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BOILING AND

CONDENSATION

Boiling – The change from the liquid to the vapor state is sustained by heat

transfer from the solid surface.

Condensation – The change from the vapor to the liquid state results in heat

transfer to the solid surface.

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CONVECTION PROCESSES OF BOILING ANDCONDENSATION

Boiling Modes

•  When evaporation occurs at a solid-liquid interface, it is termed boiling• Heat is transferred from the solid surface to the liquid

q”s = h (Ts – Tsat) = h ΔTe , ΔTe = excess temp.

• The process is characterized by the formation of vapor bubbles

• Boiling may occur under various conditions:

i) Pool boiling- process in which the heating surface is submerged in a large

 body of stagnant liquid

ii) Forced convection boiling

- fluid motion is induced by external means as well as by free

convection and bubble induced mixing

iii) Subcooled boiling

- the temp.of the liquid is below the saturation temp. and

 bubbles formed at the surface may condensed in liquid

iv) Saturated boiling

- the temp. of the liquid slightly exceeds the saturation temp.

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Homeworks

Describe briefly the boiling regimes as shown above

(Figure 10.4)

Explain briefly the forced convection boiling flow

regimes as shown above (Figure 10.8)

Submit: 23rd of September 2010

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Pool Boiling Correlations

Nucleate Pool Boiling Correlation:

 – The coefficient Cs,f and the exponent n depend on the solid-liquid combination and representative

experimentally determined values are presented in Table 10.1

• Critical Heat Flux

 – For horizontal plates (C = 0.149)

 – For sphere, large horizontal cylinders and large finite heated surfaces (C = 0.131)

• Minimum Heat Flux

C = 0.09

 All properties are evaluated at the saturation temperature.

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Pool Boiling Correlations

• Film Pool Boiling Correlation:

 – For horizontal cylinders (C = 0.62)

 –For spheres (C = 0.67)

Vapor properties are evaluated at the film temperature, Tf = (Ts + Tsat)/2 and the liquid density is evaluated

at the saturation temperature (Tsat).

 At Ts ≥ 300°C, radiation across the vapor film becomes significant. To calculate total heat transfer 

coefficient:

The effective radiation coefficient is expressed as

( )sats

4sat

4s

rad TT

TTεσ

=h

ε = emissivity of the solid (Table A.11)

σ = Stefan-Boltzman constant

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PROBLEM 10.10 – Nucleate Boiling

PROBLEM 10.27 – Film Boiling 

EXAMPLES:

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CONDENSATION : PHYSICAL MECHANISMS

• Condensation occurs when the temperature of a vapor is reduced below its saturation temperature

• The latent energy of the vapor is released, heat is transferred to thesurface and the condensate is formed

• Modes of Condensation :

i) Film condensation (Figure 10.9 a)

- occurs in clean and uncontaminated surfaceii) Dropwise condensation (Figure 10.9 b)

- occurs in coated surface with a substance that inhibits wetting

- the drops form in crack, pits and cavities on the surface

iii) homogenous condensation (Figure 10.9 c)- vapor condenses out as droplets suspended in a gas phase to

form a fog

iv) direct contact condensation (Figure 10.9 d)

- occurs when vapor is brought into contact with a cold liquid

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LAMINAR CONDENSATION ON A VERTICALPLATE

• For laminar film condensation, the total condensation rate may bedetermined from the relation :

m = q q = total heat transfer to the surface

h’fg • The total heat transfer to the surface is

q = hL A (Tsat – Ts)

• The average Nusselt number :NuL = hL L = 0.943 ρℓ g (ρℓ - ρ v ) h’fg L3 1/4 

k  μℓk ℓ (Tsat – Ts)

• Heat of vaporization, h’fg 

h’fg = hfg (1 + 0.68Ja)Ja = CPℓ (Tsat – Ts)

hfg 

* All liquid properties (ρℓ , μℓ , CPℓ , k ℓ) should be evaluated at the filmtemperature, Tf = (Tsat – Ts)/2 and ρ v and hfg should be evaluated at Tsat *

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TURBULENT FILM CONDENSATION• To check the flow conditions, Reynolds number may be expressed as

Reδ = 4m = 4ρℓ Um δ 

μℓ  b μ ℓ 

• For Laminar Wave – free Region:hL (υℓ

2/g)1/3 = 1.47 Reδ-1/3 , Reδ ≤ 30 

k ℓ • For Laminar Wavy Region :

hL

(υℓ

2/g)1/3 = Reδ

, 30 ≤ Reδ ≤ 1800 

k ℓ  1.08 Reδ1.22 – 5.2 

• For Turbulent Region :

hL (υℓ2/g)1/3 = Reδ

, Reδ ≥ 1800 

k ℓ  8750 + 58Pr-0.5 (Reδ

0.75 – 253) 

L

b

Laminar wave-free region (Re ≤ 30) 

Laminar wavy region (30 ≤ Re ≤ 1800) 

Turbulent region (Re ≥ 1800) 

υℓ  = μℓ /ρℓ  g = 9.81 m/s2 

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• To determine the value of Reynolds number,

Reδ  :

( )

( )

( )

( )

( )( )1800 ≥Re 253+Pr 151Pr +

g/υhμ

TTLk069.0=Re

1800 ≤Re ≤30 8.4+g/υhμ

TTLk70.3=Re

 30 ≤Re g/υhμ

TTLk78.3=Re

δ345.05.0

312'fg

ssatδ

δ

82.0

312'fg

ssatδ

δ

43

312'fg

ssatδ

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FILM CONDENSATION ON RADIAL SYSTEMS

• Laminar film condensation on the outer surface of a sphere may be

expressed as :hD = 0.826 g ρℓ (ρℓ  - ρ v ) k ℓ

3 h’fg ¼ 

μℓ (Tsat – Ts) D

• Laminar film condensation on the outer surface of a horizontal tube:

hD = 0.729 g ρℓ (ρℓ  - ρ v ) k ℓ3 h’fg 

¼ 

μℓ (Tsat – Ts) D

• For N horizontal tubes :

hD,N = 0.729 g ρℓ (ρℓ  - ρ v ) k ℓ3 hfg 

¼ 

Nμℓ (Tsat – Ts) D

hD,N = hDN-1/4 , hD = heat transfer coefficient for thefirst (upper) tube

h’fg = hfg [1 + 0.68 Ja] , Ja = CPℓ (Tsat – Ts)

hfg 

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FILM CONDENSATION IN HORIZONTAL TUBES

• For low vapor velocities :Reυ,i = ρυ um,υ D < 35,000

μυ i

• Laminar film condensation in the inner surface of a horizontal tubemay be expressed as :

hD = 0.555 g ρℓ (ρℓ  - ρ v ) k ℓ3 h’fg  ¼ 

μℓ (Tsat – Ts) D

h’fg = hfg + 3 CPℓ  (Tsat – Ts)

8

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DROPWISE CONDENSATION

• For drop wise condensation :hdc = 51104 + 2044 Tsat (°c) , 22°c ≤ Tsat ≤ 100°c

hdc = 255510 , Tsat ≥ 100°c

•  All liquid properties are evaluated at the film temperature

Tf = (Tsat + Ts)/2

• ρυ and hfg are evaluated at Tsat

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PROBLEM 10.47

Saturated ethylene glycol vapor at 1 atm is exposed to a vertical plate

300 mm high and 100 mm wide having a uniform temperature of 420 K.Estimate the heat transfer rate to the plate and the condensation rate. Approximate the liquid properties as those corresponding to saturated

conditions at 373 K (Table A.5) 

Example  – Film condensation on vertical plate

Example  – Film condensation on radial system

PROBLEM 10.55 

 A horizontal tube of 50mm diameter with a surface temperature of 34°c isexposed to steam at 0.2 bar. Estimate the condensation rate and heat transferrate per unit length of the tube?