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Brownian Motion

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Suppose you are sitting in a big stadium, watching a game of football, being played between two equally good teams.

Suppose the players are invisible: nothing except the ball is visible.

Open your eyes once every 15 sec.What will you see?

A Thought Experiment (a gedanken experiment)

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Result of an actual experimentParticle positions were recorded at intervals

of 30 sec.

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History of the Brownian Motion

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Brownian Motion: Discovery

Discovered by Scottish botanist Robert Brown in 1827 while studying pollens of Clarkia (primrose family) under his microscope

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Robert Brown (1773-1858) (Scottish Botanist)

To his surprise, he noticed that tiny particles suspended within the fluid of pollen grains were moving in a haphazard fashion.

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Robert Brown

Robert Brown’s main claim to fame is his discovery of the cell nucleus when looking at cells from orchids under his microscope

20 orchid epidermal cells showing nuclei (and 3 stomata) seen under Brown’s original microscope preserved by the Linnean Society London

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Brown’s Microscope

And Brownian motion of milk globules in water seen under Robert Brown’s microscope

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If you were Robert Brown

How would you understand this observation? (Remember, you are in 1827!)

Would you suspect that the pollen is alive? Would you get excited at the thought that you

may have discovered the very essence of life or a latent life force in every pollen? What other experiments would you perform to

test your suspicions?

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This is what Mr. Brown did:

He repeated his experiment with other fine particles including the dust of igneous rocks,

which is as inorganic as could be. He found that any fine particle suspended in

water executes a similar random motion.This phenomenon is now called Brownian

Motion.

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Basic Understanding

Sizes (radius or diameter) Suspended particle: a few microns (10-6 m) Atom: 10-10 m Water molecule: somewhat larger Thus the suspended particle is a monster,

about 10,000 times bigger compared to a water molecule.

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Basic Understanding (contd.)

Numbers: A spoonful of water contains about 1023 water molecules.

Speeds: They are perpetually moving in different directions, some faster than others.

As they move, they keep colliding with each other, which can possibly change their speeds and directions of motion.

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Basic Understanding (contd.)

Now you can very well imagine the fate of the particle unfortunate enough to be placed in the mad crowd of water molecules. The poor fellow is getting hit, at any instant, from all sides, by millions of water molecules. The net force on it keeps fluctuating in time and it keeps getting kicks in the direction of the net instantaneous force. The end result is that its position keeps changing randomly.

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Some questions:◦ Is "Brownian" movement more rapid for bigger

particles or smaller particles ? Explain

◦ How does Brownian motion depend on temperature? Explain

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Albert Einstein

Worked out a quantitative description of Brownian motion based on the Molecular-Kinetic Theory of Heat

Published as the third of 3 famous three 1905 papers

Awarded the Nobel Prize in 1921 in part for this.

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The Big Question: What is the mass of air in the room?

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Thank you