRIFT

CURVETYPE Q

cis-1,3-Dichloropropene 47.995654 50 0.6184 0.2 -4.01 50Dibromochloromethane 48.18989 50 0.51644 0.1 -3.62 50Dibromomethane 49.784173 50 0.24454 -0.43 50Dichlorodifluoromethane 45.613492 50 0.44904 -8.77 50Ethylbenzene 53.907906 50 0.63784 0.1 7.82 50Hexachlorobutadiene 47.308234 50 0.57459 -5.38 50Isopropylbenzene 46.798358 50 2.01051 -6.4 50m,p-Xylene 112.308935 100 0.77562 12.31 50Methylene chloride 46.227347 50 0.62 -7.55 50Naphthalene 71.694775 50 4.35727 43.39 50n-Butylbenzene 43.561113 50 2.65862 -12.88 50n-Propylbenzene 49.170019 50 4.47307 -1.66 50o-Xylene 53.84032 50 0.81383 7.68 50sec-Butylbenzene 41.025022 50 4.09082 -17.95 50Styrene 49.351078 50 1.31738 0.3 -1.3 50tert-Butylbenzene 50.871711 50 2.99131 1.74 50Tetrachloroethene 52.461597 50 0.42674 0.2 4.92 50Toluene 48.619129 50 1.96139 0.4 -2.76 50trans-1,2-Dichloroethene 48.041558 50 0.58546 -3.92 50trans-1,3-Dichloropropene 53.136182 50 0.53067 0.1 6.27 50Trichloroethene 50.697682 50 0.46302 0.3 1.4 50Trichlorofluoromethane 51.305169 50 0.82721 2.61 50Vinyl chloride 45.472003 50 0.75039 0.1 -9.06 501,2-Dichloroethane-d4 45.820183 50 0.46738 -8.36 504-Bromofluorobenzene 51.13537 50 0.45354 0.2 2.27 50Dibromofluoromethane 45.191852 50 0.40403 -9.62 50Toluene-d8 45.501442 50 1.25784 -9 50



51 of 595

00913542

Form 8 - Volatile Internal Standard Area and RT Summary

Lab File ID:

Contract: SAS No.: Date Time:

D090603.DVOA2Instrument ID:

2018-09-06 08:47



IS2Area

IS1RT

IS1AreaSample ID

IS2RT

IS3Area

IS3RT

IS4Area

Run ID: VOA2_323037

IS4RT

11.841286319.536.585.78 28318830628020699512 HOUR STD

12.3425726210.037.086.28 566376612560413990UPPER LIMIT

11.34643169.036.085.28 141594153140103498LOWER LIMIT

11.841183419.536.575.79 249691289557196571CCV_END

11.841221889.536.585.79 275115296491206639VLCSW-180906

11.841117919.536.585.78 269797302079218901VBLKW-180906

11.831307189.526.585.79 292423327902225622ZZZZZZMS

11.831289249.536.585.79 294188291105199447ZZZZZZMSD

11.841186339.526.575.78 278547309004219449HS18081540-02

11.831208979.526.585.78 291510323923230281HS18081540-01


AREA UPPER LIMIT = +100% of internal standard area RT UPPER LIMIT = + 0.50 minutes of internal standard RTAREA LOWER LIMIT = - 50% of internal standard area RT LOWER LIMIT = - 0.50 minutes of internal standard RT

# Column used to flag values outside QC limits with an asterisk* Values outside of QC limits

IS1 = Pentafluorobenzene IS3 (CBZ) = Chlorobenzene-d5IS2 (DFB) = 1,4-Difluorobenzene IS4 (DCB) = 1,4-Dichlorobenzene-d4

52 of 595

00913543

VOA2_321352Run ID:

FORM 13 - ANALYSIS RUN LOG

Instrument:

Sample No. D/F Time



VOA2

Start Date: End Date:02-Aug-2018 03-Aug-2018

File IDBFB 1 02-Aug-2018 19:45 E080201.DVSTD0005 1 02-Aug-2018 20:37 E080203.DVSTD001 1 02-Aug-2018 21:03 E080204.DVSTD002 1 02-Aug-2018 21:29 E080205.DVSTD005 1 02-Aug-2018 21:55 E080206.DVSTD010 1 02-Aug-2018 22:21 E080207.DVSTD020 1 02-Aug-2018 22:47 E080208.DVSTD050 1 02-Aug-2018 23:12 E080209.DVSTD100 1 02-Aug-2018 23:38 E080210.DVSTD200 1 03-Aug-2018 00:04 E080211.DVSTD050 1 03-Aug-2018 00:56 E080213.D


53 of 595

00913544

Data File: \\nahstws003\Target\CHEM\VOA2.i\E180802.b\E080201.D Page 1 Report Date: 04-Sep-2018 17:00

ALS Laboratory Group

Data file : \\nahstws003\Target\CHEM\VOA2.i\E180802.b\E080201.DLab Smp Id: BFB Client Smp ID: BFBInj Date : 02-AUG-2018 21:45 Operator : AP Inst ID: VOA2.iSmp Info : BFB;BFB;3;;BFBMisc Info : HS15080001;WATER;0;1;Comment : Method : \\NAHSTWS003\Target\CHEM\VOA2.i\E180802.b\bfb.mMeth Date : 04-Jun-2018 15:21 Cesar.Lira Quant Type: ISTDCal Date : Cal File: Als bottle: 27 QC Sample: BFBDil Factor: 1.00000 Integrator: HP RTE Compound Sublist: all.subTarget Version: 4.14 Sample Matrix: WATER

Concentration Formula: Amt * DF * Uf * Vf * Vi * CpndVariable

Name Value Description-------------- ---------- ----------------------- DF 1.000 Dilution Factor Uf 5.000 ng unit correction factor Vf 1.000 Volumetric correction factor Vi 2.000 Injection VolumeCpnd Variable Local Compound Variable

CONCENTRATIONS ON-COL FINAL

RT EXP RT REL RT MASS RESPONSE ( ug/L) ( ug/l) TARGET RANGE RATIO ==== ======== ======== ==== ======== ======= ======= ============ =====

1 bfb CAS #: 460-00-410.695 10.696 ( 0.000) 95 94968 0.00- 100.00 100.00

10.695 10.696 ( 0.000) 50 17752 15.00- 40.00 18.69

10.695 10.696 ( 0.000) 75 43808 30.00- 60.00 46.13

10.695 10.696 ( 0.000) 96 6211 5.00- 9.00 6.54

10.695 10.696 ( 0.000) 173 0 0.0 0.0 0.00- 2.00 0.00

10.695 10.696 ( 0.000) 174 79536 50.00- 0.00 83.75

10.695 10.696 ( 0.000) 175 6049 5.00- 9.00 7.61

10.695 10.696 ( 0.000) 176 78648 95.00- 101.00 98.88

10.695 10.696 ( 0.000) 177 4780 5.00- 9.00 6.08

-------------------------------------------------------------------------------

54 of 595

00913545

55 of 595

00913546

56 of 595

00913547

57 of 595

00913548



Data file : \\nahstws003\Target\CHEM\VOA2.i\E180802.b\E080203.DLab Smp Id: VSTD0005 Inj Date : 02-AUG-2018 22:37 Operator : AP Inst ID: VOA2.iSmp Info : VSTD0005;VSTD0005;1;1;Misc Info : HS15080001;WATER;0;1;Comment : Method : \\NAHSTWS003\Target\CHEM\VOA2.i\E180802.b\8260LL.mMeth Date : 17-Aug-2018 12:13 Shiva.Targ Quant Type: ISTDCal Date : 09-JUN-2018 13:37 Cal File: D060910.DAls bottle: 29 Calibration Sample, Level: 1Dil Factor: 1.00000 Integrator: HP RTE Compound Sublist: 00000_8260-LLw.subTarget Version: 4.14

Concentration Formula: Amt * DF * (Uf/Vo)*1 * CpndVariable

Name Value Description-------------- ---------- ----------------------- DF 1.000 Dilution Factor Uf 5.000 ng unit correction factor Vo 5.000 sample purged Va 0.00000 Cpnd Variable Local Compound Variable

AMOUNTS QUANT SIG CAL-AMT ON-COL

Compounds MASS RT EXP RT REL RT RESPONSE ( ug/l) ( ug/l)========================== ==== ==== ======== ======== ======== ======= =======

* 1 Pentafluorobenzene 168 5.782 5.783 (1.000) 276417 50.0000 2 Dichlorodifluoromethane 85 1.444 1.454 (0.250) 1421 0.50000 0.52(aM)

186 Isobutylene 56 1.665 1.666 (0.288) 2119 0.50000 0.43(aAM) 3 Chloromethane 50 1.617 1.601 (0.280) 3847 0.50000 0.56(aM) 4 Propionitrile 54 5.253 5.276 (0.908) 5735 5.00000 4.58(aM) 5 Vinyl Chloride 62 1.691 1.688 (0.293) 2110 0.50000 0.46(aM)

159 Dichlorofluoromethane 67 2.253 2.227 (0.390) 3475 0.50000 0.51(aM) 8 Trichlorofluoromethane 101 2.269 2.253 (0.392) 2323 0.50000 0.52(aM) 12 Isobutyl Alcohol 74 6.251 6.184 (1.081) 75 10.0000 2.65(TaM) 13 Acetonitrile 39 3.177 3.174 (0.549) 1605 5.00000 8.83(aM) 14 Allyl Chloride 41 3.199 3.180 (0.553) 6134 0.50000 0.54(aM) 15 Iodomethane 142 2.926 2.914 (0.506) 425 1.00000 1.25(aM) 16 Acrylonitrile 53 3.748 3.710 (0.648) 1113 1.00000 1.14(aM) 18 Methyl tert-butyl ether 73 3.697 3.697 (0.639) 5039 0.50000 0.50(aM) 19 Carbon Disulfide 76 2.968 2.962 (0.513) 6063 1.00000 0.98(aM) 20 trans-1,2-Dichloroethene 96 3.700 3.668 (0.640) 1362 0.50000 0.40(aM) 21 Vinyl Acetate 43 5.263 5.256 (0.910) 4310 1.00000 0.94(aM) 22 1,1-Dichloroethane 63 4.293 4.281 (0.743) 3931 0.50000 0.50(aM) 24 2-Butanone 43 5.173 5.150 (0.895) 1608 1.00000 0.84(aM) 25 Methacrylonitrile 41 5.429 5.414 (0.939) 1772 0.50000 0.42(aM) 26 2,2-Dichloropropane 77 5.060 5.044 (0.875) 2021 0.50000 0.48(aM) 27 cis-1,2-Dichloroethene 96 5.073 5.073 (0.877) 1962 0.50000 0.48(aM)

58 of 595

00913549




28 Chloroform 83 5.500 5.497 (0.951) 3588 0.50000 0.55(aM) 29 Bromochloromethane 128 5.381 5.378 (0.931) 768 0.50000 0.40(aM)

$ 30 Dibromofluoromethane 113 5.702 5.689 (0.986) 1255 0.50000 0.50(aM) 31 1,1,1-Trichloroethane 97 5.657 5.657 (0.978) 2803 0.50000 0.51(a) 33 1,2-Dichloroethane 62 6.155 6.148 (0.937) 2131 0.50000 0.46(aM)

$ 35 1,2-Dichloroethane-d4 65 6.074 6.059 (1.050) 1330 0.50000 0.47(aM)

* 36 1,4-Difluorobenzene 114 6.572 6.575 (1.000) 416679 50.0000 37 Benzene 78 6.094 6.097 (0.927) 8213 0.50000 0.57(Ta) 38 Trichloroethene 130 6.825 6.819 (1.039) 2018 0.50000 0.53(aM) 39 Bromodichloromethane 83 7.387 7.381 (1.124) 2313 0.50000 0.48(aM) 40 Methyl Methacrylate 41 7.252 7.252 (1.254) 2173 0.50000 0.51(aM) 41 2-Chloroethylvinyl ether 63 8.160 8.164 (1.242) 629 1.00000 1.08(aM) 42 1,2-Dichloropropane 63 7.069 7.069 (1.076) 1962 0.50000 0.47(aM) 43 2-Nitropropane 43 8.029 8.038 (1.388) 4342 0.50000 0.49(aM) 44 Dibromomethane 93 7.207 7.194 (1.097) 1017 0.50000 0.49(aM) 45 4-Methyl-2-Pentanone 43 8.029 8.038 (0.843) 4299 1.00000 1.04(aM) 46 cis-1,3-Dichloropropene 75 7.839 7.843 (1.193) 2319 0.50000 0.43(aM)

* 47 Chlorobenzene-d5 117 9.524 9.527 (1.000) 362887 50.0000

$ 48 Toluene-d8 98 8.086 8.093 (0.849) 6082 0.50000 (aM) 49 Ethyl Methacrylate 69 8.539 8.539 (1.299) 2559 0.50000 0.49(aM) 50 Toluene 91 8.157 8.164 (0.856) 8058 0.50000 0.55(Ta) 52 2-Hexanone 43 8.876 8.873 (0.932) 2612 1.00000 0.97(aM) 53 1,1,2-Trichloroethane 83 8.597 8.600 (0.903) 1387 0.50000 0.49(aM) 54 1,3-Dichloropropane 76 8.757 8.760 (0.919) 2695 0.50000 0.48(aM) 55 Dibromochloromethane 129 8.969 8.975 (0.942) 1938 0.50000 0.49(aM) 56 Tetrachloroethene 164 8.683 8.693 (0.912) 1632 0.50000 0.55(aM) 57 1,2-Dibromoethane 107 9.072 9.072 (0.952) 1501 0.50000 0.44(aM) 59 Chlorobenzene 112 9.550 9.556 (1.003) 4751 0.50000 0.52(Ta) 60 1,1,1,2-Tetrachloroethane 131 9.643 9.652 (1.012) 1717 0.50000 0.48(aM) 64 Styrene 104 10.201 10.204 (1.071) 4925 0.50000 0.50(aM) 66 Bromoform 173 10.381 10.378 (1.090) 1283 0.50000 0.47(aM) 67 Isopropylbenzene 105 10.551 10.551 (1.108) 9258 0.50000 0.59(a) 68 1,1,2,2-Tetrachloroethane 83 10.872 10.878 (0.919) 2214 0.50000 0.51(aM)

$ 69 4-Bromofluorobenzene 95 10.695 10.699 (1.123) 2589 0.50000 (aM)

* 70 1,4-Dichlorobenzene-d4 152 11.834 11.838 (1.000) 135495 50.0000 71 1,2,3-Trichloropropane 75 10.901 10.907 (0.921) 2036 0.50000 0.50(aM) 72 trans-1,4-Dichloro-2-butene 53 10.942 10.936 (1.149) 139 0.50000 1.61(M) 74 Bromobenzene 156 10.830 10.837 (0.915) 2081 0.50000 0.56(aM) 75 1,3,5-Trimethylbenzene 105 11.128 11.138 (0.940) 11256 0.50000 0.42(aM) 81 sec-Butylbenzene 105 11.664 11.674 (0.986) 7738 0.50000 0.57(aM) 82 p-Isopropyltoluene 119 11.812 11.825 (0.998) 6989 0.50000 0.62(aM) 83 1,3-Dichlorobenzene 146 11.764 11.774 (0.994) 3233 0.50000 0.51(Ta) 84 1,4-Dichlorobenzene 146 11.860 11.863 (1.002) 3178 0.50000 0.54(aM) 87 n-Butylbenzene 91 12.226 12.226 (1.033) 4651 0.50000 0.56(Ta) 88 1,2-Dichlorobenzene 146 12.226 12.229 (1.033) 3468 0.50000 0.55(aM) 146 Methyl acetate 43 3.267 3.241 (0.565) 2305 0.50000 0.52(aM) 139 Diethyl ether 59 2.567 2.545 (0.444) 3024 0.50000 0.45(aM) 133 Ethyl Acrylate 55 6.992 7.018 (1.209) 6858 0.50000 0.57(aM) 141 Cyclohexane 56 5.689 5.689 (0.984) 4072 0.50000 0.58(a) 142 Tetrahydrofuran 42 5.452 5.423 (0.943) 1555 1.00000 1.02(aM) 148 Tert-butyl alcohol 59 3.527 3.597 (0.610) 4246 10.0000 10.69(M) 170 1,3,5-Trichlorobenzene 180 13.201 13.208 (1.116) 2081 0.50000 0.51(aM) 175 tert-Butyl ethyl ether 59 6.248 6.254 (1.080) 2257 0.50000 0.44(aM) 157 2-Methylnaphthalene 142 15.185 15.191 (1.283) 2578 0.50000 6.20(M)

59 of 595

00913550



Compounds MASS RT EXP RT REL RT RESPONSE ( ug/l) ( ug/l)========================== ==== ==== ======== ======== ======== ======= ======= 156 Diisopropyl ether 45 4.431 4.435 (0.766) 7511 0.50000 0.50(aM) 171 1-Methylnaphthalene 142 15.377 15.387 (1.299) 2289 0.50000 5.50(M) 130 Ethyl Acetate 43 5.263 5.256 (0.910) 4511 0.50000 0.49(aM)

M 94 1,2-Dichloroethylene (total) 96 3324 1.00000 0.88(a)

QC Flag Legend

T - Target compound detected outside RT window.a - Target compound detected but, quantitated amount Below Limit Of Quantitation(BLOQ).A - Target compound detected but, quantitated amount exceeded maximum amount.M - Compound response manually integrated.

60 of 595

00913551

61 of 595

00913552








* 1 Pentafluorobenzene 168 5.779 5.783 (1.000) 273991 50.0000 2 Dichlorodifluoromethane 85 1.460 1.454 (0.253) 2672 1.00000 0.99(aM)

186 Isobutylene 56 1.656 1.666 (0.287) 5049 1.00000 1.03(aAM) 3 Chloromethane 50 1.601 1.601 (0.277) 7562 1.00000 1.11(aM) 4 Propionitrile 54 5.250 5.276 (0.908) 13233 10.0000 10.68(M) 5 Vinyl Chloride 62 1.691 1.688 (0.293) 5159 1.00000 1.14(M) 7 Chloroethane 64 2.041 2.031 (0.353) 3360 1.00000 1.16(M)

159 Dichlorofluoromethane 67 2.236 2.227 (0.387) 7158 1.00000 1.06(M) 8 Trichlorofluoromethane 101 2.262 2.253 (0.391) 4689 1.00000 1.06(T) 10 Acetone 43 2.872 2.869 (0.497) 5616 2.00000 1.22(aM) 11 1,1-Dichloroethene 96 2.756 2.750 (0.477) 3423 1.00000 1.05(M) 12 Isobutyl Alcohol 74 6.257 6.184 (1.083) 453 20.0000 23.51(TM) 13 Acetonitrile 39 3.170 3.174 (0.549) 3797 10.0000 14.22(M) 14 Allyl Chloride 41 3.170 3.180 (0.549) 12524 1.00000 1.12(TM) 15 Iodomethane 142 2.914 2.914 (0.504) 1514 2.00000 1.62(aM) 16 Acrylonitrile 53 3.713 3.710 (0.642) 3033 2.00000 2.27(M) 18 Methyl tert-butyl ether 73 3.684 3.697 (0.637) 10928 1.00000 1.10(M) 19 Carbon Disulfide 76 2.968 2.962 (0.514) 12132 2.00000 1.98(aM) 20 trans-1,2-Dichloroethene 96 3.664 3.668 (0.634) 3595 1.00000 1.07(M) 21 Vinyl Acetate 43 5.246 5.256 (0.908) 9691 2.00000 2.15(M) 22 1,1-Dichloroethane 63 4.287 4.281 (0.742) 8043 1.00000 1.05(M) 24 2-Butanone 43 5.163 5.150 (0.893) 4090 2.00000 2.17(M)

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00913553




25 Methacrylonitrile 41 5.420 5.414 (0.938) 4112 1.00000 0.99(aM) 26 2,2-Dichloropropane 77 5.044 5.044 (0.873) 4631 1.00000 1.11(M) 27 cis-1,2-Dichloroethene 96 5.067 5.073 (0.877) 4183 1.00000 1.03(T) 28 Chloroform 83 5.494 5.497 (0.951) 6863 1.00000 1.06(T) 29 Bromochloromethane 128 5.375 5.378 (0.930) 1853 1.00000 0.98(aM)

$ 30 Dibromofluoromethane 113 5.696 5.689 (0.986) 2748 1.00000 1.12(M) 31 1,1,1-Trichloroethane 97 5.648 5.657 (0.977) 5825 1.00000 1.07 33 1,2-Dichloroethane 62 6.148 6.148 (0.936) 5052 1.00000 1.09(T)

$ 35 1,2-Dichloroethane-d4 65 6.065 6.059 (1.049) 2923 1.00000 1.04(M)

* 36 1,4-Difluorobenzene 114 6.572 6.575 (1.000) 421528 50.0000 37 Benzene 78 6.094 6.097 (0.927) 15832 1.00000 1.09 38 Trichloroethene 130 6.822 6.819 (1.038) 4143 1.00000 1.07 39 Bromodichloromethane 83 7.374 7.381 (1.122) 4811 1.00000 0.99(Ta) 40 Methyl Methacrylate 41 7.252 7.252 (1.255) 4028 1.00000 0.96(Ta) 41 2-Chloroethylvinyl ether 63 8.160 8.164 (1.242) 1294 2.00000 2.21(aM) 42 1,2-Dichloropropane 63 7.066 7.069 (1.075) 4621 1.00000 1.10(M) 43 2-Nitropropane 43 8.029 8.038 (1.389) 8918 1.00000 1.01(Ta) 44 Dibromomethane 93 7.197 7.194 (1.095) 1990 1.00000 0.96(aM) 45 4-Methyl-2-Pentanone 43 8.029 8.038 (0.843) 8918 2.00000 2.11 46 cis-1,3-Dichloropropene 75 7.839 7.843 (1.193) 5368 1.00000 0.98(aM)

* 47 Chlorobenzene-d5 117 9.524 9.527 (1.000) 369694 50.0000

$ 48 Toluene-d8 98 8.093 8.093 (0.850) 11126 1.00000 (aM) 49 Ethyl Methacrylate 69 8.532 8.539 (1.298) 5580 1.00000 1.06(T) 50 Toluene 91 8.157 8.164 (0.856) 17667 1.00000 1.18(T) 51 trans-1,3-Dichloropropene 75 8.417 8.420 (1.281) 3841 1.00000 0.91(aM) 52 2-Hexanone 43 8.873 8.873 (0.932) 5809 2.00000 2.15(M) 53 1,1,2-Trichloroethane 83 8.590 8.600 (0.902) 3155 1.00000 1.11(T) 54 1,3-Dichloropropane 76 8.747 8.760 (0.918) 6213 1.00000 1.10(M) 55 Dibromochloromethane 129 8.969 8.975 (0.942) 4195 1.00000 1.05(T) 56 Tetrachloroethene 164 8.693 8.693 (0.913) 3160 1.00000 1.05 57 1,2-Dibromoethane 107 9.071 9.072 (0.952) 3519 1.00000 1.03(T) 59 Chlorobenzene 112 9.550 9.556 (1.003) 10312 1.00000 1.11 60 1,1,1,2-Tetrachloroethane 131 9.649 9.652 (1.013) 3809 1.00000 1.04 64 Styrene 104 10.201 10.204 (1.071) 10002 1.00000 1.01 66 Bromoform 173 10.377 10.378 (1.090) 2801 1.00000 1.01(M) 67 Isopropylbenzene 105 10.544 10.551 (1.107) 18031 1.00000 1.13 68 1,1,2,2-Tetrachloroethane 83 10.868 10.878 (0.918) 5075 1.00000 1.14(M)

$ 69 4-Bromofluorobenzene 95 10.702 10.699 (1.124) 3985 1.00000 (aM)

* 70 1,4-Dichlorobenzene-d4 152 11.834 11.838 (1.000) 139045 50.0000 71 1,2,3-Trichloropropane 75 10.904 10.907 (0.921) 4735 1.00000 1.13(T) 72 trans-1,4-Dichloro-2-butene 53 10.939 10.936 (1.149) 579 1.00000 2.01(M) 74 Bromobenzene 156 10.830 10.837 (0.915) 4077 1.00000 1.08 75 1,3,5-Trimethylbenzene 105 11.132 11.138 (0.941) 17555 1.00000 0.94(aM) 81 sec-Butylbenzene 105 11.664 11.674 (0.986) 16230 1.00000 1.17 82 p-Isopropyltoluene 119 11.815 11.825 (0.998) 13433 1.00000 1.17 83 1,3-Dichlorobenzene 146 11.767 11.774 (0.994) 7046 1.00000 1.09 84 1,4-Dichlorobenzene 146 11.860 11.863 (1.002) 6547 1.00000 1.08 87 n-Butylbenzene 91 12.223 12.226 (1.033) 9281 1.00000 1.09 88 1,2-Dichlorobenzene 146 12.223 12.229 (1.033) 6975 1.00000 1.09 91 Hexachlorobutadiene 225 13.991 13.988 (1.182) 1961 1.00000 1.16(M) 146 Methyl acetate 43 3.241 3.241 (0.561) 4908 1.00000 1.12(aM) 139 Diethyl ether 59 2.561 2.545 (0.443) 6755 1.00000 1.02 133 Ethyl Acrylate 55 6.986 7.018 (1.209) 12977 1.00000 1.10(M) 136 n-Hexane 57 4.075 4.063 (0.705) 4855 1.00000 1.09(M)

63 of 595

00913554



Compounds MASS RT EXP RT REL RT RESPONSE ( ug/l) ( ug/l)========================== ==== ==== ======== ======== ======== ======= ======= 141 Cyclohexane 56 5.680 5.689 (0.983) 7787 1.00000 1.12(a) 142 Tetrahydrofuran 42 5.429 5.423 (0.939) 3444 2.00000 2.29(M) 149 Isopropyl alcohol 45 3.090 3.093 (0.535) 5362 20.0000 20.10(M) 151 4-Methyl-2-pentanol 45 8.478 8.478 (0.890) 16254 20.0000 18.52(a) 167 Ethanol 45 2.551 2.545 (0.441) 7150 20.0000 21.22(M) 170 1,3,5-Trichlorobenzene 180 13.205 13.208 (1.116) 3996 1.00000 0.96(Ta) 172 tert-Butyl formate 59 4.916 4.919 (0.851) 10316 2.00000 2.14(T) 174 tert-Amyl methyl ether 73 6.260 6.261 (1.083) 10047 1.00000 1.07(M) 175 tert-Butyl ethyl ether 59 6.254 6.254 (1.082) 4764 1.00000 0.94(a) 157 2-Methylnaphthalene 142 15.188 15.191 (1.283) 2108 1.00000 6.04(M) 156 Diisopropyl ether 45 4.428 4.435 (0.766) 15655 1.00000 1.06(M) 171 1-Methylnaphthalene 142 15.393 15.387 (1.301) 1653 1.00000 5.30(M) 130 Ethyl Acetate 43 5.246 5.256 (0.908) 9531 1.00000 1.06(aM)


QC Flag Legend


64 of 595

00913555

65 of 595

00913556








* 1 Pentafluorobenzene 168 5.786 5.783 (1.000) 271653 50.0000 2 Dichlorodifluoromethane 85 1.463 1.454 (0.253) 5607 2.00000 2.09(M)

186 Isobutylene 56 1.668 1.666 (0.288) 10160 2.00000 2.10(aAM) 3 Chloromethane 50 1.608 1.601 (0.278) 14179 2.00000 2.11(aM) 4 Propionitrile 54 5.250 5.276 (0.907) 20732 20.0000 16.88 5 Vinyl Chloride 62 1.701 1.688 (0.294) 8869 2.00000 1.97 7 Chloroethane 64 2.063 2.031 (0.357) 6305 2.00000 2.20(M)

159 Dichlorofluoromethane 67 2.249 2.227 (0.389) 12766 2.00000 1.91(T) 8 Trichlorofluoromethane 101 2.269 2.253 (0.392) 8455 2.00000 1.93(T) 9 Acrolein 56 2.708 2.699 (0.468) 2930 4.00000 2.47(M) 10 Acetone 43 2.878 2.869 (0.498) 7793 4.00000 3.15(M) 11 1,1-Dichloroethene 96 2.772 2.750 (0.479) 6540 2.00000 2.03 12 Isobutyl Alcohol 74 6.180 6.184 (1.068) 536 40.0000 28.34(M) 13 Acetonitrile 39 3.180 3.174 (0.550) 8437 20.0000 25.74(M) 14 Allyl Chloride 41 3.196 3.180 (0.552) 17668 2.00000 1.60(T) 15 Iodomethane 142 2.920 2.914 (0.505) 4031 4.00000 2.48(M) 16 Acrylonitrile 53 3.735 3.710 (0.646) 3527 4.00000 2.57 18 Methyl tert-butyl ether 73 3.703 3.697 (0.640) 19411 2.00000 1.98(T) 19 Carbon Disulfide 76 2.968 2.962 (0.513) 24809 4.00000 4.09(M) 20 trans-1,2-Dichloroethene 96 3.684 3.668 (0.637) 6703 2.00000 2.02 21 Vinyl Acetate 43 5.253 5.256 (0.908) 18601 4.00000 4.16(M) 22 1,1-Dichloroethane 63 4.303 4.281 (0.744) 15546 2.00000 2.04(M)

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24 2-Butanone 43 5.163 5.150 (0.892) 7361 4.00000 3.94(M) 25 Methacrylonitrile 41 5.426 5.414 (0.938) 8234 2.00000 2.01 26 2,2-Dichloropropane 77 5.047 5.044 (0.872) 8758 2.00000 2.11(M) 27 cis-1,2-Dichloroethene 96 5.073 5.073 (0.877) 7546 2.00000 1.88 28 Chloroform 83 5.494 5.497 (0.950) 12430 2.00000 1.95 29 Bromochloromethane 128 5.368 5.378 (0.928) 3625 2.00000 1.94(M)

$ 30 Dibromofluoromethane 113 5.699 5.689 (0.985) 5344 2.00000 2.20 31 1,1,1-Trichloroethane 97 5.657 5.657 (0.978) 11469 2.00000 2.13 32 1,1-Dichloropropene 75 5.869 5.856 (0.893) 9958 2.00000 0.58(a) 33 1,2-Dichloroethane 62 6.155 6.148 (0.936) 9800 2.00000 2.14 34 Carbon Tetrachloride 117 5.837 5.837 (0.888) 9623 2.00000 0.65(Ta)

$ 35 1,2-Dichloroethane-d4 65 6.071 6.059 (1.049) 5882 2.00000 2.12(T)

* 36 1,4-Difluorobenzene 114 6.575 6.575 (1.000) 417699 50.0000 37 Benzene 78 6.097 6.097 (0.927) 29178 2.00000 2.04 38 Trichloroethene 130 6.825 6.819 (1.038) 7757 2.00000 2.03 39 Bromodichloromethane 83 7.380 7.381 (1.122) 10305 2.00000 2.14(T) 40 Methyl Methacrylate 41 7.252 7.252 (1.253) 8260 2.00000 1.99(Ta) 41 2-Chloroethylvinyl ether 63 8.157 8.164 (1.241) 2211 4.00000 3.81(aM) 42 1,2-Dichloropropane 63 7.069 7.069 (1.075) 8728 2.00000 2.10(M) 43 2-Nitropropane 43 8.032 8.038 (1.388) 17673 2.00000 2.03(Ta) 44 Dibromomethane 93 7.197 7.194 (1.095) 3908 2.00000 1.90 45 4-Methyl-2-Pentanone 43 8.032 8.038 (0.843) 17673 4.00000 4.25 46 cis-1,3-Dichloropropene 75 7.842 7.843 (1.193) 10628 2.00000 1.97

* 47 Chlorobenzene-d5 117 9.524 9.527 (1.000) 364855 50.0000

$ 48 Toluene-d8 98 8.093 8.093 (0.850) 20619 2.00000 0.93(Ta) 49 Ethyl Methacrylate 69 8.529 8.539 (1.297) 11204 2.00000 2.15(T) 50 Toluene 91 8.160 8.164 (0.857) 31354 2.00000 2.13 51 trans-1,3-Dichloropropene 75 8.420 8.420 (1.281) 8195 2.00000 1.96(M) 52 2-Hexanone 43 8.869 8.873 (0.931) 11116 4.00000 4.30(M) 53 1,1,2-Trichloroethane 83 8.597 8.600 (0.903) 5864 2.00000 2.09 54 1,3-Dichloropropane 76 8.747 8.760 (0.918) 11742 2.00000 2.12 55 Dibromochloromethane 129 8.972 8.975 (0.942) 7781 2.00000 1.99(T) 56 Tetrachloroethene 164 8.686 8.693 (0.912) 6293 2.00000 2.12 57 1,2-Dibromoethane 107 9.071 9.072 (0.952) 6385 2.00000 1.89(T) 59 Chlorobenzene 112 9.553 9.556 (1.003) 19081 2.00000 2.09 60 1,1,1,2-Tetrachloroethane 131 9.646 9.652 (1.013) 7754 2.00000 2.16 61 Ethylbenzene 106 9.668 9.678 (1.015) 11299 2.00000 0.37(a) 64 Styrene 104 10.198 10.204 (1.071) 19882 2.00000 2.04 66 Bromoform 173 10.371 10.378 (1.089) 5215 2.00000 1.91(T) 67 Isopropylbenzene 105 10.548 10.551 (1.107) 32668 2.00000 2.08 68 1,1,2,2-Tetrachloroethane 83 10.868 10.878 (0.918) 9995 2.00000 2.23(M)

* 70 1,4-Dichlorobenzene-d4 152 11.834 11.838 (1.000) 140271 50.0000 71 1,2,3-Trichloropropane 75 10.904 10.907 (0.921) 9210 2.00000 2.19 72 trans-1,4-Dichloro-2-butene 53 10.926 10.936 (1.147) 1639 2.00000 3.00(M) 74 Bromobenzene 156 10.833 10.837 (0.915) 8034 2.00000 2.11 75 1,3,5-Trimethylbenzene 105 11.128 11.138 (0.940) 28270 2.00000 1.86 81 sec-Butylbenzene 105 11.667 11.674 (0.986) 30286 2.00000 2.16 82 p-Isopropyltoluene 119 11.818 11.825 (0.999) 23826 2.00000 2.05 83 1,3-Dichlorobenzene 146 11.767 11.774 (0.994) 13443 2.00000 2.06 84 1,4-Dichlorobenzene 146 11.857 11.863 (1.002) 12345 2.00000 2.02 87 n-Butylbenzene 91 12.219 12.226 (1.033) 17327 2.00000 2.02 88 1,2-Dichlorobenzene 146 12.223 12.229 (1.033) 13071 2.00000 2.03 89 1,2-Dibromo-3-Chloropropane 75 13.009 13.009 (1.099) 1249 2.00000 1.45(M) 90 1,2,4-Trichlorobenzene 180 13.821 13.821 (1.168) 4411 2.00000 1.05(T)

67 of 595

00913558




91 Hexachlorobutadiene 225 13.984 13.988 (1.182) 3440 2.00000 2.01(M) 93 1,2,3-Trichlorobenzene 182 14.296 14.302 (1.208) 4040 2.00000 1.07(T) 146 Methyl acetate 43 3.257 3.241 (0.563) 8624 2.00000 1.99(aM) 139 Diethyl ether 59 2.554 2.545 (0.442) 12298 2.00000 1.88 147 Methylcyclohexane 83 6.989 6.992 (1.063) 12089 2.00000 0.41(a) 135 1,4-Dioxane 88 7.249 7.246 (1.253) 1370 40.0000 35.04(M) 132 n-Butanol 56 6.992 6.996 (1.209) 5725 40.0000 20.17 131 Methyl Acrylate 55 5.282 5.282 (0.913) 8116 2.00000 0.39(a) 133 Ethyl Acrylate 55 7.011 7.018 (1.212) 23903 2.00000 2.05(M) 136 n-Hexane 57 4.072 4.063 (0.704) 9085 2.00000 2.06 141 Cyclohexane 56 5.689 5.689 (0.983) 13956 2.00000 2.03(a) 142 Tetrahydrofuran 42 5.442 5.423 (0.941) 6428 4.00000 4.32(M) 148 Tert-butyl alcohol 59 3.594 3.597 (0.621) 13853 40.0000 33.91 149 Isopropyl alcohol 45 3.084 3.093 (0.533) 10546 40.0000 39.88(M) 151 4-Methyl-2-pentanol 45 8.471 8.478 (0.889) 33569 40.0000 38.77 167 Ethanol 45 2.557 2.545 (0.442) 14168 40.0000 42.41(M) 170 1,3,5-Trichlorobenzene 180 13.205 13.208 (1.116) 8459 2.00000 2.02(T) 172 tert-Butyl formate 59 4.919 4.919 (0.850) 18847 4.00000 3.94 173 3,3-Dimethyl-1-butanol 57 9.113 9.110 (0.957) 11060 40.0000 34.50 174 tert-Amyl methyl ether 73 6.260 6.261 (1.082) 17566 2.00000 1.90(T) 175 tert-Butyl ethyl ether 59 6.244 6.254 (1.079) 9590 2.00000 1.91 176 tert-Amyl alcohol 59 6.244 6.254 (1.079) 9590 40.0000 38.28 157 2-Methylnaphthalene 142 15.194 15.191 (1.284) 1755 2.00000 5.92(M) 156 Diisopropyl ether 45 4.435 4.435 (0.767) 28685 2.00000 1.97(T) 171 1-Methylnaphthalene 142 15.393 15.387 (1.301) 1500 2.00000 5.25(M) 130 Ethyl Acetate 43 5.253 5.256 (0.908) 20327 2.00000 2.29(aM)


QC Flag Legend


68 of 595

00913559

69 of 595

00913560








* 1 Pentafluorobenzene 168 5.783 5.783 (1.000) 253796 50.0000 2 Dichlorodifluoromethane 85 1.467 1.454 (0.254) 13256 5.00000 5.30(T)

186 Isobutylene 56 1.672 1.666 (0.289) 24641 5.00000 5.46(AM) 3 Chloromethane 50 1.617 1.601 (0.280) 32514 5.00000 5.19 4 Propionitrile 54 5.243 5.276 (0.907) 57765 50.0000 50.35 5 Vinyl Chloride 62 1.698 1.688 (0.294) 22321 5.00000 5.32 6 Bromomethane 94 1.961 1.941 (0.339) 17001 5.00000 5.06(TM) 7 Chloroethane 64 2.051 2.031 (0.355) 14143 5.00000 5.28

159 Dichlorofluoromethane 67 2.243 2.227 (0.388) 33404 5.00000 5.37(T) 8 Trichlorofluoromethane 101 2.269 2.253 (0.392) 21379 5.00000 5.22(T) 9 Acrolein 56 2.702 2.699 (0.467) 3154 10.0000 3.00(T) 10 Acetone 43 2.882 2.869 (0.498) 14782 10.0000 10.09(M) 11 1,1-Dichloroethene 96 2.769 2.750 (0.479) 16201 5.00000 5.40 12 Isobutyl Alcohol 74 6.161 6.184 (1.065) 1685 100.000 98.77(M) 13 Acetonitrile 39 3.180 3.174 (0.550) 8459 50.0000 27.26 14 Allyl Chloride 41 3.193 3.180 (0.552) 47608 5.00000 4.62 15 Iodomethane 142 2.920 2.914 (0.505) 15445 10.0000 6.71(T) 16 Acrylonitrile 53 3.719 3.710 (0.643) 12477 10.0000 8.34 17 Methylene Chloride 84 3.350 3.334 (0.579) 19984 5.00000 4.48 18 Methyl tert-butyl ether 73 3.697 3.697 (0.639) 49506 5.00000 5.42(T) 19 Carbon Disulfide 76 2.968 2.962 (0.513) 59068 10.0000 10.43 20 trans-1,2-Dichloroethene 96 3.684 3.668 (0.637) 15996 5.00000 5.17

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00913561




21 Vinyl Acetate 43 5.250 5.256 (0.908) 46660 10.0000 11.18(M) 22 1,1-Dichloroethane 63 4.284 4.281 (0.741) 37049 5.00000 5.22(T) 24 2-Butanone 43 5.160 5.150 (0.892) 17114 10.0000 9.82 25 Methacrylonitrile 41 5.417 5.414 (0.937) 20311 5.00000 5.32 26 2,2-Dichloropropane 77 5.051 5.044 (0.873) 19461 5.00000 5.04 27 cis-1,2-Dichloroethene 96 5.080 5.073 (0.878) 19860 5.00000 5.32 28 Chloroform 83 5.500 5.497 (0.951) 31810 5.00000 5.34 29 Bromochloromethane 128 5.378 5.378 (0.930) 9657 5.00000 5.55

$ 30 Dibromofluoromethane 113 5.689 5.689 (0.984) 12457 5.00000 5.49 31 1,1,1-Trichloroethane 97 5.654 5.657 (0.978) 26302 5.00000 5.24 32 1,1-Dichloropropene 75 5.856 5.856 (0.891) 21413 5.00000 4.02 33 1,2-Dichloroethane 62 6.145 6.148 (0.935) 23092 5.00000 5.32 34 Carbon Tetrachloride 117 5.840 5.837 (0.888) 24656 5.00000 4.89(M)

$ 35 1,2-Dichloroethane-d4 65 6.065 6.059 (1.049) 13785 5.00000 5.32

* 36 1,4-Difluorobenzene 114 6.575 6.575 (1.000) 397495 50.0000 37 Benzene 78 6.097 6.097 (0.927) 74577 5.00000 5.48 38 Trichloroethene 130 6.825 6.819 (1.038) 19772 5.00000 5.44 39 Bromodichloromethane 83 7.377 7.381 (1.122) 24672 5.00000 5.39(T) 40 Methyl Methacrylate 41 7.249 7.252 (1.254) 20610 5.00000 5.33 41 2-Chloroethylvinyl ether 63 8.157 8.164 (1.241) 6081 10.0000 11.02(T) 42 1,2-Dichloropropane 63 7.073 7.069 (1.076) 21892 5.00000 5.54(M) 43 2-Nitropropane 43 8.029 8.038 (1.388) 41947 5.00000 5.16(T) 44 Dibromomethane 93 7.188 7.194 (1.093) 9731 5.00000 4.98 45 4-Methyl-2-Pentanone 43 8.029 8.038 (0.843) 41947 10.0000 10.58 46 cis-1,3-Dichloropropene 75 7.843 7.843 (1.193) 27121 5.00000 5.29

* 47 Chlorobenzene-d5 117 9.524 9.527 (1.000) 348068 50.0000

$ 48 Toluene-d8 98 8.090 8.093 (0.849) 49918 5.00000 5.17 49 Ethyl Methacrylate 69 8.529 8.539 (1.297) 25823 5.00000 5.22 50 Toluene 91 8.157 8.164 (0.856) 78323 5.00000 5.57 51 trans-1,3-Dichloropropene 75 8.420 8.420 (1.281) 19557 5.00000 4.92 52 2-Hexanone 43 8.866 8.873 (0.931) 27891 10.0000 11.63(M) 53 1,1,2-Trichloroethane 83 8.594 8.600 (0.902) 14798 5.00000 5.53 54 1,3-Dichloropropane 76 8.751 8.760 (0.919) 28604 5.00000 5.41 55 Dibromochloromethane 129 8.969 8.975 (0.942) 20462 5.00000 5.48(T) 56 Tetrachloroethene 164 8.690 8.693 (0.912) 15770 5.00000 5.56 57 1,2-Dibromoethane 107 9.068 9.072 (0.952) 17544 5.00000 5.45(T) 58 1-Chlorohexane 55 9.550 9.559 (1.452) 20511 5.00000 4.20 59 Chlorobenzene 112 9.550 9.556 (1.003) 47868 5.00000 5.49 60 1,1,1,2-Tetrachloroethane 131 9.643 9.652 (1.012) 18909 5.00000 5.52 61 Ethylbenzene 106 9.669 9.678 (1.015) 27181 5.00000 4.53 62 m,p-Xylenes 106 9.787 9.800 (1.028) 68774 10.0000 8.21 63 o-Xylene 106 10.176 10.182 (1.068) 34473 5.00000 4.13 64 Styrene 104 10.195 10.204 (1.070) 51262 5.00000 5.51 66 Bromoform 173 10.378 10.378 (1.090) 14038 5.00000 5.39(T) 67 Isopropylbenzene 105 10.545 10.551 (1.107) 81872 5.00000 5.47 68 1,1,2,2-Tetrachloroethane 83 10.869 10.878 (0.918) 24724 5.00000 5.53(M)

$ 69 4-Bromofluorobenzene 95 10.692 10.699 (1.123) 16698 5.00000 4.06

* 70 1,4-Dichlorobenzene-d4 152 11.835 11.838 (1.000) 140027 50.0000 71 1,2,3-Trichloropropane 75 10.901 10.907 (0.921) 22269 5.00000 5.31 72 trans-1,4-Dichloro-2-butene 53 10.926 10.936 (1.147) 3925 5.00000 5.32(M) 73 n-Propylbenzene 91 10.952 10.962 (0.925) 87800 5.00000 3.79 74 Bromobenzene 156 10.830 10.837 (0.915) 20340 5.00000 5.37 75 1,3,5-Trimethylbenzene 105 11.129 11.138 (0.940) 66428 5.00000 5.22 76 2-Chlorotoluene 91 11.026 11.036 (0.932) 56944 5.00000 4.13

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00913562




77 4-Chlorotoluene 91 11.138 11.145 (0.941) 59905 5.00000 3.84 78 tert-Butylbenzene 119 11.449 11.456 (0.967) 55700 5.00000 3.89 79 1,2,4-Trimethylbenzene 105 11.498 11.507 (0.972) 64820 5.00000 3.80 81 sec-Butylbenzene 105 11.664 11.674 (0.986) 75987 5.00000 5.44 82 p-Isopropyltoluene 119 11.815 11.825 (0.998) 61403 5.00000 5.31 83 1,3-Dichlorobenzene 146 11.767 11.774 (0.994) 34922 5.00000 5.36 84 1,4-Dichlorobenzene 146 11.854 11.863 (1.002) 30480 5.00000 5.01 87 n-Butylbenzene 91 12.223 12.226 (1.033) 45367 5.00000 5.30 88 1,2-Dichlorobenzene 146 12.223 12.229 (1.033) 34656 5.00000 5.39 89 1,2-Dibromo-3-Chloropropane 75 13.009 13.009 (1.099) 3274 5.00000 4.40 90 1,2,4-Trichlorobenzene 180 13.818 13.821 (1.168) 15011 5.00000 4.04 91 Hexachlorobutadiene 225 13.988 13.988 (1.182) 9227 5.00000 5.42 92 Naphthalene 128 14.062 14.065 (1.188) 35263 5.00000 3.12 93 1,2,3-Trichlorobenzene 182 14.302 14.302 (1.209) 14249 5.00000 4.32 146 Methyl acetate 43 3.251 3.241 (0.562) 21428 5.00000 5.30(M) 138 Freon TF 101 2.785 2.763 (0.482) 15238 5.00000 5.02 139 Diethyl ether 59 2.554 2.545 (0.442) 33674 5.00000 5.51 147 Methylcyclohexane 83 6.986 6.992 (1.062) 28010 5.00000 4.49 135 1,4-Dioxane 88 7.249 7.246 (1.254) 4074 100.000 112.92 132 n-Butanol 56 6.992 6.996 (1.209) 14197 100.000 100.27 131 Methyl Acrylate 55 5.269 5.282 (0.911) 30172 5.00000 4.35 133 Ethyl Acrylate 55 7.008 7.018 (1.212) 55713 5.00000 5.11 136 n-Hexane 57 4.066 4.063 (0.703) 22171 5.00000 5.40 141 Cyclohexane 56 5.686 5.689 (0.983) 33906 5.00000 5.30 142 Tetrahydrofuran 42 5.436 5.423 (0.940) 13050 10.0000 9.38 148 Tert-butyl alcohol 59 3.575 3.597 (0.618) 34626 100.000 89.58 149 Isopropyl alcohol 45 3.081 3.093 (0.533) 26438 100.000 107.03(M) 151 4-Methyl-2-pentanol 45 8.459 8.478 (0.888) 84509 100.000 102.32 166 1,2,3-Trimethylbenzene 105 11.912 11.921 (1.007) 61020 5.00000 4.01 167 Ethanol 45 2.551 2.545 (0.441) 33679 100.000 107.91(T) 170 1,3,5-Trichlorobenzene 180 13.202 13.208 (1.116) 21868 5.00000 5.23 172 tert-Butyl formate 59 4.919 4.919 (0.851) 47230 10.0000 10.59 173 3,3-Dimethyl-1-butanol 57 9.110 9.110 (0.957) 29975 100.000 98.01 174 tert-Amyl methyl ether 73 6.261 6.261 (1.083) 47286 5.00000 5.47 175 tert-Butyl ethyl ether 59 6.241 6.254 (1.079) 23164 5.00000 4.94 176 tert-Amyl alcohol 59 6.241 6.254 (1.079) 23164 100.000 98.99 157 2-Methylnaphthalene 142 15.198 15.191 (1.284) 2327 5.00000 6.10(M) 156 Diisopropyl ether 45 4.428 4.435 (0.766) 72470 5.00000 5.34(T) 171 1-Methylnaphthalene 142 15.380 15.387 (1.300) 2166 5.00000 5.44(M) 130 Ethyl Acetate 43 5.250 5.256 (0.908) 42308 5.00000 5.10

M 94 1,2-Dichloroethylene (total) 96 35856 10.0000 10.49

M 95 Xylenes (total) 106 103247 15.0000 12.34

QC Flag Legend

T - Target compound detected outside RT window.A - Target compound detected but, quantitated amount exceeded maximum amount.M - Compound response manually integrated.

72 of 595

00913563

73 of 595

00913564








* 1 Pentafluorobenzene 168 5.779 5.783 (1.000) 259438 50.0000 2 Dichlorodifluoromethane 85 1.457 1.454 (0.252) 24910 10.0000 9.75(T)

186 Isobutylene 56 1.666 1.666 (0.288) 50118 10.0000 10.87(AM) 3 Chloromethane 50 1.605 1.601 (0.278) 65577 10.0000 10.24(T) 4 Propionitrile 54 5.240 5.276 (0.907) 115507 100.000 98.49 5 Vinyl Chloride 62 1.698 1.688 (0.294) 46176 10.0000 10.78 6 Bromomethane 94 1.961 1.941 (0.339) 27205 10.0000 9.96(T) 7 Chloroethane 64 2.054 2.031 (0.355) 28101 10.0000 10.27

159 Dichlorofluoromethane 67 2.246 2.227 (0.389) 64582 10.0000 10.16 8 Trichlorofluoromethane 101 2.262 2.253 (0.392) 43211 10.0000 10.33 9 Acrolein 56 2.696 2.699 (0.466) 12659 10.0000 14.67 10 Acetone 43 2.866 2.869 (0.496) 25014 20.0000 19.07 11 1,1-Dichloroethene 96 2.763 2.750 (0.478) 31839 10.0000 10.38 12 Isobutyl Alcohol 74 6.171 6.184 (1.068) 3016 200.000 174.04(AM) 13 Acetonitrile 39 3.190 3.174 (0.552) 36985 100.000 100.41 14 Allyl Chloride 41 3.193 3.180 (0.553) 96536 10.0000 9.16 15 Iodomethane 142 2.923 2.914 (0.506) 44110 20.0000 16.77 16 Acrylonitrile 53 3.703 3.710 (0.641) 28626 20.0000 18.10 17 Methylene Chloride 84 3.344 3.334 (0.579) 38425 10.0000 9.83 18 Methyl tert-butyl ether 73 3.690 3.697 (0.639) 93072 10.0000 9.97(T) 19 Carbon Disulfide 76 2.965 2.962 (0.513) 116990 20.0000 20.22 20 trans-1,2-Dichloroethene 96 3.674 3.668 (0.636) 32367 10.0000 10.23

74 of 595

00913565




21 Vinyl Acetate 43 5.243 5.256 (0.907) 85414 20.0000 20.03(M) 22 1,1-Dichloroethane 63 4.284 4.281 (0.741) 71894 10.0000 9.91 24 2-Butanone 43 5.150 5.150 (0.891) 35600 20.0000 19.98 25 Methacrylonitrile 41 5.410 5.414 (0.936) 38891 10.0000 9.97 26 2,2-Dichloropropane 77 5.045 5.044 (0.873) 38792 10.0000 9.82 27 cis-1,2-Dichloroethene 96 5.073 5.073 (0.878) 39191 10.0000 10.27 28 Chloroform 83 5.497 5.497 (0.951) 60313 10.0000 9.92 29 Bromochloromethane 128 5.365 5.378 (0.928) 17916 10.0000 10.08

$ 30 Dibromofluoromethane 113 5.693 5.689 (0.985) 23591 10.0000 10.17 31 1,1,1-Trichloroethane 97 5.657 5.657 (0.979) 51685 10.0000 10.08 32 1,1-Dichloropropene 75 5.856 5.856 (0.891) 43842 10.0000 10.11 33 1,2-Dichloroethane 62 6.148 6.148 (0.936) 41299 10.0000 9.23 34 Carbon Tetrachloride 117 5.837 5.837 (0.888) 43106 10.0000 9.58(M)


* 36 1,4-Difluorobenzene 114 6.572 6.575 (1.000) 409662 50.0000 37 Benzene 78 6.097 6.097 (0.928) 141855 10.0000 10.12 38 Trichloroethene 130 6.819 6.819 (1.038) 37563 10.0000 10.03 39 Bromodichloromethane 83 7.377 7.381 (1.123) 48254 10.0000 10.23 40 Methyl Methacrylate 41 7.249 7.252 (1.254) 40096 10.0000 10.16 41 2-Chloroethylvinyl ether 63 8.157 8.164 (1.241) 11589 20.0000 20.39(T) 42 1,2-Dichloropropane 63 7.069 7.069 (1.076) 41267 10.0000 10.14(M) 43 2-Nitropropane 43 8.026 8.038 (1.389) 85587 10.0000 10.31 44 Dibromomethane 93 7.194 7.194 (1.095) 20744 10.0000 10.30 45 4-Methyl-2-Pentanone 43 8.026 8.038 (0.843) 85587 20.0000 20.67 46 cis-1,3-Dichloropropene 75 7.839 7.843 (1.193) 54887 10.0000 10.39

* 47 Chlorobenzene-d5 117 9.524 9.527 (1.000) 363386 50.0000

$ 48 Toluene-d8 98 8.090 8.093 (0.849) 94630 10.0000 10.88 49 Ethyl Methacrylate 69 8.529 8.539 (1.298) 50565 10.0000 9.93 50 Toluene 91 8.157 8.164 (0.856) 150129 10.0000 10.24 51 trans-1,3-Dichloropropene 75 8.417 8.420 (1.281) 43975 10.0000 10.74 52 2-Hexanone 43 8.866 8.873 (0.931) 53046 20.0000 21.79(M) 53 1,1,2-Trichloroethane 83 8.594 8.600 (0.902) 28314 10.0000 10.15 54 1,3-Dichloropropane 76 8.751 8.760 (0.919) 56509 10.0000 10.24 55 Dibromochloromethane 129 8.969 8.975 (0.942) 39639 10.0000 10.17 56 Tetrachloroethene 164 8.687 8.693 (0.912) 30467 10.0000 10.30 57 1,2-Dibromoethane 107 9.065 9.072 (0.952) 35052 10.0000 10.44 58 1-Chlorohexane 55 9.550 9.559 (1.453) 37440 10.0000 9.94 59 Chlorobenzene 112 9.550 9.556 (1.003) 93169 10.0000 10.24 60 1,1,1,2-Tetrachloroethane 131 9.646 9.652 (1.013) 37081 10.0000 10.38 61 Ethylbenzene 106 9.672 9.678 (1.015) 50730 10.0000 9.95 62 m,p-Xylenes 106 9.787 9.800 (1.028) 125473 20.0000 19.57 63 o-Xylene 106 10.176 10.182 (1.068) 65376 10.0000 9.75 64 Styrene 104 10.195 10.204 (1.070) 101912 10.0000 10.50 66 Bromoform 173 10.375 10.378 (1.089) 28115 10.0000 10.34 67 Isopropylbenzene 105 10.545 10.551 (1.107) 158107 10.0000 10.12 68 1,1,2,2-Tetrachloroethane 83 10.869 10.878 (0.918) 47529 10.0000 10.01


* 70 1,4-Dichlorobenzene-d4 152 11.835 11.838 (1.000) 148743 50.0000 71 1,2,3-Trichloropropane 75 10.901 10.907 (0.921) 44493 10.0000 9.99 72 trans-1,4-Dichloro-2-butene 53 10.926 10.936 (1.147) 8368 10.0000 9.39 73 n-Propylbenzene 91 10.952 10.962 (0.925) 168777 10.0000 9.78 74 Bromobenzene 156 10.830 10.837 (0.915) 40471 10.0000 10.06 75 1,3,5-Trimethylbenzene 105 11.129 11.138 (0.940) 126149 10.0000 9.90 76 2-Chlorotoluene 91 11.026 11.036 (0.932) 108992 10.0000 9.84

75 of 595

00913566




77 4-Chlorotoluene 91 11.135 11.145 (0.941) 115902 10.0000 9.66 78 tert-Butylbenzene 119 11.446 11.456 (0.967) 107434 10.0000 9.77 79 1,2,4-Trimethylbenzene 105 11.498 11.507 (0.972) 124673 10.0000 9.62 81 sec-Butylbenzene 105 11.665 11.674 (0.986) 148486 10.0000 10.01 82 p-Isopropyltoluene 119 11.815 11.825 (0.998) 119366 10.0000 9.72 83 1,3-Dichlorobenzene 146 11.767 11.774 (0.994) 69865 10.0000 10.10 84 1,4-Dichlorobenzene 146 11.857 11.863 (1.002) 62144 10.0000 9.62 87 n-Butylbenzene 91 12.220 12.226 (1.033) 89410 10.0000 9.84 88 1,2-Dichlorobenzene 146 12.223 12.229 (1.033) 68867 10.0000 10.09 89 1,2-Dibromo-3-Chloropropane 75 13.006 13.009 (1.099) 6984 10.0000 9.22 90 1,2,4-Trichlorobenzene 180 13.818 13.821 (1.168) 35028 10.0000 9.09 91 Hexachlorobutadiene 225 13.988 13.988 (1.182) 18066 10.0000 10.00 92 Naphthalene 128 14.062 14.065 (1.188) 86355 10.0000 8.61 93 1,2,3-Trichlorobenzene 182 14.299 14.302 (1.208) 31035 10.0000 9.08 146 Methyl acetate 43 3.244 3.241 (0.561) 40467 10.0000 9.79(M) 138 Freon TF 101 2.776 2.763 (0.480) 28411 10.0000 10.39 139 Diethyl ether 59 2.558 2.545 (0.443) 65398 10.0000 10.48 147 Methylcyclohexane 83 6.986 6.992 (1.063) 51617 10.0000 9.95 135 1,4-Dioxane 88 7.246 7.246 (1.254) 7134 200.000 193.89 132 n-Butanol 56 6.989 6.996 (1.209) 25030 200.000 193.41 131 Methyl Acrylate 55 5.266 5.282 (0.911) 60823 10.0000 9.49 133 Ethyl Acrylate 55 7.012 7.018 (1.213) 108114 10.0000 9.71 136 n-Hexane 57 4.063 4.063 (0.703) 40724 10.0000 9.71 141 Cyclohexane 56 5.686 5.689 (0.984) 65129 10.0000 9.96 142 Tetrahydrofuran 42 5.423 5.423 (0.938) 27495 20.0000 19.35 148 Tert-butyl alcohol 59 3.581 3.597 (0.620) 73632 200.000 185.62 149 Isopropyl alcohol 45 3.074 3.093 (0.532) 51774 200.000 205.05(M) 151 4-Methyl-2-pentanol 45 8.452 8.478 (0.887) 188427 200.000 218.52 166 1,2,3-Trimethylbenzene 105 11.912 11.921 (1.007) 114630 10.0000 9.37 167 Ethanol 45 2.554 2.545 (0.442) 58210 200.000 182.46 170 1,3,5-Trichlorobenzene 180 13.202 13.208 (1.116) 44995 10.0000 10.14 172 tert-Butyl formate 59 4.919 4.919 (0.851) 94575 20.0000 20.75 173 3,3-Dimethyl-1-butanol 57 9.107 9.110 (0.956) 66519 200.000 208.34 174 tert-Amyl methyl ether 73 6.257 6.261 (1.083) 89763 10.0000 10.17 175 tert-Butyl ethyl ether 59 6.232 6.254 (1.078) 46555 10.0000 9.73 176 tert-Amyl alcohol 59 6.232 6.254 (1.078) 46555 200.000 194.63 157 2-Methylnaphthalene 142 15.194 15.191 (1.284) 4496 10.0000 6.67(T) 156 Diisopropyl ether 45 4.425 4.435 (0.766) 141565 10.0000 10.21(T) 171 1-Methylnaphthalene 142 15.380 15.387 (1.300) 4335 10.0000 5.98(T) 130 Ethyl Acetate 43 5.243 5.256 (0.907) 80336 10.0000 9.47


M 95 Xylenes (total) 106 190849 30.0000 29.33

QC Flag Legend


76 of 595

00913567

77 of 595

00913568








* 1 Pentafluorobenzene 168 5.789 5.783 (1.000) 251109 50.0000 2 Dichlorodifluoromethane 85 1.466 1.454 (0.253) 50532 20.0000 20.44

186 Isobutylene 56 1.678 1.666 (0.290) 101339 20.0000 22.71(AM) 3 Chloromethane 50 1.620 1.601 (0.280) 123465 20.0000 19.92 4 Propionitrile 54 5.246 5.276 (0.906) 244334 200.000 215.25 5 Vinyl Chloride 62 1.707 1.688 (0.295) 86204 20.0000 20.80 6 Bromomethane 94 1.977 1.941 (0.342) 50761 20.0000 22.56(M) 7 Chloroethane 64 2.063 2.031 (0.356) 53126 20.0000 20.06

159 Dichlorofluoromethane 67 2.253 2.227 (0.389) 130501 20.0000 21.22 8 Trichlorofluoromethane 101 2.275 2.253 (0.393) 85560 20.0000 21.13 9 Acrolein 56 2.715 2.699 (0.469) 28091 40.0000 34.91 10 Acetone 43 2.881 2.869 (0.498) 45660 40.0000 39.15 11 1,1-Dichloroethene 96 2.772 2.750 (0.479) 61574 20.0000 20.74 12 Isobutyl Alcohol 74 6.171 6.184 (1.066) 6649 400.000 398.27(A) 13 Acetonitrile 39 3.193 3.174 (0.552) 74469 200.000 203.54 14 Allyl Chloride 41 3.206 3.180 (0.554) 213841 20.0000 20.97 15 Iodomethane 142 2.930 2.914 (0.506) 108093 40.0000 40.75 16 Acrylonitrile 53 3.719 3.710 (0.642) 57890 40.0000 37.28 17 Methylene Chloride 84 3.360 3.334 (0.580) 75907 20.0000 21.72 18 Methyl tert-butyl ether 73 3.709 3.697 (0.641) 184825 20.0000 20.45 19 Carbon Disulfide 76 2.981 2.962 (0.515) 234013 40.0000 41.79 20 trans-1,2-Dichloroethene 96 3.687 3.668 (0.637) 63896 20.0000 20.87

78 of 595

00913569





$ 30 Dibromofluoromethane 113 5.692 5.689 (0.983) 44899 20.0000 19.99 31 1,1,1-Trichloroethane 97 5.664 5.657 (0.978) 100939 20.0000 20.34 32 1,1-Dichloropropene 75 5.863 5.856 (0.891) 84761 20.0000 21.81 33 1,2-Dichloroethane 62 6.151 6.148 (0.935) 93619 20.0000 21.15 34 Carbon Tetrachloride 117 5.843 5.837 (0.888) 87056 20.0000 21.50


* 36 1,4-Difluorobenzene 114 6.578 6.575 (1.000) 405298 50.0000 37 Benzene 78 6.100 6.097 (0.927) 278242 20.0000 20.06 38 Trichloroethene 130 6.822 6.819 (1.037) 75603 20.0000 20.42 39 Bromodichloromethane 83 7.380 7.381 (1.122) 97386 20.0000 20.87 40 Methyl Methacrylate 41 7.249 7.252 (1.252) 79558 20.0000 20.83 41 2-Chloroethylvinyl ether 63 8.157 8.164 (1.240) 22982 40.0000 40.87(T) 42 1,2-Dichloropropane 63 7.069 7.069 (1.075) 82902 20.0000 20.60 43 2-Nitropropane 43 8.029 8.038 (1.387) 170991 20.0000 21.29 44 Dibromomethane 93 7.197 7.194 (1.094) 42450 20.0000 21.32 45 4-Methyl-2-Pentanone 43 8.029 8.038 (0.843) 170991 40.0000 41.17 46 cis-1,3-Dichloropropene 75 7.842 7.843 (1.192) 112442 20.0000 21.53

* 47 Chlorobenzene-d5 117 9.524 9.527 (1.000) 364615 50.0000




79 of 595

00913570




77 4-Chlorotoluene 91 11.138 11.145 (0.941) 234044 20.0000 22.45 78 tert-Butylbenzene 119 11.449 11.456 (0.967) 221284 20.0000 23.26 79 1,2,4-Trimethylbenzene 105 11.497 11.507 (0.972) 251933 20.0000 22.52 81 sec-Butylbenzene 105 11.664 11.674 (0.986) 300936 20.0000 20.01 82 p-Isopropyltoluene 119 11.815 11.825 (0.998) 243485 20.0000 19.57 83 1,3-Dichlorobenzene 146 11.764 11.774 (0.994) 145468 20.0000 20.75 84 1,4-Dichlorobenzene 146 11.857 11.863 (1.002) 134497 20.0000 20.54 87 n-Butylbenzene 91 12.219 12.226 (1.033) 187345 20.0000 20.35 88 1,2-Dichlorobenzene 146 12.219 12.229 (1.033) 143891 20.0000 20.81 89 1,2-Dibromo-3-Chloropropane 75 13.006 13.009 (1.099) 16000 20.0000 21.29 90 1,2,4-Trichlorobenzene 180 13.817 13.821 (1.168) 81951 20.0000 21.23 91 Hexachlorobutadiene 225 13.984 13.988 (1.182) 36905 20.0000 20.14 92 Naphthalene 128 14.061 14.065 (1.188) 207414 20.0000 21.89 93 1,2,3-Trichlorobenzene 182 14.299 14.302 (1.208) 72711 20.0000 21.27 146 Methyl acetate 43 3.254 3.241 (0.562) 75829 20.0000 18.95 138 Freon TF 101 2.788 2.763 (0.482) 55977 20.0000 22.68 139 Diethyl ether 59 2.567 2.545 (0.443) 129690 20.0000 21.47 147 Methylcyclohexane 83 6.995 6.992 (1.063) 102757 20.0000 22.48 135 1,4-Dioxane 88 7.242 7.246 (1.251) 14748 400.000 414.84 132 n-Butanol 56 7.002 6.996 (1.210) 49691 400.000 426.41 131 Methyl Acrylate 55 5.275 5.282 (0.911) 124517 20.0000 21.11 133 Ethyl Acrylate 55 7.008 7.018 (1.211) 219138 20.0000 20.33 136 n-Hexane 57 4.075 4.063 (0.704) 76460 20.0000 18.83 141 Cyclohexane 56 5.692 5.689 (0.983) 133658 20.0000 21.12 142 Tetrahydrofuran 42 5.426 5.423 (0.937) 56530 40.0000 41.10 148 Tert-butyl alcohol 59 3.591 3.597 (0.620) 150333 400.000 390.80 149 Isopropyl alcohol 45 3.080 3.093 (0.532) 99193 400.000 405.88(M) 151 4-Methyl-2-pentanol 45 8.452 8.478 (0.887) 396613 400.000 458.41 166 1,2,3-Trimethylbenzene 105 11.911 11.921 (1.007) 238682 20.0000 22.38 167 Ethanol 45 2.564 2.545 (0.443) 128337 400.000 415.62 170 1,3,5-Trichlorobenzene 180 13.201 13.208 (1.116) 95929 20.0000 21.32 172 tert-Butyl formate 59 4.922 4.919 (0.850) 182102 40.0000 41.28 173 3,3-Dimethyl-1-butanol 57 9.100 9.110 (0.956) 142472 400.000 444.74 174 tert-Amyl methyl ether 73 6.264 6.261 (1.082) 172530 20.0000 20.20 175 tert-Butyl ethyl ether 59 6.238 6.254 (1.078) 98174 20.0000 21.20 176 tert-Amyl alcohol 59 6.238 6.254 (1.078) 98174 400.000 424.04 157 2-Methylnaphthalene 142 15.188 15.191 (1.283) 20571 20.0000 11.14 156 Diisopropyl ether 45 4.438 4.435 (0.767) 281344 20.0000 20.97(T) 171 1-Methylnaphthalene 142 15.383 15.387 (1.300) 29672 20.0000 12.62 130 Ethyl Acetate 43 5.253 5.256 (0.907) 168473 20.0000 20.53


M 95 Xylenes (total) 106 380427 60.0000 67.84

QC Flag Legend


80 of 595

00913571

81 of 595

00913572









186 Isobutylene 56 1.669 1.666 (0.288) 233562 50.0000 51.24(AM) 3 Chloromethane 50 1.614 1.601 (0.279) 293393 50.0000 46.35 4 Propionitrile 54 5.243 5.276 (0.906) 625936 500.000 539.80 5 Vinyl Chloride 62 1.701 1.688 (0.294) 205189 50.0000 48.47 6 Bromomethane 94 1.957 1.941 (0.338) 116355 50.0000 55.12 7 Chloroethane 64 2.054 2.031 (0.355) 125193 50.0000 46.29


82 of 595

00913573








* 47 Chlorobenzene-d5 117 9.524 9.527 (1.000) 376149 50.0000




83 of 595

00913574




77 4-Chlorotoluene 91 11.138 11.145 (0.941) 560850 50.0000 55.63 78 tert-Butylbenzene 119 11.449 11.456 (0.967) 507745 50.0000 54.98 79 1,2,4-Trimethylbenzene 105 11.501 11.507 (0.972) 590154 50.0000 54.61 81 sec-Butylbenzene 105 11.667 11.674 (0.986) 703146 50.0000 44.69 82 p-Isopropyltoluene 119 11.818 11.825 (0.999) 581129 50.0000 44.64 83 1,3-Dichlorobenzene 146 11.767 11.774 (0.994) 354486 50.0000 48.34 84 1,4-Dichlorobenzene 146 11.857 11.863 (1.002) 335572 50.0000 49.00 87 n-Butylbenzene 91 12.219 12.226 (1.033) 451878 50.0000 46.92 88 1,2-Dichlorobenzene 146 12.223 12.229 (1.033) 342263 50.0000 47.32 89 1,2-Dibromo-3-Chloropropane 75 13.009 13.009 (1.099) 40068 50.0000 51.49 90 1,2,4-Trichlorobenzene 180 13.814 13.821 (1.167) 205611 50.0000 51.18 91 Hexachlorobutadiene 225 13.988 13.988 (1.182) 88999 50.0000 46.44 92 Naphthalene 128 14.061 14.065 (1.188) 520687 50.0000 54.03 93 1,2,3-Trichlorobenzene 182 14.299 14.302 (1.208) 180007 50.0000 50.63 146 Methyl acetate 43 3.244 3.241 (0.561) 197627 50.0000 48.36 138 Freon TF 101 2.779 2.763 (0.480) 126169 50.0000 51.84 139 Diethyl ether 59 2.561 2.545 (0.443) 314479 50.0000 50.97 147 Methylcyclohexane 83 6.992 6.992 (1.063) 227867 50.0000 51.42 135 1,4-Dioxane 88 7.239 7.246 (1.251) 36043 1000.00 993.32 132 n-Butanol 56 6.995 6.996 (1.209) 116281 1000.00 1013.24 131 Methyl Acrylate 55 5.269 5.282 (0.911) 309415 50.0000 52.69 133 Ethyl Acrylate 55 7.008 7.018 (1.211) 511812 50.0000 46.50 136 n-Hexane 57 4.069 4.063 (0.703) 190912 50.0000 46.04 141 Cyclohexane 56 5.696 5.689 (0.984) 285609 50.0000 44.18 142 Tetrahydrofuran 42 5.420 5.423 (0.937) 137673 100.000 97.99 148 Tert-butyl alcohol 59 3.581 3.597 (0.619) 414105 1000.00 1052.63 149 Isopropyl alcohol 45 3.077 3.093 (0.532) 258706 1000.00 1036.26 151 4-Methyl-2-pentanol 45 8.455 8.478 (0.888) 981638 1000.00 1099.80 166 1,2,3-Trimethylbenzene 105 11.915 11.921 (1.007) 568751 50.0000 54.77 167 Ethanol 45 2.557 2.545 (0.442) 316539 1000.00 1003.49 170 1,3,5-Trichlorobenzene 180 13.198 13.208 (1.115) 230316 50.0000 48.93 172 tert-Butyl formate 59 4.919 4.919 (0.850) 425127 100.000 94.35 173 3,3-Dimethyl-1-butanol 57 9.094 9.110 (0.955) 386592 1000.00 1169.78 174 tert-Amyl methyl ether 73 6.264 6.261 (1.083) 428470 50.0000 49.12 175 tert-Butyl ethyl ether 59 6.238 6.254 (1.078) 258253 50.0000 54.59 176 tert-Amyl alcohol 59 6.238 6.254 (1.078) 258253 1000.00 1091.94 157 2-Methylnaphthalene 142 15.188 15.191 (1.283) 140132 50.0000 42.14 156 Diisopropyl ether 45 4.435 4.435 (0.767) 667093 50.0000 48.68(T) 171 1-Methylnaphthalene 142 15.387 15.387 (1.300) 162503 50.0000 45.62 130 Ethyl Acetate 43 5.250 5.256 (0.907) 411434 50.0000 49.09


M 95 Xylenes (total) 106 887150 150.000 165.54

QC Flag Legend


84 of 595

00913575

85 of 595

00913576











86 of 595

00913577




21 Vinyl Acetate 43 5.250 5.256 (0.907) 795847 200.000 185.69 22 1,1-Dichloroethane 63 4.281 4.281 (0.740) 690143 100.000 94.67 24 2-Butanone 43 5.144 5.150 (0.889) 368585 200.000 205.81 25 Methacrylonitrile 41 5.410 5.414 (0.935) 395080 100.000 100.79 26 2,2-Dichloropropane 77 5.051 5.044 (0.873) 371671 100.000 93.68 27 cis-1,2-Dichloroethene 96 5.070 5.073 (0.876) 370641 100.000 96.65 28 Chloroform 83 5.497 5.497 (0.950) 562879 100.000 92.11 29 Bromochloromethane 128 5.375 5.378 (0.929) 183010 100.000 102.44



* 36 1,4-Difluorobenzene 114 6.575 6.575 (1.000) 426918 50.0000 37 Benzene 78 6.097 6.097 (0.927) 1282968 100.000 87.84 38 Trichloroethene 130 6.819 6.819 (1.037) 355070 100.000 91.06 39 Bromodichloromethane 83 7.377 7.381 (1.122) 467428 100.000 95.14 40 Methyl Methacrylate 41 7.249 7.252 (1.253) 383130 100.000 96.58 41 2-Chloroethylvinyl ether 63 8.160 8.164 (1.241) 107489 200.000 181.51(TA) 42 1,2-Dichloropropane 63 7.069 7.069 (1.075) 385573 100.000 90.98 43 2-Nitropropane 43 8.029 8.038 (1.388) 797553 100.000 95.61 44 Dibromomethane 93 7.191 7.194 (1.094) 211579 100.000 100.89 45 4-Methyl-2-Pentanone 43 8.029 8.038 (0.843) 797553 200.000 181.38 46 cis-1,3-Dichloropropene 75 7.843 7.843 (1.193) 557549 100.000 101.36

* 47 Chlorobenzene-d5 117 9.524 9.527 (1.000) 386072 50.0000




87 of 595

00913578






M 95 Xylenes (total) 106 1691957 300.000 315.95

QC Flag Legend


88 of 595

00913579

89 of 595

00913580









186 Isobutylene 56 1.666 1.666 (0.288) 798264 200.000 166.19(AM) 3 Chloromethane 50 1.601 1.601 (0.277) 1116699 200.000 167.39(A) 4 Propionitrile 54 5.276 5.276 (0.912) 2398441 2000.00 1962.56 5 Vinyl Chloride 62 1.688 1.688 (0.292) 775310 200.000 173.78 6 Bromomethane 94 1.941 1.941 (0.336) 418221 200.000 196.68(M) 7 Chloroethane 64 2.031 2.031 (0.351) 479438 200.000 168.21

159 Dichlorofluoromethane 67 2.227 2.227 (0.385) 1174143 200.000 177.38(A) 8 Trichlorofluoromethane 101 2.253 2.253 (0.390) 773963 200.000 177.55 9 Acrolein 56 2.699 2.699 (0.467) 333458 400.000 394.85 10 Acetone 43 2.869 2.869 (0.496) 460575 400.000 396.92 11 1,1-Dichloroethene 96 2.750 2.750 (0.476) 573978 200.000 179.64 12 Isobutyl Alcohol 74 6.184 6.184 (1.069) 71030 4000.00 3964.71(A) 13 Acetonitrile 39 3.174 3.174 (0.549) 806581 2000.00 2002.83(A) 14 Allyl Chloride 41 3.180 3.180 (0.550) 2195299 200.000 200.00(A) 15 Iodomethane 142 2.914 2.914 (0.504) 1154316 400.000 394.29 16 Acrylonitrile 53 3.710 3.710 (0.642) 671162 400.000 396.51 17 Methylene Chloride 84 3.334 3.334 (0.577) 699249 200.000 197.88 18 Methyl tert-butyl ether 73 3.697 3.697 (0.639) 1727023 200.000 177.56 19 Carbon Disulfide 76 2.962 2.962 (0.512) 2249686 400.000 373.17 20 trans-1,2-Dichloroethene 96 3.668 3.668 (0.634) 639292 200.000 194.03

90 of 595

00913581




21 Vinyl Acetate 43 5.256 5.256 (0.909) 1554040 400.000 349.79(A) 22 1,1-Dichloroethane 63 4.281 4.281 (0.740) 1367578 200.000 180.97 24 2-Butanone 43 5.150 5.150 (0.891) 721259 400.000 388.52 25 Methacrylonitrile 41 5.414 5.414 (0.936) 766405 200.000 188.62 26 2,2-Dichloropropane 77 5.044 5.044 (0.872) 740521 200.000 180.05 27 cis-1,2-Dichloroethene 96 5.073 5.073 (0.877) 742976 200.000 186.91 28 Chloroform 83 5.497 5.497 (0.951) 1111271 200.000 175.44 29 Bromochloromethane 128 5.378 5.378 (0.930) 346258 200.000 186.97



* 36 1,4-Difluorobenzene 114 6.575 6.575 (1.000) 454445 50.0000 37 Benzene 78 6.097 6.097 (0.927) 2486220 200.000 159.92 38 Trichloroethene 130 6.819 6.819 (1.037) 710981 200.000 171.30 39 Bromodichloromethane 83 7.381 7.381 (1.122) 912989 200.000 174.57 40 Methyl Methacrylate 41 7.252 7.252 (1.254) 745382 200.000 181.27 41 2-Chloroethylvinyl ether 63 8.164 8.164 (1.242) 215382 400.000 341.67(TA) 42 1,2-Dichloropropane 63 7.069 7.069 (1.075) 776902 200.000 172.22 43 2-Nitropropane 43 8.038 8.038 (1.390) 1518699 200.000 175.63 44 Dibromomethane 93 7.194 7.194 (1.094) 421946 200.000 189.02 45 4-Methyl-2-Pentanone 43 8.038 8.038 (0.844) 1518699 400.000 333.27 46 cis-1,3-Dichloropropene 75 7.843 7.843 (1.193) 1087445 200.000 185.71

* 47 Chlorobenzene-d5 117 9.527 9.527 (1.000) 400102 50.0000

$ 48 Toluene-d8 98 8.093 8.093 (0.849) 1519477 200.000 183.51 49 Ethyl Methacrylate 69 8.539 8.539 (1.299) 983733 200.000 174.18 50 Toluene 91 8.164 8.164 (0.857) 2489442 200.000 154.23 51 trans-1,3-Dichloropropene 75 8.420 8.420 (1.281) 931967 200.000 205.34(A) 52 2-Hexanone 43 8.873 8.873 (0.931) 1038275 400.000 351.06(M) 53 1,1,2-Trichloroethane 83 8.600 8.600 (0.903) 534482 200.000 174.01 54 1,3-Dichloropropane 76 8.760 8.760 (0.920) 1051453 200.000 173.15 55 Dibromochloromethane 129 8.975 8.975 (0.942) 763414 200.000 178.04 56 Tetrachloroethene 164 8.693 8.693 (0.912) 546562 200.000 167.93 57 1,2-Dibromoethane 107 9.072 9.072 (0.952) 686213 200.000 185.66 58 1-Chlorohexane 55 9.559 9.559 (1.454) 626126 200.000 195.37 59 Chlorobenzene 112 9.556 9.556 (1.003) 1632277 200.000 163.05 60 1,1,1,2-Tetrachloroethane 131 9.652 9.652 (1.013) 678538 200.000 172.63 61 Ethylbenzene 106 9.678 9.678 (1.016) 904574 200.000 197.07 62 m,p-Xylenes 106 9.800 9.800 (1.029) 2064636 400.000 389.83 63 o-Xylene 106 10.182 10.182 (1.069) 1144596 200.000 196.18 64 Styrene 104 10.204 10.204 (1.071) 1812413 200.000 169.69 66 Bromoform 173 10.378 10.378 (1.089) 556359 200.000 185.91 67 Isopropylbenzene 105 10.551 10.551 (1.107) 2586647 200.000 150.48 68 1,1,2,2-Tetrachloroethane 83 10.878 10.878 (0.919) 874313 200.000 162.77



91 of 595

00913582




77 4-Chlorotoluene 91 11.145 11.145 (0.941) 2015459 200.000 195.03 78 tert-Butylbenzene 119 11.456 11.456 (0.968) 1836426 200.000 194.25 79 1,2,4-Trimethylbenzene 105 11.507 11.507 (0.972) 2151827 200.000 194.75 81 sec-Butylbenzene 105 11.674 11.674 (0.986) 2557821 200.000 152.34 82 p-Isopropyltoluene 119 11.825 11.825 (0.999) 2167935 200.000 156.07 83 1,3-Dichlorobenzene 146 11.774 11.774 (0.995) 1321401 200.000 168.87 84 1,4-Dichlorobenzene 146 11.863 11.863 (1.002) 1307352 200.000 178.91 87 n-Butylbenzene 91 12.226 12.226 (1.033) 1730717 200.000 168.42 88 1,2-Dichlorobenzene 146 12.229 12.229 (1.033) 1246745 200.000 161.52 89 1,2-Dibromo-3-Chloropropane 75 13.009 13.009 (1.099) 164158 200.000 198.72 90 1,2,4-Trichlorobenzene 180 13.821 13.821 (1.168) 845299 200.000 197.68 91 Hexachlorobutadiene 225 13.988 13.988 (1.182) 363074 200.000 177.54 92 Naphthalene 128 14.065 14.065 (1.188) 1981453 200.000 195.47 93 1,2,3-Trichlorobenzene 182 14.302 14.302 (1.208) 747952 200.000 197.77 146 Methyl acetate 43 3.241 3.241 (0.561) 785872 200.000 182.47(A) 138 Freon TF 101 2.763 2.763 (0.478) 499355 200.000 198.75 139 Diethyl ether 59 2.545 2.545 (0.440) 1174554 200.000 180.65 147 Methylcyclohexane 83 6.992 6.992 (1.063) 918919 200.000 196.30 135 1,4-Dioxane 88 7.246 7.246 (1.253) 152862 4000.00 3999.15 132 n-Butanol 56 6.996 6.996 (1.210) 469334 4000.00 3960.35 131 Methyl Acrylate 55 5.282 5.282 (0.913) 1205457 200.000 197.27 133 Ethyl Acrylate 55 7.018 7.018 (1.214) 1992940 200.000 171.80 136 n-Hexane 57 4.063 4.063 (0.703) 769334 200.000 176.06 141 Cyclohexane 56 5.689 5.689 (0.984) 1121288 200.000 164.58(A) 142 Tetrahydrofuran 42 5.423 5.423 (0.938) 530912 400.000 358.55 148 Tert-butyl alcohol 59 3.597 3.597 (0.622) 1649053 4000.00 3975.42 149 Isopropyl alcohol 45 3.093 3.093 (0.535) 1078445 4000.00 4098.77(A) 151 4-Methyl-2-pentanol 45 8.478 8.478 (0.890) 3274909 4000.00 3449.48 166 1,2,3-Trimethylbenzene 105 11.921 11.921 (1.007) 2082564 200.000 195.17 167 Ethanol 45 2.545 2.545 (0.440) 1174855 4000.00 3533.98 170 1,3,5-Trichlorobenzene 180 13.208 13.208 (1.116) 907869 200.000 180.75 172 tert-Butyl formate 59 4.919 4.919 (0.851) 1756860 400.000 369.96 173 3,3-Dimethyl-1-butanol 57 9.110 9.110 (0.956) 1421960 4000.00 4045.11(A) 174 tert-Amyl methyl ether 73 6.261 6.261 (1.083) 1651456 200.000 179.65 175 tert-Butyl ethyl ether 59 6.254 6.254 (1.082) 1020675 200.000 204.73(A) 176 tert-Amyl alcohol 59 6.254 6.254 (1.082) 1020675 4000.00 4094.79(A) 157 2-Methylnaphthalene 142 15.191 15.191 (1.283) 876986 200.000 199.01 156 Diisopropyl ether 45 4.435 4.435 (0.767) 2530817 200.000 175.24 171 1-Methylnaphthalene 142 15.387 15.387 (1.300) 828046 200.000 199.59 130 Ethyl Acetate 43 5.256 5.256 (0.909) 1554040 200.000 175.94


M 95 Xylenes (total) 106 3209232 600.000 586.01

QC Flag Legend


92 of 595

00913583

93 of 595

00913584



Data file : \\nahstws003\Target\CHEM\VOA2.i\E180802.b\E080213.DLab Smp Id: VSTD050 Inj Date : 03-AUG-2018 02:56 Operator : AP Inst ID: VOA2.iSmp Info : VSTD050;VSTD050;2;;Misc Info : HS15080001;WATER;0;1;Comment : Method : \\NAHSTWS003\Target\CHEM\VOA2.i\E180802.b\8260LL.mMeth Date : 17-Aug-2018 12:13 Shiva.Targ Quant Type: ISTDCal Date : 02-AUG-2018 22:37 Cal File: E080203.DAls bottle: 39 Continuing Calibration SampleDil Factor: 1.00000 Integrator: HP RTE Compound Sublist: 00000_8260-LLw.subTarget Version: 4.14







159 Dichlorofluoromethane 67 2.240 2.227 (0.387) 297636 50.0000 46.78 8 Trichlorofluoromethane 101 2.262 2.253 (0.391) 190700 50.0000 45.52 9 Acrolein 56 2.699 2.699 (0.466) 90534 100.000 110.83 10 Acetone 43 2.866 2.869 (0.495) 118757 100.000 103.85 11 1,1-Dichloroethene 96 2.763 2.750 (0.478) 144263 50.0000 46.97 12 Isobutyl Alcohol 74 6.161 6.184 (1.065) 16736 1000.00 970.90(AH) 13 Acetonitrile 39 3.186 3.174 (0.551) 188092 500.000 489.71 14 Allyl Chloride 41 3.196 3.180 (0.552) 546187 50.0000 51.77 15 Iodomethane 142 2.923 2.914 (0.505) 234052 100.000 84.06 16 Acrylonitrile 53 3.700 3.710 (0.640) 163655 100.000 100.97 17 Methylene Chloride 84 3.347 3.334 (0.579) 175252 50.0000 50.42 18 Methyl tert-butyl ether 73 3.700 3.697 (0.640) 455348 50.0000 48.71 19 Carbon Disulfide 76 2.968 2.962 (0.513) 554956 100.000 95.78 20 trans-1,2-Dichloroethene 96 3.677 3.668 (0.636) 156679 50.0000 49.48

94 of 595

00913585




21 Vinyl Acetate 43 5.247 5.256 (0.907) 406557 100.000 95.21 22 1,1-Dichloroethane 63 4.287 4.281 (0.741) 343327 50.0000 47.27 24 2-Butanone 43 5.144 5.150 (0.889) 185701 100.000 104.08 25 Methacrylonitrile 41 5.413 5.414 (0.936) 198490 50.0000 50.82 26 2,2-Dichloropropane 77 5.048 5.044 (0.872) 177985 50.0000 45.02 27 cis-1,2-Dichloroethene 96 5.077 5.073 (0.877) 186378 50.0000 48.78 28 Chloroform 83 5.500 5.497 (0.951) 283193 50.0000 46.51 29 Bromochloromethane 128 5.369 5.378 (0.928) 92094 50.0000 51.74




* 47 Chlorobenzene-d5 117 9.524 9.527 (1.000) 382506 50.0000

$ 48 Toluene-d8 98 8.090 8.093 (0.849) 415869 50.0000 51.23 49 Ethyl Methacrylate 69 8.529 8.539 (1.298) 251750 50.0000 48.06 50 Toluene 91 8.157 8.164 (0.856) 672527 50.0000 43.58 51 trans-1,3-Dichloropropene 75 8.417 8.420 (1.281) 222567 50.0000 52.88 52 2-Hexanone 43 8.452 8.873 (0.887) 228035 100.000 98.60(H) 53 1,1,2-Trichloroethane 83 8.597 8.600 (0.903) 136213 50.0000 46.38 54 1,3-Dichloropropane 76 8.754 8.760 (0.919) 272556 50.0000 46.94 55 Dibromochloromethane 129 8.969 8.975 (0.942) 197163 50.0000 48.09 56 Tetrachloroethene 164 8.690 8.693 (0.912) 134074 50.0000 43.09 57 1,2-Dibromoethane 107 9.065 9.072 (0.952) 173602 50.0000 49.13 58 1-Chlorohexane 55 9.550 9.559 (1.453) 155496 50.0000 49.95 59 Chlorobenzene 112 9.550 9.556 (1.003) 434390 50.0000 45.38 60 1,1,1,2-Tetrachloroethane 131 9.643 9.652 (1.012) 172361 50.0000 45.86 61 Ethylbenzene 106 9.668 9.678 (1.015) 231645 50.0000 51.06 62 m,p-Xylenes 106 9.787 9.800 (1.028) 558367 100.000 105.27 63 o-Xylene 106 10.175 10.182 (1.068) 302795 50.0000 52.29 64 Styrene 104 10.195 10.204 (1.070) 481091 50.0000 47.11 66 Bromoform 173 10.371 10.378 (1.089) 141452 50.0000 49.44 67 Isopropylbenzene 105 10.544 10.551 (1.107) 706017 50.0000 42.96 68 1,1,2,2-Tetrachloroethane 83 10.869 10.878 (0.918) 229574 50.0000 44.70



95 of 595

00913586






M 95 Xylenes (total) 106 861162 150.000 157.56

QC Flag Legend

T - Target compound detected outside RT window.A - Target compound detected but, quantitated amount exceeded maximum amount.M - Compound response manually integrated.H - Operator selected an alternate compound hit.

96 of 595

00913587

97 of 595

00913588

VOA2_323037Run ID:

FORM 13 - ANALYSIS RUN LOG

Instrument:

Sample No. D/F Time



VOA2

Start Date: End Date:06-Sep-2018 06-Sep-2018

File IDBFB 1 06-Sep-2018 07:58 D090601.DCCV 1 06-Sep-2018 08:47 D090603.DVLCSW-180906 1 06-Sep-2018 09:36 D090605.DVBLKW-180906 1 06-Sep-2018 10:01 D090606.DHS18081540-02 1 06-Sep-2018 10:25 D090607.DHS18081540-01 1 06-Sep-2018 10:50 D090608.DZZZZZZZZZZZZ 1 06-Sep-2018 12:52 D090613.DZZZZZZZZZZZZ 1 06-Sep-2018 14:30 D090617.DZZZZZZZZZZZZ 1 06-Sep-2018 14:55 D090618.DCCV_END 1 06-Sep-2018 19:37 D090629.D


98 of 595

00913589

Data File: \\nahstws003\Target\CHEM\VOA2.i\D180906.b\D090601.D Page 1 Report Date: 20-Sep-2018 14:43


Data file : \\nahstws003\Target\CHEM\VOA2.i\D180906.b\D090601.DLab Smp Id: BFB Client Smp ID: BFBInj Date : 06-SEP-2018 09:58 Operator : AP Inst ID: VOA2.iSmp Info : BFB;BFB;3;;BFBMisc Info : HS15080001;WATER;0;1;Comment : Method : \\NAHSTWS003\Target\CHEM\VOA2.i\D180906.b\bfb.mMeth Date : 04-Jun-2018 15:21 Cesar.Lira Quant Type: ISTDCal Date : Cal File: Als bottle: 1 QC Sample: BFBDil Factor: 1.00000 Integrator: HP RTE Compound Sublist: all.subTarget Version: 4.14 Sample Matrix: WATER

Concentration Formula: Amt * DF * Uf * Vf * Vi * CpndVariable

Name Value Description-------------- ---------- ----------------------- DF 1.000 Dilution Factor Uf 5.000 ng unit correction factor Vf 1.000 Volumetric correction factor Vi 2.000 Injection VolumeCpnd Variable Local Compound Variable

CONCENTRATIONS ON-COL FINAL

RT EXP RT REL RT MASS RESPONSE ( ug/L) ( ug/l) TARGET RANGE RATIO ==== ======== ======== ==== ======== ======= ======= ============ =====

1 bfb CAS #: 460-00-410.695 10.696 ( 0.000) 95 80920 0.00- 100.00 100.00

10.695 10.696 ( 0.000) 50 14189 15.00- 40.00 17.53

10.695 10.696 ( 0.000) 75 37808 30.00- 60.00 46.72

10.695 10.696 ( 0.000) 96 6340 5.00- 9.00 7.83

10.695 10.696 ( 0.000) 173 824 0.00- 2.00 1.08

10.695 10.696 ( 0.000) 174 76552 50.00- 0.00 94.60

10.695 10.696 ( 0.000) 175 5827 5.00- 9.00 7.61

10.695 10.696 ( 0.000) 176 75896 95.00- 101.00 99.14

10.695 10.696 ( 0.000) 177 4192 5.00- 9.00 5.52

-------------------------------------------------------------------------------

99 of 595

00913590

100 of 595

00913591

101 of 595

00913592

102 of 595

00913593



Data file : \\nahstws003\Target\CHEM\VOA2.i\D180906.b\D090603.DLab Smp Id: CCV Client Smp ID: CCVInj Date : 06-SEP-2018 10:47 Operator : AP Inst ID: VOA2.iSmp Info : CCV;CCV;2;;Misc Info : HS15080001;WATER;0;1;Comment : Method : \\nahstws003\Target\chem\voa2.i\D180906.b\8260LL.mMeth Date : 06-Sep-2018 23:07 VOA2.i Quant Type: ISTDCal Date : 03-AUG-2018 02:04 Cal File: E080211.DAls bottle: 3 Continuing Calibration SampleDil Factor: 1.00000 Integrator: HP RTE Compound Sublist: 00000_8260-LLw.subTarget Version: 4.14






186 Isobutylene 56 1.665 1.672 (0.288) 142579 50.0000 38.76(AM) 3 Chloromethane 50 1.614 1.611 (0.279) 208364 50.0000 40.79(M) 4 Propionitrile 54 5.243 5.247 (0.907) 441483 500.000 471.82 5 Vinyl Chloride 62 1.698 1.698 (0.294) 150923 50.0000 44.18 6 Bromomethane 94 1.961 1.961 (0.339) 95979 50.0000 56.42 7 Chloroethane 64 2.054 2.060 (0.355) 92470 50.0000 42.37

159 Dichlorofluoromethane 67 2.246 2.249 (0.389) 233296 50.0000 46.03 8 Trichlorofluoromethane 101 2.266 2.269 (0.392) 168724 50.0000 50.55 9 Acrolein 56 2.699 2.708 (0.467) 62712 100.000 96.24 10 Acetone 43 2.869 2.872 (0.496) 75523 100.000 82.18 11 1,1-Dichloroethene 96 2.766 2.769 (0.478) 109015 50.0000 44.56 12 Isobutyl Alcohol 74 6.168 6.168 (1.067) 12779 1000.00 930.51(AM) 13 Acetonitrile 39 3.183 3.186 (0.551) 134965 500.000 441.58 14 Allyl Chloride 41 3.190 3.193 (0.552) 377092 50.0000 44.87 15 Iodomethane 142 2.923 2.927 (0.506) 209608 100.000 94.36 16 Acrylonitrile 53 3.713 3.709 (0.642) 114023 100.000 88.37 17 Methylene Chloride 84 3.347 3.347 (0.579) 133110 50.0000 48.00 18 Methyl tert-butyl ether 73 3.700 3.697 (0.640) 334803 50.0000 44.95 19 Carbon Disulfide 76 2.971 2.975 (0.514) 405244 100.000 87.79 20 trans-1,2-Dichloroethene 96 3.677 3.677 (0.636) 119055 50.0000 47.19

103 of 595

00913594








* 47 Chlorobenzene-d5 117 9.524 9.524 (1.000) 283188 50.0000

$ 48 Toluene-d8 98 8.093 8.093 (0.850) 335924 50.0000 42.91 49 Ethyl Methacrylate 69 8.529 8.532 (1.297) 184380 50.0000 48.44 50 Toluene 91 8.157 8.157 (0.856) 515454 50.0000 45.11 51 trans-1,3-Dichloropropene 75 8.417 8.420 (1.280) 176060 50.0000 57.55 52 2-Hexanone 43 8.863 8.866 (0.931) 194486 100.000 92.90 53 1,1,2-Trichloroethane 83 8.597 8.597 (0.903) 101449 50.0000 46.66 54 1,3-Dichloropropane 76 8.754 8.754 (0.919) 203232 50.0000 47.28 55 Dibromochloromethane 129 8.969 8.972 (0.942) 151968 50.0000 50.07 56 Tetrachloroethene 164 8.690 8.690 (0.912) 116184 50.0000 50.43 57 1,2-Dibromoethane 107 9.068 9.065 (0.952) 132935 50.0000 50.81 58 1-Chlorohexane 55 9.553 9.550 (1.453) 127419 50.0000 56.73 59 Chlorobenzene 112 9.553 9.553 (1.003) 341586 50.0000 48.20 60 1,1,1,2-Tetrachloroethane 131 9.646 9.646 (1.013) 136013 50.0000 48.89 61 Ethylbenzene 106 9.672 9.672 (1.015) 184830 50.0000 55.21 62 m,p-Xylenes 106 9.790 9.790 (1.028) 444930 100.000 113.83 63 o-Xylene 106 10.179 10.175 (1.069) 235813 50.0000 55.15 64 Styrene 104 10.195 10.198 (1.070) 375610 50.0000 49.68 66 Bromoform 173 10.374 10.374 (1.089) 111748 50.0000 52.75 67 Isopropylbenzene 105 10.544 10.544 (1.107) 578795 50.0000 47.57 68 1,1,2,2-Tetrachloroethane 83 10.872 10.869 (0.919) 169632 50.0000 41.33



104 of 595

00913595






M 95 Xylenes (total) 106 680743 150.000 168.99

QC Flag Legend


105 of 595

00913596

106 of 595

00913597



Data file : \\nahstws003\Target\CHEM\VOA2.i\D180906.b\D090605.DLab Smp Id: VLCSW-180906 Client Smp ID: VLCSW-180906Inj Date : 06-SEP-2018 11:36 Operator : AP Inst ID: VOA2.iSmp Info : VLCSW-180906;VLCSW-180906;3;;LCSMisc Info : HS15080001;WATER;0;1;Comment : Method : \\nahstws003\Target\chem\voa2.i\D180906.b\8260LL.mMeth Date : 06-Sep-2018 23:07 VOA2.i Quant Type: ISTDCal Date : 03-AUG-2018 02:04 Cal File: E080211.DAls bottle: 5 QC Sample: LCSDil Factor: 1.00000 Integrator: HP RTE Compound Sublist: 00000_8260-LLw.subTarget Version: 4.14



CONCENTRATIONS QUANT SIG ON-COLUMN FINAL





107 of 595

00913598







* 36 1,4-Difluorobenzene 114 6.575 6.575 (1.000) 296491 50.0000 37 Benzene 78 6.097 6.097 (0.927) 208632 20.5691 20.56 38 Trichloroethene 130 6.819 6.822 (1.037) 59174 21.8529 21.85 39 Bromodichloromethane 83 7.377 7.380 (1.122) 74298 21.7752 21.77 40 Methyl Methacrylate 41 7.246 7.249 (1.252) 59873 19.0505 19.05 41 2-Chloroethylvinyl ether 63 8.157 8.157 (1.241) 17480 42.5026 42.50 42 1,2-Dichloropropane 63 7.069 7.069 (1.075) 61374 20.8537 20.85(M) 43 2-Nitropropane 43 8.026 8.029 (1.386) 122171 18.4856 18.48 44 Dibromomethane 93 7.191 7.194 (1.094) 32205 22.1137 22.11 45 4-Methyl-2-Pentanone 43 8.026 8.029 (0.843) 122171 38.9908 38.99 46 cis-1,3-Dichloropropene 75 7.843 7.843 (1.193) 89097 23.3230 23.32

* 47 Chlorobenzene-d5 117 9.524 9.524 (1.000) 275115 50.0000

$ 48 Toluene-d8 98 8.093 8.093 (0.850) 338821 44.5507 44.55(M) 49 Ethyl Methacrylate 69 8.529 8.532 (1.297) 78546 21.3170 21.31 50 Toluene 91 8.160 8.157 (0.857) 221205 19.9308 19.93 51 trans-1,3-Dichloropropene 75 8.417 8.420 (1.280) 72934 24.6313 24.63 52 2-Hexanone 43 8.866 8.866 (0.931) 83266 40.9450 40.94 53 1,1,2-Trichloroethane 83 8.597 8.597 (0.903) 43342 20.5224 20.52 54 1,3-Dichloropropane 76 8.754 8.754 (0.919) 86088 20.6179 20.61 55 Dibromochloromethane 129 8.969 8.972 (0.942) 63233 21.4470 21.44 56 Tetrachloroethene 164 8.687 8.690 (0.912) 49112 21.9456 21.94 57 1,2-Dibromoethane 107 9.065 9.065 (0.952) 53932 21.2214 21.22 58 1-Chlorohexane 55 9.553 9.550 (1.453) 53696 22.8770 22.87 59 Chlorobenzene 112 9.553 9.553 (1.003) 145924 21.1990 21.19 60 1,1,1,2-Tetrachloroethane 131 9.643 9.646 (1.012) 58209 21.5374 21.53 61 Ethylbenzene 106 9.668 9.672 (1.015) 79890 23.2587 23.25 62 m,p-Xylenes 106 9.787 9.790 (1.028) 191969 46.6790 46.67 63 o-Xylene 106 10.175 10.175 (1.068) 100539 22.6593 22.65 64 Styrene 104 10.195 10.198 (1.070) 159832 21.7637 21.76 66 Bromoform 173 10.374 10.374 (1.089) 45928 22.3194 22.31 67 Isopropylbenzene 105 10.545 10.544 (1.107) 247892 20.9736 20.97 68 1,1,2,2-Tetrachloroethane 83 10.869 10.869 (0.918) 72252 18.5359 18.53



108 of 595

00913599




77 4-Chlorotoluene 91 11.138 11.138 (0.941) 185236 21.8648 21.86 78 tert-Butylbenzene 119 11.446 11.449 (0.967) 172030 22.1902 22.19 79 1,2,4-Trimethylbenzene 105 11.498 11.501 (0.972) 193963 21.2363 21.23 81 sec-Butylbenzene 105 11.668 11.668 (0.986) 236558 19.4154 19.41 82 p-Isopropyltoluene 119 11.815 11.815 (0.998) 197558 19.5988 19.59 83 1,3-Dichlorobenzene 146 11.764 11.767 (0.994) 115011 20.2536 20.25 84 1,4-Dichlorobenzene 146 11.857 11.857 (1.002) 109855 20.7170 20.71 87 n-Butylbenzene 91 12.220 12.220 (1.033) 149820 20.0902 20.09 88 1,2-Dichlorobenzene 146 12.223 12.223 (1.033) 111391 19.8865 19.88 89 1,2-Dibromo-3-Chloropropane 75 13.006 13.006 (1.099) 11493 18.8427 18.84 90 1,2,4-Trichlorobenzene 180 13.814 13.818 (1.167) 67090 21.4585 21.45 91 Hexachlorobutadiene 225 13.984 13.984 (1.182) 31297 21.0890 21.08 92 Naphthalene 128 14.058 14.061 (1.188) 156958 20.3749 20.37 93 1,2,3-Trichlorobenzene 182 14.299 14.299 (1.208) 57460 20.7478 20.74 146 Methyl acetate 43 3.254 3.251 (0.562) 53552 16.2687 16.26(M) 138 Freon TF 101 2.782 2.779 (0.481) 43320 21.2470 21.24 139 Diethyl ether 59 2.558 2.557 (0.442) 93142 18.7433 18.74 147 Methylcyclohexane 83 6.992 6.992 (1.063) 77286 23.1899 23.18 135 1,4-Dioxane 88 7.239 7.236 (1.251) 12038 411.482 411.48 132 n-Butanol 56 6.992 6.999 (1.208) 32630 334.560 334.55 131 Methyl Acrylate 55 5.275 5.269 (0.911) 86673 17.7169 17.71 133 Ethyl Acrylate 55 7.012 7.011 (1.211) 160067 18.0539 18.05 136 n-Hexane 57 4.075 4.079 (0.704) 60603 18.1452 18.14 141 Cyclohexane 56 5.693 5.693 (0.983) 90029 17.2892 17.28 142 Tetrahydrofuran 42 5.423 5.420 (0.937) 36880 32.5870 32.58 148 Tert-butyl alcohol 59 3.584 3.581 (0.619) 114522 361.830 361.83 149 Isopropyl alcohol 45 3.084 3.077 (0.533) 76249 379.150 379.14(M) 151 4-Methyl-2-pentanol 45 8.452 8.455 (0.887) 305372 467.778 467.77 166 1,2,3-Trimethylbenzene 105 11.912 11.915 (1.007) 188225 21.7096 21.70 167 Ethanol 45 2.561 2.561 (0.442) 90163 354.837 354.83 170 1,3,5-Trichlorobenzene 180 13.201 13.198 (1.116) 80302 22.0312 22.03 172 tert-Butyl formate 59 4.923 4.919 (0.850) 135117 37.2262 37.22 173 3,3-Dimethyl-1-butanol 57 9.097 9.091 (0.955) 111178 459.958 459.95 174 tert-Amyl methyl ether 73 6.261 6.261 (1.081) 140816 20.0420 20.04 175 tert-Butyl ethyl ether 59 6.235 6.235 (1.077) 78395 20.5742 20.57 176 tert-Amyl alcohol 59 6.235 6.235 (1.077) 78395 411.484 411.48 157 2-Methylnaphthalene 142 15.188 15.188 (1.283) 16612 11.1249 11.12 156 Diisopropyl ether 45 4.435 4.438 (0.766) 184927 16.7531 16.75 171 1-Methylnaphthalene 142 15.384 15.387 (1.300) 23568 12.4700 12.47 130 Ethyl Acetate 43 5.253 5.247 (0.907) 109359 16.1995 16.19


M 95 Xylenes (total) 106 292508 69.3383 69.33

QC Flag Legend

A - Target compound detected but, quantitated amount exceeded maximum amount.M - Compound response manually integrated.

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Data file : \\nahstws003\Target\CHEM\VOA2.i\D180906.b\D090606.DLab Smp Id: VBLKW-180906 Client Smp ID: VBLKW-180906Inj Date : 06-SEP-2018 12:01 Operator : AP Inst ID: VOA2.iSmp Info : VBLKW-180906;VBLKW-180906;3;;BLANKMisc Info : HS15080001;WATER;0;1;Comment : Method : \\nahstws003\Target\chem\voa2.i\D180906.b\8260LL.mMeth Date : 06-Sep-2018 23:07 VOA2.i Quant Type: ISTDCal Date : 03-AUG-2018 02:04 Cal File: E080211.DAls bottle: 6 QC Sample: BLANKDil Factor: 1.00000 Integrator: HP RTE Compound Sublist: 00000_8260-LLw.subTarget Version: 4.14





* 1 Pentafluorobenzene 168 5.782 5.786 (1.000) 218901 50.0000

$ 30 Dibromofluoromethane 113 5.689 5.689 (0.984) 89913 45.9435 45.94


* 36 1,4-Difluorobenzene 114 6.575 6.575 (1.000) 302079 50.0000

* 47 Chlorobenzene-d5 117 9.524 9.524 (1.000) 269797 50.0000

$ 48 Toluene-d8 98 8.090 8.093 (0.849) 339647 45.5396 45.53


* 70 1,4-Dichlorobenzene-d4 152 11.834 11.834 (1.000) 111791 50.0000

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00913710

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00913711



Data file : \\nahstws003\Target\CHEM\VOA2.i\D180906.b\D090608.DLab Smp Id: HS18081540-01 Client Smp ID: HS18081540-01Inj Date : 06-SEP-2018 12:50 Operator : AP Inst ID: VOA2.iSmp Info : HS18081540-01;HS18081540-01;;;Misc Info : HS15080001;WATER;0;1;Comment : Method : \\nahstws003\Target\chem\voa2.i\D180906.b\8260LL.mMeth Date : 06-Sep-2018 23:07 VOA2.i Quant Type: ISTDCal Date : 03-AUG-2018 02:04 Cal File: E080211.DAls bottle: 8 Dil Factor: 1.00000 Integrator: HP RTE Compound Sublist: 00000_8260-LLw.subTarget Version: 4.14





* 1 Pentafluorobenzene 168 5.782 5.786 (1.000) 230281 50.0000 5 Vinyl Chloride 62 1.697 1.698 (0.294) 5318 1.39943 1.39 27 cis-1,2-Dichloroethene 96 5.076 5.076 (0.878) 11824 3.49225 3.49

$ 30 Dibromofluoromethane 113 5.692 5.689 (0.984) 98531 47.8591 47.85


* 36 1,4-Difluorobenzene 114 6.575 6.575 (1.000) 323923 50.0000

* 47 Chlorobenzene-d5 117 9.524 9.524 (1.000) 291510 50.0000

$ 48 Toluene-d8 98 8.090 8.093 (0.849) 364065 45.1777 45.17


* 70 1,4-Dichlorobenzene-d4 152 11.831 11.834 (1.000) 120897 50.0000


QC Flag Legend

a - Target compound detected but, quantitated amount Below Limit Of Quantitation(BLOQ).

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Data file : \\nahstws003\Target\CHEM\VOA2.i\D180906.b\D090617.DLab Smp Id: HS18090060-11MS Client Smp ID: HS18090060-11MSInj Date : 06-SEP-2018 16:30 Operator : AP Inst ID: VOA2.iSmp Info : HS18090060-11MS;HS18090060-11MS;3;;MSMisc Info : HS15080001;WATER;0;1;Comment : Method : \\nahstws003\Target\chem\voa2.i\D180906.b\8260LL.mMeth Date : 06-Sep-2018 23:07 VOA2.i Quant Type: ISTDCal Date : 03-AUG-2018 02:04 Cal File: E080211.DAls bottle: 17 QC Sample: MSDil Factor: 1.00000 Integrator: HP RTE Compound Sublist: 00000_8260-LLw.subTarget Version: 4.14








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* 47 Chlorobenzene-d5 117 9.524 9.524 (1.000) 292423 50.0000




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77 4-Chlorotoluene 91 11.138 11.138 (0.941) 175264 18.9625 18.96 78 tert-Butylbenzene 119 11.449 11.449 (0.968) 166861 19.8097 19.80 79 1,2,4-Trimethylbenzene 105 11.497 11.501 (0.972) 179253 17.8859 17.88 81 sec-Butylbenzene 105 11.664 11.668 (0.986) 230720 17.7006 17.70 82 p-Isopropyltoluene 119 11.815 11.815 (0.999) 183357 17.0030 17.00 83 1,3-Dichlorobenzene 146 11.764 11.767 (0.994) 109761 18.0678 18.06 84 1,4-Dichlorobenzene 146 11.857 11.857 (1.002) 102203 18.0162 18.01 87 n-Butylbenzene 91 12.216 12.220 (1.033) 143341 17.9671 17.96 88 1,2-Dichlorobenzene 146 12.223 12.223 (1.033) 105341 17.5792 17.57 89 1,2-Dibromo-3-Chloropropane 75 13.009 13.006 (1.100) 9603 14.6368 14.63 90 1,2,4-Trichlorobenzene 180 13.814 13.818 (1.168) 60117 17.9439 17.94 91 Hexachlorobutadiene 225 13.984 13.984 (1.182) 31071 19.5705 19.57 92 Naphthalene 128 14.061 14.061 (1.188) 134383 16.0905 16.09 93 1,2,3-Trichlorobenzene 182 14.299 14.299 (1.209) 51799 17.4500 17.45 146 Methyl acetate 43 3.247 3.251 (0.561) 48537 13.5046 13.50 138 Freon TF 101 2.785 2.779 (0.481) 44682 19.9893 19.98 139 Diethyl ether 59 2.564 2.557 (0.443) 76596 14.1169 14.11 147 Methylcyclohexane 83 6.995 6.992 (1.063) 82534 22.3088 22.30 135 1,4-Dioxane 88 7.239 7.236 (1.251) 9345 292.373 292.37 132 n-Butanol 56 6.999 6.999 (1.210) 36829 346.794 346.79 131 Methyl Acrylate 55 5.272 5.269 (0.911) 84126 15.6464 15.64 133 Ethyl Acrylate 55 7.011 7.011 (1.212) 162074 16.7422 16.74 136 n-Hexane 57 4.066 4.079 (0.703) 72376 19.8469 19.84 141 Cyclohexane 56 5.696 5.693 (0.984) 98397 17.3063 17.30 142 Tetrahydrofuran 42 5.426 5.420 (0.938) 38274 30.9734 30.97 148 Tert-butyl alcohol 59 3.591 3.581 (0.621) 104120 301.402 301.40 151 4-Methyl-2-pentanol 45 8.452 8.455 (0.887) 230646 332.399 332.39 166 1,2,3-Trimethylbenzene 105 11.911 11.915 (1.007) 173468 18.2909 18.29 167 Ethanol 45 2.564 2.561 (0.443) 71125 256.362 256.36 170 1,3,5-Trichlorobenzene 180 13.198 13.198 (1.116) 70783 18.1524 18.15 172 tert-Butyl formate 59 4.922 4.919 (0.851) 125640 31.7028 31.70 173 3,3-Dimethyl-1-butanol 57 9.094 9.091 (0.955) 80392 312.907 312.90 174 tert-Amyl methyl ether 73 6.264 6.261 (1.083) 112974 14.7265 14.72 175 tert-Butyl ethyl ether 59 6.238 6.235 (1.078) 59779 14.3686 14.36 176 tert-Amyl alcohol 59 6.238 6.235 (1.078) 59779 287.372 287.37 157 2-Methylnaphthalene 142 15.191 15.188 (1.284) 8740 8.22046 8.22 156 Diisopropyl ether 45 4.435 4.438 (0.767) 193866 16.0852 16.08 171 1-Methylnaphthalene 142 15.387 15.387 (1.301) 11074 8.18625 8.18 130 Ethyl Acetate 43 5.250 5.247 (0.907) 108801 14.7608 14.76


M 95 Xylenes (total) 106 283925 62.4894 62.48

QC Flag Legend

A - Target compound detected but, quantitated amount exceeded maximum amount.M - Compound response manually integrated.

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Data file : \\nahstws003\Target\CHEM\VOA2.i\D180906.b\D090618.DLab Smp Id: HS18090060-11MSD Client Smp ID: HS18090060-11MSDInj Date : 06-SEP-2018 16:55 Operator : AP Inst ID: VOA2.iSmp Info : HS18090060-11MSD;HS18090060-11MSD;3;;MSDMisc Info : HS15080001;WATER;0;1;Comment : Method : \\nahstws003\Target\chem\voa2.i\D180906.b\8260LL.mMeth Date : 06-Sep-2018 23:07 VOA2.i Quant Type: ISTDCal Date : 03-AUG-2018 02:04 Cal File: E080211.DAls bottle: 17 QC Sample: MSDDil Factor: 1.00000 Integrator: HP RTE Compound Sublist: 00000_8260-LLw.subTarget Version: 4.14








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00913827








* 47 Chlorobenzene-d5 117 9.524 9.524 (1.000) 294188 50.0000

$ 48 Toluene-d8 98 8.093 8.093 (0.850) 335403 41.2421 41.24(R) 49 Ethyl Methacrylate 69 8.526 8.532 (1.297) 71318 19.7134 19.71 50 Toluene 91 8.154 8.157 (0.856) 198963 16.7645 16.76 51 trans-1,3-Dichloropropene 75 8.417 8.420 (1.280) 62557 21.5177 21.51 52 2-Hexanone 43 8.866 8.866 (0.931) 71599 32.9253 32.92 53 1,1,2-Trichloroethane 83 8.594 8.597 (0.902) 37699 16.6931 16.69 54 1,3-Dichloropropane 76 8.754 8.754 (0.919) 77599 17.3799 17.37 55 Dibromochloromethane 129 8.972 8.972 (0.942) 58637 18.5988 18.59 56 Tetrachloroethene 164 8.690 8.690 (0.912) 46286 19.3419 19.34 57 1,2-Dibromoethane 107 9.065 9.065 (0.952) 49779 18.3174 18.31 58 1-Chlorohexane 55 9.550 9.550 (1.452) 53313 23.1703 23.17 59 Chlorobenzene 112 9.553 9.553 (1.003) 140436 19.0791 19.07 60 1,1,1,2-Tetrachloroethane 131 9.643 9.646 (1.012) 55285 19.1293 19.12 61 Ethylbenzene 106 9.669 9.672 (1.015) 77743 20.9542 20.95 62 m,p-Xylenes 106 9.787 9.790 (1.028) 180090 40.0952 40.09 63 o-Xylene 106 10.176 10.175 (1.068) 94912 19.6816 19.68 64 Styrene 104 10.195 10.198 (1.070) 148443 18.9025 18.90 66 Bromoform 173 10.375 10.374 (1.089) 41295 18.7669 18.76 67 Isopropylbenzene 105 10.545 10.544 (1.107) 242941 19.2220 19.22 68 1,1,2,2-Tetrachloroethane 83 10.869 10.869 (0.919) 66166 16.0877 16.08



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00913828




77 4-Chlorotoluene 91 11.135 11.138 (0.941) 165015 17.9548 17.95 78 tert-Butylbenzene 119 11.446 11.449 (0.967) 166405 20.0674 20.06 79 1,2,4-Trimethylbenzene 105 11.498 11.501 (0.972) 182852 18.6145 18.61 81 sec-Butylbenzene 105 11.664 11.668 (0.986) 229264 17.8337 17.83 82 p-Isopropyltoluene 119 11.815 11.815 (0.999) 187810 17.6583 17.65 83 1,3-Dichlorobenzene 146 11.764 11.767 (0.994) 110398 18.4255 18.42 84 1,4-Dichlorobenzene 146 11.857 11.857 (1.002) 104291 18.6401 18.64 87 n-Butylbenzene 91 12.220 12.220 (1.033) 145500 18.4915 18.49 88 1,2-Dichlorobenzene 146 12.223 12.223 (1.033) 106101 17.9524 17.95 89 1,2-Dibromo-3-Chloropropane 75 13.006 13.006 (1.099) 10083 15.6058 15.60 90 1,2,4-Trichlorobenzene 180 13.818 13.818 (1.168) 61889 18.7379 18.73 91 Hexachlorobutadiene 225 13.985 13.984 (1.182) 30575 19.5261 19.52 92 Naphthalene 128 14.062 14.061 (1.188) 143269 17.4806 17.48 93 1,2,3-Trichlorobenzene 182 14.299 14.299 (1.209) 53390 18.2458 18.24 146 Methyl acetate 43 3.254 3.251 (0.562) 41423 13.0378 13.03 138 Freon TF 101 2.789 2.779 (0.482) 41602 21.1327 21.13 139 Diethyl ether 59 2.561 2.557 (0.443) 77975 16.2571 16.25 147 Methylcyclohexane 83 6.989 6.992 (1.063) 72919 22.1896 22.18 135 1,4-Dioxane 88 7.243 7.236 (1.252) 8604 304.544 304.54 132 n-Butanol 56 6.996 6.999 (1.209) 31624 336.053 336.05 131 Methyl Acrylate 55 5.269 5.269 (0.911) 74948 15.7760 15.77 133 Ethyl Acrylate 55 7.012 7.011 (1.212) 145174 16.9645 16.96 136 n-Hexane 57 4.072 4.079 (0.704) 62164 19.2837 19.28 141 Cyclohexane 56 5.693 5.693 (0.984) 84932 16.8985 16.89 142 Tetrahydrofuran 42 5.426 5.420 (0.938) 33357 30.5369 30.53 148 Tert-butyl alcohol 59 3.584 3.581 (0.620) 86034 281.776 281.77 151 4-Methyl-2-pentanol 45 8.449 8.455 (0.887) 224305 321.321 321.32 166 1,2,3-Trimethylbenzene 105 11.912 11.915 (1.007) 171398 18.3295 18.32 167 Ethanol 45 2.564 2.561 (0.443) 75041 305.974 305.97 170 1,3,5-Trichlorobenzene 180 13.198 13.198 (1.116) 75049 19.5142 19.51 172 tert-Butyl formate 59 4.923 4.919 (0.851) 106591 30.4259 30.42 173 3,3-Dimethyl-1-butanol 57 9.094 9.091 (0.955) 84214 325.817 325.81 174 tert-Amyl methyl ether 73 6.261 6.261 (1.082) 109193 16.1016 16.10 175 tert-Butyl ethyl ether 59 6.235 6.235 (1.078) 57538 15.6450 15.64 176 tert-Amyl alcohol 59 6.235 6.235 (1.078) 57538 312.899 312.89 157 2-Methylnaphthalene 142 15.191 15.188 (1.284) 10362 8.78917 8.78 156 Diisopropyl ether 45 4.435 4.438 (0.767) 158309 14.8588 14.85 171 1-Methylnaphthalene 142 15.390 15.387 (1.301) 14629 9.32497 9.32 130 Ethyl Acetate 43 5.250 5.247 (0.907) 93927 14.4153 14.41


M 95 Xylenes (total) 106 275002 59.7768 59.77

QC Flag Legend

A - Target compound detected but, quantitated amount exceeded maximum amount.R - Spike/Surrogate failed recovery limits.M - Compound response manually integrated.

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Data file : \\nahstws003\Target\CHEM\VOA2.i\D180906.b\D090629.DLab Smp Id: CCV_END Client Smp ID: CCV_ENDInj Date : 06-SEP-2018 21:37 Operator : AP Inst ID: VOA2.iSmp Info : CCV_END;CCV_END;2;;Misc Info : HS15080001;WATER;0;1;Comment : Method : \\nahstws003\Target\chem\voa2.i\D180906.b\8260LL.mMeth Date : 06-Sep-2018 23:07 VOA2.i Quant Type: ISTDCal Date : 03-AUG-2018 02:04 Cal File: E080211.DAls bottle: 27 Continuing Calibration SampleDil Factor: 1.00000 Integrator: HP RTE Compound Sublist: 00000_8260-LLw.subTarget Version: 4.14








447 of 595

00913938








* 47 Chlorobenzene-d5 117 9.524 9.524 (1.000) 249691 50.0000




448 of 595

00913939






M 95 Xylenes (total) 106 590540 150.000 166.14

QC Flag Legend


449 of 595

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Semivolatile Organics Data Package



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Wet Chemistry Data Package



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Sub Contract Data



509 of 595

00914000

Case Narrative Method: 6850 Analysis: Perchlorate Analysis SOP: LC-MS-CLO4 ALS WO ID(s): 1824768; 1824771; 1824779; 1825466


General Set Information: There four field samples in these Work Orders. The samples were analyzed for perchlorate. Method Summary: Each sample was prepared as noted below and analyzed using an Agilent 1100 LC/MSD system in select ion monitoring (SIM) mode at m/z 83 and 85, which corresponds to the loss of one oxygen atom from the perchlorate molecule. ChemStation software was used for instrument control and data analysis. The ion ratio of m/z 83 to 85 was used to positively identify the response peak as perchlorate. Quantitation was performed using the m/z 83 peak area. An internal standard (ISTD) of 18O labeled perchlorate was added to each sample to establish the perchlorate peak retention time and used in quantitation. Sample Preparation: A 10.0mL aliquot of each sample was transferred into a 15-mL centrifuge tube. 50µL of an 18O labeled perchlorate solution was added to each sample as an internal standard. The samples were then capped, vortexed, and filtered into autosampler vial using Phenex PES membrane 0.45µm Syringe filters. Holding Times: Holding times were met for all analyses. Dilutions: Sample 1824779001 was analyzed and reported from a 1:1,000 dilution. The reporting limit has been adjusted accordingly. Method QC data: The method blank (LMB 618015) was less than 1/2 the CRDL. The recovery for the LCS (618016) was within acceptable parameters.

510 of 595

00914001

MS/MSD Analysis: MS/MSD was performed on sample 1824771001 (Client ID: LH18/24-SP650_083018). 5.0µl of Working Standard Solution Horizon ID 41828 was added to 10.0mL of sample preparation. The percent recoveries and relative percent difference (RPD) were within the performance limits. Instrument QC: Instrument initial and continuing calibrations were performed in accordance with published procedures. NC/CAR(s): NA Sample Calculation: Samples were reported in µg/L. Results were calculated in µg/L by the equation (A)x(B),

where: A = Analyte concentration from the standard curve (µg/L) B = Dilution performed at time of analysis Miscellaneous Comments: These samples were analyzed in accordance with the requirements found in the DOD QSM Version 5.1. Due to limitations of the Chemstation Software, some of the chromatographic peaks require manual integration. Manual integrations were performed for datafile 12SEPPD02/03/13. The ion ratio of m/z 83 to 85 may fail at levels near the reported Detection Limit (DL). The 83/85 ion ratio failed for field sample 1824779001.

Thomas Bosch September 14, 2018 Analyst Date

511 of 595

00914002

ANALYTICAL REPORT


Phone:

E-mail:

281 530-5656

[email protected]




Project ID:



1824771001 08/30/18LH18/24-SP650_083018 09/01/18

Page 1 of 3 Fri, 09/14/18 2:01 PM ENVREP-V4.8



||

512 of 595

00914003

ANALYTICAL REPORT




Analytical Results

Sample ID: 08/30/201809/01/20181824771001Lab ID:

Collected:Received:

LH18/24-SP650_083018 NA


Media:

Water





LCMS04

Report Basis: Wet









/S/ Stephen Brose



Phone:Email:Web:


513 of 595

00914004

ANALYTICAL REPORT










Website








514 of 595

00914005

Analysis:


Workorder: 1824771




Limits:Basis:


Blank

LMB:

Analyte

Units:

Result

Analyzed:61801509/12/2018 11:40

ug/L

MDL RL



Dilution: 1ug/L


LCS:Analyzed:

61801609/12/2018 11:54

Units:

Target

Perchlorate 4.22 5.00 78.8 123.884.3


MS:Analyzed:


109/12/2018 12:29618027Sample:

Analyzed:Dilution:

Units: ug/L109/12/2018 12:151824771001


MSD:Analyzed:

61802809/12/2018 12:43

% Rec



Perchlorate ND 78.8 123.85 99.34.96 20.00.04.56 8.5591.1



CCV:Analyzed:

61801209/12/2018 10:56

Units:

Target


Result % Rec.

CCV:Analyzed:

61801709/12/2018 14:10

Units:

Target


Perchlorate 21.8 25.0 87.2 25.1 25.0 100



ICSA:Analyzed:

61801409/12/2018 11:26

Units:

Target





LODV:Analyzed:

61801309/12/2018 11:11

Units:

Target


Result % Rec.

LODV:Analyzed:

61801809/12/2018 13:55

Units:

Target


Perchlorate 0.972 1.00 97.2 0.947 1.00 94.7

Page 1 of 2 Friday, September 14, 2018


QCS V4.4515 of 595

00914006

Analysis:


Workorder: 1824771




Limits:Basis:







# -

Analyst Peer Review


09/13/2018 11:22 09/14/2018 13:46



QCS V4.4516 of 595

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September 19, 2018


This is a REVISED REPORT. Please see the Case Narrative for discussion concerning this revision.

Regards,



Dear Marcia,


Project Manager


RJ Modashia

1Revision:



Page 1 of 20

00914087






Revision: 1

Page 2 of 20

00914088



Project:

Work Order Comments


Work Order Comments

Report revised to correct the attachment for ALS Salt Lake City Perchlorate•



Batch ID: 132160




Sample Filtered•


1Revision: Page 3 of 20

00914089



WorkOrder:Lab ID:

Collection Date:

HS18081541HS18081541-01


ANALYTICAL REPORT





1mg/L 06-Sep-2018 15:00U 0.000200Silver 0.002000.00100 0.00100


1mg/L 31-Aug-2018 11:57U 0.00600Chromium, Hexavalent 0.01000.0100 0.0100SUBCONTRACT ANALYSIS - PERCHLORATE (EPA 6850)




1Revision: Note: See Qualifiers Page for a list of qualifiers and their explanation.

Page 4 of 20

00914090

WEIGHT LOG

HS18081541Longhorn GW Treatment PlantBhate Environmental Associates, Inc.




Final Volume

Prep Factor

HS18081541-01 1 10 10 (mL) 1


1Revision: Page 5 of 20

00914091


WorkOrder:Project:






31 Aug 2018 11:57HS18081541-01 30 Aug 2018 14:00 1LH18/24-SP140_083018


17 Sep 2018 09:31HS18081541-01 30 Aug 2018 14:00 1LH18/24-SP140_083018


Revision: 1Page 6 of 20

00914092

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Selenium 0.00200 U0.00200

Silver 0.00100 U0.00200




Value %RECControl

LimitRPD Ref


LCS

Client ID:

Selenium 0.04796 0.05 0 95.9 80 - 1200.00200

Silver 0.04759 0.05 0 95.2 80 - 1200.00200




Value %RECControl

LimitRPD Ref


MS

Client ID:

Selenium 0.04576 0.05 0.000541 90.4 80 - 1200.00200

Silver 0.04675 0.05 0.000039 93.4 80 - 1200.00200




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Selenium 0.04832 0.05 0.000541 95.6 80 - 120 0.04576 5.44 200.00200

Silver 0.04661 0.05 0.000039 93.1 80 - 120 0.04675 0.3 200.00200




Value %RECControl

LimitRPD Ref


PDS

Client ID:

Selenium 0.08799 0.1 0.000541 87.5 75 - 1250.00200

Silver 0.09738 0.1 0.000039 97.3 75 - 1250.00200


Note: See Qualifiers Page for a list of qualifiers and their explanation.1Revision:

Page 7 of 20

00914093

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


SD

Client ID:

Selenium 0.0100 0.000541 0 10 U0.0100

Silver 0.00500 0.000039 0 10 U0.0100




Page 8 of 20

00914094

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:





Value %RECControl

LimitRPD Ref


LCS

Client ID:

Chromium, Hexavalent 0.26 0.25 0 104 80 - 1200.0100




Value %RECControl

LimitRPD Ref


MS

Client ID:

Chromium, Hexavalent 0.267 0.25 -0.001 107 75 - 1250.0100




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Chromium, Hexavalent 0.264 0.25 -0.001 106 75 - 125 0.267 1.13 200.0100




Page 9 of 20

00914095





a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution




Page 10 of 20

00914096




Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


Page 11 of 20

00914097

NDR


HS18081541

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

2.4c/2.1c U/c IR25431778/31/18 11:10


Yes No N/A

Yes No N/A


31-Aug-201831-Aug-2018





Comments:

Corrective Action:

Yes



Page 12 of 20

00914098

of 2

0

00914099

of 2

0

00914100

ANALYTICAL REPORT


Phone:

E-mail:

281 530-5656

[email protected]




Project ID:



1824779001 08/30/18LH18/24-SP140_083018 09/01/18




||

Page 15 of 20

00914101

ANALYTICAL REPORT




Analytical Results

Sample ID: 08/30/201809/01/20181824779001Lab ID:

Collected:Received:

LH18/24-SP140_083018 NA


Media:

Water





LCMS04

Report Basis: Wet




400010004800 2000Perchlorate 1000

Comments

Workorder: 1824779

Sample 1824779001 was analyzed and reported from a 1:1,000 dilution. The reporting limit has been adjusted accordingly.

As directed by client, the sample from 1824779 (HS18081539) and 1824768 (HS18081541) were apparently flipped in the field.HS18081539 sample should be reported as HS18081541 and vice versa.





/S/ Stephen Brose



Phone:Email:Web:


Page 16 of 20

00914102

ANALYTICAL REPORT










Website








Page 17 of 20

00914103

of 20

00914104

of 20

00914105

of 20

00914106




Lakewood CO 80228

15-Oct-2018


1 of 79

00914107

September 19, 2018





Sincerely,

ALS Environmental received 1 sample(s) on Sep 07, 2018 for the analysis presented in the following report.


Dear Marcia,


Project Manager


RJ Modashia



2 of 79

00914108




HS18090255-01 06-Sep-2018 14:00 07-Sep-2018 08:50LH18-24-SP650_090618 Water


3 of 79

00914109



Project:

Work Order Comments

The analysis for Total Organic Carbon was subcontracted to ALS Kelso, WA. Final report attached.•


Batch ID: R323332



Batch ID: R323197



4 of 79

00914110


Bhate Environmental Associates, Inc.Longhorn GW Treatment PlantLH18-24-SP650_090618

WorkOrder:Lab ID:

Collection Date:

HS18090255HS18090255-01

06-Sep-2018 14:00 Matrix:Water

ANALYTICAL REPORT



AMMONIA AS N BY E350.3(ISE) Method:E350.3 Analyst: MZD1mg/L 11-Sep-2018 11:300.20Nitrogen, Ammonia (As N) 0.2015 0.20



10mg/L 07-Sep-2018 16:300.100Phosphorus, Total Orthophosphate (As P)

0.2502.40 0.250

SUBCONTRACT ANALYSIS - TOC ANALYSIS





5 of 79

00914111


WorkOrder:Project:




11 Sep 2018 11:30HS18090255-01 06 Sep 2018 14:00 1LH18-24-SP650_090618


07 Sep 2018 16:30HS18090255-01 06 Sep 2018 14:00 10LH18-24-SP650_090618

Batch ID R323666 Test Name : SUBCONTRACT ANALYSIS - TOC ANALYSIS Matrix: Water

19 Sep 2018 08:25HS18090255-01 06 Sep 2018 14:00 1LH18-24-SP650_090618


6 of 79

00914112

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:





Value %RECControl

LimitRPD Ref


LCS

Client ID:





Value %RECControl

LimitRPD Ref


MS

Client ID:





Value %RECControl

LimitRPD Ref


MSD

Client ID:





7 of 79

00914113

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:


0.0250 U0.0250




Value %RECControl

LimitRPD Ref


LCS

Client ID:


0.249 0.25 0 99.6 85 - 1150.0250




Value %RECControl

LimitRPD Ref


MS

Client ID: LH18-24-SP650_090618


4.74 2.5 2.4 93.6 80 - 1200.250




Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18-24-SP650_090618


4.81 2.5 2.4 96.4 80 - 120 4.74 1.47 200.250




8 of 79

00914114





a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution




9 of 79

00914115




Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


10 of 79

00914116

JRM

07-Sep-2018 08:50Date/Time Received:

HS18090255

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

3.3c/2.9c U/C IR11433489/7/18 10:20


Yes No N/A

Yes No N/A


10-Sep-20187-Sep-2018





Comments:

Corrective Action:

Yes



11 of 79

00914117

12 o

f 79

00914118

13 o

f 79

00914119

Wet Chemistry Raw Data


ALS WO# HS18090255

14 of 79

00914120

15 of 79

00914121

16 of 79

00914122

17 of 79

00914123

Sub Contract Data


ALS WO# HS18090255

18 of 79

00914124

September 18, 2018 Analytical Report for Service Request No: K1808659

RJ ModashiaALS Laboratory Group10450 Stancliff RoadSuite 210Houston, TX 77099-4338

Analyses were performed according to our laboratory’s NELAP-approved quality assurance program. The test results meet requirements of the current NELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP-accredited analytes, refer to the certifications section at www.alsglobal.com. All results are intended to be considered in their entirety, and ALS Group USA Corp. dba ALS Environmental (ALS) is not responsible for use of less than the complete report. Results apply only to the items submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the report.

For your reference, these analyses have been assigned our service request numberEnclosed are the results of the sample(s) submitted to our laboratory September 11, 2018

RE: ALS-Houston Environmental / HS18090255

Dear RJ,

K1808659.

Please contact me if you have any questions. My extension is 3350. You may also contact me via email at [email protected].

Respectfully submitted,


Kelley LovejoyProject Manager

ALS Group USA, Corp1317 South 13th AvenueKelso, WA 98626

+1 360 577 7222+1 360 636 1068

T :F :

ALS Environmental

www.alsglobal.com

RIGHT SOLUTIONS | RIGHT PARTNER19 of 79

00914125

kelley.lovejoy

Kelley Lovejoy

www.alsglobal.com

ALS Environmental

F :T :

+1 360 636 1068+1 360 577 7222

Kelso, WA 986261317 South 13th AvenueALS Group USA, Corp

Table of Contents

RIGHT SOLUTIONS | RIGHT PARTNER

Acronyms

Qualifiers

State Certifications, Accreditations, And Licenses

Case Narrative

Chain of Custody

General Chemistry

Raw Data

General Chemistry

20 of 79

00914126

ASTM American Society for Testing and Materials

A2LA American Association for Laboratory Accreditation

CARB California Air Resources Board

CAS Number Chemical Abstract Service registry Number

CFC Chlorofluorocarbon

CFU Colony-Forming Unit

DEC Department of Environmental Conservation

DEQ Department of Environmental Quality

DHS Department of Health Services

DOE Department of Ecology

DOH Department of Health

EPA U. S. Environmental Protection Agency

ELAP Environmental Laboratory Accreditation Program

GC Gas Chromatography

GC/MS Gas Chromatography/Mass Spectrometry

LOD Limit of Detection

LOQ Limit of Quantitation

LUFT Leaking Underground Fuel Tank

M ModifiedMCL Maximum Contaminant Level is the highest permissible concentration of a substance

allowed in drinking water as established by the USEPA.


MPN Most Probable Number

MRL Method Reporting Limit

NA Not Applicable

NC Not Calculated

NCASI National Council of the Paper Industry for Air and Stream Improvement

ND Not Detected

NIOSH National Institute for Occupational Safety and Health

PQL Practical Quantitation Limit

RCRA Resource Conservation and Recovery Act

SIM Selected Ion Monitoring

TPH Total Petroleum Hydrocarbonstr Trace level is the concentration of an analyte that is less than the PQL but greater than or

equal to the MDL.

Acronyms

21 of 79

00914127

Inorganic Data Qualifiers* The result is an outlier. See case narrative.



E The result is an estimate amount because the value exceeded the instrument calibration range.






H The holding time for this test is immediately following sample collection. The samples were analyzed as soon as possible afterreceipt by the laboratory.

Metals Data Qualifiers# The control limit criteria is not applicable. See case narrative.


E The percent difference for the serial dilution was greater than 10%, indicating a possible matrix interference in the sample.

M The duplicate injection precision was not met.

N The Matrix Spike sample recovery is not within control limits. See case narrative.

S The reported value was determined by the Method of Standard Additions (MSA).


W The post-digestion spike for furnace AA analysis is out of control limits, while sample absorbance is less than 50% of spike absorbance.



+ The correlation coefficient for the MSA is less than 0.995.


Organic Data Qualifiers* The result is an outlier. See case narrative.


A A tentatively identified compound, a suspected aldol-condensation product.


C The analyte was qualitatively confirmed using GC/MS techniques, pattern recognition, or by comparing to historical data.

D The reported result is from a dilution.

E The result is an estimated value.


N The result is presumptive. The analyte was tentatively identified, but a confirmation analysis was not performed.

P The GC or HPLC confirmation criteria was exceeded. The relative percent difference is greater than 40% between the two analytical results.


i The MRL/MDL or LOQ/LOD is elevated due to a chromatographic interference.



Additional Petroleum Hydrocarbon Specific QualifiersF The chromatographic fingerprint of the sample matches the elution pattern of the calibration standard.

L The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates the presence of a greater amount of lighter molecular weight constituents than the calibration standard.

H The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates the presence of a greater amount of heavier molecular weight constituents than the calibration standard.

O The chromatographic fingerprint of the sample resembles an oil, but does not match the calibration standard.Y The chromatographic fingerprint of the sample resembles a petroleum product eluting in approximately the correct carbon range,

but the elution pattern does not match the calibration standard.

Z The chromatographic fingerprint does not resemble a petroleum product.

22 of 79

00914128

Agency Web Site Number

Alaska DEH http://dec.alaska.gov/eh/lab/cs/csapproval.htm UST-040

Arizona DHS http://www.azdhs.gov/lab/license/env.htm AZ0339

Arkansas - DEQ http://www.adeq.state.ar.us/techsvs/labcert.htm 88-0637

California DHS (ELAP) http://www.cdph.ca.gov/certlic/labs/Pages/ELAP.aspx 2795

DOD ELAP http://www.denix.osd.mil/edqw/Accreditation/AccreditedLabs.cfm L16-58-R4

Florida DOH http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm E87412

Hawaii DOH http://health.hawaii.gov/ - ISO 17025 http://www.pjlabs.com/ L16-57

Louisiana DEQ http://www.deq.louisiana.gov/page/la-lab-accreditation 03016

Maine DHS http://www.maine.gov/dhhs/ WA01276

Minnesota DOH http://www.health.state.mn.us/accreditation 053-999-457

Nevada DEP http://ndep.nv.gov/bsdw/labservice.htm WA01276

New Jersey DEP http://www.nj.gov/dep/enforcement/oqa.html WA005

New York - DOH https://www.wadsworth.org/regulatory/elap 12060

North Carolina DEQ

https://deq.nc.gov/about/divisions/water-resources/water-resources-data/water-sciences-home-page/laboratory-certification-branch/non-field-lab-certification 605

Oklahoma DEQ http://www.deq.state.ok.us/CSDnew/labcert.htm 9801

Oregon – DEQ (NELAP)http://public.health.oregon.gov/LaboratoryServices/EnvironmentalLaboratoryAccreditation/Pages/index.aspx WA100010

South Carolina DHEC http://www.scdhec.gov/environment/EnvironmentalLabCertification/ 61002

Texas CEQ http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html T104704427

Washington DOE http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html C544

Wyoming (EPA Region 8) https://www.epa.gov/region8-waterops/epa-region-8-certified-drinking-water- -

Kelso Laboratory Website www.alsglobal.com NA

ALS Group USA Corp. dba ALS Environmental (ALS) - KelsoState Certifications, Accreditations, and Licenses

Analyses were performed according to our laboratory’s NELAP-approved quality assurance program. A complete listing of specific NELAP-certified analytes, can be found in the certification section at www.ALSGlobal.com or at the accreditation bodies web site.Please refer to the certification and/or accreditation body's web site if samples are submitted for compliance purposes. The states highlighted above, require the analysis be listed on the state certification if used for compliance purposes and if the method/anlayte is offered by that state.

23 of 79

00914129

Case Narrative



00914130

CASE NARRATIVE


Service Request:Date Received:

ALS Environmental - USALS-Houston EnvironmentalWater

K180865909/11/2018

All analyses were performed consistent with the quality assurance program of ALS Environmental. This report contains analytical results for samples designated for Tier IV validation deliverables including summary forms and all of the associated raw data for each of the analyses. When appropriate to the method, method blank results have been reported with each analytical test.

Sample Receipt:One water sample was received for analysis at ALS Environmental on 09/11/2018. The sample was received in good condition and consistent with the accompanying chain of custody form. The sample was stored in a refrigerator at 4ºC upon receipt at the laboratory.General Chemistry:No significant anomalies were noted with this analysis.

1317 South 13th Ave, Kelso, WA 98626 | 1-360-577-7222 | www.alsglobal.com

Approved by Date 09/18/201825 of 79

00914131

kelley.lovejoy

Kelley Lovejoy

Chain of Custody



00914132

A fl I So S9


Houston, TX 77099

T: + 1 281 530 5656

F: +1 281 530 5887

www.alsglobal.com

Subcontract Chain of Custody

SUBCONTRACT TO:

ALS Environmental Kelso

1317 S. 13th Avenue

Kelso, WA 98626

CUSTOMER INFORMATION:

Company:

Contact:

Address:

Phone:

Email:

Alternate Contact: Email:

ALS Houston

RJ Modashia


+ 1 281 530 S656

RJ. Modashia@a lsg lobal. com

Jumoke M. Lawal

[email protected]

LAB SAMPLE ID CUENT SAMPLE ID ANALYSIS REQUESTED

1. HS18090255-01

DOD Level IV

LH18-24-SP650_090618

Comments: Please analyze for the analysis listed above. Send report to the emails shown above.

DOD IV

QC Level: DOD IV (DoD Data Package)

Relinquished By: 4~~ Received By: .=/_/

~

Cooler ID(s):

COC ID: 9781

Phone: +1 360 501 3312

INVOICE INFORMATION:

Company: ALS Houston

Contact: Accounts Payable

Address: 10450 Stancliff Rd, Ste 210

Phone: +1 281 530 5656

Reference: HS18090255

TSR: Danielle Winnings

MATRIX

Water

Date/Time:

Date/Time:

Temperature(s):

COLLECT DATE DUE DATE

06 Sep 2018 14:00

17 Sep 2018

c.ibl ('j_ _d;,;5_0

<?/,1 lt,f 1 0910 '

27 of 79

00914133

Pc CL Cooler Receipt and Preservation Form

~ Client 111..-;--> / /1tJUS~ sq_ce Request KI so ~Z 5 lcf Received: g If( } I r Opene;:j/I fr& ByQ -~unloaded: u • .

. ~--I.

2.

3.

Samples were received via? USPS (·Fed"£~

Samples were received in: (circle) c~) Were custody seals on coolers? NA (t

UPS

Box

DHL POX Courier Hand Delivered

Envelope Otlter h ---±:- NA

If present, were custody seals intact? G_,. N

N

If yes, how many and where? CJ f 1~11_-=--lfpresent, were they signed and dated? 6.) N

.

•

Raw Corrected. ·- Corrected Corr. Thermometer Cooler/CCC ID Cooler Temp CoolerT ....... Te"'"' Blank Te ...... Blank Factor ID NA /l, '} !},/) i. (,1 I . f,; (/) ::>70 C::::tn 1 ti J.P 6

' , , <

:-:,1~ z. I > 1-' .2()

''f-5'?:~

4. Packing material: Inserts C!f!:./fii:,~Cfm.~/J> Gel Packs~-;,Dry Ice Sleeves

5. Were custody papers properly filled out (ink, signed, etc.)?

6, Were samples received in good condition (temperature, unbroken)? Indicate in the table below.

Tracking Number

? '5 3 :,/. '-/ 0 ,'}-/

-

NA

NA If applicable, tissue samples were received:

7. Were all sample labels complete (i.e analysis, preservation, etc.)? Frozen Partially Thawed Tltawed

NA

8. Did all sample labels and tags agree with custody papers? Indicate maior discrepancies in the tah!e on page 2. NA

9. Were appropriate bottles/containers and volumes received for the tests indicated? NA

I 0. Were the pH-preserved bottles (see SMO GEN SOP) received at the appropriate pH? Indicate in the table below § 11. Were VOA vials received without headspace? Indicate in the table below. ~

12. Was Cl2/Res negative? @' -

'

' Samnle ID on Bottle Samnle ID on COC Identified bv:

;

Bottle Count Out of Head- Volume Reagent Lot

~ 'C /'

~ y' e:,; y

y

y

SamolelD Bottle Tvpe Temo soace Broke pH Reaaent added Number Initials

'

.

'

NA Filed

N

N

N

N

N

N

N

N

Time

Notes, Discrepancies, & Resolutions: _____________________________________ _

7125116 28 of 79

00914134

General Chemistry



00914135

Client:

09/11/18

K1808659

Date Received:Date Collected:

Service Request:


Sample Matrix:Project: 09/6/18


Basis:Units: mg/L

NASM 5310 CNonePrep Method:

Analysis Method:

Lab CodeSample Name LODDate

AnalyzedDil.LOQResult Q

LH18-24-SP650_090618 09/13/18 03:4510.200.5020.4K1808659-001Method Blank 09/12/18 16:1410.200.50 UNDK1808659-MB1Method Blank 09/13/18 01:0510.200.50 UNDK1808659-MB2

Analytical Report



00914136


QA/QC Report

Client:ProjectSample Matrix:



SM 5310 CNone

Service Request:Date Collected:Date Received:

Basis:Units:

K180865909/06/1809/11/18

mg/LNA

Replicate Sample SummaryCarbon, Total Organic

Sample Name: Lab Code:Date

AnalyzedRPDLimitLOQMRL RPD

DuplicateResult Average

SampleResult

5 0.50 20.4 19.4 19.9 100.20LH18-24-SP650_090618 K1808659-001DUP 09/13/18





00914137

QA/QC Report

mg/LK1808659-001 Basis:Lab Code:

Units:Sample Name: LH18-24-SP650_090618

Carbon, Total OrganicMatrix Spike Summary

NA



Service Request:

Date Analyzed:Date Received:

K1808659

09/13/1809/11/18

Date Collected: 09/06/18

NoneSM 5310 C


Analyte Name ResultSample Result Spike Amount % Rec

Matrix SpikeK1808659-001MS

% Rec Limits


NADate Extracted:

Carbon, Total Organic 20.4 42.1 25.0 87 83-117





00914138

Sample Name

K1808659Date Analyzed:Service Request:


Sample Matrix:Project:Client:

Lab Control Sample SummaryCarbon, Total Organic

Analysis Method:Prep Method:

SM 5310 CNone NA

mg/LBasis:Units:

Analysis Lot: 606439

09/12/18

Spike AmountResult % Rec

% Rec Limits

NADate Extracted:

Lab Code

dba ALS EnvironmentalALS Group USA, Corp.

QA/QC Report

Lab Control Sample 83-11797 21.921.3K1808659-LCS1Lab Control Sample 83-11797 21.921.2K1808659-LCS2

18-0000480735 rev 00Superset Reference:Printed 9/18/2018 2:52:20 PM

33 of 79

00914139

ALS Group USA, Corp.


QA/QC Report

Continuing Calibration Verification (CCV) Summary

Analysis Lot Lab Code

Date Analyzed

True Value

Measured Value

Percent Recovery Acceptance Limits

Project:ALS Environmental - USALS-Houston Environmental/HS18090255

Client: Service Request: K1808659

Analysis Method: SM 5310 C mg/LUnits:

dba ALS Environmental

90-1109824.6606439 25.009/12/18 15:41KQ1812842-60CCV190-1109924.8606439 25.009/12/18 19:28KQ1812842-61CCV290-1109724.2606439 25.009/13/18 00:32KQ1812842-62CCV390-1109724.2606439 25.009/13/18 05:05KQ1812842-63CCV490-1109724.4606439 25.009/13/18 13:00KQ1812842-64CCV590-1109924.6606439 25.009/13/18 21:42KQ1812842-65CCV6

18-0000480735 rev 00Printed 9/18/2018 2:52:20 PM Superset Reference:

34 of 79

00914140

ALS Group USA, Corp.

SM 5310 C


Client:Project:

ALS Environmental - US Service Request:K1808659

QA/QC Report

mg/L

ALS-Houston Environmental/HS18090255

Analysis Method:

Continuing Calibration Blank (CCB) Summary

Units:

Analysis Lot Lab Code

Date Analyzed LOQ LOD QResult

dba ALS Environmental

CCB1 KQ1812842-66 09/12/18 15:58 0.50606439 0.20 UNDCCB2 KQ1812842-67 09/12/18 19:44 0.50606439 0.20 UNDCCB3 KQ1812842-68 09/13/18 00:48 0.50606439 0.20 UNDCCB4 KQ1812842-69 09/13/18 05:21 0.50606439 0.20 UNDCCB5 KQ1812842-70 09/13/18 13:17 0.50606439 0.20 UNDCCB6 KQ1812842-71 09/13/18 21:59 0.50606439 0.20 UND

18-0000480735 rev 00Printed 9/18/2018 2:52:20 PM Superset Reference:

35 of 79

00914141

Raw Data



00914142

General Chemistry



00914143

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00914144

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00914145

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00914146

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00914160

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00914184

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00914185

September 14, 2018





Sincerely,



Dear Marcia,


Project Manager


RJ Modashia



1 of 23

00914186




HS18090257-01 06-Sep-2018 14:00 07-Sep-2018 08:50LH18/24-SP650_090618 Water

HS18090257-02 06-Sep-2018 00:00ALS-060618-57

07-Sep-2018 08:50Trip Blank Water


2 of 23

00914187



Project:HS18090257


Batch ID: R323350




MS and MSD are for an unrelated sample (Sulfate)•


3 of 23

00914188



WorkOrder:Lab ID:

Collection Date:

HS18090257HS18090257-01


ANALYTICAL REPORT




Method:SW8260 Analyst: PC




























1ug/L 13-Sep-2018 12:580.40Acetone 2.03.2 2.01ug/L 13-Sep-2018 12:58U 0.20Benzene 1.00.50 0.50













4 of 23

00914189



WorkOrder:Lab ID:

Collection Date:

HS18090257HS18090257-01


ANALYTICAL REPORT


















1ug/L 13-Sep-2018 12:58U 0.30o-Xylene 1.00.50 0.50


1ug/L 13-Sep-2018 12:58U 0.30Styrene 1.00.50 0.50



1ug/L 13-Sep-2018 12:58U 0.20Toluene 1.00.50 0.50



1ug/L 13-Sep-2018 12:58J 0.20Trichloroethene 1.00.77 0.501ug/L 13-Sep-2018 12:58U 0.30Trichlorofluoromethane 1.00.50 0.50


Surr: 1,2-Dichloroethane-d4 1%REC 13-Sep-2018 12:5899.2 81-1180Surr: 4-Bromofluorobenzene 1%REC 13-Sep-2018 12:5897.9 85-1140Surr: Dibromofluoromethane 1%REC 13-Sep-2018 12:5894.5 80-1190Surr: Toluene-d8 1%REC 13-Sep-2018 12:58106 89-1120

ANIONS BY SW9056A Method:SW9056 Analyst: KMU10mg/L 13-Sep-2018 11:022.00Chloride 5.00568 5.0010mg/L 13-Sep-2018 11:022.00Sulfate 5.0015.6 5.00



5 of 23

00914190



WorkOrder:Lab ID:

Collection Date:

HS18090257HS18090257-02


ANALYTICAL REPORT
































1ug/L 13-Sep-2018 12:330.40Acetone 2.022 2.01ug/L 13-Sep-2018 12:33U 0.20Benzene 1.00.50 0.50













6 of 23

00914191



WorkOrder:Lab ID:

Collection Date:

HS18090257HS18090257-02


ANALYTICAL REPORT



















1ug/L 13-Sep-2018 12:33U 0.30o-Xylene 1.00.50 0.50


1ug/L 13-Sep-2018 12:33U 0.30Styrene 1.00.50 0.50



1ug/L 13-Sep-2018 12:33U 0.20Toluene 1.00.50 0.50






Surr: 1,2-Dichloroethane-d4 1%REC 13-Sep-2018 12:3398.3 81-1180Surr: 4-Bromofluorobenzene 1%REC 13-Sep-2018 12:3398.1 85-1140Surr: Dibromofluoromethane 1%REC 13-Sep-2018 12:3390.8 80-1190Surr: Toluene-d8 1%REC 13-Sep-2018 12:33107 89-1120



7 of 23

00914192


WorkOrder:Project:



Batch ID R323304 Test Name : ANIONS BY SW9056A Matrix: Water

13 Sep 2018 11:02HS18090257-01 06 Sep 2018 14:00 10LH18/24-SP650_090618


13 Sep 2018 12:58HS18090257-01 06 Sep 2018 14:00 1LH18/24-SP650_090618

13 Sep 2018 12:33HS18090257-02 06 Sep 2018 00:00 1Trip Blank


8 of 23

00914193

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:






















2-Butanone 1.0 U2.0


2-Hexanone 1.0 U2.0




Acetone 2.0 U2.0

Benzene 0.50 U1.0




Bromoform 0.50 U1.0




9 of 23

00914194

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:















m,p-Xylene 1.0 U2.0





o-Xylene 0.50 U1.0


Styrene 0.50 U1.0



Toluene 0.50 U1.0









53.62 50 0 107 89 - 1121.0Surr: Toluene-d8



10 of 23

00914195

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:





1,1-Dichloroethane 20.58 20 0 103 77 - 1251.0

1,1-Dichloroethene 19.34 20 0 96.7 71 - 1311.0







1,2-Dibromoethane 20.66 20 0 103 77 - 1211.0


1,2-Dichloroethane 21.65 20 0 108 73 - 1281.0







2-Butanone 43.62 40 0 109 56 - 1432.0

2-Chlorotoluene 20 20 0 100.0 79 - 1221.0

2-Hexanone 41.29 40 0 103 57 - 1392.0

4-Chlorotoluene 20.34 20 0 102 78 - 1221.0



Acetone 49.4 40 0 123 39 - 1602.0

Benzene 21.54 20 0 108 79 - 1201.0

Bromobenzene 19.18 20 0 95.9 80 - 1201.0



Bromoform 18.52 20 0 92.6 66 - 1301.0

Bromomethane 22.07 20 0 110 53 - 1411.0



11 of 23

00914196

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:

Carbon disulfide 42.69 40 0 107 64 - 1332.0

Carbon tetrachloride 19.25 20 0 96.3 72 - 1361.0

Chlorobenzene 20.5 20 0 103 82 - 1181.0

Chloroethane 20.48 20 0 102 60 - 1381.0

Chloroform 20.25 20 0 101 79 - 1241.0

Chloromethane 21.03 20 0 105 50 - 1391.0




Dibromomethane 20.51 20 0 103 79 - 1231.0


Ethylbenzene 20.05 20 0 100 79 - 1211.0



m,p-Xylene 40.11 40 0 100 80 - 1212.0


Naphthalene 20.36 20 0 102 61 - 1281.0

n-Butylbenzene 20.25 20 0 101 75 - 1281.0

n-Propylbenzene 19.92 20 0 99.6 76 - 1261.0

o-Xylene 20.08 20 0 100 78 - 1221.0


Styrene 20.92 20 0 105 78 - 1231.0



Toluene 21 20 0 105 80 - 1211.0





Vinyl chloride 20.62 20 0 103 58 - 1371.0




52.2 50 0 104 89 - 1121.0Surr: Toluene-d8



12 of 23

00914197

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS

Client ID:





1,1-Dichloroethane 21.9 20 0 110 77 - 1251.0

1,1-Dichloroethene 22.83 20 0 114 71 - 1311.0



1,2,3-Trichloropropane 20.96 20 0 105 73 - 1221.0




1,2-Dibromoethane 21.4 20 0 107 77 - 1211.0


1,2-Dichloroethane 22.37 20 0 112 73 - 1281.0







2-Butanone 49.12 40 0 123 56 - 1432.0

2-Chlorotoluene 21.8 20 0 109 79 - 1221.0

2-Hexanone 50.52 40 0 126 57 - 1392.0

4-Chlorotoluene 22 20 0 110 78 - 1221.0

4-Isopropyltoluene 21.74 20 0 109 77 - 1271.0


Acetone 62.07 40 0 155 39 - 1602.0

Benzene 23 20 0 115 79 - 1201.0

Bromobenzene 20.37 20 0 102 80 - 1201.0



Bromoform 18.77 20 0 93.9 66 - 1301.0

Bromomethane 17.46 20 0 87.3 53 - 1411.0



13 of 23

00914198

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS

Client ID:



Chlorobenzene 21.24 20 0 106 82 - 1181.0

Chloroethane 22.96 20 0 115 60 - 1381.0

Chloroform 20.98 20 0 105 79 - 1241.0

Chloromethane 19.09 20 0 95.4 50 - 1391.0

cis-1,2-Dichloroethene 21.05 20 0 105 78 - 1231.0



Dibromomethane 21.5 20 0 108 79 - 1231.0


Ethylbenzene 22.09 20 0 110 79 - 1211.0



m,p-Xylene 43.83 40 0 110 80 - 1212.0


Naphthalene 23.23 20 0 116 61 - 1281.0

n-Butylbenzene 22.09 20 0 110 75 - 1281.0

n-Propylbenzene 22.35 20 0 112 76 - 1261.0

o-Xylene 21.32 20 0 107 78 - 1221.0

sec-Butylbenzene 21.79 20 0 109 77 - 1261.0

Styrene 21.62 20 0 108 78 - 1231.0



Toluene 22.21 20 0 111 80 - 1211.0





Vinyl chloride 21.8 20 0 109 58 - 1371.0




52.39 50 0 105 89 - 1121.0Surr: Toluene-d8



14 of 23

00914199

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD

Client ID:



1,1,2,2-Tetrachloroethane 20.89 20 0 104 71 - 121 21.29 1.94 201.0

1,1,2-Trichloroethane 20.66 20 0 103 80 - 119 21.27 2.89 201.0

1,1-Dichloroethane 20.72 20 0 104 77 - 125 21.9 5.57 201.0

1,1-Dichloroethene 21.49 20 0 107 71 - 131 22.83 6.04 201.0



1,2,3-Trichloropropane 20.62 20 0 103 73 - 122 20.96 1.6 201.0




1,2-Dibromoethane 20.82 20 0 104 77 - 121 21.4 2.73 201.0

1,2-Dichlorobenzene 21.39 20 0 107 80 - 119 22.26 3.97 201.0

1,2-Dichloroethane 21.87 20 0 109 73 - 128 22.37 2.24 201.0







2-Butanone 48.2 40 0 120 56 - 143 49.12 1.9 202.0

2-Chlorotoluene 21.14 20 0 106 79 - 122 21.8 3.09 201.0

2-Hexanone 49.66 40 0 124 57 - 139 50.52 1.72 202.0

4-Chlorotoluene 21.18 20 0 106 78 - 122 22 3.81 201.0

4-Isopropyltoluene 20.38 20 0 102 77 - 127 21.74 6.43 201.0

4-Methyl-2-pentanone 47.57 40 0 119 67 - 130 48.92 2.81 202.0

Acetone 59.58 40 0 149 39 - 160 62.07 4.1 202.0

Benzene 22.19 20 0 111 79 - 120 23 3.59 201.0

Bromobenzene 19.61 20 0 98.1 80 - 120 20.37 3.82 201.0

Bromochloromethane 20.84 20 0 104 78 - 123 21.44 2.84 201.0

Bromodichloromethane 20.66 20 0 103 79 - 125 21.11 2.16 201.0

Bromoform 18.55 20 0 92.8 66 - 130 18.77 1.17 201.0

Bromomethane 18.31 20 0 91.6 53 - 141 17.46 4.75 201.0



15 of 23

00914200

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD

Client ID:

Carbon disulfide 41.9 40 0 105 64 - 133 43.49 3.74 202.0


Chlorobenzene 20.39 20 0 102 82 - 118 21.24 4.06 201.0

Chloroethane 22.62 20 0 113 60 - 138 22.96 1.46 201.0

Chloroform 20.2 20 0 101 79 - 124 20.98 3.81 201.0

Chloromethane 18.54 20 0 92.7 50 - 139 19.09 2.93 201.0

cis-1,2-Dichloroethene 20.13 20 0 101 78 - 123 21.05 4.48 201.0


Dibromochloromethane 20.14 20 0 101 74 - 126 20.51 1.83 201.0

Dibromomethane 20.91 20 0 105 79 - 123 21.5 2.79 201.0


Ethylbenzene 21.2 20 0 106 79 - 121 22.09 4.12 201.0


Isopropylbenzene 20.92 20 0 105 72 - 131 22.28 6.29 201.0

m,p-Xylene 41.71 40 0 104 80 - 121 43.83 4.96 202.0

Methylene chloride 21.26 20 0 106 74 - 124 22.55 5.89 202.0

Naphthalene 22.44 20 0 112 61 - 128 23.23 3.44 201.0

n-Butylbenzene 20.38 20 0 102 75 - 128 22.09 8.06 201.0

n-Propylbenzene 21.3 20 0 106 76 - 126 22.35 4.83 201.0

o-Xylene 20.56 20 0 103 78 - 122 21.32 3.58 201.0

sec-Butylbenzene 20.46 20 0 102 77 - 126 21.79 6.31 201.0

Styrene 20.75 20 0 104 78 - 123 21.62 4.08 201.0


Tetrachloroethene 20.71 20 0 104 74 - 129 21.99 5.98 201.0

Toluene 21.25 20 0 106 80 - 121 22.21 4.41 201.0

trans-1,2-Dichloroethene 20.73 20 0 104 75 - 124 22.1 6.4 201.0


Trichloroethene 20.23 20 0 101 79 - 123 21.49 6.04 201.0

Trichlorofluoromethane 20.86 20 0 104 65 - 141 22.58 7.94 201.0

Vinyl chloride 20.4 20 0 102 58 - 137 21.8 6.62 201.0




52.05 50 0 104 89 - 112 52.39 0.644 201.0Surr: Toluene-d8



16 of 23

00914201

Client:Project:



QC BATCH REPORT





17 of 23

00914202

Client:Project:



QC BATCH REPORT

Batch ID: R323304 Instrument: ICS2100 Method: SW9056

Sample ID: WBLKW1-091218 Units: mg/L Analysis Date: 12-Sep-2018 13:36



Value %RECControl

LimitRPD Ref


MBLK

Client ID:



Sample ID: WLCSW1-091218 Units: mg/L Analysis Date: 12-Sep-2018 13:51



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Chloride 21.08 20 0 105 80 - 1200.500

Sulfate 20.52 20 0 103 80 - 1200.500

Sample ID: WLCSDW1-091218 Units: mg/L Analysis Date: 12-Sep-2018 14:12



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Chloride 21.31 20 0 107 80 - 120 21.08 1.09 200.500

Sulfate 20.55 20 0 103 80 - 120 20.52 0.146 200.500




Value %RECControl

LimitRPD Ref


MS

Client ID:

Chloride 1791 50 1751 80.0 80 - 120 EO 2.50

Sulfate 4049 50 4047 3.75 80 - 120 SEO 2.50




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Chloride 1792 50 1751 82.8 80 - 120 1791 0.0781 20 EO 2.50

Sulfate 4051 50 4047 7.86 80 - 120 4049 0.0508 20 SEO 2.50




18 of 23

00914203





a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution





19 of 23

00914204




Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


20 of 23

00914205

JRM


HS18090257

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

3.3c/2.9c U/C IR11433489/7/18 11:35


Yes No N/A

Yes No N/A


7-Sep-20187-Sep-2018





Comments:

Corrective Action:

Yes



21 of 23

00914206

22 o

f 23

00914207

23 o

f 23

00914208




Lakewood CO 80228

17-Sep-2018


1 of 97

00914209

September 17, 2018





Sincerely,



Dear Marcia,


Project Manager


RJ Modashia



2 of 97

00914210






3 of 97

00914211



Project:

Work Order Comments



4 of 97

00914212



WorkOrder:Lab ID:

Collection Date:

HS18090275HS18090275-01


ANALYTICAL REPORT








5 of 97

00914213


WorkOrder:Project:




17 Sep 2018 09:31HS18090275-01 06 Sep 2018 14:00 1LH18/24-SP650_090618


6 of 97

00914214





a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution




7 of 97

00914215




Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


8 of 97

00914216

JRM


HS18090275

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

3.3c/2.9c U/c IR11433489/7/18 16:00


Yes No N/A

Yes No N/A


10-Sep-20187-Sep-2018





Comments:

Corrective Action:

Yes



9 of 97

00914217

10 o

f 97

00914218

11 o

f 97

00914219



General Set Information: There four field samples in these Work Orders. The samples were analyzed for perchlorate. Method Summary: Each sample was prepared as noted below and analyzed using an Agilent 1100 LC/MSD system in select ion monitoring (SIM) mode at m/z 83 and 85, which corresponds to the loss of one oxygen atom from the perchlorate molecule. ChemStation software was used for instrument control and data analysis. The ion ratio of m/z 83 to 85 was used to positively identify the response peak as perchlorate. Quantitation was performed using the m/z 83 peak area. An internal standard (ISTD) of 18O labeled perchlorate was added to each sample to establish the perchlorate peak retention time and used in quantitation. Sample Preparation: A 10.0mL aliquot of each sample was transferred into a 15-mL centrifuge tube. 50µL of an 18O labeled perchlorate solution was added to each sample as an internal standard. The samples were then capped, vortexed, and filtered into autosampler vial using Phenex PES membrane 0.45µm Syringe filters. Holding Times: Holding times were met for all analyses. Dilutions: Sample 1824779001 was analyzed and reported from a 1:1,000 dilution. The reporting limit has been adjusted accordingly. Method QC data: The method blank (LMB 618015) was less than 1/2 the CRDL. The recovery for the LCS (618016) was within acceptable parameters.

12 of 97

00914220

MS/MSD Analysis: MS/MSD was performed on sample 1824771001 (Client ID: LH18/24-SP650_083018). 5.0µl of Working Standard Solution Horizon ID 41828 was added to 10.0mL of sample preparation. The percent recoveries and relative percent difference (RPD) were within the performance limits. Instrument QC: Instrument initial and continuing calibrations were performed in accordance with published procedures. NC/CAR(s): NA Sample Calculation: Samples were reported in µg/L. Results were calculated in µg/L by the equation (A)x(B),

where: A = Analyte concentration from the standard curve (µg/L) B = Dilution performed at time of analysis Miscellaneous Comments: These samples were analyzed in accordance with the requirements found in the DOD QSM Version 5.1. Due to limitations of the Chemstation Software, some of the chromatographic peaks require manual integration. Manual integrations were performed for datafile 12SEPPD02/03/13. The ion ratio of m/z 83 to 85 may fail at levels near the reported Detection Limit (DL). The 83/85 ion ratio failed for field sample 1824779001.


13 of 97

00914221

ANALYTICAL REPORT


Phone:

E-mail:

281 530-5656

[email protected]



HS18090275 090618HS18090275Purchase Order:

Project ID:



1825466001 09/06/18LH18/24-SP650_090618 09/11/18




||

14 of 97

00914222

ANALYTICAL REPORT




Analytical Results

Sample ID: 09/06/201809/11/20181825466001Lab ID:

Collected:Received:

LH18/24-SP650_090618 NA


Media:

Water





LCMS04

Report Basis: Wet









/S/ Stephen Brose



Phone:Email:Web:


15 of 97

00914223

ANALYTICAL REPORT










Website








16 of 97

00914224

Analysis:


Workorder: 1825466




Limits:Basis:


Blank

LMB:

Analyte

Units:

Result

Analyzed:61801509/12/2018 11:40

ug/L

MDL RL



Dilution: 1ug/L


LCS:Analyzed:

61801609/12/2018 11:54

Units:

Target

Perchlorate 4.22 5.00 78.8 123.884.3


MS:Analyzed:


109/12/2018 12:29618027Sample:

Analyzed:Dilution:

Units: ug/L109/12/2018 12:151824771001


MSD:Analyzed:

61802809/12/2018 12:43

% Rec



Perchlorate ND 78.8 123.85 99.34.96 20.00.04.56 8.5591.1



CCV:Analyzed:

61801209/12/2018 10:56

Units:

Target


Result % Rec.

CCV:Analyzed:

61801709/12/2018 14:10

Units:

Target


Perchlorate 21.8 25.0 87.2 25.1 25.0 100



ICSA:Analyzed:

61801409/12/2018 11:26

Units:

Target





LODV:Analyzed:

61801309/12/2018 11:11

Units:

Target


Result % Rec.

LODV:Analyzed:

61801809/12/2018 13:55

Units:

Target


Perchlorate 0.972 1.00 97.2 0.947 1.00 94.7



QCS V4.417 of 97

00914225

Analysis:


Workorder: 1825466




Limits:Basis:







# -

Analyst Peer Review


09/13/2018 11:22 09/14/2018 13:46



QCS V4.418 of 97

00914226

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00914228

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00914230

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96 of 97

00914304

97 of 97

00914305

September 28, 2018





Sincerely,



Dear Marcia,


Project Manager


RJ Modashia



1 of 58

00914306





HS18090654-02 13-Sep-2018 14:00 14-Sep-2018 08:46LH18/24-SP650_091318_AIX Water

HS18090654-03 13-Sep-2018 14:00ALS-080918-98

14-Sep-2018 08:46Trip Blank Water


2 of 58

00914307



Project:

Work Order Comments


GCMS Semivolatiles by Method SW8270SIM

Batch ID: 132529Sample ID: LH18/24-SP650_091318 (HS18090654-01)

The surrogate recoveries could not be determined due to dilution below the calibration range. •


Batch ID: R323768Sample ID: CCV

2,2-Dichloropropane exceeded %D limits on CCV. Samples ND.•

Sample ID: LH18/24-SP650_091318 (HS18090654-01MS)

MS/MSD and RPD recovered outside the control limits for some few compounds•


Batch ID: 132542Sample ID: HS18090658-01MS

MS and MSD are for an unrelated sample•

Sample ID: HS18090658-01PDS

PDS is for an unrelated sample•



Sample Filtered•


3 of 58

00914308



WorkOrder:Lab ID:

Collection Date:

HS18090654HS18090654-01


ANALYTICAL REPORT


























1ug/L 19-Sep-2018 12:390.502-Butanone 2.040 1.01ug/L 19-Sep-2018 12:39U 0.302-Chlorotoluene 1.00.50 0.50




1ug/L 19-Sep-2018 12:39J 0.704-Methyl-2-pentanone 2.01.1 1.01ug/L 19-Sep-2018 12:390.40Acetone 2.0270 2.01ug/L 19-Sep-2018 12:39U 0.20Benzene 1.00.50 0.50













4 of 58

00914309



WorkOrder:Lab ID:

Collection Date:

HS18090654HS18090654-01


ANALYTICAL REPORT


















1ug/L 19-Sep-2018 12:39U 0.30o-Xylene 1.00.50 0.50


1ug/L 19-Sep-2018 12:39U 0.30Styrene 1.00.50 0.50



1ug/L 19-Sep-2018 12:39J 0.20Toluene 1.00.76 0.501ug/L 19-Sep-2018 12:39U 0.20trans-1,2-Dichloroethene 1.00.50 0.50




1ug/L 19-Sep-2018 12:390.20Vinyl chloride 1.01.1 0.50Surr: 1,2-Dichloroethane-d4 1%REC 19-Sep-2018 12:39100.0 81-1180Surr: 4-Bromofluorobenzene 1%REC 19-Sep-2018 12:39103 85-1140Surr: Dibromofluoromethane 1%REC 19-Sep-2018 12:3997.7 80-1190Surr: Toluene-d8 1%REC 19-Sep-2018 12:3991.3 89-1120

SEMIVOLATILES SIM Method:SW8270SIM Analyst: ACNPrep:SW3510 / 18-Sep-2018

100ug/L 18-Sep-2018 12:041.01,4-Dioxane 1.03.0 1.0Surr: 2-Fluorobiphenyl 100%REC 18-Sep-2018 12:04S0 40-1400

Surr: 4-Terphenyl-d14 100%REC 18-Sep-2018 12:04S0 40-1400

Surr: Nitrobenzene-d5 100%REC 18-Sep-2018 12:04S0 40-1400


1mg/L 28-Sep-2018 12:310.00190Barium 0.004000.180 0.002501mg/L 28-Sep-2018 12:31U 0.000600Lead 0.002000.00100 0.00100


1mg/L 28-Sep-2018 12:31U 0.000200Silver 0.002000.00100 0.00100



5 of 58

00914310



WorkOrder:Lab ID:

Collection Date:

HS18090654HS18090654-01


ANALYTICAL REPORT




1mg/L 14-Sep-2018 12:30J 0.00600Chromium, Hexavalent 0.01000.00700 0.0100



6 of 58

00914311


Bhate Environmental Associates, Inc.Longhorn GW Treatment PlantLH18/24-SP650_091318_AIX

WorkOrder:Lab ID:

Collection Date:

HS18090654HS18090654-02


ANALYTICAL REPORT








7 of 58

00914312



WorkOrder:Lab ID:

Collection Date:

HS18090654HS18090654-03


ANALYTICAL REPORT
































1ug/L 19-Sep-2018 12:15U 0.40Acetone 2.02.0 2.0

1ug/L 19-Sep-2018 12:15U 0.20Benzene 1.00.50 0.50













8 of 58

00914313



WorkOrder:Lab ID:

Collection Date:

HS18090654HS18090654-03


ANALYTICAL REPORT



















1ug/L 19-Sep-2018 12:15U 0.30o-Xylene 1.00.50 0.50


1ug/L 19-Sep-2018 12:15U 0.30Styrene 1.00.50 0.50



1ug/L 19-Sep-2018 12:15U 0.20Toluene 1.00.50 0.50






Surr: 1,2-Dichloroethane-d4 1%REC 19-Sep-2018 12:1599.3 81-1180Surr: 4-Bromofluorobenzene 1%REC 19-Sep-2018 12:15101 85-1140Surr: Dibromofluoromethane 1%REC 19-Sep-2018 12:1596.4 80-1190Surr: Toluene-d8 1%REC 19-Sep-2018 12:1590.5 89-1120



9 of 58

00914314

WEIGHT LOG

HS18090654Longhorn GW Treatment PlantBhate Environmental Associates, Inc.


Batch ID: 132529 Method: SEMIVOLATILES SIM 3510_B_SIMPrep:


Final Volume

Prep Factor

HS18090654-01 1 980 1 (mL) 0.00102



Final Volume

Prep Factor

HS18090654-01 1 10 10 (mL) 1


10 of 58

00914315


WorkOrder:Project:



Batch ID 132529 Test Name : SEMIVOLATILES SIM Matrix: Water

18 Sep 2018 10:23 18 Sep 2018 12:04HS18090654-01 13 Sep 2018 14:00 100LH18/24-SP650_091318


18 Sep 2018 13:00 28 Sep 2018 12:31HS18090654-01 13 Sep 2018 14:00 1LH18/24-SP650_091318


14 Sep 2018 12:30HS18090654-01 13 Sep 2018 14:00 1LH18/24-SP650_091318


19 Sep 2018 12:39HS18090654-01 13 Sep 2018 14:00 1LH18/24-SP650_091318

19 Sep 2018 12:15HS18090654-03 13 Sep 2018 14:00 1Trip Blank


27 Sep 2018 15:27HS18090654-02 13 Sep 2018 14:00 1LH18/24-SP650_091318_AIX


11 of 58

00914316

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Barium 0.00250 U0.00400

Lead 0.00100 U0.00200

Selenium 0.00200 U0.00200

Silver 0.00100 U0.00200




Value %RECControl

LimitRPD Ref


LCS

Client ID:

Barium 0.04679 0.05 0 93.6 80 - 1200.00400

Lead 0.05326 0.05 0 107 80 - 1200.00200

Selenium 0.04975 0.05 0 99.5 80 - 1200.00200

Silver 0.0497 0.05 0 99.4 80 - 1200.00200




Value %RECControl

LimitRPD Ref


MS

Client ID:

Barium 1.072 0.05 0.9887 166 80 - 120 SO 0.00400

Lead 0.04751 0.05 0.000142 94.7 80 - 1200.00200

Selenium 0.05094 0.05 0.001256 99.4 80 - 1200.00200

Silver 0.04744 0.05 0.000026 94.8 80 - 1200.00200




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Barium 1.042 0.05 0.9887 106 80 - 120 1.072 2.84 20 O 0.00400

Lead 0.04711 0.05 0.000142 93.9 80 - 120 0.04751 0.841 200.00200

Selenium 0.05233 0.05 0.001256 102 80 - 120 0.05094 2.7 200.00200

Silver 0.04631 0.05 0.000026 92.6 80 - 120 0.04744 2.41 200.00200



12 of 58

00914317

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


PDS

Client ID:

Barium 1.131 0.1 0.9887 142 75 - 125 SO 0.00400

Lead 0.1047 0.1 0.000142 105 75 - 1250.00200

Selenium 0.1132 0.1 0.001256 112 75 - 1250.00200

Silver 0.1014 0.1 0.000026 101 75 - 1250.00200




Value %RECControl

LimitRPD Ref


SD

Client ID:

Barium 0.9762 0.9887 1.26 100.0200

Lead 0.00500 0.000142 0 10 U0.0100

Selenium 0.0100 0.001256 0 10 U0.0100

Silver 0.00500 0.000026 0 10 U0.0100




13 of 58

00914318

Client:Project:



QC BATCH REPORT

Batch ID: 132529 Instrument: SV-5 Method: SW8270SIM

Sample ID: MBLK-132529 Units: ug/L Analysis Date: 18-Sep-2018 13:58



Value %RECControl

LimitRPD Ref


MBLK

Client ID:

1,4-Dioxane 0.010 U0.010


0.0856 0.08 0 107 40 - 1400Surr: 4-Terphenyl-d14


Sample ID: LCS-132529 Units: ug/L Analysis Date: 18-Sep-2018 14:18



Value %RECControl

LimitRPD Ref


LCS

Client ID:

1,4-Dioxane 0.06752 0.08 0 84.4 40 - 1400.010

0.07826 0.08 0 97.8 40 - 1400Surr: 2-Fluorobiphenyl

0.08695 0.08 0 109 40 - 1400Surr: 4-Terphenyl-d14


Sample ID: LCSD-132529 Units: ug/L Analysis Date: 18-Sep-2018 14:39



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

1,4-Dioxane 0.07223 0.08 0 90.3 40 - 140 0.06752 6.74 200.010

0.08992 0.08 0 112 40 - 140 0.07826 13.9 200Surr: 2-Fluorobiphenyl

0.08943 0.08 0 112 40 - 140 0.08695 2.81 200Surr: 4-Terphenyl-d14

0.04938 0.08 0 61.7 40 - 140 0.04963 0.505 200Surr: Nitrobenzene-d5




14 of 58

00914319

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:






















2-Butanone 1.0 U2.0


2-Hexanone 1.0 U2.0




Acetone 2.0 U2.0

Benzene 0.50 U1.0




Bromoform 0.50 U1.0




15 of 58

00914320

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:















m,p-Xylene 1.0 U2.0





o-Xylene 0.50 U1.0


Styrene 0.50 U1.0



Toluene 0.50 U1.0









45.67 50 0 91.3 89 - 1121.0Surr: Toluene-d8



16 of 58

00914321

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:





1,1-Dichloroethane 20.7 20 0 104 77 - 1251.0

1,1-Dichloroethene 20.4 20 0 102 71 - 1311.0







1,2-Dibromoethane 22.85 20 0 114 77 - 1211.0


1,2-Dichloroethane 23.21 20 0 116 73 - 1281.0







2-Butanone 45.46 40 0 114 56 - 1432.0

2-Chlorotoluene 21.65 20 0 108 79 - 1221.0

2-Hexanone 48.01 40 0 120 57 - 1392.0

4-Chlorotoluene 21.76 20 0 109 78 - 1221.0



Acetone 47.82 40 0 120 39 - 1602.0

Benzene 20.93 20 0 105 79 - 1201.0

Bromobenzene 20.36 20 0 102 80 - 1201.0



Bromoform 23.16 20 0 116 66 - 1301.0

Bromomethane 24.14 20 0 121 53 - 1411.0



17 of 58

00914322

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:



Chlorobenzene 21.61 20 0 108 82 - 1181.0

Chloroethane 20.51 20 0 103 60 - 1381.0

Chloroform 20.42 20 0 102 79 - 1241.0

Chloromethane 20.14 20 0 101 50 - 1391.0

cis-1,2-Dichloroethene 20.38 20 0 102 78 - 1231.0



Dibromomethane 23.09 20 0 115 79 - 1231.0


Ethylbenzene 22.97 20 0 115 79 - 1211.0



m,p-Xylene 47.93 40 0 120 80 - 1212.0


Naphthalene 20.41 20 0 102 61 - 1281.0

n-Butylbenzene 20.47 20 0 102 75 - 1281.0

n-Propylbenzene 22.2 20 0 111 76 - 1261.0

o-Xylene 23.1 20 0 116 78 - 1221.0


Styrene 22.23 20 0 111 78 - 1231.0



Toluene 20.93 20 0 105 80 - 1211.0





Vinyl chloride 21.05 20 0 105 58 - 1371.0

51.05 50 0 102 81 - 1181.0Surr: 1,2-Dichloroethane-d4



44.68 50 0 89.4 89 - 1121.0Surr: Toluene-d8



18 of 58

00914323

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS

Client ID: LH18/24-SP650_091318





1,1-Dichloroethane 18.16 20 0 90.8 77 - 1251.0

1,1-Dichloroethene 17.11 20 0 85.6 71 - 1311.0







1,2-Dibromoethane 19.35 20 0 96.7 77 - 1211.0

1,2-Dichlorobenzene 15.9 20 0 79.5 80 - 119 S1.0

1,2-Dichloroethane 20.56 20 0 103 73 - 1281.0



1,3-Dichlorobenzene 15.63 20 0 78.1 80 - 119 S1.0




2-Butanone 81.8 40 39.93 105 56 - 1432.0

2-Chlorotoluene 16.94 20 0 84.7 79 - 1221.0

2-Hexanone 42.27 40 0 106 57 - 1392.0

4-Chlorotoluene 16.68 20 0 83.4 78 - 1221.0


4-Methyl-2-pentanone 43.81 40 1.052 107 67 - 1302.0

Acetone 353.5 40 266.6 217 39 - 160 SO2.0

Benzene 18.41 20 0 92.0 79 - 1201.0

Bromobenzene 16.17 20 0 80.8 80 - 1201.0



Bromoform 19.13 20 0 95.7 66 - 1301.0

Bromomethane 9.879 20 0 49.4 53 - 141 S1.0



19 of 58

00914324

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS

Client ID: LH18/24-SP650_091318



Chlorobenzene 18.31 20 0 91.6 82 - 1181.0

Chloroethane 17.67 20 0 88.4 60 - 1381.0

Chloroform 17.68 20 0 88.4 79 - 1241.0

Chloromethane 16.87 20 0 84.4 50 - 1391.0

cis-1,2-Dichloroethene 21.17 20 3.003 90.8 78 - 1231.0



Dibromomethane 19.61 20 0 98.0 79 - 1231.0


Ethylbenzene 19.73 20 0 98.7 79 - 1211.0



m,p-Xylene 39.02 40 0 97.5 80 - 1212.0


Naphthalene 15.22 20 0 76.1 61 - 1281.0

n-Butylbenzene 16.54 20 0 82.7 75 - 1281.0

n-Propylbenzene 17.64 20 0 88.2 76 - 1261.0

o-Xylene 18.67 20 0 93.4 78 - 1221.0

sec-Butylbenzene 16 20 0 80.0 77 - 1261.0

Styrene 17.97 20 0 89.9 78 - 1231.0



Toluene 18.73 20 0.7648 89.8 80 - 1211.0





Vinyl chloride 18.51 20 1.074 87.2 58 - 1371.0

51.28 50 0 103 81 - 1181.0Surr: 1,2-Dichloroethane-d4



44.21 50 0 88.4 89 - 112 S1.0Surr: Toluene-d8



20 of 58

00914325

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18/24-SP650_091318





1,1-Dichloroethane 17.45 20 0 87.3 77 - 125 18.16 4 201.0

1,1-Dichloroethene 17.39 20 0 87.0 71 - 131 17.11 1.61 201.0







1,2-Dibromoethane 19.67 20 0 98.3 77 - 121 19.35 1.65 201.0


1,2-Dichloroethane 21.3 20 0 106 73 - 128 20.56 3.54 201.0



1,3-Dichlorobenzene 15.9 20 0 79.5 80 - 119 15.63 1.71 20 S1.0




2-Butanone 83.63 40 39.93 109 56 - 143 81.8 2.21 202.0

2-Chlorotoluene 17.19 20 0 85.9 79 - 122 16.94 1.47 201.0

2-Hexanone 42.79 40 0 107 57 - 139 42.27 1.24 202.0

4-Chlorotoluene 17.18 20 0 85.9 78 - 122 16.68 2.93 201.0


4-Methyl-2-pentanone 43.95 40 1.052 107 67 - 130 43.81 0.322 202.0

Acetone 362.6 40 266.6 240 39 - 160 353.5 2.54 20 SO2.0

Benzene 18.71 20 0 93.6 79 - 120 18.41 1.65 201.0

Bromobenzene 16.74 20 0 83.7 80 - 120 16.17 3.47 201.0


Bromodichloromethane 20.09 20 0 100 79 - 125 19.69 2.02 201.0

Bromoform 19.75 20 0 98.8 66 - 130 19.13 3.17 201.0

Bromomethane 10.15 20 0 50.7 53 - 141 9.879 2.67 20 S1.0



21 of 58

00914326

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18/24-SP650_091318

Carbon disulfide 41.47 40 0 104 64 - 133 43.17 4.02 202.0


Chlorobenzene 18.28 20 0 91.4 82 - 118 18.31 0.155 201.0

Chloroethane 16.39 20 0 82.0 60 - 138 17.67 7.49 201.0

Chloroform 17.52 20 0 87.6 79 - 124 17.68 0.923 201.0

Chloromethane 15.72 20 0 78.6 50 - 139 16.87 7.05 201.0

cis-1,2-Dichloroethene 20.83 20 3.003 89.1 78 - 123 21.17 1.6 201.0



Dibromomethane 20.64 20 0 103 79 - 123 19.61 5.13 201.0


Ethylbenzene 19.68 20 0 98.4 79 - 121 19.73 0.258 201.0



m,p-Xylene 38.69 40 0 96.7 80 - 121 39.02 0.845 202.0


Naphthalene 16.03 20 0 80.1 61 - 128 15.22 5.18 201.0

n-Butylbenzene 16.63 20 0 83.1 75 - 128 16.54 0.518 201.0

n-Propylbenzene 17.58 20 0 87.9 76 - 126 17.64 0.31 201.0

o-Xylene 19.17 20 0 95.9 78 - 122 18.67 2.66 201.0

sec-Butylbenzene 16.26 20 0 81.3 77 - 126 16 1.58 201.0

Styrene 17.91 20 0 89.6 78 - 123 17.97 0.332 201.0

tert-Butylbenzene 18.28 20 0 91.4 78 - 124 17.81 2.57 201.0


Toluene 18.9 20 0.7648 90.7 80 - 121 18.73 0.937 201.0





Vinyl chloride 17.12 20 1.074 80.2 58 - 137 18.51 7.81 201.0

50.06 50 0 100 81 - 118 51.28 2.41 201.0Surr: 1,2-Dichloroethane-d4

53 50 0 106 85 - 114 51.92 2.07 201.0Surr: 4-Bromofluorobenzene


44.5 50 0 89.0 89 - 112 44.21 0.668 201.0Surr: Toluene-d8



22 of 58

00914327

Client:Project:



QC BATCH REPORT





23 of 58

00914328

Client:Project:



QC BATCH REPORT


Sample ID: MBLK-R323660 Units: mg/L Analysis Date: 14-Sep-2018 12:30



Value %RECControl

LimitRPD Ref


MBLK

Client ID:


Sample ID: LCS-R323660 Units: mg/L Analysis Date: 14-Sep-2018 12:30



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Chromium, Hexavalent 0.249 0.25 0 99.6 80 - 1200.0100




Value %RECControl

LimitRPD Ref


MS

Client ID:

Chromium, Hexavalent 1.19 1.25 0 95.2 75 - 1250.0500




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Chromium, Hexavalent 1.195 1.25 0 95.6 75 - 125 1.19 0.419 200.0500




24 of 58

00914329





a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution




25 of 58

00914330




Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019




Dept of Defense ANAB L2231 22-Dec-2018

Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


26 of 58

00914331

RPG


HS18090654

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

0.8C/0.4C UC/C IR # 11432539/14/2018 11:00


Yes No N/A

Yes No N/A

Checklist completed by: Pablo MarinezDateeSignatureDateeSignature

14-Sep-201814-Sep-2018

FedEx Priority OvernightWATER Carrier name:Matrices:




Comments:

Corrective Action:

Yes



27 of 58

00914332

28 o

f 58

00914333

29 o

f 58

00914334



General Set Information: There were five field samples in these Work Orders. The samples were analyzed for perchlorate. Method Summary: Each sample was prepared as noted below and analyzed using an Agilent 1100 LC/MSD system in select ion monitoring (SIM) mode at m/z 83 and 85, which corresponds to the loss of one oxygen atom from the perchlorate molecule. ChemStation software was used for instrument control and data analysis. The ion ratio of m/z 83 to 85 was used to positively identify the response peak as perchlorate. Quantitation was performed using the m/z 83 peak area. An internal standard (ISTD) of 18O labeled perchlorate was added to each sample to establish the perchlorate peak retention time and used in quantitation. Sample Preparation: A 10.0mL aliquot of each sample was transferred into a 15-mL centrifuge tube. 50µL of an 18O labeled perchlorate solution was added to each sample as an internal standard. The samples were then capped, vortexed, and filtered into autosampler vial using Phenex PES membrane 0.45µm Syringe filters. Holding Times: Holding times were met for all analyses. Dilutions: Sample 1826197001 was analyzed and reported from a 1:1,000 dilution. Samples 1826185001, 1826186001/02 and 1826550001 failed the 50-150% method requirement for ISTD recovery. The samples were re-analyzed and reported from 1:10 dilutions. The reporting limits have been adjusted accordingly. Method QC data: The method blank (LMB 620036) was less than 1/2 the CRDL. The recovery for the LCS (620037) was within acceptable parameters.

30 of 58

00914335

MS/MSD Analysis: MS/MSD was performed on sample 1826185001 (Client ID: LH18/24-SP650_091318_AIX). 5.0µl of Working Standard Solution Horizon ID 41828 was added to 10.0mL of sample preparation. The parent sample and the MS/MSD were analyzed at 1:10 dilutions. The effective spike target was 50.µg/L. The percent recoveries and relative percent difference (RPD) were within the performance limits. Instrument QC: Instrument initial and continuing calibrations were performed in accordance with published procedures. NC/CAR(s): NA Sample Calculation: Samples were reported in µg/L. Results were calculated in µg/L by the equation (A)x(B),

where: A = Analyte concentration from the standard curve (µg/L) B = Dilution performed at time of analysis Miscellaneous Comments: These samples were analyzed in accordance with the requirements found in the DOD QSM Version 5.1. Due to limitations of the Chemstation Software, some of the chromatographic peaks require manual integration. A manual integration was performed for datafile 26SEPPD03.


31 of 58

00914336

ANALYTICAL REPORT


Phone:

E-mail:

281 530-5656

[email protected]



HS18090654 091318HS18090654Purchase Order:

Project ID:



1826185001 09/13/18LH18/24-SP650_091318_AIX 09/18/18




||

32 of 58

00914337

ANALYTICAL REPORT




Analytical Results

Sample ID: 09/13/201809/18/20181826185001Lab ID:

Collected:Received:

LH18/24-SP650_091318_AIX NA


Media:

Water





LCMS04

Report Basis: Wet




4010ND 20 UPerchlorate 10





/S/ Stephen Brose



Phone:Email:Web:


33 of 58

00914338

ANALYTICAL REPORT










Website








34 of 58

00914339

Analysis:


Workorder: 1826185




Limits:Basis:


Blank

LMB:

Analyte

Units:

Result

Analyzed:62003609/26/2018 08:52

ug/L

MDL RL



Dilution: 1ug/L


LCS:Analyzed:

62003709/26/2018 09:06

Units:

Target

Perchlorate 5.06 5.00 78.8 123.8101


MS:Analyzed:


1009/26/2018 12:03620038Sample:

Analyzed:Dilution:

Units: ug/L1009/26/2018 11:481826185001


MSD:Analyzed:

62003909/26/2018 12:18

% Rec



Perchlorate ND 78.8 123.850 94.247.1 20.00.046.8 0.55893.7



CCV:Analyzed:

62003309/26/2018 08:09

Units:

Target


Result % Rec.

CCV:Analyzed:

62004009/26/2018 11:17

Units:

Target


Result % Rec.

CCV:Analyzed:

62018909/26/2018 13:14

Units:

Target


Perchlorate 25.0 25.0 100 24.0 25.0 96.1 24.1 25.0 96.6



ICSA:Analyzed:

62003509/26/2018 08:38

Units:

Target





LODV:Analyzed:

62003409/26/2018 08:24

Units:

Target


Result % Rec.

LODV:Analyzed:

62004109/26/2018 11:31

Units:

Target


Result % Rec.

LODV:Analyzed:

62019009/26/2018 13:29

Units:

Target


Perchlorate 1.17 1.00 117 1.19 1.00 119 1.19 1.00 119

Page 1 of 2 Thursday, September 27, 2018


QCS V4.435 of 58

00914340

Analysis:


Workorder: 1826185




Limits:Basis:







# -

Analyst Peer Review


09/27/2018 10:32 09/27/2018 13:01

Page 2 of 2 Thursday, September 27, 2018


QCS V4.436 of 58

00914341

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00914363

Case Narrative Method: 6850 Analysis: Perchlorate Analysis SOP: LC-MS-CLO4 ALS WO ID(s): 1827524


General Set Information: There was one field sample in this Work Order. The sample was analyzed for perchlorate. Method Summary: Each sample was prepared as noted below and analyzed using an Agilent 1100 LC/MSD system in select ion monitoring (SIM) mode at m/z 83 and 85, which corresponds to the loss of one oxygen atom from the perchlorate molecule. ChemStation software was used for instrument control and data analysis. The ion ratio of m/z 83 to 85 was used to positively identify the response peak as perchlorate. Quantitation was performed using the m/z 83 peak area. An internal standard (ISTD) of 18O labeled perchlorate was added to each sample to establish the perchlorate peak retention time and used in quantitation. Sample Preparation: A 10.0mL aliquot of each sample was transferred into a 15-mL centrifuge tube. 50µL of an 18O labeled perchlorate solution was added to each sample as an internal standard. The samples were then capped, vortexed, and filtered into autosampler vial using Phenex PES membrane 0.45µm Syringe filters. Holding Times: Holding times were met for all analyses. Dilutions: NA Method QC data: The method blank (LMB 620915) was less than 1/2 the CRDL. The recovery for the LCS (620916) was within acceptable parameters. MS/MSD Analysis: The matrix spike and matrix spike duplicate (MS/MSD) was performed on sample 1826719001 of Work Order 1826719. The Matrix Spike and duplicate (MS/MSD – 620917/18) failed QC acceptance criteria for percent recoveries. The Matrix Spike and Matrix Spike duplicate is reported for the clients’ information only. The sample matrix may be inappropriate for the method selected. The MS/MSD relative percent difference (RPD) was within the performance limits.

00914364

Instrument QC: Instrument initial and continuing calibrations were performed in accordance with published procedures. NC/CAR(s): NA Sample Calculation: Samples were reported in µg/L. Results were calculated in µg/L by the equation (A)x(B),

where: A = Analyte concentration from the standard curve (µg/L) B = Dilution performed at time of analysis Miscellaneous Comments: These samples were analyzed in accordance with the requirements found in the DOD QSM Version 5.1. The ion ratio of m/z 83 to 85 often fails at levels near or below the Limit of Detection (LODV). The ion ratio failed for the Limit of Detection Verification standards (LODV1,2 – 620913/20). Manual Integrations were performed for some of the Initial Calibration analyses (datafiles: 27SEPI01/02) along with datafiles 02OCTP02/03/15-19/22/23/25/27. .

Thomas Bosch October 03, 2018 Analyst Date

00914365

ANALYTICAL REPORT


Phone:

E-mail:

281 530-5656

[email protected]

Report Date: October 04, 2018


HS18090657HS18090657Purchase Order:

Project ID:



1827524001 09/13/18LH18/24-SP650_091318_AIX 09/18/18 HS18090657

Page 1 of 3 Thu, 10/04/18 8:25 AM ENVREP-V4.8



||

00914366

ANALYTICAL REPORT




Analytical Results

Sample ID: 09/13/201809/18/20181827524001Lab ID:

Collected:Received:

LH18/24-SP650_091318_AIX HS18090657


Media:

Water


Analysis: EPA 6850, Water



LCMS04

Report Basis: Wet


Result (ug/L)Analyte MDL (ug/L) RL (ug/L) Dilution Qual

Analysis Method - EPA 6850

10.0600.44 0.20Perchlorate




EPA 6850 /S/ Thomas Bosch10/03/2018 10:52 10/04/2018 07:56

/S/ Stephen Brose



Phone:Email:Web:


00914367

ANALYTICAL REPORT










Website








00914368

Analysis:


Workorder: 1827524

EPA 6850Batch: NA


Preparation: NAHistorical/PerformanceALS Laboratory Group

Limits:Basis:


Blank

LMB:

Analyte

Units:

Result

Analyzed:62091510/02/2018 09:19

ug/L

MDL RL

Perchlorate 0.06 0.200ND


Dilution: 1ug/L


LCS:Analyzed:

62091610/02/2018 09:51

Units:

Target

Perchlorate 4.46 5.00 86.0 111.789.2


MS:Analyzed:


110/02/2018 10:22620917Sample:

Analyzed:Dilution:

Units: ug/L110/02/2018 10:081826719001


MSD:Analyzed:

62091810/02/2018 10:37

% Rec



Perchlorate 0.510 86.0 111.75 76.54.33 20.00.04.59 5.8581.7##



CCV:Analyzed:

62091110/02/2018 08:20

Units:

Target


Result % Rec.

CCV:Analyzed:

62091910/02/2018 12:45

Units:

Target


Result % Rec.

CCV:Analyzed:

62092110/02/2018 15:09

Units:

Target


Perchlorate 24.4 25.0 97.4 21.3 25.0 85.3 23.7 25.0 94.7



ICSA:Analyzed:

62091410/02/2018 09:05

Units:

Target





LODV:Analyzed:

62091310/02/2018 08:50

Units:

Target


Result % Rec.

LODV:Analyzed:

62092010/02/2018 13:39

Units:

Target


Result % Rec.

LODV:Analyzed:

62092210/02/2018 15:25

Units:

Target


Perchlorate 0.134 0.100 134 0.120 0.100 120 0.119 0.100 119

Page 1 of 2 Thursday, October 04, 2018


QCS V4.4

00914369

Analysis:


Workorder: 1827524

EPA 6850Batch: NA


Preparation: NAHistorical/PerformanceALS Laboratory Group

Limits:Basis:







# -

Analyst Peer Review


10/03/2018 10:53 10/04/2018 07:56

Page 2 of 2 Thursday, October 04, 2018


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