LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2

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Nicolaou , K. C.; Tria , G. Scott; Edmonds, David J.; Kar , Moumita . Total Syntheses of ()- Platencin and (-)- Platencin . Journal of the American Chemical Society (2009), 131(43), 15909-15917. LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2. PMB = p-methoxybenzyl. - PowerPoint PPT Presentation

Transcript of LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe 3)2

Nicolaou, K. C.; Tria, G. Scott; Edmonds, David J.; Kar, Moumita. Total Syntheses of ()-Platencin and (-)-Platencin. Journal of the American Chemical Society (2009), 131(43), 15909-15917.

LiHMDS = Lithium Hexamethyldisilazide = LiN(SiMe3)2

PMB = p-methoxybenzyl

NMO = N-methylmorpholine-N-OxideTPAP = Tetrapropylammonium perruthenate

Bn = Benzyl = CH2PH

TBS = tert-butyldimethylsilyl

Tf = Trifluoromethanesulfonyl

SEM-Cl =

TIPS = triisopropylsilyl

TASF = Tris(dimethylamino)sulfonium difluorotrimethylsilicate