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Page 1: Biocompatible Responsive Polypyrrole/GO nanocomposite ... · Biocompatible Responsive Polypyrrole/GO nanocomposite Coatings for biomedical applications A. Madhan Kumar a*, Bharathi

Biocompatible Responsive Polypyrrole/GO nanocomposite

Coatings for biomedical applications

A. Madhan Kumar a*, Bharathi Suresh b, c, Suresh Ramakrishna b, c,

and Kye-Seong Kim b, c*

a Centre of Research Excellence in Corrosion, Research Institute, King Fahd University of

Petroleum and Minerals, Dhahran, Saudi Arabia

b Graduate School of Biomedical Science and Engineering, Hanyang University, Seoul, Korea.

c College of Medicine, Hanyang University, Seoul, Korea.

*Correspondence authors

A. Madhan Kumar (Email: [email protected] ), Tel: +966538801789.

Kye-Seong Kim (Email: [email protected]), Tel: +82-2-2220-0607, Fax: +82-2-

2220-2422

Electronic Supplementary Material (ESI) for RSC Advances.This journal is © The Royal Society of Chemistry 2015

Page 2: Biocompatible Responsive Polypyrrole/GO nanocomposite ... · Biocompatible Responsive Polypyrrole/GO nanocomposite Coatings for biomedical applications A. Madhan Kumar a*, Bharathi

-0.6 -0.4 -0.2 0.0 0.2 0.4 0.6 0.8 1.0 1.2-0.004

0.000

0.004

0.008

0.012

0.016

0.020Pure PPy

Cur

rent

, i/A

Potential, E / V vs SCE

-0.6 -0.3 0.0 0.3 0.6 0.9 1.2-0.02

0.00

0.02

0.04

0.06

0.08

Potential, E / V vs SCE

Cur

rent

, i/A

Pure PPy PGO1 PGO2 PGO3

-0.6 -0.3 0.0 0.3 0.6 0.9 1.2-0.02

0.00

0.02

0.04

0.06

0.08

Potential, E / V vs SCE

Cur

rent

, i/A

PGO1

-0.6 -0.3 0.0 0.3 0.6 0.9 1.2

-0.04

0.00

0.04

0.08

0.12

Potential, E / V vs SCE

Curr

ent,

i/A

PGO2

-0.6 -0.3 0.0 0.3 0.6 0.9 1.2-0.04

0.00

0.04

0.08

0.12

0.16

Potential, E / V vs SCE

Cur

rent

, i/A

PGO3

Figure S1 CV curves of pure PPy and PGO nanocomposite coatings on 316L SS substrates

Figure S2 UV-Vis spectral results of GO, pure PPy and PGO nanocomposite coatings

Page 3: Biocompatible Responsive Polypyrrole/GO nanocomposite ... · Biocompatible Responsive Polypyrrole/GO nanocomposite Coatings for biomedical applications A. Madhan Kumar a*, Bharathi

10 20 30 40 50 60 702 Theta (degree)

PGO2

pure PPy

Inten

sity,

(A.U

.)

(001)

GO

(001)

200 300 400 500 600 700 8001

2

3

4

5

6 Pure PPy GO PGO2

Abso

rban

ce (A

.U.)

Wavelength (nm)

Figure S3 XRD pattern of GO, pure PPy and PGO nanocomposite coatings.

Figure S4

Page 4: Biocompatible Responsive Polypyrrole/GO nanocomposite ... · Biocompatible Responsive Polypyrrole/GO nanocomposite Coatings for biomedical applications A. Madhan Kumar a*, Bharathi