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Silblock* Masonry Water Repellents
Product Description
Silblock masonry water repellents are
high performance water or solvent-basedsilicone sealing-impregnating agents thathave displayed outstanding reduction incapillary water absorption and organicstain repellency. Our intermediates serveas a building block for high performancemasonry water repellents.
Silblock masonry water repellents can offe
a wide range of performance propertiesfor potential use on concrete and masonrysurfaces. In addition to excellent freezethaw performance, Silblock masonry waterepellents typically exhibit resistance tochloride ion intrusion and moisture vaportransmission.
Momentive Performance Materialsprovides versatile materials as the startingpoint for our creative approach to ideasthat help enable new developments acrosshundreds of industrial and consumerapplications. We are helping customers
solve product, process, and performanceproblems; our silanes, fluids, elastomers,sealants, resins, adhesives, urethaneadditives, and other specialty productsare delivering innovation in everythingfrom car engines to biomedical devices.
From helping to develop safer tires andkeeping electronics cooler, to improvingthe feel of lipstick and ensuring thereliability of adhesives, our technologiesand enabling solutions are at the frontlineof innovation.
Product Key Features Typical Benefits
All Silblock Products Reduced Water Absorption Minimize spalling, efflorescence and improve
Test Method: ASTM D-6489 freeze thaw
All Silblock Products High Vapor Permeability Allows the surface to breathe
All Silblock Products Method of Application Application freedom
Spray, Paint, Dip, Addmix
All Silblock Products Available in water-based and solvent reducible Formulation freedom
All Silblock Products Available for silica and calcium carbonate-based
substrates
Silblock WA NCHRP Series II and IV tested Independent data supporting performance
Silblock SO & WSR Unique combination of water and stain resistance Resistance to aqueous-oil-and-acidic-based
stains
Silblock LD & CoatOSil* 2059 Low VOC Content Broader utility
Test Method: US EPA Method 24
Independent testing data available upon request.
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Silblock* Masonry Water Repellents
P. 02 Momentive Performance Materials
Product Description (continued)
We will focus on the following products and applications:
1) General purpose masonry water repellents Silblock LO-N
masonry water repellent and Silblock WA masonry waterrepellent.
2) Silblock WSR masonry water repellent that combines oleophobic
and hydrophobic behavior, typically resulting in an outstanding
reduction of capillary water absorption and an increased stain
resistance. It is a water-based stain and water repellent resin
solution.
3) CoatOSil* 2059 masonry water repellent that can impart water
and stain resistance onto calcium carbonate based substrates.
4) Paint additives that can add durability to exterior latex and
acrylic based paints.
General Purpose Masonry Water Repellents
Silblock LO-N masonry water repellent is approximately 100%
alkylated alkoxy siloxane which may be considered for use in water
repellent treatments of highly alkaline building materials such as
concrete, mortars, porous ceramic bodies (examples of which are
ceramic roofing tiles and facing bricks), calcium silicate bricks and
natural stones. It must be diluted before use in anhydrous solvents
such as aliphatic or aromatic hydrocarbons (examples of which are
toluene, xylene and mineral spirits).
Silblock WA masonry water repellent is a 60% active silane/siloxane
emulsion. It can offer excellent water absorption reductions and
chloride penetration reductions (NCHRP244 Series II and IV). It may
be considered for use in water repellent treatments of concrete,
plasters/mortars, porous ceramic bodies, lime sand stones, natural
stones and cement fiberboards.
15
10
5
0
24HourW
eightGain(%)
Water Absorption
Substrate
Ceramic Calcium Cement CementBrick Silicate Brick Plaster Mortar
Water-Based Silblock masonry water repellents
Solvent-Based Silblock masonry water repellents
Uncoated
Silblock WSR Masonry Water Repellent
A New Intermediate for Masonry Water Repellents:Single-Product Innovation for Protecting Construction
Materials
Silblock WSR masonry water repellent is an innovative
silicone-based emulsion that can combine water resistance and
oil resistance properties in a single additive to be considered for
formulated coatings used to treat masonry construction materials.
By typically offering good penetration on highly alkaline building
materials, Silblock WSR masonry water repellent can deliver
advanced water and oil protection in numerous potential
applications, including concrete, building restorations, bridge
decking, patios and sidewalks, roofing tiles and interior counter
tops. The material can help to reduce efflorescence and to improvefreeze thaw resistance.
Silblock WSR masonry water repellent is a waterborne material
that complements our solvent-based Silblock SO masonry water
repellent. This combined offering gives flexibility of choice for a
formulation that best addresses product requirements from both
a performance and environmental aspect.
With Silblock WSR masonry water repellent, we have combined
oleophobic and hydrophobic behaviors in a single product,
resulting in typically outstanding stain resistance and reduction of
capillary water absorption.
Note: Test data. Actual results may vary.
Figure 1 demonstrates that Silblock WA masonry water repellent
can provide performance similar to conventional solvent-base
systems.
Figure 1:The solvent based sealer (Silblock LO-N masonry waterrepellent) and the water-based sealer (Silblock WA masonry water
repellent) were both diluted to 5.5% actives and applied by brush
to different substrates. After seven days drying, the coated side was
exposed to water and the water intake was measured by weight.
The result is expressed as a percentage of the untreated uptake.
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Silblock* Masonry Water Repellents
P. 03 Momentive Performance Materials
Silblock WSR Masonry Water Repellent (continued)
Silblock WSR masonry water repellent may effectively penetrate
a number of building materials, including fresh concrete, plaster,
calcium silicate brick, fibrous cement and expanded concrete, to
deliver water and stain resistance. In addition, it typically allowsexcellent water vapor permeability, so surfaces can breathe.
The performance of fluoropolymers as stain resistant materials
is well known. However, they do not offer long-term water
repellency. Alternatively, silicones are effective and widely
used water repellents that can also provide vapor permeability.
However, until now, due to lack of oleophobicity, silicones have
exhibited limited stain resistance properties.
The water absorption and stain performance of new Silblock WSR
masonry water repellent on concrete was compared to stan-
dard products and to untreated substrates. For testing, the five
products were diluted to 5% actives by weight. The prepared
emulsions were applied by brush to the substrate at 150 g/m2
.After application, the panels were dried for seven days at room
temperature. For the water absorption measurements, the coated
sides of the specimens were exposed to tap water, and the water
absorption was calculated as water uptake in %. The results are
shown in Figure 2. Silblock WSR masonry water repellent ex-
hibited low water absorption while the fluoropolymers exhibited
significantly higher water absorption.
Figure 2: Water Absorption of Various Fluoropolymers
For the stain resistance test, drops of the following staining
agents were applied to the coated substrates described above:
Old machine oil
Machine oil Olive Oil
Mustard
Ketchup
The staining agents were left on the specimens for five hours and
then washed off with tap water. The results are shown in Figure 3.
Silblock WSR masonry water repellent was comparable with the
silicone emulsion in terms of reduced water absorption and with
the fluoropolymer in its stain resistance.
Figure 3: Silblock WSR Masonry Water Repellent
on Concrete and Terracotta
1400
1200
1000
800600
400
200
0
WaterAbsorption(percent on
concrete)
2 hours 6 hours 24 hours
Untreated 1147 1250 1265
Silblock WSRmasonry waterrepellent 59 88 147
Fluoropolymer 118 265 574
Silblock WAmasonry waterrepellent 29 59 103
Fluorosilane 44 59 118
Organic Anti-Stain 338 691 1250
Time
Note: Test data. Actual results may vary.
Note: Test data. Actual results may vary.
Immediately After
Application of Stains
After 5 hr., Washed Off
with Tap Water
Concrete
Untreated withSilblock WSR
water repellent
Untreated withSilblock WSR
water repellent
Immediately After
Application of Stains
After 5 hr., Washed Off
with Tap Water
Terracotta
Untreated withSilblock WSR
water repellent
Untreated withSilblock WSR
water repellent
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Silblock* Masonry Water Repellents
P. 04 Momentive Performance Materials
CoatoSil* 2059 Masonry Water Repellent
Non-Fluorine-Based Stain Resistant Penetrant
The industry is making a strong effort to find alternatives to
fluorocarbons for water repellency and stain resistance protectionfor substrates. Silicone-based sealers are of considerable interest
for the improvement of capillary water absorption and minimiza-
tion of oleophobicity for reactive masonry surfaces like concrete
and marble.
CoatOSil 2059 masonry water repellent is the first generation
surface protectant for possible use with concrete and calcium
carbonate based masonry. This non-fluorine-based masonry water
repellent is inherently oloephobic and hyrdrophobic, due to its
superior film forming capabilities. CoatOSil 2059 masonry water
repellent can offer combined reduction in capillary water absorp-
tion and organic stain repellency for calcium carbonate masonry
such as quartz, tumbled marble, honed marble, limestone, certain
pavers and terracotta. It is a solvent-less water-based emulsionof an aminofunctional siloxane. CoatOSil 2059 masonry water
repellent has exhibited performance profiles superior to original
silicone-type water repellents. Potential applications for this water
repellent may include: office buildings, schools, parking garages,
bridges, retaining walls, remedial applications as well as new
construction.
Silblock Additives for Masonry Paint Systems
Paint systems are used primarily in the refurbishment and
restoration of buildings. While a mineral-based paint may onlybe applied on an untreated substrate, silicone masonry paints
may be applied easily on walls that have already been coated.
The key characteristics of a properly formulated silicone masonry
paint are the low water permeability (typical of emulsion paints),
or high water vapor permeability (typical of mineral-based paints)
and good weather stability.
Silblock F masonry paint additive and Silblock 3657 masonry
paint additive are solvent-less silicone emulsions to be considered
for use in silicone masonry paints. Silblock F masonry paint
additive can be considered for use with straight acrylics, where
a high transition glass temperature is needed Silblock 3657
masonry paint additive can be considered for use with styreneacrylics, where a lower glass transition temperature is needed.
If a primer is required, either aqueous Silblock LD masonry water
repellent or aqueous Silblock WA masonry water repellent may
be considered.
Figure 4-6: Building Refurbished with Paint Additive: Silblock F Masonry Paint Additive
Figure 4: 1993 After Refurbishment Figure 5: 12 Years after Treatment Figure 6: 12 Years after Treatment
Note: Sample results. Actual results may vary.
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Silblock* Masonry Water Repellents
P. 05 Momentive Performance Materials
Silblock Masonry Water Repellents
Potential Application Areas
Five application areas for which to consider Silblock masonry water repellents are:
1.Building Restoration:The treatment of porous mineral building materials.
2. Construction:Building / bridging deck rehabilitation and restoration for vertical and horizontal applications
3. Patio and Sidewalks:Materials maintain better appearance if treated for protection caused by exposure to water.
4. Kitchen Counter Tops:Preventative impregnation during building construction is generally more advantageous. Water Repellents
formulated using the new Silblock product line may help accomplish successful rehabilitation and durable restoration
5.Roofing Tiles
Application 1: Building Restoration
Problem Solved:Water repellency for vertical surfaces
Application 2: Bridging Deck
Problem Solved:Reduced chloride ion and alkalinity build up
Application 3: Patios and Sidewalks
Problem Solved:Water repellency for horizontal surfaces
Application 4: Counter Tops
Problem Solved:Water and stain repellency for horizontal surfaces
This photograph illustrates the difference betweentwo ceramic roof tiles, one coated with Silblock LDmasonry water repellent, the other untreated. Thetop tile was not treated, while the bottom tile wasimmersed in a 3% solution of Silblock LD masonrywater repellent for 30 seconds. Both tiles were thenplaced in a stand at a 35 angle and exposed toweather for 10 months.
Application 5: Roofing Tiles
Problem Solved:Water and UV resistance
Note: Test data. Actual results may vary.
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Silblock* Masonry Water Repellents
P. 06 Momentive Performance Materials
Silblock Masonry Water Repellents (continued)
Potential Application Areas (continued)
Key Features
Silblock masonry water repellents can help provide a dry environment discouraging
the staining that can occur on a wet environment.
Silblock masonry water repellents may help to surpress the growth of efflorescence.
Silblock masonry water repellents can improve freeze thaw resistance.
Note: Test data. Actual results may vary.
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Silblock* Masonry Water Repellents
P. 07 Momentive Performance Materials
Typical Performance of Silblock Masonry Water Repellents on Various Substrates
Substrate Silblock WSR Silblock WA Silblock LD CoatOSil* 2059 Silblock SO Silblock LO-N
Concrete G E S G E E
Clay Roof Tiles E E G G S S
Exterior Plaster E E G G G S
Calcium Sil Brick E E G E E E
Light Concrete E E G G S E
Natural Stone E G S G E G
Clay Brick E E G G E E
Horizontal Barrier E G G G G S
Terracotta E E S G E S
Saltillo E E S G E S
Marble E G G E G G
Granite E G G E G G
Lime Sandstone E S S E S S
Legend: E = Excellent
G = Good
S = Suitable
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Silblock* Masonry Water Repellents
P. 08 Momentive Performance Materials
Overview: Silblock Masonry Water Repellents
Silblock WSR Speciality siloxane emulsion. This emulsion combines oleophobic and hydrophobic behavior
masonry water repellent in a single product, typically resulting in an outstanding reduction of capillary water
absorption and stain resistance. May be considered for application to highly alkalinebuilding materials such as fresh concrete, plaster, calcium silicate brick, fibrous cement
and expanded concrete.
Silblock WA Solvent-less, water-thinnable emulsion of a combination of alkyl alkoxysilane and alkyl
masonry water repellent alkoxysiloxane. May be considered for use on common substrates, and may be particularly
beneficial on highly alkaline mineral substrate, and for fine-pored building materials, such
as concrete.
Silblock LD Solvent-less, water-thinnable emulsion of a more highly alkylated alkoxysiloxane.
masonry water repellent May be considered for waterproofing during manufacture and for highly absorbent
mineral building materials.
CoatOSil* 2059 Emulsion of an amino functional siloxane. May be considered for calcium carbonate based
masonry water repellent substrates such as marble, limestone and calcium silicate brick. This product may also
impart stain resistance on marble substrates.
Silblock LO-N Solvent-less alkoxysiloxane, may be considered for highly alkaline mineral substrates.
masonry water repellent Typically good penetration.
Silblock SO Solvent-based specialty siloxane. This emulsion combines oleophobic and hydrophobic
masonry water repellent behavior in a single product, typically resulting in an outstanding reduction of capillary
water absorption and stain resistance. May be considered for application to highly alkaline
building materials such as fresh concrete, plaster, calcium silicate brick, fibrous cement and
expanded concrete.
Silblock F Polysiloxane emulsion may be considered for use as masonry paint additive. This emulsion
masonry paint additive may provide high vapor permeability and low water absorption.
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Silblock* Masonry Water Repellents
P. 09 Momentive Performance Materials
Typical Product Detail: Silblock Masonry Water Repellents
Water Dilutable Masonry Water Repellents
Silblock WSR Silblock WA Silblock LD CoatOSil* 2059
Product Type Emulsion Emulsion Emulsion Emulsion
Active Substance 30% 60% 35% 35%
Content
Appearance White White White White
Potential Uses Oleophobic and hydrophobic Faade impregnation Faade impregnation Marble and limestone
treatment of mineral In factory treatment In factory treatment stain resistance
substrates Water proofing additive treatment
for concrete
Typical Features 1. Superior water repellency 1. Long dilution stability 1. Oldest water-based 1. Beading effect
2. Good stain resistance 2. Patented technology 2. Compatible with calcium
3. Good storage stability manufacturing process 2. Recommend for large carbonate substrates
3. Stable emulsion pored substrate 3. Stain resistance
4. Dense substrate penetration
Composition Siloxane emulsion with fluoro Solvent-less siloxane / Solvent-less alkylated Emulsion of an amino
alkoxysilane emulsion alkoxy siloxane emulsion functional siloxane
in water in water
Specific Gravity 1.025 0.98 1.06 0.99
Recommended Dilution 1:5 - 1:2 1:11 - 1:5 1:6 - 1:3 1:6 - 1:3
pH 5 to 6 8 to 10 7 to 8.5 N/A
Flash Point C (F) >100 (>212) by DIN 51758 90 (194) by DIN 51758 >100 (>212) by DIN 51758 >100 (>212)
VOC (g/L) in form supplied 202(1) 298(1) 80(1) 121(1)
(1) VOC determined in accordance with procedures outlined in EPA Method 24
Solvent Dilutable Masonry Water Repellents
Silblock SO Silblock LO-N
Product Type Solution Pure substance
Active Substance 30% 100%
Content
Appearance Colorless to yellowish Yellow
Potential Uses Oleophobic and hydrophobic Faade impregnation
treatment of mineral
substrates
Typical Features 1. High vapor permeability 1. Color enhancement
2. Superior water repellency 2. Good barrier properties
3. Good stain resistance
4. Good storage stability
Composition Silane ester oligomer Solvent-less alkylated
solution alkoxy siloxane
Specific Gravity 0.8 1.1
Recommended Dilution 1:5 - 1:2 1:17 - 1:10
pH N/A N/A
Flash Point C (F) 36 (97) by DIN EN 13736 35 (95) by DIN 51758
VOC (g/L) in form supplied >700 224(1)
(1) VOC determined in accordance with procedures outlined in EPA Method 24
Suitable solvents are anyhydrous aliphatic or aromatic hydrocarbons. Examples of such solvents includetoluene, xylene, or mineral spirits, IsoparG and Tarksone.
Isoparis a registered trademark of Exxon Mobil Corporation.
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Silblock* Masonry Water Repellents
P. 10 Momentive Performance Materials
Typical Product Detail: Silblock Masonry Water Repellents (continued)
Masonry Paint Systems
Paint Additive Primer
Silblock 3657 Silblock F Silblock WA Silblock LD
Product Type Emulsion Emulsion Emulsion Emulsion
Active Substance 54% 60% 60% 35%
Content
Appearance White White White White
Potential Uses Co-binder in silicone masonry Co-binder in silicone masonry Deeply penetrating primer Primer
paints/plaster paints/plaster Additive to silicone masonry
Co-binder in flexible silicone Additive to masonry paints/plasters for
masonry paints paints/plasters improved water resistance
Additive to masonry and beading
paints/plasters
Typical Features Cost/efficient formulations Most universal paint Patented manufacturing Oldest water-based
Used primarily with stryene additive process technology
acrylics Used with straight acrylics Long dilution stability Recommended for large
Excellent scrub resistance Stable emulsion pored substrate Dense substrate penetration
Total Weight Blend Ratio: 70-85 : 30-15 Ratio: 70-85 : 30-15 Dilute down to 5% active As primer dilute down
(acrylate : silicone) (acrylate : silicone) for priming 5% active
As additive dilute down
1% on paint
Composition Resin emulsion Siloxane Solvent-less siloxane/ Solvent-less alkylated
alkoxysilane emulsion alkoxy siloxane emulsion
in water in water
Specific Gravity 1.07 1 0.98 1.06
pH 5.5 to 8.5 5.5 to 7 8 to 10 7 to 8.5
Flash Point C (F) >100 (>212) >100 (>212) 90 (194) >100 (>212)
Note: Formulation Guides are available upon request.
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Silblock* Masonry Water Repellents
P. 11 Momentive Performance Materials
Product Safety, Handling and Storage
Customers considering the use of this product should review
the latest Material Safety Data Sheet and label for product
safety information, handling instructions, personal protective
equipment if necessary, and any special storage conditionsrequired. Material Safety Data Sheets are available at
www.momentive.com or, upon request, from any Momentive
Performance Materials representative. Use of other materials
in conjunction with Momentive Performance Materials products
(for example, primers) may require additional precautions.
Please review and follow the safety information provided by
the manufacturer of such other materials.
Limitations
Customers must evaluate Momentive Performance Materials
products and make their own determination as to fitness of use
in their particular applications.
Emergency Service
Momentive Performance Materials maintains an around-the-clock emergency service for its products. The American Chemistry Council
(CHEMTREC), Transport Canada (CANUTEC), and the Chemical Emergency Agency Service also maintain an around-the-clock emergency
service for all chemical products:
Location Momentive Performance Materials Products All Chemical Products
Mainland U.S., Puerto Rico 518.233.2500 CHEMTREC: 800.424.9300
Alaska, Hawaii 518.233.2500 CHEMTREC: 800.424.9300
Canada 518.233.2500 CANUTEC: 613.996.6666 (collect)or CHEMTREC: 800.424.9300
Europe, Middle East, Africa +32.(0)14.58.45.45 (Belgium) CHEMTREC: +1-703.527.3887 (collect)
Latin America, Asia/Pacific, +518.233.2500 CHEMTREC: +1-703.527.3887 (collect)all other locations worldwide
At sea Radio U.S. Coast Guard, which can directly contact Momentive Performance Materials at 518.233.2500 or
CHEMTREC at 800.424.9300.
DO NOT WAIT. Phone if in doubt. You will be referred to a specialist for advice.
Patent Status
Technical subject matter in this publication is described and
protected by one or more of the following U.S. Patents and
their foreign counterpart patents and/or patent applications:
U.S. Patent No. 5,531,812. Other U.S. and foreign patents and/orpatent applications not listed covering the subject matter may
be relevant.
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*Silblock and CoatOSil are trademarks of Momentive Performance Materials Inc.
Momentive and M-design logo are trademarks of Momentive Performance Materials Inc.Copyright 2008 Momentive Performance Materials Inc. All rights reserved.
113-601-00E-GL05/08
CUSTOMER SERVICE CENTERS
North America [email protected]
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UA, Silanes and Specialty Coatings T+1.800.334.4674 F+1.304.746.1623
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T+1.800.295.2392
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